EPA/540/2-89/035
SUPERFUND TREATABILITY
CLEARINGHOUSE
Document Reference:
Shirco Infrared Systems. "Final Report, Onsite Incineration Testing at Brio Site,
Friendswood, Texas" Final Technical Report No. 8467-87-1 prepared for the U.S. EPA
Brio Task Force. Approximately 750 pp. February 1987.
EPA LIBRARY NUMBER:
Superfund Treatability Clearinghouse - EZZB
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SUPERFUND TREATABILITT CLEARINGHOUSE ABSTRACT
Treatment Process: Thermal Destruction - Infrared
Media: Soil/Clayey
Document Reference: Shirco Infrared Systems. "Final Report, Onsite
Incineration Testing at Brio Site, Friendswood,
Texas" Final Technical Report No. 8467-87-1
prepared for the U.S. EPA Brio Task Force.
Approximately 750 pp. February 1987.
Document Type: Contractor/Vendor Treatability Study
Contact: U.S. EPA - Region I
John F. Kennedy Federal Building, Room 2203
Boston, MA 02203
617-565-3715
Site Name: Brio Refinery Superfund Site (NPL)
Location of Test: Friendsvood, TX
BACKGROUND! Shirco Infrared Systems, operated a pilot-scale infrared unit
on-site at the Brio Refinery Site in Texas. Eight tests were run over a
four day period with various soil compositions, including clay-like soils
from four pits.
OPERATIONAL INFORMATION; The objectives of these thermal pilot treatment
tests on excavated pit material were as follows:
1. To determine the incinerator ash chemical composition.
2. To demonstrate that the incinerator feed system can reliably provide a
continuous, blended feed to the incinerator and deposit this feed
material in a uniform manner on the incinerator belt.
3. To demonstrate that the incinerator can meet the RCRA required >99.99%
destruction efficiency for Principal Organic Hazardous Constituents
(POHCs).
4. To provide design information and economic data required to evaluate
the feasibility of incinerating certain Brio Site pit wastes.
The feed analyses targeted approximately 120 priority pollutants.
However, only 18 were usually found above the detection limits. Each
sample tested vas about 50 pounds and was spiked with carbon tetrachloride
as the principal organic hazardous constituent. The soil was mechanically
worked and screened to break up clay lumps. The destruction of the spiked
contaminant vas used to measure the success of the testing. Other analyses
performed included analysis of the scrubber inlet & outlet, stack flow, and
ash. The ash analyses included a mass and volume reduction analysis.
PERFORMANCE; Removal efficiency under all test conditions with 12 or 18
minute primary chamber residence time at 1600°F was greater than 99.9997%.
The cost of treatment with their largest mobile unit, which will process
67,000 tons per year, was estimated at $119 per ton. This does not include
costs of feed excavation, feed preparation, interest and taxes. The
document details each aspect of the tests, which lends much credibility to
3/89-15 Document Number: EZZB
NOTE: Quality assurance of data may not be appropriate for all uses.
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its data. QA/QC and sampling protocol are given along with details of the
testing procedures, test equipment, materials, and results. Sections are
devoted entirely to results, safety procedures, an economic analysis and
conclusions and recommendations.
CONTAMINANTS;
Analytical data is provided in the treatability study report.
breakdown of the contaminants by treatability group is:
The
Treatability Group
WOl-Halogenated Aromatic
Compounds
W04-Halogenated Aliphatic
Solvents
W07-Heterocyclics and Simple
Aromatics
W08-Polynuclear Aromatics
W09-0ther Polar Organic
Compounds
CAS Number
108-90-7
71-55-6
79-34-5
75-35-4
107-06-2
56-23-5
67-66-3
127-18-4
79-01-6
75-01-4
71-43-2
100-41-4
100-42-5
91-20-3
85-01-8
67-64-1
75-15-0
Contaminants
Chlorobenzene
1,1,1-Trichloroethane
1,1,2-Tetrachloroethane
1,1-Dichloroethene
1,2-Dichloroethane
Carbon Tetrachloride
Chloroform
Tetrachloroethene
Trichloroethene
Vinyl Chloride
Benzene
Ethylbenzene
Styrene
Naphthalene
Phenanthrene
Acetone
Carbon Disulfide
3/89-15 Document Number: EZZB
NOTE: Quality assurance of data Bay not be appropriate for all uses.
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FINAL REPORT
ON-SITE INCINERATION TESTING
AT
BRIO SITE
FRIENDSWOOD, TEXAS
BY
SHIRCO INFRARED SYSTEMS PORTABLE TEST UNIT
FEBRUARY 10 - 13, 1987
REPORT NO. 8A6-87-1
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TABU OP COHTHTP8
P»ge
No.
Executive Summary 1
l.o introduction 4
2.0 Test Equipment 5
2.1 General s
2.2 Peed Material 5
2.3 Primary Chamber 5
2.4 Secondary Chamber. 6
2.5 Combustion Air System 6
2.6 Off Gas Handling Systam 6
2.7 control Systam .7
2.8 Data Acquisition Systam 7
2.9 Haating Zlamant Povar Cantars (RIFCs) 8
Pigura 2.1 Procass Plow Diagram
3.0 Sita and Tast Matarial Dascription 10
3.1 Sita Dascription 10
3.2 Tast Matarial 10
Pigura 3.1 Facility Layout
4.0 Tast Procaduras * . 13
.1 Equipment Set-Up 13
.2 Systam Heat-Up 13
.3 Material Peed 13
.4 operational History 13
.5 Scrubbing System 16
.6 Operating Data Log 16
.7 operating Conditions 16
4.7.1 Test Condition Matrix
Table 4.7-1 Process conditions
4.7.2 Primary Chamber Temperature
4.7.3 Primary Chamber Residence Time
4.7.4 Secondary Combustion Chamber (SCC) Temperature
.7.5 Primary and SCC Combustion Air
.7.6 Soil Peed Rate
.7.7 System Povar Usage
4.S Emissions Testing 19
.t.l General
.•.2 Waste Spiking Procedures
s.o Test Results 22
5.1 Peed Material 22
5.1.1 Material Properties
5.1.2 Peed Preparation
5.1.3 Peed Rate
5.2 Processed Material (Ash) Data 23
5.2.1 Laboratory Data
5.2.2 Mass and Volume Reduction
Table 5.1 Component Analysis for Brio Ash
Table 5.2 Incinerator Ash Cyanide/Sulfide/
Pluoride Concentrations
Table 5.3 weight and Volume Reduction of
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Peed Materials
5.3 Scrubber Inlet/Stack Gas Data 25
5.3.1 Partieulats Emissions
5.3.2 continuous Missions Monitoring
5.3.3 Priority Pollutant Emissions (OKI)
Table 5.4 Stack Oas Analyses
Table 5.5 POHC DUE Kasults
Table S.f Polyehlorinatad Dibento-p-dioxins and
Dibentofurans Summary Rasults
5.4 scrubber Effluent/Make-Op Water .64
Tabla 5.7 scrubber Water Carbon Tetrachlorida Rasults
Tabla S.t water Analysis
6.0 Pull Scala Systa* Siting and Economic Analysis 70
7.0 Conclusions and Racoaaandations 79
7.1 Incinarator Ash 79
7.2 Incinarator Paad Systaa 79
7.3 Destruction Efficiency so
7.4 Design Data and Economics 80
Appendix A
Appendix B
•
Appendix C
Appendix D
Appendix I
Appendix P
Eagle Picher Research Laboratory
Saaple Analysis Report
ARZ Environmental Report Mo. 475-01
Emissions Sampling Report
Galbraith Laboratories Inc. - Laboratory
Analysis Report - Ultimate Analysis of Pit Peed
Samples
Shireo Infrared Systems Laboratory
Proximate and Theraogravimetric Analysis Report
Shireo Infrared Systems
Portable Unit Operating Logs
Safety Procedures and Equipment
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EXECUTIVE SUMHARY
The Shirco Infrared System Pilot Unit, contracted by the
Brio task fore* vac in operation at the Brio refinery site
in Houston, Texas, between February 9 and February 14, 1987.
The objectives of these thermal treatment tests on excavated
pit material were as follows:
1. To determine the incinerator ash chemical
composition.
2. To demonstrate that the incinerator feed system
can reliably provide a continuous, blended feed to
the incinerator and deposit this feed material in
a uniform manner on the incinerator belt.
3. To demonstrate that the incinerator can meet the
RCRA required 99.99% destruction efficiency for
POHCS.
4. To provide design information and economic data
required to evaluate the feasibility of
incinerating certain Brio Site pit wastes.
The actual series of test burns was performed from February
10 through February 13, 1987. Shirco Infrared Systems
personnel operated the furnace and prepared the test matrix.
The scrubber inlet and stack gas sampling and particulate
emission analyses were performed by ARI Environmental, Inc.
The analytical work on the solid waste feed, ash, scrubber
liquid, and exhaust gas samples was performed by Eagle-
Picher, a certified EPA, CLP laboratory.
The portable pilot unit arrived, was set up, and was brought
up to processing temperature on February 9, 1987. The feed
material was screened before introduction to the feed hopper
using a 1/2" mesh screen. Testing was initiated on February
10, 1987. Three additional tests were performed on February
11 and two on each of the following two days to complete the
test matrix on February 13, 1987.
For each test burn, the complete analysis on samples from
each test run included an analysis of:
feed
ash
scrubber make-up water (before test run)
scrubber water (after test run)
scrubber inlet gas
scrubber exhaust gas (stack)
The complete results of all analytical work performed on the
feed and residual samples is presented in Appendices A and
B.
A detailed account of test conditions and results are
presented in the body of this report. Presented below is a
summary of the results related to each defined objective for
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this test program.
I. Incinerator ash chemical composition.
The ash was analyzed for Appendix XX compounds and
elements, as appropriate for the feed stock. Complete
analytical results are presented.
II. Demonstrate the incinerator feed system will be
functional.
Experience gained during the test period will be
valuable for use in the design of a proper feed
preparation and feed system. It was discovered that
the Pit J waste, excluding rocks, would break apart
easily and could be expected to be prepared for feeding
to the furnace by a commercial lump breaker. For
example, a sealed drag flight conveyor linked to a
SHIRCO sealed spreading/leveling conveyor including a
rubber belt and leveling auger could feed the material
to the furnace. The material from Pits B, I, and M was
much more clay-like and included some tarry chunks.
This material required a great deal of effort to
prepare through a 1/2" mesh screen. The clay had to be
pressed through the screen and the tarry chunks had to
be broken by impact and passed through the screen.
Subsequently, the material had to be hand worked to
prevent it from adhering and jamming at the feed
conveyor gate. Although the SHIRCO feed operators had
to continuously hand level and spread the material so
it would pass into the furnace under the conveyor gate,
the feed rates during the test were kept fairly steady.
The February test did not serve as a demonstration of
feed preparation equipment; but rather proved that
properly prepared feed from the Brio Site could be
treated by infrared incineration.
III. Demonstrate that the incinerator can meet RCRA levels
for ORE for POHCs.
The U.S. EPA has established a hierarchy of compounds
in descending order of difficulty of destruction. One
of the most difficult compounds to destroy is carbon
tetrachloride, CC14. The feed material was spiked with
CC14, and each potential effluent point for CC14 was
sampled and analyzed. In all cases, for all waste
feeds, DREs of 99.99% or greater were achieved.
IV. Provide design information and economic data required
to evaluate the feasibility of incineration.
The data obtained from the operation of the Shirco
Infrared Systems Portable Pilot Unit, including but not
limited to energy consumption, residence times,
temperature, and feed and ash analyses were used as
input data for the Energy Balance Computer Simulation.
The output of this program as well as an economic
operating model are presented in Section 6.0 of this
report.
The economic analysis concludes that using the
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currently available Shirco Infrared mobile systems,
estimated commercial incineration costs for the
materials tested range from $119 to $143 per ton. The
accuracy of this cost estimate is ±25 percent. Note
that this cost estimate does not include costs for feed
excavation, feed preparation, interest and taxes.
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1.0 IMTRQDOCTION
During the period from February 10 to 13, 1987,
demonstration teata were performed at the Brio Sit* in
Friendswood, Taxaa. Tha purpoaa of thaaa taata vaa to
determine tha ability of tha Shirco Infrarad Syatam
tachnology to affactivaly traat tha varioua organic
compound* containad in tha pita at tha aita. Tha taat
program conaiatad of four (4) daya of tharmal process-
ing, with collaction of air emission and raaidua
aamplaa. Tha remaining time vaa devoted to equipment
aet-up, decontamination, and demobilization.
Tha objectivea of thia taat program aa defined by both
SHIRCO and tha Brio Taak Force were:
l. To determine the incinerator aah chemical
conpoaition.
2. To demonstrate that the incinerator feed ayatem
can reliably provide a continuoua, blended feed to
the incinerator and depoait thia feed material in
a uniform manner on the incinerator belt.
3. To demonstrate that the incinerator can meet the
RCRA required 99.99% destruction efficiency for
POHCS.
4. To provide design information and economic data
required to evaluate the feaaibility of
incinerating certain Brio Site pit vaatea.
In order to satiafy these objectivea, a teat program
was designed that would enable the proceaaing of
material from four repreaentativa pit wastes at two
predetermined operating conditiona each. During these
operations, samples at all inlet and outlet streams
were acquired and were analyaed by ARI Environmental
and Eagle Picher . The samples were analyzed in a
laboratory for EPA Appendix IX priority pollutants,
metals, carbon tetrachloride, moiature, and several
other specific elements and compounds. Presented in
the following sections and appendices are a Portable
Unit System description, General Process description,
Site and Material description, Test Procedures, Results
and Conclusions, Sizing and Economic Analysis, and
Analysis Data.
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2.0 TEST EQUIPMENT
2.1 General
The Shirco Infrared Systems Portable Demonstration
Unit (Figure 2.1) is designed to demonstrate the
performance of the Shirco Infrared furnace in a
variety of thermal processing applications. The
system consists of a feed metering section,
electrically heated primary chamber, gas fired
secondary chamber, off-gas handling, data
acquisition and control equipment, and heating
element power centers. The entire system is
enclosed in a single 45 foot van-trailer.
2.2 Feed Material
The feed is manually introduced into a feed hopper
onto a flighted metering conveyor located at the
end of the furnace. The metering belt is
synchronized with the furnace belt to control the
material feed rate. The feed hopper is mounted
above the furnace belt. The metering belt is
shrouded and equipped with rubber skirts to
minimize leakage of air or exhaust gases. There
is an adjustable guillotine-type gate at the
discharge end of the metering section. This gate
assures that an amount of material no greater than.
that which can pass through a preset slot size can
enter the furnace. The slot size is adjusted by
the height of the gate above the conveyor belt.
The feed material behind the gate forms a seal
against leakage of air into the system and process
gases out of the system.
2.3 Primary Cha.mb.e.r
The basis for the primary chamber is a rectangular
"box* fabricated from carbon steel and lined with
layers of ceramic fiber blanket insulation. The
insulation is mounted on stainless steel studs,
and retained with ceramic fasteners. The material
is transported through the furnace on a woven wire
belt which is supported on high temperature alloy
rollers. The rollers are, in turn, supported by
external flange-mounted bearings. A mechanical
variable speed drive and tension rollers are used
to pull the belt through the furnace. The
material on the woven belt passes under the
transverse mounted silicon carbide heating
elements. The heating elements are electrically
powered and access to the elements is available
from either side of the furnace. The heating
elements are grouped into two (2) zones, each zone
containing six rods. Also, each zone is
controlled by a separate heating element power
center (HEPC). At four locations in the primary
chamber are mounted a transverse shaft on which L-
shaped fingers are welded. This assembly is
rotated by a chain and sprocket system connected
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to the belt support roller drive. The purpose of
these "cakebreakers" is to gently stir and break
vast* material particles to expose maximum surface
area. These cakebreakers enhance the speed at
which the process can be completed and the
completeness of the decontamination. Once the
material reaches the end of the belt, it drops off
the belt and is transported via an auger outside
the trailer to a sealed ash drum. The discharge
hopper contains a small sampling drawer for
collection of a grab sample of ash.
2.4 Secondary Chamber
The secondary chamber is similar in construction
to the primary chamber and also uses ceramic fiber
blanket insulation. A propane-fired burner is
used to ignite any combustible gases that are
present in the primary exhaust, and burn them at a
pre-determined temperature. Propane is supplied
from a bottle located outside the trailer. The
chamber is sized to provide the required
combustion residence time for the gases at a given
set point temperature, typically a two-second
residence time at 2000 to 2200°F. The burner is
mounted on the end plate, with the flame pattern
intercepting incoming primary chamber exhaust
gases at a 90° angle. A pilot and electronic
flame monitoring device are provided as safety
measures. Chamber operating temperature is
controlled by adjusting the manual gas valve and
air registers.
2.5 Combustion Air System
Combustion air for the primary and secondary
chamber is supplied by a single blower with manual
adjustments of air flow and distribution. The
manifold on the blower acts as a splitter in that
the air flow to each chamber can be adjusted
through butterfly valves.
In the primary chamber, air may be injected
through five banks of four jets each located along
the length of the chamber. The air is distributed
to the jets through a manifold system. Adjustment
of flow to a bank of jets is by five manually
operated blast gate valves.
In the secondary chamber, air can be injected
through the chamber sides directed at the
interface of the burner flame pattern and the
primary chamber exhaust gas flow into the
secondary chamber.
2.6 Off Gas Handling System
Exhaust gases from the secondary chamber pass
through a venturi scrubber section containing
water sprays followed by a spray separator tower.
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For gas quenching, scrubbing liquid flows into a
bowl at the inlet of the venturi. Up stream of
the venturi throat in the converging section,
•pray nozzles in j act scrubbing liquid into the gas
stream for the particulate removal process. The
diverging section of the venturi connects to a
short square duct which connects to the separator
tower. Scrubbing liquid is sprayed into the tower
through two spray nozzles. Below the separator
tower is located a scrubbing liquid recirculation
tank. Scrubbing liquid is pumped from this tank
to the inlet locations described. A sump tank
with a recirculation system is included in the
scrubbing system. The sump tank has a 30-gallon
reservoir with provisions for water make-up,
system blowdown, and water sample collection.
An induced draft blower is located at the
discharge side of the scrubber. The blower causes
the primary and secondary chambers to operate at a
slightly negative draft. The draft is regulated
by a cone-type damper in the venturi along with a
damper located between the primary and secondary
chamber. In addition, a butterfly damper is
located on the outlet side of the blower.
A removable exhaust stack is installed through the
trailer roof. The stack extends 10 feet above the
trailer roof, and is equipped with two (2)
standard sampling ports. Access to the sampling
ports is provided by scaffolding or a lift
platform installed alongside the trailer.
2.7 Control
The master control panel is located at the front
of the trailer. The panel consists of controllers
for the primary chamber temperature controls, and
hand-off-auto switches for mechanical pumps,
blowers and motors. Also, the panel displays a
row of alarm lights which indicate low furnace
temperature, high stack temperature, and low
scrubber pressure.
2.8 Data Acquisition System
The control panel also contains the following for
data recording: multipoint temperature recorder
(6 point) , digital thermocouple reading display
(12 points), furnace running time totalizer, and
primary chamber power consumption totalizer. Also
the following parameters can be monitored at
designated areas along the system:
Primary Chamber Draft
Primary Chamber Exhaust
Secondary Chamber Draft
Propane Pressure
Venturi Differential Pressure
Spray Tower Pressure
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Standard sampling ports are provided in the
primary and ••condary exhaust ducts for •mission
testing.
2.9 Heating Element Power Centers
Heating elements in the two primary chamber zones
are powered by two 125 KVA beating element power
centers to control the flow of electricity to the
heating elements. Primary power input required
for each power center is a 3 -phase, 60 Hz, 480
volt at 12 KVA.
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FIGURE 2.1
SHIRCO INFRARED INCINERATOR - PROCESS DIAGRAM
Wast* Feed
Secondary Conbuator
Offgaa
Outlet
Infrared Chamber
Heating Eleawnta
Conbuatlon
Air Preheatar
F.D. Air
Blower
Aah Dlacharge
Coabuation
Air Inlet
I.D. Fan
Scrubber Sy«t<
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3.0 SITE AND TEST MATERIAL DESCRIPTIQH
3.1 Site Description
The test program was performed at the Brio sit* in
Houston, Texas. The layout of the facility is shown in
Figure 3.1.
Th« pilot test was performed in the refinery area shown
in Figure 3.1. Th* portable pilot trailer was set up
inside a building with large doors on both ends. A
supervisor's office was in the south side of the same
building. The south side of the building also
contained a restroom and a break area. Electrical
power cane from directly outside the building through a
480 volt/3 phase breaker box. Scrubber water was
supplied from inside the building.
A Class C restricted area was set up in the building
which included the Portable Unit and a perimeter
approximately 15 feet away from the trailer. An
operator decontamination station was set up in that
area toward the north side. Material from the pits
contained in sealed 5 gallon buckets was stored in the
building to the north of the trailer. The feed
preparation area was about 100 feet to the west of the
Shirco portable pilot unit on a concrete slab with a
drain in the middle. This slab was designated by Brio
site personnel as a decontamination area.
3.2 Test Material
The feed for each test was excavated from the Brio on-
site pits using a backhoe. Materials from Pits J, I,
M, and B were obtained and placed in 55 gallon drums
for storage. Analysis of the feed material in terms of
properties and chemical composition is presented in
Section 5 of this report.
Prior to use as feed for the Shirco furnace, the
material was worked through a 1/2" hardwire cloth to
remove large clay chunks, sticks, and rocks. This
sized material was then used for spiking.
Spiking of the feed material was performed in order to
determine the Destruction Removal Efficiency of the
incineration process. The method employed to
accomplish spiking involved placing a preweighed amount
of feed, about 50 pounds, in a cement box and adding to
the feed a predetermined amount of carbon tetrachloride
CC1*), diluted with hexane. The feed was then quickly
hand mixed using a garden hoe, immediately shoveled
into plastic 5 gallon buckets, and sealed.
Carbon tetrachloride was chosen as the spiking agent
for two reasons.
The feed remained in a sealed bucket until the testing
was conducted. The bucket was placed by the feed
10
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hopper and the lid was removed to allow feeding of the
material. The lid was placed on top of the feed bucket
between feeding intervale to reduce emission* and
evaporation of carbon tetrachloride.
1. The U.S. EPA has established a hierarchy of
compounds based on the difficulty to destroy by
thermal treatment. Carbon tetrachloride is the
number 4 compound on the list indicating that CC14
is the fourth hardest compound for which to
achieve an acceptable Destruction Removal
Efficiency (ORE). It has a higher rating than any
other compound of interest in this project.
2. The vapor pressure of CC14 is low, 100mm Hg at
23°C. This means that the evaporation rate of the
spiking agent is also low. Upon injecting the
CC14 on the soil using a syringe, it was observed
to be readily absorbed into the soil. Manual
mixing was continued for several minutes to
improve the homogenity of the blend.
Due to the difficulty encountered in obtaining
uniform mixtures of liquids and clay like solids,
grab sampling to determine constituent
concentration and subsequent DRE can not
accurately be relied on. Therefore, the testing
procedure developed to calculate Destruction
Removal Efficiency was based on the total quantity
of material processed during each test.
11
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SHIRCO'TEST" BORN
LOCATION
FIGURE A.I
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4.0 TEST PROCEDURES
4.1 'Equipment Set-Up
The portable pilot test unit and Shirco personnel
arrived on site February 6, 1987. The equipment and
supplies stored in the trailer as well as spare parts
and supplies not immediately needed were stored outside
the supply room. All the safety supplies and clean
sample jars were stored inside the supply room.
Electrical power was hooked up on February 6, 1987.
The primary chamber heating elements, scrubber water
supply hose, control panel instruments, ash discharge
barrel, scrubber drain hose, the interior trailer
lights and the exhaust stack were all installed by
Shirco personnel on the same day. The set-up of the
trailer and boundaries was finished after arrival of
additional Shirco personnel on February 9, 1987. The
furnace was heated to processing temperatures and coded
that afternoon to verify all systems were operational.
4.2 System Heat Up
The primary chamber heat up was started the morning of
February 10, 1987. when the primary chamber reached
lOOOjjF, the secondary furnace was fired and brought to
2200°F using maximum propane flow to minimize heat up.
time. This heat up procedure was followed during all,
startups.
4.3 Material Feed
Test material was fed to the furnace at the beginning
of each run in a 25 pound increment to determine a feed
rate so that the proper amount of material could be
spiked for each test. The material was transferred
from a barrel in the decontamination area to five
gallon pails after screening. The scale was tared to
zero so that when the buckets were weighed, the weight
recorded would be the net weight of the feed. A lid
was quickly placed on the bucket to minimize any
evaporation of the carbon tetrachloride on spiked feed
samples.
4.4 Operational History
The average feed rate for each pit was established by
feeding a bucket of material from that pit. The time
required to feed this material allowed a throughput to
be calculated for a 90 minute test at a nominal stack
sampling rate of 35 DSCFM. When the amount of feed
needed for the test was determined, the material was
spiked in three equal weights for the test. The
beginning of each run was started by feeding unspiked
material until the system was stabilized. The start up
of the actual test began when the feed of spiked
material began. The test ended when the last of the
spiked feed was discharged off of the main belt in the
furnace. The test times as reported by Shirco
operators are recorded in Table 4.7-1.
13
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Thermogravimetric Analyzer (TGA) tests performed (in
the SHIRCO laboratory) on representative samples prior
to the Portable Unit testing found that residence times
of 12 and 18 minutes would bound that needed for
processing the Brio Site materials. The 12 minute
residence time would be expected to remove the moisture
and volatiles. The 18 minute residence time would be
expectd to remove all moisture and volatiles and allow
a portion of the pyrolized carbon to be burned off.
This latter condition would assure the removal of
organic pollutants. Following field tests it was found
that all volatile and semi-volatile organics equally
destroyed at both residence time conditions. Also, a
review of the Appendix C ultimate analysis shows a
minimal difference between carbon contents of the ash
from the same pit at the two residence items. However,
there is a trend toward.an increased percentage of
carbon on the 18 minute residence time samples over
those processed for 12 minutes.
The first day of processing was February 10, 1987.
Heatup of the unit began at 0730. The primary chamber
was brought to 160Q°F and the secondary chamber was
brought up to 2200°F. One 37.5 pound bucket of Pit J
material was fed to the furnace between 1150 and 1215.
This procedure was used to allow the process to achieve
equilibrium. The first test on Pit J material began at
approximately 1535 with the start of emissions sampling
and spiked feed. Feed residence time in the primary
chamber was set at 12 minutes. Feeding of all the CC14
spiked material was completed by 1712. In order to
assure completion of processing of all CC14, feed of
non- spiked material was started at 1715 and the
sampling was concluded at 1725.
The second day of testing began by thoroughly cleaning
the scrubber recycle tank. This cleaning was to assure
that settled solids from the previous day would not
affect the next test. System heat up began at 0630
with residence time in the primary chamber set to 18
minutes. The feed rate of Pit J material during this
test was based on data from the previous day, and
determined to be 60 Ibs/hr. The test began at
approximately 1005 and ended at about 1155.
Pit I feed material was prepared during the second Pit
J test. A 25 pound bucket of Pit I material was fed
into the unit between 1220 and 1250 to determine the
feed rate that might be expected during the emissions
test and what quantity would need to be spiked. A
primary residence time of 18 minutes was used. It was
determined from this feed rate that 63 Ibs of material
would be required for a 90 minute test. Consequently
63 Ibs of material was spiked with 30 ml of carbon
tetrachloride for the first test on Pit I material.
14
-------
A second test was than run on Pit I aaterial. This
tast utilizad tha 12 ainute rasidanca tiae. Tha bad
dapth was changad froa 1 3/8" for tha 18 ainuta
rasidanca tiaa to 1 1/8" for tha 12 ainuta rasidanca
tiaa in ordar to maintain tha noainal 2.2 sacond
rasidanca tiaa in tha secondary chaabar. This sacond
tast on Pit I aatarial began at approximately 1846 and
ended at 2000.
On February 12, 1987, the start-up of the furnace bagan
at 0700. A 25 pound bucket of Pit M aatarial was fad
into the unit between 0840 and 0910 to define the tast
feed rate. It was determined froa the stack flow rate
that a 90 ainute sample catch would accumulate the
nominal 35 DSCF of sample specified for the Modified
Method 5 test. Thus using the feed rate of 50 Ib/hr, a
total of 75 Ibs of Pit M material was spiked with 30
ailliliters of CC14... The first sampling test of the
incinerator streams while processing the Pit M waste
began at 1053 and ended at 1250. A primary chamber
residence time of 12 minutes was used.
At the conclusion, the residence time was changed to 18
minutes for the second test on Pit M material. A
preliminary feed rate check was aade using non-spiked
Pit M waste. This feed rate was calculated at 41
Ib/hr. For consistency, it was decided to spike 70 •-
Ibs. with 30 ml of CC14. There was some difficulty
encountered during this last test with clogging in the
feed chute which lowered the feed rate to 33 Ib/hr.
Consequently, the feed of the entire 75 Ib of spiked
feed and concurrent sampling ran froa 1504 hrs to 1806
hrs.
Tha last day of testing, February 13, 1987, began with
the start-up at 0645. On this day, the Pit B waste
aaterial was processed. Between 0835 hrs and 0935 hrs
the non-spiked test bucket was fed to determine the
waste feed rate at the 18 ainute residence time. The
rate was 32 Ib/hr. Based on the stack flow rate, a
sampling period of two hours was estimated to catch the
needed 35 DSCF of stack gas. Consequently, three 20 Ib
buckets of Pit B feed were prepared, each spiked with
10 al of CC14. The streaa sampling of this 18 ainute
primary chamber residence time process began at 1022
and ended at 1218.
The second test on the Pit B feed used a 12 ainute
residence time. The feed rates were checked as in the
other tests and found to be approxiaataly 41 Ib/hr. To
obtain a nominal 35 DSCF gas sample, again a 90 minute
sampling period was suggested. Consequently 60 Ib of
waste was spiked with 30 ml of CC14 . The sampling for
this last test started at 1345 hrs and ended at 1548
hrs.
15
-------
4.5 Scrubbing System
The wet gas scrubbing system described in Section 2.6
was adjusted to product a nominal pressure drop. The
system was operated so that tha stack temperature
measured approximately 170°F.
Tha scrubbar liquid was a racirculating vatar flow from
tha sump tank located below the scrubber tower. The
tank was filled at the beginning of each day and
drained at the end of each day into labeled drums. On
the morning of February 11, 1987, the scrubber tank was
thoroughly cleaned. The water fro* this cleanup was
channeled into the decon drain. During operation, the
operator regularly checked and filled the tank as
needed.
4.6 Operating Data Log
The Shirco operators .maintained an operations log.
Comments relative to changes, pertinent observations
and system interruptions were recorded as they
occurred.
4.7 Operating Conditions
4.7.1 Teat Condition Matrix
The conditions for the various tests are
outlined in Table 4.7.1.
4.7.2 primary Chgnber Temperature
For the tests of the Shirco system, at the
Brio site, the primary chamber Zone A and
Zone B were controlled at a setpoint
temperature of 1600°F. These temperatures
were maintained by adjusting the control for
each zone to that setpoint value.
In addition to the Table 4.7.1 operating
parameter summary, presented in Appendix D
are copies of the system operating logs.
From these two sources, it is seen that
throughout the test program, the primary
chamber temperature was controlled through
combustion air addition and auxiliary
electric power to between 1550°F and 1600UF
in Zone A and a nominal 1600°F in Zone B.
The primary chamber exhaust temperature was
maintained between 1600°F and 1700°F for the
Pit J and I materials. However, for the Pits
M and B materials, the primary chamber
exhaust and the Zone A temperatures were
decreased. This is the result of a higher
combustible content in the Pits J and I
compared to the lower BTU content of the Pit
M and B material. The scrubber stack
temperature was maintained a level between
175 and 181°F throughout the tests.
16
-------
Table 4.7.1
Process Conditions
CC1« Res. Feed
"F
2/10
2/11
2/11
2/11
2/12
2/12
2/13
2/13
Run
Time Pit
1537
to
1707 J
1002
to
1200 J
1416
to
1604 I
1845
to
1958 I
1050
to
1249 H
1502
to
1807 M
1021
to
1216 B
1343
to
1548 B
Test
No.
1
2
3
4
5
6
7
8
Spike
(•1)
30
30
30
30
30
30
30
30
Time
(mln.)
12
18
18
12
12
18
18
12
Rate
(Ib/hr)
71.9
58.2
50.2
67.3
43.2
33.0
41.7
42.3
Temp
Zone A
1596
1596
1601
1600
1510
1565
1540
1531
Temp
Zone B
1612
1613
1608
1586
1599
1612
1612
-1«12
Temp
sec
2159
2224
2204
2200
2235
2209
' 2195
2216
Primary
Exhaust
1727
1611
1601
1601
1189
1258
1234
1232
Powei
(KWHR
15.3
16.5
13.8
16.8
21.9
19.6
23.0
21.6
Knife
10.9 1 1/8
11.7 1 1/4
9.7 1 3/8
8.9 1 1/8
9.7 1 1/8
8.3 11/8
1 1/4
-------
4.7.3. Primary Cha.ffib.e.r Residence Tina
Two residence times were run on each of the
four samples for a total of eight tests.
These times are based on an effective belt
length of 66.5 inches. The residence time
was set by adjusting the variable speed drive
motor. The rotational speed of the end drum
was measured by a stopwatch. The motor was
then adjusted to produce the desired belt
speed.
4.7.4 secondary CPffifcUPtion Qia.mjfre.r,
Temperature
The secondary chamber was heated by a propane
burner with manual control. Maximum propane
flow was utilized during heat-up with a
manual valve upstream from the burner. The
fuel rate was .decreased as the SCC approached
operating temperature. The secondary chamber
was maintained between 2150°F and 2250°F
during all testing. Some adjustments were
required at the start of feed to hold the set
point. During the first test of Pit J
material with a 12 minute residence time, it
was difficult to hold a steady secondary
chamber temperature. The other tests
required minimal adjustments to hold steady.
temperatures .
4.7.5 primary and SCC C,Qmb,ustion Air
Combustion air for the secondary chamber was
regulated based upon the residual oxygen
concentration measured in the secondary
chamber exhaust stream. The portable unit
was designed to process a wide range of
materials. When processing a feed, the air
blower damper was adjusted to keep the
turbulence high in the secondary and maintain
a 7% oxygen content in the exhaust gases.
Air feed to the primary chamber was adjusted
to maintain maximum combustion.
4.7.6 Soil Feed Rate
The feed rate was altered by varying the
residence time and changing the bed depth by
varying the feed conveyor guillotine gate
opening. The feed belt and main belt are
driven by the same motor and are
synchronized. The feed rates and guillotine
gate openings for all the tests are given in
Table 4.7.1.
4.7.7 System Power Usage
Presented on Table 4.7.1 as a summary and as
data in the Appendix D operating logs are the
primary chamber electric power usage data an
the secondary chamber fuel usage data. Note
18
-------
that these data nay not be used as a direct
scale up for a full scale system, since the
small size of the portable unit has a much
greater heat-loss per pound of material
processed than does a full scale unit. Note
that the higher volatile Pits I and J
materials require less primary chamber power
than do the materials from Pits M and B which
have a lower BTU valve.
Also presented in Table 4.7.1 are the propane
fuel usage rates for the secondary chamber.
As is noted, the rates range from 8.3 to
11.76 Ib/hr or 0.179M BTU/hr to 0.252
MBTU/hr. Using the feed rates for each case,
the specific fuel consumption by the
secondary chamber burner was low at 2853
BTU/lb and 3270 BTU/lb for the 12 minute
residence time processing of the I and J pit
material. For the same residence time on
Pits M and B, the respective propane usage
rates were 4844 BTU/lb and 4843 BTU/lb. The
lower fuel usage for Pit I and J material
corresponded to a higher BTU content in the
feed. For the 18 minute residence time, the
Pit I and J runs experienced fuel usage rates
of 4168 BTU/lb and 4337 BTU/lb. The Pits M
and B 18 minute residence time cases had 5426
BTU/lb and 5329 BTU/lb fuel usage rates. As
is the case with the primary chamber power
usage, the secondary chamber fuel usage for
the Portable Unit will be greater due to the
larger surface area per pound of feed than
will be experienced by a full scale system.
4.8 Emissions Testing
4.8.1 General
During each of two primary chamber residence
time tests of each pit material, the scrubber
inlet and exhaust stack gases were sampled.
ARI conducted simultaneous sampling at the
secondary chamber exhaust/scrubber inlet duct
location and on the scrubber exhaust stack.
Sampling at the scrubber inlet duct was
conducted for particulates and POHCs using an
EPA Modified Method 5 sampling train. CO,
NOX , CO* and 0, were also continuously
monitored at this location during each
sampling run. Sampling on the scrubber
exhaust stack was conducted for particulates
and POHCs using a Modified Method 5 sampling
train, and for S02 and SO* following TACB
Method 29 ( Modified EPA Method 8). A
complete description of the sampling
procedure is presented in Appendix B.
19
-------
4.8.2 Spiking Procedures
Carbon tetrachlorida was added to the feed as
a trace compound to determine the destruction
removal efficiency (DRE) of the system. The
ORE results were based upon the total amount
of carbon tetrachloride that was added to the
feed rather than analyses of individual grab
samples. The reason for this approach is
that when adding a liquid chemical into a
material with a clay like content, as this
test material, a homogeneous mixture cannot
practically be obtained. The amount of CC14
to be added to the feed was based upon the
estimated laboratory detection limit of 10
nanograms and a determination that a nominal
45 DSCF would pass through the sampling train
for a sample catch. Based upon the nominal
flow rate but of the exhaust stack of 205CFM
£ 175°F, a minimum 90 minute sampling period
was required to capture the 45 DSCF. In
addition, a target DRE of 99.9999% was used
for the spiking weight calculations.
Presented below is a sample calculation of
the amount of CC14 needed as a spike for a
given operating condition.
Estimated gas sampling rate: 45 DSCF/ 90 min.
estimated stack gas flow rate: 205 ACFM @
175°F. If.the stack gas flow rate was 205
ACFM § 175°F, the saturated gas would contain
29.465 ft3 of saturated gas per Ib of dry
gas . Consequently
Dry aaa-205ft^/min -6.961b drv eras
29.465 ft3/lb dry gas min
At standard conditions the stack dry gas flow
rate would be:
6.95 Ib drv eras 1 ft3-
DSCFM • min X 0.0749 Ib « 92.79 min
then over a 90 minute period the stack flow
would be :
DSCF - 92.79 It3 x 90 min - 8351 ft3/90 min
min
The sample volume to stack flow ratio is:
45 DSCF/8351 DSCF -0.005388
Now, considering that the minimum amount of
CC14 detectable on the trap carbon is 10 x
10"*gm, the minimum amount of CC14 that coulr'
flow out the stack would be:
20
-------
10 x lO^9- - 1.85 x 10"6g»
.005388
In order to prove as much as 99.9999% ORE the
feed must contain the fraction !/(!-.999999)
- 1 x 106 more CC14 than could exit the
stack. Then the minimum amount of CC14 that
must be spiked on the waste fed over a 90
minute would be:
1.85 x 10"6gm x 106 - 1.85gm
In order to provide a safety factor of 3 for
sampling methodology and a factor of 10 for
unknown analysis errors, the spike amount
was multiplied by a factor of 30. The
density of ,CC14 of 1.6 g/cc was used to
determine the volume of the spike required.
Then the total spike would be:
(1.85 gm x 30)/1.6 g/cc - 34.7 cc - 34.7 ml.
Recall that:
DRZ - CC1, in - CCl^ out X 100%
k> A •^AU^MM^^^
CC14 in
Thus in this case back calculating and
assuming the factor of safety is given up
DRE% - 1.85cm - 1.85 x I0"6om X 100% - 99.9999%
1.85ga
21
-------
5.0 TEST RESULTS
As more •pacifically enumerated in the summary, the
primary objectives of the test program were:
1) To confirm that the Shirco Infrared Systems
process could successfully reduce the constituents
present in samples from Pits J, I, M and B to
acceptable levels.
2) At the same time meet the required 99.99% ORE
levels for a spiked Principal Organic Hazardous
Constituent (carbon tetrachloride).
3) Establish that the solid material can be fed
through the Shirco equipment successfully.
4) Provide data for full scale design equipment.
The test procedures described in the previous
section produced direct results or data and
samples requiring post test laboratory and
engineering analysis. The resulting data and
analysis are presented in this section. Results
to be presented herein include:
A. Feed Material (Properties and Furnace Feed
Rates) - Section 5.1, Appendix A and Appendix
C.
B. Processed Material (Properties, Mass and
Volume Reduction) - Section 5.2, Appendix A,
Appendix B, Appendix C, Appendix D.
C. Scrubber Inlet Gas (Gas Sampling Analysis) -
Section 5.3, Appendix A, Appendix B.
D. Stack Gas (Gas Sampling Analysis) - Section
5.3, Appendix A, Appendix B
E. Scrubbing Liquid (Recycle and Make-up Water-
Analysis) - Section 5.4, Appendix A, Appendix
B.
F. Equipment Operation - Section 5.5
G. Process Operation - Section 5.6, Appendix E
5.1 Feed Material
5.1.1 Material Properties
The feed material for this test was analyzed
on both samples taken before the test from
the source pits and composite samples
acquired during the test period. The scope
of feed material analysis included:
22
-------
A. Pretest analysis of samples taken from
Pits J, I, M, Q, B. This analysis
included EPA Methods 8240 (Volatile
Organic*), 8270 (Seni Volatile
Organic*), GC Procedure 8080
(chlorinated pesticides/PCBs), Procedure
8140 (organic phosporous pesticides), GC
Procedure 8150 (phenoxy herbicides),
6010-7060-7471-7740-7841 (Priority
Pollutant Metals), 9030 (cyanide,
sulfide, flouride) and Karl Fischer for
Moisture. (Appendix A)
B. An analysis of composite samples taken
during each soil processing test
condition on soils from Pits J, I, M
and B. This analysis was performed by
the same methods with the addition of
analysis for carbon tetrachloride.
(Appendix A)
C. An ultimate analysis of composite
samples taken during the test period.
(Appendix C)
D. A pretest analysis in the SHIRCO
laboratory for density, pH, Heating
Value. This analysis also included a
Thermogravimetric Analysis (TGA),
examination of each sample to determine
the characteristic weight loss time
trend for materials from each pit.
(Appendix D)
The pretest laboratory analysis for priority
pollutants was a screening analysis to show
ranges of constituent concentrations. Since
the test procedures are performed in groups,
this analysis was used to determine which
laboratory procedures would be performed on
the composite feed, ash, and scrubber water
samples taken during the portable unit test.
The laboratory analysis of the composite feed
samples are presented in Appendix A. Those
data are presented in tabular form. The feed
composites from only one of the two Portable
Unit test conditions for each pit were
analyzed. Presented in Appendix A are.
analyses for samples from Pits I and J Run 1
and Pits M and B Run 2.
Presented in Appendix C are the ultimate
analysis data. As noted, a composite sample
from each pit was analyzed. Because of the
non-homogenity in the pits, the data can be
23
-------
assumed to vary somewhat. However, the
composite is expected to be representative of
the material processed in the Portable Unit.
Note that the ash content varies nominally
from 58 to 67% of the as received sample and
moisture varies from 14 to 27%. Relative to
the combustible portion of the feed, hydrogen
ranges from 2.67 to 3.87% and carbon ranges
from 1.75 to 20.6%. The pretest laboratory
analysis presented in Appendix D indicates
that Pit I has the highest heating value and
total weight lost during processing. Pit I
is expected to lose 55% of its weight
compared to 35% for Pits M and J. The
Appendix C and D data were used for the
process economic analysis.
Observations made by system operators and
feed preparation personnel are that overall
the consistency of the feed was a tacky soil
that had a portion of clay mixed in. Large
pieces of tar required mechanical breaking.
These tar chunks, however, shattered when
struck.
5.1.2 Re_e.d
_.
A pretest feed preparation study was not
performed. As a result, equipment available
for screening, delumping, and mixing was not
adequate for the task. It was found that in
order to produce a feed that had less than 1"
diameter particles, manual screening and
delumping was necessary. Although lime was
not needed for acid neutralization, a small
percentage would be useful to reduce the
tacky nature of the feed. A hardwire screen
was needed to breakup the lumps and remove
rocks larger than 1" O.D.
5.1.3 Feed Rate
The operating logs presented in Appendix E
include the feed weight history. From that
data, the average feed rates presented in
Table 4.7.1 were calculated.
As previously noted, the furnace feed
conveyor has a gate at its discharge end
which allows a set leveled height of feed to
enter the furnace. This gap is adjustable up
to 1 1/2". The gate gap was adjusted to
attempt to maintain a nominally equal feed
rate among the tests with the same residence
time. Pits J and I feeds produced near equal
feed rates and Pits M and B were similar.
The Pit M and B materials were more tacky and
clay- like than I and J.
24
-------
5.2 Processed Material fAahl Data
5.2.1 Laboratory Data
Appendix A presents the results of the
laboratory analysis of ash samples taken
during «ach test run. Those data arc
presented again in Table 5.1 and 5.2. These
tables indicate the destruction of all
potential problem compounds to levels below
the level of concern and often below the
minimum level of detection. Also included in
Appendix A are analysis data for Chlorinated
Pes tic ides/ PCBs, Organophosphorus pesticides,
Phenoxy herbicides, metals, Cyanide, Sulfide,
Flour ide, Dioxins, and Purans. There were
none of the chemical pollutants found. The
EP TOX test for leachable metals showed all
to be below the RCRA leachability limits.
Sulfides combined in the ash ranged from 170
ppm in Pit M to 9350 ppm in the Pit I ash.
5.2.2 Mass an.d. Volume Reduction
Table 5.3 presents the weights and volumes of
feed material fed during the test program.
From this data, weight and volume reduction
percentages were calculated. These two
percentages were defined as the percentage of
the initial value removed. The table shows
that a nominal range from 38 to 51% weight
reduction was accomplished for each test.
Pits I and J had weight reduction ranging
from 38 to 45% while both pits N and B
resulted in 51% reductions. The volume
reduction was similar. All 12 minute primary
chamber residence time cases were a nominal
55% volume reduction whereas the 18 minute
cases were lower, near 45%. This suggests
some increase in ash particle size with
extended thermal exposure. In summary, These
tests indicate that mass and volume may both
be cut in half by the SHIRCO thermal
processing.
5. 3 sgr^frfrar Inlet/Stack Gas Data
Presented in Appendix B is the scrubber inlet and
stack gas sampling data in terms of flows,
temperatures, particulate weights, and continuous
emissions monitoring (CEM) data. Appendix A
presents the laboratory analysis of the samples in
terms of priority pollutants, metals, HC1, and
Dioxins/Furans. Using the Appendix A and B data
of flows, carbon tetrachloride catches, and the
spike flow rates, the Destruction and Removal
Efficiency (DRE) for each test was calculated.
Presented in the following subsections are the
results of the emissions sampling.
25
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT B
RUN II - T«st No.
TABLE 5.1-B
COMPOUND
Acetone
Acetonltrile
Acetophenone
Xcrolein
FEED
mg/Kg
39
ND
NT)
ND
ASH
ag/KB
LT 0.01
KD
ND
ND
Aczylonltrlle
Aide in
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Beryllium
Bii-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chloroisopropylether)
Bromodichloroaethane
Bromoaethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,€-dinitrophenol
Carbon Disulfide
Carbon Tetrachloride
Chlordane
Chlorobenzene
Chlorod ibromoethane
l-Chloro-2,3-epoxypropane
Chloroform
p-Chloro-m-cresol
Chloromethyl-Mthyl ether
2-Chlorophenol
Chrysene
Cresols
ND
LT 0.12
ND
LT 20
32
LT 12
LT 0.50
LT 100
LT 20
LT 20
LT 20
LT 20
LT I
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
LT 0.50
4.0
LT 1.2
4.7
LT 0.50
ND
0.58
LT 20
ND
LT 20
LT 20
ND
LT 0.008
ND
LT 0.33
LT 0.33
25
LT 0.005
LT 0.15
LT 0.03
UT0.03
LT ,0.03
LT 0.33
LT 1
LT 0.33
LT 0.03
LT 0.33
LT 0.010
LT 0.010
LT 0.33
ND
LT 0.005
LT 0.005
LT Q.008
LT 0.005
LT 0.005
ND
LT 0.005
LT 0.33
ND
LT( 0.03
LT 0.33
ND ORTHCXO .33; P ARAO., 3 3
**LT • Less Than
26
-------
PIT B
RUN II
TABLE &1-B
PAGE 2
COMPOUND
Dlbenz(a,h)acridlnt
Dibenz(a,h)anthzacene
l,2-Dlbzomo-3-chloropropane
1,2-Dichlozobenzene
1,3-Dichlozobenzene
1,4-Dichlozobenzene
3,31-Dichlozobenzidine
Dichlozodifluozonethane
1,2-Dichloroethane
1,1-Dichloroethane
1,1-Dlchloroethylcne
FEED
•a/Kg
ND
LT 20
ND
LT 20
LT 20
LT20
LT AO
ND
106
0.65
0.50
ASH
ag/Kg
ND
LT 0.33
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.66
ND
LT 0.005
LT 0.005
LT 0.005
Dichloronethane
2,4-Dichlorophenol
1,2-Dichloropropane
Diethyl phthalate
7,l2-Dimethylbenz(a)anthracen«
2,4-Dimethylphenol
LT 0.50
LT20
ND
LT 20
ND
LT20
LT 0.01
LT 0.33
LT 0.005
LT 0.33
ND
LT 0.33
Dimethyl phthalate
Dimethyl terephthalate
4,6-Dlnitzo-o-cresol
2,4-Dinitzophenol
2,4-Dinitzotoluene
Di-n-butyl phthalate
Di-n-octyl phthalate
1,4-Dloxane
Diphenylamine
1,2-Dlphenylhydrazlne
Ethyl benzene
Ethylene oxide
Fluocanthene
Fluorene
LT 20
ND
LT 100
LT 100
LT 20
LT 20
LT 20
ND
ND
ND
14
ND
LT 20
LT 20
LT 0.33
ND
LT 1.6
LT 1.6
LT 0.33
LT 0.33
LT 0.33
ND
ND
ND
LT 0.005
ND
LT 0.33
LT 0.33
Heptachloz
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadlene
Hexachloroethane
LT 0.12
LT 20
LT 20
LT 20
LT 20
LT 0.008
LT 0.33
LT 0.33
LT 0.33
LT 0.33
Tt,-..
27
-------
PIT B
RUN II - Test No. 7
TABLE Sl-B
PAGE 3
COMPOUND
Hydrazlne
Ideno(l,2,3,cd)-pyrene
Isobutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
Methyl Isobutyl ketone
Methyl nethacrylate
Naphthalene
Nitrobenzene
Nitrosodinethylamine
Nitrosodiphenylamine
PCS's (all common aroclors)
Pentachlorobenzene
Pentachloronitco-benzene
Pentachlorophanol
Phenanthrene
Phenol
FEED
mg/Kg
ASH
mg/Kg
ND
LT 20
ND
LT 20
LT 1.0
ND
LT 1.0
ND
ND
LT 20
LT 20
LT 20
LT 100
ND
ND
LT 100
51
LT 20
ND
LT 0.33
ND
LT 0.33
LT 0.005
ND
LT 0.010
ND
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.33
LT 0.12
ND'
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorinated biphenyls
Pronamide
Pyrene
Pyridine
LT 1.6
LT 1.2
ND
LT 20
ND
LT 1.6
LT 0.08
ND
LT 0,33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachloroaethane
2,3,4,6-Tetrachlorophenol
r
Thallic oxide
Thallium acetate
Thallium carbonate
Thallium chltride
Thallium nitrate
Thallium selenite
Thallium sulfate
10
ND
7.7
2.9
4
ND
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
2
2
2
LT
LT
LT
LT 2
LT 2
LT 2
LT 2
Toluene
1.4
LT 0.005
-------
PIT •
RUN M
TABLE 5.1-1
PACT 4
COHPOOMD FEED ASH
l,2-trans-Dlchlozo«thylena 0.83 LTO.OOS
1,2,4-Trlchlorobanzena LT20 LTD. 33
1,1,1-Trichloroathane LTD.50 LT 0.005
1,1,2-Trlchloroethane 132 LTO.OOS
TzichloroathylaiM LT0.50 LTO.OOS
Trlchloro£luoro»cthana LT0.50 LTO.OOS
2,4,5-Trlchlorophtnol LT20 LT0.033
2,4,5-Trlchloroph«nol LT100 LTl.6
2,4,5-Trlchlorophenoxy acetic acid H> LT0.33
Vinyl chlotlda LT1.0 LT0.010
lylana LT0.50 LTO.OOS
**LT - Lcca Than
29
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT B
RUN 12 - Test No.
TABLE 8.1-B
COMPOUND
Acetone
Acetonitzile
Acetophenone
Acrolein
Acrylonltrile
Aldrin
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzldlne
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Beryl HUB
Bis-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chlorolsopropylether)
Bromodichloronethane
Bromomethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dlnltrophenol
Carbon Dlsulfide
Carbon Tetrachlorlde
Chlordane
Chlorobenzene
Chlorodlbromoethane
l-Chloro-2,3-epoxypropane
Chloroform
p-Chloro-m-cresol
Chloromethyl-methyl ether
2-Chlorophenol
Chrysene
Cresols
FEED
•g/Kft
39
ND
ND
ND
ND
LTD. 12
ND
LT20
32
LT 12
LT 0.50
LT 100
LT20
LT20
LT20
LT20
LT1
IT 20
LT 20
LT20
LT0.50
LT1.0
LT20
ND
LT0.50
4.0
LT1.2
4.7
LT0.50
ND
0.58
LT20
ND
LT20
LT20
ND
ASH
Bg/Kg
LT 0.010
ND
ND
ND
ND
LT 0.008
ND
LT0.33
LT0.33
LT 12
LT 0.005
LT1.6
LT0.33
LTD. 33
LT0.33
LT0.33
LT1
LT0.33
LTD. 33
LT0.33
LT 0.005
LTD. 010
LT0.33
ND
LTD. 005
LTD. 005
LT 0.008
LT 0.005
LTD. 005
ND
LTD. 005
LTD. 33
ND
LTD. 33
LTD. 33
ORTHO<0 . 33 ;PARA<0 . 3
**LT • Less Than
30
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT B
RUN if 2
TABLE 5.1-B
Page 2
COMPOUND
2,4-D
Dibenz(a,h)acrldlne
Dibenz( a, h) anthracene
1, 2-Dlbromo-3-chloropropane
1,2-Dichlorobenzene
1,3-Dlchlorobenzene
1, 4-Dlchlor obenzene
3,3'-Dichlorobenzldlne
Dichlorodifluoromethane
1,2-Dichloroethane
1,1-Dichloroethane
1, 1-Dichloroethylene
Dichloromethane
2,4-Dichlorophenol
1,2-Dichloropropane
Dlethyl phthalate
7,12-Dlmethylbenz(a)anthracene
2,4-Dlmethylohenol
Dimethyl phthalate
Dimethyl terephthalate
4,6-Dinltro-o-cresol
2,4-Dinitrophenol
2,4-Dlnitrotoluene
Di-n-butyl phthalate
Di-n-octyl phthalate
1,4-Dioxane
Diphenylamine
1,2-Dlphenylhydrazlne
Ethyl benzene
Ethylene oxide
Pluoranthene
Fluorene
FEED
ing /Kg
ND
LT 20
ND
LT 20
LT20
LT20
LT40
ND
106
0.65
0.50
LT0.50
LT20
ND
LT20
ND
LT20
LT20
ND
LT100
LT100
LT20
LT20
LT20
ND
ND
ND
14
ND
•
LT20
LT20
ASK
ng/Kg
ND
LT 0.03
ND
LT0.33
LT 0.33
LTD. 33
• LT0.06
ND
LT 0.005
LTD. 005
LT 0.005
0.007
LTD. 33
LT0.01
LTD. 33
ND
LTD. 33
LTD. 33
ND
LT1.6
LT1.6
LT 0 .0 3
LT0.33
LTD. 33
ND
ND
ND
LT 0.005
ND
LT0.33
LTD. 33
Heptachlor
Hexachlorobenzene
Hexachlorobutadlene
Hexachlorocyclopentadlene
Hcxachloroethane
LT0.12
LT20
LT20
LT20
LT20
LT 0.008
LTO.Q3
LTD.33
LT0.33
LT0.33
**LT • Less Than
31
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT B
RUN 12
TABLE 5.1-B
Page 3
COMPOUND
Hydrazlne
Ideno(l,2,3,cd)-pyrene
Isobutanol
Isophotonc
Methyl chloride
Methyl chryiene
Methyl ethyl ketone
Methyl isobutyl ketone
Methyl methacrylate
Naphthalene
Nitrobenzene
Nitrosodimethylamlne
Nitrosodiphenylanine
Pentachlorobenzene
Pentachloronitro-Benzene
Pentachlorophanol
Phenanthrene
Phenol
FEED
mg/Kg
ND
LT 20
ND
LT 20
LT 1.0
ND
LT 1.0
ND
ND
LT 20
LT 20
LT 20
100
ND
ND
LT 100
51
LT 20
ASH
ag/Kg
ND
LT 0.33
ND
LT 0.33
LT 0.005
ND
LT 0.010
ND
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.33
ND
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorinated biphenyls
Pronamlde
Pyrene
Pyridine
LT 1.6
LT 1.2
ND
LT 20
LT ND
LT 1.6
LT 0.008
ND
LT 0.33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
TetrachloroMthane
2,3,4,6-Tetrachloroohenol
10
ND
7.7
2.9
4.0
ND
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
Thallic oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thilllum nitrate
Thallium selenlte
Thallium sulfatc
Toluene
LT 2
LT 2
LT 2
LT
LT
LT
LT
1.4
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 0.005
**LT - Less Than
32
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT B
tarn n
TABLB ».1-B
?••• 4
COMPOUHD FEED ASH
»t/Ki
**LT • Lees Than
33
1,2-trans-Dlchloroethylene 0.85 LT 0.005
1, 2, 4-Tt ichlorobenzene LT 20 LTo.33
1,1,1-Trichloroethane LTo.50 LT 0.005
1,1,2-Trlchloroethane 132 LT 0.005
Trlchloroethylene LTo.50 LT 0.005
TrichlorofluoroMthane LTo.50 LTo.005
2,4,6-Ttlchlorophenol LT 20 LT 0.033
2,4,5-Trichlotophenol LT 100 LT 1.6
2,4,5-Trlchlorophenoxy acetic acid HD LT 0.33
Vinyl chloride LT l.o LTo.010
Xylene LTQ.50 LTQ.005
-------
COMPONENT ANALYSIS FOR BRin ASH
PIT I
RUN II - Te«t No.
TABLE 5.1-1
COMPOUND
Acetone
Acetonitrlle
Acetophenone
Acroleln
Acrylonitrile
Aldtin
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluorantheno
Benzo(k)fluoranthene
Beryllium
Bis-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chlorolsopropylether)
Bromodichloromethane
Brononethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Dlsulfide
Carbon Tetrachloride
Chlordane
Chlorobenzene
Chlorodibronoethane
l-Chloro-2,3-Epoxyprop*ne
Chloroform
p-Chloro-m-cresol
Chloromethyl-methyl ether
2-Chlorophenol
Chrysene
Cresols
FEED
SB/Kg
LT 1.0
ND
ND
ND
ND
LT 0.12
ND
LT 20
LT 20
LT 12
LT 0.50
LT 100
LT 20
LT 20
LT 20
LT 20
LT 1.0
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
2.5
34
LT 1.2
LT 0.50
LT 0.50
ND
LT0.50
LT 20
ND
LT 20 \
LT20
ND ORTHO<0
ASH
mg/KR
0.18
ND
ND
ND
ND
LT 0,,008
ND
LT 0.33
LT 0.33
LT 12
LT 0.005
LT 0.15
LT 0.03
LT 0,03
LT 0.33.
LT 0.03 .
LT 1.0
LT 0.33
LT 0.03
LT 0.33
LT 0.005
LT 0.010
LT 0.33
ND
LT 0.005
LT 0.005
LT 0.008
LT 0.005
LT 0.005
ND
LT 0.005
LT 0.33
ND
LT 0.03
LT 0.33
.33 PARA<0.33
**LT - Less Than
34
-------
PIT I
RUN II
TABLE S.I-I
PAGE 2
COMPOUND
FEED
Dlbenz(a,h)acrldine
Dibenz(a,h)anthracene
l,2-Dlbroao-3-chloropropane
1,2-Dlchlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,31-Dlchlorobenzidine
Dichlorodifluoronethane
1,2-Oichloroethane
1,1-Dlchloroethane
1,1-Dlchloroethylene
ASH
ffig/Kg
ND
LT 20
ND
LT 20
LT 20
LT 20
LT 40
ND
8.3
LT 0.50
LT 0.50
ND
LT 0.33
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.66
ND
LT 0.005
LT 0.005
LT 0.005
Dich lor one thane
2,4-Dichlorophenol
1,2-Dichloropropane
Diethyl phthalate
7,12-Dlmethylbenz(a)anthracent
2,4-Dimethylphenol
LT 0.50
LT 20
ND
LT 20
ND
LT 20
0.074
LT 0.33
LT 0.005
LT 0.33
ND
LT 0.33
Dimethyl phthalate
Dimethyl terephthalate
4,6-Dinltro-o-cresol
2,4-Dinltrophenol
2,4-Dlnitrotoluene
Di-n-butyl phthalate
Di-n-octyl phthalate
1,4-Dloxane
Diphenylamine
1,2-Diphenylhydrazine
Ethyl benzene
Bthylene oxide
Fluozanthene
Fluorene
ND
ND
LT 100
LT 100
LT 20
LT 20
LT 20
ND
ND
ND
10
ND
LT 20
.LT 20
LT 0.33
ND
LT 1.6
LT 1.6
LT 0.33
LT 0.33
LT 0.33
ND
ND
ND
LT 0.005
ND
LT 0.33
LT 0.33
Heptachlor
Hexachlotobenzene
Hexachlorobutadlene
Hexachlorocyclopentadiene
Hexachloroethane
LT 0.12
LT 20
LT 20
LT 20
LT 20
LT 0.008
LT 0.33
LT 0.33
LT 0.33
LT 0.33
**LT - Less Than
35
-------
PIT T
RUN »l
TABLE 5.1-1
PAGE 3
COMPOUND
Hydrazlne
Ideno(l,2,3,cd)-pyrene
Isobutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
FEED
eg/Kg
NO
LT 20
NO
LT 20
LT 1.0
ND
LT 1.0
ASH
mg/Kg
ND
LT 0.33
ND
0.34
LT 0.010
ND
LT 0.010
Methyl methacrylate
Naphthalene
Nitrobenzene
\
Mitrosodimethylamine
Nitrosodiphenylamine
PCR's (all common aroclors)
Pentachlorobenzene
Pentachloronitro-benzene
Pentachlorophanol
Phenanthrene
Phenol
ND
LT 20
LT 20
ND
31
ND
ND
LT 100
267
LT 20
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.33
LT 0.12
ND
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorinated biphenyls
Pronamide
Pyrene
Pyridine
LT 1.6
LT 1.2
ND
LT 20
ND
LT 1.6
LT 0.08
ND
LT 0.33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
TetrachloroMthane
2,3,4,6-Tetrachlorophenol
LT 0.50
ND
LT 0.50
LT 0.50
34
ND
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
Thallic oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thallium nitrate
Thallium selenite
Thallium sulfate
Toluene
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT
LT
LT
LT
LT
LT
LT
1.5
LT 0.005
**LT • Less Than
36
-------
PIT I
RUN #1
TABLE 5.1-1
PACE 4
COMPOUND FEED
ag/Kg rag/Kg
Toluene-2,6-diamine 2,4,5-TP
1,2-trans-Dichloroethylene LT 0.50 LT 0.005
1,2,4-Trichlorobenzene LT 20 LT 0.33
1,1,1-Trichloroethane LT 0.50 LT 0.005
1,1,2-Trichloroethane 12 LT 0.005
Ttlchloroethylene LT o.SO LT 0.005
Trichlorofluoronethane LT 0.50 LT 0.14
2,4,6-Trichlorophenol LT 20 LT 0.033
2,4,5-Trichlorophenol LT 100 LT 1.6
2,4,5-Trichlorophenoxy acetic acid ND LT 0.33
Vinyl chloride LT i.o LT 0.010
Xylene LT o.SO LT 0.005
**LT • Lesa'Than
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT I
RUN 12 - Test No. 4
TABLE 5.1-1
COMPOUND
Acetone
Acetonitrlle
Acetophenone
Acrolein
FEED
ag/Kg
LT 1.0
HD
ND
MD
ASH
tag/Kg
0.37
ND
ND
ND
Acrylonltiile
Aldrln
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzidine
BenzolaJanthracene
Benzo(a)pyzene
Benzo(b)fluoranthent
Benzolk)fluoranthene
Beryllium
Bls-2-ethylhexylphthalate
Bis(2-chloroethyl}ether
Bis(2-chlorolsopropylether)
Bromodichloromethane
Bxoaomethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Dlsulflde
Carbon Tetrachlorlde
Chlordane
Chlorobtnzene
Chlorodibromoethane
l-Chloro-2,3-epoxypropane
Chloroform
p-Chloro-a-cresol
ChlOtonethyl-methyl ether
2-Chlorophenol
Chrysene
Cresols
ND
LT 0.12
MD
LT 20
LT 20
LT 12
LT 0.50
LT 100
LT 20
LT 20
LT 20
LT 20
LT 1.0
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
2.5
34
LT 1.2
LT 0.50
LT 0.50
ND
LT 0.50
LT 20
ND
LT 20
LT 20
ND
ND
LT 0.008
ND
LT 0.33
LT 0.33
LT 12
LT 0.057
LT 1.6
LT 0.33
LT 0.33
LT 0.33
LT 0.33
LT 1.0
LT 0.33
LT 0.33
LT 0.33
LT 0.005
LT 0.010
LT 0.33
ND
LT 0.005
LT 0.005
LT 0.008
LT 0.005
LT 0.005
ND
LT 0.005
LT 0.33
ND
LT 0.33
LT 0.33
ORTHO<0.33J
PAFJK0.33
**LT • Less Than
38
-------
PIT I
RUN ill
TABLE 5.1-1
PAGE 2
COMPOUND FEED ASH
tng/Kg ing/Kg
Dlbenz(a,h)acridine ND
Dibenz(a,h)anthracene LT 20 LT 0.33
l,2-Dibromo-3-chloropropane ND LT 0^03
1,2-Dichlorobenzene LT 20 LT 0.33
1,3-Dichlorobenzene LT 20 LT 0.33
1,4-Dichlorobenzene LT 20 LT 0.33
3,31-Dichlorobenzidine LT 40 LT o.<06
Dichlorodifluoromethane ND ND
1,2-Dichloroethane 8.3 LT 0.005
1,1-Dichloroethane LT 0.50 LT 0.005
1,1-Dichloroethylene LT 0.50 LT 0.005
Dichloromethane LT o.50 ND
2,4-Dichlorophenol LT 20 LT 0.33
1,2-Dichloropropane ND LT 0.005
Diethyl phthalate LT 20 LT o.33
7,12-Diftethylbenz(a)anthracene ND ND
2,4-Dimethylphenol LT 20 LT o.33
Dimethyl phthalate ND LT o.33
Dimethyl terephthalate ND
4,6-Dinitro-o-cresol LT 100 LT 1.6
2,4-Dinltrophenol LT 100 LT 1.6
2,4-Dinitrotoluene LT 20 LT 0.03
Di-n-butyl phthalate LT 20 LT 0.33
Di-n-octyl phthalate LT 20 LT 0.33
1,4-Dioxane ND ND
Diphenylamine ND ND
1,2-Diphenylhydrazlne ND ND
Ethyl benzene 10 LT 0.005
Ethylene oxide ND ND
Fluoranthene LT 20 LT 0.33
Fluorene LT 20 LT 0.33
Heptachlor LT 0.12 LT 0.008
Hexachlorobenzene LT 20 LT0.03
Hexachlozobutadiene LT 20 LT 0.33
Hexachlorocyclopentadiene LT 20 LT 0-33
Hexachloroethane LT 20 LT 0.33
**LT - Less Than
39
-------
PIT I
RUN 12
TABLE 5.1-1
PAGE 3
COMPOUND ASH
»g/Kg mg/Kg
Hydrazine ND
Ideno(l,2,3,cd)-pyrene LT 20 LT 0.33
Isobutanol ND ND
Isophorone LT 20 2.5
Methyl chloride LT 1.0 LT 0.01
Methyl chrysene ND ND
Methyl ethyl ketone LT 1.0 LT 0.010
Methyl Isobutyl kctone ND ND
Methyl methacrylate ND ND
Naphthalene LT 20 LT 0.33
Nitrobenzene LT 20 LT 0.33
Nitrosodimethylamine ND LT 0.33
NltrosodlphenylaBine 31 LT 0.33
Pentachlbrobenzene ND ND
Pentachloronltro-benzene ND ND.
Pentachlorophanol LT 100 LT 1.6
Phenanthrene 267 LT 0.33
Phenol LT 20 ND
Phorate LT 1.6 LT 1.6
Polychlorlnated biphenyls LT 1.2 LT 0.08
Pronamide ND ND
Pyrene LT 20 LT 0.33
Pyrldlne ND LT 0.33
Styiene LT 0.50 LT 0.005
1,2,4,5-Tetrachlorobenzene ND ND
1,1,2,2-Tttrachloroethane LT 0.50 LT 0.016
Tetrachloroethylene LT 0.50 LT 0.005
Tetrachloromethane 34 LT 0.005
2,3,4,6-Tetrachlorophenol ND ND
Thailie oxide LT 2 LT 2
ThallluB acetate LT 2 LT 2
Thallium carbonate LT 2 LT 2
Thallium chloride LT 2 LT 2
Thallium nitrate LT 2 LT 2
Thallium selenlte LT 2 LT 2
Thallium sulfate LT 2 LT 2
Toluene 1.5 0.005
**LT » Less Than
40
-------
PIT I
RUM 12
TABL1 5.1-1
PAGI 4
COMPOUND FEED ASH
l,2-trana-Dlchlozo«thylen« LT 0.50 LT 0.005
1,2,4-Trichlorobtnzene LT 20 LT 0.33
1,1,1-Trlchloroethane LT 0.50 LT 0.005
1,1,2-Trlchlorot thane 12 LT 0.005
Trichloroethylene LT 0.50 NT)
TrichlorofluoroMthane LT 0.50 ND
2,4,8-Trichlorophenol LT 20 LT 0.033
2,4,5-Trichlozophenol LT 100 LT 1.6
2,4,5-Trlchlorophenoxy acetic acid RD LT 0.33
Vinyl chloride LT 1.0 LT 0.010
Xylene LT 0.50 LT 0.005
**LT • Less Than
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT J
RUN II - Test No.
TABLE 5,1-J
COMPOUND
Acetone
Acetonltrlle
Acetophenone
Acrolein
FEED
•g/Kg
120
ND*
ND*
ND*
ASH
ag/Kg
0.89
ND*
ND*
ND
Acrylonitrile
Aldrin
Allyl Alcohol
Aniline
Anthracene
Antlaony
Benzene
Benzldine
Benzo(*)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthenp
Benzo(k)fluoranthene
Beryllium
Bis-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chloroisopropylether)
Bromodlchloronethane
Bromoaethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Dlsulfide
Carbon Tetrachloride
Chlordane
Chlozobenzene
Chlorodlbronoethane
l-Chloro-2,3-epoxypropane
Chloroform
p-Chloro-»-cresol
Chloromethyl-methyl ether
2-Chlorophenol
Chrysene
Cresols
ND*
LT 0.12
ND*
LT 20
LT 20
LT 12
3.6
.LT 100
LT 20
LT 20
LT 20
LT 20
LT 1
LT20
LT20
LT20
LT 0.50
LT 1.0
LT 20
ND
5.7
128
LT 1.2
31
LT0.50
ND
43
LT 20
ND
LT20
LT20
ND*
LT 0.008
ND
LT 0.33
LT 0.33
LT 12
0.092
LT 1,
LTO.
LT 0,
LT 0.
.6
,33
,33
.33
LT 0.33
LT 1
LT 0.33
LT 0.33
LTO. 33
LT 0.005
LT 0.010
LT 0.33
ND
.005
.005
.008
.005
.005
LT 0,
LTO.
LT 0,
LT 0.
LT 0.
ND
LT 0.005
LTO.33
ND
LTO.33
LT 0.33
ND ORTHO^) .33; PARA<0.
*Detection limit not determined.
**LT - Lu-.. ...an
-------
PIT J
RUN II
TABLE 1.1- J
Page 2
COMPOUND
Dlbenz(a,n)acnaine
Dibenz(a,h)anthracene
l,2-Dibromo-3-chloropropane
1,2-Dichloxobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,31-Dlchlorobenzidine
Dichlorodifluoronethane
1,2-Dlchloroethane
1,1-Dichloroethane
1,1-Dlchloroethylene
FEED
an/Kg
ND
LT 20
ND*
LT 20
LT 20
LT 20
LT 40
ND
86
31
16
ASH
as/Kg
ND
LT 0.33
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.66
ND
LT 0.005
LT 0.005
LT 0.005
Dichloromethane
2,4-Dichlorophenol
1,2-Dichloropropane
Diethyl phthalate
7,l2-Dimethylbenz(a)anthracene
2,4-Dimethylphenol
LT 0.50
LT 20
ND*
LT 20
ND*
LT20
0.99
LT 0.33
LT 0.005
LT 0.33 '
ND* :
LT 0.33
Dimethyl phthalate
Dimethyl terephthalate
4,6-Dinltro-o-cresol
2,4-Dinitrophenol
2,4-Dlnitrotoluene
Di-n-butyl phthalate
Di-n-octyl phthalate
1,4-Dioxane
Diphenylamine
1,2-Diphenylhydrazine
Ethyl benzene
Ethylene oxide
Pluoranthene
Fluorene
ND*
ND
LT 100
LT 100
LT 20
LT 20
LT 20
ND*
ND*
ND*
160
ND*
LT 20
LT 20
LT 0.33
ND
LT 1.6
LT 1.6
LT 0.33
LT 0.33
LT 0.33
ND
ND*
ND*
LT 0.005
ND
LT 0.33
LT 0.33
Heptachlor
Hexachlorobenzene
Hexachlorobutadlene
Hexachlorocyclopcntadlene
Hexachloroethane
LT0.12
LT 20
LT 20
LT 20
LT 20
LT 0.008
LT 0.33
LT 0.33
LT 0.33
LT 0.33
*notort1on limit not.determined.
43
-------
PIT J
RUN II
TABLE 5.1-J
P«g« 3
COMPOUND
Hydra zlne
Ideno(l,2,3,cd)-pyrene
Isobutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
Methyl Isobutyl ketone
Methyl methacrylate
Naphthalene
Nitrobenzene
Nltrosodlmethylamlne
Nltrosodiphenylaaine
Pentachlorobenzene
Pentachloronitro-benzene
Pentachlorophanol
Phenanthrene
Phenol
as/Kg
ND
LT 20
ND*
LT 20
LT 1.0
ND
LT 1.0
ND
ND*
140
LT 20
ND
27
ND
ND
LT 100
416
LT 20
ng/Kg
ND
LT 0.33
ND
LT 0.33
LT 0.010
ND
LT 0,010
ND
ND*
LT 0.33
LT 0.33
LT 0.33
LT 0.33
ND
ND
LT 1.6 '
LT 0.33 •
ND
Phorate
Polychlorinated biphenyls
Pronamlde
Pyrene
Pyrldlne
LT 1.6
LT 1.2
ND
LT 20 v
ND*
LT 1.6
LT 0.08
ND
LT 0.33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachl or ome thane
2,3,4,6-Tetrachlorophenol
140
ND*
39
28
128
ND*
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
KD
Thai lie oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thallium nitrate
Thallium selenlte
Thallium sulfate
Toluene
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
17
LT2
LT2
LT2
LT2
LT2
LT2
LT2
LT 0.00!
•Detection limit not determined.
T m 1 r>e
-------
PIT J
RUN II
TABLE 5.1- J
Page 4
COMPOUND FEED ASH
mg/Kg
l,2-trans-Dichloro«thylene LT 0.50 LT O.OOS
1,2,4-Trichlorobenzene . LT 20 LT 0.33
1,1,1-Trlchloroetnane 1.5 LT 0.034
1,1,2-Trichloroethane LT 0.50 LT 0.005
Trichlorocthylene ; 33 LT 0.046
Trichlozofluoroaethane LT 0.50 LT 0.005
2,4,6-Trlchlorophenol LT 20 LT 0.033
2,4,5-Trichlorophenol LT 100 LT 1.6
2,4,S-Trichlorophenoxy acetic acid ND*
Vinyl chloride 3.0 LT 0.010
Xylene LT 0.50 LT 0.005
**LT - Less Than
45
-------
PIT J
RUN 12 - Test No.
TABLE 5.1-J
COMPONENT ANALYSIS FOR BRIO ASH
COMPOUND
Acetone
Acetonltrlle
Acetophenone
Acrolein
FEED
mg/Kg
120
ND
ND
ND
ASH
mg/Kg
0.094
ND
ND
ND
Acrylonltrile
Aldrln
Allyl Alcohol
Aluminum Phosphide
Aniline
Anthracene
Antimony
Benzene
Benzldine
Benzo(a)anthracene
BenzoUJpyrene
Benzo(b)£luoranthene
Benzo(k)fluoranthene
Beryllium
Bls-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chlorolsopropylether)
Bromodichloroaethane
Bromooethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Dlsulfide
Carbon Tetrachloride
Chlordane
Chlorobenzene
Chlorodibromoethane
l-Chloro-2,3-epoxypropane
Chiorofora
p-Chloro-»-cresol
Chloroaethyl-nethyl ether
2-Chlorophenol
Chrysene
Cresols
ND
LT.0.12
ND
26.100
LT 20
LT.20
LT 12
3.6
LT 100
LT 20
LT 20
LT 20
LT 20
LT 1
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
5.7
128
LT 1.2
31
LT 0.50
ND
43
LT 20
ND
LT 20
LT 20
ND
LT 0.008
ND
LT 0.33
LT 0.33
LT 12
0.075
LT 0.15
LT 0.03
LT 0.03
LT 0.03
LT 0.33
LT 1 .-
LT 0.33
LT 0.03
LT 0.33
LT 0,005
LT 0.010
LT 0.33
ND
0.005
0.005
0.008
LT
LT
LT
LT 0.005
LT 0.005
ND
0.005
0.33
ND
LT 0.03
LT 0.33
LT
LT
ND ORTHO<0.33;PARA
-------
PIT J
RUM 12
TABLE 5J1-J
PACE 2
COMPOUND
Dlbenz(a,h)acridine
Dlbenz(a,h)anthxacene
1,2-Dlbro«o-3-chloropropane
1,2-Dlchlorobenzene
1,3-Dlchlorobenzene
1,4-Dichlorobenzene
3,31-Dichlorobenzldlne
Dlchlorodlfluotomethane
1,2-Dlchloroethane
1,1-Dlchloroethane
1,1-Dichlotoethylene
FEED
BS/K
ASH
ND
LT 20
ND
LT 20
LT 20
LT 20
LT 40
ND
86
31
16
ND
LT 0.33
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.66
ND
LT 0.005
LT 0.005
LT 0.005
Dlchloronethane
2,4-Dlchlorophenol
1,2-Dlchloropropane
Dlethyl phthalate
1,12-Dlaethylbenz(a)anthracene
2,4-Dl»ethylphenol
W 0.50
W 20
ND
LT 20
ND
LT 20
• 0.024
LT 0.33
LT 0.005
LT 0.33
KD
LT 0.33
Dimethyl phthalate
Dimethyl tecephthalate
4,6-Dlnitro-o-cresol
2,4-Dlnltrophenol
2,4-Dlnltrotoluene
Dl-n-butyl phthalate
Dl-n-octyl phthalate
1,4-Dtoxane
Dlphenylamlne
1,2-Dlphenylhydrazlne
Ethyl benzene
Ethylene oxide
Pluoranthene
Fluoxene
ND
ND
LT 100
LT 100
LT 20
LT 20
LT 20
ND
ND
ND
160
ND
LT 20
LT 20
LT 0.33
ND
LT 1.6
LT 1.6
LT 0.33
LT 0.33
LT 0.33
ND
ND
ND
LT 0.005
ND
LT 0.33
LT 0.33
Heptachloz
Hcxachlorobenzene
Hexachlorobutad iene
Hexachlorocyclopentadiene
Hexachloroethane
LT 0.12
LT 20
LT 20
LT 20
LT 20
LT 0.008
LT 0.33
LT 0.33
LT 0.33
LT 0.33
** LT • Less Than
-------
PIT J
RUN 12
TABLE 5.1-J
PACE 3
COMPOUND
PEED
Hydrazine
Ideno(l,2,3,cd)-pyrene
Isobutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
Methyl Isobutyl ketone
Methyl Mthacrylate
Naphthalene
Nitrobenzene
Nltrosodlmethylamine
Nltrosodiphenylamlne
PCS'* (all coonon aroclors)
Pentachlorobenzene
Pentachloronitro-benzene
Pentachlorophanol
Phenanthrene
Phenol
g/Ke
ND
LT 20
ND
LT 20
LT 1.0
ND
LT 1.0
ND
ND
140
LT 20
ND
27
ND
ND
LT 100
416
LT 20
ND
LT 0.33
ND
LT 0.2"*
LT 0.01
ND
LT 0.010
ND
ND
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.12
ND
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorlnated biphenyls
Pronaalde
Pyrene
Pyridine
LT 1.6
LT 1.2
ND
LT 20
ND
LT 1.6
LT 0.08
ND
LT 0.33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachloroaethane
2,3,4,6-Tetrachlorophenol
140
ND
39
28
128
ND
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
Thai lie oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thallium nitrate
Thallium selenite
Thallium sulfate
Toluene
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
17
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 0.005
** LT - Less Th.in
-------
PIT J
RUN 12
TA2LB Si J
PACE 4
COHPOUIfD FEED
1,2-trana-Dlchloroethyleot LT 0.50 LT 0.005
l,2,4-Trlchlorob«nzene LT 20 LT 0.33
l,l,l-Trlchloro«thane 1.5 LT 0.005
l,l,2-Trlchloro«thane LT 0.50 LT 0.005
TrlchlotMthylent 33 LT 0.005
TxichloroflttoroMthant LT 0.50 LT 0.008
2,4,6-Trlchlorophtnol LT 20 LT 0.033
2,4,5-Trlchlorophtnol LT 100 ' LT 1.6
2,4,5-Trichloropbtnoxy acetic acid MD LT 0.33
Vinyl chloride ' 3.0 LT 0.010
Xylene LT 0.50 LT 0.005
**LT • Leic Than
49
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT M
RUN II - Test No.
