United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park. NC 27711
EPA - 454/R-00-024
May 2000
Air
&EPA
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Instrumental Methods Testing
Asphalt Plant C
Los Angeles, California
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Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Instrumental Methods Testing
Asphalt Plant C
Los Angeles, California
Final Report
For U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring, and Analysis Division
Emission Measurement Center (MD-19)
4930 Old Page Road
Research Triangle Park, North Carolina 27709
Mr. Michael L. Toney, Work Assignment Manager
EPA Contract No. 68-D-98-027
Work Assignment No. 3-02
MRI Project No. 4952-02
U.S. environmental Proton Agenc,
Region 5, Library (PL-12J) othFta- *'
77 West Jackson Boulevard. 12th fWf
Chicago. IU 60604-3590
Midwest Research Institute • 425 Volker Boulevard • Kansas City, Missouri 64110-2299
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under
contract 68-D-98-027 to Midwest Research Institute. It has been subjected to EPA's
review, and it has been approved for publication as an EPA document. Mention of trade
names or commercial products is not intended to constitute endorsement or
recommendation for use.
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Preface
This report was prepared by Midwest Research Institute (MRI) for the U.S.
Environmental Protection Agency (EPA) under EMC Contract No. 68-D-98-027, Work
Assignment Number 3-02. A draft of this report was prepared previously under WA 2-04.
Mr. Michael Toney is the EPA Work Assignment Manager. The MRI Work Assignment
Leader is Mr. Scott Klamm and Mr. John Hosenfeld is the Program Manager of MRI's
contract with EMC.
This report presents the results from an emissions test using FTIR spectroscopy and
FID at a hot mix asphalt plant.
MIDWEST RESEARCH INSTITUTE
Scott Klamm
Work Assignment Leader
Approved:
John Hosenfeld
Program Manager
Paul Constant
Acting Director
Applied Engineering
May, 2000
MR]-AED\R4951-04-08.»pd 111
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Glossary
ASTM—American Society for Testing and Materials
GEMS—Continuous Emissions Monitoring System
CO—Carbon Monoxide
CTS—Calibration Transfer Standard
EMAD—Emissions Measurement and Analysis Division
EMC—Emissions Measurement Center
ESP—Electrostatic Precipitator
FID—Flame lonization Detector
FTIR—Fourier Transform Infrared Spectroscopy
HAP—Hazardous Air Pollutant
MRI—Midwest Research Institute
NO—Nitric Oxide
NO2—Nitrogen Dioxide
N2O—Nitrous Oxide
NOX—Nitrogen Oxides (generally comprised of the chemical species NO, NO2 and N2O)
PES—Pacific Environmental Services
PTE—Permanent Total Enclosure
RAP—Recycled Asphalt
RTFOT—Rolling Thin Film Oven Test
SED—Silo Emissions Duct
SF6—Sulfur Hexafluoride
SMTG—Source Measurement Technology Group
SO2—Sulfur Dioxide
TED—Tunnel Emissions Duct
THC—Total Hydrocarbons
VOST—Volatile Organic Sampling Train
MRI-AEDXR4951 -04-08.wpd
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Contents
Preface iii
Figures ix
Tables ix
Executive Summary xi
Section 1. Introduction 1-1
1.1 Background 1-1
1.2 Project Summary 1-1
1.3 Project Personnel 1-3
Section 2. Process Description and Test Locations 2-1
2.1 Process Description 2-1
2.2 Test Locations 2-3
Section 3. Test Results 3-1
3.1 Objectives and Test Matrix 3-1
3.2 Field Test Changes and Problems 3-7
3.3 Summary of Test Results 3-7
3.4 Line Calibration Checks 3-21
Section 4.
Sampling and Analytical Methods 4-1
4.1 Sampling System Description 4-1
4.2 Sampling Procedures 4-4
4.3 FTIR Analytical Procedures 4-4
4.4 Total Hydrocarbon Sampling Procedures 4-9
Section 5. QA/QC Summary 5-1
5.1 Sampling and Test Conditions 5-1
5.2 FTIR Spectra 5-2
5.3 Method 25A 5-3
Section 6. References 6-1
Appendices
Appendix A—Process Data
Appendix B—Process Stack Testing Raw Data Sheets
Appendix C—Direct (Extractive) FTIR Results
Appendix D—Sample Concentration FTIR Results
Appendix E—THC Data
Appendix F—SF6 Capture and Loadout Summaries
Appendix G—SF6 Gas Release Data
Appendix H—Loadout Raw Data
Appendix I—Sample Concentration Procedure and Raw Data Sheets
Appendix J—Equipment Calibration Data
MRI-AEDXR4951 -04-08. wpd
VII
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Figures
Figure 2-1. Process Flow Schematic 2-2
Figure 2-2. Load-Out Station, Top View 2-4
Figure 2-3. Load-Out Station, Side View 2-5
Figure 2-4. Hot Mix Drying Exhaust System 2-6
Figure 3-1. Capture System with Tracer Gas Placement 3-6
Figure 3-2. Process Stack Concentration (7/21/98) 3-12
Figure 3-3. Process Stack Concentrations (7/22/98) 3-12
Figure 3-4. THC Concentrations During Intermittent Loadout Testing 3-18
Figure 4-1. Extractive Sampling System 4-2
Tables
Table 1-1. Project Personnel 1-3
Table 3-1. Summary of Sampling and Analysis Parameters 3-2
Table 3-2. Summary of Test Run Times 3-8
Table 3-3. Source Gas Composition and Flow Summary 3-9
Table 3-4. Dryer Stack Emissions Summary 3-11
Table 3-5. SED Emissions Summary 3-13
Table 3-6. TED Emissions Summary 3-14
Table 3-7. THC Emissions Summary 3-16
Table 3-8. Intermittant Loadout Summary and Statisical Analysis 3-17
Table 3-9. SF6 Capture Efficiency Calculations 3-20
Table 3-10. Calibration Standard Line Check Results 3-21
Table 4-1. Program Input for FTIR Analysis (Loadout and Silo Samples 4-6
Table 4-2. Program Input for FTIR Analysis (Process Stack and Tenax Samples) .... 4-7
Table 4-3. Program Input for Analysis of CTS Spectra 4-9
Table 4-4. Path Length Determinations From the Analysis of
Hot (397 K) CTS Spectra 4-9
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Overview
Test results are summarized in Table ES-1, and show both average concentrations and
emission factors for the Plant C test program. Three types of samples were collected as
part of this test program. Production emissions were collected from the process dryer stack
(two test runs), silo filling emissions were measured at the Silo Emissions Duct (SED,
three test runs, collected simultaneous with the loadout testing), and loadout emissions
testing was conducted at the tunnel exhaust duct (TED, three test runs). A fourth,
background, emissions test was also performed at the TED location to measure emissions
due to truck traffic alone. Note that no emission factor can be calculated for the
background test, since no truck loading was underway at the time.
The data in Table ES-1 are broken into two primary categories. First, all
concentrations and emission factors are reported on an "as measured" basis. These values
are derived directly from the instrument readings, flow measurements, and truck loading
data collected while on-site. Second, tracer gas testing at the TED location allowed a
determination of capture efficiency to be made. The average capture efficiency for all
three runs was 61% (determined by the 90% lower confidence limit approach), and was
45% for the background run. Table ES-1 includes the capture efficiency corrected TED
concentrations and emission factors.
With the exception of Total Hydrocarbon (THC, by Method 25A) data, all
concentrations reported in the table were determined by direct (extractive) Fourier
Transform Infrared Spectroscopy (FTIR, by Method 320). Many additional compounds,
particularly SO2 and NOX, were analyzed for, but were not detected, and are therefore not
included in the main summary table. A Tenax sample concentration technique (with FTIR
analysis) was also used for this test program, but did not reveal the presence of any
additional analytes. The Tenax sample concentration results, although qualitative, thus
suggest that the extractive FTIR detection limits reported in Appendix C may be high by a
factor of as much as 30-40.
MRI-AED\R4951-04-08 wpd XI
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Table OV-1. Summary of Results—Average Concentrations and Emission Factors
Propane
Methane
CO
Hydrocarbon
Mixture A1
Hydrocarbon
Mixture B'
Ethylene
Formaldehyde
Isooctane
THC2
As measured
Dryer stack production
Ppm
2.05
55.4
62.6
ND
ND
ND
ND
ND
19.0
Ib/ton
7.14x10"
8.00 x10'3
1.44x102
-
-
-
-
-
7.34 x 10'3
SED production
ppm
ND
6.43
80.0
104
202
8.24
7.33
5.63
5.26
Ib/ton
-
2.44 x 10 5
4.33x10"
1.83X103
4.20x10-3
3.95 x 10s
5.24 x 10s
1.48X104
5.29 x 10 3
TED production
ppm
ND
3.20
5.73
0.0100
3.03
0.0833
0.00800
ND
7.50
Ib/ton
-
1.64 x 10 4
5.20 x 10 4
3.75 X 10 6
8.36x10"
6.35 x 10 6
5.20x10'
-
1.14 x10'3
TED background
ppm
ND
3.00
3.50
ND
ND
ND
ND
ND
1.20/0.8303/1.60"
Capture Efficiency Corrected5
TED production
ppm
ND
5.29
9.54
0.0154
5.02
0.144
0.148
ND
12.4
Ib/ton
-
2.66x10"
8.44x10"
5.74 x 10 6
1.36x103
1.07x105
9.57 x 10 7
-
1.85X10-3
TED background
ppm
ND
6.67
7.78
ND
ND
ND
ND
ND
2.67/1 .843/3.56"
ND = Not detected.
1 Together, "hydrocarbon mixture A" and hydrocarbon mixture B" represent the best least-squares spectral fit for a nonaromatic hydrocarbon mixture. Mixture A was
quantitated using reference spectra for toluene, and Mixture B was quantitated using reference spectra for hexane.
2 Method 25A, determined as ppm propane.
3 Value taken from first half of background test (Run 4).
' Value taken from second half of background test (Run 4).
6 Using 90% lower confidence limit capture efficiencies for each run (Run 1 = 64%, Run 2 = 65%, Run 3 = 54%, Run = 45%).
MRI-AED\R4951 -04-08. wpj
Xll
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Section 2.
Process Description and Test Locations
2.1 Process Description
This plant was selected for the emissions testing due to its high production rate and
enclosure/ventilation of the storage silos and load-out bay.
The Plant C facility has a rated production capacity of 650 tons per hour (tph). Daily
production varies from approximately 2,000 tons per day (tpd) to 6,000 tpd depending on
demand. The plant produces five different categories of asphalt cement, 3/8 in, 1/2 in,
3/4 in, fines, and recycled asphalt (RAP). These categories indicate the average size and
type of aggregate in the mix. In RAP, small amounts of recycled asphalt are added to the
mix. The plant also adds small amounts of rubber to some products as a crack inhibitor.
The plant uses two different kinds of liquid asphalt, AR-4000 and AR-8000. AR-4000
is a softer asphalt with a higher volatile content and is used approximately 90% of the time.
The percent by weight of liquid asphalt in the mix varies from 4.8% to 6.0% depending on
the size of the aggregate (the smaller the aggregate, the higher the liquid asphalt content).
A schematic of the process is provided in Figure 2-1.
2.1.1 Aggregate Processing Operations
In this continuous process, cold aggregate is introduced to the rotary drum dryer. The
dryer dries the cold aggregate and then mixes the heated and dried aggregate with the
liquid asphalt cement. As the drum rotates, the aggregates move toward the other end of
the drum. Asphalt cement and recycled asphalt pavement (RAP) are typically introduced
either midway down the drum or at the end of the drum in a lower temperature zone. A
ventilation system exhausts the gases and condensed paniculate from the rotary drum dryer
through a baghouse and exhaust stack.
2.1.2 Load-Out Operations
Five 200-ton heated silos sit on top of a load-out tunnel. The silos serve as a holding
station between production and the loading of the asphalt cement into transport trucks. The
asphalt cement in storage can have a temperature up to 160°C (320 °F). The load-out
tunnel is approximately 183 ft long. During a full load-out schedule, trucks enter the
tunnel approximately every 3 min. Single bed trucks hold approximately 21 tons of asphalt
cement. Dual bed trucks (i.e., a truck and trailer) hold approximately 25 tons. The
temperature of the asphalt cement as it drops from the silo into the truck is approximately
300°F.
MR!-AED\R4951-04-08.wpd 2-1
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Atmosphere
Stack
Hot Mix
Asphalt
Fan
Baghouse
r
Natural Gas
Fired
Rotary Drum
Dryer
Secondary
Chamber
....
. - ..
....
• - - •
J
«-
-*
*-
-*
*-
->
*-
-^
L»-
(
t
Silos
5 total)
Smog
Hog +
E.S.P.
l r
Permanent
Total
Enclosure
(PTE)
Fan
\ I—Rubber
'•—-RAP
Aggregate
• Liquid Asphalt
Asphalt Storage Tanks
Figure 2-1. Process Flow Schematic
•Atmosphere
Air Flow
Material Flow
980524
MRI-AED\R4951-04-08.wpd
2-2
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The truck is positioned under the silo containing the desired aggregate where it is
loaded into the truck bed. During loading, emissions are captured by activating a double-
slotted capture hood located at each silo. With the truck positioned under the silo, one
free-standing slot will be at the forward edge and one at the aft edge of the truck bed. No
more than one silo can operate at a given time and only the capture hood associated with
that silo is activated to capture the emissions. It typically takes 15 to 30 seconds to load a
truck. However, the activated capture hood continues operating until the next truck enters
and another silo/capture hood is activated. One capture hood is always active, even when
no loading is occurring. Constant flow is maintained by the fan setting, thus, a constant
airflow is always exhausted from the load-out tunnel to the emission abatement system.
2.2 Test Locations
Figures 2-2 and 2-3 show the load-out and silo storage combined ventilation system
from the top and side, respectively. Finished product from the aggregate process is
conveyed into the five heated silos located above the truck load-out bay. A header captures
emissions from the storage silos and where it is ducted to the load-out bay emission
abatement system.
2.2.1 Outlet Duct, Storage Silo No. 2 Vent System
Sampling Location No. 1 was positioned at the outlet duct of storage silo No. 2 prior
to connection to the common silo storage ventilation system. Since no isokinetic sampling
was performed by MRI at this location, sample collection was taken at a single point.
2.2.2 Outlet of the Load-Out Bay Ventilation System
Sampling Location No. 2 was positioned between Silos 1 and 2 along the common
header to the Smog Hog. This was a 36-in diameter round duct with a horizontal gas flow.
Since no isokinetic sampling was performed by MRI at this location, sample collection was
taken at a single point. This location is upstream of Silo 1, so no emissions data from
Silo 1 load-out were gathered during this test program.
2.2.3 Hot Mix Drying Exhaust System
Figure 2-4 shows the hot mix process drying exhaust system. This was a
54 in x 36 in rectangle duct with six 5-in ports. Since no isokinetic sampling was
performed by MRI at this location, sample collection was taken at a single point, but the
entire duct was traversed by MRI in order to collect the appropriate measurements of gas
temperature, flow rate, moisture, CO2, and O2.
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2-3
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Smog Hog
E.S.P.
Silo Storage System
Exhaust Ducting
.Sampling Location No. 2
Load-Out
Exhaust
Ducting
.Sampling Location No. 1
Tunnel Entrance
Silo Storage
Hot Mix
Storage Silos
(5 total)
*• Tunnel Exit
Figure 2-2. Load-Out Station, Top View
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2-4
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Sampling Location No. 3
6 Ports (~ 5" diameter)
Side View
980524
Fan
Figure 2-4. Hot Mix Drying Exhaust System
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2-6
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Section 1.
Introduction
1.1 Background
The United States Environmental Protection Agency (EPA) is investigating hot mix
asphalt plants to identify and quantify paniculate matter and organic hazardous air
pollutants (HAPs) emitted from asphalt cement load-out operations. EPA issued a work
assignment to Midwest Research Institute (MRI) to conduct an air emissions test program
to collect data in support of the investigation. The testing program was conducted through
EPA Contract No. 68-W6-0048, Work Assignment No. 2-08, and results are presented in
this report.
The test facility (referred to as "Plant C") was selected as the host facility for this
project, primarily because load-out emissions are controlled by a silo exhaust system and a
load-out tunnel. The plant has a production capacity of 650 tons per hour (TPH).
The primary objective of the project was to characterize air emissions of organic HAPs
from asphalt cement load-out operations and operation of the hot mix dryer. Testing was
performed to characterize emissions from the storage silos, the load-out tunnel, and the hot
mix dryer. Section 1.2, below, summarizes the specific measurements collected during the
various tests.
In addition to MRI's testing, manual samples were collected simultaneously by Pacific
Environmental Services, Inc. (PES) in order to address all needs of the work request.
Work performed by PES was under a separate work assignment and discussion of this
additional testing is outside the scope of this report.
1.2 Project Summary
The site selected for performing the emissions tests performs all truck loading
operations inside a tunnel approximately 183 ft in length with open doorways at both ends.
During loading, emissions are captured by activating a double-slotted capture hood located
at each individual silo. Thus, the tunnel, ventilation system, and capture hoods work
together to form a near-total enclosure for determination of mass emissions for the loading
operations.
The selected test site, however, did not meet all of the criteria for a permanent total
enclosure (PTE) as defined by EPA Method 204, "Criteria for Verification of a Permanent
or Temporary Total Enclosure," Federal Register, Vol. 62, No. 115, June 16,1997.
Specifically, the chosen test site did not meet all the criteria for building geometry, or
average face velocity across the two doorways. A building which does not meet criteria for
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PTE is required to undergo capture efficiency testing in order to demonstrate effectiveness
of the air handling system. Preliminary capture efficiency tests were conducted at the site
during the week of May 11-15,1998, and capture efficiency tests were also performed in
conjunction with the tests described in this report.
Three ventilation system tests and a capture efficiency test on the load-out system
(alone) were performed to determine emissions at the facility. The three ventilation
systems are referred to as the load-out system, the silo storage system, and the hot mix
dryer system. Two or three test runs were performed to test each ventilation system, as
summarized below:
• The Load-out system was tested for HAPs, CO, SO2, and NOX, using extractive
Fourier Transform Infrared Spectroscopy (FTIR) (EPA Method 320) and FTIR
with sample concentration; and for total hydrocarbons (THC) using a flame
ionization detector (FID) (Method 25A). Three test runs were performed during
normal load-out operations. A fourth test run was also performed with trucks
traversing the load-out area while no loading was occurring in order to determine
background emissions contributed by diesel truck exhaust.
• The Silo storage system was tested for HAPs, CO, SO2, and NOX, using extractive
FTIR (EPA Method 320) and FTIR with sample concentration; and for total
hydrocarbons (THC) using a flame ionization detector (FID) (Method 25A). This
storage system was tested intermittently with the load-out system whenever silo
loading operations occurred, and was not included in the background test.
• The Hot mix dryer system was tested for HAPs, CO, SO2, and NOX, using
extractive FTIR (EPA Method 320) and FTIR with sample concentration; and for
total hydrocarbons (THC) using a flame ionization detector (FID) (Method 25A).
Two test runs were performed.
• Capture efficiency tests of the load-out system were also performed
simultaneously with the load-out system and silo storage system tests. Tracer gas
was released from a manifold in the load-out bay, was collected by the ventilation
system, and air concentrations were measured, allowing capture efficiency to be
calculated.
The load-out and silo storage ventilation systems combine into one common duct
which passes through an electrostatic precipitator and is exhausted to air. Testing for the
load-out system was performed at a port located between Silos 1 and 2, which is upstream
of the combined common duct. Similarly, the silo storage testing was performed from an
extension at the top of Silo 2, which is also located upstream of the combined common
duct.
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1.3 Project Personnel
This EPA project is administered by the Emission Measurement Center (EMC). The
test request was initiated by the Emission Factor and Inventory Group (EFIG) of the
Emission Standards Division (ESD), both from the Office of Air Quality Planning and
Standards (OAQPS). Key project personnel are listed below in Table 1-1.
Table 1-1. Project Personnel
Organization Name and title Phone number
U.S. EPA EMC Michael Toney, Work (919) 541 -5247
Assignment Manager (919) 541 -1039 (fax)
Asphalt Plant C Richard Burnett, Manager (909) 736-7600
Corporate Operations
Asphalt Plant C Pat McClure, Plant Operator (949) 786-1290
Midwest Research Institute Scott Klamm, Work (816) 753-7600, ext. 1228
425 Volker Boulevard Assignment Leader (816) 531-0315 (fax)
Kansas City, MO 64110
Midwest Research Institute John Hosenfeld, Program (816) 753-7600, ext. 1336
425 Volker Boulevard Manager (816) 531 -0315 (fax)
Kansas City, MO 64110
MRI-AEDVR4951 -04-08 wpd
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Section 3.
Test Results
Three ventilation systems were tested to determine emissions at the facility: load-out,
silo storage, and hot mix dryer. Two test runs were performed on the hot mix dryer, while
three test runs were performed at the load-out and silo storage systems. A fourth,
background, test run at the load-out system was also performed to characterize emissions
from the truck exhausts. Testing at these systems is discussed below.
3.1 Objectives and Test Matrix
Objectives for the testing program were as follows:
• Perform three tests of the silo storage system for HAPs, CO, SO2, and NOX using
extractive FTIR (EPA Method 320) and FTIR with sample concentration; and for
THC using Method 25 A.
• Perform three tests of the load-out system for HAPs, CO, SO2, and NOX using
extractive FTIR (Method 320) and FTIR with sample concentration; and for THC
using Method 25 A. Also perform a fourth, background test to determine
emissions contributed by the truck diesel exhaust alone.
• Determine capture efficiency of the load-out system simultaneously with the load-
out emissions testing.
• Perform three tests of the hot mix dryer system (process stack) for HAPs, CO,
SO2, and NOX using extractive FTIR (EPA Method 320) and FTIR with sample
concentration; and for THC using Method 25A.
An additional, minor objective of the test program was to characterize emissions from
intermittent loading (4 x 5.5-ton drops) relative to normal loading (1 x 22-ton drops) by
THC (Method 25A).
Due to process problems, only two tests of the hot mix dryer system (process stack)
were performed. For the load-out testing, three test runs and a background run were
performed. Three tests of the silo storage system were also completed, as well as the
intermittent loading test. Table 3-1 summarizes the matrix completed by the field
activities, and Sections 3.1.1 to 3.1.3 briefly describe the test activities.
Three different types of measurements were performed with the FTIR system. First,
an extractive sampling system was used to transport sample gas from the sampling location
MRl-AED\R4951-04-08.wpd
3-1
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Table 3-1. Summary of Sampling and Analysis Parameters
No. of
test
runs
3
1
Test Condition
Load-Out
Background (No
load-out
operations)
Sample
Load-out duct
emissions
Load-out duct
capture efficiency
Storage silo duct
Incremental load-
out emissions,
4x5.5-ton vs
1x22-ton
Load-out duct
emissions
Load-out duct
capture efficiency
Sampling
port location
No. 2
No. 2
No. 1
No. 2
No. 2
No. 2
Sample frequency for
each run
4-hr continuous extractive
sampling
4-hr composite per run
Continuous during 4-hr run
4-hr continuous extractive
sampling
Intermittent sampling,
coincident with silo loading
operations
Estimated 2-hr composite
per run
Continuous during run
Continuous, as time and
plant conditions allow
4-hr continuous extractive
sampling
4-hr composite per run
Continuous during 4-hr run
4-hr continuous extractive
sampling
Sampling method
Extractive FTIR
Method 320
Adsorbent trap
Method 25A
Extractive FTIR
Method 320
Extractive FTIR
Method 320
Adsorbent trap
Method 25A
Method 25A
Extractive FTIR
Method 320
Adsorbent trap
Method 25A
Extractive FTIR
Method 320
Analytical
parameters
CO, S02,
NOX, HAPs
HAPs
THC
SF6
CO, S02,
NOX, HAPs
HAPs
THC
THC
CO, S02,
NOX, HAPs
HAPs
THC
SF6
Analytical
method
FTIR
Spectral analysis
Desorption/FTIR
spectral analysis
FID
FTIR spectral
analysis
FTIR
Spectral analysis
Desorption/FTIR
spectral analysis
FID
FID
FTIR
Spectral analysis
Desorption/FTIR
spectral analysis
FID
FTIR spectral
analysis
MRI-AED\R4951-04-08.wpd
3-2
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Table 3-1 (Continued)
No. of
test
runs
2
Test Condition
Hot Mix Process
Operations
Sample
Hot mix drying
stack
Sampling
port location
No. 3
Sample frequency for
each run
3-hr continuous extractive
sampling
3-hr composite per run
Continuous during 3-hr run
Once per run
3-hr composite
3-hr composite
Sampling method
Extractive FTIR
Method 320
Adsorbent trap
Method 25A
Methods 1 and 2
Method 3
Method 4
Analytical
parameters
CO, SO2,
NOX, HAPs
HAPs
THC
Velocity
Temperature
02, C02
Stack H2O
Analytical
method
FTIR
Spectral analysis
Desorption/FTIR
spectral analysis
FID
Pitot tube
Thermocouple
Orsat
Gravimetric
MRI-AED\R4951-04-08.wpd
3-3
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directly to the FTIR gas cell where the spectra were recorded. This is referred to as
"extractive" or "direct" sampling. Second, in the "sample concentration" procedure, a
manual sampling train was used to collect a measured volume of gas onto a tube packed
with Tenax sorbent. Contents of the tube were then heated and desorbed into the gas cell
where the spectrum was recorded. Third, in the capture efficiency study, a metered volume
of sulfur hexafluoride (SF6) gas was released into the loadout tunnel while extractive
measurements were being conducted. The SF6 measured by the FTIR system was assumed
to be equivalent to the SF6 taken up by the loadout tunnel ducts. These procedures are all
described more fully in Section 4.
3.1.1 Hot Mix Dryer (Process Stack) Testing
The hot mix dryer system was tested for HAPs, CO, SO2, NOX, and other compounds
for which there are reference spectra using extractive FTIR and sample concentration with
FTIR analysis. In addition to FTIR spectroscopy, monitoring for THC using FED per
Method 25 A was performed. Two 3-hr runs of testing during normal process operations
were performed.
During the dryer testing, MRI monitored the process and baghouse operating
conditions. Parameters were logged manually or obtained from plant logs, where
applicable. Manual readings were logged every 15 min. Some of the parameters
monitored were:
• Feed rate of aggregates
• Feed rate of liquid asphalt
• Liquid asphalt temperature
• Mix temperature
• Natural gas usage rates
• Baghouse pressure drop
Several operational problems were encountered during the dryer stack testing which
contributed to process instability and generation of inconsistent emissions data. First, high
moisture was present in the aggregate feeds due to heavy rainfall in the region (post El
Nino conditions). Also contributing to high moisture were large amounts of soil/humus
material in the RAP, which was considered to be of poor quality. This additional moisture
created difficult production conditions in which the stack emissions varied significantly
towards the end of each run. Time plots presented later in this report (Section 3.3.1)
clearly show these trends.
Appendix A contains summaries of the process operating data collected during the
testing. Appendix B contains raw data from the manual methods operated during the
process stack testing.
MRI- AEDVR4951 -04-08. wpd
3-4
-------
3.1.2 Tunnel Emissions Duct (TED) Testing
Emissions from the load-out system were tested simultaneously with the silo emissions
duct (SED) using extractive FTIR, sample concentration with FTIR analysis, and THC
analysis. Each test period was approximately 4 to 5 hours in length, and also corresponded
to time periods of manual sample collection by PES.
Concurrent with FTIR testing of the load-out emissions discussed above, capture
efficiency testing at this location was also performed. Simultaneous with sampling at this
location, tracer gas (SF6) was released at whichever silo was currently active (Nos. 2
through 5). Thus, four separate gas release manifolds were placed within the load-out
tunnel, one along the wall near each of the silos (Nos. 2 through 5). As the capture hood
for any one of the silos was activated, an MRI operator also activated tracer gas flow to that
particular release manifold. Tracer gas was released at a constant rate (measured by a mass
flowmeter). Each manifold dispersed tracer gas evenly from six nozzles spaced along its
length (Figure 3-1). For each set of six nozzles, two nozzles were directed generally
upwards at 45°, two were directed generally downward at 45°, and two were directed
horizontally. Sample spectra were collected by extractive FTIR, where concentrations
were determined and converted to mass emissions over time. These were compared to the
measured tracer gas emission rate, allowing duct capture efficiency to be calculated.
Results are presented later in Section 3.3.3.
A stable, nonflammable gas (sulfur hexafluoride, or SF6) was used as the tracer gas.
Approximately 41pm of 2% sulfur hexafluoride was released, resulting in an air
concentration of around 0.10 to 0.20 ppm, a concentration level easily detected
(approximately 0.05-0.10 absorbance units) by extractive FTIR with an approximately
10-m pathlength.
THC monitoring was also conducted to perform a comparison test of emissions
generated from incremental loading versus total loading. The facility normally operates
using total loading, with a 22-ton loadout being dropped all at one time. Using incremental
loading, a 22-ton loadout was instead dropped as four 5.5-ton loads, one after the other.
Response of the THC served as a measure of total emissions. This test was performed
separately from other load-out testing and provided rough information on expected
emission levels for an upcoming test at a batch mix facility (Plant D). Intermittent loadout
test results are reported later in Section 3.3.2.
3.1.3 Silo Emissions Duct (SED) Testing
Testing at the silo location was performed concurrently with the load-out system
testing during periods in which loading of silo No. 2 occurred. Thus, the silo storage
testing was divided into several periods of 15 to 160 min each throughout a 4-hr load-out
emissions test run. Three test runs were performed at a rate of one run per day.
MRI-AEDNR4951-04-08 wpd
3-5
-------
O O 0 \
o o o /
Capture Hood
SF6 Dispersion Manifold
s-*^ ^—v r \.
990203
End
View
Figure 3-1. Capture System with Tracer Gas Placement
MRI-AED\R4951-04-08 wpd
3-6
-------
3.2 Field Test Changes and Problems
1. Due to process problems on July 20, a test run of the process stack (hot mix dryer)
could not be performed. Two tests of the process stack were performed, one each
on July 21 and July 22.
2. Due to process problems on July 21, the test of the process stack (hot mix dryer)
was shortened from the planned 4-hr to 3-hr. The second test of the hot mix dryer
(July 22) was thus also reduced to a 3-hr test to provide consistency between the
two data sets.
3. Failure of the load-out damper on Silo No. 2 on July 23 created conditions which
prevented the collection of representative samples. Testing for that day was
aborted and facility maintenance was performed. No analysis of the partially
collected samples was performed.
4. High moisture created sampling difficulties during Run 3 at the SED for the
extractive FTIR. As a precautionary measure, the FTIR sample collection was
changed from continuous to grab sampling during the indicated time periods.
Thus, the reported data is from three grab samples collected over a 20-minute time
period, and is therefore less informative about the overall process than data from
Runs 1 and 2.
3.3 Summary of Test Results
Table 3-2 summarizes the run times for each of the test methods. Table 3-3
summarizes the measured air flow rates and gas composition data for the test program.
As a general note, the extractive FTIR method provides the most direct analyte
measurements and proved to be the most useful technique for identification and
quantitation of analytes. Because the sample is untreated, the gas was composed primarily
of moisture and CO2, both of which are spectral interferences. These interferences limited
the measurements of many compounds to the low-ppm concentration range. No additional
target analytes were detected in the sample concentration spectra, which indicates that the
quantitation limits were actually lower. The Method 25 A results were consistent with the
direct FTIR results. Complete extractive FTIR results tables are presented in Appendix C,
sample concentration FTIR results are presented in Appendix D, and THC data are
presented in Appendix E. Orientation limits for ND (not-detected) compounds are
contained in Appendix C.
MRI-AED\R4951 -04-08.wpd
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Table 3-2. Summary of Test Run Times
Date
Inclusive run
time
THC times
FTIR times
Tenax
sampling
times
Velocity
traverse
Moisture train
Dryer stack
Run 1
7/21/98
0930-1421
1120-1209
1218-1238
1249-1302
1305-1318
1320-1332
1338-1420
1137-1232
1240-1420
1121-1421
0930-0950
1122-1420
Dryer stack
Run 2
7/22/98
0902-1246
0935-1056
1104-1237
0937-1110
1129-1235
0935-1236
0902-0916
1229-1246
0936-1234
Loadout/silo
emissions
ducts
Run 1
7/24/98
0720-1258
0720-0805
(SED)
0814-0917
(TED)
0936-1030
(SED)
1036-1257
(TED)
0725-0805
(SED)
0805-0915
(TED)
0921-0935
(TED)
0935-1030
(SED)
1057-1258
(TED)
0720-1257
(TED)
0720-0801
(SED)
0858-0913
(SED)
0921-1030
(SED)
NA
NA
Loadout/silo
emissions
ducts
Run 2
7/25/98
0710-1126
0710-1118
(TED)
0845-0925
(SED)
0711-0844
(TED)
0844-0927
(SED)
0927-1112
(TED)
0710-1126
(TED)2
0715-0808
(SED)
0844-0958
(SED)
NA
NA
Loadout/silo
emissions
ducts
Run3
7/27/98
0705-1200
0710-1200
(TED)
0720-0737
(SED)
0750-0930
(SED)
1010-1200
(SED)
0705-0933
(TED)
0955-1040
(TED)
1051-1112
(SED)1
1115-1200
(TED)
0710-1152
(TED)2
0710-0951
(SED)
NA
NA
Loadout/silo
emissions
ducts
(background)
Run 4
7/26/98
0923-1347
0925-1125
1148-1345
0923-1126
1150-1347
0925-1125
(TED)
1145-1345
(TED)
NA
NA
1 Batch or grab sampling
2 Duplicate sample also collected
NA = Not applicable
MR1-AEDNR4951-04-08. wpd
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-------
Table 3-3. Source Gas Composition and Flow Summary
Date
Dryer stack
Run 1
7/21/98
Dryer stack
Run 2
7/22/98
Loadout/silo
emissions
ducts
Run 1
7/24/98
Loadout/silo
emissions
ducts
Run 2
7/25/98
Loadout/silo
emissions
ducts
Run3
7/27/98
Loadout/silo
emissions
ducts
(background)
Run 4
7/26/98
Dryer Stack
Oxygen, %
Carbon
dioxide, %
Moisture
content, %
Volumetric
flow rate,
dscfm
wscfm
acfm
9.2
6.0
25.4
18,758
25,145
34,837
4.0
12.2
31.9
19,441'
28,548'
47,901
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Tunnel Emissions Duct (TED)
Oxygen, %
Carbon
dioxide, %
Moisture
content,2 %
Volumetric
flow rate,2
dscfm
wscfm
acfm
-
-
-
-
-
-
-
-
20.9
0.0
3.6
10,227
10,609
11,261
20.9
0.0
3.0
9,933
10,240
10,922
20.9
0.0
2.7
9,743
10,013
10,832
20.9
0.0
3.4
10,665
11,040
11,886
Silo Emission Duct (SED)
Oxygen, %
Carbon
dioxide, %
Moisture
content,3 %
Volumetric
flow rate,3
dscfm
wscfm
acfm
-
-
-
-
-
-
-
-
20.9
0.0
12.8
503
577
777
20.9
0.0
22.5
445
574
780
20.9
0.0
59.4
230
56
761
-
-
-
-
1 Average of two velocity traverses at beginning and end of test.
2 Average of two trains (PES data for Method 315 and Method 0010).
3 Data from single train operating during time period of FTIR sampling (PES data from Method 0010,
trains S-MM5-1, S-MM5-2, and S-MM5-3, respectively).
MRI-AED\R4951 -04-08.wpd
3-9
-------
3.3.1 Gaseous HAP Emission Results
Process Stack Results
Table 3-4 summarizes the gaseous HAPs identified by extractive FTIR in the process
dryer stack emissions. Figures 3-2 and 3-3 show time plots of the data, and indicate most
of emissions occurred later in the test run, when process stability became difficult to
maintain.
SEP Results
Table 3-5 summarizes the gaseous HAPs identified by extractive FTIR in the SED
during the loadout testing. Time plots of the individual species are presented in
Appendix C, and the FTIR results were consistent with the THC analyzer results.
TED Results
Table 3-6 summarizes the gaseous HAPs identified by extractive FTIR in the TED
during the loadout testing. As with the SED HAP data, above, time plots of the individual
species are presented in Appendix C, and the FTIR results were consistent with the THC
analyzer results.
Note that the SED emissions, both the measured concentrations and the volumetric
flowrates, were much more variable than the TED emissions.
Sample Concentration Results
The results from the sample concentration spectra were consistent with the load-out
quantitation limits calculated from the direct-FTIR spectra (Appendix C). The sample
concentration results indicate that the actual quantitation limits were lower than those
reported in Appendix C, because none of the analytes was detected in the sample
concentration spectra.
Preliminary measurements performed by PES during the site visit indicated that
toluene, meta- and para-xylenes might be present at concentrations between 60 and 75 ppb
(as measured by VOST). The preliminary results provided the justification for performing
sample concentration FTIR during the main field test. The sample concentration flow rates
and total collection volumes were calculated to provide the sensitivity to measure the target
analytes at those concentrations (i.e., concentration factor of approximately 50).
The sample concentration spectra were qualitatively similar to the direct-FTIR spectra
and toluene and the xylenes were not detected. The minimum sample concentration
quantitation limits were estimated to be about 50 ppb. Analysis of these spectra was
complicated by the presence of the non-aromatic hydrocarbon mixture that was measured
MRI-AED\R4951 -04-08.wpd
3-10
-------
in the direct FTIR samples. This hydrocarbon mixture was particularly high in the sample
concentration spectra of the silo emissions.
The non-aromatic hydrocarbon mixture in the TED sample concentration spectra was
measured as "hydrocarbon mixture B" (quantitated using hexane reference spectra) and the
results were compared to the direct-FTIR measurements. After correcting for the sample
concentration factor, the average measured mixture B concentration was 1.9 ppm in the
front-trap samples. This compares to an average mixture B concentration of 3 ppm
measured in the direct-FTIR samples. One would expect the sample concentration result to
be lower because some sample won't be recovered from the adsorbent material.
Table 3-4. Dryer Stack Emissions Summary
Compound emissions
Date
Flowrate (wscfm)
Propane (ppm, average)
Propane (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Methane (ppm, average)
Methane (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
CO (ppm, average)
CO (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
S02 (ppm)
Emission rate (g/hr)
Emission rate (Ib/hr)
NOX (includes NO, NO2, and N2O, ppm)
Emission rate (g/hr)
Emission rate ( Ib/hr)
Run 1
7/21/98
25,145
4.1
ND/75.1
320
0.71
42.5
ND/268
1207
2.66
103
ND/355
5118
11.3
ND
-
-
ND
-
-
Run 2
7/22/98
28,548
ND
-/-
—
-
68.3
ND/268
2202
4.85
22.1
ND/318
1247
2.75
ND
-
-
ND
-
-
wscfm = wet standard cubic feet per minute
ND = Not detected above practical quantitation limit
MRI-AED\R4951-04-08.wpd
3-11
-------
Process Stack Concentrations (7/21/98)
| -»- Propane -»- Methane -*-CO~|
330-
280
230-
E ISO
o.
PL,
130-
80-
30-
-20 -
11
;00 11:30 12:00 12:30 13:00 13:30 14:00 14:30
Time
Figure 3-2. Process Stack Concentration (7/21/98)
Process Stack Concentrations (7/22/98)
|-»-Propane -"-Methane -*-CO |
330
280 -
230 -
180 -
130
80-
30 -
-20
/i.
9:30 10:00 10:30
11:00 11:30 12:00 12:30
Time
13:00
Figure 3-3. Process Stack Concentrations (7/22/98)
MRl-AED\R4951-04-08.wpd
3-12
-------
Table 3-5. SEP Emissions Summary
Compound emissions
Date
Flowrate (dscfm)
Production rate (tons/hr)b
Asphalt temp, at loadout (°F)°
RTFOT Results (%)d
Methane (ppm, average)
Methane (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission f£ ctor (Ib/ton)
CO (ppm, average)
CO (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Hydrocarbon Mixture A6 (ppm, average)
Hydrocarbon Mixture A"(ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Hydrocarbon Mixture B" (ppm, average)
Hydrocarbon Mixture B" (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Ethylene (ppm, average)
Ethylene (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Formaldehyde (ppm, average)
Formaldehyde (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission rate (Ib/ton)
Isooctane (ppm, average)
Isooctane (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Run 1
7/24/98
577
398
321
-0.362
17
ND/37
11.1
0.024
6.1 X10-5
82
61/108
93
0.21
5.2x10-"
130
54/236
488
1.07
2.7 x 10-3
221
104/371
776
1.71
4.3X10-3
3.5
1 .4/4.7
4.0
0.0088
2.2 x10'5
19
ND/38
23
0.051
1.3x10-*
16
9.8/30
74
0.16
4.1 x 10-*
Run 2
7/25/98
574
278
316
-0.322
2.3
ND/17
1.5
0.0033
1.2x10"*
16
ND/105
18
0.040
1.4x10-*
7.5
ND/98
28
0.062
2.2x10-*
215
3.2/337
751
1.65
5.9X10-3
0.23
ND/3.3
0.26
0.00057
2.1 x 10-6
3.0
ND/32
3.6
0.0080
2.9X1Q-5
0.89
ND/7.9
4.1
0.0091
3.3 x 1Q-5
Run3"
7/27/98
567
550
291
-0.284
ND
-/-
-
-
-
142
ND/426
159
0.35
6.4 x 1Q-4
174
ND/522
641
1.41
2.6 x 10-3
170
126/233
586
1.29
2.3 X10-3
21
ND/63
23.5
0.052
9.4X10-5
ND
-/-
-
-
-
ND
—l~
-
-
'Due to sampling difficulties, grab or "batch" sampling procedure used. Emissions data is considered qualitative due to
reduced sampling frequency.
"Determined during time periods in which SED emissions monitoring by FTIR occurred.
cAverage value obtained from PES.
"Average value obtained from PES as per ASTM method D2872-88.
•Together, "hydrocarbon mixture A" and "hydrocarbon mixture B" represent the best least-squares spectral fit for a
nonaromatic hydrocarbon mixture. Mixture A was quantitated using reference spectra for toluene, and Mixture B was
quantitated using reference spectra for hexane.
ND = Not detected above practical quantitation limit.
MRI-AEDVR4951 -04-08.wpd
3-13
-------
Table 3-6. TED Emissions Summary
Compound emissions
Date
Flowrate (dscfm)
Loadout rate (tons/hr)a
Asphalt temp, at loadout (°F)b
RTFOT Results (%)°
Methane (ppm, average)
Methane (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
CO (ppm, average)
CO (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Hydrocarbon Mixture Ad (ppm, average)
Hydrocarbon Mixture Ad (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Hydrocarbon Mixture Bd (ppm, average)
Hydrocarbon Mixture Bd (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Ethylene (ppm, average)
Ethylene (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Formaldehyde (ppm, average)
Formaldehyde (ppm, min/max)
Emission rate (g/hr)
Emission rate (Ib/hr)
Emission factor (Ib/ton)
Run 1
7/24/98
10,609
478
321
-0.362
3.2
2.8/3.5
38.3
0.084
1.8x10-*
2.3
ND/14
48
0.11
2.2x10-*
ND
-/-
-
-
-
3.2
0.9/6.5
207
0.45
9.5x10-"
0.11
ND/0.7
2.3
0.0051
1.1 x10'5
ND
-/-
-
-
-
Run 2
7/25/98
10,240
391
316
-0.322
3.1
2.6/3.4
35.8
0.079
2.0x10-"
8.2
ND/17
166
0.365
9.3x10^
0.030
ND/3.2
2.0
0.0044
1.1 x1Q-5
2.8
0.7/6.2
174
0.38
9.8x10-*
ND
-/-
-
-
-
ND
-/-
-
-
-
Run 3
7/27/98
10,013
723
291
-0.284
3.3
2.8/4.2
37.3
0.082
1.1 X10-"
6.7
ND/18
133
0.29
4.0x10-"
ND
-/-
-
-
-
3.1
ND/6.4
189
0.42
5.8x10-"
0.14
ND/0.8
2.8
0.0061
8.4x10-"
0.024
ND/1.6
0.51
0.001 1
1.5X10-6
Run 4
7/26/98
11,040
-
-
-
3.0
2.7/3.2
37.4
0.082
-
3.5
ND/7.6
76
0.17
-
ND
-/-
-
-
-
ND
-/-
-
-
-
ND
-/-
-
-
-
ND
-/-
-
-
-
* Determined during time periods in which TED emissions monitoring by FTIR occurred.
b Average value obtained from PES.
c Average value obtained from PES as per ASTM method D2872-88.
d Together, "hydrocarbon mixture A" and "hydrocarbon mixture B" represent the best least-squares spectral fit for a
nonaromatic hydrocarbon mixture. Mixture A was quantitated using reference spectra for toluene, and Mixture B was
quantitated using reference spectra for hexane.
ND = Not detected above practical quantitation limit.
MRI-AED\R4951-04-08.wpd
3-14
-------
Tenax samples from the process stack SED were concentrated at a factor of
approximately 30-40, and could not quantitatively measure the non-aromatic hydrocarbon
fraction, since the relatively high concentrations encountered saturated the sorbent material.
It was evident from other regions of these spectra that additional analytes were not present,
and quantitation limits for these compounds are presented in Appendix C.
Toluene-d8 was spiked into some of the Tenax samples as a surrogate to evaluate the
sample percent recovery. The toluene-cfg was not detected in the spiked samples. Spectral
bands of toluene-rf8 are shifted to lower frequencies with respect to the toluene spectrum.
While this provides a potential advantage in discriminating between the spiked and
unspiked components, the lower frequency regions were more difficult to analyze for the
deuterated species. This was primarily because the spiked samples still contained
significant amounts of CO2 and moisture, which interfered with the toluene-J8 analysis.
For this technique to become more quantitative, further development of deuterated species
spiking procedures and/or more effective procedures for removal of moisture and CO2,
either spectrally or from the traps themselves, should be undertaken.
3.3.2 Total Hydrocarbon Emission Results
Table 3-7 summarizes the THC data for the test program. For the loadout (TED)
testing, average THC emissions were fairly consistent at 7.1 to 7.7 ppm. The emission rate
due to loadout operations was thus calculated to be 0.52 to 0.54 Ib/hr. Baseline (Run 4)
emissions were clearly present, but were much lower than the loadout emissions, and
averaged 0.8 ppm (0.057 Ib/hr) for the first half of the run, and 1.6 ppm (0.11 Ib/hr) for the
second half of the run.
Emissions at the SED were much more variable than those observed at the TED, due
to greater variation in both the measured THC concentrations and the gas flowrates.
Average THC concentrations ranged from 531 to 590 ppm for the test series, amounting to
roughly 1.8 to 2.3 Ib/hr. Note that the SED location, silo loading operations only occur
during a fraction of the work day.
In addition to the TED and SED testing, two tests were performed on the process dryer
stack. Average THC emissions were approximately 19 ppm for both of these tests,
amounting to about 3.3 to 3.7 Ib/hr.
In addition to the process dryer stack, TED and SED testing, a comparison of
"intermittent loadout" emissions was performed. This test was performed to provide rough
information on expected emission levels for an upcoming test at a batch mix facility
(Plant D). Using only the THC analyzer for measuring emissions, a series of asphalt
loadout drops were performed under controlled conditions. In Case 1, a typical 22-ton
loadout was performed as four 5.5-ton drops, spaced at approximately 30-sec intervals.
For Case 2, the 22-ton drop was performed all at once. Six drops of each type were
performed.
MR1-AED\R4951-04-08. wpd
3-15
-------
Table 3-7. THC Emissions Summary
Concentration (ppm as
propane)
Minimum
Maximum
Average
Emission rate (Ib/hr)
Production rate (tons/hr)
Emission factor (Ib/ton)
Dryer Stack
Run 1
5.1
63.5
19.2
3.3
494
6.7 x1(T3
Run 2
2.8
84.4
18.7
3.7
457
8.0 xKT3
Run 1
-
-
-
-
Run 2
-
-
-
-
Run 3
-
-
-
-
Run 4 Run 4
(1st (2nd
half) half)
-
-
-
-
-
-
-
-
Tunnel Emissions Duct (TED)
Concentration (ppm as
propane)
Minimum
Maximum
Average
Emission rate (Ib/hr)
Loadout rate (tons/hr)b
Emission Factor (Ib/ton)
-
-
-
-
-
-
-
-
-
-
-
-
0.0
26.0
7.1
0.52
453
1.1 x10'3
0.0
33.0
7.7
0.54
400
1.3X10'3
1.7
17.1
7.7
0.53
573
9.2x10-"
0.6
1.1
0.83
0.057
-
-
1.2
1.8
1.6
0.11
-
-
Silo Emission Duct (SED)
Concentration (ppm as
propane)
Minimum
Maximum
Average
Emission rate (Ib/hr)
Production rate (tons/hr)c
Emission factor (Ib/ton)
-
-
-
-
-
-
-
-
-
-
-
-
56.1
790
531
2.1
398
5.3 X10'3
28.9
656
456
1.8
278
6.4 x10'3
34.9
1000s
590
2.3
550
4.2 x10-3
-
-
-
-
-
-
-
-
-
-
-
-
Asphalt Conditions
Asphalt temp at loadout
(°F)d
RTFOT Results (%)"
—
-
—
-
321
-0.362
316
-0.322
291
-0.284
—
-
—
-
' Maximum reading of instrument.
b Determined during time periods in which TED emissions monitoring by THC occurred.
0 Determined during time periods in which SED emissions monitoring by THC occurred.
d Average value obtained from PES.
8 Average value obtained from PES as per ASTM method D2872-88.
MRI-AEDXR4951 -04-08.wpd
3-16
-------
Figure 3-4 shows THC emissions results from Case 1 and Case 2 loadout methods.
The THC integration time was set to 10-sec intervals to provide better resolution, and areas
under each peak were integrated as shown in the figure.
The two data sets are summarized in Table 3-8, and were examined to determine if
there was a significant difference between the means of each set. A Student's t-test was
performed as shown in the table.
The difference in means is 361 ppm-sec, or 32.3%. These two means were compared
using the Student two-sample t-test. First, the equality of variances in the two groups was
tested via an F-test. The calculated F-value was 1.93 with (5,5) degrees of freedom. This
value is not statistically significantly different from one (p-value of 0.49). Thus, the two
variances can be assumed to be equal at the 95% confidence level.
The t-value was then calculated as 1.59 with 10 degrees of freedom (6+6-2). The
significance level associated with this t-value is 0.14. Therefore, although there is a
361 ppm-sec difference in the mean values for Case 1 and Case 2, 361 ppm-sec is not
statistically different from zero at the 95% confidence level.
Table 3-8. Intermittent Loadout Summary and Statisical Analysis
Observations (ppm-sec)
Average (Mean)
Differences in Averages (ppm-sec)
Standard Deviation
Variance
Number of Observations
Casel
(4 x 5.5 ton)
1,564
2,304
1,243
1,524
1,189
1.040
1,477
361
452
204,304
6
Case 2
(1 x 22 ton)
1,243
917
1,729
935
936
934
1,116
326
106,276
6
Minute-by-minute summaries and time plots of the THC data are contained in
Appendix E. All THC data were calculated on a ppm as propane basis.
It should be noted that while 30-sec intervals between drops were used for this
equipment, the intervals between drops at the Plant D test were approximately 60-sec. The
Case 1 data resulting from drops at 60-sec intervals may be different than are presented in
Table 3-8. As a result, the statistical analysis would also be different.
MRI-AED\R4951 -04-08.wpd
3-17
-------
16.0
14.0
0.0
13:33:36 13:40:48 13:48:00 13:55:12 14:02:24 14:09:36 14:16:48 14:24:00 14:31:12 14:38:24 14:45:36 14:52:48
Time
Figure 3-4. THC Concentrations During Intermittent Loadout Testing
MRI-AED\R4951-04-08.w|xl
3-18
-------
3.3.3 Tracer Gas Capture Efficiency Test Results
Tracer gas capture efficiency was calculated using the lower confidence limit (LCL)
approach contained in the EPA guidance document EMC GD-036.1 Using this approach,
the LCL was determined at the 90% confidence limit, and capture data from each test run
was broken into 7 to 10 approximately equal time intervals of greater than 20 min each.
The exact number of individual time intervals for each run was dependent upon the raw
data and timing of SF6 data collection within the run. Similarly, not every individual time
interval was the exact same length, and actual time intervals varied from 21 to 21 min in
length, depending upon the data available for each run. Table 3-9 summarizes this
information and the LCL capture efficiency calculations.
As shown in Table 3-9, the 90%-LCL for the test series ranged from 54% to 65% for
the three loadout test runs. The reported tracer gas capture efficiencies are believed to be
underestimates of the actual emission capture efficiency. The tracer gas injection angles,
location, and direction imposed a more severe challenge to the capture system than the
emissions produced during loadout operations. The baseline test (Run 4) showed the
poorest 90%-LCL capture efficiency (45%) and may be partially explained by the
noticeably higher winds during the test. Of even greater importance, only two trucks were
operating during the baseline test, creating large time intervals in which winds into the
tunnel doorway were not blocked by awaiting truck traffic.
Appendix F contains a full summary of the SF6 capture data and time plots of the
measured SF6 concentrations with the corresponding asphalt loadout. SF6 gas release data
is summarized in Appendix G. Loadout raw data is contained in Appendix H.
MRI-AED\R4951-04-08.wpd
3-19
-------
Table 3-9. SFfi Capture Efficiency Calculations
Test conditions
Test date
Nominal test times (24-hr)
Elapsed time (min)
Silos operating
Loadout during capture tests (tons/hr)
Loadout during all testing (tons/hr)
Average release rate (LPM)
Gas SF6 concentration
Mass release rate (g/min)
Interval No."
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
No. 8
No. 9
No. 10
Average capture efficiency
Std. Deviation
n
t (0.90 LCL)
Capture Efficiency @ 90% LCL
Run 1
7/24/98
805-808
830-916
925-932
1100-1257
173
Silos 2,3,4 & 5
478
453
SF6 Release
Run 1
4.07
0.0199
0.490
Run 2
7/25/98
713-844
931-1112
192
Silos 2,3,4 & 5
391
400
Rates
Run 2
4.04
0.0199
0.487
Capture Efficiency3 (%)
Run 1 Run 2
93.0
90.1
82.1
67.3
64.4
49.4
63.1
-
-
-
72.8
16.0
7
1.440
64
78.5
81.2
82.3
71.0
53.7
65.0
73.9
59.4
-
-
70.6
10.5
8
1.415
65
Run3
7/27/98
715-932
1003-1044
1117-1135
1137-1152
1154-1200
217
Silos 2,4 & 5
723
573
Run3
4.01
0.0200
0.486
Run3
79.8
77.6
65.1
79.4
53.0
49.9
46.1
55.6
50.1
47.4
60.4
13.8
10
1.383
54
Run 4
7/26/98
931-1345
254
Silo 2
NA
NA
Run 4
4.11
0.0200
0.498
Run 4
55.9
51.1
65.6
82.9
55.2
68.8
38.1
51.3
23.4
32.8
52.5
17.7
10
1.383
45
Complete calculation spreadsheets are contained in Appendix F.
Exact times for each interval are in Appendix F.
MR1-AEDVR4951 -04-08.wpd
3-20
-------
3.4 Line Calibration Checks
The calibration standard mixture of 105 ppm toluene and 3.83 ppm SF6 was measured
directly by filling the FTIR cell from the cylinder and recording the spectrum of the gas
standard. Then at least once each test day the same calibration mixture was injected into
the sample line directly upstream of the first particulate filter at the end of the sample
probe. The gas standard was allowed to flood the line from the probe to the FTIR cell.
The cell was filled and the spectrum of the line spike was recorded. The line-spike spectra
were analyzed using the spectrum of the direct measurement to calculate the recovered
concentrations. The calculated concentrations in each of the line-spike spectra were
compared to the 100 % recovery concentrations. The results are shown in Table 3-10.
Table 3-10. Calibration Standard Line Check Results
File Name
SP0727B
SP0727A
SP0726A
SP0722Aa
SP0721A
Toluene
(ppm)
102.0
103.0
104.0
99.5
101.7
% Recovery
97.1%
98.1%
99.0%
94.7%
96.8%
SF6
(ppm)
2.72
3.70
3.79
3.67
3.75
% Recovery
97.2%
96.7%
98.8%
95.9%
97.8%
aThe calculated recovery for "sp0722a" was slightly below 95% because this sample contained
a significant amount of moisture compared to the direct measurement or the other line
measurements. This indicates "sp0722a" was slightly diluted by air compared to the other
measurements. If the line had been purged longer with the gas standard, this measurement
would also have been within 95%. The SF6 recovery for "sp0722a" fell within 95%, but the SF6
measurement also shows the slight dilution from air.
MRI-AED\R4951-04-08 wpd
3-21
-------
-------
Section 4.
Sampling and Analytical Methods
Midwest Research Institute operated a sampling system (Figure 4-1) that transports
sample gas through heated Teflon® lines. The sample stream passed through a gas
manifold that distributed sample to the FTIR instrumentation and the total hydrocarbon
analyzers (THC CEMS). Concentrated samples for FTIR analysis were collected
separately, using a sampling train at each sampling location.
Sampling procedures followed the test plan and are further described in the FTIR Draft
EPA Method 3202 for hazardous air pollutants (HAPs), the EPA Protocol3 for extractive
FTIR testing at industrial point sources, and EPA Method 25 A. The objectives of the field
test were to use the FTIR method to measure emissions from the processes, screen for
HAPs in the EPA FTIR reference spectrum library, conduct analyte spiking for quality
assurance, and analyze the spectra for compounds not in the EPA library. The manual
emissions measurements were performed by PES, who provided the manual data to MRI
for the load-out and silo tests. MRI collected manual emission data for the process stack
tests.
4.1 Sampling System Description
4.1.1 Extractive System
Sample was extracted through a single port using a 0.5-in diameter stainless steel
probe (Figure 4-1). Sample was transported through heated Teflon® line using a KNF
Neuberger heated head sample pump (Model No. 35 ST.l II). A Balston paniculate filter
(holder Model Number 30-25, filter element Model Number 100-25-BH, 99% removal
efficiency at 0.1 mm) was connected in-line at the outlet of the sample probe. The sample
line was heat wrapped and insulated.
The sample pump outlet was connected to the sample manifold where the sample
stream passed through a secondary Balston paniculate filter immediately after entering the
manifold box. The manifold was constructed of stainless steel 3/8-in tubing and contains
4-way valves and heated rotameters (0 to 20 LPM) to allow the operator to control sample
flow to the FTIR cell and the THC CEMS. A heated 1/4-in diameter 20-ft long Teflon
jumper line connected the manifold to the inlet of the FTIR gas cell and to the THC CEMS.
All sampling system components were maintained above the duct temperature (200 °F for
the load-out testing, 300 °F for the process stack).
The manifold consists of a secondary paniculate filter, control valves, rotameters, back
pressure regulators and gauges, and a mass flow controller. The manifold can control
MR]-AED\R4951-04-08.wp
-------
LVent
Unheated Line
Heated Line
Heated
Sample Manifold
Secondary
particulate filter
3-way valve
To Calibration
Gas Cylinders
Figure 4-1. Extractive Sampling System
980806
4-2
-------
two sample gas stream inputs, eight calibration gases, and has outputs for three analyzers.
Also included on the cart is a computer work station and controls for the spike valves and
mass flow controller.
MRI used a KVB/Analect model RFX-40 FTIR spectrometer equipped with a liquid
nitrogen cooled mercury cadmium telluride (MCT) detector. Samples were contained in an
Infrared Analysis (model D-22H) variable path gas cell equipped with treated ZnSe
windows. The cell was equipped with temperature controllers and was fitted with a digital
pressure gauge. The FTIR gas cell was maintained at 250°F (120°C). The interior cell
walls were coated with Teflon to minimize potential analyte losses.
The cell pathlength was set by adjusting an objective mirror to control the number of
IR beam passes through the cell. The number of beam passes was measured by shining a
He/Ne laser through the optical path and observing the number of laser spots on the field
mirror. The pathlength in meters was determined by comparing Calibration Transfer
Standard (CTS) EPA reference spectra to the CTS spectra recorded in the field, and was
measured to be 9.9 meters. This path length was used in all of the analyses.
All data were collected at a resolution of 1.0 cm. One hundred scans were co-added
for each spectrum (200 for background spectra). Each spectrum required about 2 min to
record.
4.1.2 Sample Concentration
Using procedures contained in Appendix I, a measured volume of sample gas was
collected using an absorbent tube filled with 10 g of Tenax sorbent material. The sampling
train was a modified VOST train and used both a primary and backup trap for all tests.
Prior to testing, the primary trap for each train was spiked with a measured volume of d%-
toluene in nitrogen (compressed gas). One sample concentration train was set up and run
simultaneously with other methods (PES manual methods) at each test location.
Prior to sampling, each train was checked for contamination by collecting a measured
volume of dry nitrogen through the sampling train. This tube was then desorbed in the
same way as all of the sample tubes. One contamination check was run for each sampling
train.
Field raw data sheets for the sample concentration technique are contained in
Appendix I.
MRI-AED\R4951 -04-08.wpd
4-3
-------
4.2 Sampling Procedures
Most of the FTIR measurements were performed using the continuous sampling
procedure described below. Spectra of all calibrations, background measurements and
some samples were recorded using the batch sampling procedure. All of the Method 25A
measurements were performed as indicated in the method.
Batch Sampling—This procedure is described in Section 8.7.1 in EPA Method 320.
With this technique, sample gas continuously flows from the probe, through the sample
line, through the manifold, and out a manifold vent. A 4-way valve on the manifold is
turned to direct a portion of the gas stream to fill the evacuated FTIR cell to ambient
pressure. The manifold total flow meter before the vent is monitored to ensure that a
positive flow is always directed out the vent during sampling. The cell is pressurized to
slightly over 1 atmosphere before the inlet is closed. The cell outlet vent valve is opened to
allow the sample to equilibrate at 1 atmosphere and then closed. The spectrum of the static
sample is then recorded before the cell is evacuated to prepare for the next sample.
Continuous Sampling—Sample gas is flowed continuously from the probe through
the sample line, through the manifold, and to the FTIR cell at ambient pressure. After the
cell is filled as in the batch sampling procedure, the cell inlet and outlet valves are kept
open to allow gas to pass through the cell. Spectra of the flowing sample is collected
continuously by co-addition of 50 to 100 scans (approximately 1-min time period). The
sampling and measurement times are expected to be longer than the 30-sec truck loading
events. The observed emissions peaks may appear lower and to occur over a longer
interval than the actual emissions from each 30-sec event. However, the integrated area
under a plot of the observed emissions vs. time should give an accurate representation of
the total emissions. Sample flow rate through the cell will be monitored and recorded so
that a determination of cell purge time can also be made. Performance Specification 15
gives more detail on sampling rate and its effect on continuous measurements.
