United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park, NC 27711
EPA-454/R-00-025A
May 2000
AIR
&EPA
Final Report
Hot Mix Asphalt Plants
Truck Loading and Silo Filling
Manual Methods Testing
Asphalt Plant C
Los Angeles, California
Volume 1 of 8
^___
of Air
Cltftft
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FINAL REPORT
HOT MIX ASPHALT PLANTS
TRUCK LOADING AND SILO FELLING
MANUAL METHODS TESTING
ASPHALT PLANT C, LOS ANGELES, CALIFORNIA
VOLUME 1 OF 8
TEXT AND APPENDIX A
EPA Contract No. 68-D-98-004
Work Assignment No. 3-02
Prepared for:
Mr. Michael L. Toney (MD-19)
Work Assignment Manager
SMTG, EMC, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
May 2000
Submitted by
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Post Office Box 12077
Research Triangle Park, NC 27709-2077
(919) 941-0333
FAX (919) 941-0234
U.S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Bpulevard, 12th Floor
Chicago, II 60604-3590
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DISCLAIMER
The information in this document has been funded wholly or in part by the Office of Air
Quality Planning and Standards, U.S. Environmental Protection Agency (EPA) under contract
to Pacific Environmental Services, Inc. (PES). PES performed the work presented in this
document under three EPA contracts and seven Work Assignments; EPA Contract
No. 68-D-98-004, Work Assignment Nos. 1-08, 2-07, 3-02, and 3-05, EPA Contract
No. 68-D-70002, Work Assignment Nos. 0-05 and 1-07; and EPA Contract No. 68-D-70069,
Work Assignment No. 2-16. This document has been prepared by PES, reviewed following
PES' internal quality assurance procedures, and approved by PES for distribution. This
document has been subjected to the Agency's review, and has been approved by EPA for
publication as an EPA document. Mention of trade names does not constitute endorsement by
the EPA or PES.
11
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TABLE OF CONTENTS
VOLUME 1 Page
1.0 INTRODUCTION 1-1
2.0 SUMMARY OF TEST RESULTS 2-1
2.1 OVERVIEW 2-1
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES 2-2
2.3 TUNNEL EXHAUST DUCT 2-2
2.4 SILO EXHAUST DUCT RESULTS 2-12
2.5 PM AND MCEM DEPOSITION ESTIMATES 2-15
2.6 METEOROLOGICAL STATION RESULTS 2-15
3.0 PROCESS DESCRIPTION 3-1
3.1 COORDINATION BETWEEN TESTING AND PROCESS
OPERATIONS 3-3
3.2 PROCESS MONITORING DURING TESTING 3-3
3.3 PROCESS SAMPLES 3-4
3.4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 3-5
4.0 SAMPLING LOCATIONS 4-1
4.1 TUNNEL EXHAUST DUCT 4-1
4.2 SILO EXHAUST DUCT 4-1
5.0 SAMPLING AND ANALYTICAL PROCEDURES 5-1
5.1 LOCATION OF MEASUREMENT SITES AND
SAMPLE/VELOCITY TRAVERSE POINTS 5-1
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC
FLOWRATE 5-1
5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR
WEIGHT 5-3
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT 5-3
iii
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TABLE OF CONTENTS (CONTINUED)
VOLUME 1 (CONTINUED^ Page
5.5 DETERMINATION OF PM AND MCEM 5-3
5.6 DETERMINATION OF VOHAPs 5-3
5.7 DETERMINATION OF SVOHAPs 5-7
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION,
AMBIENT TEMPERATURE, AND AMBIENT HUMIDITY 5-7
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING
OF THE LOAD-OUT TUNNEL DOWNSTREAM OF SILO NO. 5 5-7
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO NO. 2 EXHAUST PLENUM 5-9
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE SILO EXHAUST DUCT 5-9
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE
WALLS OF THE TUNNEL EXHAUST DUCT 5-10
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC) PROCEDURES
AND RESULTS 6-1
6.1 CALIBRATION AND PREPARATION OF APPARATUS 6-1
6.2 REAGENTS AND GLASSWARE PREPARATION 6-2
6.3 ON-SITE SAMPLING 6-3
6.4 SAMPLE RECOVERY 6-4
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES 6-5
6.6 QA COORDINATOR FIELD AUDIT 6-7
APPENDIX A - TEST RESULTS AND CALCULATIONS 1
A.I TED TEST RESULTS 3
A.2 SED TEST RESULTS 101
A.3 EXAMPLE CALCULATIONS 195
A.4 PARTICULATE DEPOSITION DATA 204
A.5 CAPTURE EFFICIENCY CALCULATIONS 211
VOLUME 2
APPENDIX B - PROCESS DATA 1
B.I PRODUCTION RECORDS FOR 7/24/98 THROUGH 7/28/98 3
B.2 PRODUCT STORAGE RECORDS FOR 7/25/98 THROUGH 7/28/98 .... 9
iv
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TABLE OF CONTENTS (CONTINUED)
VOLUME 2 ('CONTINUED')
APPENDIX B - PROCESS DATA (CONTINUED)
B.3 LOAD-OUT RECORDS USED IN TED EMISSION CALCULATIONS .. 19
B.4 LOAD-OUT RECORDS FOR 6/18/98 THROUGH 7/26/98 33
B.5 LOAD-OUT RECORDS FOR 7/24/98 THROUGH 7/28/98 44
B.6 SILO NO. 2 LOAD-IN RECORDS USED IN SED EMISSION
CALCULATIONS 68
B.7 ASPHALT TEMPERATURES AT LOAD-OUT 90
B.8 MASS CHANGE RESULTS FROM ASTM TESTS PERFORMED ON
ASPHALT CEMENT SAMPLES 93
B.9 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS
DURING LOAD-OUT 100
B.10 METALS ANALYSIS OF PROCESS SAMPLES 104
VOLUME 3
APPENDIX C - FIELD DATA 1
C.I TED FIELD DATA 2
C.2 SED FIELD DATA 59
C.3 METEOROLOGICAL STATION DATA 89
C.4 ON-SITE GC/MS REPORT AND DATA 118
APPENDIX D - QA/QC DATA 230
APPENDIX E - PROJECT PARTICIPANTS 280
APPENDIX F - TEST METHODS
F.I EPA METHOD 1
F.2 EPA METHOD 1A
F.3 EPA METHOD 2
F.4 EPA METHOD 4
F.5 EPA METHOD 18
F.6 EPA METHOD 315
F.7 SW-846 METHOD 0010
F.8 SW-846 METHOD 0030
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TABLE OF CONTENTS (CONCLUDED)
VOLUME 4
APPENDIX G - ANALYTICAL DATA 1
G.I PM AND MCEM DATA la
G.2 PAH/SVOHAPS CASE NARRATIVE AND PAH DATA Ik
VOLUMES
APPENDIX G - ANALYTICAL DATA (CONTINUED) 659
G.3 SVOHAPS DATA 659
VOLUME 6
APPENDIX G - ANALYTICAL DATA (CONTINUED) 1248
G.3 SVOHAPS DATA (CONCLUDED) 1248
VOLUME 7
APPENDIX G - ANALYTICAL DATA (CONTINUED) la
G.4 VOHAPS DATA Ic
VOLUME 8
APPENDIX G - ANALYTICAL DATA (CONCLUDED) la
G.4 VOHAPS DATA (CONCLUDED) Ic
G.5 EPA METHOD 18 REPORT AND DATA 260
VI
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LIST OF TABLES
Page
Table 1.1 Test Log Tunnel Exhaust Duct, Asphalt Plant C - California 1-4
Table 1.2 Test Log Silo Exhaust Duct, Asphalt Plant C - California 1-5
Table 2.1 Summary of Results, Production Emissions for PM, MCEM, PAH,
SVOHAP and VOHAP, Asphalt Plant C, California - July 1998 2-3
Table 2.2 Summary of Results, Average PM and MCEM Emissions,
Asphalt Plant C, California - July 1998 2-4
Table 2.3 Summary of Results, Average PAH and SVOHAP Emissions,
Asphalt Plant C, California - July 1998 2-5
Table 2.4 Summary of Results, Average VOHAP Emissions,
Asphalt Plant C, California - July 1998 2-6
Table 2.5 Summary of Results, PAHS, SVOHAPS, & VOHAPS Average
Emissions, Silo Exhaust Duct - Asphalt Plant C, California, July 1998 2-7
Table 2.6 PM and MCEM Emissions Sampling and Exhaust Gas Parameters
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California .. 2-16
Table 2.7 PM and MCEM Exhaust Gas Concentrations and Emission Rates, Normal
Operations, Tunnel Exhaust Duct, Asphalt Plant C - California 2-17
Table 2.8 PAHs and Semi-Volatile Organics Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-18
Table 2.9 PAHs Exhaust Gas Concentrations and Emission Rates, Normal
Operations Tunnel Exhaust Duct, Asphalt Plant C - California 2-19
Table 2.10 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Normal Operations, Tunnel Exhaust Duct, Asphalt Plant C - California .. 2-21
Table 2.11 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-30
Table 2.12 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Normal Operation, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-31
Table 2.13 Volatile Organics - EPA Method 18 Emissions Sampling and
Exhaust Gas Parameters, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-36
Table 2.14 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations
and Emission Rates, Normal Operations, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-37
Table 2.15 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) and EPA Method 18
Comparison, Tunnel Exhaust Duct, Asphalt Plant C - California 7/24/98 . 2-38
Table 2.16 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-39
vii
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LIST OF TABLES (CONTINUED)
Page
Table 2.17 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-40
Table 2.18 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-41
Table 2.19 PAHs Exhaust Gas Concentrations and Emission Rates, Background
Condition, Tunnel Exhaust Duct, Asphalt Plant C - California 2-42
Table 2.20 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-44
Table 2.21 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-53
Table 2.22 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-54
Table 2.23 Volatile Organics - EPA Method 18 Emissions Sampling and Exhaust Gas
Parameters, Background Condition, Tunnel Exhaust Duct, Asphalt
Plant C - California 2-59
Table 2.24 Volatile Organics - EPA Method 18 Exhaust Gas Concentrations and
Emission Rates, Background Condition, Tunnel Exhaust Duct,
Asphalt Plant C - California 2-60
Table 2.25 Sample Log Silo Exhaust Duct, Asphalt Plant C - California 2-61
Table 2.26 PM and MCEM Emissions Sampling and Exhaust Gas Parameters,
Silo Exhaust Duct, Asphalt Plant C - California 2-62
Table 2.27 PM and MCEM Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-63
Table 2.28 PAHs and Semi-Volatile Organics Emissions Sampling and Exhaust Gas
Parameters, Silo Exhaust Duct, Asphalt Plant C - California 2-64
Table 2.29 PAHs Exhaust Gas Concentrations and Emission Rates, Silo Exhaust Duct,
Asphalt Plant C - California 2-65
Table 2.30 Semi-Volatile Organics Exhaust Gas Concentrations and Emission Rates,
Silo Exhaust Duct, Asphalt Plant C - California 2-67
Table 2.31 Volatile Organics - SW-846 Method 0030 Emissions Sampling and
Exhaust Gas Parameters, Silo Exhaust Duct, Asphalt Plant C - California . 2-76
Table 2.32 Volatile Organics - SW-846 Method 0030 Exhaust Gas Concentrations
and Emission Rates, Silo Exhaust Duct, Asphalt Plant C - California .... 2-77
Table 2.33 On-Site GC/MS Volatile Organics Exhaust Gas Concentrations and
Emission Rates with Vost (SW-846 Method 0030) Comparison,
Silo Exhaust Duct, Asphalt Plant C - California 7/25/98 2-82
Vlll
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LIST OF TABLES (CONCLUDED)
Page
Table 2.34 PM and MCEM Deposition Estimates, Asphalt Plant C - California 2-83
Table 2.35 Meteorological Data Summary, Asphalt Plant C - California 2-84
Table 3.1 Load-out Data Used in TED Emission Calculations 3-6
Table 3.2 Load-in Data for Silo No. 2 Used in SED Emission Calculations 3-7
Table 3.3 Asphalt Temperatures at Load-out, Asphalt Plant C, California 3-8
Table 3.4 Mass Change of Asphalt, Asphalt Plant C, California 3-9
Table 3.5 Results of Metals Analyses of Asphalt Samples, Asphalt Plant C,
California 3-10
Table 3.6 Air Velocity Over Transport Trucks During Load-out, Asphalt Plant C,
California 3-11
Table 5.1 Summary of Sampling and Analytical Methods, Asphalt Plant C,
California 5-2
Table 6.1 Summary of Temperature Sensor Calibration Data 6-8
Table 6.2 Summary of Pitot Tube Dimensional Data 6-9
Table 6.3 Summary of Dry Gas Meter and Orifice Calibration Data 6-10
Table 6.4 Summary of EPA Method 315 and SW-846 Method 0010
Field Sampling QA/QC Data 6-11
Table 6.5 Summary of EPA Method 315 Blank Sample Catches 6-12
Table 6.6 S W-846 Method 0010 P AHs Field and Laboratory Blanks Results,
Tunnel Exhaust Duct 6-13
Table 6.7 S W-846 Method 0010 P AHs Field and Laboratory Blanks Results,
Silo Exhaust Duct 6-14
Table 6.8 S W-846 Method 0010 PAHs Surrogate Recovery Results,
Tunnel Exhaust Duct 6-15
Table 6.9 S W-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Tunnel Exhaust Duct 6-16
Table 6.10 SW-846 Method 0010 PAHs Surrogate Recovery Results,
Silo Exhaust Duct 6-17
Table 6.11 SW-846 Method 0010 Semi-Volatile Surrogate Recovery Results
Silo Exhaust Duct 6-18
Table 6.12 SW-846 Method 0030 Field and Laboratory Blanks Results
Tunnel Exhaust Duct 6-19
Table 6.13 SW-846 Method 0030 Laboratory Blank Results, Silo Exhaust Duct 6-20
Table 6.14 SW-846 Method 0030 Surrogate Recovery Results
Tunnel Exhaust Duct 6-21
Table 6.15 SW-846 Method 0030 Surrogate Recovery Results
Silo Exhaust Duct 6-22
IX
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LIST OF FIGURES
Page
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California 1-6
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction 2-85
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California 3-2
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks .. 3-12
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-2
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations,
Asphalt Plant C, California 4-3
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C, California 4-4
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California .. 4-5
Figure 5.1 EPA Method 315 Sampling Train Schematic 5-4
Figure 5.2 SW-846 Method 0030 Sampling Tram Schematic 5-6
Figure 5.3 SW-846 Method 0010 Sampling Tram Schematic 5-8
Figure 5.4 Location of TED Deposition Test Plates T,, T2, and T3 5-11
GLOSSARY OF TERMS
ASTM - American Society for Testing and Materials
CEMS - Continuous Emissions Monitoring System
CTS - Calibration Transfer Standard
EMC - Emissions Measurement Center
EMAD - Emission Monitoring and Analysis Division
ESP - Electrostatic Precipitator
FID - Flame lonization Detector
FTIR - Fourier Transform Infrared Spectroscopy
HAP - Hazardous Air Pollutant
MCEM - Methylene Chloride Extractable Matter
MRI - Midwest Research Institute
PES - Pacific Environmental Services
PM - Paniculate Matter
PTE - Permanent Total Enclosure
RAP - Recycled Asphalt
RTFOT - Rolling Thin Film Oven Test
SED - Silo Exhaust Duct
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GLOSSARY OF TERMS (CONTINUED)
SMTG - Source Measurement Technology Group
SVOHAP - Semi-Volatile Organic Hazardous Air Pollutant
TED - Tunnel Emissions Duct
TFOT - Thin Film Oven Test
THC - Total Hydrocarbons
VOHAP - Volatile Organic Hazardous Air Pollutant
VOST - Volatile Organic Sampling Train
XI
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1.0 INTRODUCTION
The United States Environmental Protection Agency (EPA) Office of Air Quality
Planning and Standards (OAQPS) is investigating hot mix asphalt plants to identify and quantify
particulate matter (PM), methylene chloride extractable matter (MCEM), and organic hazardous
air pollutant (HAP) emissions during asphalt concrete loading operations. In support of this
investigation, the OAQPS issued Pacific Environmental Services, Inc. (PES) Work Assignment
Nos. 0-05 and 1-07 on EPA Contract No. 68-D7-002, Work Assignment Nos. 1-08,2-07,
3-05, and 3-02 on EPA Contract 68D-98-004, and Work Assignment No. 2-16 on EPA Contract
68-D7-0069 to conduct emissions testing at a hot mix asphalt plant during load-out operations.
The primary objective of the emissions testing was to characterize the uncontrolled
emissions of PM, MCEM, polynuclear aromatic hydrocarbons (PAHs), semi-volatile organic
hazardous air pollutants (SVOHAPs), and volatile organic hazardous air pollutants (VOHAPs)
from a hot mix asphalt production plant during loading operations. An asphalt plant located
south of Los Angeles, CA, (referred to in this report as Asphalt Plant C or Plant C), was selected
as ths host facility. Testing was performed over five consecutive days beginning on July 24,
1998. Testing was performed under two conditions - normal operations and a background
condition.
Under normal operations, testing was performed in the 32 inch (") inside diameter (ID)
tunnel exhaust duct (TED) to characterize load-out emissions. Load-out in this report refers to
the loading of hot mix asphalt concrete into a transport truck. Also under normal operations,
testing was performed to characterize emissions from an asphalt concrete storage silo during
load-in operations. Load-in in this report refers to the loading of asphalt concrete into a storage
silo. To characterize load-in emissions, testing was performed in the 10" ID duct that is used to
exhaust load-in fumes off Silo No. 2. This 10" ID duct is referred to in this report as the Silo
Exhaust Duct (SED).
Under the background condition, testing was performed in the TED to characterize
emissions from the combustion of diesel fuel in transport trucks. The background testing was
performed in the TED on July 26,1998 when Plant C was shut down. Two transport trucks were
used to simulate normal load-out operations and spent four hours moving through the load-out
tunnel using the same routine the trucks use when the plant is running and loading asphalt
concrete.
Table 1.1 is a Test Log for the TED location and identifies the test ran numbers, dates,
sampling objectives, run times, and whether results are presented for the run. Table 1.2 is a Test
Log listing all the test runs performed in the SED and has the same parameters as Table 1.1.
1-1
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Note that results are not available for all the test runs performed. In some cases sampling
problems, and in some cases, problems in the analysis were sufficient to invalidate the test run.
These problems are discussed in Section 2.0 of this report.
Along with the testing, PES monitored and recorded ambient weather conditions,
monitored and documented process operations, collected process samples, and measured the
temperature of the asphalt concrete in the bed of randomly selected transport trucks as the trucks
left the load-out tunnel. PES also took measurements to estimate the deposition of PM and
MCEM on the inside walls of the TED, the inside walls of the exhaust plenum above Silo No. 2,
the inside walls of the SED, and the ceiling of the load-out tunnel.
In addition, for a separate project, PES collected and analyzed a short series of grab
samples from the Plant C dryer baghouse stack on July 25, 1998 using an on-site GC/MS. PES
measured 6 VOHAPs in the baghouse stack at concentrations ranging from 10 to 330 parts per
billion. These results are not load-out emissions and are not presented in the text of this report.
These results are presented in Volume 3, Appendix C.4, beginning on page 146.
PES used six subcontractors for this effort: Advanced Asphalt Technologies, LP (AAT),
Eastern Research Group (ERG), Enthalpy Analytical, Inc. (EAI), Quanterra Incorporated (QI),
Triangle Laboratories, Inc. (TLI), Emission Monitoring, Inc. (EMI), and Atlantic Technical
Services, Inc. (ATS). AAT provided analysis of the process samples. ERG provided analysis of
the EPA Method 315 samples. EAI provided support for the EPA Method 18 sampling and
analysis. TLI provided analysis of the SW-846 Method 0030 samples. QI provided analysis of
the SW-846 Method 0010 samples. EMI provided the on-site Gas Chromatograph/Mass
Spectrometry (GC/MS) data. ATS provided support services during the preparation of the Site
Specific Test Plan (SSTP), the preparation of the Quality Assurance Project Plan (QAPP), and
the preparation of the Draft Final Report.
The PES field test crew consisted of Frank Phoenix (Project Manager and Field Team
Leader), Michael Maret, Dennis D. Holzschuh, Joe Rubio, Nick Nielsen, Troy Abernathy, Jairo
Barreda, and Jessica Swift. The PES on-site QA coordinator was Dennis P. Holzschuh. Laura
Kinner and Jim Peeler, of EMI, ran the on-site GC/MS instrumentation. Brian Purser, of EAI,
provided support for the Method 18 sampling. On-site direction and overall coordination for the
project was provided by Michael L. Toney, the EPA Emission Measurement Center Work
Assignment Manager for WA 2-07, and Ron Myers with the EPA Emission Factor and Inventory
Group. The test project organization and major lines of communication are presented in
Figure 1.1. Note that Scott Klamm with Midwest Research Institute (MRI) is identified in
Figure 1.1. MRI, under a separate EPA contract, was also on-site and performed testing
simultaneous with PES for total hydrocarbons, selected organics, and measured the capture
efficiency (CE) of the load-out tunnel. The results of the MRI tests appear in a separate report.
Including this introduction, this report consists of seven sections and seven appendices in
eight volumes. Sections 1.0 through 7.0 and Appendix A are contained in Volume 1.
Appendix B is contained in Volume 2. Appendices C, D, E, and F are contained in Volume 3,
and Appendix G is contained in Volumes 4, 5, 6, 7, and 8. In Section 2.0, a summary of results
1-2
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is presented. More detailed results appear in Appendix A. In Section 3.0, a brief description of
the process is presented along with a summary of the process data collected and results of
analyses of the process samples. More detailed process information is presented hi Appendix B.
In Section 4.0, descriptions of the sampling locations are presented. In Section 5.0, descriptions
of the sampling and analytical procedures used during the test program are given. In Section 6.0,
descriptions of the quality assurance/quality control (QA/QC) procedures used during the test
program are discussed. Field data and meteorological data are in Appendix C. QA/QC data are
presented in Appendix D. Copies of the test methods are presented hi Appendix F. Detailed
analytical results are presented hi Appendix G.
1-3
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TABLE 1.1
TEST LOG
TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run Number*
T-MM5-1
T-M18-1
T-M315-1
T-V-1-1
T-V-1-2
T-V-1-3
T-V-1-4
T-MM5-2
T-M18-2
T-M315-2
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
T-MM5-4
T-M18-4
T-M315-4
T-V-4-1
T-V-4-2
T-V-4-3
T-V-4-4
T-MM5-3
T-M18-3
T-M315-3
T-V-3-1
T-V-3-2
T-V-3-3
Date
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
Sampling Objective
Semi-volatiles/PAHs
Select Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Volatiles
Semi-volatiles/PAHs
Select Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Volatiles
Semi-volatiles/PAHs
Select Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Volatiles
Semi-volatiles/PAHs
Select Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Run Time
0720-1256
0720-1256
0720-1303
0829-0849
0910-0945
1058-1133
1219-1249
0710-1121
0710-1126
0711-1127
0802-0827
0859-0924
0951-1023
1102-1122
0925-1343
0925-1346
0926-1340
0925-0950
1025-1050
1152-1222
1255-1320
0710-1155
0710-1155
0711-1200
0917-0947
1009-1034
1053-1123
Results Presented b
No
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Yes
No
Yes
Yes
Yes
Yes
Yes
Yes
Yes
Run Numbers are composed of the sampling location, sampling method, repetition number, and sample number.
Where T = TED, MM5 = Modified Method 5 (SW-846 Method 0010), V = VOST (SW-846 Method 0030),
M18 = EPA Method 18, M315 = EPA Method 315.
Example T-V-1-1 = VOST run 1, sample 1 at the TED.
Refer to Section 2.0 for an explanation.
1-4
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TABLE 1.2
TEST LOG
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run Number *
^S-MMS-1
S-M18-1
S-M315-1
S-V-1-1
S-V-1-2
S-V-1-3
S-V-1-4
S-MM5-2
S-M18-2
S-M315-2
S-V-2-1
S-V-2-2
S-V-2-3
S-V-2-4
S-MM5-3
S-M18-3
S-M315-3
S-V-3-1
S-V-3-2
S-V-3-3
S-V-3-4
S-V-3-5
S-V-3-6
S-M315-4
S-MM5-4
S-MM5-5
Date
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/26/98
07/28/98
07/28/98
07/28/98
Sampling Objective
Semi-volatiles/PAHs
Selected Volatiles
PMandMCEM
Volatiles
Volatiles
Volatiles
Volatiles
Semi-volatiles/PAHs
Selected Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Volatiles
Semi-volatiles/ 'AHs
Selected Volatiles
PM and MCEM
Volatiles
Volatiles
Volatiles
Volatiles
Volatiles
Volatiles
PM and MCEM
Semi-volatiles/PAHs
Semi-volatiles/PAHs
Run Time
0720-1018
0920-1008
1141-1243
0726-0736
0859-0909
0934-0944
1004-1014
0710-0950
0710-0954
1015-1117
0710-0720
0746-0756
0849-0859
0910-0920
0804-1050
1023-1248
1230-1257
0816-0821
0831-0836
0938-0943
0955-1002
1022-1029
1035-1042
0649-0840
0913-1323
1358-1940
Results Presented b
No
No
Yes
Yes
Yes
No
Yes
Yes
No
Yes
No
No
No
Yes
No
No
No
No
No
Yes
No
No
No
Yes
Yes
Yes
Run Numbers are composed of the sampling location, sampling method, repetition number, and sample number.
Where S = TED, MM5 = Modified Method 5 (SW-846 Method 0010), V = VOST (SW-846 Method 0030),
M18 = EPA Method 18, and M315 = EPA Method 315.
Example S-V-1-1 = VOST run 1, sample 1 at the SED.
Refer to Section 2.0 for an explanation.
1-5
-------
Asphalt Plant C
Richard Burnett
1
PES
OA/OC Officer
Jeff Van Atten
(703)471-8383
EPA/EMC
Work Assignment Manager
Michael I
(919)54
., Toney
1-5247
EPA/EFIO
Ron Myers
(919)541-5407
PES
Program Manager
John Chehaske
(703)471-8383
PES
Project Manager
Frank Phoenix
(919)941-0333
1
MRI
Proiect Manager
Scott Klamm
(816)753-7600
Pretest Site
Survey
PES
SSTP
PES
Subcontractor
Atlantic Techmca
Services, Inc
QAPP
PES
Subcontractor
Atlantic Technical
Services, Inc.
Field Testing
PES
Subcontractors
Emissions
Monitoring, Inc.,
Enthalpy
Analytical, Inc.
Analyses
PES
Report
Preparation
PES
Subcontractors
Eastern Research Group,
Quanterra Incorporated,
Triangle Laboratories, Inc.,
Enthalpy Analytical, Inc ,
Advanced Asphalt
Technologies, LP
Subcontractor
Atlantic Technical
Services, Inc.
Figure 1.1 Project Organization - US EPA Hot Mix Asphalt Load-out Operation,
Asphalt Plant C, California
-------
2.0 SUMMARY OF TEST RESULTS
In this section, a summary of results are presented for the emissions testing performed at
Asphalt Plant C in California. First an overview is presented in summary of results Tables 2.1
through 2.5. Next an extensive and detailed discussion of results is presented. The results of the
TED test runs performed under normal operations are discussed first, beginning with the PM and
MCEM results, and followed in order by the PAHs results, the SVOHAPs results, and the
VOHAPs results. Next the results of the TED test runs performed under the background
condition are discussed, followed in order by the results of the SED testing, the PM and MCEM
deposition estimates, and the meteorological data. After the discussions, 30 summary tables are
presented, beginning on page 2-16 with the TED normal operations tables, and followed in order
by the TED background condition tables, the SED tables, the PM and MCEM deposition table,
and the meteorological data table. For an index of tables, refer to the List of Tables beginning on
page vii.
In this Summary of Results section, an extensive amount of data is presented. The vast
majority of data met the quality objectives set at the beginning of the project, however, some
problems were encountered. The most significant problems were encountered during analysis of
the SED samples. At the SED, the relatively large concentration of non-target hydrocarbons
interfered with the analysis of the target HAPs. As a result, some of the QA/QC criteria were not
met, and some of the HAPs results are ± 100%. These problems are discussed in detail below.
2.1 OVERVIEW
The primary objective of the project was to characterize emissions from loading
operations at a hot mix asphalt plant. Sampling and analysis were performed at two locations for
PM, MCEM, and 156 organic HAPs, including 19 PAHs, 87 SVOHAPs, and 50 VOHAPs.
Sampling was performed in the TED to characterize load-out emissions and in the SED to
characterize load-in emissions. Load-out refers to the loading of hot mix asphalt concrete into a
transport truck. Load-in refers to the loading of asphalt concrete into a storage silo. In this
overview section, load-out and load-in are referred to jointly as "production".
The overall average TED and SED results for production emissions are summarized in
Table 2.1. In Table 2.1 and in the rest of this overview section, TED emissions are also referred
to as Truck Loading emissions and the SED emissions are referred to as Silo emissions. The
results have been normalized to a pounds per ton basis (i.e., pounds of emissions per ton of
asphalt concrete loaded) and can be used to estimate total loading emissions using plant loading
2-1
-------
records or estimates. The Silo emissions are presented on an "as measured" basis. The Truck
Loading emissions are presented on an "as measured" basis and on a "Capture Efficiency
Corrected" basis. The adjustments for capture efficiency (CE) use the lower 90% confidence
level CE values for each run. The lower 90% confidence level CE values were determined by
MRI from tracer gas measurements conducted simultaneously with the TED testing. The
calculations used to correct the TED results are presented in this report in Appendix A.5
beginning on page 211. Table 2.2 presents average production emissions for PM and MCEM.
Table 2.3 presents average production emissions for individual PAH and SVOHAP compound.
Table 2.4 presents average production emissions for individual VOHAP compounds. Table 2.5
presents average Silo emissions for individual PAH and VOHAP compounds.
2.2 TREATMENT OF NON-DETECTS AND ESTIMATES
Many of the compounds were never detected and the catch weight and results for these
compounds were reported as non-detects (ND). Some compounds were detected in one or two
test runs but not all three. In these cases, two formatting procedures were followed. First, NDs
were reported for the non-detect compounds and the ND values were counted as zero in the test-
run-average calculations. Second, the test run averages were enclosed in parentheses "()" to
indicate that they included at least one ND zero value. Some compounds were detected outside
the calibration range of the method. In these cases, the catch weights and all the results were
enclosed in braces" { }" to identify the values as estimates. If one test run in the set was a ND
and another test run hi the set was an estimate, the ND formatting was chosen over the estimate
formatting and the test-run-average results were enclosed hi parentheses"()".
2.3 TUNNEL EXHAUST DUCT
Sampling at the TED was performed over four consecutive days beginning on July 24,
1998. The first two days and fourth day of testing were performed under normal operations. The
third day of testing was performed under the background condition. Simultaneous with the TED
testing, MRI, under a separate EPA contract, measured the capture efficiency (CE) of the load-
out tunnel. In a separate report, MRI reports 90% lower confidence level tunnel capture
efficiencies of 64% for the testing on July 24,1998,65% for testing on July 25,1998,45% for
testing on July 26,1998, and 54% for testing on July 27,1998. In Tables 2.1,2.2,2.3, and 2.4,
TED emissions are presented "as measured11 and "corrected for the capture efficiency". In Tables
2.5 through 2.33, TED emissions are presented "as measured" only.
2-2
-------
TABLE 2.1
SUMMARY OF RESULTS
PRODUCTION EMISSIONS FOR PM, MCEM, PAH, SVOHAP, and VOHAP
ASPHALT PLANT C, CALIFORNIA - JULY 1998
Test Parameter6-7'8
PM- Method 3 15
PM - Deposition Estimate 9
PM - Total
MCEM-Method315
MCEM - Deposition Estimate 9
MCEM - Total
Total PAHs
Total SVOHAPs
Total VOHAPs
As Measured '
Silo
Production 4
Ib/ton 5
3.95E-04
7.12E-05
4.66E-04
1.34E-04
1.12E-06
1.35E-04
9.69E-06
NP
3.49E-05
Truck Loading3
Production
Ib/ton
1.70E-04
1.06E-04
2.76E-04
9.59E-05
7.73E-06
1.04E-04
2.01E-06
3.55E-07
2.21E-05
Capture Efficiency Corrected
Truck Loading 3
Production
Ib/ton
2.75E-04
1.34E-04
4.09E-04
1.53E-04
8.68E-06
1.62E-04
3.12E-06
5.82E-07
3.65E-05
1 The As Measured data is taken from Tables 2.2,2.3,2.4, and 2.34; Silo emissions were measured in the SED, Truck Loading emissions were measured in the TED.
1 90% lower confidence level CE corrections are based on run by run CE tests performed by MRI; see Appendix A.5, pages 211 and 212 for the calculations.
3 Truck Loading emissions include background emissions from truck operations. See Table 2-2.
4 Production in this table represents Normal Operation.
5 Pounds per ton of asphalt loaded.
6 PM represents Particulate Matter, MCEM represents Methylene Chloride Extractable Matter.
7 MCEM is a component of PM (i.e., the methylene chloride extractable portion of PM) and it is not appropriate to add the PM and MCEM together.
1 PAH represents Polynuclear Aromatic Hydrocarbons; SVOHAP, Semi-Volatile Organic Hazardous Air Pollutants; VOHAP, Volatile Organic Hazardous Air Pollutants.
9 Data taken from Table 2.34, see also Appendix A.4, pages 206 through 209.
-------
TABLE 2.2
SUMMARY OF RESULTS
AVERAGE PM AND MCEM EMISSIONS
ASPHALT PLANT C, CALIFORNIA - JULY 1998
PM7
MCEM7'8
As Measured l
Silo
Production 3
gr/dscf5 Ib/ton6
3.63E-02 3.95E-04
1.19E-02 1.34E-04
Truck Loading
Production
gr/dscf Ib/ton
9.42E-04 1.70E-04
5.25E-04 9.59E-05
Background 4
gr/dscf
7.93E-04
3.78E-04
Capture Efficiency Corrected 2
Truck Loading
Production
gr/dscf Ib/ton
1.55E-03 2.75E-04
8.44E-04 1.53E-04
Background
gr/dscf
1.76E-03
8.40E-04
>, Truck Loading emissions were measured in the TED.
)endix A.5, pages 211 and 212 for the calculations.
1 The As Measured data is taken from Tables 2.7, 2.17 and 2.27; Silo emissions were measured in the SED, Truck Loading emi
2 90% lower confidence level CE corrections are based on run by run CE tests performed by MRI; see Appendix A.5, pages 21
3 Production in this table represents Normal Operation.
4 The Background test was performed while no asphalt was loaded and represents emissions from diesel trucks only.
5 Grains per dry standard cubic foot.
6 Pounds per ton of asphalt loaded.
7 PM represents Particulate Matter, MCEM represents Methylene Chloride Extractable Matter.
8 MCEM is a component of PM (i.e., the methylene chloride extractable portion of PM) and it is not appropriate to add the PM and MCEM together.
-------
TABLE 2.3
SUMMARY OF RESULTS
AVERAGE PAH AND SVOHAP EMISSIONS
ASPHALT PLANT C, CALIFORNIA - JULY 1998
PAH5'6'7
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno( 1 ,2,3-cd)pyrene
2-Methylnaphthalene
Naphthalene
Perylene
Phenanthrene
Pyrene
Total PAH's
SVOHAPs5'6'7'8
Phenol
Total PAH + SVOHAP
As Measured '
Silo
Production
ppbvd 4 Ib/ton 4
1.80E+01 3.80E-07
4.38E-01 9.04E-09
4.54E400 1.10E-07
1.50E-H)0 4.33E-08
ND ND
ND ND
ND ND
ND ND
1.82E-01 6.17E-09
5.60E+00 1.62E-07
ND ND
4.38E400 1.16E-07
3.60E+01 8.89E-07
ND ND
2.22E-H)2 4.52E-06
8.52E-HH 1.50E-06
6.19E-01 2.77E-08
6.01E+01 1.55E-06
1.32E+01 3.78E-07
9.69E-06
NP NP
| 9.69E-06
Truck Loading
Production
ppbvd Ib/ton
1.70E-01 8.47E-08
1.90E-02 9.30E-09
4.35E-02 2.67E-08
8.23E-03 6.28E-09
3.18E-03 2.69E-09
8.88E-04 7.62E-10
7.71E-04 7.2 IE- 10
9.10E-04 7.80E-10
3.29E-03 2.85E-09
4.84E-02 3.66E-08
1.61E-04 1.82E-10
2.91E-02 1.99E-08
5.14E-01 3.04E-07
1.92E-04 2.27E-10
1.65E+00 7.47E-07
9.25E-01 3.77E-07
8.90E-03 7.90E-09
5.28E-01 3.26E-07
8.06E-02 5.45E-08
2.01E-06
1.54E-KX) 3.55E-07
| 2.36E-06
Background
ppbvd
1.79E-02
2.60E-03
6.19E-03
3.29E-04
3.58E-04
ND
1.36E-04
ND
2.58E-04
6.81E-03
ND
7.44E-03
4.83E-02
ND
9.17E-02
ND
ND
1.13E-01
1.49E-02
--
ND
—
Capture Efficiency Corrected 2
Truck Loading
Production
ppbvd Ib/ton
2.64E-01 1.31E-07
2.94E-02 1.44E-08
6.76E-02 4.15E-08
1.28E-02 9.77E-09
4.93E-03 4.18E-09
1.38E-03 1.19E-09
1.20E-03 1.12E-09
1.41E-03 1.21E-09
5.11E-03 4.43E-09
7.51E-02 5.69E-08
2.51E-04 2.84E-10
4.52E-02 3.09E-08
7.99E-01 4.74E-07
3.01E-04 3.55E-10
2.55E-KJO 1.16E-06
1.43E+00 5.85E-07
1.38E-02 1.23E-08
8.21E-01 5.07E-07
1.25E-01 8.47E-08
3.I2E-06
2.52E400 5.82E-07
| 3.70E-06
Background
ppbvd
3.97E-02
5.78E-03
1.38E-02
7.32E-04
7.95E-04
ND
3.02E-04
ND
5.74E-04
1.51E-02
ND
1.65E-02
1.07E-01
ND
2.04E-01
ND
ND
2.50E-01
3.31E-02
-
ND
—
The As Measured data is taken from Tables 2.9,2.10,2.19,2.20 and 2.29; Silo emissions were measured in the SED, Truck Loading emissions were measured in the TED.
90% lower confidence level CE corrections are based on run by run CE tests performed by MRI; see Appendix A.5, pages 211 and 212 for the calculations.
Production represents Normal Operations, the Background test was performed while no asphalt was loaded and represents emissions from diesel trucks only.
ppbvd represents parts per billion by volume dry, Ib/ton represents pounds per ton of asphalt loaded.
PAH represents polynuclear aromatic hydrocarbons; SVOHAP represents semi-volatile organic hazardous air pollutants.
The formatting procedures discussed in Section 2.2 using parentheses and braces were not followed here.
ND Non Detects - Results were below analyte detection limit.
NP Not Presented - The four detected SVOHAP compounds in Table 2.30 are already presented as PAH compounds and are not presented again here.
-------
TABLE 2.4
SUMMARY OF RESULTS
AVERAGE VOHAP EMISSIONS
ASPHALT PLANT C, CALIFORNIA - JULY 1998
VOHAPS5'6'7
Acetone
Benzene *
Bromomethane
2-Butanone
Carbon Disulfide
Chloroethane
Chloroform
Chloromethane
Cumene *
Ethylbenzene *
Hexane *
Isooctane
Methylene Chloride
MTBE
Styrene
Tetrachloroethene
Toluene *
1,1,1-Trichloroethane
Trichloroethene
Trichlorofluoromethane
m-/p-Xylene 8
o-Xylene 8
Total VOHAFs
As Measured '
Silo
Production 3
ppbvd 4 Ib/ton 4
3.54E+02 2.87E-06
1.60E+02 1.81E-06
1.71E+01 2.98E-07
2.10E+02 1.81E-06
6.73E+01 8.94E-07
1.56E+01 2.52E-07
ND ND
1.47E+02 1.37E-06
ND ND
1.54E+02 2.01E-06
4.81E+02 6.09E-06
1.05E+00 2.45E-08
8.61E-01 1.78E-08
no data no data
2.16E+01 2.32E-07
ND ND
2.82E+02 3.42E-06
ND ND
ND ND
ND ND
7.84E+02 1.06E-05
2.26E+02 3.18E-06
| 3.49E-05
Truck Loading
Production
ppbvd Ib/ton
4.57E+00 9.65E-07
2.65E+00 7.76E-07
5.06E-01 1.72E-07
2.60E+00 6.97E-07
5.30E-01 1.57E-07
1.64E-02 3.59E-09
ND ND
1.35E+00 2.45E-07
3.95E+00 1.75E-06
1.46E+01 5.53E-06
6.70E+00 2.18E-06
8.60E-02 4.03E-08
4.41E+00 1.20E-06
2.73E-01 8.78E-08
2.29E-01 8.13E-08
2.05E-01 1.20E-07
1.15E+01 3.73E-06
ND ND
ND ND
6.96E-02 3.30E-08
7.03E+00 2.70E-06
3.05E+00 1.16E-06
| 2.21E-05
Background 3
ppbvd
2.00E+00
5.34E-01
9.15E-02
2.67E-01
ND
ND
1.90E-02
3.74E-01
ND
7.80E+00
1.95E-01
1.06E-01
1.21E+01
7.07E-01
1.45E-01
8.65E-02
5.90E+00
3.40E-02
2.87E-03
7.42E-02
1.36E-01
8.71E-02
—
Capture Efficiency Corrected 2
Truck Loading
Production
ppbvd
7.23E+00
4.18E+00
7.90E-01
4.12E+00
8.45E-01
2.57E-02
ND
2.15E+00
9.21E+00
2.32E+01
1.04E+01
1.37E-01
7.50E+00
4.51E-01
3.92E-01
3.34E-01
1.85E+01
ND
ND
1.16E-01
1.10E+01
4.81E+00
Ib/ton
1.52E-06
1.22E-06
2.69E-07
1.10E-06
2.48E-07
5.61E-09
ND
3.88E-07
4.08E-06
8.73E-06
3.39E-06
6.34E-08
2.01E-06
1.42E-07
1.36E-07
1.94E-07
5.94E-06
ND
ND
5.41E-08
4.22E-06
1.83E-06
3.65E-05
Background
ppbvd
4.43E+00
1.19E+00
2.03E-01
ND
ND
ND
4.22E-02
8.31E-01
ND
1.73E+01
4.33E-01
2.35E-01
2.68E+01
1.57E+00
3.22E-01
1.92E-01
1.31E+01
7.55E-02
6.39E-03
1.65E-01
3.03E-01
1.94E-01
—
to
1 The As Measured data is taken from Tables 2.12,2.22,2.32 and Appendix A.5, page 212; Silo emissions were measured in the SED, Truck Uading emissions were measured in the TED.
1 90% lower confidence level CE corrections are based on run by run CE tests performed by MRI; see Appendix A.5, pages 211 and 212 for the calculations.
3 Production represents Normal Operations, the Background test was performed while no asphalt was loaded and represents emissions from diesel trucks only.
4 ppbvd represents parts per billion by volume dry, Ib/ton represents pounds per ton of asphalt loaded.
1 VOHAPs represents volatile organic hazardous air pollutants.
' The formatting procedures discussed in Section 2.2 using parentheses and braces were not followed here.
7 ND Non Detects - Results were below analyte detection limit
-------
TABLE 2.5
SUMMARY OF RESULTS
PAHS, SVOHAPS, & VOHAPS AVERAGE EMISSIONS
SILO EXHAUST DUCT - ASPHALT PLANT C, CALIFORNIA
JULY 1998
PAH
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(e)pyrene
Chrysene
Fluoranthene
Fluorene
2-Methylnaphthalene
Naphthalene
Perylene
Phenanthrene
Pyrene
Total PAH
SVOHAP
Total PAH + SVOHAP
Normal Operations 1
ppbvd 2
1.80E+01
4.38E-01
4.54E+00
1.50E+00
1.82E-01
5.60E+00
4.38E+00
3.60E+01
2.22E+02
8.52E401
6.19E-01
6.01E+01
1.32E-HJ1
—
NP4
—
lb/ton3
3.80E-07
9.04E-09
1.10E-07
4.33E-08
6.17E-09
1.62E-07
1.16E-07
8.89E-07
4.52E-06
1.50E-06
2.77E-08
1.55E-06
3.78E-07
9.69E-06
NP
9.69E-06
VOHAPS
Acetone
Benzene
Bromomethane
2-Butanone
Carbon Bisulfide
Chloroethane
Chloromethane
Ethylbenzene
n-Hexane
Isooctane
Methylene Chloride
Styrene
Toluene
m-/p-Xylene
o-Xylene
Total VOHAPS
Normal Operations l
ppbvd 2
3.54E-K)2
1.60E+02
1.71E-K)!
2.10E402
6.73E+01
1.56E+01
1.47E+02
1.54E-H)2
4.81E+02
1.05E+00
8.61E-01
2.16E+01
2.82E+02
7.84E+02
2.26E+02
~
lb/ton3
2.87E-06
1.81E-06
2.98E-07
1.81E-06
8.94E-07
2.52E-07
1.37E-06
2.01E-06
6.09E-06
2.45E-08
1.78E-08
2.32E-07
3.42E-06
1.06E-05
3.18E-06
3.49E-05
1 The formatting procedures discussed in Section 2.2 using parentheses and braces were not followed here.
2 Parts per billion by volume, dry.
3 Pounds per ton of asphalt loaded in.
4 NP Not Presented - The four detected SVOHAP are already presented as PAH and are not presented again here.
2-7
-------
2.3.1 Tunnel Exhaust Duct Results - Normal Operations
Normal operations in this report refers to the routine loading of asphalt concrete into
transport trucks (often referred to hi this report as "load-out"). Under normal operations, testing
in the TED was conducted only during load-out. When load-out stopped, the testing stopped.
Refer to Section 3.0 for more information on the coordination between testing and load-out
operations. In the tables that follow, target compound concentrations are presented in grains per
dry standard cubic feet (gr/dscf) or parts per billion by volume dry (ppbvd) and emissions are
presented in pounds per ton (Ib/ton) of asphalt concrete loaded. Pounds per ton emissions were
calculated by dividing the emissions hi pounds per test period by the tons of asphalt concrete
loaded into transport trucks during the test period. Pounds per test period emissions were
calculated by multiplying the target compound concentration by the TED exhaust gas flow rate
and by the test time. The data are presented "as measured" and are not corrected for background
or capture efficiency. Detailed results of the PM, MCEM, PAHs, SVOHAPs, VOHAPs, are
presented in Volume 1, Appendix A. Example calculations are presented in Volume 1,
Appendix A.3, beginning on page 195.
2.3.1.1 PM and MCEM Results - Normal Operations
In Table 2.6, emissions sampling and exhaust gas parameters are presented for the PM
and MCEM tests performed under normal operations. In Table 2.7, exhaust gas concentrations
and emissions are presented for the PM and MCEM tests performed under normal operations.
2.3.1.2 PAHs and SVQHAPs JRgsultjt- fformaj Operations
In Table 2.8, emissions sampling and exhaust gas parameters are presented for the PAHs
and SVOHAPs test runs performed under normal operations. A single SW-846 Method 0010
Modified Method 5 (MM5) sampling train was used to collect both PAHs and SVOHAPs. Note
that PAHs are SVOHAPs, but for clarity are referred to separately in this report. Also note that
some of the SVOHAPs and some of the VOHAPs presented is this report are not listed in the
CAA as HAPs. The results from T-MM5-1 are not presented. The sample from test run
T-MM5-1 was mistakenly separated from the other samples, discarded, and never analyzed. As a
result, this report presents two sets of PAHs and SVOHAPs data from the TED instead of three.
The average absolute difference between test runs T-MM5-2 and T-MM5-3 is 0.065 ppbvd. This
indicates good precision and data quality for the two runs presented.
In Table 2.9, exhaust gas concentrations and emissions are presented for all 19 PAHs. At
1 .65 ppbvd, 2-methylnaphthalene ranked the highest. Nine of the 19 PAHs were found at levels
above the method calibration range but were still within the linear response range of the detector.
The results for these nine PAHs were enclosed in braces "{ } " identifying them as estimates. In
Table 2.10, exhaust gas concentrations and emissions are presented for three of the 87 target
SVOHAPs; 84 target SVOHAPs were not detected. At 2.60 ppbvd, 2-methylnaphthalene ranked
the highest. Note that 2-methylnaphthalene, naphthalene, and pyrene were analyzed as PAHs
and as SVOHAPs and appear hi both Table 2.9 and Table 2.10. Also note that the results of the
two analyses for each of the three compounds were essentially the same.
2-8
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2.3.1.3 VOHAPs Results - Normal Operations
Three different procedures were used to measure VOHAPs: 1) sampling procedure
SW 846 Method 0030 in combination with analytical procedure SW 846 Method 8260 (often
referred to in this report as VOST), 2) Method 18, and 3) on-site GC/MS. The VOST results are
presented first, followed in order by the Method 18 and on-site GC/MS results.
2.3.1.3.1 VOST VOHAPs Results - Normal Operations. The Volatile Organic Sampling
Tram (VOST) of SW-846 Method 0030 was used to collect VOHAPs. The analytical procedures
of SW-846 Method 8260 were used to analyze for VOHAPs. Each VOST test run, with the
exception of T-V-3, consisted of four samples (three as required by the method, and a fourth as a
back-up sample) collected over the four-hour test period. For T-V-3 a fourth back-up sample
was not collected. In Table 2.11, emissions sampling and exhaust gas parameters for the VOST
test runs are presented. In Table 2.12, exhaust gas concentrations and emissions are presented
for "VOST" VOHAPS. Test run T-V-1 represents the sum of three samples, T-V-1-1, T-V-1-2,
and T-V-1-3 (T-V-1-4 was lost during analysis). Test run T-V-2 represents the sum of four
samples, T-V-2-1, T-V-2-2, T-V-2-3, and backup sample T-V-2-4. Test run T-V-3 represents the
sum of three samples T-V-3-1, T-V-3-2, and T-V-3-3. A total of 10 samples were analyzed for
50 target VOHAPs. Eighteen VOHAPs were detected; m-/p-xylene ranked the highest at
5.18ppbvd.
Note that most of the results presented in Table 2.12 are enclosed in either braces "{ }" or
parentheses"()". The braces indicate that at least one of the samples in the test run was below
the lower quantification limit of SW-846 Method 8260 of 0.05 ug/sample, and identifies the sum
presented as containing an estimate. The parentheses indicate that at least one of the samples in
the test run was a ND identifying the sum presented as containing a zero.
Note also that the samples were not analyzed within the 14 day analysis window in the
method. The laboratory started with the SED samples and after encountering severe matrix
problems (see Section 2.4 for details), delayed analyzing all remaining Plant C samples until
August 9, 1998. The first set of TED samples were analyzed on August 9, 1998, three days
outside the 14 day window. The last set of TED samples were analyzed on August 24,1998,
17 days outside the 14 day window. As a result, even though the samples were sealed and stored
in a freezer, it is possible that some portion of the most volatile compounds was lost before
analysis.
