EPA/540/2-89/033
SUPERFUND TREATABILITY
CLEARINGHOUSE
Document Reference:
PEI Associates, Inc. "Low Temperature Treatment of CERCLA Soils and Debris using
the IT Laboratory Scale Thermal Desorption Furnaces." Prepared for U.S. EPA, HWERL,
Cincinnati, OH. 120pp. October 1987.
EPA LIBRARY NUMBER:
Super-fund Treatability Clearinghouse - EZYQ
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Treatment Process:
Media:
Document Reference:
Document Type:
Contact:
Site Name:
Location of Test:
SUFERFUND TREATABILITT CLEARINGHOUSE ABSTRACT
Physical/Chemical - Low Temperature Thermal
Stripping
Soil/Generic
PEI Associates, Inc. "Low Temperature Treatment of
CERCLA Soils and Debris using the IT Laboratory
Scale Thermal Desorption Furnaces." Prepared for
U.S. EPA, HWERL, Cincinnati, OH. 120 pp. October
1987.
EPA ORD Report
Robert Thurnau
U.S. EPA, ORD
HVERL
26 W. St. Clair Street
Cincinnati, OH 45268
513-596-7692
BOAT SARM-Manufactured Waste (Non-NPL)
ORD - Edison, NJ
BACKGROUND; This study report on laboratory experiments on low temperature
treatment of soils using thermal desorption. The purpose of the study was
to determine if thermal desorption could remove volatile and semi-volatile
contaminants from a synthetically prepared soil spiked with predetermined
quantities of contaminants. This study supports the U.S. EPAs' program to
demonstrate various technologies for treating contaminated soils for the
purposes of CERCLA/SARA compliance with the proposed 1988 banning of land
disposal of wastes.
OPERATIONAL INFORMATION; The laboratory testing program consisted of 15
separate bench-scale tests. The EPA synthetic soil had two levels of
contaminants which are shown on Table 1. Thermal desorption test were
conducted at three temperatures 150°C, 350°C and 500°C for 30 minutes to
determine the effect of temperature on thermal desorption efficiency. The
surrogate soil or synthetic analytical reference matrix (SARM) is similar
to Superfund site soils and is 30% by volume clay, 25% silt, 20% sand, 20%
topsoil and 5% gravel. The SARMs were air dried to minimize moisture.
Approximately 80 gms of SARM soil were used in the tests in the tray fur-
nace. The tray furnace interior space is approximately 10 cm wide, 14 cm
high and 21 cm deep. A QA/QC plan is contained in the study. Gas bags
were utilized to collect off gas samples from the furnace and THC, CO, CH,
and C«Hc were analyzed by GC. Soils were analyzed for the remaining SARM
constituents using GC/MS.
PERFORMANCE; Thermal desorption of volatile and semi-volatile contaminants
from soils at moderate temperatures can be achieved with reasonable
success. At 550°C most of the volatile constituents are removed to below
the one/ppm level. Acetone appeared to remain in the matrix possibly due
3/89-40 Document Number: EZYQ
NOTE: Quality assurance of data may not be appropriate for all uses.
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to bound water in the soil. Semivolatile constituents are also removed to
a large extend except for pentachorophenol. Anthracene and phalate are
removed to levels near the detection limit. At 350°C temperature most of
the volatile contaminants are removed down to the 1 ppm level except for
acetone. Semivolatiles are reduced at 350°C, though not significantly.
The author cautions not to place quantitative credence in the results since
the precision of duplicate samples indicated that the data is only useful
in a qualitative manner.
CONTAMINANTS;
Analytical data is provided in the treatability study report. The
breakdown of the contaminants by treatability group is:
Treatability Group
WOl-Halogenated Aromatic
Compounds
W03-Halogenated Phenols,
Cresols, Thiols
W04-Halogenated Aliphatic
Solvents
V07-Heterocyclics and Simple
Aromatics
W08-Polynuclear Aromatics
W09-0ther Polar Organic
Compounds
WlO-Non-Volatile Metals
Wll-Volatile Metals
CAS Number
108-90-7
87-86-5
107-06-2
127-18-4
100-42-5
100-41-4
1330-20-7
120-12-7
67-64-1
117-81-7
7440-02-0
7440-47-3
7440-50-8
7440-38-2
7440-43-9
7439-92-1
7440-66-6
Contaminants
Chlorobenzene
Pentachlorophenol
1,2-Dichloroethane
Tetrachloroethene
Styrene
Ethylbenzene
Xylenes
Anthracene
Acetone
Bis(2-ethylhexyl)phthalate
Nickel
Chromium
Copper
Arsenic
Cadmium
Lead
Zinc
3/89-40 Document Number: EZYQ
NOTE: Quality assurance of data Hay not be appropriate for all uses.
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TABLE 1
SARM CONTAMINANTS UTILIZED IN
THERMAL DESORPTION TEST AND THEIR CONCENTRATIONS IN THE SOIL
(ppm)
High Low
Volatiles
Ethylbenzene 3200 320
Xylene 8200 820
Tetrachloroethylene 600 60
Chlorobezene 400 40
Styrene 1000 100
1,2 Dichloroethane 600 60
Acetone 6800 680
Semivolatiles
Anthracene 6500 650
Bis (2-ethylhexyl) phtahalate 2500 250
Pentachlorophenol 1000 100
Metals
Lead 280
Zinc 450
Cadmium 20
Arsenic 10
Copper 190
Nickel 30
Chromium 30
Note: This is a partial listing of data. Refer to the document for more
information.
3/89-40 Document Number: EZYQ
NOTE: Quality assurance of data may not be appropriate for all uses.
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LOW-TEMPERATURE TREATMENT OF
CERCLA SOILS AND DEBRIS USING THE
IT LABORATORY SCALE
THERMAL DESGRPTION .FURNACES
by
PEI Associates, Inc.
11499 Chester Road
Cincinnati, Ohio 45246
and
International Technology Corporation
304 Directors Drive
Knoxville, Tennessee 37923
Contract No. 68-03-3389
Task Assignment No. 5
PN 3724-5
for
U.S. Environmental Protection Agency
Hazardous Waste Engineering and Research Laboratory
26 W. Martin Luther King Drive
Cincinnati, Ohio 45268
Robert Thurnau, Project Manager
and
U.S. ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF SOLID WASTE
401 M STREET, SW
WASHINGTON, D.C. 20460
October 1987
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CONTENTS
Page
Section 1. Introduction 1-1
Purpose and scope 1-1
Technical background on thermal desorption 1-3
Thermal desorption equipment utilized 1-4
Section 2. Waste Description 2-1
Section 3. Description of Test Equipment and Procedures 3-1
Thermal Treatment Test Equipment 3-1
Standard Thermal Treatment Tray Test Procedure 3-6
Standard Procedure for Tube Furnace Tests 3-7
Section 4. Operating Data 4-1
Section 5. Sampling and Analysis Plan 5-1
Sampling point descriptions 5-1
Data and operating data collection 5-5
Safety considerations 5-6
Deviations from samples and analyses plan 5-6
Section 6. Analytical Results 6-1
Section 7. Quality Assurance and Quality Control 7-1
Section 8. Data Summary and Conclusions 8-1
Appendix A.
Appendix B.
Chain of Custody Records
Certificates of Analysis for Volatile*,
Sem1-volat1les, and Metals Analysis
A-l
B-l
11
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TABLES
Number Page
2-1 SARM Contaminants Utilized in Thermal 2-2
Desorption Test and Their Concentrations
in the Soil
4-1 PEI Soil Thermal Treatment Experimental Survey 4-2
4-2 Tray Test Operating Conditions Summary 4-3
4-3 Tube Test Operating Conditions Summary 4-4
6-1 Tray Test Results 6-2
6-2 Tray Test Removal Summary 6-3
6-3 Tube Test Soil Data Summary 6-4
6-4 Tube Test Soil Removal Summary 6-5
6-5 Tray Test Data Summary 6-6
6-6 Tray Test Soil Removal Summary 6-7
6-7 Soils Volatiles Analysis Summary 6-8
6-8 Soils Semivolatiles Analysis Summary 6-9
6-9 Soils Metals Analysis Summary 6-10
7-1 Precision Among Replicate Samples 7-2
7-2 Quality Assurance and Quality Control - 7-3
Laboratory Spikes
111
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FIGURES
Number Page
3-1 Schematic of Interior of Tray Furnace 3-3
with the Tray Inserted.
3-2 Schematic of the Tube Furnace Apparatus 3-4
and Collection System.
iv
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SECTION 1
INTRODUCTION
The U.S. Environmental Protection Agency (EPA) is evaluating best dem-
onstrated available technology (BOAT) treatment levels for contaminated
Superfund soils and debris for purposes of CERCLA/SARA compliance with the
proposed 1988 Land Ban. The Superfund exemption expires in November 1988.
These BOAT treatability levels are intended to provide the user community
with performance information on five technologies: Incineration*
temperature thermal desorptlon, chemical treatment, physical
ment, and solidification/stabilization. This project deals with the
temperature thermal dtserptlon technology.
PURPOSE AND SCOPE
The purpose of this project was to investigate the capability of a
laboratory-scale low-temperature thermal desorption technology to remove
volatile and semivolatile contaminants from a synthetically-prepared soil
spiked with predetermined quantities of these contaminants.
available lot rmrnnriira tiiiinnlnjlir and
.for tettiaft baAfc4j»-th* t*«4 eomb4*»et1e« of
availability that would mitt, the needs of the
project.
2) PrepiratlwTfSr a test awl QA/QC plan.
1-1
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3) Laboratory testing of the IT thermal desorption equipment using a
synthetic soil (supplied by EPA) that has been contaminated with
vol|L|1eSt semivolatiles and metals, at two different levels and at
thrfF*te.mperatures (150°, 350°, and 550°F) to determine the most
tmpirature range for pollutant removal.
4) SanpUnf and analysis of the process off-gas for volatile and
semi volatile compounds using approved EPA methods, to attempt to
develop a material balance for the thermal desorption process.
5) Analysis of the process residue for 1) volatiles, semivolatiles and
metals and 2) TCLP analysis (through Lee Wan Associates).
6) preparation of a report summarizing the results of the laboratory
testing and analysis.
The laboratory testing program consisted of 15 separate bench scale
tests (10 in a tray furnace and 5 1n a tube furnace). The EPA synthetic soil
with two levels (H1/H1 and low/low of volatile and sear!-volatile compounds
*
(and a low concentration of metals) wa» tested at IMP, 350* and 550*£,fer 9
minutes at temperature t* determine the effect of tH1t ran?* of teope«Ltures_
on removal of tfee contaminants. The tray furnace MM used to determine the
effectiveness of thermal desorption in removing contaminants from the soil.
The tube fugrn*«fcj*Mi-»•*-** provide daU oa tht^cgng^rAtioa of contami-
nants in the pf^-^.^fg&j^TOWiuofi Mitfe, *«& coecaatrettoM. in a* attempt to
establish? feMtiMtefc*********! It should also be noted that the tube furnace
data was not necessary to achieve the objectives of the project since removals
of volatiles and semi-volatiles from the tray furnace tests was the main
measurement objective.
For the tray furnace the bed of soil that is heated represented the
entire sample. For the tube furnace, all of the off-gas was collected as the
sample, and the remaining soil residue was also collected as a sample.
1-2
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The first series of 10 tests involved using the tray furnace. The high
and low soil contaminant levels was tested once each at 150° and 350°F (4
tests) and 3 times each at 550CF (6 tests) so that a statistical analysis of
the data would be performed on 550°F tests.
The second series of five tests involved use of the tube furnace to
simulate the generation of off-gas (desorbed volatiles) during thermal treat-
ment. One tube furnace test will be run at 150 and 350°F on the high concen-
tration of soil sample; three tube furnace tests will be run at 550°F also on
a high concentration sample.
TECHNICAL BACKGROUND ON THERMAL DESORPTION
The treatment of contaminated soils at elevated temperatures involves
many different potentially interrelated physical and chemical processes which
may occur simultaneously and/or consecutively. These various processes are
subject to unsteady- state conditions, and the relative significance of these
processes to treatment performance is expected to change during the treatment
period. Appropriate operating conditions to be employed in a thermal treat-
ment system, such as the IT Thermal Desorber can be selected based on an
understanding of these processes and the relationship between operating
conditions and soil characteristics, and corresponding treatment performance.
Much work has been done to describe the interaction between soil and
specific che»1cals and to define the mechanisms through which chemicals
change or migrate within a soil matrix. These mechanisms Include volatiliza-
tion, diffusion and mass flow, and reactions. However, the results and
conclusions from essentially all of this work, whether laboratory or field
studies, have been based on naturally occurring environmental forces at
1-3
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ambient conditions. Research findings, such as the correlation between the
organic content of the soil and the apparent affinity of the soil for a
chemical, and theoretical expressions which have been developed describing
the rate of mass flow of a chemical volatilizing through a static soil mass,
have been based on the relative importance of adsorption and diffusion
mechanisms.
Several obvious differences complicate the transfer of such scientific
information to the prediction of the behavior of a chemically contaminated
soil at conditions experienced in the thermal desorber. Most significant are
the physical and chemical changes that can occur as a result of the elevated
temperature. These changes include direct increases in such properties as
vapor pressure, diffusion coefficients, and reaction rate constants, in
addition to potential thermochemical modifications of the soil matrix and
the chemical itself which will drastically affect the interaction between the
chemical and the soil. Secondly, the soil within the desorber is in constant
motion, which minimizes the relative importance of diffusion of the chemical
through the soil matrix. Also, the gas flow passing through the desorber can
promote mass transfer of volatilized materials from the soil to the gas.
Through previous experience, IT has developed a basic understanding of
the dependent variables for the thermal desorption process. The experimental
plan for this project was developed to define these variables within the
intended operating range of concentration, time, and temperature.
THERMAL DESORPTION EQUIPMENT UTILIZED
Two major low-temperature thermal desorption systems have been tested at
the pilot-scale level. One is the IT thermal desorber, which is a rotary
1-4
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Indirect-fired calciner that was used as the desorber. The calciner consists
of a 3.3-meter-long by 16-cm internal diameter rotating tube through which
the soil is transferred, and a gas-fired furnace which surrounds the middle 2
meters of the tube length. The other is a thermal screw-type desorption
system developed for the U.S. Army Toxic and Hazardous Materials Agency
(USATHAMA) by Roy F. Weston, Inc. The soil is conveyed from the feed end of
the thermal processor trough by twin screws. An indirect heat transfer fluid
(oil) is circulated through pipes that run the length of the screw conveyor.
The oil is recycled continuously throughout the system.
The above-mentioned units were considered to be too large for the scope
of the present project. Large quantities of synthetic soil would be required
for testing and operational/analytical costs would far exceed the existing
project budget. Therefore, it was decided that a laboratory-scale test would
be the most efficient way to test the effectiveness of low-temperature ther-
mal desorption on the synthetically-spiked soils. Laboratory-scale thermal
desorption units were available from IT Corporation and were chosen for the
analysis because they were 1) of an adequate size in relation to the amount
of synthetic soil available; 2) readily available; and 3) provided the best
combination of efficiency, size, and availability to meet the needs of the
project.
The remainder of this report is organized as follows: Section 2 -
description of the synthetically-prepared soil used in this project; Sec-
tion 3 - description of the thermal desorption equipment utilized in the
project; Section 4 - summary of the operating log for the thermal desorption
tests; Section 5 - summary of the sampling and analysis plan; Section 6 -
presentation of analytical results; Section 7 - quality assurance/quality
control results.
1-5
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SECTION 2
WASTE DESCRIPTION
The contaminated soil that was tested during this project was a surro-
gate Superfund soil bearing a wide range of chemical contaminants typically
occurring at Superfund sites. The surrogate soil 1s referred to as SARM, an
acronym for synthetic analytical reference matrix. After considerable re-
search Into the types of soils found at Superfund sites nationwide, Em /
decided on a soil composition of 30 percent by volume clay (a matrix of mont-
morillinite and kaolinite), 25 percent silt, 20 percent sand, 20 percent
topsoil, and 5 percent gravel. These components were air-dried to minimize
moisture and mixed together in batches using a standard truck-mounted cement
mixer.
A prescribed list of chemicals found to be widely and frequently occur-
ring at Superfund sites was then added to the clean SARM in a series of
smaller-scale mixing operations. Organic chemicals added included ethyl ben-
zene, xylene, l,2-d1chloroethane, perch!oroethylene, acetone, chlorobenzene,
styrene, anthracene, pentachlorophenol, and bis(2-ethylhexyl)phthalate.
Salts or oxides of the following metals were also added: lead, zinc, cad-
mium, arsenic, copper, chromium, and nickel. Because contaminants occur in
soils at a wide range of concentrations, four different SARM formulas con-
taining either high or low levels of organics and metals were prepared for
use in various BOAT tests [soil washing, chemical treatment (KPEG), incinera-
tion, stabilization/fixation, and for this project, thermal desorption].
2-1
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The concentrations of volatiles, semivolatiles, and metals that were
used in this project are shown in Table 2-1.