TABLE 6.1-M
COMPOUND
Acetone
Acetonitrile
Acetophenone
Acrolein
FEED
mg/Kg
LT 1.0
ND
HD
ND
ASH
mg/Kg
LT 0.010
ND
ND
ND
Acrylonltrile
Aldrin
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzidine
Benzo(a)anthzacene
Benzo(a)pyrene
Benzo(b)£luorantheno
Benzodcjfluoranthene
Beryllium
Bis-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chloroisopropylether)
Bromodlchloromethane
Bromomethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Disulfide
Carbon Tetrachloride
Chlordane
Chlorobenzene
Chlorodibromoethane
l-Chloro-2,3-epoxypropane
Chloroform
p-Chloro-m-cresol
Chioromethyl-methyl ether
2-Chlorophenol
Chrysene
Cresols
NT)
LT 0.12
ND
LT 20
LT 20
LT 12
LT 0.50
LT 100
LT 20
LT 20
LT 20
LT 20
LT 1
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
0.052
40
LT 1.2
1.8
LT 0.50
ND
1.5
LT 20
ND
LT 20
LT 20
ND
LT 0.008
ND
LT 0.33
LT 0.33
LT 12
LT 0.005
LT O.L5
LT 0.03
LT 0.03
LT 0.03
LT 0.33
LT 1 "
LT 0.33
LT 0.03
LT 0.33
LT 0.005
LT 0.010
LT 0.33
ND
LT 0.005
LT 0.005
LT 0.008
LT 0.005
LT 0.005
ND
LT 0.005
LT 0.33
ND
LT 0.03
LT 0.33
ND ORTBO<0.33;PARA<0.3
**LT • Less Than
50
-------
PIT M
RUN II
TABLE 5.1-M
FACE 2
COMPOUND
Dibenz(a,h)acrldlne
Dibenz(a,h)anthracene
l,2-Dibromo-3-chloropropane
1,2-Dichlorobenzene
1,3-Dichlorobenzene
I/4-Dichlorobenzene
3,31-Dlchlorobenzidlne
Dichlorodifluoroaethane
1,2-Dlchloroethane
1,1-Dichloroethane
1,1-Dichloroethylene
FEED
•g/Kg
ND
LT20
HD
LT20
LT20
LT20
LTAO
ND
32
0.92
1.6
ASH
mg/Kg
ND
LTD. 33
ND
LTD. 33
LT0.33
LT0.33
LT 0.66
ND
LT 0.005
LT 0.005
LT 0.005
Dichlorotnethane
2,4-Dichlorophenol
1,2-Dichloropropane
Diethyl phthalate
7/12-Dimethylbenz(a)anthracene
I, 4-Dloethylphenol
LT 0.50
LT20
HD
LT20
ND
LT20
LT 0.005
LT 0.33
LT 0.005
LT0.33
ND
LT 0.33
Dimethyl phthalate
Dimethyl tecephthalate
4,6-Dinitro-o-cresol
2,4-Dinltrophenol
2,4-Dlnitxotoluene
Di-n-butyl phthalate
Di-n-octyl phthalate
1,4-Dioxane
Diphenylamine
1,2-Diphenylhydrazine
Ethyl benzene
Ethylene oxide
Fluoranthene
Fluorene
LT20
ND
LT100
LT 100
LT20
LT20
LT20
ND
ND
ND
7.4
ND
LT 20
LT20
6
33
33
33
LT 0.33
ND
LT 1.6
LT 1
LT 0
LT 0
LTO
ND
ND
ND
LT 0.005
ND
LT 0.33
LT 0.33
Heptachlor
Hexachlorobenzene
Hexachlorobutadlene
Hexachlorocyclopentadiene
Hexachloroethane
LT 0.12
LT 20
LT 20
LT 20
LT 20
LT 0.008
LT 0.33
LT 0.33
LT 0.33
LT 0.33
** LT - Less Than
51
-------
PIT M
RUN 01
TABLE 5.1-M
PAGE 3
COMPOUND
FEED
mg/Kg
Hydrazine
Idenod, 2,3,cd)-pyrene
Isobutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
Methyl Isobutyl ketone
Methyl methacrylate
Naphthalene
Nitrobenzene
Nltrosodlmethylamine
Nltrosodiphenylanine
ASH
mg/Kg
PCB's (all common aroclors)
PentachloroDenzene '
Pentachloronitro-benzene
Pentachlorophanol
Phenanthrene
Phenol
NO
LT 20
ND
LT 20
LT 1.0
ND
LT 1.0
ND
ND
LT 20
LT 20
LT 20
LT 20
ND
LT 100
LT 20
LT 20
ND
LT 0.33
ND
LT 0.33
LT 0.010
ND
LT 0.010
ND
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.33
LT 0.12
ND
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorinated biphenyls
Pronamide
Pyrene
Pyridine
LT 1.2
LT 1.2
ND
LT 20
ND
LT 1.6
LT 0.080
ND
LT 0.33
LT 0.33
Styrene
1,2,4,5-Tetrachlorobenzene
1,1,1, 2-Tetrachloroethane
Tetrachloroethylene
Tetrachloromethane
2,3,4,6-Tetrachlorophenol
4.7
ND
2.3
2.3
40
ND
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
Thallic oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thallium nitrate
Thallium selenite
Thallium sulfate
Toluene
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
0.89
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT O.OOi
**LT - Less Than
52
-------
PIT M
RUM II
TABLE 6.1-M
PACI 4
COKPOUMO FEED ASH
**LT • Less Than GT • Greater Than
53
li 2-tranf-Dlchlorotthyltnt 2.6 LT 0.005
1,2,4-Trichlorobtnxtnt LT 20 LT 0.33
1,1,1-Tr Ichlorotthant LT 0.30 LT 0.005
1,1, 2-Tr ichlorotthant « I LT 0.005
Txichlorotthyltnt i.8 LT 0.005
TrichloroflooroMthant LT 0.50 LT 0.005
2,4,6-Trichlorophtnol LT 20 LT 0.033
2,4,5-Trichlorophtnol LT 100 LT 1.6
2,4,5-Trlchlorophtnoxy acttlc acid n> LT 0.33
Vinyl Chlorldt LT 1.0 LT 0.010
Xylent LT 0.50 LT 0.005
-------
COMPONENT ANALYSIS FOR BRIO ASH
PIT M
RUN 92 - Test No. 6
TABLE 5.1-M
COMPOUND
Acetone
Acetonltrile
Acetophenone
Acrolein
FEED
ing/Kg
LT l.o
ND
ND
ND
ASH
tng/Kg
LT 0.010
NT)
ND
ND
Acrylonitrile
Aldrin
Allyl Alcohol
Aniline
Anthracene
Antimony
Benzene
Benzidine
Benzo(a)anthracene
Benzo(a)pyxene
Benzo(b)fluorantheno
Benzolk)fluoranthene
Beryllium
Bls-2-ethylhexylphthalate
Bis(2-chloroethyl)ether
Bis(2-chlotoisopropylether)
Bromodichloromethane
Bromomethane
Butyl Benzyl Phthalate
2-sec-Butyl-4,6-dinitrophenol
Carbon Disulfide
Carbon Tetrachloride
Chlordane
Chlorobenzene
Chlorodibromoethane
l-Chloro-2,3- Epoxypropane
Chloroform
p-Chloro-m-cresol
ChloroMethyl-Methylether
2-Chlorophenol
Chrysene
Cresols
ND
LT 0.12
ND
LT 20
LT 20
LT 12
LT O.SO
LT 100
LT 20
LT 20
LT 20
LT 20
LT 1
LT 20
LT 20
LT 20
LT 0.50
LT 1.0
LT 20
ND
0.52
40
LT 1.2
1.8
LT 0.50
1.5
LT 20
LT 20
LT 20
ND
LT 0..008
ND
LT 0.33
LT 0.33
LT 12
LT 0.005
LT 1.6
LT 0.33
LT 0.33
LT 0.33
LT 0.33
LT 1
LT 0.33
LT 0.33
LT 0.33
LT 0.005
LT 0.010
LT 0.33
ND
LT 0.005
LT 0.005
LT 0.008
LT 0.005
LT 0.005
ND
LT 0.005
LT 0.33
ND
LT 0.33
LT 0.33
ND ORTHO<0.33;PA8A<0.33
**LT - Less Than
54
-------
PIT M
RUN «2
TABLE 5.1-M
PAGE "2
COMPOUND FEED ASH
__ me/Kg ag/Kg
Dibenzo(a,h)acridine ND
Dlbenz(a,h)anthracene LT 20 LT 0.33
l,2-Dibromo-3-chloropropane :• ND ND
1,2-Dlchlorobenzene LT 20 LT 0.33
1,3-Dlchlorobenzene LT 20 LT 0.33
1,4-Dichlorobenzene LT 20 LT 0.33
3,31-Dichlorobenzldlne LT 40 LT 0.66
Dichlorodifluoromethane ND ND
1,2-Dichloroethane 32 LT 0.005
1,1-Dlchloroethane 0.92 LT 0.005
1,1-Dichloroethylene 1.6 LT 0.005
Dlchloromethanc LT 0.50 LT 0.005
2,4-Dichlorophenol LT 20 LT 0.33
1,2-Dichloropropane ND LT 0.005
Diethyl phthaiate LT 20 LT 0.33
7,12-Dlmethylbenz(a)anthracene ND ND
2,4-Diaethylphenol LT 20 LT 0.33
Dimethyl phthaiate LT 20 LT 0.33
Dimethyl Terephthalate ND
4,6-Dlnltro-o-cresol LT 100 LT 1.6
2,4-Dinitrophenol LT 100 LT 1.6
2,4-Dinitrotoluene LT 20 LT 0.33
Dl-n-butyl phthaiate LT 20 LT 0.33
Dl-n-octyl phthaiate LT 20 LT 0.33
1/4-Dioxane ND ND
Dlphenylanine ND ND
1,2-Diphenylhydrazlne ND ND
Ethyl benzene 7.4 LT 0.005
Ethylene oxide ND ND
Fluoranthene LT 20 LT0.33
Pluorene LT 20 LT0.33
Heptachlor LT 0.12 LT 0.008
Hexachlorobenzene LT 20 LT0.33
Hexachlorobutadiene LT 20 LT0.33
Hexachlorocyclopentadicnc LT 20 LT0.33
Hexachloroethane LT 20 LTo.33
**LT • Less Than 55
-------
PIT M
RUN #2
TABLE 5.1-M
PAGE 3
COMPOUND
Hydrazine
Ideno(l,2,3,cd)-pyrene
Isouutanol
Isophorone
Methyl chloride
Methyl chrysene
Methyl ethyl ketone
Methyl Isobutyl keytone
Methyl methacrylate
Naphthalene
Nitrobenzene
Nltrosodlmethylamlne
Nitrosodlphenylamine
Pentachlorobenzene
Pentachloronitro-benzene
Pentachlorophanol
Phenanthrene
Phenol
FEED
mg/Kg
ASH
ag/Kg
ND
LT 20
ND
LT 20
LT 1.0
ND
LT 1.0
ND
ND
LT 20
LT 20
LT 20
LT 20
ND
ND
LT 100
LT 20
LT 20
ND
LT 0.33
ND
LT 0.33
LT 0.010
ND
LT 0.010
ND
ND
LT 0.33
LT 0.33
LT 0.33
LT 0.33
ND
ND
LT 1.6
LT 0.33
ND
Phorate
Polychlorinated biphenyls
Pronamide
Pyrene x
Pyrldine
LT 1.5
LT 1.2
ND
LT 20
ND
LT 1.6
LT 0.080
ND
LT 0.33
LT 0.33
Styrene
1,2,4/5-Tetrachlorobenzene
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Tetrachloroaethane
2,3,4,6-Tetrachloroohenol
4.7
ND
2.3
2.3
40
ND
LT 0.005
ND
LT 0.005
LT 0.005
LT 0.005
ND
Thailie oxide
Thallium acetate
Thallium carbonate
Thallium chloride
Thallium nitrate
Thallium selenlte
Thallium sulfate
Toluene
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT 2
LT
LT
LT
LT
0.89
LT 0.005
**LT -Less Than
56
-------
PIT M
RUN n
TABLE 5.1-M
PACI 4
COMPOUND
t/K M/Kt
1,2-trana-Dlchloroethylene 2.6 LT 0.005
1,2,4-TrIchlorobenzene LT 20 LT 0.33
1,1,1-Trlchloroethane LT 0.50 LT 0.005
1,1,2-TrIchloroethane or 1 LT 0.005
Trichloroethylene 1.8 LT 0.005
Trlchloro£luoroMthane LT 0.50 LT 0.005
2,4,6-Trlchlorophenol LT 20 LT 0.033
2,4,5-Trichlorophenol LT 100 LT 1.6
2.4.5-Trlchlorophenoxy acetic acid HD LT 0.33 _
Vinyl chloride - LT 1.0 LT 0.010
Xylene LT 0.50 LT 0.005
**LT • Less Than CT • f.rr ter Than
57
-------
TABLE 5.3
HEI6HT and VOLW1E REDUCTION
of HASTE TEED MATERIALS
Pntary Charter
Residence TIM (Kin) Run
12 J-l
18 J-2
18 1-1
12 1-2
12/18 H-1,2
18 B-l
12 B-2
Initial Height Ash Height
(Ibj) (Lbi)
260.5
162
138
113
302
100
155
ISO
101
78
£2
147.5
77
75
Height Reduction
(I)
38.6
37.7
43.5
45.1
51.2
23.0
51.fi
Initial Volute
(Ft)*
5.788
3.6
2.37
3.63
7.02
2.22
3.44
Ash Volute
(Ft)1
2.588
1.956
1.6
1.6
2.99
1.15
1.61
Voluw Reduct
(I)
55.3
45.66
45.86
55.67
57.42
48.25
53.19
58
-------
TABLE 5.2
INCINERATOR ASH CYANIDE/SULFIDE/FLUORIDE CONCENTRATION
Pit Run Cvanida Sulfida Fluoride
J 1 <.l 1600 15
J 2 <.l 3010 12
I 1 <.l 9350 29
I 2 <.l 8940 25
M 1 <.l 268 20
M 2 <.l 177 <10
B 1 <.l 414 <10
B 2 <.l 231 11
59
-------
5.3.1 Particulate Emissions
Presented in Appendix B are the results of
the EPA Method 5 particulate catches at both
the scrubber inlet and stack. Appendix A
also presents the probe wash particulate
weights. Table 5.4 summarizes the exhaust
stack particulate loadings for each run. The
levels are all veil below the .08 gr/dscf
RCRA performance requirement.
5.3.2 Continuous Emissions Monitoring
Also summarized on Table 5.4 are the nominal
emissions of SO3 , SO2 , CO, and MOX as
measured by the continuous monitoring
equipment at the scrubber inlet. A more
complete report of these data are presented
in Appendix B*
5.3.3 Priority Pollutant Emissions fDREl
Appendix A presents the semi-volatile and
volatile organic pollutant data. Of primary
importance in this analysis was the carbon
tetrachloride (CC14 ) detected on the
charcoal tubes located on the downstream side
of the XAD-2 resin in the Modified Method 5
sampling train. The Appendix A results show
that the CC14 that passed through the system
did not exceed carbon capacity. These
calculations are presented in a tabular form
in Appendix A. Using the stack gas flow rate
and the volume of gas sample caught, the
maximum amount of CC14 that could have passed
through the stack was calculated. All these
values were transformed into hourly flow
rates using the total test time. Table 5.,5
presents these calculations in tabular form
along with the resulting destruction and
removal efficiency, DRE. The ORE was
calculated using the equation:
ORE - CC1, rate in CC1, rate out X 100%
CC14 rate in
The results presented in Table 5.5 show that
the DRE of the system relative to CC14 was at
minimum, greater than 99.9997% for the eight
tests performed.
The DRE results were based upon the total
amount of carbon tetrachloride added to the
feed. The reason for this approach as
opposed to a DRE based on feed sample
analysis is that when adding a liquid
chemical into a material with a high clay
content such as the test material, one cannot
60
-------
Table 5.4
Stack Gas Analyses
Analysis
J-l J-2 1-1
1-2
M-l
M-2
B-l
B-2
Particulate*
(gr/dscf )
SOj
Obs/hr)
(Ibs/hr)
CO (ppm)
(Ibs/hr)
HC1
(mg/L)
0.015
0.12
0.34
0.0
0.022
<.0678
0.022
0.29
0.20
0.0
0.021
<1.095
0.027
0.10
0.11
0.0
0.025
<1.380
0.034
0.076
0.055
0.0
0.026
<1.323
0.007
0.014
0.077
0.0
0.027
<1.034
0.006 0.018
0.005 0.013
0.001 0.004
0.0 0.0
0.025 0.030
<0.619 <1.031
0.016
0.010
0.001
0.0
0.022
<0.95
*Corrected to 7\
61
-------
ro
PIT
STACK FLOy (DSCFri)
. (DSCF)
SAMPLE VOLUME (ISCF)
(DSCFH)
SAMPLING DATE
SAMPLING INTERVAL (MRS)
(HIN)
TOTAL UASTE FED (LBS)
TOTAL CC14 IN FEED
TOTAL CC14 IN SAMPLE (gi)
TOTAL CC14 IN STACK (gi)
CCI EMISSION RATE (ga/hr
CCI4 FEED RATE (gi/hr)
DRE (I)
J-l
SI13
9035
65.035
37.1(28
2/10/87
1537-1722
105
ISO
48
<7.10BilO-7
(9.875x10-5
(5.643x10-5
27.4286
>99.999B
POHC
J-2
5542
10899
59.121
30.0615
2/11/87
1002-1200
118
105
48
(7.131x10-7
(1.315x10 4
(6.684x10-5
24.4067
>99.9997
TABLE 5.5
DPE RESULTS
1-1
6063
10913
54.924
30.5133
2/11/87
1416-1604
108
63
48
(7.282x10-7
99.
2327x10-7
357x10-4
USilO-4
452
9997
IH
4426
8778
44.
22.
259
3154
2/12/87
1050-1249
119
"K
48
?7.
n.
(7.
24.
)99.
263x10-7
440x10-4
263x10-5
2017
9997
H-2
4883
15056
72.
23.
527
5222
2/12/87
1502-1807
165
75
48
<7.
99.
0434
9997
1-2
4872
10150
49.154
23.5939
2/13/87
1343-1548
125
75
48
(7.383x10-7
(1.525x10-4
(7.318x10-5
23.0400
>99.9997
CCI , FEED RATE - CCL, EMISSION RATE I 1001
=p|l
CCI^FEEO'RATE
LEGEND: DSCFH — Dry Standard Cubic Feed per Hour
DSCF — Dry Standard Cubic Feed
-------
Method 8280
TABLE 5.6
Polychlorinated Dibenzo-p-dloxins and Dibenzofurans
Summary Results Runs 1-8 Stack
•
Level (ug/hr)
PolychlorInated Dibenzo-p-dioxins
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCDD
1,3,7,9-TCDD
1,2,7,8-TCDD
1,2,8,9-TCDD
1,2,3,4,7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
TEST
J-l
<59.5
H
n
N
N
n
H
H
TEST
J-2
<70.3
H
N
n
N
It
n
N
TEST TEST
1-1 1-2
<82.8 <
n
N
M
N
n
it
H
n
n
it
H
It
n
H
TEST
M-l
I <75.0
n
H
M
N
N
It
TEST
M-2
<50.5
n
it
it
n
it
M
It
TEST
B-l
<82.1
M
H
N
N
H
H
tl
TEST
B-2
<73.3
it
n
N
tt
N
It
N
Polychlorinated Dibenzofurans
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
<59.5 <70.3 <82.8
Level*, ug/hr
2 <75.0 <50.5 <82.1 <73.3
* In concentrated extract.
63
-------
achieve a homogeneous mixture capable of
supporting testable grab samples. For
example in a grab feed sample testing
program, the composite feed sample could
potentially contain a small or large
concentration of the trace compound producing
data for DUE purposes that would not be
comparable.
Included also in Appendix A are the results
of the analysis of the XAD-2 resin in the
Modified Method 5 sampling train at both the
scrubber inlet and the stack for
Polychlorinated Dibenzo-p-dioxins and Dibenzo
furans. As can be seen by reviewing this
data, none of these compounds were found at a
detection level of <0.75 micrograms/milli-
liter of concentrated extract.
Also presented in Appendix A are the results
of the laboratory analysis of the charcoal
tubes in the MM5 train for volatile organics.
In each run, a quantity of Methyl Chloride
was detected. This was the solvent used to
clean the train prior to the test. The only
other compounds found were Toluene, Methyl
bromide, Tetrachloroethane, chloroform, and
Trichloroethylene. These were in small
quantities, however.
5.4 pcr^bber Effluent/Make Up Water
Scrubber water was analyzed for priority
pollutants, cyanide, total organic carbon, and
chlorides. The organic portion of the priority
pollutants were all lower than the detection limit
with the exceptions of Methyl bromide (.Olmg/1),
Di-N-Butyl Phthalate (.39mg/l), Methylene chloride
(.012mg/l), Methyl chloride (.010mg/l), 2-
ethylhexyl phthalate (.04mg/l) and Phenol (.13
mg/1). The priority pollutant metals are listed
on Table 5.8 with the make up water analysis. The
high chloride levels are due to the high
concentration of chlorinated hydrocarbons in the
feed. Chloride exists as sodium chloride in the
scrubber water. Carbon tetrachloride levels in
both the make up and the scrubber were all <5.0
ug/1 indicating virtually no carbon tetrachloride
in the water.
A comparison using Table 5.8 shows that the metal
and organic concentrations in both the plant
supplied make-up water and the scrubber effluent
were essentially the same in each case. Thus, it
can be concluded that there was no significant
addition of metals to the scrubbing liquid during
thermal processing.
64
-------
TABLE 5.7
SCRUBBER WATER
CARBON TETRACHLORIDE RESULTS
ug/L ug/L
Shirco I.D. Maka-U
Pit J Run 1 <5. <5.
Pit J Run 2 <5. <5.
Pit I Run 1 <5. <5.
Pit I Run 2 <5. <5.
Pit M Run 1 <5. <5.
Pit M Run 2 <5. <5.
Pit B Run 1 <5. <5.
Pit B Run 2 <5. <5.
65
-------
TABLE 5.8
Metal
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
J-l
Makeup
Sample
.60
.70
<.005
.075
8.06
283.
6.76
.0033
7.10
<.02
.03
.01
90.
Total Cyanides <.01
Total Organic
Carbon 855.3
Chloride 7060
Water Analysis
(rag/1)
J-l
Scrubber
Sample
.49
.51
<.005
.066
8.82
209.
4.83
.0008
7.17
<.02
<.01
.02
75.
73.1
4140
J-2
Makeup
Sample
<.06
.17
<.005
.014
1.59
17.7
1.65
.0008
,62
,02
,01
,01
3
<
<
<
6.29
457.2
1120
J-2
Scrubber
Sample
.07
.25
<.005
.021
4.52
13.4
2.42
.0006
5.42
<.02
<.01
.02
12. •
4.6
5990
66
-------
TABLE 5.8
Water Analysis
(mg/1)
(Continued)
Metal
1-1
Makeup
Sample
Antimony .06
Arsenic .15
Beryllium <.005
Cadmium .006
Chromium 2.36
Copper 7.50
Lead 1.11
Mercury .0007
Nickel 3.12
Selenium <.02
Silver <.01
Thallium <.01
Zinc 5.18
Total Cyanides <.01
Total Organic
Carbon 66.3
Chloride 1640
1-1
Scrubber
Samplq
<.06
.14
<.005
" .005
2.14
6.96
1.20
.0003
2.54
<.02
4.49
1-2
Makeup
Sample
<.06
.05
<.005
<.005
.17
.60
.20
<.0002
.21
<.02
( » 01
{ • 01
.43
<.Q1
15.2
2050
75.9
329
1-2
Scrubber
Sample
<.06
.15
<.005
<.005
.30
.95
.057
.0003
.55
<.02
.64
255.5
698.0
67
-------
TABLE 5.8
Water Analysis
(mg/1)
(Continued)
Metal
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Total Cyanides
Total Organic
Carbon
Chloride
M-l
Makeup
Sample
<.06
.03
<.005
.008
.64
11.0
.38
.0003
1.09
<.02
<.01
.02
5.16
<,01
43.2
440
M-l
Scrubber
Sample
<.06
.06
<.005
- .006
.52
9.76
.54
.0004
.83
<.02
4.27
261.8
720
M-2
Makeup
Sample
<.06
<.005
<.005
.27
3.70
.35
.0005
.27
<.02
1.66
M-2
Scrubber
Sample
<.06
.03
<.005
<.005
.45
3.64
.49
<.0002
.22
<.02
1.96
1152
397
1830.5
1000
68
-------
TABLE S.8
Vatez Analysis
(mg/1)
(Continued)
Metal
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Total Cyanides
Total Organic
Carbon
Chloride
B-l
Makeup
Sample
<.06
.01
<.005
.005
.89
12.6
.42
<.0002
1.00
<.02
<.01
.01
8.57
<.01
6.2
800
B-l
Scrubber
Sample
<.06
.05
<.005
X.005
1.12
15.1
1.37
.0017
1.10
<.02
<.01
<.01
9.89
3330
2650
B-2
Makeup
Sample
<.06
.01
<.005
<.005
.45
4.78
.52
.0095
.36
<.02
3.17
B-2
Scrubber
Sample
06
02
005
005
38
85
45
0002
42
02
01
oi
2.26
565.3
1480
1.4
1650
69
-------
6.0 Full Seal* System Sizing and Economic Analysis
Included on the following page* is an analysis
including sizing and operating economics for a full
scale infrared system. The sizing of a furnace system
was based both on the use of a currently in production
size mobile incineration system, and the largest single
mobile system that can be built at this time. A site
size of 125,000 tons was used for the analysis. The
process for this system would include an 18 minute
primary chamber residence time with a bed depth similar
to that tested of 1 1/2". For the mass and energy
balance, the nominal feed properties used were those of
Pit J as found in the ultimate analysis of Appendix c
and the SHIRCO laboratory analysis of Appendix D. It
is believed that these properties most nearly represent
the bulk of the materials on site requiring
incineration .
The full scale system sizing and economics are provided
for planning purposes only and reflect an accuracy of
plus or minus 25%.
70
-------
SHIRCO INFRARED FURNACE ANALYSIS
BRIO - 220 TPD UNIT
FURNACE PARAMETERS (9N vide X 85" long)
Total Feed 18,200 Ib/hr. (1 1/21" bed depth)
Total Dry Solids 14,378 Ib/hr.
%Dry Solids 79
% Water £1
Total 100
%Volatile (Organic) Solids 15
Vol.(Org.)Solid Heating Value 15,000 Btu/lb.
Furnace Area 2,190 ft.2
% Residual Oxygen 0
% Vol. Solid Combusted 100
Furnace Exhaust Temp. 1700° :
Solid Product (Ash) Temp. 1000°
Solid Product Spray Cooled Yes
Combustion Air Inlet Temp. 70°
AFTERBURNER PARAMETERS (9' vide x 70' long)
Exhaust Gas Temp. 2200°F
Area 2,779 ft.2
Gas Heating Value Organics 15,000 Btu/lb.
% Residual Oxygen 5% (by volume dry)
Combustion Air Inlet Temp. 70°F
-------
SYSTEM ELECTRIC POWER REQUIRED f OPERATING }
30 KW (FURNACE)
75 KW (HEATING ELEMENT POWER CENTER LOSSES)
300 KW (MOTORS)
SYSTEM NATURAL GAS FUEL
14,471 ACFH
SCRUBBER SYSTEM
90 gpm maximum at 60 pcig (85°F max)
(includes: 55 gpm evaporation make-up and 35 gpm
blovdovn make-up)
blovdovn make-up)
SCRUBBER EXHAUST PLOW
21,682 cfm at 180 °F
72
-------
SHIRCO INFRARED FURNACE ANALYSIS
BRIO - 150 TPD UNIT
FURNACE PARAMETERS (9" wide x 61" long)
Total Feed 12,500 Ib/hr. (1 1/21" bed depth)
Total Dry Solids 9,875 Ib/hr.
\Dry Solids 79
\ Water 21
Total 100
%volatile (Organic) Solids 15
Vol.(Org.)Solid Heating Value 15,000 Btu/lb.
Furnace Area 1,719 ft.*
\ Residual Oxygen 0
\ Vol. Solid Combusted 100
Furnace Exhaust Temp. 1700°
Solid Product (Ash) Temp. 1000°
Solid Product Spray Cooled Yes
Combustion Air Inlet Temp. 70°
AFTERBURNER PARAMETERS (9' wide x 70' long)
Exhaust Gas Temp. 2200°F
Area 2,779 ft.»
Gas Heating Value 15,000 Btu/lb. organics
% Residual Oxygen 5\ (by volume dry)
Combustion Air Inlet Temp. 70°F
-------
5R REQUIRED (OPERATING\
36 KW (FURNACE)
75 KW (HEATING ELEMENT POWER CENTER LOSSES)
300 KW (MOTORS)
SYSTEM NATURAL GAS FUEL REQUIREMENT
10,600 ACFH
SCRUBBER SYSTEM REQUIREMENT
75 gpm maximum at 60 psig (85°F max)
(includes: 45 gpm evaporation make-up and 30 gpm
blovdovn make-up)
SCRUBBER EXHAUST PLOW
10,206 cfm at 180 °F
74
-------
i S
I i
s -
= 2 S™ S a ?? l**S?}?£5gjs
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I
-------
NODCl ASSUMPTIONS (9 x 85)
Furnace Residence Tie»
Material Density
•ad Thickneea
Operating Utility
15.00 *1n
82.SO Ib/ft3
1.85 In
Dally Tana
222
6 days/*
SO t*a/yr ( 300 dayt/yr)
82.42X out of 7 daya for S2 Maaka
Payout Period
36
Price par Ton
$119.00 Annual Thruput 66,701 tona/yr
1 UnitU)
Oparating Crw
Oparatora •
Naintananea •
Suparviaora -
Lab and tafaty
$/hr
S10.SO
$16.50
$20.00
• $11.50
Total Craw
Overhead Rate
Ho.
16
2
3
3
24
40. OW
Annual $ par Nan
21,840
34,320
41,600
23,920
$640,848 Cn
256,339
OvartlBB/Nan/Wk Ho. Locala
2 8
Par Die* Coat par Nan
For 16 Nan
Naintanance Coat par ton
Fual Coat: Elact Coat • KU
Energy Coat:
Startup Power
Priaary - Opar
Afterburner
Notora Max
Energy coat per ton
Chaaical Coat per ton
Safety t Compliance:
Supplies t Nad Taata/ton
Taating Coat/ton
Total
Scrubber Water Coat
Water Uaaga per ton
Total Payroll Expense
$75.00 •
$5.00 •
$0.08
$897.187 Average Hourly Wage
$6.57 /ton • Groaa Coat
$333,503 /yr
Gas • NCF $3.50 Oil Par Gal $0.80
$12.84
0.09 /ton
2.56 /ton
0.10 /ton
1.93 /ton
$4.59
$1.25
0.99
1.50
$2.49
1,200 Nax InatalIad KVA
534 Reqd ITU/lb Addition
2,200 F Tee? Reqd
300 tnatallad HP
$83,376 /yr
66,000
100,329
PHnary Sourc
x Electric
Fuel Oil
Gas
$166,329 /yr
$0.80 / 1000 gal
767 gal •
Monthly Opar Overhead $22,820 per ao
x 12 • $273,839 per yr
Equip Insurance
$550,000 per yr
• • $40,928
3.45X of Monthly "Revenue"
10.OCX of Equip Coat
Naterial Properties
Organic Content 1SX
Water Content 21X
Waste Heating Valua/Lb VS 15,000 RTU/lb
Hat BTU/Lb
1,967
76
-------
iul-87
ON-SITE MOilLE IMCIHfUTIOM SERVICE
ESTIMATED ECONOMIC MODEL
JULY 1987
EqulpMnt •
Effective Thruput
Operating Expense:
Personnel
Uege Rate
Overhead Rate
1 Shiree Mobile Furnace System 9x61 with related anciliarlea
45,045 torn In 50 Mka/yr 8 150 torn/day •
At 82.42X Utilization
24 Men - 3 Shifta • 6 daya/Mk average operation
S12.84 per hr • 126,702 per yr average rete
40.001 of Direct Wage Rate
Total Labor
$897,187 Per Tear
TOTAL EQUIPMENT COfT
EQUIPMENT C08T PER TOM
4,035,000
For Payback in -
36 Months
PROFIT,TAXES t OPPORTUNITY-C01T Of CAPITAL 8 35.00X
MINIMUM INCINEUTION COST PER TON ASSUMING THIRD PARTY CONTRACTOR
12,513 Ib/hr
8/TON
19.92
Site Expenses:
Personnel Living S75 per day
Chemical Coat S1.2S per ton
Energy Coat SS.42 per ton (aax)
Ash Disposal >
Scrubber Effluent >
Cooling Water SO. 80 per 1000 gal
Spare Parts
Maintenance SS.OO per ton
Monthly Oper Costs
Compliance, Etc S2.97 per ton
Fuel SO. 10 per ton
Oper Ovtvd S18.519 per ae
Remit /Process Assistance • 08IS
Relocation, Transport
Insurance
Misc Contingency 10. OCX
TOTAL OPERATING COSTS
EqulpMnt Coat Estiaate:
Shirco Mobile Systaai 9 x 61
* Instrumentation, Control Van
Generators, Feed Prep Equip (Eat)
Field Facilities (Est)
438,000
56,306
244,224
62,500
48,000
27,640
80,000
225,225
133,568
0
222,230
125,000
150,000
403,500
311,338
S3.424.717
3,250,000
650,000
135,000
9.72
1.25
5.42
1.39
1.07
0.61
1.78
5.00
2.97
0.00
4.93
2.78
3.33
8.96
6.91
DIRECT COST/TON S76.03
( S24.05 )
( 4.81 )
( 1.00 )
77
-------
MODEL A88U*»T10M (9 x 61)
Furnaca Raaldanca Tla»
Material Danalty
Bad ThickmM
Operating Utility
18.00 Bin
82.50 Ib/ft3
1.SO In
Dally Tor
150
6 days/*
50 Hka/yr ( 300 daya/yr)
82.42X out of 7 daya for 52 t»aka
Payout Period
Price par Ton
$143.00 Annual Thruput 45,0*5 tona/yr
1 Un)t(i)
Operating Craw
Operatora •
Maintenance •
Superviaora -
Lab and Safety
8/hr
810.50
816.50
820.00
• 811.50
Total Craw
Overhead Rate
Mo.
16
2
3
3
24
40.00X
Annual 8 par Nan
21.840
34,320
41,600
23.920
8640,848 Or
256,339
OvertiM/Man/Mc Ho. Locals
2 8
Per Die* Coat per Nan
For 16 Nan
Maintenance Coat per ten
Fuel Coat: Elect Coat - KU
Energy Coat:
Startup Power
Primary - Oper
Afterburner
Motors Nax
Energy coat per ton
Cheetlcal Coat par ton
Safety I CoBpliance:
Supplies t Nad Teats/ton
Testing Coat/ton
Total
Scrubber Water Coat
Water Usage per ton
Total Payroll Expense
875.00 •
85.00 •
80.08
8897,187 Average Hourly Wage
89.72 /ten - Groaa Coat
8225,225 /yr
Gaa • NCF 83.50 Oil Per Gal 80.80
812.84
0.13 /ton
2.56 /ton
0.10 /ton
2.86 /ton
85.52
81.25
1.47
1.50
82.97
1,200 Max Inatallod KVA
534 Mod BTU/lb Addition
2,200 F Taap Raqd
300 Inatallod HP
856,306 /yr
66,000
67.753
Priavry Sourc
8133,753 /yr
80.80 / 1000 «al
767 gal •
140
Monthly Opar Ovarhaad 818,519 par mo
x 12 « 8222,230 par yr
Equip Inaurance
8403,500 par yr
p* • 827.640
3.45X of Monthly "Kavanua"
10.OCX of Equip Coat
Matarlal Propartlaa
Organic Contant 15X
Uatar Contant 2U
Uaata Haatlng Valua/Lb VS 15,000 BTU/lb
Hat ITU/Lb
1,967
78
-------
7.0 CONCLUSIONS AND RECOMMENDATIONS
It was stated in the introduction that the objectives
of this test program were:
1. To determine the incinerator ash chemical
composition.
2. To demonstrate that the incinerator feed
system could provide a continuous, blended
feed which could be fed to the furnace in a
uniform manner.
3. To demonstrate that the incineration system
can meet the RCRA requirement of 99.99%
destruction efficiency for POHCs.
4. To provide design information and economic
data required to evaluate the feasibility of
incinerating certain Brio site pit wastes.
These objectives were accomplished by the test
program.
7.1 Incinerator Ash
The laboratory analysis for both feed and ash are
presented in Appendix A. All compounds detected in the
feed were reduced substantially in concentration as
indicated by the corresponding ash concentrations.
This holds for all pit materials processed at both the
12 minute and 18 minute primary chamber residence
times. The process conditions which produced these
results included nominal bed depths from 1 1/4 to ln3/8
inches deep, chamber temperatures ranging from 1550°F
in Zone A to 1600°F in mid furnace to 1575°P at the end
of Zone B, oxidizing atmosphere or reducing at the
other extreme, and auxiliary power from the heating
elements as needed to maintain the chamber
temperatures.
7.2 Incinerator Feed Svatea
The material processed from each pit required
preparation prior to being placed in the feed conveyor
hopper. Recall that the feed conveyor used on the
Portable Unit is a simple conveyor with leveling gate
that allows operation with a wide range of waste
materials but does require operator aid with most
materials other than dry sand, soil, and small granules
material. The Pit J material, along with the others
tested, required delumping and screening. However, it
did not display the clay like properties as did the Pit
M, I, and B materials. It is concluded that all
materials will require delumping and screening prior to
incineration. For Pits M, I, and B mixing with lime,
kiln dust, fly ash, or dry soil is expected to minimize
the sticky nature and simplify materials handling. The
mixing of such an agent during the excavation and prior
to delumping and screening is recommended to minimize
79
-------
equipment clogging and reduce power requirement*. To
facilitate system design a material* preparation test
is recommended.
7.3 Destruction Efficiency
The emissions sampled by the Modified Method 5 sampling
train and the the subsequent analysis of the charcoal
tubes found that the destruction and removal efficiency
of the system was greater than 99.9997% for each of the
eight test conditions. Thus, processing at either an
18 or 12 minute residence time in the primary chamber
at a temperature of 1600°F and passing the exhaust
gases through a secondary chamber with a minimum
residence time of 2.2 seconds at 2200°F, satisfies the
objective. Analysis of the resulting scrubber recycle
liquid verifies that the destruction is complete and
the hazard is not transferred from the feed to the
scrubber effluent or atmosphere.
7.4 Design Data and Economics
Design data for a full scale system was obtained
including proximate and ultimate analysis of the waste
streams, process temperatures, bed depth and residence
time, and laboratory analysis of the feed, ash,
scrubber water, and exhaust gas streams. The sizing
and economic analysis is presented in Section 6.0 of
this report. This analysis concludes that using the
currently available size mobile system (9'x61' primary
chamber) 45,000 tons per year could be processed at an
estimated cost before taxes of $143 (ONE HUNDRED FORTY-
THREE DOLLARS) per ton. Using the largest mobile
system that may be built at this time (9' x 85' primary
chamber) a total of 67,000 tons per year could be
processed at a cost of $119 (ONE HUNDRED NINETEEN
DOLLARS) per ton. The accuracy of this cost estimate
is ±25 percent. Note that this cost estimate does not
include costs for feed excavaton, feed preparation,
interest and taxes.
80
-------
APPENDIX A
EAGLE PICKER RESEARCH LABORATORY
SAMPLE ANALYSIS REPORT
-------
EAQLE-^PKHER
LABORATORY
SAMPLING PROTOCOL
AND QUALITY ASSURANCE PROCEDURES
SHIRCO INCINERATOR POHC TRIAL BURN TEST
BRIO REFINING, INC. : FRIENDSWOOD, TEXAS
BRIO TRIAL BURN EMISSION TEST
A. g/-T-nV»b«r Exhaust Stack
1. Test Procedures
The formal trial burn test consisted of two
sampling runs per day for 4 days on the Shirco
prototype incinerator scrubber exhaust stack at the
Brio Refining, Inc. facility in Friendswood, Texas.
For each sampling run, the following stack gas
parameters were determined:
Temperature - *F
Velocity - fps
Volume flow - acfra, scfra, dscfh
Moisture - * by volume
Oxygen and carbon dioxide concentration - * by volume
Particulate
concentration - gr/d»cf, Ibs/dscf,
gr/dscf (corrected to 7* 02
if required)
emission rate - Ibs/hr
Sulfur trioxide and sulfur dioxide
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
Carbon monoxide
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
POHC (Appendix VIII compounds, as required)
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
Hydrogen chloride (HC1)
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
The non-POHC parameters, as listed above, were
determined following the procedural requirements as
detailed in the CFR40, EPA Methods 1 through 5, 6/8 and
10 as detailed below;
-------
EAGLE If°)PKHER
RESEARCH
LABORATORY
Method
Method 1
Method 2
Method 3
Method 4
Method 5
Method 6/8
Method 10
Description
Sample and Velocity Traver*e«
for Stationary Source*.
Determination of Stack Gas
Velocity and Volumetric Flow
Rate.
Gas Analysis for Carbon
Dioxide, Oxygen, Excess Air
and Dry Molecular Weight.
Continuous C* and C0_ monitors
were used.
Determination of Moisture
Content in Stack Gases.
Determination of Particulate
Emissions from Stationary
Sources.
Determination of Sulfur
Trioxide and Sulfur Dioxide
Emissions from Stationary
Sources.
Determination of Carbon
Monoxide Emissions from
Stationary Sources.
2. Sampling Location
Sampling was conducted using the two sampling ports
provided on one aide of the scrubber exhaust stack at 24" and
54" above the trailer platform. At this location the stack
inside diameter is 3-7/8 inches. The sampling ports are
located greater than 8 diameters downstream of the breeching
and greater than 8 diameters upstream of the stack top. Due
to the very small diameter of the scrubber stack, only two
campling points can be sampled along the one traverse that is
available.
3. Velocity and Volume Flow
Gas velocity and volume flow rate were determined
following EPA Method 2 as detailed in the CFR40. Velocity
determinations were performed using an "S" type pitot tube
and inclined manometer. Temperature measurements were
conducted using a Keithley digital temperature meter and
chromel-alumel thermocouple.
Page 2
-------
4. Stack
-------
EAQLElf°>PKHER
RESEARCH
LABORATORY
•o that gas exhausts directly from the filter holder into the
first XAD-2 resin cartridge and (2.) The addition of a third
trap containing activated charcoal to be placed on the inlet
of the impinger labeled as No. 4.
An illustration of the XAD-2 trap is given in
Figure 2. Please note that all traps and the condenser are
ice water cooled so that low boiling as well as high boiling
point POHCs can be collected.
The residue free XAD-2 sorbent media is described in
Figure 3. This resin was purchased commercially and has been
precleaned to eliminate all 'extractable organic impurities
following EPA procedures.
Two complete Modified Method 5 (Semi-VOST) sampling
trains were prepared for the two test runs conducted each
day.
The sampling train glassware and traps were precleaned
with a mixture of pesticide grade methylene chloride and
methyl alcohol.
The sampling train remained sealed prior to use at the
test location, at which time the sorbent cartridges were
installed on the train.
Following the completion of each sampling run the train
was leak checked and sealed and transported to the clean-up
area. After completion of the two sampling runs performed
each day, the sampling trains were disassembled and cleaned
as follows:
a.) The probe and filter holder upstream glassware
were rinsed with the methylene chloride-methanol
mixture and the rinse stored in an amber glass bottle
with Teflon lined screw cap and labeled as Container
No. 1.
b.) The filter was placed in a glass Petri dish and
sealed with Teflon tape and labeled as Container No. 2.
c.) The sorbent cartridges were removed and sealed
with glass end caps and Teflon tape.
d.) The impinger condensate was emptied from the
impingers and stored in an amber glass bottle with
Teflon lined cap and labeled as Container No. 3.
e.) The impingers and connecting glassware were
rinsed with the methylene chloride and methanol mixture
and the rinse stored in an amber glass bottle with
Teflon lined cap and labeled as Container No. 4.
Page 4
-------
EAGLE 3TPKHER
RESEARCH
LABORATORY
f.) The silica gel was emptied into its respective
container No. 5.
The contents of Containers 1 and 2 were dried and
desiccated at room temperature and weighed to the nearest
0.1 mg to determine the total particulate catch prior to the
analysis for POCHs. An aliquot was taken from Container
No. 3 for hydrogen chloride analysis.
8. Hydrogen Chloride
Hydrogen chloride concentration and emission rate were
determined by collection of HC1 in the back half impinger
catch of the Modified Method 5 particulate/POHC sampling
train. HC1 analyses were performed using 1C techniques.
9. Sulfur Oxides
Sampling an analyses for sulfur trioxide and sulfur
dioxide conducted in a Modified Method 6/8 sampling train
following the Texas Air Control Board Method 29 as detailed
in the TACB Sampling and Laboratory procedures manual.
10. Carbon Monoxide
Carbon monoxide concentration and emission rate were
determined continuously during each test run following EPA
Method 10.
B. Afterburner Exhaust S^Tubber Inlet Duct
•
1. Test Procedures
The formal trial burn tests consisted of two runs per
day for 4 days. For each sampling run, the following stack
gas parameters were measured:
Temperature - *F
Moisture - * by volume
Nitrogen oxides
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
POHC (Appendix VIII compounds, as required)
concentration - ppm, Ibs/dscf
emission rate - Ibs/hr
The non-POHC parameters were determined following the
procedural requirements as detailed in the CFR40, EPA Methods
1.2,4 and 7 as detailed below:
Page 3
-------
EAQLE^PKHER
RESEARCH
LABORATORY
Method
Method 1
Method 2
Method 4
Method 7
Description
Sample and Velocity Traverses
for Stationary Sources
Determination of Stack Gas
Velocity and Volumetric
Flow Rate
Determination of Moisture
Content in Stack Gases
Determination of Nitrogen
Oxides Emissions from
Stationary Sources
2. Sampling Location
Sampling was conducted using the one port provided in
the after burner exhaust duct.
3. Stack Gas Moisture
Moisture content of the exhaust gas was determim
following EPA Method 4 concurrently with the POHC sampling.
4. Nitrogen Oxides
NO/NO, sampling was conducted following EPA Method 7E
procedures (Ising TECO Model 10 NO/NO, monitor.
QUALITY ASSURANCE PROCEDURES
1.) Pretest Calibration of Test Equipment
2.) Preparation of Test Equipment
3.) Field Testing
4.) Sample Storage
5.) Chain of Custody Record
6.) Data Reduction
7.) Post Test Calibration of Test Equipment
8.) Reporting (Non POHC and HC1)
A. Pretest Calibration of Equipment
Pretest calibration of sampling equipment followed the
protocol as detailed in the Quality Assurance Handbook for
Air Pollution Measurement Systems. Volume III, 1977 and the
Code of Federal Regulations. CFR40, Part 60, 1985.
Page 6
-------
EAQLE^PKHER
RESEARCH
LABORATORY
Calibration of the following equipment was conducted
within 30 days prior to the test program:
1.) Pitot Tub*
2.) Stack Temperature Sensor
3.) Dry Gas Meter Orifice
4.) Dry Gas Meter
5.) Dry Gas Meter Temperature Gauges
Standard procedures and data forms were used for
pretest calibration of equipment.
B. Preparation of Sampling Equipment
Type and configuration of sampling equipment used
follows the CFR40 protocol for EPA Methods 1 through 5, 6, 7
and 10 and current state of the art POHC sampling procedures
using the Modified Method 5 Semi-VOST sampling train.
Specifically, all sampling equipment were prepared and
maintained to meet or exceed EPA method requirements.
Additional quality assurance procedures for the
preparation of sampling equipment were as follows:
(Methods 1-5)
1.) Modified Method 5 glassware and sample bottles
were precleaned with a mixture of pesticide grade
methyl alcohol and methylene chloride.
2.) Sampling train heaters prechecked.
3.) Probes precleaned and pitot tubes inspected.
4.) Sampling nozzles precleaned and inspected.
5.) Glass fiber filters visually checked and weighed
immediately prior to field testing.
6.) Silica gel preweighed immediately prior to field
testing.
7.) Sampling equipment organized and packed using ARI
Equipment Checklist.
(Method 3 and 10)
1.) Analyzers prechecked for span and three point
linearity check.
2.) Certified calibration gases checked.
Page 7
-------
EAGLE l§°> PICHER
RESEARCH
LABORATORY
c. Fjfij TMtinq
Quality assurance procedures during field testing
included the leak check, sampling, clean-up and performance
check protocol as detailed in EPA Reference methods 1-5, 6 7
and 10.
Additional quality assurance procedures during field
testing included the following:
(Methods 1-5)
1.) Daily filter, water and solvent blanks were
collected. (Method 5)
2.) Sample bottles used were amber glass with Teflon
lined caps. (Method 5)
3.) Standard field test data sheets were used during
sampling.
4.) Glass wash bottles were used during clean-up.
Method 5)
5.) Teflon probe brushes were used during clean-up.
(Method 5)
6.) Glass Petri dishes were used for filter storage.
(Methods )
(Method 3 and 10)
1.) Oxygen, carbon dioxide and carbon monoxide
monitors operational for minimum 2 hours prior to
field testing.
2.) Calibration checks conducted immediately prior to
and following each test run.
D. Sample Storage
(Method 5)
All water and solvent rinses were stored in amber glass
bottles with Teflon lined caps and the levels marked.
Filters were stored in glass Petri dishes and sealed with
Teflon tape.
Page 8
-------
EAQLEli°)PKHER
RESEARCH
LABOfUCfOKf
E. Chain of Custody of Collected POHC Samples
(Method 5 and HC1)
All camples for POHC and HC1 analysis were yielded to
Eagle-Picher following the completion of each day of field
testing. A strict chain of custody was maintained for
samples collected throughout the test series.
F. Data Reduction
Calculations and da.ta reduction were performed using
standard calculation sheets for CO. and 0, and concentration,
stack gas volume flow rate, CO, SO , ana N0x emissions and
particulate emissions. All calculations were performed
twice.
i
G. Post-Test Calibration of Equipment
Post-test calibration of all sampling equipment used
during the test were conducted following the pretest
procedures. The dry gas meters in each console post-test
calibrated at the average 1 H and highest vacuum documented
during the test series.
Page 9
-------
PKHER
ftCSEAACM
E-P Analytical Report
Customer ID:Pit J Waste Feed Run #1
SW-846 Method 8240
Work Order * 87-02-130-01A
mg/Kg
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-4S-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-*
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01-7
110-86-1
100-42-5.
630-20-6
79-34-5
127-18-4
108-48-4
156-60-5
75-25-2
71-55-6
79-00-5
79-01-6 '
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) methane
Bis(2-chloroethyl) ether
Bii( 2-chloroisopropyl) echer
Bromodichlorome thane
Bromorae thane
Carbon disulfide
Carbon Tetrachloride
Chlorobenzene
Chi or odibromome thane
Chloroechane
Chloroform
Chlorome thane
1 ,2-Dibrorao-3-chloropropane
1 ,2-Dibrotnoethane
Dibromomethane
Oichlorodifluor one thane
1 , 1 -Dichloroe thane
1 ,2-Dichloroethane
1 , 1-Dichloroethylene
Die h lor otne thane
1 ,2-Dichioropropane
Ethyl benzene
Hexachloroethane
2-Hexanone
lod one thane
Methyl ethyl Ice tone
Pen tachloroe thane
Pyridine
Styrene
1,1 , 1 ,2-Tetrachloroethane
1,1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Trans-1 ,2-Dichloroethene
Tribromone thane
. 1 ,1, 1-Trichioroe thane
1,1,2- Trichloroethane
Trichloroethene
Trichiorooonofluoroae thane
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
120.
NO*
3.6
<20.
<20.
<20.
<0.50
<1.0
5.7
128.
31.
<0.50
<1.0
43.
<1.0
ND*
ND*
ND*
ND*
31.
86.
, 16.0
<0.50
ND*
160.
<20.
<1.0
ND*
<1.0
ND*
ND*
140.
ND*
39.
28.
17.
<0.50
<0.50
1.5
<0.50
33.
<0.50
ND*
3.0
<0.50
ND*-Nominal Detection L;.mit»<50. mg/Kg
-------
AESCAACH
LABORATORY
PKHER
E-P Analytical Report
Customer ID:Pit J Waste Feed Run #1
EPA SW-846 METHOD 8270
Work Order # 87-02-130-01A
Detection limit:
CAS RN COMPONENT
208-96-8 AcenaphChalene
83-32-9 Acenaphchene
75-05-3 Aceconitrile
98-86-2 AceCophenone
53-96-3 2-Acetylaninofluorene
107-13-1 Acrylonicrile
122-09-3 Alpha, alpha-diaeehylphenethylaraine
92-67-1 4-Aainobiphenyl
62-53-3 Aniline
120-12-7 Anthracene
140-57-8 Aramite
56-55-3 3enz[ a] anthracene
108-98-5 Benzenethiol
92-37-5 Benzidine
2Q5-99-2 Benzol b] fluoranehene
207-08-9 Benzol k] fluoranehene
65-85-0 Benzoic acid
106-51-4 £-Benzoquinone
191-24-2 flenzo(ghi)perylene
50-32-8 Benzo[ a] pyrene
100-51-6 Benzyl alcohol
117-81-7 Bii(2-ethylhexyl)phthalate
101-55-3 4-Bromophenyl phenyl ether
85-68-7 Butyl benzyl phchalate
106-47-d £-Chloroaniline
510-15-6 .Chlorobenzilate
126-99-8 2-Chloro-l,3-bueadiene
59-50-7 £-Chloro-m-cre§ol
110-75-8 2-ChloroeThyl vinyl ether
91-58-7 2-Chloronaphchalene
95-57-8 2-Chlorophenol
7005-72-3 4-Chlorophenyl phenyl ether
107-05-1 3-Chloropropene
218-01-9 Chryaene
10061-01-5 cie-1 , 3-Dichloropropene
53-70-3 Dibenzl a, h] anthracene
132-64-9 Dibenzofuran
192-65-4 Dibenzo[a,e)pyrene
189-64-0 Dibenzofa, hjpyrcne
189-55-9 Dibenzo[a,i]pyrene
84-74-2 Di-£,-bueyl phthalate
541-73-1 m-olchlorobenzene
95-50-1 £-Dichlorobenzene
106-46-7 £-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidine
ND*
ND*
NO*
NO*
<20.
<20.
ND*
<20.
ND*
<100.
<20.
<20.
<100.
ND*
<20.
<20.
<20.
<20.
<20.
<20.
<20.
ND*
ND*
<20.
<1.0
<20.
<20.
<20.
ND*
<20.
<0.5
<20.
<20.
ND*
ND*
ND*
20.
<20.
<20.
<20.
<40.
ND*«Nominal Detection Limit-<50. mg/Kg
-------
LABORATORY
E-P Analytical Report Work Order * 37-02-130-01A
EPA SW-846 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <20.
87-65-0 2,6-Dichlorophenol ND*
94-75-7 2,4-Dichlorophenoxyacetic acid ND*
84-66-2 Dicthyl phthalate <20.
119-90-4 3,3'-Diaethoxybenzidine ND*
60-11-7 £-Dimethylaminoazobenzene ND*
57-97-6 7,12-Di.iiethylbenzt a] anthracene ND*
119-93-7 3,3'-Dimcthylbenzidine ND*
105-67-9 2,4-Dimethylphenol <20.
131-11-3 Dimethyl phthalate ND*
534-52-1 4,6-Dinitro-o-cresol <100.
51-28-5 2,4-Dinicrophenol <100.
121-14-2 2,4-Dinitrotoluene <20.
606-20-2 2,6-Dinitrotoluene <20.
117-84-0 Di-n-octyl phthalate <20.
122-39-4 Diphenylamine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-£-propylnitroaamine <20.
107-12-0 Etfvyl cyanide ND*
206-44-0 Fluoranthene <20.
86-73-7 Fluorene <20.
118-74-1 Hexachlorobenzene <20.
87-68-3 Hexachlorobutadiene <20.
77-47-4 Hexachlorocyclopentadiene <20.
Hexachlorodibenzo-£-dioxin« ND*
Hexachlorodibenzofurana ND*
70-30-4 Hexachlorophene ND*
1888-71-7 Hexachloropropene ND*
193-39-5 Indcno(l,2,3-cd)pyrene <20.
78-59-1 laophorone <20.
120-r58-l Ito«afrole ND*
109-77-3 Malonitrile ND*
100-25-4 aeta-Dinitrobenzenc ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
101-14-4 4,4'-rMethylenebi«(2-chloroaniline) ND*
80-62-6 Methyl nethacrylate ND*
66-27-3 Methyl methaneaulfonate ND*
91-57r6 2-rMethylnaphthalene <20.
108-10-1 4-Hethyl-2-pentanonc <1.0
91-20-3 Naphthalene 140.
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone ND*
88-74-4 2-Nitroaniline <100.
99-09-2 3-Nitroaniline 553.
100-01-6 £-Nitroaniline <100.
98-95^3 Nitrobenzene <20.
88-75-5 2-Nitrophenol <20.
ND*-Nominal Detection Liait*<50. mg/Kg
-------
EAQLEli°> RICHER
RCSCAKCH
LABORATORY
E-P Analytical Report Work Order * 87-02-130-01A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
100-02-7 4-Nitrophenol
924-16-3 JN-Nicrosodi-jv-butylaaiine
55-18-5 . £-Nitrosodie7hylamine
62-75-9 ti-Nitrosodimechylamine
86-30-6 £-Nitrosodiphenylanine
10595-95-6 ^-Nitrosoratthylethylamine
59-89-2 £-Nicrosonorpholine
100-75-4 ^-Nitrosopiperidine
930-55-2 Tj-Nitrosopyrrolidine
99-55-8 5~-Nitro-£-toluidine
95-48-7 ortho-Cresol
106-44-5 para-Cresol
608-93-5 Pentachlorobenzene
Pentachlorodibenzo-£-dioxins
Pentachlorodibenzofurans
82-68-8 Pentachloronitrobenzene
87-86-5 Pentachlorophenol
62-44-2 Phenacetin
85-01-8 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-58-5 Pronamide
129-00-0 Pyrtne
108-46-3 Reiorcinol
94-59-7 Safrole
88-85-7 2-see-Buty1-4,6-dinitfophenol
95-94-3 1,2,4,5-Tetrachlorobenzene
1746-K)l-6 2,3,7,8-Tetrachlorodibenzo-£-
dioxin
Tetrachlorodibenzo-£-dioxini
Tetrachlorodibenzofurans
58-90-2 2,3,4,6-Tetrachlorophenol
110-57-6 Crans-1,4-Dichloro-2-butene
10061^02-6 trans-1,3-Dichloropropene
120-82-1 l,2,4-Trichlorob«nzene
75-70-7 Trichloromethanethiol
95-95-4 2,4,5-Trichlorophenol
88-?06-2 2,4,6-Trichlorophenol
93-76-5 2,4,5-T
126-72-7 Tris-(2,3-dibroraopropyl)phosphate
ND*-Nominal Detection Liait"<50. »g/Kg
-------
RESEARCH
LABORATORY
c-PA jn-o-ib Mi.'lllUD
A.*> K.'J
ouo-9J-5
106-95-Z
l2y-UU-0
{ib-HD-7
J5-y*-J
1 7 40-o 1-0
110-3/-0
lOOul-02-6
75-7U-7
VJ-70-5.
12b-72-7
..-.. LC rosupipcr i
^_-..iiruso|>yrr jl
5-Nitro-o-toluidinc
PenL.ichlorubenzene
HenLjcliiorodioenzo-p-dioxins
IV-iiCaciiiorodi benzol urans
Pencucliloronicrobctizene
Piienacecin
I' i ic ua neuron
ljlieaoi
2-HiCuiinci
Pyretic
iiesorcinol
2-sec-tutyl-t.o-dinicrophenol
1 ,2 ,4 ,5-TccruChlorobenzene
2 ,J ,7 ,6-TiCrdc!ilorodibcnzo-£-
Jioxia
Tccnchiorodibcn2o-£-dioxins
Tecrachiorodioenzoturdns
2,3,4,6-Tecrachiorophenol
Lraiib-i ,4-Dichioro-2-Ducene
t.rans-1 ,3-Uicnlurupropene
1 ,2,4-Trichlorobeuzeno
Tricnioromecnancchiol
2,4,3-Trichloropnenol
2,4,6-Triclilorophenol
2,4,5-T
Tns-(2,3-diDroraopropyl)phosphdte
NO
Nu
NL)
.',0
wo
NO
310
ND
ND
NU
ND
ND
ND
Nu
NO
NU
NU
N'j
ND
NU
NU
NU
ND
NU
ND
ND
NO
NU
-------
RESEARCH
LABORATORY
SW-a4fo
I.-P Anjiytic-u
10: i>l Jb lu Pit !J
thod 6240
ui'J'T :' X/'-D I ~2 1 d-U 1 ,\
Low
Mi.-d
10.UOO Co 50,000
bU.UUO Co 200,OUO
>200,000
LAS KN
o
b7-o4-l
i J/-U2-6
10d-oO-I
73-27-4
74-aJ-9
75-15-U
56-^3-5
67-ob-J
M-4/-J
>> 0-i 2-6
lUb-93-4
74-^5-J
75-/1-8
/5-J4-3
107-00-2
/o-Ji-H
75-OV-2
7a-87-4
1UU-4I-4
07-72-1
7B-V3-3
7&-U1-7
I 10-do-i
100-42-5
bJO-2U-b
79-J4-5
12/-1B-4
15o-oO-5
/b-25-2
Ace cone
Acroiein
iiis(2-cnioroechoxy ) tnectirino
riiaC2-ctilorwocnyl) edier
Bis(2-chioroisiiprr>pyi ) ether
Bromodi chlorome thane
Uronomcthane
Car Don disulfide
Carbon Tec rachioride
CliioroDcnzuiie
Clilorodibrumonechane
Chioroechane
CUloroiorra
1 ,2-Dibromo-3-chioropropane
1 ,2-Uibromoe thane
Dibromomechane
Uicniorodif luorumechane
1 , 1-Dichloroethatie
1 ,2-Dichlotoetiidne
1 , 1-Uichloroethylene
Uicliiororaettiane
1 ,2-Uichlorupropane
tltuyi DC u ze no
hiixa Chioroechane
2-uexanono
lodomechanu
Mechyl echyl kecoiu?
Fencachioroechane
Pyridine
Styrene
1,1,1 ,2-TttCr«ichloroecl>une
1 ,1 ,2 ,2-Tccrachioryothane
/5-01-4
1JJU-20-/
Toluene
Trans-1 ,2-UichiorueChane
Tflbroinometlianc
1 , 1 , l-Trichloroeth.inj
1,1,2- Trictiiorocchane
Trichloroethene
Triciiioroi-ionor iuoromethane
Tricnlorunietiiane
Vinyl ciiloride
Xyleue (.cocaij
NO
ND
High
NU
ND
High
ND
NU
NU
NU
ND
Ned
Mud
ND
Med
ND
Med
Nu
i\D
NU
ND
NU
i4D
NU
Med
NL)
Nu
High
'Ingh
ND
Nu
NU
-------
AQLEL^pPKHER
RESEARCH
LABORATORY
- L-e An.iiytic.ii
jsLi..,i«-i- iU: U'l' 3h 10 fit ri
. er .c.-durc »oau, h 1 50, and
UUTK. Order // 87-U1-216-0I A
KN
12674-11-2
1UU4-20--2
Ul4i-lo-5
00-5/-1
/2-20-a
IJ24-5/-J
14J-50-0
72-4J-5
aOUl-J5-2
CiimponunL
Aidria
Alpna-UHC
Aroclor 1016
Aroclor 1221
Arocior 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1200
DtiCii-nllC
Ciiurd.inc
UUU
UDt
UUT
deita-ttHC
Dielurin
t-ndoauiinn 1
i-.ndosultan 1]
tndrin
Endrin
garama-BiiC
Hepcachior epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
NU
NU
NU
NU
NU
NU
NU
t.'U
NU
NU
NU
NU
NU
NU
NU
ND
7.1
5.5
NU
ND
5.7
NO
NU
NU
ND
OC Procedure di4u
-97-2 0,0-Uiethyi 0-2-pyrazinyl ND
Ptiosphorocnioace
2y»-U4-4 uisulfocon ND
i2-85-7 Faraphur NU
2*a-uu-U Methyl parachion NU
Sto-JJ-2 Paratnion NU
2^a-u2-2 Pnorate w'D
Joay-24-5 Tccruechyldithlopyrophosphatc ND
GC
y<4-75-7 2,4- Uichiorophcnoxyacecic acid
VJ-7o-5 2,4,5-T
ND
NU
wU
-------
RESEARCH
LABORATORY
r
h.-P An.ilyiic.iJ
i iu: BT Jo 10 Pic ri
.jnulyzjd Dy mutuod
•P"rt
K. f)rdi>r
Mi'iiiuuy
00 K'
oUlO
/OOO
00 U
OUiO
6010
oOlo
OUlO
0010
OJ10
0010
uOiU
0010
0010
74/1
oOU
>j01U
00 10
//4U
OUlO
00 10
7641
0010
OUlO
Mt'luUJ
tCP/ALS
iCP/AtS
Uf'AA
ICF/AtS
ICP/AtS
ICF/AtS
ICF/ACS
lCF//U:S
ICP/AtS
ICP/AEb
ICP/AtS
iCF/ALa
ICP/AEo
ICF/AtS
CVAA
ICF/AtS
ICP/HtS
ICF/AtS
GrAA
ICP/AtS
ICP/AES
GFAA
1CP/AES
ICF/AtS
OMPUMi.i'T
Aluminum
Ancimony
Arsenic
D.irium
(lory lliun
Cacimiua
Calcium
Llir^jQiuia
Cobalt
Copper
Iron
Lead
Mcujnesium
Mang.mcbO
Mercury
Kickei
Osmium
FuCdssium
Selenium
Silver
Sodium
Tlialiiua
Vanadium
Zinc
UEThiCT. LIMIT
10.
12.
2.
2.
1.
1.
2.
I.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
c
-------
RESEARCH
LABORATORY
L-f An.iLyiic.ji K,'|>nri U.-r* ui.lor •( H/-U1-2 16-0 I A
vJu->L inner Lu: iH" Jo lu fit li
A iifjtcu .jur^e anJ trap moiUi ic.it ion ol Method a24U.
CA> K.J
I07-i8-o
1U7-1V-7
COMPONtNT
Allyl .iicohol
oxide
tthyi muthucrylate
Isoljutyi
2-Propyu-l-ol
SAMPLE
ND
nU
n'U
NO
NU
fcU
NU
Mectiud
for determination or Local and ameitaole cyanide.
CAS Kis
lUo-5t-4
CUHPONEiJT
SAMPLE
7ui2 ~
Metliud ^030 lor determination of suifide.
CAS
Sulliae
SAMPLE
5010.
Method 34U.-1 fluoride by distiiiatiou.
VA_S RN
COMPONENT
Fluoride
SAMPLE
.13
Mo is cure determination by Karl Fischer method.
COMPONENT
Moisture
SAMPLE
27. JX
-------
tAQLE^PKHER
RESEARCH
LABORATORY
r
Shirco Sample
T-2 (0-2) i ;/2
k.P .Sample fr'M7-()2-216-05A
C
C
-------
EAGLE l^p RICHER
RESEARCH
LABORATORY
t.-r An i I y i i r.. I K.'|MI-L W/UK or.-l.T it ft / -O I -2 I 'J-
LPA
NLillUO .S2/0
Ui'Cecrion IJ.TUC: 3D u",/:
io K.J
c
73-U3-0
IU/-1 J-l
02-53-J
65-83-0
iUo-51-4
10U-51-0
1U-81-7
101-55-3
31U-15-0
11J-75-8
91-30-7
95-57-8
IU7-U5-1
10Ubl-01-5
53-/U-3
95-50-1
lUo—4
NU
NU
ND
ND
ND
ND
NU
ND
ND
Nu
NJ
ND
Nli
ND
ND
NU
-------
eAGLEl^PKHER
RESEARCH
LABORATORY
c
uu-i 1 -/
57-V/-1.
i Iv-VJ-/
iU3-o7-
1 Jl-1 l-
Ul-U-2
bUo-2U-2
l22-ob-7
621-b4-/
1U/-12-U
2(Jb-44-u
do-7j-7
118-74-1
b7-oo-J
77-47-4
7U-JU-4
1688-/1-7
1^0-58-1
iOl-14-4
6U-62-0
91-59-tt
1JU-15-4
100-Ul-o
iuu-u^-7
/ , 12-Uina cliyiDcnzj. » j.mtur.Tcoiii.'
J , J'-uiraochylbenzid1 nt.'
i ,4-uiraettiy l|)lienol
Uincchyi plicnairtCe
4 ,o-uiuit ro-c^-cresoi
2 ,4-uinit rophunul
i ,4-L)inicrottjiuene
2 ,6-Uin.i.crocoluene
L)i-£-occyi
Uiphenyianine
1 , ^-Llipii
Di-_n-,>ropylnicrobamine
t.Lliyi cyanide
Fiuo rant hone
Kluorene
huxaciiloroDenzene
HexactUoruDutadiene
ticxactilorucyclopencadicne
Hoxact»iorodibcnzo-p_-aioxins
ilexuCiiiorodibenzofurans
hexaculorophenc
HexactUoropropene
hidenot i ,2 , J-cd jpyrene
Ibopnurone
Isosutruie
Mdioiiitrile '
meca-ui nitrobenzene'
Methacrylonicrile
Hechapynlenc
Metnylcliolanthrene
4 ,4'-tlethylcnebis( 2-chioro.iniline;
Mochyl methacryiate
Nccnyl mctnanesulronnce
2-MecnylnaptiCiiaiene
4-Methyi-2-peutanone
Naphthalene
1-NaphCliylaraine
^-Nupntnyiamine
1 ,4-Naphciioquinone
2-Nitroaniline
J-Nicroaniline
p_-Nitroaniltne
bo-JU-o
2-Mtrophenol
4-Nitropneuoi
^-iii trosodi-u_-niitylatnine
_N_-Ni trosodietuylaminc
^-isitrosudimecnylaminu
rosonu: ciiyieChyiaraine
NU
NU
NU
i\U
NU
NU
NU
ND
ND
ND
ND
ND
NU
ND
NU
ND
NU
NU
NU
NU
ND
i^U
NU
ND
NU
ND
ND
WD
NU
ND
NU
NU
-------
ON !-?'d<>jdojoTiPT(!-f' i-SUeJl
QN 3Uf»3nq-7-ojo'[ i|D to—*?' I -*>UPJ 3
ON jouPi|dojOTU3t'J33.T.-o' v' r' 7
ON
ON
QfJ UTXOIP
ON -H-nruaqipojoig3PJ3~i-fi'/T'7
ON
ON
OW
ON
ON
ON OpTUll'UOJ,} C-PC-OCAT7
OM
ON
no? i
ON
ON
OK'
ON
ON
ON'
ON
ON _
Of?
0'.'
-------
L^p RICHER
RESEARCH
LABORATORY
r
t.-lj Aii.iJyCiC.u .»<.|>nrt WOIK OrdVr -V 87-01 -I lt>-05A
Customer lu: iiT-2 (U-2) I rf.1
bW-tt<»6 Method »2*U
K.m>j«s: Low 1J.OUU to 50,000
Mod 3U,OUU to 200,000
Rii >200,000
CAS i\.J COMPUi.c.u'1 SAMPLE
b7-o4-l Acetone Mod
iu/-u^-o Acrolein ND
lll-yi-1 Bis(2-cnloroethoxy) methane NU
100-bu-i b.is(.2-cnloroisopropyl) ether NU
75-2/->* bromodictuoromoth.invi Nu
74-83-9 jjromoraechane NU
75-15-0 cai'Don aisulfide NU
5o-23-5 Carbon Tetracnioride NU
106-^0-7 Chlorooenzenc High
l24-44«s-l ChiorodiDroraomecnane NU
75-UU-3 Ctiloroecnane Low
07-bo-3 Cniorororm Hign
74-o7-3 Chlorometuane NO
y6-12-8 1,2-Uibromo-3-chloropropane NU
luo-f3-'» 1 ,2-Uioromoetlianc NU
74-95-3 Uibroraoraetnane NU
75-71-6 Uiclilorodif luoromeLhane ND
75-34-3 1,i-uicnioroethrtne Hign
lu7-Ob-2 1 ,2-Uichioroethane NU
/a-^3-4 1,1-uicnloroethyiene High
73-UV-2 uictiloronetiiane Med
78-07-4 1,2-Jiciiioropropane NJJ
luO-««l-4 ttiiyi uenzene NU
67-72-1 Hexacnloroetn.ine NO
3yi-7B-6 2-ticxanuiie iNU
/4-08-4 lodomethane ND
7a-^j-3 Methyl ethyl ketone NU
/b-Ol-7 fentachioroethane NU
I10-ttto-l fyridine NU
lou-w-5 Styrene High
o3u-2U-b 1,1,1 ,2-TetraciiloroiitlMne ND
7y-34-3 I,1,2,2-Ietrachloruethane ND
127-18-4 1'eiracnloroetncnc High
10e-ori-3 'ioluene High
Uo-oD-5 'ir.in.H-1 ,2-Dichioroctnane ND
75-^5-2 TriDroinometiiunc ND
7l-j5-o 1,1 ,1-Trichlorueui.iiie Med
79-OU-5 1,1,2- Tricnloroethjno ND
/V-Ol-o 11 iciiloroc'Llienu - High
75-fa9-4 Tnchloromonoi iuoromothane ND
'>o-ld-^ Trichloromi't haiiu NU
75-Ul-'* Vinyl cniorifle ND
133U-2U-7 Aylenu (toLai)
-------
iSJ) RICHER
RESEARCH
LABORATORY
- L-P Analytical import W.>rn urdi-r "• 67-U1-216-U5A
GC t'roctuurc «>08u, 815U, auu dt4u.
CAia KN
J09-UO-2
Jl 9-64-o
I2n>74-l 1-2
1 1 1U4-2S-2
11141-16-5
5j4o*-2l-9
l2t>72-29-b
1 lU9/-o'-J-l
1 1090-8^-5
Jl9-o5-7
57-74-9
72-54-6
72-55-9
iu-29-3
jj^-Bb-b
6U-3/-1
959-90-6
JJ21 J-65-9
/ 2-20-6
/421-93-4
36-69-9
76-44-a
1024-57-3
4oi-7j-o
14J-5U-0
72-43-5
6001-J5-2*
GC Procudure
297-97-2
29B-U4-4
D2-85-7
29d-UO-0
50-J6-2
290-U2-2
J669-24-5
GC froccrluro
94-75-7
9J-/0-5
yj-72-1
Cumpnuunt
Aldrfn
Alpaa-BilC
Arocior 1016
Arociur 1221
Arocior 1232
Arocior 1242
Arocior 1248
Arocior 1254
Arocior 1260
beCa-uuC
Chlordaue
UUU
L)UL
UUT
dcUa-firiC
Diciarin
Enao»uiian i
Ltiuosuiian 11
tndrin
Laarin aldeliyde
gamm.i-BHC
liopcacnlur
ne pea en lor epoxide
Isourin
uepone
Methoxychior
'i'nxaphene
6140
0,U-Uiechyi 0-2-pyrazinyl
Pnosphorocnioate
Uisuifoton
Famphur
Mecliyi parachion
Harathion
Phorate
Tocraetnyldictiiopyrophosphace
6150
2,4- bicliiurophenoxyacecic acid
2,4,5-T
Siiv^x
S.nmple
NJ
NU
NU
ND
NU
ND
NU
NU
ND
NU
ND
NU
ND
ND
ND
ND
NU
ND
2.3
ND
0.6
ND
NU
NU
NU
NU
NU
NU
ND
ND
NU
ND
ND
NU
NU
ND
ND
-------
EAGL
r
RESEARCH
LABORATORY
Custumer lu:
h-P Aiuiyiic.ii
-i (.U-2J 1 "2
Order # b7-')l-21b-05A
rinaiyzcd by mecuod fj
Nt'iUUUtf
OUIU
oulu
/UoU
oulu
oUiU
OUiU
oOiU
(>UtU
uUlV
oulu
oOiU
UUlU
oOiU
OUiU
74/1
oUiU
ouiu
OUIU
774U
oUiU
OOIU
7
iCP/Ata
Ch'AA
iCf/Ai.S
iCP/AES
iCtVAtb
ICP/AtS
ICf/Atb
ICH/Ati
ICP/rtLS
1CP/ALS
iCf//\tS
ILP/AES
iCP/Ata
CVAA
iLP/Atb
iLP/ALS
iCH/AtS
GFAA
iCP/AtS
ICP/AES
ot'/iA
1CP/ALS
iCPMtS
. COMPOivuNT
Aluminun
Antimony
Arsenic
uarium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Mauganubo
Mercury
Nickel
Osmium
Potassium
Selenium
silver
Sodium
Ttiailium
Vunauium
^inc
SAMPLE
462.
19.
DKTLCT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.U4
8.
20.
100.
1.
2.
2.
10.
4.
.02
C
-------
RESEARCH
L-C An.uyn.cil iu port Work Order >' J7-UI -2 1 1>-U5A
Cu3Lnin..r lu: uC-2 (U-2/ 1 ill
,\ uc'jced |'urjc olid Lfdp noji lie.' C toil til Mctiiorf H24U.
tab K» CUMPUnt.n;
iU/-io-() Aliyl .ticohui
/j-21-o ttuyiene oxid<; iJU
y/-bJ-2 tthyi raetlidcrylate NU
7a-dJ-l Isobutyi alcolioi NO
n-l-ui NU
yulO tor detdrmi nation or Local and amenable cyanide.
CAS K;; cu-iPuNLNT SAMP it:
'lUb-31-4 Cyanide <.U1U
Method ^030 tor determination or suitide.
CAb RN Cptlt'uNic.NT SAMPLE
152.
Hoc nod J4U.1 rluoride oy distillation.
CAS RN COMPUNENT SAMPLE
loytt4-4a-8 fluoride .13
MU Is cure determination by tne Karl Fischer method
SAMPLE
Moisture 27.62
-------
RESEARCH
LABORATORY
r
bni rco h'cod
For Sample local
iieaccu volatile* $ltf8.ou -40.00
Sciiuvoiaciics $500.00 **.JOO.OU
CuijrinaniU Hescicicles $115.00 $575.00
o-f fescicide^ $115.00 $575.00
fticuoxy rierbic .us $100.00 $500.00
$370.00 $l»50.00
$J5.00 $175.00
.ido $JO.OO $150.00
$25.00 $125.00
.ri-1-iihcr Moiscurc $25.00 $125.00
TOTAL b455.00
>r-»
C
-------
•AQLE^pPKHER
RESEARCH
LABORATORY
oiurco Sample
6rio/Uop )/149 Q
Sample tf»/-Ol-2io-02A
-------
RESEARCH
LABORATORY
.,-!' '.i i I . I 1 C
;> i r l
r
c
Ci is i oner. 1U:
LJ'.» SVJ-
/5-05-tf
yjj-ttu-2
1U/-1J-1
02-53-3
l/U-12-/
UO-57-u
2u;j-yy-2
30-32-tt
10U-51-0
ll/-bi-7
101-55-3
63-bd-/
10b-47-b
510-15-0
llJ-75-« •
9 5-.3 7-a
/U03-/2-3
1U7-J5-1
lOOol-Oi-5
5J-/0-3
132-04-*
04-74-2
341-/J-1
y5-50-l
V4-73-/
MliTilOj S2/0
COMPUNLNi;
AeenH|>utlid If ne
Ace Loiiit rile
AceLoplicnone
2-Acttylaninuiluorene
Aery Lonitrile
Alpha.ciiph.i-uimetnyipheneLhyiarainc
Aniline
rtiitlir.iccnt;
/vrdinite
iz [.i jatithr.icenc
benzidine
licnzo I o j 1 iuoroiithene
lieniiu [ K 11 luorantheiie
Kenzoic acid
^-benzoquinone
flenzoC^hiJperyiene
benzolJ Jpyrene
benzyl alcoliol
lii&(2-t:tnylhexyi>phtliaiate
4-Bromophcnyl plienyl ether
Duty! benzyl pnuiialate
£-Chlorouniline
Chloruuenzilate
jv-(-hloro-m-cresoi
2-CliloroeLhyi vinyl ether
2-Cnloruiia|jlitnaiene
4-Chioropnenyi pheuyi ether
3-Chioropropcne
Chrysene
cis-1,3-Uichioropropene
Dioenzla.hjanthraceue
Uibenzoturan
Dibon^oI a,e]pyrene
Dibenzol a,hjpyrene
uibenzol a,iJ^yrene
l)i-n-outyl pliciialrtte
m-Uichlorobenzene
£-Uicuiorooenzone
£-UichloroL»enzene
3 ,3'-Uiciiiorobcnzidine
2 ,b-UictiiL>n>|)i>enol
2 ,4-Uichloro|)hcnuxy.iCctic
•r '/ rf/'-02- 12 J-U2A
>j_ LCCC HIM I liiii ; 3t) ur,/4
NU
ND
NU
NU
ND
NU
ND
NU
NU
ND
ND
ND
ND
i.D
ND
ND
NU
NU
NU
f.U
NU
ND
430
ND
ND
ND
NU
ND
ND
NU
NU
ND
NU
NU
NU
NU
ND
ND
-------
•AQLEL3J) RICHER
RESEARCH
LABORATORY
Ll'A .».-,,"'tu ili.IllOU U//0
oU-ll-/'
Ui-il-J
5J^t-l)2-l
5J-/«-5
121-jH-z
6UO-/U-2
122-00-/
o2i-t>4-/
1U/-12-U
oo-7j-y
ile-74-i
d/-oa-J
/ 7-47-4
7U-3U-4
l{J<5B-/l-7
lyj-jy->
7tJ-5y-l
12U-5B-1
1UV-77-J
1UO-23-4
•^l-eu-5
:>o-4y-5
1U1-14-4
oO-o2-o
OD-2/-3
Vi-57-0
1U8-1U-1
91-20-3
134-32-7
*i-5y-d
130-15-4
ttb-74-4
yy-05-2
10o-01-fa
yti—#5-3
«»-O-5
1UO-U2-7
So-30-o
_^-iji.-ncLliyi.imi
/ , l2-Jim«diyi!
J, J'-ji.nccliylDenzicUne
Z ,A-L)iineLtiylpiicuji
Uirat: thy! phch.,l:ici'
2 ,4-Oinitrophunol
2. ,4-JiruLrDColiieni;
^ ,0-Uinicrotolucne
Ui-n_-uctyi pncluilrice
UipTicnylamine
I ,2-uiphenyiiiyurcizino
Di-n-pro|jyinicros.>minc
Ltnyl cyanide
Kiuoranchene
l-'Luoronc
ilRxachiorobutauieii*;
Huxactilorocyc lupencddiene
tiexaCiiloroclibenzo-£-ciioxJ.ns
Hexacluorodibenzofurans
cexaciiioropropene
iudeno( 1 ,2, J-cd)|)yrcne
Isopnorone
laosutrolc
Nalonicrile
neca-Dinicro bonze no
Mechacrylonicriie
Meciiapyriieiie
Nectiyiciioianthreau
4 ,4'-Mechylfne£)is(2-chloronniiine)
Mechyi mocnacrylatc
Mecnyl raechnnesuU'on.ice
2-HeCaylndphciialt«nc
4-ileCnyl-2-pentanone
Naphthalene
1-Napncnylaraine
2-Naphchylaminu
l ,4-Naphthoquinono
2-Nicroaniiine
3-Nitroanilinc
£-Nitroaniline
Nitrobenzene
2 -Nitro phenol
4-ivicrophenoj.
c
iN-..itrosomutiiylcthylamine
^-Nitrosomorpnoline
Nu
No
NO
Nl)
HD
NO
NU
ND
NO
N'U
iJU
NU
ND
NU
ND
NJ
ND
NU
NU
NU
HU
Nu
ND
NU
NU
NU
NU
NU
ND
NU
ND
NU
ND
ND
NU
ND
ND
NU
ND
NU
NU
NU
NU
NU
ND
ND
NU
ND
ND
-------
EAGLE L3J> RICHER
RESEARCH
LABORATORY
r
MLTiiOU rt270
CUMPlMbNi"
1UU-75-4
»JO-b:>-2
N-.»icrosopiperidinc
C
b/-bci-8
o7-do-5
02-44-2
03-Jl-ti
lua-9i-2
JUtf-46-J
l74h-UJ-o
11U-5/-6
10Uoi-U2-b
12U-82-1
7 5-70- /
^3-yi-A
S&-U6-2
y3-/o-5
120-72-/
urcho-Crcsni
para-Cresoi
Pencjchiorotxiiizcnc
Pentachiorodibcn^o-j^-dioxins
PcnLdchiorodibenzofurjns
Pontachioronitrohcnzcne
Pcnc.ichJornpnen ji
Hticnacctin
Phenantnriinf
Pnenoi
2-Picoiine
Pron.imide
fyrcne
Kesorcinol
S^.rrole
2-soc-ttutyi-4,o-dinitrophenoI
| ,2,4,5-ItitrachioroDonzene
2 ,3,7 ,B-TeCracniorudAoenzo-£-
dioxin
TatrachlorodiDcnzo-£-dioxins
Tecracnlorodibenzoxurans
2,3,4,b-Tetrachiorophenol
tra)is-l ,4-Uichloro-2-buteno
Crans-i ,3-uicniuropropcne
1 ,2 ,4-Tri.chiorooen?:one
TriciUoromechaneLhiol
2,4,b-Trictiior<>|)iienol
2 ,4,b-'irichiorophenol
2,4,5-T
Iris-(.2 ,3-aiDromopropyl)phosptiace
Nl)
NO
NU
NU
NL)
ND
ND
NU
NU
rtD
NU
160
NU
.\D
KU
NU
NU
wl)
NU
wU
NU
NO
NU
NU
Nu
370
3'j(J
NU
NU
WD
NU
NU
Nu
C
-------
RESEARCH
LABORATORY
" L-H An.ilyt ic.il K^n^rt v.\.n. Order ./ ,S/-u I-2 I h-02,\
Cu-.Coi.n-r iu: brio/UUP 14* y
S'.J-a-«ii ,'letnud «240
u-.n^cs-: Low 10,000 co 50,000
Hod 5U.UUU to 2UU.OUO
Uijjh >200,UOU
CaS
o7-t)4-t Acetone Mcd
1U/-U2-8 Acroicin ND
Hl-Vi-i Bis»,2-clilorueCtLOxy; methane NO
111-U4-4 tJi3( 2-chloroccnyl) eciier NU
10a-bU-l ttis(2-ciuoruisopropyl) ether NO
//3-27-4 tor.jmodichiorometnane NO
74-t5J-y aromomethane NU
73-15-0 Cciroon disult'ide wO
56-2J-3 Curbon Tetracnloride ND
^U-/ Chiorobenzene High
•*<}-{ Cnlorodi ororaometliane NO
75-uu-J Caluroechane Nu
o7-oo-J Cnlorororm Hign
74-S/-J Uiiorometliune NU
Vb-12-a 1,2-Oibrorao-3-chLoropropaue NU
iOo-yj-4 1,2-oibronoethane ND
/4-V5-J Dibromomethane ND
75-71-8 Uichlorodifluoromethane NU
/5-J4-J 1,1-jichioroethane Hi^h
lu7-uo-2 1 ,2-Oiciiluroechane Hi^li
75-J5-4 1,1-Dichloroechylenc High
73-u*-2 Ijichioromethaae ND
78-e/-4 I ,2-iJichlorcH>ropan«i ND
luu-41-4 t-tnyi benzene ttigh
67-72-1 ilexacnloroeth.ine NO
3*1-78-0 2-rtexanone NO
M-o
-------
L^p RICHER
s
C
RESEARCH
LABORATORY
OC Procedure
CA^ KN
309-00-2
.J19-64-b
Uo74-ll-2
11 104-26-2
11141-lb-5
5340V-21-9
12b72-29-b
1 1U97— b9-l
1 109b— 8^-5
319-35-7
i7-74-9
72-54-8
/2-S5-9
50-2^-3
319-6b-8
oO-57-l
959-96-8
332i3-u5-9
'/ 2-20-8
7421-93-4
38-8*-9
7b-4*»-8
1024-57-3
4o5-73-b
143-50-0
72-4 j-3
8001-35-2
OC Procedure
297-*7-2
2*B-U<*-4
52-85-7
290-UO-O
5b-38-2
2*a-u2-2
3b69-24-5
94-75-7
93-/0-3
93-72-1
t-P AnjiyCic.il kcpuri Work
^u/JUP 14. Q
6O80, 6150, and 8140.