2.3.1.3.2 Method 18 VOHAPs Results - Normal Operations. In addition to VOST,
Method 18 was used in a backup capacity to collect and analyze eight VOHAPs. The eight
"Method 18" VOHAPs were expected to be above the upper quantification limit of SW-846
Method 8260 of 1.0 ug/sample (as it turned out, the eight "Method 18" VOHAPs were detected
using SW-846 Method 8260 at levels well below 1.0 ug/sample). In Table 2.13, the emissions
sampling parameters and exhaust gas parameters for the Method 18 test runs are presented. In
Table 2.14, exhaust gas concentrations and emissions are presented for the "Method 18"
VOHAPs. Note that for five of the eight "Method 18" VOHAPs, the Method 18 results were
2-9
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higher than the VOST results. Also note that the concentrations of the "Method 18" VOHAPs
were lower than expected, are close to the lower detection limits of Method 18, and therefore are
less reliable than the VOST results.
2.3.1.3.3 GC/MS VOHAPs Results - Normal Operations. A portable, direct interface GC/MS
system was used as an on-site screening tool for the measurement of selected VOHAPs. The
GC/MS system used a grab sample technique where the effluent sample was co-mixed with the
internal standard mixture in the GC sampling loop before injection into the GC/MS. The sample
conditioning system consisted of an unheated stainless steel probe, a 0.3 micron quartz filter, a
Teflon®-heated diaphragm pump, and Teflon® tubing connected to the GC/MS. Under normal
operations, 16 separate samples were collected and analyzed with the GC/MS system on July 23,
24, and 25, 1998, as discussed below.
1. On July 23,1998, three samples were collected at the exit end of the load-out runnel
through the sampling system and conveyed to the GC/MS. No compounds were detected
in these samples.
2. One July 23,1998, one sample was collected upwind of the load-out tunnel through the
sampling system and conveyed to the GC/MS. No compounds were detected in this
sample.
3. On July 24,1998, seven samples were collected from the TED through the sampling
system and conveyed to the GC/MS. Results from the last three samples are presented in
Table 2.15.
4. On July 24,1998, four samples were collected from the TED through the sampling
system and conveyed to a Tedlar® bag and then to the GC/MS. Results of these samples
are presented in Table 2.15.
5. On July 25, 1998, one sample was collected from directly above a transport truck inside
the load-out tunnel during load-out. This sample was collected through the sampling
system and conveyed to a Tedlar® bag and then to the GC/MS. The results of this sample
are presented in Table 2.15.
In Table 2.15, the results of the "GC/MS" VOHAPs testing are presented. For
comparison, selected "VOST" and "Method 18" VOHAPs are also presented. A detailed
presentation of the "GC/MS" VOHAPs testing is presented in Volume 3, Appendix C.4,
beginning on page 118.
2.3.2 Tunnel Exhaust Duct Results - Background Condition
The background condition testing was performed to characterize emissions from the
combustion of diesel fuel in the transport trucks. The background testing was performed in the
TED on Sunday, July 26,1998, when the plant was shut down. Two transport trucks were used
2-10
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to simulate normal load-out operations and spent four hours sequentially entering, stopping,
sitting, and exiting the load-out tunnel. In the tables that follow, target compound concentrations
are presented in gr/dscf or ppbvd, and emissions are presented in pounds per hour (Ib/hr).
Pounds per hour emissions were calculated by multiplying the target compound concentration by
the TED exhaust gas flow rate.
2.3.2.1 PM and MCEM Results - Background Condition
In Table 2.16, emissions sampling and exhaust gas parameters are presented for the PM
and MCEM tests performed under the background condition. In Table 2.17, exhaust gas
concentrations and emissions are presented for the PM and MCEM tests performed under the
background condition.
2.3.2.2 PAHs and SVOHAPs Results - Background Condition
In Table 2.18, emissions sampling and exhaust gas parameters are presented for the PAHs
and SVOHAPs test runs performed under the background condition. In Table 2.19, exhaust gas
concentrations and emissions are presented for 13 of the 19 PAHs; six of the PAHs were ND. At
0.113 ppbvd, phenanthrene ranked the highest. Note that during normal operations,
phenanthrene averaged 0.528 ppbvd. In Table 2.20, the exhaust gas concentrations and
emissions for all 87 target SVOHAP compounds are reported as NDs.
2.3.2.3 VOHAPs Results - Background Condition
In Table 2.21, emissions sampling and exhaust gas parameters are presented for the
VOST test runs performed under the background condition. In Table 2.22, exhaust gas
concentrations and emissions are presented for "VOST" VOHAPs. Results are presented for
three samples for test run T-V-4: T-V-4-1, T-V-4-2, and T-V-4-4 (T-V-4-3 was lost during
analysis). Nineteen of the 50 VOHAPs were detected. Methylene chloride ranked the highest at
12.1 ppbvd. This background concentration appears high (during normal operations, methylene
chloride averaged 4.41 ppbvd) and may be the result of field contamination. Note first that
methylene chloride was used as a clean-up solvent in the field, and second that methylene
chloride was found in significant quantities in the TED VOST field blank (see Table 6.12 in
Section 6.0).
Note that for samples T-V-4-1, T-V-4-2, and T-V-4-4, unlike the normal operations
samples, the Tenax® and Tenax®/charcoal tubes were desorbed and analyzed separately. This
was done as a precaution against the matrix interferences encountered analyzing the SED
samples. As it turned out, matrix interferences were not a problem at the TED, and the
remaining TED Tenax® and Tenax®/charcoal tube combinations were analyzed together.
Method 18 was used in a backup capacity during the background condition. In
Table 2.23, emissions sampling and exhaust gas parameters are presented for the eight
"Method 18" VOHAPs. In Table 2.24, exhaust gas concentrations and emissions are presented
for the eight "Method 18" VOHAPs.
2-11
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2.4 SILO EXHAUST DUCT RESULTS
Sampling at the SED was performed over five days beginning on Friday, July 24,1998.
Testing was not performed at the SED on Sunday, July 26,1998 when the plant was shut down.
All the testing at the SED was performed under normal operations. Normal operations at the
SED refers to the routine production and loading of asphalt concrete into Silo No. 2 (also
referred to in this report as "load-in").
In Table 2.25, a sample log is presented identifying the 27 test runs performed at the
SED. Results are presented in this section for 11 of the 27 test runs performed. Results are not
presented for 16 of the test runs for the reasons discussed below. Two major problems were
encountered during the testing in the SED. First, the exhaust gas moisture content in the SED
varied significantly (from 15% to 70%) as the moisture content in the reclaimed asphalt changed.
As a result, the sampling rates on three runs (S-MM5-1B, S-MM5-3, and S-M315-3) were over-
isokinetic and replacement runs (S-MM5-4, S-MM5-5, and S-M315-4) were performed. Second,
the total hydrocarbon concentrations in the SED were much higher than expected, creating
extensive matrix interference problems during analysis. As a result, it was necessary to modify
the PAHs, SVOHAPs, and VOHAPs analytical procedures. For the PAHs and SVOHAPs
analyses, the samples were diluted and re-analyzed. For the VOHAPs, since dilution was not an
option, only selected samples were analyzed. Because of these matrix problems, the PAHs,
SVOHAPs, and VOHAPs results presented are qualitative, and only identify the compounds and
approximate the concentrations present. More detailed explanations of these problems are
presented below.
In the summary of results tables that follow, target compound concentrations are
presented in gr/dscf or ppbvd and emissions are presented in Ib/tons of asphalt concrete loaded.
Pounds per ton emissions were calculated by dividing the emissions hi pounds per test period by
the tons of asphalt concrete loaded into Silo No. 2 during the test period. Pounds per test period
emissions were calculated by multiplying the target compound concentration firstly the SED
exhaust flow rate and second by the test time. Detailed results are presented in Volume 1,
Appendix A.2, beginning on page 102.
2.4.1 Silo Exhaust Duct - PM and MCEM Results
In Table 2.26, emissions sampling and exhaust gas parameters are presented for the PM
and MCEM test runs performed at the SED. In Table 2.27, exhaust gas concentrations and
emissions are presented for the PM and MCEM tests performed at the SED. Note that test run
S-315-3 is not presented. The sampling rate for test run S-315-3 was over-isokinetic and a
replacement run (S-315-4) was performed.
2.4.2 Silo Exhaust Duct - PAHs and SVOHAPs Results
In Table 2.28, emissions sampling and exhaust gas parameters are presented for the PAHs
and SVOHAPs test runs performed at the SED. A single SW-846 Method 0010 Modified
Method 5 (MM5) sampling train was used to collect both PAHs and SVOHAPs. Note that
2-12
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results from test runs S-MM5-1, S-MM5-1B, and S-MM5-3 are not presented. The sample jar
containing test run SMM5-1 was broken during transport to the laboratory and a replacement run
(S-MM5-1B) was performed. The sampling rates for test runs S-MM5-1B and S-MM5-3 were
over-isokinetic and replacement runs (S-MM5-4 and S-MM5-5) were performed. In Table 2.29,
exhaust gas concentrations and emissions are presented for 13 of the 19 PAHs; 6 of the PAHs
were not detected. In Table 2.30, exhaust gas concentrations and emissions are presented for 4 of
the 87 target SVOHAPs; 83 of the SVOHAPs were not detected.
The PAH analyses, using California Air Resources Board (CARB) Method 429 were, as
the QI case narrative indicates, "significantly compromised by extensive matrix interferences,
including retention-time shifts and co-eluding interferences, and saturated analyte levels." As a
result, no usable data was obtained from the initial analyses. After the initial analyses, however,
aliquots of the SED sample extracts were diluted and re-analyzed. These dilutions minimized the
matrix interferences but also pushed the internal standards (introduced before extraction) below
the instrument detection limits. After dilution, QI introduced new internal standards at normal
levels for calculating the target analyte levels. Without the original internal standards, the
opportunity to perform recovery corrections, and the opportunity to measure the efficiency of
sample extraction and clean-up were lost. The QI case narrative indicates that the net result is a
potential low bias in the reported concentrations.
Like the PAHs analysis, the initial SVOHAPs analyses (using SW-846 Method 8270)
encountered severe matrix interferences that required dilutions. In these cases, the Method 8270
detection limits were approximately 200 times higher than the CARB 429 detection limits;
therefore, all but four target compounds were pushed below the detection limits. One compound
(2-methylnaphthalene) was detected above the quantification limit and three compounds
(fluorene, naphthalene, and phenanthrene) were detected below the quantification limit but above
the detection limit. The remaining 83 target SVOHAPs and the internal standards spiked at the
time of extraction were not detected. In an effort to help characterize the non-target
hydrocarbons causing the matrix interferences, the highest 20 chromatogram peaks were semi-
quantified using the NIST 44,000 compound library. These data are presented as tentatively
identified compounds (TICs) in Volume 1, Appendix A.2, beginning on page 133.
2.4.3 Silo Exhaust Duct - VOHAPs Results
Three different procedures were used to measure VOHAPs in the SED: VOST,
Method 18, and on-site GC/MS. The VOST results are presented first, followed in order by the
Method 18 and the on-site GC/MS results.
2.4.3.1 Silo Exhaust Duct - VQHAPs Results. VOST
In Table 2.31, emissions sampling and exhaust gas parameters are presented for the
VOST test runs performed at the SED. In Table 2.32, exhaust gas concentrations and emissions
are presented for the "VOST" VOHAPs. In Table 2.32, test run S-V-1 represents the sum of
three samples; test run S-V-2 represents one sample; and S-V-3 represents one sample.
2-13
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Matrix problems, similar to those encountered during the PAHs and SVOHAPs analyses
were encountered during the "VOST" VOHAPs analyses. For the first set of analyses, the
Tenax® and Tenax® charcoal tubes were analyzed together. The non-target hydrocarbons in the
samples overwhelmed and shut down the analyzer, and no usable data was obtained. Unlike the
PAHs and SVOHAPs, the volatile samples could not be diluted and re-analyzed (i.e., in
Method 8260, the sample is thermal desorbed and immediately injected into the analyzer). It
became clear that a quantitative analysis that met all the QA/QC criteria of VOST was unlikely.
A decision was made to analyze selected samples and establish a qualitative understanding of the
VOHAPs present.
Five samples were chosen: three samples from the first test run (S-V-1-1, S-V-1-2, and
S-V-1-4), one from the second test run (S-V-2-4), and one from the third test run (S-V-3-3). This
time the Tenax® and Tenax® charcoal tubes were analyzed separately (note that the data from
Tenax®-charcoal tube from S-V-1-1 was lost in analysis). This generated 450 data points. Three
hundred and fifty-three (353) of the 450 data points were ND. Twenty-eight data points were
found at levels above the upper quantification limit of 1.0 jig/sample; 36 were found between the
lower quantification limit of 0.1 u^/sample and the detection limit of 0.001 (ig/sample; 24 were
found within the upper and lower limits; and no data was available for 9 data points (a calibration
standard was not available for methylene chloride). Results of the 28 VOHAPs above the
quantification limit and the 36 VOHAPs below the quantification limit are enclosed in braces
"{ }" identifying them as estimates. As a worst case, these estimates are ± 100 % and serve to
identify the VOHAPs present and approximate the concentrations.
Note also that the samples were analyzed 26 days outside the 14 day analytical window in
the method. As a result, even though the samples were sealed and stored in a freezer, it is
possible that some portion of the most volatile compounds was lost before analysis.
2.4.3.2 Silo Exhaust Duct - VOHAPs Results. Method 18
Method 18 was used in a backup capacity to collect and analyze eight VOHAPs. Matrix
problems were encountered here as well. EAI's case narrative states, "The large number of
peaks made quantification impossible. There were literally hundreds of peaks. The FID was
unable to differentiate the target peaks from the crowd. There is a significant possibility that the
concentrations presented include extraneous peaks that co-eluded with the target peaks." Given
these problems, it was decided not to present the Method 18 results. Instead, in an effort to better
understand the makeup of the non-target hydrocarbons, the Method 18 extracts were qualitatively
characterized using the analytical procedures of SW-846-Method 8260. The highest 30 peaks
were given the best tentative identification using the NIST 44,000 compound library. The peaks
were semi-quantified using the internal standard 4-bromofluorobenzene and a response factor of
1.00. Some of the compounds appear more than once indicating the presence of isomers. The
concentrations and emissions appear in Volume 1, Appendix A.2, beginning on page 180. The
results have an estimated error of+100% to -50%.
2-14
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2.4.3.3 Silo Exhaust Duct - VOHAPs Results. On-site GC/MS
A portable, direct interface GC/MS was used as an on-site screening tool for the
measurement of selected VOHAPs. On July 25,1998, four separate 15-minute samples were
collected at the SED between 9:00 a.m. and 10:30 a.m. through a sample conditioning system
and conveyed to the GC/MS. The sample conditioning system consisted of an unheated stainless
steel probe, a 0.3 micron quartz filter, a stainless steel heat exchanger, two glass impingers for
moisture removal, a Teflon®-heated diaphragm pump, and Teflon® tubing connected to the
GC/MS. The result of the "GC/MS" VOHAPs analyses are presented in Table 2.33. The average
concentration of the selected VOHAPs measured with VOST are also presented.
2.5 PM AND MCEM DEPOSITION ESTIMATES
Measurements were made to estimate the PM and MCEM deposition on the inside walls
of the TED, the inside walls of the exhaust plenum above Silo No. 2, the inside walls of the SED
and on the ceiling of the load-out tunnel downstream of Silo No. 5. These estimates are
summarized in Table 2.34. A more detailed account of these estimates appears in Volume 1,
Appendix A.4, beginning on page 204. Silo specific load-out data was not available. It was
therefore assumed for the deposition calculations that load-out was evenly spread between the
five silos. For the Old SED estimate, it was assumed that Plant C produced 3,000,000 tons from
start-up through July 19,1998.
The Method 315 results in Table 2.1 show that all the PM in the TED was MCEM. The
deposition estimates for the TED, however, show significantly more PM than MCEM. The
difference points to a high bias in the deposition estimates due to ambient dust generated in the
load-out tunnel and drawn into the TED each morning at start-up. This bias is discussed in more
detail hi Section 5.12.
2.6 METEOROLOGICAL STATION RESULTS
A meteorological (MET) monitoring station was positioned on top of the load-out tunnel,
above the entrance. The station monitored the wind speed, wind direction, and ambient
temperature. Readings from the MET station were recorded once per minute during the testing
and downloaded to a data acquisition system. Due to a hardware problem, no data were collected
on 7/26/98 during the background condition testing. Ambient humidity was measured manually
using a sling psychrometer and recorded in a field notebook. Table 2.35 summarizes the
meteorological data collected. Figure 2.1 shows the position of the load-out tunnel and the MET
station and the average wind direction for each test day.
2-15
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TABLE 2.6
PM AND MCEM
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfm '
Capture Efficiency, percent b
Sample Volume:
dscf"
dscmd
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfin'
dscfin*
dscmmf
Isokinetic Sampling Ratio, %
Process Parameters
RTFOT Results, Mass Change at 325°F, % g
Asphalt Temperature at Load-out, °F h
Asphalt Loaded per Test Period, Tons '
T-M315-1
7/24/98
0720-1303
240
0.671
64
160.986
4.559
85
3.5
11,200
10,200
288
101.6
-0.362
321
1,875.0
T-M315-2
7/25/98
0711-1127
240
0.679
65
162.940
4.614
88
2.4
11,200
10,200
289
102.4
-0.322
316
1,499.7
T-M315-3
7/27/98
0711-1200
240
0.636
54
152.700
4.324
94
1.9
10,500
9,510
269
103.7
-0.284
291
2,529.7
Average
0.662
61
158.875
4.499
89
2.6
11,000
9,970
282
102.6
-0.322
310
1,968.1
* Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Lower 90% confidence level capture efficiency was determined by MRI.
c Dry standard cubic feet at 68°F (20°C) and 1 atm.
" Dry standard cubic meters at 68°F (20°C) and 1 atm.
' Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
g Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
h From Table 3.3 in Section 3.
1 From Table 2.7 in Section 2.
2-16
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TABLE 2.7
PMANDMCEM
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Met Test Time, minutes
Tons of asphalt loaded per test period
Equivalent Hourly Load-out Rate, ton/hr
Particulate Matter
Concentration, gr/dscf a
Concentration, g/dscm b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Methylene Chloride
Extractable Matter
Concentration, gr/dscf a
Concentration, g/dscm
Emission Rate, Ib/test period c
Emission Rate, Ib/ton
T-M315-1
7/24/98
0720-1303
240
1,875.0
468.8
1.23E-03
2.81E-03
4.27E-01
2.28E-04
1.07E-03
2.46E-03
3.74E-01
1.99E-04
T-M315-2
7/25/98
0711-1127
240
1,499.7
374.9
7.39E-04
1.69E-03
2.58E-01
1.72E-04
2.27E-04
5.20E-04
7.95E-02
5.30E-05
T-M315-3
7/27/98
0711-1200
240
2,529.7
632.4
8.59E-04
1.97E-03
2.80E-01
1.11E-04
2.73E-04
6.24E-04
8.90E-02
3.52E-05
Average
1,968.1
492.0
9.42E-04
2.15E-03
3.22E-01
1.70E-04
5.25E-04
1.20E-03
1.81E-01
9.59E-05
* Grains per dry standard cubic feet at 68°F (20°C) and 1 atm.
b Grams per dry standard cubic meters at 68°F (20°C) and 1 atm.
c Pounds per test period.
d Pounds per ton of asphalt loaded.
2-17
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TABLE 2.8
PAHs AND SEMI-VOLATILE ORGANICS
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfm a
Capture Efficiency, percent b
Sample Volume:
dscfc
dscmd
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfm'
dscfm "
dscmm f
Isokinetic Sampling Ratio, %
Process Parameters
RTFOT Results, Mass Change at 325°F, % g
Asphalt Temperature at Load-out, °F h
Asphalt Loaded per Test Period, Tons '
T-MM5-2
7/25/98
0710-1121
240
0.634
65
152.087
4.307
82
3.5
10,600
9,660
274
105.8
-0.322
316
1,478.7
T-MM5-3
7/27/98
0710-1155
240
0.648
54
155.540
4.404
89
3.5
11,100
9,970
282
104.8
-0.284
291
2,530.2
Average
0.641
60
153.813
4.356
85
3.5
10,900
9,820
278
105.3
-0.303
304
2,004.5
a Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Lower 90% confidence level capture efficiency was determined by MRI.
0 Dry standard cubic feet at 68°F (20°C) and 1 atm.
d Dry standard cubic meters at 68°F (20°C) and 1 atm.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
8 Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
h From Table 3.3 in Section 3.
' From Table 2.9 in Section 2
2-18
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TABLE 2.9
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acenaphthene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Acenaphthylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(k)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(ghi)perylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(a)pyrene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Benzo(e)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chrysene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
7/25/98
0710-1121
1478.7
{1.63E-01}
{1.02E-07}
1.70E-02
1.07E-08
{5.33E-02}
{3.87E-08}
9.05E-03
8.41E-09
3.54E-03
3.64E-09
1.04E-03
1.07E-09
8.89E-04
l.OOE-09
1.06E-03
1.09E-09
3.98E-03
4.09E-09
{5.14E-02}
{4.77E-08}
T-MM5-3
7/27/98
0710-1155
2530.2
{1.77E-01}
{6.70E-08}
2.09E-02
7.91E-09
3.37E-02
1.47E-08
7.42E-03
4.16E-09
2.81E-03
1.74E-09
7.36E-04
4.56E-10
6.52E-04
4.42E-10
7.58E-04
4.69E-10
2.60E-03
1.61E-09
{4.55E-02}
{2.55E-08}
Average
2004.45
{1.70E-01}
{8.47E-08}
1.90E-02
9.30E-09
{4.35E-02}
{2.67E-08}
8.23E-03
6.28E-09
3.18E-03
2.69E-09
8.88E-04
7.62E-10
7.71E-04
7.21E-10
9.10E-04
7.80E-10
3.29E-03
2.85E-09
{4.84E-02}
{3.66E-08}
2-19
-------
TABLE 2.9 (Concluded)
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
Dibenz(a,h)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
?luoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
?luorene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Indeno(l ,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methylnaphthalene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Naphthalene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Perylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Phenanthrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
3.21E-04
3.64E-10
{3.31E-02}
{2.73E-08}
{7.06E-01}
{4.77E-07}
3.85E-04
4.55E-10
{1.49E+00}
{8.64E-07}
{8.28E-01}
{4.32E-07}
1.17E-02
1.20E-08
{6.58E-01}
{4.77E-07}
{8.84E-02}
{7.28E-08}
T-MM5-3
ND
ND
{2.51E-02}
{1.25E-08}
{3.22E-01}
{1.31E-07}
ND
ND
{1.81E+00}
{6.30E-07}
{1.02E+00}
{3.22E-07}
6.06E-03
3.75E-09
{3.98E-01}
{1.74E-07}
{7.29E-02}
{3.62E-08}
Average
(1.61E-04)
(1.82E-10)
{2.91E-02}
{1.99E-08}
{5.14E-01}
{3.04E-07}
(1.92E-04)
(2.27E-10)
{1.65E+00}
{7.47E-07}
{9.25E-01}
{3.77E-07}
8.90E-03
7.90E-09
{5.28E-01}
{3.26E-07}
{8.06E-02}
{5.45E-08}
Parts per billion by volume dry.
Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{} Estimate - Concentration in the sample exceeded the method calibration range,
but was still within the linear response range of the detector.
( ) Results in parentheses include NDs which were averaged as zero.
2-20
-------
TABLE 2.10
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acenaphthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Acenaphthylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Acetophenone
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Aminobiphenyl
Concentration, ppbvd "
Emission Rate, Ib/ton b
Aniline
Concentration, ppbvd "
Emission Rate, Ib/ton b
Anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(k)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
7/25/98
0710-1121
1478.7
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
7/27/98
0710-1155
2530.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
2004.45
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-21
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
Jenzoic acid
Concentration, ppbvd "
Emission Rate, Ib/ton b
Jenzo(g,h,i)perylene
Concentration, ppbvd "
Emission Rate, Ib/ton b
3enzo(a)pyrene
Concentration, ppbvd "
Emission Rate, Ib/ton b
3enzo(e)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Jenzyl alcohol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Mphenyl
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Bromophenyl phenyl ether
Concentration, ppbvd *
Emission Rate, Ib/ton b
Butyl benzyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloroacetophenone
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Chloroaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
bis(2-Chloroethoxy)-methane
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average ||
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
.._
ND
ND
ND
II
ND
ND
ND
2-22
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
bis(2-Chloroethyl) ether
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Chloro-3-methylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Chloronaphthalene
Concentration, ppbvd "
Emission Rate, Ib/ton b
2-Chlorophenol
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Chlorophenyl phenyl ether
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chrysene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Cumene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Dibenz(a,h)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Dibenzofuran
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 ,2-Dibromo-3-chloropropane (DBCP)
Concentration, ppbvd "
Emission Rate, Ib/ton b
Di-n-butyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-23
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
,2-Dichlorobenzene
Concentration, ppbvd "
Emission Rate, Ib/ton b
,3-Dichlorobenzene
Concentration, ppbvd a
Emission Rate, Ib/ton b
,4-DichIorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
3,3'-Dichlorobenzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4-Dichlorophenol
Concentration, ppbvd "
Emission Rate, Ib/ton b
Diethyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
^-N-Diethylaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
3,3'-Dimethoxybenzidine
Concentration, ppbvd '
Emission Rate, Ib/ton b
Dimethyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Dimethylaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
3,3'-Dimethylbenzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-24
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
tun No.
2,4-Dimethylphenol
Concentration, ppbvd "
Emission Rate, Ib/ton b
4,6-Dinitro-2-methylphenol
Concentration, ppbvd °
Emission Rate, Ib/ton b
2,4-Dinitrophenol
Concentration, ppbvd "
Emission Rate, Ib/ton b
2,4-Dinitrotoluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,6-Dinitrotoluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Di-n-octyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
bis(2-Ethylhexyl)-phthalate
Concentration, ppbvd 8
Emission Rate, Ib/ton b
Fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Fluorene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Hexachlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Hexachlorobutadiene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MMS-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-25
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
Hexachlorocyclopentadiene
Concentration, ppbvd *
Emission Rate, Ib/ton b
iexachloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
-lydroquinone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Indeno(l ,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
isophorone
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methoxybenzenamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
4,4'-Methyl-bis(2-chloroaniline)
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methylnaphthalene
Concentration, ppbvd "
Emission Rate, Ib/ton b
2-Methylphenol
Concentration, ppbvd a
Emission Rate, Ib/ton b
3/4-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Naphthalene
Concentration, ppbvd s
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.36E+00
1.36E-06
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.84E+00
9.92E-07
ND
ND
ND
ND
1.66E+00
5.23E-07
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.60E+00
1.18E-06
ND
ND
ND
ND
(8.31E-01)
(2.61E-07)
2-26
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
2-Nitroaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
3-Nitroaniline
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Nitroaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
Nitrobenzene
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Nitrodiphenyl
Concentration, ppbvd "
Emission Rate, Ib/ton b
2-Nitrophenol
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Nitrophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitrosodimethylamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitrosodiphenylamine
Concentration, ppbvd "
Emission Rate, Ib/ton b
N-Nitroso-di-n-propylamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitrosomorpholine
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-27
-------
TABLE 2.10 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
2,2'-Oxybis( 1 -chloropropane)
Concentration, ppbvd "
Emission Rate, Ib/ton b
'entachloronitrobenzene (PCNB)
Concentration, ppbvd *
Emission Rate, Ib/ton b
5entachlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Phenanthrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Phenol
Concentration, ppbvd a
Emission Rate, Ib/ton b
Pyrene
Concentration, ppbvd "
Emission Rate, Ib/ton b
o-Toluidine
Concentration, ppbvd a
Emission Rate, Ib/ton b
1 ,2,4-Trichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4,5-Trichlorophenol
Concentration, ppbvd a
Emission Rate, Ib/ton b
2,4,6-Trichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-MM5-3
ND
ND
ND
ND
ND
ND
ND
ND
3.08E+00
7.11E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
(1.54E+00)
(3.55E-07)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-28
-------
TABLE 2.10 (Concluded)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Trifluralin
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-MM5-2
ND
ND
T-MM5-3
ND
ND
Average
ND
ND
Parts per billion by volume dry.
Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
( ) Results in parentheses include NDs which were averaged as zero.
2-29
-------
TABLE 2.11
VOLATILE ORGANICS - SW-846 METHOD 0030
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Capture Efficiency, percent *
Average Sampling Rate, dsLpm b
Total Sample Volume, dsL c
Average Exhaust Gas Temperature, °F d
Moisture, % by Volume d
Exhaust Gas Volumetric Flow Rate: d
acfrn e
dscfm f
dscmm g
Process Parameters
RTFOT Results, Mass Change at 325°F, % h
Asphalt Temperature at Load-out, °F '
Asphalt Loaded per Test Period, Tons j
T-V-1
7/24/98
0829-1133
89.9
64
0.610
52.98
81
3.7
11,300
10,300
292
-0.362
321
709.1
T-V-2
7/25/98
0802-1122
102.3
65
0.817
82.64
82
3.5
10,600
9,660
274
-0.322
316
586.1
T-V-3
7/27/98
0917-1123
85.0
54
0.720
60.89
89
3.5
11,100
9,970
282
-0.284
291
824.5
Average
92.4
61
0.716
65.50
84
3.6
11,000
9,977
283
-0.322
310
706.6
* Lower 90% confidence level capture efficiency was determined by MRL
b Dry standard liters per minute at 68°F (20°C) and 1 atm.
c Dry standard liters at 68°F (20°C) and 1 atm.
d Data taken from concurrent SW-846 Method 0010 train.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
8 Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
h Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
1 From Table 3.3 in Section 3.
1 From Table 2.12 in Section 2.
2-30
-------
TABLE 2.12
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acetone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Acrylonitrile
Concentration, ppbvd *
Emission Rate, Ib/ton b
Allyl chloride
Concentration, ppbvd '
Emission Rate, Ib/ton b
Benzene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Bromodichloromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Bromoform
Concentration, ppbvd *
Emission Rate, Ib/ton b
Bromomethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1,3-Butadiene
Concentration, ppbvd "
Emission Rate, Ib/ton b
2-Butanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Carbon disulfide
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-V-1
7/24/98
0829-1133
709.1
{8.18E+00}
{1.61E-06}
ND
ND
ND
ND
4.37E+00
1.16E-06
ND
ND
ND
ND
{1.17E+00}
{3.77E-07}
ND
ND
(3.59E+00)
(8.77E-07)
{2.98E-01}
{7.69E-08}
T-V-2
7/25/98
0802-1122
586.1
4.30E+00
1.09E-06
ND
ND
ND
ND
2.85E+00
9.75E-07
ND
ND
ND
ND
(3.25E-01)
(1.35E-07)
ND
ND
(3.29E+00)
(1.04E-06)
{1.02E+00}
{3.40E-07}
T-V-3
7/27/98
0917-1123
824.5
(1.24E+00)
(1.93E-07)
ND
ND
ND
ND
1.80E+00
3.75E-07
ND
ND
ND
ND
(2.08E-02)
(5.27E-09)
ND
ND
(9.10E-01)
(1.75E-07)
{2.70E-01}
{5.48E-08}
Average
706.6
(4.57E+00)
(9.65E-07)
ND
ND
ND
ND
3.01E+00
8.35E-07
ND
ND
ND
ND
(5.06E-01)
(1.72E-07)
ND
ND
(2.60E+00)
(6.97E-07)
{5.30E-01}
{1.57E-07}
2-31
-------
TABLE 2.12 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Carbon tetrachloride
Concentration, ppbvd "
Emission Rate, Ib/ton b
Chlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
Chloroform
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Cumene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Dibromochloromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 ,2-Dibromoethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1-Dichloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 ,2-Dichloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
1 , 1 -Dichloroethene
Concentration, ppbvd a
Emission Rate, Ib/ton b
T-V-1
ND
ND
ND
ND
(4.93E-02)
(1.08E-08)
ND
ND
2.14E+00
3.66E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-V-2
ND
ND
ND
ND
ND
ND
ND
ND
{1.33E+00}
{2.93E-07}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
T-V-3
ND
ND
ND
ND
ND
ND
ND
ND
(5.71E-01)
(7.70E-08)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
(1.64E-02)
(3.59E-09)
ND
ND
(1.35E+00)
(2.45E-07)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-32
-------
TABLE 2.12 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Xun No.
cis- 1 ,2-Dichloroethene
Concentration, ppbvd "
Emission Rate, Ib/ton b
trans- 1 ,2-Dichloroethene
Concentration, ppbvd "
Emission Rate, Ib/ton b
1 ,2-Dichloropropane
Concentration, ppbvd a
Emission Rate, Ib/ton b
cis- 1 ,3-Dichloropropene
Concentration, ppbvd "
Emission Rate, Ib/ton b
trans- 1 ,3-Dichloropropene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1,2-Epoxybutane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Ethyl acrylate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Ethylbenzene
Concentration, ppbvd °
Emission Rate, Ib/ton b
n-Hexane
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Hexanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
lodomethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
T-V-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.58E+00
5.69E-07
{2.04E+00}
{5.97E-07}
ND
ND
ND
ND
T-V-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{4.41E-01}
{2.05E-07}
{2.26E+00}
{8.54E-07}
ND
ND
ND
ND
T-V-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.85E-01
2.22E-07
{1.76E+00}
{4.05E-07}
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{9.36E-01}
{3.32E-07}
{2.02E+00}
{6.18E-07}
ND
ND
ND
ND
2-33
-------
TABLE 2.12 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
sooctane
Concentration, ppbvd *
Emission Rate, Ib/ton b
vlethyl methacrylate
Concentration, ppbvd *
Emission Rate, Ib/ton b
VIethylene chloride
Concentration, ppbvd *
Emission Rate, Ib/ton b
LMethyl-2-pentanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
MTBE
Concentration, ppbvd *
Emission Rate, Ib/ton b
Styrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1 ,2,2-Tetrachloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
Tetrachloroethene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Toluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1,1,1 -Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1 ,2-Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-V-1
ND
ND
ND
ND
{4.63E+00}
{1.33E-06}
ND
ND
(9.79E-02)
(2.92E-08)
ND
ND
ND
ND
(2.52E-01)
(1.42E-07)
{6.29E+00}
{1.96E-06}
ND
ND
ND
ND
T-V-2
{2.17E-01}
{1.08E-07}
ND
ND
(2.17E+00)
(8.07E-07)
ND
ND
{4.29E-01}
{1.66E-07}
(2.99E-01)
(1.36E-07)
ND
ND
{2.07E-01}
{1.50E-07}
2.34E-K)0
9.44E-07
ND
ND
ND
ND
T-V-3
(4.15E-02)
(1.27E-08)
ND
ND
{6.44E+00}
{1.46E-06}
ND
ND
{2.91E-01}
{6.85E-08}
{3.87E-01}
{1.08E-07}
ND
ND
{1.57E-01}
{6.96E-08}
2.70E+00
6.63E-07
ND
ND
ND
ND
Average
(8.60E-02)
(4.03E-08)
ND
ND
(4.41E+00)
(1.20E-06)
ND
ND
(2.73E-01)
(8.78E-08)
(2.29E-01)
(8.13E-08)
ND
ND
(2.05E-01)
(1.20E-07)
{3.78E+00}
{1.19E-06}
ND
ND
ND
ND
2-34
-------
TABLE 2.12 (Concluded)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Trichloroethene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Trichlorofluoromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Vinyl acetate
Concentration, ppbvd "
Emission Rate, Ib/ton b
Vinyl bromide
Concentration, ppbvd "
Emission Rate, Ib/ton b
Vinyl chloride
Concentration, ppbvd *
Emission Rate, Ib/ton b
m-/p-Xylene
Concentration, ppbvd "
Emission Rate, Ib/ton b
o-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-V-1
ND
ND
(5.62E-02)
(2.61E-08)
ND
ND
ND
ND
ND
ND
{9.22E+00}
{3.32E-06}
2.85E+00
1.03E-06
T-V-2
ND
ND
(7.20E-02)
(4.33E-08)
ND
ND
ND
ND
ND
ND
{2.50E+00}
{1.16E-06}
{7.16E-01}
{3.33E-07}
T-V-3
ND
ND
{8.05E-02}
{2.95E-08}
ND
ND
ND
ND
ND
ND
3.82E+00
1.08E-06
1.39E+00
3.93E-07
Average
ND
ND
(6.96E-02)
(3.30E-08)
ND
ND
ND
ND
ND
ND
{5.18E+00}
{1.85E-06}
{1.65E+00}
{5.84E-07}
Parts per billion by volume dry.
Pounds per ton of asphalt loaded
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{ } Estimate - Concentration exceeds calibration range.
( ) Results in parentheses include NDs which were averaged as zero.
2-35
-------
TABLE 2.13
VOLATILE ORGANICS - EPA METHOD 18
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Capture Efficiency, percent *
Average Sampling Rate, dsLpm b
Total Sample Volume, dsL c
Average Exhaust Gas Temperature, °F d
Moisture, % by Volume d
Exhaust Gas Volumetric Flow Rate: d
acfin'
dscfm f
dscmm g
Process Parameters
RTFOT Results, Mass Change at 325°F, % b
Asphalt Temperature at Load-out, °F '
Asphalt Loaded per Test Period, Tons '
T-M18-1A
7/24/98
0720-1256
240
64
0.966
231.9
81
3.7
11,300
10,300
292
-0.362
321
1,853.8
T-M18-2A
7/25/98
0710-1126
240
65
0.960
230.3
82
3.5
10,600
9,660
274
-0.322
316
1,499.7
T-M18-3A
7/27/98
0710-1155
240
54
0.961
230.7
89
3.5
11,100
9,970
282
-0.284
291
2,530.2
Average
240
61
0.962
231.0
84
3.6
11,000
9,977
283
-0.322
310
1,961.2
* Lower 90% confidence level capture efficiency was determined by MRI.
b Dry standard liters per minute at 68°F (20°C) and 1 atm.
c Dry standard liters at 68°F (20°C) and 1 atm.
d Data taken from concurrent SW-846 Method 0010 train.
' Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
8 Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
h Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
1 From Table 3.3 in Section 3.
j From Table 2.14 in Section 2.
2-36
-------
TABLE 2.14
VOLATILE ORGANICS - EPA METHOD 18
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
NORMAL OPERATIONS, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Jenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Cumene
Concentration, ppbvd *
Emission Rate, Ib/ton b
ithylbenzene
Concentration, ppbvd a
Emission Rate, Ib/ton b
lexane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Toluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
m-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
o-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
p-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
T-M18-1A
7/24/98
0720-1256
1,853.8
ND
ND
{1.39E+01}
{5.78E-06}
3.22E+01
1.18E-05
{1.18E+01}
{3.52E-06}
{1.71E+01}
{5.45E-06}
{6.97E+00}
{2.56E-06}
{7.80E-K)0}
{2.86E-06}
{2.08E+01}
{7.64E-06}
T-M18-2A
7/25/98
0710-1126
1,499.7
{6.86E+00}
{2.15E-06}
{9.82E+00}
{4.74E-06}
4.04E+01
1.72E-05
{2.23E+01}
{7.71E-06}
{2.91E+01}
{1.08E-05}
{6.76E+00}
{2.88E-06}
{5.57E+00}
{2.37E-06}
{1.32E+01}
{5.62E-06}
T-M18-3A
7/27/98
0710-1155
2,530.2
ND
ND
ND
ND
{1.21E+01}
{3.15E-06}
ND
ND
{1.14E+01}
{2.59E-06}
ND
ND
ND
ND
ND
ND
Average
1,961.2
(2.29E+00)
(7.17E-07)
(7.91E+00)
(3.51E-06)
{2.82E+01}
{1.07E-05}
(1.14E+01)
(3.74E-06)
{1.92E+01}
{6.27E-06}
(4.58E+00)
(1.81E-06)
(4.46E+00)
(1.75E-06)
(1.13E-K)!)
(4.42E-06)
' Parts per billion by volume dry.
b Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit Values are counted as zero (0) in averages.
{} Estimate - Concentration exceeds calibration range.
( ) Results in parentheses include NDs which were averaged as zero.
2-37
-------
TABLE 2.15
ON-SITE GC/MS VOLATILE ORGANICS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
WITH VOST (SW-846 METHOD 0030) AND EPA METHOD 18 COMPARISON
TUNNEL EXHAUST DUCT
ASPHALT PLANT C, CALIFORNIA
7/24/98
Sample ID
Acquisition Time
Toluene
Concentration, ppbvd
m/p-Xylene
Concentration, ppbvd
Ethyl Benzene
Concentration, ppbvd
Benzene
Concentration, ppbvdb
TED-
72409
1146
8
15
3
NA
TED-
72410
1203
8
18
3
NA
TED-
72411
1217
10
40
NA
10
TED-
BAG01
1230-1242
10
17
9
NA
TED-
BAG02
1230-1242
9
10
9
NA
TED-
BAG03
1230-1242
10
40
NA
10
TED-
BAG04
1230-1242
20
20
2
10
HMLO'
BAG04
1220-1235
7.67
20.0
4.33
10.0
Averages
GC/MS
Results
10.3
22.5
5.06
10.0
VOST
0829-1133
6.29
9.22
1.58
4.37
M18
0720-1256
17.1
27.8C
32.2
ND
* HMLO - Taken from Hot Mix Load-out sample above transport truck during load-out.
b Parts per billion by volume dry.
0 The EPA Method 18 results lists m-xlyene and p-xylene separately. The value shown here is the sum of the two.
Notes:
"NA" indicates compound was not analyzed. "ND" indicates compound was below the detection limit (Not Detected). NDs were not averaged as zeroes in this table.
On-site GC cannot be directly related to the longer integration times - grab samples were taken only during active loading.
-------
TABLE 2.16
PM AND MCEM
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-M315-4
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfm *
Capture Efficiency, percentb
Sample Volume:
dscfc
dscmd
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfme
dscfm'
dscmmf
Isokinetic Sampling Ratio, %
7/26/98
0926-1340
240
0.698
45
167.419
4.741
91
3.2
11,800
10,500
299
101.7
" Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Lower 90% confidence level capture efficiency was determined by MRI.
c Dry standard cubic feet at 68°F (20°C) and 1 atm.
d Dry standard cubic meters at 68°F (20°C) and 1 atm.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-39
-------
TABLE 2.17
PM AND MCEM
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-M315-4
Date
lock Time, 24-hr clock
Paniculate Matter (PM)
Concentration, gr/dscfa
Concentration, g/dscmb
Emission Rate, Ib/test periodc
Methylene Chloride
Extractable Matter (MCEM)
Concentration, gr/dscfa
Concentration, g/dscm b
Emission Rate, Ib/test periodc
7/26/98
0926-1340
7.93E-04
1.81E-03
2.87E-01
3.78E-04
8.65E-04
1.37E-01
1 Grains per dry standard cubic feet at 68°F (20°C) and 1 atm.
b Grams per dry standard cubic meters at 68°F (20°C) and 1 atm.
c Pounds per test period.
2-40
-------
TABLE 2.18
PAHs AND SEMI-VOLATILE ORGANICS
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-MM5-4
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfina
lapture Efficiency, percentb
Sample Volume:
dscfc
dscmd
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfmc
dscfin*
dscmmf
Isokinetic Sampling Ratio, %
7/26/98
0925-1343
240
0.706
45
169.391
4.797
87
3.6
12,000
10,800
310
105.6
1 Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Lower 90% confidence level capture efficiency was determined by MRI.
c Dry standard cubic feet at 68°F (20°C) and 1 atm.
d Dry standard cubic meters at 68°F (20°C) and 1 atm.
' Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-41
-------
TABLE 2.19
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-MM5-4
Date
lock Time, 24-hr clock
.cenaphthene
Concentration, ppbvd *
Emission Rate, Ib/test period b
icenaphthylene
Concentration, ppbvda
Emission Rate, Ib/test period b
Anthracene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Benzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Benzo(b)fluoranthene
Concentration, ppbvda
Emission Rate, Ib/test period b
Benzo(k)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Benzo(ghi)perylene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Benzo(a)pyrene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Benzo(e)pyrene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Chrysene
Concentration, ppbvd *
Emission Rate, Ib/test period *
7/26/98
0925-1343
{1.79E-02}
{1.85E-05}
2.60E-03
2.69E-06
6.19E-03
7.41E-06
3.29E-04
5.05E-07
3.58E-04
6.06E-07
ND
ND
1.36E-04
2.53E-07
ND
ND
2.58E-04
4.38E-07
6.81E-03
1.04E-05
2-42
-------
TABLE 2.19 (Concluded)
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-MM5-4
Dibenz(a,h)anthracene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Huoranthene
Concentration, ppbvd"
Emission Rate, Ib/test period b
'luorene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Indeno(l,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
2-Methylnaphthalene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Naphthalene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Perylene
Concentration, ppbvda
Emission Rate, Ib/test period b
Phenanthrene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Pyrene
Concentration, ppbvd *
Emission Rate, Ib/test period b
ND
ND
7.44E-03
1.01E-05
{4.83E-02}
{5.39E-05}
ND
ND
{S.17E-02}
{8.76E-05}
BRL
BRL
ND
ND
{1.13E-01}
{1.35E-04}
{1.49E-02}
{2.02E-05}
Parts per billion by volume.
Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{} Estimate - Concentration in the sample exceeded the method calibration range,
but was still within the linear response range of the detector.
BRL Below Reporting Limit based on Equation 429-32 of CARB Method 429.
2-43
-------
TABLE 2.20
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
ilun No.
T-MMS-4
Date
3Iock Time, 24-hr clock
^enaphthene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
\cenaphthylene
Concentration, ppbvd *
Emission-Rate, Ib/test period b
\cetophenone
Concentration, ppbvd"
Emission Rate, Ib/test periodb
t-Arninobiphenyl
Concentration, ppbvd *
Emission Rate, Ib/test period b
Aniline
Concentration, ppbvd"
Emission Rate, Ib/test period b
Anthracene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Benzidine
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Benzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/test period'
Benzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/test period'
Benzo(k)fluoranthene
Concentration, ppbvda
Emission Rate, Ib/test period'
7/26/98
0925-1343
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-44
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
&un No.
T-MM5-4
Benzole acid
Concentration, ppbvd *
Emission Rate, Ib/test period b
3enzo(g,h,i)perylene
Concentration, ppbvd'
Emission Rate, Ib/test periodb
3enzo(a)pyrene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
3enzo(e)pyrene
Concentration, ppbvd"
Emission Rate, Ib/test periodb
Benzyl alcohol
Concentration, ppbvd"
Emission Rate, Ib/test period *
Biphenyl
Concentration, ppbvd *
Emission Rate, Ib/test period'
4-Bromophenyl phenyl ether
Concentration, ppbvd"
Emission Rate, Ib/test periodb
Butyl benzyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/test period'
Chloroacetophenone
Concentration, ppbvd *
Emission Rate, Ib/test period'
4-Chloroaniline
Concentration, ppbvd *
Emission Rate, Ib/test period'
bis(2-Chloroethoxy)-methane
Concentration, ppbvd *
Emission Rate, Ib/test period'
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-45
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
tun No.
T-MM5-4
is(2-Chloroethyl) ether
Concentration, ppbvd *
Emission Rate, Ib/test period
-Chloro-3-methylphenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
'-Chloronaphthalene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
2-Chlorophenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
4-Chlorophenyl phenyl ether
Concentration, ppbvd *
Emission Rate, Ib/test period b
Chrysene
Concentration, ppbvd"
Emission Rate, Ib/test period b
Cumene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Dibenz(a,h)anthracene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Dibenzofuran
Concentration, ppbvd"
Emission Rate, Ib/test period b
l,2-Dibromo-3-chloropropane (DBCP)
Concentration, ppbvd'
Emission Rate, Ib/test period b
Di-n-butyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/test period b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-46
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-MM5-4
1,2-Dichlorobenzene
Concentration, ppbvd"
Emission Rate, Ib/test periodb
1,3-Dichlorobenzene
Concentration, ppbvda
Emission Rate, Ib/test periodb
1,4-Dichlorobenzene
Concentration, ppbvd"
Emission Rate, Ib/test period *
3,3'-Dichlorobenzidine
Concentration, ppbvd *
Emission Rate, Ib/test period'
2,4-Dichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/test period'
Diethyl phthalate
Concentration, ppbvd"
Emission Rate, Ib/test period'
N-N-Diethylaniline
Concentration, ppbvd *
Emission Rate, Ib/test period'
3,3 '-Dimethoxybenzidine
Concentration, ppbvd *
Emission Rate, Ib/test period'
Dimethyl phthalate
Concentration, ppbvd*
Emission Rate, Ib/test period'
Dimethylaniline
Concentration, ppbvd *
Emission Rate, Ib/test period'
3,3'-Dimethylbenzidine
Concentration, ppbvd *
Emission Rate, Ib/test period'
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-47
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-MM5-4
J,4-Dimethy]phenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
f,6-Dinitro-2-methylphenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
2,4-Dinitrophenol
Concentration, ppbvd *
Emission Rate, Ib/test period b
2,4-Dinitrotoluene
Concentration, ppbvd *
Emission Rate, Ib/test period b
2,6-Dinitrotoluene
Concentration, ppbvda
Emission Rate, Ib/test periodb
Di-n-octyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/test period b
bis(2-Ethylhexyl)-phthalate
Concentration, ppbvd*
Emission Rate, Ib/test periodb
Fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Fluorene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Hexachlorobenzene
Concentration, ppbvd"
Emission Rate, Ib/test period b
Hexachlorobutadiene
Concentration, ppbvda
Emission Rate, Ib/test period b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-48
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-MM5-4
Hexachlorocyclopentadiene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Hexachloroethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Hydroquinone
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Indeno( 1,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Isophorone
Concentration, ppbvd *
Emission Rate, Ib/test period b
2-Methoxybenzenamine
Concentration, ppbvd *
Emission Rate, Ib/test periodb
4,4'-Methyl-bis(2-chloroaniline)
Concentration, ppbvd *
Emission Rate, Ib/test period b
2-Methylnaphthalene
Concentration, ppbvd"
Emission Rate, Ib/test period b
2-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
3/4-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Naphthalene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-49
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-MM5-4
-Nitroaniline
Concentration, ppbvd"
Emission Rate, Ib/test period
-Nitroaniline
Concentration, ppbvd *
Emission Rate, Ib/test period b
-Nitroaniline
Concentration, ppbvda
Emission Rate, Ib/test periodb
Nitrobenzene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
4-NitrodiphenyI
Concentration, ppbvd *
Emission Rate, Ib/test period b
2-Nitrophenol
Concentration, ppbvd"
Emission Rate, Ib/test periodb
4-Nitrophenol
Concentration, ppbvd *
Emission Rate, Ib/test period b
^-Nitrosodimethylamine
Concentration, ppbvda
Emission Rate, Ib/test periodb
N-Nitrosodiphenylamine
Concentration, ppbvd *
Emission Rate, Ib/test period'
N-Nitroso-di-n-propylamine
Concentration, ppbvd *
Emission Rate, Ib/test period'
N-Nitrosomorpholine
Concentration, ppbvd *
Emission Rate, Ib/test period'
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-50
-------
TABLE 2.20 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-MM5-4
2,2'-Oxybis( 1 -chloropropane)
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Pentachloronitrobenzene (PCNB)
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Pentachlorophenol
Concentration, ppbvd *
Emission Rate, Ib/test period b
Phenanthrene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Phenol
Concentration, ppbvd *
Emission Rate, Ib/test period b
Pyrene
Concentration, ppbvd'
Emission Rate, Ib/test periodb
o-Toluidine
Concentration, ppbvd *
Emission Rate, Ib/test period b
1,2,4-Trichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
2,4,5-Trichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
2,4,6-Trichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/test periodb
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-51
-------
TABLE 2.20 (Concluded)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Trifluralin
Concentration, ppbvd *
Emission Rate, Ib/test period
T-MM5-4
ND
ND
Parts per billion by volume dry.
Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit.
2-52
-------
TABLE 2.21
VOLATILE ORGANICS - SW-846 METHOD 0030
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-V-4
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Capture Efficiency, percent'
Average Sampling Rate, dsLpmb
Total Sample Volume, dsLc
Average Exhaust Gas Temperature, °F
Moisture, % by Volume d
Exhaust Gas Volumetric Flow Rate:
acfme
dscfinf
dscmm8
7/26/98
0925-1222
75
45
0.850
63.72
87
3.6
12,000
10,800
310
* Lower 90% confidence level capture efficiency was determined by MRI.
b Dry standard liters per minute at 68°F (20°C) and 1 atm.
c Dry standard liters at 68°F (20°C) and 1 atm.
d Data taken from concurrent SW-846 Method 0010 train.
e Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
g Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-53
-------
TABLE 2.22
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-V-4
)ate
:iock Time, 24-hr clock
Acetone
Concentration, ppbvd *
Emission Rate, Ib/test period b
torylonitrile
Concentration, ppbvd"
Emission Rate, Ib/test period b
Mlyl chloride
Concentration, ppbvd *
Emission Rate, Ib/test period b
Benzene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Jromodichloromethane
Concentration, ppbvd *
Emission Rate, Ib/test period b
3romoform
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Bromomethane
Concentration, ppbvd *
Emission Rate, Ib/test period'
1,3-Butadiene
Concentration, ppbvd *
Emission Rate, Ib/test period'
2-Butanone
Concentration, ppbvd *
Emission Rate, Ib/test period'
Carbon disulfide
Concentration, ppbvd"
Emission Rate, Ib/test period'
7/26/98
0925-1222
(2.00E+00)
(2.43E-04)
ND
ND
ND
ND
{1.07E+00}
{1.75E-04}
ND
ND
ND
ND
(9.15E-02)
(1.82E-05)
ND
ND
(2.67E-01)
(4.04E-05)
ND
ND
2-54
-------
TABLE 2.22 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-V-4
Carbon tetrachloride
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Chlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Chloroethane
Concentration, ppbvd *
Emission Rate, Ib/test period b
Chloroform
Concentration, ppbvd *
Emission Rate, Ib/test period b
Chloromethane
Concentration, ppbvd *
Emission Rate, Ib/test period b
Cumene
Concentration, ppbvd *
Emission Rate, Ib/test period b
Dibromochloromethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
1,2-Dibromoethane
Concentration, ppbvd *
Emission Rate, Ib/test period b
1,1-Dichloroethane
Concentration, ppbvd *
Emission Rate, Ib/test period b
1,2-Dichloroethane
Concentration, ppbvd"
Emission Rate, Ib/test period b
1,1 -Dichloroethene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
ND
ND
ND
ND
ND
ND
(1.90E-02)
(4.76E-06)
(3.74E-01)
(3.96E-05)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-55
-------
TABLE 2.22 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
T-V-4
is-1,2-Dichloroethene
Concentration, ppbvd'
Emission Rate, Ib/test periodb
trans-1,2-Dichloroethene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
,2-Dichloropropane
Concentration, ppbvd *
Emission Rate, Ib/test period b
is-1,3-Dichloropropene
Concentration, ppbvd"
Emission Rate, Ib/test periodb
trans-1,3-Dichloropropene
Concentration, ppbvd *
Emission Rate, Ib/test period b
,2-Epoxybutane
Concentration, ppbvd *
Emission Rate, Ib/test period b
Ethyl acrylate
Concentration, ppbvd *
Emission Rate, Ib/test period b
ithylbenzene
Concentration, ppbvd *
Emission Rate, Ib/test period b
n-Hexane
Concentration, ppbvd *
Emission Rate, Ib/test period b
2-Hexanone
Concentration, ppbvd *
Emission Rate, Ib/test period b
lodomethane
Concentration, ppbvd"
Emission Rate, Ib/test period b
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(1.46E-01)
(3.25E-05)
{3.90E-01}
{7.05E-05}
ND
ND
ND
ND
2-56
-------
TABLE 2.22 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-V-4
Isooctane
Concentration, ppbvd *
Emission Rate, Ib/test period b
Methyl methacrylate
Concentration, ppbvd"
Emission Rate, Ib/test periodb
Methylene chloride
Concentration, ppbvd *
Emission Rate, Ib/test periodb
4-Methyl-2-pentanone
Concentration, ppbvd *
Emission Rate, Ib/test period b
MTBE
Concentration, ppbvda
Emission Rate, Ib/test periodb
Styrene
Concentration, ppbvd"
Emission Rate, Ib/test period b
1,1,2,2-Tetrachloroethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Tetrachloroethene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Toluene
Concentration, ppbvda
Emission Rate, Ib/test period b
1,1,1 -Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
1,1,2-Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
(1.06E-01)
(2.54E-05)
ND
ND
{1.21E+01}
{2.15E-03}
ND
ND
(7.07E-01)
(1.31E-04)
{1.45E-01}
{3.17E-05}
ND
ND
(8.65E-02)
(3.01E-05)
{1.33E+00}
{2.57E-04}
(3.40E-02)
(9.51E-06)
ND
ND
2-57
-------
TABLE 2.22 (Concluded)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-V-4
Trichloroethene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Trichlorofluoromethane
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Vinyl acetate
Concentration, ppbvd"
Emission Rate, Ib/test periodb
Vinyl bromide
Concentration, ppbvd *
Emission Rate, Ib/test period b
Vinyl chloride
Concentration, ppbvd *
Emission Rate, Ib/test period b
nWp-Xylene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
o-Xylene
Concentration, ppbvd *
Emission Rate, Ib/test period b
(2.87E-03)
(7.93E-07)
(7.42E-02)
(2.14E-05)
ND
ND
ND
ND
ND
ND
(4.09E-01)
(9.11E-05)
(1.74E-01)
(3.88E-05)
1 Parts per billion by volume dry.
b Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{ } Estimate - Concentration exceeds calibration range.
( ) Results in parentheses include NDs which were averaged as zero.
2-58
-------
TABLE 2.23
VOLATILE ORGANICS - EPA METHOD 18
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-M18-4A
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Capture Efficiency, percent"
Average Sampling Rate, dsLpm b
Total Sample Volume, dsLc
Average Exhaust Gas Temperature, °F
Moisture, % by Volume*1
Exhaust Gas Volumetric Flow Rate:
acfine
dscrmf
dscmm8
7/26/98
0925-1346
240
45
0.941
225.8
87
3.6
12,000
10,800
310
* Lower 90% confidence level capture efficiency was determined by MRI.
b Dry standard liters per minute at 68°F (20°C) and 1 atm.
c Dry standard liters at 68°F (20°C) and 1 atm.
d Data taken from concurrent SW-846 Method 0010 train.
c Actual cubic feet per minute at exhaust gas conditions.
f Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
8 Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
2-59
-------
TABLE 2.24
VOLATILE ORGANICS - EPA METHOD 18
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
BACKGROUND CONDITION, TUNNEL EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
T-M18-4A
Date
Clock Time, 24-hr clock
Benzene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Cumene
Concentration, ppbvd *
Emission Rate, Ib/test periodb
Ethylbenzene
Concentration, ppbvda
Emission Rate, Ib/test periodb
iexane
Concentration, ppbvd *
Emission Rate, Ib/test period'
Toluene
Concentration, ppbvd *
Emission Rate, Ib/test period'
m-Xylene
Concentration, ppbvd *
Emission Rate, Ib/test period'
o-Xylene
Concentration, ppbvd *
Emission Rate, Ib/test period'
p-Xylene
Concentration, ppbvda
Emission Rate, Ib/test period'
7/26/98
0925-1346
ND
ND
ND
ND
{1.55E+01}
{1.10E-02}
ND
ND
{1.05E+01}
{6.48E-03}
ND
ND
ND
ND
ND
ND
* Parts per billion by volume dry.
b Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit.
{} Estimate - Concentration exceeds calibration range.
2-60
-------
TABLE 2.25
10
SAMPLE LOG
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run Number
S-MM5-1
S-V-1-1
S-V-1-2
S-V-1-3
S-V-1-4
S-M18-1
S-M315-1
S-MM5-2
S-MM5-1B
S-V-2- 1
S-V-2-2
S-V-2-3
S-V-2-4
S-M18-2
S-M315-2
S-MM5-3
S-V-3-1
S-V-3-2
S-V-3-3
S-V-3-4
S-V-3-5
S-V-3-6
S-M18-3
S-M315-3
S-M315-4
S-MM5-4
S-MM5-5
Results
Presented
No
Yes
Yes
No
Yes
No
Yes
Yes
No
No
No
No
Yes
No
Yes
No
No
No
Yes
No
No
No
No
No
Yes
Yes
Yes
Comments
Integrity of the sample was compromised during transport to the laboratory.
First of 3 sets of tubes for Run S-V-1 . Tenax tube only; Tenax/charcoal tube lost in analysis.
Second of 3 sets of tubes for Run S-V-1.
Third of 3 sets of tubes for Run S-V-1; decision was made to analyze sample S-V-1-4, instead.
Fourth set of tubes from Run S-V-1.
Analyzed but no useful data were obtained because of severe matrix interferences.
No problems encountered during analysis.
Analyzed and then reanalyzed after dilution.
Sampling rate was over-isokinetic; run was rejected.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Only set of tubes from Run S-V-2 chosen for analysis; represents qualitative results for Run S-V-2.
Analyzed but no useful data were obtained because of severe matrix interferences.
Isokinetic rate was 1 10%; no problems encountered during analysis.
Sampling rate was over-isokinetic; run was rejected.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Only set of tubes from Run S-V-3 chosen for analysis; represents qualitative results for Run S-V-3.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Because of the large volume of non-target hydrocarbons present, this sample was not analyzed.
Analyzed but no useful data were obtained because of severe matrix interferences.
Sampling rate was over-isokinetic; run was rejected.
No problems encountered during analysis.
Analyzed and then reanalyzed after dilution.
Analyzed and then reanalyzed after dilution.
-------
TABLE 2.26
PM AND MCEM
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
fcun No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfm *
Sample Volume:
dscf
dscrn0
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
acfind
dscfin11
dscrnm e
Isokinetic Sampling Ratio, %
Process Parameters
RTFOT Results, Mass Change at 325°F, % f
Asphalt Temperature at Load-out, °F *'
Asphalt Loaded per Test Period, Tons h
S-M315-1
7/24/98
1141-1243
60
0.677
40.646
1.151
256
15.4
753
459
13.0
102.3
-0.362
321
336.7
S-M315-2
7/25/98
1015-1117
60
0.680
40.819
1.156
270
24.6
800
426
12.1
110.6
-0.322
316
282.7
S-M315-4
7/28/98
0649-0840
60
0.566
33.959
0.962
228
47.1
754
297
8.41
101.7
-0.346
NM
402.4
Average
0.641
38.475
1.089
251
29.1
769
394
11.2
104.9
-0.343
319
340.6
* Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Dry standard cubic feet at 68°F (20°C) and 1 atm.
c Dry standard cubic meters at 68°F (20°C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
f Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
8 From Table 3.3 in Section 3.
h From Table 2.27 in Section 2.
1 NM = Not Measured.
2-62
-------
TABLE 2.27
PM AND MCEM
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded in, per test period
Particulate Matter (PM)
Concentration, gr/dscf a
Concentration, g/dscm
Emission Rate, Ib/test period c
Emission Rate, Ib/ton
Methylene Chloride
Extractable Matter (MCEM)
Concentration, gr/dscf a
Concentration, g/dscm b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-M315-1
7/24/98
1141-1243
336.7
5.10E-02
1.17E-01
2.00E-01
5.95E-04
1.77E-02
4.04E-02
6.94E-02
2.06E-04
S-M315-2
7/25/98
1015-1117
282.7
3.39E-02
7.75E-02
1.24E-01
4.37E-04
1.24E-02
2.83E-02
4.51E-02
1.60E-04
S-M315-4
7/28/98
0649-0840
402.4
2.42E-02
5.54E-02
6.16E-02
1.53E-04
5.54E-03
1.27E-02
1.41E-02
3.51E-05
Average
340.6
3.63E-02
8.32E-02
1.29E-01
3.95E-04
1.19E-02
2.71E-02
4.29E-02
1.34E-04
* Grains per dry standard cubic feet at 68°F (20°C) and 1 atm.
Grams per dry standard cubic meters at 68°F (20°C) and 1 atm.
0 Pounds per test period.
Pounds per ton of asphalt loaded in.
2-63
-------
TABLE 2.28
PAHs AND SEMI-VOLATILE ORGANICS
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dscfin "
Sample Volume:
dscf
dscmc
Average Exhaust Gas Temperature, °F
Moisture, % by Volume
Exhaust Gas Volumetric Flow Rate:
actm"
dscfrn"
dscmm e
Isokinetic Sampling Ratio, %
Process Parameters
RTFOT Results, Mass Change at 325°F, % f>i
Asphalt Temperature at Load-out, °F *•'
Asphalt Loaded per Test Period, Tons h
S-MM5-2
7/25/98
0710-0950
120
0.706
84.662
2.397
241
22.5
780
445
12.6
109.9
-0.322
316
602.5
S-MM5-4
7/28/98
0913-1323
120
0.400
47.947
1.358
270
52.7
698
232
6.56
92.1
-0.346
NM
881.0
S-MM5-5
7/28/98
1358-1940
120
0.769
92.325
2.614
270
36.3
684
305
8.64
100.8
-0.346
NM
709.4
Average
0.625
74.978
2.123
261
37.2
721
327
9.27
100.9
-0.334
316
731.0
" Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
b Dry standard cubic feet at 68°F (20°C) and 1 atm.
c Dry standard cubic meters at 68°F (20°C) and 1 atm.
d Actual cubic feet per minute at exhaust gas conditions.
e Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
f Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
8 From Table 3.3 in Section 3.
h From Table 2.29 in Section 2.
' Average mass change for 7/25/98 and 7/28/98.
j NM = Not Measured.
2-64
-------
TABLE 2.29
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acenaphthene
Concentration, ppbvd "
Emission Rate, Ib/ton
Acenaphthylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Anthracene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Benzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(k)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(g,h,i)perylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(a)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(e)pyrene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Chrysene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
7/25/98
0710-0950
602.5
1.24E+01
4.38E-07
ND
ND
3.21E+00
1.31E-07
7.47E-01
3.92E-08
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.81E+00
1.48E-07
S-MM5-4
7/28/98
0913-1323
881.0
1.95E+01
2.46E-07
ND
ND
5.57E+00
8.12E-08
2.02E+00
3.77E-08
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
7.53E+00
1.41E-07
S-MM5-5
7/28/98
1358-1940
709.4
2.21E+01
4.56E-07
1.31E+00
2.71E-08
4.85E-K)0
1.16E-07
1.73E+00
5.30E-08
ND
ND
ND
ND
ND
ND
ND
ND
5.47E-01
1.85E-08
6.45E+00
1.97E-07
Average
731.0
1.80E+01
3.80E-07
(4.38E-01)
(9.04E-09)
4.54E+00
1.10E-07
1.50E+00
4.33E-08
ND
ND
ND
ND
ND
ND
ND
ND
(1.82E-01)
(6.17E-09)
5.60E+00
1.62E-07
2-65
-------
TABLE 2.29 (Concluded)
PAHs EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
3ibenz(a,h)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton
Fluoranthene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Fluorene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Indeno(l ,2,3-cd)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methylnaphthalene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Naphthalene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Perylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Phenanthrene
Concentration, ppbvd '
Emission Rate, Ib/ton b
Pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
2.73E+00
1.27E-07
3.62E+01
1.38E-06
ND
ND
1.98E+02
6.46E-06
6.26E+01
1.84E-06
8.35E-01
4.84E-08
5.46E+01
2.24E-06
1.14E+01
5.30E-07
S-MM5-4
ND
ND
5.87E+00
9.71E-08
3.62E+01
4.93E-07
ND
ND
2.49E-H)2
2.90E-06
9.95E+01
1.04E-06
ND
ND
6.36E+01
9.28E-07
1.49E-K)!
2.46E-07
S-MM5-5
ND
ND
4.55E+00
1.23E-07
3.54E+01
7.89E-07
ND
ND
2.20E+02
4.19E-06
9.33E+01
1.60E-06
1.02E+00
3.45E-08
6.19E+01
1.48E-06
1.32E+01
3.58E-07
Average
ND
ND
4.38E+00
1.16E-07
3.60E+01
8.89E-07
ND
ND
2.22E+02
4.52E-06
8.52E+01
1.50E-06
(6.19E-01)
(2.77E-08)
6.01E+01
1.55E-06
1.32E+01
3.78E-07
Parts per billion by volume dry.
Pounds per ton of asphalt loaded in.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
() Parentheses indicate the results include NDs that were averaged as zero.
2-66
-------
TABLE 2.30
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acenaphthene
Concentration, ppbvd '
Emission Rate, Ib/ton b
Acenaphthylene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Acetophenone
Concentration, ppbvd "
Emission Rate, Ib/ton b
4-Aminobiphenyl
Concentration, ppbvd "
Emission Rate, Ib/ton b
Aniline
Concentration, ppbvd a
Emission Rate, Ib/ton b
Anthracene
Concentration, ppbvd '
Emission Rate, Ib/ton b
Benzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
3enzo(a)anthracene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(b)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzo(k)fluoranthene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
7/25/98
0710-0950
602.5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
7/28/98
0913-1323
881.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
7/28/98
1358-1940
709.4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
731.0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-67
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Benzole acid
Concentration, ppbvd "
Emission Rate, Ib/ton b
Jenzo(g,h,i)perylene
Concentration, ppbvd "
Emission Rate, Ib/ton b
3enzo(a)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Jenzo(e)pyrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Benzyl alcohol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Biphenyl
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Bromophenyl phenyl ether
Concentration, ppbvd *
Emission Rate, Ib/ton b
Butyl benzyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton k
Chloroacetophenone
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Chloroaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
bis(2-Chloroethoxy)-methane
Concentration, ppbvd a
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-68
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
ilun No.
bis(2-Chloroethyl) ether
Concentration, ppbvd a
Emission Rate, Ib/ton b
4-Chloro-3-methylphenol
Concentration, ppbvd a
Emission Rate, Ib/ton b
2-Chloronaphthalene
Concentration, ppbvd a
Emission Rate, Ib/ton b
2-Chlorophenol
Concentration, ppbvd a
Emission Rate, Ib/ton b
4-Chlorophenyl phenyl ether
Concentration, ppbvd a
Emission Rate, Ib/ton b
Chrysene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Cumene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Dibenz(a,h)anthracene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Dibenzofuran
Concentration, ppbvd a
Emission Rate, Ib/ton b
l,2-Dibromo-3-chloropropane (DBCP)
Concentration, ppbvd a
Emission Rate, Ib/ton b
Di-n-butyl phthalate
Concentration, ppbvd a
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-69
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
1 ,2-Dichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 ,3-Dichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
,4-Dichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
3,3'-Dichlorobenzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4-Dichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Diethyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
•J-N-Diethylaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
3 ,3'-Dimethoxybenzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
Dimethyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Dimethylaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
3,3'-Dimethylbenzidine
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MMS-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-70
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
2,4-Dimethylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
4,6-Dinitro-2-methylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4-DinitrophenoI
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4-Dinitrotoluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,6-Dinitrotoluene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Di-n-octyl phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
bis(2-Ethylhexyl)-phthalate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Fluoranthene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Fluorene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Hexachlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Hexachlorobutadiene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{3.10E+01}
{6.91E-07}
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(1.03E+01)
(2.30E-07)
ND
ND
ND
ND
2-71
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
lexachlorocyclopentadiene
Concentration, ppbvd '
Emission Rate, Ib/ton b
iexachloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Jydroquinone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Indeno( 1 ,2,3-cd)pyrene
Concentration, ppbvd "
Emission Rate, Ib/ton b
sophorone
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methoxybenzenamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
4,4'-Methyl-bis(2-chloroaniline)
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methylnaphthalene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
3/4-Methylphenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Naphthalene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.54E+02
8.30E-06
ND
ND
ND
ND
{1.25E+02}
{3.69E-06}
S-MM5-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.87E+02}
{3.33E-06}
ND
ND
ND
ND
{2.07E+02}
{2.17E-06}
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.85E+02
5.43E-06
ND
ND
ND
ND
{1.87E+02}
{3.21E-06}
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.75E+02}
{5.69E-06}
ND
ND
ND
ND
{1.73E+02}
{3.02E-06}
2-72
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
2-Nitroaniline
Concentration, ppbvd "
Emission Rate, Ib/ton b
3-Nitroaniline
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Nitroaniline
Concentration, ppbvd a
Emission Rate, Ib/ton b
Nitrobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Nitrodiphenyl
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Nitrophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
4-Nitrophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitrosodimethylamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitrosodiphenylamine
Concentration, ppbvd *
Emission Rate, Ib/ton b
N-Nitroso-di-n-propylamine
Concentration, ppbvd a
Emission Rate, Ib/ton b
N-Nitrosomorpholine
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-73
-------
TABLE 2.30 (Continued)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
2,2'-Oxybis( 1 -chloropropane)
Concentration, ppbvd *
Emission Rate, Ib/ton b
^entachloronitrobenzene (PCNB)
Concentration, ppbvd "
Emission Rate, Ib/ton b
'entachlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
Phenanthrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
5henol
Concentration, ppbvd *
Emission Rate, Ib/ton b
?yrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
o-Toluidine
Concentration, ppbvd '
Emission Rate, Ib/ton b
1 ,2,4-Trichlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4,5-Trichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
2,4,6-Trichlorophenol
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
ND
ND
ND
ND
{5.35E+01}
{2.19E-06}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-4
ND
ND
ND
ND
ND
ND
{5.86E+01}
{8.55E-07}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-MM5-5
ND
ND
ND
ND
ND
ND
{6.19E+01}
{1.48E-06}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
{5.80E+01}
{1.51E-06}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-74
-------
TABLE 2.30 (Concluded)
SEMI-VOLATILE ORGANICS
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Trifluralin
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-MM5-2
ND
ND
S-MM5-4
ND
ND
S-MM5-5
ND
ND
Average
ND
ND
Parts per billion by volume dry.
Pounds per ton of asphalt loaded in.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{ } Estimate - Concentration exceeds calibration range.
( ) Results in parentheses include NDs which were averaged as zero.
2-75
-------
TABLE 2.31
VOLATILE ORGANICS - SW-846 METHOD 0030
EMISSIONS SAMPLING AND EXHAUST GAS PARAMETERS
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Total Sampling Time, minutes
Average Sampling Rate, dsLpm *
Total Sample Volume, dsL b
Average Exhaust Gas Temperature, °F c
Moisture, % by Volume0
Exhaust Gas Volumetric Flow Rate: c
acfin"
dscrrn*
dscmrnf
Process Parameters
RTFOT Results, Mass Change at 325°F, % g
Asphalt Temperature at Load-out, °F h
Asphalt Loaded per Test Period, Tons '
S-V-1
7/24/98
0726-1014
30.0
0.194
5.83
235
12.8
111
503
14.2
-0.362
321
193.5
S-V-2
7/25/98
0910-0920
10.0
0.25
2.47
241
22.5
780
445
12.6
-0.322
316
46.3
S-V-3
7/27/98
0938-0943
5.0
0.442
2.21
229
59.4
761
230
6.52
-0.284
291
47.1
Average
15.0
0.295
3.51
235
31.6
773
393
11.1
-0.322
310
95.6
* Dry standard liters per minute at 68°F (20°C) and 1 atm.
b Dry standard liters at 68°F (20°C) and 1 atm.
0 Data taken from concurrent SW-846 Method 0010 train.
d Actual cubic feet per minute at exhaust gas conditions.
c Dry standard cubic feet per minute at 68°F (20°C) and 1 atm.
f Dry standard cubic meters per minute at 68°F (20°C) and 1 atm.
8 Rolling Thin Film Oven Test (ASTM D 2872) from Table 3.4 in Section 3.
h From Table 3.3 in Section 3.
' From Table 2.32 in Section 2.
2-76
-------
TABLE 2.32
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Date
Clock Time, 24-hr clock
Tons of asphalt loaded per test period
Acetone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Acrylonitrile
Concentration, ppbvd "
Emission Rate, Ib/ton b
Allyl chloride
Concentration, ppbvd "
Emission Rate, Ib/ton b
Benzene
Concentration, ppbvd "
Emission Rate, Ib/ton b
Bromodichloromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Bromoform
Concentration, ppbvd *
Emission Rate, Ib/ton b
Bromomethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1,3-Butadiene
Concentration, ppbvd *
Emission Rate, Ib/ton b
2-Butanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
Carbon disulflde
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-V-1
7/24/98
0726-1014
193.5
{1.20E+02}
{1.41E-06}
ND
ND
ND
ND
{1.60E+02}
{2.53E-06}
ND
ND
ND
ND
{1.32E+01}
{2.54E-07}
ND
ND
ND
ND
ND
ND
S-V-2
7/25/98
0910-0920
46.3
{3.44E+02}
{4.98E-06}
ND
ND
ND
ND
{8.93E+01}
{1.74E-06}
ND
ND
ND
ND
2.33E+01
5.51E-07
ND
ND
{1.89E+02}
{3.40E-06}
1.20E+02
2.29E-06
S-V-3
7/27/98
0938-0943
47.1
{5.99E+02}
{2.21E-06}
ND
ND
ND
ND
{2.32E+02}
{1.15E-06}
ND
ND
ND
ND
1.49E+01
8.96E-08
ND
ND
{4.42E-K)2}
{2.02E-06}
8.16E+01
3.94E-07
Average
95.6
{3.54E+02}
{2.87E-06}
ND
ND
ND
ND
{1.60E+02}
{1.81E-06}
ND
ND
ND
ND
{1.71EH-01}
{2.98E-07}
ND
ND
(2.10E+02)
(1.81E-06)
(6.73E+01)
(8.94E-07)
2-77
-------
TABLE 2.32 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
Carbon tetrachloride
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chlorobenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloroform
Concentration, ppbvd *
Emission Rate, Ib/ton b
Chloromethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Cumene
Concentration, ppbvd *
Emission Rate, Ib/ton b
3ibromoch.lorometb.ane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 ,2-Dibromoethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1 -Dichloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
1,2-Dichloroethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
1,1-Dichloroethene
Concentration, ppbvd '
Emission Rate, Ib/ton b
S-V-1
ND
ND
ND
ND
ND
ND
ND
ND
8.80E+01
8.99E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-V-2
ND
ND
ND
ND
4.69E-K)!
7.55E-07
ND
ND
2.23E+02
2.80E-06
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
S-V-3
ND
ND
ND
ND
ND
ND
ND
ND
1.31E+02
4.18E-07
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
(1.56E+01)
(2.52E-07)
ND
ND
1.47E+02
1.37E-06
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-78
-------
TABLE 2.32 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
cis- 1 ,2-Dichloroethene
Concentration, ppbvd *
Emission Rate, Ib/ton b
trans- 1 ,2-Dichloroethene
Concentration, ppbvd "
Emission Rate, Ib/ton b
1 ,2-Dichloropropane
Concentration, ppbvd "
Emission Rate, Ib/ton b
cis-1 ,3-Dichloropropene
Concentration, ppbvd *
Emission Rate, Ib/ton b
trans-1 ,3-Dichloropropene
Concentration, ppbvd " .
Emission Rate, Ib/ton b
1 ,2-Epoxybutane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Ethyl acrylate
Concentration, ppbvd "
Emission Rate, Ib/ton b
Ethylbenzene
Concentration, ppbvd *
Emission Rate, Ib/ton b
n-Hexane
Concentration, ppbvd "
Emission Rate, Ib/ton b
2-Hexanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
lodomethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-V-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.50E+02}
{3.21E-06}
{6.50E+02}
{1.13E-05}
ND
ND
ND
ND
S-V-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{3.54E+01}
{9.37E-07}
{1.61E+02}
{3.46E-06}
ND
ND
ND
ND
S-V-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{2.78E+02}
{1.87E-06}
{6.33E+02}
{3.45E-06}
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.54E+02}
{2.01E-06}
{4.81E+02}
{6.09E-06}
ND
ND
ND
ND
2-79
-------
TABLE 2.32 (Continued)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
lun No.
sooctane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Methyl methacrylate
Concentration, ppbvd *
Emission Rate, Ib/ton b
vlethylene chloride
Concentration, ppbvd "
Emission Rate, Ib/ton b
^Methyl-2-pentanone
Concentration, ppbvd *
Emission Rate, Ib/ton b
MTBE
Concentration, ppbvd a
Emission Rate, Ib/ton b
Styrene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1 ,2,2-Tetrachloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
Tetrachloroethene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Toluene
Concentration, ppbvd *
Emission Rate, Ib/ton b
1,1,1 -Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
1 , 1 ,2-Trichloroethane
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-V-1
(3.07E+00)
(7.09E-08)
ND
ND
(2.91E-01)
(5.01E-09)
ND
ND
no data
no data
(1.19E-01)
(2.50E-09)
ND
ND
ND
ND
{2.99E+02}
{5.57E-06}
ND
ND
ND
ND
S-V-2
{8.52E-02}
{2.43E-09}
ND
ND
{2.29E+00}
{4.85E-08}
ND
ND
no data
no data
1.36E+01
3.54E-07
ND
ND
ND
ND
{8.75E+01}
{2.01E-06}
ND
ND
ND
ND
S-V-3
ND
ND
ND
ND
ND
ND
ND
ND
no data
no data
5.12E+01
3.38E-07
ND
ND
ND
ND
{4.61E+02}
{2.69E-06}
ND
ND
ND
ND
Average
(1.05E+00)
(2.45E-08)
ND
ND
(8.61E-01)
(1.78E-08)
ND
ND
no data
no data
(2.16E+01)
(2.32E-07)
ND
ND
ND
ND
{2.82E+02}
{3.42E-06}
ND
ND
ND
ND
2-80
-------
TABLE 2.32 (Concluded)
VOLATILE ORGANICS - SW-846 METHOD 0030
EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
SILO EXHAUST DUCT
ASPHALT PLANT C - CALIFORNIA
Run No.
Trichloroethene
Concentration, ppbvd a
Emission Rate, Ib/ton b
Trichlorofluoromethane
Concentration, ppbvd "
Emission Rate, Ib/ton b
Vinyl acetate
Concentration, ppbvd *
Emission Rate, Ib/ton b
Vinyl bromide
Concentration, ppbvd *
Emission Rate, Ib/ton b
Vinyl chloride
Concentration, ppbvd *
Emission Rate, Ib/ton b
m-/p-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
o-Xylene
Concentration, ppbvd *
Emission Rate, Ib/ton b
S-V-1
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{8.34E+02}
{1.79E-05}
{2.42E+02}
{5.21E-06}
S-V-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.93E+02}
{5.12E-06}
7.18E+01
1.90E-06
S-V-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1.32E+03}
{8.91E-06}
{3.63E+02}
{2.44E-06}
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{7.84E+02}
{1.06E-05}
{2.26E+02}
{3.18E-06}
* Parts per billion by volume dry.
b Pounds per ton of asphalt loaded in.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{ } Estimate - Concentration exceeds calibration range.
( ) Results in parentheses include NDs which were averaged as zero.
2-81
-------
TABLE 2.33
ON-SITE GC/MS VOLATILE ORGANICS EXHAUST GAS CONCENTRATIONS AND EMISSION RATES
WITH VOST (SW-846 METHOD 0030) COMPARISON
SBLO EXHAUST DUCT
ASPHALT PLANT C, CALIFORNIA
7/25/98
Sample ID
Acquisition Time
Benzene
Concentration, ppbvd*
Carbon Disulfide
Concentration, ppbvd"
Ethyl Benzene
Concentration, ppbvd"
Ffexane
Concentration, ppbvd*
Methyl Ethyl Ketone
Concentration, ppbvd*
Toluene
Concentration, ppbvd*
m/p-Xylene
Concentration, ppbvd"
o-Xylene
Concentration, ppbvd8
SED-
72501
0859
40
100
50
110
1,460
100
250
90
SED-
72502
0920
50
80
290
ND
1,400
170
300
280
SED-
72503
0944
50
50
290
ND
1,690
170
360
280
SED-
72504
1003
30
20
190
ND
1,090
140
360
180
Averages
GC/MS
42.5
62.5
205
110
1,410
145
318
208
VOST
0910-0920
89.3
120
35.4
161
189b
87.5
193
71.8
K>
oo
to
8 Parts per billion by volume dry.
b Methyl Ethyl Ketone is reported as 2-Butanone in the VOST analytical results.
Note: "ND" indicates compound was below the detection limit (Not Detected). NDs were not averaged as zeroes in this table.
-------
TABLE 2.34
PM AND MCEM DEPOSITION ESTIMATES
ASPHALT PLANT C - CALIFORNIA
Sampling Location
TED5
Tunnel Ceiling 6
Silo No. 2 Exhasut Plenum 7
TOTAL TED
New SED 8
Old SED 9' 10
Estimate of Asphalt
Concrete Loaded,1'2
Tons
75,347
20,666
4,133
-
8,142
600,000
PM Deposition
Estimate, 3
Ibs/ton
2.80E-05
6.30E-05
1.52E-05
1.06E-04
7.12E-05
1.27E-06
CE Corrected
PM Deposition
Estimate, 4
Ibs/ton
4.59E-05
6.30E-05
2.49E-05
1.34E-04
-
-
MCEM Deposition
Estimate, 3
Ibs/ton
6.40E-07
6.26E-06
8.34E-07
7.73E-06
1.12E-06
9.28E-08
CE Corrected
MCEM Deposition
Estimate, 4
Ibs/ton
1.05E-06
6.26E-06
1.37E-06
8.68E-06
_
-
to
00
u>
1 Silo specific load-out data was not available; estimates were made for TED, New SED, Old SED, and Silo No. 2 Exhaust Plenum.
2 Data taken from Volume 2, Appendix B.4, page 43.
3 Data taken from Volume 1, Appendix A.4, pages 206,207, and 208.
4 Capture Efficiency (CE) corrections based on the three run average 90% lower confidence level CE of 61%; the Tunnel Ceiling was not corrected for CE.
5 Deposition in the TED upstream of the TED sampling location; test plates were installed on June 28,1998 and cleaned on July 26,1998.
6 Deposition on the Tunnel Ceiling downstream of Silo No. 5; Ceiling plates were installed on July 23,1998 and removed on July 26,1998.
7 Deposition on the inside walls of the exhaust plenum below Silo No. 2; Box pipes were installed on July 23,1998 and removed on July 26,1998.
* Deposition in the New SED upstream of the SED sampling location; New SED was installed on July 19,1998 and cleaned on July 26,1998.
9 Deposition in the Old SED; sample taken from a section of the old SED installed at Plant C start-up and removed on July 19, 1998.
10 Total production since start-up was assumed to be 3,000,000 tons; for Silo No. 2 one fifth of 3,000,000 tons (I.e., 600,000 tons) was used.
-------
TABLE 2.35
METEOROLOGICAL DATA SUMMARY
ASPHALT PLANT C, CALIFORNIA
Date
7/24/98
7/25/98
7/27/98
Time
Periods
0646-0700
0701-0800
0801-0812
0931-1000
1001-1100
1101-1200
1201-1300
Average
0548-0559
0600-0659
0700-0759
-0800-0859
0900-0959
1000-1059
1100-1159
1200-1259
1300-1327
Average
0722-0759
0800-0859
0900-0959
1000-1059
1100-1159
1200-1202
Average
Wind Speed,
MPH
3.02
3.35
3.98
3.71
4.05
6.12
7.63
4.55
3.23
2.91
4.12
4.96
5.53
6.03
6.80
7.74
9.01
5.59
2.74
4.27
6.33
6.13
6.63
8.00
5.68
Ambient
Temperature
Degrees C
17.7
18.0
18.1
22.6
21.3
23.0
25.2
20.8
19.1
19.8
20.1
21.0
23.4
25.8
27.6
29.3
29.5
23.9
22.0
22.7
26.9
29.1
31.9
33.9
27.7
Wind
Direction,
Degrees*
173
184
151
228
224
233
219
202
281
218
262
225
206
219
213
206
204
226
135
213
231
223
219
198
203
Ambient
Relative
Humidity, %
90
60
75
77
61
69
70
70
Degrees clockwise from north (e.g. 180° = wind from the south)
2-84
-------
Runl
North
Run 2
West -X"
East
South
Run 1 - Average wind direction on July 24, 1998 (202°)
Run 2 - Average wind direction on July 25,1998 (226°)
Run 3 - Average wind direction on July 27,1998 (203°)
Run 4 - No Data for July 26,1998
Figure 2.1 Load-out Tunnel and MET Station Location and Average Wind Direction
2-85
-------
3.0 PROCESS DESCRIPTION
Asphalt Plant C is a hot mix asphalt plant located south of Los Angeles, California. A
simplified process flow schematic is shown in Figure 3.1. The plant was built in 1994 and has a
rated production capacity of 650 tons per hour (TPH) of hot mix asphalt. The plant produces five
different categories of asphalt concrete, %-inch, i^-inch, 3/4-inch, fines, and recycled asphalt
pavement (RAP). In RAP, small amounts of recycled asphalt are added to the mix. The plant
also adds small amounts of rubber to some products as a crack inhibitor. The plant uses two
different kinds of liquid asphalt, AR-4000 and AR-8000 (AR-4000 is used approximately
90 percent of the time). The percent weight of liquid asphalt in the mix varies from 4.8% to
6.0% depending on the size of the aggregate in the mix.
Five 200-ton heated storage silos sit on top of a load-out tunnel. The storage silos serve
as a holding station between production and the loading of the asphalt concrete into transport
trucks. A conveyer system carries the fresh asphalt from the secondary chamber of the dryer to
the top of the silos and loads one silo at a time. When a silo becomes full or when production
changes to a different mix, loading is switched to another silo. Asphalt fumes generated in the
silos during load-in are vented through an exhaust system on top of the silos. Each of the five
silos has its own 10 inch ID silo exhaust duct that feeds a 12 inch ID common header that carries
the asphalt fumes to the TED downstream of Silo No. 1 (see Figure 3.1). Two dampers are
positioned in each of the five silo exhaust ducts. During load-in, the dampers above the silo
being loaded are positioned to direct load-in fumes from the silo to the common header. The
dampers above the other four silos are positioned to vent the "idle" silos to atmosphere.
The load-out tunnel is approximately 183 feet long by 16 feet high by 16 feet wide.
Attached to the ceiling of the load-out tunnel, and below each of the five silos, is an exhaust
plenum that draws air and vapors off the transport trucks and out of the tunnel during load-out.
Each of the five exhaust plenums is identical and shaped like a tuning fork with holes in the
bottom and slots in the inside legs. Air and vapors from the asphalt concrete during load-out are
drawn through the holes and slots and into the tunnel exhaust duct by a constant rate induced
draft fan. Only one exhaust plenum is in operation at any one time. Dampers, triggered when
loading begins, control the flow of air and vapors into the exhaust plenums.
During a full load-out schedule, transport trucks enter the tunnel approximately every
three minutes. Single bed transport trucks hold approximately 21 tons of asphalt concrete. Dual
bed transport trucks (i.e., a truck and trailer) hold approximately 25 tons. It typically takes 15
to 30 seconds to load a transport truck. Under normal operation, the temperature of the asphalt
concrete is approximately 3 05 °F as it is dropped from the storage silo into the transport truck.
3-1
-------
Atmosphere
Silo Exhaust
Duct
Sampling
Location
Asphalt
Atmosphere Concrete"
Stack
Baghouse
Natural Gas-
Fired Rotary
Drum Dryer
Secondary
Chamber
A A
s
-
^
-->
•->
Fan
<_ ,.
Silo No. 1
Silo No. 2
Sito No. 3
Silo No. 4
Silo No. 5
Smog
Hog®
—
Entrance
Loadout
Tunnel
Exit
<
•w
>,
•
Tunnel
Exhaust Duct
Sampling Location
Natural Gas
Liquid Asphalt Cement
A
i
RAP
Aggregate
Liquid Asphalt Storage Tanks
Figure 3.1 Process Flow Schematic, Asphalt Plant C, California
3-2
-------
During normal operation, and depending on demand, the plant produces between 2,000
and 6,000 tons of asphalt concrete hi a 12 hour day. The plant typically starts up at 4:00 am and
produces asphalt concrete at a steady rate for 10 to 12 hours. Load-out typically begins at
6:30 am and continues for 8 to 10 hours. In addition, the plant often operates a second shift that
typically starts up at 6:30 pm and runs most of the night. On a daily basis, the average load-out
rate typically matches the average production rate and the storage silos begin and end each day
empty.
3.1 COORDINATION BETWEEN TESTING AND PROCESS OPERATIONS
Testing in the TED was performed to characterize emissions from the load-out tunnel
during the load-out of asphalt concrete from the storage silos into transport trucks. In Table 3.1,
the total load-out tons of asphalt concrete are presented for each TED test run. This load-out data
was used to convert the TED emissions from pounds per test period to pounds per ton of asphalt
loaded. Note that asphalt concrete loaded from Silo No. 1 is not included. The sampling
location in the TED was upstream of the Silo No. 1 exhaust plenum, as shown in Figure 3.1.
Under normal load-out operations, 21 to 25 tons of asphalt concrete are transferred in 15
to 30 seconds from the silo to the truck. Testing to characterize emissions from the load-out
tunnel was performed only when asphalt concrete was loaded from Silos 2, 3,4 or 5. If load-out
operations were suspended on Silos 2, 3,4 and 5 for more than 10 minutes, the TED testing was
stopped.
Testing was also performed to characterize emissions from Silo No. 2 during the loading
of asphalt concrete into Silo No. 2. In Table 3.2, the total load-in tons of asphalt concrete are
presented for each SED test run (load-in refers to the loading of asphalt concrete into Silo No. 2).
This load-in data was used to convert the SED emissions from pounds per test period to pounds
per ton of asphalt loaded. The SED testing was performed only when asphalt concrete was being
loaded in Silo No. 2. Testing was stopped if the loading into Silo No. 2 was stopped.
3.2 PROCESS MONITORING DURING TESTING
For the five days of testing beginning on July 24,1998, PES monitored and recorded
process operations data including plant production records, tunnel load-out data, and Silo No. 2
load-in data. PES also reviewed and recorded daily production records for plant operations from
June 18,1998 through July 23, 1998. In addition, PES measured the temperature of the asphalt
concrete in randomly selected transport trucks as the trucks left the load-out tunnel. This Plant C
process data is summarized below. The complete records appear hi Volume 2, Appendix B.
• Production Records beginning on 7/24/98 and running through 7/28/98 - These records
document plant operations and include material feed rates and temperatures, total mix
rates and product codes, and process equipment parameters. The mix feed rate data were
used to calculate the Silo No. 2 load-in data.
3-3
-------
Silo Storage Records beginning on 7/25/98 and running through 7/28/98 - These records
document the type (i.e., 3/e-inch, '/2-inch, 3/4-inch, fines, or RAP) and amount (tons) of
asphalt concrete stored in each silo during the testing. The tons of asphalt concrete in
silos, recorded every 30 minutes during the testing, changed as new product was loaded
in and stored product was loaded out of the silos. This data serves to document silo
operations. It was not used in any emission calculations.
Load-out Records used in TED Emission Calculations - These records summarize
pertinent information from the Field Load-out Records discussed below. These records
document the load-out tons used in the TED emission calculations. This data is
summarized in Table 3.1.
Load-out Records beginning on 6/18/98 and running through 7/26/98 - These records
document Plant C production beginning the day the TED test plates were installed and
running through the day the TED test plates were removed. This data was used to
estimate PM and MCEM deposition in the TED.
Field Load-out Records beginning on 7/24/98 and running through 7/28/98 - These
records document load-out operations during the testing and include product code,
product description, job name, time of loading, tons loaded, truck number, and silo
number.
Silo No. 2 Load-in Records used in SED Emission Calculations - These records estimate
the load-in tons in Silo No. 2 during the SED testing. The minute-by-minute load-in tons
were estimated based on the mix rate production data recorded during the SED testing
(i.e., mix rates hi tons per hour were converted to mix rates in ton per minute). This
minute- by-minute data is summarized in Table 3.2.
Asphalt Temperatures at Load-out beginning on 7/24/98 and running through 7/28/98 -
These records document the temperature of the asphalt concrete in randomly selected
transport trucks just after load-out. These temperatures were recorded with a dial
thermometer inserted in the asphalt concrete hi the bed of the truck shortly after the truck
left the load-out tunnel. Temperature measurements were taken from nine trucks on
July 24,1998, ten trucks on July 25, 1998, and ten trucks on July 27,1998. This data is
summarized in Table 3.3.
3.3 PROCESS SAMPLES
Asphalt cement samples (i.e., hot liquid asphalt) were collected on July 24,25,27,
and 28,1998. On July 24,25, and 27,1998 three sets of samples were taken. On July 28,1998,
four sets of samples were taken. The first set of samples each day was collected near the
beginning of the test run. The second set of samples and the third set of samples on July 28,
1998, were taken near the middle of the test run. The last set of samples were taken near the end
of the test run. Reclaimed asphalt samples (RAP) were collected on July 25,27, and 28, 1998
(RAP was not used on July 24,1998).
3-4
-------
3.3.1 Asphalt Cement Samples
Thirteen asphalt cement samples were collected following the procedures of California
Transportation Method 125. Each sample was analyzed twice for volatile content at 325 °F,
once following the procedures of ASTM D 1754 - Effects of Heat and Air on Asphalt Materials
(Thin Film Oven Test), and a second time following the procedures of ASTM D 2872 - Effects
of Heat and Air on a Moving Film of Asphalt (Rolling Thin Film Oven Test). The results are
presented in Table 3.4. In addition, the middle sample from each day was analyzed four more
times: 1) using ASTM D 1754 with an oven temperature of 300°F, 2) using ASTM D 1754
with an oven temperature of 350°F, 3) using ASTM D 2872 with an oven temperature of 300°F,
and 4) using ASTM D 2872 with an oven temperature of 350°F. The results of these analyses
appear in Volume 2, Appendix B.8, beginning on page 93.
In addition, four of the asphalt cement samples (one from each day) were analyzed using
the procedures of SW-846 Method 3050A, SW-846 Method 6010B, and SW-846 Method 7471
for antimony, arsenic, beryllium, cadmium, chromium, lead, manganese, nickel, selenium,
cobalt, and mercury. The results are summarized in Table 3.5. Detailed analytical results appear
in Volume 2, Appendix B.10, beginning on page 104.
3.3.2 RAP Samples
Eleven RAP samples were collected during the test program following the procedures of
Section 5.2.1, Sampling from a Conveyor Belt, of ASTM D 979-96, Standard Practice for
Sampling Bituminous Paving Mixtures. Three of the samples, one from each day, were
analyzed as follows (the remaining eight samples were archived). The asphalt cement in the RAP
was separated from the aggregate following the procedures of ASTM D 2172-88, Quantitative
Extraction of Bitumen from Bituminous Paving Mixtures. The asphalt cement was then
recovered from the extract following the procedures of ASTM D 1856-95a, Recovery of Asphalt
from Solution by Abson Method. The recovered asphalt cement and the recovered aggregate
were then analyzed separately using the procedures of SW-846 Method 3050A, SW-846 Method
601 OB, and SW-846 Method 7471 for antimony, arsenic, beryllium, cadmium, chromium, lead,
manganese, nickel, selenium, cobalt, and mercury. The results are summarized in Table 3.5.
Detailed analytical results appear in Volume 2, Appendix B.10, beginning on page 104.
3.4 VELOCITY OF AIR ACROSS TOP OF TRANSPORT TRUCKS DURING
LOAD-OUT
Air velocity measurements were taken above seven transport trucks inside the tunnel
during load-out from Silo No. 2. Measurements were taken using a hot wire anemometer at five
regularly spaced intervals just above the back end of the truck bed. In each case, a second truck
was waiting at the entrance of the tunnel. The results are summarized in Table 3.6; Figure 3.2
shows the measurement locations. Detailed results appear in Volume 2, Appendix B.9,
beginning on page 100.
3-5
-------
TABLE 3.1
LOAD-OUT DATA
USED IN TED EMISSION CALCULATIONS
Test Date
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/25/98 '
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
7/27/98
Run Number
T-V-1-1
T-V-1-2
T-V-1-3
T-M315-1
T-M18-1
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
T-MM5-2
T-M315-2
T-M18-2
T-V-3-1
T-V-3-2
T-V-3-3
T-MM5-3
T-M315-3
T-M18-3
Tons of Asphalt Loaded into Trucks
from
Silo Nos. 2, 3, 4, and 5 During Testing
169.9
262.3
276.9
1,875.0
1,853.8
177.8
182.6
162.9
62.8
1,478.7
1,499.7
1,499.7
258.4
292.2
273.9
2,530.2
2,529.7
2,530.2
3-6
-------
TABLE 3.2
LOAD-IN DATA FOR SILO NO. 2
USED IN SED EMISSION CALCULATIONS
Test Date
7/24/98
7/24/98
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/28/98
7/28/98
7/28/98
Run Number
S-V-1-1
S-V-1-2
S-V-1-4
S-M315-1
S-M18-1
S-V-2-4
S-MM5-2
S-M315-2
S-M18-2
S-V-3-3
S-MM5-3
S-M18-3
S-MM5-4
S-MM5-5
S-M315-4
Tons of Asphalt Loaded into
Silo No. 2 During Testing
79.2
57.7
56.6
336.7
745.4
46.3
602.5
282.7
595.5
47.1
1,079.5
472.4
881.0
709.4
402.4
3-7
-------
TABLE 3.3
ASPHALT TEMPERATURES AT LOAD-OUT
ASPHALT PLANT C - CALIFORNIA
Date
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
Daily Average
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
Daily Average
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
07/27/98
Daily Average
Average
Run No.