TABLE 2\1. SARM CONTAMINANTS UTILIZED IN
THERMAL DESORPTION TEST AND THEIR CONCENTRATIONS IN THE SOIL
(pptn)
High Low
Volatiles
Ethyl benzene 3200 320
Xylene 8200 820
Tetrachloroethylene 600 60
Chlorobenzene 400 40
Styrene 1000 100
1,2-Dichloroethane 600 60
Acetone 6800 680
Semivolatiles
Anthracene 6500 650
Bis(2-ethylhexyl)phthalate 2500 250
Pentachloropnenol 1000 100
Metals
Lead 280
Zinc 450
Cadmium 20
Arsenic 10
Copper 190
Nickel 30
Chromium 30
2-2
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SECTION 3
DESCRIPTION OF TEST EQUIPMENT AND PROCEDURES
The results developed from this study were obtained using a simple and
consistent experimental method and apparatus designed to subject the study
soils to a specified temperature for a specified time. Treatability was
measured by comparing the analyses of the SARM constituents in the untreated
and treated soil. The test equipment and procedures are described in this
section. The features which were incorporated into the test system and
procedures included: 1) sufficient soil quantity to enable analytical sensi-
tivity below 1 ppm and duplicate analysis as necessary, 2) a static but very
thin layer of soil to minimize the potential effects of temperature gradients
and gas phase diffusion (in terms of both release of volatilized materials
and exposure to the purge gas), and 3) quickly achieving and maintaining
steady-state conditions. Considering the time-sensitivity placed on this
project, the equipment and procedures had to be readily available and proven
to be functional and reliable.
THERMAL TREATMENT TEST EQUIPMENT
Tray Furnaca
The principal test equipment was a Lindberg Furnace, Model 51848, with
an electronic temperature controller and 1600-watt heater system. The oven
p
is double-shell construction with interior surfaces made of Moldatherm a
molded aluminum-silicate insulation material. This oven 1s capable of oper-
ating up to 1100°C and has a relatively fast heat-up rate due to low mass.
3-1
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The interior space is approximately 10 cm wide x 11 cm high x 21 cm deep. A
loose block (1.2 cm thick) of Moldatherm is placed on the bottom of the oven
to provide additional separation between an object placed in the oven and the
hot interior surface of the oven. Incoloy (3/8 inch) tubing was inserted
through the back wall and connected to a nitrogen cylinder to provide a
continuous purge of the interior space during each test. The purge gas was
directed against the back wall to promote preheating and distribution. The
purge gas flowrate, which was measured using a standard rotameter, was main-
tained at approximately 90 cc/minute, equivalent to about 5 percent turnover
per minute. Two extra thermocouples were used to measure temperature. One
of these was an NBS-traceable, Type K, sheathed thermocouple placed approxi-
mately 3 centimeters above the soil surface at the center of the oven. This
was the thermocouple used to measure the "test temperature". The other extra
thermocouple was used for all tests where the temperature within a soil layer
was also measured. Both thermocouples, the temperature indicator, and the
purge gas rotometer were calibrated according to standard engineering prac-
tices. Temperatures were recorded using a Leeds & Northrup Speedomax 2500.
A specially made tray was used to contain the soil within the oven. The
tray which weighed approximately 430 grams, was 9 cm wide x 3.2 cm high x
19.3 cm long and made of Incoloy to resist oxidation at the expected maximum
test temperatures. A separate Incoloy lid was used to cover the tray when
necessary. Figure 3-1 is a schematic drawn to scale of the interior of the
oven with the tray inserted. Figure 3-2 is a photograph of the assembled
test apparatus.
A quartz digital chronometer was used to measure time during each test.
3-2
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:Y
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CO
I
PRESSURE
RELIEF
CONOENSER
m-J
NITROGEN
CYLINDER
FILTER
HOLDER
CONDENSATC
RECEIVER
IN ICE BATH
25O ml
BUBBLFR
BOTTLE
TENAX
TRAPS
c!
! ROTOMETER
TUBE FURNACE APPARATUS
PEI THERMAL
IT
ttOHTS
Sot«r Tomorrow
Figure 3-2. Schematic of the tube furnace apparatus and collection system.
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Tube Furnace
The second test apparatus used during the project was a Lindberg Mini
Mite Laboratory tube furnace, Model 55035 with a manual temperature con-
p
troller and an 800-watt heater. The furnace is constructed using Moldatherm
ceramic fiber insulation and heating element composite. The chamber size is
1 in. internal diameter x 12 in. long. A built-in thermocouple was used to
control the interior oven temperature to the set point. Thermocouples placed
in the bed were used to develop the time/temperature relationships for the
tests. Figure 4 is a photograph of the assembled test apparatus. Purge gas
which was measured using a standard rotameter was introduced into the 1-in.
outer diameter x 16-in. long quartz tube prior to the heated zone. The purge
gas passed through the bed of soil in the tube, into a water cooled condenser
then to an impinger (containing 0.1 N NaOH solution) followed by a particu-
late filter and two tenax traps in series. Residual gas was then collected
in a Tedlar gas bag. The condensate from the experiment was collected in a
cold finger submerged in an ice bath. Soil bed temperatures were monitored
using a Keithley Model 871 digital temperature indicator for both thermo-
couples. A quartz digital chronometer was used to measure time during each
test. Figure 3-3 provides a schematic of the tube furnace apparatus and
collection system.
For the low (150°F) experiments a larger oven was used since the small
furnace could not be adequately controlled at the low temperature. The oven
is a single-Mil transite oven, Blue M Electric Co., Model SW17TA. It has a
temperature range of 104° to 392°F. Because the bandwidth 1s 14-16°F wide,
it will be controlled manually. The Interior space 1s approximately 43 cm
wide x 46 cm high x 29 cm deep. For this experiment, the furnace was fitted
3-5
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with a nitrogen purge system capable of controlling at an equivalent volume
turnover rate as the small furnace. Since the relative volume of nitrogen
delivered to the furnace was quite large, the nitrogen was preheated before
entering the oven. The center of the oven was monitored via an NBS traceable
thermocouple and the soil temperature was also monitored. Temperatures were
recorded using the same L&N Model 2500 recorder as for the small furnace. To
prevent large temperature cycling within the oven, the oven heater control
was manually cycled on for approximately 2 to 3 seconds out of every 10
seconds through the run to keep the variation to within 5°F. It was found
that this type of adjustment prevented the 14°F temperature variation each 2
minutes that occurred with untended operation of the oven.
STANDARD THERMAL TREATMENT TRAY TEST PROCEDURE
A single procedure was established for all thermal treatment tray tests
except for several special tests described separately below.
The standard procedure consisted of the following steps:
1. Define and record planned experiment in the data book (i.e. time,
temperature, soil, etc.).
2. Weigh the empty, clean tray.
3. Transfer a representative aliquot (approximately 80 grams) of
prepared soil from the jar to the tray using a stainless steel or
PVC scupula.
4. Weigh the soil and tray and adjust the soil quantity to achieve
approximately 80 grams.
5. Distribute and level the soil within the tray to approximately
2.5 mn depth.
6. Turn on the purge gas flow on to the proper setting on the rota-
meters.
7. Place the tray with soil in the oven at ambient temperature and
close the oven door.
3-6
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8. Set the oven temperature controller set-point to the target test
temperature and start the timer.
9. Monitor and record the temperatures and time periodically through-
out the test period.
10. When the prescribed residence time at the target temperature is
reached, shut off the oven heater and purge gas flow and open the
oven door.
11. Cautiously withdraw the hot tray and soil using special tongs,
place a cover on the tray, and place the covered tray in a separate
hood for cooling for approximately 1 hour.
12. Close the oven door and set the temperature at 1000°C for approxi-
mately one hour. This step was prescribed in the QA/QC plan to
ensure no residual materials from the sample would remain in the
oven.
13. Weigh the tray (without cover) plus treated soil.
14. Transfer an aliquot (typically about 10 grams) of treated soil fcom
the tray to a tared, 60-cc, wide-mouth, amber bottle with Teflon -
lined cap. Code, label, and submit this aliquot for PCB analysis.
Transfer the remainder of the treated soil to an identical type
bottle, label and store as a retainer.
15. Clean the tray, cover, and nondisposable implements using the
following procedure:
0 Rinse with acetone and wipe clean
0 Scrub with detergent (Alconox ) solution and rinse with hot
tap water followed by distilled water
0 Rinse with acetone and allow to dry
0 Rinse three times with methylene chloride (e.g., approximately
15 to 25 ml each rinse for the tray)
0 Air dry and store.
STANDARD PROCEDURE FOR TUBE FURNACE TESTS
1) Define and record planned experiment in the data book (i.e. time,
t«ptrature, soil, etc.).
2) Weigh the empty; clean tube with glass wool and stopper in place.
3) Transfer a representative aliquot (approximately 100 grams) of
prepared soil from the jar to the tube using a stainless steel or
PVC scupula.
4) Weigh the soil and tube and adjust the soil quantity to achieve
approximately 100 grams.
3-7
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5) Place the tube in the furnace and connect the off-gas condensing,
filter impinger, filter, trap system, and turn on the cooling
water.
6) Turn the purge gas flow to the proper setting on the rotometer.
7) Close the oven, and set the heater at the proper power setting.
8) Monitor and record the temperature and time periodically through
the test period.
9} When the prescribed residence time at the target temperature is
reached turn off the power and lower the oven away from the tube.
10) Allow the tube to cool then shut off the purge.
11} Separate the tube from the gas train and weigh the tube and the
treated soil.
12) Record the volume of the condensate phases and weigh.
13) Transfer an aliquot (approximately 10 g) of treated soil from the
tube to a 60-cc wide-mouth bottle. Code and submit for analysis.
Store remaining sample.
14) Clean apparatus as prescribed for tray tests.
3-8
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SECTION 4
OPERATING DATA
This section provides a summary of the operating conditions during the
thermal desorption experiments performed for this project. Table 4-1 sum-
marizes the experiments conducted, including all sample numbers and key
operating parameters to facilitate cross referencing to the analytical re-
sults presented in Section 6.
The key operating parameters for these thermal desorption tests are
purge rate, soil temperature, and soil weight before and after treatment.
Tables 4-2 and 4-3 provide a description of the soil characteristics before
and after treatment, maximum and minimum soil temperatures during each ex-
periment, the time to reach the target temperature, and miscellaneous re-
corder data.
4-1
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TABLE 4-1. PEI SOIL THERMAL TREATMENT EXPERIMENTAL SUMMARY
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555 20-a 541*
55S-20-3A-M1*
555-3t-a-541«
555-77-a-541*
555-22-a-M1S
555 24 a 5415
55S-24-U-M1S
555 26-a 5415
555 28- a 5415
555 16 a 5415
555 3* 11 5415
5o1-7-a-5415
555 53 3A-S41*
555-53 M 5416
555 53-71 541*
555-74-11-541*
555-53-51 541*
HI-le-1
»tl-1*-2
HI-le-3
555-M-a 541*
555-54-7I-541*
555 54-M 541*
555 74 21- M1*
555 M-SC-MU
KI-17-1
Ptl-17-2
•fl-17-3
SSS-eS-SA-MU
555-*3 »-M1*
SS5-U-4I-M1*
SSS-74-H-M1*
555-*3-2t-M1*
Hi-i9-i
rtJ-19-2
P« 1-19-3
555-*7 a-M1«
555-47-7VM1*
SSS-*7-Ot-M1«
555-74-4»-*51*
555 47-4I-M1*
Ptl-20-1
•Il-M-I
Kl-tO-S
SSS-70-2»-M1*
5SS-70-7«-M1»
5SS-74-M-M1*
SSS-70-*|.M1«
HI -21-1
HI -21-2
HI-S1-S
MNH.I
TTH
tell
Sell
tell
tell
(oil
Seil
Sell
tell
tell
tell
tell
tell
tell
toil
tell
tell
Trep
Trip
Filter
fie*
fiee
fie*
Sell
Trep
Trep
liquid
Filter
fie*
CM
CM
tell
TPVB
'rep
Filter
CM
fie*
CM
tell
Trep
Trep
lleuid
Filter
•M
CM
tell
LlduTd
Filter
tee
•M
it
•OIL •
Ml*
Ml*
Ml*
Ml*
Ml*
M1*
Ml*
MIS
MIS
MIS
M1S
MIS
MIS
M1S
MIS
Ml*
Ml*
M1*
Mle
Ml*
Ml BQ>
ten • rm
MM -1 Trey
MM -1 Trey
MM • 1 Trey
MM • Trey
MM •
MM • Trey
MM • Trey
MM-II- Trey
MM- II- Trey
MM-ll-
MM- 1 1 • Trey
MM-II-1 Trey
MM-II-1 Trey
MM-ll-1
MM-II-1 Trey
MM-l-1 Tube
MM-l-1 Tube
MM-l-1 Tube
MM-l-1 Tube
MM-l-1 Tube
MMI
•ATI
cc/Bln
90
90
90
90
90 e
90
90
90
90
90
90 I
90 e
77
77
77
77
77
T*MIT
dea F
SSO
SSO
SSO
350
ISO
350
SSO
SSO
SSO
SSO
ISO
150
SSO
SSO
SSO
SSO
ISO
MM
•OIL TO*
*• F
548
SSI
341
1*1
S44
SSO
SSO
SS2
SSO
1S2
147
5*9
S*S
SM
Se*
IS*
8TMTIM
•OIL Iff
72
73
74
75
74
105
41
41
41
41
41
109
107
9*
114
10*
1
.98
.27
.15
.74
.2*
.*•
.*2
.22
.74
.97
.44
.97
.**
.•*
.SI
.IS
nUTIB S WT COCf.SED
•OIL VT IOSS MX.IXE
• «l
60.59 17.4 kont
40.20 17.8 Her*
61.18 17.5 Don*
63.08 16.7 Don*
M.99 9.8 Don*
17.0* 17.6 Don*
39.13 0 Don*
38.76 .0 ton*
S9.25 .0 »WH
39.85 .8 Non*
39. M .6 Non*
M.92 19.1 17
•.07 18.2 16.5
11.91 17.1 17
9S.M 17.9 19
102.47 1.4 0.2
10/16/67
4-2
-------
TABLE 4-2. TRAY TEST OPERATING CONDITIONS SUMMARY
TEMPERATURES DURING OESORPTION RUN DEC F
MINUTES
EXP f
PEI-1
PEI-4
PEI-S
PEI-7
PEI-24
PEI-1S
-p.
i
oo
pEi-a
PEI-9
PEI-10
PEI-lt
PEI-14
PEI-J7
PEI SOIL t STMTINB Mil TREATED SOIL
DESCRIPTION DESCRIPTION
SARD- wet.stickv.clay-llke
SARD- strong organic odor
SARM- trey -brown color
SARN- stone* up to 3/8"
SARM'
SARM*
grey hard luapy residue
needed to be chipped
out of the tray
lighter grey color-aUaost
_ light brown, sol id, hard
light grey edges. net brown
spots
SARM- II fine brown, grey powder loo»e brown, grey powder
SARN- II MM tuapt present COM dark patches
SARM- II will peck and hold shape _
SARM- II _ brown with few dark patches
SARM- II light brown tan color
SARM II
TARGET
550
550
550
350
350
150
550
550
550
350
150
150
MAXIMUM MAXIMUM
CONTROL SOIL
559
561
561
365
369
160
560
560
562
370
162
160
549
551
551
341
344
161
550
550
552
350
152
147
MINIMUM
CONTROL
544
543
544
343
347
150
545
545
546
350
150
150
II
MINIMUM || TINE TO
SOIL || REACH TARGET
432
412
384
182
188
91
432
432
444
237
104
104
It
II
II
II
II
II
II
II
II
1 1
II
II
II
II
II
II
II
13.5
12.75
13.0
6.2
10.2
1.5
8.25
8.33
8.33
5.67
2.67
3.0
RECORDER DATA
CHART RANGE 0 - 600 f
CHART SPEED 15 inches/hour
PMNT 01 soi I teop at front of tray (a)
POINT f2 soil tea? in center of tray
POINT n control thermocouple 1/4" above center of tray
a) point 01 wonitor N2 inlet tewp for 150 F runs
rev 10/15/87
-------
TABLE 4-3. TUBE TEST OPERATING CONDITIONS SUMMARY
TEMPERATURES DURING DESORPT10N RUNS DEC F
MINUTES
ML VOL
EXP
PEI
PEI
PCI
0 PCI SOIL 0
-16 SMN-I
•17 SMN-I
-19 SMN-I
PEI -20 SMN-I
PCI
-1*
PEI
PCI
PCI
PCI
PCI
•21 SMN-I
0 PCI SOIL •
-16 SMN-I
-17 SMN-I
-19 SMN-I
-20 SMN-I
-21 SMN-1
BJMTIIW SOIL
otMflHPTIQsl
wet.atlcky clay Mfth
strong organic odor
gray-brow color
stones 19 to 3/8- _
— —
CONDENSER DESCRIPTION
Mhito crystalline solids.