Component
Aidrin
Aipua-BHC
Aroclor I0i6
Arocior 1221
Arocior 1232
Aroclor 1242
Arocior 124B
Arocior 1234
Arocior 12bO
bcCa-litlC
Cniord.ine
1JUU
DDL
UUT
delca-dilC
Uieldrin
Endosullan I
tndosuliun il
End r in
end r in aldehyde
gciram.i-UuC
ttupcuchlor
Hupcachlor epoxide
Isodrin
Kepone
MeLhoxychlor
Toxaphcne
8140
0,0-Uicthyl 0-2-pyrazinyl
PhosphorochioaCe
Uisultocon
Famphur
Mecnyi parachion
ParaCnion
Phorace
Tetrauchyidithiopyrophosphace
815U
2,4- UichlorophenoxyacetJ.c acid
2,4,5-T
Silvcx
Ord<.-r •'/ 8
Stimplc
11.6
tNU
NU
NU
NU
Nb
wu
NU
NU
NU
NU
NU
NU
NO
NU
NU
NU
i\'D
8.32
NO
19. 7
NU
ND
NO
NU
NU
Nu
NU
NO
NO
NU
NU
NO
NO
NU
NU
NU
-------
E-P Analytical Report Work Order * 37-02-130-01A
Customer 10: Pie J Waste Feed Run #1
GC Procedure 8080, 8150, and 8140.
mg/Kg
CAS RN
309-00-2
319-S4-T6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-35-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
ODE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
gamma-BHC
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Hethoxychlor
Toxaphene
GC Procedure 8140
297-97-2 O.OrDiethyl 0-2-pyraxinyl <1.0
Phosphorothioate
298-04-4 Oisulfocon <0.33
52-85-7 Fa«phur O.3
298-KJO-O He thy 1 parathion <0.33
56-38-r2 Parathion <0.33
298-02-2 Phorate <1>6
3689-24-5 Tecraethyldithiopyrophosphate <1.0
GC Procedure 8150
94-75-7 2,4- Dichlorophenoxyacetic acid <0.5
93-76-5 2,4,5-T <0.1
93-72-1 Silvex <0.1
-------
EMLElf°>PKHER
AESC4ACH
LABOMTOfTf
E-P Analytic*! Report Work Order * 87-02-130-OlA
Customer ID: Pit J Waste Feed Run #1
Metals analyzed by method given.
METHOD*
601U
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanad : urn
Zinc
SAMPLE
26,000.
<12.
<50.
<2.
<1.
<1.
1290.
25.
<10.
271.
12,700.
<20.
4930.
223.
<0.04
13.
<20.
5130.
<100.
<2.
511.
<2.
40.
38.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
1.
2.
2.
2.
10.
4.
-------
ACSEAACH
E-P Analytical Report Work Order t 87-02-130-01A
Customer ID: Pic J Waste Feed Run #1
A heated purge and trap modification of Method 8240.
mg/Kg
CAS RN COMPONENT
107-18-6 Allyl alcohol
542-76-7 3-Chloropropionitrile
123-91-1 1,4-Dioxane
75-21-8 Ethylene oxide
97-63-2 Ethyl methacrylate
78-d3-l Isobutyl alcohol
107-19-7 2-Propyn-l-ol
Method 9010 for determination of total and amenable cyanide*
CAS RN
106-51-4
COMPONENT
Cyanide
SAMPLE, ug/g
<0.01
Method 9030 for determination of sulfide.
CAS RN
COMPONENT
18496-25-8 Sulfide
SAMPLE, ug/g
8420.
Method 340.1 Fluoride by distillation.
CAS RN
COMPONENT
16984-r48-8 Fluoride
SAMPLE, ug/g
.30
Moisture determination by Karl Fischer method. ( Z )
COMPONENT
Moisture
SAMPLE, wt. Z
21.4
ND**Notninal Detection Limit»<50. mg/Kg
-------
ftCSEAACH
LABORATORY
E-P Analytical Report Work Order 1 87-02-130-03A
Customer ID:Pic I Waste Feed Run 11
SW-846 Method 8240
CAS R:I
67-64-1
107-02-3
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
73-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT SAMPLE
Acetone <1.0
Acrolein ND*
Benzene <0.50
Bis(2-chloroechoxy) methane <20.
Bi«(2-chloroethyl) ether <20.
Bis(2-chloroisopropyl) ether <20.
Bronodichloromethane <0.50
BromomeChane <1.0
Carbon disulfide 2.5
Carbon Tecrachloride 34.
Chlorobenzene <0.50
Chiorodibrononethane <0.50
Chloroethane <1.0
Chloroform <0.50
Chlororaechane <1.0
l,2-Dibromo-3-chloropropane ND*
1,2-Dibromoechane ND*
Dibromomethane ND*
Dichlorodifluororaethane ND*
1,1-Diehloroechane <0.50
1,2-Dichloroethane 8.3
1,1-Dichloroethylene ' <0.50
Dichlororaethane <0.50
1,2-Dichloropropane ND*
Ethyl benzene 10.
Hexachloroechane <20.
2-Hexanone <1.0
lodorae thane ND*
Methyl ethyl ketone <1.0
Pentachloroethane ND*
Pyridine ND*
Styrene <0.50
1,1,1,2-TeCrachloroechane ND*
1,1,2,2-Tecrachloroechane <0.50
Tetrachloroethene <0.50
Toluene 1.5
Trans-1,2-Dichloroethene <0.50
Tribromonethane <0.50
1,1,1-Tri.chloroe thane <0.50
1,1,2- Trichloroechane 12.
Trichloroechene <0.50
Trichloromonofluoromethane <0.50
Trichloropropane ND*
Vinyl chloride <1.0
Xylene (Cotal) <0.50
ND*"Norainal Detection Liraic«<50. rag/Kg
-------
RICHER
E-P Analytical Report Work Order i 87-02-130-03A
Cuatoner lD:Pit I Watte Feed Run
EPA SW-846 METHOD 8270
Detection liait:
CAS RN COMPONENT
208-96-8 Acenaphthalene
83-32-9 Acenaphthene
75-05-8 Acetonitrile
98-86-2 Acetophenone
53.95.3 2-Acetylaminofluorene
107-13-1 Acrylonitrile
122-09-8 Alpha,alpha-dimethyIphenethyIaraine
92-67-1 4-Aainobiphenyl
62-53-3 Aniline
120-12-7 Anthracene
140-57-8 Araraite
56-55-3 Benz[a]anthracene
108-98-5 Benzenethiol
92-87-5 Benzidine
205-99-2 Benzolb]fluoranthene
207-08-9 Benzolk]fluoranthene
65-85-0 Benzoic acid
106-51-4 £-Benzoquinone
191-24-2 Benzo(ghi)perylene
50-32-8 Benzo[a]pyrene
100-51-6 Benzyl alcohol
^7.51.7 Bi§(2-ethyIhexyl)phthalate
101-55-3 4-Bronophenyl phenyl ether
85-63-7 Butyl benzyl phthalate
106-47-8 £-Chloroaniline
510-15-6 Chlorobenzilate
126-99-8 2-Chloro-l,3-butadiene
59^50-7 £-Chioro-m-crtaoi
110-75-8 2-ChloroeThyl vinyl «th«r
91-58-7 2-Chloronaphthalene
95-57-8 2-rChlorophenol
7005-72-3 4-Chlorophenyl phenyl ether
107-05-1 3-rChloropropene
218-01-9 Chryaene
10061-01-5 cia-rl,3-Dichioropropene
53-70-3 Dibenz(a,h)anthracene
132-64-9 Dibenzofuran
192-65-4 Dibenzo(a,elpyrene
189-64-0 Dibenzo[a,h|pyrene
189-55-9 Dibenzo[a,ijpyrene
84-74-2 Di-n-butyl phthalate
541-73-1 a-oTchlorobenzen*
95-50-1 o-Dichlorobenzene
106-46-7 £-Oichlorobenzene
91-94-1 3,3'-Dichlorobenzidine
ND*-Nominal Detection Limit-<50. ag/K|
-------
EAGLE
RESEARCH
LA0OJU7OAY
E-P Analytical Report Work Order * 87-02-130-03A
EPA SW-846 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <20.
87-65-0 2,6-Dichloroph«noi ND*
94-75-7 2,4-Dichlorophenoxyacetic acid ND*
84-66-2 Die thy1 phthalacK <20.
119-90-4 3,3'-Diaethoxybenzidine ND*
60-11-7 £-Diraethylaminoazobenzene ND*
57-97-6 7,12-Diraethylbent[a]anthracene ND*
119-93-7 3,3'-Dimethyibenzidine ND*
105-67-9 2,4-Diaethylphenoi <20.
131-11-3 Dimethyl phthalate ND*
534-52-1 4,6-Dinitro-o-cretol <100.
51-28-5 2,4-DinitropKenol <100.
121-14-2 2,4-Dinitrotoluene <20.
606-20-2 2,6-Dinitrotoluene <20.
117-84-0 Di-£-octyl phthalate <20.
122-39-4 Diphienylamine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-£-propylnitro»araine <20.
107-12-0 Eth7l cyanide ND*
206-44-0 Fluoranthene <20.
86-73-7 Fluorene <20.
118-74-1 Hexachlorobenzene <20.
87-68-3 Hexachlorobutadiene <20.
77-47-4 Hexachlorocyclopentadiene <20.
Hexachlorodibenzo-£-dioxins ND*
Hexachlorodibenzofurans ND*
70-30-4 Hexachlorophenc ND*
1888-71-7 Hexachloropropene ND*
193-39-5 Indeno(l,2,3-cd)pyrene <20.
78-59-1 Isophorone <20.
120-58-1 Iso«a£role ND*
109-77-3 Malonitrile ND*
100-25-4 BCta-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
101-rl 4-4 4,4'-Methylenebia(2-chloroaniline) ND*
80-62-6 Methyl aethacrylate ND*
66-27-3 Methyl nethanesulfonate ND*
91-J57-6 2-Methylnaphthaiene <20.
108-10-1 4rMethyl-2-pentanone <1.0
91-20-3 Naphthalene <20.
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 ' 1,4-Naphthoquinone ND*
88r74-4 2-Nitroaniline <100.
99-09r2 3-Nitroaniline <100.
100-01-6 £-Nitroaniline <100.
98-95-3 Nitrobenzene <20.
88-75-5 2-Nitrophenol <20.
ND*»Norainal Detection Limit-<50. rag/Kg
-------
ftCSCAftCM
LABORATORY
E-P Analytical Report Work Order * S7-02-130-03A
EPA SU-846 METHOD 8270
CAS RN COMPONENT
100r02-7 4-Nitrophenol
924-16-3 £-Nicroaodi.-£-butylaraine
SS-13-S ^rNitrosodie'chylanine
62-75-9 ^-Nitroaodimethylamine
86-30-6 £-Nitro§odiphenylamine
10S9S-9S-6 ][-Nitrotoraethyl«thylamine
S9-89-2 ft-Nicrotomorpholine
100-75-4 ^-Nitroaopiperidine
930-55-2 £-Nitrotopyrrolidine
99-55-8 5-Nitro-o-toluidine
95-48-7 ortho-Creiol
106-44-5 para-Cresol
608-93-5 Pentachlorobenzene
Pencachlorodibenzo-£-dioxins
Pentachlorodibenzofurans
82^68-8 Pentachloronitrobenzene
87-86-5 Pencachlorophenol
62-44-2 Phenacetin
85-01-8 Phenanchrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-58-5 Pronamide
129-00-0 Pyrene
108-46-3 Resorcinol
94-59-7 Safrole
88-85-7 2-tec-Butyl-4,6-dinitrophenol
95-94-3 1,2,4,5-Tetrachlorobenzenc
1746-01-6 2,3,7,8-Tetrachlorodibenzo-£-
dioxin
Tecrachlorodibenzo-£-dioxini
Tetrachlorodibenzofurana
58-90-2 2,3,4,6-Tecrachlorophenol
110-57-6 tran«-l,4JDichloro-2-buCene
10061-02-6 tran»-l,3-Dichloropropene
120-82-1 • 1,2,4-Trichlorobenzene
75-T70-7 . Trichloromechanethiol
95-95-4 2,4,5-Trichlorophenol
88-06-r2 2,4,6-Trichlorophenol
93-76-rS 2,4,5-T
126-72-7 Tria-(2,3-dibroaopropyl)phosphaC«
ND*-Nominal Detection Limit"<50. ng/Kg
-------
ACSEAACH
LABORATORY
PKHER
E-P Analytical Report
Cu*toner ID: Pic I Waste Feed Run #1
CC Procedure 8080, 8150, and 8140.
Work Order * 87-02-130-03A
mg/Kg
CAS RN
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-35-7
57-74-9
72-54-8
72-T55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-^9
72-20-8
7421-93-4
58-39-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beta-atiC
Chlordane
ODD
ODE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
gamma-BHC
Heptachlor
Heptachlor epoxide
laodrin
Kcpone
Methoxychlor
Toxaphene
CC Procedure 8140
297-97-2 0,0-Diethyl 0^2-pyraxinyl <1.0
Phosphorothioate
298-04-4 DUulfoton <0.33
52-85f7 Faaphur <3.3
298-fOO-O Methyl parathion <0.33
56-38-2 Parathion <0.33
298-02-2 Phorate <1.6
3689-24-5 TeCraethyldithiopyrophosphate <1.0
CC Procedure 8150
94-75-7 2,4- Dichlorophenoxyacetic acid <0.5
93-76-5 2,4,5-T <0.1
93-T72-1 Silvex <0.1
-------
E-P Analytical Report Work Order f 87-02-130-03A
Customer ID: Pit I Waste Feed Run #1
Metals analyzed by method given.
mg/Kg
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
SodiiaB
Thallium
Vanadium
Zinc
SAMPLE
20,200.
<12.
<50.
IS.
<1.
<1.
1900.
27.
17.
490.
15,300.
<20.
3380.
242.
<0.04
19.
<20.
3800.
<100.
<2.
873.
<2.
33.
46.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2'.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
1.
2.
2.
2.
10.
4.
-------
iAQLEL^PKHER
RESEARCH
LABORATORY E"p Analytical Report Work Order * 87-02-130-03A
Customer ID: Pit I Waste Feed Run ?1
A heated purge and trap modification of Method 8240.
•g/Kg
CAS RN COMPONENT
107-18-6 Allyl alcohol
542-76-7 3-Chloropropionitrile
123-91-1 1,4-Oioxane
75-21-8 Ethylene oxide
97-63-2 Ethyl methacrylate
78-83-1 Isobutyl alcohol
107-19-7 2-Propyn-l-ol
Method 9010 for determination of total and amenable cyanide.
CAS RN COMPONENT SAMPLE, ug/g
106-51-4 Cyanide <0.01
Method 9030 for determination of sulfide.
CAS RN COMPONENT SAMPLE, ug/g
18496-25-8 Sulfide 841.
Method 340.1 Fluoride by distillation.
CAS RN COMPONENT SAMPLE, ug/g
16984-48-r8 Fluoride .17
Moiature determination by Karl Fischer method. ( X )
COMPONENT SAMPLE, wt. Z
Moisture 24.9
ND*"Nominal Detection Limita<50. mg/Kg
-------
PKHER
E-P Analytical Report
Customer ID:Pit M Waste Feed Run #2
SW-846 Method 8240
Work Order # 87-02-130-06A
CAS SN
67-64-1
107-02-3
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-43-1
75-00-3
67-66-3
74-37-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74^88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
75f01-4
1330-20-7
mg/Kg
COMPONENT SAMPLE
Acetone <1.0
Acrolein ND*
Benzene <0.50
Bis(2-chloroethoxy) methane <20.
Bis(2-chloroethyl) ether <20.
Bis(2-chloroisopropyl) ether <20.
Bromodichloromethane <0.50
Bromoraethane <1.0
Carbon disulfide 0.52
Carbon Tetrachloride 40.
Chlorobenzene 1.8
Chlorodibroaomethane <0.50
Chloroethane <1.0
Chloroform 1.5
Chloromethane <1.0
1,2-Dibromo-3-chloropropane ND*
1,2-Dibroooe thane ND*
Dibromomethane ND*
Dichlorodifluoromethane ND*
1,1-Dichloroethane 0.92
1,2-Dichloroethane 32.
1,1-Dichloroethylene 1.6
Dichloromethane <0.50
1,2-Dichloropropane ND*
Ethyl benzene 7.4
Hexachloroethane <20.
2-Hexanone <1.0
lodouM thane ND*
Methyl ethyl ketone <1.0
Pentachloroethane ND*
Pyridine ND*
Styrene 4.7
1,1,1,2-Tetrachloroethane ND*
1,1,2,2-Tetrachloroethane 2.3
Tecrachloroethene 2.3
Toluene 0.89
Tran«-l,2-Dichloroethene 2.6
Tribromomethane <0.50
1,1,1-Trichloroethane <0.50
1,1,2- Trichloroethane 71.
Tr ichloroe thene 1.8
Trichlorooonofluorooethane <0.50
Trichloropropane ND*
Vinyl chloride <1.0
Xylene (total) <0.50
ND*-Nominal Detection Limit-<50. mg/Kg
-------
ftESEAACM
LABOMTOtTf
E-P Analytical Report Work Order # 87-02-130-06A
.Cu«Comer IO:PiC H W««te Feed Run *2
EPA SW-846 METHOD 8270
Detection limit:
CAS RN
208-96-8
83-32-9
75-05-8
98-86-2
53-96-3
107-13-1
122-09-at
92-67-1 \
62-53-3
120-12-7
140-57-3
56-55-3
108-98-5
92-87-5
205-99-2
207-08-9
65-35-0
106-:51-4
191-24-2
50-32-S
100-51-6
117-81-7
101-55-3
85-68-7
106-47-8
510-15-6
126-99-8
59-50-7
110-75-8
91-53-7
95-57-8
7005-72-3
107-05-1
218-01-9
10061-01-5
53-70-3
132-64-9
192-65-4
189-64-0
189-55r9
84-74-2
541-73-1
95-50-1
106-46-7
91-94-1
COMPONENT
Acenaphthalene
Acenaphthene
Acetonitrile
Acetophenone
2-Acetylaoinofluorene
Aery Ion it rile
Alpha,alpha-diaethylphenethyl«raine
4-Aninobiphenyl
Aniline
Anthracene
Ar amice
Benz[ a] anthracene
Benzene thiol
Benridine
Benzo[b] fluoranthene
Benzo[k] £ luoranthene
Benzoic acid
£-Benzoquinone
Benzo(ghi)perylene
Benzo[a]pyrene
Benzyl alcohol
Bi§(2-echylh«xyl)phthalate
4-Bronophenyl phenyl ether
Butyl benzyl phthalate
£-Chloroaniline '
Chlorobenzilate
2-Chloro-l,3-butadiene
£-Chloro-m-cresol
2-ChloroeThyl vinyl ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenyl phenyl ether
3-Chloropropene
Chrysene
ci«-l , 3-Dichloropropene
Dibenr [a, h] anthracene
Dibenzofuran
Dibenzo[a, ejpyrene
Dibenzo[a,h] pyrene
Dibenzo[a,i jpyrene
Di-ii-butyl phthalate
m-Dichlorobenzene
£-Dichlorobenzene
£-Dichlorobenzene
3,3'-Dichlorobenzidine
ND*
ND*
ND*
<20.
<20.
ND*
<20.
ND*
<100.
<20.
<20.
<100.
ND*
<20.
<20.
<20.
<20.
<20.
<20.
<20.
ND*
ND*
<20.
<1.0
<20.
<20.
<20.
ND*
<20.
<0.5
<20.
<20.
ND*
ND*
ND*
<20.
<20.
<20.
<20.
<40.
ND*"Noainai Detection Limit"<50. Bg/Kg
-------
E-P Analytical Report Work Order * 87-02-130-06A
EPA SU-846 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <20.
37-65-0 2,6-Dichlorophenol NO*
94.75.7 2,4-Dichlorophenoxyacetic acid NO*
84-66-2 Diethyl phthalatt <20.
119-90-4 3t3'-Dimethoxybenzidine ND*
60-11-7 £-Diraethylaminoazobenzene NO*
57-97-6 7,12-Diaethylbenz[a]anthracene ND*
119-93-7 3,3'-Dimethylbenzidine ND*
105-67-9 2,4-Diaethylphenol <20.
131-11-3 Dimethyl phthalate <20.
534-52-1 4,6-Dinitro-£-cresol <100.
51-28-5 2,4-Dinitrophenol <100.
121*rl4-2 2,4-Dinitrotoluene <20.
606-20-2 2,6-Dinitrotoluene <20.
117-84-0 Di-ri-octyl phthalate <20.
122-39-4 Dipbienylamine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-n-propylnitrosamine <20.
107-12-0 Ethyl cyanide ND*
206-44-0 Fluoranthene <20.
86-73-7 Fluorene <20.
118-74-1 Hcxachlorobenzene <20.
87-63-:3 Hexachlorobutadiene <20.
77.47-4 Hcxachlorocyclopcntadiene <20.
Hexachlorodibenzo-£-dioxin« ND*
Hcxachlorodibenzofurans ND*
70-30-4 Hexachlorophene ND*
1888-71-7 Hexachloropropen* ND*
193-39-5 Indeno(l,2,3-cd)pyrene <20.
78-59-1 laophorone <20.
120-58rl Isoiafrole ND*
109-77-3 Malonitrile ND*
100-25-4 ••ta-Dinitrobenzcne ND*
126-98-7 Methacryionitrile ND*
91-80-5 ttethapyrilene ND*
56-49-5 Methylcholanthrene ND*
101-14-A 4,4'-Methylenebii(2-chloroanilin«) ND*
80-62-6 Methyl methacrylate ND*
66-27-3 Methyl methanesulfonate ND*
91-57?6 2-Methylnaphthalene <20.
108-10-1 4-Methyl-2-pentanone <1.0
91-20-3 Naphthalene <20.
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone <100.
88-74-4 2-Nitroaniline <100.
99-r09-2 3-Nitroaniline <100.
100-01-6 £-Nitroaniline <100.
98-95-3 Nitrobenzene <20.
88r75-5 2-Nitrophenol <20.
ND*-Nominal Detection Limit-<50. mg/Kg
-------
RICHER
WESEAACH
LABORATORY
E-P Analytical Report Work Order t 87-02-130-06A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
100-02-7 4-Nitrophenol
924-16-3 N-Nitrotodi-n-buCylamine
55-18-5 ii-Nitrosodie'chylaaine
62-75-9 £-Nitrosodimechylaaine
86-30-6 ]<-Nicro«odiphenylaaine
10595-95-6 £-Hitrosom«thylethylaaine
59-89-2 ^-riicrosomorpholine
100-75-4 £-Nitrosopiperidine
930-55-2 ^-Nicrosopyrrolidine
99-55-8 T-Nicro-o-coluidine
95-48-7 ortho-Cretol
106-44-5 para-Cresol
608-93-5 Pencachlorobenzene
PenCachlorodibenzo-£-dioxins
Pentachlorodibenzofurans
82-68-8 Pentachloronitrebenzene
87-86-5 Pencachlorophtnol
62-44-2 Phenacecin
85-01-8 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-58-5 Pronamide
129-00-0 Pyrene
108-46-3 Resorcinol
94-59-7 Safrole
88-85-7 2-«ec-Butyl-4,6-dinitrophenol
95-94-3 1,2,4,5-Tecraehlorobenzene
1746-01-6 2,3,7,3-Tetrachlorodibenzo-£-
dioxin
Tetrachlorodibenzo-£-dioxin*
Tecrachlorodibenzofuranl
58-90-2 2,3,4,6-Te trachloropheno1
110-57-6 tran«-l,4-Dichloro-2-butene
10061-02-6 Crana-1,3-Dichloropropene
120-82-1 1,2,4-Trichlorobenzene
75-70-7 Trichloronechanechiol
95-95-4 2,4,5-Trichlorophenol
88t06-2 2,4,6-Trichlorophenol
93-76-5 2,4,5-T
126-72-7 Trii-(2,3-dibroaopropyl)phoaphaCe
ND*«Noninal Detection Limit-<50. mg/Kg
-------
LABORATORY
E-P Analytical Report Work Order * 87-02-130-06A
Customer ID: Pic M Waste Feed Run *2
CC Procedure 8080, 8150, and 8140.
mg/Kg
CAS RN
309-00-2
319-84-6
12674-11-2
11104-23-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-35-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-^98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
ALpha-BllC
Aroclor 1016
Aroelor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beca-BHC
Chlordane
ODD
DOE
DDT
d«Ua-BHC
Dieldrin
Endotulfan I
Endosulfan II
Endrin
Endrin aldehyde
gaaoa-BHC
Hepcachlor
Hepcachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
CC Procedure 8140
297-97-2 0,0-Diechyl 0-2-pyra*inyl <1.0
PhosphoroChioate
298-04-4 Diiulfoton <0.33
52-85-7 Faaphur <3.3
298-00-0 Methyl parathion <0.33
56-38-2 Parathion <0.33
298-02-2 Phorate
-------
PKHER
RESEAACH
LABORATORY
E-P Analytical Report Work Order * 87-02-130-06A
Customer ID: Pit M Waste Feed Run #2
Metals analyzed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chroaium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
SAMPLE
35,100.
<12.
<50.
19.
<1.
<1.
3280.
34.
11.
62.
17,300.
<20.
4660.
170.
<0.04
18.
<20.
5870.
<100.
<2.
348.
<2.
93.
42.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
1.
2.
2.
2.
10.
4.
-------
RKIARCH
E-P Analytical Report Work Order t 87-02-130-06A
Customer ID: Pit M Waste Feed Run #2
A heated purge and trap modification of Method 8240.
ag/Kg
CAS RN COMPONENT SAMPLE
107-18-6 Allyl alcohol NO*
542-76-7 3-Chloropropionitrile ND*
123-91-1 1,4-Dioxane ND*
75-21-8 Ethylene oxide ND*
97-63-2 Ethyl aethacrylate ND*
78-83-1 Isobutyl alcohol ND*
107-19-7 2-Propyn-l-ol ND*
Method 9010 for determination of total and amenable cyanide.
CAS RN
106-51-4
COMPONENT
Cyanide
SAMPLE, ug/g
<0.01
Method 9030 for determination of tulfide.
CAS RN
COMPONENT
18496-25-8 Sulfidc
SAMPLE, ug/g
4880.
Method 340.1 Fluoride by distillation.
CAS RN
COMPONENT
16934-48-8 Fluoride
SAMPLE, ug/g
.08
Moisture determination by Karl Fischer method. ( Z )
COMPONENT
Moisture
SAMPLE, we. Z
37.4
ND*-Nominal Detection Liait-<50. mg/Kg
-------
ACSE4ACH
LABORATORY
PKHER
E-P Analytical Report
Customer ID:Pit B Waste Feed Run #2
SW-846 Method 8240
Work Order # S7-02-153-02A
ing/Kg
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-*
71-55-6
79-00 -r5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-r7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) •ethane
Bis(2-chloroethyl) ether
Bis(2-chloroisopropyl) ether
Bronodichloroae thane
Bronorae thane
Carbon disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodi.br onome thane
Chi or oe thane
Chloroform
Chi or one thane
1 ,2-Dibromo-3-chloropropane
1 ,2-Dibromoe thane
Dibrotnorae thane
DichlorodiCluoronethane
1 ,1 -Dichloroe thane
1 ,2-Dichloroethane
1 , 1 -Dichloroethy lene
Dichl or ome thane
1 ,2-Dichloropropane
Ethyl benzene
Hexachloroe thane
2-rHexanone
I od one thane
Methyl ethyl ketone
Pent achloroe thane
Pyridine
Styrene
1,1,1,2-Tetr achloroe thane
1, 1,2,2 -Tetrachloroe thane
Tetrachloroethene
Toluene
Trana-1 ,2-Diehloroethene
Tribromorae thane
1,1,1 -Trich lor oe thane
1,1,2- Trichloroethane
Trichloroethene
Tr ich lor oaonof luor ome thane
Trich loropropane
Vinyl chloride
Xylene (total)
SAMPLE
39.
NO*
<0.50
<20.
<20.
<20.
<0.50
<1.0
<0.50
4.0
4.7
<0.50
<1.0
0.58
<1.0
ND*
ND*
ND*
HD*
0.65
106.
<0.50
<0.50
ND*
14.
<20.
<1.0
ND*
<1.0
ND*
ND*
10.
ND*
7.7
2.9
1.4
0.85
<0.50
<0.50
132.
<0.50
<0.50
ND*
<1.0
<0.50
ND*»Notninal Detection Li»it"<50. mg/Kg
-------
E-P Analytical Report Work Order * 87-02-153-02A
GUJcomer ID:Pic B Waste Feed Run *2
EPA SW-846 METHOD 8270
Detection limit:
.
CAS RN COMPONENT SAMPLE
208-96-8 Acenaphthalene <20.
83-32-9 Acenaphthene <20.
75-05-8 Acetonitrile ND*
98-86-2 Acetophenone ND*
53-96-3 2-Acetylaminofluorene ND*
107-13-1 Acrylonitrile ND*
122-09-3 Alpha,aipha-dirnethylphenethylaraine ND*
92-67-1 4-Aminobiphenyl ND*
62-53-3 Aniline <20.
120-12-7 Anthracene 32.
140-57-3 Aramite ND*
56-55-3 Benz(a]anthracene <20.
108-98-5 Benzenechiol ND*
92-87-5 Benzidine <100.
205-99-2 Benzolbjfluoranthene <20.
207-03-9 Benzo[kjfiuoranthene <20.
65-35-0 Benzoic acid <100.
106-51-4 £-Benzoquinone ND*
191-24-2 Benzo(ghi)perylene <20.
50-32-8 Benzo[a]pyrtne <20.
100-51-6 Benzyl alcohol <20.
117-81-7 Bit(2-ethylhexyl)phthalate <20.
101-55-3 4-Broaophenyl phenyl ether <20.
85-68-7 Butyl benzyl phthalate <20.
106-47-8 £-Chloroaniline <20.
510-15-6 Chlorobenzilate ND*
126-99-8 2-Chloro-l,3-butadiene ND*
59-50-7 £-Chioro-«-creaol <20.
110-75-8 2-rChioroe'thyl vinyl ether <1.0
91?58-7 2-Chloronaphthalene <20.
95-57-8 2-Chlorophenol <20.
7005-72-3 4-Chlorophenyl phenyl ether <20.
107-05-1 3-rChloropropene HD*
218-01-9 Chryiene <20.
10061-01-5 ci«-l,3-Dichloropropene <0.5
53-70-3 Dibenz[a,h]anthracene <20.
132-64-9 Dibenzofuran <20.
192-65-4 Dibenzo(a,ejpyrene ND*
189-64-0 Dibenxo(a,h]pyrene ND*
189-55-9 Dibenzo(a,ijpyrene ND*
84-74-2 Di-n-butyl phthalate <20.
541-73-1 m-oTchiorobenzene <20.
95-50-1 £-Dichlorobenzene <20.
106-46-7 £-Dichlorobenzene <20.
91-94-1 3,3'-Dichlorobenzidine <40.
ND*«Nominal Detection Limit-<50. >t/Kg
-------
PKHER
RESEARCH
LABORATORY
E-P Analytical Report Work Order t 87-02-153-02A
EPA SW-346 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <20.
87-65-0 2,6-Dichlorophenol ND*
94-75-7 2,4-Dichlorophenoxyacetic acid ND*
84-66-2 Diethyl phthalate <20.
119-90-4 3,3'-Di:nethoxybenzidine ND*
60-11-7 £-Dimethylaninoazobenzene ND*
57-97-6 7,12-Dia>ethyibenz[a)anthracene ND*
119-93-7 3,3'-Diraethyibenzidine ND*
105-67-9 2,4-Dimethylphenol <20.
131-11-3 Dimethyl phthalate <20.
534-52-1 4,6-Dinitro-o-cre«ol <100.
51-23-5 2,4-Dinitroptienol <100.
121-14-2 2,4-Dinitrotoluene <20.
606-20-2 2,6-Dinitrotoluene <20.
117-84-0 Di-n-octyl phthalate <20.
122-39-4 Diphenylamine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-n-propylnitrosaaine <20.
107-12-0 Ethyl cyanide ND*
206-44-0 Fiuoranthene <20.
86-73-7 Fluorene <20.
118-74-1 Hexachlorobenzene <20.
87-68-3 Hexachlorobutadiene <20.
77-47-4 Hexachlorocyclopentadiene <20.
Hexachlorodibenzo-£-dioxins ND*
Hexachlorodibenzofuraps ND*
70-30-4 Hexachlorophene ND*
1888-71-7 Hexachloropropene ND*
193-39-5 Indeno(l,2,3-cd)pyrene <20.
78-59-1 Isophorone <20.
120-58-1 Isosafrole ND*
109-77-3 Malonitrile ND*
100^25-4 •eta-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
101-14-4 4,4'-Hcthylenebi*(2-chloroaniline) ND*
80-62-6 Methyl methacrylate ND*
66-27-3 Methyl methanesulfonate ND*
91-57-6 2-Methylnaphthalene <20.
108-10-1 4-Methyl-2-pentanone <1.0
91-20-3 Naphthalene <20.
134-32-7 1-Naphthylaraine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone ND*
88-74-4 2-Nitroaniline <100.
99-09-2 3-rNitroaniline <100.
100-01-6 £-Nitroaniline <100.
98-95-3 Nitrobenzene <20.
88-75-5 2-Nitrophenol <20.
ND*"Nominal Detection Limit"<50. mg/Kg
-------
LABORATORY
E-P Analytical Report Work Order * 37-02-153-02A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
100r02-7 4-Nitrophenol
924-16-3 tJ-Nitrosodi-n-butylamine
SS-18-S £-Nitroiodie7hyi«Bine
62-75-9 £-Nitrosodimethylaaine
86-30-6 tt-Nitrosodiphenylamine
10595-95-6 £-Nitroiomethylethylamine
59-89-2 £-Nitro«omorpholine
100-75-4 N-Nitrosopiperidine
930-55-2 £-Nitro»opyrrolidine
99-55-8 5"-Nitro-£-coluidine
95-43-7 ortho-Cr7sol
106-44-5 para-Crcsol
608-93-5 Pentachlorobenzene
Pentachlorod ibenzo-£-dioxins
Pentachlorodibenzofurani
82-68-8 Pcncachloronitrobenzene
87-86-5 Pentachlorophenol
62-44-2 Phenacetin
85-01-8 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-58-5 Pronaraide
129-00-0 Pyrene
108-46-3 Rcsorcinol
94-59-7 Safrole
88-85-7 2-«ec-Batyl-4,6-dinitrophenol
95-94-3 1,2,4,5-Tetrachlorobenzene
1746-01-6 2, 3,7,8-Tetrachlorodibenzo-£-
dioxin
Tetrachlorodibenzo-£-dioxin«
Te trach lorod ibenzo fur an*
58-90-2 2,3,4,6-Tetrachlorophenol
110-57-6 tran«-l ,4-Dtchloro-2-butene
10061-02-6 tran«-l,3-Dichloropropene
120-82-1 1,2,4-Trichlorobenzene
75-70-7 Trich lor methane eh iol
95-95-4 2,4,5-Trichlorophenol
88-r06-2 2,4,6-Trichlorophenol
93-76-5 2,4, 5-T
126-r72-7 Tri«-(2,3-dibro«opropyl)pho«phaee
ND*- Nominal Detection Li«it"<50. ag/Kg
-------
RICHER
KSIAKCH
LABOMTORY
E-P Analytical Report
Customer ID: Pit B Waste Feed Run #2
CC Procedure 8080, 8130, and 8140.
Work Order t 87-02-153-02A
CAS RN
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-36-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
ALpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
DDE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
gamma-BHC
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
CC Procedure 8140
297-97-2 0,0-Diethyl 0-2-pyrasinyl <1.0
Phosphorothioate
298-04-4 Disulfoton <0.33
52-85-7 Fanphur <3.3
298-00-0 Methyl parathion <0.33
56-38-2 Parathion <0.33
298-K)2-2 Phorate <1.6
3689-24-5 Tetraethyldithiopyrophosphate <1.0
CC Procedure 8150
94-75-7 2,4- Dichlorophenoxyacetic acid <0.5
93-76-5 2,4,5-T <0.1
93-72-1 Silvex <0.1
-------
£-P Analytic*! Report Work Order * 87-02-153-02A
Cut Comer ID: Pic B Waste Feed Run #2
Metals analyzed by method given
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7341
6010
6010
METHOD
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
mg/Kg
SAMPLE
31,300.
<12.
<50.
11.
<1.
<1.
4070.
34.
11.
160.
13,180.
<20.
4490.
306.
<0.04
17.
<20.
6780.
<100.
<2.
1491.
<2.
SO.
41.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
1.
2.
2.
2.
10.
4.
-------
E"p Analytical Report Work Order # 87-02-1 53HD2A
Customer ID: Pit B Uaste Feed Run #2
A heated purge and trap Modification of Method 8240.
CAS RN
107-18-6
542-76-7
123-91-1
75-21-8
97-63-2
78^83-1
107-19-7
COMPONENT
Allyl alcohol
3-Chloropropionitrile
1 ,4-Dioxane
Ethylene oxide
Ethyl methacrylate
Isobutyl alcohol
2-Propyn-l-ol
SAMPLE
ND*
ND*
ND*
ND*
ND*
ND*
ND*
Method 9010 for determination of total and amenable cyanide.
CAS RN COMPONENT SAMPLE, ug/g
106-51-4 Cyanide <0.01
Method 9030 for determination of sulfide.
CAS RN COMPONENT SAMPLE, ug/g
18496-25-8 Sulfide 616.
Method 340.1 Fluoride by distillation.
CAS RN COMPONENT SAMPLE, ug/g
16984-48-8 Fluoride .13
Moisture determination by Karl Fischer method. ( Z )
COMPONENT SAMPLE, wt. Z
Moisture 34.1
ND*-Nominal Detection Limit-<50. mg/Kg
-------
Carbon Tetrachloride Results
Shirco I.D. Result, mg/Kg E-P Sample »
Pit J Run I 128. 87-02-130-01A
Pit I Run 1 34. 87-02-130-03A
Pit M Run 2 40. 87-02-130-06A
Pit B Run 2 4.0 87-02-153-02A
Waste Feed
Moisture Content (Karl-Fischer Method)
Shirco I.D. Result, wt. I E-P Saaple »
Pit J Run 1 21.4 87-O2-130-01A
Pit I Run 1 24.9 87-02-130-03A
Pit M Run 2 37.4 87-02-130-06A
Pit B Run 2 34.1 87-02-153-02A
-------
EAGLE
RESEARCH
LABORATORY
An.i lysis Kcport
01 Coiucncs
bampio KJSUXCS: M7-U1-2 Ifa-Ul A UT36 10 Fit U
87-Ul-21o-U2A Hrio/Dop f/l4y y
87-0 1-2 16-U3A bT-6 (.U) M3
a/-Ul-21b-U4A BT3 (U-2) J
67-U1-216-05A BT-2 (0-2) I #2
invoice
-------
RESEARCH
LABORATORY
Stiirco bompij
10 fit 6
Sample f/8 7-01-216-01A
C
-------
•AQLE^pPKHER
RESEARCH
LABORATORY
LAS i<.,
/5-u5-i
*2-o7-i
02-53-3
12U-12-7
I4U-57-8
JO-3J-3
iOB-ya-5
luo-31-4
50-32-6
lOU-51-o
H7-B1-7
1U1-55-3
SlU-o-o
lu-75-8
7UU5-72-3
1U/-U5-1
2ia-ul-y
10U61-U1-5
33-/U-3
132-64-*
84-74-2
041-7J-i
12'J-.iJ-2
d7-o5-U
04-oo-2
t-l' Ail-' I v I i c.i I .(i-|>'UL
'Uc|p, ,; W -0 1 -.' lo-(
mcr iu: tit Jo 10 Hit
U<_ c>jcc LOU
Acctonitrile
Acctophcnono
2-AcrJtyiaminut luoreno
Acrylunitriie
Aiph.i, n l,ihnzene
3 , j'-UictuorobonziUino
2 ,4-Uichlof
-------
RESEARCH
I A f. OR ATOPY
S..-H40
o27i)
D/-V/-0
i ty-yj-/
ul-il-J
51-28-5
121-14-2
u(Ji>-/0-2
1 i7-e4-u
1 22-00- /
u2l-o<»-/
IU/-12-U
200-44-U
oo-/J-/
i 16-74-1
6/-06-J
7;-4 7-4
/u-3u-<*
73-59-1
120-J6-1
ioy-77-j
lUU-^5-4
91-6U-J
5o-4y-5
1U1-U-4
60-02-0
lUd-iU-1
*i-20-J
1J4-J2-7
86-74-4
y^-uy-2
1UU-01-0
^6-^>-J
b«-/3-5
1UU-U2-7
92H-16-3
Dj-ib-i
o2-7b-y
BO-Ju-0
/ , I 2-uimeCtiylucni: [ i j. MLitrncom.
J,J'
2 ,4-
4 ,u-L)iuiiro-o-erv.'sol
2 .-»-uinic ropnuno I
2 ,4-lJinj.LrotulucMiv.'
2 ,b-uinitrotoluenc
ui-r^-occyi piuhaiacc
Uipnenyi .inane
I ,2-Diplicnylnydrazine
Ui-n-propyiiiiC rosainine
tthy'l cyaniae
l-'luorene
liexdcniorobenzenc'
uexaciilorobuCddiene
licxaculorocycloponcadiene
_
Hcxacliiorodibenzof ur«ns
Hexucnioru|)liene
1 ,2 , J-cd)t»yrene
Isophurone
IriOSal rt)lc-
Maionicrile
m»- c a- Ui iii cro benzene
M^chdcrylonitrile
Meiliapyr ilone
McChyiciiul/mthrene
4 ,^'
Methyl
flutliyl mechanubulfonacc
1-NapiiChyi.iraino
i ,<*-NaphCiioquinuii(;
2-Nicroanilino
3-Nitroaniiine
£-Nitroaniline
Mi Lro benzene
2-,Nicropiu-noi
4-NiLrophenyl
o
_N-Nic i 'osudiphcnyiamine
j.^-^icrosomw:tiiylethy
i.'-Nic roi>umur|ilioli ne
NU
NU
HI)
Nil
NU
NU
ND
ND
Mu
ND
ND
ND
Nu
ND
Nu
ND
NO
ND
ND
ND
ND
ND
ND
ND
ND
UD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
iJD
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-------
RESEARCH
LABORATORY
r.-H An.uyuc.jl Kt pert
urrlor •; «/-() I -2 10-02A
by
Mr.1 UOUrr
1)0 10
oO 10
/UOU
oUlO
00 10
00 10
0010
OOlU
bOU
OJlO
OOiO
0010
0010
(J«J1J
/i71
OUlO
ftOiU
uOlO
/ ;«4(j
6010
OOUJ
/a<*i
0010
oOiO
rlKiUUJ
[(.T/Tv Kb
iCH/ Ahb
Gt-'/Vv
ICf/Al-S
Itf/A£b
iCH/Atb
ICP/AE5
iCf/HtS
1CP/AES
iCt'/Atii
ICF/Atb
iCH/Abb
ICf/AEb
[CF/ALS
CVAA
ICF/ALa
ICF/AtS
iCF/ALi
GfAA
iCF/ALS
ICF/AhlS
Gb'AA
iCF/AtS
ICP/AEa
COrtHui.tN'r
Aluminum
AtiLinuny
Arsenic
rirf Hum
ttLTyllium
Cadmium
Cjlcium
Curoraiura
CobaiL
Copper
Iron
Luad
Magnes ium
Man^anebe
Ilercury
iCickel
Osmium
Foc
-------
EAQLEl^pPKHER
r
LABORATORY
A
CAS KN
107-iti-o
lj: jJrio/uOP l«
dllU L ruiriae
SAMPLE
1000.
Method 340.1 tiuorido by distillation.
CAS
COMPONENT
Fluoride
SAMPLE
.14
Moisture determination by Karl Fischer method.
COMPONhrtT
SAMPLE
1 b . / X
-------
cAGLEL^p RICHER
RESEARCH
LABORATORY
buirco Sample
Sample 087-01-216-U3A
c
-------
RICHER
c
LABORATORY
(,u-->Li>ruc i iu: L
L^A SW-440 ML'i'UUU ii2'/U
i.-P >\n.i ly 11 C'! I i.^|i'>rt I.'.ITK
c
/5-03-H
53-vu-J
92-0/-1
14U-57-B
jo-55-3
iuo-*B-3
2u/-OB-y
tOo-51-4
lOO-51-o
117-BI-7
101-35-3
03-06-7
106-47-6
5y-5o-7
110-73-6
y1-30-7
/18-01-*
100ol-ol-5
53-/0-3
192-03-4
BA-74-2
B7-o5-0
Acenapucnnltinc
Acotonit rile
2-/vcetyioninor,
Acryioaitriie
Alplui ,n lpha-dimcthyi.phenuthylamine
4-Aminooipiionyl
Anxiim-
Aramicc;
Belli | a | .jn<. liraccne
ttcnzenu-cniol
Benzidinc
ttc»nzo [ D j l luorantnune
iicnzu i < J t* luo rantuene
Benzoic aciJ
;i;perylenc
c'i j pyrenti
bonzyi alcohol
his(2-eChyiiiexyl)|>hthalate
4-uromopnenyi phenyl ether
Butyl benzyl pnttialnte
£-tliioroani lino
Liiiorooenzilace
2-uiiloro-i, j-hnr-(uir;ie
_p_-CiUuro-m-cresoi
2-uhloroethyl vinyl ether
2-Ciii.uruiiaphtliulune
2-Lhloropiienol
^-truorupnenyi phenyl ether
3-t-hioropropene
Onrysene
cis-1,3-Uichioropropeue
Uibenzla.njantnraccne
Uihenzofur.in
Dibtinzo I A ,e J pyrene
Uibonzo [a, ti J pyrene
Uibenzo(a,i Jpyrene
Ui-^-L>utyl phthaLato
in-uicliioro benzene
2,«4-|
2 ,0-uichioroptienol
2 ,4-uicliiuru|)heni)xyficetic acid
Uiecnyl phcn.-ilJte
3 ,3'-uimi.-cti(jxybf nzidine
•'-' >•)/-!) I-J Ib-ulA
-' Cue Li on Limit : 'JO u>',/«;
NU
NU
NU
NU
ND
NU
NU
NU
ND
ND
ND
NU
NU
NU
NU
NU
NU
NU
ND
NU
NU
NU
NU
ND
NU
NU
NU
NU
NU
ND
NU
ND
NU
ND
ND
NU
ND
NU
NU
NU
NU
NU
NU
NU
-------
EAGLES PKHER
LABORATORY
t.\'.\
/0-3u-<4
loaB-/l-7
/a-5V-l
U0-5o-l
126-^0-7
yi-aO-5 •
30-4^-5
lul-14-4
tiO-b2-o
t>o-2/-J
yi-37-b'
1J4-J2-7
91-iy-a
UU-13-4
ea-74-4
y^-uy-2
iUU-Ul-0
Va-yi-J
6S-/5-5
lUU-U^-7
53-lB-b
02-/5-lJ
oo-JU-b
chyirfmo.no. jzobonzono
I , l1
2 ,'»-Uinitrop'hcni)i
,ft-L)iniCroLjluene
phcitaiutc
I ,2-Ui|)liunyliiyuraziud
L>i-n_-propylnic.roMaraine
Fluoreno
Hexdciuoruoonzenc
HeXcictUorobucnaiene
llexacltlurocyclupencauiene
tiex
riexactiioropliene
riuxacnloropropene
Indeiio(i ,2,3-cu)pyrcne
Lso^horonc
Isosutrole
Malonitriie
fiotiiacryionitriie
Meciiapyrilune
Mt-cnylcUolanthren
ND
ND
ND
Nu
NU
NU
NU
NU
NU
-------
EAGLE l^p RICHER
RESEARCH
LABORATORY
LHA SW-.Ut) MirillOO
CAS lU
COMHUNLNT
yy-55-o
u2-orf-o
o7-ao-5
lUtJ-93-2
l2y-UU-0
10B-46-3
^H-5l>-7
66-B5-/
^b-VA-J
1740-Ul-o
liU-57-b
iUUbl-u2-fa
12U-02-1 .
/3-/U-/
y3-*5-««
68-U6-2
VJ-/0-D
l2ts-72-7
N-Mtrosopyrroiidine
S-is-itro-i^-co
urciiu-Cro'sol
FetiCachiuruaiUcnzof urans
Pentaciiloronicrobunzcne
Pimn.icetin
Fyrene
Uesorcinul
2-.s«?c-Bucyi-4,b-dinltruphcnol
1 ,2 ,4,3-Tetractilorobenzpue
2 ,3,/ ,B-lecractiiorodiDenzo-£-
aioxia
Tecrcicniorodibenzo-£-d toxins
Tctrachiorodibcnzoiurans
2 ,J ,4 ,o-Tetractiiorophenol
crans-1 ,4-Dicr»loro-2-bucene
crans-i , J-uicfiioropropene
1 ,2 ,4-Trichiorooenzene
Trichioruin»ittianeciiioi
2,^,5-Irictiiorophenol
2,<4 ,o-Trichiorophfenoi
2,A,b-T
'ir is-^2, J-dibromopropyi>phosphace
NU
NU
Nu
ND
NU
NU
NU
ND
NU
t.D
NU
ND
NU
NU
Nu
NU
NU
ND
NU
NU
NU
C
-------
AQLEt^pPKHER
RESEARCH
LABORATORY
t-.-r1 An.ilyc U.i I Ki'piirr Work Order )/ «7-ul-2lb-()3A
UuaLomcl ID: ul-0 ((.)) i-U
Meciiud d240
: Low U.OOO to 5U.OUU
Mu'd 50,000 Co 200,000
tti;,u >2UO,000
RN COMPONENT
o7-o<«-t Hcecone Nl)
IU/-J2-S Acroluiu ND
lll-yl-l Hib(^-cliloroecnoxy) methane NU
lll-44-^» ius( 2-chioroiiCiiyi) otncc NU
iua-b0-l bis(2-chloruisopro|jyl) ttficr N'J
7^-27-4 Uror.iodicriloromelhfinc MU
74-aj-y liromomctiiane NO
7D-15-0 Cai-bun disult'ide ND
56-2J-5 Carbon Tecrachloride ND
10»-yo-7 Cnlorobenzene High
12A-48-1 CtiiorodibromomecUane ND
73-uo-J CnioroetUane ND
o/-t>o-J Cluoruiorm Mod
/4-a7-J Chioromethane ND
y6-12-a 1 ,2-t)iDromo-J-chioropropane ND
lUb_.j3_4 1 ,2-UibronocChanc ND
74-yj-J Dibromomethant; ND
73-7l-o uictuoroditiuoromethanc ND
/5-J4-J 1 ,l-uichloroethan« High
10/-U&-2 1 ,2-Dj.chloroetUane Med
75-35-4 1 ,i-uichlorocthyieno ND
7^-0^-2 Uichloromethane ND
/a-b7-4 l ,2-uichioropropane ND
iUU-41-4 tctiyi benzene High
o7-72-l Hoxacnioroethane ND
o*l-/3-o 2-riexunune wD
/4-B6-4 iodomecnane ND
7a-*3-J Methyl ethyl ketone ND
7o-ui-7 Pentacnloroethane ND
110-tto-l Pyridine ND
10o-**2-5 Styrene Ni>
oJo-20-o 1 ,1 , 1 ,2-Tetrachloroecltane Luw
79-34-5 1 ,1 ,2,2-Tccrachioroettiane ND
127-lo-4 Tetrachiorouthene ND
108-da-J Toluene ND
15b-oO-5 Trans-1 ,2-UicnlorocthHiie iJD
75-25-2 Tribrumometh.ine ND
71-55-0 l , i , l-Trichioroetiiano High
79-UO-5 1,1,2- i'ricnioroet! .c Hign
/V-Jl-o Trichioroetnene High
75-bV-4 Trichioromunot Luoromechane NJ
yo-10-4 Tr icnioromotlinne ND
75-01-4 Vinyl cuioriue ND
1JJU-20-7 Xyledc U"tal) ,\U
-------
cAQLEl^pPKHER
r
C
C
RESEARCH
LABORATORY
Cu.tu.yer ill:
oc PruCiidure
CAs KN
juy-ou-2
3i*-8*-0
12074-1 1-2
111U4-28-2
11141-10-5
5340V-21-*
12672-2V-0
1 iuy/-o*-i
11090-82-5
3iy-8:>-/
57-74-V
72-54-8
72-55-y
5u-2*-3
31*-Bb-8
00-5/-1
ysy-^8-8
33213-o5-y
72-20-8
74^i-^J-4
58-89-9
7o-44-J
1024-57-3
4o5-73-o
14J-50-U
7^-43-5
800 1-35-2
GC Proceaure
2*7-97-2
298-U<»-4
52-85-7
-ii>o-OU-0
56-38-2
2*e-02-2
3b^-24-5
oC Procedure
y4-75-/
VJ-/6-5
!#3-72-l
t-P Aii.iiytic.il Kcp.irt Worn
of-u vu; H3
8UdU, 8150, Jnd 8140.
Compouuiit
Aiurin
ALplu-litlC
Aroclor 1016
Aroclur 1221
Aroclor 1232
Aroclur 1242
Aroclor 1248
/troclor 1254
Aroclur 12bO
beta-oHC
Cliiuru.me
UUU
LliiE
UUT
deUa-btlC
uielurin
tndosulran I
bndoaulinn 11
tndrin
tndrin aldehyde
gjmrna-driC
Ucptactilur
iteptachior epoxide
isourin
Kepone
Metuoxychior
Toxapnene
8140
0,0-Oiethyl 0-2-pyrazinyl
Phosphorothioate
Oisulzoton
Famphur
Mecnyl paratnion
Ptirattiion
Phoraie
Tetraechyldithiopyrophosphate
8150
2,4- uiclllorophenoxyacetic acid
2,4,5-1-
Si 1 vex
Urdor *> 8
Sample
NO
NC
ND
ND
ND
ND
ND
ND
NO
ND
NO
NO
ND
i40
NO
NO
0.8
NO
ND
NO
1.3
No
NO
NO
NO
NO
NO
ND
ND
NO
ND
ND
ND
NO
NO
NO
ND
-------
RESEARCH
LABORATORY
i' ',-
uu^uu.c,
;L.LUI= .
ML'itlUU'.'
UUlO
OUlO
/uoo
AU10
bOlU
bUlU
bOlO
oOU
6Ulu
bOl'J
0010
0010
oUlU
uJlU
/471
oJlO
•jUiO
uOlO
/74U
OJlO
0010
7641
oOlO
bJlO
t-P
. LI): uT-o \dj
maiyzod uy me
.ItfliOU
1LP/ALS
ICP/AES
CFAA
ICiVALS
ICP/AES
ICP/AES
LuP/AES
lCP/Ati>
ICP/AES
icP/AtS
1CP/ALS
ICP/AtS
ICP/AES
1CP/AL5
CVAA
ICP/AES
ii-P/AEb
ICP/AES
GFAA
It-P/AES
ICP/AL6
ofAA
ICP/AES
ICP/AES
An uy t iCri i K>
,U
thod givi»n.
COMPOHtNl
Alurainun
Ant inuny
Arsenic
Jariura
neryllium
Cadmium
Calcium
Chrnraium
Cobalt
Cupper
Iron
Lead
Magnesium
ddngdiu-se
Mercury
NicKel
Usmium
Potassium
Selenium
Silver
Sodium
Taa Ilium
Vanadium
Zinc
.•,)•> rt W irK. nr'k'r
my /Kg
SAMPLE
2o,500.
t5.
<2.
125.
<1 .
2.1
3^90.
lo.
<10.
92.
17,500.
14 .
3570.
96.
<.04
12.
100.
2520.
<1.
<1 .
432.
<10.
32.
J7.
•' a;-ui-2i8-ujA
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4 .
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
in.
4.
-------
r
RESEARCH
LABORATORY
K-P Aiuiyticjl Kcport Wortc OrJ'-r // H/-0
MJ
it):
rt nc.jtcd pnr>;e and trap mud it" lent ion of Method a24U.
CAb Ki< LOMPUULNT
10/-i6-u Ally! alcohol
J-Chioropropionitriic
1,4-Uioxane
Eciiylenu oxide
y7-o3-^ Ethyl methacryiate
7a-oJ-l Isobutyi alcohol
1U7-IV-7 2-Propyn-l-ol
Srti-iPLE
NU
NU
NU
NU
NU
NO
NU
c
Method
ior determination or total and amenable cyanide.
COMPONENT
Cyaniae
SAMPLE
r
Method yU3U for determination oi sulfidu.
CAS KN
COMPONENT
bull ide
SAMPLE
465.
MeCnod JA0.1 fluoride by distillation.
CAS RN
COMPONENT
fluoride
SAMPLE
<.l
Moisture determination oy Karl Fischer method.
Moisture
SAMPLE
26.2Z
-------
EAGLE L^pPKHER
RESEARCH
LABORATORY
r
c
Sturco Sample*
BTJ (u-^) J
LP Sample V87-U1-216-04A
-------
EAGLE L^°) RICHER
|.-IJ An. i ly Lie-' ' r>.v'|>i>i'L h»r< Oidf't V o /-U I
II): !>T-3 (U-2; J
c
RESEARCH
LABORATORY
C
iinut: JO
K.J
/b-05-ti
Vb-
-------
LABORATORY
r
£•'*
fc ?..
C
7U-3U-4
UU-36-1
109-77-J
1UU-2S-4
•U-bU-5
io-49-5
bb-2/-3
»i-:>7-t>
1U8-1U-1
91-^0-3
134- J2- 7
^1-59-a
1JU-15-4
iUO-Ul-o
62-75-9
Bo-JO-o
1U595-95-0
l.t'A j'.V-o^O Mi.TIIOl) 8270
CUMPUM.NT
/ , 12-Jimet.liy luenz | .1
3 .J'-Uimotnylbcnzid
2 ,4-uimec.nyi|Jhenoi
UinieCiiyi (jlitlic.i.itc
4 ,0-DiniLro-o-CLOsoi
2 ,4-uinic ropiieriol
2 ,4-uinicroLoluene
2 ,b-Uinit rotoluenc
Ui-£-occyl phtuaiace
i ,2-uipiicnyiiiyuruzinc
ui-^-propylnitrosamine
tLuyl cyaiuac
i-'iuoraiuhcnc
Kluorcne
Hoxaciilorooenzene
ilex.ichlorobut.aai.cne
Hexjchlorocyclopuntadieno
Hexachiorodibenzo-£-dioxins
UcxcjcnlorodiDenzoturans
ilexachiorophene
dexacnluropropene
Indeno( 1 ,2 , 3-cd;pyrene
Isopnorone
Isosafrule
Malonicriie
meCd-oinicrobenzene
Nethacrylonit rile
Meinapyrilene
Motliylcrtolanchrenc
4,4'-Mectiylenebis(2-chloroaniline)
Mecnyl mechacrylace
Mtthyl meciianesultonace
2-Meciiyinaphchalene
4-Mechyl-2-pentanone
Naphthalene
1-Napticaylamine
2-^aphcUyiamine
1 ,4-Naphthoquinone
2-iVitroaniiine
3-Nicroaniline
£-Nitroaniline
Nicrooe/izene
2-Nitrophenol
4-Nitrophenoi
^-Nicrobodi-n-oucylatnine
t^-NitrosodieTnyiamine
^-.MCroaodimethylamine
.^-Nicr jsodipiienyiaraine
£^-.Nit rorforaechylethyl.tminc
N_-Nicrus>umocplioline
SAMPLE
NU
NO
No
ND
ND
ND
NO
NO
NO
^o
NO
UO
ND
ND
NO
ND
NO
ND
ND
ND
NO
ND
ND
NO
NO
ND
ND
ND
NO
ND
ND
ND
ND
UD
ND
ND
ND
NO
ND
ND
No
NO
NO
NO
ND
ND
ND
NO
-------
L^PKHER
RESEARCH
r
1UU-73-A
b7-ttb-5
02-44-2
C
1746-Ul-o
llu-57-o
10061-U^-b
75-70-7
yi-*5-4
dd-Ob-2
VJ-/b-5
120-72-7
c.HA .S»V-
MLi'nul) b270
coMt'u.>it.UT
H-IJic
-.Utro-o-Loluidine
para-Cresol
fcutdchlorobunzenu
PcaLactUorodibotizo^-uioxins
tV-uLaciilorudioenzol urans
PenCdCiilorouit rodenzene
I'entuctiloruphenol
Fnenoi
2-Picoiin«j
Pron.imide
Pyrene
Kesorcinol
Sal role
2-^uc-riutyi-4,u-dinicrophenoi
1 ,2,4,i-Tetrachlorooenzcne
2,3,7 ,d-Tecracnlorodibenzo-£-
dioxin
TiiCrdcnlorodibenzo-£-Uioxins
Tecrachlorodibcnzoturans
2,J,4,b-Tecrachiorophenol
cr.m&-l ,4-Uichloro-2-butene
crans-l , J-Uichioro|jropcne
1 ,2,««-TrichlorotX!nzene
Irichloroinecnunethiol
2,4,5-Trichlorophenol
2 ,4 ,0-Triciiiorophenol
2,4,5-r
Tris-(.2,J-dioromopropyl)phosphate
SAMPLE
NU
ND
Nl)
NU
NU
NU
ND
NU
NU
NO
NU
NU
NU
ND
Ni)
NU
ND
NU
NU
ND
NU
NU
NU
ND
ND
390
ND
ND
NU
NU
NU
ND
NU
C
-------
RESEARCH
LABORATORY
t-f Analytirji i\e|i«*rL WUTK Oraer f c7-ul-2 !*>-'
t (u-2; J
b*-84o MctiioU 6240
ss: Low 1U.UOU to 50.UUU
Mud 5U.UUO to 2UO.UUU
Hijjh >200,UOU
CAS KN COMPUTENT
67-o4-i Acetone
1U/-U2-6 Acrolein
111-Vl-l zJis(2-chloroetUoxy) methane
111-44-4 Bis(2-chloroctnyL) ctner
10d-oU-l bis(2-cnioroisopropyl; ether
/D-2/-4 bromodichloroinotlianu
74-d3-^ Jiromomethane
73-13-U Caroun disultide
56-23-5 Carbon Tetractiloridc
lua-^U-7 Chlorobenzene
124-4^-1 Cnlorodibromooethane
75-UU-3 Chiuroethane
67-ob-3 Cnloroform
74-O/-J Chloromethane
^6-12-a 1,2-Dibromo-3-chioropropanc
lUb-^3-<« 1 ,2-uibroraoe thane
74-V5-3 Uibromoiaetnane
73-71-b uichlorodit'iuoromethane
75-34-3 1,1-Uicnioroethane
iU7-oo-2 I,2-Uichloroethane
75-35-4 1,1-Uichloroethylcne
75-0^-2 Uichloromethane
7a-rf7-4 1,2-liichloropropane
1UO-4J-4 Etiiyl benzene
67-72-1 Hiixachloroethane
591-7a-6' 2-Hexanone
74-aa-4 lodomethane
7a-^3-3 Methyl ethyl ketone
/b-Ul-7 Pentachloroethane
i Pyridine
5 Styrene
oJu-20-o 1,1,1,2-Tecrachioroethane
79-J4-5 1,i,2,2-Tecrachloroetuane
'4 Tetrachluroethcnvi
3 Tuluene
l3o-ou-5 Trans-l ,2-Uichloruet.hane
75-25-2 Tnuromnmethune
/1-53-D 1,1,1-Trichloroethane
/y-OU-J 1,1,2- Trictuoroethane
7^-ul-o Trichluroethenc-
/5-by-<* Trichloruinonol luuromothanc
^o-la-4 irichioroinethane
/5-U1-4 Vmyi, ciiloriac
1J3U-2U-7 Xylouc \.total)
-------
iAOLEL^pPKHER
RESEARCH
LABORATORY
L-P.An.iiytic.4l Kep'-rt Worn Orjor » 87-UI -21f>-()4A
CuaLoilK-T it): JiT-J (O-2) J
GC Procedure ttOHO, H150, and 3140.
C/ii> KN
joy-oo-2
Ji*-b4-o
12b/4-l 1-2
1 1104-20-2
11141-lb-3
5J46y-2J-y
12b72-2«*-b
1 { 0^7—0^—1
i ioyo-a2-5
jiy-a.a-7
3 7 ** / ^»^y
7 ^— ^A^tf
72-55-9
50-2V-3
3i9-ao-a
uU-57-i
va9-9a-b
JJ213-b5-y
/2-20-a
/421-9J-4
5o-ay-y
7b-44-8
l02<«-57-J
4o5-7j-t>
14J-50-0
72-43-5
aooi-J5-2 *
uC Procedure
297-V7-2
2ya-04-«
52-a5-7
2ya-oo-u
5b-Ja-2
2ya-02-2
joay-24-5
UC Procedure
y. 75-7
VJ-/0-5
yj-72-i
Component
Aldrii;
Alpiu-bilC
Arocior lOlb
Arocior 1221
Arocior 12J2
Arucior 1242
Arocior I24a
Arociur 12^4
Arocior 12bO
beca-UHC
Crilordane
UUO
Due.
DOT
delca-ttHC
Uielurin
bndnsultan 1
Encosulfan 11
hndrin
Ladrin aldehyde
gamma -tt tlC
• Hcpcachlor
Heptaclilor epoxide
iaodrin
Kepone
Meclioxychior
Toxapnene
bl40
0,0-Diethyl 0-2-pyrazinyl
Phobi>liorochioace
Disulf oton
Fanphur
Mecnyl parachion
Paracuiun
fhorace
Tecraethyldithiopyrophosphate
ai3o
2,4- Uiclllorophenoxyacetic acid
2,«O-T
Silvex
S^mp 1 e
ND
MD
Nu
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
til)
ND
ND
ND
ND
14.4
79.7
ND
IvD
25
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
NO
ND
-------
EAGLE L^pPKHER
RESEARCH
LABORATORY
r
MetuLx
HbttiOO
0010
OJlvJ
/ObO
0010
OOlO
0010
ooio
bO 10
0010
0010
bOlO
0010
0010
7471
oOlU
0010
0010
7740
0010
0010
oOlO
0010
t-
iU: bT-J (
niyzctd oy
P Analycic^l Kepi.rt
U-t) J
met nod given.
COMPONENT • SrtMl'LE
lup/Ata
ICP/A&a
OFAA
iCf/At.S
iCP/AES
ICP/AEa
w f ' o y * t' c
AWL / ALiiJ
1CP/AES
ICP/AES
ICF/Mtb
ICP/AE5
iCP/HES
1CP/AES
ICP/AES
CVAA
ICF/AES
iCP/AES
ICf/AJiS
ot'AA
iCP/AES
ICP/AES
Gt'AA
ICf/AES
ICf/AEa
AJuminum
Ancimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cooalc
Copper
Iron
Lead
Magnesium
Manganese
Mercury
NiCKel
Osmium
Potassium
Selenium
Silver
Sodium
Tnallium
Vanaaium
X.inc
Work Order rf
Kri
OtTtCT.
19,600.
34.
2.
JJ8.
<1 .
.97
12,000.
15.
-------
EAGLE t^p RICHER
RESEARCH
LABORATORY
t-P Analytical Kc|iurt Worn order « 87-01-2 lb-\ heated purge and crap mudi.1 ication or He c hod 82
SAMPLE
^
i'~7-lb-6 Aliyl ulcohol ND
3«*2-7b-/ 3-Chioropropionitriie NO
123-tyi-l 1,4-Uioxane NU
/3-21-8 LLiiylene uxide NU
^7-bJ-2 tchyi mctUacrylatc Nu
/8-8J-1 isooucyl aicohoi ND
107-19-7 2-Hropyn-i-oi ND
Met hud 9010 tor decerminacion ot total and amenable cyanide.
S KN COi^PONENT SAMPLE
lUb-5i-4 Cyanide .10b
G
Mecnod 90JO for decerminacion of suiride.
CAS Kd COMPONENT SAMPLE
18496-25-8 bulride 4o20.
Method J40.1 fluoride by distillation.
CAS KM COMPONENT SAMPLE
ioy4>4-«a-8 Fluoride .J3
Moisture determination by the iCarl Fischer method.
COMPONENT SAMPLE
Moisture 17.b/i
C
-------
EMLEl?pPICHER
AESEAACH
E-P Analytical Report Work Order #87-02-150-02A
Customer ID:Pit B Ash Sample Run #2
Metal* analysed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Anciaony
Artenic
Barium
Beryl li.ua
Cadmium
Calciin
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
SAMPLE
48,000.
<12.
4.
254.
<1.
1.2
8620.
34.
14.
323.
24,600.
19.
5540.
407.
<.04
20.
75.
7080.
2.5
<2.
2160.
<2.
55.
57.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
-------
PKHER
E P Analytical Report Sample #87-04-113-Q4A
Cuatoner ID:Pic B Run *7 Ash
/K
Component
Benz(a]anthracene
Benzidine
Benzo[b]fluoranthcne
Benzo[a]pyrene
2-Chlorophenol
Oibenz(*,hJanthracene
3f3'-Dichlorobenzidine
2,4-Dinitrotoluene
Hexachlorobenzene
PCB's (all common arochlors)
bis (2-chloroethyl) ether
-------
LABORATORY E"p Analytical Report Work Order #87-02-150-02A
Cuatoner ID: Pit B Aah Sample Run #2
CC Procedure 8080, 8150, and 8140.
JK/Kg
CAS RN
309-rOOr2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-3
33213-65-9
72-20-8
7421-^93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
DDE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endotulfan II
Endrin
Endrin aldehyde
gacma-BUC
Heptachlor
Heptachlor epoxide
liodrin
Repone
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.008
<0.008
<0.016
<0.016
<0.016
<0.008
<0.016
<0.008
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2 0,0-Diethyi 0<*2-pyrazinyl <1.0
Phoaphorothioate
298-04-4 Ditulfoton <0.33
52-85-7 Famphur <3.3
298-OOHD Methyl parathion <0.33
56f38-?2 Parathion <0.33
298-02-2 Phoratc <1.6
3689-24*5 Tetraethyldithiopyrophoaphate <1.0
CC Procedure 8150
94-75-7 2,4- Dichlorophenoxyacetic acid <0.33
93-76-5 2,4,5-T <0.33
93-72-1 Silvex <0.33
-------
EMUEL^pnCHER
/tCSCAACH
E-P Analytical Report Work Ordar * 87-02-150-02A
EPA SU-846 METHOD 8270
CAS RN COMPONENT
100-02^7 4-Nitrophenoi
924-16*3 JJ-Nitroaodi-ti-butylaiBine
55-13-5 T5-Ni.trosodie7hylami.ne
62-7S-9 j^-Nitroaodimethylaaine
86-30-6 CJ-Nitrosodiphenylaiaine
10595-9S-6 7-Nicrosomechylathylaaina
59-39-2 £-Nitro«ooorpholine
100-75-4 14-Nitroaopiperidine
930-55-2 iJ-Nitroaopyrrolidine
99-55-8 5"-Nitro-£-toluidine
95-48r7 ortho-Cra'tol
106-44-5 para-Crasol
608-93-5 Pantachlorobenzana
Pantachlorodibenzo-£-dioxins
Pentachlorodibenzofuranc
82-68-8 Pentachloronitrobenzena
87-86-5 Pantachlorophenol
62-44-2 -Phenacetin
85-01-8 Phenanthrane
108-95-2 Phenol
109-06-8 2-Pieolina
23950^58-5 Pronamide
129-00-0 Pyrene
108-46-3 Reaorcinol
94-59-7 Safrola
88-:85-7 2-scc-BuCyl-4,6-dinitrophanol
95-94-3 1,2,4,5-Tatrachlorobenzana
1746-01-6 2,3,7,8-Ta trachlorod ibanzo-£-
dioxin
Tatrachlorodibanzo-£-dioxina
Te trachlorod ibanzo furana
58-90-2 2,3,4,6-Ta trachlorophanol
110-57-6 Crana-1,4-Dichloro-2-butane
10061-02-6 trana-1,3-Dichloropropana
120-82-1 1,2,4-Trichlorobanzaaa
75-70-7 Trichloronethanethiol
95-9S-A 2,4,5-Trichlorophenol
88-06-r2 2,4l6^TrichlorophenoL
126-72-7 Tria-(2,3-dibro«opropyl)phoiphate
<0.067
<0.067
<0.067
ND*
HD*
<0.005
<0.33
ND*
<1.6
<.033
HD*
ND*»No«inal Detection Limit-<1.0
-------
RICHER
RfSlARCH
LABORATORY
E-P Analytical Report Work Ordtr * 87-02-150-K)2A
CPA SW-846 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <0.33
87-65-0 2,6-Dichlorophenol ND*
84-66-2 DieChyl phthalate <0.33
119-90-4 3,3'-Diraethoxybenzidine ND*
60-11-7 £-Di«ethylaminoazobenzene ND*
57.97.6 7,12-Dim*chylbtnx(a]anthracene ND*
119-93-7 3,3'-Diaethylbenzidine ND*
105-67-9 2,4-Dimethylphenol <0.33
131-11-3 Dimethyl phthalate <0.33
Difflethyltercphthalate ND*
534-52-1 4,6-Dinitro-£-cre«ol <1.6
51-23-5 2,4-Dinitrophenoi <1.6
121-14-2 2,4-Dinitrotoluene <0.33
606-20-2 2,6-Dinitrotoluene <0.33
117-84-0 Di-n-octyl phthalate <0.33
122-39-4 Diphenyiaraine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-£-propylnitrotanine <0.33
107-12-0 Ethyl cyanide ND*
206-44-0 Fluoranthene <0.33
86-73-7 Fluorene <0.33
118-74-rl Hexachlorobenzene <0.33
87-68-0 Hexachlorobucadiene <0.33
77r47-4 Hexachlorocyclopentadiene <0.33
Hexachlorodibenzo-£-dioxint ND*
Hexachlorodibenzofurans ' ND*
70-30-4 Uexachlorophene ND*
1888-71-7 Hexachloropropeae ND*
Hydrazine ND*
193-39-5 Indeno(l,2,3-cd)pyrene <0.33
78-59-1 Itophorone <0.33
120-r58-l Isoaafrole ND*
109-77-3 Malonitrile ND*
100-25-4 Mta-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-r49-5 Methylcholanthrene ND*
Methyl chryaene ND*
101-14-4 4,4'-Methylenebii(2-chloroaniline) ND*
80-62-6 Methyl aethacrylate ND*
66-27-3 Methyl methanesulfonate ND*
91-57-6 2-rMethylnaphthalene <0.33
108-10-1 4-Methyl-2-pentanoac <0.010
Methyl phenyl diaaine ND*
91-20r3 Naphthalene <0.33
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylanine ND*
130-15-4 1,4-Naphthoquinone ND*
88-r74-4 2-Nitroaniline <1.6
99-09-2 3rNitroaniline <1.6
100-01-6 £-Nitroaniline <1.6
98-95-3 Nitrobenzene <0.33
88-75-5 2-Nitrophenol <0.33
ND*<*Nominal Detection Liait'<1.0 mg/Kg
-------
EAQU^PKHER
mm *M**1J
E-P Analytical Report
Customer ID: Pit B Aah Sample Run #2
ft£SEAACH
LABORATORY
Work Order # 87-02-150-02A
EPA SW-846 METHOD 8270
•g/Kg
CAS RN COMPONENT SAMPLE
208-96-8 Acenaphthalene <0.33
83-32-9 Acenaphthene <0.33
75-05-3 Acetonitrile MD*
98-86-2 Acetophenone ND*
53-96-3 2-Acetylafflinofluorene ND*
107-13-1 Acrylonitrile ND*
122-09-3 Alpha,alpha-diaethylphenethylaaine ND*
92-67-1 4-Aninobiph«nyl ND*
62-53-3 Aniline <0.33
120-12-7 Anthracene <0.33
140-57-8 Aramite ND*
56-55-3 Benz[a]anthracene <0.33
108-98-5 Benzenethiol ND*
92-37-5 Benzidine <1.6
205-99-2 Benzo(b)fluoranthene <0.33
207-03-9 Benzolkjfluoranthene <0.33
65-85-0 Benzoic acid <1.6
106-51-4 £-Benzoquinone ND*
191-24-2 Benzo(ghi)perylene <0.33
50-32-f8 Benzo{ a] pyrene <0.33
100-51-6 Benzyl alcohol <0.33
117-81-7 Bii(2-ethylhexyl)phth«latt <0.33
101-55-3 4-Bromophenyl phenyl ether <0.33
85-68-7 Butyl benzyl phthalate <0.33
106-47-8 £-Chloroaniline <0.33
510-15-6 Chlorobenziiate NO*
126-99-8 2-Chloro-l,3-butadiene NO*
59-50-7 £-Chloro-w-cre«ol <0.33
110-75-8 2-ChloroeThyl vinyl ether <0.10
Chloromethylmethylether ND*
91-58-7 2-Chloronaphthalene <0.33
95-57-8 2-Chlorophenol <0.33
7005-72-3 4-rChlorophenyl phenyl ether <0.33
107-?05-1 3-Chloropropene ND*
218-01-9 Chrysene <0.33
10061-rOl-5 cit'l,3-Dichloropropene <0.005
Dibenx[a,h]acridine ND*
53-70*3 Dibenz(a,hjanthracene <0.33
132-64-9 Dibentofuran <0.33
192-65-4 Dibenzo(a,e]pyrene ND*
189-64-0 Dibenzo(a,hlpyrene ND*
189-55-9 Dibenzo[a,ijpyrene ND*
84-74-2 Di-rn-butyl phthalate <0.33
541-73-1 m-Dlchlorobenzene <0.33
95-50-1 ^-Dichlorobenzene <0.33
106-46-7 £-Dichlorobcnzene <0.33
91-94-rl 3,3'-Dichlorobenzidine <0.66
ND*"Norainal Detection Limit*<1.0 og/Kg
-------
E-P Analytical Report
Customer ID: Pit B Ash Sample Run 12
SU-846 Method 8240
CAS RN
Work Order * 37-02-123-02A
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-33-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01r7
100-*2-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-r55-6
79-00-5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) methane
Bi«(2-chloroethyl) ether
Bit(2-chloroifopropyl) ether
Bromodichloroaethane
Bromomethane
Carbon disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibrooomethane
1-Chloro-2,3-epoxypropane
Chloroethane
Chloroform
Chloromethane
1,2-Dibrorao-3-chloropropane
1,2-Dibromoethane
Di b ronone th ane
Oichlorodif luorotne thane
1,1-Oichloroethane
1,2-Dichlorocthane
1,1-Dichloroethylene
Dichloromethane
1,2-Dichloropropane
Ethyl benzene
Hexachloroethane
2-Hexanone
lodomethane
Isobutanol
Methyl ethyl ketone
Methyl isobutyl ketone
Pencachloroechane
Pyridine
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Te trachloroethane
Tetrachloroethene
Toluene
Trans-l,2-Dichloroethane
Tr ib romooeth ane
1,1,1-Trichloroe thane
1,1,2- Trichloroethane
Trichloroethene
Trichlorononofluoroaethane
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
<0.010
NO*
<0.005
<0.33
<0.33
<0.33
<0.005
<0.010
<0.005
<0.005
<0.005
<0.005
ND*
<0.010
<0.005
<0.005
ND*
ND*
ND*
ND*
<0.005
<0.005
<0.005
0.007
<0.010
<0.005
<0.33
<0.010
ND*
ND*
<0.010
ND*
ND*
<0.33
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
ND*
<0.010
<0.005
ND*»Nominal Detection Limit"<1.0 «t/Kg
-------
EAGLE [spPKHER
ACSEAACH
E-P Analytical Report Work Order * 87-02-150-01A
Pit B Ash Sample Run fl
A heated purge and trap modification of Method 8240.
CAS RN COMPONENT
107-18-6 Allyl alcohol
542-76-7 3-rChloropropionitrile
123-91-1 1,4-Dioxane
75-21-3 Ethylene oxide
97-63-2 Ethyl aethacrylate
78-83-1 Isobutyl alcohol
107-19-7 2-Propyn-l-oi
Method 9010 for determination of total and amenable cyanide.
mg\Kg
CAS RN
106-51-4
COMPONENT
Cyanide
Determination of aulfide by ICP/AES.
CAS RN
COMPONENT
18496-25-8 Sulfidc
SAMPLE
414.
Fluoride by Specific Ion.
CAS RN
COMPONENT
16984-48-8 Fluoride
SAMPLE
ND*-No«inal Detection Limit-<1.0 «f/Kg
-------
PICHCT
,
ATORY
E-P Analytical Report Work Order #87-02-150-01A
Customer ID:Pit B A*h Sample Run #1
Metals enalyted by method given.
•I/Kg
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
SAMPLE
30,600
25.
* <4.
366.
1.
1.
6370.
35.
19.
249.
31,700
13.
6920.
695.
<.04
27.
116.
8550.
1.
<2.
2180.
<2.
73.
60.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
* Dilution required because of interference.
-------
PKHER
ABCAACH
JJUKMU7DAY
E-P Analytical Report
Cut corner ID: Pit B Ash Sample Run #1
CC Procedure 8080, 81SO, and 8140.
Work Order #87-02-150-01A
CAS RM
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-r86-8
60-57-1
959-98-8
33213-65-9
72-?20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1243
Aroclor 1254
Aroclor 1260
beta-3HC
Chlordane
ODD
DDE
DDT
delta-3HC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
gamma-BHC
Heptachlor
Heptachlor epoxide
I*odrin
Kepone
Methoxychlor
Toxaphene
ma/Kg
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.003
<0.003
<0.016
<0.016
<0.016
<0.008
<0.016
<0.008
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2 0,0-Diethyl 0-2-pyraxinyl <1.0
Phoaphorochioace
298-04-4 Disulfoton <0.33
52-85-7 Faaphur <3.3
298-00-0 Methyl paraChion <0.33
56-38-2 Parathion <0.33
298-02-2 Phorate <1.6
3689-r24-?5 Tetraethyldithiopyrophosphate <1.0
CC Procedure 8150
94-75-7 2,4- DichlorophenoxyaceCic acid <0.33
93-76-5 2,4,5-T <0.33
93-72-1 Silvex <0.33
-------
E-P Analytical Report Work Order f 87-02-150-01A
EPA SW-846 METHOD 3270
CAS RN
r6~0-02-7
924-1 6-?3
55-18-5
COMPONENT
4-Nitrophenol
N-NitroiOdi-n-butylaaine
£-Nitro»odiethylaoine
86-30-6
10595-95-6
59-39-2
100-75-A
930-55^2
99-55-3
95-4S-7
106-44-5
60S-93-5
82-63-3
87-86-5
62-44-2
35-01-3
108-95-2
109-»06-8
23950-58-5
129-00-H)
108-46-3
94-59-7
88-85-7
95-94-3
174633
Trichloroacthanethiol ND*
2,4,5-Trichlorophenol <1.6
2,4,6-Triehlorophenol <.033
Tri§-(2,3-dibromopropyl)phosphate ND*
ND*"Nominal Detection Limit-<1.0 mg/Kg
-------
LABORATORY
E-P Analytical Report Work Order # 87-02-150-01A
EPA SW-846 Method 8270
CAS__RH COMPOMEMT
120-83-2 2,4-Dichlorophenol
87-65-0 2,6-Dichlorophenol
84-66-2 Diethyl phthaUte
119-90-4 3,3'-Oiaethoxybenzidine
60-11-7 £-Diaethylaminoazobenzene
57-97-6 7,12-Di:aethylbenz[a|anthracene
119-93-7 3,3'-Di:nethylbenzidine
IOS-0/-9 2,4-Dis>ethyloh«»»nl
131-11-3 Di-aethyl phthalate
Dimethyl terephthalate
534-52-1 4,6-Dinitro-2-cresol
51-23-5 2,4-Dinitrophenol
121-14-2 2,4-Oinitrotoluene
606-20-2 2,6-Dinitrotoluene
117-84-0 Di-£-octyl phthalate
122-39-4 DiplTenyla.-aine
122-66-7 1.2-Diphenylhydrazine
621-64-7 Di-n-propylnitrosamine
107-12-0 Ethyl cyanide
206-44-0 Fluoranthene
86-73-7 Fluorene
118-74-1 Hexachlorobenzen^
87-68-3 Hexachlorubutadiene
77-47-4 Hexachlorocyclopentadiene
Hexachlorodibenzo-£-dioxins
H»xachlorodibenzofuran«
70-30-4 Hexachlorophene
1336-71-^7 Hexachloropropene
Hydrazine
193-39-5 Ind«noU,2,3-cd)pvrene
78^59-1 Isophorone
120-53-1 Iso«afrole
109-77-3 Malonicrile
100-25-4 meta-Dinitrobenzene
126-98-7 Mcthacrylonitrile
91-80-5 Mathapyrilene
56-49r5 Methylcholanthrene
Methyl ehrysene
101-14-4 4,4'-Methylenebii(2-chloroaniline)
80-62-6 Methyl methacryiate
66-27-3 Methyl methanesulfooace
91-57-6 2-Methylnaphthalene
108-10-1 4-Methyl-2-pentanone
Methyl phenyl diamine
91-20-3 Naphthalene
134-32-7 1-Naphthylamine
91-59-3 2-Naphthylamine
130-15-4 1,4-Naphthoquinone
88-74-4 2-Nitroaniline
99-09-r2 3*Nitroaniline
100-01-6 £-Nitroaniline
93-95-3 Nitrobenzene
88-75-5 2-Nitrophenol
ND*-No,T»inal Detection Li:nit«<1.0 nj/Kg
-------
PKHER
MESC4ACH
LABOMTOfTf
E-P Analytical Report Work Order * 87-02-150-01A
Cut Corner IO:Pic B A»h Sample Run #1
EPA SW-846 METHOD 8270
mg/Kg
CAS RN CqiPQNENT SAMPLE
208-96-8 AcenaphChalene <0.33
83r32-9 Acenaphchene <0.33
75-05-3 Aceconicrile »D*
98-86-2 Acetophenone NO*
53-96-3 2-Acetylaminofluorene ND*
107-13-1 Acrylonicrile ND*
122-09-8 Alpha,alpha-diaechylphenechyianine ND*
92-67-1 4-Aoinobiphenyl ND*
62-53-3 Aniline <0.33
120-12-7 Anchracene <0.33
UO-57-3 Araaite ND*
56-55-3 Benz[«Janchracen« <0.33
108-98-5 Benzenechiol ND*
92-d7-r5 Benzidin- <1 .6
205-99^2 Bento[b]fluoranthene <0.33
207-03-9 Benzn[k]fluoranchen* <0.33
65-85-0 Benzoic acid <1.6
106-51-^4 £-Benzoquinone ND*
191-24-2 Benzo(«hi)perylene <0.33
50-32-8 Benzo[a]pyrene <0.33
100-51-6 Benzyl alcohol <0.33
117-81-r7 Bi«(2-ethylhexyl)phthalate <0.33
101-55-3 4-Bronophenyl phenyl ether <0.33
85-68-7 Bucyl benzyl phth'alate <0.33
106-47-3 £-Chloroaniline / <0.33
510-15-6 Chlorobenzilace ND*
126-99-3 2-Chloro-l,3-buCadiene ND*
59-50-7 £-Chloro-m-cre§ol <0.33
110-75-8 2-ChloroeThyl vinyl echer <0.10
ChloromeChylmeChyleCher ND*
91-58-7 2-Chloronaphchalene <0.33
95-57-8 2-Chlorophenol <0.33
7005-72-3 4-Chlorophenyl phenyl echer <0.33
107-05-1 3-Chloropropene ND*
218-01-9 Chrysene <0.33
10061-01-5 ci«-l,3-Dichloropropene <0.005
Dibenz[a,h]acridine ND*
53-70-3 Dibenz[a,h)anchracene <0.33
132-r64-9 Dibenzofuran <0.33
192-65-4 Dibenzo[a,ejpyrene ND*
189-64-0 Diben*o[a,hjpyrene ND*
189-55-9 DiJ)enzo[a,ijpyrene ND*
84-74-2 Di-£-bucyl phchalate <0.33
541-73-1 m-Dichlorobenzene <0.33
95-50-1 £-Dichlorobenzene <0.33
106-46-7 £-Dichlorobenzene <0.33
91-94-1 3,3'-Dichlorobenzidine <0.66
ND*-Nominal Detection Liait»<1.0 mg/Kg
-------
RESEARCH
LABORATORY
E-P Analytical Report Work Order * 87-02-150-01A
Customer ID: Pit B Aah Sample Run ?1
SU-846 Method 8240
mg/Kg
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-33-9
75-15-0
56-23-5
108-90-7
124-43-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74^88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) methane
Bis(2-chloroethyl) ether
Bis(2-chloroisopropyl) ether
Bromodichlorone thane
Bromome thane
Carbon disulfi.de
Carbon Tetrachloride
Chlorobenzene
Chi or odibromome thane
1 -Ch lor o-2, 3 -e poxy propane
Chloroethane
Chloroform
Chlorome thane
1 ,2-Dibromo-3-chloropropane
1 , 2-Dibromoethane
Dibroraome thane
Dichlorodif luororae thane
1 , 1-Dichioroethane
1 ,2-Dichloroethane
1 , l-Dichloroethylene
Dichlorome thane
1 ,2-Dichloropropane
Ethyl benzene
Hexachloroe thane
2-Hexanone
lodome thane
Itobutanol
Methyl ethyl ketone
Methyl isobucyl ketone
Pentachloroe thane
Pyridine
SCyrene
1,1, 1 ,2-Tetr achloroe thane
1 , 1 ,2, 2-Tetr achloroe thane
Tetrachloroethene
Toluene
Tran«-l ,2-Dichloroethane
Tr ib romone t h ane
1,1,1 -Trichloroechane
1,1,2- Trichloroethane
Trichloroethene
Trichlororao no f luororae thane
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
<0.010
ND*
<0.005
<0.33
<0.33
<0.33
<0.005
<0.010
<0.005
<0.005
<0.005
<0.005
ND*
<0.010
<0.005
<0.005
ND*
ND*
ND*
ND*
<0.005
<0.005
<0.005
0.010
<0.005
<0.005
<0.33
<0.010
ND*
ND*
<0.010
ND*
ND*
<0.33
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
it"<1.0 mg/Kg
-------
EMLfl^pPKHER
ftCSCAACH
E-P Analytical Report Work Order * 87-02-123-06A
Pic M Aah Saaple Run t2
A heated purge and crap Modification of Method 8240.