Sample Concentration—After the sample tubes were collected, they were placed on
ice (up to several hours) until they could be analyzed. The sample tube was dried with a
nitrogen purge connected to the tube inlet. The dried tube was placed in a tubular heating
jacket and the tube outlet was connected to the FTIR cell inlet. The tube inlet was
connected to a nitrogen cylinder. The tube was gradually heated to 220 °C (under low
flow) before the inlet and outlet valves were opened to allow nitrogen at 1 LPM to carry
desorbed gases into the cell. Once the cell reached 1 atmosphere, the valves were closed
and a spectrum of the contained sample was recorded.
4.3 FTIR Analytical Procedures
Analytical procedures in the EPA FTIR Protocol were followed for this test.
Analytical programs were prepared prior to the field test for use in estimating some
MRI-AED\R4951 -04-08.wpd
4-4
-------
concentrations on site (i.e., SF6 concentration). After the data collection was completed the
spectra were analyzed using a computer program that employed a linear least squares fit
routine (Rho Squared, Durham, NC).4'5 The program operated in the Midac Grams/32®
software package (Version 4.11, Level n, Galactic, Inc.). The input data (reference spectra
and analytical regions) for the computer program are identified in Tables 4-1 and 4-2.
Initially, the spectra were evaluated to select suitable reference spectra as input for the
computer program. Next an analysis was run on all of the sample spectra using the
reference spectra listed in Tables 4-1 and 4-2. Undetected compounds were removed from
the analysis and the spectra were analyzed again using reference spectra only for the
detected compounds. The complete results from this second analytical run are summarized
in tables in Appendices C and D (for the direct and sample concentration results,
respectively).
The same program that performed the analysis calculated the residual spectra (the
difference between the observed and least squares fit absorbance values). Residual spectra
were calculated for each analytical region and for each sample spectrum. All of the
residuals were stored electronically and are included with the electronic copy of the sample
data provided with this report. The computer program calculated the standard Isigma
uncertainty for each analytical result, but some of the reported uncertainties for the detected
compounds are equivalent to 2*sigma.
The concentrations were corrected for differences in absorption path length and
temperature between the reference and sample spectra using the equation below.
c -fl£|(li)(l£) c (D
Ccoir ~ [ LsJl TrJl PsJ Ca'C
where: Ccorr = concentration, corrected for path length and temperature
Ccalc = uncorrected sample concentration
Lr = cell path length(s) (meters) used in recording the reference spectrum
Ls = cell path length (meters) used in recording the Sample spectra
Tr = absolute temperature(s) (Kelvin) of gas cell used in recording the
reference spectra
Ts = absolute temperature (Kelvin) of the sample gas when confined in the
FTIR gas cell
Pr = pressure of the reference spectrum sample
Ps = pressure of the sample gas in the FTIR cell
The sample path length was estimated by measuring the number of laser passes
through the infrared gas cell. These measurements were recorded in the data records. The
actual sample path length, Ls, was calculated by comparing the sample calibration transfer
standard CTS spectra to CTS spectra in the EPA FTIR reference spectrum library.
Reference CTS spectra from the EPA reference library, were used as input for an
automated analysis of the CTS spectra recorded at the test site.
MRI-AED\R4951-04-08.wpd
4-5
-------
Table 4-1. Program Input for FTIR Analysis (Loadout and Silo Samples)
Compound Name
Water
Carbon monoxide
Sulfur dioxide
Carbon dioxide
Formaldehyde
Benzene
Methane
Carbonyl Sulfide
Toluene
Methyl chloride
Methyl chloroform
1,1-Dichloroethane
1 ,3-Butadiene
Propane
Chlorobenzene
Cumene
Ethyl benzene
Hexane
Methylene chloride
Propionaldehyde
Styrene
1 ,1 ,2,2-Tetrachloroethane
p-Xylene
o-Xylene
m-Xylene
Isooctane
Ethylene
SFfi
File name
1 94jsub
1 94gsub
1 94hsub
co20829a
1 98c1 bsi
193b4a_b
087c1 anb
015a4ara
196c1bsd
030a4ase
1 53a4arc
1 07a4asa
1 08a4asc
086b4asa
023a4asc
prophan
037a4arc
046a4asc
077a4arb
095a4asd
1 1 7a4asa
140b4anc
1 47a4asb
150b4asb
1 73a4asa
171a4asa
172a4arh
165a4asc
C0726b
Sf0722a
Region No.
1,2,3
1
2
1,2,3
3
3
3
2
3
3
2
2
2
3
2
3
3
3
2
3
2
2
2
3
2
3
2
2
ISC*
100*
35.8*
61.3*
167.1
90.3
415*
100.0
496.6
80.1
19.5
103.0
501.4
98.8
499.1
98.4
39.3
502.9
96.3
515.5
101.6
498.5
99.4
550.7
493.0
488.2
497.5
497.8
101.4
99.9
0.205
Reference
Meters
22
22
11.25
3
22
3
3
3
3
2.25
3
3
3
3
3
3
3
2.25
3
2.25
3
3
3
3
9.9
9.9
T (K)
394
394
373
298
394
298
298
298
298
373
298
298
298
298
298
298
298
373
298
373
298
298
298
298
397
397
Region No.
1
2
3
Upper cm"1
2,142.0
1,275.0
3,160.8
Lower cm"1
2,002.1
722.6
2,650.1
Indicates an arbitrary concentration was used for the interferant.
MRl-AED\R4951-04-08.wpd
4-6
-------
Table 4-2. Program Input for FTIR Analysis (Process Stack and Tenax Samples)
Compound Name
Water
Carbon monoxide
Sulfur dioxide
Carbon dioxide
Formaldehyde
Benzene
Methane
Carbonyl Sulfide
Toluene
Methyl chloride
Methyl chloroform
1,1-Dichloroethane
1 ,3-Butadiene
Propane
Cumene
Ethyl benzene
Hexane
Methylene chloride
Propionaldehyde
Styrene
1 ,1 ,2,2-Tetrachloroethane
p-Xylene
o-Xylene
m-Xylene
Isooctane
Ethylene
SF6
Ammonia
File name
1 94jsub
co20829a
1 98c1 bsi
1 93c1 bsc
087c1 anb
015a4ara
1 96c1 bsb
030a4ase
t 53a4arc
1 07a4asa
1 08a4asc
086b4asa
023a4asc
prophan
046a4asc
077a4arb
095a4asd
117a4asa
1 40b4anc
1 47a4asb
1 50b4asb
1 73a4asa
1 71 a4asa
172a4arh
1 65a4asc
C0726b
Sf0722a
1 74c1 asc
Region No.
1,2,3
1
2
1,2,3
3
3
3
2
3
3
2
2
2
3
3
3
3
2
3
2
2
2
3
2
3
2
2
2
ISC*
100*
167.1
90.3
415*
100.0
496.6
80.1
19.5
103.0
501.4
98.8
499.1
98.4
39.3
96.3
515.5
101.6
498.5
99.4
550.7
493.0
488.2
497.5
497.8
101.4
99.9
0.205
10.0
Reference
Meters
22
22
11.25
3
22
3
3
3
3
2.25
3
3
3
3
3
3
2.25
3
2.25
3
3
3
3
9.9
9.9
20
T (K)
394
394
373
298
394
298
298
298
298
373
298
298
298
298
298
298
373
298
373
298
298
298
298
397
397
388
Region No.
1
2
3
Upper cm"1
2,201
1 ,331 .8
3,160.3
Lower cm"1
1952.3
750.5
2,450
Indicates an arbitrary concentration was used for the interferant.
MRI-AED\R4951-04-08.wpd
4-7
-------
4.3.1 Computer Program Input
Tables 4-1 and 4-2 present a summary of the reference spectra input for the
computer program used to analyze the sample spectra. Table 4-3 summarizes the program
input used to analyze the CTS spectra recorded at the field test. The CTS spectra were
analyzed as an independent determination of the cell path length. To analyze the CTS
spectra, MRI used 0.25 cm-1 spectra "cts0814b" and "cts0814c." These reference CTS
spectra were recorded on the same dates as the toluene reference spectra used in the
analyses. These spectra were de-resolved in the same way as the toluene reference spectra
using Section K.2.2 of the EPA FTIR protocol. The program analyzed the main two
ethylene bands centered near 2,989 and 949 cm"1. Table 4-4 summarizes the results of the
CTS analysis. The cell path length from this analysis was used as Ls in equation (1).
4.3.2 EPA Reference Spectra
HAP spectra used in the MRI analysis were taken from the EPA reference spectrum
library (http://134.67.104.12/html/emtic/ftir2.htm). The original sample and background
interferograms were truncated to the first 16,384 data points. The truncated interferograms
were Fourier transformed using Norton-Beer medium apodization and no zero filling. The
transformation parameters were chosen to agree with those used to collect the sample
absorbance spectra. The new 1.0 cm"1 toluene single beam spectra were combined with
their de-resolved single beam background spectra and converted to absorbance.
4.3.3 Estimated Uncertainties of Non-Detects
The analytical program quantified each of the principal sample components. Then
each standard spectrum was mathematically scaled and subtracted from the sample
spectrum. The resulting residual spectra were analyzed to estimate quantitation limits for
undetected HAPs. These quantitation limits, expressed as uncertainties in the non-detects
(zero concentrations) are included in Appendix C.
4.3.4 FTIR System
A KVB/Analect Diamond RFX-40 spectrometer was used to record all of the data
in this field test. The gas cell is a heated variable path (D-22H) gas cell from Infrared
Analysis, Inc. The path length of the cell was set at 20 laser passes and was measured to
be 9.9 meters using the CTS reference and sample spectra. The interior cell walls have
been treated with a Teflon® coating to minimize potential analyte losses. An MCT liquid
nitrogen detector was used. The spectra were recorded at a nominal resolution of 1.0 cm"1.
MRI-AED\R4951-04-08.wpd
4-8
-------
Table 4-3. Program Input for Analysis of CTS Spectra
Compound name
Ethylene*
Ethylene
File name
cts0814b.spc
cts081 4c.spc
ASC
1.007
1.007
ISC
1.014
0.999
% Difference
0.7349
0.7350
This spectrum was used in the analysis of the Irvine CTS spectra. Analytical Regions for CTS
analysis were 842.5 crrT1-1107 cm"1 and 2984.36 cm~1-2992.38 cm"1.
Table 4-4. Path Length Determinations From the
Analysis of Hot (397 K) CTS Spectra
CTS spectra
(99.9 ppm Ethylene)
C0721B
C0721C
C0721D
C0721 E
C0722A
C0722B
C0723A
C0723B
C0723C
C0724A
C0724B
C0725A
C0725B
C0725C
C0726A
C0726B
C0727A
C0727B
C0727C
C0727D
Average Path Length (M)
Standard Deviation
Path length results
Meters
10.3
9.9
10.1
9.9
9.8
9.9
9.8
9.8
9.9
9.8
10.0
9.8
9.8
10.0
9.9
9.9
9.8
9.9
9.8
9.9
9.9
0.12
Delta "
-0.36
-0.05
-0.20
0.03
0.08
0.04
0.12
0.11
-0.03
0.05
-0.08
0.12
0.06
-0.10
-0.01
-0.01
0.07
0.04
0.05
0.04
% Delta
-3.6%
-0.6%
-2.0%
0.3%
0.9%
0.4%
1 .2%
1 .2%
-0.3%
0.5%
-0.8%
1 .2%
0.6%
-1.0%
-0.1%
-0.1%
0.7%
0.4%
0.5%
0.5%
* The difference between the calculated and average values.
4.4 Total Hydrocarbon Sampling Procedures
THC sampling was conducted simultaneously with the FTIR sampling at each of the
test locations. The same sampling system used for the FTIR sampling was used for the
THC sampling. Sample gas was directed to the analyzer through a separate set of
rotameters and control valves on the manifold. A brief description of each system
component follows.
• THC Analyzer—The THC concentration was measured using a flame ionization
detector (FID). MRI used a J.U.M. Model VE-7 analyzer. The THC analyzer was
operated on the zero to 100 ppm range throughout the test period (0-1000 ppm for
MRI-AEDVR4951 -04-08.wpd
4-9
-------
SED). The fuel for the FED is 40 percent hydrogen and 60 percent helium
mixture.
Data Acquisition System—MRI used LABTECH notebook (Windows version),
which is an integrated system that provides data acquisition, monitoring and
control. The system normally writes data to a disk in the background while
performing foreground tasks or displaying data in real time. The averaging period
set for this test was one minute.
Calibration Gases—Calibration gases were prepared from an EPA Protocol 1
cylinder of propane (5278 ppm propane in nitrogen) using an Environics
Model 2020 gas dilution system that complies with the requirements of EPA
Method 205. High, medium, and low standard gases were generated to perform
analyzer calibration checks. The raw data are recorded in ppm as propane but are
converted to an as carbon basis for reporting.
MRI- AEDW4951 -04-08.wpd
4-10
-------
Section 5.
QA/QC Summary
5.1 Sampling and Test Conditions
Before the test, sample lines were checked for leaks and were cleaned by purging with
moist air (250°F). Following this, the lines were checked for contamination using dry
nitrogen. This is done by heating the sampling lines to 250°F and purging with dry
nitrogen. The FTIR cell was filled with some of the purging nitrogen, and the spectrum of
this sample was collected. This single beam spectrum was converted to absorbance using a
spectral background of pure nitrogen (99.9 percent) taken directly from a cylinder. The
lines were checked again on-site before sampling, after each change of location, and after
spiking.
During sampling, spectra of at least 10 different samples were collected during each
hour. Each spectrum was assigned a unique file name and written to the hard disk and a
backup disk under that file name. Each interferogram was also saved under a file name
that identifies it with its corresponding absorbance spectrum. All background spectra and
calibration spectra were also stored on disks with their corresponding interferograms.
Notes on each calibration and sample spectrum were recorded on hard copy data
sheets. Below are listed some sampling and instrument parameters that were documented
in these records.
Sampling Conditions:
• Line temperature
• Process conditions
• Sample flow rate
• Ambient pressure
• Time of sample collection
Instrument Configuration:
• Cell volume (for continuous measurements)
• Cell temperature
• Cell path length
• Instrument resolution
• Number of scans co-added
• Length of time to measure spectrum
• Time spectrum was collected
• Time and conditions of recorded background spectrum
• Apodization
MRI-AED\R4951-04-08.wpd
5-1
-------
Hard copy records were also kept of all flue gas measurements, such as sample flow,
temperature, moisture, and diluent data. Equipment calibration data and gas certifications
are presented in Appendix J.
Effluent was allowed to flow through the entire sampling system for at least 5 minutes
before a sampling run started or after changing to a different test location. FTIR spectra
were continuously monitored to ensure that there was no deviation in the spectral baseline
greater than ± 5 percent (- 0.02 < absorbance < +0.02). When this condition occurred,
sampling was interrupted and a new background spectrum was collected. The run was then
resumed until completed or until it was necessary to collect another background spectrum.
Results of the analyte spiking were presented earlier in Section 3.4 and met all QA/QC
criteria, except where noted due to the presence of ambient air. These checks served to
demonstrate sample line integrity during the field testing.
Results from the CTS spectra were presented earlier in Section 4.3.4 and met all
QA/QC criteria. These checks served to demonstrate instrument stability and optical
conditions during the field testing.
5.2 FTIR Spectra
For a detailed description of QA/QC procedures relating to data collection and
analysis, refer to the "Protocol for Applying FTIR Spectrometry in Emission Testing."
A spectrum of the CTS was recorded at the beginning and end of each test day. A leak
check of the FTIR cell was also performed according to the procedures in References 1 and
2. The CTS gas was 100 ppm ethylene in nitrogen. The CTS spectrum provided a check
on the operating conditions of the FTIR instrumentation, e.g., spectral resolution and cell
path length. Ambient pressure was recorded whenever a CTS spectrum was collected. The
CTS spectra were compared to CTS spectra in the EPA library. This comparison is used to
quantify differences between the library spectra and the field spectra so library spectra of
HAPs can be used in the quantitative analysis.
Two copies of all interferograms, processed backgrounds, sample spectra, and the CTS
were stored on separate computer disks. Additional copies of sample and CTS absorbance
spectra were also stored for data analysis. Sample absorbance spectra can be regenerated
from the raw interferograms, if necessary.
The compact disk enclosed with this report contains one complete copy of all of the
FTIR data recorded at the field test. The data are organized into directories, whose titles
identify the contents. The continuous data are in directories identified by the date on which
the spectra were recorded. Additional subdirectories "AIF" and "ASF' identify
interferograms and absorbance spectra, respectively. All of the sample data are in the
MRI-AED\R4951 -(M-Og-wpd
5-2
-------
Analect instruments software format. The directories "refs" and "residuals" contain de-
resolved reference spectra that were used in the analyses and the residual spectra,
respectively. There are three residual spectra for each sample spectrum, one for each
analytical region. The information on the enclosed disk with the data records in
Appendix A meets the reporting requirements of the EPA FTER Protocol and Method 320.
To measure HAPs detected in the gas stream MRI used spectra from the EPA library,
when available.
5.3 Method 25A
5.3.1 Initial Checks
Before starting the first run, the following system checks were performed:
1. Zero and Span check of the analyzer
2. Analyzer linearity check at intermediate levels
3. Response time check of the system
Calibration criteria for Method 25A is ± 5 % of calibration gas value.
5.3.2 Daily Checks
The following checks were made for each test run:
1. Zero/Span calibration and linearity checks before each test run
2. Final Zero and span calibration check of the analyzer at the end of each test run
The difference between initial and final zero and span checks agreed within ± 3 % of
the instrument span.
MRI- AEDW4951 -04-08.wpd
5-3
-------
-------
Section 6.
References
1. "Revised Capture Efficiency Guidance for Control of Volatile Organic Compound
Emissions," EMC GD-036, Prepared by EPA/OAQPS/EMC, February 7, 1995.
2. Test Method 320 "Measurement of Vapor Phase Organic and Inorganic Emissions by
Extractive Fourier Transform Infrared (FTIR) Spectroscopy," Proposed in Federal
Register, March 11, 1998.
3. "Protocol For The Use of FTIR Spectrometry to Perform Extractive Emissions Testing
at Industrial Sources," Revised, EPA Contract No. 68-D2-0165, Work Assignment 3-
12, September, 1996.
4. "An Examination of a Least Squares Fit FTIR Spectral Analysis Method," G. M.
Plummer and W. K. Reagen, Air and Waste Management Association, Paper
Number 96-WA65.03, 1996.
5. "Computer-Assisted Quantitative Infrared Spectroscopy," Gregory L. McClure (ed.),
ASTM Special Publication 934 (ASTM), 1987.
MRI-AED\R4951 -04-08.wpd
6-1
-------
-------
Appendix A
Process Data
MRl-AEDXR4951 -04-08. wpd
-------
-------
Process Data Spreadsheet
Sheet 1 of
MRI Project No. 4701-08-03-04 Run No.
Client/Source: EPA/Plant C (Hot Mix Asphalt Plant) Date:
Data Recorded By:
Time
1119
1130
1145
1154
1200
1215
1230
1245
1257
1306
1315
1330
1345
1355
1400
1413
1421
Avg.
Natural Gas
Rate (ACFM)
1160
1100
1140
1180
1200
1200
1190
1100
1180
1030
947
988
1070
1150
1150
R41
1102
@
&
&
«
®
&
&
&
VI
&
®
&
&
®
&
&
&
76.3
76.1
76.7
76.9
77.1
77.3
77.4
77.6
77.7
77.8
78.0
78.3
77.9
77.4
77.1
78.0
77.35
Aggregate
Feed Rate
(TPH)
436.38
490.69
491.86
492.44
505.36
500.48
508.51
510.60
503.73
465.88
438.60
463.55
438.18
436.68
448.94
390.64
470.16
Liquid
Asphalt
Feed Rate
(TPH)
23.08
25.09
25.99
26.04
28.08
27.91
28.37
28.52
28.17
24.74
23.22
23.29
23.16
23.09
25.01
21.99
25.36
Mix Rate
(TPH)
459.46
516.59
517.85
518.47
533.44
528.40
536.88
539.13
531.90
490.62
461.82
463.55
461.34
459.76
473.95
412.63
494.1 1
Liquid
Asphalt
Temp. (F)
355.24
354.88
354.89
353.24
353.24
354.18
354.87
355.05
307.32
313.00
318.18
324.24
329.13
328.68
329.50
332.53
338.64
Burner
Turndown
Position
(%)
34.5
28.8
28.8
30.0
30.0
30.0
30.0
30.0
29.5
24.0
21.5
22.5
23.4
28.3
28.3
18.0
27.4
Mix
Temp.
(F)
330.87
309.46
312.66
315.82
313.01
302.86
313.40
310.80
304.16
314.14
307.64
302.00
306.63
305.62
310.11
319.81
311.187
Cyclone
Entrance
Temp. (F)
286
271
274
273
268
268
280
264
266
254
243
241
243
251
254
224
260
Dryer
Pressure
(in Hg)
0.29
0.31
0.30
0.29
0.31
0.29
0.30
0.31
0.28
0.31
0.28
0.28
0.31
0.30
0.32
0.32
0.30
Baghouse
Exit Temp.
(F)
248
256
260
261
261
257
264
258
256
254
246
237
237
240
242
235
251
Baghouse
Pressure
Drop (in
Hg)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
7/21/98
Pam Murowchick
Exhaust
Fans
Amperage
(amps)
77
75
75
75
75
75
75
75
75
75
fij
75
75
75
75
72
75
81
80
78
78
79
80
78
78
79
75
75
75
78
75
79
75
78
Comments
Mix 2 (3/4 inch) started
testing at 11 20.
Switched to Mix 4 (1/2 inch).
Switched to Mix 2 (3/4 inch).
TPH production.
Switched to Mix 4 (1/2 inch).
Switched to Mix 2 (3/4 inch).
Plant down due to burner
out.
1/27/99 11:58 AM Procdata.xls Run1
-------
Process Data Spreadsheet
Sheet 1 of 1
MRI Project No. 4701-08-03-04
Client/Source: EPA/Plant C (Hot Mix Asphalt Plant)
Time
931
946
1001
1013
1031
1046
1101
1114
1131
1146
1201
1216
1231
Avg.
Natural Gas
Rate (ACFM)
1170
1290
1160
1100
1160
1290
1160
1240
1160
711
789
890
819
1072
@
@
@
@
@
0
@
@
@
@
&
@
@
@
73.1
73.3
73.6
73.4
73.9
73.9
74.1
74.3
75.2
75.7
76.2
76.3
77.0
74.6
Aggregate
Feed Rate
(TPH)
478.20
479.05
478.04
476.50
465.71
477.01
476.84
479.16
479.83
357.62
327.88
324.71
325.96
432.81
Liquid
Asphalt
Feed Rate
(TPH)
26.69
26.76
26.68
26.57
24.62
26.60
26.60
26.72
26.72
18.85
17.34
17.12
17.22
23.73
Mix Rate
(TPH)
504.89
505.81
504.72
503.07
490.33
503.61
503.44
505.88
506.60
376.47
345.22
341.84
343.18
456.54
Liquid
Asphalt
Temp. (F)
347.63
344.53
346.12
344.45
343.38
344.15
345.06
345.06
342.70
341.06
340.68
341.88
340.73
343.65
Run No. 2
Date: 7/22/98
Data Recorded By: Pam Murowchick
Burner
Turndown
Position
(%)
34.0
34.0
34.0
28.0
28.0
33.1
33.1
33.1
33.1
12.0
15.0
15.0
15.7
26.8
Mix
Temp.
(F)
306.86
304.08
300.89
300.55
293.55
303.98
302.96
301.19
299.46
306.95
295.30
314.52
307.53
302.91
Cyclone
Entrance
Temp. (F)
281
283
285
266
263
268
268
267
267
214
213
213
211
254
Dryer
Pressure
(in Hg)
0.31
0.31
0.32
0.30
0.30
0.28
0.31
0.30
0.30
0.31
0.31
0.31
0.32
0.31
Baghouse
Exit Temp.
(F)
268
269
271
261
254
258
258
258
259
235
216
213
211
249
Baghouse
Pressure
Drop (in
Hg)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Exhaust
Fans
Amperage
(amps)
79
80
80
78
76
79
78
78
78
72
75
74
75
77
82
81
82
79
80
82
81
80
82
72
75
75
75
79
Comments
Mix 4 (1/2 inch) Started
testing at 935.
Switched to Mix 2 (3/4 inch).
Switched to Mix 4 (1/2 inch).
Switched to Mix 2 (3/4 inch).
Started to ramp down to 325
TPH production.
-------
Process Data Spreadsheet
Sheet 1 of 1
Pacific Environmental Services Run No. 2
Client/Source: EPA/Plant C (Hot Mix Asphalt Plant) Date: 7/25/98
Data Recorded By: JHL
Time
6:12 AM
6:30 AM
7:10 AM
7:40 AM
8:11 AM
8:41 AM
9:11 AM
9:41 AM
10:11 AM
10:41 AM
11 :10 AM
11:34 AM
12:02PM
12:40PM
1:13 PM
1:42 PM
Natural
Gas
Rate
(ACFM)
700
0
745
834
950
927
710
710
733
741
854
Aggregate
Feed Rate
(TPH)
69
178.8
181.3
183.2
261.2
241.6
182.4
182.7
177.2
196.4
185.5
Kecycie
(RAP)
Feed
Rate
(TPH)
18.9
79.8
82.7
82.7
110.7
88.9
81.7
80.9
78.6
87.2
82.1
%RAP
in mix
20.4
29.3
29.8
29.6
28.2
25.5
29.4
29.2
29.2
29.2
29.2
Rubber
Feed
Rate
(TPH)
0
0
0
0
0
0
0
0
0
0
0
Plant shut down - lack of customers
789
812
880
899
0.41
207.7
255.86
292.7
0.2
82.5
112.2
113.2
31.7
27.1
29.0
26.5
0
0
0
0
Liquid
Asphalt
Feed
Rate
(TPH)
4.4
13.4
13.7
13.8
20.4
18.1
13.7
13.7
13.2
14.7
13.8
0.03
14
19.1
21
Liquid
Asphalt
Type
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
Mix Rate
(TPH)
92.7
272
277.7
279.7
392.3
348.6
277.8
277.3
269
298.3
281.4
0.63
304.2
387.1
426.9
Product
Code
4C
2
2C
2C
4C
4C
2C
2C
2C
2C
2C
2C
2C
2C
2C
Liquid
Asphalt
Temp.
(F)
319.4
321.1
321.7
321.7
325.6
326.2
324.8
325.2
325.6
327.5
328
329.8
330
331.2
332
Burner
Pos. (%)
11
15.1
14
17.6
21.4
'19
12
11
11.6
13
10.5
29.1
15
21
20
Mix
Temp.
(F)
326.6
315.7
312.1
326.1
338
336.9
324.2
317.6
323.8
327.6
307.8
216.2
336.6
329.8
324.8
Cyclone
Entrance
Temp. (F)
210
178
228
237
281
251
221
209
218
228
208
206
232
260
252
Dryer
Pressure
(in Hg)
0.33
1.84
0.28
0.27
0.31
0.31
0.32
0.28
0.29
0.29
0.28
0.23
0.29
0.29
0.27
Baghouse
Exit
Temp. (F)
205
191
203
213
255
242
219
209
210
219
208
194
219
242
251
Baghouse
Pressure
Drop
(in Hg)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Exhaust Fans
Amperage
(amps)
fan 1 / fan 2
75/75
88/92
75/78
75/80
74/79
73/79
74/75
72/76
73/75
71/74
71/73
71/74
71/72
72/75
72/75
-------
Process Data Spreadsheet
Sheet 1 of 1
Pacific Environmental Services Run No. 1
Client/Source: EPA/Plant C (Hot Mix Asphalt Plant) Date: 7/24/98
Data Recorded By: JHL
Time
6:34 AM
7:00 AM
7:29 AM
8:00 AM
8:30 AM
9:00 AM
9:37 AM
10:07 AM
10:41 AM
11:07 AM
11:37 AM
12:07PM
12:37PM
1:07 PM
Natural
Gas
Rate
(ACFM)
784
841
1320
941
1040
915
878
847
974
899
945
913
920
858
Aggregate
Feed Rate
(TPH)
184.6
295.1
458.2
409.3
383.5
328.9
322
322.6
328.6
319
320.2
319.9
320.4
320.2
Recycle
(RAP)
Feed
Rate
(TPH)
80.27
0
0
0
0
0
0
0
0
0
0
0
0
0
% RAP in
mix
28.8
0
0
0
0
0
0
0
0
0
0
0
0
0
Rubber
Feed
Rate
(TPH)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Liquid
Asphalt
Feed
Rate
(TPH)
14
15.6
24.2
21.2
21
18
16.7
16.7
18
16.6
16.6
16.6
16.6
16.6
Liquid
Asphalt
Type
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
Mix Rate
(TPH)
278.9
310.7
482.4
430.5
404.5
346.9
338.7
339.3
346.6
335.5
336.8
336.5
337
336.8
Product
Code
2C
2
2
2
4
4
2
2
4
2
2
2
2
2
Liquid
Asphalt
Temp.
(F)
329.3
329.3
331.8
332.2
332
331.6
330.7
330.5
333.2
327.6
326.5
326.3
328.3
330.2
Burner
Pos.
(%)
12.5
16
37.3
21
27
22
15
17
19.5
17.5
17.5
17.5
17.5
17.5
Mix
Temp.
(F)
340
330
319
324
323
315
316
325
324
325
330
331
331
333
Cyclone
Entrance
Temp. (F)
210
217
332
268
280
262
220
227
228
229
230
229
228
228
Dryer
Pressure
(in Hg)
0.29
0.27
0.31
0.33
0.28
0.27
0.31
0.31
0.31
0.3
0.32
0.31
0.31
0.27
Baghouse
Exit
Temp. (F)
209
206
280
283
262
245
220
219
220
221
222
223
221
223
Baghouse
Pressure
Drop
(in Hg)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Exhaust
Fans
Amperage
(amps)
fan 1 / fan 2
75/79
75/80
81/88
75/79
80/80
75/77
75/80
73/80
80/80
76/80
75/80
75/78
73/78
73/75
-------
Process Data Spreadsheet
Sheet 1 of 1
Pacific Environmental Services Run No. 3
Client/Source: EPA/Plant C (Hot Mix Asphalt Plant) Date: 7/27/98
Data Recorded By: JHL
Time
6:30 AM
6:59 AM
7:36 AM
7:55 AM
8:33 AM
8:57 AM
9:27 AM
9:57 AM
10:27 AM
10:57 AM
11:27 AM
11:57 AM
12:27 PM
12:57 PM
1-.27PM
1:57 PM
2:27 PM
Natural
Gas
Rate
(ACFM)
1190
1190
978
1280
1400
1330
1530
1470
1330
1190
1430
1420
1360
1210
1300
1120
881
Aggregate
Feed Rate
(TPH)
0.9
342.8
349.4
476.9
348.4
366.84
386.3
367.8
366.2
385.6
387.1
556
366.9
356.7
356.4
457.1
374.7
Kecycie
(RAP)
Feed
Rate
(TPH)
0
140.3
145.7
0
130.6
150.9
162
154.9
152.8
144.5
157.9
37.9
152.9
161.7
158.5
60
0
%RAP
in mix
0.0
27.6
28.0
0.0
25.9
27.7
28.1
28.2
28.0
25.9
27.5
6.1
28.0
29.7
29.3
11.0
0.0
Rubber
Feed
Rate
(TPH)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Liquid
Asphalt
Feed
Rate
(TPH)
3.6
24.6
25.6
24.6
24.8
26.8
28.4
27.1
26.9
27.5
28.2
30.6
27
26.9
26.7
26.7
19.5
Liquid
Asphalt
Type
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
4000
Mix Rate
(TPH)
1.36
507.7
520.7
501.5
503.8
544.6
576.6
549.8
545.9
557.5
573.2
624.4
546.9
545.2
541.5
543.3
394.2
Product
Code
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2C
2
Liquid
Asphalt
Temp.
(F)
319.3
321.9
327.6
332.9
339.9
342.5
346.3
346.5
346.9
349
348.9
352.5
352.5
360.9
358
363.4
362.5
Burner
Pos. (%)
24.9
31.3
27
37
35.1
36
40.1
40
40
40
40
39.5
33
38.4
26.5
33.4
17.6
Mix
Temp.
(F)
316.1
324.7
325.5
307.4
325.4
329.4
317.6
337.2
338.5
331.1
324.2
309.6
307.5
318.6
313
331.6
326.5
Cyclone
Entrance
Temp. (F)
271
341
325
341
368
354
365
372
373
370
373
357
388
370
318
289
230
Dryer
Pressure
(in Hg)
0.33
0.28
0.3
0.25
0.33
0.22
0.25
0.22
0.27
0.27
0.29
.0.34
0.4
0.22
0.52
0.3
0.25
Baghouse
Exit
Temp. (F)
231
306
319
298
332
329
336
343
344
345
347
331
356
343
305
323
253
Baghouse
Pressure
Drop
(in Hg)
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Exhaust Fans
Amperage
(amps)
fan 1 / fan 2
78/81
78/81
75/80
78/82
75/81
78/83
80/90
80/88
80/87
80/88
79/85
80/89
80/88
78/80
79/83
80/85
72/77
Comments: Rap was put on hold at 7:49 AM and continued at 8:05 AM
Plant was shut down at 3:20 AM due to energy conservation. Night shift was canceled.
-------
Appendix B
Process Stack Testing Raw Data Sheets
MRl-AED\R4951-04-08.wpd
-------
40 CFR 60, APPENDIX A, METHOD 2* - GAS STREAM VELOCITY AND VOLUMETRIC FLOW RATE
DATA ENTRY AND SUMMARY OF RESULTS
MRI Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location: JJ
Run No. 1
Date: 07/21/98
Type S Pitot Tube No. PT-003 Temperature Meter No. Y-0783
Barometer No. Y-2101
Pitot Tube Coefficient (Cp): 0.84
Thermocouple No. PT-36
Elevation Change" from Barometer Location to Sampling Location: 20 feet
Cross Sectional Area of the Duct at Sampling Location: 13.8450 fP
Carbon Dioxide Concentration By Volume, Dry Basis: 6.0 % Gas Mol. Weight, Dry Basis (Md): 29.459 Ib/lb-mole
Oxygen Concentration By Volume, Dry Basis:
FIRST TRAVERSE - START OF RUN
9.2 %
Start Time: 0930
Stop Time: 0950
Barometric Pressure at Barometer Location:
Barometric Pressure at Sampling Location:
Velocity Head at Centroid:
Total Pressure at Centroid:
Static Pressure:
Absolute Pressure in Duct (Ps):
Water Vapor Concentration By Volume:
29.37 in. Hg
29.35 in. Hg
0.400 in. w.c.
0.180 in. w.c.
-0.102 in. w.c.
29.34 in. Hg
25.42 %
Gas Mol. Weight, Wet Basis (Ms): 26.550 Ib/lb-mole
Traverse
Point
Number
1-1
1-2
1-3
1-4
2-1
2-2
2-3
2-4
3-1
3-2
3-3
3-4
4-1
4-2
4-3
4-4
5-1
5-2
5-3
5-4
6-1
6-2
6-3
6-4
Velocity
Head,
(delta-p),
inches w.c.
0.120
0.760
0.450
0.530
0.090
0.450
0.490
0.590
0.190
0.400
0.430
0.540
0.370
0.560
0.400
0.280
0.220
0.380
0.320
0.320
0.090
0.470
0.520
0.430
Gas
Stream
Temp.,
(ts), -F
259
259
259
259
259
259
259
259
258
258
258
258
257
257
257
257
256
256
256
256
253
253
253
253
Velocity,
(vs),
ft/sec
23.89
60.13
46.27
50.21
20.69
46.27
48.28
52.98
30.04
43.59
45.20
50.65
41.90
51.54
43.56
36.45
32.28
42.43
38.94
38.94
20.61
47.09
49.53
45.04
Rotation
Angle
a
21
15
13
7
18
12
8
5
17
10
8
6
16
12
9
7
15
10
5
5
12
8
6
5
Average Rotation Angle: 10.4"
Average Velocity: 41 .94 ft/sec
Volumetric Flow Rate: 34,837 acfm
Volumetric Flow Rate: 25,152 scfm
Volumetric Flow Rate: 18,758 dscfm
Volumetric Flow Rate: 531 dry std. m'/min.
SECOND TRAVERSE - END OF RUN
Start Time:
_ Stop Time:
Barometric Pressure at Barometer Location:
Barometric Pressure at Sampling Location:
Velocity Head at Centroid:
Total Pressure at Centroid:
Static Pressure:
Absolute Pressure in Duct (Ps):
Water Vapor Concentration By Volume:
Gas Mol. Weight, Wet Basis (Ms):
in. Hg
in. Hg
Jn. w.c.
Jn. w.c.
in. w.c.
in. Hg
_%
Ib/lb-mole
Traverse
Point
Number
1-1
1-2
1-3
1-4
2-1
2-2
2-3
2-4
3-1
3-2
3-3
3-4
4-1
4-2
4-3
4-4
5-1
5-2
5-3
5-4
6-1
6-2
6-3
6-4
Velocity
Head,
(delta-p),
inches w.c.
Gas
Stream
Temp.,
(ts), -F
Velocity,
(vs),
ft/sec
RESULTS FOR RUN
Average Volumetric Flow Rate: NA dry std. fP/hr.
Average Volumetric Flow Rate: NA dry std. m'/hr.
Deviation of the flow rate (acfm) after the
run from the one before the run: NA %
COMMENTS: Second traverse not conducted due to
process change before traverse could be run.
Average Velocity:
Volumetric Flow Rate:
Volumetric Flow Rate:
Volumetric Flow Rate:
Volumetric Flow Rate:
* 40 CFR 60, Appendix A, Method 3 is used for the
determination of dry molecular weight, and the
Alternative Method is used to determine moisture
ft/sec (water vapor) content.
acfm ** Positive values for locations above the barometer and
scfm negative values for locations below the barometer are
dscfm entered here. (Computations reverse the signs to
dry std. m'/min. yield correct results.)
M2TSWBDB.WK4 09/29/97 (rev. M23_1 .WK4 07/29/98 04:49 PM)
-------
40 CFR 60, APPENDIX A, METHOD 2* - GAS STREAM VELOCITY AND VOLUMETRIC FLOW RATE
DATA ENTRY AND SUMMARY OF RESULTS
MRI Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location: 3
Run No. 2
Date: 07/22/98
Type S Pilot Tube No. PT-003 Temperature Meter No. Y-0783
Barometer No. Y-2101
Pitot Tube Coefficient (Cp): 0.84
Thermocouple No. PT-36
Elevation Change" from Barometer Location to Sampling Location: 20 feet
Cross Sectional Area of the Duct at Sampling Location: 13.8450 ft3
Carbon Dioxide Concentration By Volume, Dry Basis: 4.0 % Gas Mol. Weight, Dry Basis (Md): 29.257 Ib/lb-mole
Oxygen Concentration By Volume, Dry Basis: _
FIRST TRAVERSE - START OF RUN
12.2 %
SECOND TRAVERSE - END OF RUN
Start Time: 0902
_Stop Time: 0916
Start Time: 1229
Stop Time: 1246
Barometric Pressure at Barometer Location:
Barometric Pressure at Sampling Location:
Velocity Head at Centroid:
Total Pressure at Centroid:
Static Pressure:
Absolute Pressure in Duct (Ps):
Water Vapor Concentration By Volume:
29.33 in. Hg
29.31 in. Hg
0.600 in. w.c.
0.300 in. w.c.
-0.123 in. w.c.
29.30 in. Hg
31.87 %
Barometric Pressure at Barometer Location:
Barometric Pressure at Sampling Location:
Velocity Head at Centroid:
Total Pressure at Centroid:
Static Pressure:
Absolute Pressure in Duct (Ps):
Water Vapor Concentration By Volume:
29.33 in. Hg
29.31 in. Hg
0.150 in. w.c.
0.006 in. w.c.
-0.100 in. w.c.
29.30 in. Hg
31.87 %
Gas Mol. Weight, Wet Basis (Ms): 25.674 Ib/lb-mole
Traverse
Point
Number
1-1
1-2
1-3
1-4
2-1
2-2
2-3
2-4
3-1
3-2
3-3
3-4
4-1
4-2
4-3
4-4
5-1
5-2
5-3
5-4
6-1
6-2
6-3
6-4
Velocity
Head,
(delta-p),
inches w.c.
0.130
0.510
0.720
1.020
0.400
0.400
0.550
0.690
0.390
0.530
0.590
0.820
0.700
0.790
0.570
0.780
0.680
0.940
0.860
0.820
0.800
0.900
1.050
0.920
Gas
Stream
Temp.,
(ts). -F
264
264
264
264
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
267
Velocity,
(vs),
ft/sec
25.39
50.30
59.76
71.13
44.64
44.64
52.34
58.63
44.08
51.38
54.21
63.91
59.05
62.73
53.29
62.33
58.20
68.43
65.45
63.91
63.13
66.96
72.32
67.70
Rotation
Angle
a
Average Rotation Angle: NR
Average Velocity: 57.66 ft/sec
Volumetric Flow Rate: 47,901 acfm
Volumetric Flow Rate: 34,083 scfm
Volumetric Flow Rate: 23,221 dscfm
Volumetric Flow Rate: 658 dry std. m'/min.
Gas Mol. Weight, Wet Basis (Ms): 25.674 Ib/lb-mole
Traverse
Point
Number
1-1
1-2
1-3
1-4
2-1
2-2
2-3
2-4
3-1
3-2
3-3
3-4
4-1
4-2
4-3
4-4
5-1
5-2
5-3
5-4
6-1
6-2
6-3
6-4
Velocity
Head,
(delta-p),
inches w.c.
0.330
0.340
0.330
0.320
0.200
0.320
0.270
0.230
0.190
0.240
0.180
0.170
0.340
0.350
0.130
0.130
0.360
0.470
0.440
0.400
0.200
0.200
0.550
0.220
Gas
Stream
Temp.,
(ts), °F
201
201
201
201
202
202
202
202
203
203
203
203
204
204
204
204
210
210
210
210
208
208
208
208
Velocity,
(vs),
ft/sec
38.66
39.24
38.66
38.07
30.12
38.10
34.99
32.30
29.38
33.02
28.59
27.79
39.33
39.90
24.32
24.32
40.65
46.45
44.94
42.85
30.25
30.25
50.17
31.73
RESULTS FOR RUN
Average Volumetric Flow Rate:
Average Volumetric Flow Rate:
1,166,462 dry std. ft'/hr.
33,031 dry std. m'/hr.
Deviation of the flow rate (acfm) after the
run from the one before the run: -38.3 %
COMMENTS: For the second traverse, points were
measured through ports 5 and 6 before word was
received to stop sampling. Points at ports 1 through
4 were measured shortly after word was received
to stop. The moisture and gas molecular weight
values used for the second traverse are not
representative. No data could be collected.
Average Velocity:
Volumetric Flow Rate:
Volumetric Flow Rate:
Volumetric Flow Rate:
Volumetric Flow Rate:
35.59 ft/sec
29,562 acfm
22,988 scfm
15,661 dscfm
443 dry std. m'/min.
40 CFR 60, Appendix A, Method 3 is used for the
determination of dry molecular weight, and the
Alternative Method is used to determine moisture
(water vapor) content.
Positive values for locations above the barometer and
negative values for locations below the barometer are
entered here. (Computations reverse the signs to
yield correct results.)
-------
40 CFR 60, APPENDIX A, METHOD 2* -
GAS STREAM VELOCITY AND VOLUMETRIC FLOW RATE FIELD DATA SHEET
MRl Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location: -3
Operator(s):
Run No.
Date:
Type S Pitot Tube No.
Pitot Tube Coefficient (CJ:
Temperature Meter No. Y~ O7ff3
Thermocouple No
Barometer No.
Elevation Change** from Barometer Location to Sampling Location:
Cross Sectional Area of Duct at Sampling Location:
Carbon Dioxide Concentration By Volume, Dry Basis:
Oxygen Concentration By Volume, Dry Basis:
feet
'ft3
&>•£>
FIRST TRAVERSE - START OF RUN
Start Time: O93O Stop Time:
SECOND TRAVERSE - END OF RLN
Start Time:
Barometric Pressure (Pbar) at Barometer Location: ZOsS"? in. Hg
Velocity Head (Ap) at Centroid of Duct: O>^O in. H2O
Total Pressure (P) at Centroid of Duct: -/29//^f in. H2O
Stop Time:
PK_!
AP:
P:
in. Hg
in. H,O
in. H,O
Leak Checks - Initial:
Final:
Initial:
Final:
Traverse
Point Number
J-3
3-3
Velocity Head,
(Ap), in. H2O
Gas Stream
Temp. (ts), °F
o.VJT
A
0,37
0,3-2-
0,09
Rotation
Angle, a
JZ-
so
7
SO
*
Traverse
Point Number
Velocity Head,
(Ap), in. H2O
Gas Stream
Temp, (g, °F
* 40 CFR 60, Appendix A, Method 3 is used for the determination of dry gas molecular weight, and the Alternative Method is used for
the determination of moisture content.
* * Enter positive values for locations above barometer and negative values for locations below barometer.
Comments:
M2TSWBOB.WPD September 18,1997 (lev. M2TSAMM.WPD July 15, 1998)
-------
40 CFFt 60, APPENDIX A, METHOD 2* -
GAS STREAM VELOCITY AND VOLUMETRIC FLOW RATE FIELD DATA SHEET
MR1 Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location: <2
Operator(s): J,
Run No.
Date:
&,
Type S Pitot Tube No.
Pitot Tube Coefficient (Cp):
f*r-oe>3
Temperature Meter No.
Thermocouple N
Barometer No.
Elevation Change** from Barometer Location to Sampling Location:
Cross Sectional Area of Duct at Sampling Location:
Carbon Dioxide Concentration By Volume, Dry Basis:
Oxygen Concentration By Volume, Dry Basis:
y-
feet
ft3
FIRST TRAVERSE - START OF RUN
Start Time: 09t>2~' Stop Time:
Barometric Pressure (Pbar) at Barometer Location: Z&.33 in. Hg
Velocity Head (Ap) at Centroid of Duct: 9-&O in. H2O
Total Pressure (P) at Centroid of Duct: 6,3O in. H2O
SECOND TRAVERSE - END OF RUN
Start Time: /ZZJ Stop Time:
Leak Checks - Initial: /JoLcffl<
Final:
Initial:
Traverse
Point Number
3-3
•J-J
Velocity Head,
(A^), in. H20
0,31
£>,'?<)
0,92.
0.90
Gas Stream
Temp. (ts), °F
£67
Rotation
Angle, a
Traverse
Point Number
Velocity Head,
(Ap), in. H2O
J-3
f.-L,
3-3
3-3
V-J
s-z-
0*33
0.3 ~z~-
0.ZO
0,34
&J3
0,30
Gas Stream
Temp, (ts), °F
#0)
1Z03
3Z&3
* 40 CFR 60, Appendix A, Method 3 is used for the determination of dry gas molecular weight, and the Alternative Method is used for
the determination of moisture content.
* * Enter positive values for locations above barometer and negative values for locations below barometer.
Comments:
M2TSWBDB.WPD September 18, 1997 (rev. M2TSAMM.WPD July 15. 1998)
-------
TRAVERSE POINT LOCATION FOR RECTANGULAR DUCTS
MRI Project No.
Client:
Sampling Location:
Date:
For Run Numbers:
4701.08.03.04
USEPA-EMC
3
ALL
*
a
Compass Direction
Flow is toward away from observer and is upward downward horizontal
Inside of far wall to outside of port (Distance A):
Inside of near wall to outside of port (Distance B):
Traverse distance (A - B):
Internal duct dimension normal to traverses:
Number of test ports:
Distance between port centers:
Distance of nearest flow disturbance upstream from ports:
Distance of nearest flow disturbance downstream from ports:
Number of test points per traverse (i.e., per port):
Distance between test points on a traverse:
Dimensions obtained by/from:.
Data recorded by: J-
inches
inches
inches
inches
inches
inches
inches
COMMENTS:
DUCTRECT.WPD August 12, 1996 (rev. DUCTREC.WPD July IS. 1998)
-------
OXYGEN AND CARBON DIOXIDE BY ORSAT
PROJECT NO.
SAMPLE NO
RUN NO.
DATE _
/
PLANT SAMPLING LOCATION
ANALYSIS TIME (24hr-CLOCK)
SAMPLE TYPE
OPERATOR
ORSAT LEAK CHECK BEFORE ANALYSIS:
BURETTE K%T CHANGE IN 4 MIN.
PIPETTES w* CHANGE IN 4 MIN.
ORSAT LEAK CHECK AFTER ANALYSIS:
BURETTE ^^ CHANGE IN 4 MIN.
PIPETTES &?s CHANGE IN 4 MIN.
>V\V^ RUN
GAS ^^^v^
C02
02 (NET IS SECOND
READING MINUS ACTUAL
COg READING)
1
ACTUAL
READING
1 6 ' .0
2 6,1
3 £.0
1 /T/ 1"
2 /r. i*
t> l£ 1"
NET
*'°
7 ' ^
2
ACTUAL
READING
1 £.0
2 £.0
3 /.o
1 /J",2-
2 /5"« 2-
3 /iH 2-
NET
f.o
7 • ^
3
ACTUAL
READING
1 £. o
2 x' o
3 /.o
1 /r/2-
2 /r-^
3 /^r~l^
NET
^.0
/' ')-
AVERAGE
NET
VOLUME
C.o
f, 1^"
91-16 SEV SURMANwkshl 052191
CO-
Comments:
Acceptance Criteria
.3% by Volume
.2% by Volume
02 >15% .2% by Volume
<15% .3% by Volume
-------
OXYGEN AND CARBON DIOXIDE BY ORSAT
PROJECT NO.
SAMPLE NO.-
DATE
PLANT SAMPLING LOCATION
ANALYSIS TIME (24hr-CLOCK)
SAMPLE TYPE (BAG GRAB)
OPERATOR
ORSAT LEAK CHECK BEFORE ANALYSIS:
BURETTE —<^ CHANGE IN 4 MIN.
PIPETTES —^ CHANGE IN 4 MIN.
ORSAT LEAK CHECK AFTER ANALYSIS:
BURETTE <2 CHANGE IN 4 MIN.
PIPETTES Q CHANGE IN 4 MIN.
^X. RUN
GAS ^\
C02
02 (NET IS SECOND
READING MINUS ACTUAL
COg READING)
1
ACTUAL
READING
•* j/ &
\ f -
O // fy
o (St f)
1/0-?
2 !(/• "t-
3/^.3-
NET
I*
2
ACTUAL
READING
1 tf-6
W-e
Mk-~
2/fr'to
Z «*'•>•
NET
f.o
4^
»>
3
ACTUAL
READING
1 ^*
IK
fficfa,?-
2 /£>- *
3 /^-^
NET
y.6
v
AVERAGE
NET
VOLUME
*°
ty.i-
91-16 SEV SURMANwteM 052191
CO,
Comments:
Acceptance Criteria
.3% by Volume 00 ;
.2% by Volume
.2% by Volume
<15% .3% by Volume
-------
MOISTURE (ALTERNATIVE METHOD) FIELD DATA CALCULATIONS
DATA ENTRY AND SUMMARY OF RESULTS
MRI Project No. 4701.08.03.04
Client USEPA-EMC
Sampling Location: 3
Run No. 1
Date: 07/21/98
Metering Console No. VOST 2"
Dry Gas Meter I
Imping
Gas Stream Ter
Gas Stream Static
Barometric
-actor (Y): 0.983
er Set No. A
nperature:
Pressure:
Pressure:
Gas Stream Volumetric Flow Rate:
In
Clock
Time,
24-hr
1122
1132
1142
1152
1202
1212
1222
1232
1242
1252
1302
1312
1322
1332
1342
1352
1402
1412
1422
itial Impingers Weight:
Dry Gas
, Meter
Volume;
Liters
0.000
6.250
12.580
18.800
24.080
30.320
36.570
42.790
49.060
55.320
61.600
67.850
74.120
80.360
86.620
92.870
99.140
105.400
111.250
Average
Dry Gas
Meter
Temp.,
°F •
42.0
42.0
41.0
42.0
42.0
45.0
47.0
47.0
47.0
46.0
44.0
43.0
45.0
44.0
43.0
43.0
42.0
41.0
550.90
Dry Gas
Meter
Pressure,
In. w.c.
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
grams
Gas
Stream
Temp:,
°F
— ,
Constant
Sampling
' Rate
Variation
1.12%
2.42%
0.64%
-14.57%
0.96%
1.12%
0.64%
1.45%
1.29%
1.61%
1.12%
1.45%
0.96%
1 .29%
1.12%
1.45%
1.29%
-5.35%
256
-0.10
29.35
18,758
Vapor
Pressure
Of
Water, ,
in, Hg:
°F
in. w.c.
in. Hg
dscfm
Percent
Water
Vapor
(Saturated),
v/v
Final Impingers Weight: 579.60 grams
Sample Volume and Conditions and Moisture Results
Gas Sample Volume:
Gas Sample Volume at Standard Conditions:
Average Absolute Sampled Gas Temperature:
Average Absolute Sampled Gas Pressure:
Condensate Collected:
Moisture (Water Vapor):
3.929 dcf
0.1113 dcm
3.971 dscf
0.1125 dscm
503.34 °R
279.63 °K
29.35 in. Hg
745.49 mmHg
28.70 ^rams
25.42 %v/V
MOISTURLWK4 03/02/95 (rev. MOIST3_1.WK4 07/29/98 03:52 PM)
-------
MOISTURE (ALTERNATIVE METHOD) FIELD DATA CALCULATIONS
DATA ENTRY AND SUMMARY OF RESULTS
MRI Project No.
Client:
Sampling Location:
Run No.
Date:
4701.08.03.04
USEPA - EMC
3
2
07/22/98
Initial Impingers Weight:
Clock
Time,
24-hr
0936
0946
0956
1006
1016
1026
1036
1046
1056
1106
"1116
1126
"""1136"""
1146
1156
1206
1216
1226
1234
Dry Gas
- Meter
Volume,
Liters
0.000
6.980
14.010
20.960
28.060
35.110
42.060
48.990
55.970
63.010
70.050
77.010
84.030
91.050
98.010
105.050
112.070
119.010
124.333
Average
. • Dry Gas
Meter
Temp.,
°F
28.0
29.0
30.0
33.0
35.0
36.0
37.0
37.0
37.0
38.0
38.0
40.0
40.0
40.0
40.0
39.0
40.0
40.0
Dr>
Ga
GasS
Gas Stream
550.50
Dry Gas
Meter
Pressure,
in. w.c. .
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
0.00
Metering Console No.
' Gas Meter Factor (Y):
Impinger Set No.
s Stream Temperature:
Jtream Static Pressure:
Barometric Pressure:
Volumetric Flow Rate:
grams
Gas
Stream
Temp.,
°F
Constant
Sampling
Rate
Variation
-0.07%
0.64%
-0.50%
1.65%
0.93%
-0.50%
-0.79%
I -0.07%
0.79%
0.79%
-0.36%
0.50%
0.50%
-0.36%
0.79%
0.50%
-0.64%
-3.79%
VOST2
0.983
A
267
-0.12
29.31
23,221
Vapor
Pressure.
Of
Water,
in. Hg
°F
in. w.c.
in. Hg
dscfm
, Percent
Water ...
Vapor
(Saturated),
v/v
Final Impingers Weight: 595.10 grams
Sample Volume and Conditions and Moisture Results
Gas Sample Volume:
Gas Sample Volume at Standard Conditions:
Average Absolute Sampled Gas Temperature:
Average Absolute Sampled Gas Pressure:
Condensate Collected:
Moisture (Water Vapor):
4.391
0.1243
4.496
0.1273
496.17
275.65
29.31
744.47
44.60
31.87
dcf
dcm
dscf
dscm
°R
°K
in. Hg
mm Hg
grams
% v/v
MOISTURL.WK4 03/02/95 (rev. MOIST3_2.WK4 07/29/98 04:08 PM)
-------
ALTERNATIVE METHOD - MOISTURE TRAIN FIELD DATA SHEET
MRI Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location:
Run No. /#/
Date^X^^* 07~*?J' JP
Operator(s): d*£tJi't*>&s7
Initial Imoinqers Wt.: ^*c5^' 9 qrams
Silica qel: /OO % blue
Gas S1
Initial Leak Check: O cc/min @ /5^
Dry Gas Dry Gas Dry Gas
Clock Meter Meter Meter
Time, Volume, Temperature*, Pressure
24-Hr Liters °F in. w.c.
J/0Z O.OOO
M32 &,3*T ¥& £>
//yZ' /£,58 43. ^
//£& tf.&o 41 o
Metering Console No. \SOSyZZ.
Dry Gas Meter Factor (Y): 0*f£3
Impinqer Set No. /%
Gas Stream Temperature: ^^""7 °
F
Gas Stream Static Pressure: ~-'O,J&2* jn. w.c.
Barometric Pressure: £?9>&5 \
tream Volumetric Flow Rate: ^t?<5* c
in. Hg vacuum
n. Hg
jscfm
Flow Impinger Gas
Rate Outlet Pump Stream
Meter Temperature, Vacuum, Temperature,
Setting °F in. Hg °F
7o &8 ^ /
-70 G>7 2
70 &7 Z?
/fol^ ^WtQft t£- & "71? &>8 ^
/£j3- 3&,51l V2-~ o
/#•&?• Jb.SJ ' *J& 6
fcl^rf f-J^2 SjG& £^*~J A
/^ (2 ^* *^^ ^ / / ^7 f t'
/^V/J. i
/?&£. •&&.&2* 41 O
JZtZ' bf.&O 4G> 0
70 && ^
76 •& 3
70 bO 12
*?Q 6>J x?
•70 &/ 3
7O &3 a.
t3) 1~- fcZ 8<£~ *£'£ D 7o &o Z£
/3%-Z. 2^J^2- &3 & 70 ; G?'Z~~ jZ.
/5J^- £0,36> 4<5" £> "70 /£>£ ^?
/<5v^ j^, kji //y o
70 63 ?—
J3&2- *?#> 97 43 t> ~7b &> 3 5Z-
fL}0jL ^— z_
//y/^- /^5?y^ *£3\ & 7^> &~2-~ 'z—
/nl -¥*£&%: J'J-JtD&'b f} 1,350 *}} 0
11 '
70 &>3 Z-
* For dry gas meters having two thermocouples, the average temperature is entered.
Final Leak Check: O cc/min @ /^
Final Impinaers Wt.: ^~7&>& qrams Silica
in. Hg vacuum
ael: JO % blue
Comments:
MOISTRtX.WPD April 14, 1995 (rev. MOIST.WPD July 13, 1998)
-------
ALTERNATIVE METHOD - MOISTURE TRAIN FIELD DATA SHEET
MRI Project No. 4701.08.03.04
Client: USEPA-EMC
Sampling Location: 3
Run No. £?
Date: 07~+?52-'?8'
Ooerator(s): d,3i4ff>9y?
Initial Imoinqers Wt.: ^'^0t^' qrams
Silica qel: /&& % blue
Initial Leak Check: O cc/min @
Dry Gas Dry Gas
Clock Meter Meter
Time, Volume, Temperature*,
24-Hr Liters °F
e>9y-fa 6>.3£ £fr
Metering Console No. \/0Sy£Z
Dry Gas Meter Factor (Y): 0. ^S"3
Impinger Set No. ^)
Gas Stream Temperature: °F
Gas Stream Static Pressure: in. w.c.
Barometric Pressure: £?J.3 ) in. Hq
Gas Stream Volumetric Flow Rate: dscfm
/£?"
Dry Gas
Meter
Pressure
in. w.c.
/?
in. Hg vacuum
Flow Impinger Gas
Rate Outlet Pump Stream
Meter Temperature, Vacuum, Temperature,
Setting °F in. Hg °F
6>9&(s Mol ^^ O ~7& hi ^
J& 0(0 2&.9L Z3&
O
"70 (f>7 ZL
jDJlo 3t&0(f 33 0 7O 67 ^
/02b 3&./J <35"~ O 7O &>~7 ,££
/03(o tJ-4-,0(* ' 3(0 0 7t) && ^
1 Pi /jf/ j i<3 A A ^3 **?
/ C/ *t^ jrOt€ / *-S S
/0.5& £&?7 37
//£>&, &2>\ f> / 37
O
O
£)
~7o <2x5" &•
-70 A^ z:
70 &tf "^
n) (, 70^0 W 0) 3f
//36 ^y, 03 40
// '/(y JJ' 0&~ 4 O
*/£"(* V8.O} &&
/lot, /AfT,os" 40
/£/(* J/&-0J 31
D
d
O
0
0
o
"70 ' & 6y 52.
-7& £>& ^.
7o 67 ZZ.
7D 4>6? ^?
7t> 67 X
-yp &,-? Z-
/3. I tfO O 7& i>7 "Z—
/23(s\ /1U.333 ^o
£>
70 Cal ^?
*~ Sshvfdo^j-* :»^/'X?V
• For dry gas meters having two thermocouples, the average temperature is entered.
Final Leak Check:
Final Impingers Wt.:
Comments:
cc/min @
grams Silica gel:
in. Hg vacuum
% blue
MOISTRLX.WPD April 14, 1995 (rev. MOIST.WPD July 13, 19981
-------
Appendix C
Direct (Extractive) FTIR Results
MRI-AED\R4951-04-08.wpd
-------
Loadout Concentration vs. Time (7/24)
•Toluene (ppm) —B—Propane (ppm) A Hexane (ppm) X Ethylene (ppm) —*—Methane (ppm) O CO (ppm) —I—Formal-dehyde (ppm)
350.0
300.0
250.0
200.0
I 150.0 1
100.0 -
50.0 -
0.0 -
-50.0
7:45 8:15 8:45 9:15
9:45 10:15 10:45
Time
11:15 11:45 12:15 12:45
-------
Loadout Concentration vs. Time (7/24)
•Toluene (ppm) —•— Propane (ppm) A Hexane (ppm) —*— Ethylene (ppm) X Methane (ppm) • CO (ppm) —I—Formal-dehyde (ppm)
30.0
25.0
20.0
15.0
10.0
5.0
0.0 -
S
a.