•lightly pinkish on cold side
slightly yell on- orange on
hot furnace side of the
condenser inlet
soa» uhita crystalline solids
in condenser Inlet
no solids, SOM condensation
TREATED SOIL
DESCRIPTION
grey. hard luapy dry
solids
grey hard dry luapa
no apparent change
COMPENSATE VOLUMES
AQUEOUS ORGANIC
IS 2
14.5 2
IS 2
17 2
0.2 0
TMGET
550
550
550
350
150
MAXIMUM
SKIN
555
552
542
365
168
PAPER F UTTER Iff
BEFORE
.3874
.3895
.3827
.3872
.3888
AFTER
.3881
.3904
.3830
.3871
.3888
MAXIMUM
SOIL
569
565
559
364
158
TRAP
TENAX
T1886
T3717
T3316
T3029
T3463
MINIMUM MINIMUM
SKIN SOU
517 541
516 549
512 540
320 350
145 150
NUMBERS
TENAX+CNARCOAL
TC2294
TC2297
TC3609
TC1813
TC3455
|| TINE TO || 0.1 N NaOH
|| REACH TMGET jj SCRUBBER
|| 21.0 || 200
|| 21.2 || 200
|| 20.0 || 200
II 23.0 || 200
II H.5S || 200
GAS BAG VOLUMES (I)
01 02 03
1.62 1.16 1.16
1.63 1.16 1.16
1.54 1.16 1.16
1.77 1.16 1.16
1.10 1.16 1.16
_ in all ports of tho
RECORDER SETTINGS
chart range - 0-600 F
chart speed • 15 inches/hr
point 01 • inlet N2 temp
point 03 • soil/control te*p
point 05 - tube skin temp
point #6 - heating tape temp
Rotameter range * 0 -190 cc/aiin
Inlet rotaneter a 41 Xfs
rev 10/16/87
-------
SECTION 5
SAMPLING AND ANALYSIS PLAN
SAMPLING POINT DESCRIPTIONS
Tray Test Runs
The lab scale miniature muffle furnace was operated according to the
1 2
descriptions in the QA plan. The large sample aliquot was removed from
the storage refrigerator and a small aliquot was transferred to the tared
tray. The soil was leveled as much as possible using a stainless steel
spatula and then rewelghed. This weight was recorded 1n the notebook as the
wet sample weight. The tray with the wet soil was then transferred to the
oven (previously cooled to ambient temperature) and heating started as soon
as the oven door was closed.
Time at temperature was taken from the point that the internal oven
temperature monitor indicated the desired operating temperature.
At the end of the time at temperature, the tray was removed from the
oven with a pair of tongs, covered with a I1d, and allowed to cool to ambient
temperature in a separate hood.
After cooling, the tray with the treated sample was reweighed, and an
aliquot of tht treated soil was transferred to a 60-cc wide-mouth amber jar,
D
capped with a Teflon -lined lid and kept refrigerated until delivery for
analysis.
The remainder of the unanalyzed sample was transferred to a separate
o
60-cc wide-mouth amber jar, capped with a Teflon -lined lid, and stored in a
refrigerator.
5-1
-------
The tray and all associated tools were then cleaned according to the
techniques prescribed in the QA plan.
Tube Furnace Test Sampling
The downstream portion of the tube furnace system was assembled, as
follows, before soil was added to the tube.
D
The cleaned Tedlar gas bags were first evacuated, clamped shut, and
attached to the exhaust gas manifold.
The cooling water lines were attached to the cleaned condenser and it
was positioned for attachment to the tube furnace. The condensate receiver
was attached to the condenser and the cleaned bubbler was filled with 200 ml
of fresh 0.1N NaOH and attached to the condenser system. The preweighed
clean paper filter was placed in the cleaned filter holder and the filter
holder was attached to the outlet of the bubbler.
At this time the new Tenax, and Tenax plus charcoal tube pairs were
removed from their packages, unsealed, and connected to the outlet of the
filter holder and then to the gas bag manifold. In this way, the Tenax traps
were isolated from the atmosphere by the water seal on the scrubber and the
pinch clamps on the gas bag manifold until the purge gas was started in the
tube run.
After the gas collection system was assembled the clean quartz tube was
tared. The large soil aliquot was then removed from the refrigerator and a
portion transferred to the quartz desorption tube using a stainless spatula.
The tube plus wet soil was weighed and then attached to the remainder of the
desorption system and the assembly completed by raising the cold furnace into
position and clamping it around the glass tube. The heating tape was wrapped
from the exhaust end of the furnace to the front edge of the condenser and
5-2
-------
the ice bath placed around the condensate receiver. After completing the
assembly the system was inspected to make sure it was ready to begin heating.
The heating tape was turned on and allowed to reach 100°C before starting the
furnace and the purge gas. As when the furnace was turned on and the purge
gas started, temperature recording began and one of the gas bags was opened
to the system. When the soil temperature, (measured by a thermocouple posi-
tioned in the soil in the center of the furnace) reached the desired oper-
ating temperature, the time at temperature was started. That temperature was
held as closely as possible for 30 minutes. At the start of the 30-minute
period, the first gas bag was clamped shut and a second gas bag was opened to
the system for 15 minutes. A third gas bag was opened to the system for the
final 15 minutes of the run.
At the end of the 30-minute period, the furnace was turned off, the
purge gas was shut off, the gas bag manifold was clamped shjt, and the fur-
nace was lowered away from the quartz tube to allow the tube to cool to
ambient temperature.
The Tenax traps were removed from their position on the collection
system, recapped with their initial plugs, and repackaged in their capped,
glass shipping tubes. The tube pair was then labeled, sealed in a labeled
ziploc bag, and refrigerated until delivery for analysis.
The scrubber bubbler solution was transferred to a 250-ml amber bottle,
p
capped with1» Teflon -lined I1d, labeled, and refrigerated.
The paper filter was removed from the filter holder and equilibrated in
a dessicator for 30 minutes. The filter holder was rinsed with approximately
30 to 40 ml of methylene chloride into a 60-cc wide-mouth amber bottle. The
paper filter was weighed after equilibration, added to the jar with the
p
rinses, and the jar was capped with a Teflon -lined I1d and refrigerated.
5-3
-------
The condensate receiver was then removed and the volumes of any distinct
phases were recorded. The liquid was then transferred to a 60-cc wide-mouth
p
amber jar, capped with a Teflon -lined lid, labeled, and refrigerated.
The condensate receiver was reattached to the condenser and the con-
denser was removed from the quartz tube. A mixture of 30 ml of HLO plus 30
ml of methylene chloride was then poured into the condenser and the condenser
capped. The condenser was inverted several times to dissolve the crystalline
solids that had collected in the upper portion of the condenser. When the
solid had dissolved the liquid was transferred to another 60-cc wide-mouth
p
amber jar which was then capped with a Teflon -lined lid, labeled, and re-
frigerated. ,
The quartz tube with the treated soil was then removed from the system
and weighed. An aliquot of the treated soil was removed with a clean stain-
less spatula into a 60-cc wide-mouth amber jar which was then capped with a
p
Teflon -lined lid, labeled, and refrigerated.
The remainder of the treated soil was transferred to a second 60-cc
p
wide-mouth jar, capped with a Teflon -lined lid, labeled, and refrigerated.
The entire glassware portion of the collection system and the quartz
tube were then cleaned as prescribed in the QA plan.
When the samples were ready to be delivered for analysis, the aqueous
condensate, the condenser rinse, and the scrubber solutions were composited
p
into a 500-a) amber jar, capped with a Teflon -lined lid, and relabeled using
the standard notebook number, page number, sample number, and logbook number
coding system (I.e. No. 555-70-1R-5416). This numbering system was used for
all samples delivered to an external analytical lab and referenced on the
sample analysis request sheet and the chain of custody forms delivered with
5-4
-------
the samples. The samples were hand delivered in an insulated cooler with ice
to keep the samples cold and to minimize volatile losses.
The gas bag samples were immediately analyzed or analyzed the next day
for total hydrocarbons as methane, and for carbon monoxide, methane, and
ethane.
DESIGN AND OPERATING DATA COLLECTION
During the tray desorption runs the temperature of the soil in the tray
and the temperature in the center of the oven just above the top of the tray
were recorded using an L&N Speedomax 2500 recorder using a range of 0° to
600°F. Any changes in the set points of the oven during the run were noted
on the chart paper or in the notebook during the run. Pertinent observations
before the run, during the run, and at the completion of the run were record-
ed in the notebook. Sample weights before the run and at the completion of
the run were recorded in the notebook.
During the tube furnace desorption runs, the temperature of the soil in
the center of the oven and the temperature of the glass outlet in front of
the condenser were recorded continually using an L&N Speedomax 2500 recorder
using a range of 0° to 600°F. Sample weights of the soil before and after
treatment were recorded in the notebook. Purge gas type and rotometer read-
ings were taken at the beginning of the run. Any unusual fluctuations of the
flow or the pressure at the front of the tube were also recorded in the note-
book. Liquid volumes used in the scrubber and weights of the paper filters
used were also recorded. Tenax trap pair numbers were also recorded in the
notebook for reference. At the end of the run, discrete samples produced
during the run, such as condensate, scrubber, traps, soil, filter, and rinses
5-5
-------
were separately bottled and labeled. When appropriate, volumes of discrete
condensate phases produced were also recorded in the notebook.
SAFETY CONSIDERATIONS
Since the contaminants present in the sample soil were at times both
toxic and volatile, sample handling where possible was done in a properly
vented fume hood. All experiments were done with the apparatus inside a
properly vented fume hood.
Care was taken to prevent escape of flammable volatiles into the labora-
tory atmosphere or near working electrical components by careful positioning
of auxilary equipment. Nitrogen gas was used as a purge to maintain a non-
flammable atmosphere above the soil.
When working with the starting soil or with treated soil or its con-
densed off gas components, the operator suitable wore gloves to prevent skin
contact with any contaminants.
DEVIATIONS FROM SAMPLING AND ANALYSES PLAN
During the lowest operating temperature experiments a different oven was
used to heat the tray samples. The oven was a Blue M Model SW 17TA single-
wall transit oven.
The oven was modified to allow introduction of the nitrogen purge gas at
the rear of the oven. Due to the large interior volume of the oven (approxi-
mately 57 lltars) the purge gas was preheated near the Intended operating
temperature to prevent overcooling of the oven by the volume of purge gas
necessary to obtain an equivalent gas exchange rate to the small furnace.
The actual gas flow rate was 2.8 Uters/min.
5-6
-------
Since the oven used a very simple controller, the oven heat was cycled
on manually for approximately 2 seconds out of every 10 seconds during the
run. This manual adjustment kept the temperature bandwidth of the oven to
within 5°F, whereas the natural bandwidth of the oven was approximately 14°
to 16°F with a cycle time of 2 minutes.
For the analysis of the Tenax and Tenax plus charcoal traps for vola-
tiles, the traps when received were spiked with 50 ug of surrogate standards
and then emptied into 20 ml of Methanol. The mixture was sonicated and 50 ul
of each trap solution was added to reagent water to make 5.0 ml of purging
solution. (Total extracts vol » 100 ul in 5 ml of water). This solution was
then analyzed by purge and trap GC/MS.
Recovery of the surrogates was within an acceptable 30 to 100 penient
range and the resultant analyses, corrected for dilution, represent the total
recovered micrograms of contaminant per trap pairs.
5-7
-------
SECTION 5
REFERENCES
1. PEI Associates. Test Plan and Quality Assurance Plan for Low
Temperature Treatment of CERCLA Soils and Debris. August 1987.
2. PEI Associates. Response to Comments on Test Plan and Quality Assurance
Plan for Low Temperature Treatment of CERCLA Soils and Debris. October
1987.
5-8
-------
SECTION 6
ANALYTICAL RESULTS
The data shown previously in Tables 4-1 through 4-3 provided a summary
of the experiments conducted during this project. All sample numbers and the
key operating parameters were presented in these tables to facilitate cross
referencing between operating and analytical results that are presented in
this section.
Table 6-1 shows the residual containment concentration of all compounds
monitored during the tray tests. Table 6-2 shows these results as a percent
removal based on the average starting concentration of the contaminants on
SARM-I-1 soil. Table 6-3 shows the residual contaminant concentration and
the treated soils from the tube test experiments. Table 6-4 shows these
results as a percent removal based on the average starting concentration of
the contaminants on the SARM-I-1 soil.
Table 6-5 shows the residual contaminant concentration of all compounds
monitored during the tray tests using SARM-II-1 starting soil. Table 6-6
shows these results as a percent removal based on the average starting soil
concentration.
Tables 6-7 through 6-9 show the compiled results of all experiments for
volatiles, semivolatiles, and metals, respectively.
The numbers given in the tables listed above are corrected to a wet
weight basis using the moistures determined by the analytical lab and the dry
weight basis results quoted.
6-1
-------
TABLE 6-1. TRAY TEST RESULTS
SAW 1-1 (11*5*16)
Starting soil
TRAY TEST RESIDUAL SOIL CONCEMTRAT lON(ppa)
MET WT BASIS lime at taap > 30 Minutes
VOIATILES
ACETONE
CNLOMKNZEME
1.2 D1CMLOROETHANE
ETHYL 8ENZENE
STVRENE
TETRACHLOROETNVLENE
XYLENE
SEMI -VOLATILES
ANTHRACENE
•IS(2 ETHTL-NEXVL )PNTHALATE
PEHTACNLOROPHENOL
METALS
ARSENIC
CADMIUM
CHROMIUM
COPPER
LEAD
NICKEL
ZINC
RESIDUAL X MOISTURE
•
AM!