1
1
1
1
1
1
1
1
1
2
2
2
2
2
2
2
2
2
3
3
3
3
3
3
3
3
3
Time of Reading
07:25
07:31
07:36
11:12
11:15
11:20
13:16
13:20
13:26
07:33
7;36
07:39
09:32
09:35
09:37
11:48
11:56
12:00
08:04
08:09
08:11
09:41
09:45
09:55
12:45
12:47
12:51
Truck ID
89
99
92
88
89
12
9
13
16
27
T-3
23
21
8
9
16
18
27
T-l
16
CA1138
27
T-l
2305-2
CA20119
O-8
CA21784
Temperature,°F
327
322
316
317
325
319
327
317
322
321
317
332
329
289
312
320
327
317
299
316
276
272
297
277
292
307
292
309
299
291
310
3-8
-------
TABLE 3.4
MASS CHANGE OF ASPHALT
ASPHALT PLANT C, CALIFORNIA
Date
7/24/98
7/24/98
7/24/98
7/25/98
7/25/98
7/25/98
7/27/98
7/27/98
7/27/98
7/28/98
7/28/98
7/28/98
7/28/98
Average
Sample Time
7:21 AM
11:05 AM
12:54 PM
7:16 AM
9:18 AM
11:18AM
7:28 AM
9:29 AM
12:24PM
7:41 AM
9:17 AM
1:51 PM
7:43 PM
Sample ID
AC1B
AC1M
AC1E
AC2B
AC2M
AC2E
AC3B
AC3M
AC3E
AC4B
AC5B
AC6B
AC6E
Thin Film Oven Test1
Percent Change at 325°F
-0.175
-0.178
-0.196
-0.182
-0.173
-0.186
-0.146
-0.166
-0.150
-0.141
-0.157
-0.095
-0.237
-0.169
Rolling Thin Film Oven Test2
Percent Change at 325°F
-0.347
-0.369
-0.370
-0.313
-0.311
-0.341
-0.301
-0.286
-0.264
-0.361
-0.292
-0.322
-0.408
-0.330
u>
1 ASTM D1754-94 - Effects of Heat and Air on Asphalt Materials (Thin Film Oven Test).
2 ASTM D2872-88 - Effects of Heat and Air on a Moving Film of Asphalt (Rolling Thin Film Oven Test).
-------
TABLE 3.5
RESULTS OF METALS ANALYSES OF ASPHALT SAMPLES
ASPHALT PLANT C, CALIFORNIA
Metal
Arsenic, mg/Kg
Beryllium, mg/Kg
Cadmium, mg/Kg
Cobalt, mg/Kg
Chromium, mg/Kg
Manganese, mg/Kg
Nickel, mg/Kg
Lead, mg/Kg
Antimony, mg/Kg
Selenium, mg/Kg
Mercury, mg/Kg
Virgin Asphalt
Cement
ND
ND
ND
(0.490)
ND
(0.216)
17.7
(0.448)
ND
(0.359)
ND
RAP Samples
Recovered
Asphalt Cement
ND
ND
ND
(0.195)
ND
4.28
16.5
2.90
ND
(0.217)
ND
Recovered
Aggregate
4.98
ND
0.654
6.49
13.1
249
8.91
25.1
ND
2.26
(0.0252)
Note: All results shown are the average of multiple sample analyses. ND = Not detected. Values in
parentheses indicate the average includes one or more NDs, which were averaged as a zero.
3-10
-------
TABLE 3.6
AIR VELOCITY OVER TRANSPORT TRUCKS DURING LOAD-OUT
ASPHALT PLANT C, CALIFORNIA
Test Date
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/24/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
07/25/98
Average
Point No.
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
1
2
3
4
5
Time of Reading
1209
1209
1209
1213
1213
1219
1219
1216
1216
1216
1209
1209
1211
1211
1211
1220
1220
1215
1215
1215
Truck No.
29
29
29
16
16
TP
TP
88
88
88
21
21
7
7
7
15
15
8
8
8
Velocity Reading, fpm *
60
52
59
271
220
71
21
140
135
170
104
135
136
123
72
43
41
64
55
71
102
Feet per minute.
3-11
-------
Readings taken just above rear of truck bed
168"
>
116"
\
^
f
i
\
V
64"
f
00 0
kr
Side View
Five reading points 12 inches above rear door
54321
I 4 I I I
12"
96"
Back View
Figure 3.2 Velocity Measurement Locations and Dimensions of Transport Trucks
3-12
-------
4.0 SAMPLING LOCATIONS
Source sampling was performed in the tunnel exhaust duct upstream of Silo No. 1 and in
the exhaust duct off Silo No. 2 as shown in Figure 3.1 of Section 3.0. EPA Method 1,
Section 2.1 states: "Sampling and velocity measurement is performed at a site located at least
eight duct diameters downstream and two diameters upstream from any flow disturbance. If
necessary, an alternative location may be selected, at a position at least two duct diameters
downstream and a half diameter upstream of any flow disturbance". Note that at both locations
the 8 and 2 criteria were not met but the alternative 2 and Yz criteria were met. Also note that at
both locations, the absence of non-parallel flow was confirmed following the procedures of
Section 2.4 of EPA Method 1. Brief descriptions and schematic diagrams of the sampling
locations are presented below.
4.1 TUNNEL EXHAUST DUCT
The tunnel exhaust duct is a horizontal 32-inch inside diameter (ID) duct and serves as a
common manifold for exhausting the five silos from the load-out tunnel. Sampling ports were
installed upstream of the duct breaching from Silo No.l as shown in Figure 4.1. For isokinetic
testing, a 24-point traverse matrix consisting of 12 traverse points on each of 2 perpendicular
traverse lines was used. For non-isokinetic sampling, a single sampling point near the center of
the duct was used. The results of the EPA Method 1 calculations and the locations of the
traverse points are presented in Figure 4.2.
Prior to testing, the TED was checked for the presence of non-parallel flow by recording
yaw angle misalignment at each isokinetic sampling point as specified in Section 2.4 of EPA
Method 1. The average yaw angle was found to be 1 °, which is well below the maximum EPA
requirement of 20°.
4.2 SILO EXHAUST DUCT
Fumes from Silo No. 2 exhaust through a 24-inch ID duct to a 10-inch ID duct and then
to a 12-inch ID common header that transfers the fumes from Silo No. 2 to the Smog Hog®. The
original 10-inch ID duct was removed and replaced with the new 10-inch ID duct shown in
Figure 4.3. Sampling was performed in this new section. For isokinetic testing, a 24-point
traverse matrix consisting of 12 traverse points on each of two perpendicular traverse lines was
used. For non-isokinetic sampling, a single sampling point near the center of the duct was used.
The results of the EPA Method 1A calculations and the locations of the traverse points are
presented in Figure 4.4.
4-1
-------
Section A-A
From Silo No. 1
N>
2.0' ' 2.5' 2.0' ' 1.5' ' 3.5'
From Silo No. 2
nrv
^
S" Method 3 15 VOST
r
MM5 \
\ r' 1 V
TO I ^ v
Cmrx-r ^ ^x_
omog ^ ^>
Hng 1
- a •
^A
-X- -A- -J
Method 18
/ T~V
/ GC/MS
/ / FTIR
T / n /
^
V-P
r
Frc
Nos. 2
X J
] /
v ^~
r
£ ^ f *s
Figure 4.1 Tunnel Exhaust Duct Sampling Locations, Asphalt Plant C, California
-------
Traverse Point
Number
1
2
3
4
5
6
7
8
9
10
11
12
Distance from
Wall, inches
0.7
2.1
3.8
5.7
8.0
11.4
20.6
24.0
26.3
28.2
29.9
31.3
Figure 4.2 Tunnel Exhaust Duct Traverse Point Locations, Asphalt Plant C, California
4-3
-------
To
Smog
Hog®
GC/MS
Port—->d
Damper
SectionB-B
MM5 and
Method 315
Ports
VOST and
Method 18
Ports
Figure 4.3 Silo Exhaust Duct Sampling Locations, Asphalt Plant C,
California
4-4
-------
Traverse Point
Number
1
2
3
4
5
6
7
8
9
10
11
12
Distance from
Wall, inches
0.5
0.7
1.2
1.8
2.5
3.6
6.4
7.5
8.2
8.8
9.3
9.5
Figure 4.4 Silo Exhaust Duct Traverse Point Locations, Asphalt Plant C, California
4-5
-------
Prior to testing, the SED was checked for the presence of non-parallel flow by recording
yaw angle misalignment at each isokinetic sampling point as specified in Section 2.4 of
Method 1. The average yaw angle was found to be <1 °, which is well below the maximum EPA
requirement of 20°.
4-6
-------
5.0 SAMPLING AND ANALYTICAL PROCEDURES
Source sampling was performed in the TED and SED to determine the concentrations and
mass emission rates of PM, MCEM, and organic HAPs. Four tests at the TED and three tests at
the SED were performed over five consecutive days beginning on July 24,1998. The sampling
and analysis methods that were used are summarized in Table 5.1. Brief descriptions of the
sampling and analysis procedures used are presented below. Copies of all the methods which
were used are presented in Volume, Appendix F.
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS
EPA Method 1, "Sample and Velocity Traverses for Stationary Sources," was used to
position velocity and sample traverse point locations at the TED. EPA Method 1 A, "Sample and
Velocity Traverses for Stationary Sources with Small Stacks or Ducts," was used to position
velocity and sample traverse point locations at the SED. Note that a small diameter S-type pitot
tube was used instead of the standard pitot tube specified in Method 1A due to space constraints
at the SED. Also note that this modification was approved by EPA prior to the testing and had
no impact on the results. The process ductwork and the locations of measurement sites and
traverse points were discussed in Section 4.0 of this document.
5.2 DETERMINATION OF EXHAUST GAS VOLUMETRIC FLOW RATE
EPA Method 2, "Determination of Stack Gas Velocity and Volumetric Flow Rate (Type S
Pitot Tube)," was used to determine exhaust gas velocity. A Type S Pitot tube, constructed
according to Method 2 criteria and having an assigned coefficient of 0.84, was connected to an
inclined-vertical manometer. The pitot tube was inserted into the duct and the velocity pressure
(delta p) was recorded at each traverse point. The effluent gas temperature was also recorded at
each traverse point using a Type-K thermocouple. The average exhaust gas velocity was
calculated from the average square roots of the velocity pressures, average exhaust gas
temperature, exhaust gas molecular weight, and absolute stack pressure. The volumetric air flow
rate was calculated as the product of average velocity and the cross-sectional area of the duet at
the sampling location.
5-1
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TABLE 5.1
SUMMARY OF SAMPLING AND ANALYTICAL METHODS
ASPHALT PLANT C, CALIFORNIA
Sampling
Location
TED
SED
Parameter
Air Flow Rate
Moisture
PM/MCEM
VOHAPs
SVOHAPs
Air Flow Rate
Moisture
PM/MCEM
VOHAPs
SVOHAPs
Test Methods
EPA 1 & 2
EPA 4
EPA Method 3 15
SW-846-0030
EPA 18
EPA CTM-028
SW-8460010
EPA1,1A,&2
EPA 4
EPA Method 3 15
SW-846-0030
EPA 18
On-Site GC/MS
SW-8460010
Net Run Times,
Minutes
240
240
240
20-35
240
5-15
240
60-120
60-120
60
5-10
50-120
5-15
120
5-2
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5.3 DETERMINATION OF EXHAUST GAS DRY MOLECULAR WEIGHT
The exhaust gas drawn from the TED and SED during load out was essentially ambient
air with trace levels of PM, MCEM, and organic HAPs. Correspondingly, the exhaust gases
were assigned the dry molecular weight of ambient air (28.84 grams per gram-mol).
5.4 DETERMINATION OF EXHAUST GAS MOISTURE CONTENT
EPA Method 4, "Determination of Moisture Content in Stack Gases," was used to
determine the flue gas moisture content. EPA Method 4 was performed in conjunction with each
EPA Method 315 and SW-846 Method 0010 test run. Integrated, multi-point, isokinetic
sampling was performed. Condensed moisture was determined by recording pre-test and post-
test weights of the impingers, reagents, and silica gel. Condensed moisture in the XAD®-2
sorbent trap from the SW-846 Method 0010 sample train was also determined gravimetrically
and the results included hi the moisture content calculations.
5.5 DETERMINATION OF PM AND MCEM
EPA Method 315, "Determination of Filterable Particulate Matter (PM) and Methylene
Chloride Extractable Matter (MCEM) Emissions from Stationary Sources," was used to collect
PM and MCEM samples in the TED and SED. Multi-point integrated samples were extracted
isolanetically from each of the 24 traverse points at both locations. Each point was sampled for
10 minutes at the TED, for a net run time of 240 minutes. Each point was sampled for
2.5 minutes at the SED, for net run times of 60 minutes.
The Method 315 samples were extracted from the sampling locations through a glass
nozzle, a heated glass-lined probe, a heated glass fiber filter, and a series of chilled impingers.
The first and second impinger each contained 100 milliliters (mL) of deionized (DI) water. The
third impinger remained empty. The fourth and final impinger contained 200 grams of silica gel.
A schematic of the EPA Method 315 sampling train is shown in Figure 5.1.
The samples were analyzed according to EPA Method 315. Each component of the front
half of the sample train was dried and weighed to give particulate matter results. All components
were then extracted with methylene chloride to give MCEM results.
5.6 DETERMINATION OF VOHAPS
Two test methods were used to quantify VOHAPs. SW-846 Method 0030 in
combination with SW-846 Method 8260B (referred to as VOST) was used to quantify a majority
of the targeted compounds. EPA Method 18 was used in a backup capacity to quantify benzene,
cumene, ethylbenzene, hexane, toluene, o-xylene, m-xylene, and p-xylene. In addition, a third
5-3
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Ttmptratur*
Prab*
TyptS
Pilot Tub.
Gooseneck
Nozzle
Temperature
Sftns°r /Waif
Temperature
Sensor
Temperature
Sensor
Type SP'rtot Tube
Heat Traced
Glass-lined
Probe
Temperature Dl Water Empty Silica
Sensors — Gel
Inclined
Manometer
Vacuum
Line
Figure 5.1 EPA Method 315 Sampling Train Schematic
-------
method using a direct interface GC/MS procedure was used as an on-site screening tool and QC
check for selected VOHAPs. .
5.6.1 SW-846 Method 0030 (VOST)
SW-846 Method 0030 (VOST) was used to collect VOHAPs at the SED and TED.
A single-point integrated sample was extracted at a constant rate at a point near the center of the
duct. The sample was drawn through a heated glass-lined probe, a condenser, a Tenax® tube, a
condensate trap and a Tenax® /charcoal tube. A schematic of the VOST sampling train is shown
in Figure 5.2. Four pairs of tubes were collected during each run, except during the third run at
the TED, in which three pairs of tubes were collected and during the third run at the SED, in
which six pairs of tubes were collected. Sample times varied from 5 to 35 minutes and sample
volume from 1.7 to 23.5 liters. Sampling was performed over the 240-minute test period at the
TED.
Analysis was performed by thermal desorption purge-and-trap (SW-846 Method 5040)
and high resolution gas chromatography/low resolution mass spectrometry (SW-846 Method
8260B). For test sets S-V-1-1, S-V-1-4, S-V-2-4, S-V-3-3, T-V-4-1, T-V-4-2, and T-V-4-4, each
tube was analyzed separately. For all other samples, each pair of tubes, the front Tenax® tube
and the back Tenax®/charcoal tube, were thermally desorbed and analyzed together as one
sample. Refer to Section 2.0 for a discussion of the problems encountered during the analyses.
5.6.2 EPA Method 18
EPA Method 18, "Measurement of Gaseous Organic Compound Emissions by Gas
Chromatography" (Adsorption Tube Procedure), was used to collect and analyze for selected
VOHAPs at the TED and SED. The target VOHAPs were benzene, cumene, ethylbenzene,
hexane, toluene, o-xylene, m-xylene, and p-xylene. At both locations, two sampling trains were
run in parallel. Each train consisted of a Teflon® probe and sample line, two adsorbent tubes in
series, a rotameter, a critical orifice, a vacuum gauge, and a pump. The adsorbent tubes were
1000 mg SKC Anasorb® 747 activated-polymer tubes. Pre-spiked adsorbent tubes (spiked in the
field just prior to sampling) were used in one train and non-spiked adsorbent tubes were used in
the second train. A single-point, integrated sample was drawn through each train at a constant
rate of approximately one liter per minute. Each test at the TED was 240 minutes in duration.
Each test at the SED was 120 minutes in duration, except for run S-M18-3 which was 50 minutes
in duration. Analysis was performed using gas chromatography techniques coupled with a flame
ionization detector (GC/FID). Due to the problems discussed in Section 2.2.5, additional
analysis of the SED samples was performed using GC/MS.
5.6.3 EPA CTM - 028
A portable, direct interface GC/MS was used as an on-site screening tool for the
measurement of selected VOHAPs. As a screening tool, the GC/MS was moved around the
facility at the discretion of the PES Project Manager and EPA Work Assignment Manager. It
was used to measure concentrations of specific VOHAPs in and around the load-out tunnel
5-5
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ON
Glass
Wool
Plug
I
t
Exhaust
Gas
Heated Glass
Lined Probe
Charcoal
Trap
Silica
Gel
Condensate
Trap
Tenax® /
Charcoal
Vacuum Gauge
Rotameter
Pump
Condenser
Pump in Ice
Water Bath
Temperature
Sensors
TT
Dry Gas
Meter
Exhaust
Figure 5.2 SW-846 Method 0030 Sampling Train Schematic
-------
before, during, and after selected load-outs. It was also used to periodically measure
concentrations of specific VOHAPs in the SED and TED. The sampling and analytical
procedures are described in detail in the EMI Report in Volume 3, Appendix C.4, beginning on
page 118.
5.7 DETERMINATION OF SVOHAPS
SW-846 Method 0010, "Modified Method 5 Sampling Train (MM5)," was used to collect
SVOHAPs at both locations. A multi-point integrated sample was extracted isokinetically from
the 24 traverse points in the TED and the SED. At the TED, each traverse point was sampled for
10 minutes for a net run time of 240 minutes. At the SED, each traverse point was sampled for
5 minutes for a net run time of 120 minutes. Readings were taken every 5 minutes at both test
locations during each run. The SW-846 Method 0010 samples were drawn through a glass
nozzle, a heated glass-lined probe, a pre-cleaned and heated glass fiber filter, a water-cooled
condenser coil, and a sorbent trap containing approximately 40 g of XAD®-2 sorbent resin. A
schematic of the SW-846 Method 0010 sampling train is shown in Figure 5.3.
The MM5 samples were extracted following the procedure of SW-846 Method 3542,
dated January 1995. The sample extracts were analyzed two ways: 1) in accordance with the
guidelines of SW-846 Method 8270C by high resolution gas chromatograph/low resolution mass
spectrometer (HCGC/LRMS) for SVOHAPs, and 2) in accordance with the guidelines of CARE
Method 429 by high resolution gas chromatograph/high resolution mass spectrometer
(HRGC/HRMS) for PAHs. The three sample fractions for each test run, i.e., front half extract,
the back half extract (XAD®-2 and back half rinse), and the condensate extract, were combined
for analysis.
5.8 DETERMINATION OF WIND SPEED, WIND DIRECTION, AMBIENT
TEMPERATURE, AND AMBIENT HUMIDITY
A meteorological (MET) monitoring station was positioned on top of the tunnel at the
entrance end of the tunnel, and was used to monitor wind speed, wind direction, and ambient
temperature. The station was operated according to the manufacturer's specifications. Readings
were recorded using a data acquisition system. In addition, ambient humidity was measured using
a sling psychrometer once per test run.
5.9 ESTIMATE OF PM AND MCEM ON THE CEILING OF THE LOAD-OUT
TUNNEL DOWNSTREAM OF SILO NO. 5
The ceiling downstream of Silo No. 5 was divided into three equal sections. One test
plate was installed in the center of each section at the beginning of the test program. The plates
were positioned against the ceiling. Prior to installation, the test plates were cleaned with
acetone. At the end of the test program, the test plates were removed and cleaned again with
5-7
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oo
Button Hook
Nozzle
Gas
Flow
TypeS
Pilot Tube
Gas
Exit
Stack
Wall
Temperature
Sensor
(ft Filter Holder
Condenser
Heated Glass
Liner
Temperature
Sensor
Temperature
Sensor
Inclined ^circulation
Manometer RumP
Temperature
Sensors
Empty 100 ml HPLC Water Empty Silica Gel
Orifice
I—t
Vacuum
Line
Inclined
Manometer
Vacuum
Pump
Figure 5.3 SW-846 Method 0010 Sampling Train Schematic
-------
acetone. This procedure resulted hi three acetone rinse samples. The total PM and MCEM in the
rinses were determined gravimetrically following the procedures of EPA Method 315.
PM and MCEM deposition on each ceiling section was estimated by multiplying the
sample catches from the Method 315 analysis by the ratio of the ceiling section surface area to
the test plate surface area. Total deposition on the ceiling downstream of Silo No. 5 was
calculated as the sum of the deposition on each of the three sections. A log was kept of all load-
out operations from the time the test plates were installed until the test plates were removed.
This data, along with the deposition data described above were used to calculate deposition per
ton of load-out asphalt.
5.10 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE WALLS OF
THE SILO NO. 2 EXHAUST PLENUM
Above each of the five silos is a tuning fork-shaped exhaust plenum. Asphalt fumes from
load-out operations exit the load-out runnel through the exhaust plenums and into the TED. The
five exhaust plenums are identical. On each plenum there are six 8-inch round holes hi the
bottom face and four 4x12-inch rectangular holes on the sides. Asphalt fumes from load-out
operations enter the exhaust plenums through these holes.
At the beginning of the test program, six pieces of box pipe (i.e., square cross section
steel tubing), each measuring 3x3x6 inches long were placed inside the exhaust plenum under
Silo No. 2. One box pipe was placed just downstream of each of the six 8-inch round holes in
the bottom face of the plenum. Prior to installation, the box pipes and the installation sections of
the exhaust plenum were cleaned with acetone. At the end of the test program, the box pipes
were removed and cleaned again with acetone. This procedure resulted in six acetone rinse
samples. The PM and MCEM in the rinses were determined gravimetrically following the
procedures of EPA Method 315. Deposition on the inside walls of the Silo No. 2 exhaust plenum
was estimated by multiplying the sample catches from the EPA Method 315 analyses by the ratio
of the exhaust plenum surface and to the box pipes surface area. An estimate was made of all
load-out operations from Silo No. 2 while the box pipes were in place. This data, along with the
deposition data described above, was used to calculate deposition per ton of load-out asphalt.
5.11 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE WALLS OF
THE SILO EXHAUST DUCT
Two SED deposition samples were collected and analyzed (one called the new SED and
one called the old SED). Just prior to the testing, a section of the old SED (i.e., the original silo
exhaust duct above Silo No. 2 installed when the plant was built), was removed and a new
section installed. In the new SED, sampling ports were installed as shown hi Figure 4.3. Prior to
installation, the inside walls of the new SED were cleaned with acetone. After the testing, a large
section of the inside walls of the new SED was cleaned again with acetone. This procedure
resulted in one acetone rinse sample. The total PM and MCEM hi the rinse were determined
5-9
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gravimetrically following the procedures of EPA Method 315. Deposition on the inside walls of
the new SED was estimated by multiplying the sample catches from the Method 315 analyses by
the ratio of the total surface area of the SED upstream of the sampling ports to the surface area of
the cleaned section. An estimate was made of all load-in operations into Silo No. 2 between
cleanings. These data, along with the deposition data described above, were used to calculate
deposition per ton of load-in asphalt in the new SED.
For the old SED sample, a portion of the old SED was cleaned with acetone and analyzed
as. described above. An estimate was made of all load-in operations into Silo No. 2 from start-up
until the old SED was removed. This estimate, along with the sample catches from the Method
315 analysis, were used to calculate deposition per ton of load-in asphalt in the old SED.
5.12 ESTIMATE OF PM AND MCEM DEPOSITION ON THE INSIDE WALLS OF
THE TUNNEL EXHAUST DUCT
The tunnel exhaust duct is a 32-inch diameter common manifold duct that leads from the
load-out tunnel to the Smog Hog®, as shown in Figure 3.1. Before the test program, the middle
section of the tunnel exhaust duct adjacent to Silo No. 3 was removed, cleaned, and test plates
(T,, T2 and T3) installed at the three locations shown in Figure 5.4. The original plan called for
T3 to serve as an impaction plate and Tl5 and T2 to serve as non-impaction plates. During the
testing however, Silo No. 3 saw limited use, minimizing the impaction deposition on T3.
Therefore, for the deposition calculations discussed below, the three test plates were essentially
treated as one large non-impaction plate. Prior to installation, the test plates were cleaned with
acetone. After the test program, the test plates were removed and cleaned again with acetone.
This procedure resulted in three acetone rinse samples. The total PM and MCEM in the rinses
was determined gravimetrically following the procedures of EPA Method 315. PM and MCEM
deposition in the TED upstream of the sampling location were estimated by multiplying the
sample catches by the ratio of the TED surface area upstream of the TED sampling location to
the test places surface area. An estimate was made of the total load-out tons from Silos 2, 3,4
and 5 from the time the test plates were installed until the test plates were removed. This data,
along with the sample catches were used to calculate the total deposition per ton of load-out
asphalt. Start-up procedures include a brief period when dry aggregate, absent of liquid asphalt,
is run through the entire plant and loaded in a silo. This is done to insure that the aggregate is up
to temperature before liquid asphalt is added to the mix. At the end of this brief start-up period
the dry aggregate in the silo is loaded in a truck and returned to the aggregate stockpile. At start-
up this dry aggregate generates a lot of ambient dust that is drawn off the tunnel through the
TED.
5-10
-------
32"
l\
TEDMM5
Sampling
Location
I ~ " i
P
Section
A-A
Exhaust
Plenum
for Silo
No. 2
Exhaust
Plenum
for Silo
No. 3
Exhaust
Plenum
for Silo
No. 4
Exhaust
Plenum
for Silo
No. 5
T
56"
645.5 "
Figure 5.4 Location of TED Deposition Test Plates T,,T2, and T3
-------
-------
6.0 QUALITY ASSURANCE/QUALITY CONTROL (QA/QC)
PROCEDURES AND RESULTS
For any environmental measurement, a degree of uncertainty exists in the data generated
due to the inherent limitations of the measurement system employed. The goals of a QA/QC
program are to ensure, to the highest degree possible, the accuracy of the data collected. This
section summarizes the QA/QC procedures that were employed by PES in the performance of
this test program. The procedures contained in the reference test methods and in the Quality
Assurance Handbook for Air Pollution Measurement Systems, Volume III, Stationary Source
Specific Methods, EPA/600/R-94/038c, served as the basis for performance for all testing and
related work activities in this project.
6.1 CALIBRATION AND PREPARATION OF APPARATUS
Brief descriptions of the calibration procedures used by PES are presented below.
Detailed results of equipment and sensor calibrations may be found in Volume 3, Appendix D,
beginning on page 230.
6.1.1 Barometers
PES used aneroid barometers which were calibrated against a station pressure reported by
a nearby National Weather Service Station and corrected for elevation.
6.1.2 Temperature Sensors
Bimetallic dial thermometers and Type K thermocouples were calibrated using the
procedure described in EPA/600/R-94/038c. Each temperature sensor was checked over the
expected range of use against an ASTM 3C or 3F thermometer. Digital thermocouple displays
were calibrated using a thermocouple simulator having a range of 0-2400°F. Table 6.1
summarizes the type of calibration checks performed, the acceptable levels of variance, and the
results. All the dial thermometers and thermocouples used met the variance (i.e., tolerance)
levels in the method.
6.1.3 Pitot Tubes
PES used Type S pitot tubes that were constructed and calibrated according to geometric
specifications of EPA Method 2 and were assigned a pitot coefficient (Cp) of 0.84. The
dimensional criteria results for each pitot tube used are presented in Table 6.2.
6-1
-------
6.1.4 Differential Pressure Gauges
PES used Dwyer inclined/vertical manometers to measure differential pressures. The
differential pressure measurements included velocity pressure, static pressure, and meter orifice
pressure. Manometers were selected with sufficient sensitivity to accurately measure pressures
over the entire range of observed values. Manometers are primary standards and require no
calibration.
6.1.5 Dry Gas Meters and Orifices
The EPA Method 315 and SW-846 Method 0010 dry gas meters were calibrated in
accordance with Sections 5.3.1 and 5.3.2 of EPA Method 5. This procedure involves direct
comparison of the metered volume passed through the dry gas meter to a reference dry test meter.
The reference dry test meter is calibrated annually using a wet test meter. Before its initial use in
the field, and annually thereafter, each metering system used was calibrated over the entire range
of operation as specified in EPA Method 5. After field use, a calibration check of each metering
system was performed at a single intermediate setting based on the field test. The post-test
calibration check of the dry gas meter correction factor must agree within 5% of the correction
factor generated during the initial or annual calibration. The results for the dry gas meters,
summarized in Table 6.3, show the dry gas meters used met the method criteria.
6.2 REAGENTS AND GLASSWARE PREPARATION
6.2.1 EPA Method 315
Sample reagents consisted of pesticide (or better) grade acetone and methylene chloride
for glassware preparation and sample recoveries. Water used in sample recoveries and the
impinger trains was HPLC-grade reagent water. Reagent blanks were collected and analyzed.
Refer to Section 6.5.1 for the results of the laboratory analysis of the EPA Method 315 reagent
blanks.
6.2.2 SW-846 Method 0010
All sample train glassware and sample recovery apparatus were preconditioned following
the procedures of SW-846 Method 0010. The procedures required that all sampling train
components and sample recovery apparatus be soaked in hot soapy water (Alconox®), followed
by three rinses each with tap water, distilled/deionized water, pesticide grade methanol, and
methylene chloride. All glassware was then capped with aluminum foil. Quartz-fiber filters
were used which were free of organic binders.
The XAD®-2 sorbent traps were prepared by QI. After cleaning, the traps were pre-
spiked with surrogates, and capped with glass balls and sockets. The impinger water used was
organic-free, reagent grade. Distilled-in-glass pesticide (or better) grade methylene chloride and
methyl alcohol were used in equal portions (50/50 mix) as the recovery solvent.
6-2
-------
6.2.3 SW-846 Method 0030
Prior to testing, all glassware was cleaned with non-ionic detergent in an ultrasonic bath,
rinsed well with organic-free water, and dried at 110°C. Tenax® was provided by TLI. New
Tenax® was Soxhlet extracted for 24 hours with methanol. The Tenax® was then dried for
6 hours in a vacuum oven at 50°C before use.
6.3 ON-SITE SAMPLING
The on-site QA/QC activities are described below.
6.3.1 Measurement Sites
Prior to sampling, both ducts were checked dimensionally to determine measurement site
locations, location of velocity and sample test ports, inside duct dimensions, and sample traverse
point locations. Inside duct dimensions were checked through each traverse line to ensure
uniformity of the duct inside diameter.
6.3.2 Velocity Measurements
All velocity measurement apparatus were assembled, leveled, zeroed, and leak-checked
prior to use and at the end of each test run. The static pressure was determined at a single point
near the center of the duct cross-section.
6.3.3 Moisture
The EPA Method 315 and SW-846 Method 0010 trains were used to determine stack gas
moisture. During sampling, the exit gas of the last impinger was maintained below 68°F to
ensure adequate condensation of the exhaust gas water vapor. The total condensed moisture
collected was determined on-site gravimetrically using an electronic platform balance with
0.1 gram sensitivity.
6.3.4 EPA Method 315 and SW-846 Method 0010
The field sampling QA/QC for EPA Method 315 and SW-846 Method 0010 began in the
sample recovery area. The sample trains were set up and leak-checked to verify sample train
integrity before transport to the sampling sites. At the sites, the trains were leak checked a
second time. Leak checks were also conducted before and after any sample train component
changes and upon completion of the test runs. Table 6.4 summarizes the EPA Method 315 and
SW-846 Method 0010 field sampling QA/QC measurements and EPA's acceptability criteria.
All the test runs used in the presentation of results met the QA/QC criteria of the methods, with
the exception of Run S-M315-2. The isokinetic percentage for Run S-M315-2 was 110.6%
which is 0.6% greater than the EPA criteria of 110%.
6-3
-------
In addition to the samples, field blank samples were collected. EPA Method 315 and
SW-846 Method 0010 sampling trains were assembled, transported to each sampling location,
and leak-checked. The sample trains were then recovered using the same procedures employed
during the recovery of the sample trains used during actual sample runs. The collected fractions
were transferred to labeled, pre-cleaned sample bottles, transported to the subcontract laboratory,
and analyzed in the same manner as the collected samples. Refer to Sections 6.5.1 and 6.5.2 for
the results of the laboratory analyses of the EPA Method 315 and SW-846 Method 0010,
respectively, field blanks.
6.3.5 SW-846 Method 0030
The field sampling QA/QC for the SW-846 Method 0030 testing began before the start of
the test run. Each sampling train was leak checked prior to testing by pulling a vacuum of least
10 inches of mercury. After a post-test leak check, the cartridges were sealed in a suitable
environment for storage and transport until analysis. A field blank was collected at each sample
location. Refer to the Section 6.4.3 for the results of the laboratory analyses of the SW-846
Method 0030 field blanks.
6.3.6 EPA Method 18
The field sampling QA/QC for the EPA Method 18 testing began before the start of the
test run. The sampling trains were assembled as discussed in Section 5.6.2. The adsorbent tubes
remained sealed until just before being connected to the sampling trains. The sampling trains
were calibrated using an electronic bubble meter prior to the start of each test run. Once the
sampling began, the sample rate taken from the in-line rotameter was recorded every 10 minutes.
At the completion of each test run, the sample trains were calibrated a second time using the
electronic bubble meter. A set of field blanks was collected on the second day of testing. The
sampling trains were assembled as described above. Two electronic bubble meter calibrations
were performed on each train. Following the second calibration, the field blank tubes were
capped and stored in a cooler for transport to the laboratory.
6.3.7 Particulate Deposition
The test plates were cleaned with acetone immediately prior to installation. After the test
program was completed, the plates were removed and cleaned hi the sample recovery area. The
sample recovery area was kept clean of all dust. An acetone blank and one field blank per
location were collected, analyzed, and compared to the test results. In general, field blank results
were low relative to the sample results.
6.4 SAMPLE RECOVERY
Sample recovery was performed hi an on-site laboratory under the supervision of the PES
Project Manager.
6-4
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6.4.1 EPA Method 315
Sample recovery was performed following the procedures of EPA Method 315. Reagent
blanks of the water, acetone, and methylene chloride, along with unused filters, were taken. The
reagent water was weighed and the liquid level marked. The back half of the train was rinsed
with water and the rinse added to the reagent water and the liquid level marked again. The jar
was sealed with Teflon® tape. The back half of the tram was rinsed with acetone and methylene
chloride and the rinses recovered in a separate jar. The liquid levels were marked and the lids
sealed with Teflon® tape. The front half of the train was also rinsed with acetone and methylene
chloride into a separate jar. The liquid level was marked and the jar sealed with Teflon® tape.
The liquid levels were checked at the analytical laboratory to assure sample integrity.
6.4.2 SW-846 Method 0010
Recovery of the MM5 sample train was performed following the procedures of SW-846
Method 0010. In addition to the field blank, blanks were taken of reagent grade water, methanol,
methylene chloride, unused filters, and the XAD®-2 resin. The sample recovery apparatus was
made of Teflon® or glass and pre-cleaned as described in Section 6.2.2. The sample train
cleanup was accomplished by rinsing each sample tram component three times with a 50/50
mixture of methanol and methylene chloride. All sample containers were tared and then re-
weighed following sample recovery. The samples were weighed a third time at the analytical
laboratory to ensure sample integrity. The field blanks were handled folio whig the same
procedure.
6.4.3 SW-846 Method 0030
Recovery of the SW-846 Method 0030 samples was performed following the procedures
of SW-846 Method 0030. At the end of the test run, the sample tubes were removed, capped,
and stored hi a cooler. The field blanks were treated hi the same manner.
6.4.4 EPA Method 18
At the end of each test, the EPA Method 18 adsorbent tubes were removed, capped, and
stored in a cooler for transport to the laboratory. The field blank was treated in the same way.
6.5 LABORATORY ANALYTICAL QA/QC PROCEDURES
6.5.1 EPA Method 315
The Method 315 field and laboratory blanks were analyzed folio whig the procedures of
EPA Method 315 to evaluate the effectiveness of the sample train clean-up procedures and to
check for contamination of the reagent materials. The results of these blank analyses are
presented hi Table 6.5. The TED field blank indicates a small amount of contamination, some of
which may be residue left over from T-M315-2.
6-5
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6.5.2 SW-846 Method 0010
QI analyzed the SW-846 Method 0010 samples from the TED and the SED for PAHs
following the procedures of CARB Method 429. Field blanks, method blanks, and laboratory
blanks were used to check for contamination at both locations. The blanks were processed in the
same way the field samples were processed. The TED blank results are presented in Table 6.6.
The SED blank results are presented in Table 6.7. For comparison purposes, the average catch
weights for the target PAH compounds in the field samples are also presented. Note that the
background condition run (T-MM5-4) catch weights were not averaged with the normal
operation runs (T-MM5-2 and T-MM5-2) in Table 6.6. The TED field blank results are
essentially the same as the method blank and reagent blank and do not indicate any
contamination. The SED field blank results show some contamination, but the contamination is
very low (and insignificant) compared to the average field sample catch weight at the SED.
CARB Method 429 outlines a procedure for determining whether contributions from a
field blank are significant enough to require modification of the run samples' test results. For all
PAHs results from the SED, and all compounds but naphthalene at the TED, the blank values
were low enough when compared to the target compounds that changes in the test results were
unnecessary. The naphthalene on the background condition (run T-MM5-4) fell below the report
limit when Equation 429-32 of CARB Method 429 was applied. A table showing the ratios of
the TED run samples to the field blank is included with the PAHs test results in Volume 1,
Appendix A.I, on page 22a.
The XAD®-2 resins were spiked with PAHs and SVOHAPs surrogate standards before
going in the field (referred to here as pre-spiked surrogates). The percent recoveries for the pre-
spiked PAHs surrogate in the TED samples are presented in Tables 6.8. Six of the 102 PAHs
surrogate recoveries were below the 50% QC limit. The QI case narrative (in Volume 4,
Appendix G, beginning on page 6) states that the low recoveries did not affect data quality
because the signal-to-noise ratio was greater than 10:1. Four of the 102 PAHs surrogate
recoveries were above the 150% QC limit. The QI case narrative states that for the high
recoveries quantitation by isotope dilution generally precludes any adverse effect on data
qualities. The percent recoveries for the pre-spiked SVOHAPs surrogate in the TED samples are
presented in Tables 6.9. The QC limits were met for 34 of the 36 analyses. The 2,4,6-
Tribromophenol surrogate recoveries for samples T-MM5-2 and T-MM5-3 are slightly below the
lower limit. For these two samples QI confirmed the reported results by re-injecting the sample
extracts.
Due to the dilution effects discussed in Section 2.0, the PAHs and SVOHAPs pre-spiked
surrogates in the SED samples were not detected and QI re-spiked the surrogates after sample
extraction. The percent recoveries for the re-spiked PAHs surrogates are presented in Table 6.10.
Nine of the 139 PAHs surrogate recoveries were below the 50% QC limit. The QI case narrative,
as mentioned above, states that the low recoveries did not affect data quality because the signal-
to-noise ratio was greater than 10:1. One of the 139 PAHs surrogate recoveries was above the
150% QC limit. The QI case narrative, as mentioned above, states that for the high recoveries
quantitation by isotope dilution generally precludes any adverse effect on data qualities. The
6-6
-------
percent recoveries for the re-spiked SVOHAPs surrogate in the SED samples are presented in
Table 6.11. The QC limits were met in 19 of the 38 analyses; the surrogates were not detected in
other 19 analyses.
6.5.3 SW-846 Method 0030
The SW-846 Method 0030 samples were analyzed following the procedures of SW-846
Method 8260. Field and laboratory blanks were used to check for contamination. They were
processed hi the same way the field samples were processed. Tables 6.12 and 6.13 summarize
the results for the SW-846 Method 0030 field and laboratory blanks for the TED and SED,
respectively. Due to the analytical problems discussed hi Section 2.0, the SED field blank was
not analyzed. For comparison purposes, both tables show the average run sample catch weights
for the detected target compounds in the blanks. The sample catches for the background
condition are not included in the average TED run sample catch weights.
The Tenax® and Tenax®/charcoal media were spiked with surrogate standards after the
field sampling and prior to sample analysis. The percent recoveries for the surrogates are
summarized in Tables 6.14 and 6.15 for the TED and SED, respectively. Three TED and 7 SED
samples had recoveries greater than the 150% limit. Four of the seven SED recoveries ranged
from 414 to 788% and were all for the same surrogate, 4-bromofluoro-benzene. As a result, the
concentrations presented for some of the VOST VOHAPs, and hi particular
4-bromofluoro-benzene, may be biased high.
6.6 QA COORDINATOR FIELD AUDIT
To meet the goals of the Quality Control Program as described hi the QAPP, PES
supplied an on-site QA Coordinator to observe the emission testing and to audit the personnel,
equipment, procedures, and record keeping. The QA Coordinator assured that all sampling tram
glassware and sample recovery apparatus were preconditioned following the procedures of each
test method used. Prior to testing, the QA Coordinator oversaw pre-test calibration and the
checking of the equipment. These procedures included checks on the dry gas meters, pitot tubes,
thermocouples, and sampling nozzles.
During the testing, audits and observations were conducted at regular intervals giving
ample opportunity for on-site corrections. The QA Coordinator oversaw the checks and audits of
sampling, data acquisition, sample recovery, and chain of custody. The QA Coordinator also
recorded his observations on standardized forms, copies of which appear hi Volume 3,
Appendix D, beginning on page 231.
6-7
-------
TABLE 6.1
SUMMARY OF TEMPERATURE SENSOR CALIBRATION DATA
Temp.
Sensor
I.D.
TC-25
RT-6
RT-10
RT-11
RMB-15
Usage
Stack Gas
Stack Gas
Stack Gas
Stack Gas
Meter Box
Inlet
Meter Box
Outlet
Temperature, °F
Reference
36
75
212
32
72
210
32
73
208
32
73
206
33
74
208
33
74
208
Sensor
36
75
214
32
69
210
32
68
210
36
73
206
35
74
210
33
75
208
Temperature
Difference"
0.00%
0.00%
0.27%
0.00%
- 0.56%
0.00%
0.00%
- 0.94%
0.30%
0.81%
0.00%
0.00%
0.41%
0.00%
0.30%
0.00%
0.19%
0.00%
Tolerance
^L5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
<±1.5%
iii
-------
TABLE 6.2
SUMMARY OF PITOT TUBE DIMENSIONAL DATA
Measurement
a,
CC2
Pi
P2
Y
6
A
Z
w
D,
(A/2)/D,
Criteria
<10°
<10°
<5°
<5°
-
-
-
< 0.125 in.
< 0.03 125 in.
0.1875in. i Dt^ 0.375 in.
01.05D,* A/2s 1.50D,
Acceptable
Assigned Coefficient
Results
Pitot Tube Identification
RP-11
0
0
0
1
0
1
1.022
0.000
0.018
0.375
1.36
Yes
0.84
RP-19
0
1
0
1
0
0
0.938
0.000
0.000
0.375
1.25
Yes
0.8*
D-7
<1
<1
<1
<1
<1
<1
0.885
0.015
0.015
0.315
1.40
Yes
0.84
6-9
-------
TABLE 6.3
SUMMARY OF DRY GAS METER AND ORIFICE CALIBRATION DATA
Meter
No.
3A
6A
RMB15
Dry Gas Meter Correction Factor, y
Pre-test
1.007
1.001
1.000
Post-test
0.999
1.018
0.999
% Diff.
-0.80
1.68
-0.10
EPA Criteria
±5%
±5%
±5%
6-10
-------
TABLE 6.4
SUMMARY OF EPA METHOD 315 AND SW-846 METHOD 0010 FIELD SAMPLING QA/QC DATA
Date
07/24/98
07/24/98
07/25/98
07/25/98
07/26/98
07/27/98
07/28/98
Site
TED
SED
TED
SED
TED
TED
SED
'•
Run
Number
T-MM5-1*
T-M315-1
S-MM5-1*
S-M315-1
T-MM5-2
T-M315-2
S-MM5-2
S-M315-2
T-MM5-4
T-M315-4
T-MM5-3
T-M315-3
S-MM5-4
S-MM5-5
S-M315-4
Pre-Test
Leak Rate
acfm
0.005 @ 15" Hg
0.012 @ 15" Hg
0.004 @ 12" Hg
0.013 @ 15" Hg
0.000 @1 5" Hg
0.010 @ 15" Hg
0.008 @1 5" Hg
0.002 @ 15" Hg
0.000 @1 5" Hg
0.005 @ 15" Hg
0.000 @ 15" Hg
0.003 @ 15" Hg
0.007 @ 16" Hg
0.009 @ 17" Hg
0.002 @ 15" Hg
Post-Test
Leak Rate
acfm
0.002 @1 5" Hg
0.010 @ 7.5" Hg
0.002 @ 10" Hg
0.010 @ 13" Hg
0.002 @ 8" Hg
0.008 @ 7" Hg
0.007 @ 13" Hg
0.001 @ 8" Hg
0.000 @1 5" Hg
0.004 @ll"Hg
0.010 @ 9.5" Hg
not recorded
0.006 @ 18" Hg
0.007 @1 5" Hg
0.001 @ 10" Hg
EPA
Criteria
acfm
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
0.02
Percent
Isokinetic
105.0
101.6
97.4
102.3
105.8
102.4
109.9
110.6
105.6
101.7
104.8
103.7
92.1
100.8
101.7
EPA
Criteria
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
90-110%
* Run was used for volumetric flow rate data only.
-------
TABLE 6.5
SUMMARY OF EPA METHOD 315 BLANK SAMPLE CATCHES
Blank'
Acetone Wash Blank
Methylene Chloride Blank
Deionized Water Blank
Filter Blank
TED Field Blank, Filter - PM
TED Field Blank, Filter -MCEM
TED Field Blank, FH Acetone Rinse - PM
TED Field Blank, FH MeCl Rinse - MCEM
TED Field Blank, BH Solvent Rinse - MCEM
TED Field Blank, Impinger/H2O Rinse - MCEM
SED Field Blank, Filter - PM
SED Field Blank, Filter -MCEM
SED Field Blank, FH Acetone Rinse - PM
SED Field Blank, FH MeCl Rinse - MCEM
SED Field Blank, BH Solvent Rinse - MCEM
SED Field Blank, Impinger/H2O Rinse - MCEM
Mass of
Residue
(me)
0.1
0.0
0.2
0.0
4.3
0.0
4.6
4.1
0.0
0.0
1.5
0.3
2.1
2.0
0.1
0.1
Volume
of Blank
fmL)
200.3
189.1
199.3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Concentration
of Blank
(me/m£)b
6.4E-07
0.0
l.OE-06
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
1 FH = Front Half; BH = Back Half.
b Calculated using the EPA Method 315 given densities for acetone and MeCl of 785.1 mg/mL
and 1,316.8 mg/mL, respectively.
6-12
-------
TABLE 6.6
SW-846 METHOD 0010 PAHs
FIELD AND LABORATORY BLANKS RESULTS
TUNNEL EXHAUST DUCT
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(l,2,3-cd)pyrene
2-Methylnaphthalene
Naphthalene
Perylene
Phenanthrene
Pyrene
Amount, nanograms
Average
Catch
Weight4
{4,750}
530
{1,400}
340
145
41
39
42
150
{2,000}
(8)
{1,065}
{15,400}
(10)
{42,500}
{21,500}
405
{17,000}
{2,950}
Field
Blank
60
ND
ND
ND
ND
ND
ND
ND
ND
22
ND
42
160
ND
280
290
ND
320
40
Method
Blank
43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16
43
ND
120
280
ND
82
ND
Reagent
Blank
38
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
26
43
ND
140
270
ND
110
18
* Average catch weight of normal operation runs T-MM5-2 and T-MM5-3, only.
{} Estimate - Concentration exceeds calibration range.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero in averages.
() Indicates an average value that includes one or more NDs averaged as zeroes.
6-13
-------
TABLE 6.7
SW-846 METHOD 0010 PAHs
FIELD AND LABORATORY BLANKS RESULTS
SILO EXHAUST DUCT
Compound
Acenaphthene
Acenaphthylene
Anthracene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(g,h,i)perylene
Benzo(a)pyrene
Benzo(e)pyrene
Chrysene
Dibenz(a,h)anthracene
Fluoranthene
Fluorene
Indeno(l ,2,3-cd)pyrene
2-MethyInaphthalene
Naphthalene
Perylene
Phenanthrene
Pyrene
Amount, nanograms
Average
Catch
Weight
243,000
(7,330)
69,000
28,700
ND
ND
ND
ND
(5,000)
107,000
ND
74,000
527,000
ND
2,733,000
940,000
(16,300)
937,000
230,000
Field
Blank
150
ND
100
53
26
ND
21
ND
25
300
ND
130
420
ND
490
410
70
1,600
350
Method
Blank
43
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
16
43
ND
120
280
ND
82
ND
Reagent
Blank
38
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
26
43
ND
140
270
ND
110
18
() Indicates an average value that includes one or more NDs averaged as zeroes.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero in averages.
6-14
-------
TABLE 6.8
SW-846 METHOD 0010 PAHs
SURROGATE RECOVERY RESULTS
TUNNEL EXHAUST DUCT
Surrogate
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d,0
Fluorene-d|o
Phenanthrene-d,0
Fluoranthene-d,0
Pyrene-d,0
Benzo(a)anthra-
cene-d,2
Chrysene-d,2
Benzo(b)fluor-
anthene-d,2
Benzo(k)fluor-
anthene-d,2
Benzo(a)-
pyrene-d|2
Perylene-d,2
Indeno(123-cd>
pyrene-d,2
Dibenz(a,h)-
anthracene-d,4
Benzo(g,h,i)-
perylene-d,2
Field Surrogate
13C-Fluorene
Percent Recovery
T-
MM5-2
65
73
56
42
61
30
30
62
52
101
67
83
62
174
181
177
134
T-
MM5-3
25
57
40
49
61
96
80
121
103
97
89
73
67
95
103
92
85
T-
MM5-4
90
88
86
62
74
100
98
148
130
108
94
90
82
90
84
94
104
T-MM5-
FB
54
78
84
60
77
105
104
157
145
104
105
85
79
107
110
108
102
Method
Blank
86
62
71
77
72
82
84
77
92
92
100
80
87
92
84
98
96
Reagent
Blank
59
71
74
63
75
86
88
139
127
105
102
93
90
121
120
119
113
Method
QC Limits
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-15
-------
TABLE 6.9
SW-846 METHOD 0010 SEMI-VOLATILE
SURROGATE RECOVERY RESULTS
TUNNEL EXHAUST DUCT
Surrogate
QC Limit
Sample ID
T-MM5-2
T-MM5-3
T-MM5-4
T-MM5-FB
Reagent Blank
Method Blank
Percent Recovery
Nitro-
benzene-d5
45-107
87
78
62
60
61
86
2-Fluoro-
biphenyl
62-110
105
106
86
85
86
102
Ter-
phenyl-du
58-135
78
80
110
94
97
106
Phenol-d;
43-130
67
69
61
65
67
85
2-Fluoro-
phenol
36-111
62
71
54
56
62
82
2,4,6-Tri-
bromophenol
58-131
49
52
65
70
84
94
6-16
-------
TABLE 6.10
SW-846 METHOD 0010 PAHs
SURROGATE RECOVERY RESULTS
SILO EXHAUST DUCT
Surrogate
Naphthalene-d8
Acenaphthylene-d8
Acenaphthene-d,0
Fluorene-d,0
Phenanthrene-d:o
Fluoranthene-d,0
Pyrene-d.o
Benzo(a)anthra-
cene-d,2
Chrysene-d,2
Benzo(b)fluor-
anthene-d,2
Benzo(k)fluor-
anthene-d,2
Benzo(a)-
pyrene-d,2
Perylene-d,2
Indeno(123-cd>
pyrene-d]2
Dibenz(a,h)-
anthracene-du
Benzo(g,h,i)-
perylene-d,2
Field Surrogate
13C-Fluorene
Percent Recovery
S-
MM5-2
90
140
127
96
102
34
33
38
32
128
101
98
98
95
87
86
NA
S-
MM5-4
85
121
113
92
98
49
47
52
44
134
98
98
94
85
80
78
NA
S-
MM5-5
84
122
108
88
93
50
48
51
42
125
96
95
94
82
76
73
NA
S-MM5-
FB
61
77
80
62
77
113
111
151
125
106
101
93
90
118
124
115
94
Method
Blank
86
62
71
77
72
82
84
77
92
92
100
80
87
92
84
98
96
Reagent
Blank
59
71
74
63
75
86
88
139
127
105
102
93
90
121
120
119
113
Method
QC Limits
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-17
-------
TABLE 6.11
SW-846 METHOD 0010 SEMI-VOLATILE
SURROGATE RECOVERY RESULTS
SILO EXHAUST DUCT
Surrogate
QC Limit
Sample ID
S-MM5-2
S-MM5-4
S-MM5-5
S-MM5-FB
S-MM5-RB
Method Blank
Percent Recovery
Nitro-
benzene-ds
45-107
ND
ND
ND
58
61
86
2-Fluoro-
biphenyl
62-110
ND
ND
ND
79
86
102
Ter-
phenyl-du
58-135
ND
ND
ND
101
97
106
Phenol-
el,
43-130
ND
ND
ND
59
67
85
2-Fluoro-
phenol
36-111
ND
ND
ND
54
62
82
2,4,6-Tri-
bromophenol
58-131
ND
ND
ND
74
84
94
ND Indicates that a compound was not detected.