0-
-5.0
7:45 8:15 8:45 9:15
9:45 10:15 10:45
Time
11:15 11:45 12:15 12:45
-------
Loadout Concentration vs. Time (7/25)
•Toluene (ppm) —•—Propane (ppm) A Hexane (ppm) X Ethylene (ppm) X Methane (ppm) • • CO (ppm)
190.0
140.0
90.0 -
40.0
-10.0
7:00 7:30 8:00 8:30
9:00 9:30
Time
10:00 10:30 11:00
-------
Loadout Concentration vs. Time (7/25)
14.0
12.0
-2.0
7:00
•Toluene (ppm) —•— Propane (ppm) A Hexane (ppm) X Ethylene (ppm) —5*— Methane (ppm) • CO (ppm)
7:30
8:00
8:30
9:00 9:30
Time
10:00
10:30
11:00
-------
Loadout Concentration vs. Time (7/26)
4.0
Toluene (ppm) —•— Propane (ppm) —A— Hexane (ppm) —*— Ethylene (ppm) —*—Methane (ppm) —•—CO (ppm)
3.5
3.0
2.5 -
2.0
1.0 -
0.5 -
0.0
-0.5 -
-1.0
9:00
9:30
10:00
10:30
11:00
11:30
Time
12:00
12:30
13:00
13:30
14:00
-------
Loadout Concentration vs. Time (7/27)
•Toluene (ppm) —B— Propane(ppm) A Hexane (ppm) X Ethylene (ppm) X Methane (ppm) —•—CO (ppm)
40.0
35.0
30.0
25.0
20.0-
15.0-
10.0
5.0 -
0.0 -
-5.0
7:00 7:30 8:00 8:30
9:00 9:30 10:00
Time
10:30 11:00 11:30 12:00 12:30
-------
Loadout Concentration vs. Time (7/27)
•Toluene (ppm) —•— Propane (ppm) A Hexane (ppm) —X—Ethylene (ppm) —*—Methane (ppm) • CO (ppm)
5.0
4.0
3.0
H 2.0 H
SW
1.0
0.0 -
t
-1.0
7:00 7:30 8:00 8:30 9:00
9:30 10:00
Time
10:30 11:00 11:30 12:00 12:30
-------
Silo Concentrations (7/24)
>— Carbonyl Sulfide (ppm) —a—Toluene (ppm) —A-Iso-Octane (ppm) —*— Hexane (ppm) -*—Ethyleiie (ppm) —»—Methane (ppm) —t— CO (ppm)
380
330
280
230
! 180
OH
130
80 -
30 -
-20
7:00
7:30
8:00
8:30
9:00
Time
9:30
10:00
10:30
-------
Silo Concentrations (7/25)
•Carbonyl Sulfide (ppm) O Toluene (ppm) A Iso- Octane (ppm) X Hexane (ppm) X Ethylene (ppm) • Methane (ppm) —I—CO (ppm)
330
280 -
230
180 ^
130 -
80 -
30 -
-20
8:40
8:50
9:00 9:10
Time
9:20
9:30
-------
Results:
Fit file:
1 /11/99 16:19
procstk.fit
File Name
File Name
17210008
17210009
17210010
17210011
17210012
17210013
17210014
17210015
17210016
17210017
17210018
17210019
17210020
17210021
17210022
17210023
17210024
17210025
17210026
17210027
17210028
17210029
17210030
17210031
17210032
17210033
17210034
17210035
17210036
17210037
17210038
17210039
17210040
17210041
17210042
17210043
17210044
17210045
17210046
Date
Date
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
Time
Corrected
11:28
11:43
11:44
11:46
11:48
11:50
11:51
11:53
11:55
11:57
11:58
12:00
12:02
12:04
12:06
12:07
12:09
12:11
12:13
12:14
12:16
12:18
12:20
12:21
12:23
12:25
12:27
12:28
12:30
12:41
12:42
12:44
12:46
12:48
12:49
12:51
12:53
12:55
12:57
Uncer-
Propane tainty
rop/upper/pp 2*sigma
0.0 5.2
0.0 56.1
0.0 52.3
0.0 56.2
0.0 47.5
0.0 52.2
0.0 56.1
0.0 37.8
0.0 42.6
0.0 29.0
0.0 51.8
0.0 52.2
0.0 52.0
0.0 44.2
0.0 44.2
0.0 37.9
0.0 56.6
0.0 52.2
0.0 38.2
0.0 51.8
0.0 51.7
0.0 55.8
0.0 51.8
0.0 30.5
0.0 43.4
0.0 36.9
0.0 51.8
0.0 51.8
0.0 36.9
71.5 1.8
73.9 1.5
74.5 1.5
75.1 1.5
40.6 2.0
0.0 12.8
0.0 11.7
0.0 11.5
0.0 12.5
0.0 10.9
Uncer-
Methane tainty
96/upper/ppm 2*sigma
28.7 3.8
0.0 42.7
0.0 39.9
0.0 42.8
0.0 36.2
0.0 39.8
0.0 42.7
0.0 28.8
0.0 32.5
0.0 22.1
0.0 39.4
0.0 39.8
0.0 39.6
0.0 33.7
0.0 33.7
31.1 26.8
0.0 43.1
0.0 39.8
31.3 27.0
0.0 39.4
0.0 39.4
0.0 42.5
0.0 39.4
26.9 21.6
0.0 33.1
0.0 28.1
0.0 39.4
0.0 39.5
0.0 28.1
14.3 5.9
12.3 5.1
12.3 5.1
12.2 5.1
19.1 6.7
28.2 9.1
26.5 8.3
25.9 8.2
23.2 8.8
23.0 7.7
Uncer-
CO tainty
DO/Mid/pp 2*sigma
201.2 37.7
0.0 185.3
0.0 173.0
0.0 185.8
0.0 173.8
0.0 178.7
0.0 183.6
0.0 182.9
0.0 178.2
0.0 168.1
0.0 169.7
0.0 171.1
0.0 176.9
0.0 179.0
0.0 179.1
0.0 171.6
0.0 181.9
0.0 187.6
0.0 165.8
0.0 164.3
0.0 164.9
0.0 174.6
0.0 164.3
0.0 163.8
0.0 164.7
0.0 164.7
0.0 164.1
0.0 164.8
0.0 162.5
0.0 97.5
0.0 98.0
0.0 97.9
0.0 97.9
0.0 124.1
153.4 129.9
159.0 133.2
146.3 133.8
0.0 131.5
0.0 136.3
-------
File Name
17210047
17210048
17210049
17210050
17210051
17210052
17210053
17210054
17210055
17210056
17210057
17210058
17210059
17210060
17210061
17210062
17210063
17210064
17210065
17210066
17210067
17210068
17210069
17210070
17210071
17210072
17210073
17210074
17210075
17210076
17210077
17210078
17210079
17210080
17210081
17210082
17210083
17210084
17210085
17210086
17210087
17210088
17210089
Date
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
7/21/98
Time
12:58
13:07
13:08
13:10
13:12
13:14
13:15
13:17
13:19
13:21
13:22
13:24
13:26
13:28
13:30
13:31
13:33
13:35
13:37
13:38
13:40
13:42
13:44
13:45
13:47
13:49
13:51
13:52
13:54
13:56
13:58
14:00
14:01
14:03
14:05
14:07
14:08
14:10
14:12
14:14
14:15
14:17
14:19
Average — >
Uncer-
Propane tainty
0.0 14.3
0.0 51.9
0.0 42.6
0.0 38.1
0.0 36.8
0.0 42.9
0.0 36.8
0.0 39.7
0.0 58.8
0.0 37.3
0.0 55.5
0.0 51.5
0.0 37.0
0.0 51.3
0.0 46.5
0.0 51.5
0.0 51.3
0.0 51.4
0.0 41.9
0.0 51.3
0.0 51.4
0.0 51.8
0.0 41.7
0.0 51.4
0.0 51.4
0.0 51.5
0.0 51.4
0.0 46.6
0.0 51.4
0.0 37.5
0.0 55.2
0.0 51.4
0.0 55.3
0.0 51.4
0.0 52.6
0.0 49.1
0.0 37.3
0.0 55.4
0.0 51.4
0.0 55.3
0.0 51.6
0.0 36.7
Q& 61.1
4.1 41.9
Uncer-
Methane tainty
26.1 10.1
75.9 36.7
77.1 30.2
84.2 27.0
98.3 26.0
93.3 30.4
103.5 26.0
96.0 28.1
72.9 41.6
92.5 26.3
76.8 39.3
80.3 36.4
96.7 26.2
88.5 36.3
91.2 32.9
97.7 36.4
97.3 36.3
76.2 36.4
75.1 29.7
72.2 36.3
75.3 36.3
69.8 36.6
77.3 29.5
68.4 36.4
71.8 36.3
75.2 36.5
69.3 36.4
46.6 33.0
0.0 39.1
35.5 26.6
0.0 42.0
0.0 39.1
0.0 42.1
0.0 39.1
0.0 40.0
0.0 37.4
61.6 26.4
62.5 39.3
96.3 36.4
117.4 39.1
144.1 36.5
160.0 25.9
268.Q 43.2
42.5 30.9
Uncer-
CO tainty
0.0 126.4
348.1 176.0
331.0 168.5
354.8 167.4
327.0 163.4
280.9 166.8
244.5 170.4
228.4 166.0
267.0 172.5
264.7 169.7
270.6 177.5
244.2 176.9
238.7 168.6
224.3 164.3
226.6 164.7
233.0 167.2
246.9 164.8
209.7 183.6
195.2 167.1
205.3 167.4
213.3 170.5
198.8 183.3
201.6 168.4
200.4 175.8
181.8 170.7
193.3 178.3
183.7 169.2
191.9 168.4
0.0 167.9
0.0 167.9
0.0 176.5
0.0 168.0
0.0 172.6
0.0 164.4
0.0 177.2
0.0 164.0
181.4 166.4
228.5 175.0
256.1 183.1
240.0 182.2
189.6 172.2
176.8 161.4
fiLQ 178.9
102.9 163.1
-------
File Name
17220002
17220003
17220004
17220005
17220006
17220007
17220008
17220009
17220010
17220011
17220012
17220013
17220014
17220015
17220016
17220017
17220018
17220019
17220020
17220021
17220022
17220023
17220024
17220025
17220026
17220027
17220028
17220029
17220030
17220031
17220032
17220033
17220034
17220035
17220036
17220037
17220038
17220039
17220040
17220041
17220042
17220043
17220044
17220045
17220046
17220047
17220048
Date
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
Time
9:38
9:41
9:43
9:44
9:46
9:48
9:50
9:51
9:53
9:55
9:57
9:58
10:00
10:02
10:04
10:06
10:07
10:09
10:11
10:13
10:14
10:16
10:18
10:20
10:21
10:23
10:25
10:27
10:28
10:30
10:32
10:34
10:36
10:37
10:39
10:41
10:43
10:45
10:46
10:48
10:50
10:52
10:53
10:55
10:57
10:59
11:01
Uncer-
Propane tainty
0.0 48.1
0.0 60.2
0.0 60.1
0.0 65.5
0.0 62.9
0.0 65.6
0.0 65.8
0.0 65.9
0.0 65.3
0.0 65.6
0.0 65.5
0.0 65.8
0.0 65.7
0.0 62.9
0.0 65.7
0.0 60.1
0.0 66.5
0.0 60.6
0.0 74.8
0.0 64.8
0.0 62.8
0.0 66.0
0.0 64.7
0.0 66.0
0.0 57.5
0.0 65.9
0.0 64.7
0.0 65.7
0.0 63.0
0.0 57.7
0.0 62.7
0.0 54.3
0.0 54.4
0.0 54.6
0.0 66.4
0.0 60.3
0.0 76.6
0.0 65.9
0.0 65.9
0.0 66.0
0.0 66.1
0.0 75.1
0.0 65.9
0.0 66.7
0.0 57.7
0.0 66.3
0.0 66.1
Uncer-
Methane tainty
0.0 36.6
51.8 42.9
49.5 42.9
0.0 49.9
0.0 47.9
0.0 49.9
0.0 50.1
0.0 50.2
0.0 49.7
0.0 50.0
0.0 49.9
0.0 50.1
0.0 50.0
0.0 47.9
0.0 50.0
48.7 43.0
0.0 50.6
52.2 43.3
0.0 57.0
0.0 46.3
52.1 44.8
0.0 47.1
0.0 46.1
0.0 47.1
41.7 41.0
0.0 47.1
0.0 46.2
0.0 50.0
46.7 45.0
43.4 41.2
52.7 44.7
0.0 41.4
0.0 41.4
0.0 41.5
0.0 50.5
51.2 43.1
0.0 58.3
0.0 50.2
0.0 50.2
0.0 50.2
0.0 50.3
0.0 57.2
0.0 50.2
0.0 50.8
0.0 44.0
0.0 50.5
0.0 50.3
Uncer-
CO tainty
0.0 164.3
0.0 175.8
0.0 174.2
0.0 180.8
0.0 173.8
0.0 179.6
0.0 177.5
0.0 180.4
0.0 182.6
0.0 181.2
0.0 180.9
0.0 177.8
0.0 181.1
0.0 174.5
0.0 180.9
0.0 175.3
0.0 174.2
0.0 168.9
0.0 180.5
0.0 174.9
0.0 170.2
0.0 181.6
0.0 178.8
0.0 177.0
0.0 160.0
0.0 176.7
0.0 177.6
0.0 181.5
0.0 175.4
0.0 177.8
0.0 177.0
0.0 161.0
0.0 164.0
0.0 164.4
0.0 178.9
0.0 171.1
0.0 177.3
0.0 179.0
0.0 184.6
0.0 178.4
0.0 180.1
0.0 179.0
0.0 178.5
0.0 174.3
0.0 172.8
0.0 176.8
0.0 184.0
-------
File Name
17220049
17220050
17220051
17220052
17220053
17220054
17220055
17220056
17220057
17220058
17220059
17220060
17220061
17220062
17220063
17220064
17220065
17220066
17220067
17220068
17220069
17220070
17220071
17220072
17220073
17220074
17220075
17220076
17220077
17220078
17220079
17220080
17220081
17220082
17220083
17220084
17220085
17220086
17220087
17220088
17220089
17220090
17220091
Date
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
7/22/98
Time
11:02
11:04
11:06
11:08
11:32
11:33
11:35
11:37
11:39
11:40
11:42
11:44
11:46
11:48
11:49
11:51
11:53
11:55
11:56
11:58
12:00
12:02
12:03
12:05
12:07
12:09
12:11
12:12
12:14
12:16
12:18
12:19
12:21
12:23
12:25
12:26
12:28
12:30
12:32
12:34
12:35
12:37
14:31
Average -->
Oncer-
Propane tainty
0.0 73.7
0.0 75.5
0.0 60.5
0.0 54.4
0.0 54.8
0.0 54.6
0.0 57.7
0.0 64.6
0.0 62.8
0.0 60.5
0.0 60.4
0.0 64.8
0.0 60.3
0.0 50.1
0.0 64.9
0.0 50.3
0.0 65.3
0.0 61.4
0.0 50.2
0.0 49.7
0.0 53.4
0.0 45.0
0.0 44.8
0.0 57.3
0.0 45.2
0.0 45.0
0.0 45.1
0.0 53.3
0.0 62.4
0.0 56.7
0.0 55.1
0.0 56.7
0.0 53.3
0.0 60.8
0.0 59.9
0.0 51.1
0.0 46.7
0.0 60.1
0.0 65.4
0.0 64.9
0.0 57.3
0.0 62.7
0.0 0.1
0.0 60.7
Uncer-
Methane tainty
0.0 56.1
0.0 57.5
50.6 43.2
0.0 41.5
0.0 41.8
0.0 41.6
50.7 41.1
64.9 46.0
104.2 44.7
109.9 43.1
124.2 43.0
199.1 46.2
219.1 42.9
257.7 35.5
268.2 46.2
223.5 35.7
219.8 46.5
178.6 43.7
136.0 35.7
122.0 35.3
117.6 38.0
122.3 32.0
121.6 31.8
122.8 40.8
110.6 32.1
118.1 31.9
123.7 32.0
110.3 37.9
163.3 44.5
119.9 40.3
117.8 39.2
119.7 40.3
114.7 37.9
145.3 43.3
163.5 42.7
174.8 36.2
194.8 33.1
185.7 42.7
219.8 46.6
244.8 46.2
161.1 40.8
187.3 44.6
0.0 0.1
68.3 44.5
Uncer-
CO tainty
0.0 178.8
0.0 183.6
0.0 170.8
0.0 162.9
0.0 173.6
0.0 162.9
0.0 174.3
0.0 172.2
276.8 172.2
317.9 174.0
258.5 162.6
200.2 178.4
0.0 168.2
0.0 171.1
174.6 165.4
182.6 170.7
0.0 176.9
0.0 164.3
0.0 169.3
0.0 169.6
0.0 168.4
0.0 171.8
0.0 178.0
0.0 163.8
0.0 171.1
0.0 179.9
0.0 183.2
0.0 167.2
0.0 176.1
0.0 165.8
0.0 166.6
0.0 165.6
0.0 168.1
0.0 175.6
0.0 165.9
0.0 170.4
0.0 171.3
175.5 167.1
0.0 182.3
195.1 166.8
184.2 165.7
0.0 166.4
0.0 0.2
22.1 173.7
-------
Table - . Tunnel Emissions Duct
File Name Date Time
17240030 7/24/98 8:12
17240031 7/24/98 8:14
17240032 7/24/98 8:16
17240033 7/24/98 8:18
17240034 7/24/98 8:20
17240035 7/24/98 8:21
17240036 7/24/98 8:23
17240037 7/24/98 8:25
17240038 7/24/98 8:27
17240039 7/24/98 8:28
17240040 7/24/98 8:30
17240041 7/24/98 8:32
17240042 7/24/98 8:34
17240043 7/24/98 8:36
17240044 7/24/98 8:37
17240045 7/24/98 8:39
17240046 7/24/98 8:41
17240047 7/24/98 8:43
17240048 7/24/98 8:44
17240049 7/24/98 8:46
17240050 7/24/98 8:48
17240051 7/24/98 8:50
17240052 7/24/98 8:52
17240053 7/24/98 8:53
17240054 7/24/98 8:55
17240055 7/24/98 8:57
17240056 7/24/98 8:59
17240057 7/24/98 9:00
17240058 7/24/98 9:02
17240059 7/24/98 9:04
17240060 7/24/98 9:06
Toluene
0.0 5.7
0.0 6.2
0.0 5.9
0.0 5.6
0.0 5.3
0.0 5.3
0.0 5.6
0.0 5.8
0.0 5.5
0.0 5.4
0.0 5.8
0.0 5.9
0.0 5.7
0.0 5.7
0.0 5.5
0.0 5.6
0.0 6.1
0.0 6.1
0.0 6.0
0.0 5.8
0.0 5.9
0.0 5.6
0.0 6.5
0.0 6.4
0.0 6.1
0.0 6.1
0.0 5.8
0.0 5.8
0.0 5.6
0.0 5.4
0.0 6.0
Propane Uncer-
(ppm) tainty
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.1
0.0 1.0
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.2
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.0
0.0 1.1
Hexane Uncer-
(ppm) tainty
2.8 0.2
5.0 0.2
3.4 0.2
2.2 0.2
1.3 0.2
0.9 0.2
2.4 0.2
3.3 0.2
2.6 0.2
2.0 0.2
3.6 0.2
4.5 0.2
3.4 0.2
3.3 0.2
1.6 0.2
1.9 0.2
4.4 0.2
4.9 0.2
4.0 0.2
3.0 0.2
4.0 0.2
2.6 0.2
5.0 0.2
5.1 0.2
4.6 0.2
4.7 0.2
3.2 0.2
3.1 0.2
2.4 0.2
1.3 0.2
3.8 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.4
Methane Uncer-
(ppm) tainty
3.1 0.6
3.3 0.6
3.2 0.6
3.1 0.6
3.0 0.5
3.0 0.5
3.1 0.6
3.3 0.6
3.1 0.6
3.1 0.6
3.2 0.6
3.4 0.6
3.2 0.6
3.2 0.6
3.0 0.6
3.0 0.6
3.2 0.6
3.3 0.6
3.2 0.6
3.1 0.6
3.3 0.6
3.1 0.6
3.3 0.7
3.3 0.7
3.3 0.6
3.3 0.6
3.1 0.6
3.2 0.6
3.0 0.6
3.0 0.6
3.2 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
CO Uncer-
(ppm) tainty
8.0 4.5
5.4 4.8
0.0 4.9
5.3 4.4
0.0 4.6
0.0 4.5
0.0 4.8
7.5 4.6
6.3 4.5
5.1 4.4
0.0 4.9
7.4 4.7
5.2 4.6
0.0 4.9
0.0 4.7
0.0 4.8
0.0 5.1
6.3 4.8
5.7 4.8
7.4 4,7
6.3 4.7
0.0 4.8
0.0 5.4
7.3 5.0
5.8 4.8
6.3 4.8
0.0 4.9
0.0 5.0
0.0 4.8
0.0 4.7
0.0 5.1
1 of 4 loadout
-------
Tunnel Emissions Duct
17240060 7/24/98 9:06
17240061 7/24/98 9:07
17240062 7/24/98 9:09
17240063 7/24/98 9:11
17240067 7/24/98 9:18
17240068 7/24/98 9:20
17240069 7/24/98 9:22
17240070 7/24/98 9:23
17240071 7/24/98 9:25
17240072 7/24/98 9:27
17240073 7/24/98 9:29
17240074 7/24/98 9:30
17240120 7/24/98 10:55
17240121 7/24/98 10:57
17240122 7/24/98 10:59
17240123 7/24/98 11:00
17240124 7/24/98 11:02
17240125 7/24/98 11:04
17240126 7/24/98 11:06
17240127 7/24/98 11:07
17240128 7/24/98 11:09
17240129 7/24/98 11:11
17240130 7/24/98 11:13
17240131 7/24/98 11:14
17240132 7/24/98 11:16
17240133 7/24/98 11:18
17240134 7/24/98 11:20
17240135 7/24/98 11:21
17240136 7/24/98 11:23
17240137 7/24/98 11:25
Toluene
0.0 6.0
0.0 5.8
0.0 5.5
0.0 5.9
0.0 3.6
0.0 4.5
0.0 5.3
0.0 6.1
0.0 6.7
0.0 6.2
0.0 5.9
0.0 6.1
0.0 5.7
0.0 5.6
0.0 5.9
0.0 6.2
0.0 6.1
0.0 6.2
0.0 5.7
0.0 5.6
0.0 5.7
0.0 6.0
0.0 6.1
0.0 5.7
0.0 5.7
0.0 6.1
0.0 6.4
0.0 6.1
0.0 6.1
0.0 6.4
Propane Uncer-
(ppm) tainty
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.1
data unavailable
due to
THC spiking
0.0 0.6
0.0 0.7
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.2
0.0 1.2
Hexane Uncer-
(ppm) tainty
3.8 0.2
3.3 0.2
1.5 0.2
3.0 0.2
2.9 0.3
2.6 0.3
2.1 0.3
4.0 0.4
5.5 0.2
3.6 0.2
2.3 0.2
3.0 0.2
1.5 0.2
1.4 0.2
2.8 0.2
3.6 0.2
4.0 0.2
4.4 0.2
2.6 0.2
1.5 0.2
1.9 0.2
2.7 0.2
3.0 0.2
1.6 0.2
1.3 0.2
3.0 0.2
3.9 0.2
2.7 0.2
2.9 0.2
4.2 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.4
0.0 0.2
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.7 0.4
0.7 0.4
0.0 0.4
0.7 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
Methane Uncer-
(ppm) tainty
3.2 0.6
3.1 0.6
3.0 0.6
3.1 0.6
2.2 0.4
2.8 0.5
3.0 0.5
3.3 0.6
3.3 0.7
3.1 0.6
3.1 0.6
3.2 0.6
3.0 0.6
3.1 0.6
3.3 0.6
3.3 0.6
3.4 0.6
3.5 0.6
3.1 0.6
3.0 0.6
3.1 0.6
3.2 0.6
3.2 0.6
3.0 0.6
3.1 0.6
3.2 0.6
3.3 0.7
3.2 0.6
3.2 0.6
3.4 0.7
dehyde Uncer-
(ppm) tainty
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.5
0.0 0.6
0.0 0.7
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
CO Uncer-
(ppm) tainty
0.0 4.9
0.0 4.8
0.0 5.0
3.8 3.2
7.8 3.9
9.5 4.4
8.2 4.8
5.5 5.2
0.0 5.2
0.0 5.1
0.0 5.2
0.0 4.9
0.0 4.9
7.8 4.7
7.0 4.9
13.9 4.9
10.5 4.9
0.0 4.9
0.0 4.8
0.0 4.9
0.0 5.1
0.0 5.2
0.0 4.9
0.0 4.9
5.4 4.9
0.0 5.4
0.0 5.2
0.0 5.2
0.0 5.3
2 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time
17240138 7/24/98 11:27
17240139 7/24/98 11:28
17240140 7/24/98 11:30
17240141 7/24/98 11:32
17240142 7/24/98 11:34
17240143 7/24/98 11:36
17240144 7/24/98 11:37
17240145 7/24/98 11:39
17240146 7/24/98 11:41
17240147 7/24/98 11:43
17240148 7/24/98 11:44
17240149 7/24/98 11:46
17240150 7/24/98 11:48
17240151 7/24/98 11:50
17240152 7/24/98 11:51
17240153 7/24/98 11:53
17240154 7/24/98 11:55
17240155 7/24/98 11:57
17240156 7/24/98 11:58
17240157 7/24/98 12:00
17240158 7/24/98 12:02
17240159 7/24/98 12:04
17240160 7/24/98 12:05
17240161 7/24/98 12:07
17240162 7/24/98 12:09
17240163 7/24/98 12:11
17240164 7/24/98 12:12
17240165 7/24/98 12:14
17240166 7/24/98 12:16
17240167 7/24/98 12:18
17240168 7/24/98 12:19
Toluene
0.0 6.3
0.0 6.3
0.0 6.3
0.0 5.8
0.0 5.9
0.0 6.3
0.0 6.0
0.0 6.1
0.0 6.5
0.0 6.3
0.0 6.2
0.0 6.3
0.0 6.2
0.0 5.8
0.0 6.1
0.0 5.9
0.0 6.1
0.0 6.1
0.0 6.4
0.0 5.9
0.0 5.7
0.0 6.1
0.0 6.6
0.0 6.1
0.0 6.4
0.0 6.0
0.0 6.1
0.0 5.7
0.0 6.1
0.0 6.0
0.0 6.1
Propane Uncer-
(ppm) tainty
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.1
0.0 .1
0.0 .1
0.0 .2
0.0 .1
0.0 .2
0.0 .1
0.0 .1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
Hexane Uncer-
(ppm) tainty
4.1 0.2
3.6 0.2
3.6 0.2
2.1 0.2
1.7 0.2
3.1 0.2
2.5 0.2
2.3 0.2
3.2 0.2
3.8 0.2
3.3 0.2
3.8 0.2
3.8 0.2
2.1 0.2
2.5 0.2
2.4 0.2
2.8 0.2
2.8 0.2
4.3 0.2
2.9 0.2
1.6 0.2
2.6 0.2
4.4 0.2
3.2 0.2
3.7 0.2
2.9 0.2
3.4 0.2
2.0 0.2
2.6 0.2
2.6 0.2
3.4 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.6 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.7 0.4
0.0 0.4
0.0 0.4
Methane Uncer-
(ppm) tainty
3.3 0.6
3.3 0.6
3.3 0.6
3.1 0.6
3.1 0.6
3.3 0.6
3.1 0.6
3.2 0.6
3.3 0.7
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.0 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.3 0.7
3.1 0.6
3.0 0.6
3.2 0.6
3.2 0.7
3.1 0.6
3.2 0.6
3.1 0.6
3.2 0.6
3.0 0.6
3.1 0.6
3.2 0.6
3.2 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
CO Uncer-
(ppm) tainty
0.0 5.3
0.0 5.3
6.1 5.0
0.0 5.0
0.0 5.1
0.0 5.3
0.0 5.1
0.0 5.2
0.0 5.4
0.0 5.3
0.0 5.3
6.1 5.0
5.9 4.9
0.0 5.0
0.0 5.1
0.0 5.1
0.0 5.1
0.0 5.2
0.0 5.4
0.0 5.1
0.0 4.9
0.0 5.2
0.0 5.5
0.0 5.2
5.7 5.0
0.0 5.1
0.0 5.2
0.0 4.9
0.0 5.1
0.0 5.1
0.0 5.2
3 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time
17240169 7/24/98 12:21
17240170 7/24/98 12:23
17240171 7/24/98 12:25
17240172 7/24/98 12:26
17240173 7/24/98 12:28
17240174 7/24/98 12:30
17240175 7/24/98 12:32
17240176 7/24/98 12:33
17240177 7/24/98 12:35
17240178 7/24/98 12:37
17240179 7/24/98 12:39
17240180 7/24/98 12:41
17240181 7/24/98 12:42
17240182 7/24/98 12:44
17240183 7/24/98 12:46
17240184 7/24/98 12:48
17240185 7/24/98 12:49
17240186 7/24/98 12:51
17240187 7/24/98 12:53
17240188 7/24/98 12:55
Toluene
0.0 6.2
0.0 5.9
0.0 6.3
0.0 6.0
0.0 5.7
0.0 5.9
0.0 6.0
0.0 5.8
0.0 6.9
0.0 6.9
0.0 7.0
0.0 6.7
0.0 6.3
0.0 6.1
0.0 6.2
0.0 6.0
0.0 5.9
0.0 6.1
0.0 6.1
0.0 6.3
0.0 6.0
Propane Uncer-
(ppm) tainty
0.0 1.2
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.3
0.0 1.3
0.0 1.3
0.0 1.3
0.0 1.2
0.0 1.1
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.1
Hexane Uncer-
(ppm) tainty
3.7 0.2
2.7 0.2
4.0 0.2
3.4 0.2
1.9 0.2
2.0 0.2
2.9 0.2
2.0 0.2
4.4 0.2
5.8 0.2
6.5 0.2
6.3 0.2
5.4 0.2
4.3 0.2
4.8 0.2
3.6 0.2
3.5 0.2
3.7 0.2
3.5 0.2
4.2 0.2
3.2 0.2
Ethylene Uncer-
(ppm) tainty
0.7 0.4
0.7 0.4
0.0 0.4
0.7 0.4
0.7 0.4
0.6 0.4
0.6 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.0 0.4
0.0 0.4
0.7 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.7 0.4
0.1 0.4
Methane Uncer-
(ppm) tainty
3.2 0.6
3.1 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.3 0.7
3.4 O./
3.4 0.7
3.4 0.7
3.3 0.6
3.2 0.6
3.3 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.4 0.6
3.2 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 1.0
0.0 1.0
0.0 1.0
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
CO Uncer-
(ppm) tainty
0.0 5.2
0.0 5.0
0.0 5.3
0.0 5.1
0.0 4.9
0.0 5.0
0.0 5.1
0.0 5.0
8.0 5.3
6.7 5.3
0.0 5.7
0.0 5.5
0.0 5.2
5.4 4.8
6.6 4.9
6.7 4.7
8.5 4.7
7.6 4.8
5.5 4.8
5.4 4.9
2.3 5.0
4 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17250001 7/25/98 10:12 7:12
17250002 7/25/98 10:13 7:13
17250003 7/25/98 10:15 7:15
17250004 7/25/98 10:17 7:17
17250005 7/25/98 10:19 7:19
17250006 7/25/98 10:20 7:20
17250007 7/25/98 10:22 7:22
17250008 7/25/98 10:24 7:24
17250009 7/25/98 10:26 7:26
17250010 7/25/98 10:27 7:27
17250011 7/25/98 10:29 7:29
17250012 7/25/98 10:31 7:31
17250013 7/25/98 10:33 7:33
17250014 7/25/98 10:35 7:35
17250015 7/25/98 10:36 7:36
17250016 7/25/98 10:38 7:38
17250017 7/25/98 10:40 7:40
17250018 7/25/98 10:42 7:42
17250019 7/25/98 10:43 7:43
17250020 7/25/98 10:45 7:45
17250021 7/25/98 10:47 7:47
17250022 7/25/98 10:49 7:49
17250023 7/25/98 10:50 7:50
17250024 7/25/98 10:52 7:52
17250025 7/25/98 10:54 7:54
17250026 7/25/98 10:56 7:56
17250027 7/25/98 10:57 7:57
17250028 7/25/98 10:59 7:59
17250029 7/25/98 11:01 8:01
17250030 7/25/98 11:03 8:03
17250031 7/25/98 11:05 8:05
17250032 7/25/98 11:06 8:06
17250033 7/25/98 11:08 8:08
Toluene
0.0 3.4
0.0 3.9
0.0 3.9
0.0 3.8
0.0 3.9
0.0 4.0
0.0 4.4
0.0 4.4
0.0 4.3
0.0 4.3
0.0 4.1
0.0 4.4
0.0 4.5
0.0 4.3
0.0 4.4
0.0 4.3
0.0 4.4
0.0 4.5
0.0 4.6
0.0 4.6
0.0 4.8
0.0 4.7
0.0 4.5
0.0 4.5
0.0 4.6
0.0 4.4
0.0 4.6
0.0 4.8
0.0 4.8
0.0 4.5
0.0 4.4
0.0 4.7
0.0 4.9
Propane Uncer-
(ppm) tainty
0.0 0.6
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
Hexane Uncer-
(ppm) tainty
1.4 0.1
1.9 0.1
1.6 0.1
1.0 0.1
0.7 0.1
1.4 0.1
2.5 0.1
2.2 0.1
2.0 0.1
2.1 0.1
1.5 0.1
2.0 0.1
2.5 0.1
2.2 0.1
2.6 0.1
2.1 0.1
1.9 0.1
2.1 0.1
2.8 0.2
2.8 0.2
3.3 0.2
3.4 0.2
2.8 0.1
2.3 0.1
2.5 0.1
2.0 0.1
2.6 0.2
3.1 0.2
3.3 0.2
2.2 0.1
1.6 0.1
2.2 0.2
2.8 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.2
0.0 0.2
0.0 0.2
0.0 0.2
0.0 0.2
0.0 0.2
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
2.6 0.4
3.1 0.4
3.0 0.4
2.8 0.4
2.9 0.4
3.0 0.4
3.2 0.5
3.1 0.5
3.2 0.5
3.2 0.5
3.0 0.5
3.1 0.5
3.3 0.5
3.1 0.5
3.4 0.5
3.1 0.5
3.0 0.5
3.1 0.5
3.4 0.5
3.2 0.5
3.2 0.5
3.4 0.5
3.2 0.5
3.1 0.5
3.1 0.5
3.1 0.5
3.3 0.5
3.4 0.5
3.2 0.5
3.1 0.5
3.0 0.5
3.1 0.5
3.2 0.5
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.5
0.0 0.6
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.6
0.0 0.6
0.0 0.7
0.0 0.7
CO Uncer-
(ppm) tainty
8.5 2.9
11.7 3.2
11.9 3.1
8.3 3.1
6.0 3.1
8.1 3.2
10.0 3.4
10.6 3.4
10.7 3.3
8.6 3.3
6.2 3.3
7.9 3.4
11.5 3.4
7.7 3.3
9.4 3.4
9.0 3.4
8.8 3.4
7.9 3.5
10.7 3.6
9.3 3.6
9.7 3.6
11.0 3.6
8.0 3.5
8.0 3.5
8.2 3.5
7.8 3.5
9.1 3.6
10.6 3.7
9.3 3.7
6.5 3.5
6.0 3.5
8.8 3.6
10.8 3.7
1 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17250033 7/25/98 11:08 8:08
17250034 7/25/98 11:10 8:10
17250035 7/25/98 11:12 8:12
17250036 7/25/98 11:13 8:13
17250037 7/25/98 11:15 8:15
17250038 7/25/98 11:17 8:17
17250039 7/25/98 11:19 8:19
17250040 7/25/98 11:20 8:20
17250041 7/25/98 11:22 8:22
17250042 7/25/98 11:24 8:24
17250043 7/25/98 11:26 8:26
17250044 7/25/98 11:28 8:28
17250045 7/25/98 11:29 8:29
17250046 7/25/98 11:31 8:31
17250047 7/25/98 11:33 8:33
17250048 7/25/98 11:35 8:35
17250049 7/25/98 11:36 8:36
17250050 7/25/98 11:38 8:38
17250051 7/25/98 11:40 8:40
17250076 7/25/98 12:24 9:24
17250077 7/25/98 12:29 9:29
17250078 7/25/98 12:31 9:31
17250079 7/25/98 12:33 9:33
17250080 7/25/98 12:35 9:35
17250081 7/25/98 12:36 9:36
17250082 7/25/98 12:38 9:38
17250083 7/25/98 12:40 9:40
17250084 7/25/98 12:42 9:42
17250085 7/25/98 12:43 9:43
17250086 7/25/98 12:45 9:45
17250087 7/25/98 12:47 9:47
17250088 7/25/98 12:49 9:49
17250089 7/25/98 12:51 9:51
Toluene
0.0 4.9
0.0 4.7
0.0 5.0
0.0 4.6
0.0 4.7
0.0 4.7
0.0 5.0
3.2 1.3
0.0 5.1
0.0 5.3
0.0 5.2
0.0 4.9
0.0 5.1
0.0 5.2
0.0 5.0
0.0 5.3
0.0 5.7
0.0 5.2
0.0 5.1
0.0 144.4
9.6 2.6
5.5 1.9
0.0 6.5
0.0 5.8
0.0 5.6
0.0 5.3
0.0 5.1
0.0 5.2
0.0 5.1
0.0 5.1
0.0 5.2
0.0 5.2
0.0 5.4
Propane Uncer-
(ppm) tainty
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 1.0
0.0 1.0
0.0 0.9
0.0 1.0
0.0 1.0
0.0 0.9
0.0 1.0
0.0 1.1
0.0 1.0
0.0 1.0
0.0 27.0
0.0 2.0
0.0 .4
0.0 .2
0.0 .1
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
Hexane Uncer-
(ppm) tainty
2.8 0.2
2.5 0.2
2.9 0.2
2.4 0.2
2.2 0.2
2.4 0.2
3.2 0.2
5.7 0.2
5.5 0.2
4.6 0.2
3.7 0.2
3.1 0.2
3.1 0.2
3.3 0.2
3.1 0.2
3.5 0.2
4.3 0.2
3.2 0.2
3.3 0.2
211.9 4.7
14.0 0.3
8.1 0.2
6.2 0.2
4.9 0.2
4.5 0.2
3.8 0.2
3.0 0.2
3.0 0.2
2.9 0.2
2.5 0.2
3.0 0.2
2.7 0.2
3.3 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 6.7
0.7 0.5
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
3.2 0.5
3.0 0.5
3.1 0.5
3.0 0.5
3.1 0.5
3.1 0.5
3.1 0.5
3.1 0.6
3.3 0.6
3.3 0.6
3.1 0.6
3.0 0.5
3.1 0.5
3.1 0.6
3.1 0.5
3.1 0.6
3.1 0.6
3.2 0.6
3.3 0.5
0.0 15.2
3.8 1.1
3.3 0.8
3.3 0.7
3.2 0.6
3.2 0.6
3.2 0.6
3.1 0.5
3.2 0.6
3.1 0.5
3.1 0.5
3.0 0.6
3.1 0.5
3.2 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 20.4
4.4 1.5
0.0 1.1
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
CO Uncer-
(ppra) tainty
10.8 3.7
7.9 3.6
7.6 3.8
7.1 3.6
10.1 3.7
12.6 3.7
13.7 3.9
9.9 3.9
11.9 3.9
12.3 4.0
8.7 4.0
6.1 3.8
6.8 3.9
7.3 3.9
6.8 3.8
7.1 4.0
9.3 4.2
11.4 4.0
10.0 3.9
0.0 109.1
7.1 6.9
5.3 5.1
9.0 4.7
6.6 4.3
7.3 4.2
7.1 4.0
7.0 3.9
7.4 4.0
6.5 4.0
7.0 4.0
7.7 4.0
6.9 4.0
7.7 4.1
2 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17250090 7/25/98 12:52 9:52
17250091 7/25/98 12:54 9:54
17250092 7/25/98 12:56 9:56
17250093 7/25/98 12:58 9:58
17250094 7/25/98 12:59 9:59
17250095 7/25/98 13:01 10:01
17250096 7/25/98 13:03 10:03
17250097 7/25/98 13:05 10:05
17250098 7/25/98 13:07 10:07
17250099 7/25/98 13:08 10:08
17250100 7/25/98 13:10 10:10
17250101 7/25/98 13:12 10:12
17250102 7/25/98 13:14 10:14
17250103 7/25/98 13:15 10:15
17250104 7/25/98 13:17 10:17
17250105 7/25/98 13:19 10:19
17250106 7/25/98 13:21 10:21
17250107 7/25/98 13:23 10:23
17250108 7/25/98 13:24 10:24
17250109 7/25/98 13:26 10:26
17250110 7/25/98 13:28 10:28
17250111 7/25/98 13:29 10:29
17250112 7/25/98 13:31 10:31
17250113 7/25/98 13:33 10:33
17250114 7/25/98 13:35 10:35
17250115 7/25/98 13:36 10:36
17250116 7/25/98 13:38 10:38
17250117 7/25/98 13:40 10:40
17250118 7/25/98 13:42 10:42
17250119 7/25/98 13:44 10:44
17250120 7/25/98 13:45 10:45
17250121 7/25/98 13:47 10:47
17250122 7/25/98 13:49 10:49
17250123 7/25/98 13:51 10:51
Toluene
0.0 5.1
0.0 5.0
0.0 5.4
0.0 5.6
0.0 5.5
0.0 5.4
0.0 5.3
0.0 5.4
0.0 5.4
0.0 5.2
0.0 5.0
0.0 5.3
0.0 5.1
0.0 5.3
0.0 5.3
0.0 5.1
0.0 5.0
0.0 5.0
0.0 4.9
0.0 4.9
0.0 5.1
0.0 5.4
0.0 5.4
0.0 5.6
0.0 5.3
0.0 5.3
0.0 5.2
0.0 5.0
0.0 5.1
0.0 5.2
0.0 5.3
0.0 5.2
0.0 5.2
0.0 5.5
Propane Uncer-
(ppm) tainty
0.0 1.0
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 0.9
0.0 1.0
0.0 0.9
0.0 1.0
0.0 1.0
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
Hexane Uncer-
(ppm) tainty
2.8 0.2
2.1 0.2
2.6 0.2
3.2 0.2
3.5 0.2
3.7 0.2
3.1 0.2
3.4 0.2
3.0 0.2
2.9 0.2
2.2 0.2
2.4 0.2
2.2 0.2
2.3 0.2
2.8 0.2
2.6 0.2
2.2 0.2
1.9 0.2
1.7 0.2
1.6 0.2
1.8 0.2
2.7 0.2
3.3 0.2
4.2 0.2
3.7 0.2
3.3 0.2
3.3 0.2
2.5 0.2
2.6 0.2
3.3 0.2
3.7 0.2
3.0 0.2
2.7 0.2
2.8 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
• 0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
3.1 0.5
3.0 0.5
3. 0.6
3. 0.6
3. 0.6
3. 0.6
3. 0.6
3. 0.6
3.1 0.6
3.0 0.6
3.0 0.5
3.0 0.6
2.9 0.5
3.0 0.6
3.0 0.6
3.0 0.5
3.0 0.5
3.0 0.5
2.9 0.5
2.9 0.5
3.0 0.5
3.1 0.6
3.2 0.6
3.4 0.6
3.3 0.6
3.2 0.6
3.1 0.6
3.0 0.5
3.1 0.5
3.3 0.6
3.3 0.6
3.1 0.5
3.1 0.5
3.2 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
CO Uncer-
(ppm) tainty
6.6 4.0
6.9 3.9
8.2 4.1
8.8 4.2
8.1 4.2
7.1 4.1
6.7 4.1
6.6 4.1
6.8 4.1
5.7 4.0
0.0 4.0
6.2 4.1
8.1 3.9
9.1 4,1
8.8 41
7.2 4.0
6.1 3.9
5.8 3.9
5.7 3.9
5.6 3.9
6.5 3.9
9.1 4.2
16.0 4.1
16.9 4.2
10.1 4.1
10.3 4.1
9.2 4.1
6.5 4.0
10.9 4.0
12.1 4.1
10.9 4.1
8.2 4.0
7.3 4.1
7.8 4.2
3 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17250124 7/25/98 13:52 10:52
17250125 7/25/98 13:54 10:54
17250126 7/25/98 13:56 10:56
17250127 7/25/98 13:58 10:58
17250128 7/25/98 14:00 11:00
17250129 7/25/98 14:01 11:01
17250130 7/25/98 14:03 11:03
17250131 7/25/98 14:05 11:05
17250132 7/25/98 14:07 11:07
17250133 7/25/98 14:08 11:08
17250134 7/25/98 14:10 11:10
Average — >
Toluene
0.0 5.3
0.0 5.4
0.0 5.4
0.0 5.3
0.0 5.1
0.0 5.5
0.0 5.3
0.0 5.2
0.0 5.3
0.0 5.1
0.0 5.2
0.0 4.9
Propane Uncer-
(ppm) tainty
0.0 1.0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 0.9
Hexane Uncer-
(ppm) tainty
2.8 0.2
2.8 0.2
2.7 0.2
2.9 0.2
2.2 0.2
2.6 0.2
2.6 0.2
2.2 0.2
2.4 0.2
1.9 0.2
1.6 0.2
2.8 0.2
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
3.1 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.0 0.5
3.1 0.6
3.0 0.6
3.0 0.6
3.0 0.6
3.0 0.5
2.9 0.5
3.1 0.5
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
CO Uncer-
(ppm) tainty
6.7 4.1
6.4 4.1
7.1 4.2
5.9 4.1
5.3 4.0
7.5 4.2
6.1 4.1
5.5 4.1
5.9 4.1
0.0 4.2
0.0 4.2
8.2 3.8
4 of 4 loadout
-------
Table - . Tunnel Emissions Duct
17260001 7/26/98 12:23 9:23
17260002 7/26/98 12:25 9:25
17260003 7/26/98 12:27 9:27
17260004 7/26/98 12:29 9:29
17260005 7/26/98 12:30 9:30
17260006 7/26/98 12:32 9:32
17260007 7/26/98 12:34 9:34
17260008 7/26/98 12:36 9:36
17260009 7/26/98 12:38 9:38
17260010 7/26/98 12:39 9:39
17260011 7/26/98 12:41 9:41
17260012 7/26/98 12:43 9:43
17260013 7/26/98 12:45 9:45
17260014 7/26/98 12:46 9:46
17260015 7/26/98 12:48 9:48
17260016 7/26/98 12:50 9:50
17260017 7/26/98 12:52 9:52
17260018 7/26/98 12:53 9:53
17260019 7/26/98 12:55 9:55
17260020 7/26/98 12:57 9:57
17260021 7/26/98 12:59 9:59
17260022 7/26/98 13:01 10:01
17260023 7/26/98 13:02 10:02
17260024 7/26/98 13:04 10:04
17260025 7/26/98 13:06 10:06
17260026 7/26/98 13:08 10:08
17260027 7/26/98 13:09 10:09
17260028 7/26/98 13:11 10:11
17260029 7/26/98 13:13 10:13
17260030 7/26/98 13:15 10:15
17260031 7/26/98 13:16 10:16
17260032 7/26/98 13:18 10:18
17260033 7/26/98 13:20 10:20
17260034 7/26/98 13:22 10:22
17260035 7/26/98 13:24 10:24
Toluene
0.0 5.2
0.0 5.8
0.0 6.1
0.0 6.2
0.0 6.3
0.0 6.3
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.6
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.5
0.0 6.4
0.0 6.5
0.0 6.5
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
Propane Uncer-
(ppm) tainty
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 1.2
0.0 1.2
Hexane Uncer-
(ppm) tainty
0.0 0.5
0.0 0.5
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
2.7 0.5
3.0 0.6
3. 0.6
3. 0.6
3. 0.6
3. 0.6
3. 0.7
3. 0.7
3. 0.7
3. 0.7
3. 0.7
3. 0.7
3. 0.7
3.2 0.7
3.1 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
CO Uncer-
(ppm) tainty
0.0 4.3
0.0 4.7
0.0 4.8
0.0 4.9
0.0 4.9
0.0 4.9
0.0 5.0
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 5.0
0.0 5.0
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 5.0
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.9
0.0 4.8
0.0 4.8
0.0 4.8
0.0 4.8
5.4 4.6
0.0 4.8
0.0 4.7
0.0 4.7
0.0 4.7
0.0 4.7
1 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17260035 7/26/98 13:24 10:24
17260036 7/26/98 13:25 10:25
17260037 7/26/98 13:27 10:27
17260038 7/26/98 13:29 10:29
17260039 7/26/98 13:31 10:31
17260040 7/26/98 13:32 10:32
17260041 7/26/98 13:34 10:34
17260042 7/26/98 13:36 10:36
17260043 7/26/98 13:38 10:38
17260044 7/26/98 13:40 10:40
17260045 7/26/98 13:41 10:41
17260046 7/26/98 13:43 10:43
17260047 7/26/98 13:45 10:45
17260048 7/26/98 13:47 10:47
17260049 7/26/98 13:48 10:48
17260050 7/26/98 13:50 10:50
17260051 7/26/98 13:52 10:52
17260052 7/26/98 13:54 10:54
17260053 7/26/98 13:56 10:56
17260054 7/26/98 13:57 10:57
17260055 7/26/98 13:59 10:59
17260056 7/26/98 14:01 11:01
17260057 7/26/98 14:03 11:03
17260058 7/26/98 14:04 11:04
17260059 7/26/98 14:06 11:06
17260060 7/26/98 14:08 11:08
17260061 7/26/98 14:10 11:10
17260062 7/26/98 14:11 11:11
17260063 7/26/98 14:13 11:13
17260064 7/26/98 14:15 11:15
17260065 7/26/98 14:17 11:17
17260066 7/26/98 14:19 11:19
17260067 7/26/98 14:20 11:20
17260068 7/26/98 14:22 11:22
17260069 7/26/98 14:24 11:24
Toluene
0.0 6.4
0.0 6.3
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.3
0.0 6.4
0.0 6.3
0.0 6.4
0.0 6.3
0.0 6.4
0.0 6.4
0.0 6.4
0.0 6.3
0.0 6.3
0.0 6.3
0.0 6.3
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.2
0.0 6.1
0.0 6.2
Propane Uncer-
(ppm) tainty
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
Hexane Uncer-
(ppm) tainty
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.2 0.7
3.3 0.7
3.2 0.7
3.2 0.7
3.2 0.6
3.2 0.6
3.1 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.1 0.6
3.2 0.6
3.2 0.6
3.1 0.6
3.1 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
CO Uncer-
(ppm) tainty
0.0 4.7
0.0 4.7
0.0 4.7
0.0 4.7
0.0 4.7
5.4 4.5
5.6 4.5
0.0 4.7
5.3 4.5
6.1 4.5
5.4 4.5
0.0 4.7
0.0 4.6
0.0 4.6
5.4 4.4
7.6 4.4
7.6 4.4
6.6 4.5
7.2 4.4
6.6 4.5
6.6 4.4
6.4 4.4
5.8 4.4
5.7 4.4
5.4 4.3
5.1 4.3
0.0 4.5
0.0 4.5
0.0 4.4
0.0 4.4
5.4 4.3
6.6 4.3
5.5 4.3
5.7 4.3
5.6 4.3
2 of 4 loadout
-------
Table - . Tunnel Emissions Duct
17260070 7/26/98 14:26 11:26
17260071 7/26/98 14:49 11:49
17260072 7/26/98 14:50 11:50
17260073 7/26/98 14:52 11:52
17260074 7/26/98 14:54 11:54
17260075 7/26/98 14:56 11:56
17260076 7/26/98 14:57 11:57
17260077 7/26/98 14:59 11:59
17260078 7/26/98 15:01 12:01
17260079 7/26/98 15:03 12:03
17260080 7/26/98 15:05 12:05
17260081 7/26/98 15:06 12:06
17260082 7/26/98 15:08 12:08
17260083 7/26/98 15:10 12:10
17260084 7/26/98 15:12 12:12
17260085 7/26/98 15:13 12:13
17260086 7/26/98 15:15 12:15
17260087 7/26/98 15:17 12:17
17260088 7/26/98 15:19 12:19
17260089 7/26/98 15:20 12:20
17260090 7/26/98 15:22 12:22
17260091 7/26/98 15:24 12:24
17260092 7/26/98 15:26 12:26
17260093 7/26/98 15:28 12:28
17260094 7/26/98 15:29 12:29
17260095 7/26/98 15:31 12:31
17260096 7/26/98 15:33 12:33
17260097 7/26/98 15:35 12:35
17260098 7/26/98 15:36 12:36
17260099 7/26/98 15:38 12:38
17260100 7/26/98 15:40 12:40
17260101 7/26/98 15:42 12:42
17260102 7/26/98 15:43 12:43
17260103 7/26/98 15:45 12:45
Toluene
0.0 6.2
0.0 4.9
0.0 5.4
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.6
0.0 5.6
0.0 5.6
0.0 5.6
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.4
0.0 5.4
0.0 5.4
0.0 5.4
0.0 5.4
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.2
0.0 5.2
0.0 5.3
0.0 5.3
Propane Uncer-
(ppm) tainty
0.0 1.2
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.1
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
Hexane Uncer-
(ppm) tainty
0.0 0.6
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
3.1 0.6
2.8 0.5
3.0 0.6
3.0 0.6
3.0 06
3.0 0.6
2.9 0.6
2.9 0.6
2.9 0.6
2.9 0.6
2.9 0.6
3.0 0.6
2.9 0.6
2.9 0.6
2.9 0.6
2.9 0.6
3.0 0.6
2.9 0.6
2.9 0.6
3.0 0.6
2.9 0.6
2.9 0.6
2.9 0.6
3.0 0.6
3.0 0.6
2.9 0.6
3.0 0.6
2.9 0.6
2.9 0.6
2.9 0.6
2.9 0.5
2.9 0.6
2.9 0.6
2.9 0.6
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
CO Uncer-
(ppm) tainty
4.9 3.7
5.1 3.9
5.1 4.0
4.9 4.0
4.8 4.0
5.2 4.0
5.2 4.0
5.6 4.0
5.7 4.0
5.7 4.0
5.5 4.0
5.1 4.0
5.4 4.0
5.8 4.0
5.8 4.0
5.5 4.0
5.2 3.9
5.5 3.9
7.0 4.0
6.3 4.0
5.4 3.9
5.0 3.9
5.3 3.9
6.0 3.9
7.2 3.9
6.5 3.9
5.8 3.9
5.5 3.9
5.5 3.9
5.4 3.8
5.7 3.9
5.7 3.9
5.1 3.9
3 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17260104 7/26/98 15:47 12:47
17260105 7/26/98 15:49 12:49
17260106 7/26/98 15:50 12:50
17260107 7/26/98 15:52 12:52
17260108 7/26/98 15:54 12:54
17260109 7/26/98 15:56 12:56
17260110 7/26/98 15:57 12:57
17260111 7/26/98 15:59 12:59
17260112 7/26/98 16:01 13:01
17260113 7/26/98 16:03 13:03
17260114 7/26/98 16:05 13:05
17260115 7/26/98 16:06 13:06
17260116 7/26/98 16:08 13:08
17260117 7/26/98 16:10 13:10
17260118 7/26/98 16:12 13:12
17260119 7/26/98 16:13 13:13
17260120 7/26/98 16:15 13:15
17260121 7/26/98 16:17 13:17
17260122 7/26/98 16:19 13:19
17260123 7/26/98 16:21 13:21
17260124 7/26/98 16:22 13:22
17260125 7/26/98 16:24 13:24
17260126 7/26/98 16:26 13:26
17260127 7/26/98 16:28 13:28
17260128 7/26/98 16:29 13:29
17260129 7/26/98 16:31 13:31
17260130 7/26/98 16:33 13:33
17260131 7/26/98 16:35 13:35
17260132 7/26/98 16:37 13:37
17260133 7/26/98 16:38 13:38
17260134 7/26/98 16:40 13:40
17260135 7/26/98 16:42 13:42
17260136 7/26/98 16:44 13:44
Average — >
Toluene
0.0 5.2
0.0 5.2
0.0 5.0
0.0 5.0
0.0 5.1
0.0 5.1
0.0 5.1
0.0 5.1
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.3
0.0 5.4
0.0 5.4
0.0 5.4
0.0 5.3
0.0 5.4
0.0 5.3
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.2
0.0 5.8
Propane Uncer-
(ppm) tainty
0.0 1.0
0.0 1.0
0.0 0.9
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 .0
0.0 1.0
0.0 1.1
Hexane Uncer-
(ppm) tainty
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5 -
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
0.0 0.5
Ethylene Uncer-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
2.9 0.5
3.0 0.5
2.9 0.5
2.8 0.5
2.9 0.5
2.9 0.5
2.9 0.5
2.9 0.5
2.9 0.5
2.9 0.5
2.9 0.5
2.9 0.6
2.9 0.6
2.9 0.6
2.8 0.6
2.8 0.6
2.9 0.6
2.8 0.6
2.8 0.6
2.8 0*
2.8 0.6
2.9 0.6
2.8 0.6
2.8 0.6
2.8 0.6
2.9 0.6
2.9 0.6
2.8 0.6
2.8 0.6
2.7 0.5
2.8 0.5
2.8 0.6
2.8 0.6
3.0 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
CO Uncer-
(ppm) tainty
6.0 3.9
6.0 3.9
5.3 3.8
5.1 3.7
5.1 3.8
5.1 3.8
5.1 3.8
5.4 3.8
5.6 3.8
5.4 3.9
5.4 3.8
5.1 3.9
5.2 3.9
5.9 3.9
5.4 3.9
5.3 3.9
5.3 3.9
5.3 3.9
4.9 3.9
5.3 3.9
4.8 3.9
4.7 3.9
0.0 4.0
0.0 4.0
4.7 3.9
0.0 4.0
4.9 3.9
4.6 3.8
0.0 3.9
0.0 3.9
0.0 3.9
5.3 3.8
4.6 3.8
3.5 4.3
4 of 4 loadout
-------
Table - . Tunnel Emissions Duct
17270001 7/27/98 10:06 7:06
17270002 7/27/98 10:08 7:08
17270003 7/27/98 10:09 7:09
17270004 7/27/98 10:11 7:11
17270005 7/27/98 10:13 7:13
17270006 7/27/98 10:15 7:15
17270007 7/27/98 10:17 7:17
17270008 7/27/98 10:18 7:18
17270009 7/27/98 10:20 7:20
17270010 7/27/98 10:22 7:22
17270011 7/27/98 10:24 7:24
17270012 7/27/98 10:25 7:25
17270013 7/27/98 10:27 7:27
17270014 7/27/98 10:29 7:29
17270015 7/27/98 10:31 7:31
17270016 7/27/98 10:33 7:33
17270017 7/27/98 10:34 7:34
17270018 7/27/98 10:36 7:36
17270019 7/27/98 10:38 7:38
17270020 7/27/98 10:40 7:40
17270021 7/27/98 10:41 7:41
17270022 7/27/98 10:43 7:43
17270023 7/27/98 10:45 7:45
17270024 7/27/98 10:47 7:47
17270025 7/27/98 10:49 7:49
17270026 7/27/98 10:50 7:50
17270027 7/27/98 10:52 7:52
17270028 7/27/98 10:54 7:54
17270029 7/27/98 10:56 7:56
17270030 7/27/98 10:57 7:57
17270031 7/27/98 10:59 7:59
17270032 7/27/98 11:01 8:01
17270033 7/27/98 11:03 8:03
17270034 7/27/98 11:05 8:05
17270035 7/27/98 11:06 8:06
17270036 7/27/98 11:08 8:08
17270037 7/27/98 11:10 8:10
Toluene
0.0 3.7
0.0 4.2
0.0 4.3
0.0 4.5
0.0 4.6
0.0 4.3
0.0 4.1
0.0 4.0
0.0 4.3
0.0 4.2
0.0 4.1
0.0 4.0
0.0 4.0
0.0 4.0
0.0 4.1
0.0 4.1
0.0 4.1
0.0 4.1
0.0 4.5
0.0 4.7
0.0 4.8
0.0 4.4
0.0 4.5
0.0 4.6
0.0 4.8
0.0 4.6
0.0 4.4
0.0 4.4
0.0 4.7
0.0 4.9
0.0 4.7
0.0 4.7
0.0 5.2
0.0 5.3
0.0 5.2
0.0 4.8
0.0 4.7
Propane Uncer-
(ppm) tainty
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0,8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 0.9
0.0 0.9
Hexane Uncer-
(ppm) tainty
1.9 0.1
2.5 0.1
2.5 0.
2.6 0.
2.8 0.
2.3 0.
1.4 0.
1.0 0.
1.2 0.
1.3 0.
0.8 0.
0.5 0.