•g/Kg
COMPONENT
Allyl alcohol
3-Chloropropionitrile
CAS RN
107-18-6
542-76-7
123-91-1
75-21-8
97-63-2
78r83-l
107-19-7
1,4-Dioxane
Echylene oxide
Echyl MChaerylace
Isobucyl alcohol
2-Propyn-l-ol
Method 9010 for determination of total and amenable cyanide.
mg\Kg
CAS RN
106-51-4
COMPONENT
Cyanide
Determination of sulfide By ICP/AES.
CAS RN
18496-25-8
COMPONENT
Sulfide
SAMPLE
177.
Fluoride by Specific Ion.
CAS RN
16984-48-8
COMPONENT
Fluoride
mg\Kg
ND*-No«inal Detection Limit-<1.0 ag/Kg
-------
PICHER
RESEARCH
LABORATORY
E-P Analytical Report Work Order *87-02-123-06A
Customer ID:Pit M Ash Sample Run #2
Metals analyzed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
725.
45.
43.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
* Dilution required because of interference.
-------
EMU
AESEAACH
LAJOflXrOffY
RICHER
E P Analytical Report
Customer ID:Pit M Run #6 Ash
Sample #87-04-113-03A
ug/K
Component
Benz[a)anthracene
Benzidine
Benzo[b]fluoranthene
Benzo[a)pyrene
2-Chlorophenol
Oibenz[a,h]anthracene
3f3'-Dichlorobenzidine
2,4-Dinitrotoluene
Hexachlorobenzene
PCB's (all coramon arochlors)
bis (2-chloroethyl) ether
-------
EMU
ACSEAACH
LABQMTOKY
PKHER
E-P Analytical Report
Customer ID: Pic M Ash Sample Run *2
CC Procedure 8080. 8150, and 8140.
Work Order #87-02-123-06A
CAS RN
309-0*0-2
319-84-6
12674-11-2
11104-23-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-3
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beca-BHC
Chlordane
ODD
DOE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endoaulfan II
Endrin
Endrin aldehyde
gamna-BHC
Hepcachlor
Hepcachlor epoxide
laodrin
Kepone
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.008
<0.008
<0.016
<0.016
<0.008
<0.016
<0.008
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2 0,0-Diethyl 0-2-pyraxinyl <1.0
PhotphorochioaCe
298-04-4 Diiulfoton <0.33
52-85-7 . Faaphur <3.3
298-00-0 Hethy1 paraChion <0.33
56-38-2 Parathion <0.33
298-02-2 Phorate <1.6
3689-24-5 Tetraethyldithiopyrophotphate <1.0
CC Procedure 8150
94-75-7 ' 2,4- Dichlorophenoxyacecic acid <0.33
93-76-5 2,4,5-T <0.33
93-72-1 Silvex <0.33
-------
RICHER
LABORATORY
E-P Analytical Report Work Order * 87-02-123-06A
EPA SW-S46 METHOD 8270
CAS RN
100-02-7
924-16-3
55-18-5
62-75-9
86-30-6
10595-95-6
59-89-2
100-75-4
99-55-3
106-44-5
608-93-5
82-63-3
87-86-5
62-44-2
85-01-3
103-95-2
109-06-8
23950-58-5
129-00-0
108-46-3
94-59-7
88-35-7
95-94-3
1746-01-6
58'<»0-2
110^57-6
10061*02-6
120-82-1
75-70-r7
95-r95i4
88-06t2
126-72-7
COMPONENT
4-Nitroph.snol
il-Nitrosodi-n-butylaaine
^-NitrotodieThylaaine
^-Nitrosodimethylaaine
N-Ni troiodiphenylaraine
£-!iitrosomethylechylaaine
][-Nitro«ooi«eridi»»»
}[-Nitrosopyrrolidine
F-rNitrn-£-toluidine
ortho-Cre"«ol
para-Cresol
Pentachlorobenzene
Pent ach lor odibenzo-n-dioxins
Pentachlorodibenzofurans
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
2-Picoline
Pronamide
Pyrene
Resorcinol
Safrole
2-aec-flutyl-4,&-dinitrophenol
1 ,2,4,5-Tetrachlorobenzene
2,3, 7,8-Tetrachlorodibenzo-£-
dioxin
Tetrachlorodibenzo-t>-dxoxin«
Tetrachlorodibenzofurans
2,3,4,6'Tetrachloronh^nol
tran«-l f4-Diehloro-2-butene
tr*n«-l ,3-Dichloroprooen*
l,2,/»-Trichlorobenzene
Trichloromethanethiol
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
Tris-( 2, 3-Hibromopropyl) phosphate
<0.067
<0.067
ND*
ND*
<0.005
<0.33
ND*
<1.6
<.033
ND*
ND*-Nominal Detection Limif'1.0 ag/Kg
-------
E-P Analytical Report Work Order * 87-02-123-06A
EPA SW-846 Method 8270
CAS RN COMPONENT
120-83-2 2,4-Dichlorophenol
87-65-0 2,6-Dichlorophenol
84-66-2 Oiethyl phthalate
119-90-4 3,3'-Diaethoxybenzidine
60-11-7 £-Diaethyloainoazobcnzene
57-97-6 7,12-Dinethyli>«nzta]anthracene
119-93-7 3,3'-Di.aethylbenzidine
105-67-9 2,4-Dinechylphenol
131-11-3 Di.n«sthyl phthalate
Dinethylterephthalate
534-52-1 4,6-Di.nitro-^-cresol
51-2u-5 2,4-Dinitrophenol
121-K-2 2,4-Dinitrotoluene
606-20-2 2,6-Dinitrotoluene
117-84-0 Di-£-octyl phtlialate
122-39-4 Diphenylaaine
122-66-7 l,2-0iphenylhydrazin«
621-64-7 Di-n-propylnitrotafflinc
107-12-0 Eth7l cyanide
206-44-0 Fluoranthene
86-73-7 Fluorene
113-74-1 Hexachlorobenzene
87-68-3 Hexachlorobutadiene
77-47-4 Hexachlorocyclopentadiene
Hexachlorodibenzo-£-dioxin»
Hexachlorodibenzofurani
70-:30-4 Hexachloropheae
1883-71-7 Uexachloropropene
Hydrazine
193-3.9-5 Tnd«no(l,2,3-cd)pvrea^
78.-59-rl Isophorone
120-58-1 I«o»afrole
109-77-3 Malonicrile
100-25-4 neta-Dinitrobenzene
126-98-7 Methacrylonitrile
91-80-5 Mechapyrilene
56-49-5 Methylcholanthrene
Methyl chrysene
101-14-4 4,4'-:tethyleaebis(2-ehloroanilin«)
80-62-6 Methyl nechacrylate
66-27-3 Methyl nechane«ulfonate
91-57-6 2-Methylnaphthalcne
108-10-1 4-Methyl-2-pcntanone
Methyl phenyl diaaine
91-20-3 Naphthalene
134-32-7 1-NaphthyUmine
91-59-3 2-Naphthylaaine
130-15-4 1,4-Naphthoquinone
88-74-4 2-Nitroaniline
99-09-2 3-Nitroanilin*
100-rOl-6 £-Nitroaniline
9a*r95-t Nitrobenzene
88-75-3 2-Nitrophenol
ND*"No.ainal Detection Litait»<1.0 mg/Kg
-------
AESE4ACM
LABORATORY
PKHER
E-P Analytical Report
Cua'tooer ID: Pit M Ash Sample Run #2
Work Order * 37-02-123-06A
EPA SW-346 METHOD 8270
mg/Kg
CAS RN COMPONENT SAMPLE
208-96-8 Acenaphthalen* <0.33
83-32-9 Acenaphthene <0.33
75-05-3 AcetonitriU ND*
98-86-2 Acetophenone ND*
53-96-3 2-Acetylaninofluorene ND*
107-13-1 Acrylonitrile MD*
122-09-3 Alpha,alpha-dimethylphenethylamine MD*
92-67-1 4-Arainobiphenyl ND*
62-53-3 Aniline <0.33
120-12-7 Anthracene <0.33
140-57-8 Aramite ND*
56-55-3 Benz[a]anthracene <0.33
108-»98-5 Benzenethiol ND*
92-87-5 Benzidine <1.6
205-99-2 Benzo(bjfluoranthene <0.33
207-08-9 3*nzo[k]j fluoranthene <0.33
65-85-0 Benzoic acid <1.6
106-51-4 £-Senzoquinone . ND*
191-24-2 Benzo(ghi)perylene <0.33
50-32-8 Benzo[a)pyrene <0.33
100-51-6 Benzyl alcohol <0.33
117-81-7 fli«(2-ethylhexyl)phthalate <0.33
101-55-3 4-Broaophenyl phenyl ether <0.33
85-68-7 Butyl benzyl phthalate <0.33
106-47-8 £-Chloroaniiine ' <0.33
510-15-6 Chlorobenzilate ND*
126-99-8 2-Chloro-l,3-butadiene ND*
59-50-7 £-Chloro-m-creiol <0.33
110-75-8 2-ChloroeIhyl vinyl ether <0.10
Chloromethylaethylether ND*
91-58-7 2-Chloronaphthalene <0.33
95-57r8 2-Chlorophenol <0.33
7005-72-3 4-rChlorophenyl phenyl ether <0.33
107-05-1 3-Chloropropene ND*
218-01-9 .Chrycen* <0.33
10061-01-5 ci«-l,3-Dichloropropene <0.005
Dibenz[a,h]acridine ND*
53?70-3 Dib«nz[a,h]anthracene <0.33
132-64-9 Dibenzofuran <0.33
192-65-4 Dibenzo[a,e]pyrene ND*
189-64-0 Dibenzo[afh]pyrene ND*
189-55-9 Dibenzo[a,i]pyrene ND*
84-74-2 Di-£-butyl phthalate <0.33
541-73-1 m-Dichlorobenzene <0.33
95-50-1 £-Dichlorobenzene <0.33
106-46-7 £-Dichlorobenzene <0.33
91-94-1 3,3'^Dichlorobenzidine <0.66
ND*-Nominal Detection Lirait«<1.0 ng/Kg
-------
EMLE
ftESCAftCM
LABORATORY
PKHER
E-P Analytical Report Work Order # 87-02-123-06A
Cufcomer 10: Pic M Ash Sample Run #2
SWr846 Method 8240
CAS RN
67-64-1
107-02-3
71-43-2
111-91-1
111-44-4
lOti-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-43-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-*
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5
79-01-r6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT SAMPLE
Acetone <0.010
Acrolein NO*
Benzene <0.005
Bis(2-chloroethoxy) methane <0.33
BU(2-chlaroethyl) ether <0.33
8is(2-chloroisopropyl) echtr <0.33
Bromodichloromethane <0.005
Broaomethane <0.010
Carbon disulfide <0.005
Carbon Tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibroaomethane <0.005
l-Chloro-2,3-epoxypropane ND*
Chloroethane <0.010
Chloroform <0.005
Chloromethane <0.010
1,2-Dibrorao-3-chloropropane ND*
1,2-Oibronoethane ND*
Dibronomethane ND*
Di.cn lorodifluorome thane ND*
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
Dichlororaethane <0.005
1,2-Dichloropropane <0.005
Ethyl benzene <0.005
Hexachloroethane <0.33
2-Hexanone <0.010
lodomethane ND*
Iiobutanol ND*
Methyl ethyl ketone <0.010
Methyl isobutyl ketone ND*
Pentachloroechane ND*
Pyridine <0.33
Styrene
-------
EAQLE
RESE4ACH
LABORATORY
MCHER
E-P Analytical Report Vtork Order # 87-02-123-05A
Pic M Aah Sanple Run tl
A heated purge and Crap modification of Method 3240.
I mm
CAS RN
107-18-6
542-76-7
123-91-1
75-21-8
97-63-2
78-83-1
107-19-7
COMPONENT
Allyl alcohol
3-Chloropropionitrile
1 ,4-Dioxane
Echylene oxide
Ethyl mechacrylace
Itobutyl alcohol
2-Propyn-l-ol
SAMPLE
MD*
MD*
MD*
ND*
MO*
SO*
ND*
Method 9010 for determination of total and amenable cyanide •
mg\Kg
CAS RN
106-51-4
COMPOMENT
Cyanide
Determination of aulfide by ICP/AES.
»g\Kg
CAS RN
13496-25-8
COMPONENT
Sulfide
SAMPLE
268.
Fluoride by Specific Ion.
CAS RN
16984-48-8
COMPONENT
Fluoride
ND*»Nominal Detection Limit-<1.0 ag/Kg
-------
EAQLELf°>PKHER
HKCABCH
LABORATORY
E-P Analytical Report Work Order #87-02-123-05A
Customer ID:Pit M Ash Sample Run #1
Metals analyzed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471 .
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
SAMPLE
35,900.
* <4.
158.
1.3
3420.
23.
42.
19,900.
12.
3910.
148.
<.04
23.
57.
6300.
1.9
570.
41.
47.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
Dilution required because of interference.
-------
AESEAACM
LASOMTDAY
PICHER
E-P Analytical Report
Cuatomer ID: Pit M A§h Sample Run #1
GC Proecdurt 8080, 8150, and 8140.
Work Ordar #87-02-123-05A
CAS RN
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-r89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1243
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
ODE
DDT
delta-BHC
Dieldrin
Endoaulfan I
Endoaulfan II
Endrin
Endrin aldehyde
gaauu-BHC
Heptachlor
Heptachlor epoxide
laodrin
Kepoot
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.008
<0.008
<0.016
<0.016
<0.016
<0.008
<0.016
<0.008
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2 0,0-Diethyl 0-2-pyra*inyl <1.0
Phoaphorothioate
298-04-4 Diaulfocon <0.33
52-85-7 Faaphur O-3
298-rOO-O . Methyl paraChion <0.33
56-J38-2 Parathion <0.33
298-02-2 Phorate
-------
EAGLE UjpMCHER
LABORATORY
E-P Analytical Report Work Order * 37-02-123-05A
EPA SW-S46 METHOD 8270
CAS RN COMPONENT
100-02-7 4-Nitrophenol
924-16-3 N-Nitroiodi-ti-butylamine
55-18-5 £-Nitro»odiethylainine
62-75-9 £-Nitrotodimethylaraine
36-30-6 ^-Nitrosodiphenylamine
10595-95-6 ^-Nitrosoaiethylethylaaine
59-39-2 £-Nitrosotnorpholine
100-75-4 N-Nitrosopiperidine
930-55-2 ]5-iJitrosopyrrolidine
99-55-3 5~-Nicro-£-toluidine
95-48-7 ortho-Cre"sol
106-44-5 para-Cresol
608-93-5 Pentachlorobenzene
Pentachlorodibenzo-£-dioxins
Pentachlorodibenzofurans
32-63-3 Pentachloronitrobenzene
37-36-5 Pentachlorophenol
62-44-2 Phenacetin
35-01-8 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-53-5 Pronaaide
129-00-0 Pyrene
103-46-3 Resorcinol
94-59-7 Safrole
88-35-7 2-se£-Butyl-4,6-dinitrophenol
95-94-3 1,2,4,5-Tetrachlorobenzene
1746-01-6 2,3,7,3-Tetrachlorodibenzo-£-
dioxin
Tetrachlorodibenzo-£-dioxins
Tetrachlorodibenzofurana
58-90-2 2,3,4,6-Tetrachlorophenol
110-57-6 tran«-l,4-Dichloro-2-butene
10061-02-6 tran«-l,3-Dichloropropene
120-32-1 1,2,4-Trichlorobenzene
75-70-7 Trichloroaethanethiol
95-95-4 2,4,5-Trichiorophenol
88-06-2 2,4,6-Trichlorophenol
126-72-7 Tri§-(2,3-dibromopropyl)phosphate
<0.067
<0.067
<0.067
NO*
HO*
<0.005
<0.33
MD*
<1.6
<.033
ND*-Nominal Detection Linit"<1.0 mg/Kg
-------
RICHER
AESCAACH
LA8OMTOKY
E-P Analytical Report Work Order t 87-02-123-05A
EPA S'V-846 Method 8270
CAS RN COMPONENT SAMPLE
120-83-2 2,4-Diciilorophenol <0.33
87-65-0 2,6-Dichlorophenol ND*
84-66-2 Oiethyl phthalate <0.33
119-90-4 3i3'-Dinethoxybenzidine NO*
60-11-7 £-Di=iethylaminoazobenzene NO*
57-97-6 7,12-Dimethylbenz(aJanthracene ND*
119-93-7 3,3'-Diaethylbenzidine 5»D*
105-67-9 2,4-Diaethylphenol <0.33
131-11-3 Diaethyl phthaUte <0.33
Difflethylterephthalate ND*
534-52-1 4,6-Dinitro-£-cresol <1.6
51-23-5 2,4-Dinitrophenol <1.6
121-14-2 2,4-Dinitrotoluene <0.33
606-20-2 2,6-Dinitrotoluene <0.33
117-34-0 Di-n-octyl phthalate <0.33
122-39-4 Diphenylamine KD*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-jn-propylnitrosamine <0.33
107-12-0 Ethyl cyanide ND*
206-44-U Fluoranthene <0.33
86-73-7 Fluorene <0.33
118-74-1 Hexachlorobenzene <0.33
87-68-3 Hexachlorobutadiene <0.33
77-47-4 Hexachlorocyclopentadiene <0.33
Hexichlorodibenzo-£-dioxin» ND*
Hexachlorodibenzofuran* ND*
70-30-4 Hexachlorophene ND*
1S8S-71-7 Hexachloropropene ND*
Hydrazine ND*
193-39-5 Indeno(l,2,3-cd)pyrene <0.33
78-59-1 Isophorone <0.33
120-58-1 I«o««frole ND*
109-77-3 Malonitrile ND*
100-25-4 aeca-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
Methyl chryiene ND*
101-14-4 4,4'-Methylenebii(2-chioroaniline) ND*
80-62-6 Methyl aethacrylate ND*
66-27-3 Methyl methanesulfonate ND*
91-57-6 2-Methylnaphthalene <0.33
108-10-1 4-Methyl-2-pentanone <0.010
Methyl phenyl dianine ND*
91-20-3 'Naphthalene <0.33
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone ND*
88-74-4 2-Nitroaniline <1.6
99-09-2 3-Nitroaniline <1.6
100-01-6 £-Nitroaniline <1.6
98-95-3 Nitrobenzene <0.33
88-/S-5 2-Nitrophenol <0.33
ND*"Noninal Detection LiaitB<1.0 mg/Xg
-------
RICHER
U&OMTOfrf E-P Analytical Report Work Order # 87-02-123-05A
Customer ID: Pit M Ash Sample Run *1
EPA SU-846 METHOD 8270
mg/Xg
CAS RN COMPONENT SAMPLE
203-96-8 Acenaphthalene <0.33
83-32-9 Acenaphthene <0.33
75-05-3 Acetonitrile ND*
98-36-2 Acetophenone ND*
53-96-3 2-Acetyianinofluorene ND*
107-13-1 Acrylonitrile NO*
122-09-3 Alpha, al^ha-diaiechylphenethylauine ND*
92-67-1 4-Aainobiphenyi ND*
62-53-3 Aniline <0.33
120-12-7 Anthracene <0.33
140-57-3 Araraice ND*
56-55-3 Benz[a]anthracene <0.33
108-90-5 Benzenechiol ND*
92-37-5 Senzidine <1.6
205-99-2 Benzo[b]fluoranthene <0.33
207-08-9 Benzo[<]fluoranthene <0.33
65-85-0 Benzoic acid <1.6
106-51-4 £-Senzoquinone ND*
191-24-2 Benzo(^hi)perylene <0.33
50-32-8 Benzo[a]pyrene <0.33
100-51-6 Benzyl alcohol <0.33
117-81-7 Bis(2-ethylhexyl)phthalate <0.33
101-55-3 4-Broaophenyl phenyl ether <0.33
85-68-7 Butyl benzyl phthalate <0.33
106-47-8 £-Chloroaniline <0.33
510-15-6 Chlorobenzilate NO*
126-99-3 2-Chloro-l,3-butadiene ND*
59-50-7 £-Chloro-fn-cresol <0.33
110*75-8 2-ChloroeThyl vinyl ether <0.10
Chloroiaethylmethylether ND*
91-58-7 2-Chloronaphthalene <0.33
95-57-8 2-Chlorophenol <0.33
7005-72-3 4-Chlorophenyl phenyl ether <0.33
107-05-1 3-Chloropropene ND*
218-01-9 Chrysene <0.33
10061-01-5 cis-l,3-Dichloropropene <0.005
Dibenz(a.h]acridine ND*
53-70-3 Dibenx[«,h]anthracene <0.33
132-64-9 Dibenzofuran <0.33
192-65-4 Dibenzo[a,e]pyrene ND*
189-64-0 Dibenzo[a,h]pyrene ND*
189-55-9 Dibenzo[a,ilpyrene ND*
84-74-2 Di-n-butyl phthalate <0.33
541-73-rl m-Dichlorobenzene <0.33
95-50-1 £-Dichlorobenzene <0.33
106-46-7 £-Dichlorobenzene <0*33
91-r94-rl 3,3'-Dichlorobenzidine <0.66
ND*"Norainal Detection Liait-<1.0 rag/Kg
-------
RICHER
E-P Analytical Report Work Order * 87-02-123-05A
Cuatomer ID: Pit M Aah Sample Run #1
SW-846 Method 8240
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-33-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71^8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74-^88-4
.78-93-3
76-01-7
110-86-1
100r42-5
630-20-6
79-J34-5
127-18-4
108-88-3
156-60-5
75-25-2
71^55-6
79-00-5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT SAMPLE
Acetone <0.010
Aerolein ND*
Benzene <0.005
Bi»(2-chloroethoxy) •ethane <0.33
Bis(2-chloroethyl) ether <0.33
Bis(2-chloroi»opropyl) ether <0.33
Sronodichlororaethane <0.005
Bronomethane <0.010
Carbon disulfide <0.005
Carbon Tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibromomethane <0.005
l-Chioro-2,3-epoxypropane ND*
Chloroethane <0.010
Chlorofona <0.005
Chloromethane <0.010
l,2-Dibromo-3-chloropropane ND*
1,2-Dibronoethane ND*
Dibrononethane ND*
Dichlorodifluoromethane ND*
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
Dichloromethane ' <0.005
1,2-Dichloropropane <0.005
Ethyl benzene <0.005
Hexachloroethane <0.33
2-Hexanonc <0.010
lodomethane ND*
laobutanol ND*
Methyl ethyl tee tone <0.010
Methyl iaobutyl ketooe ND*
Pentachloroethane ND*
Pyridine <0.33
Styrene <0.005
1,1,1,2-Tetrachloroethane <0.005
1,1,2,2-Tetrachloroethane <0.005
Tetrachloroethene <0.005
Toluene <0.005
Trana-1,2-Dichloroethane <0.005
Tribromone thane <0.005
1,1,1-Trichloroethane <0.005
1,1,2- Trichloroethane <0.005
Trichlorocthene <0.005
Trichlorononofluoromethane <0.005
Trichloropropane ND*
Vinyl chloride <0.010
Xylene (total) <0.005
ND*«Morainal Detection Liait"<1.0 tig/Kg
-------
EMLELfpnCHER
E-P Analytical Report Work Order # 87-02"123*04A
Pit I Aih Sample Run #2
A heated purge and trap nodification of Method 8240.
CAS RN
107-18-6
542-76-7
123-91-1
75-21-8
97-63-2
78-83-1
107-19-7
COMPONENT
Allyl alcohol
3tChloropropionitrile
1 ,4-Dioxane
Ethylene oxide
Ethyl methacrylate
Isobutyl alcohol
2-Propyn-l-ol
SAMPLE
NO*
NO*
ND*
NO*
ND*
ND*
ND*
Method 9010 for determination of total and amenable cyanide.
CAS RN
106-51-4
COMPONENT
Cyanide
Determination of sulfide by ICP/AES.
CAS RN
18496-25-8
COMPONENT
Sulfia,-
•g\Kg
SAMPLE
3940.
Fluoride by Specific Ion.
CAS RN
COMPONENT
16984-48-8 Fluoride
ND*-No«inai Detection Liait-<1.0
-------
PKHER
E-P Analytical Report Work Order * 37-02-123-01A
Cuatoner ID: Pic J Ash sample Run tl
SU-846 Method 8240
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-33-9
75-15-0
56-23-5
108-90-7
124-43-i
75-00-3
67-66-3
74-87-3
96-12-3
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
73-87-4
100-41-4
67-72-1
591-78-6
74-88-4
78-93-3
76-01-r7
110-86-1
I00-r42f5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-^5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT SAMPLE
Acetone 0.39
Acrolein ND*
Benzene 0.092
Bis(2-chloroethoxy) aethane <0.33
Bis(2-chloroethyl) ether <0.33
Bis(2-chloroisopropyl) ether <0.33
Bronodichlorooethane <0.005
Bronomethane <0.010
Carbon disulfide <0.005
Carbon Tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronora*thane <0.005
l-Chloro-2,3-epoxypropane ND*
Chloroethane <0.010
Chlorofora <0.005
Chioromethane <0.010
1t2-Dibroao-3-chloropropane ND*
1,2-Di broraoe thane ND*
Dibrononethane ND*
Dichlorodifluoromethane ND*
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
Dichloromethane 0.99
1,2-Dichloropropane <0.005
Ethyl benzene <0.005
Hexachloroethane <0.33
2-Hexanone <0.010
lodomethane ND*
Isobutanol ND*
Methyl ethyl kctone <0.010
Methyl isobutyl ketone ND*
Pentachloroethane ND*
Pyridine <0.33
Styrene <0.005
1,1,1,2-Tetrachloroethane <0.005
1,1,2,2-Tetrachloroethane <0.005
Tecrachloroethene <0.005
Toluene <0.005
Trans-1,2-Dichloroethane <0.005
Tribroraomethane <0.005
1,1,1-Trichloroethane 0.034
I,1,2- Trichloroethane <0.005
Trichloroethene 0.046
TrichloromonofluoroMthane <0.005
Trichloropropane ND*
Vinyl chloride <0.010
Xylene (total) <0.005
ND*"Noninal Detection Limit-<1.0 ag/Kg
-------
RICHER
RESEARCH
E-P Analytical Report
Customer ID: Pic J A*h Sample Run #1
EPA SW-846 METHOD 8270
CAS RN COMPONENT
208*96-8 Acenaphchalene
83-32-9 AcenaphChene
75-05-3 Aceconicrile
98-86-2 Acetophenone
53-96-3 2-Acecylaainofluorene
107-13-1 Acrylonitrile
122-09-8 Alpha, alpha-dinethylphencthylaaine
92-67-1 4-Aminobiphenyl
62-53-3 Aniline
120-12-7 Anthracene
140-57-8 Aramite
56-55-3 B*nz[ a] anthracene
108-98-5 Benzene thiol
92-87-5 Benzidine
205-99-2 Benzo[ b] fluoranthene
207-08-9 Benzol k] fluoranthene
65-85-0 Benzoic acid
106-51-4 £-Benzoquinone
191-24-2 Benzo(ghi)perylene
50-32-8 Benzo[ a] pyrene
100-51-6 Benzyl alcohol
117-81-7 Bi$(2-ethylhexyl)phthalate
101-55-3 4 -Broao phenyl phenyl echer
85-68-7 Butyl benzyl phthalate
106-47-8 £-Chloroaniline
510-15-6 Chlorobenzilate
126-99-8 2-Chloro-l,3-butadien«
59-50-7 £-Chloro-m-cre«ol
110-75-8 2-Chloroe7hyl vinyl ether
ChlororaechylmeChylether
91-53-7 2-Chloronaphthalene
95-57-8 2-Chiorophenol
7005-72-3 4-Chlorophenyl phenyl «ther
107-05-1 3-Chloropropene
218-01-9 Chrytene
10061-01-5 eit-l,3-Dichloropropcne
Dibenz[a,h)acridine
53-70-3 Dibenz I a, h] anthracene
132-64-9 Dibenzofuran
192-65-4 Dibenzo[a,e]pyrene
189-64-0 Dibenzo[a,h)pyrene
189-55-9 Dibenzo[a,i)pyrene
84-74-2 Di-n-butyl phthalate
541-73-1 •-Dlchlorobenzene
95-50-1 o"-Dichlorobenzene
106-46-7 £-Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidine
Work Order # 87-02-123-01A
ND*
ND*
<0.33
<0.33
ND*
<0.33
ND*
<1.6
<0.33
<0.33
<1.6
ND*
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
<0.33
ND*
ND*
<0.33
<0.10
ND*
<0.33
<0.33
<0.33
ND*
<0.33
<0.005
ND*
<0.33
<0.33
ND*
ND*
ND*
<0.33
<0.33
<0.33
<0.33
<0.66
ND*-Nominal Detection Limit-<1.0 mg/Kg
-------
LABORATORY
E-P Analytical Report Work Order * 87-02-123-01A
EPA SU-846 Method 8270
CAS RN COMPONENT
120-83-2 2,4-Dichlorophenol
87-65-0 2,6-Dichlorophenol
84-66-2 Diethyl phthalate
119-90-4 3,3'-Dimethoxybenzidine
60-11-7 £-Diaiethylaminoazobenzene
57.97.5 7,12-Diaethylbenz(a]anthracene
119.93-7 3,3'-Dia«ethylbenzidine
105-67-9 2,4-Dimechylphenol
131-11-3 Dimethyl phthalate
DimethyIterephthalate
534-52-1 4,6-Dinitro-o-creiol
51-28-5 2,4-Dinicrophenol
121-14-2 2,4-Dinitrotoluene
606-20-2 2,6-Dinitrotoluene
117-34-0 Di-£-octyl phthalate
122-39-4 Diphenyiamine
122-66-7 1,2-Diphenylhydrazine
621-64-7 Di-£-propylnitro»amine
107-12-0 Eth^l cyanide
206-44-0 Fluoranthene
86-73-7 Fluorene
118-74-1 Hexachlorobenzene
87-68-3 Hexachlorobutadiene
77-?47-4 Hexachlorocyclopentadiene
Hexachlorodibenzo-£-dioxina
Hexachlorodibenzofuraos
70-30-4 Hexachlorophene
1888-71-7 Hexachloropropene
Hydrazine
.193-39-5 Indeno(l,2,3-cd)pyrene
78-59-1 Isophorone
120-58-1 laotafrole
109-77-3 Malonitrile
100-25-4 Mta-Dinitrobenzene
126-98-7 Methacrylonitrile
91-80-5 Methapyrilene
56-49-r5 Meehylcholanthrene
Methyl chrysene
101-14-4 4,4'-Methylenebii(2-chloroaniline)
80-62-6 Methyl methacrylate
66-27-3 Methyl methanesulfonate
91-57-6 2-Methylnaphthalene
108-10-1 4-Methyl-2-pentanone
Methyl phenyl diaainc
91-20-3 Naphthalene
134*r32-7 1-Naphthylamine
91-59-8 2-Naphthylamine
130-15-4 1,4-Naphthoquinona
88-74-4 2-Nitroaniline
99-09-2 3-Nitroaniline
100-01-r6 £-Nitroaniline
98-95-3 Nitrobenzene
88-75-5 2-Nitrophenol
<1.6
<1.6
<0.33
<0.33
ND*«Nomin*l Detection Limit"
-------
LABOKATOKY
E-P Analytical Report Work Order * 87-02-123-01A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
100-02-7 4-*Nitrophenol
924-16-3 N-Nitro»odi-£-butyU«ine
55-18-5 N-Nitro«odieithylaaine
62-75-9 £-Nitro»odiaethylamine
86-30-6 Tj-Nitro«odiphenylamine
10595-95-6 lj-Nitro«oraethyieChyU»ine
59-39-2 N-Nitrosouorpholine
100-75-4 £-Nitrosopip«ridine
930-55-2 N-Nitro«opyrrolidine
99-55-8 T-Nitro-o-toluidine
95-48-7 orcho-Crtiol
106-44-5 para-Cresol
608-93-5 Pentachlorobenzene
Pentachlorodibenzo-£-dioxins
Pentachlorodibenzofurans
82-63-8 Pentachloronitrobenzenc
87-86-5 Pentachlorophenol
62-44-2 Phenacetin
85^01-8 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoline
23950-58-5 Pronamide
129-00-0 Pyrene
108-46-3 Resorcinol
94-59-7 Safrole
88-85-7 2-»ec-Butyl-4t6-dlaitrcph«nol
95-94-3 1,2,4,5-Tetrachlorobenzene
1746-01-6 2,3,7,8-Te trachlorod ibenzo-£-
dioxin
Te trachlorodibenzo-£-dioxin«
Tc trachlorodibenzo furana
58-90-2 2,3,4,6-Tecrachlorophenol
110-57-6 trana-1,4-Dichloro-2-butene
10061-02r6 Crans-1,3-Dichloroprop*ne
120-82-1 1,2,4-Trichlorobenzene
75-70-7 . Trichloromethanethiol
95-95-4 2,4,5-Trichlorophenol
88-06-2 2,4,6-Trichlorophenol
126^72-7 Tr£•-(2t3-dibromopropyl)phosphate
<0.067
<0.067
<0.067
NO*
ND*
<0.005
<0.33
ND*
<1.6
<.033
ND*
ND*-Noo»in«l Detection Linit-<1.0 mg/Kg
-------
°PKHEfl
E-P Analytical Report
Pic J A*h Sample Run #1
RCSCAPCH
LABORATORY
Work Order # 87-102-123-01A
A heated purge and trap modification of Method 8240.
mg/Kg
CAS RN COMPONENT SAMPLE
107-18-6 Allyl alcohol ND*
542-76-7 3-Chloropropionitrile ND*
123-91rl 1,4-tDioxane ND*
Allyl alcohol
3-Chloropropionitrile
1,4<*Dioxane
75-21-8 Ethylene oxide
97-63-2 Ethyl nethacrylate
78-83-1 Iiobutyl alcohol
107-19-7 2-Propyn-l-oi
MD*
ND*
ND*
ND*
Method 9010 for determination of total and amenable cyanide.
mg\Kg
CAS RN
106-51-4
COMPONENT
Cyanide
Determination of aulfide by ICP/AES.
CAS RN
COMPONENT
18496-25-8 Sulfide
SAMPLE
1600.
Fluoride by Specific Ion.
CAS RM
16984-48-8
COMPONENT
Fluoride
ND*>Noeuaal Detection Li«it-<1.0 «g/Kg
-------
> RICHER
ACSC4ACH
uaofuromr
E-P Analytical Report
Customer ID: Pit J Ash Sample Run #2
SW-846 Method 8240
Work Order # 87-02-123-02A
•g/Kg
CAS RN
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-8
106-93-4
74-95-3
75-71r8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
.591-78-6
74-r88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-6
79-34-5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5
79-01-6
75-69-4
96-13-4
75-01-r4
1330-20-7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) tie thane
Bis(2-chloroethyl) ether
Bis(2-chloroisopropyl) ether
Bromod ichlororae thane
Broaomethane
Carbon disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibroaoraethane
l-Chloro-2,3-epoxypropane
Ch1oroethane
Chloroform
Chioromethane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
Dibromonethane
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Oichloroethane
1,1-Dichloroeehylene
Dichloromethane '
1,2-Dichloropropane
Ethyl benzene
Hexachloroethane
2-Hexanone
lodomethane
Isobutanol
Methyl ethyl kctone
Methyl isobutyl ketone
Pentachloroe thane
Pyridine
Styrene.
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Trans-1,2-Oichloroethane
Tribroraomethane
1,1,1-Trichloroethane
1,1,2- Trichloroethane
Trichloroethene
Trichloromonofluoromethane
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
0.094
ND*
0.075
<0.33
<0.33
<0.33
<0.005
<0.010
<0.005
<0.005
<0.005
<0.005
NO*
<0.010
<0.005
<0.010
NO*
ND*
NO*
ND*
<0.005
<0.005
<0.005
0.024
<0.005
<0.005
<0.33
<0.010
ND*
ND*
<0.010
ND*
ND*
<0.33
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
0.008
ND*
<0.010
<0.005
ND*"NoRiinal Detection Limit-<1.0 rag/Kg
-------
RICHER
RESEARCH
LABORATORY
E-P Analytical Report Work Order t 87-02-123-02A
Customer 10: Pic J Ash Sample Sun #2
EPA SW-346 METHOD 8270
CAS RN COMPONENT
208-96-3 Acenaphthalene
83-32-9 Acenaphthene
75-05-8 Acetonitrile
98-86-2 Acetophenone
53-96-3 2-Acetyla.uinofluorene
107-13-1 Acrylonitrile
122-09-8 Alpha,alpha-dime thyIphenethylamine
92-67-1 4-Arainobiphenyl
62-53-3 Aniline
120-12-7 Anthracene
140-57-8 Araraite
56-55-3 Benz[a]anthracene
103-9S-5 Benzenethiol
92-37-5 Benzidine
205-99-2 Benzo[b]fluoranthene
207-08-9 Benzo(k]fluoranthene
65-35-0 Benzoic acid
106-51-A £-Senzoquinone
191-24-2 Benzo(ghi)perylene
50-32-8 Benzo[a]pyrene
100-51-6 Benzyl alcohol
117-81-7 Bis(2-ethylhexyl)phthalace
101-55-3 4-Bromophenyl phenyl ether
85-63-7 Butyl benzyl phthalate
106-47-3 £-Chloroaniline
510-15-6 Chlorobenzilate
126-99-3 2-Chloro-l,3-butadiene
59-50-7 £-Chloro-m-cresol
110-75-8 2-ChloroeThyl vinyl ether
Chloroaethylaethylether
91-58-7 2-Chloronaphthalene
95-57-3 2-Chlorophenol
7005-72-3 4-Chlorophenyl phenyl ether
107-05-1 3-Chloropropene
218-01-9 Chry»«n«
10061-01-5 eis-1,3-Dichloropropent
Dibens[a,h]acridine
53-70-3 Dibetul a,, h| anthracene
132-64-9 Dibenzofuran
192-65-4 Dib«nzo(a,e]pyrene
189-64-0 Dibenzo(a,h]pyrene
189-55-9 Dibenzo[a,i]pyrene
84-74-2 Di-n-butyl phthalate
541-73-1 m-DTchlorobenzene
95-50-1 £-Dichlorobenzene
106-46-7 £-Dichlorobenzene
91T94-1 3,3'-Dichlorobenzidine
3-
ND*-Nominal Detection Limit-<1.0 mg/Kg
-------
RICHER
ACSC4ACH
LABOMTOfTf
E-P Analytical Report Work Order t 87-02-123-02A
EPA SW-846 Method 8270
CAS RN COriPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <0.33
87-65-0 2,6-Dichlorophenol ND*
84-66-2 Diechyl phthalate <0.33
119-90-4 3,3'-Dimethoxybenzidine NO*
60-11-7 £-Diaethylaninoazobenzene ND*
57-97-6 7,12-Dimethylbenzla)anthracene ND*
119-93-7 3,3'-Diaethylbenridine ND*
105-67-9 2,4-Diaethylphenol <0.33
131-11-3 Oiaethyl phthalate <0.33
Dimethylterephthalate ND*
534-52-1 4,6-Dinitro-£-cresol <1.6
51-28-5 2,4-Dinitroph"enol <1.6
121-14-2 2,4-Dinitrotoluene <0.^1
606-20-2 2,6-Dinitrotoluene <0.33
117-34-0 Di-ji-octyl phthalate <0.33
122-39-4 Diph"enyla:nine NO*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-£-pro?ylnitrotaaine <0>33
107-12-0 Eth^l cyanide ND*
206-44-0 Fluoranthene <0.33
86-73-7 Fluorene <0.33
118-74-1 Hexachlorobenzene <0.33
87-68-3 Hexachlorobutadiene <0.33
77-47-4 Hexachlorocyclopentadiene <0.33
Hexachlorodibenzo-£-dioxins ' ND*
Hexachlorodibenzofurans ND*
70-30-4 Hexachlorophene ND*
1883-71-7 Hexachloropropene ND*
Hydrazine ND*
193-39-5 Indeno(l,2,3-ed)pyrene <0.33
78-59-1 Isophorone <0.33
120-58-1 Isoiafrole ND*
109-77-3 Mmlonitrile ND*
100-25-4 meta-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
Methyl chrysene ND*
101-14-4 4f4'-Methylenebi«(2-chloroanilin«) ND*
80-62-6 Methyl methacrylate ND*
66-27-3 Methyl aethanesulfonate ND*
91-57-6 2-Methylnaphthalene <0.33
108-10-1 4-Methyl-2-pcntanone <0.010
Methyl phenyl dianine ND*
91-20-3 Naphthalene <0.33
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone ND*
88-74-4 2-Nitroaniline <1.6
99-09-2 3-Nitroaniline <1.6
100-01-6 £-Nitroaniline <1«6
93-95-3 Nitrobenzene <0.33
88-75-5 2-Nitrophenol <0.33
ND*"Noiainal Detection Li.ait«<1.0 rag/Kg
-------
RICHER
RESEARCH
LABORATORY
E-P Analytical Report Work Order # 37-02-123-02A
EPA SW-S46 METHOD 8270
CAS RN COMPONENT
100-02-7 4-Nitrophenol
924-16-3 N-Nitro«odi-n-butyla:nine
55-18-5 fi-NitrosodieThylamine
62-75-9 Tj-Nitrosodinethylamine
86-30-6 jN-Nitrosodiphenylaaiine
10595-95-6 ^-Nitrosonethylethylanine
59-89-2 £-Mitrosomorpholine
100-75-4 ^-NitrosopiperiJine
930-55-2 N-Nicrosopyrrolidine
99-55-8 5-Nitro-£-toluidine
95-43-7 ortho-Cre"sol
106-44-5 para-Cresol
603-93-5 Pentachlorobenzene
Pentachlorodibenzo-£-
-------
AESEAACH
LUOJUTDftY
RICHER
E-P Analytical Report
Customer ID: Pic J Aah Sample Run t2
CC Procedure 8080, 8150, and 8140.
Work Order #87-02-123-02A
CAS RN
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
DDE
DDT
delca-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
gaoma-BHC
Heptachlor
Heptachlor epoxide
Isodrin
Kepone
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.008
<0.008
<0.016
<0.016
<0.016
<0.008
<0.016
<0.003
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2 0,0-Diethyl 0-2-pyraxinyl <1.0
Phoaphorothioate
298-04-4 Diaulfoton <0.33
52-85-7 Faaphur <3.3
298-00-0 Methyl parathton <0.33
56-38-2 Parathion <0.33
298-02-2 Phorate <1.6
3689-24-5 TetraethyldithiopyrophoaphaCe <1.0
CC Procedure 8150
94-75-7 2,4- Dichlorophenoxyacecic acid <0.33
93-76-5 2,4,5-T <0.33
93r72-l Silvex <0.33
-------
RESEARCH
LABORATORY
RICHER
E P Analytical Report
Customer ID:?it J Run 02 Ash
Sample J87-04-U3-01A
Component
Benz[a]anthracene
Benzidine
Benzo[b]fluoranchene
Benzo[ajpyrene
2-Chlorophenol
Dibenz[a,h]anthracene
3,3'-Dichlorobenzidine
2,4-Oinitrotoluene
Hexachlorobenzene
PCS's (all common arochlors)
bis (2-chloroethyl) ether
-------
RICHER
Jt£S£AACH
LA8QMTOHY
E-P Analytical Report Work Order 08702123-02A
Customer ID:Pit J Ash Sample Run 02
Metals analyzed by Mthod given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminun
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
•I/Kg
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
* Dilution required because of interference.
-------
LABORATORY
E-P Analytical Report
E P Tox Extraction of Samples: 8702123-02A
8702123-03A
8702123-02A
Customer ID: Pit J Ash Sample Run f2
As
Ba
.51
Cd
<.OOS
Cr
.08
ng/L
Pb
.13
Hg
<.0002
S6
I -12 |
8702123-03A
Customer 13: Pit I Ash Sample Run >1
As
Ba
.55
Cd
.014
Cr
.09
ng/L
Pb
^^••H
.23
Hg
<.0002
Se
.05
-------
EAQJJ
RESEAACN
LABORATORY
PKHER
E-P Analytical Report
Pit J A»h Sample Run #2
Work Order # 87-02-123-02A
A heated purge and Crap •edification of Method 8240.
•I/Kg
CAS RN COMPONENT
107-18-* Ally! alcohol
542-76-7 3-Chloropropionitrile
123-91-rl 1,4-Dioxane
75-21-8 Ethylene oxide
97-63-2 Ethyl aethacrylate
73-^83-1 Isobutyl alcohol
107-19-7 2-Propyn-l-ol
Method 9010 for determination of total and amenable cyanide.
•g\Kg
CAS RN
106-51r4
COMPONENT
Cyanide
Oeterraination of aulfide by ICP/AES.
CAS RN COMPONENT
18496-25-8 Sulfide
SAMPLE
3010.
Fluoride by Specific Ion.
CAS RN
16984-48-8
COMPONENT
Fluoride
mg\Kg
ND*-No«inal Detection Li«ic»<1.0 mg/Kg
-------
EAGLE
E-P Analytical Report Work Order * 37-02-123-03A
Customer ID: Pit I Aah Sample Run fl
SW-S46 Method 8240
mg/Kg
CAS R2J
67-64-1
107-02-8
71-43-2
111-91-1
111-44-4
108-60-1
75-27-4
74-83-9
75-15-0
56-23-5
108-90-7
124-48-1
75-00-3
67-66-3
74-87-3
96-12-3
106-93-4
74-95-3
75-71-8
75-34-3
107-06-2
75-35-4
75-09-2
78-87-4
100-41-4
67-72-1
591-78-6
74r88-4
78-93-3
76-01-7
110-86-1
100-42-5
630-20-*
79-34-5
127-18-4
108-88T3
156-60-5
75-25-2
71-55-r6
79-00-5
79-01-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPONENT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) methane
Bis(2-chloroethyl) ether
Bis(2-chloroisopropyl) ether
Bromodichlorome thane
Brotaome thane
Carbon disulfide
Carbon Tetrachloride
Chlorobenzene
Chlorodibronome thane
l-Chloro-2, 3 -e poxy propane
Chloroethane
Chloroform
Chlororae thane
l,2-Oibroao-3-chloropropane
1 , 2-Dibromoethane
01 bromorae thane
Dichlorodif luorome thane
1 , 1-Oichloroethane
1 ,2-Dichloroe thane
1 t 1-Dichloroethylene
Dichlorome thane
1 , 2-Dichloropropane
Ethyl benzene
Hexachloroe thane
2-Hexanone
lodome thane
Isobutanol
Methyl ethyl ketone.
Methyl isobutyl ketone
Pentachloroe thane
Pyridint
Styrene
1 t 1 i 1 ,2-Tetrachloroe thane
1 ,1,2,2-rTetrachloroethane
Tetrachloroethene
Toluene
Trans-l,2-Dichloroe thane
Tribromoae thane
1,1,1 -Trichloroe thane
1,1,2- Trichloroethane
Trichloroe thene
Trichloromonof luorome thane
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
0.18
ND*
<0.005
<0.33
<0.33
<0.33
<0.005
<0.010
<0.005
<0.005
<0.005
<0.005
ND*
<0.010
<0.005
<0.010
ND*
ND*
ND*
ND*
<0.005
<0.005
<0.005
0.074
<0.005
<0.005
<0.33
<0.010
MD*
ND*
<0.010
ND*
ND*
<0.33
<0.005
<0.005
-------
•MLEL^pPKHER
STABf^H
E-P Analytical Report
Customer ID: Pit I Ash Sample Run #1
AffSCAACH
LABOMTORI
Work Order * 87-02-123-03A
EPA SW-846 METHOD 8270
CAS UN COMPONENT SAMPLE
208-96-8 Ac«naphthalene <0.33
83-32-9 Acenaphchene <0.33
75-05-8 Acetonitrile NO*
98-86-2 Acecophenone ND*
53-96-3 2-Acetylaninofluorene NO*
107-13-1 Acrylonicrile NO*
122-09-3 Alpha, alpha-dimethylphenechylaraine ND*
92-67-1 4-Aninobiphenyl ND*
62-53-3 Aniline <0.33
120-12-7 Anthracene <0.33
140-57-3 Aramite ND*
56-55-3 Benz[a]anchracene <0.33
108-98-5 Benzenechiol ND*
92-87-5 Benzidine <1.6
205-99-2 Benzo[b]fluoranchene <0.33
237-08-9 Benzol kjfluoranchene <0.33
65-85-0 Benzoic acid <1.6
106-51-4 £-Benzoquinone ND*
191-24-2 Benro(ghi)perylene <0.33
50-32-8 Benzo[ajpyrene <0.33
100-51-6 Benzyl alcohol <0.33
117-81-7 Bis(2-echylhexyl)phCh«late <0.33
101-55-3 4-Bromophenyl phenyl ether <0.33
85-68-7 Butyl benzyl phthalate <0.33
106-47-8 £-Chloro aniline <0.33
510-15-6 Chlorobenzilate ND*
126-99-8 2-Chloro-l,3-butadiene ND*
59-50-7 £-Chloro-tn-cre«ol <0.33
110-15-8 2-ChloroeThyl vinyl ether <0.10
ChloromethylmethyleCher ND*
91-58-7 2-Chloronaphthalene <0.33
95-57-8 2-Chlorophenol <0.33
7005-72-3 4-Chlorophenyl phenyl ether <0.33
107-05-1 3-Chloropropene ND*
218-01-9 Chry«ene <0.33
10061r01-5 cis-l,3-Dichloropropene <0.005
Dibenz(a,h]acridine ND*
53-70-3 Dibenz( a, h] anthracene <0.33
132-64-9 Dibenrofuran <0.33
192-65-4 Dibenzo[a,e]pyrene ND*
189-64-0 Dibenzo[a,hjpyrene ND*
189-55-9 Dibenzo[a,i]pyrene ND*
84-74-2 Di-n-butyl phthalate <0.33
541-73-1 m-oTchlorobenzene <0.33
95-50-1 o-Dichlorobenzen* <0.33
106-46-7 £-Dichlorobenzene .33
91-94-1 3,3'-Dichlorobenzidine <0.66
ND*-Nominal Detection Liait»<1.0 mg/Kg
-------
RCSIABCH
LABOMTOM
E-P Analytical Report Work Order * 37-Q2-123-Q3A
EPA SW-846 Method 8270
CAS SN COMPONENT SAMPLE
120-83-2 2,4-Dichlorophenol <0.33
87-65-0 2,6-Dichlorophenol ND*
84-66-2 Diethyl phthalate <0.33
119-90-4 3,3'-Dimethoxybenzidine ND*
60-11-7 £-Di:aethylaminoazobenxene ND*
57-97-6 7,12-Ditnethylbenz[a]anthracene ND*
119-93-7 3,3'-Oiaethylbenzidine ND*
105-67-9 2,4-Dinethylphenol <0.33
131-11-3 Dimethyl phthaiate <0.33
Diraethylterephthalate ND*
534-52-1 4,6-Oinitro-o-cresol <1.6
51-23-5 2,4-Dinitrophenol <1.6
121-14-2 2,4-Dinitrotoluene <0.33
606-20-2 2,5-Dinitrotoluene <0.33
117-34-0 Di-n-octyl phthalate <0.33
122-39-4 Diphenyla-nine ND*
122-66-7 1,2-Diphenylhydrazine ND*
621-64-7 Di-n-propylnitrosaaine <0.33
107-12-0 Ethyl cyanide ND*
206-44-0 Fluoranthene <0.33
36-73-7 Fluorene . <0.33
113-74-1 Hexachlorobenzene <0.33
87-68-3 Hexachlorobutadiene <0.33
77-47-4 Hexachlorocyclopentadiene <0.33
Hexachlorodibenzo-£-dioxini ND*
HexachLorodibenzofuran* ND*
70-30-4 Hexachlorophene ND*
1888-71-7 Hexachloropropene ND*
llydrazine ND*
193-39-5 Indeno(l,2,3-cd)pyrene <0.33
78-59-1 liophorone 0.34
120-58-1 I«o«afrole ND*
109-77-3 Malonitrile ND*
100-25-4 meta-Dinitrobenzene ND*
126-98-7 Methacrylonitrile ND*
91-80-5 Methapyrilene ND*
56-49-5 Methylcholanthrene ND*
Methyl chryscne ND*
101-14-4 4,4'-;1«thylenebU(2-chloro«niline) ND*
80-62-6 Methyl aethacrylate ND*
66-27-3 Methyl methanesulfonaCe ND*
91-57-6 2-Methylnaphthalene <0.33
108-10-1 4-Methyl-2-pentanone <0.010
Methyl phenyl diamine ND*
91-20-3 Naphthalene <0.33
134-32-7 1-Naphthylamine ND*
91-59-8 2-Naphthylamine ND*
130-15-4 1,4-Naphthoquinone ND*
88-74-4 2-Nitroaniline <1.6
99-09-2 3-Nitroaniline <1.6
100-01-6 £-Nitroaniline <1.6
98-95-3 Nitrobenzene <0.33
88-75-5 2-Nitrophenol <0.33
ND*"Nominal Detection Liait«<1.0 mg/Kg
-------
E-P Analytical Report Work Order # 87-02-123-03A
EPA SW-346 METHOD 8270
CAS RN
100-02-7
924-16-3
55-18-5
62-75-9
86-30-6
10595-95-6
59-89-2
100-75-4
930-55-2
99-55-8
95-48-7
106-44-5
608-93-5
82-63-8
87-86-5
62-44-2
85-01*8
108-95-2
109-06-S
129-00-0
10 8-46 -r3
94-r59-7
88-35-7
95-94-3
1746-01-6
58-90-2
1 10^57-6
1006l-02r6
120-82-rl
75-70-7
95-95-4
88-06-2
1 2 6-72-7
COMPONENT
4-Nitrophenol
£-Nicroiodi-n-butyi«aine
TJ-Nitrotodielhylanine
£-NitroiodimeChyl«mine
2J-Nitro§odiphenyla«ine
?-Nicro8omethylechyl«mine
£-Nitrosomorpholine
£-Nitrosopiperidine
£-Nitros-pyrrolidine
5~-Nitro-£-toluiJine
ortho-Cr7sol
para-Cresol
Pentachlorobenzene
Pentachlorodibenzoflirans
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanchrene
Phenol
2-Picoline
Pyrene <0.33
Resorcinol ND*
Safrole ND*
2-«ec-Butyl-4,6-dinitropheitol ND*
1,2,4,5-Tecrachlorobenzene ND*
2,3, 7,8-Tetrachlorodibenzo^-
dioxin <0.067
Tetrachlorodibenzo-£-dioxin« <0.067
Tetrachlorodibenzofurans <0.067
2,3,4,6-Tetrachlorophenol ND*
Crans-l,4fDichloro-2-buceae ND*
tran»-l,3-Dichloropropene <0.005
1,2,4-Triehlorobenzene <0.33
Trichloromethanethiol ND*
2,4,5-Trichlorophenol <1.6
2,4,6-Trichlorophenol <.033
Trii-(2,3-dibromopropyl)pho«phate ND*
ND*-Nominal Detection Limit-<1.0 ag/Kc
-------
U&QfUaQW E-P Analytical Report
Customer ID: Pit I Aah Sample Run #1
GC Procedure 8080, 8150, and 8140.
Work Order #87-02-123-03A
CAS RN
309-00-2
319-84-6
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-85-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58-89-9
76-44-8
1024-57-3
465-73-6
143-50-0
72-T43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
beca-BHC
Chlordane
ODD
DOE
DDT
delta-BHC
Dieldrin
Endosulfan I
Endosulfan II
Endrin
Endrin aldehyde
ganma-BHC
Hepcachlor
Heptachlor epoxide
liodrin
Kepone
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
-------
RICHER
ftCSCAACH
E P Analytical Report
Sample #87-04-113-02A.
Customer 10:Pit I Run 03 Ash
ug/Kg
Component
Btnz[a]anthracene
Bcnzidine
Benzo[b]fluoranthene
Benzo[a]pyrene
2-Chlorophenol
Dibenz[a,h]anthracene
3,3'-Dichlorobenzidine
2,4«ninitrotolu«nc
Hexachlorobenzene
PCB's (all common arochlort)
bis (2-chloroethyl) ether
-------
LABORATORY
E-P Analytical Report Work Ordtr #87-02-123-03A
Customer ID:Pic I Ash Sample Run #1
Mecals analyzed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
mg/Kg
SAMPLE
26,000.
<12.
7.
175.
<1.
1.3
118,000.
22.
31.
1150.
25,400.
35.
3760.
372.
<.04
37.
65.
4110.
<1.
<2.
1851.
<2.
41.
71.
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
-------
EAGLE
ftCSCAACH
LABOMTOKV
RICHER
E-P Analytical Report
Pit I Ash Sample Run *1
Work Ordtr * 87-02-123-03A
A heated purgt and trap Modification of Method 8240.
•g/Kg
CAS RN
107-18-6
542-76-7
123-r91-l
75^21-8
97-63-2
78-r83fl
107-19-7
COMPONENT
Allyl alcohol
3-Chloropropionitrila
1 ,4-Dioxane
Echylana oxidt
Ethyl Mthacrylate
laobutyl alcohol
2-Propyn-l-ol
SAMPLE
ND*
NO*
ND*
ND*
ND*
ND*
ND*
Method 9010 for determination of total and amenable cyanide.
•g\Kg
CAS RN
106-51-4
COMPONENT
Cyanide
Determination of aulfide by 1CP/AES.
CAS RN
COMPONENT
18496-25-8 Sulfide
SAMPLE
9350.
Fluoride by Specific Ion.
CAS RN
16984-48-8
COMPONENT
Fluoride
•g\Kg
ND*-Nominal Detection Limit-<1.0 mg/Kg
-------
EAOUjjPKHER
PCSIMCH
E-P Analytical Report
Customer ID: Pit I Ash Sample Run #2
SU-846 Method 8240
Work Order * 37-^)2-123-04A
mg/Kg
CAS RN
67-64-1
107-02-3
71-43-2
111-91-1
111-44-4
108-60-1
75-27-;
74-83-9
75-15-0
56-23-5
108-90-7
124-48-1
75-rOO-3
67-66-3
74-37-3
96-12-3
106-93-4
74-95-3
75-71-8
75r34-3
107-06-2
75-35-4
75-09-2
78-87*4
100-41-4
67-72-1
591-78-6
74-88-4
7S-93-3
76-01-7
110-86-1.
100-42-5
630-20-6
79-34-r5
127-18-4
108-88-3
156-60-5
75-25-2
71-55-6
79-00-5 '
79-KH-6
75-69-4
96-18-4
75-01-4
1330-20-7
COMPOSE NT
Acetone
Acrolein
Benzene
Bis(2-chloroethoxy) methane
Bis(2-chloroethyl) ether
Bi«(2-chloroiiopropy 1) ether
Broaodichlororae thane
Bromomethane
Carbon disulfi.de
Carbon Tetrachloride
Chlorobenzene
Chlorodibr on one thane
l-Chloro-2 ,3-e poxy propane
Chloroethane
Chloroform
Chlorome thane
1 t2-Oibromo-3-chloropropane
1 t2-Dibromoe thane
Oibroraome thane
Dichlorodi fluorome thane
1 , 1 -Dichloroe thane
1,2-Dichloroe thane
1 ,1-Dichloroethylene
Dichlorooe thane
1 ,2-Dichloropropane
Ethyl benzene
Hexachloroe thane
2 -Hex a none
lod one thane
Isobutanol
Methyl ethyl ketone
Methyl isobutyl ketone
Pent achloroe thane
Pyridine
Styrene
1 1 1 , 1 ,2-Tetrachloroe thane
1, 1 ,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
Trans-1 , 2-Dichloroethane
Tribr on ome thane
1 , 1 , 1-Trichloroethane
1,1,2- Trichloroethane
Trichloroethene
Trichlororaono fluorome than*
Trichloropropane
Vinyl chloride
Xylene (total)
SAMPLE
0.37
ND*
0.057
<0.33
<0.33
<0.33
<0.005
<0.010
<0.005
<0.005
<0.005
<0.005
ND*
<0.010
<0.005
<0.010
ND*
ND*
ND*
ND*
<0.005
<0.005
<0.005
ND*
<0.005
<0.005
<0.33
<0.010
ND*
ND*
<0.010
ND*
ND*
<0.33
<0.005
-------
AfSEAACH
LABOMTOKf
RICHER
£•»? Analytical Report
Cu»comer ID: Pic I A*h Sample Run #2
Work Order # 87-02-123-04A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
208-96-8 Accnaphchalene
S3-32-9 AcenaphChene
75-05-3 Aceeonicrile
93-86-2 Acecophenone
53-96-3 2-Acetylaminofluorene
107-13-1 Acrylonitrile
122-09-3 Alpha,alpha-dimethylphenethylamine
92-67-1 4-.Vainobiphenyl
62-53-3 Aniline
120-12-7 Anthracene
140-57-8 Aramite
56-55-3 Benz[a]anthracene
108-98-5 Benzenethiol
92-87-5 Benzidine
205-99-2 Benzo[blfluoranthene
207-08-9 Renzn'k]fluoranthene
65-85-0 ••or.oic acid
106-51-4 £-Benzoquinone
191^24-2 Benzo(ghi)perylene
50-32-8 Benzo[a]pyrene
100-51-6 Benzyl alcohol
117-81-7 Bi«(2-ethylhexyl)phthalate
101-55-3 4-Bromophenyl phenyl echer
85-68-7 Butyl benzyl phthalate
106-47-8 £-Chloroaniline
510-15-6 Chlorobenzilate
126-99-8 2-Chioro-l,3-butadiene
59-50-7 p-Chloro-m-cre»ol
110-75-3 I-TChloroelhyl vinyl ether
Chloromethylmethylether
91-58-7 2-Chloronaphthaiene
95-57-3 2-Chlorophenol
7005-72-3 4-Chlorophenyl phenyl ether
107-05-1 3-Chioropropene
218-01-9 Chryiene
10061-01-5 cii-l,3-Dichloropropene
Dib*nx(a,h]acridine
53-70-3 Dibenz(a,h]anthracene
132-64-9 Dibcnzofuran
192-65-4 Dibenzo[a,e)pyrene
189-64-0 Dibenzo[a,hjpyrene
189-55-9 Dibenzo[a,ijpyrene
84-74-2 Di=n»butyl phthalate
541-73-1 m-Dlchlorobenzene
95-50-1 £-Dichlorobenzene
106-46-7 £-»Dichlorobenzene
91-94-1 3,3'-Dichlorobenzidine
ND*-Nominal Detection Limit-<1.0 mz/Kg
-------
RICHER
ftfSEAACH
LABORATORY
E-P Analytical Report Work Order * 87-02-123-04A
EPA SW-846 Method 3270
CAS RN COMPONENT SAMPLE
120-33-2 2,4-Dichlorophenol
-------
RICHER
ftCSCAACH
LABOMTOBY
E-P Analytical Report Work Order t 87-02-123-04A
EPA SW-846 METHOD 8270
CAS RN COMPONENT
i00-02-7 4-Nitrophenol
924-16-3 j)-Nitrosodi-ti-butylaaine
55-18-5 TJ-NitrosodieThylanine
62-75-9 jf-Nitrosodimethylamine
86-30-6 £-Nitrosodiphenyl«nine
10595-95-6 ft-Nitrosoaethylethylaaine
59-39-2 jN-Nitrosonorpholine
100-75-4 £-Nicrosopiperidine
930-55-2 ^-Nitroiopyrrolidine
99-55-8 5-Nicro-£-coluidine
95-48-7 ortho-Cre"iol
106-44-5 para-Cresol
608-93-5 Pentachlorobenzene
Pencachlorod ibenzo-£-d ioxins
Pentachlorodibenzofurans
32-68-S Pencachloronitrobenzene
87-86-5 Pencachlorophenol
62-44-2 Phenacetin
85-01-3 Phenanthrene
108-95-2 Phenol
109-06-8 2-Picoiine
23950-53-5 Prona-nide
129-00-0 Pyrene
108-46-3 Retorcinol
94r59-7 Safrole
88-85-7 2-iec-BuCyl-4.6-dinitrophenol
95-94-3 1,2,4,5-Tetrachlorobenzen*
1746-01-6 2,3,7,8-Tetr*chlorodibenzo-£-
dioxin
Tetrachlorodibenzo-£-dioxins
Tetraehlorodibenzofuranc
58-90-2 2,3,4,6-Tetrachlorophenol
110-57-6 trant-1,4-Dichloro-2-butene
10061-02-6 Crans-1,3-Dichloropropcne
120-82-1 1,2,4-Trichlorobenzene
75-70-7 Trichlorowethanethiol
95-95-4 2,4,5-Triehlorophenol
88-06-2 2,4,6-Trichlorophenol
126-72-7 Tri»-(2,3-dibromopropyl)phosphate
ND*»(tominal Detection Limit-<1.0 mg/Kg
<0.067
<0.067
O.067
MD*
ND*
<0.005
<0.33
ND*
<1.6
<.033
ND*
-------
E-P Analytical Report
Customer ID: Pit I A«h Sample Run #2
CC Procedure 8080, 8150, and 8140.
Work Order J87-02-123-04A
CAS RN
309-00-2
319-84-6
12674-11-Z
11104-23-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5
319-35-7
57-74-9
72-54-8
72-55-9
50-29-3
319-86-8
60-57-1
959-98-8
33213-65-9
72-20-8
7421-93-4
58^39-9
76-r44r8
1024-57-3
465-73-6
143-50-0
72-43-5
8001-35-2
Component
Aldrin
Alpha-BHC
Aroclor 1016
Aroclor 1221
Aroclor 1232
Aroclor 1242
Aroclor 1243
Aroclor 1254
Aroclor 1260
beta-BHC
Chlordane
ODD
DDE
DDT
delta-BUC
Dieldrin
Endosulfan I
Endoaulfan II
Endrin
Endrin aldehyde
gamma-BHC
Heptachlor
Heptachlor epoxide
Itodrin
Kepone
Methoxychlor
Toxaphene
Sample
<0.008
<0.008
<0.080
<0.080
<0.080
<0.080
<0.080
<0.160
<0.160
<0.008
<0.008
<0.016
<0.016
<0.016
<0.008
<0.016
<0.008
<0.016
<0.016
<0.016
<0.008
<0.008
<0.008
<0.080
<0.160
CC Procedure 8140
297-97-2
298-04-4
52-85-7
298-00-0
56-38-2
298-02-2
3689-24-5
0,0-Diethyl 0^2-pyra*inyl <1.0
PhoaphorothioaC*
Diiulfoton <0.33
Faaphur <3.3
Methyl parathion <0.33
Farathion <0.33
Phorate
-------
MSE4ACH
E-P Analytical Report Work Order 08702123-04A
CustooMr IDrPit I Ash Sample Run #2
Metals analysed by method given.
METHOD*
6010
6010
7060
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
6010
7471
6010
6010
6010
7740
6010
6010
7841
6010
6010
METHOD
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
ICP/AES
CVAA
ICP/AES
ICP/AES
ICP/AES
CFAA
ICP/AES
ICP/AES
GFAA
ICP/AES
ICP/AES
COMPONENT
Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
Lead
Magnesium
Manganese
Mercury
Nickel
Osmium
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
DETECT. LIMIT
10.
12.
2.
2.
1.
1.
2.
2.
10.
5.
4.
20.
2.
3.
.04
8.
20.
100.
1.
2.
2.
2.
10.
4.
-------
EAGLE
E p Analytical Report 87-02-158-02A
Custoaer ID:Pit B Make-up Water Run #2
Priority Pollutants Volatile Organic*
mg\L
COMPONENT SAMPLE
Ac role in <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloromethyi) ether <0.100
Bronofona <0.005
Carbon tetrachloride O.005
Chlorobenzene <0.005
Chlorodibroraoraethane <0.005
Chloroethane O.310
2-Chloroethvlvinyl ether <0.010
Chloroform <0.005
Dichlorobromomethane <0.005
Dichlorodifluoronethane <0.005
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
1,2-Dichloropropane O.OOS
1,3-Dichloropropylene 0.005
Ethylbenzene <0.005
Methyl bromide <0.010
Methyl chloride <0.010
Methylene chloride 0.036
1,1,2,2-Tetrachloroethane <0.005
Tetrachloroethylene <0.005
Toluene <0.005
1,2-Trans-dichloroethylene <0.005
1,1,1-Trichloroethane <0.005
1,1,2-Trichloroethane <0.005
Trichloroethylene <0.005
Trichlorofluororaethane <0.005
Vinyl chloride <0.010
-------
EAGLE
RESEARCH
LABORATORY E f Analytical Report Work Order #87-02-158-03A
Customer .ID: Pit B Scrubber Water Run II
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc 9.89
Priority Pollutants Miscellaneous
mg\L
COMPONENT SAMPLE
Total Cyanides <.01
Additional Analysis;
Tota.l Organic Carbon
Chloride
-------
EAGLE
E P Analytical Report
Customer ID:Pit fl Make-up Water Run #2
Priority Pollutants Acid Extractable Organic*
#87-02-1 58-O2A
COMPONENT
2-Chlorophenol
2,4-Dichlorophenol
214 -Di.ne thy 1 pheno 1
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenoi
p-Chloro-m-c reio1
Pentachlorophenol
Phenol
2,4,6-Tricnlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Gamraa-BHC
Delta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endos,ulfan I
Endosulfan II
Endosulfan sulfate
Endrin
End.rin aldehyde
Hepcachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
-------
EMLEL^pPKHER
AESEAftCH
E P Analytical Report
#87-02-158-02A
Customer. ID:Pit B Make-up Water Run #2
Priority Pollutants Base/M»utral Extractable Organic*
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
BenzoC a)anthracene
Benzo(a)pyrene
3,4-3enzofluoranthene
Benzo(^hi)perylene
BenzoC k)fluoranthene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis( 2-Ethylhexyl)phthalate
4-Brotnophenyl phenyl ether
Sutyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,2-Oiphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethan*
Indeno(1,2,3-c,d)pyrene
Itophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nitrosodi-n-propylaaine
N-Ni trosodiphenylaraine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3f7,8-TCDD
-------
E p Analytical Report 87-02-1 58-04A
Customer ID:Pit B Scrubber Water Run #2
Priority Pollutanti Volatile Organic!
SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloromethyl) ether <0.100
BromoJona <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronorae thane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Dichlorobrononethane <0.005
Dich lor odifluoroiae thane <0.005
1,1-Dichioroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
1 ,2-Dichloropropane <0.005
1 ,3-Dichloropropylene <0.005
Ethylbenzene <0.005
Methyl bromide <0.010
Methyl chloride <0.010
Methylene chloride 0.006
1,1,2,2-Tetrachloroethane <0.005
Tetrachloroethylene ^O.OOS
Toluene <0.005
1 ,2-Trans-dichloroethylene <0.005
1,1,1-Trichloroethane <0.005
1,1,2-Trichloroethane <0.005
Trichloroethylene <0.005
Trichlorof luoromethane <0.005
Vinyl chloride <0.010
-------
RICHER
LABORATORY E f Analytical Report Work Order f 87-02-1 58-02A
Customer .ID: Pit B Make-up w«ter tan *2
Priority Pollutants Metals «g\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chraniun
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
SAMPLE
Additional Analysis;
Total Organic Carbon
Chloride
-------
EAQLE^pPKHER
smAWH
E P Analytical Report
Customer ID:Pit B Scrubber Water Run #2
ftESCAACH
LABORATORY
Priority Pollutants Acid Extractable Organic*
#87-02-158-04A
COMPONENT
2-Chloropheno 1
2,4-Dichlorophenol
2,4-Diaethylphcnol
4,6-Dinitro-o-cresol
2,4-Dinicrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-n>-cre«ol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Gamma-BHC
Deita-BHC
Ch lordan*
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Hepcachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1243
PCB-1254
PCB-1260
Toxaohene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
LABOMTOftr E P Analytical Report
Customer !D:Pit B Scrubber Water Run #2
#87-02-158-04A
Priority Pollutants Base/Neutral Extractable Organic*
COMPONENT
Acenaphthene
Acenaphtaylene
Anthracene
Renzidi n?
BenzoC a)anthracene
Benzola)oyrene
3,4-Benzofluoraachene
Benzo(ghi)perylene
BenzoC k)fluoranthene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-EthyIhe»yi>phthalate
4-flroraophenyi phenyl eth«r
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Oichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl nhthalace
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeaof1,2,3-c,d)pvren?
Itophorone
Naphthalene
Nitrobenzene
N-'Nitrosodimethylamine
N-Nitrosodi-n-propylamine
N-Nicrosodiphenylamina
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
EAQLf^PKHER
RESEARCH , . ,
LABORATORY E P Analytical Report Work Order *87-02-l 58-04A
Cuscomer 10: Pic B Scrubber Water Run 42
Priority Pollutant* Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cad.niura
Chromium
Copper
Lead
Mercury
Nickel
Selenium
SiIver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
-------
M» I—,-> • •*• •
RESEARCH
2/10/87
2/11/37
2/12/87
None
None
None
Data for DIE Calculations
Brio Inlet & Stock Charcoal
£ 2.
.6617 <0.05
1.084 <0.05
.6619 <0.05
C D
14.0817 <7.04
14.874 <7.44
13.7019 <6.85
Column A: Weight of charcoal analyzed; gm
Column D: Amount of CCl^ found in charcoal analyzed; mg/kg
Column C: Total weight of charcoal; gm
Column 0: . ...Calculated amount of CC1. in
total charcoal; 10 gm ^
-------
RICHER
RCSC4ACH
LABORATORY
Inlec
-------
LABORATORY
Probe Wash Partieulate Weights
Customer I.D.
Inlet, gm Stack, gm
Pic
Pic
Pit
Pit
Pit
Pit
Pit
Pit
J
J
I
I
M
M
B
B
Run
Run
Run
Run
Run
Run
Run
Run
1
2
3
4
5
6
7
8
0
0
0
0
0
0
0
0
.0425
.0181
.0265
.0202
.0094
.0089
.0073
.0099
0
0
0
0
0
0
0
0
.0256
.0288
.0338
.0131
.0094
.0096
.0140
.0104
E-P Sample *'»
87-02-157-02A, -OIA
87-02-157-04A, -03A
87-02-156-02A, -OIA
87-02-156-04A, -03A
87-02-155-02A, -OIA
87-02-155-04A, -03A
87-02-154-02A, -OIA
87-02-154-04A, -03A
-------
RESEARCH
LABORATORY
for i)7E C;ilcul.ic ions
brio Inlet i ''.c.nck Charcoal
INLET
Shireo
Pit J
Pit J
I'ic I
Pic I
Hit M
Pit M
'Pit B
Pit B
Shireo
Pit J
Pic J
Pit I
Pic I
Pit M
Pic M
Pic B
Pit B
ID
R-l
a-2
K-3
R-4
R-5
R-6
R-7
R-8
ID
R-l
R-2
R-3
R-4
R-5
R-6
R-7
R-8
EPKL #
8702157-02A
3702157-04A
8702156-02A
8702156-04A
S702155-02A
S702155-04A
8702154-02A
87021 54-04A
SPRL *
8702157-01A
3702157-03A
S702156-01A
3702156-03A
8702155-01A
S702155-03A
8702154-01A
S702154-03A
A
.536
.3135
.4495
.5620
.6236
.8839
1.4911
.9997
A
.7962
.d446
1.1444
1.0454
1.1074
.9127
1.4613
1.3467
n
<0.05
<0.05
<0.05
<0.05
<0.05
0.072
<0.05
0.12
STACK
B
<0.05
<0.05
<0.95
<0.05
<0.05
<0.05
<0.05
<0.05
C D
13.956 <7.0
14.2385 <7.12
13.3695 <6.94
13.982 <7.u
14.0436 <7.0
14.3089 10.30
14.9111 <7.46
14.4197 17.3
C D
14.2162 <7.11
14.2646 <7.13
14.5644 <7.3
14.4654 <7.23
14.5274 <7.3
14.3327 <7.2
14.8313 <7.44
14.7667 <7.4
-------
EflaLEL5°>nCHER
E P Analytical Report 87-02-157-02A
Customer ID:Pit J Inlet Charcoal Tube Run £1
Priority Pollutants Volatile Organics
mg\Kg
COMPONENT SAMPLE
Acrolein <1.0
Acrylonitrile <1.0
Benzene <0.050
bis (Chloroiaethyl) ether <1.0
Broaofotm O.050
Carbon tetrachloride <0.050
Chlorobenzene <0.050
Chlorodi'uronone thane <0.050
Chloroethane <0.10
2-Chloroethylvinyl ether <0.10
Chloroform <0.050
Dichlorobronomethane <0.050
Oichlorodifluoronethane <0.050
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Hethylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylenft
Toluene
1,2-Trans-dichloroethylene
1,1,1-Trichloroethane
1,1,2,-Trichloroethane
Trichloroethylene
Trichlorofluoromethane
Vinyl chloride
-------
LABOMTOfTf
Inl*t and Stack Water
Chloride Results
Shirco I.D. Inlet, mg/L Stack, rag/L EP Sample »'s
Pit J Run 1 9590. <10. 87-02-157-02A, -01A
Pit J Run 2 4880. <10. 87-02-157-04A, -03A
Pit I Run 3 777.
Pit I Run 4 546.
87-02-1 56-02A, -01A
87-02-1 56-04A, -03A
Pit M Run 5
Pit M Run 6
667.
No Sample
Pit B Run 7 2870.
Pit B Run 8 2470.
87-02-1 55-02A, -01A
87-02-1 55-04A, -03A
87-02-1 54-02A, -01A
87-02-1 54-04A, -03A
Stack Water Blank <10. »g/L
-------
• SMdAOT MATOMAIS DIVISION '
• I AOU.MOVR KMAKH IAMMATOCY
LQPP-12
Revision:
Date: 11/25/86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Analytical
Procedures
Initiated By:
Sharon Parris
Approvals:
Quality .Assurance Dept.
EPRL
Director
1.0 Introduction
Analytical procedures for the analysis of samples include the
following:
1.1 Prescribed method for saople preparation, including observance
of stated saaple holding tines (such as shown on Table )and
necessary extractions, dilutions, etc.
1.2 Instrument standardization, including calibration and
preventive maintenance
1.3 Analytical techniques to be used in prcessing the sample
1.4 Prescribed format on prepared data sheets for
recording raw data which include:
Identification of project(s)
Identification of sample number(s)
Identification of Analyst
Identification of Analyst performing data validation
Dates for sample analysis and data validation
Raw data resulting from the analysis with appropriate
calibration standards and blanks.
-KAOLX
-------
> SFICIALTT MATHIAU DIVISION •
• IAWJ.PICHI* MSIAKH IABOIATOIY
LQPP-11
Revision: 1
Date 6-13-86
Page 4 of 4
2.8 verification/Reference Standard
On a quarterly basis, the Quality Control Coordinator should
introduce a group of prepared verification samples/ or standard
reference materials, into the analytical testing regime. Results of
these data will be summarized, evaluated, and presented to
laboratory management for review and corrective actions, if
appropriate. The data are reported to and summarized by the Quality
Control Coordinator.
-------
• IMCUUTV MAMMALS MVttlON •
lULIOtATOtT
LIST OP APPROVED INORGANIC TEST PROCEDURES
PARAMETER
METHODS
REFERENCE
L
r
1. Acidity, as CaCO ,«q/L:
3
Elect rometric end point
or phenolphthalein end
point.
2. Alkalinity, at CaCO ,
3
•g/L: Elactroattric
or colorimtric:
Titration to pB 4.5
•anual
Or autonatcd
3
3. AluninuB-Total ag/L:
3
Oigtstion followed by:
AA direct aspiration
AA furnace
Inductively coupled
Or coloriMtric
(EriochroM cyanine R)
4. Anonia (as N), ag/L:
5
Manual distillation (at
PH 9.5):
-Poiioved by
Nesslerization
Titration
Electrode
Automated phenate, or
Automated electrode
305.1, 402(4. d),
D10€7-70(E)
1,2,3
310.1,403
D1067JB),1-1030-78,
P.548.(2)
310.2, 1-2030-78
202.1, 202C, 1-3051-78
202.2, 304
Method 200.7(4)
306B >
1,2,3,4
1,2,4
5
2
350.2, 417A 1,2
350.2, 417.B, D1426- 1,2,3,4
79(A),1-3520-78
350.2, 417D 1,2
350.3, D-1426-79(0) 1,3
350.1, 417P, D1426-79(C) 1,2,3,4
1-4523-78
(6) 5
Page 1 of 18
-------
. SMCMITT MATiaUU MVMtON lAOU-MCNIt MHAKM LAKWATOCT
LQPP-12
Revision:
Date: 11/25/86
Page 2 of 2
1.5 Method for computation of analytical results, which can be
included on the data sheet.
2.0 Documentation
Documentation of the above as an analytical procedure is dependent
upon the specific instrumentation and data collection and reduction
nethods used within the laboratory. Therefore, EPRL Analytical
Division shall prepare and maintain as a Laboratory Specific
Attachment to this manual an Analytical Laboratory Standard
Operating Procedures (ALSOP) which includes the above for all
analyses performed. The requirements of the Quality Assurance
Policy Manual for activities such as calibration, preventive
maintenance, and quality control sample analysis shall be
incorporated into the laboratory specific manuals as appropriate.
3.0 Analytical Methods
Whenever possible, EPRL Analytical Division utilises industry
recognized analytical methods from source documents published by
agencies such as the U.S. Environmental Protection Agency (CSEPA),
American Public Health Association (APBA), American Society for
Testing and Materials (ASTM), and the National Institute for
Occupational Safety and Health (NZOSB).
Methods as they appear in CFR 40 Part 136 lists the analytical
methods typically used throughout EPRL Analytical Division.
4.0 ' Variance -from-Stated Analytical Methods
Analyses will be performed in accordance with the methods cited
herein unless specific project requirements or needs dictate
adoption of an alternate method or modification of the cited
methods.
If analysis is peformed in an alternate manner, the method shall be
documented.
-------
WfdAlTT MATOHAU DIVISION •
PARAMETER
METHODS
11. Bromide, mg/L: Titrimetric
12. Cadmium - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
Inductively coupled
plasma
9
Voltametry or
Colorimetric (Dithizone)
3
Calcium - Total mg/L:
3
Digestion followed by:
Atoad c absorption
13.
14
Inductively coupled
Or EDTA titration
Carbonaceous Biochemical
oxygen demand (CBQO ),
5
mg/L: Hinkler (Azide modi-
fication)or-electrode
method with nitrification
inhibitor.