6.800
400
600
3.200
1000
600
8.200
13.000
5.000
2.000
10
20
30
190
280
20
450
BWC
AV8/3 apl
4330
322
304
3116
6S1
423
5277
7271
2527
381
13.6
18.0
22.0
225
222
19.8
431
16.89
Tray
PEI-3
48
<.005
NDa.005
.006
ND8.005
ND8.005
.02
<9.4
<9.4
60
15.8
24.2
32.1
215
280
29.7
533
0
550 F
Tray
PEI-4
160
.003
.004
.011
N08.005
<.005
.03
<19
ND319
75
17.4
26.3
37.7
260
342
34.5
651
0
Tray
PEI-5
5.4
NDa.005
Noa.oo5
.009
NDa.005
<,005
.026
NDa20
ND820
40
18.7
28.6
38.8
255
356
35
670
0
AVG
71.1
<.004
<.005
.009
ND8.005
<.005
.025
<16.1
<16.1
50
17.3
27.0
36.2
243
326
33.1
618
(a)
Tray
PEI-7
47
.065
.01
.48
.52
.023
.77
1300
1600
200
13.2
23.9
32.0
280
280
28.9
579
0.75
(a)
Tray
Ptl-7
77
.059
.006
.41
NDa.005
.021
.71
1600
1400
230
12.8
25.5
34.6
309
305
30.2
535
0.51
350 F
Tray
PE1 24
58
.052
.008
.39
NDa.005
.018
1.37
1177
1570
275
18.9
25.5
30.3
391
338
27.5
731
1.9
AVG
60.7
.059
.008
.43
08
.021
.95
1359
1523
235
15.0
25.0
32.3
327
308
28.9
615
150 F
Tray
PCI-15
20
13
NDa.005
130
NDa.005
4.1
320
5800
2100
330
17.8
24.6
31.6
301
298
28.9
543
7.27
a Duplicate sample
rev 10/16/07
-------
TABLE 6-2. TRAY TEST REMOVAL SUMMARY
SARM-l-1
i
OJ
VOLATILES
ACETONE
CNLOROKNZENE
1,2 OICHLOROETHANE
ETNYL 8ENZCME
STYRENE
TETRACNLOROETNYLERC
XVLENE
SEMI -VOLATILES
ANTHRACENE
• IS(2-ETHVL-NEXVL- WTNALATE
KNTACNLOROPNEMOl
RESIDUAL X MOISTURE
•Ml
6.800
400
600
3,200
1000
600
8,200
13,000
5.000
2.000
Cane (ppa)
AM/3 apt
4330
322
304
3116
651
423
5277
7271
2527
381
16.89
Tray
PCI 3
98.89
>99.99
>99.998
W» TMM^B
>99.999
>99.999
99.9996
>99.87
>99.63
84.25
0
550 F
Tray
PEI-4
96.30
>99.999
99.999
99.9996
>99.999
>99.999
99.9994
>99.74
>99.25
80.31
0
Tray
PEI-S
99.87
>99.99
>99.998
99.9997
>99.999
>99.999
99.9995
>99.72
>99.21
89.50
0
AVG
98.36
>99.99
>99.998
99.9997
>99.999
>99.999
99.9995
>99.78
>99.36
84.78
(a)
Tray
PEI-7
98.91
99.98
99.997
99.98
99.92
99.99
99.985
82.12
36.68
47.51
0.75
(a)
Tray
PEI-7
98.22
99.98
99.998
99.99
>99.999
99.99
99.986
77.99
44.60
39.63
0.51
350 F
Tray
PEI 24
98.66
99.98
99.997
99.99
>99.999
99.99
99.974
83.81
37.87
27.82
1.9
AVG
98.60
99.98
99.997
99.99
>99.97
99.99
99.982
81.31
39.73
38.32
ISO F
Tray
PEI-15
99.54
95.96
>99.998
95.83
>99.999
99.03
93.93
20.73
16.90
13.38
7.27
a Dtf>licata taapla
rev 10/16/87
-------
TABLE 6-3. TUBE TEST SOIL DATA SUMMARY
SARM-l-1 (ITI5416)
Starting soil
TUBE TEST RESIDUAL SOIL COMCENTRATION(ppM)
Ti«e at leap « 50 Minutes (WET WT BASIS)
Ot
VOLATILE*
ACETONE
f Hi QMMNZf HE
1,2-OICNLOMXTIMIIi
ETNVL BENZENE
STVRENE
TETRACMLOROETHYLENE
XYLENE
SEMI -VOLATILES
ANTHRACENE
•IS<2-ETKYL-NEm- )PKTHAUTE
•EHTACNLOROPNEHOL
METALS
ARSENIC
CADMIUM
CHROMIUM
COPPER
LEAD
NICKEL
ZINC
RESIDUAL X MOISTURE
Goat
6,800
400
600
3,200
1000
600
8,200
13.000
5,000
2.000
10
20
30
190
280
20
450
Cone
AVG/3 spl
4330
322
304
3116
651
423
5227
7271
2527
381
13.6
18.0
22.0
225
222
19.8
431
16.89
Tube
PCI 16
5.4
.014
.033
.12
.007
.015
.22
34
MM20
0.2
22.1
23.2
27.8
281
328
25.1
639
0
550 F
Tube
PEI-17
2.0
.005
.029
.035
ND3.005
.005
.082
10.4
HD811
NM11
18.7
18.0
23.6
262
215
21.7
503
13.11
Tube
PEI-19
.67
.005
.005
.015
.005
.005
.04
9
1
2
19.6
23.3
28.2
291
323
25.7
654
0
AVG
2.69
.008
.02
.06
<.006
.008
.11
18.3
<8.3
<4.4
20.1
21.5
26.5
278
289
24.2
599
350 f
Tube
PEI-20
5
.02
.027
.17
ma. 005
.017
.27
2092
1295
239
20.7
26.3
31.5
360
360
28.9
758
0.36
ISO F
Tube
PEI-21
707
228
19.6
2285
Hoa.oos
267
4080
87
1686
250
17.5
22.1
27.7
267
283
25.2
577
45.6
rev 10/16/87
-------
SARN-l-1 ClffMtt)
TABLE 6-4. TUBE TEST SOIL REMOVAL SUMMARY
Starting coil
TUK TEST X REMOVAL
lime at te*p = 30 Minute* (UET UT BASIS)
cn
i
01
VOLATILES
ACETONE
CNLOROBEN2ENE
1.2-DICNLOMCTNANE
ETNYL KNZEHE
STYRENE
TETRACNLOROETHYLENE
XYLENE
SEMI -VOLATILES
ANTHRACENE
•IS(2-ETMYL-HEXVL- >f>NTHALATE
PENTACNLOROPMENOL
RESIDUAL X MOISTURE
Goal
6.800
400
600
3.200
1000
600
a. 200
13.000
5.000
2.000
Cone (KM)
AVG/3 *pl
4330
322
304
3116
651
423
S227
7271
2527
3S1
16.89
Tube
PEI-16
99.87
99.996
99.989
99.996
99.999
99.996
99.996
99.53
>99.21
99.95
0
550 f
Tube
PEI-17
99.95
99.998
99.99
99.999
>99.999
99.999
99.998
99.86
>99.56
>97.11
13.11
Tube
PEI-19
99.98
99.998
99.998
99.999
99.999
99.999
99.999
99.88
99.96
99.47
0
AVG
99.94
99.997
99.993
99.998
>99.999
99.998
99.998
99.75
>99.67
>98.8
350 F
Tube
PEI-20
99.88
99.994
99.99
99.99
>99.999
99.996
99.995
71.23
48.75
37.27
0.36
150 F
Tube
PCI 21
83.67
29.19
93.55
26.67
>99.9W
36.88
22.68
98.8
33.28
34.38
45.6
rev 10/16/87
-------
TABLE 6-5. TRAY TEST DATA SUMMARY
SMM-ll-1 (IT 05415)
o\
TRAY TEST RESIDUAL SOIL
SMt
VOLATILES
ACETONE 680
CNLOMKNZENE 40
1,2 OICHLOROETHANE 60
ETHYL BENZENE 520
STVRENE 100
TETRACHLOMCTHYLENE 60
XVLENE 820
SEMI -VOLATILES
ANTHRACENE 1500
•IS(2 ETHVL-HEXYL-)PNTNALATE 500
PEHTACHLOROPHENOL 200
METALS
ARSENIC 10
CADMIUM 20
CHROMIUM 50
COPPER 190
LEAD 280
NICKEL 20
ZINC 450
RESIDUAL X MOISTURE
Starting
toll Cone
<«->
450
6.6
1.5
82.5
NOa.005
4.4
155
550
150
29
14.5
28.1
55.5
278
273
50
594
6.0
PEI-B
67
.006
.012
.044
ND8.005
.008
.14
N099.8
NM9.8
NM9.8
19.4
51.5
46.9
525
597
55.5
771
12.38
(UET UT BASIS)
550 F
(•)
PEI-9
120
.004
.008
.034
NM.005
.005
.097
NOaB.2
NMB.2
Noae.2
14.1
29.8
37.1
251
297
33.0
706
0.87
PEI-10
100
.004
.007
.03
NOa.005
.006
.089
H039.4
N009.4
ND89.4
16.1
29.0
33.4
231
286
29.5
613
2.46
CONCENTRATION
Tine at teap
(•)
PEI-9
110
.004
.005
.054
NOa.005
.004
.074
<10
Noaio
Noaio
20.2
51.5
57.8
259
541
34.2
750
1.94
* 30 Minutes
350 F
AVG
99.2
.004
.008
.035
NOa.005
.006
.1
<9.5
<9.5
NM9.3
17.4
50.4
58.8
266
330
32.5
705
PEI-11
100
.017
.006
.18
NOa.005
.009
.57
23
54
<9.5
13.1
25.9
31.7
256
289
27.6
563
0
(b)
PEI-14
6.6
.098
.014
2.5
NOa.005
.028
4.2
170
170
13
20
29.6
36.1
298
303
31.6
665
1.93
150 F
(b)
PEI-14
3.1
.16
.02
2.9
.045
.045
4.7
220
160
18
6.9
24.3
26.6
231
258
24.6
523
0
PEI-37
35
.016
Noa.oi
.061
.24
Noa.oi
.343
324
210
36
17.1
30.8
31.2
275
299
30.1
601
4.73
AVG
15.0
.091
<.015
1.82
<.097
<.028
3.1
238
180
22.3
14.7
28.3
31.3
268
287
28.8
596
a implicate sample
b duplicate sanple
rev 10/16/87
-------
SARM 11-1 (IT 15415)
TABLE 6-6. TRAY TEST SOIL REMOVAL SUMMARY
TRAY TEST X REMOVAL
(MET UT BASIS) Ti«e at tea? = 30 Minutes
VOLATILES
ACETONE
CMLOROKNZEME
1,2 OICMLOROETHANE
ETNVL BENZENE
STVRENE
TETRACNLOROETNVLENE
XVLENE
SEMI- VOLATILES
ANTHRACENE
BIS(2 ETHYL HEXVL- )PNTHALATE
PENTACNLOROPNENOL
RESIDUAL X MOISTURE
Coal
680
40
60
320
100
60
820
1300
500
200
Starting *oil
Cent (pp.)
430
6.6
1.1
82.S
NM.OOS
4.4
155
350
150
29
6.0
PCI -8
84.42
99.91
99.08
99.95
>99.995
99.82
99.91
>97.2
>93.47
>66.2
12.38
550 F
(b)
PEI-9
72.09
99.94
99.38
99.96
>99.995
99.89
99.94
>97.66
>94.53
>71.7
0.87
PEI 10
76.74
99.94
99.46
99.96
>99.995
99.86
99.94
>97.3
>93.73
>67.6
2.46
(b)
PEI-9
74.42
99.94
99.61
99.96
>99.995
99.91
99.95
>97.1
>93.33
>65.5
1.94
AVG
76.93
99.94
99.38
99.96
>99.995
99.86
99.93
>97.34
>93.8
>67.9
350 F
PEI-11
76.74
99.74
99.54
99.78
>99.995
99.79
99.63
93.43
64.0
>67.2
0
(c)
PEI 14
98.42
98.51
98.82
96.97
>99.995
99.36
97.29
51.43
NC
55.2
1.93
150 F
(c)
PEI 14
99.28
97.57
98.46
96.48
99.95 a
98.98
96.97
37.14
NC
37.9
0
AVG
PEI 37
91.9 96.51
99.76 98.62
>99.23 >8B.t6
99.93 97.79
99.76 a >99.9
>99.77 >99.J6
99.78 98.0
7.43 32.0
NC NC
NC <31.0
4.73
• Baaed on star tins theoretical doeage
b duplicate Maple
c duplicate sample
MC no chan0e
rev 10/16/87
-------
TABLE 6-7. SOILS VOLATILES ANALYSIS SUMMRY
SOILS VOtATHES CONCENTRATION AFTER TREATNENT(ppM)
EXP 0
PEI-3
PEI-4
PEI-S
PEI-7
PEI-15
PEI-24
PEI-16
PEI-17
PEI-19
PEI-20
PEI -21
IT TARGET
SOIL 0 PEI 0 TEMP f
5416 SARN-
5416 SARN
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
5416 SARN-
550
550
550
350
150
350
550
550
550
350
150
NAXIMM
•OIL
n»F
548
551
551
Ml
161
344
569
565
559
364
158
X
WEIGHT EXP.
LOSS TYPE
17.4 Tray
17.8 Tray
17.5 Tray
16.7 Tray
9.8 Tray
17.6 Tray
19.1 Tuba
18.2 Tuba
17.1 Tuba
17.9(a) Tuba
1.6 Tuba
(Uncorrected for Moisture content)
ACETONE
48
160
5.4
47/77
20
58
5.4
2
.67
5
707
CHLOROBENZENE
<.005
.003
ND8.005
.065/.059
13
.052
.014
.005
.005
.02
228
1,2 01CHLOROETHANE
NDa.005
.004
NDa.005
.01/.006
NDa.005
.008
.033
.029
.005
.027
19.6
ETHYLBEH2ENE
.006
.011
.009
.48/.41
130
.39
.12
.035
.015
.17
2285
STYRENE
NDa.005
NDa.005
NDa.005
.052/ND
NDa.005
NDa.005
.007
NDa.005
.005
NDa.005
ND8.005
TETRACHLOROETHYLENE
ND
.002
<.005
.023/.021
4.1
.018
.015
.005
.005
.017
267
XYLENE
.02
.03
.026
.77/.71
320
1.37
.22
.082
.04
.27
4080
a\
i
co
(a) Freah lead aaapla Iron pail
•EI-8
•EI-9
PCI -10
PEI-11
PCI -14
PEI-37
5415
5415
5415
5415
5415
5415
SARN-ll-1 550
SARN-II-
SARM-II-
SARN-II-
SARN-II-
SARN-ll-
550
550
350
150
150
550
550
552
350
152
147
6.0
6.0
6.0
5.8
4.6
5.2
Tray
Tray
Tray
Tray
Tray
Tray
67
120/110
100
100
6.8/3.1
35
.006
.0043/.004
.004
.017
.098/.160
.016
.012
0.008/0.005
.007
.006
.014/.02
H08.01
.044
.034/.034
.030
.18
2.5/2.9
.061
NOa.005
MO/NO
MM.005
NDa.005
NO/0.45
.24
.008
.005/.004
.006
.009
.028/.045
NOa.01
.14
.097/.074
.089
.57
4.2/4.7
.343
SOILS VOLATILES CONCENTRATION KFORE TREATMENT
5416 SARN-l-1
5416 SARN-l-1 Duplicate
5415 SARN-ll-1
5416 SARN-l-1 Jar bottoo
5416 THEORETICAL DOSAGE
5415 THEORETICAL DOSAGE
5417 CLEAN SOIL
5300
5600
430
2091
6800
680
.035
350
360
6.6
256
400
40
Noa.oos
370
410
1.3
132
600
60
<.005
3500
3700
82.5
2148
3200
320
Noa.oos
680
710
ND(20)
562
1000
100
Noa.oos
450
490
4.4
330
600
60
Noa.oos
5600
6100
155
4130
8200
820
NDa.005
rev 10/16/87
-------
TABLE 6-8. SOILS SEMIVOLATILES ANALYSIS SUMMARY
SOILS SENI-VOLATILES CONCENTRATION AAFTER TREATMENT (pp»
(Uncorrected for Moisture content)
EXP. i
PEI-3
PEI-4
PEI-5
PEI-7
PEI-15
PEI-24
PCI -16
PEI-17
PEI 19
<* PCI-20
*> Pfl-21
IT TARGET
SOIL i Ptl • TEMP f
5416 MM-
5416 8MN-
5416 SMN-
5416 SARM-
5416 SARM-
5416 SAW-
5416 SARM-
5416 SARM
5416 SARM-
5416 SARM-
5416 8ARM-
-
-
•
-
-
•
.
-
-
550
550
550
350
150
350
550
550
550
•1 350
-1 150
MAXIMUM
SOIL
TEMP f
548
551
551
341
161
344
569
565
559
364
158
X WEIGHT
LOSS
17.4
17.8
17.5
16.7
9.8
17.6
19.1
18.2
17.1
17.9(a)
1.6
EXP
TYPE
Tray
Tray
Tray
Tray
Tray
Tray
Tube
Tube
Tube
Tube
Tuba
ANTHRACENE
<9.4
<19
ND320
1300/1600
5800
1177
34
10.4
9
2092
87
BIS(2-ETHYL-
HEXYL)-
PHTHALATE
<9.4
NM19
M>a20
1600/1400
2100
1570
ndB20
ND311
1
1295
1686
PENTACHLOROPHENOL
60
75
40
200/230
330
275
.2
refill
2
239
250
(a) FrMh faad saapU froa pail
PEI-8
KI-9
•CI-10
PEI-11
PEI-14
P£l 37
5415 1
5415 1
5415 1
5415 1
5415 t
5415 1
(MN-II-
EARN-II
MRM-II-
1ARM-II-
MWI-II-
MW-II-
550
550
550
350
150
150
550
550
552
350
152
147
6.0
6.0
6.0
5.8
4.6
5.2
Tray
Tray
Tray
Tray
Tray
Tray
ND89.8
NOaB.2/<10
M>a9.4
23
170/220
324
ND39.8
N088.2/ND
ND39.4
54
170/160
210
ND39.8
MDae.Z/NO
ND89.4
<9.5(9)
13/18
36
SOILS SENI-VOLATILES CONCENTRATION tEFORE TREATMENT (pf»)
5416 SARN-l-1
5416 SARN-l-1
5415 SARM-ll 1
5416 SARM-l-1 Jar bottoai
5416 THEORETICAL DOSAGE
5415 THEORETICAL DOSAGE
5417 CLEAN SOIL
4700
3900
350
13214
13000
1300
NOW. 7
2900
2700
150
1982
5000
SOO
HDa9.7
230
210
29
702
2000
200
ND39.7
rev 10/16/87
-------
TABLE 6-9. SOILS METALS ANALYSIS SUMMARY
EXP *
SOILS METALS CONCENTRATIONS AFTER TREATNENT(pfM)
(Uncorrected for Moisture content)
IT SOIL * PEI f
MAXIMUM
SOIL TEMP F
X WEIGHT
LOSS
EXP. TYPE ARSENIC CADMIUM CHROMIUM
COPPER
LEAD
NICKEL
ZINC
PEI 3
PEI -4
PEI 5
Pll-7
PEI -15
PEI -2*
5416 SARN-
5416 SARN-
5416 SARN-
5416 8AM-
5416 SAM-
5416 SAM-
550
550
550
350
150
350
548
5S1
551
341
161
344
17.4
17.8
17.5
16.7
9.8
17.6
Tray
Tray
Tray
Tray
Tray
Tray
15.8
17.4
18.7
13.2/12.8
17.8
18.9
24.2
28.3
28.6
23.9/25.5
24.6
25.5
32.1
37.7
38.8
32/34.6
31.6
30.3
215
260
255
280/309
301
391
280
342
356
280/305
298
338
29.7 533
34.5 651
35 670
28.9/30.2 579/535
28.9 543
27.5 731
PEI 16
PEI-17
PEI -19
o> Pil-20
^ PEI-21
O
(a) Fresh
PEI 8
PEI -9
PCI -10
Ptl-11
PEI -14
PEI -37
5416
5416
5416
5416
5416
feed Maple
5415
5415
5415
5415
5415
5415
5416
5416
5415
5416
5417
SAM- -1
SAM- -1
SAM- -1
SAM- -1
SAM- -1
fro* pail
SARN- II 1
SAM-ll-1
SAM-ll-1
SAM-ll-1
SAM-ll-1
SAM-ll-1
SARM- 1-1
SARN- 1-1
SARM II 1
550
550
550
350
150
550
550
550
350
150
ISO
569
565
559
364
158
550
550
552
350
152
147
19.1
18.2
17.1
17.9
-------
In some cases, to obtain a 'reasonable' dry weight basis the percent
moisture given should be ignored (as in PEI-17, and PEI-8) and in other cases
corrected to the near starting value as in PEI-21. In the former case it
appears that an aliquot with an excessive amount of moisture was used for the
determination and thus moisture content should be corrected to a value more
consistent with the remainder of the observations.
The tube furnace condensate analyses are not presented here, because the
mass balance was poor on all of these runs, especially for the 550°F temp-
erature and these data were not the central objective of the project. The
most likely explanation for the poor mass balance is that the volatile com-
ponents were extracted into the methylene chloride rinse phase and were
subsequently lost when the methylene chloride was phase separated and concen-
trated for analyses of the semi-volatiles. Since the gas bag analyses did
not show unusally high hydrocarbon values, the volatiles did not pass by the
traps, even through the traps may have been saturated.
Another possibility is that the extraction of components from the traps
using methanol may not have been as efficient for some of the less volatile
constituents.