0.4 0.1
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.7 0.1
1.5 0.1
2.2 0.2
1.4 0.1
1.3 0.1
1.8 0.1
2.3 0.2
2.0 0.1
1.4 0.1
1.3 0.1
2.0 0.1
2.6 0.2
2.0 0.1
1.5 0.1
2.2 0.2
2.4 0.2
2.5 0.2
1.6 0.2
1.1 0.1
Ethylene Uncer-
(ppm) tainty
0.0 0.2
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.2
0.0 0.2
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0,0 0.3
0.0 0.3
Methane Uncer-
(ppm) tainty
2.8 0.4
3.1 0.4
3.2 0.5
3.2 0.5
3.1 0.5
3.1 0.5
3.0 0.4
3.0 0.4
3.0 0.5
3.1 0.4
3.0 0.4
3.0 0.4
3.0 0.4
3.0 0.4
3.0 0.4
3.0 0.4
2.9 0.4
2.9 0.4
3.0 0.5
3.0 0.5
3.1 0.5
3.0 0.5
3.1 0.5
3.1 0.5
3.2 0.5
3.1 0.5
3.0 0.5
3.0 0.5
3.1 0.5
3.2 0.5
3.1 0.5
3.1 0.5
3.2 0.5
3.3 0.6
3.3 0.5
3.2 0.5
3.2 0.5
dehyde Uncer-
(ppm) tainty
0.0 0.5
0.0 0.6
1.6 0.6
1.6 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.7
0.0 0.7
0.0 0.6
0,0 0.6
0.0 0.7
0.0 0.7
0.0 0.6
0.0 0.6
0.0 0.6
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
CO Uncer-
(ppm) tainty
7.9 3.0
10.1 3.2
11.3 3.3
9.8 3.4
7.6 3.4
6.9 3.3
6.7 3.2
6.6 3.2
7.5 3.3
6.4 3.3
4.4 3.2
0.0 3.3
0.0 3.3
0.0 3.3
0.0 3.4
6.0 3.3
5.4 3.3
6.8 3.3
8.1 3.5
8.9 3.6
9.2 3.6
6.1 3.4
8.5 3.5
10.0 3.6
9.8 3.7
8.5 3.6
11.7 3.5
13.0 3.6
9.8 3.7
8.1 3.8
6.1 3.7
6.9 3.7
6.7 3.9
6.2 4.0
5.5 3.9
0.0 3.9
0.0 3.9
1 of 4 loadout
-------
Table - . Tunnel Emissions Duct
17270037 7/27/98 11:10 8:10
17270038 7/27/98 11:12 8:12
17270039 7/27/98 11:13 8:13
17270040 7/27/98 11:15 8:15
17270041 7/27/98 11:17 8:17
17270042 7/27/98 11:19 8:19
17270043 7/27/98 11:21 8:21
17270044 7/27/98 11:22 8:22
17270045 7/27/98 11:24 8:24
17270046 7/27/98 11:26 8:26
17270047 7/27/98 11:28 8:28
17270048 7/27/98 11:29 8:29
17270049 7/27/98 11:31 8:31
17270050 7/27/98 11:33 8:33
17270051 7/27/98 11:35 8:35
17270052 7/27/98 11:37 8:37
17270053 7/27/98 11:38 8:38
17270054 7/27/98 11:40 8:40
17270055 7/27/98 11:42 8:42
17270056 7/27/98 11:44 8:44
17270057 7/27/98 11:45 8:45
17270058 7/27/98 11:47 8:47
17270059 7/27/98 11:49 8:49
17270060 7/27/98 11:51 8:51
17270061 7/27/98 11:53 8:53
17270062 7/27/98 11:54 8:54
17270063 7/27/98 11:56 8:56
17270064 7/27/98 11:58 8:58
17270065 7/27/98 12:00 9:00
17270066 7/27/98 12:01 9:01
17270067 7/27/98 12:03 9:03
17270068 7/27/98 12:05 9:05
17270069 7/27/98 12:07 9:07
17270070 7/27/98 12:09 9:09
17270071 7/27/98 12:10 9:10
17270072 7/27/98 12:12 9:12
17270073 7/27/98 12:14 9:14
Toluene
0.0 4.7
0.0 5.0
0.0 5.4
0.0 5.4
0.0 5.3
0.0 5.1
0.0 5.3
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.5
0.0 5.6
0.0 5.6
0.0 5.7
0.0 5.9
0.0 5.9
0.0 5.7
0.0 5.8
0.0 5.9
0.0 5.8
0.0 5.6
0.0 5.6
0.0 5.6
0.0 5.8
0.0 5.9
0.0 6.0
0.0 5.8
0.0 6.0
0.0 5.9
0.0 5.9
0.0 6.0
0.0 6.0
0.0 6.2
0.0 5.8
0.0 5.7
0.0 5.9
0.0 6.1
Propane Uncer-
(ppm) tainty
0.0 0.9
0.0 0.9
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.0
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 .1
0.0 .1
0.0 .1
0.0 .2
0.0 .1
0.0 .1
0.0 .1
0.0 .1
Hexane Uncer-
(ppm) tainty
1.1 0.1
2.3 0.2
3.3 0.2
3.4 0.2
3.3 0.2
3.0 0.2
3.3 0.2
3.8 0.2
3.7 0.2
4.0 0.2
3.7 0.2
3.4 0.2
3.6 0.2
4.4 0.2
4.9 0.2
4.5 0.2
4.4 0.2
4.0 0.2
4.7 0.2
5.0 0.2
4.7 0.2
3.8 0.2
3.0 0.2
3.1 0.2
3.4 0.2
3.4 0.2
2.9 0.2
3.4 0.2
3.2 0.2
3.4 0.2
3.5 0.2
3.6 0.2
4.2 0.2
4.8 0.2
3.6 0.2
3.2 0.2
3.5 0.2
Ethylene Unccr-
(ppm) tainty
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.3
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.4
Methane Uncer-
(ppm) tainty
3.2 0.5
3.3 0.5
3.4 0.6
3.5 0.6
3.5 0.5
3.5 0.5
3.6 0.5
3.7 0.6
3.7 0.6
3.8 0.6
3.8 0.6
3.9 0.6
4.0 0.6
4.1 0.6
4.1 0.6
4.2 0.6
4.1 0.6
4.1 0.6
3.9 0.6
3.6 0.6
3.7 0.6
3.4 0.6
3.3 0.6
3.3 0.6
3.3 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.1 0.6
3.1 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.7
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
CO Uncer-
(ppm) tainty
0.0 4.1
4.6 4.1
5.4 4.1
5.9 4.0
5.0 3.9
5.0 4.0
5.6 4.1
5.7 4.2
5.9 4.1
5.8 4.2
5.7 4.2
11.5 4.2
11.5 4.3
8.2 4.5
7.0 4.4
6.0 4.3
6.8 4.4
6.8 4.4
7.6 4.4
12.3 4.3
6.6 4.3
5.3 4.3
5.2 4.4
5.5 4.5
5.2 4.5
5.4 4.4
5.9 4.5
5.9 4.5
7.1 4.5
6.8 4.6
6.6 4.5
5.8 4.7
5.1 4.5
5.0 4.4
4.9 4.5
5.2 4.6
2 of 4 loadout
-------
File Name
7270074
17270075
17270076
17270077
17270078
17270079
17270080
17270081
17270082
17270083
17270089
17270090
17270091
17270092
17270093
17270094
17270095
17270096
17270097
17270098
17270099
17270100
17270101
17270102
17270103
17270104
17270105
17270106
17270107
17270108
17270109
17270110
17270111
17270112
17270113
17270114
^^=^==
Date
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
= .- .
Time
12:16
12:17
12:19
12:21
12:23
12:25
12:26
12:28
12:30
12:32
12:57
12:59
13:01
13:03
13:05
13:06
13:08
13:10
13:12
13:13
13:15
13:17
13:19
13:21
13:22
13:24
13:26
13:28
13:29
13:31
13:33
13:35
13:37
13:38
13:40
13:42
Time
9:16
9:17
9:19
9:21
9:23
9:25
9:26
9:28
9:30
9:32
9:57
9:59
10:01
10:03
10:05
10:06
10:08
10:10
10:12
10:13
10:15
10:17
10:19
10:21
10:22
10:24
10:26
10:28
10:29
10:31
10:33
10:35
10:37
10:38
10:40
10:42
Toluene
=^==^
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
1 1 1
6.0
6.0
6.0
5.7
5.6
5.8
5.6
5.7
5.9
5.8
5.2
5.6
6.0
5.9
6.1
6.2
6.3
6.3
6.3
6.2
6.0
6.1
6.1
5.7
5.8
6.1
5.9
6.0
6.4
6.5
6.2
6.4
6.4
6.8
6.4
6.1
Propane Uncer-
(ppm) tainty
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.0
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.1
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 0.7
0.0 1.2
0.0 1.1
Hexane Uncer-
(ppm) tainty
3.3 0.2
3.4 0.2
3.8 0.2
3.0 0.2
2.5 0.2
2.4 0.2
2.1 0.2
1.9 0.2
2.2 0.2
2.3 0.2
1.9 0.2
3.6 0.2
3.9 0.2
2.9 0.2
3.1 0.2
3.5 0.2
3.6 0.2
3.5 0.2
3.4 0.2
3.3 0.2
2.9 0.2
2.7 0.2
2.9 0.2
2.3 0.2
2.1 0.2
2.5 0.2
2.4 0.2
2.6 0.2
2.9 0.2
3.3 0.2
3.7 0.2
3.8 0.2
5.3 0.2
6.2 0.2
5.0 0.2
4.2 0.2
======
Ethylene Uncer-
(ppm) tainty
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.3
0.0 0.3
0.0 0.4
0.0 0.3
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.0 0.4
0.5 0.4
0.5 0.4
0.0 0.4
Methane Uncer-
(ppm) tainty
3.0 0.6
3.1 0.6
3.0 0.6
3.0 0.6
3.0 0.6
3.0 0.6
3.0 0.6
3.0 0.6
3.1 0.6
3.0 0.6
2.8 0.5
3.2 0.6
3.3 0.6
3.2 0.6
3.2 0.6
3.3 0.6
3.3 0.6
3.3 0.6
3.2 0.7
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.2 0.6
3.1 0.6
3.1 0.6
3.2 0.7
3.2 0.7
3.3 0.6
3.3 0.7
3.5 0.7
3.6 0.7
3.5 0.7
3.4 0.6
Formal-
dehyde Uncer-
(ppm) tainty
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.7
0.0 0.8
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.8
0.0 0.8
0.0 0.9
0.0 0.8
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 1.0
0.0 0.9
0.0 0.9
CO Uncer-
(ppm) tainty
5.4 4.6
5.0 4.6
5.5 4.6
4.9 4.5
4.8 4.4
4.9 4.5
5.4 4.4
5.7 4.4
5.8 4.5
5.6 4.5
5.6 4.2
7.6 4.4
5.7 4.6
5.2 4.6
6.4 4.7
7.1 4.8
6.6 4.8
5.8 4.8
5.5 4.8
5.5 4.8
5.4 4.6
6.8 4.7
6.0 4.7
0.0 4.7
0.0 4.8
5.2 4.7
5.3 4.6
5.5 4.7
5.3 4.8
6.3 4.9
10.2 4.8
12.1 4.9
13.8 4.9
10.4 5.1
8.4 4.9
6.8 4.7
3 of 4 loadout
-------
Table - . Tunnel Emissions Duct
File Name Date Time Time
17270115 7/27/98 14:15 11:15
17270116 7/27/98 14:17 11:17
17270117 7/27/98 14:19 11:19
17270118 7/27/98 14:21 11:21
17270119 7/27/98 14:22 11:22
17270120 7/27/98 14:24 11:24
17270121 7/27/98 14:26 11:26
17270122 7/27/98 14:28 11:28
17270123 7/27/98 14:29 11:29
17270124 7/27/98 14:31 11:31
17270125 7/27/98 14:33 11:33
17270126 7/27/98 14:35 11:35
17270127 7/27/98 14:37 11:37
17270128 7/27/98 14:38 11:38
17270129 7/27/98 14:40 11:40
17270130 7/27/98 14:42 11:42
17270131 7/27/98 14:44 11:44
17270132 7/27/98 14:45 11:45
17270133 7/27/98 14:47 11:47
17270134 7/27/98 14:49 11:49
17270135 7/27/98 14:51 11:51
17270136 7/27/98 14:52 11:52
17270137 7/27/98 14:54 11:54
17270138 7/27/98 14:56 11:56
17270139 7/27/98 14:58 11:58
17270140 7/27/98 15:00 12:00
SP0727B 7/27/98 17:13 14:13
Average — >
Toluene
24.3 4.8
10.7 2.5
0.0 7.3
0.0 6.7
0.0 6.5
0.0 6.7
0.0 6.4
0.0 6.3
0.0 6.2
0.0 6.1
0.0 6.2
0.0 6.5
0.0 6.6
0.0 6.6
0.0 6.6
0.0 6.4
0.0 6.4
0.0 6.5
0.0 6.3
0.0 6.2
0.0 6.4
0.0 6.4
0.0 6.5
0.0 6.3
0.0 6.4
0.0 6.5
151.0 2.0
0.0 5.6
Propane Uncer-
(ppm) tainty
0.0 2.4
0.0 1.3
0.0 1.4
0.0 1.3
0.0 1.2
0.0 .3
0.0 .2
0.0 .2
0.0 .2
0.0 .1
0.0 .2
0.0 .2
0.0 .2
0.0 1.2
0.0 1.2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 .2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 1.2
0.0 0.3
0.0 1.0
Hexane Uncer-
(ppm) tainty
37.7 0.6
14.7 0.3
7.8 0.2
6.1 0.2
5.1 0.2
5.1 0.2
4.8 0.2
4.2 0.2
3.7 0.2
3.6 0.2
3.3 0.2
3.9 0.2
4.8 0.2
6.4 0.3
5.9 0.2
5.0 0.2
4.6 0.2
4.5 0.2
4.3 0.2
3.7 0.2
3.8 0.2
4.0 0.2
4.3 0.2
4.1 0.2
4.2 0.2
4.7 0.2
0.0 0.2
3.1 0.2
Ethylene Uncer-
(ppm) tainty
1.2 0.9
0.8 0.5
0.7 0.4
0.7 0.4
0.7 0.4
0.6 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.8 0.4
0.8 0.4
0.8 0.4
0.8 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.7 0.4
0.8 0.4
0.7 0.4
0.7 0.4
0.8 0.4
0.8 0.4
0.7 0.4
0.8 0.4
1.9 1.7
0.1 0.3
Methane Unce---
(ppm) tainty
5.7 2.1
4.0 1.1
3.5 0.8
3.3 0.7
3.3 0.7
3.3 0.7
3.2 0.7
3.2 0.7
3.2 0.6
3.2 0.6
3.2 0.6
3.2 0.7
3.4 0.7
3.6 0.7
3.5 0.7
3.3 0.7
3.3 0.7
3.3 0.7
3.2 0.7
3.2 0.6
3.2 0.7
3.2 0.7
3.3 0.7
3.2 0.6
3.2 0.7
3.3 0.7
2.3 0.3
3.3 0.6
Formal-
dehyde Uncer-
(ppm) tainty
8.4 2.8
3.9 1.5
0.0 1.0
0.0 1.0
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
0.0 0.9
1.3 0.4
0.0 0.8
CO Uncer-
(ppm) tainty
0.0 12.8
9.4 7.3
6.7 5.3
7.6 5.0
6.5 4.9
6.5 5.0
6.2 4.8
6.1 4.7
5.8 4.7
6.0 4.6
6.1 4.6
7.6 4.8
16.5 4.9
17.7 5.0
11.6 4.9
9.4 4.8
8.0 4.8
7.2 4.8
6.4 4.8
5.8 4.7
6.2 4.8
6.9 4.8
11.0 4.9
8.8 4.7
7.8 4.8
7.9 4.8
3.1 0.2
6.7 4.3
4of41oadout
-------
Silo Emissions Duct
17240003 7/24/98 7:25
17240004 7/24/98 7:26
17240005 7/24/98 7:28
17240006 7/24/98 7:30
17240007 7/24/98 7:32
17240008 7/24/98 7:34
17240009 7/24/98 7:35
17240010 7/24/98 7:37
17240011 7/24/98 7:39
17240012 7/24/98 7:41
17240013 7/24/98 7:42
17240014 7/24/98 7:44
17240015 7/24/98 7:46
17240016 7/24/98 7:48
17240017 7/24/98 7:49
17240018 7/24/98 7:51
17240019 7/24/98 7:53
17240020 7/24/98 7:55
17240021 7/24/98 7:56
17240022 7/24/98 7:58
17240023 7/24/98 8:00
17240077 7/24/98 9:39
17240078 7/24/98 9:41
17240079 7/24/98 9:43
17240080 7/24/98 9:45
17240081 7/24/98 9:46
17240082 7/24/98 9:48
17240083 7/24/98 9:50
17240084 7/24/98 9:52
17240085 7/24/98 9:53
17240086 7/24/98 9:55
17240087 7/24/98 9:57
17240088 7/24/98 9:59
17240089 7/24/98 10:00
17240090 7/24/98 10:02
17240091 7/24/98 10:04
17240092 7/24/98 10:06
17240093 7/24/98 10:07
17240094 7/24/98 10:09
Toluene
53.6 10.6
86.8 17.1
108.9 21.7
126.8 25.7
167.9 37.2
182.6 41.0
191.9 44.2
200.9 46.6
176.8 45.5
192.0 52.9
201.5 58.0
234.9 59.0
236.2 59.6
174.6 36.9
163.4 34.2
206.8 48.8
179.1 45.3
210.9 49.9
224.0 53.2
216.6 51.5
216.9 51.3
109.9 23.3
108.5 23.5
102.9 22.2
101.8 21.9
100.8 21.5
102.0 21.8
105.5 22.2
106.7 22.4
105.4 22.5
103.2 22.2
102.8 22.0
103.7 21.9
104.4 22.0
102.8 21.7
101.8 21.5
100.8 21.5
101.3 21.5
98.7 21.0
Iso-
Octane
(ppm) Uncertainty
9.8 2.1
15.7 3.4
18.4 4.3
20.5 5.1
23.5 7.4
25.0 8.2
23.7 8.8
25.8 9.3
16.9 9.0
14.4 10.5
11.9 11.5
23.8 11.8
26.8 11.9
23.3 7.3
22.7 6.8
26.7 9.7
17.0 9.0
27.0 9.9
29.6 10.6
28.2 10.3
26.8 10.2
13.1 4.6
12.0 4.6
11.7 4.4
11.9 4.3
12.2 4.3
11.9 4.3
13.0 4.4
13.1 4.4
12.0 4.5
12.0 4.4
12.1 4.4
13.0 4.3
12.9 4.4
12.9 4.3
12.6 4.2
12.2 4.3
12.1 4.3
12.0 4.2
Hexane
(ppm) Uncertainty
104.0 2.9
165.2 4.7
205.3 6.0
238.3 7.1
258.7 10.3
276.7 11.3
284.5 12.2
294.3 12.9
331.9 12.6
356.0 14.6
371.0 16.0
314.8 16.3
313.8 16.4
302.1 10.2
288.4 9.4
284.5 13.5
330.6 12.5
289.2 13.8
293.4 14.7
290.2 14.2
292.9 14.1
204.4 6.4
201.5 6.5
191.4 6.1
187.5 6.1
186.7 5.9
188.5 6.0
194.9 6.1
197.2 6.2
194.7 6.2
191.0 6.1
192.7 6.1
192.4 6.1
193.4 6.1
191.4 6.0
188.2 5.9
187.8 5.9
189.2 5.9
183.3 5.8
Ethylene
(ppm) Uncertainty
1.4 0.7
2.2 0.9
2.7 1.2
3.1 1.4
3.7 1.6
3.9 1.7
4.1 1.9
4.3 2.0
4.4 2.1
4.6 2.2
4.6 2.3
4.7 2.4
4.7 2.4
4.6 2.4
4.4 2.3
4.3 2.2
4.3 2.2
4.3 2.3
4.5 2.4
4.3 2.4
4.2 2.4
3.5 1.9
3.6 .9
3.5 .9
3.5 .9
3.3 .9
3.4 .8
3.3 .8
3.3 .8
3.4 1.9
3.5 1.9
3.4 1.8
3.2 1.8
3.2 1.7
3.2 1.8
3.1 1.7
3.2 1.7
3.2 1.7
3.2 1.7
Methane
(ppm) ncertaint
10.3 4.5
15.6 7.2
18.6 9.2
21.3 10.9
31.5 15.9
33.9 17.5
34.9 18.8
36.0 19.9
14.6
18.0
20.2
14.6
14.8
10.0
23.6 14.5
36.2 20.8
14.6
35.8 21.3
10.7
36.8 21.9
37.3 21.9
18.4 9.9
18.0 9.9
17.0 9.4
16.8 9.3
16.8 9.1
16.9 9.2
17.4 9.4
17.2 9.5
17.2 9.5
17.1 9.4
17.5 9.3
17.4 9.3
17.5 9.3
17.3 9.2
17.0 9.1
16.7 9.1
16.8 9.1
16.4 8.9
hyde
(ppm) ncertaint
16.4 6.1
23.8 9.8
28.5 12.4
32.1 14.7
21.4
23.6
25.7
27.1
19.5
24.0
27.0
33.5
33.8
37.5 21.1
37.9 19.6
28.5
19.5
29.1
31.1
30.0
29.9
28.7 13.3
30.4 13.4
28.3 12.7
27.6 12.5
26.6 12.3
27.7 12.5
27.7 12.7
27.2 12.8
28.0 12.9
27.8 12.7
28.6 12.6
27.7 12.5
27.9 12.6
27.6 12.4
27.2 12.3
28.4 12.3
27.9 12.3
26.6 12.0
CO
(ppm) Uncertainty
61.3 10.6
115.4 65.0
97.7 18.6
104.1 22.0
108.0 25.6
107.9 28.2
104.0 31.8
104.4 34.0
105.6 37.0
107.3 39.2
106.1 42.7
96.6 48.2
95.7 49.2
89.5 47.9
88.3 44.7
95.7 41.3
100.7 40.4
95.6 42.7
96.9 49.1
97.7 46.4
97.9 46.4
76TI 3ll
73.4 31.0
67.9 30.7
67.0 30.5
67.6 29.9
69.8 29.2
72.9 28.6
70.8 29.2
68.4 30.1
70.0 30.5
75.8 29.7
77.1 28.5
77.1 27.7
75.4 28.0
73.4 27.4
73.7 26.5
73.2 27.2
70.8 27.4
1 of 2 silo
-------
Silo Emissions Duct
File Name Date Time
17240094 7/24/98 10:09
17240095 7/24/98 10:11
17240096 7/24/98 10:13
17240097 7/24/98 10:14
17240098 7/24/98 10:16
17240099 7/24/98 10:18
17240100 7/24/98 10:20
17240101 7/24/98 10:22
17240102 7/24/98 10:23
17240103 7/24/98 10:25
17240104 7/24/98 10:27
Average — >
Toluene
(ppm) Uncertainty
98.7 21.0
95.3 20.2
94.6 19.9
95.1 19.9
94.1 20.1
92.2 19.6
91.1 19.3
91.3 19.1
90.2 19.1
92.0 19.3
94.0 19.7
130.4 29.7
Iso-
Octane
(ppm) Uncertainty
12.0 4.2
11.7 4.0
11.7 3.9
11.7 3.9
11.2 4.0
10.5 3.9
10.6 3.8
10.8 3.8
10.3 3.8
10.6 3.8
10.5 3.9
15.7 5.9
Hexane
(ppm) Uncertainty
183.3 5.8
177.2 5.6
176.2 5.5
176.6 5.5
175.5 5.5
172.4 5.4
169.9 5.3
170.6 5.3
170.2 5.3
172.1 5.3
177.2 5.4
221.1 8.2
Ethylene
(ppm) Uncertainty
3.2 1.7
3.1 1.6
3.0 1.6
3.0 1.6
3.1 1.6
3.1 1.6
3.0 1.5
3.0 1.5
3.0 1.6
3.0 1.6
3.0 1.6
3.5 1.8
Methane
(ppm) ncertaint
16.4 8.9
15.9 8.6
15.7 8.4
15.7 8.4
15.6 8.5
15.2 8.3
15.1 8.2
15.5 8.1
15.6 8.1
16.2 8.2
16.8 8.3
16.9 11.4
Formalde-
hyde
(ppm) ncertaint
26.6 12.0
26.3 11.6
26.1 11.4
25.8 11.4
26.5 11.5
25.8 11.2
26.0 11.0
25.1 10.9
26.1 10.9
26.2 11.1
26.8 11.3
19.0 16.5
CO
(ppm) Uncertainty
70.8 27.4
69.4 26.1
70.0 24.7
68.5 24.6
66.7 25.9
64.7 25.7
66.4 24.2
70.8 24.4
74.4 24.8
79.2 25.9
84.4 26.0
81.7 31.9
2 of 2 silo
-------
Silo Emissions Duct
File Name Date Time
17250052 7/25/98 8:42
17250053 7/25/98 8:43
17250054 7/25/98 8:45
17250055 7/25/98 8:47
17250056 7/25/98 8:49
17250057 7/25/98 8:51
17250058 7/25/98 8:52
17250059 7/25/98 8:54
17250060 7/25/98 8:56
17250061 7/25/98 8:58
17250062 7/25/98 8:59
17250063 7/25/98 9:01
17250064 7/25/98 9:03
17250065 7/25/98 9:05
17250066 7/25/98 9:06
17250067 7/25/98 9:08
17250068 7/25/98 9:10
17250069 7/25/98 9:12
17250070 7/25/98 9:13
17250071 7/25/98 9:15
17250072 7/25/98 9:17
17250073 7/25/98 9:19
17250074 7/25/98 9:20
17250075 7/25/98 9:22
Average — >
Toluene
(ppm) Uncertainty
10.6
11.3
13.7
27.1 6.0
54.4 11.4
98.3 21.3
284.5
305.0
427.0
425.1
452.3
435.2
434.2
432.7
408.1
401.3
402.5
403.3
355.6
321.4
303.8
288.9
291.9
302.2
7.5 281.2
Iso-
Octane
(ppm) Uncertainty
1.0
0.6
1.8 0.7
4.7 1.2
6.9 2.3
7.9 4.2
14.6
15.8
39.1
38.9
41.4
39.9
39.8
21.7
20.2
19.7
19.7
19.7
17.4
15.6
14.8
14.4
14.6
14.7
0.9 18.0
Hexane
(ppm) Uncertainty
3.2 0.3
6.1 0.4
20.8 1.2
53.2 1.7
105.5 3.2
181.3 5.9
273.5 9.6
322.8 10.5
333.6 14.2
337.0 14.3
326.2 15.0
334.5 14.7
319.8 14.6
297.5 14.4
253.6 13.4
242.1 13.1
235.7 13.1
225.9 13.1
214.8 11.5
209.0 10.4
216.5 9.9
216.5 9.5
214.1 9.6
208.5 9.8
214.7 9.7
Ethylene
(ppm) Uncertainty
0.6
0.6
0.7
0.9
2.3 1.0
3.3 1.7
3.7
15.5
23.0
23.7
26.2
27.4
27.6
27.0
22.7
23.2
18.7
18.6
18.6
19.3
14.0
13.5
13.7
19.4
0.2 15.1
Methane
(ppm) ncertaint
3.1 1.1
4.5 1.2
7.3 1.6
10.2 2.6
13.5 4.8
17.2 9.0
30.0
32.2
45.1
44.9
47.8
46.0
45.9
45.7
43.1
42.4
42.5
42.6
37.6
33.9
32.1
30.5
30.8
31.9
2.3 30.2
Formalde-
hyde
(ppm) ncertaint
1.5
1.6
6.6 2.1
12.7 3.5
20.9 6.5
31.7 12.2
40.2
43.1
60.3
60.0
63.9
61.5
61.3
61.1
57.6
56.7
56.9
57.0
50.2
45.4
42.9
40.8
41.2
42.7
3.0 40.4
CO
(ppm) Uncertainty
8,3
29.5 8.5
69.0 10.2
88.6 11.6
104.9 16.2
102.4 30.0
179.3
212.8
253.4
243.5
245.8
252.4
253.5
250.7
244.6
246.8
223.7
223.8
222.4
228.2
214.9
218.5
222.0
211.4
16.4 176.4
1 of 1 silo
-------
Silo Emissions Duct
File Name Date Time
SED0727A 7/27/98 10:51
SED0727B 7/27/98 11:01
SED0727C 7/27/98 11:12
Average — ^
Toluene
(ppm) Uncertainty
522.4 197.7
357.7
571.2
174 1 375 6
Iso-
Octane
(ppm) Uncertainty
75.9
32.8
27.2
45.3
Hexane
(ppm) Uncertainty
233.1 26.5
126.0 11.3
150.5 18.1
169.9 18.6
Etfiylene
(ppm) Uncertainty
54.2
62.9 16.1
37.5
21.0 35.9
Methane
(ppm) ncertaint
87.4
37.8
60.3
61.8
Formalde-
hyde
(ppm) ncertaint
117.0
50.5
80.7
82.7
CO
(ppm) Uncertainty
426.4 390.7
288.7
326.7
142.1 335.4
1 of 1 silo
-------
Estimated Quantitation Limits (QL, ppm) From FTIR Spectra of Direct Samples Taken From the Silo,
Loadout, and Process Stack Locations.
Compound Name
Acetaldehyde
Benzene
Carbonyl Sulfide
Methyl Chloride
Methyl Chloroform
1,1-dichloroethane
Toluene
1,3-Butadiene
Methanol
Cumene
Ethylbenzene
Hexane
Methylene chloride
Propionaldehyde
Styrene
1, 1,2,2-Tetrachloroethane
p-Xylene
o-Xylene
m-Xylene
2,2,4-Trimethylpentane
Formaldehyde
S02
NO
NO2
N2O
Molar
Mass
(g/mol)
44.05
78.11
60.07
50.49
133.42
98.96
92.13
54.09
32.04
120.19
106.16
86.17
84.94
58.08
104.14
167.86
106.16
106.16
106.16
114.22
30.03
64.1
30.0
46.0
44.0
Silo
QL (ppm)
1.20
3.77
0.16
2.92
0.37
0.42
3.52
0.45
1.96
0.76
3.48
0.06
0.39
0.37
1.38
0.23
1.44
0.09
2.48
0.45
1.15
2.94
4.38
0.63
0.19
Loadout
QL (ppm)
0.34
1.89
0.07
3.83
0.41
0.45
2.4
0.5
0.78
0.38
2.06
0.21
0.35
0.82
1.31
0.32
1.08
0.68
0.79
0.25
0.48
0.36
1.21
0.20
0.024
Process
Stack
QL (ppm)
1.49
5.36
0.07
2.52
2.16
1.3
12.56
2.27
2.08
2.24
3.95
0.42
2.27
0.31
2.69
0.88
0.82
6.91
8.73
0.32
3.94
2.94
4.38
0.63
0.19
Differences in quantitation limits among the locations are primarily due to differences in moisture
concentration.
-------
Procedure for Estimating Quantitation Limits
Measurement limits are typically estimated by using the method to analyze samples known to contain zero
concentrations of the target analytes. Usually these samples are blanks that are prepared by procedures
similar to the samples.
For Method 320 the samples are spectra. The most important feature of the spectra for determining
measurement limits is the spectral absorbance of interfering compounds. For this source the major
interfering species were water vapor and carbon dioxide. The objective is to prepare spectra containing
levels of water vapor and C02, equivalent to those in the sample spectra, but containing none of the target
analytes. These spectra are then analyzed using the same computer program that was used to analyze the
sample spectra. The average of the concentration results obtained from this analysis are presented as the
estimated quantitation limits for the target analytes.
The spectra were prepared from the sample spectra measured in the field. Most of the sample spectra
contained primarily percent levels of water vapor and CO2 with a mixture of ppm concentrations of
hydrocarbon species. The interference concentrations were similar in all of the spectra at each location, but
in most of the samples the hydrocarbon spectral absorbance was relatively low, while in some samples the
hydrocarbon absorbance was much higher. The hydrocarbon absorbance was removed from some low-
hydrocarbon spectra with little effect on the absorbance of the interferences. This was done by scaling a
high-hydrocarbon spectrum and then subtracting the result from a low-hydrocarbon spectrum. For example
spectrum "17240103" was multiplied by a constant factor of 0.01 and the result was subtracted from
spectrum "17240075" (see figures 1 and 2). Some of these spectra had also been spiked with SF6, which
was removed by subtracting a scaled spectrum of the SF6 , standard. This procedure was performed on at
least three spectra from each location. The subtracted spectra were then analyzed with the computer
program. The results for each compound were averaged and the averages are presented in Table 1 as the
quantitation limits for the listed HAPs. Before the quantitation limit analysis the program was modified to
include a reference spectrum of acetaldehyde, but this did not significantly affect the results for the other
target analytes. The advantage of preparing the spectra by the above procedure is that these spectra closely
model the sample spectra.
-------
.15-
C/i
.1-
.05-
0-
Spectrum "17240075" from the Silo
17240075" minus (0.01* "17240103")
3000
2900
Wavenumbers (cm-1)
2800
Figure 1. Spectrum before and after hydrocarbon subtraction to prepare for quantitation limit analysis. Both spectra are
plotted on the same absorbance scale from -.045 to .07 absorbance units. Note that the water vapor features don't
change appreciably after subtraction of the hydrocarbon component.
-------
.15-
.1-
8 -05-
0-
Spectrum "17240075" from the Silo
"17240075" After Subtraction of SFfi Standard
1050
1000
950
900
Wavenumbers (cm'1)
Figure 2. Same Spectra as in Figure 1 plotted on a scale from -.045 to .07 absorbance units. The SF6 in the top spectrum
resulted from the controlled release of the gas standard during testing.
-------
-------
Appendix D
Sample Concentration FTIR Results
MRl-AED\R4951-04-08.wpd
-------
-------
Tenax Concentration Factors
Run No.
-
-
—
-
1
2
1
1
2
2
2
3
3
3
4
Location
Train Blank
Train Blank
Train Blank
Upwind
Process Stack
Process Stack
TED
SED
TED
TED
(duplicate)
SED
TED
TED
(duplicate)
SED
TED
Date
7/20/98
7/21/98
7/22/98
7/22/98
7/21/98
7/22/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/26/98
Adj. Volume (L)
85
86
85
82
239
211
338
177
336
213
169
331
331
173
328
Cell Volume (L)
6.3
Cone. Factor
13.5
13.6
13.5
13.0
37.9
33.5
53.7
28.1
53.3
33.8
26.8
52.5
52.5
27.5
52.1
-------
Table
Adjusted Tenax Concentration Sample Volumes
Run#
1
1 -Rerun
2
3
1
2
Blank
Preliminary
Preliminary
1
2
2-Dup.
3
3-Dup
4
Blank
Blank
VOST
Sampling Console
Location No.
#1
#1
#1
#1
#3
#3
#3
Tunnel Entrance
Loadout
Loadout
Loadout
Loadout
Loadout
Loadout
Loadout
Trailer
Trailer
1
1
1
1
1
1
1
3
3
3
3
2
3
2
3
3
3
Date
7/23/98
7/24/98
7/25/98
7/27/98
7/21/98
7/22/98
7/20/98
7/22/98
7/23/98
7/24/98
7/25/98
7/25/98
7/27/98
7/27/98
7/26/98
7/21/98
7/22/98
Volume
sampled
(L)
69.4
187.7
181.0
187.6
268.6
233.7
93.2
90.2
108.2
360.0
360.0
231.5
360.1
360.1
360.0
90.3
90.5
Meter
temp.
(°C)
25.6
22.6
25.1
27.3
41.1
36.1
32.2
34.4
23.1
26.2
27.9
34.4
31.9
33.3
35.2
23.1
26.0
BP
("Hg)
29.28
29.30
29.28
29.17
29.35
29.31
29.33
29.34
29.33
29.35
29.33
29.33
29.24
29.24
29.31
29.30
29.34
Meter
coef.
0.971
0.971
0.971
0.971
0.971
0.971
0.971
0.978
0.978
0.978
0.978
0.983
0.978
0.983
0.978
0.978
0.978
Adjusted
volume
(m3)
0.065
0.177
0.169
0.173
0.239
0.211
0.085
0.082
0.103
0.338
0.336
0.213
0.331
0.331
0.328
0.086
0.085
1/12/99 3:38 PM Vostvol.xls Sheetl
-------
Summary of Tenax Concentrated Sam
Date
7/20/98
7/21/98
7/22/98
7/22/98
7/21/98
7/22/98
7/23/98
7/24/98
Run
—
—
—
—
1
2
1 -aborted
1
Sample
Train Blank
Train Blank
Train Blank
Upwind
Process Stack
Process Stack
Tunnel Exhaust Duct
Silo Exhaust Duct
Tunnel Exhust
Silo Exhaust Duct
Trap Nos.
101
103
101
102
102
101
106
105
104
103
108
107
112
111
106
105
Spectral Files
T010720i
T010720f
T010720g
T030720i
T030721f
T0107221
T010722f
T020722i
T020722f
T020720i
T020721f
T020721g
T010720g
T010721f
T06072H
T060722f
T05072H
T050722f
T040720i
T040723f
T030722i
T030723f
T080722i
T080723f
T070722i
T070723f
T120722i
T120725f
%110722i
T110725f
T060723i
T060725f
T050723i
NA
pies
Spiking
NA
NA
NA
NA
8.5L
NA
8.5L
NA
8.5L
NA
8.5L
NA
16.5L
NA
16.5L
NA
Notes
Sample lost-overhead
-------
Date
7/25/98
7/26/98
7/27/98
Run
2
4
3
Sample
Tunnel Exhaust Duct
Silo Exhaust Duct
Tunnel Exhaust Duct
Tunnel Exhaust Duct
Silo Exhaust Duct
Trap Nos.
101
107
113
103
102
104
115
108
111
107
101
103
113
104
Spectral Files
T010723i
T010725f
T070724i
T070725f
Tl 307231
T130725f
T0307241
T030725f
T0207231
T020725f •
T0407241
T040725f
Tl 507251
T150726f
T080725i
T080726f
Tl 107261
T110727f
T0707261
T070727f
T010726i
T010727f
T0307261
T030727f
Tl 307261
T130727f
T0407261
T040727f
Spiking
16.5L
NA
16.5L
NA
16.5L
NA
16.5L
NA
16.8L
NA
16.8L
NA
16.8L
NA
Notes
Duplicate Train
Duplicate Train
Duplicate Train
Duplicate Train
1:1 dilution w/N2
during final desorption
-------
File Name Date Time
Benzene ppm A
Toluene-
d8 ' ppm A 2
Methyl
chloride ppm A
Methyle
chloroform ppm A 2
Ethylene
dichloride ppm A 2
Toluene ppm A 2
Train Blanks
T010720I 7/20/98 19:13
T010720F 7/20/98 21:39
T010720G 7/20/98 21:53
T030720I 7/20/98 20:52
T030721F 7/21/98 20:58
TO 107221 7/22/98 11:42
T010722F 7/22/98 20:51
0.0 0.8
0.0 1.0
0.0 0.7
0.0 1.2
0.0 1.9
0.0 0.7
0.0 1.1
14.6 4.2
13.0 5.9
0.0 3.8
28.0 9.2
0.0 8.5
0.0 0.9
0.0 6.0
0.0 2.2
0.0 2.8
0.0 2.1
0.0 4.2
0.0 5.1
0.0 1.8
0.0 3.1
1.7 0.2
2.6 0.3
1.7 0.2
4.1 0.4
0.0 0.4
0.1 0.0
0.0 0.3
0.8 0.5
0.0 0.6
0.0 0.4
0.0 1.1
0.0 1.0
0.0 0.1
0.0 0.7
0.0 2.3
0.0 2.9
0.0 2.1
0.0 4.4
4.8 1.1
5.4 0.4
0.0 3.2
Average
0.0
1.1
7.9
5.5
0.0
3.0
1.4
0.3
0.1
0.6
2.6
2.3
1 High CO2 gives a false positive
2 ppm A = the estimted uncertainty in the measurement
-------
File Name Date
1,3-
butadiene ppm A 2
Methanol ppm A 2
Cumene ppm A 2
Ethyl
benzene ppm A 2
Hexane ppm A 2
Methylene
chloride ppm A 2
Propionald
ehyde ppm A 2
Train Blanks
TO 107201 7/20/98
T010720F 7/20/98
T010720G 7/20/98
T030720I 7/20/98
T030721F 7/21/98
TO 107221 7/22/98
T010722F 7/22/98
0.0 0.4
0.0 0.6
0.0 0.4
0.0 1.0
0.0 0.9
0.2 0.1
0.0 0.6
0.4 0.3
0.0 0.4
0.4 0.3
0.0 0.7
0.0 0.7
0.0 0.1
0.5 0.4
0.0 0.8
0.0 0.5
0.0 0.8
0.0 0.8
0.0 2.0
0.0 0.7
0.0 1.2
0.0 0.8
0.0 3.0
0.0 0.8
0.0 4.4
0.0 5.4
0.0 1.9
0.0 3.2
1.6 0.1
6.9 0.3
1.2 0.1
14.4 0.2
4.1 0.2
1.3 0.1
2.1 0.1
0.0 0.3
0.0 0.4
0.0 0.3
1.5 0.6
0.0 0.6
0.0 0.1
0.0 0.4
0.0 0.4
0.0 0.5
0.0 0.3
0.0 0.7
0.0 0.9
2.3 0.2
0.0 0.5
Average
O.I
0.6
0.1
0.5
0.0
1.2
0.0
3.7 I 4.5
0.2
0.2
0.4
1 High C02 gives a false p
2 ppm A = the estimted un
0.3
0.5
-------
File Name Date
Train Blanks
T010720I 7/20/98
T010720F 7/20/98
T010720G 7/20/98
T030720I 7/20/98
T030721F 7/21/98
TO 107221 7/22/98
T010722F 7/22/98
Average
Styrene ppm A 2
0.0 0.7
0.0 0.9
0.0 0.6
0.0 1 .6
0.0 1.4
0.0 0.2
0.0 1.0
0.0 0.9
1,1,2,2-
Tetrachlor
oethane ppm A 2
1.3 0.3
2.1 0.4
1.5 0.3
2.9 0.7
0.0 0.6
0.0 0.1
0.0 0.4
1.1 0.4
p-Xylene ppm A 2
1.5 0.7
1.7 0.9
1.6 0.6
3.8 1.7
0.0 1.4
0.0 0.1
0.0 1.0
1.2 0.9
o-Xylene ppm A 2
0.0 ' 1.4
0.0 1.8
0.0 1.3
0.0 2.5
0.0 2.7
0.0 1.1
0.0 2.0
0.0 1.8
m-Xylene ppm A 2
0.0 0.7
0.0 0.9
0.0 0.7
3.3 1.4
0.0 4.2
0.0 1.5
0.0 2.5
0.5 1.7
2,2,4-
Trimethylp
entane ppm A 2
0.0 0.2
1.8 0.2
0.0 0.2
0.0 0.4
0.0 0.5
0.0 0.2
0.0 0.3
0.3 0.3
Formaldeh
yde ppm A 2
1.4 0.3
2.3 0.4
2.0 0.4
3.9 0.7
1.2 0.6
0.0 0.3
0.5 0.4
1.6 0.4
High CO2 gives a false p
ppm A = the estimted un
-------
File Name Date Time
Upwinds
T020722I 7/22/98 14:26
T020722F 7/22/98 20:10
Benzene ppm A 2
0.0 1.9
0.0 3.8
Toluene-
d8 ' ppm A 2
0.0 8.9
21.0 16.4
Methyl
chloride ppm A 2
0.0 5.3
0.0 10.6
Methyle
chloroform ppm A 2
0.0 0.4
0.0 0.8
Ethylene
dichloride ppm A 2
0.0 1.0
0.0 2.0
Average
I 0.0
2.9
10.5
12.6
0.0
7.9
0.0
0.6
0.0
1.5
-------
File Name Date
Upwinds
T020722I 7/22/98
T020722F 7/22/98
Average
Toluene ppm A 2
0.0 5.5
0.0 11.0
0.0 8.2
1,3-
butadiene ppm A 2
0.0 0.9
0.0 1.8
Methanol ppm A 2
0.0 0.6
0.0 1.4
0.0 1.4 | 0.0 1.0
Cumene ppm A 2
0.0 2.0
0.0 4.1
Ethyl
benzene ppm A 2
0.0 5.5
0.0 11.1
0.0 3.1 | 0.0 8.3
Hexane ppm A 2
1.2 0.2
2.8 0.3
2.0 0.2
-------
File Name Date
Upwinds
T020722I 7/22/98
T020722F 7/22/98
Average
Methylene
chloride ppm A
0.0 0.6
0.0 1.3
0.0 0.9
Propional
dehyde ppm A
0.0 0.9
0.0 1.8
Styrene ppm A 2
0.0 1.5
0.0 3.0
0.0 1.3 | 0.0 2.2
U,2,2-
Tetrachlor
oethane ppm A
0.0 0.6
0.0 1.3
p-Xylene ppm A 2
0.0 1.5
0.0 2.9
o-Xylene ppm A 2
0.0 3,3
0.0 6.7
0.0 1.0 | 0.0 2.2 | 0.0 5.0
-------
File Name
Upwinds
T020722I
T020722F
Date
7/22/98
7/22/98
Average
m-Xylene ppm A 2
0.0 4.3
0.0 8.6
0.0 6.4
2,2,4-
Trimethyl
pentane ppm A
0.0 0.5
0.0 1.1
0.0 0.8
Formaldeh
yde ppm A
0.7 0.6
0.0 1.5
0.3 1.1
-------
File Name Date Time
Benzene ppm A 2
Toluene-
d8 l ppm A 2
Methyl
chloride ppm A 2
Methyle
chloroform ppm A
Ethylene
dichloride ppm A 2
Silo Exhaust
T080723F 7/23/98 17:38
T070723F 7/23/98 17:25
T060725F 7/25/98 19:08
T020725F 7/25/98 18:46
T040725F 7/25/98 16:14
T130726I 7/26/98 18:33
T130727F 7/27/98 18:31
T040726I 7/26/98 19:08
T040727F 7/27/98 16:59
0.0 194.3
0.0 1.9
242.1 194.0
215.0 193.4
0.0 13.7
0.0 1.0
334.1 195.1
0.0 0.8
0.0 142.6
399.1 109.7
0.0 9.4
1477.0 351.8
1346.1 368.8
0.0 24.0
0.0 4.7
0.0 68.9
0.0 3.5
0.0 22.4
0.0 771.2
0.0 5.3
0.0 1043.1
0.0 1030.5
0.0 28.0
0.0 2.7
0.0 1085.0
0.0 2.2
0.0 565.5
0.0 5.1
1.2 0.4
0.0 16.3
0.0 17.1
0.0 1.1
0.0 0.2
10.8 3.0
0.0 0.2
0.0 1.0
0.0 13.0
1.9 1.0
0.0 41.9
0.0 43.8
8.0 2.6
0.0 0.5
0.0 7.8
0.0 0.4
0.0 2.5
Average
0.0
4.3
0.0
10.4
0.0
9.5
0.3
0.5
1.1
-------
File Name Date
Toluene ppm A 2
1,3-
butadiene ppm A 2
Methanol ppm A 2
Cumene ppm A 2
Ethyl
benzene ppm A
Silo Exhaust
T080723F 7/23/98
T070723F 7/23/98
T060725F 7/25/98
T020725F 7/25/98
T040725F 7/25/98
T130726I 7/26/98
T130727F 7/27/98
T040726I 7/26/98
T040727F 7/27/98
Average
0.0 801.5
0.0 5.5
0.0 1084.1
0.0 1071.0
0.0 31.9
0.0 2.8
0.0 1127.7
0.0 2.2
0.0 587.8
0.0 10.6
0.0 11.8
0.0 0.8
0.0 38.3
0.0 40.0
5.5 2.1
0.0 0.5
0.0 7.1
0.0 0.4
9.9 2.3
1.4 0.9
0.0 8.8
0.0 0.7
0.0 28.5
0.0 29.7
0.0 1.9
0.0 0.3
0.0 5.3
0.4 0.2
0.0 1.7
0.1 0.8
0.0 297.1
0.0 2.0
0.0 401.9
0.0 397.1
0.0 10.8
0.0 1.0
0.0 418.1
0.0 0.8
0.0 217.9
0.0 3.7
0.0 301.9
0.0 2.2
0.0 443.5
0.0 438.9
0.0 19.1
0.0 0.9
0.0 462.1
0.0 0.8
0.0 220.2
0.0 5.7
-------
File Name Date
Hexane ppm A 2
Methylene
chloride ppm A 2
Propional
dehyde ppm A 2
Styrene ppm A 2
U,2,2-
Tetrachlor
oethane ppm A
Silo Exhaust
T080723F 7/23/98
T070723F 7/23/98
T060725F 7/25/98
T020725F 7/25/98
T040725F 7/25/98
T130726I 7/26/98
T130727F 7/27/98
T040726I 7/26/98
T040727F 7/27/98
Average
1197.6 34.9
7.5 0.5
840.3 73.9
854.1 73.7
145.1 4.6
0.7 0.1
859.5 79.0
1.2 0.1
1095.6 52.3
38.6 1.3
0.0 8.2
0.0 0.7
0.0 26.5
0.0 27.7
0.0 1.7
0.0 0.3
10.3 3.4
0.0 0.2
0.0 1.6
0.0 0.7
0.0 128.1
15.2 0.9
0.0 173.2
0.0 171.1
0.0 8.5
0.0 0.4
0.0 180.2
0.0 0.4
0.0 84.7
3.8 2.6
29.7 16.8
0.0 1.6
111.0 54.1
85.1 56.5
0.0 4.1
0.0 0.8
61.2 10.3
0.0 0.6
6.9 3.9
0.0 1.8
12.5 6.7
0.0 0.7
0.0 26.9
36.2 22.7
3.0 1.5
0.0 0.3
26.6 4.5
0.0 0.3
0.0 1.5
0.7 0.7
-------
File Name Date
p-Xylene ppm A 2
o-Xylene ppm A 2
m-Xylene ppm A 2
2,2,4-
Trimethyl
pentane ppm A 2
Formaldeh
yde ppm A 2
Silo Exhaust
T080723F 7/23/98
T070723F 7/23/98
T060725F 7/25/98
T020725F 7/25/98
T040725F 7/25/98
Tl 307261 7/26/98
T130727F 7/27/98
T040726I 7/26/98
T040727F 7/27/98
Average
0.0 18.8
0.0 1.6
0.0 60.8
0.0 63.5
0.0 4.0
0.0 0.8
0.0 11.3
0.0 0.6
0.0 3.7
0.0 1.7
0.0 487.2
3.6 1.2
0.0 659.0
0.0 651.0
0.0 28.0
0.0 1.7
0.0 685.5
0.0 1.4
0.0 357.3
0.9 8.1
727.4 201.8
0.0 4.3
0.0 845.4
0.0 835.2
96.1 13.9
0.0 0.8
0.0 879.4
0.0 0.7
289.7 153.8
24.0 4.9
0.0 46.6
1.2 0.3
0.0 71.5
0.0 70.7
30.1 3.0
0.0 0.2
0.0 74.5
0.0 0.1
61.2 35.0
7.8 0.9
613.6 100.1
6.8 0.8
724.3 133.7
733.6 133.3
46.6 6.6
0.0 0.3
857.0 141.1
0.0 0.3
0.0 82.6
13.3 2.0
-------
File Name Date Time
Benzene ppm A 2
Toluene-
d8 ' ppm A 2
Methyl
chloride ppm A 2
Methyle
chloroform ppm A 2
Ethylene
dichloride ppm A 2
Toluene ppm A 2
Tunnel Exhaust
T040723F 7/23/98 16:51
T030723F 7/23/98 17:08
T120725F 7/25/98 18:00
T110725F 7/25/98 16:01
T010725F 7/25/98 18:33
T070725F 7/25/98 15:48
T030725F 7/25/98 15:32
T150726F 7/26/98 19:47
T080726F 7/26/98 19:24
T110727F 7/27/98 18:00
T070727F 7/27/98 16:47
T010727F 7/27/98 17:45
T030727F 7/27/98 17:30
Average
0.0 2.9
0.0 1.4
0.0 12.2
0.0 2.6
0.0 11.8
0.0 3.0
0.0 1.9
0.0 3.8
0.0 5.4
0.0 14.6
10.9 4.1
0.0 51.6
0.0 3.7
0.8 9.2
18.3 12.9
0.0 7.0
276.9 78.1
12.8 10.2
197.1 64.1
17.8 12.1
0.0 7.6
88.9 39.6
40.1 25.3
226.5 71.6
143.1 59.5
1724.8 413.7
0.0 17.9
211.3 63.1
0.0 10.3
0.0 3.9
0.0 31.2
0.0 7.2
0.0 28.0
0.0 8.3
0.0 5.1
0.0 20.6
0.0 15.0
0.0 32.5
0.0 24.6
0.0 142.1
0.0 10.3
0.0 26.1
0.0 0.6
0.0 0.3
0.0 3.7
0.0 0.5
0.0 3.0
0.0 0.6
0.0 0.3
0.0 1.9
0.0 1.2
0.0 3.4
0.0 2.8
0.0 19.6
0.0 0.8
0.0 3.0
0.0 1.6 0.0 10.8
0.0 0.8
0.0 9.5
0.0 1.2
0.0 7.8
0.0 1.5
0.0 0.9
0.0 4.8
0.0 3.1
0.0 8.7
0.0 7.2
0.0 50.3
0.0 2.0
0.0 7.7
0.0 4.1
35.4 9.5
0.0 7.5
0.0 31.2
0.0 8.6
0.0 5.3
0.0 21.4
0.0 15.5
0.0 38.8
0.0 25.6
0.0 147.7
0.0 10.7
2.7 25.9
-------
File Name Date
U-
butadiene ppm A 2
Methanol ppm A 2
Cumene ppm A 2
Ethyl
benzene ppm A 2
Hexane ppm A 2
Methylene
chloride ppm A 2
Propional
dehyde ppm A 2
Tunnel Exhaust
T040723F 7/23/98 0.0 1.4 0.0 1.1 0.0 4.0 0.0 10.8
T030723F 7/23/98
T120725F 7/25/98
Tl 10725F 7/25/98
T010725F 7/25/98
T070725F 7/25/98
T030725F 7/25/98
T150726F 7/26/98
T080726F 7/26/98
T110727F 7/27/98
T070727F 7/27/98
T010727F 7/27/98
T030727F 7/27/98
Average
0.0 0.7
0.0 8.7
0.0 1.1
0.0 7.1
0.0 1.3
0.0 0.8
0.0 4.4
0.0 2.8
0.0 8.0
0.0 6.6
0.0 45.9
0.0 1.9
0.0 7.0
0.0 0.5
0.0 6.5
0.0 0.8
0.0 5.3
0.0 1.0
0.0 0.6
0.0 3.3
0.0 2.1
0.0 5.9
0.0 4.9
0.0 34.2
0.0 1.4
0.0 5.2
0.0 1.5
0.0 12.0
0.0 2.8
0.0 10.8
0.0 3.2
0.0 2.0
0.0 7.9
0.0 5.8
0.0 12.5
0.0 9.5
0.0 54.8
0.0 4.0
0.0 10.1
0.0 1.1
0.0 32.6
0.0 7.5
0.0 29.2
0.0 8.6
0.0 5.3
0.0 21.5
0.0 15.6
0.0 33.9
0.0 25.7
0.0 148.5
0.0 10.7
0.0 27.0
34.2 1.1
2.3 0.3
102.7 3.2
4.8 0.5
79.3 2.9
3.0 0.5
1.2 0.3
30.0 0.7
3.2 0.5
116.7 3.7
0.0 2.5
95.1 4.5
4.3 0.7
36.7 1.6
0.0 1.0
0.0 0.5
0.0 6.0
0.0 0.8
0.0 4.9
0.0 0.9
0.0 0.5
0.0 3.1
0.0 1.9
0.0 5.5
0.0 4.6
0.0 31.8
0.0 1.3
0.0 4.8
0.0 1.7
0.0 0.7
0.0 5.2
0.0 1.2
0.0 4.6
0.0 1.4
0.0 0.8
0.0 3.4
0.0 2.5
0.0 5.4
0.0 4.1
0.0 23.6
0.0 1.7
0.0 4.3
-------
File Name Date
Styrene ppm A 2
1,1,2,2-
Tetrachlor
oethane ppm A 2
p-Xylene ppm A 2
o-Xylene ppm A 2
m-Xylene ppm A 2
2,2,4-
Trimethyl
pentane ppm A 2
Formaldeh
yde ppm A 2
Tunnel Exhaust
T040723F 7/23/98
T030723F 7/23/98
T120725F 7/25/98
T110725F 7/25/98
T010725F 7/25/98
T070725F 7/25/98
T030725F 7/25/98
T150726F 7/26/98
T080726F 7/26/98
T110727F 7/27/98
T070727F 7/27/98
T010727F 7/27/98
T030727F 7/27/98
Average
0.0 2.4
0.0 1.2
0.0 14.2
0.0 1.8
0.0 11.7
0.0 2.2
0.0 1.3
0.0 7.2
0.0 4.6
0.0 13.0
0.0 10.8
0.0 75.3
0.0 3.0
0.0 11.4
0.0 1.0
0.0 0.5
0.0 6.1
0.0 0.8
0.0 5.0
0.0 0.9
0.0 0.6
0.0 3.1
0.0 2.0
0.0 5.6
0.0 4.6
0.0 32.3
0.0 1.3
0.0 4.9
0.0 2.3
0.0 1.1
0.0 13.8
0.0 1.8
0.0 11.3
0.0 2.1
0.0 1.3
0.0 7.0
0.0 4.5
0.0 12.6
0.0 10.5
0.0 73.0
0.0 3.0
0.0 11.1
0.0 5.9
0.0 2.5
0.0 22.5
0.0 4.5
0.0 17.9
0.0 5.2
0.0 3.2
0.0 13.0
0.0 9.5
0.0 22.2
0.0 15.6
0.0 89.8
0.0 6.5
0.0 16.8
20.9 3.3
0.0 3.2
0.0 25.3
0.0 5.8
50.9 8.8
0.0 6.7
0.0 4.1
0.0 16.7
0.0 12.1
75.5 11.2
0.0 , 20.0
0.0 115.2
0.0 8.3
11.3 18.5
2.8 0.7
0.0 0.4
6.9 2.3
0.0 0.7
2.9 1.9
0.0 0.8
0.0 0.5
0.0 1.4
0.0 1.5
2.5 2.4
0.0 2.5
0.0 7.3
1.0 0.5
1.2 1.8
6.8 1.6
0.0 0.6
28.2 5.1
1.5 0.8
13.6 42
1.9 0.9
0.8 0.6
3.3 2.6
0.0 2.2
18.9 5.3
0.0 36
21.6 16.6
0.0 1.5
7.4 3.5
-------
File Name Date Time
Process Stack
T020721F 7/21/98 20:10
T010721F 7/21/98 20:41
T060722F 7/22/98 19:28
T050722F 7/22/98 19:55
Average
Benzene ppm A 2
0.0 12.1
32.6 7.5
16.7 6.9
26.9 7.1
19.0 8.4
Toluene-
d8 ' ppm A 2
362.0 97.8
1917.8 340.3
162.0 66.6
1925.6 339.1
1091.9 210.9
Methyl
chloride ppm A 2
0.0 38.3
0.0 45.2
0.0 30.4
0.0 42.4
0.0 39.1
Methyle
chloroform ppm A 2
0.0 4.6
0.0 16.1
0.0 3.1
0.0 16.1
0.0 10.0
Ethylene
dichloride ppm A 2
0.0 11.7
0.0 41.3
0.0 8.1
0.0 41.2
0.0 25.6
-------
File Name Date
Process Stack
T020721F 7/21/98
T010721F 7/21/98
T060722F 7/22/98
T050722F 7/22/98
Toluene ppm A 2
92.0 9.0
0.0 47.0
0.0 31.6
0.0 44.1
1,3-
butadiene ppm A 2
13.5 9.6
0.0 37.7
10.6 5.8
0.0 37.6
Methanol ppm A 2
0.0 7.9
0.0 28.0
0.0 5.5
0.0 28.0
Cumene ppm A
0.0 14.8
0.0 17.4
0.0 11.7
0.0 16.3
Ethyl
benzene ppm A 2
0.0 40.1
0.0 47.2
0.0 31.7
0.0 44.3
Average 23.0 32.9 6.0 22.7 0.0 17.4 0.0 15.1 0.0 40.8
Hexane ppm A 2
79.0 1.5
9.2 1.5
37.6 1.9
5.9 1.4
32.9 1.6
-------
File Name Date
Process Stack
T020721F 7/21/98
T010721F 7/21/98
T060722F 7/22/98
T050722F 7/22/98
Average
Methylene
chloride ppm A 2
0.0 7.4
0.0 26.1
0.0 5.1
0.0 26.0
0.0 16.2
Propional
dehyde ppm A 2
8.0 6.3
10.5 5.8
0.0 4.9
7.6 5.4
6.5 5.6
Styrene ppm A 2
17.3 17.0
0.0 61.8
0.0 12.0
0.0 61.6
4.3 38.1
U,2,2-
Tetrachlor
octhane ppm A 2
0.0 7.5
0.0 26.5
0.0 5.2
0.0 26.4
0.0 16.4
p-Xylene ppm A
0.0 16.9
0.0 59.9
0.0 11.7
0.0 59.7
0.0 37.1
o-Xylene ppm A
0.0 22.6
0.0 28.6
22.1 8.7
0.0 26.8
5.5 21.7
-------
File Name
Date
Process Stack
T020721F
T010721F
T060722F
T050722F
7/21/98
7/21/98
7/22/98
7/22/98
Average
m-Xylene
0.0
0.0
0.0
0.0
0.0
ppm A2
31.1
36.7
24.6
34.4
31.7
2,2,4-
Trimethyl
pentane
0.0
0.0
0.0
0.0
0.0
ppm A2
3.9
4.5
3.1
4.3
3.9
Formaldeh
yde
16.5
0.0
9.7
0.0
6.6
ppm A 2
5.8
6.6
3.8
6.2
5.6
-------
Appendix E
THC Data
MRI-AED\R4951-04-08.wpd
-------
THC
Cal Gas
Value
0.0
90.3
50.2
25.0
Measured
Value
0.0
90.2
50.9
25.0
Run 1 - Dryer Stack - 7/21/98
Calibration Error Determination
Difference
As % span error
0.0
0.1
0.7
0.0
Instrument Span for THC is 100 ppm
Pass/Fail Criteria is +/- 5% of Ca! Gas for THC
Initial
Value
0.0
1st Drift Check
Value
0.3
Zero Drift
1st Drift Check
Value
0.3
Final
Value
0.3
Difference
As % span error
0.3
Difference
As % span error
0.0
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Span Drift
Initial
Value
90.2
1st Drift Check
Value
89.9
1st Drift Check
Value
89.9
Final
Value
89.5
Difference
As % span error
0.3
Difference
As % Error
0.4
Pass/Fail
Pass
Pass/Fail
Pass
CAL721A.WK4
-------
Run 2 - Dryer Stack - 7/22/98
Calibration Error Determination
THC
Cal Gas
Value
0.0
90.3
50.2
25.0
Measured
Value
0.2
90.1
50.6
25.6
Difference
As % span error
0.2
0.2
0.4
0.6
Instalment Span for THC is 100 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
Initial
Value
0.2
1st Drift Check
Value
-0.1
Zero Drift
1st Drift Check
Value
-0.1
Final
Value
0.3
Difference
As % span error
0.3
Difference
As % span error
0.4
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Span Drift
Initial
Value
90.2
1st Drift Check
Value
89.9
1st Drift Check
Value
90.9
Final
Value
90.3
Difference
As % span error
0.7
Difference
As % Error
0.4
Pass/Fail
Pass
Pass/Fail
Pass
CAL722A.WK4
-------
Run 1 - Load Out - 7/24/98
Calibration Error Determination
Cai Gas
Value
Measured
Value
THC 0.0 1.2
899.0 905.1
498.0 508.0
249.0 246.0
Instrument Span for THC Silo is 1000 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
Initial
Value
THC 1.2
Initial
Value
THC Silo 905.0
Final
Value
-0.1
Final
Value
906.8
Difference
As %span error
0.1
0.6
1.0
0.3
Zero Drift
Difference
As % span error
0.1
Span Drift
Difference
As % span error
0.2
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail Criteria for Drift is +/-3% of THC Span
CAL724A.WK4
-------
Run 2 - Load Out - 7/25/98
Calibration Error Determination
Cal Gas
Value
Measured
Value
THC 0.0 1.7
899.0 902.4
498.0 506.3
249.0 254.6
Instrument Span for THC is 1000 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
Initial
Value
THC 1.7
Initial
Value
THC Silo 902.0
Final
Value
3.7
Final
Value
900.1
Difference
As % span error
0.2
0.3
0.8
0.6
Zero Drift
Difference
As % span error
0.2
Span Drift
Difference
As % span error
0.2
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail Criteria for Drift is +/-3% of THC Span
CAL725A.WK4
-------
Run 3 - Load Out - 7/27/98
Calibration Error Determination
THC Silo
Cal Gas
Value
0.0
899.0
498.0
249.0
Instrument Span for THC Silo is 1000
Pass/Fail Criteria is +/- 5% of Cal Gas
THC Tunnel
Cal Gas
Value
0.0
90.4
50.2
25.0
Measured
Value
1.1
907.6
505.0
261.3
ppm
for THC
Measured
Value
0.2
90.4
50.9
25.5
Difference
As % span error
0.1
0.9
0.7
1.2
Difference
As % span error
0.2
0.0
0.7
0.5
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/ Fail
Pass
Pass
Pass
Pass
Instrument Span for THC Tunnel is 100 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
Zero Drift
Initial
Value
THC Silo 1.1
Initial
Value
THC Tunnel 0.2
Initial
Value
THC Silo 907.6
Initial
Value
THC Tunnel 90.4
Final
Value
-0.9
Final
Value
0.1
Final
Value
903.3
Final
Value
Difference
As % span error
0.2
Difference
As % span error
0.1
Span Drift
90.6
Difference
As % span error
0.4
Difference
As % span error
0.2
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail Criteria for Drift is +/-3% of THC Span
CAL727A.WK4
-------
Run 4 - Baseline - 7/26/98
THC
Cal Gas
Value
0.0
90.3
50.2
25.0
Measured
Value
0.2
90.6
51.1
25.5
Calibration Error Determination
Difference
As % span error
0.2
0.3
0.9
0.5
Instrument Span for THC is 100 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
. Initial
Value
0.2
1st Drift Check
Value
0.1
Zero Drift
1st Drift Check
Value
0.1
Final
Value
0.1
Difference
As % span error
0.1
Difference
As % span error
0.0
Pass/ Fail
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Span Drift
Initial
Value
90.5
1st Drift Check
Value
90.4
1st Drift Check
Value
90.4
Final
Value
90.8
Difference
As % span error
0.1
Difference
As % span error
0.4
Pass/Fail
Pass
Pass/Fail
Pass
CAL726A.WK4
-------
Intermittent Load Dump - 7/25/98
Calibration Error Determination
Cal Gas
Value
Measured
Value
Difference
As % span error
THC 0.0 0.2
90.4 90.7
50.2 50.9
25.0 24.7
Instalment Span for THC is 100 ppm
Pass/Fail Criteria is +/- 5% of Cal Gas for THC
Zero Drift
Initial
Value
THC 0.2
1st Drift Check
Value
0.4
Initial
Value
THC Silo 90.7
1 st Drift Check
Value
90.4
1st Drift Check
Value
0.4
Final
Value
0.0
Difference
As % span error
0.2
Difference
As % span error
0.4
Span Drift
1 st Drift Check
Value
90.4
Final
Value
90.4
Difference
As % span error
0.3
Difference
As % span error
0.0
Pass/ Fail
0.2
0.3
0.7
0.3
Pass
Pass
Pass
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail
Pass
Pass/Fail Criteria for Drift is +/-3% of THC Span
CAL725IA.WK4
-------
Response Times
Analyzer Response Time
THC Silo 1 min. 25 sec.