6-18
-------
TABLE 6.12
SW-846 METHOD 0030
FIELD AND LABORATORY BLANKS RESULTS
TUNNEL EXHAUST DUCT
Compound
Benzene
Bromomethane
Chloromethane
Cumene
n-Hexane
Methylene Chloride
Styrene
Toluene
m-/p-Xylene
Amount, in micrograms
Avg.
Catch
Weight*
0.187
(0.036)
(0.054)
ND
{0.144}
(0.288)
(0.021)
{0.265}
{0.409}
TED
Field
Blank
{0.006}
ND
ND
ND
ND
0.054
ND
{0.006}
ND
VOST
Blank
80998
{0.048}
{0.010}
{0.015}
ND
ND
{0.001}
{0.001}
{0.003}
ND
VOST
Blank
81798
{0.013}
ND
ND
ND
ND
ND
ND
{0.005}
ND
VOST
Blank
81898
{0.023}
ND
ND
ND
ND
ND
ND
{0.008}
ND
VOST
Blank
81998
ND
ND
{0.003}
{0.001}
{0.001}
{0.002}
ND
{0.003}
{0.001}
VOST
Blank
82198
{0.039}
ND
ND
ND
ND
ND
ND
ND
ND
VOST
Blank
82498
ND
ND
ND
ND
ND
ND
ND
ND
ND
' Average Catch Weight = Average of all 10 TED normal operation SW-846 Method 0030 run samples.
ND Indicates that a compound was not detected.
() Indicates an average value which includes one or more NDs averaged as zeroes.
{ } Indicates an average value which includes one or more estimated values.
NOTE: All other VOST compounds were not detected in the blanks and are not listed here.
6-19
-------
TABLE 6.13
SW-846 METHOD 0030
LABORATORY BLANK RESULTS
SILO EXHAUST DUCT
Compound
Acetone
Benzene
Bromomethane
2-Butanone
Chloroform
Chloromethane
Cumene
Ethylbenzene
n-Hexane
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
m-/p-Xylene
o-Xylene
Amount, in micrograms
Avg. Catch Weight*
{1.388}
{1.082}
{0.132}
(0.867)
ND
0.568
ND
{1.391}
{4.006}
ND
(0.005)
(0.128)
ND
{2.281}
{7.301}
{2.112}
VOSTBLK 090498
{0.005}
{0.027}
{0.022}
{0.003}
{0.001}
{0.025}
{0.001}
{0.001}
{0.001}
{0.002}
{0.004}
{0.002}
{0.001}
{0.004}
{0.001}
{0.001}
1 Average Catch Weight = Average of all five of the SED SW-846 Method 0030 run samples.
ND Indicates that a compound was not detected.
() Indicates an average value which includes one or more NDs averaged as zeroes.
{ } Indicates an average value which includes one or more estimated values.
NOTE: All other VOST compounds were not detected in the blank and are not listed here.
6-20
-------
TABLE 6.14
SW-846 METHOD 0030
SURROGATE RECOVERY RESULTS
TUNNEL EXHAUST DUCT
Sample ID
T-V-1-l-AT
T-V-1-l-BTC
T-V-1-2-AT
T-V-1-2-BTC
T-V-1-3-AT
T-V-1-3-BTC
T-V-2-l-A,BT/TC
T-V-2-2-A.B T/TC
T-V-2-3-A.B T/TC
T-V-2-4-A,B T/TC
T-V-3-1-A.B T/TC
T-V-3-2-A.B T/TC
T-V-3-3-A.B T/TC
T-V-4-1-AT
T-V-4-1-BTC
T-V-4-2-A T
T-V-4-2-B TC
T-V-4-4-A T
T-V-FB-A.B T/TC
VOSTBLK080998 T/TC
VOSTBLK081798
VOSTBLK081898
VOSTBLK081998
VOSTBLK082 198 T/TC
VOSTBLK082498 T/TC
Percent Recovery
Dibromo-
fluoromethane
92
100
92
98
103
97
88
85
83
83
84
82
84
105
103
97
101
83
117
99
107
102
109
109
93
Toluene-d,
136
122
140
126
135
125
111
107
104
104
102
104
106
113
116
98
107
104
105
104
118
127
112
104
102
4-Bromofluoro-
benzene
162
113
170
111
136
114
128
126
119
118
113
133
107
154
116
108
107
102
95
109
102
106
117
81
79
Method QC
Limits
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-21
-------
TABLE 6.15
SW-846 METHOD 0030
SURROGATE RECOVERY RESULTS
SILO EXHAUST DUCT
Sample ID
S-V-1-l-AT
S-V-1-2-AT
S-V-1-2-BTC
S-V-1-4-A T
S-V-1-4-B TC
S-V-2-4-A T
S-V-2-4-B TC
S-V-3-3-A T
S-V-3-3-B TC
VOSTBLK090498 T/TC
Percent Recovery
Dibromo-
fluoromethane
156
133
114
128
115
108
114
117
119
112
Toluene-dg
174
144
114
133
114
127
113
160
113
109
4-Bromofluoro-
benzene
788
414
132
120
132
582
130
695
127
126
Method QC
Limits
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
50-150
6-22
-------
VOLUME 1
APPENDIX A
TEST RESULTS AND CALCULATIONS
A. 1 TED TEST RESULTS
A.2 SED TEST RESULTS
A.3 EXAMPLE CALCULATIONS
A.4 PARTICIPATE DEPOSITION DATA
-------
-------
APPENDIX A.I
TED TEST RESULTS
-------
Summary of Stack Gas Parameters and Test Results
PM and MCEM - EPA Method 315
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 2
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
AP1/2
0
Dn
An
Vm(std)
Vm(std)
PS
BWS
Bws(sat)
V/wstd
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozz.le Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb«mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-M315-1
7/24/98
0720-1303
1.001
1.62
29.35
169.030
86
-4.7
85
124.0
0.0
20.9
79.1
0.84
0.5736
240
0.258
1,875.0
0.000363
160.986
4.559
29.00
3.5
4.2
5.837
0.965
28.84
28.46
33.5
5.59
11,220
10,159
288
101.6
T-M315-2
7/25/98
0711-1127
1.001
1.69
29.33
172.210
90
-5.9
88
84.8
0.0
20.9
79.1
0.84
0.5729
240
0.258
1,499.7
0.000363
162.940
4.614
28.90
2.4
4.5
3.992
0.976
28.84
28.58
33.5
5.59
11,226
10,201
289
102.4
T-M315-3
7/27/98
0711-1200
1.001
1.46
29.23
162.817
92
-4.5
94
64.5
0.0
20.9
79.1
0.84
0.5352
240
0.257
2,529.7
0.000360
152.700
4.324
28.90
1.9
5.5
3.036
0.981
28.84
28.62
31.4
5.59
10,535
9,514
269
103.7
Average
1.001
1.59
29.30
168.019
89
-5.0
89
91.1
0.0
20.9
79.1
0.84
0.5606
240
0.258
1,968.1
0.000362
158.875
4.499
28.93
2.6
4.8
4.288
0.974
28.84
28.55
32.8
5.59
10,994
9,958
282
102.6
-------
Summary of Stack Gas Parameters and Test Results
PM and MCEM - EPA Method 315
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 2
PM
CpM
CpM
MCEM
CMCEM
CMCEM
EMCEM
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
Paniculate Matter
Target Catch, g
Concentration, gr/dscf
Concentration, g/dscm
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylene Chloride Extractable
Target Catch, g
Concentration, gr/dscf
Concentration, g/dscm
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-M315-1
7/24/98
0720-1303
0.0128
1.23E-03
2.81E-03
4.27E-01
2.28E-04
Matter
0.0112
1.07E-03
2.46E-03
3.74E-01
1.99E-04
T-M315-2
7/25/98
0711-1127
0.0078
7.39E-04
1.69E-03
2.58E-01
1.72E-04
0.0024
2.27E-04
5.20E-04
7.95E-02
5.30E-05
T-M315-3
7/27/98
0711-1200
0.0085
8.59E-04
1.97E-03
2.80E-01
1.11E-04
0.0027
2.73E-04
6.24E-04
8.90E-02
3.52E-05
Average
9.42E-04
2.15E-03
3.22E-01
1.70E-04
5.25E-04
1.20E-03
1.81E-01
9.59E-05
-------
Summary of Stack Gas Parameters and Test Results
PM and MCEM - EPA Method 315
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 2
Y
AH
Pbar
vm
Tm
Pstatic
Ts
v,c
CO2
02
N2
cp
Ap1/2
©
Dn
An
Vm(std)
Vm(std)
PS
Bws
Bws(sat)
Vwstd
1-Bws
Md
Ms
Vs
A
Qa
Qs
^s(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1'2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-M315-4
7/26/98
0926-1340
1.001
1.88
29.31
180.285
100
-5.9
91
115.7
0.0
20.9
79.1
0.84
0.5985
240
0.258
0.000363
167.419
4.741
28.88
3.2
5.1
5.446
0.968
28.84
28.49
35.2
5.59
11,788
10,549
299
101.7
-------
Summary of Stack Gas Parameters and Test Results
Asphalt Plant C - California
PM and MCEM - EPA Method 315
Background Condition, Tunnel Exhaust Duct
Page 2 of 2
RUN NUMBER T-M315-4
RUN DATE 7/26/98
RUN TIME 0926-1340
EMISSIONS DATA
Particulate Matter
PM Target Catch, g 0.0086
CPM Concentration, gr/dscf 7.93E-04
CPM Concentration, g/dscm 1.81E-03
Emission Rate, Ib/test period 2.87E-01
Methylene Chloride Extractable Matter
MCEM Target Catch, g 0.0041
CMCEM Concentration, gr/dscf 3.78E-04
CMCEM Concentration, g/dscm 8.65E-04
Emission Rate, Ib/test period 1.37E-01
-------
M315 Analytical Calculations
Run Number: T-M315-1
Particulate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
Ma
PA
Va
ca
V,w
w,
Mass of residue of acetone, mg
Density of acetone, mg/mL
Volume of acetone blank, ml
Acetone blank concentration, mg/mg
Volume of acetone used in wash, ml
Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
55.1
0.028
Container
Number
1
Final weight
grams
147.3795
Tare of dish
or beaker, g
146.9268
Tare of
filter, g
0.4491
Weight Gain
grams
0.0036
Total particulate catch weight, in milligrams = 12.8
Total particulate minus the acetone blank (Wa), mg = 12.77
0.043
MeCI Extractable Matter (MCEM) Determinations
Container Final weight Tare of Weight Gain Acetone Wash MeCI Wash
Number
2+2M
3W
3S
W.
Mt
PT
V,
C,
w,
M
MCEM
in grams
1.6326
1.6262
1.6621
1.0236
dish, g
1.6303
1.6209
1.6620
1.0200
grams
0.0023
0.0053
Volume, mL [ Volume, mL
55.1 | 100
0.0001
totals from line above are:
0.0036
0.0113
mtotai in mg
11.3
119.1
174.2
sum of Vaw, mL
174.2
119.1
219.1
sum of Vtw, ml
219.1
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, mL
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Sample Data
0.087
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
11.21
QC limit
0.137
0.462
-------
M315 Analytical Calculations
Run Number: T-M315-2
Particulate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
Ma Mass of residue of acetone, mg
PA Density of acetone, mg/mL
Va Volume of acetone blank, mL
Ca Acetone blank concentration, mg/mg
Vaw Volume of acetone used in wash, ml
Wa Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
40.9
0.020
Container
Number
Final weight
grams
203.3178
Tare of dish
or beaker, g
202.8661
Tare of
filter, g
0.4489
Weight Gain
grams
0.0028
0.0050
0.0078
Total particulate catch weight, in milligrams •
Total particulate minus the acetone blank (Wa), mg;
7.8
7.78
0.032
MeCI Extractable Matter (MCEM) Determinations
Container Final weight Tare of Weight Gain Acetone Wash MeCI Wash
Number
2+2M
3W
3S
Wa
M,
PT
V,
C,
w,
in grams
1.6459
1.6294
1.6374
1.0229
dish, g
1.6458
1.6273
1.6373
10227
grams
0.0001
0.0021
0.0001
0.0002
0.0025
totals from line above are:
mtoU| in mg
2.5
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, mL
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Volume, mL
90.5
131.4
sum of Vaw, ml
131.4
90.5
190.5
sum of V,,,, mL
190.5
Sample Data
0.07
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
2.43
QC limit
0.103
0.401
ID
-------
M315 Analytical Calculations
Run Number: T-M315-3
Particulate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
Ma
PA
V,
Ca
"»w
w.
Mass of residue of acetone, mg
Density of acetone, mg/mL
Volume of acetone blank, ml
Acetone blank concentration, mg/mg
Volume of acetone used in wash, ml
Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
125.4
0.063
Container
Number
Final weight
grams
162.6478
Tare of dish
or beaker, g
162.1919
Tare of
filter, g
0.4530
Weight Gain
grams
0.0029
Total particulate catch weight, in milligrams >
Total particulate minus the acetone blank (Wa), mg •
8.6
8.54
0.098
MeCI Extractable Matter (MCEM) Determinations
Container
Number
2+2M
3W
W,
Mt
PT
V,
Ct
wt
M
MCEM
Final weight
in grams
1.6396
1.6420
1.6065
1.0261
Tare of
dish, g
1.6390
1.6402
1.6064
1.0258
Weight Gain Acetone Wash
grams
0.0006
0.0018
0.0001
totals from line above are:
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, mL
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Volume, mL
0.0003
0.0028
I mtot»i in m9
2.8
129.3
254.7
sum of Vaw, mL
254.7
129.3
229.3
sum of V^, mL
229.3
Sample Data
0.13
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
2.67
QC limit
0.200
0.483
l\
-------
M315 Analytical Calculations
Run Number: T-M315-4
Particulate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
Ma Mass of residue of acetone, mg
PA Density of acetone, mg/mL
V, Volume of acetone blank, ml
Ca Acetone blank concentration, mg/mg
Vaw Volume of acetone used in wash, ml
Wa Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
136
0.068
Container
Number
Final weight
grams
157.8204
Tare of dish
or beaker, g
157.3657
Tafe of
filter, g
0.4527
Weight Gain
grams
0.0020
Total particulate catch weight, in milligrams:
Total particulate minus the acetone blank (Wa), mg
8.7
8.63
0.107
MeCI Extractable Matter (MCEM) Determinations
Container Final weight Tare of
Number
2+2M
3W
3S
W,
Mt
PT
Vt
C,
w,
in grams
1.6384
1.6422
1.5927
1.0274
dish, g
1.6384
1.6392
1.5923
1.0267
Weight Gain Acetone Wash MeCI Wash
grams
0.0000
0.0030
0.0004
totals from line above are:
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, ml
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Volume, mL
0.0007
0.0041
mtotai in mg
4.1
99.5
235.5
sum of Vaw, mL
235.5
99.5
199.5
sum of V^, mL
199.5
Sample Data
0.12
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
3.98
QC limit
0.185
0.420
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 5
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
CP
Ap1*
©
Dn
An
Vm(std)
Vm(std)
PS
Byvs
Bws(sat)
Vwstd
1-B«
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-MM5-2
7/25/98
0710-1121
1.000
1.44
29.33
157.650
78
-4.8
82
116.4
0.0
20.9
79.1
0.84
0.5442
240
0.252
1 ,478.7
0.000346
152.087
4.307
28.98
3.5
3.8
5.479
0.965
28.84
28.46
3t.7
5.59
10,618
9,663
274
105.8
T-MM5-3
7/27/98
0710-1155
1.000
1.56
29.23
163.906
85
-4.5
89
121.0
0.0
20.9
79.1
0.84
0.5660
240
0.252
2,530.2
0.000346
155.540
4.404
28.90
3.5
4.7
5.695
0.965
28.84
28.45
33.2
5.59
11,128
9,972
282
104.8
X
Average
1.000
1.50
29.28
160.778
82
-4.7
85
118.7
0.0
20.9
79.1
0.84
0.5551
240
0.252
2,004.5
0.000346
153.813
4.356
28.94
3.5
4.3
5.587
0.965
28.84
28.46
32.4
5.59
10,873
9,818
278
105.3
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 5
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton "
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton a
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
154.21
{4.500}
{1.04E-03}
{1.63E-01}
{1.51E-04}
{1.02E-07}
154.21
0.470
1.09E-04
1.70E-02
1.58E-05
1.07E-08
178.22
{1.700}
{3.95E-04}
{5.33E-02}
{5.72E-05}
{3.87E-08}
228.29
0.370
8.59E-05
9.05E-03
1.24E-05
8.41 E-09
252.32
0.160
3.71 E-05
3.54E-03
5.38E-06
3.64E-09
T-MMS-3
154.21
{5.000}
{1.14E-03}
{1.77E-01}
{1.70E-04}
{6.70E-08}
154.21
0.590
1.34E-04
2.09E-02
2.00E-05
7.91 E-09
178.22
1.100
2.50E-04
3.37E-02
3.73E-05
1.47E-08
228.29
0.310
7.04E-05
7.42E-03
1.05E-05
4.16E-09
252.32
0.130
2.95E-05
2.81 E-03
4.41 E-06
1.74E-09
Average
{4.750}
{1.09E-03}
{1.70E-01}
{1.60E-04}
{8.47E-08}
0.530
1.22E-04
1.90E-02
1.79E-05
9.30E-09
{1.400}
{3.22E-04}
{4.35E-02}
{2.67E-08}
{2.67E-08}
0.340
7.81 E-05
8.23E-03
1.15E-05
6.28E-09
0.145
3.33E-05
3.18E-03
4.89E-06
2.69E-09
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 5
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Benzo(ghi)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Cor centration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MMS-2
252.32
0.047
1.09E-05
1.04E-03
1.58E-06
1.07E-09
276.34
0.044
1.02E-05
8.89E-04
1.48E-06
1.00E-09
252.30
0.048
1.11E-05
1.06E-03
1.61E-06
1.09E-09
252.30
0.180
4.18E-05
3.98E-03
6.05E-06
4.09E-09
228.28
{2.100}
{4.88E-04}
{5.14E-02}
{7.06E-05}
{4.77E-08}
T-MM5-3
252.32
0.034
7.72E-06
7.36E-04
1.15E-06
4.56E-10
276.34
0.033
7.49E-06
6.52E-04
1.12E-06
4.42E-10
252.30
0.035
7.95E-06
7.58E-04
1.19E-06
4.69E-10
252.30
0.120
2.72E-05
2.60E-03
4.07E-06
1.61E-09
228.28
{1.900}
{4.31 E-04}
{4.55E-02}
{6.45E-05}
{2.55E-08}
Averaae
0.041
9.32E-06
8.88E-04
1.37E-06
7.62E-10
0.039
8.85E-06
7.71 E-04
1.30E-06
7.21 E-10
0.042
9.55E-06
9.10E-04
1.40E-06
7.80E-10
0.150
3.45E-05
3.29E-03
5.06E-06
2.85E-09
{2.000}
{4.59E-04}
{4.84E-02}
{6.75E-05}
{3.66E-08}
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 5
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
lndeno(1 ,2,3-cd)py rene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2-Methylnaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MMS-2
278.33
0.016
3.71 E-06
3.21E-04
5.38E-07
3.64E-10
202.26
{1.200}
{2.79E-04}
{3.31 E-02}
{4.03E-05}
{2.73E-08}
166.21
{21.000}
{4.88E-03}
{7.06E-01}
{7.06E-04}
{4.77E-07}
290.34
0.020
4.64E-06
3.85E-04
6.72E-07
4.55E-10
142.20
{38.000}
{8.82E-03}
{1.49E+00}
{1.28E-03}
{8.64E-07}
T-MMS-3
278.33
ND
ND
ND
ND
ND
202.26
{0.930}
{2.11E-04}
{2.51 E-02}
{3.15E-05}
{1.25E-08}
166.21
{9.800}
{2.22E-03}
{3.22E-01}
{3.32E-04}
{1.31E-07}
290.34
ND
ND
ND
ND
ND
142.20
{47.000}
{1.07E-02}
{1.81E+00}
{1.59E-03}
{6.30E-07}
Averaae
(0.008)
(1.86E-06)
(1.61E-04)
(2.69E-07)
(1.82E-10)
{1.065}
{2.45E-04}
{2.91 E-02}
{3.59E-05}
{1.99E-08}
{15.400}
{3.55E-03}
{5.14E-01}
{5.19E-04}
{3.04E-07}
(0.010)
(2.32E-06)
(1.92E-04)
(3.36E-07)
(2.27E-10)
{42.500}
{9.75E-03}
{1.65E+00}
{1.44E-03}
{7.47E-07}
It,
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 5
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
128.16
{19.000}
{4.41 E-03}
{8.28E-01}
{6.39E-04}
{4.32E-07}
252.30
0.530
1.23E-04
1.17E-02
1.78E-05
1.20E-08
178.22
{21.000}
{4.88E-03}
.{6.58E-01}
{7.06E-04}
{4.77E-07}
202.24
{3.200}
{7.43E-04}
{8.84E-02}
{1.08E-04}
{7.28E-08}
T-MM5-3
128.16
{24.000}
{5.45E-03}
{1.02E+00}
{8.14E-04}
{3.22E-07}
252.30
0.280
6.36E-05
6.06E-03
9.50E-06
3.75E-09
178.22
{13.000}
{2.95E-03}
{3.98E-01}
{4.41 E-04}
{1.74E-07}
202.24
{2.700}
{6.13E-04}
{7.29E-02}
{9.16E-05}
{3.62E-08}
Averaae
{21.500}
{4.93E-03}
{9.25E-01}
{7.26E-04}
{3.77E-07}
0.405
9.33E-05
8.90E-03
1 .37E-05
7.90E-09
{17.000}
{3.91 E-03}
{5.28E-01}
{5.74E-04}
{3.26E-07}
{2.950}
{6.78E-04}
{8.06E-02}
{9.96E-05}
{5.45E-08}
Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
c Pounds per test period.
d Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero.
{} Estimate - Concentration in the sample exceeded the method calibration range,
but was still within the linear response range of the detector.
n
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 5
Y
AH
Pbar
vm
Tm
"static
Ts
V,c
CO2
02
N2
CP
AP1/2
0
Dn
An
Vm(std)
Vm(std)
PS
Bws
Bvre(sat)
Vwstd
1-B,*
Md
Ms
Vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb«mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-MM5-4
7/26/98
0925-1343
1.000
1.85
29.31
179.672
91
-4.9
87
132.9
0.0
20.9
79.1
0.84
0.3108
240
0.252
none
0.000346
169.391
4.797
28.95
3.6
4.5
6.256
0.964
28.84
28.45
35.8
5.59
11,981
10,784
305
105.6
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 5
T-MM5-4
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period °
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm"
Concentration, ppbvdb
Emission Rate, Ib/test period °
154.21
{0.550}
{1.15E-04}
{1.79E-02}
{1.85E-05}
154.21
0.080
1.67E-05
2.60E-03
2.69E-06
178.22
0.220
4.59E-05
6.19E-03
7.41 E-06
228.29
0.015
3.13E-06
3.29E-04
5.05E-07
252.32
0.018
3.75E-06
3.58E-04
6.06E-07
252.32
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 5
T-MMS-4
Benzo(ghi)perylene
Molecular Weight, g/g-mole
Target Catch, \ig
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscme
Concentration, ppbvd "
Emission Rate, Ib/test periodc
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
276.34
0.0075
1.56E-06
1.36E-04
2.53E-07
252.30
ND
ND
ND
ND
252.30
0.013
2.71 E-06
2.58E-04
4.38E-07
228.28
0.310
6.46E-05
6.81 E-03
1.04E-05
278.33
ND
ND
ND
ND
202.26
0.300
6.25E-05
7.44E-03
1.01E-05
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 5
T-MM5-4
luorene
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period °
ndeno(1,2,3-cd)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
2-Methy I naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test periodc
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period °
Perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
166.21
{1.600}
{3.34E-04}
{4.83E-02}
{5.39E-05}
290.34
ND
ND
ND
ND
142.20
{2.600}
{5.42E-04}
{9.17E-02}
{8.76E-05}
128.16
BRL
BRL
BRL
BRL
252.30
ND
ND
ND
ND
178.22
{4.000}
{8.34E-04}
{1.13E-01}
{1.35E-04}
2.1
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 5
T-MM5-4
Pyrene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
202.24
{0.600}
{1.25E-04}
{1.49E-02}
{2.02E-05}
Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
c Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero.
{} Estimate - Concentration in the sample exceeded the method calibration range,
but was still within the linear response range of the detector.
BRL Below Reporting Limit based on Equation 429-32 of CARB Method 429.
1-2-
-------
PAHs RUN SAMPLES TO METHOD BLANK RATIOS
TUNNEL EXHAUST DUCT
ASPHALT PLANT C - LOS ANGELES, CA
PAHs Compound
Naphthalene
Methylnaphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(e)pyrene
Benzo(a)pyrene
Perylene
Indeno(l ,2,3-cd)pyrene
Dibenz(a,h)anthracene
B enzo(ghi)perylerie
TED
Field
Blank
catch, ng
290
280
ND
60
160
320
ND
42
40
ND
22
ND
ND
ND
ND
ND
ND
ND
ND
Run
T-MM5-2
sample
catch, ng
{19,000}
{38,000}
470
{4,500}
{21,000}
{21,000}
{1,700}
{1,200}
{3,200}
370
{2,100}
160
47
180
48
530
20
16
44
Ratio of
sample
to blank
65.5
135.7
NA
75.0
131.3
65.6
NA
28.6
80.0
NA
95.5
NA
NA
NA
NA
NA
NA
NA
NA
Run
T-MM5-3
sample
catch, ng
{24,000}
{47,000}
590
{5,000}
{9,800}
{13,000}
1,100
{930}
{2,700}
310
{1,900}
130
34
120
35
280
0
0
33
Ratio of
sample
to blank
82.8
167.9
NA
83.3
61.3
40.6
NA
22.1
67.5
NA
86.4
NA
NA
NA
NA
NA
NA
NA
NA
Run
T-MM5-4
sample
catch, ng
{1,400}
{2,600}
80
{550}
{1,600}
{4,000}
220
300
{600}
15
310
18
0
13
0
0
0
0
7.5
Ratio ol
sample
to blanl
4.8
9.3
NA
9.2
10.0
12.5
NA
7.1
15.0
NA
14.1
NA
NA
NA
NA
NA
NA
NA
NA
Based on Equation 429-32 of CARB Method 429, a ratio < 5 indicates the compound is below the reporting limit (BRL).
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 19
Y
AH
Pbar
vm
Tm
Pstatic
Ts
Vte.
CO2
02
N2
cp
Ap1/2
©
Dn
An
" m(std)
" m(std)
PS
BWS
1-EU
Md
Ms
Vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1'2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb»mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-MM5-2
7/25/98
0710-1121
1.000
1.44
29.33
157.650
78
-4.8
82
116.4
0.0
20.9
79.1
0.84
0.5442
240
0.252
1,478.7
0.000346
152.087
4.307
28.98
3.5
5.479
0.965
28.84
28.46
31.7
5.59
10,618
9,663
274
105.8
T-MM5-3
7/27/98
0710-1155
1.000
1.56
29.23
163.906
85
-4.5
89
121.0
0.0
20.9
79.1
0.84
0.5660
240
0.252
2,530.2
0.000346
155.540
4.404
28.90
3.5
5.695
0.965
28.84
28.45
33.2
5.59
11,128
9,972
282
104.8
Average
1.000
1.50
29.28
160.778
82
-4.7
85
118.7
0.0
20.9
79.1
0.84
0.5551
240
0.252
2,004.5
0.000346
153.813
4.356
28.94
3.5
5.587
0.965
28.84
28.46
32.4
5.59
10,873
9,818
278
105.3
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 19
Acenaphthene
Molecular Weight, g/g-mo!e
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Acetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Aminobiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Aniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
154.21
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
120.15
ND
ND
ND
ND
ND
169.22
ND
ND
ND
ND
ND
93.12
ND
ND
ND
ND
ND
T-MM5-3
154.21
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
120.15
ND
ND
ND
ND
ND
169.22
ND
ND
ND
ND
ND
93.12
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 19
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
178.22
ND
ND
ND
ND
ND
184.23
ND
ND
ND
ND
ND
228.29
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
T-MM5-3
178.22
ND
ND
ND
ND
ND
184.23
ND
ND
ND
ND
ND
228.29
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 19
tenzoic acid
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzyl alcohol
Molecular Weight, g/g-mole
Target Catch, \tg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
122.12
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
T-MM5-3
122.12
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 19
Biphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
4-Bromophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Butyl benzyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Chloroacetopnenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Chloroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
154.20
ND
ND
ND
ND
ND
249.11
ND
ND
ND
ND
ND
312.36
ND
ND
ND
ND
ND
154.59
ND
ND
ND
ND
ND
127.57
ND
ND
ND
ND
ND
T-MMS-3
154.20
ND
ND
ND
ND
ND
249.11
ND
ND
ND
ND
ND
312.36
ND
ND
ND
ND
ND
154.59
ND
ND
ND
ND
ND
127.57
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of 19
bis(2-Chloroethoxy)-methane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
bis(2-Chloroethyl) ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Chloro-3-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Chloronaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Chlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
173.04
ND
NO
ND
ND
ND
143.02
ND
ND
ND
ND
ND
142.58
ND
ND
ND
ND
ND
162.61
ND
ND
ND
ND
ND
128.56
ND
ND
ND
ND
ND
T-MM5-3
173.04
ND
ND
ND
ND
ND
143.02
ND
ND
ND
ND
ND
142.58
ND
ND
ND
ND
ND
162.61
ND
ND
ND
ND
ND
128.56
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 7 of 19
4-Chlorophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Dibenzofuran
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
204.66
ND
ND
ND
ND
ND
228.28
ND
ND
ND
ND
ND
120.19
ND
ND
ND
ND
ND
278.33
ND
ND
ND
ND
ND
168.20
ND
ND
ND
ND
ND
T-MMS-3
•
204.66
ND
ND
ND
ND
ND
228.28
ND
ND
ND
ND
ND
120.19
ND
ND
ND
ND
ND
278.33
ND
ND
ND
ND
ND
168.20
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of 19
1 ,2-Dibromo-3-chloropropane (DBCP)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Di-n-butyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
,2-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1 ,3-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1 ,4-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
236.36
ND
ND
ND
ND
ND
278.34
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
T-MMS-3
236.36
ND
ND
ND
ND
ND
278.34
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 9 of 19
3,3'-Dichlorobenzidine
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4-Dichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Diethyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
N-N-Diethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3,3'-Dimethoxybenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm e
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
253.13
ND
ND
ND
ND
ND
163.01
ND
ND
ND
ND
ND
222.24
ND
ND
ND
ND
ND
149.23
ND
ND
ND
ND
ND
244.28
ND
ND
ND
ND
ND
T-MM5-3
253.13
ND
ND
ND
ND
ND
163.01
ND
ND
ND
ND
ND
222.24
ND
ND
ND
ND
ND
149.23
ND
ND
ND
ND
ND
244.28
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 10 of 19
Dimethyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Dimethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3,3'-Dimethylbenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2,4-Dimethylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4,6-Dinitro-2-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
194.19
ND
ND
ND
ND
ND
121.18
ND
ND
ND
ND
ND
212.28
ND
ND
ND
ND
ND
122.17
ND
ND
ND
ND
ND
198.13
ND
ND
ND
ND
ND
T-MM5-3
194.19
ND
ND
ND
ND
ND
121.18
ND
ND
ND
ND
ND
212.28
ND
ND
ND
ND
ND
122.17
ND
ND
ND
ND
ND
198.13
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
. ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
•52.
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 11 of 19
2,4-Dinitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2,4-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,6-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Di-n-octyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a ,
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
bis(2-Ethylhexyl)-phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate. Ib/ton d
T-MM5-2
184.11
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
390.56
ND
ND
ND
ND
ND
390.54
ND
ND
ND
ND
ND
T-MM5-3
184.11
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
390.56
ND
ND
ND
ND
ND
390.54
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 12 of 19
Fluoranthene
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Hexachlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Hexachlorobutadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Hexachlorocyclopentadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
202.26
ND
ND
ND
ND
ND
166.21
ND
ND
ND
ND
ND
284.80
ND
ND
ND
ND
ND
260.76
ND
ND
ND
ND
ND
272.77
ND
ND
ND
ND
ND
T-MM5-3
202.26
ND
ND
ND
ND
ND
166.21
ND
ND
ND
ND
ND
284.80
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
272.77
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 13 of 19
Hexachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Hydroquinone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
lndeno(1 ,2,3-cd)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
sophorone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2-Methoxybenzenamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
236.74
ND
ND
ND
ND
ND
110.11
ND
ND
ND
ND
ND
290.34
ND
ND
ND
ND
ND
138.20
ND
ND
ND
ND
ND
123.15
ND
ND
ND
ND
ND
T-MM5-3
236.74
ND
ND
ND
ND
ND
110.11
ND
ND
ND
ND
ND
290.34
ND
ND
ND
ND
ND
138.20
ND
ND
ND
ND
ND
123.15
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 14 of 19
4,41-Methyl-bis(2-chloroaniline)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Methy I naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2-Methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3/4-Methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
267.16
ND
ND
ND
ND
ND
142.20
60
1.39E-02
2.36E+00
2.02E-03
1.36E-06
108.13
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
128.16
ND
ND
ND
ND
ND
T-MM5-3
267.16
ND
ND
ND
ND
ND
142.20
74
1.68E-02
2.84E+00
2.51 E-03
9.92E-07
108.13
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
128.16
39
8.85E-03
1.66E+00
1.32E-03
5.23E-07
Average
ND
ND
ND
ND
ND
67.0
1.54E-02
2.60E+00
2.26E-03
1.18E-06
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(19.5)
(4.43E-03)
(8.31 E-01)
(6.62E-04)
(2.61 E-07)
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 15 of 19
2-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Nitrobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
4-Nitrodiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
123.11
ND
ND
ND
ND
ND
199.20
ND
ND
ND
ND
ND
T-MM5-3
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
123.11
ND
ND
ND
ND
ND
199.20
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 16 of 19
2-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
N-Nitrosodimethylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
N-Nitrosodiphenylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period e
Emission Rate, Ib/ton d
N-Nitroso-di-n-propylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
139.11
ND
ND
ND
ND
ND
139.11
ND
ND
ND
ND
ND
74.08
ND
ND
ND
ND
ND
198.22
ND
ND
ND
ND
ND
130.19
ND
ND
ND
ND
ND
T-MM5-3
139.11
ND
ND
ND
ND
ND
139.11
ND
ND
ND
ND
ND
74.08
ND
ND
ND
ND
ND
198.22
ND
ND
ND
ND
ND
130.19
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 17 of 19
N-Nitrosomorpholine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,2'-Oxy bis(1 -chloropropane)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm e
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Pentachloronitrobenzene (PCNB)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Pentachlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton a
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
116.11
ND
ND
ND
ND
ND
171.07
ND
ND
ND
ND
ND
295.30
ND
ND
ND
ND
ND
266.35
ND
ND
ND
ND
ND
178.22
ND
ND
ND
ND
ND
T-MM5-3
116.11
ND
ND
ND
ND
ND
171.07
ND
ND
ND
ND
ND
295.30
ND
ND
ND
ND
ND
266.35
ND
ND
ND
ND
ND
178.22
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 18 of 19
'henol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
'yrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
o-Toluidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
1 ,2,4-Trichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4,5-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd "
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
T-MM5-2
94.11
ND
ND
ND
ND
ND
202.24
ND
ND
ND
ND
ND
107.15
ND
ND
ND
ND
ND
181.46
ND
ND
ND
ND
ND
197.46
ND
ND
ND
ND
ND
T-MMS-3
94.11
53
1.20E-02
3.08E+00
1.80E-03
7.11E-07
202.24
ND
ND
ND
ND
ND
107.15
ND
ND
ND
ND
ND
181.46
ND
ND
ND
ND
ND
197.46
ND
ND
ND
ND
ND
Average
(26.5)
(6.02E-03)
(1.54E+00)
(8.99E-04)
(3.55E-07)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 19 of 19
2,4,6-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Trifluralin
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
T-MM5-2
197.46
ND
ND
ND
ND
ND
335.29
ND
ND
ND
ND
ND
T-MMS-3
197.46
ND
ND
ND
ND
ND
335.29
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
a Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
c Pounds per test period.
Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
-------
42-
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 16
Y
AH
Pfaar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
AP1/2
©
Dn
An
Vm(std)
Vm(std)
PS
Bws
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Prtot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of Asphalt loaded per hour
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-MM5-4
7/26/98
0925-1343
1.000
1.85
29.31
179.672
91
-4.9
87
132.9
0.0
20.9
79.1
0.84
0.6108
240
0.252
none
0.000346
169.391
4.797
28.95
3.6
6.256
0.964
28.84
28.45
35.8
5.59
11,981
10,784
305
105.6
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 16
T-MMS-4
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
Acetophenone
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
4-Aminobiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period c
Aniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
154.21
ND
ND
ND
ND
154.21
ND
ND
ND
ND
120.15
ND
ND
ND
ND
169.22
ND
ND
ND
ND
93.12
ND
ND
ND
ND
178.22
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 16
T-MM5-4
Benzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period '
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period '
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period '
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period '
Benzole acid
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period '
Benzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period'
184.23
ND
ND
ND
ND
228.29
ND
ND
ND
ND
252.32
ND
ND
ND
ND
252.32
ND
ND
ND
ND
122.12
ND
ND
ND
ND
276.34
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 16
T-MM5-4
3enzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
Benzyl alcohol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test periodc
Biphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
4-Bromophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Butyl benzyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
252.30
ND
ND
ND
ND
252.30
ND
ND
ND
ND
108.13
ND
ND
ND
ND
154.20
ND
ND
ND
ND
249.11
ND
ND
ND
ND
312.36
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 16
T-MMS-4
Chloroacetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
4-Chloroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
bis(2-Chloroethoxy)-m ethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvdb
Emission Rate, Ib/test periodc
bis(2-Chloroethyl) ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
4-Chloro-3-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
2-Chloronaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
154.59
ND
ND
ND
ND
127.57
ND
ND
ND
ND
173.04
ND
ND
ND
ND
143.02
ND
ND
ND
ND
142.58
ND
ND
ND
ND
162.61
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of 16
T-MMS-4
-Chlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period °
Chlorophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
umene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd "
Emission Rate, Ib/test period c
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm"
Concentration, ppbvdb
Emission Rate, Ib/test period °
Dibenzofuran
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm"
Concentration, ppbvdb
Emission Rate, Ib/test period c
128.56
ND
ND
ND
ND
204.66
ND
ND
ND
ND
228.28
ND
ND
ND
ND
120.19
ND
ND
ND
ND
278.33
ND
ND
ND
ND
168.20
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page? of 16
T-MM5-4
1,2-Dibromo-3-chloropropane (DBCP)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
Di-n-butyl phthalate
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
1,2-Dichloro benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
1,3-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
1,4-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
3,3'-Dichlorobenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
236.36
ND
ND
ND
ND
278.34
ND
ND
ND
ND
147.01
ND
ND
ND
ND
147.01
ND
ND
ND
ND
147.01
ND
ND
ND
ND
253.13
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of 16
T-MM5-4
2,4-Dichlorophenol
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Diethyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
N-N-Diethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period °
3,3'-Dimethoxybenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Dimethyl phthalate
Molecular Weight, g/g-mofe
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
Dimethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period °
163.01
ND
ND
ND
ND
222.24
ND
ND
ND
ND
149.23
ND
ND
ND
ND
244.28
ND
ND
ND
ND
194.19
ND
ND
ND
ND
121.18
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
PageS of 16
T-MM5-4
,3'-Dimethylbenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
2,4-Dimethylphenol
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period °
4,6-Dinitro-2-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
2,4-Dinitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
2,4-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvdb
Emission Rate, Ib/test period c
2,6-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
212.28
ND
ND
ND
ND
122.17
ND
ND
ND
ND
198.13
ND
ND
ND
ND
184.11
ND
ND
ND
ND
182.14
ND
ND
ND
ND
182.14
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 10 of 16
T-MMS-4
'i-n-octyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
is(2-Ethylhexyl)-phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
;luoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Hexachlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
Hexachlorobutadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
390.56
ND
ND
ND
ND
390.54
ND
ND
ND
ND
202.26
ND
ND
ND
ND
166.21
ND
ND
ND
ND
284.80
ND
ND
ND
ND
154.21
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 11 of 16
T-MM5-4
Hexachlorocyclopentadiene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period'
Hexachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period '
Hydroquinone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period'
lndeno(1,2,3-cd)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm"
Concentration, ppbvd b
Emission Rate, Ib/test period '
Isophorone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period'
2-Methoxybenzenamine
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period'
272.77
ND
ND
ND
ND
236.74
ND
ND
ND
ND
110.11
ND
ND
ND
ND
290.34
ND
ND
ND
ND
138.20
ND
ND
ND
ND
123.15
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 12 of 16
T-MM5-4
,4'-Methyl-bis(2-chloroaniline)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
-Methylnaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
-Methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period °
3/4-Methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
2-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
267.16
ND
ND
ND
ND
142.20
ND
ND
ND
ND
108.13
ND
ND
ND
ND
108.13
ND
ND
ND
ND
128.16
ND
ND
ND
ND
138.12
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 13 of 16
T-MM5-4
3-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm*
Concentration, ppbvdb
Emission Rate, Ib/test periodc
4-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
Nitrobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test periodc
4-Nitrodiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
2-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period c
4-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period °
138.12
ND
ND
ND
ND
138.12
ND
ND
ND
ND
123.11
ND
ND
ND
ND
199.20
ND
ND
ND
ND
139.11
ND
ND
ND
ND
139.11
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 14 of 16
T-MM5-4
-Nitrosodimethylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
N-Nitrosodiphenylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
N-Nitroso-di-n-propylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
4-Nitrosomorpholine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
2,2'-Oxy bis(1 -chloropropane)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period c
Pentachloronitrobenzene (PCNB)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test periodc
74.08
ND
ND
ND
ND
198.22
ND
ND
ND
ND
130.19
ND
ND
ND
ND
116.11
ND
ND
ND
ND
171.07
ND
ND
ND
ND
295.30
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 15 of 16
T-MMS-4
Pentachlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test period'
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period '
Phenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm"
Concentration, ppbvdb
Emission Rate, Ib/test period'
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvdb
Emission Rate, Ib/test periodc
o-Toluidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test period '
1,2,4-Trichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test periodc
266.35
ND
ND
ND
ND
178.22
ND
ND
ND
ND
94.11
ND
ND
ND
ND
202.24
ND
ND
ND
ND
107.15
ND
ND
ND
ND
181.46
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 16 of 16
T-MMS-4
2,4,5-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test periodc
2,4,6-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscma
Concentration, ppbvd b
Emission Rate, Ib/test period c
Trifluralin
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvdb
Emission Rate, Ib/test periodc
197.46
ND
ND
ND
ND
197.46
ND
ND
ND
ND
335.29
ND
ND
ND
ND
Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
c Pounds per test period.
ND Not Detectable - Results are below target analyte detection limit.
-------
-------
-------
Run Number
Run Date
Run Time
Net Run Time
Pbar Barometric Pressure, inches Hg
y Dry Gas Meter calibration factor
Vm Sample Volume, liters
Tm Avg. Meter temperature, °R
AH Pressure diff. of meter, in. H2O
Vm(std) Sample Volume, dry std. liters
Qs Volumetric Flow Rate, dscfm
Tons of asphalt per test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 11
T-V-1-1
7/24/98
0829-0849
20
29.35
0.967
15.600
532
1.20
14.738
10,295
169.9
T-V-1-2
7/24/98
0910-0945
35
29.35
0.967
20.119
537
1.10
18.821
10,295
262.3
T-V-1-3
7/24/98
1058-1133
34.9
29.35
0.9995
20.160
539.7
1.73
19.423
10,295
276.9
TOTAL
89.9
52.982
10,295
709.1
Acetone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, \ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Allyl chloride
Molecular Weight, g/g-mole
Target Catch, (ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
58.08 58.08
0.137 {0.243}
58.08 58.08
0.666 {1.046}
{1.97E-02}
{8.18}
{1.14E-03}
{1.61E-06}
53.06
ND
76.53
ND
53.06
ND
76.53
ND
53.06
ND
76.53
ND
53.06
ND
ND
ND
ND
ND
76.53
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
Run Number T-V-1-1 T-V-1-2 T-V-1-3 TOTAL
Benzene
Molecular Weight, g/g-mole 78.11 78.11 78.11 78.11
Target Catch, ug 0.106 0.129 0.516 0.751
Concentration, mg/dscm 1.42E-02
Concentration, ppbvd 4.37
Emission Rate, Ib/test period 8.19E-04
Emission Rate, Ib/ton 1.16E-06
Bromodichloromethane
Molecular Weight, g/g-mole 163.82 163.82 163.82 163.82
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromoform
Molecular Weight, g/g-mole 252.77 252.77 252.77 252.77
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromomethane
Molecular Weight, g/g-mole 94.95 94.95 94.95 94.95
Target Catch, ug 0.056 {0.075} {0.114} {0.245}
Concentration, mg/dscm (4.62E-03 }
Concentration, ppbvd {1-17}
Emission Rate, Ib/test period {2.67E-04}
Emission Rate, Ib/ton {3.77E-07}
1,3-Butadiene
Molecular Weight, g/g-mole 58.08 58.08 58.08 58.08
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Run Number
2-Butanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon disulfide
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon tetrachloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
T-V-1-1
72.10
0.061
153.84
ND
112.56
ND
64.52
ND
T-V-1-2
72.10
ND
153.84
ND
112.56
ND
64.52
ND
T-V-1-3
72.10
0.509
153.84
ND
112.56
ND
64.52
{0.007}
TOTAL
72.10
(0.570)
(1.08E-02)
(3.59)
(6.22E-04)
(8.77E-07)
76.14
{0.015}
76.14 76.14 76.14
{0.017} {0.018} {0.050}
{9.44E-04}
{0.298}
{5.45E-05}
{7.69E-08}
153.84
ND
ND
ND
ND
ND
112.56
ND
ND
ND
ND
ND
64.52
(0.007)
(1.32E-04)
(0.0493)
{7.63E-06}
(1.08E-08)
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
Run Number T-V-1-1 T-V-1-2 T-V-1-3 TOTAL
Chloroform
Molecular Weight, g/g-mole 119.39 119.39 119.39 119.39
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chloromethane
Molecular Weight, g/g-mole 50.49 50.49 50.49 50.49
Target Catch, ug 0.075 0.080 0.083 0.238
Concentration, mg/dscm 4.49E-03
Concentration, ppbvd 2.14
Emission Rate, Ib/test period 2.60E-04
Emission Rate, Ib/ton 3.66E-07
Cumene
Molecular Weight, g/g-mole 120.19 120.19 120.19 120.19
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Dibromochloromethane
Molecular Weight, g/g-mole 208.27 208.27 208.27 208.27
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dibromoethane
Molecular Weight, g/g-mole 187.88 187.88 187.88 187.88
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
Run Number T-V-1-1 T-V-1-2 T-V-1-3 TOTAL
1,1-Dichloroethane
Molecular Weight, g/g-mole , 98.97 98.97 98.97 98.97
Target Catch, ng ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dichloroethane
Molecular Weight, g/g-mole 98.96 98.96 98.96 98.96
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1 -Dich loroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
Run Number T-V-1-1 T-V-1-2 T-V-1-3 TOTAL
1,2-DichIoropropane
Molecular Weight, g/g-mole 112.99 112.99 112.99 112.99
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Epoxybutane
Molecular Weight, g/g-mole 72.12 72.12 72.12 72.12
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Ethyl acrylate
Molecular Weight, g/g-mole 100.11 100.11 100.11 100.11
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton . ND
-------
Run Number
Ethylbenzene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
n-Hexane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Hexanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
lodomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Isooctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
T-V-1-1
100.16
ND
141.95
ND
114.22
ND
T-V-1-2
100.16
ND
141.95
ND
114.22
ND
T-V-1-3
100.16
ND
141.95
ND
114.22
ND
TOTAL
106.16
0.137
106.16 106.16 106.16
0.128 0.105 0.370
6.98E-03
1.58
4.04E-04
5.69E-07
86.17
{0.128}
86.17 86.17 86.17
{0.148} {0.112} {0.388}
{7.32E-03}
{2.04}
{4.23E-04}
{5.97E-07}
100.16
ND
ND
ND
ND
ND
141.95
ND
ND
ND
ND
ND
114.22
ND
ND
ND
ND
ND
-------
Run Number
Methyl methacrylate
Molecular Weight, g/g-mole
Target Catch, (ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylene chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
4-Methyl-2-pentanone
Molecular Weight, g/g-mole
Target Catch, |ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
T-V-1-1
MTBE
Styrene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
86.09
ND
100.16
ND
88.15
ND
104.14
ND
T-V-1-2
86.09
ND
100.16
ND
88.15
ND
104.14
ND
T-V-1-3
86.09
ND
100.16
ND
88.15
{0.019}
104.14
ND
TOTAL
86.09
ND
ND
ND
ND
ND
84.94
0.456
84.94 84.94
0.326 {0.084}
84.94
{0.866}
{1.63E-02}
{4.63E+00}
{9.45E-04}
{1.33E-06}
100.16
ND
ND
ND
ND
ND
88.15
(0.019)
(3.59E-04)
(9.79E-02)
(2.07E-05)
(2.92E-08)
104.14
ND
ND
ND
ND
ND
-------
Run Number
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tetrachloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Toluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,1 -Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,2-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
T-V-1-1
167.86
ND
133.42
ND
T-V-1-2
167.86
ND
133.42
ND
T-V-1-3
167.86
ND
133.42
ND
TOTAL
167.86
ND
ND
ND
ND
ND
165.85
ND
92.13
{0.380}
133.42
ND
165.85 -165.85 165.85
0.054 {0.038} (0.092)
(1.74E-03)
(0.252)
(l.OOE-04)
(1.42E-07)
92.13 92.13 92.13
0.436 {0.460} 1.1-276}
{2.41E-02}
{6.29}
{1.39E-03}
{1.96E-06}
133.42 133.42 133.42
ND ND ND
ND
ND
ND
ND
133.42
ND
ND
ND
ND
ND
-------
Run Number
Trichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trichlorofluoromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl acetate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl bromide
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
T-V-1-1
131.40
ND
137.38
{0.008}
86.09
ND
106.96
ND
62.50
ND
T-V-1-2
131.40
ND
137.38
ND
86.09
ND
106.96
ND
62.50
ND
T-V-1-3
131.40
ND
137.38
{0.009}
86.09
ND
106.96
ND
62.50
ND
TOTAL
131.40
ND
ND
ND
ND
ND
137.38
(0.017)
(3.21E-04)
(0.0562)
(1.85E-05)
(2.61E-08)
86.09
ND
ND
ND
ND
ND
106.96
ND
ND
ND
ND
ND
62.50
ND
ND
ND
ND
ND
C/7
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Number T-V-1-1 TW-1-2 T-V-1-3 TOTAL
m-/p-Xylene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16
Target Catch, ug 0.720 {0.678} 0.758 {2.156}
Concentration, mg/dscm {4.07E-02}
Concentration, ppbvd {9.22}
Emission Rate, Ib/test period {2.35E-03}
Emission Rate, Ib/ton {3.32E-06}
o-Xylene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16
Target Catch, ug 0.251 0.235 0.181 0.667
Concentration, mg/dscm 1.26E-02
Concentration, ppbvd 2.85
Emission Rate, Ib/test period 7.27E-04
Emission Rate, Ib/ton 1.03E-06
ND indicates compound was not detected. A zero was used in the total and the value enclosed in parentheses ().