6-11
-------
SECTION 7
QUALITY ASSURANCE AND QUALITY CONTROL
The data in Tables 7-1 and 7-2 indicate the precision of duplicate
analyses and the recovery of contaminants freshly spiked onto a sample of
clean SARM soil in the laboratory. The presence of significant levels of
some of the metal contaminants makes the interpretation of the metal spike
recoveries difficult. The level of the recoveries of the semi-volatile
contaminants and the apparent precision of duplicate sample analyses imply
that the data is useful only in a qualitative predictive manner and that
quantitative interpretation should not be attempted.
7-1
-------
TABLE 7-1. PRECISION AMONG REPLICATE SAMPLES
SAMPLE SOURCE
ruaber of replicates
COMPOUND
ACETONE
CMLOROBENZENE
1,2-OICHLOROETHANE
ETHYLBEM2ENE
STYRENE
TETRACHLOROETHYLENE
XYLENE
ANTHRACENE
IIS(2-ETHYLHEXYL- >PHTMALATE
PENTACNLOROPHENOL
ARSENIC
CADMIUM
CHROMIUM
COPPER
LEAD
NICKEL
ZINC
STARTING
SARM-I
n-2
2.7
1.4
5.1
2.8
2.1
4.2
4.3
9.3
3.6
4.5
10.3
0.
2.
0.
0.
4.
2.
| STARTING
SARM-I
n»3<«>
36.7
14.5
40.4
22.1
9.8
16.1
15.8
SS.O
15.6
59.7
30.9
1.6
3.5
16.5
16.2
4.5
17.8
| P6I-9 | PEI-7
(5415) (5416)
n-2(b) n>2(c)
4.4 24.2
0 4.8
23.1 25
0 7.9
0 98
11.1 4.5
13.4 4.0
9.
9.
9.
17.
2.
0.
1.
6.
1.
10.3
6.7
7.0
1.5
3.2
3.9
4.9
4.3
2.2
1.7 3.9
| PEI-14
(5415)
n-2(d)
37.4
24
17.6
7.4
80
23.3
5.6
12.8
3.0
16.1
48.7
10.2
15.1
12.7
8.0
12.4
11.9
(•) two starting soil sanple* plus • jar bottom sample
(b) treated at 550 F
(c) treated at 350 f
(d) treated at 150 f
rev 10/23/87
7-2
-------
TABLE 7-2. QUALITY ASSURANCE AND QUALITY CONTROL - LABORATORY SPIKES
SAMPLE • 557-7-6-5417
SAMPLE fl 557-7-7-5*17
SAMPLE i 557-7-8 5417
COMPOUND
I
OJ
CHROMIUM
COPPER
LEAD
ZINC
PENTACNLOROPNENOL
ANTHRACENE
ACTUAL
SPIKf
LEVEL
17.6
27.1
27.1
80.3
37.1
54.0
lf*L
MMKTED
18.7
51.0
38.2
92.0
40.0
36.8
X
RECOVERY
106
188
1*V
114
108
68
X RECOVERY
WITH ILAMK
CORRECTION
82
155
106
83
108
68
II
II
II
II
II
II
II
II
II
II
II
ACTUAL
SPIKE
LEVEL
10.3
11.9
47.5
46.9
65.0
31.5
LEVEL
REPORTED
12.8
25.1
57.2
56.7
42.2
19.2
X
RECOVERY
124
211
120
121
65
61
X RECOVERY
WITH ILAMK
CORRECTION
83
134
100
68
65
61
II
II
II
II
II
II
II
II
II
II
II
ACTUAL
SPIKE
LEVEL
5.9
40.9
81.9
26.9
112
18.1
LEVEL
REPORTED
8.6
48.0
76.9
32.4
84.4
11.2
X
RECOVERY
146
117
94
120
75
62
X RECOVERY
WITH M.ANK
CORRECTION
75
95
82
28
75
62
rtv 10/22/87
-------
SECTION 8
DATA SUMMARY AND CONCLUSIONS
Thermal desorption of volatile and semi-volatile contaminants from soils
at mode rate temperatures such as 550°F can be achieved with reasonable
success. Most of the volatile constituents are removed to well below 1 ppm
residual concentration on the treated soil. Acetone appears to remain in the
soil matrix, perhaps due to the presence of bound water in the soil.
s Semi-volatile contaminants are removed to a large extent except for
pentachlorophenol, perhaps due to its ability to form stable phenates. The
anthracene and phthalate are apparently removed at least to levels near the
method detection levels.
At a temperature of 350°F most of the volatiles with the exception of
acetone are reduced to levels below 1 ppm residual concentration on the
treated soil. The semi-volatile contaminants are reduced, though not to any
moderate treatment criterion that might be desired.
Due to the volatility of the contaminants and the apparent non-homo-
geneity of the starting soil, the data are apparently non reproducible. The
starting soil was very moist and sticky and had large pebbles throughout the
material. Unless a great deal of care went into the removal of aliquots from
the soil for the various analyses, it 1s extremely likely that a sample with
excessive moisture or a pebble could be obtained. This would result in
extreme variations in the concentrations of components between samples. The
data on the starting soils indicate that the contaminants themselves were not
uniformly mixed into the soil matrix, especially for the semi-volatiles components,
8-1
-------
APPENDIX A
CHAIN OF CUSTODY RECORDS
-------
*•> „,
«t. :MT -
CARRIER/WAYBILL NO. - I r "
Condition on R*c*p(
i!i;^^INfcff
Date and TfhM)
tTP
3. RrtlnquWwd By:
4. Rellnqutehed By:
Received By.
-------
R/A Control No
CHAIN-OF-CUSTODY RECORD
J. A
C/CControlNo. 52949
LAB DESTINATION
I . ^,
CARRIER/WAYBILL NO
•r « >' ;••
I . T.-
: f '•ijiVj. -4 Vt><'.
3. Rallnqutohed By:
Received by:
4. Relinquished By.
Received By
-------
PROJECT NAME/NUMBER
SAMPLE TEAM MEMBERS.
PCI -
CHAIN-OF-CUSTODY RECORD
LAB DESTINATION
R/A Control No.
C/C Control No. 62352
IT -
CARRIER/WAYBILL NO.
IT - K .
Svnpto
Number
Date and Time
Collected
Sample
Container
Type
Condition on R*c*lpt
(Nam* and Data)
OltpoMl
RacordNo
44 -
IL
3A
5*5
9*5
4 7 -
70 -7 A
tift
Li
^1H
i
t
SIGNATURES: (Nam*. Company. Data and Time)
2. Relinquished By:
Received By: —
Received by:
4. Relinquished By:
Received By:
WHITE - Toacoompany MmpM
YELLOW • FMd copy
-------
TJMNATJORM.
>S
PROJECT NAME/NUMBER P£ I
SAMPLE TEAM MEMBERS fr-
CHAIN-OF-CUSTODY RECORD
LAB DESTINATION
R/A Control No.
C/C Control No' D
CARRIER/WAYBILL NO.
O«l* end Tim*
Coltoctcd
Sampl*
Contolnw
Type
Condition on R«c*lpi
(Nam« and Data)
OIlpOMl
Record No
/^ 7
dr fvx^ft yj^V?-1
*-
4-
5T-
^y T*>M»
I
f
555
^ ALL
, fldf#/*c
r-zr
SIGNATURES: (Nttrw. Compwiy, Date and Time)
1. *-{&**«'^7° '
2. Relinquished By:
Received By:
3. Relinquished By:
Received by:
4. Relinquished By:
Received By:
WHITE - To •coxnpany
YELLOW-FMd copy
-------
PROJECT NAME/NUMBER
SAMPLE TEAM MEMBERS
P£' -
CHAIN-OF-CUSTODY RECORD
R/A Control No.
C/C Control No. 3 2 ? 5
LAB DESTINATION
CARRIER/WAYBILL NO
Poulbto Sample Hazanto:
SIGNATURES: (Name. Company, Date and Time)
1. Rrtnqufchrt By: £!**+*, I? &, */**/? 7
//^//T
3. Relinquished By:
Received by:
2. Relinquished By:
Received By: —
4. Relinquished By:
Received By:
WHITE - To accompany MmptM
YELLOW - FlaM ^«~,
-------
CHAIN-OF-CUSTODY RECORD
R/A Control No.
C/C Control No. 62S54
DESTINATION _ IT - *\IP0L£
CARRIERAVAYBIUNO. -./T"
Date and fan*
CondMononR«Mipt
(N«m< and D«t»)
^
3. Relinquished By:
r
Received by:
4. Relinquished By:
Received By.
-------
MMfe'','**". —••••• vAJKrvnuuiuN CHAIN-OF-CUSTODY RECORD
PROJECTNAME/NUMBER P£ 1 - 8 O *?0 /5" '
R/A Control No.
C/C Control No.
I DPI
LAB DESTINATION
SAMPLE TEAM MEMBERS
CARRIER/WAYBILL NO. /T —
Sampt* ^~ "
H /^:S'
.SIGNATURES: (Name. Company. D«t» and Time)
3. Rellnqutoh6d^
Recent*
2. Rrtlnqulshwl By:
R«c*hr*dBy:
4. RallnquMwd By:
Received By:
..:-:';f'!
-------
'<«. ^ :
PROJECT NAME/NUMBER
^ ,';, . SAMPLE TEAM MEMBERS K«h*»4U
***
CHAIN-OF-CUSTODY RECORD
LAB DESTINATION
CARRIER/WAYBILL NO.
SIGNATURES: (Ntmt. Compwty, D*t« and Time)
ntcttvtd By
2. Relinquished By:
Received By:
3.
Received by:
4 Relinquished By:
Received By:
WHTTt • To »ccon»«««
YELLOW FMd copy
// .
R/A Control No.
C/C Control No.
-------
>NAL
•m
PROJECT NAME/NUMBER r £ I -
SAMPLE TEAM MEMBERS K* f
_ f _ .,
-7S
CHAIN-OF-CUSTODY RECORD
LAB DESTINATION ^ "
R/A Control No. _
C/CControlNo. 62354
CARRIER/WAYBILL NO. IT ~ fc-FEffc
DM* and Tim*
Swnpl*
ConMntr
• *
l< '. (v ' "- ', ' ' - .
• •; BIONATUflEB: i
-------
Robyn Wagner - Middlebrook August 24, 1987
Ken Ferguson - TD Laboratory
v
ANALYSIS OF FEZ SOIL SAMPLES
Please call Arie Groen for instructions before analyzing samples.
Please analyze the soil for all compounds on attached list. The
condensate-scrubber-rinse samples are to be analyzed for volatiles
and semi-volatiles on attached list. Paper filter and rinse
samples are to be analyzed for semi-volatiles only. Tenax traps
and Tenax with carbon traps are to be extracted in methanol and
each pair combined as a composite. The composites probably need
to be diluted, especially 555-53, 555-56, 555-63. Traps need to
be extracted before 9/1/87. Return traps, fittings, and extracted
sorbent to the TD Lab.
-------
The following compounds are known to be present in the starting soils
555-6-3-5416
555-6-4-5416
555-6-2-5415
Organic Compounds
Ethyl benzene
Xylene
Tetrachloroethylene
Chlorobenzene
Styrene
1,2-Dichloroethane
Acetone
Anthracene
Bis(2-ethylhexyl)-phthalate
Pentachlorophenol
Metals
Lead
Zinc
Cadmium
Arsenic
Copper
Nickel
Chromium
Ref RAI 61101, 61102
Ref C/Cf 62948, 62949
Range of Concentration
300-3000 ppm
800-8000 ppm
60-600 ppm
40-400 ppm
20-200ppm
60-600 ppm
600-6000 ppm
1000-10,000 ppm
500-5000 ppm
200-2000 ppm
levels up to
300 ppm
500 ppm
25 ppm
25 ppm
200 ppm
A
25 ppm
50 ppm
-------
APPENDIX B
CERTIFICATES OF ANALYSIS FOR
VOLATILES, SEMI-VOLATILES, AND
METALS ANALYSIS
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Arie Groen
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED
PROJECT CODE.
ORDER NUMBER:
PAGE
October 7, 1987
I TEC 24761
805015
L_ OF 1
Sample Description: Seventeen (17) soil samples received August 6, 1987
555-12-
555-14-
555-16-
555-20-
555-20-
555-22-
555-24-
555-26-
555-28-
555-36-
555-38-
555-24-
555-36-
555-6-2
555-6-3
555-6-4
555-35-
2A-5416, Treated
2A-5416, Treated
2A-5416, Treated
2A-5416, Treated
3A-5416, Treated
2A-5415. Treated
2A-5415. Treated
2A-5415, Treated
2A-5415, Treated
2A-5415, Treated
2A-5416, Treated
1R-5415, Treated
1R-5415, Treated
-5415, Untreated
-5416, Untreated
-5416, Untreated
1-5417, Clean Soi
Soil, 7-30-87
Soil, 7-30-87
Soil, 7-30-87
Soil, 8-3-87
Soil, 8-3-87
Soil, 8-3-87
Soil, 8-3-87
Soil, 8-3-87
Soil. 8-3-87
Soil, 8-3-87
Soil, 8-5-87
Soil, 8-3-87
Soil, 8-5-87
Soil, 7-29-87
Soil, 7-29-87
Soil. 7-29-87
l. 8-5-87
% Moisture
0
0
0
0.51
0.75
12.38
0.87
2.46
0
1.93
7.27
1.94
0
6.00
16.58
16.67
4.68
Approved
Asst. Laboratory Manager
TIM
Accredit*! by th* Am*neon Amoaaaan tor laboratory Acctodttaoor in the ctwmcal
ii«id oi t«inn0. a bmd in ttw cunvnt AALA DMdonr oi AoavdiMd Latoeraton«
-------
NATIONAL
OLOGY
'RATION
ANALYTICAL
SERVICES
5815 Middiebrook Pike • Knoxvilie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 01 rectors Drive
KnoxvUle, TN 37923
DATE REPORTED
PROJECT CODE:
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
_L_OF_3a_
Sample Description: Four (4) soil samples received August 6, 1987
Concentration units are mg/kg (ppm)
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
555-12-2A-5416
Treated Soil
7/30/87
15.8
24
32
215
280
29
533
.2
.1
555-14-2A-5416
Treated Soil
7/30/87
17.4
28.3
37.7
260.
342
34.5
651
555-16-2A-5416
Treated Soil
7/30/87
18.7
28.6
38.8
255
356
35.0
670.
555-20-2A-541
Treated Soil
8/3/87
13.2
23.9
32.0
280.
280.
28.9
535
Laboratory Manager
TU*
m AMoaonon tor Lob
twid ex
as U««d in m« cun»ni AALA OirKtory
tniht chtRUGQl
wQDOVQlOfMA
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 MiddlebfOOk Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED
PROJECT CODE.
ORDER NUMBER:
PAGE-
September 30, 1987
ITEC 24761
805015
9 OF 3Q
Sample Description: Four (4) soil samples received August 6, 1987
Concentration units are mg/kg (ppm)
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
555-20-3A-5416
Treated Soil
8/3/87
12.8
25.5
34.6
309
305
30.2
579
555-22-2A-5415
Treated Soil
8/3/87
19
31
46
323
397
33
771
4
5
.9
555-24-2A-5415
Treated Soil
8/3/87
14.1
29.8
37.1
251
297
33.0
706
555-26-2A-541!
Treated Soil
8/3/87
16,
29,
33,
231
286
29,
613
Laboratory Manager
•no*
AcCT»cM«d tvth«Am*ncanAaoc>ation lor l^boraiocy Accreditation in trweteiMcal
tMld ol i««ng. as UMd in th* cumnt AALA Duvctoiy « AccrMit*d taboraionw
*J-»-45
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED:
PROJECT CODE:
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
Sample Description: Four (4) soil samples received August 6, 1987
Concentration units are mg/kg (ppm)
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Z1nc
555-28-2A-5415
Treated Soil
8/3/87
13.1
25.9
31.7
256
289
27.6
563
555-36-2A-5415
Treated Soil
8/3/87
20.0
29.8
36.1
298
303
31.6
665
555-38-2A-5416
Treated Soil
8/5/87
17.8
24.6
31.6
301
298
28.9
543
555-24-1R-541
Treated Soil
8/3/87
20.2
31.5
37.8
259
341
34.2
730.
Laboratory Manager
Tit*
AccT»d»«d by ih« Am»ncon AapaoBon tar Laboratory Aixmiiiuuon m ttx chtmteal
oi tMtmg. a* UMd in if* cunwnt AALA OtfMory « Atxr»cui«
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE.
ORDER NUMBER.
PAGE-
September 30, 1987
ITEC 24761
805015
Sample Description: Four (4) soil samples received August 6, 1987
Concentration units are mg/kg (ppm)
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
555-36-1R-5415
Treated Soil
8/5/87
.3
.6
6.9
24
26
231
258
24
523
555-6-2-5415
Untreated Soil
7/29/87
14.3
28.1
33.5
278
273
30.0
594
555-6-3-5416
Untreated Soil
7/29/87
.7
.9
11.8
17
21
200
198
20
388
555-6-4-5416
Untreated Soi
7/29/87
9.6
17.9
20.9
198
195
18.5
367
Approved
A\'
Laboratory Manager
Tltto
oi mana ai ltt«d in uw CUITWW AALA DMcMty at AecradiMd LaboratotM*
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED.
PROJECT CODE.