THC Tunnel 35 sec.
THC Dryer Stack 1 min. 30 sec.
-------
Run 1 - Process Stack
11:00 11:30 12:00 12:30 13:00 13:30 14:00 14:30
Time (24-hr clock)
-------
Run 2 - Process Stack
90
80
70
re
o.
o
Q. 60
o
c
o
O
O
50
40
30
20
10
0
9:30 10:00 10:30 11:00 11:30 12:00 12:30
Time (24-hr clock)
-------
Run 1 - THC Loadout
0
c
(0
a
o
a
o
c
o
o
o
8:00
9:00
10:00
11:00
12:00
13:00
Time (24-hr clock)
-------
Run 2 - THC Loadout
7:00
8:00
9:00
10:00
Time (24-hr clock)
11:00
12:00
-------
Run 3 - THC Loadout
0)
c
ra
a
o
a.
o
c
o
o
o
X
7:00
8:00
9:00
10:00
11:00
12:00
Time (24-hr clock)
-------
Run 4 - THC Loadout (Bkgd)
O
9:00 10:00 11:00 12:00 13:00 14:00
Time (24-hr clock)
-------
Run 1 - THC Silo Storage
OS
Q.
O
700
Q.
&.
•
O
c
o
o
100
0
7:00
,-V^ f'\"'t£":f "<;1fy<
s, t>i . «„,.- i; ^ /AS;,^->A ;-^
«*^; "^ •> ^ i' TI '-^ " » •-*_ ^ ,->*< .',
8:00
9:00
10:00
11:00
Time (24-hr)
-------
Run 2 - THC Silo Storage
~7r\r\
700
^
C cr\r\
g 600 -
Q.
O cnn
»- oUU
Q.
P A An
= 400 -
Q.
<^—x onA
. oOO
0
** onn
o 200-
C3 4 nn
if 100
H
/-
*i.
- r ? " „
t v t ^ ' -•
,as^;S^3fe^ -•-:„.- :'.. -^^i.
'. (^ -\ ,' j^,p4Mss*.,-^?'/ "' ' ;- ~".f ">%/-i A ^r"*-","
j "\ • • "V^-"^''- '*"- "x -
|i - - ' - ..".*'*•> '
• -i
' VA
-* -.
• :•'•:•• ::
/ 'ii
- - ,/.-•.. J
_i
8:00
^ 'j - _^ ^ ^ i ^ ^ ^ t it - f
*. J '- ^
' / -
^ev.
^ / ( l
" "r ^
s t •* *
-" ( f
*"*,,/'" Jl '* *? 2-*S-i*' 'I *
, ,/ '"jt * , . '*->^I>t, "i
' • ' '/'*'"''•<.....
^''/"^'- ,, '': - 5j^i^ ' *",'_'-'
*;./; -lC:r, t - <-, - ,;^-f"<*
V" • ' v v,- .
^~~*- k — - — • ^^^J^AS^^VX — . — ^~:<;A f*
1 ' 1 1
9:00 10:00 11:00 12:00
Time (24-hr clock)
-------
Run 3 - THC Silo Storage
-------
THC Concentration (ppm)
TJ
05
CQ
CD
-j
3
CD
co
CO
CO
CO
co
ji.
p
ji.
oo
CO
ife.
co
b
o
co
en
Ul
o
N>
Kb
o
CD
CO
p?
*.
oo
Kb
'6
o
CO
co
Op
ro
Ol
co
O)
en
ro
O
O
O
3
o
(D
D
(A
O
c
2.
3
CQ
r*
(D
fl)
O
fi)
CL
O
(D
CQ
Q
s
oa
-------
Plant C
Run 1 Dryer Stack
Date: 7/21/98
Project #4701-08-03-04
Operator: Gulick
TIME
24 hr
1120
1121
1122
1123
1124
1125
1126
1127
1128
1129
1130
1131
1132
1133
1134
1135
1136
1137
1138
1139
1140
1141
1142
1143
1144
1145
1146
1147
1148
1149
1150
1151
1152
1153
1154
1155
1156
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
THC Dryer
ppm
10.7
5.2
8.7
11.5
18.5
20.7
16.1
20.8
23.8
24.4
22.1
21.4
23.9
21.5
20.2
23.0
19.3
16.5
14.0
17.6
14.2
14.8
16.9
13.6
15.4
17.9
18.2
11.3
14.6
17.9
11.4
12.7
12.2
11.6
11.1
13.1
10.4
-------
1157
1158
1159
1200
1201
1202
1203
1204
1205
1206
1207
1208
1209
Flame Out
1218
1219
1220
1221
1222
1223
1224
1225
1226
1227
1228
1229
1230
1231
1232
1233
1234
1235
0:00
0:00
0:00
Calibration Check
1249
1250
1251
1252
1253
1254
1255
1256
1257
1258
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
12:08
12:09
12:18
12:19
12:20
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:49
12:50
12:51
12:52
12:53
12:54
12:55
12:56
12:57
12:58
14.7
17.2
16.2
12.6
13.4
17.1
17.2
14.6
16.5
16.7
16.5
16.9
18.2
11.0
14.7
18.8
14.9
16.0
16.2
10.0
8.6
9.6
8.6
6.2
7.3
5.7
7.1
7.6
7.5
9.9
9.6
13.9
6.9
7.8
8.8
11.4
17.3
16.2
13.0
12.7
8.1
9.1
8.5
10.1
-------
1259
1300
1301
1302
Flame Out
1305
1306
1307
1308
1309
1310
1311
1312
1313
1314
1315
1316
1317
1318
Flame Out
1320
1321
1322
1323
1324
1325
1326
1327
1328
1329
1330
1331
1332
Flame Out
1338
1339
1340
1341
1342
1343
1344
1345
1346
1347
1348
1349
12:59
13:00
13:01
13:02
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
13:38
13:39
13:40
13:41
13:42
13:43
13:44
13:45
13:46
13:47
13:48
13:49
9.5
10.6
10.5
6.0
19.3
26.7
28.0
32.0
24.0
28.7
24.1
28.7
32.8
28.4
38.4
33.2
36.3
35.5
21.0
23.4
29.6
32.6
24.3
24.3
24.8
26.0
31.4
26.9
26.2
31.1
31.8
25.7
26.5
28.1
26.3
27.4
19.7
27.5
30.7
24.2
22.2
30.5
27.1
-------
1350
1351
1352
1353
1354
1355
1356
1357
1358
1359
1400
1401
1402
1403
1404
1405
1406
1407
1408
1409
1410
1411
1412
1413
1414
1415
1416
1417
1418
1419
1420
Minimum=
Maximum=
Average=
13:50
13:51
13:52
13:53
13:54
13:55
13:56
13:57
13:58
13:59
14:00
14:01
14:02
14:03
14:04
14:05
14:06
14:07
14:08
14:09
14:10
14:11
14:12
14:13
14:14
14:15
14:16
14:17
14:18
14:19
14:20
22.8
24.2
24.0
14.5
12.6
8.8
10.5
9.5
10.4
5.8
6.0
8.5
7.6
5.1
12.7
11.0
9.3
12.8
18.5
17.0
16.5
24.2
25.5
34.1
55.8
54.1
49.4
58.9
63.5
40.8
47.0
5.1
63.5
19.2
-------
Run 1 - Process Stack
o
11:00 11:30
12:00 12:30 13:00 13:30
Time (24-hr clock)
14:00 14:30
-------
Plant C
Run 2 Dryer Stack
Date: 7/21/98
Project # 4701 =08-03-04
Operator: Gulick
TIME
24 hr
935
936
937
938
939
940
941
942
943
944
945
946
947
948
949
950
951
952
953
954
955
956
957
958
959
1000
1001
1002
1003
1004
1005
1006
1007
1008
1009
1010
1011
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
THC Drye
ppn
8.2
8.4
7.0
7.1
8.2
6.0
7.1
7.3
8.4
7.1
5.6
6.9
7.6
6.6
5.6
6.8
5.6
5.8
5.8
6.0
4.7
6.1
6.1
6.6
4.8
6.5
5.6
5.4
6.6
6.5
4.8
5.1
5.7
4.5
4.4
7.7
2.9
-------
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
1027
1028
1029
1030
1031
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
1047
1048
1049
1050
1051
1052
1053
1054
1055
1056
Calibration Check
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
7.2
8.0
7.5
7.6
7.5
8.8
7.2
8.1
6.9
7.0
7.5
9.7
8.2
7.1
8.1
6.6
7.4
7.0
8.1
8.7
9.0
7.8
7.2
7.9
8.2
7.3
8.0
7.5
4.9
4.7
5.2
4.6
3.4
4.2
3.5
3.2
4.0
4.0
3.7
3.4
3.8
2.8
4.8
3.6
3.5
-------
1104
11-05
1106
1107
1108
1109
1110
1111
1112
1113
1114
1115
1116
1117
1118
1119
1120
1121
1122
1123
1124
1125
1126
1127
1128
1129
1130
1131
1132
1133
1134
1135
1136
1137
1138
1139
1140
1141
1142
1143
1144
1145
1146
1147
1148
1149
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
4.7
4.6
5.2
4.9
5.8
5.5
5.4
5.3
5.2
5.4
5.1
6.4
9.0
4.7
6.0
6.7
7.6
6.5
6.3
6.5
6.8
6.2
6.2
6.6
6.8
6.0
6.7
6.8
4.6
6.1
10.6
14.3
10.7
6.9
10.3
24.1
24.5
41.8
28.8
35.8
22.7
46.7
65.4
84.4
67.9
80.9
-------
1150
1151
1152
1153
1154
1155
1156
1157
1158
1159
1200
1201
1202
1203
1204
1205
1206
1207
1208
1209
1210
1211
1212
1213
1214
1215
1216
1217
1218
1219
1220
1221
1222
1223
1224
1225
1226
1227
1228
1229
1230
1231
1232
1233
1234
1235
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
12:08
12:09
12:10
12:11
12:12
12:13
12:14
12:15
12:16
12:17
12:18
12:19
12:20
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
61.6
53.8
66.3
58.3
45.1
35.8
36.8
47.3
37.8
41.3
37.2
38.7
38.3
38.3
39.2
27.5
32.1
26.8
34.0
57.3
42.4
41.8
36.5
28.7
33.7
30.2
40.1
35.7
39.6
31.2
37.5
41.0
34.5
31.3
34.4
45.9
37.5
57.3
41.7
72.5
63.3
46.4
44.6
55.1
65.6
24.1
-------
1236
1237
Minimum=
Maximum=
Average=
12:36
12:37
38.3
36.4
2.8
84.4
18.7
Run 2 - Process Stack
9:30 10:00 10:30 11:00 11:30 12:00 12:30
Time (24-hr clock)
-------
Plant C
Run 1 Load Out
Date 7/24/98
Project # 4701-08-03-04
Operator: Gulick
Time
24 hr
720
721
722
723
724
725
726
727
728
729
730
731
732
733
734
735
736
737
738
739
740
741
742
743
744
745
746
747
748
749
750
751
752
753
754
755
756
7:20
7:21
7:22
7:23
7:24
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:38
7:39
7:40
7:41
7:42
7:43
7:44
7:45
7:46
7:47
7:48
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
THC Silo
ppm
56.1
99.8
146.2
202.8
259.0
314.7
360.5
412.4
447.5
490.0
532.5
560.9
599.7
614.5
647.5
638.6
639.6
658.4
682.0
690.3
707.7
726.4
749.8
771.4
748.9
726.4
751.0
765.5
724.9
692.9
699.6
692.4
723.1
757.2
780.2
732.6
734.5
THC Tunnel
Ppm
7:20
7:21
7:22
7:23
7:24
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:38
7:39
7:40
7:41
7:42
7:43
7:44
7:45
7:46
7:47
7:48
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
-------
757
758
759
800
801
802
803
804
805
806
807
808
809
810
811
812
813
814
815
816
817
818
819
820
821
822
823
824
825
826
827
828
829
830
831
832
833
834
835
836
837
838
839
840
841
842
7:57 767.0
7:58 789.5
7:59 747.8
8:00 748.5
8:01 770.8
8:02 744.2
8:03 702.6
8:04 712.4
8:05 714.0
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
8:33
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
7:57
7:58
7:59
8:00
8:01
8:02
8:03
8:04
8:05
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
8:33
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
12.8
26.0
15.5
11.5
10.1
8.4
7.1
6.3
5.6
5.3
10.0
15.5
12.7
10.1
6.6
8.0
6.1
17.2
10.1
16.8
7.5
9.6
14.9
6.2
4.6
4.1
3.7
15.6
17.3
-------
843
844
845
846
847
848
849
850
851
852
853
854
855
856
857
858
859
900
901
902
903
904
905
906
907
908
909
910
911
912
913
914
915
916
917
Off Line
936
937
938
939
940
941
942
943
944
945
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:36 394.0
9:37 509.3
9:38 512.5
9:39 499.6
9:40 505.3
9:41 512.2
9:42 489.5
9:43 468.7
9:44 456.3
9:45 457.5
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
11.1
15.6
6.0
17.3
6.8
4.7
18.2
6.6
4.7
19.1
16.0
12.0
12.9
12.0
12.0
14.4
8.3
5.2
4.9
14.9
5.2
3.5
3.0
11.7
10.9
11.0
4.6
3.3
2.8
14.2
11.0
4.6
14.9
6.8
19.0
-------
946
947
948
949
950
951
952
953
954
955
956
957
958
959
1000
1001
1002
1003
1004
1005
1006
1007
1008
1009
1010
1011
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
1027
1028
1029
1030
1031
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
454.1
461.6
467.1
472.5
484.4
495.4
485.9
482.8
473.7
465.0
468.1
477.0
494.8
481.6
485.2
487.3
477.8
473.7
457.0
460.9
472.6
475.1
479.8
473.3
454.8
445.9
438.0
434.1
442.0
438.8
444.6
444.7
437.7
430.8
427.2
423.3
426.2
425.9
427.9
424.6
442.1
451.3
455.2
455.4
454.3
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
-------
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
1047
1048
1049
1050
1051
1052
1053
1054
1055
1056
1057
1058
1059
1100
1101
1102
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1113
1114
1115
1116
1117
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
1 1 :07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
9.3
13.9
10.3
16.3
7.6
13.0
8.2
6.3
14.2
7.9
15.4
5.3
3.0
11.9
5.5
2.4
1.4
1.0
0.8
1.1
1.9
0.1
-0.2
9.3
2.0
8.0
8.7
4.3
12.9
5.9
2.6
0.8
0.0
-0.2
4.0
3.7
2.7
9.4
1.8
0.2
-0.6
-1.1
-------
1118
Off Line
1124
1125
1126
1127
1128
1129
1130
1131
1132
1133
1134
1135
1136
1137
1138
1139
1140
1141
1142
1143
1144
1145
1146
1147
1148
1149
1150
1151
1152
1153
1154
1155
1156
1157
1158
1159
1200
1201
1202
1203
1204
1205
1206
1207
11:18
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
11:18
6.0
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
12:04
12:05
12:06
12:07
6.3
6.0
9.0
11.4
3.6
8.2
2.9
9.7
2.8
1.1
0.2
3.9
3.7
9.4
2.5
1.1
4.8
5.8
6.5
7.1
7.1
1.7
11.5
3.7
12.0
4.3
2.0
0.8
3.0
7.1
2.4
4.2
4.2
1.6
9.0
9.4
6.9
2.2
0.9
0.4
0.2
10.6
7.6
10.2
-------
1208 12:08 12:08 2.7
1209 12:09 12:09 1.5
1210 12:10 12:10 11.9
1211 12:11 12:11 3.6
1212 12:12 12:12 2.1
1213 12:13 12:13 9.0
1214 12:14 12:14 2.3
1215 12:15 12:15 1.0
1216 12:16 12:16 0.2
1217 12:17 12:17 8.7
1218 12:18 12:18 3.3
1219 12:19 12:19 3.3
1220 12:20 12:20 8.1
1221 12:21 12:21 2.9
1222 12:22 12:22 9.4
1223 12:23 12:23 2.8
1224 12:24 12:24 1.3
1225 12:25 12:25 9.7
1226 12:26 12:26 8.9
1227 12:27 12:27 4.6
1228 12:28 12:28 2.0
1229 12:29 12:29 0.9
1230 12:30 12:30 0.2
1231 12:31 12:31 3.3
1232 12:32 12:32 8.4
1233 12:33 12:33 2.5
1234 12:34 12:34 1.0
1235 12:35 12:35 3.3
1236 12:36 12:36 7.3
1237 12:37 12:37 18.6
1238 12:38 12:38 11.4
1239 12:39 12:39 13.1
1240 12:40 12:40 12.1
1241 12:41 12:41 14.7
1242 12:42 12:42 9.4
1243 12:43 12:43 11.5
1244 12:44 12:44 3.8
1245 12:45 12:45 9.4
1246 12:46 12:46 10.6
1247 12:47 12:47 6.9
1248 12:48 12:48 3.0
1249 12:49 12:49 8.1
1250 12:50 12:50 5.2
1251 12:51 12:51 5.3
1252 12:52 12:52 6.8
1253 12:53 12:53 2.4
-------
1254
1255
1256
1257
Minimum=
Maximum=
Average=
12:54
12:55
12:56
12:57
56.1
789.5
531.4
12:54
12:55
12:56
12:57
8.6
7.7
6.5
10.3
-1.1
26.0
7.1
Run 1 - THC Silo Storage
7:00
8:00
9:00
Time (24-hr)
10:00
11:00
8:00
Run 1 - THC Loadout
9:00
10:00 11:00
Time (24-hr clock)
12:00
13:00
-------
Plant C
Run 2 Load Out
Date: 7/25/98
Project #4701-08-03-04
Operator: Gulick
Time
24 hr
710
711
712
713
714
715
716
717
718
719
720
721
722
723
724
725
726
727
728
729
730
731
732
733
734
735
736
737
738
739
740
741
742
743
744
745
746
7:10
7:11
7:12
7:13
7:14
7:15
7:16
7:17
7:18
7:19
7:20
7:21
7:22
7:23
7:24
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:38
7:39
7:40
7:41
7:42
7:43
7:44
7:45
7:46
THC Tunnel
ppm
3.1
8.5
11.1
5.7
7.3
9.5
6.0
7.6
3.8
7.3
8.6
9.4
9.4
8.1
2.0
10.4
13.5
4.9
9.0
8.7
7.2
4.7
7.3
1.9
5.3
8.1
8.6
7.1
8.3
10.8
8.9
10.6
6.3
11.8
4.1
4.3
14.1
7:10
7:11
7:12
7:13
7:14
7:15
7:16
7:17
7:18
7:19
7:20
7:21
7:22
7:23
7:24
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:38
7:39
7:40
7:41
7:42
7:43
7:44
7:45
7:46
THC Silo
ppm
-------
747
748
749
750
751
752
753
754
755
756
757
758
759
800
801
802
803
804
805
806
807
808
809
810
811
812
813
814
815
816
817
818
819
820
821
822
823
824
825
826
827
828
829
830
831
832
7:47
7:48
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
7:57
7:58
7:59
8:00
8:01
8:02
8:03
8:04
8:05
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
5.9
4.8
12.3
8.7
9.5
9.0
4.0
11.7
6.8
8.1
8.0
16.0
14.7
12.1
4.3
13.0
11.8
11.0
9.8
12.0
10.2
10.6
9.7
10.9
7.9
11.9
10.6
11.8
7.5
8.5
8.0
10.7
8.9
7.4
11.5
10.3
1.6
8.0
7.6
10.2
7.2
12.1
6.3
2.8
10.5
7.8
7:47
7:48
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
7:57
7:58
7:59
8:00
8:01
8:02
8:03
8:04
8:05
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
-------
833
834
835
836
837
838
839
840
841
842
843
844
845
846
847
848
849
850
851
852
853
854
855
856
857
858
859
900
901
902
903
904
905
906
907
908
909
910
911
912
913
914
915
916
917
918
8:33
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:18
8.0
5.4
8.5
6.0
7.6
6.5
9.3
6.0
3.4
8.4
8.0
4.9
8.8
5.1
5.8
9.3
6.8
8.0
9.2
10.3
13.4
15.0
16.9
15.5
14.8
16.0
16.4
14.7
15.6
17.5
13.1
13.1
15.4
10.0
10.5
12.7
9.8
13.3
11.1
11.5
12.6
14.4
11.7
11.0
12.6
11.7
8:33
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:18
28.9
56.4
97.8
147.5
213.1
286.7
370.5
468.5
548.6
609.1
639.2
648.8
646.2
652.6
655.6
649.0
655.2
632.3
605.6
595.1
587.0
560.5
477.3
447.8
444.7
439.2
443.7
448.3
433.1
423.6
419.6
411.9
426.8
442.7
-------
919
920
921
922
923
924
925
926
927
928
929
930
931
932
933
934
935
936
937
938
939
940
941
942
943
944
945
946
947
948
949
950
951
952
953
954
955
956
957
958
959
1000
1001
1002
1003
1004
9:19
9:20
9:21
9:22
9:23
9:24
9:25
9:26
9:27
9:28
9:29
9:30
9:31
9:32
9:33
9:34
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
13.6
14.0
13.8
11.7
13.4
11.5
17.5
14.2
6.4
4.1
5.9
8.6
6.9
4.0
11.6
5.6
7.7
4.5
2.5
7.5
9.4
7.3
8.9
5.1
7.0
9.3
8.4
6.7
7.6
8.7
6.6
10.0
4.7
8.9
7.8
3.0
6.1
7.1
11.8
7.1
8.7
4.9
12.0
4.7
13.6
6.7
9:19
9:20
9:21
9:22
9:23
9:24
9:25
9:26
9:27
9:28
9:29
9:30
9:31
9:32
9:33
9:34
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
443.8
435.0
432.5
446.5
458.4
456.5
439.9
431.5
264.3
69.3
48.0
37.5
35.0
28.8
26.3
24.5
21.3
20.3
18.4
20.5
16.7
15.3
14.2
14.2
15.1
14.1
12.8
12.0
12.5
14.2
11.7
12.6
12.7
14.4
11.5
10.3
9.7
9.3
12.8
11.5
13.7
12.0
12.7
13.9
11.1
9.9
-------
1005
1006
1007
1008
1009
1010
1011
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
1027
1028
1029
1030
1031
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
1047
1048
1049
1050
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
8.2
8.7
9.1
6.9
5.3
5.0
7.0
11.3
14.0
12.3
6.2
5.2
11.4
2.2
6.5
6.3
6.0
9.9
4.6
6.3
2.9
6.0
5.8
6.6
8.6
7.9
5.4
6.9
5.9
-0.1
33.0
6.2
0.0
-0.2
-0.2
-0.2
-0.2
-0.1
-0.2
-0.2
-0.2
-0.2
0.7
1.1
1.0
1.0
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
14.2
11.5
9.7
11.9
10.4
9.0
8.0
7.6
10.3
8.9
7.8
7.8
10.8
10.1
10.2
8.9
8.4
7.9
7.4
7.1
6.8
6.8
6.3
6.7
7.1
9.9
9.1
9.6
12.0
13.6
10.7
8.4
5.5
12.9
4.0
2.8
7.5
7.0
7.4
12.7
7.8
13.8
8.2
5.6
4.1
1.8
-------
1051
1052
1053
1054
1055
1056
1057
1058
1059
1100
1101
1102
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
Offline
1114
1115
1116
1117
1118
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:14
11:15
11:16
11:17
11:18
1.0
1.0
1.0
16.4
6.9
7.1
4.1
-0.2
-3.2
-0.1
8.3
2.3
0.7
-1.9
2.0
3.0
2.3
1.6
1.5
1.4
1.2
1.2
1.1
0.7
0.3
0.8
0.7
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:14
11:15
11:16
11:17
11:18
8.7
9.5
8.6
6.9
9.4
0.5
6.6
10.2
8.4
7.0
6.2
6.0
9.9
6.8
4.2
5.7
8.2
6.1
6.2
5.0
1.2
7.2
6.4
6.7
3.7
-1.1
4.4
Minimum= -3.2 -1.1
Maximum= 33.0 655.6
Average= 7.7 135.1
-------
Run 2 - THC Loadout
7:00 8:00 9:00 10:00 11:00 12:00
Time (24-hr clock)
Run 2 - THC Silo Storage
8:00 9:00 10:00 11:00
Time (24-hr clock)
12:00
-------
Plant C
Run 3 Loadout
Date: 7/27/98
Project #4701-08-03-04
Operator: Gulick
TIME
THC Tunnel
ppm
THC Silo
ppm
710
711
712
713
714
715
716
717
718
719
720
721
722
723
725
726
727
728
729
730
731
732
733
734
735
736
737
741
742
743
744
745
746
747
748
7:10
7:11
7:12
7:13
7:14
7:15
7:16
7:17
7:18
7:19
7:20
7:21
7:22
7:23
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:41
7:42
7:43
7:44
7:45
7:46
7:47
7:48
7.9
6.3
8.7
6.9
7.8
5.6
4.3
3.7
3.2
3.0
2.9
6.0
4.3
3.1
2.2
2.2
2.0
1.9
1.8
1.8
1.8
1.7
1.8
2.0
1.9
1.8
2.0
7.5
6.3
4.0
3.1
3.0
6.5
5.1
6.3
7:10
7:11
7:12
7:13
7:14
7:15
7:16
7:17
7:18
7:19
7:20
7:21
7:22
7:23
7:25
7:26
7:27
7:28
7:29
7:30
7:31
7:32
7:33
7:34
7:35
7:36
7:37
7:41
7:42
7:43
7:44
7:45
7:46
7:47
7:48
999.5
999.5
856.4
999.5
999.5
999.5
999.5
999.5
999.5
999.5
999.5
999.5
999.5
811.9
548.2
388.9
263.2
999.5 = Off Scale
-------
749
750
751
752
753
754
755
756
757
758
759
800
801
802
803
804
805
806
807
808
809
810
811
812
813
814
815
816
817
818
819
820
821
822
823
824
825
826
827
828
829
830
831
832
833
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
7:57
7:58
7:59
8:00
8:01
8:02
8:03
8:04
8:05
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
8:33
7.4
6.4
5.0
4.4
4.0
3.9
6.0
6.7
6.3
8.4
5.7
4.5
3.8
5.4
7.1
8.0
5.8
7.8
6.4
4.3
3.5
3.1
4.6
8.1
5.5
12.1
7.9
7.4
8.6
8.9
7.7
6.6
9.3
10.1
10.1
7.7
10.5
9.9
10.7
8.7
8.7
8.6
9.0
11.0
11.8
7:49
7:50
7:51
7:52
7:53
7:54
7:55
7:56
7:57
7:58
7:59
8:00
8:01
8:02
8:03
8:04
8:05
8:06
8:07
8:08
8:09
8:10
8:11
8:12
8:13
8:14
8:15
8:16
8:17
8:18
8:19
8:20
8:21
8:22
8:23
8:24
8:25
8:26
8:27
8:28
8:29
8:30
8:31
8:32
8:33
52.5
49.5
45.5
42.2
39.6
37.6
34.9
35.2
61.0
105.2
167.0
235.9
301.3
355.7
393.7
419.8
448.1
466.0
487.8
505.9
518.6
532.2
532.6
524.7
538.5
532.6
542.7
545.4
552.0
553.9
556.5
561.7
563.1
589.8
618.6
634.8
658.4
686.2
738.8
752.5
776.0
797.0
807.4
816.0
-------
834
835
836
837
838
839
840
841
842
843
844
845
846
847
848
849
850
851
852
853
854
855
856
857
858
859
900
901
902
903
904
905
906
907
908
909
910
911
912
913
914
915
916
917
918
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:18
14.4
11.2
10.4
11.1
13.1
8.5
10.7
9.7
13.1
12.5
11.8
12.9
10.6
10.7
7.9
7.3
8.9
7.6
9.4
10.0
8.5
9.1
6.8
8.4
9.7
8.7
7.9
9.4
9.3
8.7
9.7
9.8
8.3
11.2
13.5
11.1
8.3
8.5
7.3
9.0
10.0
7.3
8.6
8.3
5.8
8:34
8:35
8:36
8:37
8:38
8:39
8:40
8:41
8:42
8:43
8:44
8:45
8:46
8:47
8:48
8:49
8:50
8:51
8:52
8:53
8:54
8:55
8:56
8:57
8:58
8:59
9:00
9:01
9:02
9:03
9:04
9:05
9:06
9:07
9:08
9:09
9:10
9:11
9:12
9:13
9:14
9:15
9:16
9:17
9:18
847.2
872.3
871.7
919.0
931.7
960.3
993.6
999.5
999.5
999.5
999.5
982.1
939.4
815.5
668.0
743.7
758.1
759.6
781.1
794.4
810.1
900.8
979.8
999.5
979.7
999.5
976.6
962.0
909.3
919.7
852.7
745.0
634.0
726.4
687.6
642.3
642.1
610.3
573.2
504.3
545.8
564.8
585.0
568.2
497.0
-------
919
920
921
922
923
924
925
926
927
928
929
930
931
932
933
934
935
936
937
938
939
940
941
942
943
944
945
947
948
949
950
951
952
953
954
955
956
957
958
959
1000
1001
1002
1003
9:19
9:20
9:21
9:22
9:23
9:24
9:25
9:26
9:27
9:28
9:29
9:30
9:31
9:32
9:33
9:34
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
9.6
9.3
6.6
7.2
5.6
6.2
6.6
6.0
5.0
4.6
6.4
5.7
8.2
5.7
5.7
7.3
5.8
7.7
7.1
11.7
6.8
7.2
6.0
4.7
4.2
5.6
7.5
6.0
7.8
6.2
6.6
5.4
4.4
4.0
5.4
5.9
6.0
6.1
5.5
5.9
9.4
10.1
10.9
6.7
9:19
9:20
9:21
9:22
9:23
9:24
9:25
9:26
9:27
9:28
9:29
9:30
9:31
9:32
9:33
9:34
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
503.3
601.4
651.2
710.8
722.4
720.5
672.0
653.6
632.6
554.0
559.7
530.3
-------
1004
1005
1006
1007
1008
1009
1010
1011
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
1027
1028
1029
1030
1031
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
1047
1048
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
5.8
9.0
7.9
8.8
8.7
9.1
8.6
8.7
9.1
7.5
8.9
7.1
7.1
7.1
6.7
8.0
7.7
6.3
4.9
5.2
5.7
6.6
7.9
5.6
7.0
6.6
7.0
8.4
8.2
8.0
10.4
8.3
9.4
14.6
13.4
13.5
15.8
9.3
12.6
8.7
6.8
6.0
10.4
8.7
12.3
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
603.4
619.9
570.4
522.9
526.6
512.5
568.3
526.1
560.2
559.1
524.7
486.9
516.0
522.2
505.5
518.0
493.9
463.6
505.2
521.8
503.7
455.1
486.5
473.6
475.0
488.1
496.3
477.9
455.6
525.3
514.2
533.4
543.4
549.3
541.9
494.1
578.8
508.5
571.6
-------
1049
1050
1051
1052
1053
1054
1055
1056
1057
1058
1059
1100
1101
1102
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1113
1114
1115
1116
1117
1118
1119
1120
1121
1122
1123
1124
1125
1126
1127
1128
1129
1130
1131
1132
1133
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
7.7
12.6
8.4
9.9
10.0
12.6
11.3
8.9
8.8
7.6
8.0
9.7
8.8
7.3
7.4
8.5
8.3
10.1
6.7
5.7
4.9
6.9
9.1
12.6
9.2
11.4
7.8
10.2
8.9
6.4
5.6
5.0
7.8
7.9
5.7
8.1
7.3
9.5
7.0
6.4
6.8
5.1
5.6
6.5
4.8
10:49
10:50
10:51
10:52
10:53
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:31
11:32
11:33
576.2
562.7
591.2
569.7
550.3
543.4
518.4
499.3
514.1
511.4
543.1
533.2
506.3
514.9
530.8
518.4
505.3
519.8
468.7
580.6
579.3
657.3
553.5
605.3
589.7
565.8
518.4
491.0
503.6
505.5
525.1
495.6
518.5
514.3
511.9
497.2
472.3
463.4
448.1
445.2
474.0
493.6
504.4
483.7
498.5
-------
1134
1135
1136
1137
1138
1139
1140
1141
1142
1143
1144
1145
1146
1147
1148
1149
1150
1151
1152
1153
1154
1155
1156
1157
1158
1159
1200
Minimum=
Maximum=
Average=
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
4.9
7.7
7.4
8.5
11.3
17.1
13.2
10.9
11.1
8.7
9.6
8.5
9.9
8.6
9.5
6.8
6.9
7.5
9.0
7.6
9.4
9.0
9.8
7.3
9.0
8.9
9.7
1.7
17.1
7.7
11:34
11:35
11:36
11:37
11:38
11:39
11:40
11:41
11:42
11:43
11:44
11:45
11:46
11:47
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
527.0
499.8
500.9
492.8
495.0
498.6
484.9
486.6
489.8
512.0
516.6
514.6
485.2
518.9
522.9
527.5
523.8
512.5
505.9
452.6
471.9
452.3
444.7
451.4
449.8
437.7
433.8
34.9
999.5
590.1
-------
o
Run 3 - THC Loadout
7:00 8:00 9:00 10:00 11:00
Time (24-hr clock)
12:00
Run 3 - THC Silo Storage
1200
1000
7:00 8:00 9:00 10:00 11:00
Time (24-hr clock)
12:00
-------
run4baseline
Plant C
Run 4 - Baseline
Date: 7/26/98
Project #4701-08-03-04
Operator: Gulick
TIME
24 hr
925
926
927
928
929
930
931
932
933
934
935
936
937
938
939
940
941
942
943
944
945
946
947
948
949
950
951
952
953
954
955
956
957
958
959
1000
1001
1002
1003
1004
THC Tunnel
9:25
9:26
9:27
9:28
9:29
9:30
9:31
9:32
9:33
9:34
9:35
9:36
9:37
9:38
9:39
9:40
9:41
9:42
9:43
9:44
9:45
9:46
9:47
9:48
9:49
9:50
9:51
9:52
9:53
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:04
ppm
1.1
1.1
1.1
1.1
1.1
1.0
1.0
1.0
0.9
1.0
0.9
1.0
0.9
0.9
0.9
0.9
0.9
0.9
0.9
0.8
0.8
0.8
0.7
0.8
0.8
0.8
0.9
0.8
0.8
0.8
0.7
0.8
0.8
0.8
0.7
0.8
0.7
0.8
0.8
0.8
Page 1
-------
run4baseline
1005
1006
1007
1008
1009
1010
1011
1012
1013
1014
1015
1016
1017
1018
1019
1020
1021
1022
1023
1024
1025
1026
1027
1028
1029
1030
1031
1032
1033
1034
1035
1036
1037
1038
1039
1040
1041
1042
1043
1044
1045
1046
1047
1048
1049
1050
1051
1052
1053
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:13
10:14
10:15
10:16
10:17
10:18
10:19
10:20
10:21
10:22
10:23
10:24
10:25
10:26
10:27
10:28
10:29
10:30
10:31
10:32
10:33
10:34
10:35
10:36
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
0.8
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.7
0.6
0.7
0.6
0.6
0.6
0.7
0.7
0.7
0.8
0.8
0.9
0.8
0.8
0.8
0.7
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
0.8
Page 2
-------
run4baseline
1054
1055
1056
1057
1058
1059
1100
1101
1102
1103
1104
1105
1106
1107
1108
1109
1110
1111
1112
1113
1114
1115
1116
1117
1118
1119
1120
1121
1122
1123
1124
1125
Cal Check
1148
1149
1150
1151
1152
1153
1154
1155
1156
1157
1158
1159
1200
1201
1202
1203
10:54
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:03
11:04
11:05
11:06
11:07
11:08
11:09
11:10
11:11
11:12
11:13
11:14
11:15
11:16
11:17
11:18
11:19
11:20
11:21
11:22
11:23
11:24
11:25
11:48
11:49
11:50
11:51
11:52
11:53
11:54
11:55
11:56
11:57
11:58
11:59
12:00
12:01
12:02
12:03
0.8
0.9
0.9
0.9
0.9
0.9
1.0
1.0
1.0
1.0
1.1
1.0
1.0
1.0
0.9
0.9
0.9
0.9
0.9
0.8
0.8
0.8
0.8
0.9
0.9
0.9
0.9
0.9
0.8
0.8 1st half
0.9 average=
0.9 0.83
1.2
1.2
1.3
1.3
1.3
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.4
1.5
1.5
PageS
-------
run4baseline
1204
1205
1206
1207
1208
1209
1210
1211
1212
1213
1214
1215
1216
1217
1218
1219
1220
1221
1222
1223
1224
1225
1226
1227
1228
1229
1230
1231
1232
1233
1234
1235
1236
1237
1238
1239
1240
1241
1242
1243
1244
1245
1246
1247
1248
1249
1250
1251
1252
12:04
12:05
12:06
12:07
12:08
12:09
12:10
12:11
12:12
12:13
12:14
12:15
12:16
12:17
12:18
12:19
12:20
12:21
12:22
12:23
12:24
12:25
12:26
12:27
12:28
12:29
12:30
12:31
12:32
12:33
12:34
12:35
12:36
12:37
12:38
12:39
12:40
12:41
12:42
12:43
12:44
12:45
12:46
12:47
12:48
12:49
12:50
12:51
12:52
1.5
1.5
1.5
1.6
1.5
1.5
1.5
1.5
1.5
1.6
1.6
1.7
1.7
1.7
1.6
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.7
1.7
1.7
1.8
1.7
1.8
1.8
1.8
1.7
1.8
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.7
1.7
1.8
1.8
1.7
1.7
Page 4
-------
run4baseline
1253
1254
1255
1256
1257
1258
1259
1300
1301
1302
1303
1304
1305
1306
1307
1308
1309
1310
1311
1312
1313
1314
1315
1316
1317
1318
1319
1320
1321
1322
1323
1324
1325
1326
1327
1328
1329
1330
1331
1332
1333
1334
1335
1336
1337
1338
1339
1340
1341
12:53
12:54
12:55
12:56
12:57
12:58
12:59
13:00
13:01
13:02
13:03
13:04
13:05
13:06
13:07
13:08
13:09
13:10
13:11
13:12
13:13
13:14
13:15
13:16
13:17
13:18
13:19
13:20
13:21
13:22
13:23
13:24
13:25
13:26
13:27
13:28
13:29
13:30
13:31
13:32
13:33
13:34
13:35
13:36
13:37
13:38
13:39
13:40
13:41
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.7
1.6
1.6
1.6
1.5
1.6
1.5
1.6
1.6
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.5
1.4
Page5
-------
run4baseline
1342
1343
1344
1345
13:42
13:43
13:44
13:45
1.4
1.5
1.4
1.4
2nd half
average=
1.60
Minimum=
Maximum=
Average=
0.6
1.8
1.2
Run 4 - THC Loadout (Bkgd)
9:00 10:00 11:00 12:00 13:00 14:00
Time (24-hr clock)
Page 6
-------
Plant C
InteFmittent Loading Test 1
Date: 7/25/98
Project # 4701-08-03-04
Operator: Gulick
IME THC Tunnel
ours
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
Min
42
42
42
42
43
43
43
43
43
43
44
44
44
44
44
44
45
45
45
45
45
45
46
46
46
46
46
46
47
47
47
47
47
47
47
48
48
Sec
24 13:42:24
34 13:42:34
44 13:42:44
54 13:42:54
4 13:43:04
14 13:43:14
24 13:43:24
34 13:43:34
44 13:43:44
54
4
14
24
34
44
54
4
14
24
34
44
54
4
14
24
34
44
54
4
14
24
34
39
13:43:54
13:44:04
13:44:14
13:44:24
13:44:34
13:44:44
13:44:54
13:45:04
13:45:14
13:45:24
13:45:34
13:45:44
13:45:54
13:46:04
13:46:14
13:46:24
13:46:34
13:46:44
13:46:54
13:47:04
13:47:14
13:47:24
13:47:34
13:47:39
44 13:47:44
54 13:47:54
4 13:48:04
14 13:48:14
ppm
6.8
6.7
6.5
6.2
5.9
5.7
5.6
5.5
5.3
5.3
6.7
7.0
6.6
7.5
8.1
7.5
7.4
8.8
8.1
7.7
8.9
8.2
7.5
6.9
6.5
6.2
6.1
5.9
5.7
5.6
5.5
5.4
5.3
5.2
5.1
5.1
4.9
°*™*™»>K»'»a^^
52.979 n
67.432
69.531
66.26
75.049
81 .299
75.049
74.17
87.939 I
81 .494 |
77.246
88.672
81 .738
74.902
68.945
64.941
62.061
60.742
58.936
56.934
55.908
54.59
26.782
1563.599 integral 1
-------
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
13
48
48
48
48
49
49
49
49
49
49
50
50
50
50
50
50
51
51
51
51
51
51
52
52
52
52
52
52
53
53
53
53
53
53
54
54
54
54
54
54
55
55
55
57
57
57
24 13:48:24
34 13:48:34
44 13:48:44
54 13:48:54
4 13:49:04
14 13:49:14
24 13:49:24
34 13:49:34
44 13:49:44
54 13:49:54
4 13:50:04
14 13:50:14
24 13:50:24
34 13:50:34
44 13:50:44
54 13:50:54
4 13:51:04
14 [13:51:14
24 1 13:51:24
34 113:51:34
44 j 13:51:44
54 113:51:54
4
14
24
34
44
54
13:52:04
13:52:14
13:52:24
13:52:34
13:52:44
13:52:54
4 ! 13:53:04
14
24
34
44
54
4
14
24
34
44
54
4
14
13:53:14
13:53:24
13:53:34
13:53:44
13:53:54
13:54:04
13:54:14
13:54:24
13:54:34
13:54:44
13:54:54
13:55:04
13:55:14
24 (13:55:24
21 13:57:21
31 13:57:31
41 13:57:41
4.9
4.8
4.7
4.7
4.7
4.6
4.5
4.5
4.4
4.4
4.4
4.4
4.3
4.3
4.3
4.2
4.2
4.2
10.1
12.8
13.0
12.8
12.9
13.2
14.5
14.2
14.1
14.8
13.4
5.7
6.3
7.3
7.1
7.9
6.9
6.4
6.0
5.7
5.5
5.4
5.2
5.0
4.8
4.2
3.9
3.9
41.602 j
100.635 j
128.418 |
130.127 |
128.125 |
128.906 j
131.836 |
144.922
141.797
141.406
148.145 |
134.18 |
57.178
62.744
72.803 |
70.947
79.102
69.336 |
63.818
59.863
56.641
55.029 i
54.248
52.148
50.244 I
2304.2 = Integral 2
-------
13
13
13
13
13
13
13
13
13
13
13
13
13
13
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
57
58
58
58
58
58
58
58
59
59
59
59
59
59
0
0
0
0
0
0
1
1
1
1
1
1
2
2
2
2
2
2
3
3
3
3
3
3
4
4
4
4
4
4
5
51 13:57:51
1 13:58:01
11 13:58:11
21 13:58:21
31 13:58:31
41 13:58:41
46 n^ss^e1
51 13:58:51
1
11
21
31
13:59:01
13:59:11
13:59:21
13:59:31
41 1 13:59:41
51 (13:59:51
1 ! 14:00:01
11 j 14:00:11
21
31
41
51
1
11
21
14:00:21
14:00:31
14:00:41
14:00:51
14:01:01
14:01:11
14:01:21
31 14:01:31
41 14:01:41
51
1
11
21
31
41
51
1
11
21
31
41
51
1
11
21
31
41
51
1
14:01:51
14:02:01
14:02:11
14:02:21
14:02:31
14:02:41
14:02:51
14:03:01
14:03:11
14:03:21
14:03:31
14:03:41
14:03:51
14:04:01
14:04:11
14:04:21
14:04:31
14:04:41
14:04:51
14:05:01
3.9
3.8
3.7
3.7
3.7
4.0
- ^ ^ .^,»
5.5
5.5
6.0
7.3
6.6
7.4
8.1
7.2
8.4
8.1
7.3
6.7
6.1
5.8
5.6
5.3
5.2
5.0
4.9
4.8
6.1
6.5
6.1
6.9
8.4
7.5
6.8
8.5
8.6
8.8
8.6
7.8
7.0
6.5
6.2
5.9
5.7
5.5
„_
54.883
55.029
60.498
73.145
65.82
73.584
80.713
71.631
83.887
80.957
73.193
66.504
60.742
57.764 |
56.055 I
53.467
51.514
50.098
49.121
__ 1242-605 = Integral 3
48.0471
61.279]
64.648
61.475
68.652
83.594
75
68.066
84.912
85.596
88.037
86.475
77.734
69.678
64.941
62.354
58.984!
56.592J
54.834!
-------
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
5
5
5
5
5
6
6
6
6
6
6
6
7
7
7
7
7
7
8
8
8
8
8
8
9
9
9
9
9
9
10
10
10
10
10
10
11
11
11
11
11
11
12
12
12
11 114:05:11
21 14:05:21
31 {14:05:31
41 ! 14:05:41
51 1 14:05:51
1 14:06:01
11 14:06:11
21 14:06:21
31 14:06:31
41 14:06:41
45 |1T06:45~
51 14:06:51
1 14:07:01
11 14:07:11
21 114:07:21
31 1 14:07:31
41 j 14:07:41
51 1 14:07:51
1 ! 14:08:01
5,
11 [14:08:11
21 114:08:21
31
41
51
1
11
14:08:31
14:08:41
14:08:51
14:09:01
14:09:11
21 14:09:21
31 14:09:31
41 ^4:09:41
51
1
11
21
31
41
14:09:51
14:10:01
14:10:11
14:10:21
14:10:31
14:10:41
51 14:10:51
1 114:11:01
11 14:11:11
21
31
41
51
1
14:11:21
14:11:31
14:11:41
14:11:51
14:12:01
I
21 14:12:21
5.3
5.1
5.0
4.9
4.8
4.7 """"-*""
4.5
4.5
4.4
4.6
" 5.0
5.7
5.7
5.5
6.4
6.4
7.3
8.4
8.1
8.9
7.7
6.7
6.2
5.9
5.7
5.5
5.4
5.2
5.1
5.0
7.1 ~"
11.2
12.7
10.6
9.1
8.1
7.3
6.8
6.6
6.4
6.1
5.8
5.6
5.5
5.3
Integral 4 =
30 "1
57.324 [
57.08 !
54.688 1
64.258 1
64.258 |
73.193 j
83.74 j
81.494 I
s
89.063 {
76.611 j
67.236 !
62.207 |
58.984 I
56.738 I
55.322 I
54.248 I
52.148 !
50.684 j
1189.276 integral 5 |
53.271 j
51.3181
50.049!
48.682J
1524.2181
50.098
70.752!
112.354:
126.758
106.006
90.723
80.908
72.51
68.359
65.527
63.574
60.84
58.203
56.396
55.029
52.734
-------
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
12
12
12
13
13
13
13
13
13
14
14
14
14
14
14
15
15
15
15
15
15
16
16
16
16
16
16
17
17
17
17
17
17
17
18
18
18
18
18
18
19
19
19
19
19
31 14:12:31
41 [14:12:41
51 14:12:51
1 14:13:01
11 14:13:11
21 14:13:21
31 14:13:31
41 14:13:41
51 14:13:51
1 14:14:01
11 14:14:11
21 14:14:21
31 14:14:31
41 14:14:41
51 14:14:51
1 14:15:01
11 14:15:11
21 14:15:21
31 14:15:31
41 14:15:41
51 14:15:51
1 14:16:01
11 14:16:11
21 14:16:21
31 14:16:31
41 14:16:41
51 14:16:51
1 14:17:01
7
11
21
31
14:17:07
14:17:11
14:17:21
14:17:31
41 1 14:17:41
51
1
11
21
31
41
51
1
11
21
31
41
14:17:51
14:18:01
14:18:11
14:18:21
14:18:31
14:18:41
14:18:51
14:19:01
14:19:11
14:19:21
14:19:31
14:19:41
5.2
5.0
4.9~*
4.8
4.8
4.6
4.5
4.5
4.4
4.3
4.3
4.2
4.1
4.1
4.0
4.1
4.0
4.0
4.0
3.9
3.9
3.8
3.8
3.8
3.7
3.7
3.6
3.7
5.0
6.0
10.3
12.5
9.9
8.4
7.3
6.7
6.3
5.9
5.7
5.4
5.2
5.0
5.9
9.7
12.5
51.758?
Integral 6 = 1242.529J
_-_~~--_-__-_
60.254
103.32 j
125.049
99.219
83.936
73.096
67.09
62.695
59.082
57.178
54.004
51 .709
916.632 = Integral^] 50
59.277
96.68
125.195
-------
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
19
20
20
20
20
20
20
21
21
21
21
21
21
22
22
22
22
22
22
23
23
23
23
23
23
24
24
24
24
24
24
25
25
25
25
25
25
25
26
26
26
26
26
26
27
27
51
1
11
21
31
41
51
1
11
21
31
41
51
1
11
21
31
41
51
1
11
21
31
41
51
1
11
21
31
41
51
1
11
21
31
41
51
57
1
11
21
31
41
51
1
11
114:19:51
J14:20:01
•14:20:11
[14:20:21
j 14:20:31
j 14:20:41
1 14:20:51
J14:21:01
j 14:21:1 1
14:21:21
114:21:31
114:21:41
J 14:21:51
1 14:22:01
(14:22:11
i14:22:21
j 14:22:31
j 14:22:41
M4:22:51
1 14:23:01
•14:23:11
1 14:23:21
[U:23:31_
14:23:41
14:23:51
14:24:01
14:24:11
14:24:21
14:24:31
14:24:41
14:24:51
14:25:01
14:25:11
14:25:21
14:25:31
14:25:41
14:25:51
1 14:25:57
j 14:26:01
14:26:11
14:26:21
14:26:31
1 14:26:41
[14:26:51
1 14:27:01
14:27:11
11.7
9.6
8.6
7.9
7.1
6.7
6.5
6.2
6.0
5.8
5.7
5.6
5.5
5.4
5.3
5.3
5.2
5.2
5.2
5.1
5.1
5.1
5.0
5.0
4.9
4.9
4.8
4.8
4.7
4.7
4.7
4.6
4.5
4.5
4.5
4.5
4.4
5.1
5.6
7.1
6.3
5.8
7.2
8.2
7.6
6.9
Integral 8 =
20.4
56.152
71.484
62.793
58.496
71.826
82.178
75.83
68.848
116.699}
96.436J
85.938J
78.662)
71.387J
66.797J
65.186J
61.768J
60.205
58.203
56.592
55.615
54.59
53.857
53.369
52.881 j
52.441 I
52.0511
51.807|
51.221J
50.977s
50.7811
1728.615
-------
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
27
27
27
27
28
28
28
28
28
28
28
29
29
29
29
29
29
30
30
30
37
37
38
38
38
38
38
38
39
39
39
39
39
39
40
40
40
40
40
40
41
41
41
41
41
21
31
41
51
1 J
11 j
21
26
31
41
51
1
11 I
21 I
31 j
41
51
1
11
21
45 '
55
5
15
25
35
45
55
5
15
OK
25
35
45
55
5
15
25
35
45
55
5
15
25
35
45
14:27:21
14:27:31
14:27:41
14:27:51
14:28:01
14:28:11
14:28:21
14:28:26
14:28:31
14:28:41
14:28:51
14:29:01
14:29:11
14:29:21
14:29:31
14:29:41
14:29:51
14:30:01
14:30:11
14:30:21
14:37:45
14:37:55
14:38:05
14:38:15
14:38:25
14:38:35
14:38:45
14:38:55
14:39:05
14:39:15
14:39:25
14:39:35
14:39:45
14:39:55
14:40:05
14:40:15
14:40:25
14:40:35
14:40:45
14:40:55
14:41:05
14:41:15
: 14:41:25
14:41:35
14:41:45
6.4
6.0
5.7
5.4
5.3
5.2
5.1
5.9
6.6
9.2
12.6
12.8
10.0
8.4
7.6
7.2
6.7
6.4
6.1
5.9
7.4
9.7
7.8
6.8
6.2
5.8
5.5
5.3
5.2
5.0
""" 4.8
5.3
7.2
9.2
8.5
7.6
7.0
6.3
6.0
5.7
5.5
5.3
5.2
5.0
4.9
64.258 !
60.303 |
56.982
54.199
53.467
52.197 j
25.2685 I
934.681 5 integral 9 j
Integal 10
iSW*v^^1*,^.^>*-rt^Kftt^»**^>SHJ«^«ftfl^^
!*&>!•& ^K^^
-------
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
41
42
42
42
42
42
42
43
43
43
43
43
43
43
44
44
44
44
44
44
45
45
45
45
45
45
46
55
5
15
25
35
45
55
5
15
20
25
35
45
55
5
15
25
35
45
14:41:55
"14:42:05"
14:42:15
14:42:25
14:42:35
14:42:45
14:42:55
14:43:05
14:43:15
14:43:20
14:43:25
14:43:35
14:43:45
14:43:55
14:44:05
14:44:15
14:44:25
1 14:44:35
; 14:44:45
55 [14:44:55
5
15
25
35
45
55
5
i 14:45:05
14:45:15
14:45:25
14:45:35
14:45:45
14:45:55
14:46:05
Minimum=
Maximum=
Average=
4.8
"~ 4.7 ~~
4.6
4.5
4.4
4.4
4.2
4.2
4.3
4.6
5.9
5.9
5.5
5.6
6.5
6.4
6.5
7.4
7.0
8.0
7.4
6.7
6.1
5.8
5.6
5.4
5.1
3.6
14.8
3.6
933.544 = Integral 11
_.,_»— —_-__«___.^
59.473 I
58.594 I
55.322 j
56.152 !
65.234 J
63.623 !
64.893 |
73.779 !
69.922
80.225 |
73.926 |
66.797
61.084
58.252
55.908
53.76
1039.944 integral 12
-------
-------
Appendix F
SF6 Capture and Loadout Summaries
MRJ-AEDXR4951-04-08 wpd
-------
-------
SF6 Concentration
x
w
o
Q)
to
3
s
Q.
O
H
3
CD
*M
Ol
NJ
00
N>
to
00
Ol
(O
ro
M
CO
en
Ol
to
ro
ro
en
NJ
[O
K)
N>
10
en
N)
-------
SFg Concentration
ro
en
Q>
o.
a
x_
(n
O
01
CO
-n
cn
o
03
a.
o
H
(D
o
(D
(A
!•»
ro
KJ
cn
to
to
oo
cn
Loadout (tons/load)
-------
SF6 Concentration
CO
Kb
01
CO
01
01
p
Kb
01
01
01
ro
O)
§
Q.
X.
CO
B-
0)
W
Tl
C3>
3
N>
Ol
Ol
O)
CO
ho
01
Ol
-01-
00
01
o
s
I
(Q
i
ro
O)
-------
SF( Concentration
ISi
55
x_
VI
o
Q)
CO
-n
en
D)
Q.
O
H
3
O
(D
&
W
*<
10
-I
CO
00
U1
Loadout (tons/load)
-------
Run 1 - Capture Efficiency LCL Calculations
SF6 Release Rates
Avg. Release Rate (LPM)
Gas SF6 concentration
Mass release rate (g/min)
Time of Release (min)
Mass released (g)
Capture Rates
Avg. Concentration (ppm)
Avg. Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Avg. Capture Efficiency
No. 1
4.07
0.0199
0.490
25
12.26
0.236
4.05E-05
11261
0.456
25
11.40
93.0
Run 1 - Statistical Calculations
LCL Subset No.
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
Average
Std. Dev.
n
t
LCL
CE
93.0
90.1
82.1
67.3
64.4
49.4
63.1
72.8
16.0011
7
1.440
64.058
No. 2
4.07
0.0199
0.490
23
11.28
0.228
3.92E-05 3.
11261
0.442
23
10.16
90.1
Time Interval
Start
8:30
8:55
11:00
11:23
11:48
12:12
12:37
No. 3
4.07
0.0199
0.490
23
11.28
0.208
58E-05
11261
0.403
23
9.26
82.1
(24-hr)
Stop
8:55
9:18
11:23
11:48
12:12
12:37
13:02
No. 4
4.07
0.0199
0.490
25
12.26
0.170
2.93E-05
11261
0.330
25
8.25
67.3
No. 5
4.07
0.0199
0.490
24
11.77
0.163
2.81 E-05
11261
0.316
24
7.58
64.4
No. 6
4.07
0.0199
0.490
25
12.26
0.125
2.15E-05
11261
0.242
25
6.05
49.4
No. 7
4.07
0.0199
0.490
25
12.26
0.160
2.75E-05
11261
0.310
25
7.74
63.1
AIINA
4.07
0.0199
0.490
7
3.43
0.202
3.47E-05
11261
0.391
7
2.74
79.7
-------
Run 2 - Capture Efficiency LCL Calculations
SF6 Release Rates
Avg. Release Rate (LPM)
Gas SF6 concentration
Mass release rate (g/min)
Time of Release (min)
Mass released (g)
Capture Rates
Avg. Concentration (ppm)
Avg. Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Avg. Capture Efficiency
Run 2 - Statistical Calculations
LCL Subset No.
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
No. 8
Average
Std. Dev.
n
t
LCL
No. 1
4.04
0.0199
0.487
23
11.20
0.203
3.50E-05
10922
0.382
23
8.78
78.5
IS
No. 2
4.04
0.0199
0.487
23
11.20
0.211
3.62E-05
10922
0.395
23
9.09
81.2
CE
78.5
81.2
82.3
71.0
53.7
65.0
73.9
59.4
70.6
10.4603
8
1.415
65.367
No. 3
4.04
0.0199
0.487
23
11.20
0.213
3.67E-05 3
10922
0.401
23
9.22
82.3
Time Interval
Start
7:13
7:36
7:59
8:22
9:31
9:58
10:24
10:49
No. 4
4.04
0.0199
0.487
23
11.20
0.184
.16E-05
10922
0.345
23
7.95
71.0
(24-hr)
Stop
7:36
7:59
8:22
8:45
9:58
10:24
10:49
11:14
No. 5
4.04
0.0199
0.487
27
13.14
0.139
2.39E-05
10922
0.261
27
7.06
53.7
No. 6
4.04
0.0199
0.487
26
12.66
0.168
2.89E-05
10922
0.316
26
8.22
65.0
No. 7
4.04
0.0199
0.487
25
12.17
0.192
3.29E-05
10922
0.360
25
8.99
73.9
No. 8
4.04
0.0199
0.487
25
12.17
0.154
2.65E-05
10922
0.289
25
7.22
59.4
-------
SF6 Release Rates
Avg. Release Rate (LPM)
Gas SF6 concentration
Mass release rate (g/min)
Time of Release (min)
Mass released (g)
Capture Rates
Avg. Concentration (ppm)
Avg. Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Avg. Capture Efficiency
Run 3 - Capture Efficiency LCL Calculations
No. 1
4.01
0.0200
0.486
25
12.14
0.208
3.58E-05
10832
0.388
25
9.69
No. 2
4.01
0.0200
0.486
23
11.17
0.202
3.48E-05
10832
0.377
23
8.67
No. 3
4.01
0.0200
0.486
23
11.17
0.170
2.92E-05
10832
0.316
23
7.27
No. 4
4.01
0.0200
0.486
23
11.17
0.207
3.56E-05
10832
0.385
23
8.87
No. 5
4.01
0.0200
0.486
23
11.17
0.138
2.38E-05
10832
0.258
23
5.92
No. 6
4.01
0.0200
0.486
22
10.68
0.130
2.24E-05
10832
0.242
22
5.33
No. 7
4.01
0.0200
0.486
21
10.20
0.120
2.06E-05
10832
0.224
21
4.70
No. 8
4.01
0.0200
0.486
22
10.68
0.145
2.49E-05
10832
0.270
22
5.94
No. 9
4.01
0.0200
0.486
21
10.20
0.131
2.25E-05
10832
0.243
21
5.11
No. 10
4.01
0.0200
0.486
23
11.17
0.124
2.13E-05
10832
0.230
23
5.30
79.8
77.6
65.1
79.4
53.0
49.9
46.1
55.6
50.1
47.4
Run 3 - Statistical Calculations
LCL Subset No.