Estimated values and totals using estimated values are enclosed in brackets {}.
-------
-------
-------
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 11
Run Number
Run Date
Run Time
Net Run Time
Pbar Barometric Pressure, inches Hg
y Dry Gas Meter calibration factor
Vm Sample Volume, liters
Tm Avg. Meter temperature, °R
AH Pressure diff. of meter, in. H2O
Vm(Std) Sample Volume, dry std. liters
Qs Volumetric Flow Rate, dscfin
Tons of asphalt per test period
Acetone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Allyl chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
7/25/98
0802-0827
25.3
29.33
1.0392
19.70
532
1.6
19.986
9,663
177.8
58.08
0.193
53.06
ND
76.53
ND
T-V-2-2
7/25/98
0859-0924
25
29.33
1.0392
21.43
541
1.6
21.392
9,663
182.6
58.08
0.232
53.06
ND
76.53
ND
T-V-2-3
7/25/98
0951-1023
32
29.33
1.0392
24.11
554
1.6
23.495
9,663
162.9
58.08
0.137
53.06
ND
76.53
ND
T-V-2-4
7/25/98
1102-1122
20
29.33
1.0392
18.39
559
1.8
17.768
9,663
62.8
58.08
0.296
53.06
ND
76.53
ND
TOTAL
102.3
82.641
9,663
586.1
58.08
0.858
1.04E-02
4,30
6.41E-04
1.09E-06
53.06
ND
ND
ND
ND
ND
76.53
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
Run Number
Benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromodichloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromoform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,3-Butadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
TOTAL
78.11 78.11 78.11
0.263 0.238 0.156
163.82 163.82 163.82
ND ND ND
252.77 252.77 252.77
ND ND ND
94.95 94.95 94.95
{0.036} {0.035} {0.035}
58.08 58.08 58.08
ND ND ND
78.11 78.11
0.108 0.765
9.26E-03
2.85
5.71E-04
9.75E-07
163.82 163.82
ND ND
ND
ND
ND
ND
252.77 252.77
ND ND
ND
ND
ND
ND
94.95 94.95
ND (0.106)
(1.28E-03)
(0.325)
(7.92E-05)
(1.35E-07)
58.08 58.08
ND ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
Run Number
2-Butanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon disulfide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon tetrachloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chlorobenzene
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
72.10
ND
76.14
0.104
153.84
ND
112.56
ND
64.52
ND
T-V-2-2
72.10
0.312
76.14
0.093
153.84
ND
112.56
ND
64.52
ND
T-V-2-3
72.10
0.161
76.14
{0.026}
153.84
ND
112.56
ND
64.52
ND
T-V-2-4
TOTAL
72.10
0.342
76.14
{0.044}
153.84
ND
112.56
ND
64.52
ND
72.10
(0.815)
(9.86E-03)
(3.29)
(6.09E-04)
(1.04E-06)
76.14
{0.267}
{3.23E-03}
{1.021}
{1.99E-04}
{3.40E-07}
153.84
ND
ND
ND
ND
ND
112.56
ND
ND
ND
ND
ND
6452
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
Run Number
Chloroform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dibromochloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Dibromoethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
119.39
ND
50.49
0.056
120.19
ND
208.27
ND
187.88
ND
T-V-2-2
119.39
ND
50.49
0.092
120.19
ND
208.27
ND
187.88
ND
T-V-2-3
119.39
ND
50.49
{0.042}
120.19
ND
208.27
ND
187.88
ND
T-V-2-4
TOTAL
119.39
ND
50.49
{0.040}
120.19
ND
208.27
ND
187.88
ND
119.39
ND
ND
ND
ND
ND
50.49
{0.230}
{2.78E-03}
{1.326}
{1.72E-04}
{2.93E-07}
120.19
ND
ND
ND
ND
ND
208.27
ND
ND
ND
ND
ND
187.88
ND
ND
ND
ND
ND
12,
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
Run Number
1,1-DichIoroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Dichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1-Dichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
cis-l,2-Dichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
trans-l,2-Dichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
TOTAL
98.97
ND
98.96
ND
96.95
ND
96.95
ND
96.95
ND
98.97 98.97 98.97 98.97
ND ND ND ND
ND
ND
ND
ND
98.96 98.96 98.96 98.96
ND ND ND ND
ND
ND
ND
ND
96.95 96.95 96.95 96.95
ND ND ND ND
ND
ND
ND
ND
96.95 96.95 96.95 96.95
ND ND ND ND
ND
ND
ND
ND
96.95 96.95 96.95 96.95
ND ND ND ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
Run Number
1,2-Dichloropropane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
cis-l,3-Dichloropropene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Epoxy butane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ethyl acrylate
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
T-V-2-2
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
T-V-2-3
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
T-V-2-4
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
TOTAL
112.99
ND
ND
ND
ND
ND
110.98
ND
ND
ND
ND
ND
110.98
ND
ND
ND
ND
ND
72.12
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
Run Number
Ethylbenzene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
n-Hexane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Hexanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
lodomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Isooctane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
TOTAL
106.16
{0.015}
86.17
0.266
100.16
ND
141.95
ND
114.22
{0.029}
106.16 106.16 106.16 106.16
0.069 0.050 {0.027} {0.161}
{1.95E-03}
{0.441}
{1.20E-04}
{2.05E-07}
86.17 86.17 86.17 86.17
{0.176} {0.145} {0.083} {0.670}
{g.HE-03}
{2.26}
{5.00E-04}
{8.54E-07}
100.16 100.16 100.16 100.16
ND ND ND ND
ND
ND
ND
ND
141.95 141.95 141.95 141.95
ND ND ND ND
ND
ND
ND
ND
114.22 114.22 114.22 114.22
{0.016} {0.019} {0.021} {0.085}
{1.03E-03}
{0.217}
{6.35E-05}
{1.08E-07}
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SVV-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
Run Number
Methyl methacrylate
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylene chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
4-Methyl-2-pentanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
MTBE
Styrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
TOTAL
86.09 86.09 86.09
ND ND ND
84.94 84.94 84.94
0.488 ND 0.081
100.16 100.16 100.16
ND ND ND
88.15 88.15 88.15
{0.033} {0.022} {0.039}
104.14 104.14 104.14
ND 0.052 {0.038}
86.09 86.09
ND ND
ND
ND
ND
ND
84.94 84.94
0.064 (0.633)
(7.66E-03)
(2.17)
{4.73E-04}
(8.07E-07)
100.16 100.16
ND ND
ND
ND
ND
ND
88.15 88.15
{0.036} {0.130}
{1.57E-03}
{0.429}
{9.71E-05}
{1.66E-07}
104.14 104.14
{0.017} (0.107)
(1.29E-03)
(0.299)
(7.99E-05)
(1.36E-07)
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
Run Number
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tetrachloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Toluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,1 -Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,2-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, fig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
IQIAL
167.86 167.86 167.86
ND ND ND
165.85 165.85 165.85
{0.017} {0.035} {0.035}
92.13 92.13 92.13
0.132 0.247 0.218
133.42 133.42 133.42
ND ND ND
133.42 133.42 133.42
ND ND ND
167.86 167.86
ND ND
ND
ND
ND
ND
165.85 165.85
{0.031} {0.118}
{1.43E-03}
{0.207}
{8.81E-05}
{1.50E-07}
92.13 92.13
0.144 0.741
8.97E-03
2.34
5.53E-04
9.44E-07
133.42 133.42
ND ND
ND
ND
ND
ND
133.42 133.42
ND ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
Run Number
Trichloroethene
Molecular Weight, g/g-mole
Target Catch, fig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trichlorofluoromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl acetate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl bromide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-2-1
T-V-2-2
T-V-2-3
T-V-2-4
TOTAL
131.40 131.40
ND ND
137.38 137.38
{0.014} {0.011}
86.09 86.09
ND ND
106.96 106.96
ND ND
62.50 62.50
ND ND
131.40 131.40 131.40
ND ND ND
ND
ND
ND
ND
137.38 137.38 137.38
ND {0.009} (0.034)
(4.11E-04)
(0.0720)
(2.54E-05)
(4.33E-08)
86.09 86.09 86.09
ND ND ND
ND
ND
ND
ND
106.96 106.96 106.96
ND ND ND
ND
ND
ND
ND
62.50 62.50 62.50
ND ND ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Number T-V-2-1 T-V-2-2 T-V-2-3 T-V-2-4 TOTAL
m-/p-Xylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
o-Xylene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16 106.16
Target Catch, ug {0.012} 0.119 0.088 {0.042} {0.261}
Concentration, mg/dscm {3.16E-03}
Concentration, ppbvd {0.716}
Emission Rate, Ib/test period {1.95E-04}
Emission Rate, Ib/ton {3.33E-07}
ND indicates compound was not detected. A zero was used in the total and the value enclosed in parentheses ().
Estimated values and totals using estimated values are enclosed in brackets {}.
106.16 106.16
{0.078} 0.428
106.16 106.16 106.16
0.255 0.149 {0.910}
{1.10E-02}
{2.50}
{6.80E-04}
{1.16E-06}
-------
-------
-------
-------
Run Number
Run Date
Run Time
Net Run Time
Pbar Barometric Pressure, inches Hg
y Dry Gas Meter calibration factor
Vm Sample Volume, liters
Tm Avg. Meter temperature, °R
AH Pressure diff. of meter, in. H2O
m(std) Sample Volume, dry std. liters
Qs Volumetric Flow Rate, dscfm
Tons of asphalt per test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 11
T-V-3-1
7/27/98
0917-0947
30.0
29.23
1.0392
22.380
550
1.6
21.888
9,972
258.4
T-V-3-2
7/27/98
1009-1034
25.0
29.23
1.0392
20.480
560
1.7
19.692
9,972
292.2
T-V-3-3
7/27/98
1053-1123
30.0
29.23
1.0392
20.410
569
1.6
19.305
9,972
273.9
Total
85.0
60.885
9,972
824.5
Acetone
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ally! chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
58.08 58.08
0.183 ND
58.08 58.08
ND (0.183)
(3.01E-03)
(1.24)
(1.59E-04)
(1.93E-07)
53.06
ND
76.53
ND
53.06
ND
76.53
ND
53.06
ND
76.53
ND
53.06
ND
ND
ND
ND
ND
76.53
ND
ND
ND
ND
ND
-------
Run Number
Benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromodichloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromoform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,3-Butadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
T-V-3-1
78.11
0.096
163.82
ND
252.77
ND
58.08
ND
T-V-3-2
78.11
0.131
163.82
ND
252.77
ND
58.08
ND
T-V-3-3
78.11
0.129
163.82
ND
252.77
ND
58.08
ND
Total
78.11
0.356
5.85E-03
1.80
3.09E-04
3.75E-07
163.82
ND
ND
ND
ND
ND
252.77
ND
ND
ND
ND
ND
94.95
{0.005}
94.95 94.95 94.95
ND ND (0.005)
(8.21E-05)
(0.0208)
(4.35E-06)
(5.27E-09)
58.08
ND
ND
ND
ND
ND
-------
Run Number
2-Butanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon disulfide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon tetrachloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
T-V-3-1
112.56
ND
64.52
ND
T-V-3-2
T-V-3-3
112.56
ND
64.52
ND
112.56
ND
64.52
ND
TotaJ
72.10
0.166
76.14
{0.015}
153.84
ND
72.10 72.10 72.10
ND ND (0.166)
(2.73E-03)
(0.910)
(1.44E-04)
(1.75E-07)
76.14 76.14 76.14
{0.017} {0.020} {0.052}
{8.54E-04}
{0.270}
{4.52E-05}
{5.48E-08}
153.84 153.84 153.84
ND ND ND
ND
ND
ND
ND
112.56
ND
ND
ND
ND
ND
64.52
ND
ND
ND
ND
ND
-------
Run Number
Chloroform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dibromochloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Dibromoethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
T-V-3-1
119.39
ND
50.49
{0.030}
120.19
ND
208.27
ND
187.88
ND
T-V-3-2
119.39
ND
50.49
ND
120.19
ND
208.27
ND
187.88
ND
T-V-3-3
119.39
ND
50.49
{0.043}
120.19
ND
208.27
ND
187.88
ND
Total
119.39
ND
ND
ND
ND
ND
50.49
(0.073)
(1.20E-03)
(0.571)
(6.35E-05)
(7.70E-08)
120.19
ND
ND
ND
ND
ND
208.27
ND
ND
ND
ND
ND
187.88
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
Run Number T-V-3-1 T-V-3-2 T-V-3-3 Total
1,1 -Dich loroethane
Molecular Weight, g/g-mole 98.97 98.97 98.97 98.97
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-DichIoroethane
Molecular Weight, g/g-mole 98.96 98.96 98.96 98.96
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND NE
Concentration, mg/dscm NE
Concentration, ppbvd NE
Emission Rate, Ib/test period NE
Emission Rate, Ib/ton NE
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
Run Number T-V-3-1 T-V-3-2 T-V-3-3 Total
1,2-Dichloropropane
Molecular Weight, g/g-mole 112.99 112.99 112.99 112.99
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,3-Dich!oropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Epoxybutane
Molecular Weight, g/g-mole 72.12 72.12 72.12 72.12
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Ethyl acrylate
Molecular Weight, g/g-mole 100.11 100.11 100.11 100.11
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
Run Number T-V-3-1 T-V-3-2 T-V-3-3
Ethylbenzene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16
Target Catch, ug 0.075 0.065 0.071 0.211
Concentration, mg/dscm 3.47E-03
Concentration, ppbvd 0.785
Emission Rate, Ib/test period 1.83E-04
Emission Rate, Ib/ton 2.22E-07
n-Hexane
Molecular Weight, g/g-mole 86.17 86.17 86.17 86.17
Target Catch, ug {0.107} {0.135} {0.142} {0.384}
Concentration, mg/dscm {6.31E-03}
Concentration, ppbvd {1.76}
Emission Rate, Ib/test period {3.34E-04}
Emission Rate, Ib/ton {4.05E-07}
2-Hexanone
Molecular Weight, g/g-mole 100.16 100.16 100.16 100.16
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
lodomethane
Molecular Weight, g/g-mole 141.95 141.95 141.95 141.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Isooctane
Molecular Weight, g/g-mole 114.22 114.22 114.22 114.22
Target Catch, ug {0.012} ND ND (0.012)
Concentration, mg/dscm (1.97E-04)
Concentration, ppbvd (0.0415)
Emission Rate, Ib/test period (1.04E-05)
Emission Rate, Ib/ton (1.27E-08)
-------
Run Number
Methyl methacrylate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylene chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
4-Methyl-2-pentanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
T-V-3-1
MTBE
Styrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
T-V-3-2
T-V-3-3
86.09
ND
84.94
0.508
100.16
ND
88.15
{0.028}
104.14
{0.029}
86.09 86.09 86.09
ND ND ND
ND
ND
ND
ND
84.94 84.94 84.94
0.828 {0.049} {1.385}
{2.27E-02}
{6.44}
{1.20E-03}
{1.46E-06}
100.16 100.16 100.16
ND ND ND
ND
ND
ND
ND
88.15 88.15 88.15
{0.022} {0.015} {0.065}
{1.07E-03}
{0.291}
{5.65E-05}
{6.85E-08}
104.14 104.14 104.14
{0.036} {0.037} {0.102}
{1.68E-03}
{0.387}
{8.87E-05}
{1.08E-07}
-------
Run Number
1,1,2,2-TetrachIoroethane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tetrachloroethene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Toluene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,1-TrichIoroethane
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,2-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
T-V-3-1
167.86
ND
92.13
0.212
133.42
ND
133.42
ND
T-V-3-2
167.86
ND
92.13
0.200
133.42
ND
133.42
ND
T-V-3-3
167.86
ND
92.13
0.217
133.42
ND
133.42
ND
Total
167.86
ND
ND
ND
ND
ND
165.85 165.85
{0.023} {0.015}
165.85 165.85
{0.028} {0.066}
{1.08E-03}
{0.157}
{5.74E-05}
{6.96E-08}
92.13
0.629
1.03E-02
2.70
5.47E-04
6.63E-07
133.42
ND
ND
ND
ND
ND
133.42
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
Run Number T-V-3-1 T-V-3-2 T-V-3-3 Total
Trichloroethene
Molecular Weight, g/g-mole 131.40 131.40 131.40 131.40
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Trichlorofluoromethane
Molecular Weight, g/g-mole 137.38 137.38 137.38 137.38
Target Catch, ug {0.011} {0.011} {0.006} {0.028}
Concentration, mg/dscm {4.60E-04}
Concentration, ppbvd {0.0805}
Emission Rate, Ib/test period {2.43E-05}
Emission Rate, Ib/ton {2.95E-08}
Vinyl acetate
Molecular Weight, g/g-mole 86.09 86.09 86.09 86.09
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl bromide
Molecular Weight, g/g-mole 106.96 106.96 106.96 106.96
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl chloride
Molecular Weight, g/g-mole 62.50 62.50 62.50 62.50
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Normal Operations, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Number T-V-3-1 T-V-3-2 T-V-3-3 Total
m-/p-Xy!ene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16
Target Catch, ug 0.335 0.314 0.378 1.027
Concentration, mg/dscm 1.69E-02
Concentration, ppbvd 3.82
Emission Rate, Ib/test period 8.93E-04
Emission Rate, Ib/ton 1.08E-06
o-Xylene
Molecular Weight, g/g-mole 106.16 106.16 106.16 106.16
Target Catch, ug 0.131 0.118 0.124 0.373
Concentration, mg/dscm 6.13 E-03
Concentration, ppbvd 1.39
Emission Rate, Ib/test period 3.24E-04
Emission Rate, Ib/ton 3.93E-07
ND indicates compound was not detected. A zero was used in the total and the value enclosed in parentheses ().
Estimatsd values and totals using estimated values are enclosed in brackets {}.
-------
-------
-------
-------
Run Number
Run Date
Run Time
Net Run Time
Pbit Barometric Pressure, inches Hg
y Dry Gas Meter calibration factor
Vm Sample Volume, liters
Tm Avg. Meter temperature, °R
AH Pressure diff. of meter, in. H2O
Vm(std) Sample Volume, dry std. liters
Qs Volumetric Flow Rate, dscfin
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of9
T-V-4-1 T-V-4-2 T-V-4-4 * TOTAL
7/26/98 7/26/98 7/26/98
0925-0950 1025-1050 1255-1320
25.0 25.0 25.0 75.0
29.31 29.31 29.31
1.0392 1.0392 1.0392
21.600 20.690 23.030
544 552 564
1.7 1.6 1.8
21.445 20.239 22.035 63.719
10,784 10,784 10,784 10,784
Acetone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Allyl chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
58.08 58.08
0.238 {0.069}
53.06 53.06
ND ND
58.08 58.08
ND (0.307)
(4.82E-03)
(2.00)
(2.43E-04)
53.06 53.06
ND ND
ND
ND
ND
76.53
ND
78.11
{0.101}
76.53
ND
78.11
{0.049}
76.53
ND
78.11
0.071
76.53
ND
ND
ND
ND
78.11
{0.221}
{3.47E-03}
{1.07}
{1.75E-04}
Rl
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Bromodichloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Bromoform
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Bromomethane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
1,3-Butadiene
Molecular Weight, g/g-mole
Target Catch, \ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
2-Butanone
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Carbon disulfide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 2 of9
T-V-4-1
163.82
ND
252.77
ND
58.08
ND
72.10
0.051
76.14
ND
T-V-4-2
163.82
ND
252.77
ND
58.08
ND
72.10
ND
76.14
ND
T-V-4-4 * IQIAL
163.82
ND
252.77
ND
58.08
ND
72.10
ND
76.14
ND
163.82
ND
ND
ND
ND
252.77
ND
ND
ND
ND
94.95
{0.013}
94.95
{0.010}
94.95
ND
94.95
(0.023)
(3.61E-04)
(0.0915)
(1.82E-05)
58.08
ND
ND
ND
ND
72.10
(0.051)
(8.00E-04)
(0.267)
(4.04E-05)
76.14
ND
ND
ND
ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Carbon tetrachloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Chlorobenzene
Molecular Weight, g/g-mole
Target Catch, \ig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Chloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Chloroform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Chloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 3 of9
T-V-4-1
153.84
ND
112.56
ND
64.52
ND
119.39
{0.006}
50.49
{0.030}
120.19
ND
T-V-4-2
153.84
ND
112.56
ND
64.52
ND
119.39
ND
50.49
{0.020}
120.19
ND
T-V-4-4 * TOTAL
153.84
ND
112.56
ND
64.52
ND
119.39
ND
50.49
ND
120.19
ND
153.84
ND
ND
ND
ND
112.56
ND
ND
ND
ND
64.52
ND
ND
ND
ND
119.39
(0.006)
(9.42E-05)
(0.0190)
(4.76E-06)
50.49
(0.050)
(7.85E-04)
(0.374)
(3.96E-05)
120.19
ND
ND
ND
ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 4 of 9
Run Number T-V-4-1 T-V-4-2 T-V-4-4 * TOTAL
Dibromochloromethane
Molecular Weight, g/g-mole 208.27 208.27 208.27 208.27
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1 ,2-Dibromoethane
Molecular Weight, g/g-mole 187.88 187.88 187.88 187.88
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1,1-Dichloroethane
Molecular Weight, g/g-mole 98.97 98.97 98.97 98.97
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1,2-Dichloroethane
Molecular Weight, g/g-mole 98.96 98.96 98.96 98.96
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1,1-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
cis-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 5 of 9
Run Number T-V-4-1 T-V-4-2 T-V-4-4 * IQIAL
trans-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95 96.95 96.95 96.95
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1,2-Dichloropropane
Molecular Weight, g/g-mole 112.99 112.99 112.99 112.99
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
cis-1 ,3-Dichloropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98 110.98 110.98 110.98
Target Catch, ug ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
1,2-Epoxy butane
Molecular Weight, g/g-mole 72.12 72.12 72.12 72.12
Target Catch, jig ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Ethyl acrylate
Molecular Weight, g/g-mole 100.11 100.11 100.11 100.11
Target Catch, jig ND ND ND ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Ethylbenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
n-Hexane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
2-Hexanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
lodomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Isooctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Methyl methacrylate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 6 of9
T-V-4-1
141.95
ND
114.22
{0.022}
86.09
ND
T-V-4-2
141.95
ND
114.22
ND
86.09
ND
T-V-4-4 * TOTAL
106.16
{0.019}
86.17
{0.039}
100.16
ND
106.16 106.16 106.16
ND {0.022} (0.041)
(6.43E-04)
(0.146)
(3.25E-05)
86.17 86.17 86.17
{0.009} {0.041} {0.089}
{1.40E-03}
{0.390}
{7.05E-05}
100.16 100.16 100.16
ND ND ND
ND
ND
ND
141.95
ND
114.22
{0.010}
86.09
ND
141.95
ND
ND
ND
ND
114.22
(0.032)
(5.02E-04)
(0.106)
(2.54E-05)
86.09
ND
ND
ND
ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Methylene chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
4-Methyl-2-pentanone
Molecular Weight, g/g-mole
Target Catch, fig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
MTBE
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Styrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Tetrachloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 7 of9
T-V-4-1
84.94
{0.365}
100.16
ND
165.85
{0.016}
T-V-4-2
84.94
{2.340}
100.16
ND
165.85
ND
T-V-4-4 * TOTAL
84.94
{0.009}
100.16
ND
165.85
{0.022}
84.94
{2.714}
{4.26E-02}
{12.1}
{2.15E-03}
100.16
ND
ND
ND
ND
88.15
{0.128}
104.14
{0.027}
167.86
ND
88.15 88.15 88.15
ND {0.037} (0.165)
(2.59E-03)
(0.707)
(1.31E-04)
104.14 104.14 104.14
{0.004} {0.009} {0.040}
{6.28E-04}
{0.145}
{3.17E-05}
167.86 167.86 167.86
ND ND ND
ND
ND
ND
165.85
(0.038)
(5.96E-04)
(0.0865)
(3.01E-05)
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Toluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
1,1,1-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
1,1,2-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Trichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Trichlorofluoromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Vinyl acetate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 8 of9
T-V-4-1
92.13
{0.149}
133.42
{0.012}
133.42
ND
131.40
{0.001}
137.38
{0.024}
86.09
ND
T-V-4-2
92.13
{0.017}
133.42
ND
133.42
ND
131.40
ND
137.38
{0.003}
86.09
ND
T-V-4-4 * TOTAL
92.13
0.158
133.42
ND
133.42
ND
131.40
ND
137.38
ND
86.09
ND
92.13
{0.324}
{5.08E-03}
{1.33}
{2.57E-04}
133.42
(0.012)
(1.88E-04)
(0.0340)
(9.51E-06)
133.42
ND
ND
ND
ND
131.40
(0.001)
(1.57E-05)
(0.00287)
(7.93E-07)
137.38
(0.027)
(4.24E-04)
(0.0742)
(2.14E-05)
86.09
ND
ND
ND
ND
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Run Number
Vinyl bromide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Vinyl chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
m-/p-Xylene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
o-Xylene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Background Condition, Tunnel Exhaust Duct
Asphalt Plant C - California
Page 9 of9
T-V-4-1
106.96
ND
62.50
ND
106.16
{0.058}
106.16
{0.025}
T-V-4-2
106.96
ND
62.50
ND
106.16
ND
106.16
ND
T-V-4-4 *
106.96
ND
62.50
ND
106.16
{0.057}
106.16
{0.024}
TOTAL
106.96
ND
ND
ND
ND
62.50
ND
ND
ND
ND
106.16
(0.115)
(1.80E-03)
(0.409)
(9.11E-05)
106.16
(0.049)
(7.69E-04)
(0.174)
(3.88E-05)
ND indicates compound was not detected. A zero was used hi the total and the value enclosed in parentheses ()•
Estimated values and totals using estimated values are enclosed in brackets {}.
* Note: Set T-V-4-4 includes analytical results for the tenax tube only; the tenax/charcoal tube was broken and could not be
analyzed.
-------
Summary of Stack Gas Parameters and Test Results
SW-846 Method 0010 - Flow Rate Only
Tunnel Exhaust Duct
Asphalt Plant C - California
Page 1 of 1
1
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
AP1/2
©
Dn
An
Vm(std)
Vm(std)
PS
BWS
Bws(sat)
Vwstd
1-Bws
Md
Ms
Vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Moisture (at saturation), % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
T-MM5-1
7/24/98
0720-1256
1.000
1.62
29.35
165.345
74
-4.7
81
254.4
0.0
20.9
79.1
0.84
0.5799
240
0.252
0.000346
160.904
4.556
29.00
6.9
3.7
11.975
0.963
28.84
28.44
33.7
5.59
11,301
10,295
292
105.0
\00
-------
APPENDIX A.2
SED TEST RESULTS
lo\
-------
Summary of Stack Gas Parameters and Test Results
PM and MCEM - EPA Method 315
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 2
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,0
CO2
02
N2
CP
A.J/2
Ap
0
Dn
An
Vm(std)
Vm(std)
PS
Bm
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUNTIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), lb/lb«mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
S-M315-1
7/24/98
1141-1243
1.007
1.69
29.28
43.141
94
-0.25
256
157.7
0.0
20.9
79.1
0.84
0.3375
60
0.380
336.7
0.000788
40.646
1.151
29.26
15.4
7.423
0.846
28.84
27.16
23.0
0.545
753
459
13.0
102.3
S-M315-2
7/25/98
1015-1117
1.007
1.80
29.26
43.882
101
-0.25
270
283.1
0.0
20.9
79.1
0.84
0.3483
60
0.380
282.7
0.000788
40.819
1.156
29.24
24.6
13.326
0.75'
28.84
26.17
24.4
0.545
800
426
12.1
110.6
S-M315-4
7/28/98
0649-0840
1.007
1.28
29.05
35.703
84
-0.25
228
643.3
0.0
20.9
79.1
0.84
0.3213
60
0.433
402.4
0.001023
33.959
0.962
29.03
47.1
30.280
0.529
28.84
23.73
23.1
0.545
754
297
8.41
101.7
Average
1.007
1.59
29.20
40.909
93
-0.3
251
361.4
0.0
20.9
79.1
0.84
0.3357
60
0.398
340.6
0.000866
38.475
1.089
29.18
29.1
17.010
0.709
28.84
25.69
23.5
0.545
769
394
11.2
104.9
-------
Summary of Stack Gas Parameters and Test Results
PM and MCEM - EPA Method 315
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 2
PM
CpM
CPM
EPM
MCEM
CMCEM
CMCEM
EMCEM
RUN NUMBER
RUN DATE
RUN TIME
EMISSIONS DATA
Particulate Matter
Target Catch, g
Concentration, gr/dscf
Concentration, g/dscm
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylene Chloride Extractable
Target Catch, g
Concentration, gr/dscf
Concentration, g/dscm
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-M315-1
7/24/98
1141-1243
0.1342
5.10E-02
1.17E-01
2.00E-01
5.95E-04
Matter
0.0465
1 J7E-02
4.04E-02
6.94E-02
2.06E-04
S-M315-2
7/25/98
1015-1117
0.0896
3.39E-02
7.75E-02
1.24E-01
4.37E-04
0.0327
1 .24E-02
2.83E-02
4.51 E-02
1 .60E-04
S-M315-4
7/28/98
0649-0840
0.0533
2.42E-02
5.54E-02
6.16E-02
1 .53E-04
0.0122
5.54E-03
1.27E-02
1.41 E-02
3.51E-05
Average
3.63E-02
8.32E-02
1.29E-01
3.95E-04
1.19E-02
2.71 E-02
4.29E-02
1 .34E-04
-------
M315 Analytical Calculations
Run Number: S-M315-1
Particulate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
M,
PA
V.
C,
Vaw
w,
Mass of residue of acetone, mg
Density of acetone, mg/mL
Volume of acetone blank, ml
Acetone blank concentration, mg/mg
Volume of acetone used in wash, ml
Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
46.0
0.023
Container
Number
Final weight
grams
157.0836
Tare of dish
or beaker, g
156.5417
Tare of
filter, g
0.4481
Weight Gain
grams
0.0938
Total participate catch weight, in milligrams:
Total particulate minus the acetone blank (Wa), mg •
134.2
134.18
0.036
MeCI Extractable Matter (MCEM) Determinations
Container Final weight Tare of Weight Gain Acetone Wash MeCI Wash
Number
2+2M
3W
3S
Wa
M,
PT
Vt
C,
w,
Fb
MMCEM
in grams
1.6484
1.6760
1.6210
1.0212
dish, g
1.6478
1.6363
1.6170
1.0189
grams
Volume, ml_ Volume, ml_
0.0006
0.0397
0.0040
totals from line above are:
0.0023
0.0466
mtoU| in mg
46.6
129.15
175.15
sum of Vaw, ml
175.15
129.15
229.15
sum of Vtw, mL
229.15
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, ml
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Sample Data
0.09
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
46.51
QC limit
0.138
0.483
-------
M315 Analytical Calculations
Run Number: S-M315-2
Participate Matter (PM) Determinations
Acetone Wash Blank PM Calculations
QC limit
M, Mass of residue of acetone, mg
PA Density of acetone, mg/mL
Va Volume of acetone blank, ml
Ca Acetone blank concentration, mg/mg
Vaw Volume of acetone used in wash, ml
Wa Acetone wash blank, mg
0.1
785.1
200.3
6.4E-07
71.1
0.035
Container
Number
1
Final weight
grams
187.9376
Tare of dish
or beaker, g
187.4323
Tare of
filter, g
0.4466
Weight Gain
grams
0.0587
0.0309
0.0896
Total particulate catch weight, in milligrams :
Total particulate minus the acetone blank (Wa), mg ;
89.6
89.6
0.056
MeCI Extractable Matter (MCEM) Determinations
Container Final weight Tare of
Number
2+2M
3W
W.
M,
PT
V,
C,
w,
Fb
MMCEM
in grams
1.6461
1.6874
1.6180
1.0292
dish, g
1.6454
1.6599
1.6145
1.0281
Weight Gain | Acetone Wash MeCI Wash
grams
0.0007
0.0275
0.0035
totals from line above are:
0.0011
0.0328
I nitotai in mg
32.8
62.95
134.05
sum of Vaw, ml
134.05
62.95
162.95
sum of Vtw, ml
162.95
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, ml
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Sample Data
0.07
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
32.73
QC limit
0.105
0.343
-------
M315 Analytical Calculations
Run Number: S-M315-4
Particulate Matter (PM) Determinations
Ma
PA
V.
Ca
"aw
w.
Acetone
Wash Blank PM Calculations
Mass of residue of acetone, mg 0.1
Density of acetone, mg/mL 785. 1
Volume of acetone blank, mL 200.3
Acetone blank concentration, mg/mg 6.4E-07
Volume of acetone used in wash, ml 141 .7
Acetone wash blank, mg 0.071
Container
Number
1
2
Total
Final weight
grams
166.2156
Tare of dish
or beaker, g
165.7223
Tare of
filter, g
0.4494
179.7134 179.7039 ^^^^^^B
Total particulate catch weight, in milligrams =
Total particulate minus the acetone blank (Wa), mg =
Weight Gain
grams
0.0439
0.0095
0.0534
53.4
53.33
QC limit
0.111
MeCI Extractable Matter (MCEM) Determinations I
Container
Number
1
2+2M
3W1
3W2
3W3
3W4
3S
Total
w,
M,
Pr
vt
c,
wt
Fb
MMCEM
Final weight
in grams
1.6516
1.6671
1.6011
1.6064
1.6139
1.5938
1.0305
^^•i
totals from
Tare of
dish, g
1.6501
1.6598
1.6000
1.6061
1.6134
1.5936
1.0291
line above are:
Weight Gain
grams
0.0015
0.0073
0.0011
0.0003
0.0005
0.0002
0.0014
0.0123
•"total in mg
12.3
Acetone wash blank, mg
Mass of residue of MeCI blank, mg
Density of MeCI, mg/mL
Volume of MeCI blank, mL
MeCI blank concentration, mg/mg
MeCI wash blank, mg
Filter Blank, mg
Total MeCI Extractable Matter weight, mg
Acetone Wash
Volume, mL
141.7
113
254.7
sum of Vaw, mL
254.7
MeCI Wash I
Volume, mL |
^^100^^1
113
213
sum of V^, mL
213
Sample Data
0.13
0.0
1316.8
189.1
O.OOE+00
0.00
0.0
12.17
QC limit
0.200
0.449
(01
-------
Summary of Stack Gas Parameters and Test Results
SW-846 Method 0010 - Flow Rates
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 1
RUN NUMBER S-MM5-1
RUN DATE 7/24/98
RUNTIME 0720-1018
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
AP1/2
©
Dn
An
Vm(std)
Vm(std)
PS
Bws
iXs
Md
Ms
Vs
A
Qa
Qs
Qs(cmm)
I
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
1.007
1.85
29.28
88.250
84
-0.25
235
265.7
0.0
20.9
79.1
0.84
0.3554
120
0.380
0.000788
84.822
2.402
29.26
12.8
12.506
0.872
28.84
27.44
23.7
0.545
111
503
14.2
97.4
S-MM5-3
7/27/98
0804-1050
1.007
1.42
29.16
76.522
101
-0.26
229
2207.0
0.0
20.9
79.1
0.84
0.3151
120
0.431
0.001013
70.925
2.008
29.14
59.4
103.883
0.406
28.84
22.40
23.3
0.545
761
230
6.52
138.2
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 5
Y
AH
Pbar
vm
Tm
Pstatic
Ts
V,c
CO2
02
N2
cp
AP1/2
0
Dn
An
Vm(std)
vm(std)
PS
BWS
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of asphalt loaded per test period
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
S-MM5-2
7/25/98
0710-0950
1.007
1.83
29.26
88.998
89
-0.25
241
522.4
0.0
20.9
79.1
0.84
0.3481
120
0.380
602.5
0.000788
84.662
2.397
29.24
22.5
24.589
0.775
28.84
26.40
23.8
0.545
780
445
12.6
109.9
S-MM5-4
7/28/98
0913-1323
1.007
0.611
29.05
52.202
103
-0.25
270
1133.6
0.0
20.9
79.1
0.84
0.2846
120
0.433
881.0
0.001023
47.947
1.358
29.03
52.7
53.359
0.473
28.84
23.13
21.3
0.545
698
232
6.56
92.1
S-MM5-5
7/28/98
1358-1940
1.007
2.28
29.05
98.934
96
-0.25
270
1119.9
0.0
20.9
79.1
0.84
0.2895
120
0.500
709.4
0.001364
92.325
2.614
29.03
36.3
52.714
0.637
28.84
24.90
20.9
0.545
684
305
8.64
100.8
Average
1.007
1.58
29.12
80.045
96
-0.25
261
925.3
0.0
20.9
79.1
0.84
0.3074
120
0.438
731.0
0.001058
74.978
2.123
29.10
37.2
43.554
0.628
28.84
24.81
22.0
0.545
720
327
9.26
100.9
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 5
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
154.21
190
7.92E-02
1.24E+01
2.64E-04
4.38E-07
154.21
ND
ND
ND
ND
ND
.178.22
57
2.38E-02
3.21 E+00
7.92E-05
1.31E-07
228.29
17
7.09E-03
7.47E-01
2.36E-05
3.92E-08
252.32
ND
ND
ND
ND
ND
S-MM5-4
154.21
170
1.25E-01
1.95E+01
2.17E-04
2.46E-07
154.21
ND
ND
ND
ND
ND
178.22
56
4.12E-02
5.57E+00
7.15E-05
8.12E-08
228.29
26
1.91E-02
2.02E+00
3.32E-05
3.77E-08
252.32
ND
ND
ND
ND
ND
S-MM5-5
154.21
370
1.42E-01
2.21 E+01
3.24E-04
4.56E-07
154.21
22
8.41 E-03
1.31 E+00
1.92E-05
2.71 E-08
178.22
94
3.60E-02
4.85E+00
8.22E-05
1.16E-07
228.29
43
1.64E-02
1 .73E+00
3.76E-05
5.30E-08
252.32
ND
ND
ND
ND
ND
Average
243
1.15E-01
1.80E+01
2.68E-04
3.80E-07
(7.33)
(2.80E-03)
(4.38E-01)
(6.42E-06)
(9.04E-09)
69.0
3.37E-02
4.54E+00
7.77E-05
1.10E-07
28.7
1.42E-02
1 .50E+00
3.15E-05
4.33E-08
ND
ND
ND
ND
ND
tio
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 3 of 5
Benzo(k)fluoranthene
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd "
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
252.32
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
228.28
64
2.67E-02
2.81 E+00
8.89E-05
1.48E-07
S-MM5-4
252.32
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
228.28
97
7.14E-02
7.53E+00
1.24E-04
1.41E-07
S-MM5-5
252.32
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
15
5.74E-03
5.47E-01
1.31E-05
1.85E-08
228.28
160
6.12E-02
6.45E+00
1.40E-04
1.97E-07
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(5.00)
(1.91E-03)
(1.82E-01)
(4.37E-06)
(6.17E-09)
107
5.31 E-02
5.60E+00
1.18E-04
1.62E-07
\\\
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 5
>ibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
:luoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Fluorene .
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton "
ndeno(1 ,2,3-cd)py rene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2-Methylnaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
278.33
ND
ND
ND
ND
ND
202.26
55
2.29E-02
2.73E+00
7.64E-05
1.27E-07
166.21
600
2.50E-01
3.62E+01
8.34E-04
1.38E-06
290.34
ND
ND
ND
ND
ND
142.20
2,800
1.17E+00
1.98E+02
3.89E-03
6.46E-06
S-MM5-4
278.33
ND
ND
ND
ND
ND
202.26
67
4.93E-02
5.87E+00
8.56E-05
9.71 E-08
166.21
340
2.50E-01
3.62E+01
4.34E-04
4.93E-07
290.34
ND
ND
ND
ND
ND
142.20
2,000
1.47E+00
2.49E+02
2.55E-03
2.90E-06
S-MM5-5
278.33
ND
ND
ND
ND
ND
202.26
100
3.82E-02
4.55E+00
8.75E-05
1.23E-07
166.21
640
2.45E-01
3.54E+01
5.60E-04
7.89E-07
290.34
ND
ND
ND
ND
ND
142.20
3,400
1.30E+00
2.20E+02
2.97E-03
4.19E-06
Average
ND
ND
ND
ND
ND
74.0
3.68E-02
4.38E+00
8.32E-05
1.16E-07
527
2.48E-01
3.60E+01
6.09E-04
8.89E-07
ND
ND
ND
ND
ND
2,733
1.31E+00
2.22E+02
3.14E-03
4.52E-06
-------
Summary of Stack Gas Parameters and Test Results
PAHs - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 5
Naphthalene
Molecular Weight, g/g-mole
Target Catch, \ig
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Perylene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
128.16
800
3.34E-01
6.26E+01
1.11E-03
1.84E-06
252.30
21
8.76E-03
8.35E-01
2.92E-05
4.84E-08
178.22
970
4.05E-01
5.46E+01
1.35E-03
2.24E-06
202.24
230
9.59E-02
1.14E+01
3.20E-04
5.30E-07
S-MMS-4
128.16
720
5.30E-01
9.95E+01
9.20E-04
1.04E-06
252.30
ND
ND
ND
ND
ND
178.22
640
4.71E-01
6.36E+01
8.18E-04
9.28E-07
202.24
170
1.25E-01
1.49E-I-01
2.17E-04
2.46E-07
S-MM5-5
128.16
1,300
4.97E-01
9.33E+01
1.14E-03
1.60E-06
252.30
28
1.07E-02
1 .02E+00
2.45E-05
3.45E-08
178.22
1,200
4.59E-01
6.19E+01
1.05E-03
1.48E-06
202.24
290
1.11E-01
1.32E+01
2.54E-04
3.58E-07
Average
940
4.54E-01
8.52E+01
1.06E-03
1.50E-06
(16.3)
(6.49E-03)
(6.19E-01)
(1.79E-05)
(2.77E-08)
937
4.45E-01
6.01 E+01
1.07E-03
1.55E-06
230
1.11E-01
1.32E+01
2.63E-04
3.78E-07
Milligrams per dry standard cubic meter at 68° F (20° C) and 1 atm.
Parts per billion by volume.
0 Pounds per test period.
Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero.
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 19
Y
AH
Pfaar
vm
Tm
Pstatic
Ts
Vlc
CO2
02
N2
Cp
Ap1'2
e
Dn
An
Vm(std)
Vm(std)
PS
BWS
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUN TIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, "F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volum
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duratior, minutes
Nozzle Diameter, inches
Tons of Asphalt loaded per hour
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), Ib/lb-mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
S-MM5-2
7/25/98
0710-0950
1.007
1.83
29.26
88.998
89
-0.25
241
522.4
0.0
20.9
79.1
0.84
0.3481
120
0.380
602.5
0.000788
84.662
2.397
29.24
22.5
24.589
0.775
28.84
26.40
23.8
0.545
780
445
12.6
109.9
S-MM5-4
7/28/98
0913-1323
1.007
0.611
29.05
52.202
103
-0.25
270
1133.6
0.0
20.9
79.1
0.84
0.2846
120
0.433
881.0
0.001023
47.947
1.358
29.03
52.7
53.359
0.473
28.84
23.13
21.3
0.545
698
232
6.56
92.1
S-MM5-5
7/28/98
1358-1940
1.007
2.28
29.05
98.934
96
-0.25
270
1119.9
0.0
20.9
79.1
0.84
0.2895
120
0.500
709.4
0.001364
92.325
2.614
29.03
36.3
52.714
0.637
28.84
24.90
20.9
0.545
684
305
8.64
100.8
Average
1.007
1.58
29.12
80.045
96
-0.25
261
925.3
0.0
20.9
79.1
0.84
0.3074
120
0.438
731.0
0.00105.8
74.978
2.123
29.10
37.2
43.554
0.628
28.84
24.81
22.0
0.545
720
327
9.26
100.9
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 19
Acenaphthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Acenaphthylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/hr c
Emission Rate, Ib/ton d
Acetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Aminobiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Aniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
154.21
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
120.15
ND
ND
ND
ND
ND
169.22
ND
ND
ND
ND
ND
93.12
ND
ND
ND
ND
ND
S-MM5-4
154.21
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
120.15
ND
ND
ND
ND
ND
169.22
ND
ND
ND
ND
ND
93.12
ND
ND
ND
ND
ND
S-MM5-5
154.21
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
120.15
ND
ND
ND
ND
ND
169.22
ND
ND
ND
ND
ND
93.12
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 3 of 19
Anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(b)fluoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(k)fl uoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
178.22
ND
ND
ND
ND
ND
184.23
ND.