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
.5—OF 23-
Sample Description: One (1) soil sample received August 6, 1987
Concentration units are mg/lcg (ppm)
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Z1nc
555-35-1-5417
Clean Soil
8/5/87
3.3
<0.4
4.2
9.1
9.5
6.8
25.0
Laboratory Manager
TIM
Aecndit«d by th* Am«ncon Aaoaooon tor Laboratory AocndNemen M ih» ehMiuool
twkd oi tMhne. at UMd in tn« currant AALA Directory oi Acemdii«d LaboraionM
-------
ATIONAL
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO. IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle. TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER. 805015
PAGE__6_ OF ^Q
Sample Description: 555-12-2A-5416, Treated Soil, 7/30/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
48,000
<5
NO
6
ND
NO
20.
Remarks: 5 *
NO »
1on Lfnlt
ed
but at a level less than the quantItat1on limit.
•Mponcnt has a quantltatlon limit two (2) times that listed.
Approved
Laboratory Manager
nti*
Mtd ot M*»O. ai UMd m th* cunvnr AALA Duvctary of
-------
Q3
INTERNATIONAL
TECHNOLOGY
COBPOBATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
~%"tt;
•*.»£:
3b
-«
TO IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER: 805015
PACE 7 OF 3Q
Sample Description: 555-14-2A-5416, Treated Soil, 7/30/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
160,000
<5
<5
11
ND
<5
30.
Remarks: 5 • QMptttatlon Limit
NO « ** dtttcted
< - (NHCttd but at a level less than the quantUatlon limit.
1 » TMs component has a quantltatlon limit two (2) times that listed.
Laboratory Manager
Till*
Aect»d««d toy th« Amwicon Aaoaonon tor Lot*
ry AecndHonon m KM ehcmeoi
oi t«mng 01 M«d in th* currvnt AALA Diraeery ct AcovdMd LoboraMnw
*3-*-4S
-------
IATIONAL
rOLOGY
'RATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxvilie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE
ORDER NUMBER:
PAGE_
September 30, 1987
1TEC 24761
805015
ft DP ?g
Sample Description: 555-16-2A-5416, Treated Soil, 7/30/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tet rach1oroethene
xylenes (total)
Concentration
(ug/kg)
5,400
ND
NO
9
NO
<5
26
Remarks: 5 * Qw*tlUt1on Unit
NO - §j| *tected
< » Bpettd but at a level less than the quant 1tat 1 on limit.
1 • TIRf component has a quantltatlon limit two (2) times that listed,
3T
Laboratory Manager
TW«
AccmdJWd by ttw American Aaoaanon tor Laboratory t
oi M«no. as UMd in ih« cumtM AALA Oiractoiy of Aoa*dtMd Laboraonw
-------
EE3
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED-
PROJECT CODE:
ORDER NUMBER.
PAGE_
September 30, 1987
ITEC 24761
805015
-SL_OF_J3_
Sample Description: 555-20-2A-5416, Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
77,000
59
6
410
ND
21
710
Remarks: 5 • QiiMtltatlon Limit .
ND " 91 dttcct«d
< " Ogfected but at a level less than the quant1tat1on limit.
1 « TMt component has a quantltatlon limit two (2) times that listed.
Approved
>?\
Laboratory Manager
TM*
AecndiMd by th* A
Mid ex MBWQ CB
W-t-IS
in th» cumni AAIA Duvciefy of AcefMind LoberawnM
-------
TATIONAL
CHNOLCX3Y
RATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED
PROJECT CODE
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
-lfl_OF_39_
Sample Description: 555-20-3A-5416, Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
47,000
65
10.
480
52
23
770
Remarks: 5 • Qpirtttatlon Limit .
NO - ** detected
< * MKttd but at a level less than the quant 1tat 1 on limit.
1 - Tflg component has a quantltatlon limit two (2) times that listed.
Laboratory Manager
TlU*
Accredited by ih« Anwncon A»oaaflon tor Laboratory Aacradttalx
B«td ol Mttno- at loMd in in* curnnt AALA Ov*ctory at AixftOiimi Lafcoraionw
-------
TE
CO
RATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED; September 30, 1987
PROJECT CODE: I TEC 24761
ORDER NUMBER: 805015
PACE 11 OF 39
Sample Description: 555-22-2A-5415, Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Concentration
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
67,000
6
12
44
NO
8
140
Remarks: 5 - Quwtltatlon Limit
ND - NoT detected
< " MUcttd but at « level less than the quant 1tat 1 on limit.
1 - This component has a quantltatlon Unit two (2) times that listed.
Approved by/
Laboratory Manager
Tito
Aeo»dtt«<3 by «h» Anwncon AaoaotJon tor Lotwwtory Acawttknon m tt» ehwnieal
6«ld 01 tMbng. as Ufl«d in ttw cunvni AALA Duwctoey « AoaMiWd LateraionM
-------
.TIONAL
JLOGT
'RATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECTCODE ITEC 24761
ORDER NUMBER: 805015
PACE \? OF "M
Sample Description: 555-24-2A-5415, Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
cilorcbenzene
!,2-d1ch1oroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
120,000
<5
8
34
NO
5
97
Remarks: 5 - Qafptltatlon Limit .
NO « M| detected
< • Olfetettd but at a level less than the quant1tat1on limit.
1 * Tnfs component has a quant1tat1 on limit two (2) times that listed.
Approved EV*
Laboratory Manager
Accredited by th« Amwneon AHoaonon tor laboratory AeenMttanon in in* etwmeol
Mkt at tMOng. as IttM in U» cunwnt AALA Directory at Aoa«dM*d LabaraMfiM
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED.
PROJECT CODE.
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
13 OP 39
Sample Description: 555-26-2A-5415. Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
t et ra ch 1 o roet hene
xylenes (total)
Concentration
(ug/kq)
100,000
<5
7
30.
NO
6
89
Remarks: 5 - QpBtUatlon Limit
NO « *£ detected
< • fljteettd but at a level less than the quant1tat1on limit.
1 - Tills component has a quantItatlon limit two (2) times that listed,
Approved
Laboratory Manager
Till*
(MM ot (Mdng. ai Ufl«d in Uw cumnt AALA Duwetory oi Aoei«d«*d LaberatorM*
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxvitle. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER: 805015
PAGE Id OF 33
Sample Description: 555-28-2A-5415. Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Concentration
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
100,000
17
6
180
ND
9
570
Remarks: 5 « (fefftltatlon Limit
NO - to* detected
< - OftMCtcd but at a level less than the quantltatlon limit.
1 • This component has a quantltatlon limit two (2) times that listed.
Approved
Laboratory Manager
•mi*
Accredited by the American Aaodooon lor Laboratory
tdttaoon in the chemical
Mid o( Mmng as Wed in the eunvni AALA Du»ctory ol Accredited Labemane*
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE:
ORDER NUMBER:
PACE
September 30, 1987
I TEC 24761
805015
1 f, OF 30
Sample Description: 555-36-2A-5415, Treated Soil, 8/3/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(yg/kg)
6,800
98
14
2,500
NO
28
4,200
Remarks:
5
NO
<
1
QUifit 1tat1on Unit
N* detected
Difecttd but at a level less than the quantUatlon limit.
Tfcfs component has a quantltatlon limit two (2) times that listed,
Laboratory Manager
•nu*
gotten tor LabcroKjry At
MM el tMnn0. a UMd in ttw euirtnt AALA DMaay « Accndii^d Lottxmonm
-------
nna
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO
IT Corporation
ATTN: Ed Alperln
312 Directors Orlve
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE:
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
-lfi-OF_39_
Sample Description: 555-38-2A-5416, Treated Soil, 8/5/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Concentration
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
16,000
13,000
NO
130,000
NO
<5,000
320,000
Remarks: 5,000 * Quantltatlon
ND - tot detected
< * Detected but at a level less than the quantltatlon limit.
TKIs component has a quantltatlon limit two (2) times that listed.
i
Approved)
Laboratory Manager
Accredited ty th» Ant«ncan Aaoaation tar lab
ia
twld oi (MRng as UMd in th* cunvn AALA Duveiofy ot
dnaOan in m* chumttxti
-------
nra
INTERNATIONAL
-
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
3@S§*.
TO IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
KnoxvUle. TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER: 805015
PACE 17 OF "W
Sample Description: 555-24-1R-5415, Treated Soil. 8-3-87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
110,000
34
NO
74
Remarks: 10. • Qwptltatlon Limit
NO * N» detected
< - Olticttd but at a level less than the quant1tat1on limit.
1 * TKff conponent has a quantHat1 on limit two (2) times that listed.
Laboratory Manager
TlU*
Accr»dH»d by iho Am»ncan Aaoaafton lor Latxyatory AcerntfauiMi m th» chemical
oi t«nng. a lai«d in the eun*nt AA1A DirKiory of Acemdind Laboraton«
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24761
ORDER NUMBER: 805015
PAGE 1ft OF 3Q
Sample Description: 555-36-1R-5415, Treated Soil, 8-5-87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
3,100
160
20.
2,900
450
45
4.700
Remarks: 5 • <^pt1tat1on Limit .
NO - Nil *t»cted
. ||fei
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24761
ORDER NUMBER: 805015
PAGE____1SL OF 30
Sample Description: 555-6-2-5415, Untreated Soil, 7-29-87, received August 6. 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
430,000
6,600
1.300
82,500
NO
4,400
155,000
Remarks: 250 « QMwt1tat1on Limit
NO « N|| detected
< » (meted but at a level less than the quant 1tat 1 on limit.
1 » This component has a quantltatlon limit two (2) times that listed.
Approved
Laboratory Manager
Titfr
Aeer»dit»d by th* Anwncon Amosaoon tor laboratory Aacndttaac
Mid ct Ming, a UMd in in* cun«nl AALA Ouveioty o< AoeradiMd
-------
^NATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE
ORDER NUMBER
PAGE
September 30, 1987
ITEC 24761
805015
?f> OF 3Q
Sample Description: 555-6-3-5416, Untreated Soil, 7-29-87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
5,300,000
350,000
370,000
3,500,000
680,000
450.000
5,600,000
Remarks: 125,000 • Ouantltatlon Limit ,
NO • Not detected
Detected but at a level less than the quant 1t at 1 on limit.
This component has a quant 1t at 1 on limit two (2) times that listed
<
1
Approwd
Laboratory Manager
TUt*
rtttoaon m the chemical
told o> letting, a l««d in the current AALA Direaoiy
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED
PROJECT CODE
ORDER NUMBER.
PAGE.
September 30, 1987
ITEC 24761
805015
-2JLOF_J9_
Sample Description: 555-6-4-5416, Untreated Soil, 7-29-87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg)
5,600,000
360,000
410,000
3,700,000
710.000
490.000
6,100,000
Remarks: 130,000 • Quant1tat1on Limit
NO • Not detected '
< • Detected but at a level less than the quant Itat1on J1m1t.
1 » This component has a quant1tat1on limit two (2) times that listed,
Approved
Laboratory Manager
TIM
Accredited by the American Aaeaauon lor Laboratory Accreduaaon in the chemical
Held ot tettng as U«ed in the current AAIA Directory ol Accredited
•3-4-IS
-------
INTERNATIONAL
TECHNOLOGY
COBPOBATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED
PROJECT CODE.
ORDER NUMBER:
PAGE
September 30, 1987
ITEC 24761
805015
22_ OF 10
Sample Description: 555-35-1-5417, Clean Soil, 8/5/87, received August 6, 1987
VOLATILE ORGANIC ANALYSIS
Concentration
Compound
acetone1
chlorobenzena
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
35
NO
<5
NO
NO
NO
NO
Remarks: 5
NO
<
1
QuMt1tat1on Unit .
Not
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
: i'-=_r 'fl-A.
\V
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER. 805015
PAGE__23_ OF 39
Sample Description: 555-12-2A-5416, Treated Soil, 7-30-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexy1)phthalate
pentachlorophenol
Concentration
(yg/granO
<9.4
<9.4
60.
Remarks: 9.4 « Owpt1tat1on Unit.
NO « Nrff detected.
< « Detected but at a level less than the quantltatlon limit.
Laboratory Manager
Tllto
Aen«dii*dbyih«Am«nconAaoaoiionlorLateratofyteei«diioiionmitwelMfnical
tMkt
-------
INTERNATIONAL
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxvflle. TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER. 805015
PAGE__2A_ OF "SO
Sample Description: 555-14-2A-5416, Treated Soil, 7-30-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phtha1ate
pentachlorophenol
Concentration
(yg/gram)
NO
75
Remarks: 19 • Oi*it1tat1on limit.
ND - Not detected.
< » Detected but at a level less than the quantltatlon limit.
Laboratory Manager
THto
AccmdiMd by ih« Anwneon Aaocionon tor Laboratory Aocrvdnabon m ttw ch«mteal
of t««ing. as laMd in tn« cun»ni AALA Oiraaory ol AcawdMd LaboraiorMt
93»-«5
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviile Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
;«
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
KnoxvUle. TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER. 805015
PAGE___25_ OF ^0
Sample Description: 555-16-2A-5416, Treated Soil. 7-30-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
NO
NO
40.
Remarks: 20. • QHBt1tat1on limit.
NO - Not detected.
< * Detected but at a level less than the quant1tat1on limit.
Approved
Laboratory Manager
rm*
n«ld oi M«>no a* l««d in th* cuirwnt AA1A DirKMty at AcavdiMd Laborawnw
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO
IT Corporation
ATTN: Ed Alperin
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. JJEC 24761
ORDER NUMBER: 805015
PAGE 26 OF 19
Sample Description: 555-20-2A-5415, Treated Soil. 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phtha1ate
pentachlorophenol
Concentration
(tig/gram)
1,300
1,600
200
Remarks: 88 • CHfWt1t«t1on limit.
NO « Not detected.
< « Detected but at a level less than the quant1tat1 on limit.
Laboratory Manager
TU)«
Accr»dtt«d by th« Am«ncan AMoaobon tor Laboratory Aocn
t»M 01 iMing as land in the cunwtt AALA Directory « AcerMitod LaboraionM
aninth*ch«nical
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AlpeMn
312 Directors Drive
Knoxvllle. TN 37923
DATE REPORTED
PROJECT CODE.
ORDER NUMBER:
PAGE.
September 30, 1987
ITEC 24761
805015
-2jLOF_3L9_
Sample Description: 555-20-3A-5416, Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bi s(2-ethy1hexy1)phthalate
pentachlorophenol
Concentration
(ug/gram)
1,600
1,400
230
Remarks: 98 • Qwtltrtlon 11*11.
NO « Not detected.
< • Detected but at a level less than the quantHat1on limit.
Laboratory Manager
TIM
MM 01 t»«ing. at luted in in* cunwu AALA OifMoty « Aea«d>l«d Lafioratoow
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 nirectors nrlve
Knoxvllle, TN 37<»23
DATE REPORTED September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER: 805015
PAGE___28_ OF 1Q
Sample Description: 555-22-2A-5415, Treated Soil. 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexylJphthalate
pentachlorophenol
Concentration
(ug/gram)
NO
NO
ND
Remarks: 9.8 « O^Wtltatlon limit.
NO - ft* dttected.
< « Detected but at a level less than the quantltatlon limit.
Laboratory Manager
Aocr*dn«d by Om Amcnc
Al
Tlti*
anon tar Laboratory fe
rtaaen in OM ctwmicai
iwld oi tMdng. a MM in th* cxurant AALA Duwaory a AcawdiMd Labomonw
-------
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
a i ' . • •
TO IT Corporatfon
ATTN: Ed AT perin
312 Directors Drive
Knoxvllle. TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE: ITEC 24761
ORDER NUMBER: 805015
PAGE___2SL OF 3Q
Sample Description: 555-24-2A-5415, Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
ND
NO
ND
Remarks: 8.2 » OjUMtltatlon limit.
NO * Not dttected.
< « Detected but at a level less than the quant1tat1on limit.
Laboratory Manager
Tnt*
AccrwiMd by th» Am»ncon A»ocwnon tor laboratory Aca»d»abon m lh* etMnucal
Mid ol Wang at lows in the eunwu AALA DuvcMfy al Accr»dn«d Uaboraton«
-------
INTERNATIONAL
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER: 805015
PAGE___3Q_ OF ™
Sample Description: 555-26-2A-5415, Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
NO
ND
ND
Remarks: 9.4 * OjHMtltatlon limit.
ND « Not detected.
< » Detected but at a level less than the quantltatlon limit.
Laboratory Manager
TUto
Accr»dj««<3 by th« Anwneon A»oaono« tor Laboratory tocradnanan «Itw etwnueal
h»id ot iMting. at laMd in \t» cunvnl AALA OirKtaty oc AccrwSWd Laboratonw
»}•••«$
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Ptke • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE; ITEC 24761
ORDER NUMBER: 805015
PAGE___3J_ OF 39
Sample Description: 555-28-2A-5415, Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-etny1hexyl)phtha1ate
pentachlorophenol
Concentration
(tig/gram)
23
54
<9.5
Remarks: 9.5 • QuMtltitlon limit.
NO - Net detected.
< « Detected but at a level less than the quant1tat1on limit.
Laboratory Manager
Till*
Accr»dii«d by \ n> Am«ncon Aaoacmon tot Lobotqiory
ol (Ming a la>«d in m* cucrtnt AALA Duvciory oi AecmdiHd
m tt» chanueol
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO
IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE JTEC 24761
ORDER NUMBER: 805015
PAGE 32 OF ?Q
Sample Description: 555-36-2A-5415, Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATUE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
170
170
13
Remarks: 9.4 • Q*iiit1t«t1on limit.