15. Chemical oxygen demand
(COD), mg/L:
Titrimetric colorimetric
Manual or
Automated
Spectrophotoaetric
320.1, D-1246-77(C),
1-1125-78
213.2, 303A or 303B,
D3557-78 (A or B),
1-3135-78 or 1-3136-78
213.2, 304
Method 200.7(4)
D-3S57-78CC)
310B
215.1, 303A, D5U-
77(0,1-3152-78
Method 200.7(4)
US.2, 311C, D511-
77 (B)
507(5.e.6)
1,3,4
410.1, 508A, D1252-
78, I-35W-78
410.2, 1-3562-78
410.3, 1-3561-78
410.4
(11)
1,2,3,4
1,2
5
3
2
1*2,3,4
5
1,2,3
2
1,2,3,4
1,4
1
5
Page 3 of 18
-------
ITT MATBMAU MVMIOM <
IUMMTOCY
5. Antimony - Total / mg/L:
3
Digwsi-.i-M followed by:
AA direct aspiration
AA furnace/ or
Inductively coupled
plasma
3
6. Arsenic - Total , mg/L:
3
Digestion followed by:
Hydride
AA Furnace
Inductively coupled
plasma
Or/ colorimetric (SDK)
7. Barium - Total / »gL/:
3
Digestion followed by:
AA direct aspiration
AA furnace/ or
Inductively coupled
plasma
I 3
8. Beryllium - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
Inductively coupled
plasma
Or color imetri
(aluminon)
9. Biochemical Oxygen demand
(BODS), mg/L:
Kinkier Ulide modifi-
cation
Or electrode method
10. Boron - Total/ mb/L:
Oolorimatic (Curcumin or
Inductively coupled
204.1, 303A 1/2
204.2, 304 1/2
Method 200.7(4) 5
206.5 1
206.3, 303B/ D2972- 1/2/3/4
78(B), 1-3062-78
206.2, 304 1/2
Method 200.7(4) 5
206.4, 307B, D2972- 1/2/3,4
78(A), 1-3060-78
208.1, 303C/ 1-3084-78 1,2,4
208.2, 304 1/2
Method 200.7(4) 5
210.1, 303C, D364S-78,
1-3095-78
210.1, 304
Method 200.7 (4)
309B
405.1, 507, 1-1578-78
P. 548(2)
1,2,3,4
1,2
5
1,2,3
5
212.3, 404A, 1-3112-78 1,2/3
Method 200.7(4) 5
Page 2 of 18
-------
E p Analytical Report 87-02-156-03A
Cuttoatr ID:Pic I Stack Charcoal Tube Run
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Ac rolein <1.0
Acrylonitrile <1.0
Benzene <0.050
bis (Chloronethyl) ether <1.0
Broooforn <0.050
Carbon tetrachloride <0.050
Chlorobenzene <0.050
Chlorodibroaonethane <0.050
Chloroethane <0.10
2-Chloroethylvinyl ether <0.10
Chloroform <0.050
Dichlorobroaomethane <0.050
Dichlorodifluoroaethane <0.050
1,1-Oichloroethane <0.050
1,2-Dichloroethane <0.050
1,1-Dichloroethylene <0.050
1i2-Dichloropropane <0.050
1,3-Dichloropropylene <0.050
Ethylbenzene <0.050
Methyl broaide <0.10
Methyl chloride <0.10
Methylene chloride 340.
1,1,2,2-Tetrachloroethane <0.050
Tetrachloroethylene
-------
E»P Analytical Report
Work Order No. 87-02-156-04A/
87-03-052-12A
PolychlorinaCtd Dibenso-£-dioxins and Dibenzofurans
Method 8280
Customer 1.0. Pit I Run 04 Inlet
Polychlorinated Dibenzo-£-dioxina
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCDD
1,3,7,9-Trnn
1,3,7,3-TCDD
1,2,7,8-TCDD
1,2,8,9-TCDD
1,2.3,4,7-PeCDD
1.2,3,7,8-PeCDD
l,2,3,4,7.«-»HxCOO
1,2,3,4,6,7,8-HpCOD
Polychlorinated Oibenzofurans
1,2,7,8-TCDF
1.2,3,7,8-PeCOF
1,2,3,4,7,8-lixCDF
1,2,3.4.«.7.8,9-OCDF
LEVEL , ug/ml
<0.75
<0.75
-'0.75
<0.75
<0.75
v'0.75
<0.75
<0.75
<0.75
LEVEL*, ug/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
RESEARCH
LA«O«4TOffY E p Analytic*! Report 87-02-156-04A
Custoner ID:Pic I Inlet Charcoal Tube Run #4
Priority Pollutants Volatile Organic!
COMPOMENT
Ac role in
Aerylonitrile
Benzene
bis (Chloromethyl) ether
Brouofom
Carbon tetrachloride
Chlorobenzene
Chlorodibronoraethane
Chloroethane
2-Chloroethylvinyl ether
Chloroforn
Dichlorobroaomethane
Dichlorodifluororaethane
1,1-Diehloroethane
1|2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
1,2-Trans-dichloroethylene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Tr ichlorofluoronethane
Vinyl chloride
-------
AESI4*CH
LAiKMUTOffY
E-P Analytical Report
Work Order No. 87-02-156-OU/
87-03-052-03A
Polychlorinated Dibenso-£-dioxins and Dibensofurans
Method 8280
Custoraer I.D. Pit I Run #3 Stack
Polychlorinated Diben*o-£-dioxins
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCDD
1,3,7,9-TCDD
1,3,7,8-TCDD
1,2,7,8-TCDD
1,2,3,9-TCDD
1,2,3,4,7-PeCDO
1,2,3,7,8-PeCDO
1,2,3,4,7,3-llxCDD
1,2,3,4,6,7,3-HpCDD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibenzofurans
1,2,7,8-TCDF
1,2,3,7,8-PeCOF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCOF
LEVEL , ug/al
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
PICHER
E p Analytical Report 87-02-1 56-01A
Customer in:Pic I Stack Charcoal Tube Run *3
Priority Pollutants Volatile Organic*
COMPONENT SA1
Acrolein <1
Acrylonitrile <1.
Benzene <0.
bis (Chloromethyl) ether <1
Bronofom <0.
Carbon tetrachloride 0
Chlorobenzene <0.
Chlorodibrononethane <0.
Chloroethane <0.
2-Chloroethylvinyl ether <0
Chloroforn <0
Oichlorobromonethane <0
Diehlorodifluororaethane <0
1,1-Dichloroethane <0
1,2-Dichloroechane <0
1,1-Dichloroechylene <0
1,2-Dichloropropane <0
1,3-Dichloropropylene <0
Ethylbenzene <0
Methyl bromide <0
Methyl chloride <0
Methylene chloride 350
1,1,2,2-Tetrachloroethane <0
Tetrachloroethylene <0
Toluene 0
1,2-Trans-dichloroethylene <0
1,1,1-Trichloroethane <0
1t1iJ-Trichloroethane <0
Trichloroethylene <0
Trichlorofluoronethane <0
Vinyl chloride <0
-------
—
TOKf
E-P Analytical Report
Work Order No. 87-02-156-02A/
87-03-052-11A
Polychlorinated Dibenzo-£-dioxina and Dibentofurans
Method 8280
Customer I.D. Pit I Run #3 Inlet
Polychlorinated Dibenzo-£-dioxini
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6.8-TCDO
I.?,7,9-TCDD
1,1,7,8-TCDD
1,2,7,8-TCnn
1,2,8,9-TCOD
1,2,3,4,7-PeCDD
1,2,3,7,3-PeCDD
1,2.3,4,7,8-fHxCDD
l,2,3,4,6,7,A-r:ipCDD
LtVEL , ug/mi
<0.75
<0.75
<0.75
'0.75
<0.75
-------
PICKER
* * Analytical Report 87-02-156-02A
Customer ID:Pit I Inlet Charcoal Tube Run f3
Priority Pollutants Volatile Organic*
n»g\Kg
COMPONENT SAMPLE
Acrolein . <1.0
Acrylonitrile <1.0
Benrene
-------
ftESCAACH
E-P Analytical Report
Work Order No. 87-02-157-03A/
87-03-052-02A
Polychlorinated Dibenzo-£-dioxin» and Dibenzofurant
Method 8280
Customer I.D. Pic J Run #2 Stack
Polychlorinated Dibenzo-£-dioxina
2,3,7,3-TCDD
1,2,3,4-TCDD
1,3,6,3-TCOD
1.3,7,9-TCDO
1,3,7,8-TCDD
1,2,7,8-TCDD
1,2,8,9-TCOD
1,2,3,4.7-PeCDD
1,2,3,7,8-PeCOD
1,2,3,4,7,3-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL . ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibenzofurans
1,2,7,8-TCOF
1,2,3,7,8-P«CDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL t uj/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract,
-------
PKHER
E P Analytical Raport 87-02-157-03A
Customer IDrPit J Stack Charcoal Tube Run #2
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Acrolein <1.0
Acrylonitrile <1.0
Benzene <0.050
bis (Chloromethyl) ether <1.0
Bronoform <0.050
Carbon tetrachloride <0.050
Chlorobenzene <0.050
Chlorodibroaomethane <0.050
Chloroethane <0.10
2-Chloroethylvinyl ether <0.10
Chloroform 0.14
Dichlorobromomethane <0.050
Dichlorodifluoronethane <0.050
1,1-Dichloroethane <0.050
l,2-*I:hloroethane O.050
1,1-Dichloroethylene <0.050
1,2-Dichloropropane <0.050
1,3-Dichloropropylene <0.050
Ethylbenzene <0.050
Methyl bromide <0.10
Methyl chloride <0.10
Methylene chloride >500.
1,1,2,2-T«crachloroethane 0.064
Tetrachlornethylene O.050
Toluene 0.09^
1,2-Trans-dichloroethylenr
-------
E-P Analytical Report Work Order No. 87-02-157-04A/
87-03-052-10A
Polychlorinated Dibenzo-£-dioxina and Dibtnxofur«n«
Method 8230
Customer 1.0. Pit J Run #2 Inlet
Pol/chlorinated Dibenzo-£-dioxin*
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCDD
1,3,7,9-TCDD
1,3,7,8-TCDD
1,2,7,3-TCDD
1,2,8,9-TCOD
1,2,3,4,7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/«l
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Oibenxofurant
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
l,2,3',4|7,8-IixCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL , ug/al
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
RICHER
E P Analytical Report 87-02-157-OAA
Customer ID:Pit J Inlet Charcoal Tube Run «
Priority Pollutants Volatile Organic*
COMPONENT ___
Acrolein <1.0
Acrylonitrile <1.0
Benzene <0.050
bis (Chloromethyl) ether <1.0
Bronoforut <0.050
Carbon tetrachloride <0.050
Chlorobenzene <0.nso
Chlorodibromoroethane <0.050
Chloroethane <0.10
2-Chloroethylvinyl ether (0.10
Chloroform 0.072
Dichlorobromomethane <0.050
OichlorodiCluoroaethane <0.050
1,1-Dichloroethanr '0.050
1,2-Dichloroechane <0.050
1,1-Dichloroethylene <0.050
1 f2-Dichloropropane <0.050
1,3-Dichloropropyltne <0.050
Ethylbcnzene <0.050
Methyl bromide <0.10
Methyl chloride 3.1
Methylene chloride 490.
1,1,2,2-Tetrachloroethane <0.050
Tetrachlornethylene <0.050
Toluene <0.050
1,2?Trans-dichloroethyleo- <0.050
1 ,l,i**Trichloroethane <0.050
1.1,2VXrichlorocthane
-------
E-» Analytical Report Work Order No. 87-02-157-01A/
87-03-052-01A
Polychlorinated Dibenzo-£-dioxins and Dibenzofurans
Method 8280
Custoner I.D. Pit J Run #1 Stack
Polychlorinated Dibenzo-£-dioxins
2,3,7,3-TCOD
1,2,3,4-TCOD
1,3,6,8-TCOD
1,3.7.9-TCDD
1,3,7,8-TCOO
1,2,7,8-TCOD
1,2,8,9-TCUD
1,2,3.4.7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/«i
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
O.75
<0.75
<0.75
Polychlorinated Dibenzofurans
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3.4.6,7,8,9-OCDF
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
AESfAACH
UtOfUTOftY
E P Analytical Report
Cuatomer IDtPit J Stack Charcoal Tube Run *1
Priority Pollutanta Volatile Organict
87-02-157-01A
COMPONENT
Acroltin
Acrylonitrile
Benzene
bia (Chloronechyl) ether
Broaofora
Carbon tetrachloride
Chlorobenzene
Chlorodib rononethane
Chloroethane
2-Chlorn*thylvinyl ether
Chloroform
Dichlorobromooethane
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroe chylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
1,2-Trans-dichloroethylene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoronethane
Vinyl chloride
-------
JtfSfAACM
E-P Analytical Report
Work Order No. 87-02-157-02A/
87-03-052-09A
Polychlorinated Dibenzo-£-dioxin« and Dibenzofurani
Method 8280
CuscoQer 1.0. Pic J
Run
Inlet
PolychlorinaCed Dib«nzo-£-dioxint
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCDD
1.3.7,9-TCOD
1,3,7,8-TCDD
1,2,7,8-TCDD
1,2,8,9-TCOO
1,2,3,4,7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,6-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
PolychlorinaCed Dibenzofurana
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4.6.7,8,9-OCDF
LEVEL , ug/al
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
BAQLi^PKHER
L4atO«4tO*V E P A"*1*'"*! *•?««
Customer IO:Pit B Scrubber Water Run 01
087-02-158-03A
Priority Pollutants Base/Neutral Extractable Organic*
COMPOS NT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
3enzo(a)anthracene
Benzo(a}pyrene
3,4-3enzo fluoranthene
Benzo(jhi)perylene
Benzolk)fluoranthene
bis(2-Chloroethoxy)methane
bi*(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Brcoophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrvsene
OibenzoC a,h)anthracene
1,2-Dichlorobenzene
1,3-Dicl»lorobenzene
1,4-Dichlorobenzene
3,3'-Dicnlorobenzidene
Diethyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-pinitrotoluene
Di-n-octyl phthal«te
1,2-Diphenylhydrazin»
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-c f d)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylaaine
N-Ni trosodi-n-propylanine
N-Nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
<0.0i
<0.04
<0.04
-------
RICHER
MfSCAACH
LAtOJUrOftY
E P Analytical Report
Customer ID:Pit B Scrubber Water Run #1
Priority Pollutants Acid Extractable Organic*
COMPOSEHT
2-ChiorophenoI
2,4-Dichlorophenol
2,4-DimethyIphenol
4,6-Dinitro-o-cresol
2t4-Dinitrophenol
2-Hitroph*nol
4-N!crophenol
»-Chloro-m-cresol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Canma-BHC
Delta-BHC
Chlordane
4,4'-OOT
4,4'-DDE
4,4'-ODD
Dieldrin
Cndosulfan I
Endoaulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
O.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
-------
E P Analytical Report Work Order #87-02-158-01A
Customer ID: Pit B Mik«*up W«eer tun #1
Priority Pollutant* Metals m^\L
METAL
Antimony
Arsenic
Bcrylliun
Cad-nium
Chromium
Copper
Lead
Mercury
Nickel
Seleniu-
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
SAMPLE
<.01
-------
PtCHER
E ' Analytical Report 87-02-158-03A
Customer ID:Pit B Scrubber Water Run fl
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Ac role in . <0.100
Acrylonicrile <0.100
Benzene <0.005
bia (Chloromethyl) ether <0.100
Brcoofonn <0.005
Carbon tctrachloride ^0.005
Chlorobenzene <0.005
Chiorodibromomethane <0.005
Chloroethane <0.010
2-Chloroechylvinyl ether <0.010
Chloroform <0.005
Dichlorobronoraethane <0.005
Dichlorodifluoronethane
-------
EMU
ftfSC4ACM
LABOMTOfTf
PKHER
E P Analytical Report
Customer ID:Pit B Make-up Water Run #1
Priority Pollutants Base/Neutral Extractable Organic*
#37-02-158-01A
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
BenzoCa)anthracene
BenzoC a)pyrene
3,i-Qenzofluorinehene
B«nzoCghi)perylene
BenzoC k)fluoranthene
bis(2-Chloroethoxy)a«thane
bii(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Broiaophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chloroph«nyl phenyl ether
Chrysene
DibenzoC a,h)anthracene
1,2-Oichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di^n-octyl phthalate
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-c,d)pyrene
Isopherone
Naphthalene
Nitrobenzene
N-Ni trosod ime thylamine
N-Nitrosodi-n-propylaaine
N-Nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
PKHER
E P Analytical Report
Customer ID:Pic B Make-up Water Run fl
Priority Pollutants Acid Extractable Organic*
#87-02-158-01A
COMPONENT
2-Chlorophenol
2,4-nichlorophertol
2,4-Di-»ethylphenol
4,6-Dinitro-o-cr«»ol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-m-cresol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Gamma-BHC
Delta-BHC
Chlordane
4,4'-DDT
4,4'-ODE
4,4'-ODD
Dieldrin
Cndosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Cndrin aldehyde
Htptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
-------
E p Analytical Report «ork Order #87-02-133-02A
Customer 10: Pic M Scrubbtr Wattr Bun #2
Priority Pollutants Metals ag\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thailium
Zinc
Prioricy Pollucancs Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis:
Total Organic Carbon
Chloride
-------
LABOMTOHY E p Analytical R«port 87-02-158-OIA
Customer IO:Pic B Make-up Water Run II
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.905
bia (Chloronethyl) ether <0.100
Bronoforn <0.005
Carbon tetrachloride '0.005
Chlorobenxene <0.005
Chlorodibromoaechane <0*OOS
Chloroethane O.010
2-Chloroechylvinyl ether <0.310
Chloroform <0.005
Dichlorobromnmethan* <0.005
Dichlorodifluorontthane <0.005
1,1-Dichloroethane <0.005
1,2-Diehloroethane <0.005
1,1-Oichloroethylene <0.005
1,2-Dichloropropane <0.005
1,3-Dichloropropylene <0.005
Ethylbenzene <0.005
Methyl bromid- <0.010
Methyl chloride <0.010
Methylene chloride 0.012
1,1,2,2-Tctrachloroethane <0.005
Tetrachloroethylene <0.005
Toluene <0.005
1,2-Trans-dichloroethylene <0.005
1,1,1-Trichloroethane <0.005
1,1,2-Trichloro«thane <0.005
Trichloroethylene <0.005
Trichlorofluoronethane <0.005
Vinyl chloride <0.010
-------
PKHER
LABOMOKT E p Analytical Report
Customer ID:Pic H Scrubber Water Run #2
#87-02-133-02A
Priority Pollutants Base/Neutral Extractable Organic*
COMPONENT
Acenaphthene
Aeenaphthylene
Anthracene
Benzidine
BenzoC a)anthracene
BenzoCa)pyrene
3,4-Benzofluoranthene
Senzo(^hi)perylene
B«nzo(k)fluorantnene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Uthylhexyl)phthalate
4-Bronophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Oibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Oichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,2-Oiphenylhydrazine
Fluoranthene
Fluorene
Hcxaehlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indenod ,2l3-c,d)pyrene
Isophoront
Naphthalene
Nitrobenzene
N-Nitrosodimethyl«ine
N-Nitrosodi-n-propvianin*
N-Nitrosodiphenylanine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCOD
-------
LAaKMUrbffY E p Analytical Report
Customer ID:Pit M Scrubber Water Run #2
Priority Pollutants Acid Extractable Organic*
#87-02-133-02A
COMPONENT
2-Chlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-m-cresol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Camoa-BHC
Delta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
-------
EAQUJ^PKHER
LABORATORY E P Analytical Report Work Order J87-Q2-133-04A
Customer ID: Pit M Make-up Water Run #2
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadaiun
Chronium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
-------
PICKER
AESCAftCH
E P Analytical Report 87-02-133-02A
Customer ID:Pit M Scrubber Water Run #2
Priority Pollutants Volatile Organic!
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloromethyl) ether <0.100
Bronofora <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronome thane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Oichlorobromonethane <0.005
Oichlorodifluoroaethane <0.005
1,1-Oichloroethane <0.005
1 ,2-Dichloroethane <0.003
1 ,1-Dichloroethylene <0.005
1, 2-Dichloropropane <0.005
1 ,3-Dichloropropylene <0.005
Ethylbenzene <0.005
Methyl bromide <0.010
Methyl chloride <0.010
Methylene chloride <0.005
1,1,2,2-Tetrachloroethane <0.005
Tetrachloroethylene <0.005
Toluene <0.005
1,2-Trans-dichloroe thylene <0.005
1 ,1 , 1-Trichloroethane <0.005
lf 1 ,2rTrichloroethane <0.005
Trichloroethylene <0.005
Trichlorof luoromethane <0.005
Vinyl chloride <0.010
-------
RICHER
HCSIMCH
LMOfUTOffV
E P Analytical Report
Customer ID:Pit M Make-up Water Run #2
#87-02-133-04A
Priority Pollutants Base/Neutral Cxtractable Organic•
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
3,4-Benzofluoranthene
3enzo(jhi)perylene
3enzo(k)fluoranehene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis( 2-Ethylhexyl)phthalate
4-Brono?henyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyi phenyl ether
Chrysene
Oibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalate
2,4-?initrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hcxachlorocyclopentadiene
Mexachloroethane
Indeno(l,2,3-e,d)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamine
N-Nicrosodi-n-propylaaine
N-Nitrosodiphenyl anine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCOD
-------
RICHER
MfSCAftCH
LABOJUTOffY
E P Analytic*!. Report
Customer IDrPit M Make-up Uattr Run #2
Priority Pollutants Acid Extractablt Organic*
#87-02-133-04A
COMPONENT
2-Chlorophenol
2 f4-Oichlorophcnol
2,4-Diaethy1phenol
4,6-Dinitro-o-crtsol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-ra-cresol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Garama-BHC
D«lta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4t4'-DDD
Oieldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrih aldehyde
Hcptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
E f Analytical Report Work Order #87-02-133-01A
Customer ID: Pit M Scrubber Water Run #1
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chroniura
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thalliun
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Orjanic Carbon
Chloride
-------
RICHER
fteSCAHCM
* Analytical Report 87-02-133-04A
Cu§ toner ID:Pit M Make-up Water Run *2
Priority Pollutants Volatile Organics
rag\L
COMPONENT SAMPLE
Acrolem <0.100
Acrylonitrilc <0.100
Benzene <0.005
bis f Chloromethyl) ether <0.100
Broaoform <0.005
Carbon tetrachloride <0.005
Chlorobenzcne <0.005
Chlorodibroraonethane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chlorofora <0.005
Oichlorobroaoaethane <0.005
Diehlorodifluoronethane <0.005
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
1,2-Dichloropropane <0.005
1,3-Dichloropropylene <0.005
Ethylbenzene <0.005
HethyL bromide <0.010
Methyl chloride <0.010
Me thylent chloride <0.005
1,1,2,2-Tetrachloroethane <0.005
Tetrachloroethylene <0.005
Toluene <0.005
1,2-Trans-dichloroethylene <0.005
1,1,1-Trichloroethane <0.005
1,1,2-Trichloroethane <0.005
Trichloroethylene <0.005
Trichlorofluoronethane <0.005
Vinyl chloride <0.010
-------
-PKHER
MfSCAACH
E P Analytical Report
#87-02-133-01A
Customer IO:Pit M Scrubber Water Run #1
Priority Pollutant* Bate/Neutral Extr«ctable Organic!
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
3,4-3enzofluoranthene
BenzoC^hi)perylene
Benzo(k)fluoranthene
bi»(2-Chloroethoxy)methane
bi«(2-Chloroethyl)*ther
bis(2-Chloroiaopropyl)ether
bi•(2-EthylhexyI)phthalate
4-Broraophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Oichlorobenzen*
1,3-Dichlorobenzene
1,4-Dichlorobenzta*
3,3'-Dichlorobenzidene
Oiethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalate
2,4-Oinitrotoluene
2,6-Dinitrotoluene
Di.-n-octyl phthalate
1.2-Oiphenylhydraziae
Fluoranthene
Fluoren^
Hexachlorobenzene
Hexachlorobutadiene
Uexachlorocyclopentadiene
Hexachloroethan«
IndenoC1,2,3-c.d)pyrene
laophorone
Naphthalene
Nitrobenzene
N?Ni troiodiaethylanine
N«Nitrosodi-n-propylaaine
N-Nitroiodiphanylamine
Phenanthrene
Pyrene
1,2,4-rTr ichlorobenrene
2,3,7,8-TCDD
-------
E P Analytical Keport
Customer XD:Pit M Scrubber Water tun 01
Priority Pollutants Acid Extractable Organic*
•87-02-133-01A
COMPONENT
2-Chloroph«nol
2,4-Dichlorophenol
2,4-Diaethylphenol
4,6-Dinitro-o-er««ol
2,4-Dinitrophenol
2-Nitrophtnol
4-Nitrophenol
p-Chloro-m-creiol
Pcntachlorophcnol
Phenol
2,4,6-Trichlorophcnol
Priority Pollutants Pestieidei/PCB"S
M/L
COMPONEOT
Aldrin
Alpha-BHC
Btta-BHC
Gamma-BHC
Dclta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endoaulfan I
Endoaulfan II
Endoaulfan aulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
-------
•MLElSpPKHER
ACSfAACH
E p Analytical lUport Work Order #87-02-1 33-03A
Customer ID: Pit M Make-up Water Run 91
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis!
Total Organic Carbon
Chloride
-------
ACSCAftCM
LABOJUTDftY E p Analytical Report 87-02-133-01A
Customer IDrPit H Scrubber Water Run #1
Priority Pollutants Volatile Organic!
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Senzene <0.005
bis (Chloronethyl) ether <0.100
Bronoforn <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronoaethane <0.005
Chloroethane <0.010
2-Chlorocthylvinyl ether <0.010
Chloroform <0.005
Dichlorobroraoaethane <0.005
Oiehlorodifluorone thane <0.005
1,1-Dichloroethine <0.005
112-Dichloroethane <0.005
1.1-Dichloroethylene <0.005
1,2-Dichloropropane
-------
U&OMOKr E P Analytical Report
Customer IO:Pit M Make-up Water Run #1
#87-02-133-03A
Priority Pollutant* Bate/Neutral Extractable Organic!
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Senzo(a)anthracene
Benzo(a)pyrene
3,4-Benzofluoranthene
Senzo({hi)perylene
ii«snzo(k)fluoranthene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)eth,er
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthaiate
4-Bronophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3f3'-Dichlorobenzidene
Oiethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,2-Diphenylhydrazine
Fluoranthenc
Fluorene
Hcxachlorobcnxeoe
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indcnod ,2,3-c,d)pyrene
laophorone
Naphthalene
Nitrobenzene
N-Nitroaodimethylanine
N-Nitroaodi-n-propylaaine
N-Nitroaodiphenylanine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
SAMPLE
<0.04
<0.04
<0.04
<0.20
<0.04
<0.04
O.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
<0.04
-------
PICHER
MfS&UICH
E P Analytical Report
Custoaer ID:Pit M Make-up Vater Run #1
Priority Pollutants Acid Extractable Organic*
#87-02-133-03A
COMPONENT
2-Chlorophenol
2,4-Dichloropheriol
2,4-Diaethy1phenol
4,6-Dinitro-o-cre*ol
2,4-Dinitrophenol
2-Nitrophenol
4-N'itrophenol
p-Chloro-«-cresol
Pcntachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPOHENT
Aldrin
Alpha-BHC
Beta-BHC
Caama-BHC
Delta-BHC
Chlordan;
4,4'-DDT
4.4'-DDE
4,4'-DDD
Dieldrin
Endosulfan I
Endosulfan II
Cndoculfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Hepcachlor cpoxide
PCB-1016
PCI-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
-------
PKHER
E P Analytical Report Work Ordtr #87-Q2-l31-02A
Customer ID: Pit I Scrubber Water Run #2
Priority Pollutants Metals «g\L
METAL
An t iraony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
ThaiIium
Zinc
•riority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
\L
SAMPLE
<.01
mz\L
255.5
698.
-------
E p Analytical Report 87-02-!33-03A
Customer ID:Pit H Make-up Water Run #1
Priority Pollutants Volatile Organic!
•g\L
COMPONENT SAMPLE
Acroleio . <0.100
Acrylonitrile <0.190
Benzene <0.005
bis (Chloromethyl) ether <0.100
Broaofona <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibroaomethane <0.005
Chloroethane <0.010
2-Chloro«thylvinyl ether <0.010
Chlorofom O.005
Oichlorobroaomethane <0.005
Dichlorodifluoroiaethane <0.005
1,1-Dichloroethane <0.005
1,2-Dichloroethane
-------
PKHER
MffSfAftCH
E P Analytical Report
Customer ID;Pit I Scrubber Water tun #2
#87-02-131-02A
Priority Pollutant* Base/Neutral Extractable Organic!
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Benzo(a)pyrene
3t4-Benzofluoranthene
B«nzo(ghi)perylene
Benzo(k)fluoranthene
bi»(2-f!hloroethoxy)methane
bia(2-Chioroethyl)ether
bi«(2-Chloroisopropyl)ether
bif(2-Ethylhexyl)phthalate
Ar&ronopheayl phenyl ethe~
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a.h^ anthracene
l,2^0ichlorobencene
1,3-Dichlorobenzene
I,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Oiethvl Phthalate
Dinethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Oinitrotoluene
Di-n-occyl phthalate
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Uexachlorobenzene
Hexachlorobutadiene
Hcxachlorocyelopentadiene
Hcxachloroethane
Indenod,2,3-c ,d)pyrene
laophorone
Naphthalene
Nitrobenzene
N-Nitroaodimethylaaine
N-Nitroiodi-n-propylaaine
N-Nitrosodiphehylaaine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
ABEAM*
LA9OMTOM
E P Analytical Report
Customer lD:Pit I Scrubber Wattr Run #2
Priority Pollutant* Acid Cxtractable Organic*
*87-02-131-02A
COMPONENT
2~Chlorophenol
2,4-Dichlorophehol
2,4-Dirtethylphenol
4,6-Dinitro-o-crtsol
2,4-DinitTOphenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-a-cresol
Pentachlorophcnol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Ptsticidea/PCB'S
mi/L
COMPONENT
Aldrin
Alpha-BHC
B«C«-BHC
Caama-BHC
Dtlta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-ODO
Oicldrin
Endosulfan I
Endosulfan II
Endosulfan sulfate
Endrin
Endrin aldehyde
Ueptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PC8-1232
PCB-1242
PCB-1248
PCB-1254
PCfl-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
40.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
iAQliL^pPrCHER
AfSC4ACM
- — E P Analytical Report Work Order #87-02-131-04A
Customer ID: Pit I Make-up Water Run #2
Priority Pollutants Metals «i\L
METAL
Antimony
Arsenic
Beryllium
Ch rom i urn
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
mt\L
COMPONENT SAMPLE
Total Cyanides <*01
Additional Analyai's;
Total Organic Carbon
Chloride
-------
E p Analytical Report 87-02-131-02A
Customer ID:Pit Z Scrubber Water Run #2
Priority Pollutants Volatile Organic!
COMPONENT SAMPLE
Aerolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloroaethyl) ether <0.100
Bronoforn <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibroaomethan-* <0.005
Chloroethane <0.010
2<*Chloroethylvinyl ether '0.010
Chloroform <0.005
Diehlorobromomethane XO.OOS
Dichlorodifluorooethane <0.005
1tl-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Oichloroethylene
-------
JtfSfAACH
E P Analytical Report
#87-02-131-04A
Customer ID:Pit I Make-up Water Run 12
Priority Pollutant* Bate/Neutral Cxtraetable Organic•
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Bcnzidine
Benzo(a)anthracene
Benzo(a)pyrene
3,4-Benzofluoranchene
Benzo(ghi)perylene
Benzo(k)fluoranthene
bi»(2-Chloroethoxy)methane
bis(2-Chioroethyl)ether
bi*(2-Chloroi*opropyl)ether
bi»( 2-Ethylhexyl)phthalate
4-Broraophenyl uhenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Oib«nzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzenc
3,3'-Dichlorobenzidene
Diethyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Oinitrotoluene
2t6-Dinitrotoluene
Oi-n-octyl phthalate
1|2-0iph«nylhydrazine
Fluoranthene
Fluortnc
Itexachlorobcnzene
Hexachlorobutadiene
Hexachlorocyclopencadiene
Hexaehloroethane
Indeno(l,2f3-c,d)pyrene
laophorone
Naphthalene
Nitrobenzene
N-Nitroaodiaethylamine
N-Nitroaodi-n-propylaoiine
N-Nitrosodiphenylaain*
Phenanchrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
E P Analytical Report
Cutconcr ID:Pit I Make-up Wattr Run #2
Priority Pollutant* Acid Cxtraetablt Orjanics
#37-02-131-04A
COMPONENT
2-Chlorophcnol
2,4-Dichlorophenol
2,4-Diaethylphenol
4,6-Dinitro-o-cresol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophtnol
p-Ch1o r o-nt-c re s o1
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
CaMPOMENT
Aldrin
Alpha-BHC
Beta-BHC
Canuaa-BHC
Dtlta-BHC
Chlordane
4,4'-DOT
4,4'-DDE
4,4'-DDD
Dicldrin
Endofulfan I
Endosulfan II
Endosulfan aulfate
Endrin
Endrin aldehyde
Heptachlor
Heptaehlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
E P Analytical Report Work Order *87-02-131-01A
Customer ID: Pit I Scrubber Water Run *1
Priority Pollutants Hetals mg\L
Ant iaony
Arsenic
Serylliun
Cadmium
Chronium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
SAMPLE
<.06
.14
<.005
.005
2.U
6.96
1.20
.0003
2.54
<.02
4.49
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
SAMPLE
Additional Analysis;
Total Organic Carbon
Chloride
^
1S.2
2050.
-------
E P Analytical Report 87-02-131-04A
Customer ID:Pit I Make-up Water Run #2
Priority Pollutant* Volatile Organic*
ng\L
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.905
bi* (Chloroaethyl) ether <0.100
Sronoforin O.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronoraethane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Oichlorobrotaomethane <0.005
Dichlorodifluoromethane <0.005
1,1-Dichloroethane <0.005
1,2-Dichloroethane
-------
ftCSEAACH
UftOMJOftY
PKHER
£ P Analytical Report
Custoner ID:Pic I Serubbtr Water Run #1
Priority Pollutants Base/Neutral Extractable Organic*
*37-02-131-01A
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
BcnzoC a)pyrene
3,4-Benzofluoranthene
Benzo(ghi)perylene
BenzoC k)fluoranthene
bi«(2-Chloroethoxy)methane
bi»(2-Chioroethyi)ether
bis(2-Chloroi*opropyl)ether
bi»(2-Ethylhexyl)phthalate
4-Bronophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chry»ene
DibenzoCa,h)anthracene
1,2-Dichlorobenzene
1,3-Dichiorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Diethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalat*
2.4-"Initrotoluene
2,6-Dinitrotoluene
Di-n-nctyl phthaiate
l,2-Diphenylhydra*in«
Fluoranthene
Fluoreo;
Hekachlorobenxene
Hexachlorobutadieae
HexachLorocyclopentadiene
Hexachloroethan*
Indeno(1,2,3-c.d)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-»Ni troaod ime thy lani ne
N-Nicrotodi-n-propylamin*
N-Nitroiodiphenylaaine
Phenanthrene
Pyrene
1,2t4-Trichlorobenzene
2,3,7,8-TCDD
-------
MSE4ACH
LAaWUTOAY
E P Analytical Report
Customer ID:Pit I Scrubber Water Run #1
Priority Pollutant* Acid Extractablc Organic*
#87-02-131-01A
COMPONENT
2-Chlorophenol
2,4-Dichlorophenol
2,4-Diacthylphceol
4,6-Dinitro-o-cresol
2,4-Oinitrophenol
2-Uitrophenol
4-Nitrophenol
p-Chloro-m-cre*ol
Pentachlorophenol
Phenol
2,4,6-Trichlorophcnol
Priority Pollutant* Pe*ticidet/PCB'S
COMPOS NT
Aldrin
Alpha-BHC
Beta-BHC
Camma-BHC
Dclta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endo*ulfan I
Endo*ulfan II
Endoculfan aulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PC3-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
X0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
AfSCAftCH
LMOfUTOffY
PtCHER
C P Analytical Report
Customer ID: Pic I Make-up Water Run 41
Priority Pollutants Metals «t\L
METAL
Antimony
Arsenic
Beryllium
Cad-a i urn
Chroaiun
Copper
Lead
Mercury
Nickel
Selenium
SiIver
Thalliun
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
Work Qrdtr f 87-02-131 -03A
SAMPLE
-------
HCHER
MfSCAACH
E p Analytical Report 87-02-131-OU
Customer ID:Pit I Scrubber Water Run fl
Priority Pollutant* Volatile Organic!
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloronethyl) ether <0.100
Bromofonn <0.005
Carbon tetrachloridc <0.005
Chlorobenzene <0.005
Chlorodibromonethane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Dichlorobroraonethane <0.005
Dichlorodifluoronethane <0.005
1,1-Dichloroethane <0.005
1,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
1,2-Oichloropropane <0.005
1,3-Dichloropropylene <0.005
Ethylbenzene <0.005
Methyl bromide 0.010
Methyl chloride 0*010
Hethylene chloride <0.005
1,1,2,2-Tetrachloroethane <0.005
Tcertchloroethylene <0.005
Toluene
-------
fiAQU
"RICHER
E P Analytical Reoort
Cm comer ID:Pic I JUke-up Water Run #1
HCSIABCH
LAJCWUTOflY
*87-02-131-03A
<0,
<0,
Priority Pollutants Base/Neutral Extraetable Organic*
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
B«nzo(a)pyrene
3t4-8enzofluoranthene
5«nzo<2hi)perylene
Benzo(k)fluoranthene
bii(2-Chloroethoxy)methane
bis(2-Chioroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
4-Broraophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
OibenzoCa,h)anthracene
1»2-Oichlorobenzene
1,3-Dichlorobenzene
1|4-Dichlorobenzene
3|3'-0ichlorobenziden^
Diethyl Phthalate
Dinethyl phthalate '
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Oi-n-octyl phthalate
1i2-Diphenylhydrazine
Fluoranthene
Fluorenc
H«xachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-c,d)pyrene
laophorone
Naphthalene
Nitrobenzene
N-Nicro«odi»ethylaaine
N-Nitro»odi-n-propyla«ine
N-Nitro«odiphenylaaine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
<0.04
Not Requested
-------
PICHIR
AESCAftCM
E P Analytical Report
Cua tomer ID:Pit I Make-up Water Run #1
Priority Pollutanta Acid Extractable Organic*
#87-02-131-03A
COMPOtlEi-rr
2-Chlorepheno1
2,4-Dichlorophehol
2,4-Di.»ethylphenol
4tS-Dinitro-o-creaol
2,4-Dinitrophenol
2-Nitrophenol
4-Hitrophenol
p-Chloro-n-cresol
Pencachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticidea/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
G«nma-BHC
Delta-BHC
Chlordane
4,4'-DOT
4,4'-DDE
4,4'-ODD
Dieldrin
Endotulfan I
Cndoaulfan II
Endoaulfan aulfate
Endrin
Endrin aldehyde
Hepcachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB'1242
PCB-1248
PCB-12S4
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
-------
JtfSEAACH
E P Analytical Report Work Order *87-02-132-02A
Customer ID: Pit J Scrubber Water Run #2
Priority Pollutants Metals ag\L
METAL
Antimony
Arsenic
Beryllium
Cadaiurn
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis;
Total Organic Carbon
Chloride
-------
E p Analytical Report 87-02-U»-03A
Customer ID:Pit I Make-up Water Run #1
Priority Pollutants Volatilt Organic!
agM
COMPONENT SAMPLE
Acrolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bis (Chloromethyl) «th«r <0.100
3rocioforn O.OOS
Carbon tttrachloride <0.005
Chlorobenzene
-------
LABOMTOM
£ P Analytical Report
187-02-132-02A
Cuatoaer ID:Pit J Scrubber water Run 02
Priority Pollutants Base/Neutral Extractable Organic*
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
Senzo(a)pyrene
3,4-3enzofiuoranthene
Benzo(ghi)perylene
3enzo(it)fluoranthene
bis(2-Chloroethoxy)raethane
bis(2-Chloroethyl)cther
bis(2-Chloroi§opropyl)ether
bii(2-Ethylhexyl)phthalate
4-Broraophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Oichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3,3'-Dichlorobenzidene
Dicthyl Phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinicrotoluene
Di-n-octyl phthalate
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
IndenoCl,2,3-cld)pyTene
Isophorone
Naphthalene
Nitrobenzene
N-Nitroiodimethylamine
N-Nitrosodi-n-propylamine
N-Nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzenc
2,3,7,8-TCDD
-------
E P Analytical Report
Customer ID:Pit J Scrubber Water Run #2
Priority Pollutant* Acid Extractable Organic*
#87-02-132-02A
COMPONENT
2-Chlorophtno1
2,4-Dichlorophenol
2,4-DimethyIphenol
4,6-Dinitro-o-cre«ol
2,4-Oinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-«-cretoi
Ptntachlorophcnol
Phenol
2,4,6-Trichlorophtnol
Priority PolK^anta Pcsticidcs/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Btta-BHC
Caouta-BHC
Dtlta-BHC
Chlordanc
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dicldrin
Cndoaulfan I
Endoaulfan II
Endoculfan sulfatc
Cndrin
Cndrin aldehyde
Hcptachlor '
Hcptachlor tpoxida
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphcne
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
IMlElTpPICHER
IMCH
UTOffY E p Analytical Report Work Order #87-02-132-OAA
Customer ID: Pie J Make-up Water Run §2
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
ng\L
COMPONENT SAMPLE
Total Cyanides <.01
Additional Analysis!
Total Organic Carbon 457.2
Chloride 1120.
-------
MStMCH
E t Analytical "cporc 87-02-132-02A
Customer ID:Pit J Serubbtr Water Run #2
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Aerolein <0.100
Acrylonitrile <0.100
Benzene <0.005
bit (Chloromcthyl) ether <0.100
Bronoform <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibronomethane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Dichlorobroaomethane <0.005
Dichlorodifluoroaethane
-------
BAQLE^PKHER
E P Analytical Report
Customer ID: Pit J Ma Ice-up Water Run
*87-02-132-04A
Priority Pollutants Base/Neutral Cxtractable Organic*
COMPONENT
Acenaphthene
Acenaphthylene
Anthracene
Senzidine
Senzo(a)anthracene
BenzoC a)pyrene
3,4-flenzofluoranthene
BenzoC^hi)perylene
Benzo(k)fluoranthene
bis(2-Chloroethoxy)nethane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-Ethylhexyl)phthalate
A-Bronophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Oibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Dichlorobenzene
3t3'-Dichlorobenzidene
Diethyl Phthalate
Dimethyl phthalate'
Di-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phchalate
1,2-Oiphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indenod ,2,3-c,d)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodiraethylamine
N-Xitrosodi-n-propylamine
N-Nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,6-Trichlorobenzene
2,3,7,8-TCOD
-------
PICHER
ftCSHftCM
LAaKMUTDAY
£ P Analytical Report
Custoner ID:Pit J Make-up Water Run #2
Priority Pollutants Acid Extractablt Organic!
*37-02-132-04A
COMPONENT
2-Chlorophenol
2,4-Dichlorophciiol
2,4-Diaethylphenol
4,6-Dinitro-o-crt§ol
2,4-Dinitrophenol
2-'.litrophenol
4-Nitrophenol
p-Chloro-a-cresol
Ptncachlorophenol
Phenol
2,4,6-Tr ichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BHC
Gaama-3HC
Delta-BHC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endosulfan I
Endosulfan II
Endotulfan culfac*
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
-------
IM.Lf[f»>nCHER
MSIAftCH
LA9OMTOKT
I P Analytical Report Work Order *87-02-132-01A
Customer ID: Pit J Scrubber Water Run #1
Priority Pollutant! Metals ag\L
METAL
Antimony
Arsenic
Beryllium
Cadmium
Chromium
Copper
Lead
Mercury
Nickel
Seleniua
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
SAMPLE
Additional Analysis;
Total Organic Carbon
Chloride
-------
FKHER
Jtff3£AACH
E P Analytical Report
Cultoner IDtPit J Make-up Water Run 02
Priority Pollutants Volatile Organic*
87-02-132-04A
COMPONE.TT
Acrolein
Acrylonitrile
Benzene
bis (Chloroaethyl) ether
Broooform
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Dichlorobroaonethane
Oichlorodifluoromethane
1,1-Dichloroetbane
1,2-Dichloroethane
1,l-Dichloro*thyl«ne
1,2-Diehloropropane
1f3-Dichloropropylene
Ethylbenaene
Methyl bromide
Methyl chloride
Hethylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
1,2-Trant-dichloroethylene
1,1,1-Trichloroethane
1,l,2rTrichloroethan»
Trichloroethylene
Trichlorofluoronethan*
Vinyl chloride
SAMPLE
<0.100
<0.100
<0.005
<0.100
<0.005
<0.005
-------
-PKHER
ftCSCAJICM
E P Analytical Report
*87-02-132-01A
Customer ID:Pit J Scrubber Water Run
Priority Pollutant! Bate/Neutral Extractable Organic*
COMPONENT
Actnaphthene
Acenaphthylene
Anthracene
Benzidine
Benzo(a)anthracene
B«nzo(a)pyrene
3,4-Benzofluoranthene
Benzo(ghi)pcrylene
Benzo(k)fluoranthene
bis(2-Chloroethoxy)methane
bif(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bif(2-Ethylhexyl)phthalate
6-Bronophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
Dibenzo(a,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1,4-Oichlorobenzcne
3,3'-Dichlorobenzidene
Diethyl Phthalate
Diaethyl phthalate
Di-n-butyl phthalate
2,4rDinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1,2-Diphenylhydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutad iene
Hexachlorocyclopentadiene
Hexachloroethane
IndenoC1,2,3-c,d)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitroiodimethylamine
N-Nitrnsodi-n-propylaaine
N-Nitroiodiphenylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
PKHER
ftCSCMCH
E P Analytical Report
Customer IO:Pit J Scrubber Water Run tl
Priority Pollutant! Acid Extractable Organic•
#87-02-132-01A
COMPONENT
2-Chlorophtnol
2,4-Dichlorophenol
2,4-Dimethylphenol
4,6-Dinitro-o-cretol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-«-cre»ol
Pentachlorophenol
Phenol
2,4,6-Trichlorophenol
Priority Pollutants Pesticides/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Beta-BUC
Canma-BHC
Delta-BUC
Chlordane
4,4'-DDT
4,4'-DDE
4,4'-DDD
Dieldrin
Endo»ul£an I
Endosulfan II
Endotulfan tulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
<0.0002
<0.0002
<0.0002
<0.0002
<0.0002
<0.002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0004
<0.0004
<0.0004
<0.0004
<0.0002
<0.0002
<0.002
<0.002
<0.002
<0.002
<0.002
<0.004
<0.004
<0.004
-------
' Analytical R«port Work Order *87-02-132-03A
Cus comer 10: Pic J Make-up Wacer Run #1
Priority Pollutants Metals mg\L
METAL
Antimony
Arsenic
Beryllium
Cadaiun
Chr ouiurn
Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Priority Pollutants Miscellaneous
COMPONENT
Total Cyanides
Additional Analysis:
Total Organic Carbon 855.3
Chloride 7060.
-------
PKHER
AfSEAftCH
E P Analytical Rtport
Customer IDtPit J Scrubber Water Run #1
Priority Pollutant* Volatile Organic*
87-02-132-OU
COMPONENT
Ac role in
Acrylonitrilc
Benzene
bit (Chloroaethyl) ether
Brooofonn
Carbon tetrachloride
Chlorobenzene
Chlorodibroaonethane
Chioroethane
2'Chloroethylvinyl ether
Chloroform
Dichlorobronometliane
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Mrthvlene chloride
1,1,2,2-Tetrachloroechane
Tetrachloroethylene
Toluene
1,2-Tran«-dichloroethylcne
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Tr ichloroCluoromethane
Vinyl chloride
SAMPLE
<0.100
<0.100
<0.005
<0.100
<0.005
<0.005
<0.005
<0.005
<0.010
<0.010
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.005
<0.010
<0.010
<0.005
<0.005
<0.005
-------
PICKER
JtCSEAACM
E P Analytical Report
#37-02-132-03A
Customer ID:Pit J Make-up Water Run
Priority Pollutants Base/Wfutral Cxtractable Organics
COMPOSE ;rr
Acenaphthene
Acenaphthylene
Anthracene
Benzidine
BenzoC a)anthracene
BenzoC a)pyrene
3,4-Benzofluoranthene
B*nzo(£hi)ptrylene
Benzo(k)fluoranthene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl)ether
bis(2-Chloroisopropyl)ether
bis(2-£thylhexyl)phthalate
4-Bromophenyl phenyl ether
Butyl benzyl phthalate
2-Chloronaphthalene
4-Chlorophenyl phenyl ether
Chrysene
DibenzoCa,h)anthracene
1,2-Dichlorobenzene
1,3-Dichlorobenzene
1|4-0ichlorobenzene
3,3'-Oichlorobenzidene
Oiethyl Phthalate
Diaethyl phthalate
Oi-n-butyl phthalate
2,4-Dinitrotoluene
2,6-Dinitrotoluene
Di-n-octyl phthalate
1f2-Diphenyihydrazine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(l,2,3-ctd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-Nitrosodimethylamiae
N-Nitrosodi-n-propylanine
N-Nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-Trichlorobenzene
2,3,7,8-TCDD
-------
HCHER
L4iOftffOffV E P Analytical Report
Customer IDtPit J Make-up Water Run #1
Priority Pollutants Acid Cxtractable Organic*
#87-02-132-03A
COMPONENT
2-Chlorophenol
2|4-Dichlorophehol
2,4-Diaethylphenol
4,6-Dinitro-o-creiol
2,4-Dinitrophenol
2-Nitrophenol
4-Nitrophenol
p-Chloro-n-craaol
Ptntachlorophtnol
Phenol
2,4,6-Trichlorophenol
Priority Pollutant* Pcsticidet/PCB'S
COMPONENT
Aldrin
Alpha-BHC
Btta-BliC
Canma-BHC
Dtlta-BHC
Chlordane
4 ,4 '-DDE
4,4'-DDD
Dicldrin
Endoaulfan I
Cn^oaulfan II
Endosulfan aulfate
Endrin
Cndrin aldehyde
Heptachlor
Heptachlor epoxidt
PCB-1016
PCB-1221
PCB-1232
PCB-1242
PCB-1248
PCB-1254
PCB-1260
Toxaphene
SAMPLE
-------
VWVMf wn •
Carbon Ttcrachloride Results
ug/L
Shirco I.D. Make-Up
Pic J Run 1 <.5
Pic J Run 2 <.5
Pic I Run 1 <.S
Pic I Run 2 <.S
Pie « Run 1 <.5
Pic M Run 2 - <.5
Pic B Run 1 <.5
Pic B Run 2 <.5
ug/L
Scrubber E-P Saaple #'»
<.5 87-02-132-03A,
<.5 87-02-132-04A,
<.5 87-02-1 31 -03A,
<.5 8 7 -02 -13 1-04 A,
<.5 87-02-1 33-03A,
<.5 87-r02-133-04A,
<.5 87-42 -158-01 A,
<.5 87-02-1 58-02A,
-01A
-02A
-01A
-02A
-01A
-02A
-03A
-04A
-------
•JPKHER
AESCMCM
E P Analytical Rtport
Customer IO:Pit J Make-up Water Run #1
Priority Pollutants Volatile Organics
87-02-132-03A
COMPONENT
Acrolein
Acrylonitrile
Benzene
bis (Chloromtthyl) ether
Bronofonn
Carbon tecrachloride
Chlorobenzene
Chlorodibrofflomethane
Chloroettune
2-Chloroethylvinyl ether
Chloroform
Dichlorobrononethane
Dichlorodifluororaethane
1,1-Oichloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylcne chloride
1,1,2,2-Tetrachloroethane
Te trachloroe thyltne
Toluene
1,2-Trani-dichloroethylene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichloro fluorone thane
Vinyl chloride
SAMPLE
C0.100
<0.100
<0.005
<0.100
O.005
-------
SMCIAITV MATniAlS DIVISION •
• lAOll.PICMM IISIAKM LASOIATOIY
LQPP-10
Revision: 1
Date: 6-13-86
Page 1 of 5
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Customer or
Regulating Agency
Audits
Initiated By:
Sharon Farris
Approvals:
By;
Quality Assurance Dept.
By:
EPRL Apdlytic/I Director
1.0 Introduction
This standard Laboratory Quality program Procedure (LQPP) provides
general information on the procedures for customer and/or their
regulating agency's inspections/audits of projects conducted under
EPA regulations.
•
2.0 EPRL Policy
It is the policy of EPRL to permit inspections and audits by
customers and/or their regulating agency when such is understood to
be part of the order/contract.
2.1 Unless waived or otherwise stipulated by contract, advance
notice of at least two weeks is required.
2.2 Inspection/audits shall be conducted during normal business
hours.
2.3 The confidentiality of a client's identity and data shall be
maintained at all times. Requests by regulatory agencies to
inspect specific project data shall be honored only after
written permission of the customer is obtained.
>PKHCA
-------
• MfCIALTY MATMIAIS DIVISION <
• IAOII.MCHH MMAKM IAMIATOIV
2.4
LQPP-10
Revision: 1
Date: 6-13-86
Page 2 of 5
Inspectors shall comply with EPRL regulations governing
visitors.
2.5 When inspecting facilities, inspectors shall comply with EPRL
and project operation and safety procedures.
3.0 Inspection/Audit Procedures
3.1 Initial Contact/Preliminary Procedures: Regulatory agencies
may or may not give advance notice to arrange an inspection
date. This shall be dependent upon the customer's program
requirements as stipulated by contract. (When not stipulated
by contract, advance notice is required.)
3.1.1 Upon initial customer/regulatory contact, EPRL shall
obtain the following information:
Desired inspection date(s) and alternative date(s)
Name of the inspector (s)
Type of inspection to be conducted (surveillance
and/or directed — see "definitions" above)
Project(s) to be examined
Request that an inspection/audit plan be forwarded
to the Group Leader or QAD prior to the date of
the audit.
3.1.2 It shall be the responsibility of the EPRL individual
contacted to advise the affected departments/personnel.
As a minimum this shall include EPRL Management,
Contracts, Laboratory Director and/or Group Leader, and
QAD.
3.1.3 The QAD shall prepare for the inspection as follows:
3.1.3.1 Coordinate and verify that all affected
personnel have been informed.
3.1.3.2 Have a room reserved for the inspectors.
The room shall be secure, quiet, and contain
the necessary chairs and tables.
-------
> SPICIALTV MATftlALS DIVISION •
• lAOll.PICMU ItMAKH tABOtATOIT
LQPP-10
Revision: 1
Date: 6-13-86
Page 3 of 5
3.1.3.3 If a project's program is to be inspected
(i.e. a review of the data and records), the
QAD shall:
Assure that customer's permission in
writing, has been obtained
Assure that all study and QA records are
available and retrievable
Coordinate with Laboratory Director and
Group Leader and associated technical
support staff and explain inspection
procedures that may be expected and
encourage a courteous, cooperative spirit.
3.2 Inspection Procedure
3.2.1 Upon arrival of the inspectors in the lobby, the QAD
shall greet the inspectors and escort them to the
Conference Room where EPRL Management and affected
personnel will meet for:
Greeting and introduction of the inspectors
Verifying of inspectors' credentials
Initial pre-inspection conference
3.2.2 The inspectors shall:
Submit a signed notice of inspection
Describe the purpose of their visit
List the studies to be examined
State the approximate length of the inspection
Give an approximate date/time for the exit
debriefing and discussion of findings
3.2.3 The QAD shall:
Escort the inspectors of the reserved room
Request definition of the inspection plan (i.e.
what records and areas/facilities will be
examined)
Request the time plan
Accomodate the requests of the inspectors, when
possible
Resolve any scheduling problem
Explain the EPRL visitor policy
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• SMCUITY MATUIAU DIVISION •
• t AOU.PICHM MUAtCH lAtOIATOIT
F
LQPP-10
Revision: 1
Date: 6-13-86
Page 4 of 5
3.2.4 When inspecting the Analytical Lab facilities, the QAD
and/or Group Leader shall escort the inspectors at all
tines.
3.2.5 Interviews of staff members by the inspectors should be
carried out in the presence of the QAD. If this is not
possible, the staff member shall report the substance of
the interview to the QAD, or to the Laboratory Director
and/or Group Leader who shall in turn advise the QAD.
3.2.6 If documents are requested by the inspectors, the QAD
shall deliver them to the reserved inspection room, then
shall:
3.2.6.1 Maintain a record of all paperwork inspected
3.2.6.2 Maintain control of all documents in the
inspector's office
3.2.6.3 If copies of the documents are requested,
the QAD shall:
Provide two copies, one for the inspectors
and one for QAD
Stamp copies of documents considered to be
proprietary (SOP's, etc.) with an
appropriate stamp
Have the inspectors sign and date one copy
and countersign the one retained by the QAD.
3.3 Post-Inspection Procedure
3.3.1 At the conclusion of the inspection, the inspectors
shall arrange for a deabriefing meeting. EPRL
Management, QAD, Group Leader, and Laboratory Director
shall meet with the inspectors.
3.3.2 At the debriefing:
The inspectors shall submit a listing of any
adverse findings.
EPRL Management shall discuss any differing
opinion and attempt to clarify the inspectors'
perception or observations. Management may also,
at the conclusion, offer to explain what
Management considers to be erroneous observations.
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• SPICIAlTY MATIIIALS DIVISION
• I AOII.PICHIC HSIAKMlABOIATOCY
LQPP-10
Revision: 1
Date: 6-13-86
Page 5 of 5
3.4 Staff Debriefing: The QAD shall conduct a debriefing for the
technical/support staff involved.
3.5 Records: The QAD shall maintain a complete record of the
inspection, including:
Data inspected
Facilities/areas visited
Staff interviewed
Copies of records taken and receipts for them
Any other pertinent information
•KAQll
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• mClAlTV MATUIALS DIVISION <
• t AOll.FICMII NSIAKN LAtOt ATOtT
LQPP-11
Revision: 1
Date 6-13-86
Page 1 of 4
EAGLE-PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Sub ject: Analys is
of Quality Control
Samples
Initiated By:
Sharon Parris
Approvals:
Quality Assurance Dept.
By:
yticjrl Director
1.0 Introduction
This LQPP discusses samples which are routinely added to the normal
laboratory sample routine to demonstrate that the laboratory is
operating within prescribed requirements for accuracy and
, precision. Quality control samples are of known content and
concentration (with the exception of field blanks) so that accuracy
and precision can b« determined and control charts can be prepared.
Evaluation of these data are discussed in LQPP-13.
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SPICIAITY MATIIIAkS DIVISION '
• IAOU.PICMM MUAKM LAtOt ATOIY
LQPP-11
Revision: 1
Date 6-13-86
Page 2 of 4
2.0 Types of Quality Control Samples
2.1 Field Blank (Trip Blank) Analyses
Volatile ocganics samples are susceptible to contamination by
diffusion of organic contaminants through the teflon-faced
silicone rubber septum of the sample vial; therefore, field
blanks shall be analyzed to monitor for possible sample
contamination during shipment. Field blanks will be prepared
by filling two VOA vials from organic-free water and shipping
the blanks with the field kit. Field blanks accompany the
sample bottles through collection and shipment to the
laboratory and are stored with the samples. Following the
analyses, if the field blanks indicate possible contamination
of the samples, depending upon the nature and extent of the
contamination, the samples may be corrected for the field
blank concentration or the sources resanpled. Results of
field blank analyses should be maintained with the
corresponding sample analytical data in the project file.
2.2 Reagent Blank Analyses
A reagent blank is a volume of deionized, distilled laboratory
water for water samples, or a purified solid matrix for
soil/sediment samples carried through the entire analytical
procedure. The volume or weight of the blank must be
approximately equal to the sample volume or sample weight
processed. A reagent blank verifies that method interferences
caused by contaminants in solvents, reagents, glassware, and
other sample processing hardware are known and minimized.
Optimally, a reagent blank should contain no greater than two
times (2X) the method detection limit for the parameter.
Results of reagent blank analyses should be maintained with
the corresponding analytical data in the project file.
2.3 Duplicate Sample Analysis
Duplicate analyses are performed to evaluate the precision of
an analysis. Results of the duplicate analyses are used to
determine the relative percent difference between replicate
samples. Criteria for evaluating duplicate sample results are
provided in LQPP-13.
A duplicate analysis should be performed whenever a group of
five or more samples are analyzed at one time. Duplicate
analysis results should be summarized on the quality control
data summary form.
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• SMCIAITV MATIRIAU DIVISION <
• iAOll-PtCMff N8IAKM lAMIATOtT
LQPP-11
Revision: 1
Date 6-13-86
Page 3 of 4
2.4 Check Standard Analyses
Because standards and calibration curves are subject to change
and can vary from day to day, a midpoint standard or check
standard should be analyzed with each group of staples.
Analysis of this standard is necessary to verify the standard
curve and may serve in some cases as sufficient for
calibration. This value should be entered in the instrument
calibration log whenever performed. Check standard analyses
results should be summarized on the quality control data
summary form.
2.5 Surrogate Standard Analyses
Surrogate standard determinations should be performed on all
samples and blanks for OC/MS analyses. All samples and blanks
are fortified with surrogate spiking compounds before purging
or extraction to monitor preparation and analysis of samples.
-Recoveries should meet acceptance criteria which are
established as laboratory results become available. Surrogate
standard data should be summarized on the surrogate standard
recovery form.
2.6 Matrix Spike Analyses
To evaluate the effect of the sample matrix upon analytical
methodology, a separate aliquot sample should be spiked with
the analyte of interest and analyzed with the sample. The
percent recovery for the respective compound will then be
calculated. If the percent recovery falls outside established
quality control limits (75 to 125 percent for most
parameters), the data should be evaluated and the sample
reanalyzed if criteria are not met. Matrix spike results
should be summarized on the quality control data summary
sheets.
2.7 Blind Replicate Analysis
A blind replicate sample is a duplicate sample which has been
introduced as a separate sample by the Quality Control
Coordinator during the log-in process or prior to analysis.
Evaluation of the replicate is discussed in Section 10.1.
This data is reported to and summarized by the Quality control
Coordinator.
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• SMCIAITY MATMIALS DIVISION
• IAOU-MCHH MSIAKM LASOIATOIY
LQPP-9
Revision: 1
Date: 6-13-86
Page 2 of 3
3.0 Corrective Action Procedures
On-the-spot corrective action usually applies to spontaneous,
generally non-recurring problems, such as an instrument
malfunction. Recurring quality assurance problems may require
closed-loop corrective action involving EPRL Management.
Deviations from established procedures, program plan, or customer's
regulations reported by QAD shall be immediately communicated to the
Group Leader and Laboratory Director for corrective action.
3.1 On-the-spot Corrective Action Procedure
3.1.1 Any staff member who detects/suspects nonconformance to
perviously established criteria or procedure in
equipment, instruments, data, methods, etc. shall
immediately notify the appropriate Group Leader and/or
Laboratory Director. In many cases, the staff member
will be able to correct the problem.
When a situation results in a change in data reported, a
corrected report shall be prepared or reported to the
Laboratory Director who shall then forward corrected
copy following routine distribution of the original
report.
The corrected report shall then be attached to the top
of the original report so that sample analytical data is
complete and accurate.
3.1.2 If a large quantity of data is affected, or if any of
the analyses conducted during the suspect period where
of a critical nature, or if the program involved is one
which requires documented corrective action, the closed-
loop corrective action procedure is to be followed.
>PKHC*
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• mClAlTY MATIIIALS DIVISION •
• IAOLI.PICMM KSIAKH LAftOtATOIT
LQPP-9
Revision: 1
Date: 6-13-86
Page 3 of 3
3.2 Closed-loop Corrective Action Procedure
3.2.1 Any staff member who detects a recurring or unresolved quality
assurance problem shall advise the Laboratory Director and
QAD.
3.2.2 The QAD shall contact the Laboratory Director and Group Leader
if applicable, and prepare and route a Corrective Action
Request (CAR), and advise EPRL Management by copy of the CAR.
3.2.3 As determined appropriate, the staff member, Group Leader,
Laboratory Director, QAD and EPRL Management shall consult to
determine appropriate corrective action plan and report same
on CAR.
3.2.4 The corrective action shall be initiated, documented and
results forwarded to QAD.
3.2.5 QAD shall investigate to verify resolution.
3.2.6 The QAD shall close the CAR or plan for follow up if
determined necessary before CAR may be considered closed.
3.2.7 Zf the corrective action was unsuccessful, above procedure is
to be repeated.
-tAQUE
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• SMCIAITY MATMIAIS DIVISION <
• IAOLI.MCMII MSIAKM IABOIATOIT
LQPP-8
Revision: 1
Date: 6-13-86
Page 3 of 3
4.3 Additional items required in a report of an EPA related
project are:
4.3.1 Study initiation and completion dates.
4.3.2 Clear statement of objectives.
4.3.3 Description of methods, procedures, and test system
used. The methods, etc. must be consistent with the
Project's program requirements. Any change must be
documented and justified. (Refer to LQPP-5 for
procedure.)
4.3.4 Adequate identification of the test/control substance.
4.3.5 Stability of the test/control substance under study
conditions.
4.3.6 Description of all circumstances that may have affected
quality or integrity of the data.
4.3.7 The name of the Group Leader and the names of other
analysts and/or professionals and all supervisory
personnel involved with the project.
4.3.8 Final reports shall also include:
Signature by the Group Leader
Indication of review by EPRL Management
QAD Statement
4.3.9 Any corrections to final report must specify the portion
of the final report being amended and must be signed by
Group Leader, EPRL Management, and QAD.
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• SMCIAITY MAT!HALS DIVISION •
IAOU .PICMII IIMAtCM lABOIATOIT
LQPP-9
Revision: 1
Date: 6-13-86
Page 1 of 3
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Corrective
Action Procedures
Initiated By:
Sharon Farris
Approvals:
By:
Quality Assurance Dept.
EPRL Analytical Director
1.0 Introduction
This standard Laboratory Quality Program Procedure (LQPP) provides
general information on corrective action procedures, and is based on
the principles of Eagle-Picher Industries, Inc, Q.A.P.
2.0 -Background
A quality assurance system must be sensitive and responsive in
detecting problems and unusual project activities and provide a
timely, systematic mechanism to rectify the situation. Two types of
systems are described below: On-the-spot and Closed-loop-corrective
action procedures.
•IMUI
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• SPKIAITY MATtttAlft DIVISION •
• lAOll.MCHIl MUAKM LAtOIATOIT
LQPP-8
Revision: 1
Date: 6-13-86
Page 1 of 3
EAGLE- PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: QA Review
and Audit of Reports
Initiated By:
Sharon Parr is
Approvals:
By:^\p ^ONW-*
Quality Assurance Dept.
•X^LS*^^*
ujf *^^^^j^jLy^ * jt^^^^^
EPRL Analytical Director
1.0 Introduction
This standard Laboratory Quality Program Procedure (LQPP) provides
specific information for Quality Assurance Department (QAD) reviews
or audits of reports.
2.6 Responsibility
2.1 The QAD shall review or audit reports when:
2.1.1 Required by a specific project's requirements,
regulations, or by department policy, or upon request of
EPRL Management.
2.1.2 Laboratory Director or Group Leader specifically
requests a review or audit.
UOLM
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• SMCIAITY MATMIAIS DIVISION •
.PICHU IISIAKM LAtOIATOIT
LQPP-8
Revision: 1
Date: 6-13-86
Page 2 of 3
2.2 The Laboratory Director and/or Group Leader are respnsible
for:
2.2.1 A two-level technical review of a report prior to a QAD
review/audit.
NOTE: Technical reaview shall be documented to include
signature and dates of the review attached directly to
the applicable report.
2.2.2 Ensuring that the QAD receives all reports required to
be reviewed or audited.
3.0 Corrective Action
Problems shall be referred to the Laboratory Director and/or Group
Leader who shall then take/initiate appropriate corrective action.
4.0 Guidelines
4.1 Items generally included in a review or audit (by both the
technical group and QAD), but not limited to, are:
4.1.1 Clarity.
4.1.2 Accuracy of the description of results: reported data
in any form (figures, tables, graphs, etc.) must reflect
the raw data.
4.1.3 Completeness and accuracy of any instrumental
parameters.
4.1.4 Random checks for computational errors.
4.2 Additional items which may be included in an audit are:
4.2.1 Examination of the study files.
4.2.2 Documentation procedures.
4.2.3 Data calculation procedures.
4.2.4 Internal quality control procedures.
•IAOUI
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• SMCI AlTT MATMIAkS DIVISION •
• lAOU-PfCHft IIMAICM LABORATORY
LQPP-7
Revision: 1
Date: 6-13-86
Page 2 of 3
3.0 Department Compliance
4.0
To assure laboratory QC/QA compliance, the QAD shall:
3.1 Periodically conduct general inspections/audits of:
3.1.1 Laboratory Facilities: These shall be maintained in
accordance with the policies of the Analytical Lab as
well as EPRL's applicable safety policies, and the Good
Laboratory Practices Act (GLP).
3.1.2 Equipment: Equipment used on projects for sampling
and/or analysis shall have standard operating
procedures, use logs, and calibration and/or maintenance
records in accordance with LQPP-3.
3.1.3 Methods and Practices: Methods and practices shall be
in accordance with the Quality Assurance Manual for the
Analytical Lab unless superseded by specific project
requirements in which case EPRL Management/QAD approval
is required.
3.1.4 Records: Records shall be documented and retained in
accordance with LQPP-5 and LQPP-6.
3.2 Prepare and submit the results to EPRL Management, noting
problems and recommended actions.
3.3 Maintain the written and signed records of inspection/audits.
Project Compliance
4.1 For projects requiring EPRL Management/QAD approved QA plans
and procedures, the QAD shall conduct or direct inspections
and/or audits specific to the project. These shall include
but not be limited to facilities, equipment, methods and
practices, procedures, records and QA program plans specific
to the project.
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> SMC1AITY MATUIAIS WVISK
• IAOU.MCMH MMAtCM kABOIATOIT
LQPP-7
Revision: 1
Date: 6-13-86
Page 3 of 3
4.2 For projects conducted under EPA regulations, the QAD shall
also:
4.2.1 As a minimum, inspect each critical phase of a study as
follows:
Studies lasting 6 months or more—-every 3 months
Studies lasting less than 6 months sufficiently
to adequately ensure study/program integrity
To determine that no SOP deviations were made without
proper authorization and documentation.
4.2.2 Prepare and submit the results to Group Leader and
Laboratory Director as well as EPRL Management.
4.2.3 Maintain the written and signed records of each
inspection.
4.2.4 Prepare and sign a statement to be included with the
final report which specifies the inspection date(s) and
the date(s) of reports to EPRL Management.
4.2.5 Review the final report to assure that report accurately
reflects methods, SOP's, and the results of the raw
data.
KAQU
JWCHIH
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• SMCIALTT MATMIALS DIVISION •
• I AOU.PIO4II MMAKM lABOIATOtT
LQPP-2
Revision: 1
Date: 6-13-86
Page 1 of 3
EAGLE-PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Staff
Qualifications
Initiated By:
Sharon Farris
Approvals:
Quality Assurance Dept.
By:
EPRL Analytical Director
1.0 Introduction
This standard Laboratory Quality Program Procedure (LQPP)
provides general information on qualification* and training of staff
personnel, and for documenting the staff qualifications.
2.0 Requirement
2.1
2.2
Personnel shall be qualified to perform assigned work.
Staff who do not possess specific experience by prior
training or background shall be trained before
assignment to projects requiring that experience.
Staff resumes and/or curriculum vitae shall be updated
at least annually.
•KAOil
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• IHClAm MAT! tlALS OlVlf *
ffCHII MUAftCM LAMIATOIT
LQPP-2
Revision: 1
Date: 6-13-86
Page 2 of 3
3.0 Responsibility
3.1 The Laboratory Director is responsible for:
* Initiating the preparation and/or updating of all
resumes and/or curriculum vitae.
* Ensuring that department staff resumes and
qualification and training documentation are
current, complete, and provided to QAD.
* Defining job descriptions, determining the extent
of training required and the training methods, and
documenting successful completion of training.
NOTE: This does not preclude any policies or
requirements of the Personnel Office, but as a
minimum is in addition to requirements of the
Personnel Office.
3.2 The QAD shall maintain current summaries of the various
job descriptions, experience, and pertinent training of
staff relating to projects which require EPRL
management/QAD approved program plans or projects
conducted under regulations.
4.0 Training Methods
Training methods may include the following:
4.1 Training courses •offered by an accredited university,
technical school, professional associations, seminars,
instrument manufacturer or EPRL.
4.2 On-the-job training, consisting of:
4.2.1 Instruction on the general theory and operation of
a task.
4.2.2 Observation of the trainee performing the task by
an experienced person.
4.2.3 Performance of the task by the trainee under close
supervision.
4.2.4 Semi-independent performance of tasks by the
trainee using check samples or equivalent.
•EAOil
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> SMOAIT1 MATfRIAlSOtVIStOM •
• lAOtl-MCMtl IIMAtCM lAftOCATOlY
LQPP-2
Revision: 1
Date: 6-13-86
Page 3 of 3
5.0 Documentation Procedures
To cover projects requiring QAD review of staff credentials:
5.1 Staff members shall send copies of certificates,
diplomas, or evidence of training courses, etc. to Lab
Director who shall in turn be responsible for providing
information to the QAD.
5.2 For on-the-job training:
5.2.1 The job instructor shall prepare documentation to
include:
* Names of the trainee(s) and instructor(s)
* Date(s) of instruction
* Detailed instruction procedure (if
applicable). As a minimum, an outline of
training covered.
* Results of the proficiency exam (if
applicable).
5.2.2 The Laboratory Director shall sign the memo,
signifying that the trainee(s) are now prepared
for the specific task(s) assigned. A copy of the
documentation shall be sent to QAD.
5.3 QAD shall follow through on documentation
recording/filing procedure.
6.0 Corrective Action
Problems shall be referred to the Laboratory Director who
shall then take the appropriate corrective action.
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• S»f CIAITY MATHIAU DIVISION <
• IAOU.MCHU IIMAtCM LASOIATOIT
LQPP-5
Revision: 1
Date: 6-13-86
Page 1 of 4
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject:
Documentation
Procedures
Initiated By:
Sharon Farris
Approvals:
Quality Assurance Dept.
.
EPRL ADftlyticai Director
1.0 Introduction
This standard Laboratory Quality Program Procedure (LQPP) provides
.general guidelines on documentation procedures.
2.0 Responsibility
2.1 The Laboratory Director and Group Leader are responsible for
training the staff and for enforcing this LQPP.
2.2 The Quality Assurance Department (QAD) is responsible for
verifying compliance (via inspections) and maintaining
inspection records.
3.0 Corrective Action
Problems shall be referred to the Laboratory Director and/or Group
Leader who shall then take the appropriate corrective action.
••AOL*!
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• SMCIALTT MATIIIALS DIVISION •
• IAOU.PICMI• tlSIAKH LAtOIATOIT
LQPP-5
Revision: 1
Date: 6-13-86
Page 2 of 4
4.0 Documentation Procedures
Project documentation requirements which supersede or supplement
current policy shall be communicated by the Laboratory Director and/or
Group Leader to project staff, in such cases, project SOP's are
required.
It should be noted that "raw data" are any original observation
project records, or exact copies thereof, necessary for the
reconstruction and evaluation of a report.
4.1 Validation
^•MVO^—•••—1^—_ |
For a project subject to a QAD audit, project staff who enter,
review, correct, or add project information of original data
shall print and sign their names and date entery accordingly.
4.2 Laboratory Notebooks
All staff who enter or review entries in the notebook shall
print and sign their names and write their initials on the
signature page at the front of the notebook. Thereafter,
initials may be used in place of signatures.
4.2.1 Record all entries legibly in permanent, preferably black,
ink.
4.2.2 Record information in chronological order, preferably on
the day the work is performed.
4.2.3 Complete the information blocks at the top and bottom of
each page. The Group Leader or designee shall frequently
review entries, initial and date the bottom of each page
of "raw data".
4.2.4 Enter information directly into the notebook unless
conditions do not permit such entry. Discuss "restricted-
access" procedures with supervisor.
•CAOil
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> SPICIAITY MATUIALS MVISION <
> lAOll-PICHIH MMAtCH LAtOIATOtT
LQPP-5
Revision: 1
Date: 6-13-86
Page 3 of :
4.2.5 include all data, observations, calculations, notes and
pertinent procedures. Include sufficient detail that a
coworker could continue the work. Record all activities
regardless of outcome. Record unusual observations or
unexplained results, and if possible, add an explanation.
Describe results that may warrant future investigation.
Include new ideas, concepts, or applications of an idea,,
4.2.6 Document ALL deviations from standard operating procedures
(SOP's) and include reason.
4.2.7 Fully identify loose sheets or equipment printouts as
applicable if they are attached to notebook pages. (See
"Equipment Printouts" on following pages.)
4.2.8 CORRECTIONS/ADDITIONS: Draw a single line through the
incorrect entry so that the original entry remains
legible. Add the correct entry then explain, initial, and
date the correction. Mew information may be added to the
original page if initialed and dated. Erasures are NOT
allowed.
4.3 Equipment Printouts
4.3.1 Input (if computerized) or record legibly, in permanent
ink, the following information on each printout:
* Project identification (i.e. job number)
* Date work was performed
* Other pertinent information (analyst, sample number,
instrument parameters, etc.)
4.3.2 Sign or initial and date each printout or the cover sheet
of printout sets.
4.3.3 Where applicable, cross reference the printout or cover
sheet to the applicable lab notebook (book number and page
number).
u
0
0
•EAOLE
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> f MCIALTY MATUIALS DIVISION <
.PICMI• IIUAICH LAtOI AT00Y
LQPP-5
Revision: 1
Date: 6-13-86
Fage 4 of 4
4.3.4 CORRECTIONS/ADDITIONS:
4.3.4.1 Manual Changes; See "Laboratory Notebooks" section.
4.3.4.2 Automated Changes;
4.3.4.2.1 Keep the original entry intact in the system. If
possible/ do not transfer the original entry to a
new position (to avoid transfer errors).
4.3.4.2.2 Code the original entry to show it has been
superseded.
4.3.4.2.3 Input the correct entry so that it is traceable to a
person. Date and explain the correction, use
traceable codes when possible.
4.4 Q.A. Records
All QAD records shall be maintained by the QAD.
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• SMOAITY MATHIALS DIVISION <
• IAOU-MCHUMMAICM IABORATOIT
LQPP-7
Revision: 1
Date: 6-13-86
Page 1 of 3
EAGLE-PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: QAD
Inspections and
Audits
Initiated By:
Sharon Parris
Approvals:
Quality Assuranc
ity Assurance Dept.
EPRL Apalyticaf Director
1.0 Introduction
/
This standard Laboratory Quality Program Procedure (LQPP) provides
general information on inspections/audits conducted or directed by
Quality Assurance Department (QAD). In some instances, the QAD may
request assistance in an inspection/audit by a Quality Control
Coordinator (QCC).
2.0 Definition
Quality Control Coordinator; Someone considered by the Quality
Assurance Manager and EPRL Management to be qualified to perform a
particular field or laboratory audit who is temporarily assigned to
the QAD. This may be a member of EPRL, of the Division, or an
outside source.
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• mooirr MATONAU WVWOM •
rotT
LQPP-1
Revision: 3
Date: 11-25-86
Page 1 of 8
EAGLC-FICBEK RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSORAMCE PROCEDURES MANOAL
Subject: Quality
Assuranee Program
Initiated By:
Sharon Parris
Approvals:
By; *S.#.
Quality Assurance Dept.
Director
1.0 Introduction
The Analytical Laboratory of Eagle-Picher Research
Laboratories (EPRL) perteras a variety of analytical services for a
• vide range of custoners which represents Mny varying specifications
and requirements. The QA/QC prograa was developed to ensure that a
high standard of performance-wcwld be consistently applied to these
services.
These services are performed by trained analysts. The
technical reports include the analytical results, analytical
s*thods, and a thorough discussion of the subject arterial, aa
required by the customer.
Quality assurance is monitored on a continuing basis by the
Quality Control Coordinator or his designate from the Quality
Assurance Department(QAD). The QAD reports directly to EPRL
management. This permits complete independence in overall program
review and direct access to EPRL management.
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• WtCUUTY MATMAU DIVISION •
• lAOU^KHU MMAKM LAKWAKMT
LQPP-1
Revision: 3
Date: 11-25-86
Page 2 of 8
2.0 Definitions
2.1
2.2
2.3
2.4
Quality Assurance Policy Manual - Quality assurance and
quality control procedures which state the official Quality
Assurance and Quality Control procedures for all activities
vhich oould dirtctly or indirtctly influence data quality.
Standard Operating Procedures (SOP's) - Standard documents
used to define the guidelines and/or procedures to be followed
in the various operations of the laboratory.
general in nature or project specific.
These aay be
Project Quality Assurance Plan - A formalized document which
will be initiated when a project requires EPRL/QAD approved
project plans. The plans Bay supercede QA/QC policy programs
and procedures. Gustos** specifications and regulations will
be the basis of a project QA program plan and for project
specific operating procedures.
Regulations/ Standards, and Guidelines - Those requiresjents on
which the basic and project specific QA activities are based.
3*0 Quality Assurance Policy
laglt-Picntr Rtsearch Laboratories is committed to providing
services which Met clients' needs, satisfy regulatory requirements,
and utilize state of the art technology. EPRL policy is to conduct
all projects in a timely, efficient, and consistent Banner so as to
provide customers with consistent and reliable services. The
quality assurance program is to ensure that all data generated and
reported is accurate, precise, scientifically valid, and legally
defensible.
4.0 Responsibility
The responsibility and authority for establishing,
coordinating, and implementing the quality assurance program has
been delegated to the QAD. The Quality Control Coordinator reports
directly to the EPRL Director cf Research and Development.
-------
• SMCUITT MATUIAU DIVISION
IATC«Y
LQPP-1
Revision: 3
Date: 11-25-86
Page 3 of 8
5.0 Quality Aaaauranee Program
The Quality Assurance Program for the Analytical Division of
EPRL is designed to encompass the baaic principles aa aet forth in
Good Laboratory Practice Regulationa (Part 58 of Federal Register).
In the event of a conflict between the Laboratory QA program
and Project QA program, the Project QA program ahall take precedence
as will Project SOP'a.
6.0. QA Program Requirements
The Laboratory'a quality assurance program ia designed to
ensure QA compliance to customers' specifications of all applicable
projects.
6.1 Responsibility
6.1.1 The Laboratory Director and/or Project Manager ahall:
6.1.1.1 Identify, compile, and write the SOP.
6.1.1.2 Make pertinent SOP's available to the
appropriate staff and in the appropriate
areas.
6.1.1.3 Monitor and assure compliance with the SOP.
6.1.2 The Quality Assurance Officer ahall:
6.1.2.1 Coordinate SOP preparation.
6.1.2.2 Coordinate review/revision of SOP*a.
6.1.2.3 Verify conformance (via inspections or
audits).
6.1.2.4 Direct or supervise the following:
• Reproducing and issuing controlled copies of
SOP'S
* Retaining current and superseded copies of
the SOP's and LQPP'a.
• Maintenance of inspection records.
-------
• tMOALTY MATOMAU MVWON •
• IAOU-MOMI ttUAKM lAMMATOtr
LQPP-1
Revision: 3
Date: 11-25-86
Page 4 of 8
6.2 Format Criteria for SOP*s and LQpp's
6.2.1 These shall be written in a standardized foraat as
follows:
6.2.1.1 First Page:
* Code identification nuaber
* Revision nuaber (Original to be denoted as
"0")
• Date of issue (i.e. effective date)
* Page nuaber and total nuaber of pages
(page of )
* Title
• Revision Status (MSOP's)
* Approval signatures
MOTE: For LQPP's, QAD, and EPRL Management
signature required. For .SOP's, Laboratory
Director and QAD signature required.
6.2.1.2 Subsequent pages:
* Code identification number
• Revision number
• Date of issue
* Page -number and total number of pages
6.2.1.3 Additional requin
Quality Manual:
t for Laboratory
Table of Contents
Revision suaaary page
Bach page revised in a specific manual
Revision will denote manual revision in
Upper right corner above the code number.
-------
• ftPICIALTY MATOHALS DIVISION
IATOVT
LQPP-1
Revision: 3
Date: 11-25-86
Page 5 of 8
6.3
6.4
6.2.2 HSOP'a (Mthod SOP1*) shall be formatted in the
following sequence:
Sumary
Application
Apparatus 4 Chemicals
Calibration
Sample Handling i Storage
Procedure
Calculations
Quality Control
References
NOTE: MSOP's will be maintained under seperate covers, but
trill be required to follow the saae prodedure as for
•Controlled Copies."
LQPP's and SOP's shall be written in such tens as to be
complete, concise, and easily understood by the user.
Equipment SOP's may omit detailed instructions by referring to
portions of the equipment Manual. The manual is to be
referenced and is to be in the work area where the equipment
is located.
6.5 As a minima, there shall be LQPP's covering the following:
Quality Assurance Policy
Staff Orgahlffation/Qoaiifieations/Training
QA Review and Audit of Reports
Reagent Labeling, Storing and Testing
Documentation
QA Record Storage and Retention Tim*
Inspections/Audits
Ronconformanca and corrective Action
Analysis of QC Samples
Analytical Procedures
Data Verification and Reports
•ft
-------
PtOAiTY NUTUHAU DIVISION •
I LAtOIATOlY
LQPP-1
Revision: 3
Date: 11-25-86
Page 6 of 8
6.6 As a minimum, there shall be Analytical Laboratory Standard
Operating Procedure* (ALSO?) covering the following:
• Facility Security
• Visitors
• Temperature Monitoring of Refrigerated Storage
Areas
* Hater Purification System Honitoring
* Instrument Operation, Calibration, and
Maintenance
• Preparation of Sanple Containers
* Reagent Procurement, Reciept, and Storage
• Sample Receipt and Log-in
• Sample Storage
* Sample Chain of Custody
• Glassware Cleanup
• Calibration of Measuring Equipment
• Standards Preparation and Tracking system
* Sample Analysis and Tracking
* Data Recording, Assembly, and Storage
* Sample Disposal
• Safety Manual
6.7 If forms are referenced, refer to then by title and form
number and by what other identification they have been given
in the text. (Example: Figure 3 or Exhibit *C", etc.).
Sample forms should have "SAMPLE" marked on then.
7.0 Responsibility for Compliance
7.1 General QA Compliance
7.1.1 The Analytical Laboratory staff shall:
* Conduct their respective tasks and responsibilities in
accordance with generally
•MOUl
-------
• SMCIAOT MATOHAU OIVtSION -
IIABO«ATO*Y
LQPP-1
Rtviaion: 3
Date: 11-25-86
Page 7 of 8
accepted good laboratory practice* and the
established laboratory quality assurance program.
• Update staff credentials as changes occur.
7.1.2 At least annually, unless otherwise required by
specific contract requires*nts, the QAD shall:
• Assist in implementing and ami tor ing QA/QC
programs.
* Review and initiate update of QA-related policies
and procedures.
* Inspect project-specific archives.
• Report the results of inspection to Lab Management
and EPRL Management.
7.2 Proposal Compliance
7.2.1 Por proposals that, in the opinion of EPRL Management,
require a QA/QC plan, the QAD shall:
* Review the program requirements.
* If required, assist in the
preparation/revision of the proposed
program and QA/QC plan.
7.3 Project Compliance
7.3.1 Por projects requiring approved QA/QC plans, the QAD
shall:
• Review the project proposal for adequacy of the
QA/QC plan.