ND
ND
ND
ND
228.29
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
S-MM5-4
178.22
ND
ND
ND
ND
ND
184.23
ND
ND
ND
ND
ND
228.29
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
S-MMS-5
178.22
ND
ND
ND
ND
ND
184.23
ND
ND
ND
ND
ND
228.29
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
252.32
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 19
Benzole acid
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(g,h,i)perylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzo(a)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3enzo(e)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Benzyl alcohol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
122.12
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
S-MM5-4
122.12
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
S-MM5-5
122.12
ND
ND
ND
ND
ND
276.34
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
252.30
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 19
Biphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Bromophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Butyl benzyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Chloroacetophenone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Chloroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
154.20
ND
ND
ND
ND
ND
249.11
ND
ND
ND
ND
ND
312.36
ND
ND
ND
ND
ND
154.59
ND
ND
ND
ND
ND
127.57
ND
ND
ND
ND
ND
S-MM5-4
154.20
ND
ND
ND
ND
ND
249.11
ND
ND
ND
ND
ND
312.36
ND
ND
ND
ND
ND
154.59
ND
ND
ND
ND
ND
127.57
ND
ND
ND
ND
ND
S-MM5-5
154.20
ND
ND
ND
ND
ND
249.11
ND
ND
ND
ND
ND
312.36
ND
ND
ND
ND
ND
154.59
ND
ND
ND
ND
ND
127.57
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 6 of 19
bis(2-Chloroethoxy)-methane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
bis(2-Chloroethyl) ether
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
4-Chloro-3-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Chloronaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Chlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
173.04
ND
ND
ND
ND
ND
143.02
ND
ND
ND
ND
ND
142.58
ND
ND
ND
ND
ND
162.61
ND
ND
ND
ND
ND
128.56
ND
ND
ND
ND
ND
S-MM5-4
173.04
ND
ND
ND
ND
ND
143.02
ND
ND
ND
ND
ND
142.58
ND
ND
ND
ND
ND
162.61
ND
ND
ND
ND
ND
128.56
ND
ND
ND
ND
ND
S-MM5-5
173.04
ND
ND
ND
ND
ND
143.02
ND
ND
ND
ND
ND
142.58
ND
ND
ND
ND
ND
162.61
ND
ND
ND
ND
ND
128.56
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 7 of 19
4-Chlorophenyl phenyl ether
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Chrysene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Dibenz(a,h)anthracene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period e
Emission Rate, Ib/ton d
Dibenzofuran
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
204.66
ND
ND
ND
ND
ND
228.28
ND
ND
ND
ND
ND
120.19
ND
ND
ND
ND
ND
278.33
ND
ND
ND
ND
ND
168.20
ND
ND
ND
ND
ND
S-MM5-4
204.66
ND
ND
ND
ND
ND
228.28
ND
ND
ND
ND
ND
120.19
ND
ND
ND
ND
ND
278.33
ND
ND
ND
ND
ND
168.20
ND
ND
ND
ND
ND
S-MM5-5
204.66
ND
ND
ND
ND
ND
228.28
ND
ND
ND
ND
ND
120.19
ND
ND
ND
ND
ND
278.33
ND
ND
ND
ND
ND
168.20
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 8 of 19
1 ,2-Dibromo-3-chloropropane (DBCP)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Di-n-butyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1 ,2-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1,3-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1 ,4-Dichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
236.36
ND
ND
ND
ND
ND
278.34
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
S-MM5-4
236.36
ND
ND
ND
ND
ND
278.34
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
S-MM5-5
236.36
ND
ND
ND
ND
ND
278.34
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
147.01
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 9 of 19
3,3'-Dichlorobenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm 8
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4-Dichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Diethyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
N-N-Diethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3,3'-Dimethoxybenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
253.13
ND
ND
ND
ND
ND
163.01
ND
ND
ND
ND
ND
222.24
ND
ND
ND
ND
ND
149.23
ND
ND
ND
ND
ND
244.28
ND
ND
ND
ND
ND
S-MM5-4
253.13
ND
ND
ND
ND
ND
163.01
ND
ND
ND
ND
ND
222.24
ND
ND
ND
ND
ND
149.23
ND
ND
ND
ND
ND
244.28
ND
ND
ND
ND
ND
S -MM 5-5
253.13
ND
ND
ND
ND
ND
163.01
ND
ND
ND
ND
ND
222.24
ND
ND
ND
ND
ND
149.23
ND
ND
ND
ND
ND
244.28
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 10 of 19
Dimethyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Dimethylaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
3,3'-Dimethylbenzidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4-Dimethylphenol
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4,6-Dinitro-2-methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
194.19
ND
ND
ND
ND
ND
121.18
ND
ND
ND
ND
ND
212.28
ND
ND
ND
ND
ND
122.17
ND
ND
ND
ND
ND
198.13
ND
ND
ND
ND
ND
S-MM5-4
194.19
ND
ND
ND
ND
ND
121.18
ND
ND
ND
ND
ND
212.28
ND
ND
ND
ND
ND
122.17
ND
ND
ND
ND
ND
198.13
ND
ND
ND
ND
ND
S-MM5-5
194.19
ND
ND
ND
ND
ND
121.18
ND
ND
ND
ND
ND
212.28
ND
ND
ND
ND
ND
122.17
ND
ND
ND
ND
ND
198.13
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 11 of 19
2,4-Dinitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,6-Dinitrotoluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Di-n-octyl phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
bis(2-Ethylhexyl)-phthalate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MMS-2
184.11
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
390.56
ND
ND
ND
ND
ND
390.54
ND
ND
ND
ND
ND
S-MMS-4
184.11
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
390.56
ND
ND
ND
ND
ND
390.54
ND
ND
ND
ND
ND
S-MM5-5
184.11
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
182.14
ND
ND
ND
ND
ND
390.56
ND
ND
ND
ND
ND
390.54
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
' Silo Exhaust Duct
Asphalt Plant C - California
Page 12 of 19
Muoranthene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton a
Fluorene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
-lexachlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Hexachlorobutadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Hexachlorocyclopentadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
202.26
ND
ND
ND
ND
ND
166.21
ND
ND
ND
ND
ND
284.80
ND
ND
ND
ND
ND
260.76
ND
ND
ND
ND
ND
272.77
ND
ND
ND
ND
ND
S-MM5-4
202.26
ND
ND
ND
ND
ND
166.21
ND
ND
ND
ND
ND
284.80
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
272.77
ND
ND
ND
ND
ND
S-MM5-5
202.26
ND
ND
ND
ND
ND
166.21
{560}
{2.14E-01}
{3.10E+01}
{4.90E-04}
{6.91 E-07}
284.80
ND
ND
ND
ND
ND
154.21
ND
ND
ND
ND
ND
272.77
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
(187)
(7.14E-02)
(1.03E+01)
(1.63E-04)
(2.30E-07)
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 13 of 19
Hexachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Hydroquinone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
lndeno(1,2,3-cd)pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Isophorone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Methoxybenzenamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
236.74
ND
ND
ND
ND
ND
110.11
ND
ND
ND
ND
ND
290.34
ND
ND
ND
ND
ND
138.20
ND
ND
ND
ND
ND
123.15
ND
ND
ND
ND
ND
S-MM5-4
236.74
ND
ND
ND
ND
ND
110.11
ND
ND
ND
ND
ND
290.34
ND
ND
ND
ND
ND
138.20
ND
ND
ND
ND
ND
123.15
ND
ND
ND
ND
ND
S-MM5-5
236.74
ND
ND
ND
ND
ND
110.11
ND
ND
ND
ND
ND
290.34
ND
ND
ND
ND
ND
138.20
ND
ND
ND
ND
ND
123.15
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 14 of 19
4,4'-Methyl-bis(2-chloroaniline)
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
2-Methylnaphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2-Methylphenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
3/4-Methylphenol
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Naphthalene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MMS-2
267.16
ND
ND
ND
ND
ND
142.20
3,600
1.50E+00
2.54E+02
5.00E-03
8.30E-06
108.13
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
128.16
{1,600}
{6.67E-01}
{1.25E+02}
{2.22E-03}
{3.69E-06}
S-MM5-4
267.16
ND
ND
ND
ND
ND
142.20
{2,300}
{1.69E+00}
{2.87E+02}
{2.94E-03}
{3.33E-06}
108.13
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
128.16
{1,500}
{1.10E+00}
{2.07E+02}
{1.92E-03}
{2.17E-06}
S-MM5-S
267.16
ND
ND
ND
ND
ND
142.20
4,400
1.68E+00
2.85E+02
3.85E-03
5.43E-06
108.13
ND
ND
ND
ND
ND
108.13
ND
ND
ND
ND
ND
128.16
{2,600}
{9.94E-01}
{1.87E+02}
{2.27E-03}
{3.21 E-06}
Average
ND
ND
ND
ND
ND
{3,433}
{1.63E+00}
{2.75E+02}
{3.93E-03}
{5.69E-06}
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{1,900}
{9.22E-01}
{1.73E+02}
{2.14E-03}
{3.02E-06}
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 15 of 19
2-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
3-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Nitroaniline
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Nitrobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Nitrodiphenyl
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
123.11
ND
ND
ND
ND
ND
199.20
ND
ND
ND
ND
ND
S-MM5-4
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
123.11
ND
ND
ND
ND
ND
199.20
ND
ND
ND
KID
ND
S-MM5-5
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
138.12
ND
ND
ND
ND
ND
123.11
ND
ND
ND
ND
ND
199.20
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 16 of 19
2-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
4-Nitrophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
N-Nitrosodimethylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
N-Nitrosodiphenylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm *
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
N-Nitroso-di-n-propylamine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
S-MM5-2
139.11
ND
ND
ND
ND
ND
139.11
ND
ND
ND
ND
ND
74.08
ND
ND
ND
ND
ND
198.22
ND
ND
ND
ND
ND
130.19
ND
ND
ND
ND
ND
S-MMS-4
139.11
ND
ND
ND
ND
ND
139.11
ND
ND
ND
ND
ND
74.08
ND
ND
ND
ND
ND
198.22
ND
ND
ND
ND
ND
130.19
ND
ND
ND
ND
ND
S-MM5-5
139.11
ND
ND
ND
ND
ND
139.11
ND
ND
ND
ND
ND
74.08
ND
ND
ND
ND
ND
198.22
ND
ND
ND
ND
ND
130.19
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 17 of 19
N-Nitrosomorpholine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,2'-Oxybis(1 -chloropropane)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Pentachloronitrobenzene (PCNB)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Pentachlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period °
Emission Rate, Ib/ton d
Phenanthrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
116.11
ND
ND
ND
ND
ND
171.07
ND
ND
ND
ND
ND
295.30
ND
ND
ND
ND
ND
266.35
ND
ND
ND
ND
ND
178.22
{950}
{3.96E-01}
{5.35E+01}
{1.32E-03}
{2.19E-06}
S-MMS-4
116.11
ND
ND
ND
ND
ND
171.07
ND
ND
ND
ND
ND
295.30
ND
ND
ND
ND
ND
266.35
ND
ND
ND
ND
ND
178.22
{590}
{4.35E-01}
{5.86E+01}
{7.54E-04}
{8.55E-07}
S-MM5-5
116.11
ND
ND
ND
ND
ND
171.07
ND
ND
ND
ND
ND
295.30
ND
ND
ND
ND
ND
266.35
ND
ND
ND
ND
ND
178.22
{1,200}
{4.59E-01}
{6.19E+01}
{1.05E-03}
{1.48E-06}
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
{913}
{4.30E-01}
{5.80E+01}
{1.04E-03}
{1.51E-06}
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 18 of 19
Phenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Pyrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
o-Toluidine
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
1 ,2,4-Trichlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
2,4,5-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm "
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
94.11
ND
ND
ND
ND
ND
202.24
ND
ND
ND
ND
ND
107.15
ND
ND
ND
ND
ND
181.46
ND
ND
ND
ND
ND
197.46
ND
ND
ND
ND
ND
S-MM5-4
94.11
ND
ND
ND
ND
ND
202.24
ND
ND
ND
ND
ND
107.15
ND
ND
ND
ND
ND
181.46
ND
ND
ND
ND
ND
197.46
ND
ND
ND
ND
ND
S-MM5-5
94.11
ND
ND
ND
ND
ND
202.24
ND
ND
ND
ND
ND
107.15
ND
ND
ND
ND
ND
181.46
ND
ND
ND
ND
ND
197.46
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Semi-volatile Organics - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 19 of 19
2,4,6-Trichlorophenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
Trifluralin
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm a
Concentration, ppbvd b
Emission Rate, Ib/test period c
Emission Rate, Ib/ton d
S-MM5-2
197.46
ND
ND
ND
ND
ND
335.29
ND
ND
ND
ND
ND
S-MM5-4
197.46
ND
ND
ND
ND
ND
335.29
ND
ND
ND
ND
ND
S-MM5-S
197.46
ND
ND
ND
ND
ND
335.29
ND
ND
ND
ND
ND
Average
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
" Milligrams per dry standard cubic meter at 68° F (20° C) and 1 aim.
b Parts per billion by volume.
c Pounds per test period.
d Pounds per ton of asphalt loaded.
ND Not Detectable - Results are below target analyte detection limit. Values are counted as zero (0) in averages.
{} Estimate - Concentration exceeds calibration range.
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 10
Y
AH
Pbar
vm
Tm
^static
Ts
Vic
C02
02
N2
cp
AP1/2
0
Dn
An
Vm(std)
Vm(std)
PS
BWS
Vwstd
1-Bws
Md
Ms
vs
A
Qa
Qs
Qs(cmm)
I
RUN NUMBER
RUN DATE
RUNTIME
MEASURED DATA
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volum
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Tons of Asphalt loaded per hour
CALCULATED DATA
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, % by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight (d.b.), lb/lb»mole
Molecular Weight (w.b.), Ib/lb-mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfm
Stack Gas Volumetric flow, dscfm
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
S-MM5-2
7/25/98
0710-0950
1.007
1.83
29.26
88.998
89
-0.25
241
522.4
0.0
20.9
79.1
0.84
0.3481
120
0.380
602.5
0.000788
84.662
2.397
29.24
22.5
24.589
0.775
28.84
26.40
23.8
0.545
780
445
12.6
109.9
S-MM5-4
7/28/98
0913-1323
1.007
0.611
29.05
52.202
103
-0.25
270
1133.6
0.0
20.9
79.1
0.84
0.2846
120
0.433
881.0
0.001023
47.947
1.358
29.03
52.7
53.359
0.473
28.84
23.13
21.3
0.545
698
232
6.56
92.1
S-MM5-5
7/28/98
1358-1940
1.007
2.28
29.05
98.934
96
-0.25
270
1119.9
0.0
20.9
79.1
0.84
0.2895
120
0.500
709.4
0.001364
92.325
2.614
29.03
36.3
52.714
0.637
28.84
24.90
20.9
0.545
684
305
8.64
100.8
Average
1.007
1.58
29.12
80.045
96
-0.25
261
925.3
0.0
20.9
79.1
0.84
0.3074
120
0.438
731.0
0.001058
74.978
2.123
29.10
37.2
43.554
0.628
28.84
24.81
22.0
0.545
720
327
9.26
100.9
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 10
NUMBER
S-MM5-2
Jnknown alkane
Target Catch, ^g
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Unknown
Target Catch, |jg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown PAH
Target Catch, (jg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Unknown alkene
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
Jndecane
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Dodecane, 2,6,10-trimethyl-
Target Catch, pg
Concentration, mg/dscm *
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
7,900
3.29
1.10E-02
1.82E-05
13,000
5.42
1.81E-02
3.00E-05
15,000
6.26
2.08E-02
3.46E-05
8,900
3.71
1.24E-02
2.05E-05
8,600
3.59
1.19E-02
1.98E-05
8,400
3.50
1.17E-02
1.94E-05
17,000
7.09
2.36E-02
3.92E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
PageS of 10
RUN NUMBER
S-MMS-2
Tetradecane
Target Catch, \ig
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown alkene
Target Catch, |jg
Concentration, mg/dscma
Emission Rate, Ib/test period "
Emission Rate, Ib/ton c
Heptadecane, 2,6,10,14-tetramethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Undecane, 2-methyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Unknown alkane
Target Catch, pg
Concentration, mg/dscm "
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Nonadecane
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6,-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
22,000
9.18
3.06E-02
5.07E-05
12,000
5.00
1.67E-02
2.77E-05
18,000
7.51
2.50E-02
4.15E-05
19,000
7.92
2.64E-02
4.38E-05
13,000
5.42
1.81E-02
3.00E-05
24,000
10.0
3.33E-02
5.53E-05
15,000
6.26
2.08E-02
3.46E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 10
RUN NUMBER
S-MM5-2
Heptadecane, 2,6,-dimethyl-
Target Catch, pg
Concentration, mg/dscm"
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Heptadecane, 2,6,-dimethyl-
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Heptadecane, 2,6,-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Nonadecane
Target Catch, pg
Concentration, mg/dscm "
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6,10,14-tetramethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Nonadecane
Target Catch, \ig
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
32,000
13.3
4.45E-02
7.38E-05
10,000
4.17
1.39E-02
2.31 E-05
14,000
5.84
1.95E-02
3.23E-05
7,700
3.21
1.07E-02
1.78E-05
9,700
4.05
1.35E-02
2.24E-05
7,500
3.13
1.04E-02
1.73E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 10
RUN NUMBER
S-MM5-4
Undecane
Target Catch, \ig
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Unknown alkane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Decane, 2,5,9-Trimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown alkane
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Unknown hydrocarbon
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
7.600
5.60
9.71 E-03
1.10E-05
7,500
5.52
9.58E-03
1.09E-05
7,100
5.23
9.07E-03
1.03E-05
6,200
4.57
7.92E-03
8.99E-06
12,000
8.84
1.53E-02
1.74E-05
12,000
8.84
1.53E-02
1.74E-05
6,900
5.08
8.81 E-03
1.00E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page6 of 10
HJN NUMBER
Octane, 3,5-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Unknown
Target Catch, \ig
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6-dimethyl-
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Tetradecane
Target Catch, |jg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Unknown
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6,10,14 -tetramethyl-
Target Catch, |jg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Pentadecane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
S-MM5-4
9,800
7.22
1.25E-02
1.42E-05
6,400
4.71
8.18E-03
9.28E-06
13,000
9.57
1.66E-02
1.88E-05
18,000
13.3
2.30E-02
2.61 E-05
8,600
6.33
1.10E-02
1.25E-05
12,000
8.84
1.53E-02
1.74E-05
14,000
10.3
1.79E-02
2.03E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 7 of 10
RUN NUMBER
S-MM5-4
Unknown
Target Catch, \ig
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Nonadecane
Target Catch, yg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/tonc
Undecane, 2,6-dimethyl-
Target Catch, \ig
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Heptadecane, 2,6-dimethyl-
Target Catch, (jg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
Unknown alkane
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
6,400
4.71
8.18E-03
9.28E-06
16,000
11.8
2.04E-02
2.32E-05
13,000
9.57
1.66E-02
1.88E-05
28,000
20.6
3.58E-02
4.06E-05
7,600
5.60
9.71 E-03
1.10E-05
9,800
7.22
1.25E-02
1.42E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 8 of 10
RUN NUMBER
S-MM5-S
Unknown
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period "
Emission Rate, Ib/ton c
Decane, 2,9-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
Undecane, 2,6-dimethyl-
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Unknown alkane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, jjg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/tonc
11,000
4.21
9.62E-03
1.36E-05
13,000
4.97
1.14E-02
1.60E-05
9,200
3.52
8.05E-03
1.13E-05
9,500
3.63
8.31 E-03
1.17E-05
15,000
5.74
1.31E-02
1.85E-05
20,000
7.65
1.75E-02
2.47E-05
12.000
4.59
1.05E-02
1.48E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 9 of 10
RUN NUMBER
S-MMS-5
Unknown alkane
Target Catch, jjg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Unknown
Target Catch, |jg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, pg
Concentration, mg/dscm"
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Dodecane, 2,6,10-trimethyl-
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Tetradecane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Unknown
Target Catch, \ig
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton °
Heptadecane, 2,6,10,14 -tetramethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
11,000
4.21
9.62E-03
1.36E-05
10,000
3.82
8.75E-03
1.23E-05
12,000
4.59
1.05E-02
1.48E-05
19,000
7.27
1.66E-02
2.34E-05
25,000
9.56
2.19E-02
3.08E-05
15,000
5.74
1.31E-02
1.85E-05
22,000
8.41
1.92E-02
2.71 E-05
-------
Summary of Stack Gas Parameters and Test Results
Tentatively Identified Compounds - SW-846 Method 0010
Silo Exhaust Duct
Asphalt Plant C - California
Page 10 of 10
RUN NUMBER
S-MM5-S
Dodecane, 3-methyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Oxirane, hexadecyl-
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton °
Unknown alkane
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test periodb
Emission Rate, Ib/ton c
Unknown alkane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Heptadecane, 2,6-dimethyl-
Target Catch, pg
Concentration, mg/dscm a
Emission Rate, Ib/test period b
Emission Rate, Ib/ton c
Nonadecane
Target Catch, pg
Concentration, mg/dscma
Emission Rate, Ib/test periodb
Emission Rate, IbAon °
25,000
9.56
2.19E-02
3.08E-05
13,000
4.97
1.14E-02
1.60E-05
27,000
10.3
2.36E-02
3.33E-05
14,000
5.35
1.22E-02
1.73E-05
28,000
10.7
2.45E-02
3.45E-05
11,000
4.21
9.62E-03
1.36E-05
" Milligrams per dry standard cubic meter at 68° F (20* C) and 1 atm.
" Pounds per test period.
c Pounds per ton of asphalt loaded.
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 11
Run Number
Run Date
Run Time
Net Run Time, minutes
Pbar Barometric Pressure, inches Hg
y Dry Gas Meter calibration factor
Vm Sample Volume, liters
Tm Avg. Meter temperature, °R
AH Pressure diff. of meter, in. H2O
Vm(std) Sample Volume, dry std. liters
Qs Volumetric Flow Rate, dscfm
Tons of asphalt per test period
Acetone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Aliyl chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-V-1-1
7/24/98
0726-0736
10.0
29.28
1.0309
1.980
529
1.0
2.001
503
79.2
58.08
0.670
53.06
ND
76.53
ND
S-V-1-2
7/24/98
0859-0909
10.0
29.28
1.0309
2.120
540
1.0
2.098
503
57.7
58.08
{0.660}
53.06
ND
76.53
ND
S-V-1-4
7/24/98
1004-1014
10.0
29.28
1.0309
1.750
539
1.0
1.735
503
56.6
58.08
{0.355}
53.06
ND
76.53
ND
lalal
30.0
5.834
503
193.5
58.08
{1.685}
{0.289}
{120}
{2.72E-04}
{1.41E-06}
53.06
ND
ND
ND
ND
ND
76.53
ND
ND
ND
ND
ND
-------
Run Number
Benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromodichloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromoform
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,3-Butadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SVV-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
S-V-1-1
78.11
{1.206}
163.82
ND
252.77
ND
94.95
0.116
58.08
ND
S-V-1-2
78.11
{0.771}
163.82
ND
252.77
ND
94.95
{0.124}
58.08
ND
S-V-1-4
78.11
{1.054}
163.82
ND
252.77
ND
94.95
{0.064}
58.08
ND
Total
78.11
{3.031}
{0.519}
{160}
{4.89E-04}
{2.53E-06}
163.82
ND
ND
ND
ND
ND
252.77
ND
ND
ND
ND
ND
94.95
{0.304}
{0.0521}
{13.2}
{4.91E-05}
{2.54E-07}
58.08
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
Run Number
2-Butanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon disulfide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Carbon tetrachloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chlorobenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-V-1-1
72.10
ND
76.14
ND
153.84
ND
112.56
ND
64.52
ND
S-V-1-2
72.10
ND
76.14
ND
153.84
ND
112.56
ND
64.52
ND
S-V-1-4
72.10
ND
76.14
ND
153.84
ND
112.56
ND
64.52
'ND
Total
72.10
ND
ND
ND
ND
ND
76.14
ND
ND
ND
ND
ND
153.84
ND
ND
ND
ND
ND
112.56
ND
ND
ND
ND
ND
64.52
ND
ND
ND
ND
ND
-------
Run Number
Chloroform
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Chloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Cumene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dibromochloromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Dibromoethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
S-V-1-1
119.39
ND
50.49
0.363
120.19
ND
208.27
ND
187.88
ND
S-V-1-2
119.39
ND
50.49
0.459
120.19
ND
208.27
ND
187.88
ND
S-V-1-4
119.39
ND
50.49
0.255
120.19
ND
208.27
ND
187.88
ND
Total
119.39
ND
ND
ND
ND
ND
50.49
1.077
0.185
88.0
1.74E-04
8.99E-07
120.19
ND
ND
ND
ND
ND
208.27
ND
ND
ND
ND
ND
187.88
ND
ND
ND
ND
ND
-------
Run Number
1,1-Dichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Dichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1-Dichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
cis-1,2-Dich loroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
trans-l,2-Dichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
S-V-l-l
98.97
ND
98.96
ND
96.95
ND
96.95
ND
96.95
ND
S-V-1-2
98.97
ND
98.96
ND
96.95
ND
96.95
ND
96.95
ND
S-V-1-4
98.97
ND
98.96
ND
96.95
ND
96.95
ND
96.95
ND
Total
98.97
ND
ND
ND
ND
ND
98.96
ND
ND
ND
ND
ND
96.95
ND
ND
ND
ND
ND
96.95
ND
ND
ND
ND
ND
96.95
ND
ND
ND
ND
ND
-------
Run Number
1,2-Dichloropropane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
cis-l,3-Dichloropropene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,2-Epoxy butane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ethyl acrylate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
S-V-1-1
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
S-V-1-2
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
S-V-1-4
112.99
ND
110.98
ND
110.98
ND
72.12
ND
100.11
ND
Total
112.99
ND
ND
ND
ND
ND
110.98
ND
ND
ND
ND
ND
110.98
ND
ND
ND
ND
ND
72.12
ND
ND
ND
ND
ND
100.11
ND
ND
ND
ND
ND
-------
Run Number
Ethylbenzene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
n-Hexane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Hexanone
Molecular Weight, g/g-mole
1'arget Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
lodomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Isooctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
S-V-1-1
106.16
{1.752}
86.17
{7.610}
100.16
ND
141.95
ND
114.22
ND
S-V-1-2
106.16
{1.292}
86.17
{3.321}
100.16
ND
141.95
ND
114.22
ND
S-V-1-4
106.16
0.808
86.17
{2.662}
100.16
ND
141.95
ND
114.22
{0.085}
Total
106.16
{3.852}
{0.660}
{150}
{6.22E-04}
{3.21E-06}
86.17
{13.593}
{2.33}
{650}
{2.20E-03}
{1.13E-05}
100.16
ND
ND
ND
ND
ND
141.95
ND
ND
ND
ND
ND
114.22
(0.085)
(0.0146)
(3.07)
(1.37E-05)
(7.09E-08)
-------
Run Number
Methyl methacrylate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methyiene chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
4-Methyl-2-pentanone
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
S-V-l-l
MTBE
Styrene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-V-1-2
S-V-1-4
Total
86.09 86.09
ND ND
84.94 84.94
ND {0.004}
100.16 100.16
ND ND
88.15 88.15
no data no data
304.14 104.14
ND {0.002}
86.09 86.09
ND ND
ND
ND
ND
ND
84.94 84.94
{0.002} (0.006)
(1.03E-03)
(0.291)
(9.69E-07)
(5.01E-09)
100.16 100.16
ND ND
ND
ND
ND
ND
88.15 88.15
no data NA
NA
NA
NA
NA
104.14 104.14
{0.001} (0.003)
(5.14E-04)
(0.119)
(4.84E-07)
(2.50E-09)
-------
Run Number
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tetrachloroethene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Toluene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,1-TrichIoroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1,1,2-Trichloroethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
S-V-1-1
167.86
ND
165.85
ND
92.13
{3.278}
133.42
ND
133.42
ND
S-V-1-2
167.86
ND
165.85
ND
92.13
{2.015}
133.42
ND
133.42
ND
S-V-1-4
167.86
ND
165.85
ND
92.13
{1.380}
133.42
ND
133.42
ND
Total
167.86
ND
ND
ND
ND
ND
„ 165.85
ND
ND
ND
ND
ND
92.13
{6.673}
{1.14}
{299}
{1.08E-03}
{5.57E-06}
133.42
ND
ND
ND
ND
ND
133.42
ND
ND
ND
ND
ND
\s\
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
Run Number
Trichloroethene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trichlorofluoromethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl acetate
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl bromide
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Vinyl chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-V-1-1
131.40
ND
137.38
ND
86.09
ND
106.96
ND
62.50
ND
S-V-1-2
131.40
ND
137.38
ND
86.09
ND
106.96
ND
62.50
ND
S-V-1-4
131.40
ND
137.38
ND
86.09
ND
106.96
ND
62.50
ND
Total
131.40
ND
ND
ND
ND
ND
137.38
ND
ND
ND
ND
ND
86.09
ND
ND
ND
ND
ND
106.96
ND
ND
ND
ND
ND
62.50
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Number
m-/p-Xylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
o-Xylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-V-1-1
106.16
{10.364}
106.16
{2.951}
S-V-1-2
106.16
{7.040}
106.16
{2.084}
S-V-1-4
106.16
{4.068}
106.16
{1.203}
Total
106.16
{21.472}
{3.68}
{834}
{3.47E-03}
{1.79E-05}
106.16
{6.238}
{1.07}
{242}
{1.01E-03}
{5.21E-06}
ND indicates compound was not detected. A zero was used in the total and the value enclosed in parentheses ()•
Estimated values and totals using estimated values are enclosed in brackets {}.
V53
-------
SW-846 Method 0030 Catch Weights in Micrograms, Test Run S-V-1, Test Set 2
Samples: S-V-1-2A (Tenax tube) and S-V-1-2B (Tenax/charocal tube)
Target Compound
Acetone
Acrylonitrile
Allyl chloride
Benzene
Jromodichloromethane
Jromoform
Jromomethane
1,3-Butadiene
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cumene
3ibromochloromethane
1 ,2-Dibromoethane
1,1-Dichloroethane
1 ,2-Dichloroethane
1 , 1 -Dichloroethene
cis-1 ,2-Dichloroethene
trans- 1 ,2-Dichloroethene
1 ,2-Dichloropropane
cis- 1 ,3-Dichloropropene
trans- 1 ,3-Dichloropropene
1 ,2-Epoxybutane
Ethyl acrylate
Ethylbenzene
n-Hexane
2-Hexanone
[odomethane
Isooctane
Methyl methacrylate
Methylene chloride
4-Methyl-2-pentanone
MTBE
Styrene
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1 -Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl bromide
Vinyl chloride
m-/p-Xylene
o-Xylene
Sample ID
S-V-1-2A
Flag*
B
B
BJ
B
BE
BE
BE
BE
BE
catch, fig
0.653
ND
ND
0.728
ND
ND
0.033
ND
ND
ND
ND
ND
ND
ND
0.160
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.292
3.320
ND
ND
ND
ND
ND
ND
no data
ND
ND
ND
2.010
ND
ND
ND
ND
ND
ND
ND
7.039
2.084
S-V-1-2B
Flag*
BJ
BJ
B
B
BJ
BJ
BJ
BJ
B
catch, fig
0.007
ND
ND
0.043
ND
ND
0.091
ND
ND
ND
ND
ND
ND
ND
0.299
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.001
ND
ND
ND
ND
0.004
ND
no data
0.002
ND
ND
0.005
ND
ND
ND
ND
ND
ND
ND
0.00
ND
Flag*
BJ
BJ
BJ
B
BE
BEJ
BJ
BJ
BEJ
BE
BE
TOTAL
catch, jig
0.660
ND
ND
0.771
ND
ND
0.124
ND
ND
ND
ND
ND
ND
ND
0.459
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.292
3.321
ND
ND
ND
ND
0.004
ND
no data
0.002
ND
ND
2.015
ND
ND
ND
ND
ND
ND
ND
7.040
2.084
* Analytical Flags: B = compound present in lab blank, E = concentration found above calibration limit, J = compound detected, but below the
quantitation limit.
-------
SW-846 Method 0030 Catch Weights in Micrograms, Test Run S-V-1, Test Set 4
Samples: S-V-1-4A (Tenax tube) and S-V-1-4B (Tenax/charocal tube)
Target Compound
Acetone
Acrylonitrile
Allyl chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
1,3-Butadiene
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cumene
Dibromochloromethane
1 ,2-Dibromoethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis- 1 ,2-Dichloroethene
trans- 1 ,2-Dichloroethene
1 ,2-Dichloropropane
cis- 1 ,3-Dichloropropene
trans-1 ,3-Dichloropropene
1,2-Epoxybutane
Ethyl acrylate
Ethylbenzene
n-Hexane
2-Hexanone
lodomethane
Isooctane
Methyl methacrylate
Methylene chloride
4-Methyl-2-pentanone
MTBE
Styrene
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1 -Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl bromide
Vinyl chloride
m-/p-Xylene
o-Xylene
Sample ID
S-V-1-4A
Flag*
B
BE
BJ
B
B
BE
J
BE
BE
BE
catch, fig
0.349
ND
ND
1.043
ND
ND
0.022
ND
ND
ND
ND
ND
ND
ND
0.098
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.808
2.661
ND
ND
0.085
ND
ND
ND
no data
ND
ND
ND
1.376
ND
ND
ND
ND
ND
ND
ND
4.068
1.203
S-V-1-4B
Flag*
BJ
BJ
BJ
B
BJ
BJ
BJ
BJ
catch, fig
0.006
ND
ND
0.011
ND
ND
0.042
ND
ND
ND
ND
ND
ND
ND
0.157
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.001
ND
ND
ND
ND
0.002
ND
no data
0.00
ND
ND
0.004
ND
ND
ND
ND
ND
ND
ND
ND
ND
Flag*
BJ
BEJ
BJ
B
B
BEJ
J
BJ
BJ
BE
BE
BE
TOTAL
catch, fig
0.355
ND
ND
1.054
ND
ND
0.064
ND
ND
ND
ND
ND
ND
ND
0.255
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.808
2.662
ND
ND
0.085
ND
0.002
ND
no data
0.001
ND
ND
1.380
ND
ND
ND
ND
ND
ND
ND
4.068
1.203
* Analytical Flags: B
quantitation limit.
= compound present in lab blank, E = concentration found above calibration limit, J = compound detected, but below the
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 1 of 11
Run Numbers S-V-2-4
Test Date 7/25/98
Sample Times 0910-0920
Net Run Time, minutes 10
Pbjr Barometric Pressure, inches Hg 29.26
Dry Gas Meter calibration factor 1 .0309
Sample Volume, liters 2.490
Avg. Meter temperature, °R 537
Pressure diff. of meter, in. H2O 0.8
Sample Volume, dry std. liters 2.473
Volumetric Flow Rate, dscfm 445
Tons of asphalt per test period 46.3
y
Vm
Tm
AH
m(st(1)
Qs
Acetone
Molecular Weight, g/g-mole
Target Catch, jig
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Acrylonitrile
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ally! chloride
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
58.08
{2.054}
{0.831}
{344}
{2.31E-04}
{4.98E-06}
53.06
ND
ND
ND
ND
ND
76.53
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
Run Numbers S-V-2-4
Benzene
Molecular Weight, g/g-mole 78.11
Target Catch, ug {0.717}
Concentration, mg/dscm {0.290}
Concentration, ppbvd {89.3}
Emission Rate, Ib/test period {8.05E-05 }
Emission Rate, Ib/ton {1.74E-06 }
Bromodichloromethane
Molecular Weight, g/g-mole 163.82
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromoform
Molecular Weight, g/g-mole 252.77
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromomethane
Molecular Weight, g/g-mole 94.95
Target Catch, ug 0.227
Concentration, mg/dscm 0.0918
Concentration, ppbvd 23.3
Emission Rate, Ib/test period 2.55E-05
Emission Rate, Ib/ton 5.51E-07
1,3-Butadiene
Molecular Weight, g/g-mole 58.08
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
Run Numbers S-V-2-4
2-Butanone
Molecular Weight, g/g-mole 72.10
Target Catch, fig {1.402}
Concentration, mg/dscm {0.567}
Concentration, ppbvd {189}
Emission Rate, Ib/test period {1.58E-04}
Emission Rate, Ib/ton {3.40E-06}
Carbon disulfide
Molecular Weight, g/g-mole 76.14
Target Catch, ng 0.943
Concentration, mg/dscm 0.381
Concentration, ppbvd 120
Emission Rate, Ib/test period 1.06E-04
Emission Rate, Ib/ton 2.29E-06
Carbon tetrachloride
Molecular Weight, g/g-mole 153.84
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chlorobenzene
Molecular Weight, g/g-mole 112.56
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chloroethane
Molecular Weight, g/g-mole 64.52
Target Catch, ug 0.311
Concentration, mg/dscm 0.126
Concentration, ppbvd 46.9
Emission Rate, Ib/test period 3.49E-05
Emission Rate, Ib/ton 7.55E-07
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
Run Numbers S-V-2-4
Chloroform
Molecular Weight, g/g-mole 119.39
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chloromethane
Molecular Weight, g/g-mole 50.49
Target Catch, ng 1.156
Concentration, mg/dscm 0.467
Concentration, ppbvd 223
Emission Rate, Ib/test period 1.30E-04
Emission Rate, Ib/ton 2.80E-06
Cumene
Molecular Weight, g/g-mole 120.19
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Dibromochloromethane
Molecular Weight, g/g-mole 208.27
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dibromoethane
Molecular Weight, g/g-mole 187.88
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
Run Numbers S-V-2-4
1,1-Dichloroethane
Molecular Weight, g/g-mole 98.97
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dich loroethane
Molecular Weight, g/g-mole 98.96
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-1,2-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-1,2-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
Run Numbers S-V-2-4
1,2-Dichloropropane
Molecular Weight, g/g-mole 112.99
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Epoxy butane
Molecular Weight, g/g-mole 12.12
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd , ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Ethyl acrylate
Molecular Weight, g/g-mole 100.11
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
Run Numbers S-V-2-4
Ethylbenzene
Molecular Weight, g/g-mole 106.16
Target Catch, ng {0.386}
Concentration, mg/dscm {0.156}
Concentration, ppbvd {35.4}
Emission Rate, Ib/test period {4.34E-05}
Emission Rate, Ib/ton {9.37E-07}
n-Hexane
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Hexanone
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
lodomethane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Isooctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
86.17
{1.425}
{0.576}
{161}
{1.60E-04}
{3.46E-06}
100.16
ND
ND
ND
ND
ND
141.95
ND
ND
ND
ND
ND
114.22
{0.001}
{4.04E-04}
{0.0852}
{1.12E-07}
{2.43E-09}
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
Run Numbers S-V-2-4
Methyl methacrylate
Molecular Weight, g/g-mole 86.09
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Methylene chloride
Molecular Weight, g/g-mole 84.94
Target Catch, ng {0.020}
Concentration, mg/dscm {8.09E-03}
Concentration, ppbvd {2.29}
Emission Rate, Ib/test period {2.25E-06}
Emission Rate, Ib/ton {4.85E-08}
4-MethyI-2-pentanone
Molecular Weight, g/g-mole 100.16
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
MTBE
Styrene
Molecular Weight, g/g-mole
Target Catch, ng
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
88.15
no data
no data
no data
no data
no data
104.14
0.146
0.0590
13.6
1.64E-05
3.54E-07
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
Run Numbers S-V-2-4
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole 167.86
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Tetrachloroethene
Molecular Weight, g/g-mole 165.85
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Toluene
Molecular Weight, g/g-mole 92.13
Target Catch, ug {0.829}
Concentration, mg/dscm {0.335}
Concentration, ppbvd {87.5}
Emission Rate, Ib/test period {9.31 E-05}
Emission Rate, Ib/ton {2.01E-06}
1,1,1-Trichloroethane
Molecular Weight, g/g-mole 13 3.42
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1,2-Trichloroethane
Molecular Weight, g/g-mole 13 3.42
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
Run Numbers s-V-2-4
Trichloroethene
Molecular Weight, g/g-mole 131.40
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Trichlorofluoromethane
Molecular Weight, g/g-mole 137.38
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl acetate
Molecular Weight, g/g-mole 86.09
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl bromide
Molecular Weight, g/g-mole 106.96
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl chloride
Molecular Weight, g/g-mole 62.50
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Numbers S-V-2-4
m-/p-Xylene
Molecular Weight, g/g-mole 106.16
Target Catch, ug {2.109}
Concentration, mg/dscm {0.853}
Concentration, ppbvd {193}
Emission Rate, Ib/test period {2.37E-04}
Emission Rate, Ib/ton (5.12E-06}
o-Xylene
Molecular Weight, g/g-mole 106.16
Target Catch, ug 0.784
Concentration, mg/dscm 0.317
Concentration, ppbvd 71.8
Emission Rate, Ib/test period 8.81E-05
Emission Rate, Ib/ton 1.90E-06
ND indicates compound was not detected. A zero was used in the total and the value enc
Estimated values and totals using estimated values are enclosed in brackets {}.
-------
SW-846 Method 0030 Catch Weights in Micrograms, Test Run S-V-2, Test Set 4
Samples: S-V-2-4A (Tenax tube) and S-V-2-4B (Tenax/charocal tube)
Target Compound
Acetone
Acrylonitrile
Allyl chloride
Benzene
Bromodichloromethane
Bromoform
Bromomethane
1,3-Butadiene
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cumene
Dibromochloromethane
1 ,2-Dibromoethane
1 , 1 -Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis- 1 ,2-Dichloroethene
trans- 1 ,2-Dichloroethene
1 ,2-Dichloropropane
cis-1 ,3-Dichloropropene
trans-l,3-Dichloropropene
1,2-Epoxybutane
Ethyl acrylate
Ethylbenzene
n-Hexane
2-Hexanone
lodomethane
Isooctane
Methyl methacrylate
Methylene chloride
4-Methyl-2-pentanone
MTBE
Styrene
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1 -Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl bromide
Vinyl chloride
m-/p-Xylene
o-Xylene
Sample ID
Flag*
BE
B
B
BE
B
B
BE
B
B
BE
B
S-V-2-4A
catch, fig
2.048
ND
ND
0.711
ND
ND
0.086
ND
1.402
0.943
ND
ND
0.311
ND
0.390
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.385
1.423
ND
ND
ND
ND
ND
ND
no data
0.145
ND
ND
0.820
ND
ND
ND
ND
ND
ND
ND
2.108
0.784
Flag*
BJ
BJ
B
B
BJ
BJ
J
BJ
BJ
BJ
BJ
S-V-2-4B
catch, jig
0.006
ND
ND
0.006
ND
ND
0.141
ND
ND
ND
ND
ND
ND
ND
0.766
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.001
0.002
ND
ND
0.001
ND
0.020
ND
no data
0.001
ND
ND
0.009
ND
ND
ND
ND
ND
ND
ND
0.001
ND
Flag*
BEJ
BJ
B
BE
B
BJ
BEJ
J
BJ
BJ
BJ
BEJ
B
TOTAL
catch, jig
2.054
ND
ND
0.717
ND
ND
0.227
ND
1.402
0.943
ND
ND
0.311
ND
1.156
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.386
1.425
ND
ND
0.001
ND
0.020
ND
no data
0.146
ND
ND
0.829
ND
ND
ND
ND
ND
ND
ND
2.109
0.784
* Analytical Flags: B = compound present in lab blank, E = concentration found above calibration limit, J = compound detected, but below the
quantitation limit.
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Pagel of 11
Run Number S-V-3-3
Run Date 7/27/98
Run Time 0938-0943
Net Run Time, minutes 5
Pbar Barometric Pressure, inches Hg 29.16
y Dry Gas Meter calibration factor 0.9360
Vm Sample Volume, liters 2.480
Tm Avg. Meter temperature, °R 542
AH Pressure diff. of meter, in. H2O 1.0
Vm(std) Sample Volume, dry std. liters 2.211
Qs Volumetric Flow Rate, dscfin 230
Tons of asphalt per test period 47.1
Acetone
Molecular Weight, g/g-mole 58.08
Target Catch, ug {3.199}
Concentration, mg/dscm {1.45}
Concentration, ppbvd {599}
Emission Rate, Ib/test period {1.04E-04}
Emission Rate, Ib/ton {2.21E-06}
Acrylonitrile
Molecular Weight, g/g-mole 53.06
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Allyl chloride
Molecular Weight, g/g-mole 76.53
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 2 of 11
Run Number S-V-3-3
Benzene
Molecular Weight, g/g-mole 78.11
Target Catch, ng {1.664}
Concentration, mg/dscm {0.752}
Concentration, ppbvd {232}
Emission Rate, Ib/test period {5.40E-05}
Emission Rate, Ib/ton {1.15E-06}
Bromodichloromethane
Molecular Weight, g/g-mole 163.82
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromoform
Molecular Weight, g/g-mole 252.77
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Bromomethane
Molecular Weight, g/g-mole 94.95
Target Catch, ug 0.130
Concentration, mg/dscm 0.0588
Concentration, ppbvd 14.9
Emission Rate, Ib/test period 4.22E-06
Emission Rate, Ib/ton 8.96E-08
1,3-Butadiene
Molecular Weight, g/g-mole 58.08
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 3 of 11
Run Number S-V-3-3
2-Butanone
Molecular Weight, g/g-mole 72.10
Target Catch, ug {2.931}
Concentration, mg/dscm {1.33}
Concentration, ppbvd {442}
Emission Rate, Ib/test period {9.52E-05}
Emission Rate, Ib/ton {2.02E-06}
Carbon disulfide
Molecular Weight, g/g-mole 76.14
Target Catch, ug 0.571
Concentration, mg/dscm 0.258
Concentration, ppbvd 81.6
Emission Rate, Ib/test period 1.85E-05
Emission Rate, Ib/ton 3.94E-07
Carbon tetrachloride
Molecular Weight, g/g-mole 15 3.84
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chlorobenzene
Molecular Weight, g/g-mole 112.56
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chloroethane
Molecular Weight, g/g-mole 64.52
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 4 of 11
Run Number S-V-3-3
Chloroform
Molecular Weight, g/g-mole 119.39
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Chloromethane
Molecular Weight, g/g-mole 50.49
Target Catch, ng 0.606
Concentration, mg/dscm 0.274
Concentration, ppbvd 131
Emission Rate, Ib/test period 1.97E-05
Emission Rate, Ib/ton 4.18E-07
Cumene
Molecular Weight, g/g-mole 120.19
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Dibromochloromethane
Molecular Weight, g/g-mole 208.27
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dibromoethane
Molecular Weight, g/g-mole 187.88
Target Catch, ^ig ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
n
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 5 of 11
Run Number S-V-3-3
1,1-DichIoroethane
Molecular Weight, g/g-mole 98.97
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Dichloroethane
Molecular Weight, g/g-mole 98.96
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,2-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-1,2-Dichloroethene
Molecular Weight, g/g-mole 96.95
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 6 of 11
Run Number S-V-3-3
1,2-DichIoropropane
Molecular Weight, g/g-mole 112.99
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
cis-l,3-Dichloropropene
Molecular Weight, g/g-mole 110.98
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
trans-l,3-Dich!oropropene
Molecular Weight, g/g-mole 110.98
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,2-Epoxy butane
Molecular Weight, g/g-mole 72.12
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Ethyl acrylate
Molecular Weight, g/g-mole 100.11
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 7 of 11
Run Number S-V-3-3
Ethylbenzene
Molecular Weight, g/g-mole 106.16
Target Catch, ug {2.716}
Concentration, mg/dscm {1.23}
Concentration, ppbvd {278}
Emission Rate, Ib/test period {8.82E-05}
Emission Rate, Ib/ton {1.87E-06}
n-Hexane
Molecular Weight, g/g-mole 86.17
Target Catch, ug {5.011}
Concentration, mg/dscm {2.27}
Concentration, ppbvd {633}
Emission Rate, Ib/test period {1.63E-04}
Emission Rate, Ib/ton {3.45E-06}
2-Hexanone
Molecular Weight, g/g-mole 100.16
Terget Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
lodomethane
Molecular Weight, g/g-mole 141.95
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Isooctane
Molecular Weight, g/g-mole 114.22
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 8 of 11
Run Number S-V-3-3
Methyl methacrylate
Molecular Weight, g/g-mole 86.09
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Methylene chloride
Molecular Weight, g/g-mole 84.94
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
4-Methyl-2-pentanone
Molecular Weight, g/g-mole 100.16
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
MTBE
Molecular Weight, g/g-mole 88.15
Target Catch, ug no data
Concentration, mg/dscm no data
Concentration, ppbvd no data
Emission Rate, Ib/test period no data
Emission Rate, Ib/ton no data
Styrene
Molecular Weight, g/g-mole 104.14
Target Catch, ug 0.490
Concentration, mg/dscm 0.222
Concentration, ppbvd 51.2
Emission Rate, Ib/test period 1.59E-05
Emission Rate, Ib/ton 3.3 8E-07
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 9 of 11
Run Number S-V-3-3
1,1,2,2-Tetrachloroethane
Molecular Weight, g/g-mole 167.86
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Tetrachloroethene
Molecular Weight, g/g-mole 165.85
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Toluene
Molecular Weight, g/g-mole 92.13
Target Catch, ug {3.903}
Concentration, mg/dscm {1.76}
Concentration, ppbvd {461}
Emission Rate, Ib/test period {1.27E-04}
Emission Rate, Ib/ton {2.69E-06}
1,1,1-Trichloroethane
Molecular Weight, g/g-mole 133.42
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
1,1,2-Tr ichloroethane
Molecular Weight, g/g-mole 13 3.42
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 10 of 11
Run Number S-V-3-3
Trichloroethene
Molecular Weight, g/g-mole 131.40
Target Catch, U£ ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Trichlorofluoromethane
Molecular Weight, g/g-mole 137.38
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl acetate
Molecular Weight, g/g-mole 86.09
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl bromide
Molecular Weight, g/g-mole 106.96
Target Catch, ng ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
Vinyl chloride
Molecular Weight, g/g-mole 62.50
Target Catch, ug ND
Concentration, mg/dscm ND
Concentration, ppbvd ND
Emission Rate, Ib/test period ND
Emission Rate, Ib/ton ND
-------
Summary of Stack Gas Parameters and Test Results
Volatile Organics - SW-846 Method 0030
Silo Exhaust Duct
Asphalt Plant C - California
Page 11 of 11
Run Number S-V-3-3
m-/p-Xylene
Molecular Weight, g/g-mole 106.16
Target Catch, ug {12.924}
Concentration, mg/dscm {5.84}
Concentration, ppbvd {1,324}
Emission Rate, Ib/test period {4.20E-04}
Emission Rate, Ib/ton {8.91E-06}
o-Xylene
Molecular Weight, g/g-mole 106.16
Target Catch, ug {3.540}
Concentration, mg/dscm {1.60}
Concentration, ppbvd {363}
Emission Rate, Ib/test period {1.15E-04}
Emission Rate, Ib/ton {2.44E-06}
ND indicates compound was not detected. A zero was used in the total and the value enclosed in parentheses ()•
Estimated values and totals using estimated values are enclosed in brackets {}.
-------
SW-846 Method 0030 Catch Weights in Micrograms, Test Run S-V-3, Test Set 3
Samples: S-V-3-3A (Tenax tube) and S-V-3-3B (Tenax/charocal tube)
'arget Compound
Acetone
Acrylonitrile
Allyl chloride
Benzene
romodichloromethane
Tomoform
Bromomethane
1 ,3-Butadiene
2-Butanone
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cumene
Dibromochloromethane
1 ,2-Dibromoethane
1,1-Dichloroethane
1 ,2-Dichloroethane
1,1-Dichloroethene
cis- 1 ,2-Dichloroethene
trans- 1 ,2-Dichloroethene
,2-Dichloropropane
cis-l,3-Dichloropropene
trans- 1 ,3-Dichloropropene
1,2-Epoxybutane
Ethyl acrylate
ithylbenzene
n-Hexane
2-Hexanone
lodomethane
sooctane
Methyl methacrylate
viethylene chloride
4-Methyl-2-pentanone
MTBE
Styrene
1 , 1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1 -Trichloroethane
1 , 1 ,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl bromide
Vinyl chloride
m-/p-Xylene
o-Xylene
Sample ID
Flag*
BE
BE
B
BE
B
BE
BE
B
BE
B
B
S-V-3-3A
catch, u,g
3.124
ND
ND
1.627
ND
ND
0.059
ND
2.881
0.571
ND
ND
ND
ND
0.253
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.716
5.008
ND
ND
ND
ND
ND
ND
no data
0.49
ND
ND
3.89
ND
ND
ND
ND
ND
ND
ND
12.92
3.54
Flag*
B
BJ
B
B
B
BJ
B
S-V-3-3B
catch, fig
0.075
ND
ND
0.037
ND
ND
0.071
ND
0.050
ND
ND
ND
ND
ND
0.353
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.003
ND
ND
ND
ND
ND
ND
no data
ND
ND
ND
0.00
ND
ND
ND
ND
ND
ND
ND
NE
ND
Flag*
BE
BEJ
B
BE
B
E
BEJ
BE
TOTAL
catch, u.g
3.199
ND
ND
1.664
ND
ND
0.130
ND
2.931
0.571
ND
ND
ND
ND
0.606
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.716
5.011
ND
ND
ND
ND
ND
ND
no data
0.490
ND
ND
3.903
ND
ND
ND
ND
ND
ND
ND
12.924
3.540
* Analytical Flags: B = compound present in lab blank, E
quantitation limit.
= concentration found above calibration limit, J = compound detected, but below the
-------
Summary of Stack Gas Parameters and
Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant
Pagel
RUN NUMBER
RUN DATE
C, California
of 15
S-M18-1A
7/24/98
RUN TIME 0920-1008
0 Net run time, minutes
Pbar Barometric pressure, in Hg
Bubble Meter Calibration Data
Pre-test
Time, seconds
Volume, milliliters
Ambient Temperature, "F
Post-test
Time, seconds
Volume, milliliters
Ambient temperature, °F
ACT Average calibration time, seconds
Vc Average calibration volume, milliliters
ta Average ambient temperature, °F
vm(std) Standard Meter Volume, Liters, dry
Qsd Stack Gas Volumetric Flow, dscfm
Tons of asphalt loaded per test period
Benzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Toluene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
120
29.28
60
977
68.0
60
979
68.4
60.0
978
68
114.8
503
745.4
78.1
42.7
0.372
115
1.40E-03
1.88E-06
92.1
294
2.56
669
9.65E-03
1.29E-05
S-M18-2A
7/25/98
0710-0954
120
29.26
60
993
67.8
60
1004
75.2
60.0
999
72
116.4
445
595.5
78.1
ND
ND
ND
ND
ND
92.1
ND
ND
ND
ND
ND
S-M18-3A
7/27/98
1023-1248
50
29.16
60
1020
84.7
60
992
93.7
60.0
1006
89
47.1
231
472.4
78.1
ND
ND
ND
ND
ND
92.1
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 2 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
rimethanolpentanol
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
rimethylhexane (RT=11.5)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trimethylcyclohexane (RT=13.2)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ethylbenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Ethylhexane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
130.0
213
1.86
343
6.99E-03
9.38E-06
128.2
397
3.46
649
1.30E-02
1.75E-05
126.1
228
1.99
379
7.48E-03
1.00E-05
106.2
126
1.10
249
4.14E-03
5.55E-06
114.1
618
5.38
1,135
2.03E-02
2.72E-05
130.0
ND
ND
ND
ND
ND
128.2
ND
ND
ND
ND
ND
126.1
ND
ND
ND
ND
ND
106.2
ND
ND
ND
ND
ND
114.1
ND
ND
ND
ND
ND
130.0
ND
ND
ND
ND
ND
128.2
204
4.33
812
3.12E-03
6.61 E-06
126.1
ND
ND
ND
ND
ND
106.2
ND
ND
ND
ND
ND
114.1
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 3 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
m-/p-Xylene (RT=13.8)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
o-Xylene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Nonane (RT=15.0)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylpentadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethyloctane (RT=15.9)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
106.2
571
4.97
1,127
1.87E-02
2.51 E-05
106.2
240
2.09
474
7.88E-03
1.06E-05
128.2
236
2.06
386
7.75E-03
1.04E-05
82.1
207
1.80
528
6.80E-03
9.12E-06
142.2
306
2.67
451
1.00E-02
1.35E-05
106.2
ND
ND
ND
ND
ND
106.2
ND
ND
ND
ND
ND
128.2
ND
ND
ND
ND
ND
82.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
106.2
366
7.77
1759
5.60E-03
1.19E-05
106.2
ND
ND
ND
ND
ND
128.2
435
9.23
1732
6.66E-03
1.41 E-05
82.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 4 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Methyloctane
Molecular Weight, g/g-mole
Target Catch, (jg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trimethylbenzene (RT=17.3)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Decane (RT=17.6)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trimethylbenzene (RT=18.0)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylnonane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
128.2
270
2.35
441
8.86E-03
1.19E-05
120.1
212
1.85
370
6.96E-03
9.34E-06
142.2
378
3.29
557
1.24E-02
1.66E-05
120.1
422
3.68
736
1.39E-02
1.86E-05
156.2
427
3.72
573
1.40E-02
1.88E-05
128.2
ND
ND
ND
ND
ND
120.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
120.1
326
2.80
561
9.34E-03
1.57E-05
156.2
ND
ND
ND
ND
ND
128.2
ND
ND
ND
ND
ND
120.1
ND
ND
ND
ND
ND
142.2
493
10.46
1770
7.54E-03
1.60E-05
120.1
ND
ND
ND
ND
ND
156.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page
RUN NUMBER
RUN DATE
RUN TIME
5 of 15
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Ethylmethylcyclopropane
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
84.1
310
2.70
772
1.02E-02
1.37E-05
84.1
ND
ND
ND
ND
ND
84.1
ND
ND
ND
ND
ND
Methylmethylenecyclohexane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
110.1
255
2.22
485
8.37E-03
1.12E-05 .