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
No. 8
No. 9
No. 10
Average
Std. Dev.
n
t
LCL
Time Interval (24-hr)
CE
79.8
77.6
65.1
79.4
53.0
49.9
46.1
55.6
50.1
47.4
60.4
13.8381
10
1.383
54.356
Start
7:15
7:40
8:03
8:26
8:49
9:12
10:03
10:24
11:19
11:40
Stop
7:40
8:03
8:26
8:49
9:12
9:34
10:24
10:46
11:40
12:03
-------
Run 4 - Capture Efficiency LCL Calculations
SF6 Release Rates
Avg. Release Rate (LPM)
Gas SF6 concentration
Mass release rate (g/min)
Time of Release (min)
Mass released (g)
Capture Rates
Avg. Concentration (ppm)
Avg. Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Avg. Capture Efficiency
No. 1
4.11
0.0200
0.498
24
11.94
0.136
2.34E-05
11886
0.278
24
6.68
No. 2
4.11
0.0200
0.498
25
12.44
0.125
2.14E-05
11886
0.254
25
6.36
No. 3
4.11
0.0200
0.498
23
11.45
0.160
2.75E-05
11886
0.327
23
7.51
No. 4
4.11
0.0200
0.498
23
11.45
0.202
3.47E-05
11886
0.413
23
9.49
No. 5
4.11
0.0200
0.498
23
11.45
0.135
2.31 E-05
11886
0.275
23
6.32
No. 6
4.11
0.0200
0.498
25
12.44
0.168
2.88E-05
11886
0.342
25
8.56
No. 7
4.11
0.0200
0.498
23
11.45
0.093
1.60E-05
11886
0.190
23
4.36
No. 8
4.11
0.0200
0.498
23
11.45
0.125
2.15E-05
11886
0.255
23
5.87
No. 9
4.11
0.0200
0.498
23
11.45
0.057
9.80E-06
11886
0.116
23
2.68
No. 10
4.11
0.0200
0.498
23
11.45
0.080
1.38E-05
11886
0.163
23
3.76
55.9
51.1
65.6
82.9
55.2
68.8
38.1
51.3
23.4
32.8
Run 4 - Statistical Calculations
LCL Subset No.
No. 1
No. 2
No. 3
No. 4
No. 5
No. 6
No. 7
No. 8
No. 9
No. 10
Average
Std. Dev.
n
t
LCL
Time Interval (24-hr)
CE
55.9
51.1
65.6
82.9
55.2
68.8
38.1
51.3
23.4
32.8
52.5
17.7252
10
1.383
44.777
Start
9:31
9:55
10:20
10:43
11:06
11:50
12:15
12:38
13:01
13:24
Stop
9:55
10:20
10:43
11:06
11:29
12:15
12:38
13:01
13:24
13:47
-------
Run 1 - 7/24/98 (equal intervals)
SF6 Cone.
Subsample
NA
NA
No. 1
No. 2
NA
NA
NA
NA
NA
No. 3
Filename
17240026 ASF
17240027 ASF
17240039 ASF
17240040 ASF
17240041 ASF
17240042 ASF
17240043 ASF
17240044 ASF
17240045 ASF
17240046 ASF
17240047 ASF
17240048 ASF
17240049 ASF
17240050 ASF
17240051 ASF
17240052 ASF
17240053 ASF
17240054 ASF
17240055 ASF
17240056 ASF
17240057 ASF
17240058 ASF
17240059 ASF
17240060 ASF
17240061 ASF
17240062 ASF
17240063 ASF
17240064 ASF
17240065 ASF
17240070 ASF
17240071 ASF
17240072 ASF
17240073 ASF
17240074 ASF
17240122 ASF
17240123 ASF
17240124 ASF
17240125 ASF
17240126 ASF
17240127 ASF
17240128 ASF
17240129 ASF
17240130 ASF
17240131 ASF
17240132 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
(PST)
8:07
8:09
8:30
8:32
8:34
8:36
8:37
8:39
8:41
8:43
8:45
8:46
8:48
8:50
8:52
8:53
8:55
8:57
8:59
9:00
9:02
9:04
9:06
9:08
9:09
9:11
9:13
9:15
9:16
9:25
9:27
9:29
9:30
9:32
11:00
11:02
11:04
11:06
11:07
11:09
11:11
11:13
11:15
11:16
11:18
(ppm)
0.134
0.183
0.206
0.262
0.264
0.218
0.215
0.242
0.261
0.224
0.199
0.227
0.251
0.247
0.241
0.239
0.208
0.206
0.240
0.250
0.215
0.246
0.256
0.229
0.244
0.216
0.235
0.235
0.187
0.151
0.198
0.211
0.264
0.273
0.166
0.162
0.229
0.220
0.207
0.182
0.153
0.203
0.254
0.226
0.228
Subsample
Time & Avg.
Time (min)
25
Avg. (ppm)
0.236
Time (min)
23
Avg. (ppm)
0.228
Time (min)
23
-------
No. 4
No. 5
No. 6
No. 7
17240133 ASF
17240134 ASF
17240135 ASF
17240136 ASF
17240137 ASF
17240138 ASF
17240139 ASF
17240140 ASF
17240141 ASF
17240142 ASF
17240143 ASF
17240144 ASF
17240145 ASF
17240146 ASF
17240147 ASF
17240148 ASF
17240149 ASF
17240150 ASF
17240151 ASF
17240152 ASF
17240153 ASF
17240154 ASF
17240155 ASF
17240156 ASF
17240157 ASF
17240158 ASF
17240159 ASF
17240160 ASF
17240161 ASF
17240162 ASF
17240163 ASF
17240164 ASF
17240165 ASF
17240166 ASF
17240167 ASF
17240168 ASF
17240169 ASF
17240170 ASF
17240171 ASF
17240172 ASF
17240173 ASF
17240174 ASF
17240175 ASF
17240176 ASF
17240177 ASF
17240178 ASF
17240179 ASF
17240180 ASF
17240181 ASF
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
11:20
11:22
11:23
11:25
11:27
11:29
11:30
11:32
11:34
11:36
11:37
11:39
11:41
11:43
11:44
11:46
11:48
11:50
11:52
11:53
11:55
11:57
11:59
12:00
12:02
12:04
12:05
12:07
12:09
12:11
12:12
12:14
12:16
12:18
12:19
12:21
12:23
12:25
12:26
12:28
12:30
12:32
12:34
12:35
12:37
12:39
12:41
12:42
12:44
0.234
0.243
0.242
0.248
0.187
0.158
0.193
0.225
0.145
0.159
0.152
0.097
0.144
0.172
0.139
0.124
0.170
0.163
0.186
0.215
0.137
0.091
0.100
0.127
0.135
0.152
0.180
0.164
0.206
0.257
0.131
0.164
0.139
0.104
0.135
0.159
0.129
0.089
0.139
0.117
0.092
0.128
0.135
0.092
0.159
0.151
0.182
0.175
0.146
Avg. (ppm)
0.208
Time (min)
25
Avg. (ppm)
0.170
Time (min)
24
Avg. (ppm)
0.163
Time (min)
25
Avg. (ppm)
0.125
-------
17240182 ASF
17240183 ASF
17240184 ASF
17240185 ASF
17240186 ASF
17240187 ASF
17240188 ASF
17240189 ASF
All NA'S
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
12:46
12:48
12:49
12:51
12:53
12:55
12:56
12:58
13:02
0.168
0.165
0.123
0.183
0.166
0.137
0.123
0.203
Time (min)
25
Avg. (ppm)
0.160
Time (min)
7
Avg (ppm)
0.202
-------
725lc!
Run 2 - 7/25/98
Subsample
No. 1
No. 2
No. 3
No. 4
Filename
17250001 ASF
17250002 ASF
17250003 ASF
17250004 ASF
17250005 ASF
17250006 ASF
17250007 ASF
17250008 ASF
17250009 ASF
17250010 ASF
17250011 ASF
17250012 ASF
17250013 ASF
17250014 ASF
17250015 ASF
17250016 ASF
17250017 ASF
17250018 ASF
17250019 ASF
17250020 ASF
17250021 ASF
17250022 ASF
17250023 ASF
17250024 ASF
17250025 ASF
17250026 ASF
17250027 ASF
17250028 ASF
17250029 ASF
17250030 ASF
17250031 ASF
17250032 ASF
17250033 ASF
17250034 ASF
17250035 ASF
17250036 ASF
17250037 ASF
17250038 ASF
17250039 ASF
17250040 ASF
17250041 ASF
17250042 ASF
17250043 ASF
17250044 ASF
Date
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
Time (PST)
7:13
7:15
7:17
7:19
7:20
7:22
7:24
7:26
7:28
7:29
7:31
7:33
7:35
7:36
7:38
7:40
7:42
7:43
7:45
7:47
7:49
7:50
7:52
7:54
7:56
7:58
7:59
8:01
8:03
8:05
8:06
8:08
8:10
8:12
8:13
8:15
8:17
8:19
8:21
8:22
8:24
8:26
8:28
8:29
SF6 Cone,
(ppm)
0.176
0.194
0.206
0.193
0.269
0.272
0.234
0.236
0.168
0.161
0.148
0.156
0.231
0.181
0.199
0.217
0.228
0.227
0.231
0.213
0.199
0.218
0.188
0.222
0.199
0.213
0.197
0.174
0.143
0.131
0.221
0.238
0.220
0.223
0.281
0.260
0.250
0.216
0.219
0.204
0.231
0.175
0.197
0.133
. Subsample
Time & Avg.
Time (min)
23
Avg. (ppm)
0.203
Time (min)
23
Avg. (ppm)
0.211
Time (min)
23
Avg. (ppm)
0.213
Prepared by MRI 2/4/00
Pagel
-------
725lcl
Run 2 - 7/25/98
Subsample
No. 5
No. 6
No. 7
Filename
17250045 ASF
17250046 ASF
17250047 ASF
17250048 ASF
17250049 ASF
17250050 ASF
17250051 ASF
17250052 ASF
17250077 ASF
17250078 ASF
17250079 ASF
17250080 ASF
17250081 ASF
17250082 ASF
17250083 ASF
17250084 ASF
17250085 ASF
17250086 ASF
17250087 ASF
17250088 ASF
17250089 ASF
17250090 ASF
17250091 ASF
17250092 ASF
17250093 ASF
17250094 ASF
17250095 ASF
17250096 ASF
17250097 ASF
17250098 ASF
17250099 ASF
17250100 ASF
17250101 ASF
17250102 ASF
17250103 ASF
17250104 ASF
17250105 ASF
17250106 ASF
17250107 ASF
17250108 ASF
17250109 ASF
17250110 ASF
17250111 ASF
17250112 ASF
Date Time
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
(PST)
8:31
8:33
8:35
8:36
8:38
8:40
8:42
8:44
9:31
9:33
9:35
9:36
9:38
9:40
9:42
9:44
9:45
9:47
9:49
9:51
9:52
9:54
9:56
9:58
10:00
10:01
10:03
10:05
10:07
10:08
10:10
10:12
10:14
10:15
10:17
10:19
10:21
10:23
10:24
10:26
10:28
10:30
10:31
10:33
SF6 Cone.
(ppm)
0.107
0.106
0.188
0.197
0.193
0.214
0.232
0.216
0.188
0.169
0.170
0.132
0.114
0.147
0.116
0.101
0.161
0.183
0.158
0.098
0.099
0.103
0.151
0.166
0.199
0.174
0.137
0.172
0.193
0.152
0.137
0.165
0.156
0.160
0.204
0.156
0.168
0.185
0.207
0.151
0.106
0.149
0.238
0.263
Subsample
Time & Avg.
Time (min)
23
Avg. (pprn)
0.184
Time (min)
27
Avg. (ppm)
0.139
Time (min)
26
Avg. (ppm)
0.168
Prepared by MRI 2/4/00
Page 2
-------
725lcl
Run 2 - 7/25/98
SF6 Cone.
Subsample Filename
17250113 ASF
17250114 ASF
17250115 ASF
17250116 ASF
17250117 ASF
17250118 ASF
17250119 ASF
172501 20 ASF
No. 8 17250121 ASF
17250122 ASF
17250123 ASF
17250124 ASF
17250125 ASF
17250126 ASF
17250127 ASF
17250128 ASF
17250129 ASF
17250130 ASF
17250131 ASF
17250132 ASF
17250133 ASF
17250134 ASF
Date Time
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
(PST)
10:35
10:37
10:38
10:40
10:42
10:44
10:45
10:47
10:49
10:51
10:53
10:54
10:56
10:58
11:00
11:01
11:03
11:05
11:07
11:08
11:10
11:12
(ppm)
0.277
0.200
0.189
0.179
0.161
0.178
0.190
0.193
0.135
0.167
0.178
0.127
0.140
0.136
0.149
0.142
0.179
0.134
0.171
0.118
0.167
0.213
Subsample
Time & Avg.
Time (min)
25
Avg. (ppm)
0.191
Time (min)
25
Avg. (ppm)
0.154
Prepared by MRI 2/4/00
PageS
-------
727lcl
Run 3 - 7/27/98
Subsample
No. 1
No. 2
No. 3
No. 4
Filename
17270005 ASF
17270006 ASF
17270007 ASF
17270008 ASF
17270009 ASF
17270010 ASF
17270011 ASF
17270012 ASF
17270013 ASF
17270014 ASF
17270015 ASF
17270016 ASF
17270017 ASF
17270018 ASF
17270019 ASF
17270020 ASF
17270021 ASF
17270022 ASF
17270023 ASF
17270024 ASF
17270025 ASF
17270026 ASF
17270027 ASF
17270028 ASF
17270029 ASF
17270030 ASF
17270031 ASF
17270032 ASF
17270033 ASF
17270034 ASF
17270035 ASF
17270036 ASF
17270037 ASF
17270038 ASF
17270039 ASF
17270040 ASF
17270041 ASF
17270042 ASF
17270043 ASF
17270044 ASF
17270045 ASF
17270046 ASF
17270047 ASF
17270048 ASF
Date Time
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
(PST)
7:15
7:17
7:18
7:20
7:22
7:24
7:25
7:27
7:29
7:31
7:33
7:34
7:36
7:38
7:40
7:42
7:43
7:45
7:47
7:49
7:50
7:52
7:54
7:56
7:58
7:59
8:01
8:03
8:05
8:06
8:08
8:10
8:12
8:14
8:15
8:17
8:19
8:21
8:22
8:24
8:26
8:28
8:29
8:31
SF6 Cone.
(ppm)
0.206
0.226
0.253
0.240
0.211
0.201
0.206
0.205
0.218
0.209
0.203
0.197
0.193
0.147
0.165
0.237
0.204
0.190
0.184
0.221
0.191
0.208
0.277
0.267
0.200
0.166
0.122
0.119
0.159
0.157
0.196
0.206
0.200
0.172
0.190
0.158
0.144
0.138
0.190
0.178
0.179
0.182
0.181
0.166
Subsample
Time & Avg.
Time (min)
25
Avg. (ppm)
0.208
Time (min)
23
Avg. (ppm)
0.202
Time (min)
23
Avg. (ppm)
0.170
Prepared by MRI 2/4/00
Page 1
-------
727lcl
Run 3 - 7/27/98
SF6 Cone. Subsample
Subsample
No. 5
No. 6
No. 7
Filename
17270049 ASF
17270050 ASF
17270051 ASF
17270052 ASF
17270053 ASF
17270054 ASF
17270055 ASF
17270056 ASF
17270057 ASF
17270058 ASF
17270059 ASF
17270060 ASF
17270061 ASF
17270062 ASF
17270063 ASF
17270064 ASF
17270065 ASF
17270066 ASF
17270067 ASF
17270068 ASF
17270069 ASF
17270070 ASF
17270071 ASF
17270072 ASF
17270073 ASF
17270074 ASF
17270075 ASF
17270076 ASF
17270077 ASF
17270078 ASF
17270079 ASF
17270080 ASF
17270081 ASF
17270082 ASF
17270091 ASF
17270092 ASF
17270093 ASF
17270094 ASF
17270095 ASF
17270096 ASF
17270097 ASF
17270098 ASF
17270099 ASF
17270100 ASF
Date
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
Time (PST)
8:33
8:35
8:37
8:38
8:40
8:42
8:44
8:45
8:47
8:49
8:51
8:53
8:54
8:56
8:58
9:00
9:01
9:03
9:05
9:07
9:09
9:10
9:12
9:14
9:16
9:17
9:19
9:21
9:23
9:25
9:26
9:28
9:30
9:32
10:03
10:05
10:06
10:08
10:10
10:12
10:14
10:15
10:17
10:19
(ppm)
0.235
0.221
0.225
0.205
0.201
0.213
0.255
0.241
0.188
0.164
0.150
0.135
0.137
0.120
0.128
0.151
0.174
0.149
0.160
0.112
0.117
0.102
0.109
0.131
0.132
0.141
0.175
0.155
0.101
0.090
0.170
0.132
0.108
0.118
0.107
0.121
0.120
0.164
0.132
0.115
0.112
0.112
0.115
0.116
Time & Avg.
Time (min)
23
Avg. (ppm)
0.207
Time (min)
23
Avg. (ppm)
0.138
Time (min)
22
Avg. (ppm)
0.130
Time (min)
21
Prepared by MRI 2/4/00
Page 2
-------
727lcl
Run 3 - 7/27/98
SF6 Cone.
Subsample
No. 8
No. 9
No. 10
Filename
17270101 ASF
17270102 ASF
17270103 ASF
17270104 ASF
17270105 ASF
17270106 ASF
17270107 ASF
17270108 ASF
17270109 ASF
17270110 ASF
17270111 ASF
17270112 ASF
17270113 ASF
17270114 ASF
17270116 ASF
17270117 ASF
17270118 ASF
17270119 ASF
17270120 ASF
17270121 ASF
17270122 ASF
17270123 ASF
17270124 ASF
17270125 ASF
17270126 ASF
17270127 ASF
17270128 ASF
17270129 ASF
17270130 ASF
17270131 ASF
17270132 ASF
17270133 ASF
17270134 ASF
17270135 ASF
17270136 ASF
17270137 ASF
17270138 ASF
17270139 ASF
17270140 ASF
Date Time
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
(PST)
10:21
10:22
10:24
10:26
10:28
10:30
10:31
10:33
10:35
10:37
10:38
10:40
10:42
10:44
11:19
11:21
11:22
11:24
11:26
11:28
11:30
11:31
11:33
11:35
11:37
11:38
11:40
11:42
11:44
11:45
11:47
11:49
11:51
11:53
11:54
11:56
11:58
12:00
12:01
(ppm)
0.143
0.084
0.099
0.116
0.098
0.121
0.105
0.140
0.181
0.214
0.235
0.202
0.135
0.092
0.101
0.112
0.158
0.142
0.191
0.135
0.096
0.089
0.107
0.144
0.149
0.143
0.125
0.114
0.153
0.121
0.117
0.104
0.087
0.124
0.139
0.133
0.127
0.149
0.115
Subsample
Time & Avg.
Avg. (ppm)
0.120
Time (min)
22
Avg. (ppm)
0.145
Time (min)
21
Avg. (ppm)
0.131
Time (min)
23
Avg. (ppm)
0.124
Prepared by MRI 2/4/00
PageS
-------
726ICI
Run 4 - 7/26/98
SF6 Cone.
Subsample
No. 1
No. 2
No. 3
No. 4
Filename
17260004 ASF
17260005 ASF
17260006 ASF
17260007 ASF
17260008 ASF
17260009 ASF
17260010 ASF
17260011 ASF
17260012 ASF
17260013 ASF
17260014 ASF
17260015 ASF
17260016 ASF
17260017 ASF
17260018 ASF
17260019 ASF
17260020 ASF
17260021 ASF
17260022 ASF
17260023 ASF
17260024 ASF
17260025 ASF
17260026 ASF
17260027 ASF
17260028 ASF
17260029 ASF
17260030 ASF
17260031 ASF
17260032 ASF
17260033 ASF
17260034 ASF
17260035 ASF
17260036 ASF
17260037 ASF
17260038 ASF
17260039 ASF
17260040 ASF
17260041 ASF
17260042 ASF
17260043 ASF
17260044 ASF
17260045 ASF
17260046 ASF
17260047 ASF
Date Time
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
(PST)
9:31
9:32
9:34
9:36
9:38
9:39
9:41
9:43
9:45
9:46
9:48
9:50
9:52
9:54
9:55
9:57
9:59
10:01
10:02
10:04
10:06
10:08
10:09
10:11
10:13
10:15
10:17
10:18
10:20
10:22
10:24
10:25
10:27
10:29
10:31
10:33
10:34
10:36
10:38
10:40
10:41
10:43
10:45
10:47
(ppm)
0.134
0.160
0.164
0.103
0.144
0.152
0.156
0.176
0.147
0.108
0.108
0.103
0.107
0.147
0.136
0.075
0.103
0.096
0.093
0.101
0.088
0.127
0.115
0.125
0.176
0.175
0.182
0.151
0.172
0.184
0.146
0.169
0.148
0.175
0.160
0.122
0.170
0.225
0.148
0.114
0.144
0.106
0.156
0.211
Subsample
Time & Avg.
Time (min)
24
Avg. (ppm)
0.136
Time (min)
25
Avg. (ppm)
0.124
Time (min)
23
Avg. (ppm)
0.160
1 3 2/8/00 11:29 AM 726lcl 726lcl
-------
726lcl
SF6 Cone.
17260048 ASF
17260049 ASF
17260050 ASF
17260051 ASF
17260052 ASF
17260053 ASF
17260054 ASF
17260055 ASF
17260056 ASF
17260057 ASF
No. 5 17260058 ASF
17260059 ASF
17260060 ASF
17260061 ASF
17260062 ASF
17260063 ASF
17260064 ASF
17260065 ASF
17260066 ASF
17260067 ASF
17260068 ASF
17260069 ASF
17260070 ASF
No. 6 17260071 ASF
17260072 ASF
17260073 ASF
17260074 ASF
17260075 ASF
17260076 ASF
17260077 ASF
17260078 ASF
17260079 ASF
17260080 ASF
17260081 ASF
17260082 ASF
17260083 ASF
17260084 ASF
No. 7 17260085 ASF
17260086 ASF
17260087 ASF
17260088 ASF
17260089 ASF
17260090 ASF
17260091 ASF
17260092 ASF
17260093 ASF
17260094 ASF
17260095 ASF
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
10:49
10:50
10:52
10:54
10:56
10:57
10:59
11:01
11:03
11:04
11:06
11:08
11:10
11:11
11:13
11:15
11:17
11:19
11:20
11:22
11:24
11:26
11:27
11:50
11:52
11:54
11:56
11:57
11:59
12:01
12:03
12:05
12:06
12:08
12:10
12:12
12:13
12:15
12:17
12:19
12:21
12:22
12:24
12:26
12:28
12:29
12:31
12:33
0.149
0.190
0.218
0.229
0.202
0.234
0.229
0.257
0.234
0.211
0.195
0.129
0.186
0.173
0.175
0.178
0.157
0.074
0.089
0.124
0.107
0.089
0.072
0.179
0.180
0.153
0.125
0.125
0.165
0.199
0.219
0.185
0.189
0.148
0.162
0.164
0.154
0.133
0.142
0.077
0.085
0.114
0.145
0.107
0.107
0.077
0.096
0.062
Subsample
Time (min)
23
Avg. (ppm)
0.202
Time (min)
23
Avg. (ppm)
0.135
Time (min)
25
Avg. (ppm)
0.168
Time (min)
23
2 3 2/8/00 11:29 AM 726lcl 726lcl
-------
726lcl
SF6 Cone
17260096 ASF
17260097 ASF
No. 8 17260098 ASF
17260099 ASF
17260100 ASF
17260101 ASF
17260102 ASF
17260103 ASF
17260104 ASF
17260105 ASF
17260106 ASF
17260107 ASF
17260108 ASF
17260109 ASF
17260110 ASF
No. 9 17260111 ASF
17260112 ASF
17260113 ASF
17260114 ASF
17260115 ASF
17260116 ASF
17260117 ASF
17260118 ASF
17260119 ASF
17260120 ASF
17260121 ASF
17260122 ASF
17260123 ASF
No. 10 17260124 ASF
17260125 ASF
17260126 ASF
17260127 ASF
17260128 ASF
17260129 ASF
17260130 ASF
17260131 ASF
17260132 ASF
17260133 ASF
17260134 ASF
17260135 ASF
17260136 ASF
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
12:35
12:36
12:38
12:40
12:42
12:43
12:45
12:47
12:49
12:50
12:52
12:54
12:56
12:58
12:59
13:01
13:03
13:05
13:06
13:08
13:10
13:12
13:14
13:15
13:17
13:19
13:21
13:22
13:24
13:26
13:28
13:30
13:31
13:33
13:35
13:37
13:38
13:40
13:42
13:44
13:45
0.000
0.060
0.137
0.074
0.085
0.169
0.130
0.083
0.119
.0.132
0.100
0.156
0.144
0.145
0.150
0.081
0.099
0.093
0.086
0.095
0.049
0.061
0.000
0.000
0.000
0.047
0.069
0.062
0.093
0.070
0.069
0.059
0.053
0.052
0.068
0.073
0.109
0.082
0.072
0.131
0.108
Subsample
Avg. (ppm)
0.093
Time (min)
23
Avg. (ppm)
0.125
Time (min)
23
Avg. (ppm)
0.057
Time (min)
23
Avg. (ppm)
0.080
3 3 2/8/00 11:29 AM 726lcl 726lcl
-------
724lcl
File list for 7/24/98 - Run 1 Loadout and Silo
Filename
17240001 ASF
17240002 ASF
17240003 ASF
17240004 ASF
17240005 ASF
17240006 ASF
17240007 ASF
17240008 ASF
17240009 ASF
17240010 ASF
17240011 ASF
17240012 ASF
17240013 ASF
17240014 ASF
17240015 ASF
17240016 ASF
17240017 ASF
17240018 ASF
17240019 ASF
17240020 ASF
17240021 ASF
17240022 ASF
17240023 ASF
17240024 ASF
17240025 ASF
17240026 ASF
17240027 ASF
17240028 ASF
17240029 ASF
. 17240030 ASF
17240031 ASF
17240032 ASF
17240033 ASF
17240034 ASF
17240035 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
SF6 Cone.
(PST) (ppm)
7:22
7:24
7:26
7:28
7:30
7:32
7:34
7:35
7:37
7:38
7:39
7:41
7:42
7:43
7:44
7:45
7:46
7:48
7:49
7:50
7:51
7:52
7:53
7:55
7:56
7:57
7:58
7:59
8:00
8:02
8:04
8:05
8:07 0.134
8:09 0.183
8:11
8:12
8:13
8:14
8:15
8:16
8:18
8:20
8:21
8:23
Load Out
(tons) Comments
Silo Exhaust Duct (SED)
being monitored by FTIR,
capture data not usable.
20.89
21.45
21.20
21.34
20.83
21.39
20.10
21.04
4.03
21.19
21.12
3.99
21.27
21.12
21.17 Usable data.
21.25
Silo 1 being used
21.39 sporadically, capture data
not usable.
21.16
21.40
1 6 3/10/00 10:38 AM 724lcl 724 All
-------
724lcl
Filename
17240036 ASF
17240037 ASF
17240038 ASF
17240039 ASF
17240040 ASF
17240041 ASF
17240042 ASF
17240043 ASF
17240044 ASF
17240045 ASF
17240046 ASF
17240047 ASF
17240048 ASF
17240049 ASF
17240050 ASF
17240051 ASF
17240052 ASF
17240053 ASF
17240054 ASF
17240055 ASF
17240056 ASF
17240057 ASF
17240058 ASF
17240059 ASF
17240060 ASF
17240061 ASF
17240062 ASF
17240063 ASF
17240064 ASF
17240065 ASF
17240066 ASF
17240067 ASF
17240068 ASF
17240069 ASF
17240070 ASF
17240071 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/93
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
(PST)
8:24
8:25
8:27
8:28
8:30
8:32
8:33
8:34
8:36
8:37
8:38
8:39
8:41
8:43
8:45
8:46
8:46
8:48
8:49
8:50
8:52
8:53
8:54
8:55
8:57
8:59
9:00
9:02
9:03
9:04
9:05
9:06
9:08
9:09
9:10
9:11
9:12
9:13
9:15
9:16
9:18
9:20
9:21
9:22
9:24
9:25
9:27
SF6 Cone.
(ppm)
0.206
0.262
0.264
0.218
0.215
0.242
0.261
0.224
0.199
0.227
0.251
0.247
0.241
0.239
0.208
0.206
0.240
0.250
0.215
0.246
0.256 •
0.229
0.244
0.216
0.235
0.235
0.187
0.151
0.198
Load Out
(tons)
20.91
2.54
21.22
21.43
21.20
21.22
21.36
21.35
21.05
20.94
21.38
21.33
21.12
21.04
21.17
21.26
20.88
19.91
21.22
21.10
21.04
21.10
21.58
21.27
Comments
Usable data.
Gate open on truck; 2 tons
spilled in tunnel.
THC spike gas run through
sample lines, capture data
not usable.
Spill cleaned up in tunnel
Usable data.
2 6 3/10/00 10:38 AM 724lcl 724 All
-------
724lcl
Filename
17240072 ASF
17240073 ASF
17240074 ASF
17240075 ASF
17240076 ASF
17240077 ASF
17240078 ASF
17240079 ASF
17240080 ASF
17240081 ASF
17240082 ASF
17240083 ASF
17240084 ASF
17240085 ASF
17240086 ASF
17240087 ASF
17240088 ASF
17240089 ASF
17240090 ASF
17240091 ASF
17240092 ASF
17240093 ASF
17240094 ASF
17240095 ASF
17240096 ASF
17240097 ASF
17240098 ASF
17240099 ASF
17240100 ASF
17240101 ASF
17240102 ASF
17240103 ASF
17240104 ASF
17240105 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
SF6 Cone.
(PST) (ppm)
9:28
9:29 0.211
9:30 0.264
9:32 0.273
9:33
9:34
9:37
9:38
9:39
9:41
9:42
9:43
9:44
9:45
9:46
9:48
9:49
9:50
9:52
9:53
9:55
9:57
9:58
9:59
10:00
10:02
10:04
10:05
10:06
10:07
10:08
10:09
10:11
10:13
10:14
10:15
10:16
10:18
10:20
10:22
10:23
10:25
10:27
10:28
10:29
10:30
10:31
Load Out
(tons)
21.46
21.44
21.42
21.36
21.20
21.06
7.00
21.13
20.88
21.34
21.20
21.53
21.52
21.29
21.60
20.94
21.27
21.22
20.96
21.44
21.06
21.50
20.43
21.41
Comments
Silo Exhaust Duct (SED)
being monitored by FTIR,
capture data not usable.
3 6 3/10/00 10:38 AM 724lcl 724 All
-------
724lcl
Filename
17240106 ASF
17240107 ASF
17240108 ASF
17240109 ASF
17240110 ASF
17240111 ASF
17240112 ASF
17240113 ASF
17240114 ASF
17240115 ASF
17240116 ASF
17240117 ASF
17240118 ASF
17240119 ASF
17240120 ASF
17240121 ASF
17240122 ASF
17240123 ASF
17240124 ASF
17240125 ASF
17240126 ASF
17240127 ASF
17240128 ASF
17240129 ASF
17240130 ASF
17240131 ASF
17240132 ASF
17240133 ASF
17240134 ASF
17240135 ASF
17240136 ASF
17240137 ASF
17240138 ASF
17240139 ASF
17240140 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
(PST)
10:32
10:33
10:34
10:35
10:36
10:38
10:39
10:40
10:41
10:43
10:45
10:46
10:48
10:50
10:52
10:53
10:55
10:56
10:57
10:58
10:59
11:00
11:01
11:02
11:04
11:06
11:07
11:09
11:10
11:11
11:12
11:13
11:15
11:16
11:17
11:18
11:20
11:22
11:23
11:24
11:25
11:26
11:27
11:28
11:29
11:30
11:32
SF6 Cone.
(ppm)
0.166
0.162
0.229
0.220
0.207
0.182
0.153
0.203
0.254
0.226
0.228
0.234
0.243
0.242
0.248
0.187
0.158
0.193
0.225
Load Out
(tons) Comments
21.29
21.08
21.39
21.33
21.14
21.45
21.25
21.26
21.40
21.40
21.07
21.51 Usable data.
21.33
21.29
21.34
21.42
21.30
21.29
21.40
21.45
20.78
21.43
21.32
4 6 3/10/00 10:38 AM 724lcl 724 All
-------
724lcl
Filename
17240141 ASF
17240142 ASF
17240143 ASF
17240144 ASF
17240145 ASF
17240146 ASF
17240147 ASF
17240148 ASF
17240149 ASF
17240150 ASF
17240151 ASF
17240152 ASF
17240153 ASF
17240154 ASF
17240155 ASF
17240156 ASF
17240157 ASF
17240158 ASF
17240159 ASF
17240160 ASF
17240161 ASF
17240162 ASF
17240163 ASF
17240164 ASF
17240165 ASF
17240166 ASF
17240167 ASF
17240168 ASF
17240169 ASF
17240170 ASF
17240171 ASF
17240172 ASF
17240173 ASF
17240174 ASF
17240175 ASF
17240176 ASF
17240177 ASF
17240178 ASF
Date Time
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
(PST)
1 1 :33
11:34
11:36
11:37
1 1 :38
11:39
11:41
11:43
11:44
11:45
11:46
11:48
11:50
11:52
11:53
11:55
11:57
11:59
12:00
12:02
12:04
12:05
12:07
12:09
12:10
12:11
12:12
12:14
12:15
12:16
12:17
12:18
12:19
12:21
12:22
12:23
12:25
12:26
12:28
12:30
12:32
12:34
12:35
12:36
12:37
12:38
12:39
SF6 Cone.
(ppm)
0.145
0.159
0.152
0.097
0.144
0.172
0.139
0.124
0.170
0.163
0.186
0.215
0.137
0.091
0.100
0.127
0.135
0.152
0.180
0.164
0.206
0.257
0.131
0.164
0.139
0.104
0.135
0.159
0.129
0.089
0.139
0.117
0.092
0.128
0.135
0.092
0.159
0.151
Load Out
(tons) Comments
21.35
21.19
21.12
21.14
24.84
21.17
20.12
21.34
21.06
21.15
21.31
21.35
21.22
21.32
21.22
21.02
23.99
21.29
21.00
21.47
21.46
21.33
20.40
21.73
21.28
5 6 3/10/00 10:38 AM 724lcl 724 All
-------
724lcl
SF6 Cone. Load Out
Filename Date Time (PST)
12:40
17240179 ASF 7/24/98 12:41
17240180 ASF 7/24/98 12:42
17240181 ASF 7/24/98 12:44
17240182 ASF 7/24/98 12:46
172401 83 ASF 7/24/98 12:48
1 7240 1 84 ASF 7/24/98 1 2:49
17240185 ASF 7/24/98 12:51
17240186 ASF 7/24/98 12:53
12:54
17240187 ASF 7/24/98 12:55
17240188 ASF 7/24/98 12:56
17240189 ASF 7/24/98 12:58
13:02
Average Concentration (ppm)
Maximum Concentration (ppm)
Minimum Concentration (ppm)
Average Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Loadout during capture tests (tons/hr)
Loadout during all testing (tons/hr)
(ppm)
0.182
0.175
0.146
0.168
0.165
0.123
0.183
0.166
0.137
0.123
0.203
0.185
0.273
0.089
3.17E-05
11,261
0.357
173
61.8
(tons) Comments
21.16
21.39
20.33
21.57
21.25
21.20
21.17
21.31
21.19
478.05
453.17
6 6 3/10/00 10:38 AM 724lcl 724 All
-------
725lcl
File list for 7/25/98 - Run 2 Loadout and Silo
Filename
17250001 ASF
17250002 ASF
17250003 ASF
17250004 ASF
17250005 ASF
17250006 ASF
17250007 ASF
17250008 ASF
17250009 ASF
17250010 ASF
17250011 ASF
17250012 ASF
17250013 ASF
17250014 ASF
17250015 ASF
17250016 ASF
17250017 ASF
17250018 ASF
17250019 ASF
17250020 ASF
17250021 ASF
17250022 ASF
17250023 ASF
17250024 ASF
17250025 ASF
17250026 ASF
17250027 ASF
17250028 ASF
17250029 ASF
17250030 ASF
17250031 ASF
SF6 Cone.
Date Time (PST) (ppm)
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7:02
7:04
7:08
7:09
7:12
7:13
7:15
7:17
7:19
7:20
7:22
7:23
7:24
7:25
7:26
7:28
7:29
7:31
7:32
7:33
7:35
7:36
7:38
7:40
7:42
7:43
7:44
7:45
7:47
7:48
7:49
7:50
7:51
7:52
7:54
7:55
7:56
7:57
7:58
7:59
8:01
8:03
8:05
8:06
0.176
0.194
0.206
0.193
0.269
0.272
0.234
0.236
0.168
0.161
0.148
0.156
0.231
0.181
0.199
0.217
0.228
0.227
0.231
0.213
0.199
0.218
0.188
0.222
0.199
0.213
0.197
0.174
0.143
0.131
0.221
Load Out
(tons) Comments
21.12
21.43
21.24
21.02
Usable data.
20.92
23.87
23.65
21.21
23.93
21.09
24.43
20.59
23.24
20.64
24.47
21.26
24.52
21.32
21.26
19.73
1 5 2/10/00 11:52 AM 725lcl 725 All
-------
725lcl
SF6 Cone.
Filename
17250032 ASF
17250033 ASF
17250034 ASF
17250035 ASF
17250036 ASF
17250037 ASF
17250038 ASF
17250039 ASF
17250040 ASF
17250041 ASF
17250042 ASF
17250043 ASF
17250044 ASF
17250045 ASF
17250046 ASF
17250047 ASF
17250048 ASF
17250049 ASF
17250050 ASF
17250051 ASF
17250052 ASF
17250053 ASF
17250054 ASF
17250055 ASF
17250056 ASF
17250057 ASF
17250058 ASF
17250059 ASF
17250060 ASF
17250061 ASF
17250062 ASF
17250063 ASF
17250064 ASF
17250065 ASF
17250066 ASF
Date Time
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
(PST)
8:07
8:08
8:10
8:12
8:13
8:14
8:15
8:17
8:19
8:20
8:21
8:22
8:24
8:25
8:26
8:28
8:29
8:30
8:31
8:32
8:33
8:34
8:35
8:36
8:38
8:39
8:40
8:42
8:44
8:45
8:46
8:47
8:48
8:49
8:51
8:52
8:54
8:56
8:58
8:59
9:00
9:01
9:02
9:03
9:05
9:06
9:08
(ppm)
0.238
0.220
0.223
0.281
0.260
0.250
0.216
0.219
0.204
0.231
0.175
0.197
0.133
0.107
0.106
0.188
0.197
0.193
0.214
0.232
0.216
Load Out
(tons) Comments
21.05
21.45
21.31
24.65
24.48
21.13
24.03
21.50
21.16
21.27
21.25
24.45
21.26
21.30
SED being monitored by
23.21 FTIR, capture data not
usable.
21.00
24.47
21.18
23.80
21.00
20.80
21.18
2 5 2/10/00 11:52 AM 725lcl 725 All
-------
725ICI
SF6 Cone.
Filename
17250067 ASF
17250068 ASF
17250069 ASF
17250070 ASF
17250071 ASF
17250072 ASF
17250073 ASF
17250074 ASF
17250075 ASF
17250076 ASF
17250077 ASF
17250078 ASF
17250079 ASF
17250080 ASF
17250081 ASF
17250082 ASF
17250083 ASF
17250084 ASF
17250085 ASF
17250086 ASF
17250087 ASF
17250088 ASF
17250089 ASF
17250090 ASF
17250091 ASF
17250092 ASF
17250093 ASF
17250094 ASF
17250095 ASF
17250096 ASF
17250097 ASF
17250098 ASF
17250099 ASF
17250100 ASF
17250101 ASF
17250102 ASF
Date Time
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
(PST)
9:10
9:12
9:13
9:15
9:17
9:18
9:19
9:20
9:21
9:22
9:24
9:26
9:28
9:31
9:33
9:35
9:36
9:38
9:40
9:41
9:42
9:44
9:45
9:47
9:48
9:49
9:51
9:52
9:54
9:55
9:56
9:57
9:58
9:59
10:00
10:01
10:02
10:03
10:05
10:06
10:07
10:08
10:09
10:10
10:12
10:14
10:15
(ppm)
0.188
0.169
0.170
0.132
0.114
0.147
0.116
0.101
0.161
0.183
0.158
0.098
0.099
0.103
0.151
0.166
0.199
0.174
0.137
0.172
0.193
0.152
0.137
0.165
0.156
0.160
Load Out
(tons) Comments
23.67
20.89
20.87
21.02
12.00
2101
24.19
20.93
20.94 Usable data.
8.00
21.10
23.87
15.03
24.58
21.17
23.58
20.86
22.79
20.70
24.19
21.06
23.54
3 5 2/10/00 11:52 AM 725lcl 725 All
-------
725lcl
SF6 Cone. Load Out
Filename
17250103 ASF
17250104 ASF
17250105 ASF
17250106 ASF
17250107 ASF
17250108 ASF
17250109 ASF
17250110 ASF
17250111 ASF
17250112 ASF
17250113 ASF
17250114 ASF
17250115 ASF
17250116 ASF
17250117 ASF
17250118 ASF
17250119 ASF
17250120 ASF
17250121 ASF
17250122 ASF
17250123 ASF
17250124 ASF
17250125 ASF
17250126 ASF
17250127 ASF
17250128 ASF
17250129 ASF
17250130 ASF
17250131 ASF
17250132 ASF
17250133 ASF
17250134 ASF
Date Time
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
7/25/98
(PST)
10:16
10:17
10:19
10:21
10:23
10:24
10:26
10:28
10:30
10:31
10:32
10:33
10:35
10:37
10:38
10:39
10:40
10:41
10:42
10:43
10:44
10:45
10:46
10:47
10:48
10:49
10:50
10:51
10:52
10:53
10:54
10:56
10:58
11:00
11:01
11:03
11:04
11:05
11:07
11:08
11:10
11:12
Average Concentration (ppm)
Maximum Concentration (ppm)
Minimum Concentration (ppm)
Average Concentration (g/ft3)
(ppm)
0.204
0.156
0.168
0.185
0.207
0.151
0.106
0.149
0.238
0.263
0.277
0.200
0.189
0.179
0.161
0.178
0.190
0.193
0.135
0.167
0.178
0.127
0.140
0.136
0.149
0.142
0.179
0.134
0.171
0.118
0.167
0.213
0.182
0.281
0.098
3.13E-05
(tons) Comments
6.18
24.06
20.91
21.06
20.79
21.03
21.00
20.90
20.80
20.87
20.91
20.91
21.07
21.13
4 5 2/10/00 11:52 AM 725lcl 725 All
-------
725lcl
SF6 Cone. Load Out
Filename Date Time (PST) (ppm) (tons) Comments
Stack Gas Flowrate (acfm) 10,922
Capture Rate (g/min) 0.341
Sampling Time (min) 192
Total Capture (g) 65.6
Loadout during capture tests (tons/hr) 391.41
Loadout during all testing (tons/hr) 399.72
5 5 2/10/00 11:52 AM 725lcl 725 All
-------
727ICI
File list for 7/27/98 - Run 3 Loadout and Silo
Filename
17270001 ASF
17270002 ASF
17270003 ASF
17270004 ASF
17270005 ASF
17270006 ASF
17270007 ASF
17270008 ASF
17270009 ASF
17270010 ASF
17270011 ASF
17270012 ASF
17270013 ASF
17270014 ASF
17270015 ASF
17270016 ASF
17270017 ASF
17270018 ASF
17270019 ASF
17270020 ASF
17270021 ASF
17270022 ASF
17270023 ASF
17270024 ASF
17270025 ASF
17270026 ASF
17270027 ASF
17270028 ASF
17270029 ASF
17270030 ASF
17270031 ASF
17270032 ASF
17270033 ASF
17270034 ASF
17270035 ASF
17270036 ASF
17270037 ASF
17270038 ASF
17270039 ASF
SF6 Cone. Load Out
Date Time (PST) (ppm) (tons) Comments
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7:08
7:09
7:11
7:13
7:15
7:17
7:18
7:20
7:22
7:24
7:25
7:27
7:29
7:31
7:33
7:34
7:36
7:37
7:38
7:39
7:40
7:42
7:43
7:44
7:45
7:47
7:49
7:50
7:52
7:54
7:56
7:58
7:59
8:01
8:02
8:03
8:04
8:05
8:06
8:08
8:10
8:12
8:14
8:15
8:16
0.206
0.226
0.253
0.240
0.211
0.201
0.206
0.205
0.218
0.209
0.203
0.197
0.193
0.147
0.165
0.237
0.204
0.190
0.184
0.221
0.191
0.208
0.277
0.267
0.200
0.166
0.122
0.119
0.159
0.157
0.196
0.206
0.200
0.172
0.190
21.13
23.06
Usable data.
21.28
24.33
25.65
24.80
24.66
25.28
25.21
24.38
20.95
25.70
27.84
21.40
24.25
25.16
1 5 2/10/00 12:00 PM 727lcl 727 All
-------
727lcl
Filename
17270040 ASF
17270041 ASF
17270042 ASF
17270043 ASF
17270044 ASF
17270045 ASF
17270046 ASF
17270047 ASF
17270048 ASF
17270049 ASF
17270050 ASF
17270051 ASF
17270052 ASF
17270053 ASF
17270054 ASF
17270055 ASF
17270056 ASF
17270057 ASF
17270058 ASF
17270059 ASF
17270060 ASF
17270061 ASF
17270062 ASF
17270063 ASF
17270064 ASF
17270065 ASF
17270066 ASF
17270067 ASF
17270068 ASF
17270069 ASF
17270070 ASF
17270071 ASF
17270072 ASF
17270073 ASF
17270074 ASF
SF6 Cone.
Date Time (PST) (ppm)
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
8:17
8:19
8:21
8:22
8:23
8:24
8:25
8:26
8:28
8:29
8:30
8:31
8:32
8:33
8:34
8:35
8:37
8:38
8:40
8:41
8:42
8:43
8:44
8:45
8:47
8:48
8:49
8:51
8:53
8:54
8:55
8:56
8:58
9:00
9:01
9:02
9:03
9:04
9:05
9:07
9:08
9:09
9:10
9:12
9:14
9:16
9:17
0.158
0.144
0.138
0.190
0.178
0.179
0.182
0.181
0.166
0.235
0.221
0.225
0.205
0.201
0.213
0.255
0.241
0.188
0.164
0.150
0.135
0.137
0.120
0.128
0.151
0.174
0.149
0.160
0.112
0.117
0.102
0.109
0.131
0.132
0.141
Load Out
(tons) Comments
25.56
24.04
21.38
24.23
25.71
26.16
24.72
21.37
25.66
21.18
26.16
25.40
21.36
21.30
25.84
25.96
21.12
21.33
26.13
24.45
24.45
21.31
20.44
24.61
26.01
24.10
21.28
23.19
25.55
24.46
21.28
21.37
25.64
2 5 2/10/00 12:00 PM 727lcl 727 All
-------
727lcl
SF6 Cone.
Filename
17270075 ASF
17270076 ASF
17270077 ASF
17270078 ASF
17270079 ASF
17270080 ASF
17270081 ASF
17270082 ASF
17270083 ASF
1 7270084 ASF
17270085 ASF
1 7270086 ASF
17270087 ASF
1 7270088 ASF
17270089 ASF
17270090 ASF
17270091 ASF
17270092 ASF
17270093 ASF
17270094 ASF
17270095 ASF
17270096 ASF
17270097 ASF
17270098 ASF
17270099 ASF
17270100 ASF
17270101 ASF
17270102 ASF
17270103 ASF
Date Time
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
(PST)
9:19
9:21
9:23
9:25
9:26
9:27
9:28
9:29
9:30
9:32
9:33
9:34
9:35
9:37
9:38
9:39
9:43
9:45
9:47
9:52
9:54
9:56
9:57
9:58
9:59
10:00
10:01
10:03
10:04
10:05
10:06
10:07
10:08
10:09
10:10
10:11
10:12
10:14
10:15
10:16
10:17
10:19
10:20
10:21
10:22
10:23
10:24
(PPm)
0.175
0.155
0.101
0.090
0.170
0.132
0.108
0.118
0.107
0.121
0.120
0.164
0.132
0.115
0.112
0.112
0.115
0.116
0.143
0.084
0.099
Load Out
(tons) Comments
25.13
24.44
25.54
21.36
25.71
Instrument off-line for
27.74 manual method port change,
21 .49 capture data not usable.
24.79
24.51
25.72
25.18
25.88
26.39
8.02
21.26
21.07
Usable data.
26.08
25.78
24.42
24.33
25.93
25.22
24.78
25.86
24.52
21.25
3 5 2/10/00 12:00 PM 727lcl 727 All
-------
727lcl
SF6 Cone.
Filename
17270104 ASF
17270105 ASF
17270106 ASF
17270107 ASF
17270108 ASF
17270109 ASF
17270110 ASF
17270111 ASF
17270112 ASF
17270113 ASF
17270114 ASF
17270115 ASF
17270116 ASF
17270117 ASF
17270118 ASF
17270119 ASF
17270120 ASF
17270121 ASF
17270122 ASF
17270123 ASF
17270124 ASF
17270125 ASF
Date Time
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
(PST)
10:25
10:26
10:27
10:28
10:30
10:31
10:32
10:33
10:34
10:35
10:37
10:38
10:39
10:40
10:42
10:43
10:44
10:45
10:47
10:50
10:51
10:52
10:56
10:57
11:00
11:01
11:03
11:08
11:09
11:11
11:13
11:17
11:18
11:19
11:21
11:22
11:23
11:24
11:25
11:26
11:28
11:29
11:30
11:31
11:33
1 1 :34
11:35
(ppm)
0.116
0.098
0.121
0.105
0.140
0.181
0.214
0.235
0.202
0.135
0.092
0.101
0.112
0.158
0.142
0.191
0.135
0.096
0.089
0.107
0.144
Load Out
(tons) Comments
25.72
26.14
20.98
21.35
26.10
21.25
21.29
21.40
25.70
25.28
21.39 SED being monitored by
21.38 FTIR (grab samples),
25.76 capture data not usable.
21.21
21.44
25.52
21.61
25.58
20.87
21.30
25.74
21.45
22.47
27.91
Usable data.
23.26
25.22
25.78
24.53
25.92
25.79
24.91
4 5 2/10/00 12:00 PM 727lcl 727 All
-------
727lcl
SF6 Cone. Load Out
Filename Date Time (PST)
11:36
17270126 ASF 7/27/98 11:37
17270127 ASF 7/27/98 11:38
11:39
1 72701 28 ASF 7/27/98 1 1 :40
11:41
1 72701 29 ASF 7/27/98 1 1 :42
11:43
1 7270 1 30 ASF 7/27/98 1 1 :44
17270131 ASF 7/27/98 11:45
172701 32 ASF 7/27/98 11:47
11:48
172701 33 ASF 7/27/98 11:49
11:50
172701 34 ASF 7/27/98 11:51
11:52
172701 35 ASF 7/27/98 11:53
172701 36 ASF 7/27/98 11:54
11:55
17270137 ASF 7/27/98 11:56
172701 38 ASF 7/27/98 11:58
17270139 ASF 7/27/98 12:00
17270140 ASF 7/27/98 12:01
Average Concentration (ppm)
Maximum Concentration (ppm)
Minimum Concentration (ppm)
Average Concentration (g/ft3)
Stack Gas Flowrate (acfm)
Capture Rate (g/min)
Sampling Time (min)
Total Capture (g)
Loadout during capture tests (tons/hr)
Loadout during all testing (tons/hr)
(ppm)
0.149
0.143
0.125
0.114
0.153
0.121
0.117
0.104
0.087
0.124
0.139
0.133
0.127
0.149
0.115
0.159
0.277094
0.0843839
2.73E-05
10,832
0.296
217
64.2
(tons) Comments
24.56
26.60
26.14
25.67
26.10
24.49
25.96
25.46
24.81
21.08
24.64
722.69
573.38
5 5 2/10/00 12:00 PM 727lcl 727 All
-------
-------
726ICI
File list for 7/26/98 - Run 4 (Background) Loadout
Filename
17260001 ASF
17260002 ASF
17260003 ASF
17260004 ASF
17260005 ASF
17260006 ASF
17260007 ASF
17260008 ASF
17260009 ASF
17260010 ASF
17260011 ASF
17260012 ASF
17260013 ASF
17260014 ASF
17260015 ASF
17260016 ASF
17260017 ASF
17260018 ASF
17260019 ASF
17260020 ASF
17260021 ASF
17260022 ASF
17260023 ASF
17260024 ASF
17260025 ASF
17260026 ASF
17260027 ASF
17260028 ASF
17260029 ASF
17260030 ASF
17260031 ASF
17260032 ASF
17260033 ASF
17260034 ASF
17260035 ASF
17260036 ASF
17260037 ASF
17260038 ASF
17260039 ASF
17260040 ASF
17260041 ASF
17260042 ASF
17260043 ASF
17260044 ASF
Date Time
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
SF6 Cone.
(PST (ppm) Comments
9:25
9:27
9:29
9:31
9:32
9:34
9:36
9:38
9:39
9:41
9:43
9:45
9:46
9:48
9:50
9:52
9:54
9:55
9:57
9:59
10:01
10:02
10:04
10:06
10:08
10:09
10:11
10:13
10:15
10:17
10:18
10:20
10:22
10:24
10:25
10:27
10:29
10:31
10:33
10:34
10:36
10:38
10:40
10:41
0.134
0.160
0.164
0.103
0.144
0.152
0.156
0.176
0.147
0.108
0.108
0.103
0.107
0.147
0.136
0.075
0.103
0.096
0.093
0.101
0.088
0.127
0.115
0.125
0.176
0.175
0.182
0.151
0.172
0.184
0.146
0.169
0.148
0.175
0.160
0.122
0.170
0.225
0.148
0.114
0.144
1 4 2/10/00 12:04 PM 726lcl 726
-------
726lcl
Filename
17260045 ASF
17260046 ASF
17260047 ASF
17260048 ASF
17260049 ASF
17260050 ASF
17260051 ASF
17260052 ASF
17260053 ASF
17260054 ASF
17260055 ASF
17260056 ASF
17260057 ASF
17260058 ASF
17260059 ASF
17260060 ASF
17260061 ASF
17260062 ASF
17260063 ASF
17260064 ASF
17260065 ASF
17260066 ASF
17260067 ASF
17260068 ASF
17260069 ASF
17260070 ASF
17260071 ASF
17260072 ASF
17260073 ASF
17260074 ASF
17260075 ASF
17260076 ASF
17260077 ASF
17260078 ASF
17260079 ASF
17260080 ASF
17260081 ASF
17260082 ASF
17260083 ASF
17260084 ASF
17260085 ASF
17260086 ASF
17260087 ASF
17260088 ASF
17260089 ASF
17260090 ASF
17260091 ASF
SF6 Cone.
Date Time (PST (ppm) Comments
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
10:43
10:45
10:47
10:49
10:50
10:52
10:54
10:56
10:57
10:59
11:01
11:03
11:04
11:06
11:08
11:10
11:11
11:13
11:15
11:17
11:19
11:20
11:22
11:24
11:26
11:27
1 1 :50
11:52
11:54
11:56
11:57
11:59
12:01
12:03
12:05
12:06
12:08
12:10
12:12
12:13
12:15
12:17
12:19
12:21
12:22
12:24
12:26
0.106
0.156
0.211
0.149
0.190
0.218
0.229
0.202
0.234
0.229
0.257
0.234
0.211
0.195
0.129
0.186
0.173
0.175
0.178
0.157
0.074
0.089
0.124
0.107
0.089
0.072
0.179
0.180
0.153
0.125
0.125
0.165
0.199
0.219
0.185
0.189
0.148
0.162
0.164
0.154
0.133
0.142
0.077
0.085
0.114
0.145
0.107
2 4 2/10/00 12:04 PM 726lcl 726
-------
726lcl
Filename
17260092 ASF
17260093 ASF
17260094 ASF
17260095 ASF
17260096 ASF
17260097 ASF
17260098 ASF
17260099 ASF
17260100 ASF
17260101 ASF
17260102 ASF
17260103 ASF
17260104 ASF
17260105 ASF
17260106 ASF
17260107 ASF
17260108 ASF
17260109 ASF
17260110 ASF
17260111 ASF
17260112 ASF
17260113 ASF
17260114 ASF
17260115 ASF
17260116 ASF
17260117 ASF
17260118 ASF
17260119 ASF
17260120 ASF
17260121 ASF
17260122 ASF
17260123 ASF
17260124 ASF
17260125 ASF
17260126 ASF
17260127 ASF
17260128 ASF
17260129 ASF
17260130 ASF
17260131 ASF
17260132 ASF
17260133 ASF
17260134 ASF
17260135 ASF
17260136 ASF
SF6 Cone.
Date Time(PST (ppm) Comments
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
7/26/98
12:28
12:29
12:31
12:33
12:35
12:36
12:38
12:40
12:42
12:43
12:45
12:47
12:49
12:50
12:52
12:54
12:56
12:58
12:59
13:01
13:03
13:05
13:06
13:08
13:10
13:12
13:14
13:15
13:17
13:19
13:21
13:22
13:24
13:26
13:28
13:30
13:31
13:33
13:35
13:37
13:38
13:40
13:42
13:44
13:45
Average Concentration (ppm)
0.107
0.077
0.096
0.062
0.000
0.060
0.137
0.074
0.085
0.169
0.130
0.083
0.119
0.132
0.100
0.156
0.144
0.145
0.150
0.081
0.099
0.093
0.086
0.095
0.049
0.061
0.000
0.000
0.000
0.047
0.069
0.062
0.093
0.070
0.069
0.059
0.053
0.052
0.068
0.073
0.109
0.082
0.072
0.131
0.108
0.128
3 4 2/10/00 12:04 PM 726lcl 726
-------
726lcl
SF6 Cone.
Filename Date Time (PST (ppm) Comments
Maximum Concentration (ppm) 0.257
Minimum Concentration (ppm) 0.000
Average Concentration (g/ft3) 2.21 E-05
Stack Gas Flowrate (acfm) 11,886
Capture Rate (g/min) 0.262
Sampling Time (min) 254
Total Capture (g) 66.6
4 4 2/10/00 12:04 PM 726lcl 726
-------
-------
Appendix G
SF6 Gas Release Data
MRI-AED\R4951 -04-08.wpd
-------
-------
LRunl
SF6 Gas Delivery Data Spreadsheet
Loadout Run 1 Date: 7/24/98
Time
8:05:00
8:06:00
8:07:00
8:08:00
8:13:30
8:14:00
8:15:00
8:16:00
8:16:30
8:26:30
8:27:00
8:28:00
8:29:00
8:30:00
8:31:00
8:32:00
8:33:00
8:34:00
8:35:00
8:36:00
8:37:00
8:38:00
8:39:00
8:40:00
8:41:00
8:42:00
8:43:00
8:44:00
8:45:00
8:46:00
8:47:00
8:48:00
8:48:30
8:49:00
8:50:00
8:51:00
8:52:00
8:53:00
8:54:00
8:55:00
8:56:00
8:57:00
8:58:00
8:59:00
Silo No. Flow
2
2
2
2
2
2
2
3
3
3
2
2
3
3
3
2
2
2
2
2
2
2
2
3
2
2
2
3
3
3
2
2
2
2
2
4
3
3
4
4
4
4
Rate (LPM) Comments Liters
4.06 Usable data
4.03
4.00
Stop Gas Release
4.07 Resume Gas Release
4.05
4.03 Silo 1 being used sporadically;
4.00 data not usable.
Stop Gas Release
4.14 Resume Gas Release
4.13
4.10
4.00
4.03 Usable data
4.08
4.10
4.11
4.03
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.10
4.03
4.04
4.04
4.10
4.11
4.11
4.03
4.04
4.04
4.04
4.04
4.10
4.08
4.10
4.08
4.08
4.09
4.09
4.06
4.03
4.00
4.03
4.08
4.10
4.11
4.03
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.10
4.03
4.04
4.04
4.10
4.11
2.05
2.01
4.04
4.04
4.04
4.04
4.10
4.08
4.10
4.08
4.08
4.09
4.09
1 5 1/11/99 2:59 PM Sf6rel-1.xls LRunl
-------
LRunl
Time
9:00:00
9:01:00
9:02:00
9:03:00
9:04:00
9:05:00
9:06:00
9:07:00
9:08:00
9:09:00
9:10:00
9:11:00
9:12:00
9:13:00
9:14:00
9:15:00
9:16:00
9:17:00
9:18:00
9:19:00
9:20:00
9:21:00
9:22:00
9:23:00
9:24:00
9:25:00
9:26:00
9:27:00
9:28:00
9:29:00
9:30:00
9:31:00
9:32:00
9:33:00
9:34:00
9:35:00
10:57:00
10:58:00
10:59:00
11:00:00
11:01:00
1 1 :02:00
11:03:00
11:04:00
1 1 :05:00
1 1 :06:00
1 1 :07:00
11:08:00
Silo No.
2
2
2
2
2
3
2
2
2
2
2
2
2
2
2
3
3
4
4
4
4
4
2
3
2
2
2
2
2
2
2
2
2
2
2
5
5
3
3
4
5
5
5
5
5
5
5
Flow Rate (LPM)
4.00
4.02
4.02
4.02
4.02
4.09
4.03
4.02
4.02
4.02
4.03
4.03
4.02
4.02
4.09
4.09
4.10
4.12
4.13
4.14
4.14
4.14
4.04
4.10
4.03
4.05
4.04
4.05
4.04
4.03
4.03
4.03
4.04
4.03
4.03
4.08
4.05
4.03
4.03
4.07
4.04
4.04
4.05
4.05
4.05
4.05
4.05
Comments Liters
4.00
4.02
4.02
4.02
4.02
4.09
4.03
4.02
4.02
4.02
4.03
4.03
4.02
4.02
4.09
4.09
4.10
THC spike gas run through
sample lines; capture data
not usable.
Usable data. 4.05
4.04
4.05
4.04
4.03
4.03
4.03
4.04
SED being monitored by FTIR;
capture data not usable.