NO - Not detected.
< * Detected but at a level less than the quantltatlon limit.
Approved
laboratory Manager
T1U*
Aoer«dit*d By th* Anwncon AaoaoRten tor Loborote
b*ld ex Mbno
-------
JJBSRH- ANALYTICAL
XION SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation DATE REPORTED: September 30, 1987
ATTN: Ed AT perl n PROJECT CODE: ITEC 24761
312 Directors Drive ORDER NUMBER: 805015
KnoxvWe, TN 37923 PAGE 33-OF_29
Sample Description: 555-38-2A-5416, Treated Soil, 8-5-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Concentration
Compound (ug/gram)
anthracene 5,800
b1s(2-ethylhexyl)phthalate 2,100
pentachlorophenol 330
Remarks: 78 * Ojptltatlon limit.
ND « Nf* dttccted.
< « Detected but at a level less than the quant1tat1on limit.
Laboratory Manager
T«!«
AocivdiMd 6y \t» American AmosMan lor LaboroMty Aeovdttabon m th* ehMnnal
b«ld 01 tMbng. a Ust«d in th* currtnl AAUK Diraetoiy ol facnaont Latoraton*
-------
nra
NAL ANALYTICAL
>N SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation DATE REPORTED: September 30, 1987
ATTN: Ed Alperln PROJECT CODE: ITEC 24761
312 Directors Drive ORDER NUMBER. 805015
Knoxvllle, TN 37923 PAGE 3A-OF_33_
Sample Description: 555-24-1R-5415. Treated Soil, 8-3-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Concentration
Compound (ug/qram)
anthracene
b1s(2-ethy!hexy1)phthalate NO
pentachlorophenol NO
Remarks: 10. * QuwtHatlon Unit.
NO • Not detected.
< • Detected but at a level less than the quantltatlon limit.
Apprwwab^
Laboratory Manager
Till*
Accr»a»l«d by th« American Aaoaotion tor Uifaoraiory A
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perl n
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. I TEC 24761
ORDER NUMBER: 805015
PAGE__25_ OF 10
Sample Description: 555-36-1R-5415, Treated Soil, 8-5-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexyl)phthalate
pentachlorophenol
Concentration
(yg/gram)
220
160
18
Remarks: 9.8 * Qutttltatlon limit.
NO * Not detected.
< * Detected but at a level less than the quant1tat1on limit.
Laboratory Manager
Aeei»drt«d by \t» Am«ncan A»oacOon tor Latxjratory Aocradttonon m th* etmnacal
tMtd ot mnng. 01 tai»d in in* curnnt AALA Du*cto*y o< AoovdiMd Loboretorm
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
-,*[ -—I--.-
J.• , .' > . , V
•
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER 805015
PAGE__3fi_ OF 3Q
Sample Description: 555-6-2-5415, Untreated Soil, 7-29-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexylJphthalate
pentachlorophenol
Concentration
(yg/gram)
350
150
29
Remarks: 9.8 * QuMtttatlon limit.
NO - Not detected.
< * Detected but at a level less than the quant1tat1on limit.
Laboratory Manager
Titto
Accr*dx«d by ih* Am«ncon fmosunon tor Laboratory AoavdMaoon at ttw crwmoal
ol totting, as toMd in th« cunwu AALA DiMCMry ot Accr»dn«d LaboratonM
-------
AT1ONAL
fOLOGY
RATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed A!perin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. ITEC 24761
ORDER NUMBER. 805015
PAGE__3I_ OF IP
Sample Description: 555-6-3-5416, Untreated Soil, 7-29-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
4.700
2,900
230
Remarks: 100 « Quwtltatlon limit.
NO » Not detected.
< * Detected but at a level less than the quantitation limit.
Approved by/
Laboratory Manager
TIU*
•Utabon m ih* chemical
Accredited by th« Am«ncan AHoaatton tot Laboratory i
twld of iMbng. at l««d in th» current AAUA Duectofy ot AecradtMd Laboroionw
*3-»-U
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE ITEC 24761
ORDER NUMBER: 805015
PAGE___3j8_ OF 3Q
Sample Description: 555-6-4-5416, Untreated Soil, 7-29-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/gram)
3,900
2,700
210
Remarks: 50. - Oj«*1tat1on limit.
NO - Nit detected.
< - Detected but at a level less than the quant1tat1on limit.
Approved by
Laboratory Manager
Till*
Accredited by the American Aaoootien tor Lobe
V AecradtioiMn tn ttw chMiuool
Mid o< Mttng. 01 lot*d in th« cunwu AALA OuvcMty at AecndiMd I nrrmvii m
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperfn
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 2d761
ORDER NUMBER 805015
PACE 3Q OF 3Q
Sample Description: 555-35-1-5417, Clean Soil, 8-5-87, received August 6, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(tig/gram)
NO
NO
NO
Remarks: 9.7 « OjMfltltatlon limit.
NO - Hart detected.
< » Detected but at a level less than the quant1tat1on limit.
Approved
Laboratory Manager
TtU*
AocivdiMd by th« Anunoan A*oaemon tor Laboratory AcowdUaBon i
Mid oi i««ing. a M«d in tn« eunvnt AA1A Dirwciory el AccMdiMd LoboraionM
K-t-tt
-------
INTERNATIONAL
TECHNOLOGY
CORPORATIO
ON
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
KnoxvWe, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE; ITEC 24868
ORDER NUMBER. 805015
PAGE__1_ OF 37
Sample Description: Four (4) soil samples received August 24, 1987
Concentration units are mg/kg (ppm) on a dry weight basis
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
I Moisture
555-53-3A
22.1
23.2
27.8
281
328
25.1
639
555-56-2A
21.5
20.7
27.2
301
248
25.0
579
13.11
555-63-5A
555-64-1A
19
23
28
291
323
25
654
.6
.3
23
22
27
337
331
24.8
653
17.41
Laboratory Manager
Till*
Acci*dit«d by th» Anwncon AMoaobon tor Laboratory AccradiicMon inttwchMmeol
ti«id 01 tMnng. os im«d in ih* cun«M AALA Oiraoory at Aecradn«d Loberaton«
-------
G3
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middiebrook Pike • Knoxvilie Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PAGE_JL_ OF 37
Sample Description: Three (3) soil samples received August 24, 1987
Concentration units are mg/kg (ppm) on a dry weight basis
Arsenic
Cadmium
Chromium
Copper
Lead
Nickel
Zinc
1 Moisture
555-67-2A
20.8
26.4
31.6
361
361
29.0
761
0.36
555-70-2A
32.2
40.6
50.9
491
521
46.3
1,060
45.60
555-77-2A
19.3
26.0
30.9
399
345
28.0
745
1.90
Approved
Laboratory Manager
TH*
Accredited by th« Anwncon Aaoctouon lor Laboratory AecrwdrtoOon in the awnueaJ
Mid ot Mdn0 as imd in the eunwtt AA1> DvKtoiy « Aca«dsi*d Laboraiottw
-------
INTERNATIONAL
TECHNOLOGY
COKPOBATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. ITEC 2A868
ORDER NUMBER: 805015
PACE * OF 37
Sample Description: 555-53-3A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
fug/kg dry weight)
5,400
14
33
120
7
15
220
Remarks: 5
NO
1
X Moisture
QuantUation Unit
Not detected
OtttCttd but at a level less than the quantitation limit,
Tbfs component has a quant1tatIon limit two (2) times that listed.
Laboratory Manager
Til*
ikxk
Accredited by the American AMOS
held oi w«ir«. at iwed in trie current AALA Oireeiocy oi
in the dwmiccti
Loboraionet
-------
INTEfiNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middiebrook Pike • Knoxviiie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxviiie. TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER: 805015
A OF 37
Sample Description: 555-56-2A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(vg/kg dry weight)
2,300
<6
33
40.
ND
6
95
Remarks:
6
ND
<
1
Quantitation Limit
Not detected
but at a level less than the quant 1 tat ion limit,
component has a quantitation limit two (2) times that listed.
% Moisture •
Laboratory Manager
Till*
Accredited by tlw Airwncon AMecionon lor Loboratoty Aecradtett
(MM of Mfiino. a* Usi«d in th« cun«n AALA Diractory ex AecradMd
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxvilie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle. TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER. 805015
PAGE__5__ OF 37
Sample Description: 555-63-5A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg dry weight)
670
<5
5
15
<5
<5
40.
Remarks: 5
ND
1
% Moisture
Quant1tat1on Limit
Not detected
OcUcttd but at a level less than the quantltatlon limit,
This component has a quantltatlon limit two (2) times that listed,
Laboratory Manager
TUto
AccrwdtMd by th« American AMociation tor Laboratory AccJuMatton in th* chvmca)
ot mono, at lifl«d in th« cumnt AALA Ouvciory el AcowattwS Loboranonw
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
PAGE fi OF **7
Sample Description: 555-64-1A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dlchloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg dry weight)
3,500,000
310,000
160,000
2,600,000
680,000
400,000
5,000,000
Remarks: 6,100
NO
<
1
Quant1tat1on Limit
Not detected
QfUcted but at a level less than the quant 1tat 1 on
Tills component has a quantltatlon limit two (2) times that listed,
% Moisture • 17.41
Approved
Laboratory Manager
•nil*
Accredited By ih« Amcncon Awoaooon tor Lob
iy Accradttouon m th« chemical
n«id oi tMQng. a M«d in th* cumni AALA Omciory « AecradMd Laboraionw
93-»-i5
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. ITEC 24868
ORDER NUMBER. 805015
PAGE_2__ OF 37
Sample Description: 555-67-2A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-di chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg dry weight)
5,000
20.
27
170
NO
17
270
Remarks: 5
NO
i
Quant nation Limit
Not detected
Detected but at a level less than the quantitat1 on limit.
This component has a quant1tation limit two (2) times that listed.
1 Moisture • 0.36
Laboratory Manager
Till*
Accredited by the American Aaocxreon lor Laboratory A
held of tewing. o» luted In the current AALA Directory o» Accredtted
m the chemical
Uuxratone*
U-+4S
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perln
312 Directors Drive
Knoxvllle. TN 37923
DATE REPORTED. September 30. 1987
PROJECT CODE ITEC 24868
ORDER NUMBER. 805015
PAGE__8__ OF 17
Sample Description: 555-70-2A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(fg/kg dry weight)
1,300,000
420,000
36,000
4,200,000
NO
490,000
7,500,000
Remarks: 460
NO
1
Quant 1tat1on Unit
Not detected
tatecttd but at a level less than the quantnation limit.
TMs component has a quantltatlon limit two (2) times that listed,
% Moisture • 45.60
, X*
Approved
Laboratory Manager
Accredited by th* Am«ncan AMoaanon tar Laborawnr Aeawd*
tick) « i«nno. at UMd in Uw current AAlA Oiraaofy rt AccMtttd
in th* ehwrucol
Labaraton**
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alpenn
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED; September 30, 1987
PROJECT CODE. ITEC 24868
ORDER NUMBER 805015
PAGE__a__ OF 37
Sample Description: 555-77-2A (Soil) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg dry weight)
59,000
53
8
400
NO
18
1,400
Remarks: 5 * Quantltatlon Limit
ND - Not detected
< • Detected but at a level less than the quantltatlon limit.
1 * Thlf component has a quantltatlon limit two (2) times that listed,
X Moisture • 1.90
Approved
Laboratory Manager
Accredited by me Amenoan Aexootion lor Laboratory Accreditation in the cftemical
Mid 01 letnna a* Wed in the current AALA Directory of Accredited Laboratory
-------
INTERNATIONAL
TECHNOL
(LOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PAGE__lfl— OF ^7
Sample Description: 555-74-1R (Condensate, Scrubber & Rinses) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/Hter)
1,240,000
NO
<25,000 (13,000)
<25,000 (21,000)
NO
NO
NO
Remarks: 25,000 * Quantltation Limit
NO • Not detected
< • Detected but at a level less than the quantltation limit. Values
1n parenthesis are estimated.
1 « This component has a quantltation limit two (2) times that listed.
Laboratory Manager
TWK
by th* American Aaonanon tor Laboratory i— .... _.._ — .^^,
twtd 01 t«*ing as UMd in ih* cumra AALA Dmenry at Aoendttcd LaboratorMt
-------
ES3
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviile Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 24868
ORDER NUMBER: 805015
PAGE__1L_ OF 37
Sample Description: 555-74-2R (Condensate, Scrubber & Rinses) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/llter)
970,000
<25,000 (6,300)
<25,000 (8,500)
<25,000 (17,000)
NO
NO
NO
Remarks: 25,000 « Quantitation Limit
NO • Not detected
< * Otttcttd but at a level less than the quantitation limit. Values
In parenthesis are estimated.
1 » This component has a quantitation Unit two (2) times that listed,
Approved
Laboratory Manager
Till*
~.<.wui«u or in* wwncon AMOOonon lor LatoOftjic»Y Aocmduoaon m th* chemical
ii«id 01 t*mng. at kmd m th* curmtt AALA Duwdory o< ACOMUM Loboraionw
•-*-
Accrtdilvd by th» An
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville. TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PAGE___12_ OF 37
Sample Description: 555-74-3R (Condensate, Scrubber & Rinses) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(yg/liter)
1,500.000
<25,000 (5,900)
<25,000 (9,300)
<25,000 (14,000)
NO
NO
NO
Remarks: 25,000 * Quantitation Limit
NO « Not detected
< » Detected but at a level less than the quant1tation limit. Values
In parenthesis are estimated.
1 » This component has a quantitation limit two (2) times that listed
Approved b^
Laboratory Manager
TUfr
Accredited by the Ai
held 01 letting. o»
i tor Loborotorr AocndHonon m th* chemical
bttod m Uw cxin*nt AAJLA OirKMiy « AcCTBdtUd Latanaanm
-------
CORPORATION SERVICES
5815 Middiebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxville. TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER. 805015
PAGE 13 OF 37
Sample Description: 555-74-4R (Condensate, Scrubber & Rinses) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(»g/11ter)
1,100,000
NO
<25,000 (19,000)
<25.000 (19,000)
NO
NO
NO
Remarks: 25,000 • Quantitation Limit
NO • Not detected
< « Detected but at a level less than the quantHation limit. Values
1n parenthesis are estimated.
1 • This component has a quant1tation limit two (2) times that listed.
Laboratory Manager
TUto
Accredited by the American AMoaanon tor Laboratory
held 01 iMing. at l*ed in (he cumnl AALA Directory at
m th* chemical
-------
INTERNATIONAL
TECHNOLOGY
COBPOKATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvflle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER 805015
PAGE 1A OF 37
Sample Description: 555-74-5R (Condensate, Scrubber & Rinses) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(tig/liter)
180,000
ND
<25,000 (8,400)
<25,000 (7,100)
ND
ND
ND
Remarks: 25,000 * Quant1tat1on Limit
ND • Not detected
< * Dttected but at a level less than the quant1tat1on limit. Values
In parenthesis are estimated.
1 » This component has a quantltatlon limit two (2) times that listed,
Laboratory Manager
Till*
Acer«dii*d by th* Amcncon Aaoaonon tor Loboratoiy AeovdMoaen to m* ehMTueol
(Mid ot Mtong. at laud in ttw eunvnl AALA Directory at Acavdittd Laoonuunm
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER. 805015
PAGE__15_ OF 37
Sample Description: 555-53-3A (Soil) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexyl)phtha1ate
pentachlorophenol
Concentration
(tig/kg dry weight)
34,000
NO
<20,000 (200)
Remarks: 20,000 • Quantltatlon limit.
NO • Not detected.
< « Detected but at a level less than the quant1tat1on limit. Values in
parenthesis are estimated.
1 » This component has a quantltatlon limit two (2) times that listed.
% Moisture • 0
Laboratory Manager
Till*
i American Awoaanon tor Laboratory Accreditation m the chemical
neid ot tenina. at UMd in the current AAUk Directory ot Accredited Uatoraionet
-------
E£J
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
PAGE_16_ OF 17
Sample Description: 555-56-2A (Soil) received August 24. 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexy1)phtha1ate
pentachlorophenol
Concentration
(ug/kg dry weight)
12,000
NO
NO
Remarks: 11,000 * Quantitation limit.
NO - Not detected.
< • Detected but at a level less than the quantitation limit.
1 » This component has a quantitation limit two (2) times that listed.
% Moisture » 13*11
Laboratory Manager
TIM
u«ia o( Ming.
in \t* eun«n> AALA Du*do*y ai AoendMd Lot/orator**
-------
E53
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxviiie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
17 OF 17
Sample Description: 555-63-5A (Soil) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethy1hexy1)phtha1ate
pentachlorophenol
Concentration
(ug/kg dry weight)
<9,800 T9.000)
<9,800 (1,000)
<9,800 (2.000)
Remarks: 9,800 = Quantitation limit.
NO * Not detected.
< * Detected but at a level less than the quant1tat1on limit. Values in
parenthesis are estimated.
1 • This component has a quant1tat1on limit two (2) times {hat listed.
1 Moisture « 0
L*LZs^ ^T
Approved tff
Laboratory Manager
Tltt*
Aecr»d««d Dy tt» Anwncon Aaoaonon ttr Laboratory tccn&eaan m ttw ctwmieal
ti«id ol mung. a» itti«d m ttw cunwit AAtA DirKiafy ol AxtvdtMd lataeratonm
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER: 805015
PASE Ifl OF 37
Sample Description: 555-64-1A (Soil) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexy1)phtha1ate
pentachlorophenol
Concentration
(ug/kg dry weight)
1,600,000
2,400,000
<1,100,000 (850,000)
Remarks: 1,100,000 • Quantltatlon limit.