• Coordinate the preparation of QA/QC plans.
• Conduct inspections or audits.
* Prepare and submit the results of inspections
and/or audits to Laboratory Director, Project
Manager, and EPRL Management.
-------
• MKUUTT MATSMAU DIVISION •
• lAOU-MOW MUAKMlAte*ATO*Y
LQPP-1
Revision: 3
Dat*: 11-25-86
Page 8 of 8
8.0 Corrective Action
Problem* determined by, or referred to, the QAD shall be
reviewed by the QAD, Lab Director, and Group Leader, who shall then
initiate the appropriate corrective action. Refer to LQPP-9.
9.0 Regulations/Guidelines
General guidelines used in generating the overall Laboratory program
are:
9.4
9.5
Good Laboratory Practice Regulations for Non-Clinical
Laboratory Studies, FDA, FR 43, 59986, Dec. 22, 1978.
9.1 Good Laboratory
- id .
AMndnent'FR 45, 24865, Apr.~Ii, 1980.
9.2 Toxic Substances Control Act; Good Laboratory Practices
Standards, EPA FR 48, 53922, November 29, 1983.
9.3 Interim Guidelines and Specifications for Preparing Quality
Assurance Project Plans, QAHS-*005/80. December 29
EPRL Facility Quality Assurance Policy Manual
g Qualil
, i960.
Good Laboratory Practice Regulations for Non-Clinical
I 43, !
Amendment FR 45, 24865, Apr ."II, 1980.
3
id
Laboratory Studies, PDA, FR 43, 59986, Dec. 22, 1978,
-------
DOCUMENT NO.
EPL - 001
Rev.
NOTE:
REVISION PAGE
Current revision letter 1s to be placed 1n upper right corner of each
revised page as Identified below.
Revision
Symbol
Orig.
1
2
3
Description
QCCI 95 •
QQC* 98
QCCi 1Q3
Page
Date
10/14/85
4/3/86
7/15/86
11/25/86
Approval
J.£&
S.R.F^&-
S.R.FCS93-
S.R.F.SO-
QA-207
iii
-------
Rev. 3
Introduction
Page 1 of 3
EAGLE-PICHER INDUSTRIES, INC.
Specialty Materials Division
Eagle-Picher Research Laboratory
DOC. Ho. EPL-001
TABLE OP OOHTPTTS
Section Section Title
LQPP-1 Quality Assurance Program
LQPP-2 staff Qualifications
LQPP-5 Docunentaion Procedures
LQPP-7 QAD Inspections and Audits
LQPP-8 QA Review and Audit of Reports
LQPP-9 Corrective Action Procedures
LQPP-10 custcwr or Regulating Agency Audits
LQPP-11 Analysis of Quality Control Saiples
LQPP-12 Analytical Procedures
DQPP-3,3 Data Verification
LQPP-14 Data Reports
ALSOP-1 Glassware Clean Op
ALSOP-4 production and Monitoring of
Reagent Water
ALSOP-7 Facility security
ALSOP-8 instrument Operation, calibration,
and Maintenance
Revision No.
3
1
1
1
1
1
1
1
1
0
.2
1
1
0
-------
EAGLE-PICKER INDUSTRIES, INC.
Specialty Materials Division
Eagle-Picher Research Laboratory
DOC. No. EPL-001
Section
ALSOP-9
ALSOP-10
TABLE OP CONTENTS
Section Title
Reagent Procurement, Labeling,
and Testing
Record Retention Procedures
ALSOP-11 Sample Chain-of-Custody
ALSOP-12 Sample storage and Security
ALSOP-13 sample Reciept and Log-In
ALSOP-14 Preparation of Sample Containers
ALSOP-15 Temperature Monitoring of
Refrigerated Storage
ALSOP-16 Visitors
ALSOP-17 Sample Disposal
ALSOP-18 Report Assembly ana Data Storage
ALSQP-19 Laboratory Data Recording and validation
ALSOP-20 sample Analysis and Tracking
ALSOP-21 standards Preparation and Tracking System
ALSOP-22 Equipment Malnteneance
ALSOP-23 Calibration of Measuring Equipment
Rev. 2
Introduction
Page 2 of 3
Revision No.
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
LABORATORY
Mtamf, OK
Rev. 3
Introduction
Page 3 of 3
25 November 1986
TECHNICAL SALES
COORDINATOR
J. 8n»49 r 4••
SUPPORT CROUP
I. RlUy
DIRECTOR OF
ENVIRONMENTAL
SERVICES
Lar r y ZInn
QUALITY ASSURANCE
S. R. F»rr I *
TECHNICAL MANAGER
C. Lalng
SAMPLE MANAGEMENT
COORDINATOR
J. B«i ght»
INORGANICS
6. Organ/B. P«rrln
ORCANICS
H. Navarre
-------
QUALITY ASSURANCE PRO3DUKES
FOR THE
LABORATCRf
DOOMNT NO. EPL - 001
EAGLE-PICHSt SOU5IKZES, IMC.
Specialty MBterials Division
Eagl^Pieher nefcim-irh Ijtentccy
200 9th Ave. N J.
Miand, Cklahom 74354
COPY NO. ^.5 DA3E TSffTFP; V/? /6 *7
TO: /Lx^- /C
-------
3
4
A
\
t-
DOC. NO. EPL-001
APPROVALS
Prepared Bv: ** o* Date:
Quality Assurance
Reviewed and _-
Accepted By; f /•• JP — Date:
D1rector^f Environmental Services
Revision;
Dated; 11-25-86
-------
PKHER
E P ^lytical ..pore
Customer ID:Stack Wacer Blank
Priority Pollutants Volatile Organics
mg\L_
COMPONENT SAMPLE
Acrolein <0.10
Acrylonitrile <0.10
Benzene <0.005
bis (Chloromethyl) ether <0.005
Bronoforta <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodibromomethane <0.005
Chloroethane <0.010
2-Chloroethyivinyl ether <0.010
Chloroform 0.006
Dichlorobroraomethane <0.005
Dichlorodifluororaethane <0.010
1,1-Dichloroethane <0.005
1,2-Dichloroethane
-------
MGULEL^pPKHER
HOIAHCH
E P Analycical teport
Customer ID:Charcoal BUnk dated 2-13-87
Priority Pollutantt Volatile Orgtnici
COMPONENT SAMPLE
Acrolein <1.0
Acrylonitrile <1.0
Benzene 0.88
bis (Chlororaethyl) tther <1.0
Broraofora <0.050
Carbon tetrachloridc <0.050
Chlorobenzene <0.050
Chlorodibroiaomethane <0.050
Chloroethane <0.10
2-Chioroethylvinyl tther <0.10
Chloroform <0.050
Dichlorobroraotaethane <0.050
Dichlorodifluoroaethane <0.050
1,1-Dichloroethane <0.050
1,2-Dichloroethane <0.050
1,1-Dichloroethylene <0.050
1,2-Dichloropropane <0.050
1,3-Dichloropropylene <0.050
Ethylbenzene <0.050
Methyl bromide <0.10
:
-------
PfCHEfi
E P Analytical Report
Customer ID:XAD Resin Blank
Priority Pollutants Volatile Organic)
COMPONENT
Acroltin
Acrylonitrile
Benzene
bis (Chloronethyl) ether
Broraofora
Carbon tetrachloride
Chlorobenzene
Chlorodibronotne thane
Ch 1 or oe thane
2-Chloroethylvinyl ether
Chloroform
Dichlorobromomethane
Dichlorodifluoroaethane
1,1-DichLoroethane
1,2-Dichloroethane
1,1-Diehloroethylene
l,2-rDichloropropan«
1,3-Dichloropropylene
Ethylbenxene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
1,2-Trans-dichloroethylene
1,1t1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoroaethane
Vinyl chloride
-------
EAQLE_=pPKHER
E ? Analytical Report
Custoaer ID:Ch«rco«l Blank dattd 2-11-87
Priority Pollutants Volatile Organic*
COMPONENT SAMPLE
Ac role in <1.0
Acrylonicrile ylvinyi ether <0.10
Chlorofom <0.050
Dichlorobro.-ao.Tie thane <0.050
Dichlorodif luoronethane <0.050
1, IrDichloroethan* <0.050
1 .2-~ich1 oroethane <0.050
1 ,l-Dichlnro*thylene <0.050
1 , 2-Dichloropropane <0.050
1 ,3-Oichloropropylene <0.050
Ethylbenzene <0.050
Methyl bromide <0.10
he thy 1 chloride <0.10
Methylcne chloride 180.
1,1,2,2-Tetrachloroethane <0.050
Tetrachloroethylene <0.050
Toluene <0.050
1 i2-Tran«-dichloroethylene <0.050
1 1 1,1-Trichloroethane <0.050
1, 1 , 2-Trichloroethane <0.050
Trichloroethylene <0.050
Trichlorof luoromethane <0.050
Vinyl chloride <0.10
-------
ftffS&UICH
LAaKMUTOffY
E P Analytical Report
Customer IDtChareoal Blank dactd 2-12-87
Priority Pollutant! Volatilt Organic*
COMPONENT
Acrole in
Acrylonitrile
Bencene
bi» (Chloromcthyl) tchcr
Broaofora
Carbon tetrachloride
Chlorobenztne
Chlorodibronomethane
Chloroethane
2-Cl»lr»r«*thylvinyl ither
Chloroform
Dichlorobronomtthane
Diehlorodifluororaethane
1,1-Oichloroethane
1, 2-Dichloroethane
1,1-Dichloroethylene
1,2-Oichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Hethylene chloride
1i1,2,2-Tetrachloroethane
Tetrachloroechylene
Toluene
1,2-Trans-dichloroeehylene
1,1,1-Trichlorocchane
1,1,2-Trichloroethane
Trichloroethylene
Tr ichlorofluoromethane
Vinyl chloride
SAMPLE
<0.050
<1.0
O.050
<0.050
<0.050
<0.050
<0.10
<0.10
<0.050
<0.050
<9.050
<0.050
<0.050
<0.050
<0.050
-------
EAQUliD RICHER
A£S£AACM
LABOJUTDffV
E-P Analytical Report Work Order No. 87-02-156-03A/
87-03-052-04A
Polychlorinaeed Dibcnzo-£-dioxina and Dibenzofuran*
Method 8280
Customer I.D. Pit I Run *4 Stack
Polychlorinated Dibenzo-£»dioxins
2,3,7,8-TCDD
1,2,3,4-TCDn
1,3,6,8-TCDD
1,3,7,9-TCDD
1,3,7,8-TCDO
1,2,7,8-TCDD
1,2,8,9-TCOD
i,2,3,4,7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,3-HpCDD
LEVEL . ug/al
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibenzofurans
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL , ug/al
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
*****£*
LABOMFOM
E P Analytical Raport
87-02-155-02A
Customer ID:Pit M Inlec Charcoal Tub* Run *5
Priority Pollutant* Volatile Organic*
COMPONENT
Acrolein
Acrylonitrile
Benzene
bi* (Chlorooethyl) ether
BT ooo form
Carbon tetrachloride
Chlorobenzene
Chlorod ib ronome thane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Dichlorobroraoraethane
Dichlorodifluorooethane
1,1-Dichloroethane
1,2-Oichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
MethyUne chloride
1,1,2,2-Te trachloro*thane
Tetrachloroethylene
Toluene
1,2-Trans-dichloroethylene
1,1,1-Tr ichloroethane
1,1,2-rTrichloroethane
Trichloroethylene
Trichlorofluoromethane
Vinyl chloride
SAMPLE
<0.050
<1.0
<0.050
<0.050
<0.050
<0.050
<0.10
<0.10
<0.050
<0.050
<0.050
<0.050
<0.050
<0.050
<0.050
<0.050
<0.050
<0.10
1.1
470.
<0.050
-------
E P An*1*'"*1 *«P°r« 87-02-1 55-02A
Customer ID:XAD Re*in Tube A Inlet Pic M Run 5
Priority Pollutant* Volatile Organic*
mg\Kz
COMPONENT SAMPLE
Ac role in <0.5
Acrylonitrile <0.5
Benzene <0.025
bis (Chlorojnethyl) ether <0.02S
Brorooforra O.025
Carbon tetrachlor ide <0.025
Chlorobenzene <0.025
Chlorodibronoaethane <0.025
Chloroethane <0.050
2-Chloroethylvinyl ether <0.05
Chloroform <0.025
Oichlorobronomethane <0.025
Dichlorodifluoronethane <0.050
1,1-Dichloroechane <0.025
1 ,2-Dichloroethane <0.025
1 , 1-Dichloroethylene <0.025
1 , 2-Dichloropropane
-------
AfSEAACH
LAKMUTOffT
E P Analytical Report
Cuitoatr ID:Pic M Stick Charcoal Tube Run 45
Priority Pollutant! Volatile Organic*
87-02-155-01A
COMPOSENT
Acroleia
Acrylonitrile
Benzene
bit (Chloromethyl) ether
Broaoforn
Carbon tetrachloride
Chlorobentene
Ch lorod ib roiione thane
Chioroethane
2-Chloroechylvinyl ether
Chloroform
Dichlorobroaoaethane
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Oichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylenc
Ithylbenxene
Methyl brnmid*
Methyl chloride
Nethylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroechylene
Toluene
1,2^Tran«-dichloroethylene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethylcne
Triehlorofluoronethane
Vinyl chloride
-------
iAQU=_^pPKHER
JKSE4AC*
E-P Analytical Report Work Order No. 87-02-155-02A/
87-03-052-13A
Polychlorinated Dibenzo-£-dioxini and Dibencofurans
Method 8280
Customer I.D. Pit H
Run #5 Inlet
Polychlorinatcd Dibenzo-£-dioxin«
2,3,7,8-TCOD
1,2,3,4-TCDD
1,3,6,8-TCDD
1,3,7,9-TCDD
1,3,7,8-TCDD
1,2,7,8-TCOD
1,2,8,9-TCOD
1,2,3,4,7-PeCOD
1,2,3,7,8-PeCDO
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibenzofurant
1,2,7,8-TCDF
1,2,3,7,3-PeCDF
1,2,3,6,7,8-IlxCDF
1,2,3^4,6,7,8,9-OCDF
LEVEL , Uf/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
AfSEAACM
LAatOJUTOffV
E P Analytical Report
87-02-155-01A
Cuitoaer ID'.XAD Rt>in Tube A Stack Pit M tun 5
Priority Pollutanta Volatile Organic*
COMPONENT
Acrolein
Acrylonitrile
Benzene
bis (Chloronethyl) ether
Browofonn
Carbon tetrachloride
Chlorobenzene
Chlorodibronoraethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Oichlorobromomethane
Dichlorodifluoronethane
1,1-Diehloroethane
1,2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbencene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
1,2-Tran«-dichloroethylen«
1,1,1-Trichloroeehane
1,1,2*Trichloroethane
Trichloroethylene
Trichlorofluorowethane
Vinyl chloride
SAMPLE
<0.30
<0.50
<0.023
<0.02S
<0.025
<0.02S
<0.025
<0.02S
<0.050
<0.05
<0.025
<0.025
<0.050
<0.025
<0.025
<0.023
<0.050
<0.025
<0.025
<0.050
<0.050
256.
<0.025
<0.025
<0.025
<0.025
<0.025
<0.025
<0.02S
0.21
-------
ftffSEAflCM
E-P Analytical Rapore
Work Order No. 87-02-155-OlA/
87-03-052-05A
Polychlorinated Dibenro-£-dioxini and Dibcnzofurana
Method 8230
GUI toner I.D. Pit H Run #5 Stack
Polychlorinated Dibento-£-dioxin$
2,3,7,8-TCDD
1,2.3.4-TCDO
1,3,6,8-TCOD
1,3-7.9-TCDD
1,3,7,8-TCDD
1,2,7,3-TCDD
1,2,8,9-TCOD
1,2,3,4,7-PeCDD
1,2.3,7,8-PeCDO
1,2,3,4,7,8-HxCDO
1,2,3,4,6,7,8-HpCDD
LEVTL , ug/mi
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Oibenxofurans
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
RICHER
E ? Analytic*1 **vort 87-02-155-02A
Customer ID:Combined Inlet Water Pit M Run 5
Priority Pollutantt Volatile Organics
COMPOSEOT SAMPLE
Acrolein <0.10
Acrylonitrile <0.10
Benzene <0.005
bit (Chloromcthyl) ether <0.005
Bromofora <0.005
Carbon tetrachloridft <0.005
Chlorobenzene <0.005
Chlorodibronomethane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Diehlorobronomethane 0*010
Dichlorodifluoronethane <0.010
1,l-Dichloro«ch«n- <0.005
1,2*0ichloroethane <0.005
l,l«Dichloroethylene <0.005
1,2-Dichloropropane <0.010
1,3-Dichloropropylene <0.005
Ethylbencene <0.005
Methyl bromide 0.012
Methyl chloride <0.010
Methylene chloride 24.0
1,1,2,2-Tetrachloroethane 0.012
Tetrachloroethylene <0.005
Toluene 0.36
1.2~Trana-dichloroethylene
-------
87-02-1 55-01A
Cu it oner ID: Combined Stack Water Pit H Run 5
Priority Pollutants Volatile Organic*
mg\l
COMPONENT SAMPLE
Ac role in <0.10
Acrylonitrile <0.10
Benzene <0.005
bis (Chloromechyl) ether <0.005
Brotnofom <0.005
Carbon tetrachloride <0.005
Chlorobenzene <0.005
Chlorodi or oaome thane <0.005
Chloroethane <0.010
2-Chloroethylvinyl ether <0.010
Chloroform <0.005
Dichlorobromome thane <0.005
Dichlorodifluorooethane <0.010
1 ,1-Dichloroechane <0.005
1 ,2-Dichloroethane <0.005
1,1-Dichloroethylene <0.005
1 ,2-Dichloropropane <0.010
1 ,3-Dichloropropylene <0.005
Ethylbenxene
-------
PKHER
AfSCAAC*
p Analytical Report 87-02-1 55-04A
Cu §t oner ID:Pit M Inlet Charcoal Tube Run #6
Priority Pollutants Volatile Organic*
COMPONENT
Ac role in
Acrylonitrile
Benzene
bis (Chloromethyl) ether
Broraofora
Carbon tetrachloride
Chlorobenzene
Chlorodibronone thane
Chloroethane
2-Chloroethyivinyl ether
Chloroform
Diehlorobromomethane
Dich1orodifluorone thane
1,1-Dichloroethane
1,2-Dichloroethane
1,l-Dichloroethylen«
1,2-Dichloropropane
1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Hethylene chloride 440.
1,1,2,2-Tetrachloroethane O.OS?
Tetrachloroethylene <0.050
Toluene 0*16
1,2-Trans-dichloroethylene <0.050
1,1,1-Trichloroethane <0.050
1,1,2-Trichloroethane <0.050
Trichloroethylene • 0.098
Trichlorofluoronethane <0.050
Vinyl chloride <0.10
-------
JtESCAHCM
LABORATORY
E-P Analytical lUport
Work Order No. 87-02-1 55-04A/
87-03-052-14A
Polychlorinated Dibenzo-£-dioxins and Dibenzofurang
Method 8280
Cuitoner 1.0. Pic M Run *6 Inlec
Polychlorinated Dibenzo-£-dioxin»
2,3,7,8-TCDD
1,2,3,4-TCDD
1,3,6,8-TCOD
1,3,7,9-TCDD
1,3,7,8-TCDD
1,2,7,8-TCOD
1,2,8,9-TCDD
1,2,3,4,7-PeCDO
1,2,3,7,8-P«CDD
1,2,3,4,7,8-HxCDD
l,2,3,4,6,7,d-llpCOD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibenzofurans
1,2,7,8-TCOF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL , ug/nl
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
E P Analytical Report 87-02-155-03A
Cuttoettr ID:Pit M Stack Charcoal Tube Run #6
Priority Pollutant* Volatile Organic*
COMPONENT
Acrolein
Acrylonitrile
Bentene
oil (Chlorouethyl) ether
Broooforn
Carbon tetrichloride
Chlorobenzene
Chlorodibromoraethan-
Chlorotthane
2-Chloroethylvinyl ether
Chloroform
Oichlorobronomethane
Dichlorodifluoronethane
1,1-Dichloroethane
1,2-Oichloroethane
1,1-Oichloroethylene
1,2-Dichloropropane
1,3-Diehloropropylent
Ethylbenzene
Methyl bromide
Methyl chloride
Hethylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene
Toluene
l,2-Tran*<*dichloroethylene
1,1,1-Trichloroethane
1,1,2-Tr ichloroethane
Trichloroethylene
Trichlorofluoromethane
Vinyl chloride
-------
EAQLE.5JPKHER
AfSCAACH
E-P Analytical Report
Work Order No. 87-02-155-03A/
87-03-052-06A
Polychlorinated Dibtnto-£-dioxin» and Dibenzofurans
Method 8280
Customer I.D. Pic M Run *6 Stack
Polychlorinated Oib«nzo-£-dioxint
2,3,7,8-TCDO
1,2,3,4-TCDD
1,3,6,3-TCOD
1,3,7,9-TCDD
1,3,7,8-TCOD
1,2,7,8-TCOD
1,2,3,9-TCUD
1.2.3,A,7-PeCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinated Dibtnzofurana
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCOF
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
FKHER
AfSIAACH
E p Analytical Report 87-02-1 54-02A
Customer ID:Pit B Inltt Charcoal Tube tun #7
Priority Pollutant* Volatile Organic!
COMPONENT SAMPLE
Acrolein <1.0
Acrylonitrile <1.0
Benzene <0.030
bi* (Chloroaethyl) ether <1.0
Broaoforn <0.050
Carbon tetrachloride <0.050
Chlorobenzene <0.050
Chlorodibromooethane
-------
HOIAHCH
LABORATORY
E-P Analytical Report Work Order No. 87-02-154-02A/
87-03-052-1SA
Polychlorinattd Dibtn*o-£-dioxin« and Dibtncofurans
Method 8280
Cuctooer I.D. Pit B Run tl Inlet
Polychlorinattd Dibtnxo-j»-dioxina
2,3,7,d-TCDD
1,2,3,4-TCDD
1,3,6,8-TCUD
1,3,7,9-TCDD
1,3,7,8-TCDD
1,2,7,8-TCDD
1,2,8,9-TCDD
1,2,3,4,7-PtCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,6,7,8-HpCDD
LEVEL , ug/ml
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
<0.75
Polychlorinattd Dibtncofurani
1,2,7,8-TCDF
1,2,3,7,8-PeCDF
*
1,2,3,4,7,8-HxCDF
1,2,3,4,6,7,8,9-OCDF
LEVEL , ug/al
<0.75
<0.75
<0.75
<0.75
In concentrated extract.
-------
PICHER
ACSCAACH
E p Analytical Report 87-02-1 54-01A
Cuftooer ID:Pit B Stack Charcoal Tube Run f 7
Priority PollutanCs Volacilt Organic*
COMPONENT SAMPLE
Acrolein <1.0
Acrylonitrile <1.0
Benzene
-------
> VtdAinr MATBMAU WVIttOI
PARAMETER
IHMAKM IABOCATOIY •
METHODS
REFERENCE
16. Chloride, mg/L:
Titrimetric (silver
nitrate) or
Mercuric nitrate
Colorimetric (Perri-
cyanide) manual or
Automated
17. Chlorine - Total residual,
mg/L:
Tit rimtt ric-amperomet-
ric (12)
Starch end point
lodometric or
DPD-PAS
Spect rophotoraat ri c,
DPD; or
Electrode
18. Chromium VI dissolved,
mg/L: 0.45 micron fil-
tration with:
Extraction and atomic
absorption, or
Colorimttric (Diphenyl-
carbazide)
3
19. Chromium - Total , mg/L:
3
Digestion (optional
extraction) followed by:
AA Direct aspiration
AA furnace
Inductively coupled
407A, D512-67(B), 2,3,4
1-1183-78
325.3, 407B, D512- 1,2,3,4
€7-(A), 1-1184-78
D512-67(C), 1-1187-78 3,4
325.1 or 325.2, 407D, 1,2,4
I-a87-78
330.1, 408C, D1253- 1,2,3
76 (A)
330.2, 408B 1,2
330.3, 408A, D1253- 1,2,3
76 (B)
330.4, 408D 1,2
330.5, 403E
(27) 5
218.4, 303B, 1-1232-78 1,2,4
1-1230-78 4
218.3
218.1, 303A or 303B,
DIM 7-77 (D), 1-3236-78
218.2, 304 1,2
Method 200.7(4) 5
1.2,3,4
4 of 18
-------
• IMOA1TT MANUALS MVttlOM •
roet
PARAMETER
plaraa
Or colorlMtri (Di-
phenylcarbazide)
3
20. Cobalt - Total , »g/L:
3
Digestion followed by:
AA direct aspiration
AA furnace, or
Inductively coupled
plasma
21. Color, platinua Cobalt
unit* or dominant
wavelength nue, lumi-
nance, purity:
OoloriMtric, AOMI
FlatinuB cobalt; or
Spectrophotonetric
3
22. Copper - Total , »g/L:
3
Digestion followed by:
AA direct aapiration
AA furnace
Inductively coupled
ColorlMtric (Neocu-
proine)
Bicinchoninate
3
23. Cyanide - Total , ag/L:
Manual distillation
with Mgd
2
Pollowed by titriaetric
Manual or
METBODS
312A, D1687-77(A)
219.3
219.1, 303A or 303B,
03558-77 (A or B),
1-3240-78 or 1-3239-78
219.2, 304
Method 200.7(4)
110.1, 204D
110.2, 204A, 1-1250-78
110.3, 204B
220.1, '303A Of 303B,
D1688-77 (D or E),
1-3271-78 or 13270-78
220.2, 304
Method 200.7(4)
313B, D1688-77XA)
(14)
335.2, 412D
335.2, 412B
335.2, 412C, D2036-
75 (A)
REFERENCE
2,3
1
1,2,3,4
1,2
5
1,2
1,2,4
1,2
1,2,3,4
1,2
5
2,3
5
1,2
1,2
1,2,3
Page 5 of 18
-------
TBMAIS DIVISION •
lAeOIATOtY
PARAMETER
15
Automated spectro-
photoMtric
24. cyanide amenable to
chlorinatin, rng/1:
Manual distillation with
MgCl . Follow^ by titri-
2
••trie, aanual or automated
spectrophotometric.
25. Fluoride - Total mg/L:
Manual distillation
Followed by manual or
Automated electrode
SPAENS
Or automated complexone
3
26. Gold - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
Or AA furnace
27. Bardaess - Total as CaCo ,
3
•9/L:
Automated colorimetric
EDTA titruation
inductively coupled
' plasma
Or atomic absorption
(sum
of Ca and Mg as
their respective car-
bonates
METHODS REFERENCE
335.3, 412D, D2036- 1,2,3,4
75(A), 1-3300-78
335.1, 412F, D2036- 1,2,3
75(B)m
15
413A ' 2
340.2, 413B, D1179- 1,2,3
72 (B)
1-4327-78 4
340.3, 413C, D1179- 1,2,3
72 (A)
340.3, 413E 1,2
231.1, 303A 1,2
231.2, 304
130.1 1
130.2, 314B, D1126- 1,2,3,4
67(B), 1-1338-78
Method 200.7(4) 5
215.lt>, 303A, 1-31538- 1,2,4
242.1, 1-3446-78 1,4
Page 6 of 18
-------
> SMOAITT MATBHAU MVWOM ——
28. Hydrogen ion (pH), pB
unit*:
Electrosetric
Measurements; or auto-
Mated electrode
3
29. Xridiua - Total , ag/L:
3
Digestion followed by:
AA direct aspiration
Or AA furnace
3
30. Iron - Total , *g/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
Inductively coupled
plasma
Or coloriMtric (Pnen-
antbroline)
31. Kjeldahl Nitrogen - Total
(as N), ag/L:
Digestion and distilla-
tion
Followed titration
Hesslerization or
Electrode
Automated phenate
Seai-autoaated
block digester
Or potentioaetric
3
32. Lead - Total , *J/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
150.1, 423, D1293-
78-(A) or D1293-78(B),
1-1586-78
(16)
235.1, 303A
235.2, 304
303A or 303B, D1068-
77 (C or D)
236.1, 303B,
1-3381-78
236.2, 304
Method 200.7(4)
315B, 01068-77 (A)
351.3, 420A or B
351.3, 417D, D3S90-77
351.3, 417B
351.3, 417E, 1-4551-78
351.3, I-4S52-78
351.2
351.4
239.1, 303A or 303B
D3559-78 (A or B),
1-3399-78
239.2,304
1,2,3,4
3,4
1/2,4
1,2
5
2,3
1,2,3
1,2
1,2,4
1,4
1
1,2,3,4
1,2
Page 7 of 18
-------
AITY MATBMAU DIVISION •
ILABOeATOer
PARAMETER
Inductively coupled
plasma
9
"oltanetry or
Colorimtric (Dithi-
zone
3
33. Magnesium - Total , ng/L:
3
Digestion followed by:
Atonic Absorption
Inductively coupled
plascta
Or gravimetric
3
34. Manganese - Total , «g/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
Inductively coupled
plasma
Or colorimetric (Per-
sulfate)
Periodate
3
35. Mercury - Total , mg/L:
Cold vapor, manual or
' Automated
3
36. Molybdenum - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
AA furnace, or
Inductively coupled
METHOD
Method 200.7(4)
D35 59-78 (C)
316B
242.1, 303A, D5U-
77(B), 13447-78
Method 200.7
318B, D5U-77U)
243.1, 303A or 303B,
D8S8-77 (B or C),
1-3454-78
243.2, 304
Method 200.7(4)
319B, D858-77(A)
(18) -
245.1, 303P, D3223-
79, 1-3462-78
245.2
REFERENCE
5
3
2
1,2,3,4
5
2,3
1.2,3,4
2,3
5
1,2,3,4
1
246.1, 303C, 1-3490-78 1,2,4
246.2, 304 1,2
Method 200.7(4) 5
Page 8 of 18
-------
WflCIAITT MATMIAU DIVISION <
PARAMETER
M2THOD
•ATOtT
REFERENCE
37. Nlcktl - Total , wq/L:
3
Digestion followed by:
AA dictct aspiration
AA furnace
Inductively coupled
plasma
Or colorimtric
(Heptoxitft)
Nitrate (as N), ag/L:
Brucine sulfate, or
Nitrate-nitrite N
minus Nitrite N
Nitrate-nitrite (as N)/
•g/L:
Cadmium reduction/
manual
Or automated; or
38,
39,
40.
41,
42,
43,
Automated hydrazine
Nitrite (as N), ag/L:
Sp^ctrophotoavtric,
•anual or
Autoaated (Diazo-
tization)
Oil and greaae - Total
'recoverable, «g/L:
GraviiMtric (extraction),
Organic carbon - Total
(TOC), ab/L: Ooabuation
or oxidation.
Organic nitrogen (as N),
•gA: Total Kjeldahl N
•inus aavonia N.
249.1, 303A or 303B,
D1886-77(C or D),
1-3499-78
249.2, 304
Mthod 200.7(4)
321. B
1,2
5
352.1, D092-71 1,3
See parameters 39 and 40
353.3, 418C, D3867- 1,2,3
79 (B)
353.2, 418P, D3867- 1,2,3,4
79(A), 1-4545-78
353.1 1
354.1, 419, D1254- 1,2,3
€7
1-4540-78 4
413.1, 503A 1,2
415.1, 505, D2579- 1,2,3
78 (A) or D2579-78(B)
See paraavters 31 and 1,2,3,4
4
••AQfcll
Page 9 of 18
-------
> MffCUUTY MATBHAU MVISION •
PARAMETER
METHOD
KMlAMtATOtT
REFERENCE
44. Orthophosphate (as P),
mg/L: Ascorbic acid
method, automated
Or manual single re-
agent or
Manual two reagent
3
45. Osmium - Total , mg/L:
3
Digestion followed by:
AA direct aspiration, or
AA furnace
46. Oxygen, dissolved, mg/L:
Winkler (Azide modifi-
cation)
Or electrode
3
47. Palladium - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
Or AA furnace
48. Phenols, mg/L:
Manual distillation
Followed by manual
15
Or automated color-
• metric (4AAP)
49. Phosphorus (elemental),
—mg/L; Oas-Hquid chro-
matography.
50. Phosphorus - Total, mg/L:
Persulfate digestion
Followed by manual or
Automated ascorbic acid
Reduction; or semi-
automated block digestor
365.1, 424G, 1-4601-78 1,2,4
365.2, 424P, D515- 1,2,3
78 (A)
365.3 1
252.1, 303C
252.2, 304
360.2, 421B, D1589-
60 (A), 1-1575-78
360.1,421F, 1-1576-78
1,2
1/2
1*2,3,4
1,2,4
253.1 1
253.2 1
420.1, D1783-70 1,3
(A or B)
420.1 1
420.2 1
(21) 5
365.2, 424C (III) 1,2
365.2 or 365.3, 424F, 1,2,3
D515-78(A)
365.1, 424G, 1-4600-78 1,2,4
365.4, 1-4603-78 1,4
Page 10 of 18
-------
UTT MATMHAU MWIOM -
PARAMETER
METBGD
REFERENCE
51. Platinum - ToUl , ag/L:
3
Digestion followed by:
AA direct aspiration
Or AA furnace
3
52. Potassium - Total , mg/L:
3
Digestion followed by:
Atomic absorption
Inductively ooupled
plasma
Or flam photometric
53. Residue - total, mg/L:
Gravimetric, 103-105 C
54. Realdue - filterable*
mg/L: Gravimetric, 180 C
55. Residue - nonfilterable,
(TSS), mg/L: Gravimetric,
103-105 C pott washing of
residue.
56. Residue - settleable,
•g/L: Volumetric (Zmboff
cone) or gravimttric.
57. Residue - volatile, mg/L:
Gravimtric, 550 C
3
58. Rhodium - Total , wq/L:
3
Digestion- followed by:
AA direct aspiration
Or AA furnace
3
59. Ruthenium - Total , mg/L:
3
Digestion followed by:
AA direct aspiration
Or AA furnace
3
60. Selenium - Total mg/L:
3.
Digestion followed by:
AA furnace
Inductively coupled
255.1, 303A
255.2, 304
258.1, 303A, 1-3630-78 1,2,4
Hethod 200.7(4)
322B, D142B-64U) 2,3
160.3, 209A, 13750-78 1,2,4
160.1, 209B, 1-1750-78 1,2,4
160.2, 209D, 1-3765-78 1,2,4
160.5, 209P
265.1, 303A
265.2, 304
267.1, 303A
267.2, 304
207.2, 304
Method 200.7(4)
1,2
160.4, 209E, 1-3753-78 1,2,4
1,2
1,2
1,2
1,2
1,2
5
Page 11 of 18
-------
• lAOU^IOWIMUAKH lAWtATOIT
PARAMETER
plasma
Or hydride
61. Silica - Dissolved, «g/L:
0.45 Micron filtration:
Followed by manual or
Automated colorimetric
(Molybdosillicate), or
Inductively coupled
plasma
22
62. Silver - Total ng/L:
3
Digestion followed by:
AA direct aspiration
AA furnace/ or
Inductively coupled
plasma
3
63. Sodium - Total / wq/L:
3
Digestion followed by:
Atomic Absorption
Inductively coupled
plasma
Or flam photometric
64. Specific conductance,
mhos/cm: Mheatstone
bridge.
65. Sulfate (as SO ), mg/L:
4
Automated Mthylthymol
blue
Gravimetric, or
Turbidimetric
66. Sulfide (as S), «b/L:
Tltrimetric (iodine) or
Oolorimetric (methylene
blue
METSOD
270.3, 303E, D3859-
79, 1-3667-78
370.1, 425C, 0859-
68(B), 1-1700-78
1-2700-78
Method 200.7(4)
D-1428-64 (A)
120.1, 205, D112S-
77(A), 1-1780-78
375.2, 1-2822-78
REFERENCE
1/2,3,4
4
5
272.1, 303A, I-373S-78 1,2,4
272.1, 304 1,2
Method 200.7(4) 5
273.1, 303A, 1-3735-78 1,2,4
Method 200.7(4) 5
3
1*2,3,4
1,2,3
375.3, 426A OC 426B,
DS16-68(A)
375.4, 426C, D516-68(B) 1,2,3
376.1, 427D, 1-3840-78 1,2 4
376.2, 427C 1,2
Page 12 of 18
-------
•WKUUYMAT
PARAMETER
METHOD
REFERENCE
67. Sulfitt (as SO ), ag/L:
4
Titriaetric (iodine
iodate)
66. Surfactants, ag/L: Color-
iMtrie (aethylene blut)
69. Teaperature, C.: Therao-
Mtric
3
70. Thalliua - Total , ag/L:
3
Digestion followed by:
AA direct aspiration
M furnace, or
inductively coupled
plasaa
71. Tin - Total , »g/L:
3
Digestion followed by:
AA direct aspiration
AA furnace/
3
72. Titanium - Total , ag/L:
3
Digestion followed by:
AA direct aspiration or
73. Turbidity, NXU: Hephelo-
•etric
3
74. Vanadium - Total , ag/L:
3
' Digestion followed by:
AA direct aspiration
AA furnace
Inductively coupled
Or color iatt tic
(Gallic acid)
3
75. Sine - Total , ag/L:
3
Digestion followed by:
AA direct aspiration
AA furnace
377.1, 428F, D1339-
78(0
425.1, 512A, D2330-
68 (A)
170.1, 212
279.1, 303A
279.2, 304
Method 200.7(4)
282.1, 303A, 1-3850-78
282.2, 304
283.1, 303C
180.1, 214A, D1889-
71, 1-3860-78
286.1, 303C
286.2, 304
Method 200.7(4)
D3373-75
1,2,3
1.2.3
1,2
1,2
5
1,2,4
1,2
1,2
1,2,3,4
1,2
1,2
5
289.1, 303A or 303B, 1,2,3,4
D1691-77(D), 1-3900-78
289.2, 304, D1691-77(C) 1,2,3
Page 13 of 18
-------
SAITY MAMMALS MVWOM ———————— IABUHOM1 HMAM
PARAMETER METHOD REFERENCE
Inductivaly coupled Method 200.7(4)
plasm
Or colorinetric (Zincon) 24 5
INORGANIC TEST PROCEDURES NOTES
1 EPA 1979
2 Standard method* 15th Ed.
3 ASXM
1
4 USGS
5 Other
1
"Methods for Analysis of Inorganic Substances in Hater and
Pluvial Sediments," U.S. Department of the Interior, U.S.
Geological Survey, Open-Pile Report 78-679, or "Methods for
Determination of Inorganic Substances in Hater and Pluvial
Sedimnts," N.W. Skougstad, et al; U.S. Geological Survey,
Techniques of Water-Resources Investigatin, Book 5, Chapter Al,
1979.
2
"Official Methods of Analysis of the Association of Official
Analytical Chemists" methods manual, 13th ad. (1980).
3
For the determination of total metals the sample is not
filtered before processing. A digestion procedure is required to
solubilixe suspended material and to destroy possible organic-metal
compleies. Two digestion procedures are given in "Methods for
Chemical Analysis of Hater and Hastes, 1979." One ( 4.1.3) is a
vigorous digestion using nitric acid. A less vigorous digestion
using nitric and hydrocholoric acids ( 4.1.4) is preferred;
however, the analyst should be cautioned that this mild digestion
may not suffice for all sample types. Particularly, if a
Page 14 of 18
-------
>SMCUUTTMAT
colorimetric procedure ia to be employed, it la nacaaaary to enaure
that all organo-metallic bonds be broken ao that the metal ia in a
reactive state. In thoae aituationa, the vigorous digestion ia to
be perferred taking certain that at no time does the sample go to
dryneaa. Samples containing large asounta of organic materials
would also benefit by this vigorous digestion. Osa of the graphite
furnace technique, inductively coupled plasma, as wall as
determinations for certain elements such as arsenic, the noble
•etala, mercury, selenium, and titanium require a modified
digestion and in all cases the method write-up should be consulted
for specific instructions and/or cautions.
MOTE: If the digestion procedure for direct aspiration or
graphite furnace atomic absorption analysis included in one of the
other approved references is different that the above, the EPA
procedure must be used.
Dissolved metals are defined as those consituents which will
pass through a 0.45 micron membrane filter. Following filtration
of the sample, the referenced procedure for total metals must be
followed. Sample digestion of the filtrate for dissolved metals,
or digestion of the original sample solution for total metals may
be omitted for AA (direct aspiration or graphite furnace) and XCP
analysea provided the sample has a low COD and the filtrate meets
the following criteria:
(a) Is visibly transparent
(b) las no perceptible odor, and
(c) Is free of particulate or suspended matter
following acidification.
4
The full tart of Method 200.7, "Inductively Coupled Plasma
Atomic Emission Spectrometric Method for Trace Element Analyaia of
Hater and Hastes," is given at Appendix C of 40 OR of Part 136.
S
Manual distillation is not required if comparability data
on representative effluent samples are on company file to show that
this preliminary distillation step is not necessary* however,
manual distillation will be required to resolve any controversies.
6
Ammonia, Automated Electrode Method, Industrial Method
Number 379-7SNE, dated February 19, 1976, Technicon AutoAnalyzer
II, Technicon Industrial Systems, Tarrytown, New York 10591.
••Mill
Page 15 of 18
-------
SMCUtrr MATIMALS DIVISIOM'
7
I lASOCATOtr
Carbonaceous biochemical oxygen demand (CBOD ) must not be
5
confused with the traditional BOD test which measures "total
5
BOD". The addition of the nitrification inhibitor is not a
procedural option, but must be included to report the CBOD
5
parameter. A discharger whose permit requires reporting the
traditional CBOD may not use a nitrification inhibitor in the
5
procedure for reporting the results. Only when a discharger's
permit specifically states CBOD is required can be permittee
5
report data obtained using the nitrification inhibitor.
8
American National Standard on Photographic Processing
Effluents, Apr. 2, 1975. Available for ANSI, 1430 Broadway, Hew
York, NY 10018.
9
The use of normal and differential pulse voltage ramps to ,
increase sensitivity and resolution is acceptable.
10
Chemical Oxygen Demand, Method 8000, Bach Handbook of Mater
Analysis, 1979, Bach Chemical Company, P.O. Box 389, Loveland,
Colorado 80537.
11
COD Method, Oceanography International Corporation, 512
West Loop, P.O. Box 2980, College Station, Texas 77840.
12
The back titration method will be used to resolve
controversy.
. 13
• Rational Council of the Paper Industry for Air and stream
Improvement, Inc., Technical Bulletin 253, December 1971.
14 Copper, Bicinchoninate Method, Method 8506, Bach Handbook
of Water Analysis, 1979, Bach Chemical Company, P.O. Box 389,
Loveland, Colorado 80537.
15
After the annual distillation is completed, the auto-
analyzer manifolds in EPA Methods 335.03 (Cyanide) or 420.2
(phenols) are simplified by connecting the re-sample line directly
to the sampler. When using the manifold setup shown in Method 335,
the buffer 6.2 should be replaced with the buffer 7.6 found in
Method 335.2.
16
Hydrogen ion (pH) Automated Electrode Method, industrial
Method Number 378-75WA, October 1976, Technicon Auto-Analyzer II,
Technicon Industrial systems, Tarrytown, New York 10591.
17
iron, 1,10-Pbcnanthroline Method, Method 8008, 1980, Bach
Chemical Company, P.O. Box 389. Lureland, Colorado 80537.
Page 16 of 18
-------
• WtCUUTT MAntlAU MVWC
AKM LAVOtATOTr
18
Manganese, Periodate Oxidation Method, Method 8034, Bach
Handbook of Wastewater Analysis, 1979, pages 2-113 and 2-117, Bach
Chemical Company, Lovtland, Colorado 80537.
19
Ritrogen, Nitrite, Hstbod 8507, Bach Chemical Company, P.O.
Box 389, Lovtland, Colorado 80537.
20
Gotrlitz, 0., Brown, E., "Htthods for Analysis of Organic
Substances in Hater," O.S. Geological Survey, Techniques of Water -
Resources investigations, Book 5, Chapter A3, p. 4 (1572).
21
R.F. Addison and R.G. Ackman, "Direct Determination of
Elemental Phosphorus by Gas-Liquid Chromatography,* Journal of
Chromatography, Vol. 47, Ho. 3, pp. 421-426, 1970.
22
Recommended methods for the analysis of silver in
industrial wastewaters at concentrations of 1 mg/L and above are
inadequate where silver exists as an inorganic balide. Silver
halides such as the bromide and chloride are relatively insoluble
in reagents such as nitric acid but are readily soluble in an
aqueous buffer of sodium thioaulf ate and sodium hydroxide to a pe
of 12. Therefore, for levels of silver above 1 mg/L, 20 mL of
sample should be diluted to 100 mL by adding 40 mL each of 2 M Ha
2
8 0 and 2M RaOB. Standards should be prepared in the same
2 3
manner. For levels of silver below 1 mg/t the recommended method
is satisfactory.
23
Stevens, B.B., Ficke, J.P., and Smoot, G.P., "Water
Temperature-Influential Factors, Field Measurement and Data
Presentation," U.S. Geological survey, Techniques of Water-
Resources Investigations, Book 1, Chapter Dl, 1975.
24
Zinc, Xincon Method, Method 8009, Bach Handbook of Water
Analysia, 1979, pages 2-231 and 2-333, Bach Chemical Company,
Lcveland, Colorado 80537.
25
•Selected Analytical Methods Approved and Cited by the
United States Environmental Protection Agency," Supplement to the
the Examination of Water
Fifteenth Edition of standard Methods for
and Wastewater (1981) .
5?
The approved method is that cited in standard Methods for
the Examination of Water and Wastewater, 14th Edition. The
colorimetric reaction is conducted at a pB of 10.0 + 0.2. The
approved methods are given on pp. 576-81 of the 14tF Edition:
Method 510A for distillation, Method 510B for the manual
••AOiaTl
Page 17 of 18
-------
• SMdAOT MATSMAU MVWOM •
coloriBetrie procedure, or Method 510C for the aanual
spectrophotonetric procedure.
27
ORION Research Instruction Manual, Residual Chlorine
Electode Model 97-70, 1977, Onion Research Incorporated, 840
Memorial Drive, Cambridge, Massachusetts 02138.
Page 18 of 18
-------
f
c
?
;?
il
i"'
.
"•„
t.
t
I,
r*
£
t"
t::
77
ft
*
r
*^
—
!».
"™"
P
1.
t
r
—
*'
Hi
LIST OP APPROVED TEST
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
V
1
PARAMETER
Acenaphthene
Acenaphthylene
Acrolein
Acrylonitrile
Anthracene
Benzene
Benzidine
Benzo(A) Anthra-
cene
Benzo(a)pyrene
Benzo(b)fluor-
anthene
Benzo(ghi)pery-
lene
BenzoOOfluo-
ran thane
Benzyl Chloride
Benzyl Butyl
Phthalate
Bi«(2-Chloroe-
thoxy) •ethane
Bi«(2-chloro»-
thoxy) ether
Bi»(2-ethyl-
hezyl) phthalate
Broaodichloro-
•ethane
Btoeocon
BroaoMthane
4-Broe)ophenyl-
phenyl ether
Carbon tetra-
chloride
4-Chloro-3-
•ethylphenol
Chlorobenzene
Chloroethane
2-Chloroethyl-
vinyl ether
PROCEDURES
POR NON-PESTICIDE
2.7
EPA METHOD NUMBER
GC
610
610
603
603
610
602
-
610
610
610
610
610
610
606
611
611
606
601
601
601
611
601
604
601, 602
601
601
frtuifS-
GC/KS
625, 1625
625, 1625
4
624, 1624
4
624, 1624
625, 1625
624, 1624
5
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
624, 1624
624, 1624
624, 1624
625, 1625
624, 1624
625, 1625
624, 1624
624, 1624
624, 1624
5MCHVI
ORGANIC COMPOUNDS >
OTUUt
HPLC
610
610
-
-
610
•
605 Note 3
610
610
610
610
610
610 Note 3
Note 6
-
-
-
-
-
-
-
Note 3
-
Note 3
-
~
Page 1 of 5
-------
r
r—
[
F
r
£
•
,
r
I:
[
;
t_
F
L
r
r
rr
r
i_
i
L
r
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
. 44.
45.
46.
47.
48.
49.
50.
1!
PARAMETER
Qilo reform
Chloronethane
2-Chloroehyl-
vinyl ether
2-Chlorophenol
4-Chlo r opheny 1-
phenyl ether
Chryaene
Dibenzo (a, h) an-
thracene
Dibronochloro-
•ethane
1,2-Dichloro-
benzene
1,3-Dichloro-
benzene
1,4-Dichloro-
benzene
3,3-Dichloro-
benzidine
Dichlorodi-
fuoroavthane
1,1-Dichloro-
ethane
1,2-Dichloro-
ethane
1,1-Dichloro-
ethane
trana-l,2-Dl-
chloroethane
2,4-Dichloro-
phenol
1,2-Dichloro-
propane
ci*-l,3-Di-
chloropropene
tran«-l,3-Dl-
chloropropene
Ditthyl phtha-
late
2,4-DiMthyl-
phenol
Dimethyl phtha-
late
GC
601
601
612
604
611
610
610
601
601,602
601,602
601,602
-
601
601
601
601
601
604
601
601
601
606
604
606
•Aju.ra*
iv>
Page
GC/MS HPLC OTHER
624, 1624 - Note 3
624, 1624
625, 1625
625, 1625
625, 1625
625, 1625 610
625, 1625 610
624, 1624
,612,624,625,1625 -
,612,624,625,1625 -
,612,625,1624,1625 -
625, 1625 605
624, 1624
624, 1624
624, 1624
624, 1624
624, 1624
625, 1625
624, 1624
624, 1624
624, 1624
625, 1625
625, 1625
625, 1625
j
2 of 5
-------
PVOM
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
61.
62.
63.
64.
65.
66.
67.
68.
69.
70.
71.
72.
73.
74.
75.
76.
77.
78.
79.
80.
PARAMETER
Di-n-butyl ph-
tbalate
Di-n-octyl ph-
thalate
2,4-Dintrophenol
2, 4-Dinitro to-
luene
2,6-Dinitroto-
lUene
Epichlorohydrin
Ethylbenzene
Pluoranthene
Fluorene
Bexachloroben-
zene
Bexachlorobu-
tadiene
Bexachlorocyclo-
pentadiene
Bexachloroethane
Xd»no(l,2,3-cd)
pywnt
Xftophorom
Methylene Chlo-
ride
2-Methyl-4,6-
Dinitrophenol
naphthalene
Nitrobenesene
2-Nitroph«nol
4-Nitropbenol
N-Nitro«odi-
•etbylamlne
H-Nitco«odi-n-
propylaaiiw
H-Nitro»cx3i-
phenylaaine
2,2-oxybU(l-
chloropropane
PCB-1016
PCB-1221
PC&-1232
PCB-1242
PCB-1248
OC
606
606
604
609
609
-
602
610
610
612
612
612
612
610
609
601
604
610
609
604
604
607
607
607
611
608
608
608
608
608
GC/MS
625, 1625
625, 1625
625, 1625
625, 1625
625, 1625
-
624, 1624
625, 1625
625, 1625
625, 1625
625, 1625
5
625, 1625
625, 1625
625, 1625
62S, 1625
624, 1624
625, 1625
625, 1625
625, 1625
625, 1625
625, 162S
625, 1625
5
625, 1625
5
625, 1625
625, 1625
•
-
-
_
-
HPLC
_
_
_
-
.
-
.
610
610
.
-
-
-
610
-
-
-
-
-
-
—
-
-
-
625
625
625
625
625
OTHER
Note 3
Note 6
Note 3
Note 3
Note 3
Note 3
Note 3
Note 3
Page 3 of 5
-------
SMCULTT MATOMAU etvisiON
llASOCATOr
PARAMETER
OC
GC/MS
BPLC OTHER
81. PCB-1254 608
82. PGB-1260 608
83. Pantachloro-
phanol 604 625, 1625
84. Phenanthrene 610 625, 1625
85. Phanol 604 625, 1625
86. Pyrane 610 625, 1625
87. 2,3,7,8-Tetra-
chlorodibenzo-
5a
p-dioxin - 613
88. 1,1,2,2-Tatra-
chloroathana 601 624, 1624
89. Tetrachloroa-
thana 601 624, 1624
90. Toluana 602 624, 1624
91. 1,2,4-Trichloro-
bansana 612 625, 1625
92. 1,1,1-Trichloro-
athana 601 624, 1624
93. 1,1,2-Trichloro-
•thana 601 624, 1624
94. Trichloroathana 601 624, 1624
95. Trichlorofluoro-
•athana 601 624
96. 2,4,6-Trichloro-
Phanol 604 625, 1625
97. Vinyl Chloride 601 624, 1624
625,
625,
610
610
Note 3
Not* 3
Note 3
Note 3
Note 3
Note 3
ORGANIC GQMPOODS TEST PROCEDURES NOTES
All parametera are expressed in micrograma par litar (f/L).
2
The full taat of Method* 601-613, 624, 625, 1624, 1625, are
given at Appendix A, "Test Procedure* for Analyaia of Organic
Pollutants," of this Part 136. The atandardisad taat procedure to be
uaad to determine the aathod detection limit (HDL) for these taat
procedures is given at Appendix B, "Definition and Procedure for the
Determination of the Method Detection Limit," of this Part 136.
3
"Methods for Beruidine; Chlorinated Organic Coapounda,
Pantachlorophviiol and Pesticides in Hater and Waatevater," U.S.
Environmental Protection Agency, September, 1978.
Page 4 3* 5
-------
•IUAKM lAeoeAfOCY
• SHOAITT MATWAU MVWON ———————— |A
4
Method 624 may be extended to screen samples for Acrolein and
Scrylonitrile. lowever, when they are known to be present, the
preferred Mthod for these two compunds is Method 603 or Method 1624.
5
Method 625 My be extended to include benzidine,
hexachlorocyclopentadiene, N-nitrosodiumethyamine, and N-
nitrosodiphenylamine. However, when they ere known to be present,
Methods 605, 607, and 612, or Method 1625, are preferred methods for
these
w^
625, Screening only.
6
"Selected Analytical Methods Approved and Cited by the United
States Environmental Protection Agency," Supplement to the Fifteenth
Edition of Standard Methods for the Examination of Hater and
Wastewater (1981).
Each analyst must make an initial, one-time, demonstration of
their ability to generate acceptable precision and accuracy with
Methods 601-613, 624, 625, 1624, and 1625 (See Appendix A of this
Part 136) in accordance with procedures each in section 8.2 of each
of these Methods. Additionally, each laboratory, on an on-going
bases must spike and analyze 10% (5% for Methods 624 and 625 and 100%
for methods 1624, and 1625) of all samples to monitor and evaluate
laboratory data quality in accordance with sections 8.3 and 8.4 of
these Methods. When the recovery of any parameter falls outside the
warning limits, the analytical results for that parameter in the
unspiked sample are suspect and cannot be reported to demonstrate
regulatory compliance.
NOTE.- These warning limits are promulgated as an "interim
final action with a request for comments."
Page 5 of 5
-------
• SMdAiTT MATWAI4 OCVWOI
lAOU-MCNU HUAKM LAIOtATOlY
LIST OF APPROVED TEST PROCEDURES FOR PESTZCZDES
i STANDARD
PARAMETER (fg/L)
METHOD
EPA
2,7
METHODS
15th ED
ASTM
1. Aldcin
2. AMtryn
3. Ajninocarb
4. Atraton
5. Atrazin*
6. Axlnphoa Mthyl
7. Barban
8. %-BBC
9. a-BBC
10. k-1
11.
(Lindam)
12. Captan
13. Cacbacyl
14. Carboph*nothian
15. Chlordan*
16. ChloroprophaiB
17. 2,4-D
18. 4,4-DDD
19. 4,4-DBE
20. 4,4-DDT
21. DMHton-0
22. DaMnton-6
23. Dlaainon
24. Dicavba
GC
GC/MS
GC
TLC
GC
GC
GC
TLC
GC
GC/MS
GC
GC/MS
GC
GC/MS
GC
GC/MS
GC
TLC
GC
GC
GC-MS
TLC
GC
GC
GC-MS
GC
GC/MS
GC
GC/MS
GC
GC
GC
GC
608
625
Not* 3,
Not* 3,
Not* 3,
Not* 3,
Not* 3,
Not* 3,
608
5
625
608
625
608
S
625
608
625
Not* 3,
Not* 4,
608
625
Not* 3,
608
625
608
625
608
625
Not* 3,
Not* 3,
NOt* 3,
Not* 6
Not* 3
509A
Not* 6
Not* 6
Not* 6
Not* 6
Not* 6
Not* 6
509A
D3086
509A
509A
Not* 6
Not* 6
509A
Not* 6
509B
50 9A
509A
509A
Not* 6
Not* 6
Not* 4
D3086
D3086
D3086
D3086
D3086
«•
D3086
D3086
D3086
I
Page 1 of 4
-------
• WKIAITT MATOHAU MVHION
PARAMETER
25. Dichlof«nthion
26. Dichloran
27. Dicofol
28. Ditldrin
29. Dioathion
30. Diwlfoton
31. Diuron
32. Endowlfan I
33. Endowlfan 11
34. Endowlfan wlfate
35. Endrin
36. Endrin ald*hyd*
37. Ethion
38. P«nuron
39. P*nuron-TCA
40. Baptaehlor
41. Beptachlor epoxidt
42. ZMdrin
43.. Linuron
44. Malathion
45. Mctaiocarb
46. M*thoxycnlor
47. Meacarbet*
48. Mirex
49. Monuron
50. Monuron-TCA
51. N*buron
52. Parathion wthyl
53. Parathion ethyl
54. POO
55. Per thane
56. Proneton
^
METHOD
GC
OC
OC
GC
OC/MS
OC
OC
TLC
GC
OC/MS
OC
GC/MS
GC
GC/MS
OC
OC/MC
OC
OC/MS
OC
TLC
TLC
OC
OC/MS
OC
OC/MS
OC
TLC
G
TLC
OC
TLC
**^*»
OC
TLC
TLC
TLC
OC
OC
OC
OC
OC
-«AfllM0D»
— — -^ mm i i •• • ••• BBM«*««BVr« •••Vi
STANDARD
2,7
EPA METHODS
15TH ED
Not* 4, Not* 6
509A
-
608 509A
625
Not* 4, Not* 6
Not* 3, Not* 6
Not* 3, Not* 6
608 509A
5
625
608 509A
5
625
608
625
608 509A
5
625
608 509A
625
' Not* 4, Not* 6
Not* 3, Not* 6
Not* 3, Not* 6
608 509A
625
608 509A
625
Not* 3, Not* 6
Not* 3, Not* 6
509A
Not* 3, Not* 6
509A
Not* 3, Not* 6
S09A
Not* 3, Not* 6
Not* 3, Not* 6
Not* 3, Note 6
509A
509A
509A
-
Note 3, Note 6
tctmm
»»••»»«•» •"'^— •—>.
ASTM
03086
_
-
_
03086
.
_
.
03086
.
03086
.
03086
-
03086
-
-
03086
-
-
-
-
03086
Page 2 of 4
-------
SMdAirr MATWAU MVtttOM •
PARAMETER
METHOD
EPA
2,7
• SMAICHIAI
STMOARD
METHODS
15TH ED
ATOtT
ASTM
57. Proaetryn
58. Propazinc
59. Propham
60. Propoxur
61. Stcbumeton
62. Siduron
63. Siaazine
64. Strobane
65. Swtp
66. 2,4,5-T
67. 2,4,5-TP (Silvex)
68. Terbuthylaxine
69. Toxaphene
70. Trifluralin
GC
GC
TLC
TLC
TLC
TLC
GC
GC
TLC
GC
GC
GC
GCC
GC/MS
GC
N0t« 3,
Note 3,
Note 3,
Nott 3,
Not* 3,
Not* 3,
Not* 3,
Mot* 3,
Not*
608
625
3,
Not*
Not*
Not*
Not*
Not*
Not*
Not*
509A
Not* 6
509B
509B
Not* 6
509A
509A
D3086
TEST PROCEDURES FOR PESTICIDES NOTES
t
*
i
i
a
Pesticides at* listed in this tabl* by rnmmni, MM for th*
conv*ni*ne* of th* r*ad*r. Additional pesticides may be found under the
notes for organic compounds, where entries are listed by chemical nan*.
2
The full text of methods 608 and 625 are given at Appendix A,
"test procedures for Analysis of Organic Pollutants," of this Part 136.
The standardized test procedure to be used to determine the method
detection limit (HDL) for these test procedures is given at Appendix B,
"Definition and Procedure for the Determination of the Method Detection
Limit", of this Part 136.
3
"Methods for Benzidine, Chlorinated Organic
^
Pentachlorophenol and Pesticides in Water and Wastewater," U.S.
Environmental Protection Agency, September, 1978. This EPA publication
includes thin-layer chromatography (TLC) methods.
4
"Methods for Analysis of Organic Substances in Water," U.S.
Geological Survey, Techniques of Water-Resources Investigations, Book 5,
Chapter A3 (1972).
5
The method may b* extended to include '-BBC, k-BBC, endosulfan
I, endosulfan II, and endrin. However, when they are known to exist,
Method 608 is the preferred method.
Page 3 of 4
-------
• SMCUITT MUTWAU MVWON <
LAMIATMT
"Selected Analytical Methods Approved and Cit«d by the united
States EnvironMntal Protection Agency," Supplement to the Fifteenth
Edition of Standard Method* for the Examination of Hater and Wastewater
(1981).
7
Bach analyst must sake an initial, one-time, demonstration of
their ability to generate acceptable precision and accurcy with Methods
608 and 625 (See Appendix A of this part 136) in accordance with
procedures given in Section 8.2 of each of these methods. Additionally,
each laboratory* on an on-going basis, aust spike and analyse 10% of all
samples analyzed with Method 608 or 5% of all staples analysed with
Method 625 to monitor and evaluate laboratory data quality in accordance
with Sections 8.3 and 8.4 of these methods. Mben the recovery of any
parameter falls outside the warning limits, the analytical results for
that parameter in the unspiked sample are suspect and cannot be reported
to demonstrate regulatory compliance.
NOTE: - These warning limits are promulgated as an "interim final
action with a request for comments.11 .
>s*CMBt-
Page 4 of 4
-------
> SMOAITT MATUIAU OtVtW
HUAKN lAMtATOtY
LIST OP APPROVED RAIOLOGZCAL TEST PROCEDURES
PARAMETER
METHODS
REFERENCE (METHOD OR PAGE)
STANDARD
1 2
EPA METHODS ASTM OSGS
15TH ED.
1. Alpha-Tot Proportional 900.0 703
Ci
al, p per or acintilla-
liter tion counter
2. Alpha- Proportional or Appendix B 703
Counting er- scintillation
Ci
ror, p per counter
liter
3. Alpha- Proportional 900.0 703
Counting err- counter
Ci
or, p per
liter
4. Beta-Count- Proportional Appendix B 703
ing error, counter
Ci
p per litar
5. (a) Radium- Proportional 903.0 705
Ci
Total, p counter
per liter
226
(b) Ra, Scintillation 903.1 706
Ci
p per liter
D1943-66 75 & 78
D1943-66 79
D1690-66 75 « 78
D1890-66 79
D2460-70 -
D3454-79 81
RADIOLOGICAL TEST PROCEDORBS NOTES
"Prescribed Procedures for Measurement of Radioactivity in Drinking
Water,* EPA-600/4-80-032 (1980 update), U.S. Environmntal Protection
Agency, August 1980.
2
Fishaan, M.J. and Brown, Eugene, "Selected Methods of the U.S.
Geological Survey of Analysis of Hastevaters," O.S. Geological Survey,
File Report 76-177 (1976).
-------
ITT MATBHAU MVWON«
The Mthod found on p. 75 measures only the dissolved portion while
the method on p. 78 measures only the suspended portion. Therefore, the
two results must be added to obtain the "total.11
J \
Page 2 of 2
-------
•MOALTT MATHHALS 0*VWOM <
HAICM lASOtATOeY
LIST OP APPROVED TEST PROCEDURES
FOR SOIL AND SOLID WASTES (1)
PARAMETER
SECTION
NO.
METHOD
NO.
CHARACTERISriCS Oi» SOLID
• ignitAbUir.y 2.1
- P4
-------
'WtOAOTMATMIAU
WON
PARAMETER
SECTION
NO.
METHOD
NO.
- Column Cl*aiH7p for Oily Wastes 4.2 3570 (2)
- Sonication Extraction 4.2 3550
• Gas Bulb and Gas Bag Sample Prepara-
tion 4.2 3710
- Volatile Organic* Sampling Train Purge
and Trap Sample Preparation 4.2 3720 (2)
SAMPLE BURODOCnON TECHNIQUES 5.0
* Beadapace
* Purge and Trap
MULTIELEMENT INORGANIC METHODS
• Inductively Coupled Plasma Method
INORGANIC ANALYTICAL METHODS
Antimony, Plamt AAS
Antimony, Purnace AAS
Arsenic, Purnaoe AAS
Arsenic, Gaseous Hydride AAS
Barium, Plant AAS
Barium, Purnace AAS
Berylliua, Plame AAS
Beryllium, Purnace AAS
Cadmium, Plane AAS
Cadmium, Purnace AAS
Chromium, Plant AAS
Furnace AAS
Hexavalent, Chelation
Bexavalent, Colorimetric
Chromium, Hexavalent, Coprecipitation
Chromium, Bexavalent, Polarographpic
Copper, Plane AAS
Copper, Purnace AAS
Chromium,
Chromium,
Chromium,
5.0
5.0
6.0
6.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
5020
5030
6010
7040
7041
7060
7061
7080
7081
7090
7091
7130
7131
7190
7191
7197
7196
7195
7198
7210
7211
(2)
(2)
(2)
(2)
(2)
(2)
Page 2 of 5
-------
• WtdAlTY MATOH AU DfVIl
PARAMETER
Iron, Flame AAS
Iron, Furnace AAS
Lead, Flame AAS
Lead, Furnace AAS
Manganese, Flame AAS
Manganese, Furnace AAS
Mercury, Cold vapor Liquid
Mercury, Cold Vapor, Solid
Nickel, Flame AAS
Nickel, Furnace AAS
Osnium, Plan* AAS
Osmium, Furnace AAS
Selenium, Furnace AAS
Selenium, G**«W'ia Hydride AAS
Sodium, Flame AAS
Thallium, Flame AAS
Thallium, Furnace AAS
Vanadium, Flame AAS
Vanadium, Furnace AAS
Zinc. Flame AAS
Sine, Furnace AAS
SECTION
NO.
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.f)
7.0
7.0
7.0
7.0
7.0
7.0
7.0
7.0
METHOD
NO.
7380 (2)
7381 (2)
7420
7471
7460 (2)
7461 (2)
7470
7471
7520
7521
7550 (2)
7551 (2)
7740
7441
7750
7761
7770 (2)
7840 (2)
7841 (2)
7910 (2)
7911 (2)
7950 (2)
7951 (2)
ORGANIC ANALYTICAL METHODS
• Gas Chromatographic Methods Furnace
- Acrolein, Acrylonitrile, Aeetonitrile
- Aromatic Volatile Organic*
- Chlorinated Herbicide*
- Chlorinated Hydrocarbons
- Halogenated volatile Organics
- Nitroaromatics and cyclic Ketones
- NonBalogenated Volatile Organics
- Organochlorine Pesticides and PCBs
- Organophosphorus pesticides
- Phenols
- Phthalate Esters
- Polynuclear Aromatic Hydrocarbon*
8.0
.1
.1
.1
.1
.1
.1
.1
.1
.1
.1
.1
.1
.1
8030
8020
8150
8120
8010
8090
8015
8080
8140
8040
8060
8100
L
Page 3 of 5
-------
> IMOALTT MATCMAU MVMION •
PARAMETER
• GM Chromatographic/H»"''""" w«*
8.4
8.4
8.4
8.6
»1 for
8.6
ft ±imm
fitiza—
Mind* 8.6
>let Ab-
8.6
is
8.6
9.0
.0
.0
.0
.0
.0
.0
.0
.0
to
.0
•r .0
.0
.0
9.0
9.0
8240
8250
8270
8310
8320 (2)
8330 (2)
8410 (2)
8411 (2)
8600 (2)
8630 (2)
8610 (2)
8620 (2)
9080 (2)
9081 (2)
9250 (2)
9251 (2)
9252 (2)
9131 (2)
9132 (2)
9011 (2)
9010
9095
9310 (2)
9200 (2)
9040
9041
Page 4 of 5
-------
> WtaAlTY MATCH All MVtSIOM
PARAMETER
SECTION
NO.
MA TOO
METHOD
NO.
Phenolics
Phenolics
Phenolic*
Radiua
Radiun, 228
Soil pR
Specific Conductance
Sulfate
Sulfate
Sulfate
Sulfate
Sulfides
Total Oil and Grease
Total Oil and Grease
Total Organic Carbon
Total Organic Halogen
Total Organic Halogen
Neutron Activation
(TOX)
(TOX)
by
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9.0
9065 (2)
9066 (2)
9067 (2)
9315 (2)
9320 (2)
9045
9050
9035 (2)
9036 (2)
9037 (2)
9038 (2)
9030
9070 (2)
9071 (2)
9060 (2)
9020
9022 (2)
FOOTNOTES:
(1)
Test Methods for Evaluating Solid Haste, Physical/Chemical
Methods,.Second Edition, Sff-846, O.S. Environmental Protect-
ion Agency, 1982.
(2).
Proposed Method as Published in the "Federal Register," Vol.
49, No. 191, October 1, 1984.
Page 5 of 5
-------
• SMCUUTYMAI
LIST OP RECOMMEDED TEST PROCEDURES
POR SOIL, SEDIMENT, SLUDGE ANALYSIS
1
L-
L
E;
E
I
PARAMETER
• Acid/Base Potential*
* Neutralization potential
* Maxima Potential Acidity
• Leaching Testing
- TBP
-ASTM
-CAM-WET procedure
• PH (1:1)
• Electrical Conductivity
Saturation Paste Deter-
minations (Sodium Ab-
sorption Ratio)
* Particle Size Determina-
tiOM
• Proximate Analyait
- Percent Ash
METHOD REFERENCE
Calculation from l
Neutralization Po-
tenk.ial and % Sulfur
Determination
Titration to pa 7.0 1
Calculation from I 1
Total Sulfur Deter-
mination
Aqueous Extraction at 2
controlled pB
Aqueous Extraction 3
30 day Cumulative Ex- 4
traction TWO Extracting
Solutions; Hater and
Citrate-Nad Buffer
1:1 Soil to Water Paste 1
Extract from Saturated 1
Soil Paste
Atomic Absorption 1
Spectrophotometry of
Extract from Saturated
Soil Paste for Calcium,
Magnesium, Sodium
Hydrometer or Pipette, 1
Drying oven
Gravimetric
Page 1
-------
— WtCtALTT MA1BHALS DtVISIOM •
PARAMETER
- Percent Moisture
- Percent Solid*
* Sulfur Determination
- Total
- Sulfate
- Pyritic
- Pyritic + Organic
* Oil and Grease
* Total Organic Carbon
• Bomb Preparation
• IB -N
3"
* HO -N
3 ~"
•
• TKH-H
* Phosphorus
* Phosphate-Phosphorus
• Potassiun
* Potassium
* Lithium Netaborate Fusion
METHOD
Gravimetric
Gravimetric
REFERENCE
5
5
Sulfur Analyzer 6
extraction, Sulfur Analyzer 6
extraction, Sulfur Analyzer 6
extraction, Sulfur Analyzer 6
Drying with HgSO BO 7
4 2
followed by Freon extraction
Oxidation to CO and IR Da- 8 '
2
tection
elevated Temperature and 9
Pressure Acid Digestion
KCZ extraction Ion Meter 10
Colorimetric 7
Kjeldahl Digestion, 11
Specific ion electrode
Persulfate Digestion, 11
Colorimetric
NB F or RaBCO extraction 10
4 3
(Dependent on pB <7.00 or
>7.00)
SAR 10
Double-Acid extraction 10
Muffle Furnaoe Digestion 1
Page 2
-------
1W AlS etVWOM«
Method References
MCATOeY
(1)Field and Laboratory Methods Applicable to Overburdens and
Minesoil, by Andrew A. Scbek, William A. Schuller, John R. Freeman,
and Richard M. Smith, College of Agriculture and Forestry, Meat
Virginia University, Morgantown, West Virginia, March, 1978.
(2)federal Register, Volume 45, No. 98, Book 2, May 19, 1980.
(3)1984 Annual Book of ASTM Standards, Volume 11.04, Method D3987,
"Standard Test Method for Shake Extraction of Solid Waste with Water,"
AMriean Society for Testing and Materials, Philadelphia, PA.
(4)California Assessment Manual for Hazardous Wastes, Hazardous
Materials Management Section, California Department of Health
Services, Sacramento, CA, June 1981.
(5)Methods of Soil Analysis, Part I, Physical and Mineralogical
Properties, Including statistics of Measurement and sampling, C.A.
Black, Monograph 9, AMriean Society of Agronomists, Madison, Hi,
1965.
(6)Methods of Analyzing and Testing Coal and Coke, Bulletin 638, 0.
S. Bureau of Mines, United States Department of the Interior,
Washington, D.C. 1967.
(7)Standard Methods for the Examination of Water and Wastewater,
15th edition, Method 503D, AMriean Public Health Association,
American Water Works Association, Water Pollution Control Federation,
1980, pp. 464 to 465.
(8)Operating Procedures Manual for OS24B Total carbon system,
Oceanography International Corporation, College Station, Texas," no
date, pp. 10-2 to 10-4.
(9)"Parkin Elmer Autoclave-3 Instructions," Instrument Division,
Perkin-Elmer Corporation, Horvalk, CT, no date.
(lO)Metheds of Soil Analysis, Part II, Chemical and Microbiological
rtTes, C. A. Black, Monograph 9, AMriean Society ot Agronomists,
Madison, WI, 1965, pp. 1191 to 1195.
(11)Soil Testing and Plant Analysis, L. M. Walsh and J. D. Beaton,
Soil Science Society of America, Madison, WI, 1973.
••AOlftl
Page 3
-------
• SMQAITT MUTBBAIS MVISIOM
'
I
!'
t
-
•:.
—
L
3
,
*
2
r
T
i.
*
1
I
P
TESTS METHODS
FOR LZQDZD AMD SOLID HASTE
PARAMETER
• BTO
(Beat Content)
• % Moisture
(Hater Content)
• Organic Halogen
Content
• Organic Sulfur
Content
* % Acidity
* % Alkalinity
• Density (Specific
Gravity)
• Viscosity
• Coqpatability/
Characterization
- Water Reactivity
• Water Solubility
• Cyanide
- Cyanide
- Sulfide
- Oxidizers
- Peroxides
- Oxidation/Reduction
potential (Eh)
- Bexane Solubility
METHOD
D240(L)
D27KS)
E203(L)
D2216(S)
D808(L)
D1305(S)
D129(L)
D3177(S)
402
403
213E
D88
15.5.11
15.5.1
412E
•»
D1498
REFERENCE
2
• 2
2
2
2
2
2
2
1
1
1
2
4
4
1
3
3
3
3
2
4
1. Standard Methods for the Examination of Water and Wastewater,
15th Edition, 1980, Washington, D.C.
2. AMrican -Society for Testing and Materials,
Philadelphia, PA.
J
Page 1 of 2
L
-------
> IMOAOT MATBMA1S OIVIMO*
•ATOCY-
3. Analysis perfonatd as per test equipment Manufacturer's recom-
swndtd prootdure.
4. Drun Consolidation Protocol (Draft), U.S. Environmntal Pro-
tection A9«ncy, August 1981.
FOOTNOTES:
(1)
(2)
L indicates th« Mtbod for liquid s«pl«s.
S indicates the Bathed is for seaisolid and solid saiples.
-------
. SWCIAITY MATUIALS DIVISION •
• I AQU.PKHH MSIAKM LAtOtATORY
LQPP-13
Revision: 0
Date: 6-13-86
Page 1 of 13
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Data
Verification
Initiated By:
Sharon Farris
Approvals:
By;
Quality Assurance Dept.
Director
1.0 Introduction
Data verification is the steps taken within an analytical laboratory
so that reported results correctly represent the analyses
performed. There are two basic verification activities:
The processing of quality control sajnple results to
demonstrate that analyses are within laboratory-
prescribed bounds for accuracy, precision, and
completeness.
Data validation to demonstrate that numerical
computation of data is correct and that it is correctly
reported.
This section discusses how data verification is performed.
IPKHVI
-------
• WCIAITY MATMIAIS DIVISION •
|
• IAOU-MCMII MMAftCH lAK»t*TO«Y
LQPP-13
Revision: 0
Date: 6-13-86
Page 2 of 13
2.0 Processing of Quality Control Data
This section discusses the analytical treatment of the data
resulting from the quality control samples discussed in LQPP-11.
2.1 Specific Routine Procedurs Used to Assess Data Precision and
Accuracy
2.1.1 A reagent and/or method blank is prepared and analyzed
with each set of examples.
2.1.2 Field blanks are analyzed to determine possible sample
contamination during collection and shipment to the
laboratory. Field blanks are applicable to volatile
organics analysis (VOA) where volatile contaminants can
be introduced from ambient air on site, during shipment,
and in the laboratory.
2.1.3 A daily calibration curve consiting of at least three
standards and a reagent blank is prepared for each
parameter. If the standard curve is known to be stable,
the standard curve can be verified daily by the analysis
of a midpoint standard.
2.1.4 One sample in every sample set of fifteen samples is
analyzed in duplicate.
2.1.5 One sample in every sample set of fifteen samples is
spiked at a level to provide a final concentration
equivalent to the original concentration of the sample
before dilution.
2.1.6 A blind replicate, unknown to the Analyst, is introduced
by the Quality Control Coordinator at least once
monthly. Blind replicates are routinely used for the
analysis of metals, water quality parameters, and
organics analyses which do not require separate
extractions.
2.1.7 Standard Reference Materials (SRMs) are introduced
periodically into the testing scheme by the Quality
Control coordinator to evaluate the testing procedure
and the Analyst's performance.
-------
• SPICIALTV MATUIAIS DIVISION •
• I AGU.PICHUIfSIAKM LAftOIATOIT
LQPP-13
Revision: 0
Date: 6-13-86
Page 3 of 13
2.1.8 A check standard consisting of deionized water spiked
with the parameter of interest is analyzed. Check
standards are routinely used for the analysis of metals,
water quality parameters, and some organics parameters.
2.1.9 Every sample is spiked with the appropriate surrogate
standards prior to extraction and analysis for volatile
organic compounds/ base-neutral, and acids.
2.1.10 Internal standards are added to all samples for GC/MS
analysis prior to analysis.
2.2 When the analyses of a sample set are completed, the results
will be reviewed and evaluated to assess the validity of the
data set. Review is based on the following criteria:
2.2.1 Reagent Blank Evaluation - The reagent and/or method
blank results are evaluated for high readings
characteristic of background contamination. If high
blank values are observed, laboratory glassware and
reagents should be checked for contamination and the
analysis halted until the system can be brought under
control before further sample analysis proceeds. A high
background is defined as a background value sufficient
to result in a difference in the sample value, if not
corrected, greater than or equal to smallest significant
digit known to be true. A reagent blank should contain
no greater .than two times (2X) the parameter detection
limit for most parameters.
2.2.2 Field Blank Evaluation - Field blank results are
evaluated for high readings similar to the reagent
and/or method blanks described above. If high field
blank readings are encountered, the procedure for sample
collection, shipment, and laboratory analysis should be
reviewed. If both the reagent and/or method blanks and
the field blanks exhibit significant background
contamination, the source of contamination is probably
within the laboratory. In the case of VOA, ambieant air
in the laboratory and reagents should be checked as
possible sources of contamination. High field blank
readings for other parameters may be due to contaminated
sample bottles or cross-contaminated sample bottles or
cross-contamination due to sample leakage and poorly
sealed sample containers.
-------
-f -..*;.<
> SMOAITY MATUIALS DIVISION •
• IAGII.PIO4U MSIAKM lAtOIATOIT
LQPP-13
Revision: 0
Date: 6-13-86
Page 4 of 13
2.2.3 Calibration Standard Evaluation - The daily calibration
curve is evaluated to determine linerity through its
full range, and that sample values are within the range
defined by the low and high standards. If the curve is
not linear, sample values Must be corrected for
nonlinearity by deriving sample concentrations from a
graph or by using an appropriate algorithm to fit a
nonlinear curve to the standards.
2.2.4 Replicate Sample Evaluation - Duplicate sample analysis
for the sample set is used to determine the precision of
the analytical method for the sample matrix. The
duplicate results are used to calculate the precision as
defined by the relative percent difference (RPD). The
precision value, RPD, should be plotted on control
charts for the parameter determined, if the precision
value exceeds the warning limit for the given parameter,
the appropriate Group Leader or the QA coordinator is
notified. If the precision value exceeds the control
limit, the sample set must be reanalyzed for the
parameter in question. Attainable precision limits will
be specified by the QC Coordinators and updated
periodically following review of data.
2.2.5 Matrix Spike Evaluation - The observed recovery of the
spike versus the theoretical spike recovery is used to
calculate accuracy as defined by the percent recovery.
The accuracy value, the percent recovery, may be plotted
on a control chart for the parameter daetermined. If
the accuracy value exceeds the warning limit for the
given parameter, the appropriate Group Leader or the QA
Coordinator is notified. If the accuracy value exceeds
the control limit, the sample set must be reanalyzed for
the parameter in question.
2.2.6 Blind Replicate Evaluation - The blind replicate
analysis is evaluated in the same manner as described
above for the duplicate sample analysis and is treated
as a duplicate result for purposes of evaluating the
precision of the analytical method. This evaluation is
. performed independently by the QA Coordinator.
-------
> SMCIAITY MATIIIALS DIVISION •
' SAOU.PlCMIt HSIAKH LAftOIATOI Y
LQPP-13
Revision: 0
Date: 6-13-86
Page 5 of 13
2.2.7 Reference Standard Evaluation - Standard Reference
Materials analyses are compared with true valus and
acceptable ranges. Values outside the acceptable ranges
require corrective action determine the source of error
and provide corrective action. All sample analyses
should be halted pending this evaluation. Following
correction of the problem, the Standard Reference
Material should be reanalyzed.
2.2.8 Check Standard Evaluation - The results of check
standard analysis are compared with the true values and
the percent recovery of the check standard is
calculated. If correction is required, the check
standard should be reanalyzed to demonstrate that the
corrective action has been successful.
2.2.9 Surrogate Standard Evaluation - The results of surrogate
standard determinations are compared with the true
values spiked into the sample matrix prior to extraction
and analysis and the percent recoveries of the surrogate
standards are determined. The percent reacoveries
recommended as attainable by USEPA for volatile and
semivolatile organic compounds are followed.
2.3 Statistical Evaluation of Quality Control Data
As part of the analytical quality control program, EPRL
Analytical Division will determine precision and accuracy for
each parameter analyzed. Initially, when these data are
compiled, the evaluation is applied over a broad concentration
range. As more data are accumulated, precision and accuracy
determinations will be updated and criteria developed to
define precision and accuracy over specific concentration
ranges.
ILIi
>PKHKR
-------
SMCIAITV MATtllALS DIVISION •
IAOU.MCHII MUAKM LAIOtATOIT
LQPP-13
Revision: 0
Date: 6-13-86
Page 6 of 13
2.3.1 Evaluation of Data Using Control Charts - EPRL
Analytical Division will apply precision and accuracy
criteria to each parameter that is analyzed. When
analysis of a sample set is completed, the quality
control data are reviewed and evaluated through the use
of control charts to validate the data set.
Control charts may be established for all major
analytical parameters. A minimum of ten measurements of
precision and accuracy are required before control
limits can be established. In general, for water
samples, control limits of two standard deviations shall
be utilized; analyses of other sample types such as
hazardous waste will utilize three standard deviations
as control limits. Once established, control limits are
updated as additional precision and accuracy data become
available by the QA Coordinator.
2.3.2 Evaluation of Analytical Precision
2.3.2.1 General Considerations - To determine the
precision of the method and/or laboratory
Analyst, a routine program of replicate
analyses is performed. The results of the
replicate analyses are used to calculate the
relative percent difference (RPD) , which is
the governing quality control parameter for
precision.
The RPD for replicate analyses is defined as
100 times the difference (range) of each
replicate set, divided by the average value
(mean) of the replicate set. For replicate
results D. and D., the RPD is calculated
from Equation 1:
D - D
RPDI - X 100%
Equation 1
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• SHCIALTY MATUIAIS 0«VI»K
• IAOU.PICMU HMAKM lABOtATOIT
LQPP-13
Revision: 0
Date: 6-13-86
Page 7 of 13
When the RPD is obtained for at least ten
replicate pairs, the average RPD and the standard
deviation are calculated using:
m.
n
and
Sm -
i>
tdn-ln)
n-1
where
ro • the RPD of a replicate pair,
m" • the average of the RPD
Determinations,
Sm «the standard deviation of the data
set of RPD determinations, and
n • the number of RPD determinations.
When constructing a control chart for a specific
parameter, the warning and Control Limits are then
calculated from the following:
Opper Control Limit » m + 3 Sm
Lover Control Limit • la - 3 Sm
Opper Warning Limit - m + 2 Sm
Lower Warning Limit • m" - 2 Sra
-IA01MI
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• WCIAITT MATIIIAIS DIVISION <
— — lAOU-WOm tfSIAKM LASOCATOtr
LQPP-13
Revision: 0
Date: 6-13-86
Page 8 of 13
2.3.3 A control chart is established by plotting the RPD
of each replicate pair on a graph generated as
follows:
2.3.3.1 The average of the RPO determinations
for the original data set is
established as the midpoint on the Y
axis of the graph.
2.3.3.2 The Upper Warning and Control Limits
calculated above are plotted as solid
horizontal lines across the graph at
their respective points on the Y axis
above the mean of the RPD
determinations.
2.3.3.3 The Lower Warning and Control Limits
calculated above are plotted as solid
horizontal lines across the graph at
their respective points on the Y axis
below the mean of the RPO
determinations.
2.3.3.4 The calculated RPD of each replicate
pair is plotted on the graph to
determine whether the RPD is within
the Warning and Control Limits of the
Control Chart.
2.3.3.5 If the RPD plots between the Warning
and Control Limits, the Group Leader,
Operations Manager, or QC Coordinator
is notified for a decision as to how
to proceed.