Stop Gas Release
Resume Gas Release
Usable data. 4.03
4.07
4.04
4.04
4.05
4.05
4.05
4.05
4.05
2 5 1/11/99 2:59 PM Sf6rel~1.xls LRunl
-------
LRunl
Time
11:09:00
11:10:00
11:11:00
11:12:00
11:13:00
11:14:00
11:15:00
11:16:00
11:17:00
11:18:00
11:19:00
11:20:00
11:21:00
11:22:00
11:23:00
1 1 :24:00
11:25:00
11:26:00
11:27:00
11:28:00
1 1 :29:00
11:30:00
11:31:00
11:32:00
11:33:00
11:34:00
1 1 :35:00
11:36:00
11:37:00
11:38:00
11:39:00
1 1 :40:00
1 1 :41 :00
11:42:00
11:43:00
11:44:00
11:45:00
11:46:00
11:47:00
11:48:00
11:49:00
11:50:00
11:51:00
1 1 :52:00
1 1 :53:00
1 1 :54:00
1 1 :55:00
11:56:00
Silo No.
5
4
3
3
3
3
3
4
4
4
3
3
3
4
4
4
4
4
3
3
2
2
2
2
2
2
3
3
3
3
2
2
3
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Flow Rate (LPM) Comments
4.05
4.07
4.04
4.05
4.05
4.05
4.05
4.05
4.06
4.06
4.04
4.05
4.04
4.04
4.05
4.05
4.05
4.05
4.03
4.03
3.95
3.98
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.02
3.98
3.99
4.02
4.00
4.00
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
4.00
4.00
4.00
4.00
Liters
4.05
4.07
4.04
4.05
4.05
4.05
4.05
4.05
4.06
4.06
4.04
4.05
4.04
4.04
4.05
4.05
4.05
4.05
4.03
4.03
3.95
3.98
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.02
3.98
3.99
4.02
4.00
4.00
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
4.00
4.00
4.00
4.00
3 5 1/11/99 2:59 PM SfBreM .xls LRunl
-------
LRunl
Time
1 1 :57:00
11:58:00
11:59:00
12:00:00
12:01:00
12:02:00
12:03:00
12:04:00
12:05:00
12:06:00
12:07:00
12:08:00
12:09:00
12:10:00
12:11:00
12:12:00
12:13:00
12:14:00
12:15:00
12:16:00
12:17:00
12:18:00
12:19:00
12:20:00
12:21:00
12:22:00
12:23:00
12:24:00
12:25:00
12:26:00
12:27:00
12:28:00
12:29:00
12:30:00
12:31:00
12:32:00
12:33:00
12:34:00
12:35:00
12:36:00
12:37:00
12:38:00
12:39:00
12:40:00
12:41:00
12:42:00
12:43:00
12:44:00
Silo No. Flow
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
3
2
2
2
2
2
2
2
2
Rate (LPM) Comments
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
Liters
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4 5 1/11/99 2:59 PM Sf6rel~1.xls LRunl
-------
LRunl
Time Silo No. Flow Rate
12:45:00 2
12:46:00 2
12:47:00 2
12:48:00 2
12:49:00 4
12:50:00 4
12:51:00 4
12:52:00 4
12:53:00 2
12:54:00 2
12:55:00 2
12:56:00 2
12:57:00 Stop Gas Release
Average Release Rate (LPM) =
Mass Release Rate (g/min) =
Time of Release (min) =
Mass Released (g) =
(LPM) Comments
4.00
4.00
4.00
4.00
4.07
4.06
4.06
4.06
4.00
4.00
4.00
4.00
End of run
Liters
4.00
4.00
4.00
4.00
4.07
4.06
4.06
4.06
4.00
4.00
4.00
4.00
4.07
0.491
173
84.9
5 5 1/11/99 2:59 PM Sf6reM .xls LRunl
-------
-------
LRun2
SF6 Gas Delivery Data Spreadsheet
Loadout Run 2 Date: 7/25/98
Time
7:10:00
7:11:00
7:12:00
7:13:00
7:14:00
7:15:00
7:16:00
7:17:00
7:18:00
7:19:00
7:20:00
7:21:00
7:22:00
7:22:30
7:23:00
7:24:00
7:25:00
7:26:00
7:27:00
7:28:00
7:30:00
7:31:00
7:31:30
7:32:00
7:33:00
7:34:00
7:35:00
7:36:00
7:37:00
7:38:00
7:39:00
7:40:00
7:41:00
7:42:00
7:43:00
7:43:30
7:44:00
7:45:00
7:46:00
7:47:00
7:47:30
7:48:00
7:49:00
7:50:00
Silo No.
3
5
5
5
5
5
5
3
3
3
3
3
3
2
2
2
3
3
3
3
2
2
3
3
3
3
3
3
2
2
2
2
2
3
3
2
2
2
2
2
3
3
3
2
Flow Rate (LPM) Comments
4.10
4.00
4.05
4.06 Usable data.
4.07
4.08
4.00
4.06
4.06
4.06
4.06
4.06
4.06
4.02
4.03
4.04
4.07
4.07
4.08
4.08
4.04
4.05
4.08
4.08
4.08
4.08
4.08
4.09
4.04
4.05
4.05
4.05
4.05
4.09
4.08
4.04
4.04
4.04
4.05
4.05
4.07
4.07
4.07
4.03
Liters
4.06
4.07
4.08
4.00
4.06
4.06
4.06
4.06
4.06
2.03
2.01
4.03
4.04
4.07
4.07
4.08
8.16
4.04
2.02
2.04
4.08
4.08
4.08
4.08
4.09
4.04
4.05
4.05
4.05
4.05
4.09
2.04
2.02
4.04
4.04
4.05
2.02
2.03
4.07
4.07
4.03
1 5 1/11/99 2:59 PM Sf6rel~1.xls LRun2
-------
LRun2
Time
7:51:00
7:52:00
7:53:00
7:54:00
7:55:00
7:56:00
7:57:00
7:58:00
7:59:00
7:59:30
8:00:00
8:01:00
8:02:00
8:03:00
8:03:30
8:04:00
8:05:00
8:06:00
8:07:00
8:08:00
8:09:00
8:10:00
8:11:00
8:12:00
8:13:00
8:14:00
8:15:00
8:16:00
8:16:30
8:17:00
8:18:00
8:19:00
8:20:00
8:21:00
8:22:00
8:23:00
8:24:00
8:25:00
8:26:00
8:27:00
8:28:00
8:29:00
8:30:00
8:31:00
8:32:00
8:33:00
8:34:00
8:35:00
Silo No.
2
2
2
2
3
3
3
3
3
2
2
2
2
2
3
3
3
3
3
2
3
3
3
4
4
4
4
4
3
3
3
3
3
3
5
5
3
3
3
2
2
2
3
3
3
3
3
2
Flow Rate (LPM) Comments
4.05
4.05
4.04
4.04
4.07
4.06
4.06
4.06
4.06
4.03
4.03
4.03
4.03
4.04
4.04
4.04
4.04
4.04
4.04
4.03
4.04
4.00
4.00
4.09
4.09
4.09
4.09
4.09
4.00
4.00
4.00
4.00
4.00
4.00
4.04
4.03
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.02
4.02
4.00
4.00
4.00
Liters
4.05
4.05
4.04
4.04
4.07
4.06
4.06
4.06
2.03
2.01
4.03
4.03
4.03
2.02
2.02
4.04
4.04
4.04
4.04
4.03
4.04
4.00
4.00
4.09
4.09
4.09
4.09
2.04
2.00
4.00
4.00
4.00
4.00
4.00
4.04
4.03
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.02
4.02
4.00
4.00
4.00
2 5 1/11/99 2:59 PM Sf6rel-1 .xls LRun2
-------
LRun2
Time
8:36:00
8:36:30
8:37:00
8:38:00
8:39:00
8:40:00
8:41:00
8:42:00
8:43:00
8:44:00
9:27:00
9:28:00
9:29:00
9:30:00
9:31:00
9:32:00
9:33:00
9:34:00
9:35:00
9:36:00
9:37:00
9:38:00
9:39:00
9:40:00
9:41:00
9:42:00
9:43:00
9:44:00
9:45:00
9:46:00
9:47:00
9:48:00
9:49:00
9:50:00
9:51:00
9:52:00
9:53:00
9:54:00
9:55:00
9:56:00
9:57:00
9:58:00
9:59:00
10:00:00
10:01:00
10:02:00
10:03:00
10:04:00
Silo No.
2
4
4
4
4
4
3
3
5
2
2
2
2
2
2
3
3
2
2
2
2
2
2
2
2
2
2
2
3
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Flow Rate (LPM) Comments Liters
4.00
4.08
4.08
4.07
4.07
4.06
3.97
3.98
4.00
Stop Gas Release
4.00 Resume Gas Release
3.97 SED being monitored by FTIR;
3.95 capture data not usable.
4.06
4.06 Usable data.
4.06
4.06
4.07
4.11
4.11
4.05
4.05
4.05
4.05
4.05
4.05
4.05
4.05
4.04
4.05
4.04
4.04
4.05
4.05
4.05
4.05
4.05
4.04
4.03
4.04
4.03
4.04
4.03
4.03
4.03
4.04
4.04
4.04
2.00
2.04
4.08
4.07
4.07
4.06
3.97
3.98
4.00
4.06
4.06
4.06
4.07
4.11
4.11
4.05
4.05
4.05
4.05
4.05
4.05
4.05
4.05
4.04
4.05
4.04
4.04
4.05
4.05
4.05
4.05
4.05
4.04
4.03
4.04
4.03
4.04
4.03
4.03
4.03
4.04
4.04
4.04
3 5 1/11/99 2:59 PM Sf6rel~1.xls LRun2
-------
LRun2
Time
10:05:00
10:06:00
10:07:00
10:08:00
10:09:00
10:10:00
10:11:00
10:12:00
10:13:00
10:14:00
10:15:00
10:16:00
10:17:00
10:18:00
10:19:00
10:20:00
10:21:00
10:22:00
10:23:00
10:24:00
10:25:00
10:26:00
10:27:00
10:28:00
10:29:00
10:30:00
10:31:00
10:32:00
10:33:00
10:34:00
10:35:00
10:36:00
10:37:00
10:38:00
10:39:00
10:40:00
10:41:00
10:42:00
10:43:00
10:44:00
10:45:00
10:46:00
10:47:00
10:48:00
10:49:00
10:50:00
10:51:00
10:52:00
Silo No.
2
2
2
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
2
2
2
2
4
4
4
4
4
4
4
4
4
4
4
4
5
5
5
5
5
5
2
2
2
2
2
Flow Rate (LPM) Comments
4.04
4.04
4.04
4.04
4.04
4.03
4.03
4.03
4.04
4.04
4.04
4.04
4.05
4D6
4.07
4.06
4.06
4.09
4.06
4.06
4.07
4.00
4.00
4.00
4.00
4.05
4.07
4.06
4.06
4.06
4.06
4.06
4.06
4.06
4.05
4.05
4.05
3.96
3.96
3.97
3.97
3.97
3.97
4.04
4.04
4.03
4.00
4.00
Liters
4.04
4.04
4.04
4.04
4.04
4.03
4.03
4.03
4.04
4.04
4.04
4.04
4.05
4.06
4.07
4.06
4.06
4.09
4.06
4.06
4.07
4.00
4.00
4.00
4.00
4.05
4.07
4.06
4.06
4.06
4.06
4.06
4.06
4.06
4.05
4.05
4.05
3.96
3.96
3.97
3.97
3.97
3.97
4.04
4.04
4.03
4.00
4.00
4 5 1/11/99 2:59 PM Sf6rel~1.xls LRun2
-------
LRun2
Time Silo No.
10:53:00
10:54:00
10:55:00
10:56:00
10:57:00
10:58:00
10:59:00
11:00:00
11:01:00
11:02:00
11:03:00
11:04:00
11:05:00
11:06:00
11:07:00
11:08:00
11:09:00
11:10:00
11:11:00
11:12:00
11:13:00
11:14:00
11:15:00
11:16:00
11:17:00
11:18:00
11:19:00
11:20:00
11:21:00
11:22:00
11:23:00
1 1 :24:00
11:25:00
11:26:00
11:27:00
1 1 :28:00
11:29:00
11:29:30
Flow Rate
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
(LPM) Comments
3.98
3.96
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.98 End of Run
3.99
3.99
3.99
3.99
4.02
4.00
4.00
3.99
3.99
3.98
3.97
3.97
3.98
3.99
3.99
4.00
4.03
Stop Gas Release
Average Release Rate (LPM) =
Mass Release Rate (g/min) =
Time of Release (min)
Mass Released (g) =
=
Liters
3.98
3.96
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
4.04
0.486
192
93
5 5 1/11/99 2:59 PM Sf6rel-1.xls LRun2
-------
-------
LRunS
SFQ Gas Delivery Data Spreadsheet
Loadout Run 3 Date: 7/27/98
Time
7:10:00
7:11:00
7:12:00
7:13:00
7:14:00
7:15:00
7:16:00
7:17:00
7:18:00
7:19:00
7:20:00
7:21:00
7:22:00
7:23:00
7:24:00
7:25:00
7:26:00
7:27:00
7:28:00
7:29:00
7:30:00
7:31:00
7:32:00
7:33:00
7:34:00
7:35:00
7:36:00
7:37:00
7:38:00
7:39:00
7:40:00
7:41 :00
7:42:00
7:43:00
7:44:00
7:45:00
7:46:00
7:47:00
7:48:00
7:49:00
7:50:00
7:51:00
7:52:00
7:53:00
Silo No. Flow
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Rate (LPM) Comments
4.00 Start Gas Release
3.97
4.03
4.03
4.04
4.04 Usable data.
4.04
4.04
4.04
4.04
4.04
4.04
4.03
4.03
4.03
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
3.99
Liters
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.03
4.03
4.03
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
3.99
161/11/993:00 PMSf6rel~1 .xlsLRunS
-------
LRunS
Time
7:54:00
7:55:00
7:56:00
7:57:00
7:58:00
7:59:00
8:00:00
8:01:00
8:02:00
8:03:00
8:04:00
8:05:00
8:06:00
8:07:00
8:08:00
8:09:00
8:10:00
8:11:00
8:12:00
8:13:00
8:14:00
8:15:00
8:16:00
8:17:00
8:18:00
8:19:00
8:20:00
8:21:00
8:22:00
8:23:00
8:24:00
8:25:00
8:26:00
8:27:00
8:28:00
8:29:00
8:30:00
8:31:00
8:32:00
8:33:00
8:34:00
8:35:00
8:36:00
8:37:00
8:38:00
8:39:00
8:40:00
8:41:00
Silo No.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
4
4
4
4
4
4
4
4
4
4
4
4
Flow Rate (LPM) Comments
3.99
3.99
3.99
3.99
3.98
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.06
4.07
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
Liters
3.99
3.99
3.99
3.99
3.98
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.06
4.07
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
261/117993:00 PMSf6reM.xlsLRun3
-------
LRunS
Time
8:42:00
8:43:00
8:44:00
8:45:00
8:46:00
8:47:00
8:48:00
8:49:00
8:50:00
8:51:00
8:52:00
8:53:00
8:54:00
8:55:00
8:56:00
8:57:00
8:58:00
8:59:00
9:00:00
9:01:00
9:02:00
9:03:00
9:04:00
9:05:00
9:06:00
9:07:00
9:08:00
9:09:00
9:10:00
9:11:00
9:12:00
9:13:00
9:14:00
9:15:00
9:16:00
9:17:00
9:18:00
9:19:00
9:20:00
9:21:00
9:22:00
9:23:00
9:24:00
9:25:00
9:26:00
9:27:00
9:28:00
9:29:00
Silo No. Flow
4
4
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Rate (LPM) Comments
4.00
4.02
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
4.04
4.04
4.04
4.03
4.02
4.03
4.03
4.03
4.04
4.04
4.04
4.04
Liters
4.00
4.02
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
4.04
4.04
4.04
4.03
4.02
4.03
4.03
4.03
4.04
4.04
4.04
4.04
361/11/993:00 PMSf6rel~1 .xlsLRunS
-------
LRunS
Time
9:30:00
9:31:00
9:32:00
9:52:00
9:53:00
9:54:00
9:55:00
9:56:00
9:57:00
9:59:00
10:00:00
10:01:00
10:02:00
10:03:00
10:04:00
10:05:00
10:06:00
10:07:00
10:08:00
10:09:00
10:10:00
10:11:00
10:12:00
10:13:00
10:14:00
10:15:00
10:16:00
10:17:00
10:18:00
10:19:00
10:20:00
10:21:00
10:22:00
10:23:00
10:24:00
10:25:00
10:26:00
10:27:00
10:28:00
10:29:00
10:30:00
10:31:00
10:32:00
10:33:00
10:34:00
10:35:00
10:36:00
10:37:00
Silo No.
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
5
2
2
5
5
5
5
Flow Rate (LPM) Comments Liters
4.04
4.04
Stop Gas Release
4.08 Resume Gas Release
4.00
3.98 Instrument off-line for manual
3.98 method port change;
3.98
Stop Gas Release
4.03 Resume Gas Release
4.00
3.99
3.98
3J99 Usable data.
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
3.98
3.99
3.98
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.00
3.99
3.99
3.99
4.04
4.04
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
3.99
3.99
3.99
3.99
3.99
3.99
3.98
3.99
3.98
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.02
4.03
4.00
3.99
3.99
3.99
461/11/993:00 PMSf6rel~1.xlsLRun3
-------
LRunS
Time
10:38:00
10:39:00
10:40:00
10:41:00
10:42:00
10:43:00
10:44:00
10:45:00
10:46:00
10:47:00
10:48:00
10:49:00
10:50:00
10:51:00
10:52:00
10:53:00
10:54:00
10:55:00
10:56:00
10:57:00
10:58:00
10:59:00
1 1 :00:00
11:01:00
11:02:00
1 1 :03:00
1 1 :04:00
11:05:00
11:06:00
1 1 :07:00
11:08:00
11:09:00
11:10:00
11:11:00
11:12:00
11:13:00
11:14:00
11:15:00
11:16:00
11:17:00
11:18:00
11:19:00
11:20:00
11:21:00
11:22:00
11:23:00
11:24:00
11:25:00
Silo No. Flow
5
5
5
5
5
5
5
5
5
5
5
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
Rate (LPM) Comments Liters
3.99
3.99
3.99
4.03
3.99
4.00
4.00 SED being monitored by FTIR
4.00 (grab samples); data not usable.
4.00
3.99
3.99
4.00
4.00
4.07
4.04
4.04
4.03
4.04
4.04
4.04
4.04
4.05
4.05
4.05
4.06
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.00 Usable data.
4.00
4.00
4.00
4.00
4.00
4.03
4.04
4.00
3.99
3.99
3.99
4.03
3.99
4.00
4.00
4.00
4.00
4.00
4.00
4.00
4.03
4.04
4.00
561/11/993:00 PMSf6rel~1 .xlsLRunS
-------
LRun3
Time Silo No
1 1 :26:00
11:27:00
11:28:00
11:29:00
1 1 :30:00
11:31:00
1 1 :32:00
1 1 :33:00
1 1 :34:00
11:35:00
1 1 :35:30
11:37:00
11:38:00
1 1 :39:00
1 1 :40:00
11:41:00
11:42:00
1 1 :43:00
1 1 :44:00
1 1 :45:00
1 1 :46:00
1 1 :47:00
1 1 :48:00
11:49:00
1 1 :50:00
11:51:00
1 1 :52:00
1 1 :53:00
11:54:30
1 1 :55:00
11:56:00
1 1 :57:00
1 1 :58:00
1 1 :59:00
12:00:00
. Flow Rate
2
2
2
2
2
2
2
2
2
2
1
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
2
1
2
2
2
2
2
2
(LPM) Comments
3.98
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
Stop Gas Release
4.00 Resume Gas Release
3.96
4.03
4.05
4.05
4.05
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.00
4.00
Stop Gas Release
4.05 Resume Gas Release
4.03
4.00
3.99
3.99
3.99
Stop Gas Release
End of Run
Average Release Rate (LPM) =
Mass Release Rate
(g/min) =
Time of Release (min) =
Mass Released (g) :
Liters
3.98
3.99
3.99
3.99
3.99
3.99
3.99
3.99
4.00
4.00
3.96
4.03
4.05
4.05
4.05
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.04
4.00
2.02
4.03
4.00
3.99
3.99
3.99
4.01
0.485
217
105
661/11/993:00 PMSf6reM .xlsLRunS
-------
LRun4
SF6 Gas Delivery Data Spreadsheet
Background Loadout Run 4 Date: 7/26/98
Time Silo No. Flow
9:27:00 2
9:30:00 2
9:43:45 2
10:00:00 2
10:33:00 2
1 1 :02:00 2
11:15:00 2
11:40:00 2
12:18:10 2
12:47:00 2
13:00:35 2
13:46:20 2
Average Release Rate (LPM)
Mass Release Rate (g/min) =
Time of Release (min) =
Mass Released (g) =
Rate (LPM) Comments
4.13
4.13
4.10
4.12
4.06
4.15
4.16
4.24
4.05
4.04
4.04
End of Run
=
Liters
56.79
66.63
135.96
117.74
53.95
1 04.00
161.84
116.76
54.86
184.83
4.11
0.497
256
128
Page 1
-------
-------
SF6 Gas Delivery data Spreadsheet
Sheet / of 7
Mn Project No. 4701 -08-03-04
Client/Source:
Sampling Location' PTE LoadOUt
•T/^i
Meter No.
Run No. /
Date: 7 " A V '
Operator
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/3
/ ^
/3
QQ&l
tl
ff**
/J
ffl-MC*.
08'?
n
if,
/3
ML
,G,
*S
/J
f t'
13
tr
/3
ft "
/J
/I
/J
ff
4,03
r'
/3
/J
/3
/'
/•*
08 VJ
/J
ff
ff /.
/3
V.of
/J
/J
U
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
of 7
Sampling Locator! PTE LoadoUt
fajjf f-LOu 2?
-Oi | Quo Meter No fC *
Mn Project No 4701 -08-03-04
Client/Source
/<£.X».Vr £
Run No. /
Date: *7
Operator.
Gas Cylinder No:
~ 7$
ALi*fi(?S-]0
Time
Silo No.
Flow Rate
Pres. PSI
Comments
n
"
i, 0%
K
»
ft
/Y
If
tM
((
" U
tl
ff
11
« If
Loo
If
h /'
010
U
Mo
Al A/
\(
li
0105
/r
Z-
A/o
09/3
1±L.
n
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 3 of 7
Mn Project No 4701 -08-03-04
Client/Source:
Run No
/
Sampling Location: PTE LoadoUt
£o
No.
Date: 7'M ' 9g
Operator
Gas Cylinder No'
Time
Silo No.
Flow Rate
Pres. PSI
Comments
01 n
T/Zt/ck-
/B
V./3
V.if
fV
/t
/Y
/v
u
413V
/OS 7
/
/OS'S
/y
It
//Od
//(> 1
s/o3
/V
f
f
//*?
I'
(I
U
V.of
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet y of 7
Mn Project No. 4701 -08-03-04
Client/Source'
Run No.
Date:
Sampling Location. PTE LoadOUt
SMjSf fai»> "^
•Ccy-Cae Meter No. /C
Operator
Gas Cylinder No- rf L.fy $ 1 3 87 $
Time
Silo No.
Flow Rate Pres. PSI
Comments
7/ct/c4_ /A-/
//to
<•
/fit
/v
fl-
•H
» «
/y
// /
6)
/I
#3
#3
/v
#£_
J!L
U
t«
#3
'/
f!3 J
/y
/y
// JV
/y
-------
SF6 Gas Delivery data Spreadsheet
Sheet 5" of 7
Mn Project No. 4701 -08-03-04
Client/Source
/
Sampling Location. PTE LoadOUt
Atjosr f~£i
Di| OuJ Meter No:
Run No.
Date:
Operator
Gas Cylinder No: /QL. M flf / Jff *f $
Time
Silo No.
Flow Rate
Pres. PSI
Comments
13-
Y.oo
if. 00
//f?
3.79
1*30
, 60
/r
n
//£/
¥.00
/t
i,
//.rr
/y
f.oo
/y
//$<}
(4
I>OJ
**
-/& fl^Pft
f.60
M
«"
11-09
/lo?
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
Mn Project No. 4701-08-03-04
Client/Source:
Run No.
/
/
Date: ' ~ . A/GJ4
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/v
/U ~TcJifJ*J&L-
. 00
1113
r*>O
on
H
3.99
fr/9
3.19
^i•
/>£/
-37
/>y°
Oil
1r 2-
•3/2-
**>
y. «?£»
<<,<>*
?.**
ty
/y
/y
*• >A **
t.
^
mri fi!es\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 7 of 7
Mn Project No. 4701 -08-03-04
Client/Source.
Sampling Location PTE LoadOUt
Run No /
Date. 7 *
Operator *O •
£-0303
GasCyhnderNo 4^0/3870
TFme
Silo No.
Flow Rate
Pres. PSI
Comments
/.w
XI
*1
A
zv_
V.ot
. 00
U
ll-Sf
t/,£>0
/*/
/y
/>$"?
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
-------
SF6 Gas Delivery data Spreadsheet
Sheet./ of 9
Mri Project No 4701 -08-03-04
Client/Source'
Run No.
Date: 7 ' >f- ?#
Operator /}, /\/£//)L.
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
Tiff
1"
/v
7/3
£
#3
.06
/v
/y
/y
73-
/y
*l
713
7JV
tf.rt
/y
7J7
/Y
*•
>J
mri files\(tirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet -2- of 8
Mn Project No 4701-08-03-04
Client/Source: /y£-*>+S~r C,
Sampling Location PTE LoadoUt
Run No. />
D**e.~"7^T-yC-
Gas Cylinder No: ^l/»t 0/387$
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/v
ft
/Y
J^L
07 It,
07*7
. o?
olfl
/v
#2-
/v
/V
/v
LA
£775*8
#3
fit
/y
0600
*3
'. of
066
-------
SF6 Gas Delivery data Spreadsheet
Sheet 3 of ff
Mn Project No 4701 -08-03-04
Client/Source*
Sampling Location: PTE LoadOUt
/Z-030S
Run No. J-
0*,~~7~~ZS'-7#
Operator £/,
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
0&0&
#3
IH
/Y
00
/Y
fi
£>&>?>
ti
tt
0811
fi
ti
•tf.oo
/Y
0818
#3
-------
SF6 Gas Delivery data Spreadsheet
Sheet f of 8
Mri Project No. 4701 -08-03-04
Client/Source
Run No ,Z-
Date.
7 ->{'*} 8
Sampling Location PTE LoadOUt
Oil 6«. Meter No. ft" O3'OQ
Operator A) .
Gas Cylinder No-
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/r
0816.3-
0831
M
0818
/y
#3
5.77
/v
/v
/y
'Y
/teuf*$t
«
oi w
Y.n
4977
013.8
013*1
/y
/y
t\
/y
mri fi!es\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet £ of 6
Mri Project No 4701-08-03-04
Client/Source-
Run No. y-~
Date: ^/
Sampling Location. PTE LoadOUt
flttijS /^L#£7,y
ieterNo. /C.'
Operator jQ. ,
Gas Cylinder No:
Time
Silo No.
Flow Rate Pres. PSI
Comments
01 f
/v
/v
/v
/v
/r
it
/r
/oo(,
/y
/oof
/ooQ
#1-
/Y
/Y
/0/0
/Y
/#//
/y
/0/1
/y
to/?
/y
/on
Y^IL
/y
H
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet £ of &
Mri Project No. 4701-08-03-04
Client/Source:
Sampling Location. PTE LoadOUt
Run No.
Date-
Operator
.2-
9 B
Gas Cylinder No: /}£,*?) 0 / 3 87 0
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/oi-l
#3
/t
/oil
/y
/v
/oil
rl
/v
Li
/y
/y
*'
/oil-
?.£>(>
q.ot,
/031
**
tx
3,97
/y
*»
3^77
3-97
*'•
#5-
/y
M.
/y
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 7 of 8
Mri Project No 4701 -08-03-04
Client/Source
Run No.
.2-
Sampling Location. PTE LoadOUt
tftoffr f^bofaj—
•Biy f?a» Meter No: /X -
Operator j(J
Gas Cylinder No: tf L*l 0 (307$
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/v
/oft
3. It
/v
tA
V.OO
/oS8
tf.
00
/ /oo
//£>!
^,£70
/v
/v
/y
//of,
#2-
/y
r
tf-00
//o6
/r
/y
**
3.1?
/v
/r
3,91
/Jo
///y
/y
an
///#
/r
00
/r
/y
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 8 of 8
Mn Project No 4701 -08-03-04
Client/Source.
Sampling Location' PTE LoadOUt
/HoJf ft-o£> 7T"
-"T_F—' Meter No. f\.c~
Run No. *
Date: "/
Operator <£r
Gas Cylinder No ^ f^ fa {$ f3& J ff
Time
Silo No.
Flow Rate
Pres. PSI
Comments
H
3.91
-5,95
/y
r*
ff
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
./_«_£.
Mr. Project No 4701 -08-03-04
Client/Source.
A/7"
ampling Location- PTE LoadOUt
£-0306
Run No ,}
Date: ?- 3~
Operator fft /^S&Jtl,
Gas Cylinder No: $ f\ L. / *$ 3 3 &
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/y
//
3.97
07/2-
tv
07/3
V.of
/v
V.Of
/V
To
0117
-------
SF6 Gas Delivery data Spreadsheet
Sheet
of
Sampling Location- PTE Loadout
-Brye«s Meter No: fc •
Mn Project No. 4701 -08-03-04
Client/Source.
Run No J
Date: *J
Operator fj . fiSft^f^
Gas Cylinder No: tf £ ^_ fty 3"$&
Time
Silo No.
Flow Rate
Pres. PSI
Comments
/v
3-9?
01
/v
#2-
3.79
3-??
07 V 7
t»
/y
3*99
075V
t- t.
/y
#1-
/y
3.19
/y
C< I-
3.99
01 $1
3.18
/v
t/.oo
0800
t/.oo
i-l t,
/y
08*3
08 oy
00
/y
(.'
I/
/y
0808
f.oo
/y
08°?
tf.oo
/y
it
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 3 of ?
Mri Project No 4701-08-03-04
Client/Source:
Run No.
Sampling Location: PTE LoadOUt
Date: ?~ >^9g
Operator
Gas Cylinder No:
Time
Silo No.
Flow Rate Pres. PSI
Comments
08 il
/v
08*5
41
OQK,
oen
/v
0918
IH
/v
082-1-
f.Qo
XV
M
f.oo
t/.oo
/y
GB7-8
/y
. 06
tA
M
08 32-
/r
e/.co
&8"W
08 3 &
!<.
tl
0&18
¥.00
/v
/y
/y
l/.OO
1 .
mri riles\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
-------
SF6 Gas Delivery data Spreadsheet
Sheet
/of
Mri Project No 4701-08-03-04
Client/Source.
Run No.
Sampling Location. PTE LoadOUt
Operator
Off 8a» Meter No. /?~020ff
Gas Cinder No:
/ -
3. 7?
'Y
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
of ?
Mri Project No. 4701 -08-03-04
Client/Source-
Sampling Location. PTE Loadout
r fit-ottj ~^2
Meter No: K
Run No.
Date:
Operator
Gas Cylinder No:
Time
Flow Rate
Pres. PSI
Comments
/oof
331
/v
/v
3.??
/r
A
/oo9
3.9?
<*
JO
3.1f
3,9?
'Y
3. ?9
/r
JS.
/o/C
3.11
/v
K
3,79
/v
-IOI&
3.79
10 /
/<5>0
3.9*
M.
/v
/Y
ti
#2-
/y
t\
1*.
I*
(A.
7*33
/y
f.oo
3-91
/y
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet 7 of
Mri Project No. 4701-08-03-04
Client/Source
RmNo.
Date'
ampling Location PTE LoadOUt
Operator
& ,
Gas C^erNo: Jjt- /?3l 8
Time
Silo No.
Flow Rate
Pres. PSI
Comments
3.99
ff
t\
''«•
t/
3.99
3.99
To 3oo-t-Fi°f\
3.99
/t
¥.60
. 00
/r
3.99
/Y
/•W
M
¥-00
/y
/y
/OSS'
/j
/J
/J
l«-
M
13
**
Y-'f
S3
/3
H.
Uol-
/3
4,00
11
/3
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
e
Mn Project No. 4701 -08-03-04
Client/Source.
Sampling Location' PTE LoadoUt
Diy SM Meter No:
Run No
Date.
Operator & , As£jf(_
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
//o7
/3
//oB
//of
13
/oo
///*>
S/fl
f3
/*•
/111-
/3
///J
13
A
/3
V.oo
/3
///£
/3
*»
/It 7
/3
/3
/3
V.OQ
/J
(3
#1-
/3
/3
3,*??
3.9?
(v
3,91
/nt
/3
M
f3
//53
13
//JV
(/.Oo
(3
M-
13
/J
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
9 tit 9
Mn Project No 4701 -08-03-04
Client/Source.
Run No.
Sampling Location PTE LoadoUt
r/^
leter No.
/Z~030g
Operator 2) , A^8t) U
A _ . I*
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
13
13
//
13
t*
fOO-T-Sofft
/fit-
13
*-
13
?•*><(
/3
/J
**-
//fo
/J
J*.
/3
/J
//J-J-
(3
//r?
13
n
/j
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
-------
SF6 Gas Delivery data Spreadsheet
Sheet / of ^7
Mn Project No. 4701-08-03-04
Client/Source.
Sampling Location PTE LoadOUt
Dry Gas Meter No.
Run No.
Date:
Operator.
&-030?
Gas Cylinder No: ftVrL,\<*f ^
Time
Silo No.
Flow Rate
Pres. PSI
Comments
0TZ/7
Y-/3
2_
L JO
$9 4 3
2-
*.
.00
015-7.10
0 00.
07, HO
to
IQU.'V
2J?..
/o
lOt"). iff
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
rfo*\
/&,.;'• N
. i w.. .> *
SF6 Gas Delivery data Spreadsheet
Sheet ^- of fi
Mn Project No. 4701 -08-03-04
Client/Source.
Run No.
Date:
vfA
/•&**+
Sampling Location PTE LoadoUt
Dry Gas Meter No: A<-
Operator /C^yn*^
Gas Cylinder No:
/ ^ ? 2
/
30 «jrr\u«r
30
mri ntes\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
of G
Mn Project No 4701-08-03-04
Client/Source:
Sampling Location PTE LoadOUt
Dry Gas Meter No' f\ -
Run No.
Date:
Operator
Gas Cylinder No:
fa t *L ^ *t
Time
Silo No.
Flow Rate
Pres. PSI
Comments
10
3- f
<•/••/
A: 23: / 6
"7K*c ^ 30
f »
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet Y of
Mn Project No. 4701 -08-03-04
Client/Source.
Run No.
Sampling Location. PTE LoadOUt
Dry Gas Meter No. Q —
Date 7/2 ^/9-#
Operator fCC/frH/Vy
Gas Cylinder No:
Time
Silo No.
Flow Rate
Pres. PSI
Comments
//.'
-V
•77-****-
: 07:^.4
*r ^cp-
2-
50
*.
Sr
mri files\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
SF6 Gas Delivery data Spreadsheet
Sheet
of
Mn Project No. 4701-08-03-04
Client/Source.
Sampling Location- PTE LoadOUt
Dry Gas Meter No K
Run No.
Date.
Operator
Gas Cylinder No-
Time
Silo No.
Flow Rate Pres. PSI
Comments
rs
L
K.
*JL
30
U 06:00
30
; yr
mri flles\ftirform\gasreleasePSI
Midwest Research Institute
07/13/98
-------
V
SF6 Gas Delivery data Spreadsheet
Sheet £ of 4?
Mn Project No. 4701 -08-03-04
Client/Source:
Sampling Location PTE LoadOUt
Dry Gas Meter No. /<
Run No.
Date:
Operator
Gas Cylinder No-
Time
Silo No. Flow Rate Pres. PSI
Comments
Z
J>
-------
Appendix H
Loadout Raw Data
MRI-AED\R4951 -04-08.wpd
-------
7
o
TIL
-------
Load-Out Log Spreadsheet
Sheet / of 5
ri Project No. 4701-08-03-04
ilient/Source:
RunNo.
Data Recorded By:
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
TIT A-?
33
01
1
7JL d
3/
pin
/7
20. &f
073ft
3
07/5
00.83
/§.
33
ft !,
'*>
/£&/
IO^L
31
0752-
10 ri
xr
lo
mri fites\ftirform\ProducttonData
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet
of
ri Project No. 4701-08-03-04
Bent/Source:
Run No.
Date:
Data Recorded By.
7/2
/Y]
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
12-
e>3
33
/3
03
3o
3l
/r
B
a/. 3 s>
TTf /2> 3
21
fa
3/7
/O
E>3
sO
/£*-
2-
u
(003-
1-1
II
0}
I
3
(00^
Cy
mri files\ftirform\ProductionData
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet __3 of
. 4701-08-03-O4
RunNo.
/ —
Product
ID
Product Description
Job
Name
Time
Of
Loadlno
Actual
Ton*
Loaded
TltK*
No
S»o
No.
Mix
Temp,
in Truck
Comments
loof/
01
Tlf ft 3 /*&• */*.
j ft
tlaf
-------
Load-Out Log Spreadsheet
Sheet
of
^f ' 03 A£-fao
mrt
-------
Load-Out Log Spreadsheet
Sheet -5"of ^
Uri Project No. 47Q1-08-03-04
Ctem/Sowo* &?A
Run No.
DM>:
t-h*
Product
ID
Product Description
Job
Name
TllTI*
Of
Actual
Tons
Uaded
No
Sio
No.
Mix
Temp.
In Truck
Comtnftnts
53
P/.53
•%_
100*-
2-
1003-
7^-36
3 I
Mo
. 37
33
B>
3f
3_
A&/COO
?&
fas' i
tori
b
E>
8?
07/13AC
-------
Load-Out Log Spreadsheet
Sheet / of
ri Project No. 470 1 -08-03-04
lent/Source: £/X^ /
//I/* As
Run No.
Date:
Data Recorded By:
/^ (/ S~
~£> W
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
fob1-!
W d3
3-0
&
'ft
K (13
/C?
A
in
(f
/ft
W^
3
**/"
A
ft
tf
"
07 tf
C3
K
ll
0/8
//
,
3/(f "
/&
01 &
„
if
OWo
VJ.
K
It
T*" g
/octj
^753
>f
/I
"
13L
/&
IB C
n
2&£_
If. 13
mri fitesVftirfbim\ProductionData
Midwest Research Institute
'07/13/98
-------
Load-Out Log Spreadsheet
Sheet
<3.of /
Wri Project No. 4701-08-03-04
Client/Source:
/
Run No.
Date:
Data Recorded By:
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
Comments
V
\
fl
00 n
3
If
If
?
-------
Load-Out Log Spreadsheet
Sheet 3 of
mri Project No. 4701-08-03-04
Run NO.
Load
Data Recorded By: /^" /Y) U /~D CoCjr
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
sA
V
2#*
e 5 /
V'
/
12-
2f.ro
te
it
3s, "
I £L
B
'&
B
•ZtfL
/r
•?0.8t>
/B
A
ii
*/"
t B
/COS
a
/ocf
mri fitestftirfonnVProductionData
Midwest Research Institute
07/13/96
-------
Load-Out Log Spreadsheet
Sheet 4/ of
Mri Project No. 4701-08-03-04
Client/Source: £/"/^ /
Run No.
Date:
Data Recorded By:
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
toil
V
n
"
/a.
/Of to
/0
-------
Load-Out Log Spreadsheet
Sheet
of 7
ri Project No. 4701-08-03-04
font/Source:
Run No.
E'fA /
d
Dab Recorded By:
(f /I
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
*"
/<<
01 '0J-
2.70
/
3*1
P/./7
tool-
/2L
oi/l
//.-7V
//.
01/3
//.3Z
if
01/8
31.
/7TZ
8
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1'
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, a 1.3.
A 07
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it
v//x
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loo*
53
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08 '3
mri files\ftirform\Productk)nData
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet 2- of
Mri Project No. 4701-08-03-04
Client/Source:
Run No.
/
C
Date:
Data Recorded By.
/'/ U'i'OCiJ £/J
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
m Truck
Comments
/<* 74?
f>
//W
b.eo
-"
AW
V
3®
!&>)-
J22.
A 7 7
Tu* &
(02±.
e>
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T 5?
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3*30
V"
70
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/o
fort
o&fo
Y
Load-sol
08?
5"
/gp-,.,/, ^L
B
gg^
?ot
mri fites\ftirform\ProductionOata
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet
Project No. 4701-08-03-04
;fiant/Source:
Run NO.
L/VT
/
Data Recorded By:
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
SHo
No.
Mix
Temp.
in Truck
Comments
I'Z.OD
K
/Lf&.
ff
07
12.00
ft
if
/f
'Q*&
'•&*-
V
Ofcf
HM1
*«/*
tfoi
fool
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to
V'
Of
10° "
70
/J-.00
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09/9
tl
mri fites\ftirform\Productk>nData
Midwest Research Institute
07/13«8
-------
Load-Out Log Spreadsheet
Sheet V of
ri Project No. 4701-08-03-04
Kent/Source: r
Run No.
Date:
Data Recorded By:
0OT
: f-5
a O
tori
B
/3.00
fa/8
fori
v/ "
07^3
/-
K
/€>
SO
£-3
fooe
ti>01
1(0
B
n
K
mri filcs\ftirfonn\ProductionData
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet ^ of /
ri Project No. 4701-08-03-0^
NO.
Client/Source:
s*7/9?8
fepfoU-
Data Recorded By:
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
it
(f
loo*?
f.W
ff
V'
/Of/
I5.no
/Of/
if
&
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loi?-
/3.00;
tf
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/A73
fi
01
6
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!$.«/
K
if
low
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if
/ft*/
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if
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60*.
#2.
loo
2.0
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Midwest Research Institute
07^13/98
-------
Load-Out Log Spreadsheet
Sheet V7 of
Project No. 4701-OS-03-04
Run No.
Data:
Data Recorded By:
/Yt
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
fi
n
ff
/f
/$
/Oil
&
M
nn
/Ofl
13
x
73
20
wl
//to
V
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/?
OQ
ff
1(0®
1/07
ll/O
(1.60
it n
if
Cf
/I
11
u
n
f(
mri files\ftirform\ProductlonData
Midwest Research Institute
07/13/98
-------
Load-Out Log Spreadsheet
Sheet T of 7
Mri Project No. 4701-08-03-04 ;
t—-f\/\ /
Client/Source:
(2
Run No.
Date:
Data Recorded By:
Product
ID
Product Description
Job
Name
Time
Of
Loading
Actual
Tons
Loaded
Truck
No
Silo
No.
Mix
Temp.
in Truck
Comments
(I
•V
/f
B
f/
ZZ.
/C
/f
n
n
n
n
f/
(f
/ay
fs
r(
f
l>.oo
/I
ff
A.
/3.oo
/t
f(
fbc/r
/c
ff
TZ
//r/
if
ff
ff
n.
I^L
»
///s
ff
mri files\ftirform\Productk>nData
Midwest Research Institute
07/13/98
-------
Appendix I
Sample Concentration Procedure and
Raw Data Sheets
MRI-AED\R4951 -04-08.wpd
-------
Run No. s3 Date
Project No. 4/70>
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Sample Type
Client
Desired Probe/STL Temperature
Desired Sampling Rate />«£"
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling 0S&&
After Sampling C?'t>0
in. Hg
ft.
in. Hg
°C
Sampling Location
Operator J.
Liters/min
Liters
in.
Metering Console No..
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
0,9*?J
Tenax Inlet Thermocouple No.
Temperature Meter No. ./
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. £
Heated STL Length
STL Tubing Material _
in. Hg vacuum for
in. Hg vacuum for
in.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling 0*60 in. Hg change at _
After Sampling 0t0& in. Hq change at
in. Hg vacuum for.
in. Hq vacuum for
60
6O
. sec.
. sec.
sec.
sec.
Motes on Spiking:
Time,
24- Hr
DGM
Reading,
Liters
DGM'
Temp.,
°C
Probe/STL
Temp.,
°C
1st Tube
Inlet
Temp.,°C
Pump
Vacuum,
in. Hg
Rotameter
Setting
Remarks
WO
3.5-
***#
3.Q
9968
33,6$
09*8
083X
/a
JJ
J&&
OZfB
08S3
6908
09/8
S.f
3.0
MS;
'Ambient air, train fcjank, preliminary, duplicate train, or source sample.
SUPRVOST.WPD July 16. 1998
-------
Sample Concentrating Procedures for Gas Phase FTIR Analysis
Midwest Research Institute
Version 3
December 23, 1997
1.0 Introduction
This method describes a procedure for collection of volatile organic compounds onto
a sorbent material (Tenax), storage of samples (if necessary), thermal desorption of
captured volatile compounds from the sorbent material into a multi-pass White cell, and
analysis of the gases by FTIR. This method is intended to complement sampling and
analysis of pollutant gas streams by EPA Method 320 (FTIR) by providing one
mechanism by which, under certain circumstances, greater detection limits can be
achieved. The sorbent collection and desorption aspects of this method are based largely
upon field and laboratory work performed by Entropy Environmentalists, Inc. (Entropy),
laboratory work performed by Midwest Research Institute (MRI), and EPA-approved
Tenax-based procedures for stack sampling, such as the Volatile Organic Sampling Train
(VOST), SW-846, Method 0030, which is widely used for collection of volatile organic
compounds with analysis by GC/MS.
Previous work has been done using Tenax concentrating systems for FTIR analysis
by Entropy (1993,1994) and MRI (1993, 1994), but has not been published. Entropy's
work involved validation of certain equipment and procedures based on Method 301, and
ultimately the procedures were used for collection of field samples. MRI's work
involved laboratory validations of certain equipment and procedures in an effort to
duplicate, and potentially improve upon, the techniques developed by Entropy, and was
never used to collect field samples. The procedures described in this document represent
a hybrid of Entropy's and MRI's collective experiences and also the availability of MRI
equipment currently available to collect and analyze samples.
2.0 Sample Collection
A concentrated sample is collected by drawing source gases through a sampling train
equipped with one or more Tenax cartridges under controlled conditions. This method
uses an oversized (10 g) Tenax trap in order to concentrate a large gas volume while
protecting against breakthrough. A second trap may also be placed in-line to provide
additional protection against breakthrough, as necessary.
Components of the concentrative FTIR sampling train include a heated stainless steel
probe with a glass liner, heated filter and glass filter holder (optional), heated teflon
-------
connecting line, a water-cooled glass condenser, nickel adsorbant trap, empty catch flask
or impinger for water removal, a second water-cooled glass condenser (optional), a
second nickel adsorbant trap (optional), a silica gel drying tube, a calibrated rotometer, a
sampling pump, and a dry gas meter. An untreated glass wool plug may also be included
at the probe tip as an optional particulate removal method. Treated, or silanized, glass
wool should not be used with this sampling system as it has been shown to introduce
contamination. All heated components will be kept at a temperature of 120 C or greater
to ensure no condensation of water vapor within the system.
The Tenax cartridge design is based largely on the inside-outside VOST
configuration from SW-846, Method 0030, without using the outer metal carrier tube.
Cartridges will be made of 1" diameter nickel tubing and will be filled with about 10
grams of Tenax TA adsorbant material. Nickel was chosen as the construction material
due to its low reactivity and high thermal conductivity. It is believed that glass may have
poor heat transfer for a tube of this size, limiting both sample collection and desorption
functions, and that stainless steel is considered reactive, and may adsorb trace volatile
organics which may be present in the gas stream. Both ends of the tube will be plugged
with a 1" diameter screen held in place by a C-clip. Approximately 1" on either end of
the tubing will be polished to allow leak-free connection with the end cap o-ring.
Cartridges will be individually marked for clear identification and direction of sample
flow.
Previous field work with this method by Entropy has demontrated effective sample
collection and retention by using a stainless steel U-shaped tube (which was immersed in
an ice bath). MRI's straight nickel tube design, which has undergone laboratory
validation, is expected to provide even better performance due to reduced chemical
reactivity and improved moisture removal. "Drying" of the tube prior to thermal
desorption and analysis is discussed further in Section 5.0.
Prior to use in the field, the packed tube will be heated to 350 F while being purged
with dry nitrogen (typically 1-2 LPM) for up to 18 hours. Cleanliness may be verified by
laboratory FID (pass/fail criteria for THC of <5 ppb), laboratory FTIR, and/or field FTIR,
whichever is most appropriate for the necessary application. Note that FTIR checks for
cleanliness may allow identification of specific contaminants.
Spiking with a surrogate gas is suggested as a measure of effectiveness of the
sampling system and of the desorption/recovery procedures. To be the most
representative, spiking should be performed on-line (during normal sample collection)
with spike gases passing through the entire Tenax concentrating system, including the
probe, if possible. If spiking in this manner is not practical, other types of surrogate and
QA spiking should be considered. Section 4.1 of this method describes surrogate spiking
procedures in greater detail.
For concentration of the sample gases , one trap or (optionally) two traps will be
placed in-line in a sampling train. Inclusion of the second trap allows determination of
-------
breakthrough, if any, to be determined. The train is equipped with glass water-cooled
condensers and has fittings specifically built to allow connection of the 1" diameter
concentrative FTIR Tenax cartridges. A catch flask will be connected at the lower end of
the first trap for collection of moisture, but will not be analyzed by FTIR. If necessary,
this condensate can be archived and analyzed by purge and trap GC/MS.
Cooling water flow will be maintained through the condensers in order to collect
sample gases at the appropriate temperatures. Of primary importance is the temperature
at the base of the first condenser (inlet to the first Tenax trap), which must be maintained
at 20 C or lower. The condensers will be sized large enough to maintain <20 C
temperatures at the desired gas sampling rates.
Sample gas flow will be maintained at 1-5 LPM for the duration of the test, and will
depend upon the specific needs of the site being tested. Nominal flow will be set by a
calibrated rotometer mounted on the sampling apparatus console, and the exact volume
drawn through the collection train will be measured by a dry gas meter. An approximate
concentration factor can be calculated by dividing the dry gas meter volume by the FTIR
cell volume (nominally 7.0 liters). Thus, sample collection at 1.5 LPM for 4 hrs (240
minutes) produces approximately 360 liters of sample. Dividing 360 by 7 results in a
concentration factor of 51. Operating flowrates and breakthrough volumes for this
method have not been extensively researched, but in general one can expect concentration
factors of up to 50 to be effective and valid samples. Sample gas volumes of up to 400 L
(concentration factor of about 57) have been demonstrated in the laboratory for certain
compounds.
Since sample collection could potentially involve a time period of up to several
hours, the silica gel cartridge should be periodically checked for saturation. Saturation of
the silica gel cartridge is apparent when the silica gel begins to turn pink. If necessary,
the sampling apparatus can be shut down temporarily to replace the silica gel cartridge.
Removal of all water from the gas stream is essential to accurately measuring the dry gas
volume of the sample.
Sample train configuration is as shown in Figure 1.
3.0 Sample Storage
Following collection of the sample, sealed end caps will be placed on both ends of
the cartridge and the cartridge will be kept on ice in a contaminant-free container. The
intention of the method is to store samples only temporarily until analysis can be
performed by thermal desorption into the FTIR gas cell. Such analysis will, in all
likelihood, be performed in the field within a few hours of sample collection. Sample
storage procedures of this method, however, are identical to those of SW-846, Method
0030, which specifies a holding time of 14 days prior to analysis.
-------
4.0 QA/QC Spiking and Blanks
In an effort to somewhat duplicate the QA/QC procedures frequently associated with
other methods of sorbent tube sampling, the use of surrogate spikes and analysis of blank
traps is included in this method. Application of these procedures, however, must be
dictated by the practical aspects of field sampling conditions and the analytical matrix of
the actual gas samples. Thus, the following QA/QC procedures should be considered
only as guidelines and subject to modification under field conditions.
4.1 Surrogate Spiking
During collection of the actual field samples, traps will be simultaneously spiked
with an appropriate, non-native surrogate compound which is both effectively retained by
Tenax and which displays a distinct, identifiable infrared absorbance spectrum. Spiking
with such surrogates will demonstrate that losses are not occurring due to the sampling
equipment itself, and will also verify effective retention and recovery by the Tenax
sorbent bed. Since it may be difficult to choose a priori a compound or compounds
which are non-native, the operator may wish to examine the use of deuterated species for
use as surrogates. Deuterated species which are commonly used with Tenax-based
analytical systems and which are expected to display useful infrared spectral features
include:
Chlorobenzene-d5
1,4-Dichlorobenzene-d4
1,2-Dichlorobenzene-d4
Dichloroethane-d4
Toluene-d8
Non-deuterated species which are also commonly used for other Tenax-based
analysis also include:
1,4-Difluorobenzene
4-Bromofluorobenzene
Dibromofluoromethane
Pentafiuorobenzene
Fluorobenzene
If possible, the surrogate compound(s) will be purchased as a compressed cylinder
gas in nitrogen. Concentrations will be chosen as necessary to establish the necessary
spiking level. Some consideration should be given to choosing the gas concentration,
since this gas will be used to (1) perform the surrogate spike onto the Tenax trap, and (2)
directly fill the FTIR gas cell to generate a reference spectrum for analysis of the
surrogate recovery. Gas concentrations should approximate the levels expected in the
trap after sample collection (i.e. 20x, 50x, etc., the source gas concentration). Note that
-------
two or more gas cylinders at different concentrations may be necessary to generate proper
spiking levels in the concentrated trap and direct to the gas cell (for reference spectrum).
On-line surrogate spiking procedure with compressed gases involves first connecting
the compressed gas cylinder to a calibrated flowmeter and then connecting to a tee on the
back of the sampling probe. During the time of operation for the sampling train (1-hr or
more), surrogate gas is metered directly into the back of the sampling probe and drawn
through the sampling train along with actual source gases. An accurate record of the
surrogate gas flowrate and exact length of time for the spike must be kept, allowing the
measured volume of the spike to be calculated. The measured volume of surrogate gas
should ideally be such that the amount collected by the Tenax trap, and thus the expected
cell concentration as determined by FTIR, is fairly close to the concentrations of the
compressed gas standard (which directly fills the FTIR gas cell to generate the recovery
reference spectrum).
In situations where the practical constraints of field sampling will not allow on-line
surrogate sampling to be performed, a post-test laboratory spiking procedure may be
useful. To perform this type of surrogate spike, connect the compressed gas cylinder to a
calibrated rotometer, and then connect directly to the concentrative FTIR Tenax trap. The
trap must be aligned in the same direction as sample collection was performed, so that
surrogate gas will flow in a cocurrent direction. The trap will be kept cold (<20 C) as per
normal sample collection, and a measured volume of surrogate gas will be allowed to
flow through the trap. Again, the measured volume of surrogate gas should ideally be
such that the amount collected by the Tenax trap, and thus the expected cell concentration
as determined by FTIR, is fairly close to the concentrations of the compressed gas
standard (which directly fills the FTIR gas cell to generate the recovery reference
spectrum).
A third option for surrogate spiking is also of use, especially in cases where the
surrogate compounds of interest not available in gas cylinders at the necessary
concentrations. In these cases, spiking can be performed by using a gastight syringe and
neat or mixed chemical solutions. Calculations must be performed to determine the
liquid volume needed to achieve the desired spiking level onto the trap and/or into the
FTIR gas cell. Using a heated injection port (120 C) to assure full vaporization of the
liquid, the measured syringe volume is injected into a flowing dry nitrogen stream (0.5
LPM). For spiking onto the trap, nitrogen flow will be maintained at 0.5 LPM for 10
minutes to assure full transfer of the spike to the Tenax bed. For injection of the standard
directly into the evacuated cell, dry nitrogen will be used to backfill the FTIR gas cell
until atmospheric pressure is achieved. Note that this method of spiking may introduce a
greater amount of imprecision in the spike and recovery determinations than does use of
compressed cylinder gases. Use of neat chemicals or chemical solutions for reference
spectrum generation will also generally introduce a greater degree of interference from
atmospheric water and carbon dioxide bands than does use of compressed cylinder gases,
which can be used to thoroughly flush the cell prior to spectral collection.
-------
4.2 Blank Traps
Whenever collecting trace levels of volatile organics on a sorbent material,
appropriate blanks must be collected and analyzed. The exact number and types of
blanks necessary will vary based upon field conditions, but the following should be
considered.
Train or Baseline Blank - In order to demonstrate cleanliness of the sampling
equipment itself, install a sorbent tube in the sampling system, connect the probe, and
sample approximately 100 L of clean air or dry nitrogen. Desorb the tube using normal
procedures and analyze the sample by FTIR to verify that the sampling system is clean.
Perform this procedure when the train is initially used at a new sampling location.
Upwind or Ambient Air Blank - To allow for correction for upwind or ambient air
contamination, install a sorbent tube in the sampling system, connect the probe, and
sample approximately 100 L of ambient air. Desorb the tube using normal procedures
and analyze by FTIR. Perform this procedure as necessary to determine upwind or
ambient air contamination, or to demonstrate cleanliness.
Field Blank - To determine any contamination which may occur during installation,
leak checking, and temporary storage of Tenax traps, collect a field blank sample by
taking the trap to the appropriate sampling location and removing the end caps from the
Tenax trap for a length of time simulating installation of two traps into the sampling
apparatus. Replace the end caps and place the samples in temporary storage (if used).
Desorb the tube using normal procedures and analyze by FTIR.
Trip Blank - For samples which will be stored prior to analysis, a blank trap will be
kept in each individual container used for sample storage and analyzed for background
contamination. These samples will be treated like any other cartridge except that the end
caps will not be removed during storage at the site. Note that for many applications of
the concentrative FTIR method, samples will be stored for approximately 4-hrs or less
and will be analyzed in the field, eliminating the need for trip blanks.
5.0 Thermal Desorption
The thermal desorption procedure involves connecting the Tenax trap to an
evacuated FTIR gas cell, heating the trap to the appropriate temperature, and flushing the
heated trap with dry nitrogen directly into the evacuated gas cell until full cell pressure is
obtained. Analysis can then be performed by FTIR. The following paragraphs provide
greater details for the thermal desorption procedure.
Thermocouple placement and temperature control for the thermal desorber have been
established in previous experiments. Since the concentrative FTIR cartridge is much
larger than traditional Tenax-based sampling cartridges, heat wraps, insulation, and
-------
thermocouples may have localized effects. Such effects may ultimately cause
degradation of the Tenax and/or poor recovery of the sample.
Similarly, MRI lab personnel have observed thermal degradation of Tenax at 250 C,
which, although specified by SW-846, Method 0030 (VOST), potentially leads to poor
sample retention and recovery. MRI analysts routinely use thermal desorption
temperatures of 200 C for normal VOST analysis without sample loss, and in 1993-94
MRI demonstrated quantitative recovery of the concentrated samples at a thermal
desorption temperature of 220 C. Although not physically measured with a
thermocouple, it was believed that a shell temperature of 220 C would assure a 200 C
temperature at the core of the larger 10-g cartridge.
In order to limit interferences from water in the infrared spectrum, traps will be
"dried" prior to analysis. This will be accomplished by maintaining the trap at a cold
temperature and purging it with dry nitrogen for 8-10 minutes. Nitrogen flow is expected
to be about 2.5 LPM, and will be co-current with the direction of sample flow. Water
purged from the trap in this manner will not be retained as part of the condensate fraction.
Note that for ambient air or low moisture sources, this "drying" phase may not be
necessary. The amount of water present with MRI's straight tube design is expected to be
significantly less than the amount present with Entropy's previous U-tube design, since
any water drawn through the trap will drop out directly into a catch flask.
Thermal desorption of the traps will be accomplished by using an insulated tubular
heater monitored by thermocouples at two locations. The trap will be placed in the heater
with flow aligned countercurrent to the sampling flow direction. The upstream end of the
trap will be connected to a mass flowmeter or similar precision device and connected to a
gas stream of prepurified dry nitrogen. The downstream end of the trap will be connected
to the inlet of the FTIR gas cell. Prior to desorption of the trap, the FTIR gas cell will be
thoroughly purged with dry nitrogen and evacuated.
Upon initiating the heating cycle (ramp up), nitrogen flow will be maintained
through the trap at 0.10 LPM. This flow is necessary to insure heating in the absence of
oxygen, which could otherwise contribute to thermal degradation of the Tenax. Upon
reaching full temperature (220 C), nitrogen flow will be raised to 0.45 LPM. Flow will
then be maintained at 0.45 LPM until full cell pressure is achieved (nominally 760 mm
Hg). Typical times for desorption should be approximately 5 minutes for the ramp up
cycle and 12-15 minutes for desorption at 0.45 LPM. Previous work performed by MRI
demonstrated that complete desorption occurred will before the 15 minute desorption
cycle was finished.
Since the sample concentration methods described in this document are intended to
provide samples for field analysis, used Tenax traps will not necessarily be returned to
the laboratory for analysis and cleanup before reuse. Thus, to clearly demonstrate
thorough desorption of the samples, and that individual traps may be returned to use, it is
necessary to perform a second thermal desorption and analysis of each trap. Desorption
-------
and analysis procedures for the second desorption are identical to those followed for the
first desorption. Following the second desorption and verification of trap cleanliness, the
trap is again ready to collect field samples. Should the trap show contamination,
additional desorptions will be performed as necessary to clean the trap and/or the trap will
be removed from service.
Figure 2 shows the equipment configuration for thermal desorption.
6.0 Analysis by FTIR
Sample analysis will follow EPA Method 320, Measurement of Vapor Phase Organic
and Inorganic Emissions by Extractive FTIR. Due to the thermal desorption mechanism
by which sample is introduced into the gas cell, "Batch" mode must be used to collect the
sample spectrum.
7.0 References
1. Entropy Environmentalists, Inc., 1993-1994.
2. Midwest Research Institute, 1993-1994.
3. SW-846, Method 0030, Volatile Organic Sampling Train (VOST), September 1986.
-------
Sample Charcoal
valve tube valve
Latex tubing
I Latex
tubing
Teflon
tubing
B Absorbant
trap with
Tenax
A, B, C, and D =
Viton 0-ringed
nickel-plated fittings
T/C = Thermocouple
to pyrometer
Vacuum Leak Vacuum
gauge check gauge
valve /^x course
1 t*J adjust
Fine
adjust
Leak
check
valve
2
0
Exhaust
Rotameter
Remote ice bath
with submersible
pump
Pump
Dry gas
meter
Figure 1. Sample Concentrating System
-------
Vacuum Pump
Mass
Flowmeter
Thermal
Desorber
Heated Line
"£ '
22-m Path White Cell
N2
Figure 2. Thermal Desorber System
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Date
47&S, 08".
Run No.
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
/VV3
Desired Probe/STL Temperature
Desired Sampling Rate _
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling _
After Sampling _
in. Hg
- 30 ft.