NO * Not detected.
< * Detected but at a level less than the quant1tat1on limit. Values in
parenthesis are estimated.
1 • This component has a quantltatlon limit two (2) times that listed.
% Moisture • 17.41
Approved
mi*
Laboratory Manager
Accredited by the Amenean AMOciotion tot Lab
nrAoavdncraon in the chemical
oi i«*nng. a* lined tn the cvureni AALA Duedory of Accredited Laboratory
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED September 30. 1987
PROJECT CODE I TEC 24868
ORDER NUMBER 805015
PAGE__13_ OF 37
Sample Description: 555-67-2A (Soil) received August 24. 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexy1)phthalate
pentachlorophenol
Concentration
(ug/kg dry weight)
2,100,000
1,300,000
240,000
Remarks: 200,000 * Quant1tat1on limit.
NO * Not detected.
< • Detected but at a level less than the quantitat1on limit.
1 * This component has a quant1tation limit two (2) times that listed.
% Mo1stur» - 0.36
Approwdbr
.aboratory Manager
Tltto
Accr*diMd by th« Anwneon A«oaanon tar liberate
tdnenonin th* ctMnucol
01 (Ming, as UMO in the currant AAIA Ouvoory « AecndMd LataRMmt
-------
rra
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
PAGE_2Q_ OF 37
Sample Description: 555-70-2A (Soil) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexyl)phtha1ate
pentachlorophenol
Concentration
(ug/kg dry weight)
<170,000 (160,000)
3,100,000
460,000
Remarks: 170,000 « QuantHatlon limit.
NO » Not detected.
< • Detected but at a level less than the quant1tat1on limit. Values In
parenthesis are estimated.
1 • This component has a quantltatlon Unit two (2) times that listed.
% Molsturt • 45.60
Approved
Laboratory Manager
Til*
Accredited by th* Amencon Aaoctoflon lor Laboratory Aocnduatton in m* chemical
Held 01 wane, as uaed in in* cunwni AALA Omctory oi AceradMd Laboratonw
-------
INTERNATIONAL
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxvilie. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvilie, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE I TEC 24868
ORDER NUMBER. 805015
PAG£__2I_ OF
Sample Description: 555-77-2A (Soil) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/kg dry weight)
1,200,000
1,600,000
280,000
Remarks: 190,000 « Quant1tatIon limit.
NO - Not detected.
< • Detected but at a level less than the quantUatlon limit.
1 • This component has a quantUatlon limit two (2) times that listed,
X Moisture • 1.90 v
Approved
Laboratory Manager
Till*
Accr»dtt«d by th« American AMoacmon tor Laboratory Accndttauan m ttw chemical
01 twbno. 01 M«d in in* oanrt AALA Directory ol AcerKMd LaboraiorMi
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE. ITEC 24868
ORDER NUMBER 805015
PAGE__22_ OF 37
Sample Description: 555-53-5R (Filter & Rinse) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(no.)
<10. (1)
NO
NO
Remarks: 10.
ND
Quant1tat1on limit.
Not detected.
Detected but at a level less than the quant1tat1on limit. Values 1n
parenthesis are estimated.
This component has a quantItat1on limit two (2) times that listed.
Approve
Laboratory Manager
TU*
Accredited by th» Anwncon AHoetoaon tor Laboratory Accreditation in m* ehamieoi
01 t«nn0. as w«d m Ow currant AALA Directory ol Accredited latomonm
-------
EEJ
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER: 805015
PAGE___23_ OF 17
Sample Description: 555-59-6R (Filter & Rinse) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexy1)phtha1ate
pentachlorophenol
Concentration
(no.)
45
ND
NO
Remarks: 10. - Quantltatlon Hm1t.
ND * Not detected.
< * Detected but at a level less than the quant1tat1on limit.
1 « This component has a quant1tat1on limit two (2) times that listed.
Laboratory Manager
Tltto
AccradiMd by m* Arrwncon AHoaonon lor Laboratory Accmdaatten in th« chwnucol
oi MOing a inMd m tiw cunwn AALA OMdery « Accraditod LabocntorM*
-------
ANALYTICAL
CORPORATION SERVICES
5815 Middlebrook Pike • Knoxviite. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
PAGE_24_ OF 37
Sample Description: 555-63-2R (Filter & Rinse) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug)
28
NO
<10. (3)
Remarks: 10. - Quantltatlon limit.
NO * Not detected.
< * Detected but at a level less than the quant1tat1on limit. Values in
parenthesis are estimated.
1 - This component has a quantltatlon limit two (2) times that listed.
Approved fa*/
Laboratory Manager
Tit*
Accreditedbyth»Anwnco)AaonotiontorLobaratanrAccradiianeninttwctwcnicai
u*ld o) tMbng. at M«d m th« cumnt AALA Duwaocy at AocndM*d Laboratorm
-------
:ONAL
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED; September 30, 1987
PROJECT CODE: I TEC 24868
ORDER NUMBER: 805015
PAGE__25_ OF 37
Sample Description: 555-70-6R (Filter & Rinse) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug)
NO
<10. (5)
NO
Remarks: 10. * Quantltatlon limit.
NO « Not detected.
< = Detected but at a level less than the quantltatlon limit. Values In
parenthesis are estimated.
1 - This component has a quantltatlon limit two (2) times that listed.
Approved tjr
Laboratory Manager
Tltto
Accredited by m* American Aaoaaflon tor Laboralo
oMttwmon in tlw chemical
ti«W ol MDng. as u**d in th« cunvnt AALA Diraclaiy « AoortdiMd LatoraionM
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER: 805015
PAGE__26_ OF ^7
Sample Description: 555-56-5R (Filter & Rinse) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ufl)
160
NO
<10. (2)
Remarks: 10.
ND
Quantltatlon limit.
Not detected.
Detected but at a level less than the quant1tation limit. Values in
parenthesis are estimated.
This component has a quantltatlon limit two (2) times that listed.
Approved
Laboratory Manager
Till*
Aectudn^d by m» Am«ncan Amoaaaon let Laboratory Accmfliottem in tt» ehanucol
oi wang. a inwd in th« eumnt AALA Oiraciafy o* AoeradMd LaOorenonm
-------
EE3
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PAGE__22_ OF.
Sample Description: 555-74-1R (Condensate, Scrubber & Rinses) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(ug/Hter)
340.000
3,500
21,000
Remarks: 630 * QuantUatlon limit.
ND * Not detected.
< * Detected but at a level less than the quant1tat1on limit.
1 • This component has a quantHatIon limit two (2) times that listed.
Approved
Laboratory Manager
•mm
TV*
Accredited br 0» Amancon Aaoaanon tor Labaraiofy Aceraditaban in m* chwnical
ti*id 01 MMhne. a iMd m u>* cunvni AALA Ouveiaty o< AccradiMd Lafioratonw
»3-*-«5
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PAGE__28_ OF 37
Sample Description: 555-74-2R (Condensate, Scrubber & Rinses) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexy1)phtha1ate
pentachloropnenol
Concentration
(ug/Hter)
3,100
2,400
200,000
Remarks: 590 * Quant1tatIon limit.
NO * Not detected.
< * Detected but at a level less than the quant1tat1 on limit.
1 * This component has a quant1tat1on limit two (2) times that listed.
Laboratory Manager
AecT*d>t«d by ih* Amm
TUto
cxrton tor Loboralofv faai&uean in th» ctwmioal
»3-»-4S
01 tcttng. as i*«d in th« euirart AA1A Diracionr el Aea»dii«d LabaratoiM*
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middiebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE. ITEC 24868
ORDER NUMBER: 805015
PAGE_29_ OF 37
Sample Description: 555-74-3R (Condensate, Scrubber & Rinses) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexylJphthalate
pentachlorophenol
Concentration
WMter)
320,000
1,100
14,000
Remarks: 590 * Quant1tat1on limit.
ND « Not detected.
< » Detected but at a level less than the quant1tat1on limit.
1 - This component has a quantltatlon limit two (2) times that listed.
Laboratory Manager
T«l*
AaKxaotMrt lor UiboratoiY Aca^duaucn m lh« etmnical
t3-*-«i
ot iM»n0. a* l««d in th« cunwv AALA Duvctory a( Aoet«d>i*d
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlefirook Pike • KnoxviHe Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxville. TN 37923
DATE REPORTED; September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER. 805015
PAGE__ifl_ OF 37
Sample Description: 555-74-4R (Condensate, Scrubber & Rinses) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
bis(2-ethylhexy1)phtha1ate
pentachlorophenol
Concentration
(ug/Hter)
28,000
1,900
7,400
Remarks: 59 * Quantitation limit.
ND = Not detected.
< * Detected but at a level less than the quantitation limit.
This component has a quant1tat1on limit two (2) times that listed.
i
Approved (v
Laboratory Manager
TlU*
notion lor Laboratory Acciedftnon in *• chemical
Accredited by the American
Held 01 teaing. a* Med in the cuneni AALA Directory oi Accredited
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
- *
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER: 805015
PACE 31 OF 37
Sample Description: 555-74-5R (Condensate, Scrubber & Rinses) received August 24, 1987
SEMIVOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethy1hexy1)phthalate
pentachlorophenol
Concentration
(ug/Hter)
190
NO
150
Remarks:
67
ND
<
1
Quant1tat1on limit,
Not detected.
Detected but at a level less than the quant 1t at 1 on limit.
This component has a quant 1t at 1 on limit two (2) times that listed.
Approved
Laboratory Manager
TIM
Accredited by ttw Anwncon Aaoootton tar babocMocy Aocmdttotxin in ID* ctwmieaJ
Mid ot t«ttine. as UMd in «M eun«ni AA1A Diraciory en tcamaam LafaoraMn«
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE. I TEC 24868
ORDER NUMBER: 805015
PAGE_32_ OF 37
Sample Description: T1886, 555-53-6R & TC2294, 555-53-7R (VOST) received August 24. 198',
VOLATILE ORGANIC ANALYSIS
Concentration
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
1,100
940
2,200
15.000
500
3.700
15.000
Remarks: 10.
ND
Quantitatlon Limit
Not detected
Detected but at a level less than the quantitation limit.
This component has a quantitation limit two (2) times that listed,
Approved bK
Laboratory Manager
Till*
AcerwAMd by th« Anwncon Aaoaenon tor Laboratory AecradttaUan in ttw ctwmieai
oi M«tng. at U**d in in* cunwnt AA1A OirKMiy el Aocracbivd LabaraionM
»>*-«
-------
T
c
NATIONAL
7OLOGY
^ON
ANALYTICAL
SERVICES
5815 Middle&rook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed AT perin
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE:
ORDER NUMBER:
PAGE
September 30, 1987
ITEC 24868
805015
33_ OF •*?
Sample Description: T3717, 555-56-7R & TC2297, 555-56-8R (VOST) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug)
2.200
1,400
3,100
18,000
630
4,000
19,000
Remarks:
10.
NO
<
1
Quant 1t at 1 on Limit
Not detected
Detected but at a level less than the quant 1t at 1 on limit.
Tfct* component has a quant 1t at 1 on limit two (2) times that listed.
Laboratory Manager
Till*
Accredited by tt» Am*ncon Aaoaooon lor Laboratory Aocrvdttaaon in ttm chwiueoi
b«id oi iMnng. as w«d in th* amwtf AALA Dmeioiy el AoavdMd Laboraton
-------
INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville, Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alpenn
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED: September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER: 805015
PASS 34 OF 37
Sample Description: T3316, 555-63-4R A TC3069, 555-63-3R (VOST) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug)
1,900
1,300
3,400
15,000
880
4,300
17,000
Remarks: 10.
NO
QuantUatlon Limit
Not detected
Detected but at a level less than the quant1tat1on limit.
THIs component has a quant1tat1on limit two (2) tines that listed.
Laboratory Manager
TIM
01 iMtinQ. a» iM«d in th« currant AALA Dirwaory o( AocrMMd Uibeiqioim
-------
INTZfiNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alpen'n
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED September 30, 1987
PROJECT CODE ITEC 24868
ORDER NUMBER 805015
PAGE_aS_ OF 37
Sample Description: T3029, 555-67-8R * TC1813, 555-67-7R (VOST) received August 24, 1987
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug)
1.100
1,200
5,200
15,000
600
4,100
14.000
Remarks:
10.
NO
<
1
Quant i tat ion Limit
Not detected
Detected but at a level less than the quant 1 tat Ion limit.
This component has a quant 1 tat ion limit two (2) times that listed.
Approved
Laboratory Manager
Tito
u»ld oi t«itino. a* luted in ttw cun«nt AALA OuvetoiY « AcefBdiHd Labaraion«*
-------
iT8
INTEBNATJONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
Knoxville, TN 37923
DATE REPORTED
PROJECT CODE.
ORDER NUMBER
PAGE.
September 30, 1987
ITEC 24868
805015
_3jfi_OF_3I__
Sample Description: T3463, 555-70-8R & TC3455, 555-70-7R (VOST) received August 24, 198:
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
1,2-dichloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug)
2.100
1,500
4,200
14,000
1,100
2,400
16,000
Remarks:
10.
NO
<
l
Quant1tat1on Limit
Not detected
Dtttcttd but at a level less than the quantltatlon limit.
component has a quantltatlon limit two (2) times that listed,
Approval br
Laboratory Manager
Till*
Accredited by the American Aeiociaoon lor Laboratory Accreditation in the chemical
Held 01 letting a luted in the current AALA Directory ot Accredited Laboratories
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INTERNATIONAL
TECHNOLOGY
CORPORATION
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville, Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO IT Corporation
ATTN: Ed Alperin
312 Directors Drive
KnoxvUle, TN 37923
DATE REPORTED. September 30, 1987
PROJECT CODE: ITEC 24868
ORDER NUMBER. 805015
PAGE__3Z_ OF 37
Sample Description: Five (5) condensate, scrubber & rinse samples received
August 24, 1987
555-74-1R
555-74-2R
555-74-3R
555-74-4R
555-74-5R
Aqueous Phase
Volume
(ml)
160
170
170
170
150
Organic Phase
Volume
(ml)
60
40
60
50
50
Approved
Laboratory Manager
Accrwdiiad by 9» Anwncon Aaoaottan tor Laboratory Aocraa
Mid ol tMiino- a laud in ID* currant AALA OMCIOIY ai
-------
iNAL
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
IT Corporation
ATTN: Ed Alperln
312 Directors Drive
KnoxvWe, TN 37923
DATE REPORTED:
PROJECT CODE:
ORDER NUMBER:
PAGE-
October 12. 1987
ITEC 24899
805015
_L_OF_3
Sample Description: 561-7-2A-5415, 8/30/87 (Soil)
VOLATILE ORGANIC ANALYSIS
Compound
acetone1
chlorobenzene
l,2-d1chloroethane
ethyl benzene
styrene
tetrachloroethene
xylenes (total)
Concentration
(ug/kg dry weight)
37,000
17
NO
64
250
NO
360
Remarks: 10.
NO
I Moisture •
Quant1tat1on Limit
Not detected
QfUcttd but at a level less than the quant 1 tat Ion limit.
component has a quantltatlon Unit two (2) times that listed,
Apprewd
Laboratory Manager
•mi*
Accfwltttd by ttw AiiMfnun AModQQon tor l/ibofimj^
Mid ex (Mono, ca UMd m th« cumn AA1A Ouwtoiy
in ttw ctMmioal
-------
ANALYTICAL
SERVICES
5815 MiddleOrook Pike • Knoxville. Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO: IT Corporation
ATTN: Ed AlpeHn
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED:
PROJECT CODE.
ORDER NUMBER
PAGE.
October 12, 1987
ITEC 24899
805015
Sample Description: 561-7-2A-5415. 8/30/87 (Soil)
SEMI-VOLATILE ORGANIC ANALYSIS
Compound
anthracene
b1s(2-ethylhexyl)phthalate
pentachlorophenol
Concentration
(yg/kg dry weight)
340,000
220,000
38,000
Remarks: 21,000
NO
Molstu
Quant nation limit.
Not detected.
•cted but at a level less than the quant1tat1 on I1p1t.
Laboratory Manager
TUto
AccfvdMd by th* American AMoeioMn tor U
IwM at tMOng. at M*4 in th« eunwK AALA Oirtoory «
-------
INTERNATIONAL
HNOLOGT
ANALYTICAL
SERVICES
5815 Middlebrook Pike • Knoxville Tennessee 37921 • 615-588-6401
CERTIFICATE OF ANALYSIS
TO. IT Corporation
ATTN: Ed Alperln
312 Directors Drive
Knoxvllle, TN 37923
DATE REPORTED
PROJECT CODE:
ORDER NUMBER
PAGE-
October 12, 1987
ITEC 24899
805015
-3_OF__3__
Sample Description: One (1) soil sample received August 31, 1987
Concentration units are mg/kg dry weight
Arsenic
Cadmlurn
Chromium
Copper
Lead
Nickel
Z1nc
X Moisture
561-7-2A-5415
8/30/87
18.0
32.3
32.8
289
314
31.6
631
4.73
Laboratory Manager
•no*
Accr»cut«
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