2.3.3.6 If the RPD plots outside the Control
Limits, the data set is invalid and
the analysis is stopped until the
source of error has been determined
and corrective action taken. Once the
error source has been resolved, the
data set is reanalyzed.
I
•EAOUE
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r MATtllAlS OWWtON •
PICMM MMAKM LAtOIATOIT
LQPP-13
Revision: 0
Date: 6-13-86
Page 9 of 13
2.3.4 Evaluation of Analytical Accuracy
In addition to the evaluation of analytical precision,
EPRL Analytical Division evaluates accuracy.
When a program for evaluation of analytical accuracy is
established, the evaluation is applied over the entire
range of spiking concentrations. As more data are
accumulated, the evaluation procedure is refined to
define the analytaical accuracy of the method over
specific concentration ranges.
To determine the accuracy of an analytical method and/or
the laboratory Analyst, a periodic program of sample
spiking is conducted. The results of sample spiking are
used to calculate the quality control parameter for
accuracy evaluation, the Percent Recovery (%R).
The %R is defined as 100 tines the observed
concentration, minus the sample concentration, divided
by the true concentration of the spike.
%R -
x 100%
where
%R » the Percent Recovery
0. « the Observed Spiked Sample
Concentration
0 » the Sample Concentration, and
T. • the True concentration of the
1 Spike.
The True Concentration is calculated from:
Spike Concentration Ie) (mg/1) « vol. of Spike (ml)
Volume of Sample (in ml) + Volume of Spike (ml)
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• SPtdAlTV MATIIIAIS DIVISION •
IAOU.MCMII IIMAtCM lAtOIATOtY
LQPP-13
Revision: 0
Date: 6-13-86
Page 10 of 13
When the Percent Recovery is obtained for at least ten spiked samples, the
mean percent reacovery and the standard deviation are calculated using the
following formulae:
n
%R- 2- *«!
and
where
%R • the Mean Percent Recovery,
%R. • the Percent Recovery of a Single Spiked Sample,
n « the number of results, and
S_ • the Standard Deviation of the data set of Percent
Recovery determinations.
The Warning and Control Limits are then calculated from the
following equations:
Upper Control Limit » TR + 3 SR
Lower control Limit « %R - 3 SR
Upper Warning Limit » %R + 2 S_
R
Lower Warning Limit - %R - 2 S_
R
2.3.5 A control chart (as shown in Figure is generated by plotting
the Percent Recovery data on a graph as follows:
2.3.5.1 The average of the Percent Recovery
determinations for the original data set is
established as the midpoint on the Y axis on
the graph.
•IMUIi
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> SPICIAITT MATMIAU DIVISION <
2.3.5.2
• lAOU.PICMII MSIAKM IA»OIATO*T
LQPP-13
Revision: 0
Date: 6-13-86
Page 11 of 13
The Upper Warning and Control Limits
calculated above are plotted as solid
horizontal lines across the graph at their
respective ponts on the Y axis above the
mean of the Percent Recovery determinations.
2.3.5.3 The Lower Warning and Control Limits
calculated above are plotted as solid
horizontal lines across the graph at their
respective points on the Y axis below the
mean of the Percent Recovery determinations.
2.3.5.4 The calculated Percent Recovery of each
spiked sample is plotted on the graph to
determine whether the Percent Recovery is
within the Warning and Control Limits of the
Control Chart.
2.3.5.5 If the Percent Recovery plots between the
Warning and Control Limits/ the Group Leader
or QA Coordinator is notified for a decision
as to how to proceed.
2.3.5.6 If the Percent Recovery plots outside the
Control Limits/ the data set is invalid and
the analysis is •topped until the source of
error has been determined and corrective
action taken. Once the error source has
been resolved/ the data set is reanalyzed.
2.3.5.7 When an additional ten Percent Recoveries
have been determined/ the Warning and
Control Limits are recalculated for the
entire data set and the Control Chart for
the corresponding parameter is updated.
2.3.6 All control charts are maintained by the Quality Control
Coordinator in the QAD.
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• IMCIAITY MATttlAU DIVISION •
• lAOU.HCHH MSIAKM LAftOtATOflV
LQPP-13
Revision: 0
Date: 6-13-86
Page 12 of 13
3.0 Data Validation
Data validation begins with the processing of data and continues
through review of the data and the reporting of analytical results.
Data processing can be performed by the Analyst who obtained the
data or another Analyst. Data review starts with an Analyst
independent of the data acquisition and processing, or the Group
Leader/ reviewing (validating) that data processing has been
correctly performed and continues through verifying that the
reported analytical results correspond to the data acquired and
processed. Final review of the data to be reported is by the Group
Leader.
3.1 In general, data will be processed by an Analyst in one of the
following ways:
Manual computation of results directly on the data
sheet or on calculation pages attached to the data
sheets
Input of raw data for computer processing
Direct acquisition and processing of raw data by a
computer.
3.2 If data are manually processed by an Analyst, all steps in the
computation shall be provided including equations used and the
source of input parameters such as response factors, dilution
factors, and calibration constants. The analyst shall sign
(Full signature) and date in ink each page of calculations.
3.3 For data that are input by an analyst and processed using a
computer, a copy of the input shall be kept and uniquely
identified with the project number and other information as
needed. The samples analyzed shall be evident and the input
signed and dated by the analyst.
3.4 If data are directly acquired from instrumentation and
processed, the analyst shall verify that the following are
correct: project and sample numbers, calibration constants
and response factors, output parameters such as units, and
numerical values used for detection limits (if a value is
reported as less than). The analyst shall sign and date the
resulting output.
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> SMCIAITY MATIIIAIS DIVISION •
• lAOU.PtCMtt MSIAKM LA0OIATOIY
LQPP-13
Revision: 0
Date: 6-13-86
Page 13 of 13
4.0 Review of Data Reporting
4.1 Review of data reports is required to verify that information
reported by EPRL Analytical Division corresponds with
processed analytical results. Review is only required of the
data as it is presented for issuance. Intermediate steps
performed after the processed data are checked to prepare the
data report (such as data summaries) do not require
validation. Preparation of the report is the responsibility
of the Group Leader.
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• SWCIAITY MATUIALS DIVISION •
• IAOU.PICHII MSIAKM lAtOIATOtT
LQPP-14
Revision: 2
Date: 6-13-86
Page 1 of 3
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
QUALITY ASSURANCE PROCEDURES MANUAL
Subject: Data
Reports
Initiated By:
Sharon Parris
Approvals:
Quality Assurance Dept.
EPRL
Director
1.0 Introduction
The format and content of a data report is dependent upon project
needs, such as: whether or not explanatory text is required, client
or contract requirements, and government agency reporting formats.
The EPRL Quality Assurance Program does not specify a report format;
however, the following are applicable to data presentation:
1.1 The final data presentation shall be checked in accordance
with data verification requirements of LQPP-13 and approved by
the Laboratory Director.
1.2 Data are presented in a tabular format whenever possible.
1.3 Data are formatted as an EP-Analytical Report such as shown on
Figure 14.1, or formatted as an EP Laboratory memorandum.
1.4 Each page of data are identified with the project number and
name; date of issue; and, if appropriate, client name.
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• WCIAtTY MATCIIALS DIVISION •
• IAOU.PICMM MSIAKM lAVOIATOtT
LQPP-14
Revision: 2
Date: 6-13-86
Page 2 of 3
1.5 Data presentation includes:
1.6
1.7
Sample identification number used by the EPRL laboratory
and/or the sample identification provided to the
laboratory.
Chemical parameters analyzed, reported values, and units
of measurement
Detection limit of the analytical procedure if the
reported value is less than the detection limit
Data for a chemical parameter are reported with
consistent significant figures for all samples
Results of Quality Control sample analysis if
appropriate
Achieved accuracy, precision, and completeness of data
if appropriate
Footnotes referenced to specific data if required to
explain reported values.
Data should be transmitted from the laboratory only by the
Laboratory Director or responsible Group Leader.
If explanatory text is not issued with the analytical results,
it is recommended that:
A letter of transmittal be included for external clients
A memorandudm be included to augment data for other EP
facilities
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. SMCIALTY MATUIAIS DIVISION •
• I AOU-PtCHf I MSIAKH LA»O*ATOIT
LQPP-14
Revision: 2
Date: 6-13-86
Page 3 of 3
1.8 As necessary/ the letter of transnittal/nemorandun should
include:
Person(s) receiving the data
Person transmitting the data
Document if the chain-of-custody was provided or
correct, if any samples were damaged in shipment, if
sample containers were inappropriate for analysis, or if
volume provided was inadequate for proper analysis
Brief discussion of samples analyzed and the analytical
program
Discussion of any apparent data anomalies
Discussion of any analytical difficulties.
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> SPtCIAlTY MATMIAU DIVISION •
• CAOU-»ICMf*miAKH LAtOIATOtY
ALSOP-1
Revision: 1
Date: 6-13-86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Glassware
Clean Up
Initiated By:
Larry Zinn
Approvals:
Quality Assurance Dept.
EPRL Analytical/ Director
1.0 Methods of glassware cleaning should be selected according to
substances that are to be removed and by the analytical protocols
required.
2.0 Water soluble substances can be washed with hot water and the vessel
finally rinsed with small amounts of deionized water. Other
substances may require the use of a detergent/ organic solvent/
chromic acid cleaning solution/ nitric acid or aqua regia.
3.0 For trace metal analysis/ the glassware shall be rinsed with 1:1
nitric acid-water mixture. Rinse thoroughly with successive
portions of deionized water. Chromic acid should not be used for
cleaning of glassware for trace metal analysis.
4.0 Glassware used for phosphate determinations should be thoroughly
rinsed with tap water and then deionized water. Detergents
containing phosphates should not be used for cleaning this
glassware.
5.0 For ammonia and kjeldahl nitrogen determinations, the glassware must
be rinsed with ammonia-free water.
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• ftMCIAUY MATIIIAtS DIVISK
I AOlt-PICHIt tlSIAKM LAIO«ATOtT
ALSOP-1
Revision: 1
Date: 6-13-86
Page 2 of 2
6.0 Glassware used in the determination of trace organic constituents
should be washed with chromic acid for at least 15 minutes. Rinse
thoroughly with tap water and then with deionized water. Glassware,
other than volumetric glassware, may be dried in the oven or placed
in the muffle furnace at 400 degrees C for two hours. Glassware
could also be dried by rinsing with redistilled acetone. The
glassware should be rinsed with redistilled hexane prior to use.
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> SPIOAITT MATIIIALS DIVISION <
• lAOU.PICMIt MSIAtCM lAftOtATOIT
ALSOP-4
Revision: 1
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Production
and Monitoring of
Reagent Water
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
By:.
EPRL Anajytical^irector
1.0 Introduction
This SOP provides general information on the preparation and use of
Type I reagent water. This SOP is intended to describe the
generation of reagggent water and verify that reagent water of
sufficient quality is used in the operation of the laboratory for
the preparation of standards and dilution of samples.
2:0 A designated person must measure and record the resistivity of water
from the purification system. Initials of the person performing the
measurements must be a part of the records.
3.0 The measurements may be made by an external-calibrated conductivity
meter or an on-line resistivity meter.
4.0 If a conductivity meter is used for calibration, it must be
calibrated prior to taking measurements by using a suitable standard
solution of known conductivity.
5.0 If the resistivity drops below 14 megaohm per centimeter, .any use of
the water should be suspended and corrective action taken before
water use is resumed. All maintenance performed on the water system
should be documented. The QC Coordinator must also be informed of
all problems with the water system.
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> WCIAITT MATttlALS DIVISION •
f-
L
E
E
• IAOU.WCNII MSIAtCH IAKMUTOIY
ALSOP-7
Revision: 0
Date: 6-13-86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Facility
Security
Initiated By:
Larry 2inn
Approvals:
By:
Quality Assurance Dept
1.0 Introduction
All building entrances are locked at all tines with the exception of
the front vestibule. A receptionist Monitors access to the rest of
the building for all visitors. This vestibule is open during normal
working hours and locked at 05:00 pm, Monday through Friday. Each
employee wears an ID badge with a Magnetic key built into it for
access through the second door of the main entrance and an employee
entrance at the side of the building. The rear of the building is
protected by an eight foot security fence.
2.0
3.0
During hours when a receptionist is not on duty, the front doors
will be kept locked.
During hours when no employees are in the building, the facility
will be secured by the use of an electronic detection system
monitored by the local police department..
1PKMBPT
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• SMCJAkTV MATHIALS DIVISION •
4.0
5.0
' lAOll.PICMII MSIAtCH lAlOIATOIT
ALSOP-7
Revision: 0
Date: 6-13-86
Page 2 of 2
Doors at the back and sides of the building will remain locked at
all times.
All deliveries must be made at the back of the building. An EP
employee must remain with delivery personnel at all times.
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> SnClALTY MAWIAIS DIVISION -
ALSOP-8
Revision: 0
Date: 6-13-86
Page 1 of 3
EAGLE-PICRER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Instrument
Operation,
Calibration,
and Maintenance
Initiated By:
Larry Zinn
Quality Assurance Dept.
EPRL
AnilyU
1.0 Introduction
This SOP provides general information on instrument operation,
calibration, and maintenance requirements.
2.0 Definitions
2.1 Equipment:
2.2 Calibration:
Any nondisposable mechanical and/or
electronic device used in the generation or
measurement of data.
Adjusting equipment with reference standards
to assure that any measurement performed is
quantitatively accurate. The reference
standards should be traceable to primary
standards (e.g., National Bureau of
Standards or other certified standards). If
traceable chemical standards are not
available, standards may be prepared
according to the Laboratory's quality
control procedures or the project's
requirements.
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> SPICIALTY MATIIIALS DIVISION •
2.3 Maintenance:
3.0 Requirements
• IAOU.PICMII IIUAKM IABOBATOIT
ALSOP-8
Revision: 0
Date: 6-13-86
Page 2 of 3
Cleaning and/or replacing equipment
components to assure that the equipment has
been properly and periodically serviced and
is in satisfactory condition.
3.1 Equipment for the generation, measurement or determination of
data shall be adequately calibrated.
3.2 Equipment shall have adequate procedures for operation,
calibration, maintenance, and quality control which shall:
Be prepared in written form in accordance with LQPP-1.
Be congruent with the manufacturer's recommendations.
Reflect actual use patterns for the equipment.
Establish frequency intervals for the calibration and
maintenance particular to the equipment.
3.3 Equipment shall be calibrated and maintained in accordance
with the procedures and schedules detailed in the equipment's
SOP.
3.4 Calibration and maintenance intervals begtn from the date of
last calibration of service.
3.5 Equipment maintenance shall be documented and the records
retained in accordance with the logging requirements of the
SOP, in the respective equipment file.
4.0 Responsibility
4.1 The Laboratory Director and/or the Group Leader
shall:
r-
I
- Identify, compile, and write the SOP.
- Make pertinent SOP'S available to the appropriate staff.
(mis is to be coordinated with the QAD.)
- Maintain instalment SOP's with the instruments. Operation
manuals shall also be available in the immediate work area.
- Ensure that use logbooks are initiated and maintained in
accordance with the SOP's.
- Review records for completeness and accuracy which indicates
the equipment is in proper working order.
- Monitor and assure compliance with the SOP.
> WCHWI
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• SPICIAITV MATUIAU DIVISION •
• IAOII.PICMI t tIMAtCM lAtOIATOIT
ALSOP-8
Revision: 0
Date: 6-13-86
Page 3 of 3
4.2 The Quality Assurance Departnen" shall:
- Coordinate SOP preparation.
- Coordinate review/revision of SOP's.
- Reproduce and issue SOP's.
- Retain current and historical copies of the SOP's.
- Maintain distribution list of issued SOP's. Recall
superseded copies.
- verify compliance (via inspections).
5.0 Corrective Action
Problems shall be referred to the Laboratory Director and/or Group
Leader who shall then initiate the appropriate corrective action.
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• SMCIAITY MATItlAU DIVISION
• IAOU.PICMH ftUlAKM LAIOIATOIT
ALSOP-9
Revision: 0
Date: 6-13-86
Page 1 of 3
EAGLE-PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Reagent
Procurement,
Labeling,
Storage, and Testing
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
EPRL Analytical Director
1.0 Introduction
This SOP provides general information regarding reagents and
standard solutions for chemical analysis.
2.0 Procurement Requirements
•2.1 All reagents and chemical procurement must be entered into a
Reagent and Chemical Procurement Log when the order is made.
2.2 All solvents and chemicals purchased must be at the purity
required by the customer. Reagents for USEPA or for any state
agencies must be either pesticide residue grade or HPLC grade
or better. All chemicals used for calibration standards must
be NBS traceable.
2.3 All reagents and chemicals received must be dated on receipt
by the field services group.
2.4 All reagents or chemicals beyond the expiration date must be
discarded. All groups must maintain an inventory of chemicals
and reagents. Form ALSOP-9.1 should be used to «on<.f«' the
expiration date.
IPKHCft
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> SMCIAOT MATUIALS DIVISION •
.mCHII •IMAtCN LAKOIATOIT
ALSOP-9
Revision: 0
Date: 6-13-86
Page 2 of 3
3.0 Labeling Requirements
3.1 Labeling requirements include notations as to expiration date
and storage requirements. When there are additional contract
specific requirements they shall also apply and shall
supercede .
3.2 Storage shall be in accordance with Good Laboratory Practices,
the applicable SOP, and/or customer requirements.
3.3 Testing of standards and solutions will be accomplished as
part of routine QC by the quality control officer. Samples
will be taken and submited as blind samples.
4.0 Responsibility
4.1 It shall be the responsibility of the Laboartory Director and
the group leader to indoctrinate staff members to these
requirements and ensure compliance with this SOP.
4.2 It shall be the responsibility of the QAD to monitor the
Laboratory activity periodically to verify compliance.
Problems detected shall be followed up by request for
corrective action to the Director.
IPKHCft-
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• mciAlTY MATUIAU DIVISION •
• IAOLI.PICMM MSIAICM LABOtATOlY
ALSOP-9
Revision: 0
Date: 6-13-86
Page 3 of 3
Form ALSOP-9.1
Order Date
PO*
Vendor
Item
Recepit
Date
Expiration
Date
Initials
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> SMCIALTY MATIIIALS DIVISION <
• IAOU.mCMMMSIAKH (.AtOIATOIT
ALSOP-10
Revision: 0
Date: 6-13-86
Page 1 of 6
EAGLE-PXCHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Record
Retention Procedures
Initiated By:
Larry Zinn
Approvals:
By:
Quality Assurance Dept.
By:
EPRL Analytical/Director
1.0 Introduction
This Standard Operating Procedure (ALSOP) provides general
guidelines for project record retention.
2.0 Definitions
2.1 Laboratory Director: The analytical department di-
rector. This person is responsible for directing the
overall activity of the analytical lab and reports
directly to EPRL vice-president.
2.2 Group Leader: The person designated by EPRL Management
to be responsible for coordinating and directing a
particular program/project. This person is responsible
for producing and maintaining project records until
stored in the EPRL archives.
•LACK
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> fMCIAITY MATUIALS DIVISION •
ALSOP-10
Revision: 0
Date: 6-13-86
Page 2 of 6
2.3 Raw Data: Any "original" observation project records,
or exact copies thereof, necessary for the
reconstruction and evaluation of a report. Raw data may
include, but is not limited to:
Hand-written records
Instrument printouts
Computer printouts (direct data input)
Magnetic records
Photographs
Transscripts
Exact Copies: Records that are verified as exact
copies of raw data (e.g. photocopies, transcripts,
computer printouts, etc.) by signature and dated.
Chain-of-custody records require the additional
statement of "exact copy".
Transcripts: Exact transferrals of information,
generally from one medium to another (e.g.
magnetic records to hand-written or types notes).
If a transcript is verified as accurate by
signature and dated, it may be substituted for the
original source.
2.4 Archive: An ordered record storage system.
Project Archive: Data/records maintained under
supervision of a Group Leader until stored vis
EPRL archives.
CLP Archives: A limited access storage area for
non-regulated project records maintained under the
direction of the Laboratory Director.
3.0 Responsibility
3.1 The Laboratory Director and/or Group Leader are
responsible for training all laboratory staff in this
ALSOP.
3.2 The Laboratory Director and/or Group Leader are
responsibi* for enforcing this ALSOP.
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• snciAirr MATHIALS DIVISION
• IAOU.»tCHIItlUAKM IAMIAT00Y
ALSOP-10
Revision: 0
Date: 6-13-86
Page 3 of 6
3.3 The EPRL QAD is responsible for Baintaining the limited-
access archives.
3.4 The Group Leader is responsible for ensuring the
retention of all records associated with a project until
final archiving.
3.5 The Group Leader is responsible for ensuring automatic
distribution of reports and other important documents to
EPRL archives as they are generated.
3.6 The QAD is responsible for verifying compliance (via
inspections) and maintaining the applicable inspection
records and for final archive storage.
4.0 Corrective Action
4.1 Problems discovered prior to final archiving shall be
referred to the Group Leader who shall then take the
appropriate corrective action. If the Group Leader is
unavailable, the Laboratory Director •hall take the
appropriate corrective' action.
4.2 Problems discovered after final archiving are the
responsibility of the Group Leader, Laboratory Director/
QAD/ and EPRL Management. Information of this nature is
to be documented and sent to QAD for review and
continued coordination, and to EPRL Management.
5.0 Guidelines
5.1 Raw data and records generated as a result of/ or
directly associated with a project shall be retained in
a systematic and logical form.
Project information shall be:
Accounted for
Adequately filed for future rapid retrieval
Appropriately indexed
Stored under the required level of security
Retained at least for the specified
retention peiod.
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> mClAlTY MATIIIAIS DIVISION •
• I AOU.mCMU fttMAKM LAiORATOf Y
5.2
5.3
ALSOP-10
Revision: 0
Date: 6-13-86
Page 4 of 6
Project material generated during the course of a
project are shown in Table 1 of this ALSOP.
After project completion, the Laboratory Director and/or
Group Leader shall be responsible to collect and
transfer the records to the final lab archives.
Retention shall be for a minimum of five years unless
otherwise additionally specified by project requirements
or EPRL Management.
6.0 initial Archiving Procedure
The Group Leader or designee shall:
6.1 Complete the upper portion of the Record Index form
(copy attached) and then retain it with the project
records.
6.2 Prepare file folders according to the categaories on the
Record Index form, as appropriate, and begin filing
accordingly as soon as project information is available.
6.3 ensure that any contract-specific document control
requirements for archival are followed. If an alternate
inventory format is required, substitute it for the
Record Index form.
6.4 Maintain project records under the required level of
security.
7.0 Final Archiving Procedure
After the final report is written, the Group Leader shall:
7.1 Ensure that all required project records are placed in
storage containers (as a minimum storage file boxes) and
that extraneous information has been removed. NOTE:
QAD reports are maintained by the QAD and shall NOT be
stored with project records. Copies of QAD results
formally submitted to a client shall, however, be in
project reports.
7.2 Complete the Record Index form, sign off at the bottom
of the form, and obtain approval signatures.
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. SMdAlTY MATIIIALS DIVISION •
• IAOU.»ICMM*IUAKM LABOIATOtT
ALSOP-10
Revision: 0
Date: 6-13-86
Page 5 of 6
7.3 Make sufficient copes of the completed Record Index form
to allow for:
One copy each for file reference of Group
Leader, Laboratory Director, and QAD.
Distribute accordingly.
TWO copies for each storage container.
7.4 Place one copy of the completed Record index inside the
storage container and one taped to outside. (If stored
in storage file boxes, place on top of the files so that
it will be readily visible when box is opened.) Be sure
containers are numbered as specified on the Record
Index.
7.5 Transfer stored records to designated archive storage
area.
TABLE 1 - PROJECT RECORDS TO BE MAINTAINED
1.0 Project Administration
1.1 Naae and role of-all project staff members including
EPRL Management
1.2 External communication (communication with customer,
i.e. correspondence, telephone conversations, meetings
notes, etc.)
1.3 internal communications (field reports, lab memos, etc.)
2.0 Background Information
2.1 Safety information
2.2 published literature used as a direct source of
information
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• SMCIAITT MATIII All DIVISION •
• IAOU-PICMH MftlAKM LASOt ATOIT
ALSOP-10
Revision: 0
Date: 6-13-86
Page 6 of 6
3.0 Protocol
3.1 Copies of all protocols and their revisions
3.2 Work assignments
3.3 QA plans
3.4 Training programs
4.0 Project Data; Including but not limited to:
4.1 Sampling and/or survey information
4.2 Field and/or laboratory chain-of-custody records
4.3 Sampling and/or analysis data
4.4 Subcontractor data
4.5 Copies of analytical notebooks (case files, EPA
Archives)
4.6 Sample locations (reference storage location)
4.7 Data calculations and tabulations
4.8 Computer programs (or references), revisions,
validations, etc.
4.9 EPA regulated project records
4.10 EPA samples
5.0 All Reports
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mClAITT MATIIIALS DIVISION
• lAOU.PICMIl MSIAKH LA»OIATO«Y
AJLSOP-11
Revision: 0
Date: 6-13-86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Sample
Chain-of-Custody
Initiated By:
Larry 2inn
Approvals:
By;
Quality
ce Dept.
EPRL AnaiyticaZ Director
1.0 Introduction
All samples collected by EP Corporation must include an EPRL
chain-of-custody Record (Figures 1.1 and 1.2). The chain-of-
custody must be included with all other documents in the case
file.
2.0 Within the laboratory additional procedures are required to
demonstrate chain-of-custody. The National Enforcement
Investigations Center (NEIC) of EPA define custody in the following
ways:
It is in your actual possession or
It is in your view after being in your possession or
It was in your possession and then you locked or sealed
it up to prevent tampering of or
It was in a secure area.
In order to comply with this provision intralaboratory chair-nf-
custody record must be maintained for all samples and extracts.
IPKHCM
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• SMCIAITY MATUIAIS DIVISION — IAOU.PICMI* MMAKM LASOIATOIT
ALSOP-11
Revision: 0
Date: 6-13-86
Page 2 of 2
3.0 For samples requiring intralaboratory chain-of-custody, the
following procedure shall be used.
3.1 intralaboratory chain-of-custody form must be used. When the
sample is logged into the laboratory the laboratory sample
management computer will generate a seperate internal chain of
custody record to accompany the sample while in the
laboratory. A copy of the intralaboratory chain-of-custody
form must follow the sample and the extract within the
laboratory. The original will remain with the field services
group personnel. Upon receiving or relinquishing samples and
extracts, the personnel involved must sign the intralaboratory
chain-of-custody form.
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• SMCIALTY MATUIALS OtVtUOM •
• lAOU-PICMU MMAICM LAtOtATOIT
ALSOP-12
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject : Sample
Storage and Security
Initiated By:
Larry Zinn
Approvals:
By: .3/£>
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> SMCJAITY MATIIIAIS DIVISION •
• lAOU.UCMIi UMARCM lAIOIATOIT
ALSOP-13
Revision: 0
Date: 6-13-86
Page 1 of 3
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Sample
Receipt and Log-In
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
_
EPRLAnalytical/Jirector
1.0 Introduction
1.1 All samples will be received by the Sample Management Office
Data Custody.
1.2 All deliveries must be made at the back of the building
between the hours of 0800 through 1600 Monday through Friday,
and 0800 to 1200 hours on Saturday. There will be no receipt
of sample* at any other time than those listed above unless
prior arrangements with the appropriate laboratory pesonnel
have been made.
1.3 The designated lab employee must follow the procedures listed
below when receiving samples:
1.3.1 Sign for shipment after verifying that the number of
packages received agrees with the airbill.
T.3.2 Fill in date of receipt on Sample Receipt Log (Figure
1.1).
•IAOU
>PKHBN
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IMdAOT MATHIAkS OlVlttOI
• IAOll.?t04irilSIAtCM LA»OIATOIV
ALSOP-13
Revision: 0
Date: 6-13-86
Page 2 of 3
1.3.3 Check the ice chests for the presence, position, and
condition of Custody Seals. Note the condition of the
Custody Seals on the Chain-of-Custody shets, if
available. Otherwise, note all anomalies on the sample
log-in form.
1.3.4 Check the sample tag/label and the sample tag numbers
for listing on chain-of-custody. Note anomalies on the
sample Log-in form.
1.3.5 Check for presence of any other form or notes on the
samples. Note any additional information on the sample
Log-in form.
1.4 Procedures when Field Service Group Personnel are not
available for sample receipt.
1.4.1 Verify that the number of packages received agrees with
airbill.
1.4.2 Record the date/time samples were received on Sample
Receipt Log (Figure 1.1).
1.4.3 Record on Sample Log-in sheet the presence or absence of
the chain-of-custody records, the presence or absence of
airbills and/or bills of lading documenting shipment of
samples.
1.4.4 Hove the shipping containers to the refrigerated sample
storage area.
1.4.5 Sign and date the Sample Receipt Log and any chain-of-
custody to storage.
EH
E
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• SPICIAITY MATKIALS OIVISIOI
• I AOU.FIO4II MMAtCH LABOIATOtT
ALSOP-13
Revision: 0
Date: 6-13-86
Page 3 of 3
SAMPLE LOCATION
PROJECT SAMPLE LOG-IN FORM
EPRL LAB WORK ORDER NO.
PROJECT NUMBER:
PROJECT NAME:
PROJECT CONTACT:
SUBMITTED BY:
DATE RECEIVED:
RECEIVED BY:
REPORT TO:
REPORT DATE:
SAMPLE
IDENTIFICATION
PARAMETERS
(Hater and Hastcvater)
Comments or Special instructions
Figure 1.1
-EAOll &•>««<•*•
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• SPfdAtTY MATUIAU DIVISIOI
• IAOi.|.»tCMIt«fMAKM lAMMATOtY
ALSOP-14
Revision: 0
Date: 6-13-86
Page 1 of 3
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Preparation
of Sample Containers
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
By;
EPRETAnaJytical/Director
1.0 Only new containers will be used for collection of samples to be
shipped to the laboratory for analysis.
2.0 Preparation of volatile Organic Analysis vials
2.1 40 ml borosilicate glass vials with teflon-lined silicone
rubber septa and screw caps must be used for collection of
samples for volatile organic analysis.
2.2 Procedure
2.2.1 Soak vials in detergent solution for approximately 30
minutes.
2.2.2 Scrub vials clean with a brush.
2.2.3 Rinse several times with tap water to remove detergent.
2.2.4 Rinse the vials several times with deionized water.
2.2.5 Place vials in an oven at 180 degrees C for one hour to
dry and remove any trace contamination from volatile
organic compounds.
2.2.6 Remove vials frc
oven and allow to cool.
> PICHIR
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> WCIALTY MATHIALS DIVISION •
• lAOU-'ICMCt IISIAtCH lASOIATOIT
ALSOP-14
Revision: 0
Date: 6-13-86
Page 2 of 3
2.2.7 seal vials with the teflon-lined silicon* rubber and
screw caps. The teflon-lining must face the interior of
the vial. Store the vials in contamination-free areas
until use.
2.2.8 Prior to shipping of the vials, add 3g sodium
thiosulfate to the vials.
3.0 Preparation of Base, Neutral, Acid and Pesticide Organic Analysis
Bottles
3.1 One quart or two-quart glass bottles with teflon-lined caps
must be used for sample collection. Only new bottles should
be used for sample collection.
3.2 Procedure
3.2.1 Soak bottles in detergent solution for approximately 30
minutes.
3.2.2 Scrub bottles clean with a brush.
3.2.3 Rinse bottles several times with tap water to remove the
detergent.
3.2.4 Rinse bottles several times with distilled water.
3.2.5 Rinse bottles with pesticide-grade acetone.
3.2.6 Rinse bottles with pesticide-grade hexane.
3.2.7 Allow bottles to throroughly air dry to remove organic
solvents, seal and store until shipping.
3.2.8 Prior to shipping, add lOOg sodium thiosulfate to
bottles.
4.0 Preparation of Metals Analysis Bottles
4.1 250 ml or 500 ml new polypropylene plastic bottles must be
used for sample collection.
4.2 Procedure
4.2.1 Soak the bottles in detergent solution for approximately
30 minutes. _
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> SPICtAlTY MATIIIALS DIVISION •
' lAOU-MCMItftlSIAeCM lAKMATOtT
W.
U
1
I
ALSOP-14
Revision: 0
Date: 6-13-86
Page 3 of 3
4.2.2 Scrub the bottle* clean with a brush.
4.2.3 Rinse bottles with tap water.
4.2.4 Rinse bottles with deionized water.
4.2.5 Add 1:1 nitric acid to bottles, cap and shake briefly.
4.2.6 Allow bottles to stand for approximately 30 minutes,
shaking them intermittently.
4.2.7 Pour acid from bottles and rinse thoroughly several
times with deionized water.
4.2.8 Add 1ml of concentrated nitric acid per 100ml of volume
as preservative.
5.0 Preparation of Bottles for Other Water Quality Analysis
5.1 Bottles will be plastic (unless glass or other material
specifically requested by procedure) and the size would
dependent and the number and type of determination requested.
5.2 Procedure
5.2.1 Rinse bottles with tap water.
5.2.2 Soak bottles in detergent solution for approximately 30
minutes.
5.2.3 Scrub bottles clean with a brush.
5.2.4 Add acid solution to bottles, cap and shake briefly.
5.2.5 Allow bottles to stand for a minimum of 15 minutes,
shaking them intermittently.
5.2.6 Pour acid solution from bottles and rinse them with tap
water.
5.2.7 Rinse bottles several times with deionized water.
5.2.8 Allow bottles to dry, cap and store until use.
r
r
U
LACK
>PKHCf
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> tPKIAlTY MATIIIAIS DIVISION <
• IAOU.mCM» IISIAKNlAftORATOt
ALSOP-15
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Temperature
Monitoring of
Refrigerated Storage
Initiated By:
Larry Zinn
Approvals:
av; .
Quality Assurance Dept.
EPRfAnayticalAirector
1.0 Introduction
2.0
Tempeatures of all refrigerated storage areas must be
monitored. Calibrated thermometers must be placed in vials
containing glycerin and monitored at least once each day by a
designated person from the field services group. The
temperature must be recorded in the appropriate notebook and
initialled by the person recording the temperature.
The temperature of all refrigerated areas must remain within a
range of 1 degree C to 10 degrees C. If the temperature falls
outside this range, the Laboratory Director/ the QC
Coordinator, and the field services group leader must take
appropriate corrective action and the affected samples
flagged. The analytical results will contain the following
information:
The date and time the anomaly in temperature was
observed.
The approximate period for which the samples have been
outside the temperature window (1 degree C to 10 degrees
C).
Whether samples were maintained at the required
temperature range while corrective action was being
instituted.
Any corrective action taken must be documented in the
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> SPfCIAITT MAmtALS OIVISIOI
• IAOU.MCMM MUAKM LAKMATOtT
ALSOP-16
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Visitors
Initiated By:
Larry Zinn
Approvals:
By: *SC^o-KjJ— •
Quality
By: ^
EPRirAnad
Assurance Dept.
l^f-
TJT- <
lyticay Director
1.0 Visitors, defined as any person who is not employed by Eagle-Picher
Research Laboratory, mist sign in and out on the Visitor Log.
2.0 Visitors will be provided with safety glasses before entry into the
laboratory areas and will be required to wear the safety glasses at
all tines within safety glasses areas of the laboratory.
3.0 Visitors shall not enter the laboratory without being escorted by an
EPRL employee.
4.0 Visitors who stay for a reasonably long period (e.g. repair
equipment) nust be supervised at all tines while inside the
laboratory by EPRL personnel.
5.0 Consultants and employees from other EP locations will be considered
as visitors and should be treated as such.
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• SPICIAITY MATIRIAIS DIVISION •
• lAOlf.PICMII MSIARCM LA*OIATOIT
ALSOP-17
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Sample
Disposal
Initiated By:
Larry Zinn
Approvals:
By:
Quality Assurance Dept.
EPRL Analytical
1.0 Samples will be transferred out of the refrigerated area seven days
after issuance of the report. The saaple will be retained in a
specified area for at least 180 days. After 180 days and with the
concurrence of the client/ the sample will be disposed of in
accordance with state and federal regulations. The process used for
disposal of samples shall be recorded in the chain-of-custody forms
and any other documents required by the state or federal agencies.
2.0 For solid samples known not to contain a hazardous or regulated
(RCRA) characteristic, RCRA, TSCA, PCB, or state listed contaminant,
disposal through a local municpal solid waste collection system is
appropriate.
3.0 For water samples and generated aqueous waste, a carbon unit
filtration system shall be used.
4.0 Ignitable and combustible waste will be incinerated by Rollins
Environmental Service on a quarterly basis.
5.0 Regulated materials must be disposed of at a corporate approved
facility. US Pollution Control, Inc. is listed as the primary hauler
and disposal facility.
6.0 Clients are encouraged to accept return of samples upon Certificate
of Analysis issue. The client will be invoiced for cost of
transport and packaging. The original chain-of-custody will be sent
"
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• SMCIAUY MATMIALS DIVISION '
IAOII.PICHII RISIAtCH lASOtATOflY
ALSOP-18
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Report
Assembly and Data
Storage
Initiated By:
Larry zinn
Approvals:
Quality Assurance Dept.
EPRL Analytical/director
1.0 All raw data and processed data from the laboratory is submitted in
report format to the Organic and Inorganic Group Leaders. The
managers shall validate the reports, and the reports will then be
signed and released by the Laboratory Group Leader from the group
which performed the work or his designee.
2.0 The repots, along with the raw data, will be archived in files in
chronological order.
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> SPfClAlTY MATHIAU DIVISION •
> lAOll.PlCHtt klSIAKM LABOIATOIT
ALSOP-19
Revision: 0
Date: 6-13-86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Laboratory
Data Recording and
validation
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
EPRL Analdeal director
l/
1.0 Data Recording
1.1 Entry of raw data into laboratory documents, worksheets, or
logbooks must be made in indelible ink. Pencils shall not be
used for data entry.
1.2 Corrections of raw data must be made in ink.
1.3 If an error is made, the analyst shall correct the data by
drawing a single line through it. The line shall be drawn in
such a way as not to conceal the erroneous entry. The analyst
shall then date and initial the correction.
1.4 In situations where legible corrected entries are not
feasible, the correction shall be written in the closest
available space where legible entries could be made. The
analyst shall initial and date both the deletion and the
correction entry.
2.0 Data validation
2.1 If the raw data is manually processed, all steps in the
computation shall be provided including equations used,
response factors, calibration constants, dilution factors,
etc.
KMUI Gb> PKHM
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• SMCIAITY MATItlALS DIVISION lAOLI-PICMII tlSIAKH LABORATORY
ALSOP-19
Revision: 0
Date: 6-13-86
Page 2 of 2
2.2 All manual calculations must be checked by another analyst.Any
changes made by the checker shall be rechecked by the
originator, and agreement must be reached before the result is
released.
2.3 If the raw data was input to a computer to manipulate the raw
data, all input entries must be verified by a checker.
2.4 If the raw data is acquired and processed by the instrument,
then the analyst shall verify that the following are correct.
project and sample numbers
calibration constants, response factors, dilution
factors
units
detection limits
3.0 All validated data must be provided to the Group Leader for review
and signature.
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• SPICIAITY MATI0IAU DIVISION •
• lAOU.HCHIi IISIAKH IABOIATOIY
ALSOP-20
Revision: 0
Date: 6-13-86
Page 1 of 2
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Sample
Analysis and Tracking
Initiated By:
Larry Zinn
Approvals:
By:
Quality Assurance Dept.
By:
EPRL Analytical director
1.0 The sample analysis and tracking SOP monitors and documents the
state of analysis of the sample.
2.0 The analyst must document any analytical procedure performed on the
sample.
3.0 When a sample is received, a copy of the sample log-in sheet will be
provided to the appropriate group leader (i.e., General Chemistry,
Metals, GC, GC/MS) depending on the type of analysis requested.
4.0 The group leader will determine the method to be used for analysis,
and the appropriate personnel within the group will be assigned the
task of analysis. If extractions of the samples are involved, the
individual groups will perform the extractions.
5.0 The samples and extracts must be followed by chain-of-custody forms
and/or sample preparation work-sheets within a laboratory. All
documentation (i.e. chain-of-custody forms, sample preparation
worksheets, logbooks, etc.) must be submitted to the Group Leader
for review and subsequent reference in project/case files.
6.0 All sample extracts not scheduled for analysis must be properly
sealed and refrigerated in a designated refrigerator by the Group
Leader. The temperature of this refrigerator must be maintained
between 1 degree C and 7 degrees C at all times.
EAOLXlf->PKHKIt
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> SPf CIAITY MATMIAIS DIVISION
• tAOLI-PICHirtfSIAKH lASOIATOIT
ALSOP-20
Revision: 0
Date: 6-13-86
Page 2 of 2
ft
i.
I
7.0 Sample extracts may be removed from the refrigerator only when the
extracts are scheduled for analysis. Each time the extract is
removed or returned to the refrigerator, the chain-of-custody form
(if necessary) must be appropriately completed.
8.0 Sequence of standards and samples analyzed will be dictated by the
method used.
9.0 Each analysis (standard or sample) must be recorded in the
instrument logbook. If an autosampler is used, the tray number and
position should be recorded in the logbook.
10.0 Hard copies of all data printed out must be labeled appropriately
identifying sample number, standard, conceantration of standard,
etc.
11.0 The data is now entered by the analyst onto check sheets and all
the necessary calculations performed. This data must be verified by
another analyst (See Data Recording SOP).
12.0 The remaining extracts will be placed in sealed vials and stored for
a period of three months, or for a longer period at the request of
the client.
•CAQLE
>PKHCM
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> S»fCIAITY MATIIIALS DIVISION •
• lAGll.PICHII IISIAtCH IASOIATO«T
ALSOP-21
Revision: 0
Date: 6-13-86
Page 1 of 4
EAGLE-PICKER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Standards
Preparation and
Tracking System
Initiated By:
Larry Zinn
Quality Assurance Dept.
BY;
EPRL'AnaWticalyO
irector
1.0 Preparation of standards for calibration must be made from pure
materials (of known purity, 98% or better preferred) or from
purchased concentrates certified by NBS, EPA, or other acceptable
• agencies.
2.0 Standards for Analysis
2.1 Solvents used for preparation of standards must be checked for
purity before standard preparation.
2.1.1 If the solvents purchased are of pesticide grade and
distilled in glass a check for purity is not necessary,
but is recommended.
2.1.2 If the solvents purchased are of pesticide grade each
lot must be checked for impurities by a GC/ECD or GC/FID
method. Approximately 300ml of the solvent of one lot
is concentrated using a specially cleaned Kuderna-Danish
Flask to 5ml. Inject 5uL of the concentrate. If peaks
occur at the same retention times as the analyses of
interest at greater than 5% f.s.d., then the solvent may
be contaminated and may cause identification and
quantitation problems. These solvents may have to be
distilled in glass before use.
>PKHCR
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• SMCIALTY MATItlALS OIVISK
lAOLI^ICHII nSIAKH LABOIATOIT
ALSOP-21
Revision: 0
Date: 6-13-86
Page 2 of 4
2.1.3 Under no circumstance should solvents of lesser quality
than pesticide grade be used to prepare standards for
analysis by GC, GC/MS, or HPLC.
2.1.4 Freon used for preparation of standards and extraction
of samples for oil and grease content shall be distilled
prior to use.
2.1.5 All standards, reagents, and solvents used for trace
metal analysis must be spectro-quality.
2.2 Preparation of Standards
2.2.1 Stock standards (approximately 100 ppm) may be prepared
or purchased and stored at -10 degrees C to -15 degrees
C for a period of six months. Fresh stock standards
must be prepared or purchased every six months. Upon
preparation of the standard, the following items must be
recorded on the bottle containing the standard.
date prepared
initials of the analyst preparing the standard
a unique identification number for the standard
an expiration date.
All other information regarding the standard including
solvent used, lot number (s) of solvent use, the analyte
source, purity and lot number, concentration analyst's
initials and date prepared must be entered in the log
book. A format similar to Form 1 and 2 could be used.,
All standard preparations must be verified by a senior
chemist or group leader prior to use.
2.2.2 Preparation of intermediate standard solutions is
strongly recommended for all analysis.
2.2.3 Working Standards
2.2.3.1
2.2.3.2
Working standards includes calibration
standards, spiking solutions of analytes,
surrogates, etc., and must be stored at -10
degrees C to -15 degrees C when not is use.
Working standards for the analysis of
volatile organic constituents must be
prepared at least once in two weeks.
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SMCIALTY MATERIALS DIVISION — lAOU.FICMII tlSIAKM LABOtATOIT
ALSOP-21
Revision: 0
Date: 6-13-86
Page 3 of 4
2.2.3.3 Working standards for the analysis of semi-
volatile organic constituents and pesticides
must be prepared at least one in two weeks.
2.2.3.4 Working standards for trace metal analysis,
except for mercury, should be prepared at
least once a month, working standards foe
meracury must be made up daily.
2.2.3.5 Working standards for oil and grease and
sulfate, must be prepared at least once a
month. Standards made for the ion-
chromatograph must be prepared at least once
a week and all other standards must be
prepared immediately prior to analysis of
samples.
2.2.4 A Laboratory Calibration Standard (LCS) must be prepared
from a source other than the stock standard. The
concentration of the LCS must be verified using a
certified standard. LCS must be prepared by a senior
chemist or group leader at least once a month and be
stored at -10 degrees C to -IS degrees C when not in
use.
2.3 verification of Standards
2.3.1 All standards upon preparation must be analyzed by GC or
GC/MS and the response compared to the most recent
standard respnse.
2.3.2 All new standard analyses must be maintained in a file
in the individual groups and copies of the responses
must be submitted to the QC Coordinator.
2.3.3 LCS and working standard responses will be entered into
the computer and upper and lower control limits will be
established by the QC Coordinator. Until control charts
are developed, the response for the new standards will
not vary by more than ±20% of the response of the most
recent standard.
••AOLll
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• SPf CIALTY MATHIAU OM1ION —————————-—- IAOII-HCMM IISIAtCH LABOIATOIY
ALSOP-21
Revision: 0
Date: 6-13-86
Page 4 of 4
2.3.4 LCS analysis data will be entered into the computer and
95% and 99% confidence limits will be established. The
99% confidence interval for the LCS must not exceed a
+10% interval from the theoretical concentration of the
LCS. The QC Coordinator must be informed immediately if
such a variance occurs.
2.4 Tracking of Standards
2.4.1 The identification of each standard prepared must be
unique and all documents related to sample analysis in
which the standard was used must contain this unique
identification. The document should be such that all of
the standard information could be traced from the raw
data for the sample.
2.5 Storage of Standards
2.5.1 Temperature requirements for storage of standards are
described above.
2.5.2 Standards must be stored in separate refrigerated areas
to samples and extracts.
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> SFICIALTT MATIRIALS QIVISION •
.PlCHI• tlSIARCH LASOKATOIY
ALSOP-23
Revision: 0
Date: 6-13-86
Page 1 of 2
EAGLE-PZCHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Calibration
of Measuring
Equipment
Initiated By:
Larry Zinn
Approvals:
By;
Quality Assurance Dept.
EPRL Analytical Director
1.0 Volumetric Glassware
1.1 All volumetric glassware purchased must conform to NBS Class A
standards.
1.2 All mechanical pipets must be calibrated once a month by
taking an aliquot of deionized water and weighing the volume
delivered by the pipette.
1.3 Any graduated glassware used for measuring final volumes of
extracts in the GC or GC/MS areas (e.g. Kudena Danish
concentrator tubes) must be calibrated once a month using the
above technique. The calibrations must be performed at
volumes used in the methods listed.
1.4 All calibrations performed must be recorded in appropriate
notebooks.
2.0 Balance Calibrations
2.1 All balances must be serviced by an external certified service
engineer at least annually. The records of such maintenance
is maintained in appropriate files.
•EAOLI
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• snOAirr MATUIAU OIVISM
• lAOU-FICHirUSI AICM LAtOI ATOtT -
ALSOP-22
Revision: 0
Date: 6-13-86
Page 1 of 1
EAGLE-PICHER RESEARCH LABORATORY
ANALYTICAL DIVISION
STANDARD OPERATING PROCEDURES MANUAL
Subject: Equipment
Maintenance
Initiated By:
Larry 2inn
Approvals:
Quality Assurance Dept.
EPRL~Anal/t
rector
1.0 Routine maintenance and frequency of such maintenance of major
instrumentation are covered in this Standard Operating Procedure,
2.0 Gas Chromatograph Maintenance
• ^^^^H••»
2.1 All routine maintenance to be performed as recommended by the
manufacturer.
3.0 Gas Chromatograph - Mass Spectrometer Maintenance
3.1 All routine maintenance to be performed as recommended by the
manufacturer.
4.0 Atomic Absorption and Inductively Couple Plasma Spectrophotometer
Maintenance
4.1 All routine maintenance to be performed as recommended by the
manufacturer.
5.0 Ion Chromotograph
5.1 All routine maintenance to be performed as recommended by the
manufacturer.
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> SPtCIAlTT MATIIIALS DIVISION •
Name
Larry L. Zinn
Education
• IAOLI-PICHH IISIAKH IASOIATOIT
Program Responsibility
Director of Analytical and
Environmental Services
Dr. Zinn received his B.S. degree from Oklahoma State University in
Aquatic Zoology in 1974. He continued at Oklahoma State receiving
an M.S. from the Department of Natural Sciences in Analytical
Toxicology and finally a Ph.D. in Toxicology from the Department of
Physiological Sciences in 1982. Dr. Zinn's research interests
centered around the effects of toxicants on osmoregulation in
respiratory tissues of aquatic organisms. This research included
the design and construction of specialized apparatus including
voltage clamp and microelectrode circuitry.
Related Experience
Since 1974 Dr. Zinn has been involved with instrumental analysis of
trace contaminants. His experience includes the analysis of
environmental and industrial samples for both organic and inorganic
constituents. He has supervised or directed analytical laboratories
in academic/ commercial, and industrial environments. He has
developed and implemented laboratory quality control/quality
assurance programs to comply with the strictest of standards.
In recent years Dr. Zinn has consulted for private industry,
commercial laboratories, and state agencies involved with
environmental monitoring and analytical toxicology projects. He has
served as an expert witness in environmental toxicology litigation.
As Director of Analytical and Environmental Services, Dr. Zinn
oversees the operation of a laboratory responsible for corporate
analytical support, contract analytical research, and analysis of
environmental contaminants under contract and commercially. He also
coordinates technical consulting for potential environmental
problems. He supervises a vigorous research effort in methods
development and instrumental analysis.
Technical Experience
Gas-Liquid Chromatography — 10 years experience in the theory and
operation of GLC. Familiarity with Perkin-Elmer, Hewlett-Packard,
and Tracer .Instruments. Used in the analysis of environmental and
tissue samples for pesticides, drugs, petroleum hydrocarbons and
other organic compounds.
f-)PKHCIt-
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• tnOALTT MATMIAIS DIVISION — lAOU-PtCMII fttMAKM lAtOIATOIV
ALSOP-23
Revision: 0
Date: 6-13-86
Page 2 of 2
2.2 Prior to any weighing, the balances are calibrated using
class S weights. All such calibrations must be maintained
with calibration records for the balance.
2.3 Any deviations from the nominal values of the weights are
brought to the attention of the QC Coordinator and the Section
Manager.
3.0 Thermometer Calibrations
3.1 All thermometers must be calibrated at least once a year using
an NBS certified thermometer.
3.2 All calibrations must be recorded in appropriate notebooks.
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> SPfCIAlTY MATIIIALS DIVISION -
Larry L. Zinn
Professional Affiliations
• IAOU FICHU tISIAKH LABOIATOIT
Page 3
Society of Environmental Toxicology and Chemistry
American Chemical Society
American Association for the Advancement of Science
Publications
Masters Research - "The Relationship of Dose to Tissue Residue Level
of Toxaphene in the Female Laboratory Rat." 1978*
"A Rapid Qualitative Method for the Determination of Petroleum
Hydrocarbons in Animal Tissue". Bulletin of Environmental
Contaminants and Toxicology. Vol. 22; 285-286. 1979*
"Petroleum Toxicity in Domestic Animals". Veterinary and Human
Toxicology. Vol. 21-5; 328-337. 1979
"Diagnosis of Petroleum Hydrocarbon Poisoning in Cattle".
Veterinary Medicine/ SAC. 1514-1518 Oct. 1979.
"Toxicity of Blue-Green Algae in Livestock". Bovine Practitioner,
No. 14; 151-153. 1979*
Ph.D. Dissertation - "The Effects of Cadmium and Naphtalene on
osmoregulatory Transpota in the Opercular Epithelium of the Channel
Catfish, Ictalurus punctatus", 1982*
"A Light and Electron Microscopic Study of White Blood Cells in
Channel Catfish, Ictalurus punctatus." 1982. Zentralblatt fur
Veterinarmedizin, Reihec, Anatomia, Histologia, Embryologia, vo. 11;
107-116.
• "A Study of Hematologic Profiles of Channel Catfish, Ictalurus
punctatus". 1982. Journal of Fish Biology. Vol. 21; 305-309.
*Principle Author
Solicited Presentations
"An Electrophysiological Method for Determining Sublethal Effects of
Toxicants on the Channel Catfish". Presented to the Oklahoma
Academy of Sciences on Nov. 13, 1981 on the campus of Phillips
University, Enid, Oklahoma.
"The Opercular Epithelium as a Model for the Effects of Toxicants on
the Teleost Gill". Presented to the Society of Environmental
Toxicology and Chemistry at their annual meeting on Nov. 22-25, 1981
in Arlington, Virginia.
EAQII
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• SMCIALTT MATIIIAIS DIVISION
Larry L. Zinn
Technical Experience continued
• IAOU.MCMH MSIAKM LABOIATOIT
Page 2
Atomic Absorption Spectrophotometry — 9 years experience in the
theory and operation of AA spectrophotometers (Perkin-Elmer). Used
in the analysis of environmental and animal tissue samples for heavy
metals and normal blood cations.
Ultraviolet-Visible Spectrophotometry — 8 years experience in the
use of UV-Vis instrumentation as a method for the measurement of
drugs and normal metabolite assays in biological samples.
GC-Mass Spectrometry — Basic familiarity with Hewlett-Packard GC-
Mass Spec, instrumentation and its use to separate and identify
complex organic mixtures in industrial effluent.
Electrode systems — 10 years experience with both glass and gel
electrodes, both referenced and combination used in the measurement
of pH and other ion strength in both water and biological fluids.
Familiar with Corning, Fisher, Orion, Cole-Palmer systems and
products.
Electron Microscopy — 3 years experience with sampling techniques
and sample preparation of tissue samples for the electron microscope
and the evaluation of electron micrographs of tissues exposed to
toxic compounds.
Positions Held
'Jan. 1986 - Present - Director of Analytical and Environmental
Services - Eagle-Picher Research Labs.
June 1985 - Jan. 1986 - Director, National Analytical Laboratories
Tulsa, Ok.
Mar. 1985 - June 1985 - Associate Director, National Analytical
Laboratories - Tulsa, Ok.
Sept. 1984 - Mar. 1985- Laboratory Supervisor, National Analytical
Labs - Tulsa, Ok.
Aug. 1982 - Sept. 1984- Environmental Toxicology Consultant.
Oct. 1979 - Aug. 1982 - Graduate Research Assistant, Dept. of
Physiological Sciences - Oklahoma State
University, Stillwater, Oklahoma.
Feb. 1977 - Oct. 1979 - Analytical Toxicologist. Oklahoma Animal
Disease Diagnostic Lab, Stillwater, Ok.
>PKHKM
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• SNCIALTY MATIIIALS DIVISION '
K. S. Kumar
Technical Experience continued
.PICMH RISIAKH LAtOtATOIT
Page 2
Gas Liquid Chromatography—6 years experience in the theory and use
of gas liquid chromatographs. Familiar with Varian, Perkin-Elmer,
Hewlett Packard, and Tracer *nstruments. used the gas
chromatographs in the analysis of environmental samples for
pesticides, petroleum hydrocarbons, and organic constituents in the
hazardous substance and Appendix VIII lists. Familiar with EC, FP,
FI, PI, NP and Hall detectors.
Gas Chromatography-Mass Spectrometry—7 years experience in the
theory and use of GC-Mass Spectrometers. Familiar with Hewlett
Packard and Finnigan GC-MS instrumentation and their use in trace
analysis of organic constituents in environmental samples.
Positions Held
March 1986 - present -
Group Leader Eagle-Picher
Industries/Miami,Ok
Septemberl985-February 1986- Technical Director,IT
Corporation,Pittsburgh,Pa
September1984-August 1985-
October 1983-August1984-
March 1983-Septemberl983-
June 1981-February 1983-
February 1979-Hay 1981-
january 1976-May 1979
July 1974-December 1975-
May 1972-June 1974
Technical Support Supervisor,Lockheed
EMSCo,Las Vegas,Nv
Senior Scientist,Lockheed EMSCo,Las
Vegas,Nv
Chemist II Envirodyne
Engineers,Inc.,St.Louis,Mo
Chemist,US Pollution Control
Inc.,Tulsa,Ok
Research and Development Chemist,Brod-
Dugan Company,St.Louis,MO
Graduate student,Washington
University,St.Louis,Mo
Quality Contol
Chemist,Glaxo,Colombo,Ceylon
Research Assistant,Universuty of
Ceylon,Colombo,Ceylon
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SPfOAITT MATniALS DIVISION <
• lAOlLPtCHIt HSIAKM lASOIATOftT
Program Responsibility
Group Leader
Chemist
Education
Mr.Kumar has received a B.Sc. degree from the University of Ceylon,
Colombo in 1972 and an M.S. degree in Chemistry from Washington
University in 1979. Mr.Kumar's background includes synthetic
Organic Chemistry and Analytical Chemistry.
Related Experience
Since 1972 Mr. Kumar has been involved with the analysis of trace
organic and inorganic constituents in a variety of matrices. He has
performed and later supervised the performance of various testing
protocols including classical wet chemical techniques for phenols,
cyanides, chlorides, bromides, sulfates, nitrates, phosphates and
more sophisticated techniques such as gas chromatography, gas
chromatography-mass spectrometry, infrared and ultraviolet-visible
spectrophotometry, ion chromatography/ and atomic absorption
spectroscopy.
Mr. Kumar has been involved with the monitoring of laboratories in
the CERCLA (superfund) Contract Laboratory Program for contractual
compliance with quality assurance criteria. Mr. Kumar has also been
involved in the development of methods for the analysis of RCRA
Appendix VTII constituents and directly participated in the method
validation study for the Toxicity Leachate Characteristic Program.
As a group leader of the GC and GC/MS laboratories, Mr. Kumar is
directly responsible for the extraction and analysis of constituents
amenable to such techniques, and for the development and maintenance
of quality assurance programs for these laboratories.
Technical Experience
Infra-red Spectrometry—1 year experience in the use of infrared
spectrophotometers for oil and grease and total petroleum
hydrocarbon analyses.
Ultraviolet-visible spectrophotometry--2 years experience in the use
of UV-Visible spectrophotometric instrumentation for total phenols,
cyanides, and nitrates and for the detection, quantitation, and
quality assurance of manufactured drugs in the pharmaceutical
industry.
Atomic Absorption Spectrophotometry—1 year experience in the use of
atomic absorption spectrophotometers (Perkin-Elmer) in the analysis
of environmental samples for metals on the hazardous substances
list.
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> SPICIALTY MATIIIAIS DIVISION •
> lAOLI.PICMirtf SIARCH LASOIATOIY
Program Responsibility
Group Leader
Chemist
Education
Mr. Laing received a B.S. in Chemistry and Biology fro*i Oral Roberts
University, Tulsa, Oklahoma, 1978.
Directly Related Experience
This
Mr. Laing has been involved in analytical testing since 1976.
has included development of sampling plans, wet chemical and
instrumental analysis of environmental and industrial samples for
inorganic and organic constituents, and methods development for
analysis of high purity materials for trace constituents.
As Group Leader of the Inorganic Environmental Instrumentation
Group, Mr. Laing directs day to day operations to insure that
projects are completed in a timely fashion while adhering to the
quality control policies of the laboratory. He also has direct
responsibilty for developing methods of analysis for a variety of
sample matrices to be analyzed by Inductively Coupled Plasma/Mass
Spectrometry. These include trace metal analysis of environmental
and high purity materials.
General Experience
In the course of his work Mr. Laing has performed methods
development for multi-element analysis on many different sample
types by Inductively Coupled Plasma / Atomic Emission Spectroscopy
and Graphite Furnace Atomic Absorption Spectroscopy. This work
included extensive experience with the trace element analysis of
environmental samples to determine if safety and compliance
requirements were met, of geological samples to be used in
commercial feasibility studies at mining operations, of oils and
feedstocks to determine product purity, and of high purity materials
to locate contamination sources. In addition to this work he has
also operated a Gas Chromatograph/ Quadrupole Mass Spectrometer for
the analysis of water, wastewater, and solid waste for compliance
with CERCLA and RCRA regulations in environmental samples.
1LM
)PKHCR
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> SPfCIALTY MATMIALS DIVISION •
• lAOtl.PICMM IrtSIAKH LA>OtATO0T •
I,
'*
K. S. Kumar Page 3
Professional Affiliations
American Chemical Society
American Association for the Advancement of Science
American Society for Mass Spectrometry
Presentations
"Analysis of Organic Aerosols" Presented at the National Bureau of
Standards, 1978
" Quality Assurance Criteria for Dioxin Anaysis" Eastern Anaytical
Symposium,1984
"Dioxin Laboratory Performance" Fifth Annual Contract Laboratory
Program Conference,1985
>PKHCft
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• lAOll-PICHII klUAKM LABORATORY
Page 3
• SPICIALTY MATIRIALS DIVISION •
Guy A. Laing
Professional Affiliations
American Chemical Society
Canadian Spectroscopy Society
Solicited Presentations
"The Potential of Inductively Coupled Plasma/ Mass Spectroscopy as
an Analytical Tool in the Contract Laboratory Program". Presented
to the Contract Laboratory Program Inorganics Caucus of the U.S.
Environmental Protection Agency at their biannual meeting on Oct. 22-
24, 1985 in Oakland, California.
"An Update on Inductively Couple Plasma/ Mass Spectroscopy as an
Analytical Tool in the Contract Laboratory Program". Presented to
the Contract Laboratory Program Inorganics Caucus of the U.S.
Environmental Protection Agency at their biannual meeting on April
21-23, 1986 in Kansas City, Missouri.
•EAO1C
>PKHCJt
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> mdALTT MATIIIAU DIVISION •
Guy A. Laing
Technical Experience
• IAOU.MCMII IISIAKH lASOIATOVT
Page 2
Inductively Coupled Plasma/Mass Spectroscopy — 2 years experience
developing methods for the trace analysis of ultra high purity
materials and environmental samples (Sciex).
Inductively Coupled Plasma/Atomic Emmision Spectroscopy — 3 years
experience in ICP/AES theory, analysis, and methods development for
environmental and industial samples (Perkin-Elmer).
Atomic Absorption Spectroscopy — 5 years experience in the theory
and operation of flame and graphite furnace AA spectrophotometers
(Perkin-Elmer). Used in the analysis of on stream processes,
environmental, high purity materials, industrial , and blood
samples.
Gas Chromatograph/Mass Spectrometry — 2 years experience in the
theory and operation of GC/MS instrumentation (Pinnigan) for the
analysis of environmental samples for the priority pollutants.
Positions Held
Jan. 1986 - Present - Group Leader of Environmental
Instrumentation Group - Eagle-Picher
Research Laboratories
Nov. 1984 - Jan. 1986 - Project Chemist - Eagle-Picher
Research Laboratories
Dec. 1983 - Nov. 1984 - Laboratory Supervisor - National
Analytical Laboratory, Tulsa, Ok.
Mar. 1983 - Dec. 1983 - Chemist - National Analytical
Laboratory, Tulsa, Ok.
Sept. 1980 - Jan. 1983- Chemist - Dowell, Division of Dow
Chemical Company, Tulsa, Ok.
Mar. 1976 - Sept. 1980- Biololgist and Chemist - Clean-Flo
Laboratories, Hopkins, Mn.
>PKHVt
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SMCIALTT MATHIAIS DIVISION
• IAOLI.FICMH IISIAKH LAIOtATOIT
Mark A. Thompson
General Experience
Page 2
Mr. Thompson recently investigated a possible lithium isotope
separation method using a chromatographic technique and proprietary
column packings. He also was consulted by a sister division of
Eagle-Picher concerning problems in the production of a fast
activating primary battery.
As leader of the battery chemicals group he was responsible for the
production of battery quality lithium sulfide and electrolyte
solvents, both on a large laboratory scale. Mr. Thompson directed
the startup of lithium/metal alloy production and supervised this
project as it grew to the pilot scale. The alloys produced are
Li/B, Li/Al, and Li/Si/ the latter two being used as battery anode
materials. He was also responsible at this sane time for the
• production of the following for sales; lithium-7 hydroxide, high
purity boron tribromide, boric acid, and the complex boron <
trifluoride-calcium fluoride (the last two being enriched or
depleted in boron-10).
Since joining Eagle-Picher, Mr. Thompson has tested the corrosion
resistance of various metals, plastics, and coatings to bromine and
boron tribromide. He has also investigated a new method for
preparing doped lanthanum chromites, synthesized the II-VT compound
cadmium selenide, and developed a method to make lithium
fluoroborate for specialty batteries.
As*an undergraduate Mr. Thompson spent a semester at Argonne
National Laboratory studying the solution kinetics of aqueous
neptunium. He has experience in synthesizing, handling, and .»
characterizing air and moisture sensitive transition metal
compounds.
Professional Affiliation*
American Chemical Society, Chairman, Southeast Kansas Section
1983
Phi Beta Kappa
Publications
Mark A. Thompson, J.C. Sullivan, and Edward Deutsch, "Oxidation of
Mercury(I) by Neptunium(VII)", J. Amer. Chem. See., 93,
5667(1971).
EAOIC
1P1CHCA
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> SPfClAlTY MATItlAll DIVISION •
• lAOU.FICMIt 0IUAKM LAtOtATOIY
Name
Mark A. Thompson
Program Responsibility
Chemist
•;i
<»
*/
|
Education
Mr. Thompson received a B.A. degree (sunma cum laude) in
chemistry from Cornell College in 1971. Be received an M.S.
degree in inorganic chemistry from Northwestern University in
1975.
Technical Experience
Liquid Chromatography - 1 year experience in operation of an HPLC.
Familiarity with Varian 5500 instrument. Basic familiarity with a
Haters ILC-1 ion chromatograph.
Inert Atmosphere Equipment - 4 years experience in theory and
operation of glove boxes. Familiarity with Vacuum Atmospheres inert
gas purification and monitoring eqipment. Familiarity with Schlenck
ware techniques and vacuum distillation.
Safety and Compliance - 2 years experience in DOT and IATA
compliance for shipment of hazardous materials by air and motor
freight. Basic familiarity with OSHA, EPA, and Oklahoma regulations
for industrial safety and hazardous materials.
Positions, Held
1986-Present - Chemist, Analytical Services Group and
Plant safety Officer
Eagle-Picher Research Lab, Miami, OK
1985-1986 - Research Chemist, Miami Research Lab, Eagle-Picher
Industries, Miami, OK
1980-1985 - Group Leader, Battery Chemicals, Miami Research Lab
1976-1980 - Research Chemist, Miami Research Lab
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> SMCIAITY MATIIIAIS DIVISION •
IAOlf .FICHU fttSIAKH LABOIATOIT
Robert Perrin
Positions Held
Page 2
Jan. 1986 - Present - Senior Chemist - Eagle-Picher Research
Laboratories
Nov. 1974 - Jan. 1986 - Chemist - Eagle-Picher Research
Laboratories
May 1968 - Nov. 1974 - Chemical Technician and Field Inspector
Bruce Williams Laboratories, Joplin,
Missouri
Professional Affiliations
American Chemical Society
-tMUlUDPKHKft-
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SMC1ALTY MATItlAlS DIVISION 1
Program Responsibility
Senior Chemist
Education
Mr. Perrin recieved a B.S. in Chemistry from Missouri Southern State
College, Joplin, Missouri in 1972.
Directly Related Experience
Mr. Perrin has been involved in instrumental, wet inorganic chemical
and physical testing in analytical chemistry since 1968. This work
has involved the development, implementation, and testing of sampling
plans, environmental testing, and the assay and analysis of high
purity materials.
As the senior chemist in the inorganic Instrumentation Group, Mr.
Perrin has direct responsibility for the instrumental analysis of
environmental samples for trace constituents. He also has extensive
experience in the analysis of high purity materials for trace
constituents.
Technical Experience
Atomic Absorption Spectroscopy — 14 years experience in the theory
and operation of flame and graphite furnace AA spectrophotometers
(Perkin-Elmer). Used in the analysis of on-streao processes, ores,
environmental, high purity materials, industrial , and blood samples.
Inductively Coupled Plasma/Atomic Emmision Spectroscopy — 1 year
. experience in XCP./AES .theory., .analysis, and methods development for
environmental and industial samples (Perkin-Elmer).
Elemental Analyzers — 10 years experience in the theory and operation
of nitrogen, oxygen, and total carbon analyzers (Leco). Used for the
characterization of high purity materials for Department of Energy
specifications.
Infrared Spectrometers — 1 year experience in the theory and
operation of infrared spectrometers(Perkin-Elmer). Used for analysis
of environmental, and forensic samples.
Gas Chromatography — 1 year experience in the analysis of
environmental and forensic samples (Perkin-Elmer).
DC arc emmision spectrographs — 1 year experience in the analysis of
forensic samples.
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SPICIAITY MATUIALS DIVISION <
Name
David A. Lovelace
Education
• IAGll.PICHIt ItSIAKH lA»O«ATOtY
Program Responsisbility
Analyst
Mr. Lovelace received an A. S. degree from Northeastern Oklahoma A&M
College in 1975. He continued his study of Physical Geaography at
Oklahoma State University from 1975 until 1977. Since 1984, Mr.
Lovelace has been pursuing a B.S. degree in Chemistry from
Northeastern Oklahoma A&M College and Pittsburg State University.
Related Experience
Since 1977 Mr. Lovelace has performed a wide range of analytical and
environmental work involving the physical and chemical analysis of
water, wastewater, coal, coke, soils, and aggregates.
He has worked as an environmental specialist and consultant, as well
as a field investigator for a private environmental engineering
firm. Mr. Lovelace has compiled numerous environmental reports and
permit applications for clients in the mining and petroleum
industries.
As an analyst for Eagle-Picher Research Laboroatories, Mr. Lovelace
has been extensively involved in the testing of water quality and
sample preparation of assorted sample types for trace elements in
such materials as water, soil, high purity quartz. Indium Phosphide,
Gallium, and Germanium compounds.
Technical Experience
Gas Chromatography — 4 years experience in the theory ond operation
of Gas Chromatographs. Used in the detection of trace impurities in
high purity gases.
Atomic Absorption Spectroseopy — 1 year experience in the theory
and operation of cold vapor spectrophotometers for the analysis of
environmental samples for mercury.
Gravimetric Analysis ~ 4 years experience in utilizing ASTM methods
for the analysis of coal and coal ash.
Positions Held
July 1981 - Present
June 1980
Laboratory Technician - Eagle-Picher
Research Laboratories
July 1981 Environmental Specialist - Poe
Environmental Technology & Resource
Associates, Inc. - Tulsa, Ok.
July 1977 - June 1980
EAQIX
Technical Support Director - Russel
Creek Coal Company - DAIlas, Texas
>PKHER
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• SPICIAITY MATHIALS DIVISION <
• IAOLI-FICMII IISIAftCH LASOIATOtT
Program Responsibility
Group Leader/ Chemist
Mr. Riley received a B.S. degree in Chemistry with a Mathematic
Minor in 1951 from Pittsburg State University at Pittsburg, Kansas.
Directly Related Experience
Mr. Riley has considerable experience in assembling, and operating
vacuum distillation equipment along with the development of the
distillation procedures. He has also participated in the
construction of equipment for controlled atmosphere synthesis of
lithium alloys. This includes equipment placement, procedure check-
out, and installation of an automatically controlled, inert
atmosphere glove box.
Currently Mr. Riley is group leader of the analytical support group
of EPRL and is responsible for the classical process and quality
control work for corporate and industrial client*1.
General Experience
Prior to joining Eagle-Picher, Mr. Riley has had several years
experience in engineering and management of agricultural products
plants such as dehydrated molasses, expanded dog food, protein and
mineral products; with the supervision of appropriate laboratory
facilities.
>PKHKR
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APPENDIX B
ARI ENVIRONMENTAL
REPORT NO. 475-01
EMISSIONS SAMPLING REPORT
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SHIRCO INFRARED SYSTEMS MOBILE INCINERATOR
TRIAL BURN EMISSION TEST PROGRAM
AFTERBURNER EXHAUST SCRUBBER INLET DUCT
AND SCRUBBER EXHAUST STACK
BRIO REFINING COMPANY
FRIENDSWOOD, TEXAS
ARI PROJECT NO. 475-01
EAGLE-PICHER P.O. NO. 14084
REPORT PREPARED FOR:
EAGLE-PICHER INDUSTRIES, INC.
200 9TH. AVENUE N.E.
MIAMI, OKLAHOMA 74354
REPORT PREPARED BY:
ARI ENVIRONMENTAL, INC.
600 N. FIRST BANK DRIVE
PALATINE, ILLINOIS 60067
(312) 359-7810
FEBRUARY 10-13, 1987 TEST SERIES
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SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
I. INTRODUCTION AND SUMMARY
ARI Environmental, Inc. was retained by Eagle-Picher Industries,
Inc., to provide stack sampling services on the Shirco Infrared
Systems Mobile Incinerator at the Brio Refining site in Friends-
wood, Texas.
The purpose of this test was to determine the POHC destruction
removal efficiency (DRE) of this incinerator for a variety of POHC
waste feeds for assessing degree of compliance of this unit with
Federal EPA trial burn emission regulations for hazardous waste
incinerators.
Test methods followed those as detailed in the Federal Reg-
ister Volume 46, No. 15, January 23, 1981, the Code of Federal
Regulations. Volume 40, Part 60, 1986, and the Texas Air Control
Board Sampling and Laboratory Procedures Manual.
ARI conducted simultaneous sampling at the secondary chamber
exhaust scrubber inlet duct location and on the scrubber exhaust
stack. Sampling at the scrubber inlet duct was conducted for
particulates and POHC using a Modified Method 5 sampling train.
CO, NO , CO-, and O- were also continuously monitored at this
location during each sampling run. Sampling on the scrubber ex-
haust stack was conducted for particulates and POHC using a Modi-
"ied Method 5 sampling train, and for SO. and SO. following TACB
Method 29 (Modified EPA Method 8). Eagle-Picher also conducted
concurrent POHC sampling on the scrubber exhaust stack using the
VOST train.
Sampling was conducted from February 10-13, 1987 by Messrs.
H. M. Taylor, J. Thomas and L. Goldfine of ARI Environmental, Inc.
A total of eight runs were performed. Also present during the
test series to oversee the testing and sample recovery was
Mr. John Snodgrass of Eagle-Picher Industries. Mr. Kenneth J.
Johansen, P.E., of Shirco Infrared Systems, Inc. supervised incin-
erator operations during the test program.
All POHC, HCL and probe wash particulate samples were surren-
dered to Mr. John Snodgrass of Eagle-Picher at the test site for
subsequent analyses by Eagle-Picher's laboratory. The particu-
late filter samples were sent to Eagle-Picher after final weigh-
ing at ARI's laboratory.
This report summarizes the test procedures conducted by ARI
Environmental, Inc. at the scrubber inlet and scrubber outlet
locations and reports the results of the particulate, CO and NO
emission testing. All POHC and HCL test results will be submitted
in a separate report by Eagle-Picher Industries.
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SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
TABLE OF CONTENTS
I. INTRODUCTION
II. TESTING AND ANALYTICAL PROCEDURES
III. TEST RESULTS
APPENDICES
A - Secondary Chamber Exhaust Scrubber Inlet Duct
Field Data and Summary Calculation Data
Sheets
B - Secondary Chamber Exhaust Scrubber Inlet Duct
CEM Field Data, Summary Calculation
Data, Calibration Data and Strip
Chart Data
C - Scrubber Exhaust Stack
Particulate and Sulfur Oxides Field
Data and Calculation Summary Data Sheets
D - Test Equipment Calibration Data
Sheets
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The results of the particulate, CO, NO and SO emission
r testing are briefly summarized below:
* RUN NO.: 12 345678
p TEST DATE: 2-10 2-11 2-11 2-11 2-12 2-12 2-13 2-
SCRUBBER INLET
r
i Particulate
Concentration
gr/dscf (corr. to 7Z 02) - 0.012 0.007 0.013 0.004 0.003 0.005 0.0
Emission rate
Ib/hr • 0.006 0.005 0.008 0.002 0.001 0.002 0.0
' Carbon Monoxide (CO)
Emission rate
p Ib/hr 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0
'Nitrogen Oxide (as (NO)
E Emission rate
Ib/hr 0.022 0.021 0.025 0.026 0.027 0.025 0.30 0.0
SCRUBBER EXHAUST
r Particulate
5 Concentration
gr/dscf (corr. to 7Z 0£) 0.015 0.022 0.027 0.034 0.007 0.006 0.018 O.C
Emission rate
Ib/hr 0.011 0.018 0.023 0.023 0.004 0.004 0.010 O.C
Sulfur Dioxide SO.J
Emission rate
Ib/hr 0.338 0.195 0.109 0.055 0.007 0.001 0.004 0.1
Sulfur Trioxide
Emission rate
Ib/hr 0.123 0.299 0.100 0.076 0.014 0.005 0.013 O.i
1-2
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Filter Holder
Ilicnnocot>|ile
I«VCM*-T)PC
Pilot Tub*
1
(j) MoJi(i*d Gi*«nb>Mo-Siiiilli
G<«
§CamJcitit«
CarliiJijc''! -XAO
Co,l,i.luc*2 -XAD
Q) Cnii
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i *.
SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
.- II. TESTING AND ANALYTICAL PROCEDURES
A. Secondary Chamber Exhaust Scrubber Inlet Duct
Particulate and POHC sampling was conducted in the single
sampling port provided in the secondary chamber exhaust duct
located prior to the scrubber. At this location, the duct dia-
meter was 5.0 inches I.D.
The sampling point locations were determined following EPA
Method 1 with 6 sampling points located on one diameter traverse.
Gas velocity and volume flow rates were determined follow-
ing EPA Method 2 using an "S" type inconel pitot tube and cali-
brated magnehelic gauge. Temperature measurements were obtained
from Shirco personnel from the thermocouple located in the second-
ary chamber exhaust duct.
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The moisture content of the gas stream was determined in
the Modified Method 5 sample train following EPA Method 4.
Particulates and POHC sampling was conducted using a modi-
fied Method 5 sampling train, as detailed in Figure II-l. The
modified Method 5 sampling train consisted of a standard front
half Method 5 train modified to collect, condense and trap organic
vapors in the back half of the train. These modifications in-
cluded the addition of an ice water cooled condenser cartridge
followed by two ice water cooled in-series adsorption cartridges
containing precleaned XAD-2 resin. The XAD-2 resin used was pre-
cleaned following EPA procedures (EPA-600/7-78-201, October 1978)
for the preparation of XAD resin free extractable organics. A
description of this resin is detailed in Figure II-2. A third
in-series ice water cooled adsorption cartridge containing
activated charcoal was used to trap any volatile organics not
collected by the XAD resin.
All glassware was precleaned and distilled water rinsed
followed by a double rinse using pesticide grade methylene
chloride-methanol mixture at ARI's laboratory prior to assembly
of the sampling trains. XAD cartridges were prepared and sealed
with glass end caps prior to shipment to the Brio plant site. The
sampling trains were partially assembled and sealed with glass end
caps prior to shipment to the Brio plant site. All glassware ball
Joints and all impinger inserts were lined with Teflon for each
test run.
Particulate and POHC sampling was conducted for Runs 2-8
following EPA Method 5 procedures using a 7' quartz probe and
0.48 inch quartz nozzle. The sampling train for Run 1 was set
up for POHC sampling only, based upon initial conversations with
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Shirco and Eagle-Picher personnel. A non-tared filter and non-
isokinetic flow rates were used during that run. A qualitative
particulate concentration and emission rate was estimated for
this run however, based upon using an average tare weight typi-
cally found for the other filters used during the test series.
Following the completion of each sampling run, the train
was leak checked, sealed and transported to the clean-up area.
The sample train was disassembled and cleaned as folljws:
1.) The probe and filter holder upstream glassware
were rinsed with the methylene chloride-methanol mixture
and the rinse stored in an amber glass bottle with Teflon
lined screw cap and labeled as Container No. 1.
2.) The filter was placed in a Petri dish and sealed
with Teflon tape and labeled as Container No. 2.
3.) The sorbent cartridges were removed and sealed
with glass end caps and Teflon tape.
4.) The impinger condensate was emptied from the
impingers, the condensate volume was measured to deter-
mine stack moisture content, and then the content was
stored in an amber glass bottle with Teflon lined cap
and labeled as Container No. 3.
5.) The impingers and connecting glassware were rinsed
with the methylene chloride-methanol mixture and the
r rinse stored in an amber glass bottle with Teflon lined
;_ cap and labeled as Container No. 4.
, 6.) The silica gel was emptied into Container No. 5 and
subsequently weighed to the nearest gram for moisture
:- determination.
The filter placed in Container No. 2 for each run was dried
and desiccated at room temperature and weighed to the nearest 0.1
mg at ARI's laboratory. The filters were then shipped to Eagle-
Picher 's laboraory for POHC analysis.
~ Containers No. 1, No. 3 and No. 4 were surrendered to Eagle-
Picher personnel at the plant site for subsequent POHC analyses.
Prior to analysis however, the contents of Container No. 1 for
— each run were dried and desiccated at room temperature and weighed
to the nearest 0.1 mg by Eagle-Picher personnel.
The net weight gain recorded for Containers No. 1 (probe wash)
and No. 2 (filter) were summed to yield the total particulates
collected. Particulate results are reported on an emission rate
basis in Ib/hr and on a concentration basis in gr/dscf, gr/dscf
corrected to 7% 02 and Ib/dscf.
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SAMPLE CLEANUP
RESIDUE-FREE XAD® RESINS
• CLEANED AND EVALUATED BY EPA PROCEDURES
FREE OF IMPURITIES AND CONTAMINANTS
IDEAL FOR TRAPPING
XAO resins are widely used for sampling and
trapping orgamcs. Typical applications include air
and stack sampling, water analysis, clinical assays,
and industrial hygiene. For such applications the
resins must be tree of impurities which might
interfere with detection end increase errors in
quantitation.
HVOMOCAftBON
STAMfUAO
OCTHACTOf
O.EAMEO
XAO-2
IS i
0 5 10
Column: Irtx 2mm glut
J«e*lnc: 10%OV-l01o«G««-ChromO. 100/iM
T«mo~ «O.SO-C«iM'C/mm.
Flownue:Niirogm. aomurmn
The U.S. Environmental Protection Agency has established a procedure (EPA-flOO/7-78-201 October 1978
Appendix B) for the preparation of XAO resins free of extractive organics. These resins sold by AlitechMooticd
Science are cleaned and evaluated by EPA procedures. Chromatograms of residue-free XAO-2 resin extract and
standard hydrocarbons are compared in the figure on this page. As can be seen, the extract of our purifies XAO-
2 is free of any impurities in the 07 to CI8 hydrocarbon range.
Ambertite® XAO resins are agglomerated microspheres. beads of nearly continuous solid phase and pore
pnasc. This physical structure exposes a large surface area of adsorbent to solute molecules. Tht manly
macroreticutar structure allows rapid diffusion of solvents and solutes throughout the resin.
Adsorption of solutes on (dry) XAO resins Is determined by the hydrophobieity of the sorbate (solute). The
s, the more firmly It Is bound to the aliphatic aromatic network.
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Heated
Teflon-)
Line
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Moisture
Trap
Calibration
Valves
FIGUU n-3
Emission Monitor
Measureaeat System
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Continuous emission monitoring for CO,, 0,, CO and NO was
conducted generally following EPA Methods 3, 10 and 20. A&I's moni-
tors used in the test program were a Horiba CO- monitor, Teledyne
0, monitor, Horiba CO monitor and TECO Model 10 NO monitor.
^v
The emission monitoring measurement system consisted of a
stainless steel probe located in the secondary chamber exhaust
duct connected to a heated Teflon sample line and sample manifold.
The sample manifold diverted portions of the sample to the NO
CO, CO, and oxygen measurement systems with the remaining portion
venting to atmosphere.
The NO measurement system consisted of the following com-
ponents (in direction of flow):
1. Three way heated stainless steel calibration valve to
allow for introduction of either calibration gas or
sample gas.
2. Heated Teflon line connected to an external NO, to NO
converter. 2
3. Teflon line connected to an ice cooled condenser for
moisture removal.
4. Teflon line connected to the TECO Model 10 NO monitor.
^»
The oxygen, CO and CO, measurement systems consisted of the
following components (in direction of flow):
1. Three way calibration valve to allow for introduction
of either calibration gas or sample gas.
2. Teflon line connected to an ice cooled condenser for
moisture removal.
3. Teflon lines connected to the Teledyne oxygen monitor,
Horiba CO2 monitor and Horiba CO monitor.
A schematic of the measurement system is given in Figure XI-3.
All NO monitor calibrations were conducted with the ex-
ternal converter in the NO mode (on position) and the internal
converter located in the NO analyzer in the NO mode (off position).
^(
An external converter efficiency test was conducted prior to
beginning the testing following EPA Method 20 procedures. The test
was conducted for 30 minutes with less than a 2% change during that
time.
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A response time test was conducted following Method 20 pro-
cedures for the O. and NO monitors. The average NO measure-
ment system response time^ras 37 seconds and the average oxygen
measurement system response time was 13 seconds.
A pre-test and post-test measurement system calibration
error test was performed at the beginning and end of each day of
testing using the following calibration gas standards:
pi
I, j
C
Low:
Mid:
High:
Analyzer
57
123
199
NO
.3
.9
.2
X
ppm
ppm
ppm
CO
50
235
470
.8
.0
.0
ppm
ppm
ppm
CO
--
4.
9.
-
9%
6%
0,
2
...
12.
20.
2%
9%
Span: 250.0 ppm 500.0 ppm 15% 25%
A zero and calibration drift check was conducted on each
monitor after each run. This data was used to correct the moni-
toring data for that run.