>2 in. Hg
°C
Sample Type* "Tr;
Client
Sampling Location
Operator
ra<
Liters/min
Liters
in.
Metering Console No. _
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
&.
Tenax Inlet Thermocouple No.
Temperature Meter No. X-
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
in. Hg vacuum for
in. Hg vacuum for
A/A
in.
sec.
sec.
Leak Cr
Before
After
leek from Valve at Inle
Sampling O
Sampling O
t to First Cc
in. Hg chan
in. Hg chan
jndenser:
ae at s*3 in.
ge at ^2 in.
Hg vacuum
Hg vacuum
for fao sec.
for 6D sec.
Notes on Spiking:
Time,
24-Hr
/^£
%*6
/voC,
htt
;73t*
/Kb
mi*
DGM
Reading,
Liters
O.OO6
;j,;3
Mo.iB
IWfM.O&
£X4&>
78-, 04
93*340
DGM'
Temp.,
°C
3#.
32
32
3-y~
&x
S3
Probe/STL
Temp.,
°C
M
^V#
tf#
Mfl
AStf
A/fl
1st Tube
Inlet
Temp.,°C
#>
#)
#J
SI
/?
/ff
/92K
Pump
Vacuum,
in. Hg
^
3
3
y
y
y
-
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
M/l
Date
r
0
Run No.
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type1
Client
us
Desired Probe/STL Temperature
Desired Sampling Rate f>S"^
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No.
in. Hg
| ft.
in. Hg
°C
Sampling Location
Operator
Liters/min
Liters
in.
Metering Console No.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
Tenax Inlet Thermocouple No.
Temperature Meter No. ;_
V/-
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling
After Sampling _
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
in. Hg vacuum for
in. Hg vacuum for
A/ZE
in.
sec.
sec.
Leak Check from Valve at Inle
Before Samolina O. CJ
After
Samplina O>0
it to First C
in. Hg chan
in. Hg char
andenser:
ae at ZO, ^ in.
iae at tf<0 in.
Hg vacuum
Hg vacuurr
for v>O sec.
i for 0 O sec.
Notes on Spiking:
Time,
24-Hr
I ^i^O
/njO Q
((Of
t&ff
l£?3f
L6>3T
GylT
f»5lf
DGM
Reading,
Liters
0,00
/,5"I£0
^7. 2.0
2
-------
TEIMAX CONCENTRATED SAMPLE COLLECTION DATA
Run No. /re./)r* Date
Project No. */ *JQ)-..
Barometric Pressure 2. 9. ? */
Barometer to Location Elevation
Corrected Baro. Pressure *£?• JV
Sample Type'
Client
_a
Desired Probe/STL Temperature
Desired Sampling Rate //o
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material r
First Tenax Tube No. 5TV -
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling
After Sampling
Hg
_ ft.
in. Hg
°C
Sampling Location
Operator
Liters/min
Liters
Metering Console No.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple No.
Temperature Meter No.
1-1
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material '
in. Hg vacuum for
in. Hg vacuum for
in.
sec.
sec.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling C)>O in. Hg change at /_
After Sampling _ 0 t£) in. Hg change at
in. Hg vacuum for
. in. Hg vacuum for
slotes on Spiking:
"ime,
24-Hr
flfaV
£/
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No. rre/irti Date 77 <•
Project No. V^O/' O&-- C& ~
Barometric Pressure "Z^9-S^
Barometer to Location Elevation
Corrected Baro. Pressure £/7. J
Desired Probe/STL Temperature^
Desired Sampling Rate />o
Desired Sample Volume Y(J
Probe In-Stack Length X//X
Probe Liner Material tr/S
First Tenax Tube No. 5
Second Tenax Tube No. /?A
Leak Check from Probe Inlet:
Before Sampling K/0- in.
After Sampling A/# in.
Leak Check from Valve at Inlet tc
Before Sampling 0'\J. in.
After Sampling O iC..' in.
tc/Y?
ny
in. Ha
O ft.
'
in. Hg vacuum for
in. Ha vacuum for
»er: ^,
/tf.S in. Ha vacuum for
£/,Cf in. Hg vacuum for
€/7/A> AJ/^/r
^X?
\ a^ "Tvatir 1 £*.-Jv-r/nr e
\/OS7'3
Q-ttz-
LT- n
r?
'39 )fr~
Al/t?
tyty.
/ti in.
/£
sec.
sec.
(oO sec.
(j)O sec.
^Jotes on Spiking:
Time,
24-Hr
7225"
123$?
fuels'
\*gg
fr30,T
73/£^
I^ZfT
DGM
Reading,
Liters
O,O
|l/ 0^
"7Q O^L/
y ^j 4? \
tfO, /Z-
ff\ r^^ | ^J
/ O^ I ^^^
CjQ iff
DGM"
Temp.,
°C
30
3 2.
jy
35^
"3&
/
-------
Run No. / Date
Project No. V/7^.//
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Sample Type
Client
36>o
Desired Probe/STL Temperature
Desired Sampling Rate
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No.
in. Hg
ft.
in. Hg
°C
Sampling Location
Operator t/>
Liters/min
Liters
Metering Console No.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple No.
Temperature Meter No.
Second Tenax Tube No. 3'\J~J£>/
Leak Check from Probe Inlet:
Before Sampling O,&Q
After Sampling 0*°®
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. f-
Heated STL Length
STL Tubing Material _
in. Hg vacuum for
in. Hg vacuum for
in.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling O,0& in. Hg change at _
After Sampling £>>OO jn. Hg change at _
in. Hg vacuum for.
. in. Hg vacuum for
. sec.
sec.
sec.
sec.
otes on Spiking:
Time,
24-Hr
DGM
Reading,
Liters
DGM"
Temp.,
°C
robe/STL
Temp.,
°C
1st Tube
Inlet
emp.,°C
Pump
Vacuum,
in. Hg
totameter
Setting
Remarks
ff.POO
iff
/vo
in*
393 L
31
tfi
Mo
AS'*
/<$-<>
J7
S
90,0}
/to
/9
MD)
/&£/!
40
/<*
/yo
/So
J7
JJ
tf
3
0V***"
* Ambient air, train blank, preliminary, duplicate train, or source sample.
SUPBVOST.WPD July 16, 1998
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No. & Date
Project No. tf^ff/, OS",
Barometric Pressure }
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type
Client
Desired Probe/STL Temperature
Desired Sampling Rate _
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
in. Hg
ft.
in. Hg
°C
Sampling Location
Operator 5
Liters/min
Liters
in.
Metering Console No..
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
Tenax Inlet Thermocouple No.
Temperature Meter No. Y-
in. Hg change at
in. Hg change at
Leak Check from Probe Inlet:
Before Sampling
After
Leak Check frorn valve at Inlet to First Condenser:
Before Sampling J O>OO in. Hg change at
After Sampling//M&&£gT in. Ha change at
Temperature Controller No.,
Temperature Meter No. f^
Heated STL Length 6>D
STL Tubing Material 7^/>
in. Hg vacuum for
in.
Notes on Spiking:
. in. Hg vacuum for
in. Hg vacuum for.
. in. Hg vacuum for
6>o
. sec.
. sec.
sec.
sec.
Time,
24-Hr
^"-4^
'#0$
DGM
Reading,
Liters
90,13.
JJ7.V3
332.30
DGM"
Temp.,
°C
33
37
37
3*
38
37
Probe/STL
Temp.,
°C
Mo
we
1st Tube
Inlet
Temp.,°C
/v
/v
i?
/7
Pump
Vacuum,
in. Hg
3
3
3
Rotameter
Setting
/&&
Remarks
***•
"*
•
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
?/^/y-
Date
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type11
Client
US
in.
O
Desired Probe/STL Temperature^
Desired Sampling Rate _
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling O-O
After Sampling Q, O
Hg
ft.
in. Hg
Sampling Location
Operator
/if
Liters/min
Liters
in.
Metering Console No. \_/oS7'
Dry Gas Meter Correction (Y\ O<
Sampling Train Unit No. C2.
Tenax Inlet Thermocouple No.
Temperature Meter No.
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. _
Heated STL Length _
STL Tubing Material _
O in. Hg vacuum for
$v
Lin .
J w^d^Vy
/o^i zy
DGM"
Temp.,
°C
3Q
20
O\
^3
^V
?,S^
9^^
zn
g£ ^.jV^i
6^^
/7W/ (Jot
Probe/STL
Temp.,
/QfJ
100
106
101
|O5^
M
/07
/c;)
'uflA
1 st Tube
Inlet
Temp.,°C
/<0
l(n
iS^
ly*
Is"*
/$"*
i s~
\ y
Pump
Vacuum,
in. Hg
/'••S —
/. 5^
'1,1
/^^^
t ^^
l^T"
h^
/. S~
t ^f ^"
^otameter
Setting
1^
'/Zt
12^
ItD
I2O
_Z/5r"
jl'5'
IZO
Remarks
£76/0
STkjP
•f-f'okj
"Ambient air, train blank, preliminary, duplicate train, or source sample.
SUPRVOST.WPD July 16, 1998
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Date
Run No. /_
Project No. .
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type
Client
Desired Probe/STL Temperature
Desired Sampling Rate _
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No. -5i
Leak Check from Probe Inlet:
Before Sampling O,ot>
After Sampling . £>,&&
in. Hg
ft.
in. Hg
°C
Sampling Location
Operator P
Sampling 0,& t>
t to First C<
in. Hg chan
in. Hg char
andenser:
ge at #3 in.
ae at ^7 in.
Hg vacuum
Hg vacuurr
for ^^ sec.
for 6 ^ sec.
Notes on Spiking:
Time,
24-Hr
69$yo
$39130
IdD'i'.Za
ffilBlfr
/SO&
W/S"
W3
DGM
Reading,
Liters
0.000
/&.*&.
J9.JX
TRS-tcffip&C/ .
6.OOO
/&•*£
J&.ldO
^&&15~
DGM"
Temp.,
^t?
3tff
$lj
t3-r»f>J;rt$.
£6r
gg"
£*rj>&f>tJ
'?&'•?'&:
Probe/STL
Temp.,
°C
/#£.
^*&
ft/-2-
-/.caUCkitU.
/43
/#3
SJr»p)ln£\'
'tb&etf
\ st Tube
Inlet
Temp.,°C
/^
/3
//
6,£>0chi*4<.
Jt>
/*J
'lerU&t*
Pump
Vacuum,
in. Hg
^
J
3
& *i&"H6
3
3
O.eOtterr^
Rotameter
Setting
/£"O
/5"0
S&O
tr>t,0jec,,
/^O
;g~&
t,e Wriq
^
.-
Remarks
»* ^fcj4 ^fjl
/ /y fytS^ Cfc»- *•
* Ambient air, train blank, preliminary, duplicate train, or source sample.
• SUPRVOST.WPD July 16. 1998
-------
Run No. J Date
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure 2-7•
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Sample Type'
Client
S
in. Hg
ft.
Sampling Location
Operator
in. Hg Metering Console No.
VosT J
3BP
Desired Probe/STL Temperature
Desired Sampling Rate /.o
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling rti Q
After Sampling
Liters/min
Liters
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple r4o. 7
Temperature Meter No. !/-
in. Hg change at.
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
]/ in. Hg vacuum for
in. Hg vacuum for
sec.
sec.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling O>O in. Hg change at /ff O
After Sampling C?/O in. Hg change at
in. Hg vacuum for
in. Hg vacuum for
AcL
*Ambient air, train blank, preliminary, duplicaTe train, or source sample
SUPRVOST.WPD July 16, 1998
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No. L
Project No. QQOl-
Date
Sample Type*_
Client (A
2?.
Barometric Pressure _
Barometer to Location Elevation O
Corrected Baro. Pressure 2>9»Ss
Sampling Location
Operator
in. Hg
ft.
in. Hg Metering Console No.
Liters/min
Liters
in.
Desired Probe/STL Temperature .
Desired Sampling Rate / J
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling in. Hg change at
After Sampling in. Hg change at
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
O,
\
Tenax Inlet Thermocouple No.
Temperature Meter No.
.Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
in.
in. Hg vacuum
vacuum for
Leak Ch
Before
After
ieck from Valve at Inle
Sampling — - — • "
,**~--~~' —
Sampling
t_tp_£irsLC<
in. Hg chan
in. Hg chan
wdertSerT \jn vj>|
ge at ' in.
ge at in.
Hg vacuum
Hg vacuum
for sec.
for sec.
Motes on Spiking:
Time,
24- Hr
itn
\2£1
ifV
/£
-------
TEIMAX CONCENTRATED SAMPLE COLLECTION DATA
Date
Run No. /_
Project No. _
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type
Client
Desired Probe/STL Temperature
Desired Sampling Rate /*^"
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling ^
After Sampling 0_
in. Hg
ft.
. in. Hg
°C
Sampling Location
Operator
Metering Console No. \SQSf}
Liters/min
Liters
in.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
Tenax Inlet Thermocouple No.
Temperature Meter No.
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. j^
Heated STL Length
STL Tubing Material _
in. Hg vacuum for
in. Hg vacuum for
in.
sec.
sec.
Leak Ch
Before I
After
eck from Valve at Inle
Sampling 0,00
Samplina 0.0 &
t to First Cc
in. Hg chan
in. Hg chan
indenser:
ge at ^W in.
ge at *W in.
Hg vacuum
Hg vacuum
for 6>£> sec.
for <^C* sec.
Motes on Spiking:
"ime,
24-Hr
V&Q
ono
w/o
0130
&BDO
6301
48*2
0908
0?tf!30
O&BSO
OW30
OWJ30
tf&JJO
/0oMo
Mi 39
telll'to
/03&:oD
DGM
Reading,
Liters
Q,t>06
&.of
3&)£
4gJ%
b0.2>-j
6>/,89o
0>OOO
M96
32,30
a. 000
W.9S
30,09
VSJg'
£,0,40
V&ZG'
90-37
/eSfgo
DOM"
Temp.,
°C
#0
#0
4J
/
?&,
6^fffcis
Probe/STL
Temp.,
°C
/v/
/#*
MJ
;v;
M)
•*^0)>'/tA~-i,L
'/•&
MJ
*}f>X»A-le'
nd
/*Z
Jt-3
S*3
S43
/*3
;+3
>*tf>Jirt4
^
1st Tube
Inlet
Temp.,°C
/£
S3
;$.
SJ
jj
3)*&ietMO
/&
S3
eJZ£J}OJi.0.
/*
sz
Jl
U
J#
J*
/£
Pump
Vacuum,
in. Hg
J?
3
_?
3
3
ODefr3r>e\ot.
3 "
3
46 e>)3*ji. &
3
3
3
J
3
3
'»*> A/
/&t>
;&
3.7"AA) A^
/go
&z>
S&D
/£~i>
J3~0
;&D
S^D
Remarks
(eOft.t*'
&03£<^
* Ambient air, train blank, preliminary, duplicate train, or source sample.
SUPRVOST.WPD July 16, 1998
-------
TEIMAX CONCENTRATED SAMPLE COLLECTION DATA
Sample Type
Client
Run No. " -JL" ' Date
Project No.
Barometric Pressure _
Barometer to Location Elevation
Corrected Baro. Pressure 2-9.33
in.
O
Desired Probe/STL Temperature
Desired Sampling Rate _
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No. 5V" )0l
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling O'> 0
After Sampling
Hg
_^ ft.
in. Hg
/or" •&
_ Liters/rnin
Liters
' in.
Sampling Location
Operator
Metering Console No. \JnsT
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
O.WSL
Tenax Inlet Thermocouple No.
Temperature Meter No.
in. Hg change at.
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
in. Hg vacuum for
in. Hg vacuum for
/3
in.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling £?. 0 in. Hg change at _
After Samplinq O ,Q jn. Hq change at
7
in. Hg vacuum for.
in. Hg vacuum for
£
. sec.
. sec.
sec.
sec.
Notes on Spiking:
Time,
24-Hr
DGM
Reading,
Liters
DGM"
Temp.,
°C
Probe/STL
Temp.,
°C
1 st Tube
Inlet
Temp.,°C
Pump
Vacuum,
in. Hg
^otameter
Setting
Remarks
/^o
^/
06
7737
/OS"
+G€-
l-zz,
0870
It,
2,-cy
iz-z
on.
25^
106
IS"
•e, o
/Of?
16
/
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No. .*" Date
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure 9 \
Sample Type
Client
So v tee-
Desired Probe/STL Temperature
Desired Sampling Rate
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
in. Hg
ft.
in.Hg Metering Console No.
Sampling Location
Operator
-------
Run No. <£ Date
Project No. 4*7^
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Sample Type
Client
Desired Probe/STL Temperature
Desired Sampling Rate .
Desired Sample Volume
Probe In-Stack Length _
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling <
After Sampling i
in. Hg
ft.
Hg
°C
Sampling Location
Operator \),
in.
Liters/min
_ Liters
Metering Console No.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple No.
Temperature Meter No. Y-
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. Y_
Heated STL Length
STL Tubing Material
in. Hg vacuum for
in. Hg vacuum for
in.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling 0.0O in. Hg change at _
After Sampling 0*00 in. Hg change at.
in. Hg vacuum for.
, in. Hg vacuum for
&O
. sec.
. sec.
sec.
sec.
Notes on Spiking:
Time,
24-Hr
DGM
Reading,
Liters
DGM'
Temp.,
°C
Probe/STL
Temp.,
°C
1 st Tube
Inlet
Temp.,°C
Pump
Vacuum,
in. Hg
Rotameter
Setting
Remarks
0,000
6T3&
Jl
0,000
3
30.
ft.
O.6OO
J4-3
*Ambient air, train blank, preliminary, duplicate train, or source sample.
SUPRVOST.WPD July 16, 1998
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No.
Date
Project No. W0h Of*
Sample Type'
Client
s~
-So
ource
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure 2*?.
O
in. Hg
ft.
in. Hg Metering Console No.
Sampling Location
Operator
Desired Probe/STL Temperatures,
Desired Sampling Rate A o
Desired Sample Volume _
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No.
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling O.O
After Sampling QtQ
C/g-fT"
_ Liters/mm'
0 Liters
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple No.
Temperature Meter No. V-
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No. :
Haated STL Length /W
STL Tubing Material
in. Hg vacuum for
in.
(Lo , n in. Hg vacuum for
Leak Check from Valve at Inlet to First Condenser:
Before Sampling ^>O in. Hg change at
After Sampling n, 0 in. Hg change at
V. O
. in. Hg vacuum for.
. in. Hg vacuum for
. sec.
. sec.
sec.
sec.
otes on Spiking:
irne,
24-Hr
DGM
Reading,
Liters
DGM"
Temp.,
°C
robe/STL
Temp.,
°C
1st Tube
Inlet
emp.,°C
Pump
Vacuum,
in. Hg
^otameter
Setting
Remarks
CKU3~
II
-30,
96
11
60, i
ypy
~M
IZrl
/Zl
ois"
s?,/
/•zt
1 Of
tlf
•zrt
is"
•37
/
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Date
Run No.
Project No,
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
Sample Type*.
Client
in.
Desired Probe/STL Temperature
Desired Sampling Rate // S
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No. 5
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling & CJ
After Sampling 0. • 0
Hg
pf ft.
ir^Hg
iO<^
Sampling Location
Operator _
Liters/min
Liters
Metering Console No.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
in.
Tenax Inlet Thermocouple No.
Temperature Meter No. V
v
on
in. Hg change at
in, Hg change at
Leak Check from Valve at Inlet to First Condenser:
Before Sampling O,O in. Hg change at "?.O,CJ
After Sampling C? >Q in. Hg change at V • p
Temperature Controller No.
Temperature Meter No. ^
Heated STL Length _,
STL Tubing Material
_ in. Hg vacuum for.
_ in. Hg vacuum for,
I /So* Z-
in.
, in. Hg vacuum for.
. in. Hg vacuum for
fa CJ
.sec.
.sec.
.sec.
sec.
Notes on Spiking:
Time,
24-Hr
DGM
Reading,
Liters
DGM
Temp.,
°C
Probe/STL
Temp.,
1 st Tube
Inlet
Temp.,°C
Pump
Vacuum,
in. Hg
Rotameter
Setting
Remarks
04 /O
n.ou
2,0
IC/.9/
JOJEL
Wvoilo
cwy
60, £3
\QG_
1QA.
J!L
z.o
fifiL
r-1 rfi
(Of
22-
M2£.
J£.
UL
am
23
-2,0
2eSL
/ZJ
S/0
/I
10H-
?/w
#
o
z,o
To^r
102-Z-
33
MO, 01
fQf
f
'Z.O
tz/
7,70, V
oto ?
*Ambrent air, train blank, preliminary, duplicate train, or source sample
SUPRVOST.WPD July 16, 1998
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
flm
Run No. 1/0*^3
Project No.
Date
-c
Sample Type*.
Client
Barometric Pressure f^/Pr
Barometer to Location Elevation
Corrected Baro. Pressure
in. Hg
ft.
Sampling Location
Operator
rev
?
Desired Proba/STL Temperature _
Desired Sampling Rate )/*?"
Desired Sample Volume .
Probe In-Stack Length
Probe Liner Material
First Tenax Tubs No.
Second Tenax Tube No..
Leak Check from Probe Inlet:
Before Sampling
After Sampling ...
in. Hg Metering Console No.
(0< »&?
Liters/min
Liters
in.
Dry Gas Meter Correction (Y)
Sampling Train Unit No.
5V H I
<^ to"7
in. Hg change at.
in. Hg change at
Tenax Inlet Thermocouple No.
Temperature Meter No. \
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
Ac*.
in.
in.
Leak Ch
Before !
After
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
Run No.
Date
Project No. <*/1Oh Og ~Cft
Barometric Pressure ^fA
Barometer to Location Elevation
Corrected Baro. Pressure
-QL)
s
f]
NtfC
in.
i
in.
Hg
ft.
Hg
Sample TypeH
Client
Sampling Location
Operator
Desired Probe/STL Temperature
Desired Sampling Rate
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material
First Tenax Tube No. ^
Second Tenax Tube No. J
Leak Check from Probe Inlet:
Before Sampling O/ 0
After Sampling . Or O
Metering Console No.
°fi,f Dry Gas Meter Correction (Y)
Liters/min Sampling Train Unit No.
Liters
in.
Tenax Inlet Thermocouple No.
Temperature Meter No.
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated SVL Length
STL^Tubing Material
•O in. Hg vacuum for
Q in. Hg vacuum for
in.
O
sec.
sec.
Leak Check from Valve at Inlet to First Condenser:
Before Sampling O > O in. Hg change at (¥'
After Sampling C/'Q jn Hg change at
-------
TENAX CONCENTRATED SAMPLE COLLECTION DATA
3> Date 1 hi fat
Run No.
Project No.
Barometric Pressure
Barometer to Location Elevation
Corrected Baro. Pressure
tftr
4-
Desired Probe/STL Temperature
Desired Sampling Rate
Desired Sample Volume
Probe In-Stack Length
Probe Liner Material .
First Tenax Tube No. 4ft/)o1
Second Tenax Tube No.
Leak Check from Probe Inlet:
Before Sampling
After Sampling ,
in. Hg
ft.
in. Hq
Sample Type*
Client
Sampling Location
Operator
Liters/min
Liters
in.
Metering Console No.
fif Dry Gas Meter Correction (Y)
Sampling Train Unit No.
Tenax Inlet Thermocouple No.
Temperature Meter No.
in. Hg change at
in. Hg change at
Temperature Controller No.
Temperature Meter No.
Heated STL Length
STL Tubing Material
in. Hg vacuum for
in.
in. Hg vagi,
Leak Cr
Before
After
leek from Valve at fnle
Samplina
Sampling ^ — -
t to First Cc
in. Hgcharj
~m. Hg~chan
mdenser:____^jr —
qe at in.
'75"^~~"7^?J?''
Hg vacuum
Hg vacuum
for sec.
for sec.
Notes on Spiking:
Time,
24-Hr
HZ3
ffS3
IN?
)l,^
DGM
Reading,
Liters
3/3^06
330.1/ff-
'3Qf,<3'2,
^o, OK
DGM
Temp.,
°C
y<5
Qy
Lig
uy
Probe/STL
Temp.,
°C
K,7
m
/"Z 7
/Z,^
1 st Tube
Inlet
Temp.,°C
/?•
J^f
/9f
/r
Pump
Vacuum,
in. Hg
3.0
C?xC>
T-O
•7,0
\ ota meter
Setting
/
-------
Appendix J
Equipment Calibration Data
MRI-AEDVR4951-04-08. wpd
-------
Estimated Quantitation Limits (QL, ppm) From FTIR Spectra of Direct Samples Taken From the Silo,
Loadout, and Process Stack Locations.
Compound Name
Acetaldehyde
Benzene
Carbonyl Sulfide
Methyl Chloride
Methyl Chloroform
1,1-dichloroethane
Toluene
1,3-Butadiene
Methanol
Cumene
Ethylbenzene
Hexane
Methylene chloride
Propionaldehyde
Styrene
1, 1,2,2-Tetrachloroethane
p-Xylene
o-Xylene
m-Xylene
2,2,4-Trimethylpentane
Formaldehyde
SO2
NO
NO2
N2O
Molar
Mass
(g/mol)
44.05
78.11
60.07
50.49
133.42
98.96
92.13
54.09
32.04
120.19
106.16
86.17
84.94
58.08
104.14
167.86
106.16
106.16
106.16
114.22
30.03
64.1
30.0
46.0
44.0
Silo
QL (ppm)
1.20
3.77
0.16
2.92
0.37
0.42
3.52
0.45
1.96
0.76
3.48
0.06
0.39
0.37
1.38
0.23
1.44
0.09
2.48
0.45
1.15
2.94
4.38
0.63
0.19
Loadout
QL (ppm)
0.34
1.89
0.07
3.83
0.41
0.45
2.4
0.5
0.78
0.38
2.06
0.21
0.35
0.82
1.31
0.32
1.08
0.68
0.79
0.25
0.48
0.36
1.21
0.20
0.024
Process
Stack
QL (ppm)
1.49
5.36
0.07
2.52
2.16
1.3
12.56
2.27
2.08
2.24
3.95
0.42
2.27
0.31
2.69
0.88
0.82
6.91
8.73
0.32
3.94
2.94
4.38
0.63
0.19
Differences in quantitation limits among the locations are primarily due to differences in moisture
concentration.
-------
ANEROID BAROMETER CALIBRATION CHECK
Location: Kansas City, Missouri
Altitude Above Sea Level: 91 3 feet
Latitude: 39° 05.8' north
Meteorological Gravity: 32.1 516 feet/second2
Mercury Barometer Description: Sargent Welch, Cat. S-4519, Lot 791802000
MRI Project No. 4701-08-03-04
Date: 7-14-98
Time: 1130
Readings Obtained By: D. Neal
Observed Barometer Reading: 29.21 in. Hg
Mercury Column Temperature: 74 °F
Correction For Temperature: -0.12 in. Hg
Correction For Gravity: -0.02 in. Hg
Corrected Barometric Pressure: 29.07 in. Hg
Aneroid Barometer I.D. No.: Y-2101
Reading -Before Adjustment: 29.06 in. Hg
Calibration Check Result: within 0.1 in. Hg
Reading After Adjustment: (lvK\ in. Hg
Remarks:
BAROMETR.WK4 02/27/95 (rev. BAROMTER.WK4 07/14/98 11:46 AM)
-------
ANEROID BAROMETER CALIBRATION CHECK
Location: Kansas City, Missouri
Altitude Above Sea Level: 913 feet
Latitude: 39° 05.8' north
Meteorological Gravity: 32.1 516 feet/second2
Mercury Barometer Description: Sargent Welch, Cat. S-451 9, Lot 791 802000
MRI Project No. 4701
Date: 8-12-98
Time: 1648
Readings Obtained By: D Neal
Observed Barometer Reading: 29.33 in. Hg
Mercury Column Temperature: 73 °F
Correction For Temperature: -0.11 in. Hg
Correction For Gravity: -0.02 in. Hg
Corrected Barometric Pressure: 29.20 in. Hg
Aneroid Barometer I.D. No.: y-2101
Reading Before Adjustment: 29.09 in. Hg
Calibration Check Result: NOT Satisfactory - Needs Adjustment
Reading After Adjustment: *-\ -7^ in. Hg
Remarks:
BAROMETR.WK4 02/27/95 (rev. BAROMTER.WK4 08/12/98 04:38 PM)
-------
GAL-BENCH SERIAL NUMBER AN0125. REV 8.00.06 CALIBRATION DATA
Test Date: 4/30/1998
Sierra Instruments, Inc.
5 Harris Court, Bldg. L
Monterey, CA 93940
File Name : c:\Records\RC31392\31392
Print Date: 4/30/1998
Due Date: 4/30/99
Device Under Test
Description: 30462
Model'*: 822S-L-2-OK1 -PV1 -V1 -A1
Serial No: 31392
Accuracy: 1% OF FS
Bypass: LFE
Orifice Size: N/A
Ambient Conditions
Gas Temperature:
Room Temperature:
Ambient Pressure':
Back Pressure:
Relative Humiditv:
71.8 Degrees F
73.8 Degrees F
29.67 In Hg
1.753 In H20
45.46 Percent
Master
Serial Number:
Full Scale Flow:
0125
5.0 SLPM
Temperature:
Pressure:
STP
70.0 Degrees F
29.92 In Hg
% Density N Cp
100.00 1.250 1 .000 0.248
GAS DATA
Name
Nitrogen, N2
Test Gas: Nitrogen, N2
Calculated K Factor is: 1.000
DATA
Full Scale Flow:
5.0 SLPM.
Voltage
VDC
0.000
1 .247
2. 507
3.730
5.022
Indicated Flow
SLPM
0.0000
1 .2467
2.5065
3.7305
5.0224
Actual Flow
SLPM
0.0000
1 .2562
2.5232
3.7486
5.0237
Erro
% Full :
0.0
-0.2
-0.3
-0.4
-0.0
Error
I Readin
0.0
-0.8
-0.7
-0.5
-0.0
Device Information
Vacuum Test: 5 x 10"- 9 Atm cc/sec (He)
Fittings: 1/4" COMP Sensor mV at Full Scale: N/A
Inlet Pressure: 10 PSIG Outlet Pressure: N/A
-------
0-Rings:
.lal Number:
KALREZ
31392
Valve Seat material: N/A
Test Date: 4/30/98
1 Bench Asset
H Meter Asset
M(s) Asset No
Test Equipment
No.: 0125
No.: 0125
: 0298
Barometer Asset No.: 0396
Thermometer Asset No.: 0125
Comments
5 VDC OUTPUT
-15 VDC INPUT POWER
.ibration Technician
Technician:
Date: V-
Date:
accuracy of this equipment is 0.2% of reading.
.gested recalibration due dates for the following critical items are
Cal=Bench System: 2/6/2000 D/A and A/D converters: 8/2/1998
ss Tube Diameters: 1/6/2000 System Clock: 8/2/1998
-------
Report'ofoZ&lilr ation
Hart Scientific, Inc.
799 East Utah Valley Drive
American Fork, Utah 84003-9775
Report No. 842726
Pa°e 1 of 1
Model:
9100A
Serial No.:
84414
Description:
Dry-Well, HDRC Handheld Block A
Received Condition:
New
Procedure:
HST042
Customer: '
Midwest Research Institute i
Kansas City, MO 64110 J
USA !
Calibration Range (Limited or Full): j
Full '
The standards used in this calibration are traceable to the National Institute of Standards and Technology (NIST1)
and/or constants of nature (intrinsic standards). The working standards listed are calibrated by comparison with a
Standard Platinum Resistance Thermometer (SPRT), Hart model 5681 (low temperatures), Hart model 5684
(high temperatures), and a Han Super Thermometer, model 1575. Calibration procedures are in accordance with
ITS - 90 and ANSI/NCSL Z540 - 1.
Set-Point °C JActual "CJError °C Set-Point °F'Actual °F lError °F
50.0
100.0
150.0
200.0
250.0
300.0
49.9
100.3
149.8
200.1
249.6
-0.1
0.3
-0.2
0.1
-0.4
300.0J 0.0
122.0
212.0
302.0
392.0
482.0
572.0
121.8
212.5
301.6
392.2
481.3
-0.2
0.5
-0.4
0.2
-0.7
572.0| 0.0
°C Calibration Constants: Zero: -0.2 Span: 0.9
°F Calibration Constants: Zero: -0.4 Span: 1.6
The temperature observations were made by comparison with the following test equipment.
Test Equipment —•
Instrument Model Serial No. Recall Date
Thermometer, "Super Thermometer" 1575
Probe, Secon. PRT, 100 ohm 3/16" x 6" 5613
Approximate Uncertainties: 50 to 300°C ±0.027°C
48048
468523
09/26/1998
05/06/1998
Performed by
Environmental Conditions:
Temperature: 25°C
Humidity: 27% RH
Approved by:
Date: 04/27/1998
This renon shall not be reoroditced excent in full without written aooroval of Hart Scientific. Inc.
-------
STACK THERMOCOUPLE CALIBRATION DATA FORM
Job No. 4701-08-03-04
Date 7-14-98
76
Stack Thermocouple No.
Probe No. TP-3
Barometer
TP-36
Ambient Temp. (°F)
Performed By D. Alburty Pyrometer No.
Avg. Stack Temp. (°F) 108
29.07
in. Hg
Y-3517
Reference Instrument: Hart Scientific 9100 HDRC Dry Well
Calibration Date: 4-27-98
Reference
Instrument
Temp. (°F)
86.0
122.0
212.0
Pyrometer Temp .
(°F)
86.2
121.8
212.2
Temp. Difference
(°F)
-0.2
0.2
-0.2
Temp.
Difference
(%)
-0.037
0.034
-0.030
(ref. temp., F + 460) - (pyro. temp., F + 460)
(ref. temp., F + 460)
x 100 <. 1.5%
calibrec\stcalfml
03/06/98
-------
I CERTIFICATE OF CALIBRATION AND TESTING
~ 2268
TSI Model- 835°
TSI Serial No.
Description VELOCrCALC PORTABLE AIR VELOCITY METER
Calibration Standard WIND TUNNEL CALIBRATION SYSTEM, SERIAL NO. 102
Calibration
Standard
34.7 ft/rain
65.4 ft/min
148.9 ft/min
325.4 ft/min
652.9 ft/min
999.0 ft/min
1478.4 ft/min
2515.1 ft/min
4492.7 ft/min
' 7006.5 ft/min
' 8758.3 ft/min
32.0 °F
140.0 °F
w ^- - ^ _ .
*
!*
.
UAULDlt/\l.UJJLN VCK.
Instrument
Output
35.0 ft/min
65.0 ft/min
149.7 ft/min
326.3 ft/min
652.5 ft/min
1011.9 ft/min
1502.6 ft/min
2563.8 ft/min
4488.5 ft/min
712T.O ft/min
8844.5 ft/min
32.0 °F
140.0 °F
• ••••".{Syfl^ffflJttS'-"11
Percent Error Compared to Tolerance
Difference Tolerance Tolerance
0.9
-0.6
0.5
0.3
-0.1
1.3
1.6
1.9
-0.1
1.7
1.0
/*«•* w J_rtf f *** i
• *
* •
• *
• *
*
*
*
*
*
*
*
•
T»~l — T in ifr-
±2.5% of reading ±2f/m (30-500),
±Wf/m (500-2000), ±50 f/m (2000-6000),
±100 fhn (6000-10000)
— Velocity Corrected to Std Conditions of: —
Ambient Temperature: 21.1°C
Barometric Pressure: 760. 0 mmHg
TSLIncorporated:doesh&eby-<&rnJy*tKai-allrmaterials, components, and workmanship used in the manufacture of this
equipment are;in1 strict accordancevrith-.the applicable specifications agreed upon by TSI and the customer and with all
\ published speciftcationK All peifoi numcer and-acceptance- tests- required under this contract were successfully conducted
according to required'specifications^. Furthermore; all test and. calibration data supplied by TSI has been obtained using
standards whose accwaciefaretraceabfeto-th^National Institute of Standards and Technology (NIST) or has been veri-
fied with respect to.Mstrumentation-whose-accuracy is-traceable to NIST, or is derived from accepted values of physical
\constants. Cal&ratafr procedures for thfr.instnment comply with MIL-STD-45662A. The accuracy cf the calibration
facilities is- greater tna^a ratio- of '1:1 with- respect to the accuracy specifications of the instrument being calibrated.
Applicable Test Reports
DC voltage
Barometric- Pressure
Temperature CO°C)
(19-35°C)
(60°C)
Pressure
Velocity
Dewpoint
TSI Incorpo
Enviromnent
and Controls Division
Report Number
811/253708-94
P-8264
254798
203537
216642
822/255443-95
822/254253-94
836/254822
2S7589
Spinal
''Function Check
Date Last Verified
08-05-97
05-16-97
04-10-97
04-10-97
10-24-96
04-22-97
04-22-97
01-23-95
02-12-97
Nov 20, 1997
ents
Calibration Date
Mailing Address: P.O. Box 64394 St. Paul, MN 55164 USA
Shipping Address: 500 Cardigan Road Shoreview, MN 55126 USA
Phone: (800)-777-8356 or (612) 490-2888 Fax: (612) 490-2874
-------
DATE
NUMBER
TYPE
RANGE
CAL.
TRANSDUCER -
/oe> o
AT
o>
en
oo
LINEARITY DEVIATION VS. PRESSURE
O
- 0.5%
-f 0.5%
0.5%
- 0.5%
-FULL
SCALE
+FULL
SCALE
Q
-------
EDWARDS
BY
DATE
TRANSDUCER
SERIAL
NUMBER
TYPE
RANGE
CAL.
AT
O)
o>
oo
LINEARITY DEVIATION VS. PRESSURE
CD
§
Q
- 0.5%
+ 0.5%
+ 0.5%
-FULL
SCALE
- 0.5%
+FULL
SCALE
-------
WET TEST METER CALIBRATION
Using ASTM Method D 1071 - 83 (Reapproved 1993)
MRI Project No.
Date:
Operator:
Leak Checks:
NA
05/02/97
J. Surman
No leaks
Wet Test Meter No.
Previous Wet Test Meter Factor (Yw):
Temperature Meter No.
Balance No.
X-2538
0.9970
Y-0815
011907
;ALIBRATION DATA
Ambient Data:
Barometric Pressure, in. Hg
Room Temperature, °F
Relative Humidity, percent
'roportion of Water Vapor By Volume in ambient air
Wet Test Meter Data:
Initial Wet Test Meter Gas Volume, wet liters
Final Wet Test Meter Gas Volume, wet liters
Net Wet Test Meter Gas Volume (Vm), wet liters
Wet Test Meter Gas Temperature (tm), °F
Pressure at Wet Test Meter Inlet, in. w.c.
Aspirator Bottle System Data:
Bottle Temperature, "F
Bottle Pressure, in. w.c.
Flow Rate Data:
Time, seconds
Gas Flow Rate, actual dry liters/minute
Average Gas Flow Rate, actual dry liters/minute
Water Displacement Data:
Receptacle A Tare Weight, grams
Receptacle A Gross Weight, grams
Receptacle B Tare Weight, grams
Receptacle B Gross Weight, grams
Receptacle C Tare Weight, grams
Receptacle C Gross Weight, grams
Weight of Water Collected, grams
Buoyancy factor
Correction for Buoyancy, grams
Density of Water at Bottle Temperature, g/mL
Correction for Density of Water at Bottle
Temperature to Density at 39.2 *F, grams
Correction for Temperature Difference, grams
Correction for Pressure Difference, grams
Corresponding Weight of Water
at Maximum Density, grams
Equivalent Volume, liters
CALIBRATION RESULTS
Wet Test Meter Calibration Factor (Yw)
Acceptability Criterion: 0.99 < Yw < 1.01
Tolerance Result:
Average Wet Test Meter Calibration Factor (Yw)
Run 1
71.5
-1.23
71.1
-1.32
545
0.99
1.00
124.6
3,840.9
121.9
3,742.9
122.7
1.766.0
8,980.6
0.00101
9.04
0.99788
19.08
6.77
1.0019
Run 2
71.5
-1.23
71.2
-1.32
543
1.00
124.0
3,863.0
122.8
3,791.0
121.0
1,693.2
8,979.4
0.00101
9.04
0.99786
19.26
5.07
Run3
71.6
-1.23
71.3
-1.32
540
1.00
123.6
3,832.2
123.2
3,775.2
123.4
1,750.0
8,987.2
0.00101
9.05
0.99786
19.27
5.08
Remarks:
WTMCALB.WK4 09/07/96 (rev. WTM70502.WK4 05/02/97 03:31 PM)
-------
VOST METERING CONSOLE CALIBRATION WITH WET TEST METER
MRI Project No.
Date:
Operator:
^4701-08-03-04
8/13/98
B. Edwards
Metering Console No.
Previous Dry Gas Meter Factor (Y):
Calibrated Wet Test Meter No.
Wet Test Meter Factor (Yw):
Temperature Meter No.
Vostl
0.971
X-2538
1.0019
Y-0815
CALIBRATION DATA
Barometric Pressure, in. Hg
VOST Data
Initial Dry Gas Meter Volume, dry liters
Final Dry Gas Meter Volume, dry liters
Net Dry Gas Meter Valume (Vm), dry liters
Dry Gas Meter Temperature, °C:
Initial Inlet Temperature, °C
Final Inlet Temperature, °C
Initial Outlet Temperature*, *C
Final Outlet Temperature*, °C
Average Dry Gas Meter Temperature (tm), °C
Time, seconds
Rotameter Setting
Wet Test Meter Data
Initial Wet Test Meter Gas Volume, wet liters
Final Wet Test Meter Gas Volume, wet liters
Net Wet Test Meter Gas Volume (Vm), wet liters
Wet Test Meter Gas Temperature, °F:
Initial Temperature, °F
Final Temperature, °F
Average Wet Test Meter Gas Temperature (tm), °F
Pressure At Wet Test Meter Inlet, in. w.c.
COMPUTED CALIBRATION RESULTS
Gas Flow Rate, actual dry liters/minute
Average Gas Flow Rate, actual dry liters/minute
Dry Gas Meter Volume (Vm(std)), dry std. liters
Wet Test Meter Gas Volume (Vm(std)), dry std. liters
Dry Gas Meter Calibration Factor (Y)
Average Dry Gas Meter Calibration Factor (Y)
CALIBRATION RESULTS COMPARISON
Criterion: Y Must Be Within 2% Of Average Y
Percent Difference Of Y From Average Y
Tolerance Result
COMPARISON WITH PRETEST RESULTS
Criterion: Y Must Be Within 5% Of Previous Y
% Difference Of Average Y From Previous Y
Tolerance Result
Run 1
29*22'"""*"" '
y.5$|W^IM^*Jfe'
0.000
16.910
16.910
'SQ'A*
26.6
26.5
600
140
J\iV'^f-^-:'*f!:|^?!«/£*4|ji-
0.000
16.600
16.600
i'^iSfc i'xi'ASi-.fe; Ui£
70.0
70.5
70.3
-2.8
;&feSX ^ >4< ;VV^A 's
•.A>.!-J*^*™M'',i'/-' •»•&$? .rtiiief /v ^ V*&*'
1.64
1.65
16.155
15.646
0.968
0.975
l^i^il^*'^^
uV7i%'" """'
PASS
feS^^^i^
%*» •""•'••'...'•'»'•''."'$>!' -J"«^ •v'V'W'<4l
0.45%
PASS
Run 2
i :;Uy sVU-'^t5^" •/•' v*^6n".*
v*.i8*aRS»w!iA»asw.'
29.22
? i-llSi^is^w •
16.910
37.060
20.150
2*6.6""
26.9
26.8
720
140
4^fSiS£^3^
16.600
36.400
19.800
i i,ft:.l:'s/kid! !\i"»Ask''i t'^V^V
*!"'""to^b%'t"" "
PASS
Run 3
«^»^^«*-*v.
H?^S2i;%S&sfl$S''^
37.060
54.080
17.020
""""***27"o""" '""
27.4
27.2
600
140
t^&4l«t^2Si&'sl;
37.060
54.080
17.020
-. i i 'i/«V .-v'"'^ i* »"'-*' ;' • % /' *
^*,;:,h':'&i\4!«S£e;.?Ah
70.5
70.5
70.5
-2.8
2ii^i;S^:32£%
1.68
16.223
16.031
0.988
^ /^'tA^Xi/^Ai, ^•.S-fmyw.afviK/A \-
1.31%
PASS
* For dry gas meters having only one thermocouple, temperatures are entered as inlet temperatures.
Remarks:
VOSTCALB.WK4 09/11/95 (rev. 1V470108.WK4 08/27/98 02:41 PM)
-------
VOST METERING CONSOLE CALIBRATION WITH WET TEST METER
MRI Project No.
Date:
Operator:
4701-08-03-04
8/14/98
Edwards
Metering Console No.
Previous Dry Gas Meter Factor (Y):
Calibrated Wet Test Meter No.
Wet Test Meter Factor (Yw):
Temperature Meter No.
Vost2
0.983
x-2538
1.0019
Y-0815
CALIBRATION DATA
Barometric Pressure, in. Hg
VOST Data
Initial Dry Gas Meter Volume, dry liters
Final Dry Gas Meter Volume, dry liters
Net Dry Gas Meter Volume (Vm), dry liters
Dry Gas Meter Temperature, °C:
Initial Inlet Temperature, °C
Final Inlet Temperature, °C
Initial Outlet Temperature*, °C
Final Outlet Temperature*, °C
Average Dry Gas Meter Temperature (tm), °C
Time, seconds
Rotameter Setting
Wet Test Meter Data
Initial Wet Test Meter Gas Volume, wet liters
Final Wet Test Meter Gas Volume, wet liters
Net Wet Test Meter Gas Volume (Vm), wet liters
Wet Test Meter Gas Temperature, °F:
Initial Temperature, °F
Final Temperature, °F
Average Wet Test Meter Gas Temperature (tm), °F
Pressure At Wet Test Meter Inlet, in. w.c.
COMPUTED CALIBRATION RESULTS
Gas Flow Rate, actual dry liters/minute
Average Gas Flow Rate, actual dry liters/minute
Dry Gas Meter Volume (Vm(std)), dry std. liters
Wet Test Meter Gas Volume (Vm(std)), dry std. liters
Dry Gas Meter Calibration Factor (Y)
Average Dry Gas Meter Calibration Factor (Y)
CALIBRATION RESULTS COMPARISON
Criterion: Y Must Be Within 2% Of Average Y
Percent Difference Of Y From Average Y
Tolerance Result
COMPARISON WITH PRETEST RESULTS
Criterion: Y Must Be Within 5% Of Previous Y
% Difference Of Average Y From Previous Y
Tolerance Result
Run 1
29.15
0.000
14.700
14.700
j- '*"•''' f^py"'-j?$$-f.---tyfy\'Q
"""26.T' '
24.8
25.5
630
142
^/iS^Si^f^i^
0.000
14.630
14.630
"""""esT"''""5
68.0
68.0
-2.8
M*M^Qam*~""f
1.38
14.060
13.841
0.984
0.985
"'""*' 0.68%'*""*"''
PASS
,«*.« «^^,£..fM
" 'PASS
Run 2
29.15
14.700
30.020
15.320
"T^^i-ijJ^.^^iv-^ ;;;>
""-"••"249"
26.4
25.7
660
142
ii,^M^i£Ki
14.630
29.900
15.270
?;* sj * ""y'Sj-s vSJJ^5",is.*j
"""""""eaci '"
68.0
68.0
-2.8
1.37
14.643
14.446
0.987
.....^^*A£*,M „-„,.
PASS
Run 3
29.15
30.020
43.980
13.960
fc^'^&X "'v-
26.4
27.4
26.9
600
142
V,>"/;.;--'.'':;^8^MA v-.>«.V.''
29.900
43.730
13.830
£<"^'W^\~y«r-
"""68.6"
68.0
68.0
-2.8
1.37
13.287
13.084
0.985
,^,,,,,^1^,,-,,,,-..
PASS
* For dry gas meters having only one thermocouple, temperatures are entered as inlet temperatures.
Remarks:
VOSTCALB.WK4 09/11/95 (rev. 2V470108.WK4 08/27/98 02:43 PM)
-------
VOST METERING CONSOLE CALIBRATION WITH WET TEST METER
MRI Project No.
Date:
Operator:
4701-08-03-04
8/13/98
B. Edwards
Metering Console No.
Previous Dry Gas Meter Factor (Y):
Calibrated Wet Test Meter No.
Wet Test Meter Factor (Yw):
Temperature Meter No.
Vqst_3
0.978
X-2538
1.0019
Y-0815
CALIBRATION DATA
Barometric Pressure, in. Hg
VOST Data
Initial Dry Gas Meter Volume, dry liters
Final Dry Gas Meter Volume, dry liters
Net Dry Gas Meter Volume (Vm), dry liters
Dry Gas Meter Temperature, °C:
Initial Inlet Temperature, "C
Final Inlet Temperature, °C
Initial Outlet Temperature*, °C
Final Outlet Temperature*, °C
Average Dry Gas Meter Temperature (tm), °C
Time, seconds
Rotameter Setting
Wet Test Meter Data
Initial Wet Test Meter Gas Volume, wet liters
Final Wet Test Meter Gas Volume, wet liters
Net Wet Test Meter Gas Volume (Vm), wet liters
Wet Test Meter Gas Temperature, "F:
Initial Temperature, °F
Final Temperature, °F
Average Wet Test Meter Gas Temperature (tm), °F
Pressure At Wet Test Meter Inlet, in. w.c.
COMPUTED CALIBRATION RESULTS
Gas Flow Rate, actual dry liters/minute
Average Gas Flow Rate, actual dry liters/minute
Dry Gas Meter Volume (Vm(std)), dry std. liters
Wet Test Meter Gas Volume (Vm(std)), dry std. liters
Dry Gas Meter Calibration Factor (Y)
Average Dry Gas Meter Calibration Factor (Y)
CALIBRATION RESULTS COMPARISON
Criterion: Y Must Be Within 2% Of Average Y
Percent Difference Of Y From Average Y
Tolerance Result
COMPARISON WITH PRETEST RESULTS
Criterion: Y Must Be Within 5% Of Previous Y
% Difference Of Average Y From Previous Y
Tolerance Result
Run 1
*""' 29.22' feW>
0.000
17.220
17.220
^•^fW^^'^i
-. ' , A aw.MtVsSv -. - -;- v;i -A'<
23.8
25.3
24.6
600
142
*' S^Si&i^y** ^ u ' "
0.000
17.320
17.320
'**»!« asy-*^"";-^
t,;Vi*!As..£»,'O«»;': •'•?}':
70.5
70.5
70.5
-2.8
^M^.^,,..^^
1.71
16.559
16.313
0.985
0.987
..^A^A^^U**.,,
PASS
5»S8J5swli»«'iS6tA
0.97%
PASS
Run 2
^^'H.^"^**"*'
M^S^S^-^ ^S?;
17.220
34.470
17.250
f^av-Ci'v'"'
25.4
26.7
26.1
630
142
^fellfl^ic^SlS'i
17.320
34.710
17.390 1
\. ;> '-'^v/O •!".."• «> \ & ;Cc
70.5
70.5
70.5
-2.8
1.63
16.505
16.379
0.992
V^I&^^S^
;'. '•S'SMfKMf^'t'^'i'
U'i A
'^l^ilMtS^^''
34.470
52.730
18.260
11T ,-., '\'.^\'^ "•' "* '-'>; ;.-;
26.7
28.0
27.4
600
142
s%^i^3s;D
34.710
52.900
18.190
b'.XQ^-V^"' '"""; '"J/
""""""''''"""70.5
70.5
70.5
-2.8
"''"raT*"''"""
17.396
17.133
0.985
w"vo;26"%*""*" "
PASS
* For dry gas meters having only one thermocouple, temperatures are entered as inlet temperatures.
Remarks:
VOSTCALB.WK4 09/11/95 (rev. 3V470108.WK4 08/27/98 02:44 PM)
-------
Environiqs
•
Viel A. Kaplinski
;s Engineer
Cronies Inc.
^^',,7:^860370-9333
rid Wide Web: h«p://www.wv_iroro<*-«im
nail:
olland, CT 06084
.com
ENVIRONICS FLOW COMTRCLLER CALIBRATION SHEET
1, Description: AIR
SCCM, K—r actor:
SERIAL tt
; -flow controller was calibrated u-'sinq a Sierra. Csl B^nch CCM
! CCM
i CCM
) CCM
i CCM
! CCM
! CCM
3000.0 CCM
9000.0 CCM
10000. CCM
True Fl ow
463.02
97 1 . 62
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6076. 6
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brat ion data i--.ias 1 a-st saved on
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EMVIRQNICS FLOW CONTROLLER CALIBRATION SHEET
-: 3, Description: AIR , Si^s 1.000.0 3CCM, K— rectors 1.0
S E R I A L tt
i flaw contrallsr was calibrated u=inq a Sierra C-al i:>^p'::h ( TM) ., a traceabl
i a r y F 1 o w S t a n d a r d C a L i h r a t i o n S •/ s t e m . This c a 1 : b r a t i o n t = r e • F e r e n c o c! t a
air at a tampsrature o-f j.^Jr '• ____ C) and a pressure QT 2".':?2 in. Hg ( TiM'Tocr
Set. Fl DI/I True Fl ow
5 :•: 5tii . 0 CCM 44 „ 233 CCM
l.'ii "'. 100.0 CCM 94.S&8 CCM
20 "••: 200.0 CCM Icr6.38 CCM
30 7. 300.0 CCM 298.. 36 CCM
40 "L 400,0 CCM 399.54 CCM
50 '/. 500.0 CCM 493.17 CCM
60 7, 600.0 CCM 593.72 CCM
70 "'. 700.0 CCM o'-S.'SS CCM
30 7. 300.0 CCM 799.52 CCM
*« 7. 900.0 CCM 901.A1 CCM
.10';'"' .1000.0 CCM 10i?3.6 CCM
brat ion data was la-st saved en Thur = dav 23 April 9y at
Date:
-------
ENVIRDNIC3 FLOW CONTROLLER CALIBRATION SHEET
M-F tt:: 4, De-script ion: AIR , Si^e: 100.0 3CCM, K—factor: 1 ., 0
SERIAL # n^\J '&]oLffi 7*
This -flow controller was calibrated u-~inn a Sierra Cal Bench (TM), a traceable
Primary Flow Standard Calibration 3/stem. This calibration i~ re-Ferenced to
dry air at =>. temper at ur a o-f Jt^F < C'i and a pressure o-f 29. °2 in.H.g <760Tar.r>
Set Flow . True Flaw
3.0 CCM 5.013 CCM
10.0 CCM 10,033 CCM
20.0 CCM 20.07S CCM
30,0 CCM 30,, 135 CCM
40.0 CCM 40,196 CCM
50.0 CCM 50.254 CCM
i'3.0 CCM 60.312 CCM
70.0 CCM 70.371 CCM
30.0 CCM 30.44 CCM
-------
CHICAGO, IL 60628
Certificate of Analysis - EPA Protocol Gas Standard page i of i
PERFORMED ACCORDING TO EPA TRACEABILITY PROTOCOL FOR ASSAY AND CERTIFICATION OF GASEOUS CALIBRATION STANDARDS (PROCEDURE
Customer: Order No: 312-020638-01
AIR PRODUCTS AND CHEMICALS, INC. Batch No: 861-33582
518 CAMDEN STREET Notes:
PARKERSBURG WV 26101- Cylinder No: SG9168085BAL
Cylinder Pressure*: 2000 psig
Certification Date: 08/05/96
PO: Rel: Expiration Date: OB/05/99
*** Certified Concentration *** ********* Reference Standards ********* ************* Analytical Instrumentation ************
Certified Standard Instrument Serial Last Measurement
Component Concentration Cylinder # Number Concentration Make/Model Number Calibration Principal
PROPANE 3690 ±23 PPM SG9164860BAL GMIS 4723.0000 PPM Gow-Mac 750 59405U 07/20/96 GC-FID
Balance Gas: NITROGEN
* Standard should not be user) below 1^0 p^J.g
Analyst: ^^^^ ^ Approved By:
' RichaFd Fry
-------
AIR PRODUCTS AND CHEMICALS, INC.
SPECIALTY GAS DEPARTMENT
12722 S^WENTWORTH AVENUE
CHI^feo, IL 60628
TELEPHONE (312) 785-3000
FAX (312) 785-3008
CERTIFICATE OF ANALYSIS *
DATE: 06/17/98
TIME: 09:40
PAGE: 1
AIR PRODUCTS' i CHEMICALS, INC
13701 GREEN ASH COURT
EARTH CITY MO 6304S-
CUSTOMER ACCOUNT : 375
CUSTOMER ORDER NO :
CUST ORD LINE/REL :
ORDER NO : 375-039909-01
REMARKS :
In accordance with our internal work instruction A-3,
products below are traceable to NIST.
CERTIFIED GAS MIXTURE: HYDROGEN IN HELIUM
FILL\
BATCH ANALYSIS BAR
NO DATE CODE CYLINDER NO
COMPONENT
REQUESTED
ANALYTICAL*
CAS CONCENTRATION ANALYTICAL ACCURACY UNIT OF L,
NUMBER REQUESTED RESULT (•»•/-) MEASURE Mi
861-47678A Chicago Spec Gaa
06/11/98 DDP978 SG10397B
HYDROGEN
HELIUM
1333-74-0
7440-59-7
40
39.3
Balance
IV MOLAR * 0'
DJK992 SG137455
HYDROGEN
HELIUM
1333-74-0
7440-59-7
40
39.3
Balance
IV MOLAR V 0
DRG647 SG303336
HYDROGEN
HELIUM
1333-74-0
7440-59-7
40
39.3
Balance
IV MOLAR V 0
DJL316 SG7002B
HYDROGEN
HELIUM
1333-74-0
7440-59-7
40
39.3
Balance
IV MOLAR V 0
DFQ531 SGKK064
HYDROGEN
HELIUM
1333-74-0
7440-59-7
40
39.3
Balance
1% MOLAR V 0
+ Analytical Accuracy may vary for mixtures containing components which present
adsorption, stability, or other blending problems.
LIST OF LAB METHODS USED :
09 GC-TCD
(CONTINUED)
-------
Scott Specialty Gases
6141 EASTON ROAD
Shipped PLUMSTEADVILLE
From: Phone: 215-766-8861
CERTIFICATE
PO BOX 310
PA 18949-0310
0 F
Fax: 215-766-2070
ANALYSIS
MIDWEST RESEARCH
SCOTT KLAMM
425 VOLKER BLVD
KANSAS CITY
PROJECT #: 01-01788-001
P0#: 033452
ITEM #: 0102S3000815AL
DATE: 4/07/98
MO 64110
CYLINDER #: AAL17264
FILL PRESSURE: 1280 PSIG
ANALYTICAL ACCURACY: +/-5%
BLEND TYPE
COMPONENT
CERTIFIED WORKING STD
REQUESTED GAS
CONG MOLES
ANALYSIS
(MOLES)
SULFUR HEXAFLUORIDE
TOLUENE
NITROGEN
4.
100.
PPM
PPM
BALANCE
3.83
105.
PPM
PPM
BALANCE
ANALYST:
7
T.LUDWIG U~
-------
Scott Specialty Gases
6141 EASTON ROAD
"T-./"shipped PLUMS TEADVILLE
•/From: Phone: 215-766-8861
CERTIFICATE
PO BOX 310
PA 18949-0310
O F
Fax: 215-766-2070
ANALYSIS
MIDWEST RESEARCH
SCOTT KLAMM
425 VOLKER BLVD
KANSAS CITY
MO 64110
PROJECT #: 01-01788-004
P0#: 033452
ITEM #: 01023822 SAL
DATE: 4/07/98
CYLINDER #: ALM033887
FILL PRESSURE: 2000 PSIG
ANALYTICAL ACCURACY: +/-5%
BLEND TYPE : CERTIFIED WORKING STD
REQUESTED GAS
COMPONENT CONG MOLES
SULFUR HEXAFLUORIDE
NITROGEN
.2
PPM
BALANCE
ANALYSIS
(MOLES)
0.205 PPM
BALANCE
ANALYST:
AL ROJAS
-------
08/10/98 15:29 ©215 766 2070
SCOTT
Scott Specialty Gases
Shipped
From:
6141 EASTON ROAD
PLUMSTEADVILLE PA 18949-0310
Phone: 215-766-8861
CERTIFIC AT E OF
PO BOX 310
Fax: 215-766-2070
ANALYSIS
MIDWEST RESEARCH
SCOTT KLAMM
425 VOLKER BLVD
KANSAS CITY
MO 64110
PROJECT #: 01-017i!8-005
P0#: 033452
ITEM #: 01021951 SAL
DATE: 3/31/98
CYLINDER #: ALM005893
FILL PRESSURE: 2000 PSIG
ANALYTICAL ACCURACY: +/-5%
BLEND TYPE : CERTIFIED WORKING STD
REQUESTED GAS
CONG HOLES
2THYLENE
NITROGEN
100.
PPM
BALANCE
ANALYSIS
(MOLES)
99.9
PPM
BALiJSTCE
ANALYST:
-------
TECHNICAL REPORT DATA
(Please read Instructions on reverse before completing)
1 REPORT NO. 2
EPA- 454/R-00-024
4 TITLE AND SUBTITLE
Hoi Mix Asphalt Plants
Truck Loading and Silo Filling
Instrumental Methods Testing
Asphalt Plant C
Los Angeles, California
7. AUTHOR(S)
EMAD
9 PERFORMING ORGANIZATION NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Research Triangle Park, NC 2771 1
12. SPONSORING AGENCY NAME AND ADDRESS
Director
Office of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
3 RECIPIENT'S ACCESSION NO
5 REPORT DATE
May 2QOO
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10 PROGRAM ELEMENT NO
1 1 . CONTRACT/GRANT NO
68-D-98-027
13. TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) is investigating hot mix asphalt plants to identify
and quantify particulate matter and organic hazardous air pollutants (HAPs) emitted from asphalt plant
cement load-out operations and operation of hot mix dryer. Testing was performed to characterize emissions
from storage silos, the load-out tunnel, and hot mix dryer. EPA issued a work assignment to Midwest
Research Institute (MRI) to conduct an air emissions test program collect data in support the investigation.
The testing program was conducted through EPA Contract 68W60048, work assignment 2-08. In addition,
manual samples were collected by Pacific Environmental Services, Inc. (PES). Work performed by PES was
under a separate contract.
1 7 KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Paniculate Matter, CO, SO2, Nox, THC, FTIR,
25A
18. DISTRIBUTION STATEMENT
- --Release Unlinrited r
b. IDENTIFIERS/OPEN ENDED TERMS
19 SECURITY CLASS (Report)
Unclassified
t
2erSECURITY CLASS (Page)
Unclassified
c. COSATI Field/Group
21. NO OF PAGES
365 **•>
22 PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
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