110.1
ND
ND
ND
ND
ND
110.1
ND
ND
ND
ND
ND
Dipropylcyclopropene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
124.1
210
1.83
355
6.89E-03
9.25E-06
124.1
ND
ND
ND
ND
ND
124.1
ND
ND
ND
ND
ND
Tetradecane (RT=20.0)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
198.2
444
3.87
469
1.46E-02
1.96E-05
198.2
ND
ND
ND
ND
ND
198.2
ND
ND
ND
ND
ND
Decahydromethy (naphthalene (RT=20.5)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
152.2
247
2.15
340
8.11E-03
1.09E-05
152.2
449
3.86
610
1.29E-02
2.16E-05
152.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 6 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Octadecyne
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylundecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylundecane (RT=22.5)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trimethyldecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tridecane(RT=24.1)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
250.3
314
2.74
263
1.03E-02
1.38E-05
170.2
492
4.29
606
1.62E-02
2.17E-05
184.2
538
4.69
612
1.77E-02
2.37E-05
184.2
246
2.14
280
8.08E-03
1.08E-05
184.2
393
3.42
447
1.29E-02
1.73E-05
250.3
ND
ND
ND
ND
ND
170.2
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
184.2
825
7.09
926
2.36E-02
3.97E-05
250.3
ND
ND
ND
ND
ND
170.2
ND
ND
ND
ND
ND
184.2
210
4.46
582
3.21 E-03
6.80E-06
184.2
ND
ND
ND
ND
ND
184.2
520
11.03
1441
7.96E-03
1.68E-05
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 7 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Trimethyldodecane (RT=25.7)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Trimethylheptane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Heptyn-1-ol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2,4-Dimethylheptane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
3-Ethyl-2-methylheptane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
212.2
320
2.79
316
1.05E-02
1.41E-05
142.2
ND
ND
ND
ND
ND
112.0
ND
ND
ND
ND
ND
128.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
212.2
ND
ND
ND
ND
ND
142.2
279
2.40
405
7.99E-03
1.34E-05
112.0
203
1.74
375
5.81 E-03
9.76E-06
128.2
288
2.47
464
8.25E-03
1.39E-05
142.2
192
1.65
279
5.50E-03
9.23E-06
212.2
257
5.45
618
3.93E-03
8.32E-06
142.2
ND
ND
ND
ND
ND
112.0
ND
ND
ND
ND
ND
128.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and
Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page
RUN NUMBER
RUN DATE
RUN TIME
Tetramethylcyclohexane (RT=16.7)
Molecular Weight, g/g-mole
Target Catch, |jg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Methylnonane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Heptenal
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
1-methyl-4-(1-methylethylidene)-Cyclohexane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
5-Methyl-3-undecene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
8 of 15
S-M18-1A
7/24/98
0920-1008
140.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
112.0
ND
ND
ND
ND
ND
138.1
ND
ND
ND
ND
ND
112.1
ND
ND
ND
ND
ND
S-M18-2A
7/25/98
0710-0954
140.2
323
2.77
476
9.25E-03
1.55E-05
142.2
378
3.25
549
1.08E-02
1.82E-05
112.0
437
3.75
806
1.25E-02
2.10E-05
138.1
187
1.61
280
5.36E-03
8.99E-06
112.1
421
3.62
776
1.21E-02
2.02E-05
S-M18-3A
7/27/98
1023-1248
140.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
112.0
ND
ND
ND
ND
ND
138.1
ND
ND
ND
ND
ND
112.1
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
PageS of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
5-Methyl-1-decene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Cyclodecene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylbicyclohexane-3-one
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylnonadiene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethyloctane (RT=20.0)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
154.2
ND
ND
ND
ND
ND
138.1
ND
ND
ND
ND
ND
152.1
ND
ND
ND
ND
ND
152.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
154.2
183
1.57
245
5.24E-03
8.80E-06
138.1
265
2.28
397
7.59E-03
1.27E-05
152.1
301
2.59
409
8.62E-03
1.45E-05
152.2
390
3.35
530
1.12E-02
1.88E-05
142.2
454
3.90
660
1.30E-02
2.18E-05
154.2
ND
ND
ND
ND
ND
138.1
ND
ND
ND
ND
ND
152.1
ND
ND
ND
ND
ND
152.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and
Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page
RUN NUMBER
RUN DATE
RUN TIME
Tetradecyloxirane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Decahydro-2-methylnaphthalene(RT=20.9)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Bromotridecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Undecyne
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dodecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
10 of 15
S-M18-1A
7/24/98
0920-1008
240.2
ND
ND
ND
ND
ND
152.2
ND
ND
ND
ND
ND
262.1
ND
ND
ND
ND
ND
152.2
ND
ND
ND
ND
ND
170.2
ND
ND
ND
ND
ND
S-M18-2A
7/25/98
0710-0954
240.2
219
1.88
188
6.27E-03
1.05E-05
152.2
348
2.99
473
9.97E-03
1.67E-05
262.1
287
2.47
226
8.22E-03
1.38E-05
152.2
225
1.93
306
6.44E-03
1.08E-05
170.2
415
3.57
504
1.19E-02
2.00E-05
S-M18-3A
7/27/98
1023-1248
240.2
ND
ND
ND
ND
ND
152.2
404
8.57
1355
6.18E-03
1.31E-05
262.1
ND
ND
ND
ND
ND
152.2
ND
ND
ND
ND
ND
170.2
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 11 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Trimethylcyclohexane (RT=22.9)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylundecane (RT=23.7)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylcyclooctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Cetylpyridinium chloride
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Tetramethylheptadecane (RT=25.7)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
126.1
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
140.2
ND
ND
ND
ND
ND
357.0
ND
ND
ND
ND
ND
296.3
ND
ND
ND
ND
ND
126.1
823
7.07
1,349
2.36E-02
3.96E-05
184.2
501
4.30
562
1.43E-02
2.41 E-C5
140.2
185
1.59
273
5.30E-03
8.90E-06
357.0
343
2.95
199
9.82E-03
1.65E-05
296.3
399
3.43
278
1.14E-02
1.92E-05
126.1
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
140.2
ND
ND
ND
ND
ND
357.0
ND
ND
ND
ND
ND
296.3
ND
ND
ND
ND
ND
-------
Summary of Stack Gas Parameters and
Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo
Asphalt
Exhaust Duct
Plant C, California
Page 12 of 15
RUN NUMBER
RUN DATE
RUN TIME
Tetradecane (RT=26.0)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylnonane (RT=15.9)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethyloctane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethyloctene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
2-Ethylhexanal
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-M18-1A
7/24/98
0920-1008
198.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
140.2
ND
ND
ND
ND
ND
126.0
ND
ND
ND
ND
ND
S-M18-2A
7/25/98
0710-0954
198.2
1,411
12.1
1,471
4.04E-02
6.79E-05
142.2
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
140.2
ND
ND
ND
ND
ND
126.0
ND
ND
ND
ND
ND
S-M18-3A
7/27/98
1023-1248
198.2
659
13.98
1697
1.01E-02
2.13E-05
142.2
288
6.11
1034
4.41 E-03
9.33E-06
142.2
487
10.33
1748
7.45E-03
1.58E-05
140.2
370
7.85
1347
5.66E-03
1.20E-05
126.0
215
4.56
871
3.29E-03
6.96E-06
h\
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 13 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Ethylmethylbenzene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Methylnonane (RT=18.2)
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Hexadecyne
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Undecene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dodecenol
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
120.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
222.2
ND
ND
ND
ND
ND
154.2
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
120.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
222.2
ND
ND
ND
ND
ND
154.2
ND
ND
ND
ND
ND
184.2
ND
ND
ND
ND
ND
120.1
759
16.10
3,226
1.16E-02
2.46E-05
142.2
455
9.65
1633
6.96E-03
1.47E-05
222.2
982
20.84
2256
1.50E-02
3.18E-05
154.2
326
6.92
1079
4.99E-03
1.06E-05
184.2
209
4.43
579
3.20E-03
6.77E-06
-------
Summary of Stack Gas Parameters and Test Results
GC/MS Qualitative Characterization of EPA Method 18 Samples
Silo Exhaust Duct
Asphalt Plant C, California
Page 14 of 15
RUN NUMBER
RUN DATE
RUN TIME
S-M18-1A
7/24/98
0920-1008
S-M18-2A
7/25/98
0710-0954
S-M18-3A
7/27/98
1023-1248
Pentenal
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
kflethyloctyne
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Decane (RT=19.9)
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Hexyldecanol
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Dimethylheptadecane
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
84.1
ND
ND
ND
ND
ND
124.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
242.3
ND
ND
ND
ND
ND
268.3
ND
ND
ND
ND
ND
84.1
ND
ND
ND
ND
ND
124.1
ND
ND
ND
ND
ND
142.2
ND
ND
ND
ND
ND
242.3
ND
ND
ND
ND
ND
268.3
ND
ND
ND
ND
ND
84.1
321
6.81
1948
4.91 E-03
1.04E-05
124.1
331
7.02
1361
5.06E-03
1.07E-05
142.2
619
13.13
2222
9.47E-03
2.00E-05
242.3
563
11.95
1186
8.61 E-03
1.82E-05
268.3
344
7.30
654
5.26E-03
1.11E-05
-------
Summary of Stack Gas Parameters and
Test Results
GC/MS Qualitative Characterization of EPA Method 18
Silo
Asphalt
Exhaust Duct
Plant C, California
Samples
Page 15 of 15
RUN NUMBER
RUN DATE
RUN TIME
Tetradecene
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Teteramethylheptadecane(RT=27.2)
Molecular Weight, g/g-mole
Target Catch, pg
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Pentadecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
Hexadecane
Molecular Weight, g/g-mole
Target Catch, ug
Concentration, mg/dscm
Concentration, ppbvd
Emission Rate, Ib/test period
Emission Rate, Ib/ton
S-M18-1A
7/24/98
0920-1008
196,2
ND
ND
ND
ND
ND
296.3
ND
ND
ND
ND
ND
212.2
ND
ND
ND
ND
ND
226.3
ND
ND
ND
ND
ND
S-M18-2A
7/25/98
0710-0954
196.2
ND
ND
ND
ND
ND
296.3
ND
ND
ND
ND
ND
212.2
ND
ND
ND
ND
ND
226.3
ND
ND
ND
ND
ND
Note: The Retention Time (RT) is shown after the compound name for TICs that
once and may be isomers.
S-M18-3A
7/27/98
1023-1248
196.2
231
4.90
601
3.53E-03
7.48E-06
296.3
386
8.19
665
5.91 E-03
1.25E-05
212.2
2,074
44.0
4,989
3.17E-02
6.72E-05
226.3
687
14.58
1550
1.05E-02
2.23E-05
appear more than
-------
APPENDIX A.3
EXAMPLE CALCULATIONS
-------
Example Calculations
Asphalt Plant C- California
US EPA Method 315-PM
(Using Data from Run T-M315-1)
Note: Discrepancies may exist between the computer generated reported results, which use
more significant figures, and the values manually calculated from the displayed values.
1. Volume of dry gas sampled corrected to standard conditions of 68 °F, 29.92 in. Hg, ft3.
m(std)
= 17.64V
> +^-
baf 13.6
460 + t
V = (17.64)(169.030)(1.001)
m(std)
29.35 +
1.62
460 + 86.4
V ... = 160.986 dscf
m(std)
2. Volume of dry gas sampled corrected to standard conditions of 68°F, 29.92 in. Hg, m3.
Vm(std)m3 - Vm(std)(0.028317)
- (160.986)(0.028317)
= 4.559 dscm
3. Volume of water vapor at standard conditions, ft3.
Vw(std) ^ 0.04707V1C
Vw(std) = (0.04707)024.0)
Vw(std) = 5.837 scf
\°n
-------
4. Moisture content in stack gas, as measured.
V
w(std) (10Q)
(v V )
\vm(std) vw(std)/
Bws = -
ws 160.986+ 5.837
Bws = 3.5
Moisture content in stack gas, at saturation. (Used as Bws if lower than measured
moisture)
BWS(sat) = lO'6-691-'3144'^390'86))) / PS * 100
g = j 0(6.691-(31447(85+390.86))) / 29.QQ * 100
BWs(sat) = 4'2
5. Dry molecular weight of stack gas, Ib/lb-mol.
Md = 0.44 (%CO2) + 0.32 (%O2) + 0.28(%N2+%CO)
M. = 0.44(0.0) + 0.32(20.9) + 0.28(79.1+0)
Md - 28.84 Ib/lb-mol
6. Molecular weight of stack gas, Ib/lb-mol.
Ms = Md(l-Bws/100) + 18(BWS/100)
Ms = 28.84(1-3.5/100) + 18(3.5/100)
Ms = 28.46 Ib/lb-mol
-------
7. Absolute stack gas pressure, in. Hg.
p
p _ p + static
s " bar 13.6
p = 29.35 + -
13.6
P. = 29.00 inches Hg
8. Stack velocity at stack conditions, ft/s.
v = 85 49 C
vs OJ.H? ^p vv—r/avg
ts+460
v. = (85.49)(0.84)(0.5736)
\
(85.3 + 460)
(28.46) (29.00)
vs = 33.5 ft/s
9. Isokinetic Variation.
o/ol -
) (t
(vs)(Dn2)(e)(Ps)(l-Bws/100)
(160.986) (85.3+460) (17.32)
(33.5) (0.258)2 (240) (29.00) (1-3.5/100)
= 101.6
-------
10. Stack gas volumetric flow rate at stack conditions, acfrn.
Qa = (60) (A) (vs)
Qa = (60) (5.59) (33.5)
Qa = 11,220 acfin
11. Dry stack gas volumetric flow rate at standard conditions, dscfm.
= 17.64 C> -
460)
I \
29-°° (1-3.5/100)
/
Qs(std) = 10,159 dscfm
12. Dry stack gas volumetric flow rate at standard conditions, dscmm.
Qs(cnun) = Qs(std) 0-028317
(0.028317)
Qs(cmm) = 288
-------
13. PM concentration, gr/dscf.
gr/dscf - (15.43)
^m(std)
11 r ft r AI\ 0.012o
gr/dscf = (15.43)
160.986
gr/dscf = 0.00123 gr/dscf
14. PM concentration, g/dscm.
g/dscm =
g/dscm =
*m(std)m3
0.0128
4.559
g/dscm = 0.00281 g/dscm
15. PM emission rate, Ib/test period.
... t . . (6) (g) (Qs(std))
Ib/test penod = v '
(453.592) (Vm(std))
,,u . . , (240) (0.0128) (10,159)
Ib/test period = -^ '—^ ^— -
(453.592) (160.986)
Ib/test period = 0.427 Ib/test period
-------
16. PM Emission Rate, Ib/ton.
lb/ton = Ib per test period
tons of asphalt loaded per test period
„, 0.427
lb/ton =
1,875.0
lb/ton = 0.000228 lb/ton
-------
Nomenclature
Y
AH
Pbar
vm
tm
Astatic
ts
Vic
C02
02
N2
ACP
Api/2
0
Dn
V,
' m(std)
m(std)m3
P.
Bws
Vw(std)
1-Bws
Ma
Ms
vs
A
Qa
Qs(std)
I
gr/dscf
g/dscm
Ib/test period
Ib/ton
Meter Box Correction Factor
Avg Meter Orifice Pressure, in. H2O
Barometric Pressure, inches Hg
Sample Volume, ft3
Average Meter Temperature, °F
Stack Static Pressure, inches H2O
Average Stack Temperature, °F
Condensate Collected, ml
Carbon Dioxide content, % by volume
Oxygen content, % by volume
Nitrogen content, % by volume
Pitot Tube Coefficient
Average Square Root Ap, (in. H2O)1/2
Sample Run Duration, minutes
Nozzle Diameter, inches
Nozzle Area, ft2
Standard Meter Volume, dscf
Standard Meter Volume, dscm
Stack Pressure, inches Hg
Moisture, percent by volume
Standard Water Vapor Volume, ft3
Dry Mole Fraction
Molecular Weight, dry, lb/lb»mole
Molecular Weight, wet, lb/lb»mole
Stack Gas Velocity, ft/s
Stack Area, ft2
Stack Gas Volumetric flow, acfrn
Stack Gas Volumetric flow, dscfin
Stack Gas Volumetric flow, dscmm
Isokinetic Sampling Ratio, %
Concentration, g/dscf
Concentration, g/dscm
Emission Rate, pounds per test period
Emission Rate, pounds per ton of asphalt loaded
-------
APPENDIX A.4
PARTICIPATE DEPOSITION DATA
-------
N
o
PM and MCEM Deposition Estimates for the TED and SED at Asphalt Plant C in California
Test Plates
Plate ID1
Test Plate 1 (T1)
Test Plate 2 (T2)
Test Plate 3 (T3)
Surface
Area2, sg ft
11.167
11.167
11.167
33.500
PM Catch,
grams3' '3
22.2140
14.4564
16.1247
52.7951
MCEM
Catch,
grams3' 13
0.8525
0.0475
0.3097
1.2097
Tunnel Exhaust Duct (TED)
TED
Diameter,
ft.
-
-
-
2.667
TED
Circumference,
ft.
-
-
-
8.373
TED
Length1, ft.
-
-
-
72.460
TED Inside
Surface
Area4, ft.
-
-
-
606.732
PM
Deposition,
pounds11
-
-
-
2.11
MCEM
Deposition,
pounds12
-
-
-
0.05
Asphalt
Loaded,
Tons5
-
-
-
75,347
PM
Deposition,
Ibs/ton
-
-
-
2.80E-05
MCEM
Deposition,
Ibs/ton
-
-
-
6.40E-07
SED Sample Area
Sample ID8
New SED
Old SED
Surface
Area7, sg ft
6.54
2.62
PM Catch,
grams3
188.0179
98.5125
MCEM
Catch,
grams3
2.9505
7.2225
Silo No. 2 Exhaust Duct (SED) - Upstream of Sampling Location
SED
Diameter,
ft.
0.833
0.833
SED
Circumference,
ft.
2.617
2.617
SED
Length8, ft.
3.500
3.500
SED Inside
Surface
Area, ft.
9.158
9.158
PM
Deposition,
pounds11
0.58
0.76
MCEM
Deposition,
pounds12
0.01
0.06
Asphalt
Loaded,
Tons9'10
8,142
600,000
PM
Deposition,
Ibs/ton
7.12E-05
1.27E-06
MCEM
Deposition,
Ibs/ton
1.12E-06
9.28E-08
Notes:
1. See Figure 1; note for the calculations the three plates were essentially treated as one large plate
2. Test plate dimension; 2.667 feet by 4.187 feet
3. PM - Particulate Matter, MCEM - Methylene Chloride Extractable Matter; Catch determined using EPA Method 315 analytical procedures
4. TED dimensions; 53.792 feet long by 8.373 feet circumference plus four times 4.667 feet long by 8.373 circumference
5. Test plates were in place from June 28, 1996 through July 26, 1998; tons shown is an estimate of the load-out tons from Silos 3, 4, and 5 white plates were in place
6. New SED was installed on July 19,1998 and cleaned on July 26,1998; Old SED was section of original SED in place from Plant C start-up through July 19, 1998
7. New SED sample suface area was 2.5 feet long by 2.617 circumference; Old SED sample area was 1 foot long by 2.617 circumference
8. SED length upstream of sampling location; equal to 2.5' plus 0.5' plus 0.5' (see page 4-4)
9. It was assumed that one fifth of the total tons loaded from July 23 to 26,1998 were loaded from Silo No. 2.
10. Old SED was in place from start-up; Plant C produced approximatley 3,000,000 tons since start-up; It was assumed that one fifth of tons was loaded into Silo No. 2
11. Calculated by multiplying the PM catch by the ratio of surface areas
12. Calculated by multiplying the MCEM catch by the ratio of surface areas
13, There is no clear explanation for the variation in the PM and MCEM catches for T1, T2 and T3.
Ndepositxis, TED & SED
-------
PM and MCEM Deposition for the Silo No. 2 Exhaust Plenum at Plant C - All Data
Box Pipes
Box Pipe ID
West North (WN)
West Center (WC)
West South (WS)
East North (EN)
East Center (EC)
East South (ES)
-
Surface
Area,1 sq ft
0.8333
0.8333
0.8333
0.8333
0.8333
0.8333
5.000
PM Catch,
grams2
0.2178
0.1305
1.0095
0.1282
0.1201
2.4825
4.0886
MCEM
Catch,
grams2
0.0042
0.0012
0.0121
0.0215
0.0059
0.0808
0.1257
Silo No. 2 Exhaust Plenum
Plenum
Surface
Area3, sq ft
-
-
-
-
-
-
158.948
PM
Deposition,
pounds*
-
-
-
-
-
-
0.2863
MCEM
Deposition,
pounds5
-
-
-
-
-
-
0.0088
Asphalt
Loaded,
Tons67
-
-
-
-
-
-
4,133
PM
Deposition,
Ibs/ton
-
-
-
-
-
-
6.93E-05
MCEM
Deposition,
Ibs/ton
-
-
-
-
-
-
2.13E-06
PM and MCEM Deposition for the Silo No. 2 Exhaust Plenum at Plant C - Excluding Contaminated Box Pipe '
Box Pipes
Box Pipe ID
West North (WN)
West Center (WC)
West South (WS)
East North (EN)
East Center (EC)
East South (ES)
-
Surface
Area,1 sq ft
0.8333
0.8333
-
0.8333
0.8333
-
3.333
PM Catch.
grams2
0.2178
0.1305
-
0.1282
0.1201
-
0.5966
MCEM
Catch,
grams2
0.0042
0.0012
-
0.0215
0.0059
-
0.0328
Silo No. 2 Exhaust Plenum
Plenum
Surface
Area3, sq ft
-
-
-
-
-
-
158.948
PM
Deposition,
pounds4
-
-
-
-
-
-
0.0627
MCEM
Deposition,
pounds5
-
-
-
-
-
-
0.0034
Asphalt
Loaded,
Tons6'7
-
-
-
-
-
-
4,133
PM
Deposition,
Ibs/ton
-
-
-
-
-
-
1.52E-05
MCEM
Deposition,
Ibs/ton
-
-
-
-
-
-
8.34E-07
Notes:
1. Six pieces of box pipe, 6 in. long by 3 in. 00 and 2.75 in. ID were installed in Silo No. 2 exhaust plenum (note:outside bottom sides were not exposed to fumes)
2. PM - Particulate Matter, MCEM - Methylene Chloride Extractable Matter; Catch determined using EPA Method 315 analytical procedures
3. Exhaust Plenum was divided into 10 sections for calculating the inside surface area
4. Calculated by multiplying the PM catch by the ratio of surface areas
5. Calculated by multiplying the MCEM catch by the ratio of surface areas
6. Box pipes were installed in Silo No. 2 exhaust plenum on July 23,1998 and removed on July 26,1998
7. It was assumed that one fifth of the total tons loaded from July 23 to 26,1998 were loaded from Silo No. 2.
8. WS and ES appeared contaminated with extraneous material when removed on July 26,1998; data excludes WS and ES from the calculation.
-------
N
o
CP
PM and MCEM Deposition Estimates for the Tunnel Ceiling Downstream of Silo No. 5 at Asphalt Plant C in California
Ceiling Plates
Plate ID1
CPW
CPC
CPE
Surface
Area2, sg ft
0.1576
0.1576
0.1576
PM Catch,
grams3
0.0299
0.0580
0.1420
MCEM
Catch,
grams3
0.0087
0.0132
0.0009
Tunnel Ceiling Downstream of Silo No. 5
Ceiling
Section ID
West
Center
East
Length,
feet
19.17
19.00
19.00
Corrugated
Length
Correction4
1.217
1.217
1.217
Width, feet
17.5
17.5
17.5
Surface
Area, sq ft
408.27
404.65
404.65
PM
Deposition,
pounds6
0.17
0.33
0.80
MCEM
Deposition,
pounds7
0.05
0.07
0.01
Asphalt
Loaded,
Tons5
20,666
20,666
20,666
PM
Deposition,
Ibs/ton
8.26E-06
1.59E-05
3.89E-05
6.30E-05
MCEM
Deposition,
Ibs/ton
2.40E-06
3.61 E-06
2.46E-07
6.26E-06
Notes:
1. CPW - Ceiling Plate West section, CPC - Ceiling Plate Center section, CPE - Ceiling Plate East section
2. Ceiling plate dimensions: 2.0625 inches by 11.0 inches
3. PM - Paniculate Matter, MCEM - Methylene Chloride Extractable Matter; Catch determined using EPA Method 315 analytical procedures
4. The ceiling was made of corrugated metal, correction takes into account the additional surface area, (i.e., linear length of 2.979 ft vs. total length of 3.625 ft)
5. Ceiling plates were installed on July 23,1998 and removed on July 26, 1998; tons shown are total load-out tons while plates were in place
6. Calculated by multiplying the PM catch by the ratio of surface areas
7. Calculated by multiplying the MCEM catch by the ratio of surface areas
Ndepositxls, Ceiling
-------
TED MM5
Sampling
Location
K—
. 32"
L-- \.
r- >
p-'
Section
A-A
Exhaust
Plenum
for Silo
No. 2
Exhaust
Plenum
for Silo
No. 3
Exhaust
Plenum
for Silo
No. 4
Exhaust
Plenum
for Silo
No. 5
1
r
T
56"
1
v>»A „ y
645.5 "
Figure 1 Location of TED Deposition Test Plates T,,T2, and T3
-------
APPENDIX A.5
CAPTURE EFFICIENCY CALCULATIONS
z\o
-------
N
TED LOAD-OUT EMtSSIONS BY COMPOUND; PM, MCEM & PAHs - ASPHALT PLANT C, CALIFORNIA
Asphalt Loss on Healing (RTFOT)
Load out Temperature (F)
'90% Lower Confidence Limit Capture Efficiency >
'PM
MCEM
.PAH
Acenaphthene
Acenaphthylen«
Anthracene
Benzo(l)anthracene
BenzoOOtluoranthene
BenzoOOfluonnthene
iBenzo(g,h,i)pery}ene
; BenzrX*)pyrene
Benzo(e)pyrMie
'Chryjene
i Dibenz(a,h)anthracene
Fluor jnthcne
IFIuorene
, lndeno( 1 ,2,3-cd)pyrene
>i*thylnaprithalene
JPyrene
Rl Loading
-0 362 !
321
064 !
As Measured " Corrected For CE% '
gr/dscf " #/ton gr/dscf */ton ;
1 2270E-03 2 2794E-04
1 92E-03 3 56E-04 ,
1 0737E-03 1 9945E-04 \ 1 68E-03 3 12E-04
ppbvd */ton [ ppbvd t tUlon
16298E-OI* I0231E-07 2 55E-01 1 60E-07 .
1 7023E-02 1 0686E-08
5 3276E-02 3 8651E-08
90523E-03 84122E-09
3S4I7E-03, 36377E-09
1 0404E-03 1 0686E-09
88931E-04 1 0004E-09
I.0626E-03 1 0913E-09
3 9847E-03 4 0924E-09
5 I380E-02 4 7745E-08
32107E-04 36377E-IO
33137E-02' 27283E-08
7 0567E-OI 4 7745E-07
3 8474E-04 . 4 5471E-10
I 4925E+00 8 6396E-07
82803E-01 43198E-07
1 1733E-02 1 2050E-08
658I2E-OI , 47745E-07
8 8374E-02 . 7.2754E-08
2 66E-02 ! 67E-08 ,
832E-02 604E-08 '
141E-02 )3IE-08i
5 53E-03 ' 5 68E-09 \
\ 63E-03 ' 1 67E-09 j
1 39E-03 1 56E-09 !
1 66E-03 ' 1 7IE-09 i
623E-03 639E-09 '
8 03E-02 , 7 46E-08 ',
5 02E-04 ' 5 68E-IO j
5 I8E-02 426E-08 |
1 10E+00 • 7 46E-07 j
601E-04 '7 10E-10 |
2 33E-KW ; 1 3SE-06
1 29E+OO ' 6 75E-07 ''
1 83E-02 i 1 88E-08 '
1 03E+OO 7 46E-07 '
I 38E-OI ! 1 I4E-07 <
R2 Loading : ,' R3 Loading |
-0322 " i ! -0284 ) -0323
316 ; ' 291
065 ^054
As Measured 1 Corrected For CE% ' ' As Measured Corrected For CE%
gr/dscf #/ton gr/dscf , #/ton i gr/dscf */ton gr/dscf »/ton
7 3875E-04 ' 1 7229E-04 ' 1 I4E-03 ' 2 65E-04 ' ' 8 5904E-04 1 I077E-04 ' 1 59E-03 ' 2 05E-04
22731E-04 S3011E-05 3 50E-04 . 8.I6E-05 . : 2 7287E-04 3 5I84E-05 5 05E-04 6 52E-05
ppbvd ' */ton * ppbvd ' *Aon
I 7707E-OI , 6 7037E-08 2 72E-OI 1 03E-07 '
20894E-02 ! 79104E-O9 . 3 21E-02 1 22E-08 '
3 3708E-02 ! 1 4748E-08 5 19E-02 2 27E-08 '
74I59E-03 4 I563E-09 1 I4E-02 639E-09 j
2 8137E-03 | 1 7430E-09 4 33E-03 . 2 68E-09 ' j
73590E-04! 45585E-10 1 13E-03 , 7 OIE-IO i ! '
652I7E-04, 44244E-IO 1 OOE-03 ' 68IE-IO
75760E-04 46926E-10 1.17E-03 ! 722E-IO i
2.5975E-03 . 1 6089E-O9 < 4 OOE-03 ' 2 48E-09 ' <
4 5455E-02 2 5474E-08 ' 6 99E-02 ! 3 92E-08 '
ND; ND ND [ ND i ,
25II1E-02 I 2469E-08 ' 3 86E-02 I 92E-08 J
3 2200E-01 ' 1 3139E-07 . 4 95E-01 ' 2 02E-07 ' j
ND, ND ND , ND J j
1 805IE-KXS ! 63015E-07 ' 2 78E+00 '969E-07 .' .
1 0227E-MX) ' 32178E-07 , 1.57E+00 i 495E-07 < | | '
60608E-03 , 37541E-09 .932E-O3 ! 5 78E-09 i ] !
3 9836E-OI 1 7430E-07 i 6 I3E-OI [ 2 68E-07 '' I ;
7 2910E-02 3 6200E-08 ' 1 I2E-01 j 5 57E-08 '' '
309
061
R1-R3 Average , Background
1
I
045
As Measured i Corrected For CE% ', ' As Mea
gr/dscf
942E-04
5 2SE-04
ppbvd
1 70E-OI
1 90E-02
4 35E-02
8 23E-03
3 I8E-03
888E-04
7 71E-04
910E-04
3 29E-03
4 84E-02
1 6IE-04
*/ton • gr/dscf Wton i gr/dscf
I 70E-04 1 55E-03 J2 75E-04 ' , 793E-04
9 59E-05
8 44E-04
1 53E-04 3 78E-04
*/ton [ ppbvd #/ton , ppbvd
8 47E-08
9 30E-09
2 67E-08
6 28E-09
264E-OI JI3IE-07 1 79E-02
2 94E-02 j 1 44E-08 2 60E-03
676E-02 I4I5E-08 6 I9E-03
1 28E-02 9 77E-09 3 29E-04
2 69E-09 4 93E-03 |4 I8E-09 ; 3 58E-04
CorCE% i
gr/dscf
1 76E-03 ',
8 40E-04
ppbvd j
397E-02 1
5.78E-03
1 38E-02
732E-04 '
7 95E-04
7 62E-10 1 38E-03 i 1 I9E-09 ND ND
7 21E-IO i 1 20E-03 | 1 I2E-09 1 36E-04
7.80E-IO
2 85E-09
366E-08
1 82E-IO
29IE-02 il99E-08
5 14E-OI
192E-04
I65E+00
9 25E-01
304E-07
227E-IO
747E-07
3 77E-07
8 90E-03 i 7 90E-09
5 28E-OI
3 26E-07
806E-02 '545E-08
1 41E-03 1 2IE-09 i ND
5IIE-03 443E-09' 2 58E-04
751E-02 J569E-08 6.81E-03
25IE-04
4 52E-02
799E-OI
3.01E-04
255E-K)0
I43E+00
1 38E-02
82IE-OI
1 25E-01
284E-10; ND
3 09E-08 i 7.44E-03
4 74E-07 4 83E-02
3 55E-10 i ' ND
1 1
1 16E-O6 . 9 I7E-02
5 8SE-07 ; i ND
1 23E-08 1 , ND
5 07E-07 ! , 1 13E-OI
8 47E-08 ; 1 49E-02
3 02E-04
ND.
574E-04
1 51E-02 !
ND
I65E-02 ,'
I07E-01 ;
NDi
204E-OI j
ND'
ND;
250E-OI '
331E-02 j
Ronspred xls
-------
TED LOAD-OUT EMISSIONS BY COMPOUND. VOHAPS - ASPHALT PLANT C. CALIFORNIA
Asphalt Loss on Hearing (RTFOT)
Load out Temperature (F)
90% LCL Capture Efficiency
VOHAPS
Acetone
Benzene (M 0030)
Benzene (M It)
, Benzene (Average)
Bromomethane
'2-Butanone
Carbon Disultlde
'Chloroethane
Chloroform
,Cumene(M0030)
'Cumene(M II)
' Cumene (Average)
'Elhylbenzene(M0030)
,Ethylbenzene(M18)
jEthylbenzene (Average)
;n-Hewne(M0030)
Hexane(MI8)
Hexane (Average)
ilsooctane
jMethylene Chloride
IMTBE
jStyrene
iTetrachloroeihene
'Toluene (M 0030)
•Toluene(M IS)
Toluene (Average)
|l,l,l-Trichloroethane
' Trichloroethene
^ 4i1orofluoromethane
l-Xylene(M0030)
ylene(MI8)
VA,fene(MI8)
!nWj>-Xylene( Average)
io-Xylene(M0030)
jo-Xylene(MI8)
!o-Xylene (Average)
Rl Loading
-0362
321
064
As Measured " Corrected For CE%
ppb j (Won ppb I */lon
8 I774E+00
4 3656E400
ND
-
1 1716E+00
3 5896E+00
298I7E-01
4 9262E-02
ND
2 I403E400
ND
1 3897E+OI
.
1 5825E+00
32I5IE+01
20445E+00
1 I799E+OI
-
ND
4 6293E+00
9 7868E-02
ND
25187E-OI
6 2887E+00
I7II6E-HH
ND
ND
56187E-02
922I4E+OO
6 9676E+OO
20815E+OI
2 8528E-H10
77983E400
1 608~9E-06 1 28E-K11 2 5IE-06
1 I55IE-06 682E+00
ND ND
3 7684E-07 1 83E+00
87673E-07 56IE400
76906E-08 . 466E-OI
1 0767E-08 7 70E-02
ND ND
3 6607E-07 . 3 34E+00
ND ' ND
5 7779E-06 2 I7E-H)I
.
569IOE-07* 247E+00
1 I807E-05 i 502E+01
S9679E-07' 3 I9E-HJO
3 5I70E-06"; 1 84E+01
-
ND* ND
1 3320E-06 ' 7 23E400
2 9224E-08 . 1 S3E-01
ND • NDj
1 4I5IE-07 3.94E-01
I.9626E-06 • 983E+00
5.4549E-06; 2S7E-KH
>
ND ' ND
ND ND
26I48E-08 , 878E-02
1 80E-06
ND
5 89E-07
1 37E-06
I 20E-07
1 68E-08
ND
5 72E-07
ND
903E-06
8 89E-07
1 84E-05
.
9 32E-07
550E-06
ND
2 08E-06
457E-08
R2 Loading
-0 322
316
065
R3 Loading R1-R3 Average
As Measured Corrected For CE% ,
, ppb (I/ton ppb
I43003E+00 1 0933E-06 662E-HX)
28510E+00 97480E-07 439E+00
68605E+00 2I508E-06 1 06E+OI
.
3 2497E-OI 1 3507E-07 5 OOE-OI
• 3 2905E+00 1 0385E-06 5 06E+00
1 0208E+00 3 4023E-07 1 57E-KX)
j ND'" "ND"' " ND
1 ND ND ND
1 326IE-KX) 29308E-07 204E+00
ND ND . ND
. 982IOE+00 47376E-06 1 5IE+OI
'
i 44I47E-OI 20515E-07 6 79E-OI
! 4044IE+OI * I 723IE-05 *622E+OI
,. _. .. . _.. j. .._
| 2 2634E400 ' 8 5375E-07 ' 3 48E400
2 2305E+OI , 7 7143E-06 , 3 43E+OI
.
2 I663E-OI 1 0831E4J7 ' 3 33E-OI
2 I694E-KX) ' 8 0660E-07 3 34E+00
42930E-01 1 6565E-07 660E-OI
NDj 29909E-OI 1 3634E-07 • 4.60E-OI
22IE-07
307E-06
852E-06
.
ND
ND
409E-08
33I62E-06, I44E40I j 5 18E-06
2 5588E-06 1 09E+OI
76441E-06 i 325E-K1I
I0259E-06 : 446E+00
2 8638E-06 1 22E40I
; _-
400E-06
1 I9E-05
.
I60E-06
447E-06
[ 20711E-OI ' 1.5036E-07 3.I9E-OI
234l3E-tOO 9.4422E-07 3.60E+«0
j 29I39E+OI ' 1 0775E-OS , 4.48E+01
.
ND ND . ND
i ND ' ND' ND
I72043"E-02 4.3325E-08 j "l 1IE-OI
124953E+00 1 I596E-06 3 84E+66
1 6 7599E400 2 8803E-06 1 04E+OI
1 318SE-KII ' 561861-06 203E+01
1 - , - i -
i 7 I568E-OI , 3 3258E-07 , 1.IOE4OO
«/lon
1 68E-06
1 50E-06
33IE-06
-
2 08E-07
1 60E-06
5 23E-07
~'ND'
ND
45IE-07
ND
729E-06
_
3 I6E-07
265E-05 !
1 3IE-06 .
1 19E-05
-
1 67E37"
1 24E-06 '
255E-07 ',
-0284
291 i
054 j
As Measured
ppb 1 A/ton
1 2449E+OOJ I9292E-07
1 8008E-HXH 37531E-07
ND ND
-
2 0806E-02
90970E-OI
26984E-01
527I1E-09
1 7500E-07
S 4820E-08
• "ND Mb
ND | ND
57127E-OI i 76959E-08
ND
ND
7 8532E-OI
1 2082E+OI
1 7608E+00
ND
-
4I5IIE-02
64426E+00
29135E-OI
2.10E37 , 38700E-OI
I31E-07 ! I.5724E-OI
145E-06 '
I66E-OS
.
ND"
ND'
6.67E-08 |
1 78E-06
4 43E-06
864E-06
5 12E-07
5 5693E+00 2 3730E-06 8 57E+00 i 3 65E-06
t r
2 6976E+00
1 I431E401
ND
ND
8 0530E-02
3 8224E400
ND
ND
1 3883E400
ND
ND
_
2 2244E-07
3.I488E-06
-0 323
309
061
Corrected For CE% , As Measured Corrected For CE%
ppb | Won < ppb Mon ppb . fl/ton
231E-HX) 1 357E-07 ' ' 4 57E+00 965E-07 !723E+00 ' 1 52E-06
333E+00 | 695E-07 30IE-HJO 8 35E-07 ' 4 85E+00 , 1 33E-06
ND • ND 229E+00 7 I7E-07 ' 3 52E+00 1 IOE-06
265E-MX) 776E-07 . 4 I8E+00 1 22E-06
3 85E-02
976E-09 506E-01 1 72E-07 i 790E-OI | 269E-07
1 68E+00 | 3 24E-07 | , 260E+00 697E-07 | 4 I2E+00 , 1 IOE-06
500E-01 !I02E-07 , 530E-OI ' 1 57E-07 ' 845E-OI 248E-07
ND [" NDJ , I«4E-02 ' 3 59E-09 ] 2 57BJ62 ' 56IE-09"
ND
I06E400
ND
I45E4OO
2.24E-KH
-
40482E-07
ND
-
1 265IE-08
1 4601E-06
6 8S2SE-08
l"075"3"E-07
6.9579E-08 j
663IIE-07
2 58S6E-06
_
ND
ND
2.95I8E-08
1 0827E-06
NT)
ND
326E+00
ND
-
769E-02
I.I9E4OI
5 40E-OI
7 17E-01
29IE-OI
5.00E-KW
2 I2E-KII
ND
ND
1 49E-01
708E+00
ND
ND
T
3.9323 E-07
ND ND
-
257E+00
ND
ND , , ND ND] ND ND
143E-071! I35E4OO 245E-07 2 I5E400 3 88E-07
ND ND ND! ND . ND
79IE-MX) 3.5IE-06 , 1 84E-K)! 8.16E-06
395E-KK) 175E-06 1 9.21E+OO ! 408E-06
4I2E-07 936E-OI 3 32E-07 i 1 54E+00 5 39E-07
5.83E-06 • ' 2.82E+OI ' 1.07E-05 , 449E-M11 I.69E-05
Background
' f
[ 045
As'Mea" CorrCE%'
2 6oft66 4 43E+00
1 07E-HX) 2 37E400
ND ND
534E-01 I.19E+00
9I5E-02 203E-01
[ 2 67E-oi ND
[ ND ND'
ND " ND
1 j 46E+OI 5 53E-06 , 2 32E401 8 73E-06 '
750E-07 ' j 202E+00 6 18E-07 ^sfE+OO . 999E-07
ND ' 1 1 I4E-KII 3 74E-06 ' 1 76E+01 ' 5 79E-06
6 70E+00 2 I8E-06 ' 1 04E-KM 3 39E-06
234E-08 860E-02 4 03E-OT i 137E-OI 634EJ08
270E-06 1 44IE+00 1 20E-06 J750E+00 • 201E-06
I27E-07J, 273E-01 8 78E-08 |45IE-0"l • 1 42E-07"
I99E-07 | i 229E-01 8 I3E-08 i 3 92E-01 I.36E-07
129E-071 1 205E-01 ' i 20E-07 T 3~34E-OI '< 1.94E-07
123E-06 i . 378E+00 1 I9E-06 j 6.14E-KX) ] L92E-06
4 79E-06 j . 1 92E+01 6 27E-06 ] 3 09E+OI . 9 96E-06
1 15E+01 373E-06 ; 1 85E+OI ' 5.94E-06
ND , ND NO] ND , ND |
ND • ND* Nb| ND ' ND
547E-08 ! , 696E-02 3 30E-08 1 I6E-01 , S41E-08
201E-06 5 I8E400 1 85E-06 j 844E+00 , 299E-06
ND ' ' 458E+OO 1 81E-06 i 7 10E400 28IE-06
ND ' 1 I3E+OI 442E^06 f I.76E+OI 686E-06
, 703E+00 270E-06 | 1 IOE-K11 , 422E-06
728E-07 ' I65E+00 5 84E-07 i 27IE-KX) | 948E-07
ND I . 446E+00 1 75E-06 6.92E+00 27IE-06
; - ' ' 3 05E+00 ! 1 16E-06 i 4 81E400 ' 1 83E-06
1 90E-02 4 22E-02
374E-OI 831E-01
ND ND
ND ND
ND ND
1 46E-OI 3 24E-OI
1.55E+OI 3.43E-H11
780E-HX) 173E+OI
3 90E-OI 8"67Eil
ND ND
1 95E-OI 4 33E-01
I.06E-OI 2.35E-01
I21E+01 268E-KI1
707E-0] ISTE-tOO
j 45E-OI l_ 3.22E-OI
865E-02 | I.92E-01
133E-KX) 295E400
1 05E-HI1 j 2 33E+01
5.90E400 ' 1 3IE+OI j
346F-02' j 755E-02"
287E-03 i 639E-03
742E-02 j I65E-01
409E-OI , 909E-01
NDi ND
ND' ND
I36E-OI' 303E-01
I 74E-01 I 3 87E-01
NDI ND]
87IE-02 ! I94E-OI'
-------
From: Scott Klamm
Send reply to: "sklamm@mriresearch.org"
To: "'MYERS.RON@epamail.epa.gov'"
Copies to: "TONEY.MIKE@epamail.epa.gov"1 ,
'"frank.phoenix@pes.com"'
Subject: CE calcs
Date sent: Thu, 10 Feb 2000 13:45:15 -0600
Organization: MRI
Ron,
Here are the revised capture efficiency (CE) numbers for Plant C.
These numbers reflect the final flowrates from PES, rather than the
original data set, which used some preliminary flowrates.
Run 1 = 64%
Run 2 = 65%
Run 3 = 54%
Run 4 = 45%
The revised capture numbers were determined using the Lower Confidence
Limit approach at the 90% level. Capture data from each test run was
broken into 7-10 approximately equal time intervals of greater than 20
minutes each. The exact number of individual time intervals for each
run was dependent upon the raw data and timing of SF6 data collection
within the run. Similarly, not every individual time interval was the
exact same length, and actual time intervals varied from 21 to 27
minutes in length, depending upon the data available for each run.
Note that Runs 1 and 2 now have nearly identical CE numbers, with Run
2 even being slightly higher. This is contradictory to the CE data
presented in the draft report, where we saw a steady decrease with
each succeeding test run. A close examination of the data shows that
the new trend makes sense, however, since we are now using the LCL
calculation, rather than the overall average for the test run. Run 1
had the highest overall average, but also had large variations,
thereby dropping the LCL value by quite a bit. Run 2, on the other
hand, showed greater precision, and thus the LCL value is not too much
different from the overall average. Runs 3 and 4 fall into place as
one would expect.
For the record, approximately 7 minutes of SF6 data from Run 1 was not
used for any of the CE calculations. This data was collected during
two separate time intervals less than the required 20 minutes, and the
method does not allow them to be included. The average capture
efficiency for these 7 minutes of data was calculated to be 80%.
Thus, we can conclude that dropping these data points creates a low
bias to the overall CE calculation for Run 1, and represents a
conservative adjustment of the data (beyond the LCL calculation).
I will be correcting Table 3-9 in MRI's Plant C report to reflect the
revised CE determinations. Summary tables of CE calculations for each
test run will be included in the Appendix, along with a detailed
listing of the exact time intervals used for the data subsets. The
Frank Phoenix « 1 - Fri, 11 Feb 2000 09:54:26
-Z.13 *~-
-------
appendix data will allow the reader to reconstruct a CE for any
individual time interval during a run in approximately 21-27 minute
intervals. If any of you need to see this data prior to the final
report, please call me and I will make copies available.
If there are other questions or comments related to the CE
determinations, please let me know.
Scott Klamm
Environmental Engineer
Midwest Research Institute
Frank Phoenix -- 2 -- Fri, 11 Feb 2000 09:54:27
-------
TECHNICAL REPORT DATA
Please read instructions on the reverse before completing
1. REPORT NO.
EPA-454/R-00-025A
2.
4. TITLE AND SUBTITLE
Final Report
Hot Mix Asphalt Plants,
Truck Loading and Silo Filling,
Manual Methods Testing,
Asphalt Plant C,
Los Angeles, California
Volume 1 of 8
7. AUTHOR(S)
Frank J. Phoenix
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Pacific Environmental Services, Inc.
Post Office Box 12077
Research Triangle Park, North Carolina 27709-2077
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emissions, Monitoring and Analysis Division
Research Triangle Park, North Carolina 2771 1
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE
May 2000
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D-98004
13, TYPE OF REPORT AND PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
The United States Environmental Protection Agency (EPA) Office of Air Quality Planning and Standards (OAQPS) is investigating hot mix
asphalt plants to identify and quantify participate matter (PM), methylene chloride extractable matter (MCEM), and organic hazardous air pollutant
(HAP) emissions during asphalt concrete loading operations. In support of this investigation, the OAQPS issued Pacific Environmental Services, Inc.
(PES) a series of work assignments to conduct emissions testing at a hot mix asphalt plant during load-out operations.
The primary objective of the emissions testing was to characterize the uncontrolled emissions of PM, MCEM, polynuclear aromatic hydrocarbons
(PAHs), semi-volatile organic hazardous air pollutants (SVOHAPS), and volatile organic hazardous air pollutants (VOHAPS) from a box mix
production plant during loading operations. An asphalt plant south of Los Angeles, California was selected by EPA as the host facility. Testing
was performed over five consecutive days beginning on July 24, 1998. Testing was performed under two conditions. Under normal operations, testing
was performed to characterize load-out emissions from the tunnel exhaust and load-in emissions from the asphalt concrete storage silo. Under
background conditions, testing was performed to characterize emissions from the combustion of diesel fuel in transport trucks.
The entire report consists of eight volumes totaling 4,234 pages, Vol.1 (388 pages), Vol. 2 (308 pages), Vol. 3 (573 pages), Vol. 4 (694 pages),
Vol. 5 (606 pages), Vol. 6 (564 pages), Vol. 7 (570 pages), and Vol. 8 (53 1 pages).
17.
a. DESCRIPTIONS
Hazardous Air Pollutants
Methylene Chloride Extractable
Matter
Paniculate Matter
Polynuclear Aromatic Hydrocarbons
Semi-volatile Organic Hazardous Air
Pollutants
Volatile Organic Hazardous Air
Pollutants
18. DISTRIBUTION STATEMENT
Unlimited
KEY WORDS AND DOCUMENT ANALYSIS
b. IDENTIFIERS/OPEN ENDED TERMS
19. SECURITY CLASS (This Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COASTI Field/Group
21. NO. OF PAGES
Vol. 1 - 388
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
F:\U\FMeadows\TRD.Frm\WP 6.1
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