The external converter on the NO measurement system
was left primarily on NO mode. Whil8 on NO mode, no change
in concentration occurrea, demonstrating that NO- was not present.
in the stack gas. Therefore, NO emissions were calculated
as NO for each test run.
B. Scrubber Exhaust stack
Particulate and POHC sampling was conducted in the single
sampling port provided in the scrubber exhaust stack. At this
location, the stack diameter was 3-3/4 inches I.D. The sampling
point locations were determined following EPA Method 1 with 6
sampling points located along one diameter.
Gas velocity and volume flow rate were determined using an
"S" type pitot tube and oil manometer. Temperature measurements
were obtained using a Chromel-Alumel thermocouple and Keithley
digital thermometer.
The moisture content of the gas stream was determined in
the Modified Method 5 sample train following EPA Method 4.
Particulates and POHC sampling was conducted using a Modi-
fied Method 5 sampling train as previously described.
Isokinetic sampling was conducted for particulxtes and POHC,
using a 3* glass lined probe and stainless steel nozzle. A total
of eight runs were performed.
II-4
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Sample handling, cleanup and analyses of the collected scrubber
exhaust particulate and POHC samples were performed as described in
Section A for the secondary chamber exhaust duct sample runs.
Sulfur dioxide and sulfur trioxide sampling was conducted
in a separate Method 5 sampling train on the scrubber exhaust
stack following Texas Air Control Board Method 29 as detailed
in the TACB Sampling and Laboratory Procedures Manual. Speci-
fically, the SO sampling train consisted of a 1/4" stainless
steel probe and five impingers. The first impinger contained
200 mis of 80% IPA to collect SO., the second, third and fourth
impingers contained 200 mis each of 6% hydrogen peroxide to collect
SO-, and the fifth impinger contained 200 grams of silica gel.
SOy sampling was conducted simultaneously with the particulate/
POHC sample runs. Analysis of the SO samples were conducted
at ARI's laboratory.
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SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
III. RESULTS
The results of the particulate emission tests conducted on
the secondary chamber exhaust scrubber inlet duct are presented
in Table ni-1. The results of the particulate emission tests
conducted on the scrubber exhaust stack are presented in Table
III-2. The results of the carbon monoxide and nitrogen oxides
emission tests conducted on the scrubber inlet duct, and the
sulfur oxides emission tests conducted on the scrubber exhaust
stack, are presented in Table III-3.
Data obtained during the emission test are included in the
following Appendices:
I
t —
Appendix A
Appendix B
Secondary Chamber Exhaust Scrubber Inlet Duct
Field Data and Summary Calculation Data
Secondary Chamber Exhaust Sc
NO , CO, 0- and CO. Field Data,
Suftraary Calculation Data and Calibration
Data and Strip Chart Data
r Inlet Duet
Appendix C
Appendix D - Test Equipment Calibration Data
Scrubber Exhaust Stack
Particulate and SO Field Data, Summary
Calculation Data and Laboratory Analysis Data
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SUMMARY OF PARTICULATE EMISSION TEST RESULTS
III-l
Brio Refining
Shirco Incinerator Scrubber Inlet
TABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST TIME:
STACK GAS
Temperature, av. °f
Velocity, av. ft/sec
Volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
CO,, av. % vol
02f av. % vol
PARTICULATE SAMPLE
Time, min.
Volume, dscf
Isokinetic ratio, %
Filter, mg
Probe wash, mg
PARTICULATES
Concentration
gr/dscf
gr/dscf (corrected to 7% 0,)
Ib/dscf x 10-6 *
Emission rate
Ibs/hr •
2-10-87 2-11-87 2-11-87
1 2 3
1537-17J/T 1002-1200 1416-1604
2050
52.59
429.1
4730
14.6
11.6
6.7
1900
35.26
287.7
3370
14.6
11.5
6.2
1900
46.63
380.5
4556
12.5
11.0
7.5
90
56.553
NAG
60.4®
42.5
118
62.653
102.5
32.9
18.1
108
77.065
101.8
9.7
26.5
0.028®
0.027©
4.012®
0.013
0.012
1.795
0.007
0.007
1.036
0.019®
0.006
0.005
This run was not a formal particulate test. Sampling was
conducted at a non-isofcinetic sampling rate and an untared
filter was usea. An estimated tare weight of 180.0 mg was
used to obtain an approximate filter loading.
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SUMMARY OF PARTICULATE EMISSION TEST RESULTS
.ABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST TIME:
STACK GAS
III-l Cont'd.
Brio Refining
Shirco Incinerator Scrubber Inlet
2-11-87 2-12-87 2-12-87
456
1845-1958 1050-1249 1502-1807
Temperature, av. °f
Velocity, av. ft/sec
Volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
CO,, av. % vol
02f av. % vol
P ARTICULATE SAMPLE
Time, min.
Volume, dscf
Tsolcinetic ratio, %
,'ilter catch, mg
Probe wash, mg
P ARTICULATES
Concentration
gr/dscf
gr/dscf .(corrected to 7% 0,)
Ib/dscf x 10-6 *
Emission rate
Ibs/hr
1900
47.62
388.6
4565
14.3
9.8
7.6
1890
37.22
303.7
3468
16.2
9.2
7.6
1890
34.99
285.5
3290
15.4
7.1
10.1
73
52.598
102.7
19.2
20.2
119
65.168
102.7
6.2
9.4
185
94.718
101.1
6.2
8.9
0.012
0.013
1.652
0.008
0.004
0.004
0.528
0.002
0.002
0.003
0.352
0.001
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SUMMARY OF PARTICIPATE EMISSION TEST RESULTS
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TABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST -TIME:
STACK GAS
III-l Cont'd.
Brio Refining
Shirco Incinerator Scrubber Inlet
2-13-87 2-13-87
7 8
1021-1216 1343-1548
Temperature, av. °f
Velocity, av. ft/sec
Volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
CO, av. % vol
0
,,
f av. % vol
L
P ARTICULATE SAMPLE
Time, rain.
Volume, dscf
Isofcinetic ratio, %
Filter catch, m?
Probe wash, mg
P ARTICULATES
Concentration
gr/dscf
gr/dscf (corrected to 7% o
Ib/dscf x 10'«
Emission rate
Ibs/hr
1900
43.31
353.4
4156
13.3
8.7
9.0
115
73.815
100.4
9.5
7.3-
0.004
0.005
0.502
0.002
1900
34.14
278.6
3208
15.1
8.5
8.2
125
62.957
102.0
11.4
9.9
0.005
0.005
0.746
0.002
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SUMMARY OF PARTICIPATE EMISSION TEST RESULTS
TABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST TIME:
STACK GAS
III-2
Brio Refining
Shirco Incinerator Scrubber Exhaust
2-10-87 2-11-87 2-11-87
123
1537-17^ 1002-1200 1416-1604
Temperature, av. *f
velocity, av. ft/sec
volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
PARTICULATE SAMPLE
Time, min.
Volume, dscf
Isokinetic ratio, %
Filter catch, mg
Probe wash, ntg
PARTICULATES
Concentration
gr/dscf
gr/dscf .(corrected to 7% 0.
Ib/dscf x 10-6 <
Emission rate
Ibs/hr
173.6
39.38
181.2
5163
44.4
172.8
41.99
193.2
5542
44.0
172.0
45.16
207.8
6063
43.1
90
65.035
104.0
36.6
25.6
118
59.121
106.5
59.9
28.8
108
54.924
98.8
59.4
33.8
0.015
0.015
2.109
0.011
0.023
0.022
3.308
0.018
0.026
0.027
3.742
0.023
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SUMMARY OF PARTICIPATE EMISSION TEST RESULTS
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TABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST TIME:
STACK GAS
Temperature, av. *f
Velocity, av. ft/sec
Volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
PARTICULATE SAMPLE
Time, min.
Volume, dscf
Isokinetic ratio, %
Filter catch, mg
Probe wash, mg
PARTICULATES
Concentration
gr/dscf
gr/dscf (corrected to 7% O.
Ib/dscf .x 10-6 *
Emission rate
Ibs/hr
III-2 Cont'd.
Brio Refining
Shirco Incinerator Scrubber Exhaust
2-11-87
4
1845-1958
172.6
39.12
180.0
5164
44.0
73
33.488
104.3
53.3
13.1
0.031
0.034
4.372
2-12-87
5
1050-1249
171.1
32.63
150.2
4426
42.0
119
44.259
99.6
9.8
9.4
0.007
0.007
0.957
2-12-87
6
1502-1807
168.3
34.65
159.5
4883
40.0
185
72.527
94.3
14.4
9.6
0.005
0.006
0.730
0.023
0.004
0.004
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SUMMARY OF PARTICIPATE EMISSION TEST RESULTS
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TABLE:
COMPANY:
LOCATION:
TEST DATE:
TEST RUN:
TEST TIME:
STACK GAS
III-2 Cont'd.
Brio Refining
Shirco Incinerator Scrubber Exhaust
2-13-87 2-13-87
7 8
1021-1216 1343-1548
Temperature, av. °f
Velocity, av. ft/sec
Volume flow, acfm
Volume flow, dscfh
Moisture, av. % vol
PARTICIPATE SAMPLE
Time, rain.
Volume , dscf
IsoJcinetic ratio, %
Filter catch, mg
Probe wash, mg
P ARTICULATES
Concentration
gr/dscf
^gr/dscf (corrected to 7%
Ib/dscf x 10-6
Emission rate
Ibs/hr
0,)
168.6
33.79
155.5
4710
40.6
115
43.208
93.7
27.3
14.0
0.015
0.018
2.108
0.010
169.6
34.95
160.8
4872
40.5
125
49.154
94.8
35.9
10.4
0.015
0.016
2.077
0.010
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SUMMARY OF AVERAGE SO , CO AND NO EMISSION TEST RESULTS
— • X. X
TABLE: III-3
COMPANY: Brio Refining
OPERATORS: L. Goldfine, H. Taylor, J.
LOCATION: Shirco Incinerator
DATE:
RUN NO.:
TIME:
SULFUR TRIOXIDE (SOj)1
Concentration
' ppm by vol db -
Ibs/dscf x 10
Emission rate
Ibs/hr
SULFUR DIOXIDE1
Concentration
ppm by vol db -
Ibs/dscf x 10
Emission rate
Ibs/hr
CARBON MONOXIDE2
Concentration
ppm by vol db -
Ibs/dscf x 10 3
Emission 'rate
Ibs/hr
NITROGEN OXIDES (as NO)2' •
Concentration
ppm by vol, db.
Ibs/dscf x 10 D
2-10-87
1
1537-1707
114.5
2.378
0.12
394.3
6.551
0.34
/
0.0
0.0
0.0
60.7
0.473
Thomas
2-11-87
2
1002-1100
313.4
5.206
0.29
169.7
3.524
0.20
0.0
0.0
0.0
78.5
0.611
2-11-87
3
1416-1604
76.3
1.584
0.10
108.2
1.796
0.11
0.0
0.0
0.0
70.5
0.549
Emission rate
. Ibs/hr 0.022 0.021 0.025
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2 Measured at scrubber inlet
L1 NO and NO concentrations measured during the test series were
thl same, indicating that NO2 was not present in the stack gas,
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SUMMARY OF AVERAGE SO... CO AND NO.. EMISSION TEST RESULTS
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TABLE: III-3 Cont'd.
COMPANY: Brio Refining
OPERATORS: L. Go Id fine, H. Taylor, J. Thomas
LOCATION: Shirco Incinerator
DATE :
RUN NO. :
TIME:
SULFUR TRIOXIDE (SO^)1
Concentration
' ppro by vol, db-
Ibs/dscf x 10~3
Emission rate
Ibs/hr
SULFUR DIOXIDE l
Concentration
ppm by vol, dbe
Ibs/dscf x 10"3
Emission rate
Ibs/hr
CARBON MONOXIDE2
Concentration
ppm by .vol, db-
Ibs/dscf x 10~3
Emission rate
Ibs/hr
NITROGEN OXIDES (as NO)2'1
Concentration
ppm by vol, db.
Ibs/dscf x 10"3
2-11-87
4
1845-1958
71.0
1.475
0.076
64.5
1.068
0.055
0.0
0.0
0.0
74.2
0.578
2-12-87
5
1050-1248
15.7
0.325
0.014
10.1
0.168
0.007
0.0
0.0
0.0
98.4
0.766
2-12-87
6
1502-1807
5.1
0.105
0.005
1.3
0.021
0.001
. 0.0
0.0
0.0
97.7
0.761
L
Emission rate
, Ibs/hr 0.026 0.027 0.025
* Measured at scrubber exhaust
Measured at scrubber inlet
*NO and NO concentrations measured during the test series were
the same, indicating that NO2 was not present in the stack gas,
-------
SUMMARY OF AVERAGE SO^, CO AND NO EMISSION TEST RESULTS
TABLE: IXI-3 Cont'd.
COMPANY: Brio Refining
OPERATORS: L. Goldfine, H. Taylor, J. Thomas
LOCATION: Shirco Incinerator
DATE: 2-13-87 2-13-87
RUN NO.: 7 8
TIME: 1021-1216 1343-1548
SULFUR TRIOXIDE (SO^)1
Concentration
'ppm by vol, db- 13.7 9.5
Ibs/dscf x 10 3 0.285 0.197
Emission rate
Ibs/hr 0.013 0.010
SULFUR DIOXIDE *
Concentration
ppm by vol, db, 5.6 1.0
Ibs/dscf x 10"3 0.094 ' 0.016
Emission rate
Ibs/hr 0.004 0.001
CARBON MONOXIDE »
Concentration
ppm by vol, db. 0.0 0.0
Ibs/dscf x 10*3 0.0 0.0
Emission rate
Ibs/hr 0.0 0.0
NITROGEN OXIDES (as NO)*.*
Concentration
ppm by vol, db. 92.0 88.2
Ibs/dscf x 10 9 0.716 0.687
Emission rate
Ibs/hr 0.030 0.022
1 Measured at scrubber exhaust
[••-: 2 Measured at scrubber inlet
M INOX and NO concentrations measured during the test series were
the same, indicating that NO2 was not present in the stack gas.
r
u
•
r
-------
r.
r
r
SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
APPENDIX A
Secondary Chamber Exhaust Scrubber Inlet Duct
Field Data and Calculation
Summary Data Sheets
-------
COMPANY:
SOURCE:
REPETITION NO: '-
TEST DATE: J-/o-f7
Volume of sample ac standard
conditions on dry basis
—*
mstd
17.64J
A H
TIT
Volume of water vapor in sample at
standard conditions
witd
•Vlc
0.04707 cu. ft.
ml
JO'S* ml.
lc
Fractional moisture content of stack gas
B
w,td
vs
V V
mstd + wstd
Particle conc«ntration_ in_ stack gas on dry basis
c's - C
*>* = .
2.205 10"
M_
mstd
Stack gas volume flov rat* on dry basis
3600
(A.
sq.ft.
T.td . PS
* P
.td
ft/Me)
Process race or BTU rating P
Emission rat* ^ ,
c's
Isokinetic sampling rat*
I • fl.667 min ) T
ENGLISH UNITS
(29.92 in. Hg 68*F)
dscf.
scf.
grains/dscf.
c 10"6lbs/«f
0.00^*730 x 10°dscf/hr
0.0/9
Ibs/hr
Ibs/
[0.002669 in
.Hfc.eu.ft. VJ*V-Y rtar* *»!
/ ^T"V. ^T)
(A.
•q.ft.)
L
L
-------
COMPANY:
SOURCE:
REPETITION NO: / ~
._ST DATZ:
_ Dry molecular weight of stack gas
Md - 0.44 (ZC02) + 0.32
//•I
0.28 (Z», + XCO)
Molecular weight of stack gas, wet basis
Ms - Md U-BWS) + 18 Bws
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, inches H.O
L'.
Average absolute stack gas temperature
(Tg) avg.
460
Absolute stack gas pressure
r P - ?, + (Static Pressure/13.6)
ISO
Stack gas velocity
. -'(85.49) C
p-
L
Stack gas volume flow race
60 V A
s s •
Stack gas volume flow rate, dry basis
[ Q - 3,600 U-B1
L 9 mm
kstd . P.
_lb/lb-aole
Ib/lb-mole
a.
L
L
Q.W3Q
30. (oO
in. E
«vg. / (T)
ft/sec.
acfm
^730
dsef/>
-------
E
L
L
COMPANY:
SOURCE' ^ '/*«**•«» J~/ve.
REPETITION NO: 2- -Z
TEST DATE: J-S'-S'"?
Volume of sample at standard
conditions on dry basis
7-0
ENGLISH UNITS
(29.92 in. Hg 68'F)
rased
17.64
/•on
AH
Volume of water vapor in sample at
standard conditions
r~
\
y
vstd •
V
Ic
0.04707 cu. ft. V.
ml J lc
9-^-8' ml.
' Fractional moisture content of stack gas
I"
B
•
F • ws
wstd
mstd + vstd
Particle con£entration_in stack gas on dry basis
f
\
>
i-
»••
c
^nrJ
7)
t. 0154 3 .grj 1 Mn~
mgj V
i tn* i «~6 M_
/Q. 7 5.2.
0.0/3
mstd
Stack gas volume flov rate on dry basis
3600 (l-
(A.
sq.ft.
T.td . p,
(Ts>
• P
.td
ft/sec)
Process rate or BTU rating P
Emission rate
Q c's
Q e's
Q.QO6
Isokinetic sampling rate
I • (1.667 rnin I T
).002669 in.Ht.eu.ft. V
ml. *R
ev p A
s s n
- O
,q.ft.)
dscf.
scf.
grains/dscf.
x 10"6lbs/dcCf
10°dscf/hr
Ibs /hr
-------
.-A.r FiI'-D I AT.".
SCHEMATIC OP STAC
D:
CROSS SECTION
TRAVERSE
POINT
NUMBER
_
".
TOTAL
SAMPLING
TIME
V-^7 :
+17
67
n
in
vr
ii~j
.57
ftT7
/7
STATIC
PRESSURE
ir/MT
•0.10
*
:
f.>l/)l*
K
- 4
1,-u-
-t
STACK
TEMPERATURE
• r'.''
AVERAGE £//<>) r.-('>J^
IMPINGE R N
VOLUME OF LIQUID VOLUME «•
MATER COLLECTED I • j •
p
0
L
0
S
II
S
M
1 ^MT i •''''., "* ' '
ftff . -*^i -'//*'
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LMPLE
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sii.ir
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FINAL " • j .1 ' j ••Hi A-> -»
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'QUID COLLECTED ^C!'. \ '* " I "'>
TOTA «M| COLLECTED - •' ' | .-
M V I J
/.
MX NO.
OR MO. ,
. VK
\ /6£7
i
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WFFCRENIIAL
ACllOSS
ORIFICE
METER
O'U
b:.H,0
ACTUAL beSMCD
•70
no
.~7O
.VO
JO
,y/O
rfu
7(9
'/(f
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.
CAS SAMPLE
VOLUME
IV.I.M
ITV^Vfc,
V-1 K
./, ;'
V-/.-/
•/,; v
S'/ -i
O(<- ,'J.
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ASSUMED MOISTURE, * t
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GAS SAMPLE T
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. _ SAMPLE FILTER PHOOE V.
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FINAL WEIGHT
,,., -_,r TAME WEIGHT S
__ HEIGHT GAIN '
mill
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EMPERATURE
AS METER
OUTLET
•70
7(9
ViO
k_
'
t>
7,'?
f'-i*'
' - ^'
Ziit'
• (-/• <•-
t^-> 7
. • i
CO
• >
.!'?
SAMPLE BOX
TEMPERATURE
•F
,260
Jj>f>O
TA?
"*»"*'
»— 't''
TEMPERATURE
OF GAS
LEAVING
CONDENSER OR
LAST IMPINGER
•f
(' •'.
C. •' •
<-,;;
' ' /
«.'M »
. '
>: I
t :. . '
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-------
COMPANY:
SOURCE: 5»<* e
P PETITION NO: JL-
DATI: -*-//-*
Dry molecular weight of stack gas
- 0.44 (ZC02) + 0.32
+ 0.28
Molecular weight of stack gas, vet basis
Ms • Md (1-BWS) + 18 B^
Pitot tube coefficient
C (from calibration curve)
P
Average velocity bead of stack gas. inches E.O
( /A p ) avg.
Average absolute stack gas temperature
(T8) «vg. • 1900 «f + 460
Absolute stack gas pressure .
+ XCO)
P - P. + (Static Pras«ura/13.6)
S D ..
Stack gas velocity
avg. - (85.49) Cp (
Ib/lb-mole
Ib/lb-nole
in. B
) avg. / (^} ^^
'*'
Stack gas volume flow rate
60 V A
s s
Stack gas volume flow rate, dry basis
Qg - 3,600 (l-Btfg)
«td
(Tg)
ft/sec.
acfm
rstd J
3370
dscf/h
-------
i— r
SCHEMATIC OP STACK
I'
PLANT
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/(.
LOCATION
/ /UV~ 7X
C
BAROMETRIC PRESUME ._l£?.J
ASSUMED MOISTURE. X U.
PROBE LEHCTII. U. '/(-i
MCTtn All,
r. rAciOH
I'llOCUtl *i:iCHI HATE
•4IUMMCI
\ -Srn
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STACK NO.
RUN HO. _2i
Tl MI r'l
.»..«ri
C- NOZZLE MAMETEII. I.. _L<
STACK DIAMETER. I. .
CROSS SECTION
SAMPLE MX NO.,
METER BOX NO.
I
PROBE llEATER SETTING.
HEATER BOX SETTING c
NCICIIT Ol: fAIIIICULAlE COLLCC1I
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TAIIC MtlCIII
WEIblll CAIN
riacn
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line
fol.nl*.
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PRCUURf
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VOLUME
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At D«r GAS MEIER
INLET
IT.^I.-P
OUTLET
IT-.nl.-l5
SAMPLE BOX
TEMPEIIAIUNE
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LAST IMCIIICEH
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PUMP
VACUUM
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4^
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to
72-
70
'/K! /
7V
7V
70
/o
Jf£.
•S
6?
V
us
17
/o
TOTAL
IV
_?.JZ_
.<>-L.
.'0
AVERACK
VOLUME OP LIQUID
MATER COLLECTED
FINAL
INITIAL
LIQUID COLLECTED
TOTAL VOLUME COI.LtCTCD
1 *
IOMUIHM
ORSAT MEASUREMENT
r
I
J
4
TIME
CO
CO
,
Or/...
-------
SOURCE:
REPETITION NO: /-
TEST DATE: J-//-
Volume of sample ac standard
condicions on dry basis
rastd
Volume of vater vapor in sample at
standard conditions
wstd
0.04707 cu. ft.
ml
2-3 ml.
Fractional moisture content of stack gas
V
B
vs
V V
mstd + wstd
Particle con£entration_in_stack gas on dry basis
c's
to.01543 jrl F V
• 2.205 10"6 Mn
V
mstd
Stack gas volume flow ratt on dry basis
3600(1-8...) V_A
vs s s
(A » sq.ft. 7 •
Process rate or BTD rating P
std . s
• P
,td
ft/sec)
Emission rate
Q c's
Q c's
ENGLISH UNITS
(29.92 in. Hg 68*F)
/O>*£7
O,6O~7
scf.
zrains/dscf.
x 10"6lbs/d' •
10dscf/hr
_lbs/hr
Ibs/
Isokinetic sampling rate
I • (1.667
.002669 in.H.cu.ft.
ev p A
• » n
Y
<*
-------
:i
SCHEMATIC Of HACK
PLANT,
T
t
.L
DA» .•>/>'!.*•>
I «** A VlfUl \ t ''/ * '* •
II I- .ii^LU-Vm-Ml —
AMUIEHT TEMPCIIATUnE
LOCATION
I
OPERATOR.
STACK 110. .
RUN HO ;
01.
BAROMETRIC PRESSUNE .Iii_—J
ASSUMED MOISTURE. X / *i
PROBE LENGTH. U. 7'^
METCflAlIp
f. FAC10H .
ciiocru miiciir NAIE
"J '\sJLci
NOZZLE DIAMETER. I..
STACK DIAMETER. I*. _
CNOtt SECTION
SAMPLE BOX NO..
METER BOX NO.
!
PROBE HEATER SETTING
HEATER BOX
•CICIIT Of fAIMICIILAlE COILECIE
FMUL WIU.HI
TAHU IrllMII
WCIGMI C.AIII
riLicn
I'MOin
, ;^
101*1.
TRAVERSE
POINT
NUMBER
SAMPLING
TINE
lei. -I..
IU
STATIC
PRESSURE
|U.H,0|
STACK
TEMPERATURE
VELOCITY
HEAD
t\r,l
PRSSURE
DIFFERENTIAL
ACROSS
ORIFICE
MtTER
IAIII
«-.M,o
ACTOAl bESIRED
•10
CAS SAMPLE
VOLUME
CAS SAMPLE TEMPERATURE
AT DRY CAS MEIER
INLET
OUTLET
SAMPLE B0>
TEMI'CHAIUnE
•F
370
TEMI-EIIA1UIII:
or GAI
LI:AVIMC
COHOEIIMH OH
LAST IMriHCEH
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PUMP
VACUUM
1*. llt
10
VI
7*
170
10
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All?
72
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Lii
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£<-»
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, /
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TOTAL
M
AVERACR
bt.tl
6,1
/a.
i?
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Cs-L.
VOLUME nr LIQUID
VAICHCOU.CC ICO
FINAL
INITIAL
VIOUIO COLLECTED
10k
UUME COI.LtCTCD
IMPINCER
VOLUME »l
n i V
T~7?
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r
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1
CO.
CO
-------
COMPANY:/^'*
SOURCE ' ^^ /AC-0 ~
'.PETITION NO: 3 -
.ST DATS: 3-xx-
Dry molecular weight of stack gas
i- -
Md - 0.44 (ZC02) + 0.32 (Z02) +0.28 (ZNj + ICO)
//> O I' f/>
; Molecular weight of stack gas, vet basis
Ms - Md U-BWS) + 18 Bws
Pitot tube coefficient
'c (from calibration curve)
P
Average velocity bead of stack gas, inches B.
l: (/A p ) *vg.
r Average absolute stack gas temperature
l'~ (T ) avg. - M/0 *T + 460
.olute stack gas pressure
P - P. + (Static Pressure/13.6)
so
Stack gas velocity
- (85.
26,0 6
r '
t Stack gas volume flow rate
60 7s As
[_ Stack gas volume flow rate, dry buis
f Qg - 3,600
L
.49) C (VJ7" ) avg. / (T j
^~TT^
•td . P.
' P
•td _
_lb/lb-mole
Ib/lb-mole
•R
in. 3
ft/sec.
acfm
dscf/hr
L
-------
-------
B
I
c
COMPANY: A*. to
SOURCE: Sftitt-
R£PETITION NO: * -
TEST DATE: .?-//-/ 7
Volume of sample at standard
conditions on dry basis
ENGLISH UNITS
(29.92 in. Hg 68T)
mstd
. [n.«J
A H
ITs
Volume of water vapor in sample at
standard conditions
wstd
.Vlc
0.04707 cu. ft.
ml
lc
Fractional moisture content of stack gas
vstd
vs
V V
mstd + vstd
Particle concentration in stack gas on dry basis
~~ ~
c's
.01543^
2.205 10
mstd
M
mstd
Stack gas volume flov rate on dry basis
- 3600 U-Bwg) - ' T
(Af - sq.ft. 7§-
Process rate or BTU rating P
CT.)
' p
.td
ft/s«c)
Emission rate
Q c's
Q c's
Isokinetic sampling race
I • [1.667 min I T
).002669 in.Ht.cu.ft.
ml. "R
6V P A
s s a
dscf.
scf.
grains/dscf.
x 10"6lbs/
-------
r\
SCHEMATIC Or STACK
V •
_)]
CROSS SECTION
TRAVERSE
POINT
IIUMBEM
•
TOTAL
SAMPLING
TIME
•?£»
V
:^/rt
'«;»*»
o\
*
-,
ITATIC
PRESSURE
IU.N.OI
r ^IIWM~CI
- -!• »«•
STACK
TEMPERATURE
11,1 'f
AVERAGE JO^/v-HJ
t IMPINGER
VOLUME Or LIQUID VOLUME «J
VAIE* COLLECTED ,' , . .
P
D
L
0
S
R
S.
M
AMT i •
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ASSUMED MOIJIUUt
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PROBE HEATER SE
HEATER BOX SETT
GAS SAMPLE T
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trcicm CAIM
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HC
EMPERATURE
AS MEIER
OUTLET
'75
7&
77
V;'
• »-?
V V
7^
CO I*, CO
"f
SAMPLE BOX
TEMPEHAIURE
•r
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2^i^
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or CAS
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IS
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V
-------
COMPANY:
SOORCE:
REPETITION NO: V—
\ .1 DATE:
T~O S '
Dry molecular weight of stack gas
Md - O.U (ZC02) + 0.32 (Z02) + 0.28
Molecular weight of stack gas, vet basis
Ms • Md (1-B^) + 18 B^
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, inches H,0
( /A p ) «vg.
Average absolute stack gas temperature
(T ) avg. • t^OO *F + 460
S *"•"',^m^m^mfimimjiimftf
Absolute stack gas pressure
P « P. •*• (Static Presaure/13.6)
• o
ICO)
Stack gas velocity
/
lb/lb-aola
Ib/lb-mole
*R
in. H
Stack gas volume flow race
60V.A. -
Stack gas volume flow rate, dry basis
3,600 (l-Btff)
ft/sec.
acfa
std . P
(V
' P
.td .
dscf/h:
-------
r~" " r~""" r~~"! i
SCHEMATIC OP STACK
QT
— ^ f '• *»— 1
C AluMM
t
' i|
CROSS SECTION
1 '
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POINT
MUMBER
TOTAL
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vr
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SAMPLING
TIME
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IF.IIT TIMt
1
4
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OAROUETRIC 1
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PROBE
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STACK
PROBE
IIEATE
LEIICT
EDIAM
DIAME
HEAD
RBOX
CAS SAMPLE T
At DRY Gl
INLET
70
. ^
77
7?
7?
CO, 0,
.
"tf)
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PRdllURE
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COMPANY:
SOURCE:
PETITION NO: ST
DATE: A -/i- S" 7
Dry molecular veighc of stack gas
M. • 0.44 (ICO,) + 0.32 (10,) + 0.28 (IN, + ICO)
d 9.a 7.2
Molecular weight of stack gas, wet basis
Ms - Md (1-B ) + 18 B
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, inches ELO
( /A p ) «vg.
Average absolute stack gas temperature
(T$) avg. - /B 90 T + 460
,olute stack gas pressure
P • P. + (Static Pressure/13.6)
S D
27*1
- Stack gas velocity
T 3,7
Stack gas volume flow rate, dry ba«is
P Q • 3,600 (1-B ) V A
|^ • ws s i
I
CTf) avg . P
std
lb/lb-mole
Ib/lb-eole
•R
in. 3
ft/sec.
aefm
dscf/hr
E
-------
r
r
r
r
r
r
L_
t
L
L
L
L
L
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COMPANY:
SOURCE i
REPETITION NO: -T
TEST DATE: 3 -/a.-
Volume of sample at standard
conditions on dry basis
nscd
H
/.0/7
Volume of water vapor in sample at
standard conditions
used
Vlc
0.04707 cu. ft.
ml
ml.
Fractional moisture content of stack gas
wstd
v,
V V
nstd + vstd
Particle concentration in stack gas on dry basis
c's
-E
01543 .gr
nstd
2.205 10~6 Mn
y
astd
Stack gas volume flow rata on dry basic
- 3600 U-B..J 7 A
(A » sq.ft. 7 •
Process rate or BTU rating P
«td . .
(V «v« • p.td
^ ft/c«c) "
Emission rate
Q e'.
Q e'a
P
Isokinetic sampling rate
r "
I • 1.667 min I T
ENGLISH UNITS
(29.92 in. Hg 68*F)
. OO
[0.002669 in.Ht.eu.ft. 7
ml. "R
1<
67 P A
s s n
O-OOl^-rG sq.ft.)
dscf.
scf.
£rains/dscl
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x 10 dscf/h
_lbs/hr
Ibs/
13-6
-------
COM
REPE7ITION NO: 6
TEST DATE: a -a-
Volune of sample at standard
conditions on dry basis
nstd
Volune of water vapor in sample at
standard conditions
17.64J yjr
P . A R
**r * IT?
L Tm J
vstd
Vlc
0.04707 cu. ft.
ml
mi."
le
Fractional moisture content of stack gas
vstd
vs
V V
mstd * vstd
Particle concentration in stack gas on dry basis
c,$ . [o.01543^7j f Mn"
I tt\21 I * •
v . 2.205 10"6 Mn
V
astd
Stack gas volume flow rate on dry basis
» 3600 (1-B ) V A
vs s s
(A.
sq.ft.
ttd . s
' P
.td
ft/sec)
Process rate or BID rating P
Emission rate ,
Q e's
P
v
Isokinetic sampling rate
I - 11.667 min ) T
sec / *
ENGLISH WITS
(29.92 in. Hg 68*7)
Q.
[0.002669 in.Hg.eu.ft. V.J-fVY P
_ •
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.
oar
ev p A
s s n
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scf.
grains/<
106dsc
Ibs/hr
Ibs/
•M
13.6
(A • Q.OOIlft sq.ft.)
Q
-------
COMPANY:
SODRCZ: S
WTIIIOM NO:
TL»f DATE: 3- -'2L-
Dry molecular veight of stack gas
Md - 0.44 (2C02) + 0.32 (Z02) + 0.28 (ffl + ZCO)
Molecular veight of stack gas, vet basis
Ms • Md U-Btfa) + 18 Bws
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, inches H.O
( /A p ) •»!•
Average absolute stack gas temperature
(Tf) avg. - /& 90 *F + 460
Absolute stack gas pressure
P - P, + (Static Pressure/13.6)
so
Stack gas velocity
avg. - (83.49) C
p
Ib/lb-aole
Ib/lb-aole
•R
30.2.3
in. B
/ (T>) ^f.
Stack gas velum flow rat*
60 V A
8 S
Stack gas velum flow race, dry basis
3,600
std . p
£t/:
acfa
dscf/hr
-------
. J
t. . i » i - ..i i- • . i • •••* • • _
SCHEMATIC OP STACK P
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LEAVING
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TEMPERATURE
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FINAL
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LIOUIO COLLECTED
IMPII
1 1
1
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-------
COMPANY:
SOURCE: S »'*-<- °
REPETITION NO: 7
. JT DATE:
-^ - S- 7
Dry molecular weight of stack gas
- 0.44 (ZC02)
0.32 (202) +0.28
9,0
+ ZCO)
lb/lb-=ole
Molecular veighc of stack gas, vet basis
Ms
Pitot tube coefficient
Md (l-Btfa) + 18 Btfa
Ib/lb-aole
C (from calibration curve)
P
Average velocity head of stack gas, inches H.O
( /A p ) avg.
Average absolute stack gas temperature
(Tg) avg. • HOC* T + 460
Absolute stack gas pressure
P. • P, + (Static Prewura/13.6)
so
Stack gas velocity
(V.) «^g. " (85.
-------
SCHEMATIC
0
CROSS SECTION
TRAVERSE
POINT
NUMBER
•
TOTAL
SAMPLING
TIME
!I'J.
/•/Y
;^jX
;/^Y
t-ir}^
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•
OP STACK
T
«
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STATIC
PRESSURE
IU.N.OI
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TEMPERATURE
IM'P
•
AVERACC f{Jj>'i)
PI
0
L
0
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DCATIO
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PROBE LENC
NOZZLE WA»
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NEATER BOX
CAS SAMPLE T
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INLET
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tfCIUII CAIII
UTTIMC
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OUTLET
79
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SAMPLE BOX
TCMPEHAIURE
•F
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;• r»« »
TEMPERATURE
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•F
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FINAL
mm AL
IMPINCER
VOLUME «!
\ ' } 4
1 1 1
1 1 1
SILICA Gil
WIMIT.
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TIMt
JfL'-Jj1!-
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-------
L
L
COMPANY:
REPETITION NO: "7
TEST DATE: 3 -/.?-$• ?
Volune of sample ac standard
conditions on dry basis
ENGLISH UNITS
(29.92 in. Hg 68*F)
nstd
|l7.6«J V
Volume of water vapor in saaple at
standard conditions
wstd
Vlc
0.04707 eu. ft.
mi
ml."
Ic
fractional moisture content of stack gas
B . Vw«td
ws Vmstd + Vwstd
Particle concentration in stack gas on dry basis
. . [o.01543 jT) r M-
. .3
vstd
2.205 10
M
mjtd
Stack gas volume flow rate on dry basis
3600 d-
(A " sq.ft. V -
* n s
Process rata or BID rating P
T,td . P,
• P
.td
- ft/s«c)
Emission rate
Q c's
Q
P
c's
Isokinetic sampling rat*
I • fl.667
ffiin I T
sacj «
[0.002669 in.Ht.eu.ft.
ml. '&
ev P A
sen
(A.
L
I
dscf.
scf.
trains,
x 10"61
x 106d$
Ibs/hr
Ibs/
-------
i-
,
1
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POINT
NUMBER
1
1
1
i
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SAMPLING
TIME
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PROBE HEAT
HEATER BOX
GAS SAMPLE T
AT ORT C
INLET
~J8
°sa.
xu
g$
ylj
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y /
^"7
. /
MCllilll CAIII
SAMPLE BOX
TEMPERATURE
•F
J26O
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^ f'xJ
."{^ ^
^^.-C
^<^S
^ *i
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f7/^*
J o O
? 6»CP
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2 <•-/,
7 iA u?
^ (» *i
TOTAL
pnooe
/s" '-,
TEMPERATUNE
OF CA1
LEAVIHC
CONOEHIER OR
LAST lUriNGER
•F
'(• -i
<--
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ii /
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7
7
7
7
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7
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1
- -
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HAIER COLLECTED
FINAL
INITIAL
LIQINO COLLECTED
iaf_L^
ll/V>
E:
IC*
1 (V
IIIMHlllM:
OHSAI MEASUREMEHT
.^_
I
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TIME
CO
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i
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: s^
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COMPANY: fie/O
SOURCE: s
f REPETITION NO:
__ST DATE: 3- -/J- S-7
r
Dry molecular weight of stack gas
[ Md - 0.44 (IC02) + 0.32 (ZOj) + 0.28
r
E
Molecular weight of stack gas, wet basis
Ms » Md U-BWS) + 18 Bws
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack ga», inches
( /A p ) **!•
[ Average absolute stack gas temperature
(T ) avg. • lid O *f * 460
| Aosolute stack gas pressure
P -P. * (Static Pre««ure/13.6)
S D ••
Stack gas velocity
I (V ) avg. « (85.49) C
U ' P>
E
' Stack gas volume flow rat*
L
C
t
tO T. A,
Suck f» velm* flo* r«t«, drr bull
3,600
ICO)
ftd . P
(I.)
_____
/ &j «-i.
'•* «**
Ib/lb-aole
Ib/lb-aole
in. S
ft/sec.
scfa
dscf/h3
f
L.
-------
COMPAQ:
REPETITION NO: ^
TEST DATE: *~S-*7
Volume of sample at standard
conditions on dry basis
ENGLISH UNITS
(29.92 in. Hg 68*F)
mstd
ar
A H
13.6
Volume of water vapor in sample at
standard conditions
vstd
Vlc
0.04707 cu. ft.
~ 237
ml
ml."
Ic
//
Fractional moisture content of stack gas
B
wstd
vs
V V
mstd + vstd
Particle concentration^in_stack gas on dry basis
c,s „ 0.01543 jjr
L »L
2.205 10"6
P.
mstd
ttd
0-00^
Stack gas volume flow rate on dry basis
Q.
- 3600 (l-Bwg)
(As - sq.ft. Vg-
Process rate or BID rating P
T.td . P.
(V
- ft/sec)
Emission rate
Q c's
Q c's
Isokinetic sampling rate
I - (1.667 min 1 T
).002669 in.Hg.cu.ft.
ml. *R
dscf.
scf.
_grains/
x 10 dsc
Ibs/hr
Ibs/
13
87 P A
s s n
sq.ft.)
-------
AR
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<
.'.HEMATIC OP HACK
T
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DATE
LOCATI
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BAROMETRIC PRESSURE ..
ASSUMED MOISTURE. X \ *"">
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RUN NO. jj
PROBE LENGTH. U.
NOZZLE DIAMETER. U. _L
STACK DIAMETER. to.
PROCESS WEIGHT RATE
BOX NO..
CROSS SECTION
METER
PROBE HEATER SETTING.
HEATER BOX SETTING
WEIGHT OP PAR1ICULATE COLLECTED.
SAMPLE
FINAL WEIGHT
TARE WEIGHT
WEIGHf CAIN
FILTER
PROBE W/
TOTAL
TRAVERSE
POINT
NUMBER
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Tine
STATIC
PRESSURE
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TEMPERATURE
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ACROSS
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CAS SAMPLE
VOLUME
CAS SAMPLE TEMPERATURE
AT DRV CAS METER
INLET
IT.,,,!.-!'
OUTLET
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•F
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LAST IMPINGE*.
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•
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-------
SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
APPENDIX B
Secondary Chamber Exhaust Scrubber Inlet Duct
CEM Field Data, Summary Calculation Data,,
Calibration Data and Strip Chart Data
-------
-» • **
I- I
SOURCE: S
TEST DATE:
RUN NO.: /
I -1 • I
CAL CAS CONC
Low
Mid
y
2 *
FIELD DATA SHEET
CO (ppn) J-Q If3
NO, (ppra) T7.J
Tine
Oxygen
hart
Rdg.
C0
Chart
Rdg.
CO
5 nln aVg.
7!KirT
Rdg.
NO
5 •in »avg
Chart
Rdg.
PPM
NO
S Bin avg.
Chart
Rdg.
Z
PPM
N02
by diff.
Chart
PPM
COMMENTS
o.o
O.O
O.O
*-0
ft*
Mffrrt
WO V70
AT:T3
±5-
0-5*
1£
zz-3
O.D
/^/g
o.o
AD
£i
V3
0.1
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7.3
Ail
LE.
/^
'±A.l l*~
-------
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Low
Hid
High
SOURCE: Si Co J~fct*fs*tv** . Q _
TEST DATE: *-/•-* 7 C02 Z
. FIELD DATA SHEET co •?
jd.i d.y
C02
Chart
Rdg.
Z ZCO.
S.I
i-B
f.3
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fr.L
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l.o f
t& T
/O T
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1.0 *
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NO,
5 »in "avg.
Chart 1
**J / f
97,?
33-3
*$3
33 3
t/-o ^-^
••
COMMENTS
.
-------
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE: S»t**-o T^<-/*•**»r"*-
REPETITION NO.: '
TEST DATE: &-/O-
NO average chart reading, % • 3 V. 5"
NO average chart reading, % «
NO /NO cone (corrected) - (Av. chart reading, % - Av. zero drift reading, %) x cal ?a9 "^^f PP"
cal drift reading, %
» nan by vol, db
NO cone (corrected) - ( £V.5' % - /, p %) x I23-1 ppm
x --- ---
- £o."7 PPm by vol, db
5 9
NO cone (corrected to 15% O,) - x «ft:a » ppm by vol, db
X » ^ n" •-•-.. : r ^U •if ~" J ~ ------
NO cone (corrected) « ( % - %) x ppm
• &O>~7 ppm by vol, db
NO_ cone (corrected) = O. Q ppm by vol, db
-------
NOX CALCULATION SI JVRY DATA SHEET
METHOD 20
COMPANY: 8*'°
SOURCE: ?"'
REPETITION NO. : / -
TEST DATE: 3~/£>-
NO emission rate (Ib/hr) - NO cone (ppm by vol, db corrected*) x-- x 10~ x vol flow rate (dscfh)
Ib/hr
NO2 emission rate (Ib/hr) • NO2 cone (ppn by vol, db corrected*) x 39^6 x l x vo1 flow rate 'dscfh)
O . o x
.0 Ib/hr
NO emission rate (Ib/hr) - NO emission rate O &2,*- Ib/hr + NO2 emission rate O- 6 Ib/hr
Ib/hr
•Corrected for zero and calibration drift
-------
CO CALIBRATION CORRECTION DATA SHEET .
METHOD 20
COMPANY,
SOURCE:
REPETITION NO. : '
TEST DATE: 3.-/f>-ir1
CO average chart reading, % -
CO concentration corrected for zero and calibration drift
CO cone (corrected) « (Av. chart reading , % - Av. zero drift reading , %) x cal drif t°!Sa(ff "* "C%
CO cone (corrected) " (
ppra by vol, db
)% -
%) x
"23 f _ ppm CO
ppra by vol, db
-------
CO, CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. : '
TEST DATE: ?-/O-f-7
average chart .reading, i « _ ~70« 7
CO? concentration corrected for zero and calibration drift:
CO. cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x £ti jffif?0"^' CO:
* Coi. or it t rcdoinQ f
• % CO- by vol, db
CO, cono (corrected) » ( 7O»~f )% - ^-A I) x V. ? t CO,
* ' a 2
- ft. 6 % C02 by vol, db
-------
O, CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY!
SOURCE: SHi«co
REPETITION NO.: /
TEST DATE:
)- average chart reading, I »
O- concentration corrected for zero and calibration drift;
02 cone (corrected) - (Av. d>art reading , t - Av. zero drift reading , %) x ^[ Irlft°reaai °2 %
» t O_ by vol, db
O, cone (corrected) » ( a^«O )% - Q.Q t) x /^?. A to
- (p/7 L* O by vo1' db
-------
ZERO AND CALIBRATION DATA
COMPANY:
SOURCE:
ANALYZER: TffCo
it>
TEST DATE: 3-/O-.P7
fli>/u tvo: i
Zero gas
Low level gas
Mid level gas
High level gas
Cylinder
Value
Iff*
O
fl*
113.1
***
Pre Cal
Analyser
Response
fPl"
0.0
57.0
W
9000
Post Cal
Analyser
Response
2*
£T,o
fro.o
>u*
Cylinder Value
- Pre Cal
Response
0.0
0-3>
- O.I
- o.l
Cylinder Value
- Post Cal
Response
-ar
A-3
3.1
?.
6.I2-
0-oH
01
Post
Cal
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0-9
/^
/ •/
Cal
Drift
Z
/.*
O.J
/.6
/./
i , ^
* Linearity response
,jcylinder value -pre or post cal^ 1Q(J -hould fce < „
span value —
2 Calibration drift
100 should be < 2X
-------
I ,.•<.( |. ' -i r- i r ' .1 t '-1 F
ZERO AND CALIBRATION DATA
COMPANY:
SOURCE:
ANALYZER:
TEST DATE: A-/P-
RisF//uj.D
jy.a
P3/
f?o
Poat-Cal
Analyzer
Reaponse
fit>*
-f.o
So
aa%r
*7l>S
Cylinder Value
- Pre Cal
Reaponae
W*
C,0
3.1
3.o
o.o
Cylinder Value
- Poat Cal
Response
/VA<
Xo
o.Sr
i,t
~c,r
Pre Cal-Poat Cal
Analyzer' Response
P(>*4
<- 3~-
Linearity
Response (Z)
Pre
Cal
6-b
O.t,
o.k>
0.0
Post
Cal
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o-l
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Cal
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0.&
0.3
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1 Linearity r.apona. Jcyllndar
po.t call
, 10Q
1 Calibration drift -prC ^n'vilua x 10° 8hould be 1 2X
-------
'•-1
ZERO AND CALIURATIUN DATA
COMPANY:
SOURCE: -
ANALYZER: #Ot.tM CO&. »»x>«TWO-
TEST DATE: &-/*>-*7
Zero gaa
Low level gaa
Mid level gaa
High level gaa
Cylinder
Value
%&>*_
0.O
¥*
1,t>
Pre Cal
Analyzer
Reaponae
% ^»r.
0.3
1,7
7.3
Poat Cal
Analyser
Reaponae
*/.&>*-
0.3
y.r
9.3
Cylinder Value
- Pre Cal
Reaponae
5fc^z-
-0.3
O.OL
0.3
Cylinder Value
- Poat Cal
Reaponae
^ «^z_
- ^3
o.»-/
0-3
Pre Cal-Poat Cal
Analyzer Reaponae
X> £.&*-
O-O
- o.a.
o. o
Linearity
Reaponae (Z)
Pre
Cal
,2.0
1.3
3..O
Poat
Cal
2-0
2.7
£.O
Cal
Drift
Z
0-0
/.3
o.o
. Icylinder value -"ore or poet call tnn . ... . __
Linearity reaponae -'—* ^j L *x 100 ahould be £ 2Z
2 Calibration drift "pre ,an"vSlue C** 10° 8hould be 1 2Z
-------
ZERO AND CALIURATK DATA
COMPANY:
SOUKCE:
ANALYZER:
TEST DATE: ?-/»-/ 7
Bi£F/wiiu*-
Zero gas
Lov level gaa
lid level gaa
High level gaa
Cylinder
Value
Y.Oi
d.O
—
/a a.
20-1
Pre Cal
Analyzer
Reapooae
%Ai.
o.o
/3-0
50.^
Poet Cal
Analyser
leaponae
% Oi.
o.o
/|. I
Po.7
Cylinder Value
- Pre Cal
Reaponae
%0i
0.0
0.2-
0-0
Cylinder Value
- Poat Cal
Reaponae
7* e>t.
o.o
o.V
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°/» tfj.
O-o
o.-i.
o. z-
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Reaponae (I)
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Cal
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O.O
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I
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TF1T DATE*
RUN NO.: .2
Time
frj-TfSTC*.
low
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-------
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY: ftf-IO *.*?»**•*>*-
SOURCE: ?/"«'«> ^3
REPETITION NO. : a -
TEST DATE: 3.-X/-/7
NOX average chart reading, % «
NO average chart reading, i -
NOx/NO cone (corrected) » (Av. chart reading, % - Av. zero drift reading, %) x cal 9as conc>
cai drift reading, %
» ppm by vol, db
N0x cone (corrected) » ( Jo-9 1 - Q.y I) x /£.?.
-------
t. , i - , : i ,11 I • fc*-. •. < , ' ' '-• :.-.-.•! ' ' '
NOX CALCULATION SI 1ARY DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. i
TEST DATE: ^-//-
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected*) x * A ^ • A A x 10~ x vol flow rate (dscfh)
Ib/hr
NO 2 emission rate (Ib/hr) « NO2 cone (ppn by vol, db corrected*) x ^gg^fi' X 10~ X Vo1 f low rate (dscfh)
- Q.Q Ib/hr
NO emission rate (Ib/hr) » NO emission rate 6-O1/ Ib/hr 4 NO, emission rate £ Ib/hr
Ib/hr
•Corrected for zero and calibration drift
-------
r •"= i
CO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. : ;» - 7^
TEST DATE: 1-//-A7
CO average chart reading, t » p. Q
CO concentration corrected for zero and calibration drift;
CO cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x ca! 9a? conc. ppm CO
^ ' ' cal drift reading , %
• ppra by vol, db
CO cone (corrected) • ( /v O )% - Q. Q I) x C3.35~ ppm CO
•-/7-0 %
• O . O ppn by vol, db
-------
CO- CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO.: 2--~
TEST DATE:
CO2 average chart reading, % »
7 V-
concentration corrected for zero and calibration drift;
C00 cone (corrected) » (Av. chart reading , % - Av. zero drift reading , %) x -a. T*?g?°nC?j* C02-r
* . cal drift reading , V
- \ CO2 by vol, db
CO, cone (corrected) - ( 7V- 2- )% - ^.Q t) x ^ • 9 t CQ^
^1 COj by vol, db
-------
O, CALIBRATION COh.xt .ION DATA SHEET
METHOD 20
COMPANY*
SOURCE:
REPETITION NO.: &-
TEST DATE: 2-//-/• 7
)_ average chart reading, % «
0- concentration corrected for zero and calibration drift;
O. cone (corrected) » (Av. chart reading , t - Av. zero drift reading , t)
)2 cone (corrected)
- ( 'P-Y-
% O- by vol, db
)% - O.Q
%) x
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t \
% O
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-------
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SOURCE:
TEST DATE:
RUN NO.: 3
•"»
CAL CAS CONG
Low
Mid
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C02 X.
CO (ppm)
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COMMENTS
i • • • i - 1 1 1 ii • in ii —
-------
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOORCE:
REPETITION NO.: 3 -
TEST DATE: >-//-*• 7
NO average chart reading, % •
NO average chart reading, I •
NO /NO cone (corrected) - (Av. chart reading, t - Av. zero drift reading, %) x cal 9as conc' PP*
cal drift reading, t
» ppin by vol, db
NO cone (corrected) - ( «3 ?• / _ % - 0.£ _ %) x _ /2 3- 9 PPm
vT A 6 %
_ ppn> by vol, db
5 9
NOx conc (corrected to 15% 02) » _ x ^^-^ •_ - » _ ^ppm by vol, db
NO conc (corrected) - ( _ % - _ %) x _ ppm
%
- ~7 O . ^ _ ^ppw by vol, db
NO- conc (corrected) »
-------
NOX CALCULATION SU. JVRY DATA SHEET
METHOD 20 '
COMPANY: '° t-1 F »*•**>*•
SOURCE: J"'"*
REPETITION NO. : /?u/O3
TEST DATE: 3--
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected* )x-jg^yj^ x 10 x vol flow rate (dscfh)
70. r x
Ib/hr
NO2 emission rate (Ib/hr) <• NO2 cone (ppn by vol, db corrected*) x j^g^jg x 10~ x vo1 flow rate (dscfh)
- O-O * x x
- 0-6 Ib/hr
NO emission rate (Ib/hr) - NO emission rate 6. O* f Ib/hr -f NO2 emission rate O-O Ib/hr
0*01* Ib/hr
•Corrected for zero and calibration drift
-------
rn i.>'.f . rr.i
CO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY!
SOURCB:
REPETITION NO.:^
TEST DATE: O-//-/7
CO average chart reading, % » _ O-
CO concentration corrected for tero and calibration drift;
**
CO cone (corrected) - (Av. chart reading , 1 - Av. zero drift reading , t) x
» _ ppoi by vol, db
CO cone (corrected) " ( _ 6- O _ )* - O*O _ %) x _ 335~ _ ppm CO
- _ &.O _ ppn by vol. db
-------
CO, CALIBRATION CORRECTION DATA SHEET -
METHOD 20
COMPANY:
SOURCE : ^/f tie CO jjd c-srt-f/** J*T
REPETITION NO.: 3 3T/V/*T To
TEST DATE: JL ~//~fr J
CO2 average chart reading, 1 «
CO-, concentration corrected for zero and calibration drift;
C02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading . %) x
- _ % C02 by vol, db
C02 cone (corrected) - ( _ £7.3 )1 - Q . Q _ %) x _ ^. 9 % co_
30-O r
" _ S/-O _ 1% C02by vol, db
-------
02 CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO.: 3 - T"*-* T TO
TEST DATB: «2-//-*7
O average chart reading, I •
02 concentration corrected for zero and calibration drift;
02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , t) x
• _ 1 O, by vol, db
cone (corrected) - ( 30»S _ )% - _ £>•& %) x /a.*-
- _ 7-5^ % 02 by vol, db
-------
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TEST PATE: ~ / /-&
RUN NO.:
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7*3 »T£?* f3B Kia m r^n m
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO.:
TEST DATE: 3-
NOX average chart reading, % » ^Q. O
NO average chart reading, % - _
NOX/NO cone (corrected) - (Av. chart reading, % - Av. zero drift reading, %) x cal gas co°ct
cal drift reading, %
• ppn by vol, db
NO cone (corrected) - ( 36 _ % - O Q %)
X
ppm
" 7V. 3. ppm by vol, db
NOx cone (corrected to 15% 02) - _ x 2fl'| - • _ ppm by vol, db
NO cone (corrected) « ( _ % - _ %) x _ ppm
%
PPM by vol, db
NO, cone (corrected) « _ O. O _ ppn by vol, db
-------
' i : i
NOX CALCULATION S. MARY DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO.:V
TEST DATE: a-
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected*) x x 10"6 x vol flow rate (dscfh)
7V/ 2.
Ib/hr
"6
NO2 emission rate (Ib/hr) - NO2 cone (ppn by vol, db corrected*) x x 10" x vol flow rate (dscfh)
t>-O
Ib/hr
NO emission rate (Ib/hr) - NO emission rate Q.ozA Ib/hf •»• NO, emission rate o-Q _ Ib/hr
rt ' •^^•^•^•^^•^^^^•t ^ *^M~-M« _ — n _ . - - . _ _
0.0i(, _ Ib/hr
•Corrected for zero and calibration drift
-------
CO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. : y
TEST DATE : 2 V/V 7
CO average chart reading, % »
CO concentration corrected for zero and calibration drift;
*'
CO cone (corrected) - (Av. chart reading , t - Av. zero drift reading , t) x • . %^?F. „,_..{_„—«-
CXX.L CJL -It 17GCKJ1.I|(J t %
- ppra by vol, db
CO cone (corrected) " ( O.3 )% - Q-3 *) x 235" ppm CO
•» g>.Q ppra by vol, db
-------
CO, CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE: f ft i*£ o
REPETITION NO.:
TEST DATE: >~
CO2 average chart reading, % • £7,3
CO- concentration corrected for zero and calibration drift;
C02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x g| Irift^adi C°
- _ % CO2 by vol, db
CO- cone (corrected) - ( <<7>3 )% - — Q.T _ %) x _
-------
0, CALIBRATION CORRLCTION DATA SHEET
METHOD 20
COMPANY: A*/ O
SOURCE : $ ft i* co "ZTTi c.swmn r->e.
REPETITION NO. : y
TEST DATE: ^-
0- average chart reading, % » _ ' T f* 7
0- concentration corrected for zero and calibration drift;
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^ . • Ccij. on. rc rcdcurxj , •
» % O, by vol, db
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• ?. (
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ZERO AND CALIURATION DATA
COMPANY:
SOURCE: S/fiC<.£>
ANALYZER:
TEST DATE:
SO
Zero gaa
Low level gaa
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Cylinder
Value
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-------
^—C^ -i_
I —
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Col«-Paim«r instrument Company
ChieaflC, iltinoii 60648
-------
ZERO AND CALIURATIU, DATA
COHPANT:
SOUKCE:
ANALYZER:
TEST DATE:
Zero gas
Low level gas
Hid level gas
High level gaa
Cylinder
Value
o-o
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Analyzer
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100 should be < 2Z
-------
•r*i
ZERO AND CALIBRATION DATA
COMPANY:
SOUKCE:
ANALYZER:
TEST DATE: &-//-& 7
Zero gaa
Low level gaa
Hid level gaa
High level gaa
Cylinder
Value
0.O
3&.S
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f70
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« 100 ahould be 2Z
-------
L.ML. OAi L.UNC.
SOUKC
TKST . :
RUN NO.: S~
Low
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FIELD DATA SHEET
C0*2 I
CO (ppm)
v. y
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-------
ZERO AND CALIBRATION DATA
COMPANY:
SOURCE: StiUtio
ANALYZER:
TEST DATE:
Zero gaa
Low level gas
Hid level gaa
High level gaa
Cylinder
Value
fco,.
o.o
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Jo.?
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Analyzer
Reaponse
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Analyser
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Raaponae
% **~
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O.I
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Analyzer Reaponse
7 % oL
o.o
O. I
o.\
Linearity
Reaponse (Z)
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Cal
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apan value
1 Calibration drift Jp" c.l - poat call
apan value
x 100 ahould be < 2Z
fce <
-------
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. : 5"
TEST DATE: P"/<2-
NO average chart reading, % »
A . .
NO average chart, reading, % »
NO /NO cone (corrected) - (Mr. chart reading, t - Av. zero drift reading, %) x cal gas cone, ppm
cal drift reading, %
• ran by vol, db
NO cone (corrected)
- ( -#0,
NOX cone (corrected to 15% 02) -
\ -
%) x
ppm by vol, db
5 9
'
3. _ ppm by vol, db
-------
« "»
: •' .1 ''
CAL CAS CONG
SOURPE:
TEST DATE:
RUN NO.:
Low
Mid
FIELD DATA SHEET
C02 X —
CO (ppm) -TO.*
MOK (ppm) S~7>.
/X 3-
Time
13/0
Ji/£r
/2Z0
luf
1*30
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by dlff.
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T PPM
cxo
COMMENTS
-------
CO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY i 0£-/0
SOURCE: $& i*co
REPETITION NO.:
TEST DATE: -?-/.*--/• 7
CO average chart reading, % »
CO cone (corrected) "
' £>
)t -
%) x
ppm by vol, db
CO concentration corrected for zero and calibration drift;
CO cone (corrected) » (Av. chart reading , t - Av. zero drift reading , %) x ca qas conc' PPm co
« ppm by vol, db
%
e&3
ppm CO
-------
I I
NOX CALCULATION £ MARY DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. :
TEST DATE: d--/i-
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected* ) x x 10 x vol flow rate (dscfh)
Ib/hr
NO2 emission rate (Ib/hr) - NO2 cone (pan by vol, db corrected*) x - x 10" x vol flow rate (dscfh)
Q.6 _ Ib/hr
NO emission rate (Ib/hr) - NO emission rate
Ib/hr 4 NO2 emission rate C-O Ib/hr
Ib/hr
•Corrected for zero and calibration drift
-------
02 CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY i
SOURCE:
REPETITION NO.:
TEST DATE: jL-/*~
2 average chart reading, % » _ 3^» V
O2 concentration corrected for zero and calibration drift;
O, cone (corrected) - (Av. chart reading , t - Av. zero drift reading , %) x ca! I8?-00"0'.* °2
* ^ i • • cal drift reading , %
• % O- by vol, db
O2 cone (corrected) - ( 3o*H )% - a.Q I) x /;?. 2. t o2
- "?•(» ^% 02 by vol, db
-------
CO- CALIBRATION CORRE ION DATA SHEET
METHOD 20
COMPANY :
SOURCE:
REPETITION NO
TEST DATE: y-
average chart reading, % - _ & /-
CO, concentration corrected for zero and calibration drift;
CO- cone (corrected) - (Av. chart reading , t - Av. zero drift reading , %) x Fal gas cone, \ CO2
2 ** • • cal drift reading ,\
- _ % CO2 by vol , db
CO2 cone (corrected) - ( &/• 3 _ )% - t> . 6) _ t) x <],£ _ % co
W-0
by vol , db
-------
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ZERO AND CALIBRATION DATA
COHPANY:
SOURCE:
ANALYZER:
TEST DATE:
Jit/AJ Ax !•'>.'
f-O
-/* ~f 7
Zero gaa
Low level gaa
Mid level gaa
High level gas
Cylinder
Value
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s~o.r
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Reaponse
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Analyser
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« 100 should be < 2X
-------
ZERO AND CALIBRATION DATA
COMPANY:
SOURCE:
ANALYZER:
TEST DATE: J -/>-& 7
fLit** Ax>.'* : r*«o4
Zero gaa
Low level gaa
Mid level gaa
High level gaa
Cylinder
. Value
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r7.5
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/11.2-
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3-7
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apan value
100 should be < 21
•Calibration drift
, 100 ahould be < 2Z
-------
4 i
•- .-.J I-..- ! C.:> J
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ZERO AND CALIBRATION DATA
COMPANY:
SOURCE: S/* <*«.«>
ANALYZER:
TEST DATE: 3 -
Zero gaa
Low level gaa
Mid level gaa
High level gaa
Cylinder
Value
%<>*.
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Reaponae
% o>_
0.0
0.3.
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Reaponae
% *»-
0.0
0^
0-0
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% O t_
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Response (Z)
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Cal
0.6
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Cal
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Drift
Z
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— v - —
« Calibration drift -ll>r* .^"v^. Ml|« 10° «hould b« 1 2I
-------
r*~i
rr? rv
ZERO AND CALIURATION DATA
COMPANY: Bc'°
SOURCE:
ANALYZER:
TEST DATE: 2-/*-J7
Zero gaa
Low level gaa
Hid level gaa
High level gaa
Cylinder
Valira
% coz
0.O
v.^
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Pre Cal
Analyser
laaponae
% C«t
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:
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N02
by diff.
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NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOU RCE : 5/**/* c o
REPETITION NO. :
TEST DATE: 2~/
NOX average chart reading, I •
NO average chart reading* I »
NO /NO cone (corrected) - tAv. chart reading, % - Av. zero drift reading, %) x cal 9as oonc>
cal drift reading, t
on by vol, db
NOX cone
NO cone
NO cone
NO- cone
(corrected) « ( 3f- "7
97,7
(corrected to 15% O,) •
(corrected) - (
?77
(corrected) - O.d
% - S.O %) x /3?.« ppra
il* \
ppm by vol, db
C n
X—* —— a nnni hv vnl t\h
IJl H ... . «•«« »*y vux, uu
% - %) X ppm
t
ppm by vol, db
ppm by vol, db
-------
-------
CO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO.: C
TEST DATE: *-/*-
CO average chart .reading, % »
CO concentration corrected for zero and calibration drift;
CO cone (corrected) » (Av. chart reading , t - Av. zero drift reading , I) x
CO cone (corrected) " (
4tti
_ppm by vol, db
)% -
/.£>
t ) *
O. C>
ppm by vol, db
C
ppm CO
-------
1 I •
NOX CALCULATION S 4ARY DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. I 6
TEST DATE: jL-/Z-
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected* ) x x 10~6 x vol flow rate (dscfh)
ib/hr
NO 2 emission rate (Ib/hr) - NO2 cone (ppra by vol, db corrected*) x 355^6 x 10~ x vo1 flow rate (dscfh)
O- O v x
Ib/hr
NO emission rate (Ib/hr) - NO emission rate O-Olf Ib/hf •»• NO2 emission rate <^-Q Ib/hr
- 0.0ar Ib/hr
*Corrected for zero and calibration drift
-------
0- CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY i /?*/*>
SOURCE: Sft-i*.co
REPETITION NO. : i
TEST DATE: *-
average chart reading, % - 3 f _.
concentration corrected for aero and calibration drift:
02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x gfl Irift°readirM2 %
• % O- by vol, db
O, cone (corrected) - ( 3% / _ )% - p .O _ I) x / y ^~ * .°2
2 —^ r
_ '% O, by vol, db
-------
CO2 CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. :
TEST DATE: 3 -/*
average chart reading, % «
CO.» concentration corrected for zero and calibration drift;
JL
C02 cone (corrected) » (Av. chart reading , % - Av. zero drift reading , I) x ^} JriftTreadi ^
m _ % CO2 by vol , db
CO, cone (corrected) - ( *J$'f )% - 0.V _ %) x _ */. J t
* •-""'"••-
- _ 1.\ _ I C02 by vol , db
-------
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TEST DATE: *•
RUN NO : "7
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TEST DATE;
RUN NO.: 7
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FIELD DATA SHEET
I .'. -I , • I
CAL CAS CONG
Low
C02 Z
CO (pp.)
Oxygen
5 min avg.
Ti
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NO CALIBRATION CORRliCTtON DATA SHEBT
METHOD 20 -
COMPANY :
SOURCE:
REPETITION NO.: 7
TEST DATE: £~/3-f 7
NO average chart reading, % -
NO average chart reading, % • _
NO /NO cone (corrected) - (Av. chart reading, % - Av. zero drift reading, %) x ** 9as oonc'
x cal drift reading, %
• _ ppn by vol, db
NO cone (corrected) - ( 37>^ % - 3 -3 _ »)' * /3?-f - EE™
x
pp« by vol, db
NOX cone (corrected to 15% 02) - _ x ^|^ - " - "* by v°1'
NO cone (corrected) - ( _ % - _ »> x - EEE
%
• 9/ ^^ Pt>m by vol, db
N02 cone (corrected) = &.b _ ppm by vol, db
-------
— - ..? ^ -,~, -- , ,..,;,..,..--..
* _
SOURC.E: St*i£-i- f> £fcc./#-f*ftt~oe
TEST DATE; --/-J-fr?
RUN NO.: 1 FIELD DATA SHEET
Tine
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"~ /^.2_ PO-9
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NOX (ppm) s~7. 3, /^3'^ /ff. 2-
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by dlff.
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—
COMMENTS
-------
i. . i •• ~ i . : i .-i) i ' • i- • \ i •;• • . >••-• , . .. '• I .• . :•;:•.•.!
NO CALIBRATION CORRECTION DATA SHEET
METHOD 20
COMPANY :
SOURCE:
REPETITION NO. : 7
TEST DATE: ;i-/3-f 7
NO average chart reading, % » j?7,
NO average chart reading, % »
NO /NO cone (corrected) - (Av. chart reading, % - Av. zero drift reading, %) x cal gas oonc>
* cal drift reading, %
« npn by vol, db
NO cone (corrected) - ( 3 7- 4 _ » - 3-3 _ %) x /3?, ppm
x
» _ 9/?5"" ppm by vol, db
NO cone (corrected to 15% 02) - _ x 2oJ - - " _ ^PP1" by vo1' db
NO cone (corrected) - ( _ » - _ %) x
•*" PP»" *>y vol, db
NO2 cone (corrected) = 0.b _ ^PP"> by vol, db
-------
I < I L L I t
CO CALJ .ION CORRL^i'ION DATA SHEET
METHOD 20
COMPANY:
SOURCE :
REPETITION NO. :
TEST DATE: PL-X
CO average chart reading, % - _ O
CO concentration corrected for zero and calibration drift;
CO cone (corrected) » (Av. chart reading , % - Av. zero drift reading . t) x "j 9af conc* PP™ CO
^ cal drift reading , %
• ppm by vol, db
CO cone (corrected) - ( O )% - Q t) x &35~ ppm CO
O. O ppm by vol, db
-------
NOX CALCULATION SL..HARY DATA SHEET
METHOD 20
COMPANY :
SOURCE:
REPETITION NO. : 7
TEST DATE: A-//-/ 7
~6
NO emission rate (Ib/hr) - NO oonc (ppn by vol, db cx>rrected*)x x 10~ x vo1 flow rate (dscfh>
Cf>30 Ib/hr
NO2 emission rate (Ib/hr) - NO2 oonc (pp» by vol, db corrected*) x 39^ ' jg x 10 x vo1 flow rate (dscfh)
*
C>-O x x
- _ 6-Q _ Ib/hr
NO emission rate (Ib/hr) - NO emission rate Q.O3Q Ib/hr + NO2 emission rate Q.& Ib/hr
Ib/hr
•Corrected for zero and calibration drift
-------
I .J I • „ I. -. I . - I : » - •-, J ... .' ?-.:.: ' t • ,1 J - .4
0, CALII .VION CORRECTION DATA SHEET
METHOD 20
COMPANY:
SOURCE:
REPETITION NO. : ~7
TEST DATE: *-/?-* 7
0 average chart reading, % -
OT concentration corrected for zero and calibration drift:
02 cone (corrected) - (Av. chart reading , t - Av. zero drift reading . t) x ^ Irift°reaa* °2
% O~ by vol, db
'2
O, cone (corrected) - ( ?£•(> )% - t) x 30 ? lo
2 - _
- 2^ _% 02 by vol, db
-------
CO2 CALIBRATION -REv_fION DATA SHEET
ME1. J 20
COMPANY:
SOURCE:
REPETITION NO.: 7
TEST DATE: 3-/T-1- 7
CO2 average chart reading, %
CO2 concentration corrected for zero and calibration drift:
C02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x ^[ Icift^adi
ciftadi
% CO2 by vol t db
CO, cone (corrected) - ( f C-1 _ )% - _ 0. O _ %) x _ 9> (,
*
• "7 _ '\ CO2 by vol , db
-------
o V
r .7;
-------
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CO
CO
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x-l
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T u A 4
n « T *
n
2 5 3 i
^ '
-------
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o
UAL CAS CONG
TowMil
Hi-1-
* •* '2
TKST DATE: . /*-3? 7 C02 Z
c. f>. * FIELD DATA SHEET CO (ppn)
RUN NO.: y I£Z_ N0^ (ppm>
Tine
/.T'B1/
ififl
/rvy
A *«•*-/
™ il (
src/»i-
o
/»/
.
Oxygen
S Bin avg.
Chart
Rdg.
Z ZO*
7^3
p^..5
57^
"T?^«/Tn
* .S I
P/.o
\s-f.at3?
o.&
3V, / r, /
^j.o f-^
CO
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Chart
Rdg.
Z PPM
0.0
o-o
O.o
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O.c) 0*)
0,0 £,.<»
ft 2 Wo
V7.1 l*.o
NO
5 Bin avg.
Chart
Rdg.
* CPU
33.?
***•
3L>I
1*1?
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// *-*
72.5" r^-J
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to.i> ito-O
NO
S Bin avg.
Chart
Z6' PPM
.
N02
by dlff.
Chart
Rdg.
r PPM
— /3. 2- pt /
— V. 9 ?,&
^•ff'J 2* f~ V?0 O
> ^~7'^ /-i^'9 /ff.T—
COMMENTS
.
-------
• I - .i '
SOURCE: S*l£c O
Low
TF.ST DATE:
RUN NO.: £
>}-*-?
FIELD DATA SHEET
c *
c62 z
CO (ppB)
NO, (ppB]
ma High*
/^•^ ££• "'_
-235" ^7^> O
Time
xygen
5 Mln avg.
Chart
Rdg.
z
CO2
5 Bin avg.
URaTtl
Rdg.
Z ZCO,
CO
5 nln avg.
Chart
Rdg.
Z
NO
5 Bin avg
Chart
Rdg.
NO
5 Bin avg.
Chart
Rdg.
X
PPM
N02
by diff.
Chart
•f-
COMMENTS
A?'//
oo
p/.b
Q.O
1ft
ill
JW
3UL
/jf.o
a*.
W.7
JLfiL
37.
1^0.
DL2.
Od
00
o.o
O.b
37,z.
0-°
o.o
0-0
-------
NO C,. URATION CORRECTION DATA L
METHOD 20
COMPANY: 84/6
SOURCE:
REPETITION
TEST DATE:
NOX average chart reading, I - ;??./
NO average chart reading, I »
NO /NO cone (corrected) - (Av. chart reading, % - Av. zero drift reading, I) x cal 9as conc>
x cal drift reading, %
=• ppm by vol, db
N0x cone (corrected) - ( ?7-/ % - S-*~ t) x /3J PPm by vol, db
-------
NOX i CULATION SUiMARY DATA SHEET
METHOD 20 '
COMPANY:
SOURCE:
REPETITION NO. t
TEST DATE: 3-
NO emission rate (Ib/hr) - NO cone (ppn by vol, db corrected* Jx-- x 10 x vol flow rate (dscfh)
Ib/hr
N02 emission rate (Ib/hr) - NO2 cone (ppn by vol, db corrected*) x j8jf26 x 10~6 x vo1 flow rate
-------
: i
CO2 CALx CATION CORRECTION DATA SHEET
METHOD 20
COMPANY!
SOURCE:
REPETITION NO.: f
TEST DATE: P-//-/ 7
CO2 average chart reading, I »
CO- concentration corrected for tero and calibration drift:
C02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , ») x ^} Irif t°readi C°21
m _ % CO2 by vol , db
)% - _ O.O _ I) x _ 9. V t co..
CO, cone (corrected) - ( fS-ST
* "
_% CO2 by vol , db
-------
CO CALIBRE , CORRi^TION DATA SHEET
METHOD 20
COMPANY :
SOURCE:
REPETITION NO. : ?-
TEST DATE:
CO average chart .reading, % «• _ O •
CO concentration corrected for zero and calibration drift;
CO cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x
ppm by vol, db
CO cone (corrected) • ( **•&> _ )* - _
-------
• t
ZERO Ai ALIHRATlo.i DATA
COMPANY:
SOUKCE:
ANALYZER'.
TEST DATE:
A»0.
Zero gas
Low level gas
Mid level gas
High level gas
Cylinder
Value
o o
r?.3
/*3?
tm
Pre Cal
Analyzer
Response
O.D
&&
&¥.o
IM
Post Cal
Analyzer
Response
**
rd-3
ll>~t>
100.&
Cylinder Vslue
- Pre Cal
Response
o.o
IS
' 0,1
o.*
Cylinder Value
- Post Cal
Response
~?f
/O
- 1,1
-o.r
Pre Cal-Poat Cal
Analyzer' Response
+*•*
o.*
-//.o
y-AZ
Linearity
Response (Z)
Pre
Cal
0-0
O.-L.
,.oH
O.K.
Post
Cal
l'*~
o V
o-l'1
O ^2-
Cal
Drift
Z
Ar
O.X
/>-v
*.v*
1 Linesrity response >/""*•*
1 Calibration drift "lpr'
P°at
Cal|
n 100 should be < 2X
»«» -hould be < 2X
-------
O- CAL^.. -ATION CORRECTION DAT; ^HEET
METHOD 20
COMPANYs
SOURCE:
REPETITION NO.\&
TEST DATE: 2--/-
, average chart reading, % - 33-
0? concentration corrected for zero and calibration drift;
02 cone (corrected) - (Av. chart reading , % - Av. zero drift reading , %) x ^ d^ift°reading2, %
• % O- by vol, db
O, cone (corrected) - ( 33-Y >» - O »> x /*'*• *P-2
V ft *
'% O, by vol, db
-------
ZERO AND
.URATIi DATA
COMPANY:
SOUIICE:
ANALYZER:
TEST DATE:
Zero gas
Low level gas
Hid level gas
High level gas
Cylinder
Value
O.o
H.1
9. t,
Pre Cal
Analyzer
Reaponae
0.O
y.*Y
f.v
Post Cal
Analyzer
Reaponae
O-O
Z~i/0
f.3>
Cylinder Value
- Pre Cal
Reaponae
t>.o
—
-Q.0*l
£>.Z*>
Cylinder Value
- Poat Cal
Reaponae
0.0
~0.2.*>
0 •*
Pre Cal-Post Cal
Analyzer' Response
O . O
o./t,
oJO
Linearity
Response (Z)
Pre
Cal
0.0
—
a s
y.^
Post
Cal
O 0
• —
/-^
?.*
Cal
Drift
\
o-d
—
//
4-70
1 Linearity reaponae
1 Calibration drift -«*•
Icvlinder value -pre or poet calj^ 1QO should faa <
•pan value —
10° 8h°Uld b* 2X
-------
ZERO AND i
.RATI' DATA
COMPANY:
SOUHCE:
ANALYZER:
TEST DATE:
C.O
Zero gas
Low level gas
Hid level gee
High level gae
Cylinder
Value
o-o
foX
>3To
HIO.D
Pre Cal
Analyser
Response
00
ro.r
wr
^7*.^
Post Cal
Analyser
Response
o-o
^0
2~3t,t>
wzf'
Cylinder Value
- Pre Cal
Response
O-O
o*s>
- v.r
—0,5"
Cylinder Value
- Post Cal
Response
O-O
- O.P-
~ AD
^^.r
Pre Cal-Poat Cal
Analyser' Response
0.0
O.JT
.?.r.
-r 7/^>
Linearity
Reaponae (Z)
Pre
Cal
00
0-06
o-t
6-1
Post
Cal
d-0
0.0'/
0 i.
/•*
Cal
Drift
Z
0-0
0-|
07
/'/
i . i cylinder value -pre or post cell lnn . . . .^ . 9.
1 Linearity response -1-1 span value * should be _< 2Z
* Calibration drift
_|pre eel - post cal|x
span value
<
-------
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60648
L
[
-------
c—i IT*: LT- i .j i , i . i
r,~~ r~ '• r"r:
ZERO / v^IURATION DATA
COMPANY:
SOURCE:
ANALYZER:
TEST DATE: ,Z.-/J-»f7
Zero gas
Low level gas
Hid level gaa
High level gas
Cylinder
Value
o.o
<~
/3/2-
**1
Fre Cal
Analyser
Response
60
—
11-1
90. t
Post Cal
Analyser
Response
0.0
M
U*
Cylinder Value
- Pre Cal
Reaponae
0.0
o.S
o.l
Cylinder Value
- Post Cal
Response
O *t>
—
— O. x.
- 0.3
Pre Cal-Post Cal
Analyzer' Response
0 .€>
o.f.
o.V
Linearity
Response (Z)
Pre
Cal
0-0
—
/a.
O'H
Post
Cal
O.o
—
O tf*
/^
Cal
Drift
Z
d-0
—
P'^
/^
Icylinder value -'pre or poet
1 Llneerity response -'-« 1,
span value
lofl
' Calibration drift -
10° Bh°uld b" 2X
-------
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I
4171
OPTIMUM WAVELENGTH DETERMINATION .DATA FORM
Spectrophotometer nvunber
Calibrated by
Date
Reviewed by
Spectrophotometer
• setting, nm
399
400
401
402
403
404
405
406
407
408
409
410
411
412
413
414
415
416
Absorbance
of standard
ODa
Absorbance
of blank
ODb
.
•
Actual
absorbance of
ODC
o.Jtfy
0.24£
O.34?
0.37/
O.37i
' O.273
o.a*v
o.3?r
O.37V
0.>7-a.
0.3.7;
0.270
0.165
0.2*7
-------
1
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API
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
* p
sc
£>.i*«-
* 17.64
in. Hg, T. - f^o °R
• ^
(Vf - 25)
Pf Pi
Tf ' T^
" X**7
Euation 6.1
Total vg NO2 Per Sample
A -
OD, F
Eouation 6.2
m » 2K AF
c
of -NO
Sample Concentration
C -"6.243 « 10
-5
^^
TQ
LVSC J
^?.rfV^x io~3 Ib/dacf
Ib w 385.5
x "~ x
Emission Rate
x 0 -
/hr
dscf/hr
-------
F:
C
h
i
C
t
AF
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
in. Hg, Ti
sc
17.64 (V - 25)
Tf T±
Equation 6.1
Total ug NO. Per Sample
A • O./VO OD
Eouation 6.2
a - 2KC AF
V9 of
Sample Concentration
'5
C .6.243 x ID
Ib .. 385.5 1Q6
x "^ * i0
-S— 1 -
sc J
10"5 Ib/dscf
ppm
Emission Rate
Ib
Ib/hr
dscf/hr
-------
API
/-17-f"7
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
r p
sc
17.64 (V- - 25)
*
=
A A
S067 ml Equation 6.1
r
Total ug NO. Per Sample
K - 47?
OP, F » / Equation 6.2
m » 2K AF
"
of -NO
Sample Concentration
C -'6.243 x 10
"5
L " • ]
I sc J
• 0.
10~5 lb/dac£
Emission Rate
x Q
/te
dscf/hr
-------
\-
F:
i-
t
I
Afi
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
' p
Vsc - 17.64 (Vf - 25)
ml Equation 6.1
Total yg NO. Per Sample
A • G./VO OP/ P * / Equation 6.2
a » 2K AT
C
V9 o£
Sample Concentration
C -6.243 x 10
lb „ 385.5
"5
LV»c
10"5 Ib/dscf
ppm
Emission Rate
Ib
Ib/hr
dscf/hr
-------
r
ARI
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
' P
pi
17.64 (Vf - 25)
p p
~ - jpi
ml Equation 6.1
Total vg NO Per Sample
OD> F • / Equation 6.2
m « 2Ke AT -
pg of
Sample Concentration
C - 6.243 * 10
"5
2— 1 - t-
* 10"5 Ib/dscf
ppn
Emission Rate
lb/hr
QS «
dscf /hr
-------
API
t-W-7
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
, T -
V « 17.64 (Vf.- 25)
•
~ '
Total yg KO. Per Sample
, P • I Equation 6.2
m - 2KC AF -
of N0
Sample Concentration
C - 6.243 x 10
-5
m
sc
10"S Ib/dacf
10* -
Emission Rate
Ib/hr
dscf/hr
-------
API
3
/-;i7'/7
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
vf-
V - 17.64 (Vf -
^' Ti *
25)
ml Equation 6.1
Total yg NO2 Per Sample
K • ^7/f-
A • 19.3/&
Equation 6.2
« 2KC AP -
yg of NO2
Sample Concentration
C - 6.243 x 10
-5
ra
LVsc J
- /•
10"5 lb/dscf
Emission Rate
lb/hr
dscf/hr.
-------
ARI
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
in. Hg, TL
V - 17.64 (V, - 25)
sc *
•f Ai
E
-------
r
F
r
r
r
ARI
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
vf • 3070
/ T
pi
in. Hg, T - 5"3
sc
17.64 (V - 25)
Tf TL
ml Euation 6.1
Total vg N02 Per Sample
A
OD, F •_ / Equation 6.2
m » 2K AT •
c
vg of -NO2
Sample Concentration
C -'6.243 x 10
-5
m
sc J
» 10"5 Ib/dscf
L
L
L
Iscf
Emission Rate
Ib/hr
dscf/hr
L
-------
ARI
NITROGEN OXIDE CALCULATION FORM
(English units)
Sample Volume
ml,
Pi
V - 17.64 (V, - 25)
sc £
ml Equation 6.1
Total V9 NO, Per Sample
A - g.r/f OP
Equation 6.2
m - 2K AT 70Y vg of NO
——~~
Sample Concentration
C -6.243 » 10
-5
sc
10~5 Ib/dscf
Ib. _. 385.S^- 1Q6
X "^
Emission Rate
Ib/hr
dscf/hr
-------
-/7
NITROGEN OXIDE CALCULATION FORM
(English units)
:
Sample Volume
ml, P
pi
V - 17.64 (V, - 25)
sc
Equation 6.1
Total yg N02 Per Sample
A • O.S"/3 OP/ P » Equation 6.2
n - 2XC AF •
V9 of
Sample Concentration
C
»c
10"5 lb/d«c£
Emission Rate
lb/hr
dscf/hr
-------
-------
SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
j ,
I.—
I
APPENDIX C
Scrubber Exhaust Stack
Particulatcs and Sulfur Oxides Field Data
and Calculation Summary Data Sheets
I
r
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
SAMPLE VOLUME
P
f ,•
\ .
^»
!•'
F:
1
u
I
L
L
L
L
i:
V -,270*7 ft3
T ^L ^r ^r ^7 ®O
^J ^ '* ^? •*
Pbax » 30r6,5 i31- HK
Y « 1-OlS r
Vmf-td1 - 17'64 °R X " ••
mCstdJ in. Hg
S02 ANALYSIS DATA
N - ,&&&_&«$ /ml ,d/^6
V « —
tb « 0 ml ^
soln * /^OO ml &OO
V. • /O ml ^-5"
S02 CONCENTRATION IN STACK GAS
_c v nr • v ^ t
C~ - 7.061 x 10 * N lvt ^ l
z v ,
m (s
S02 EMISSION RATE
CS3 x Q<
so2 ^s
^s - >f/^-? . DSCffl
S03 GONCENTRATION.IN.SIAaC GAS
CgQ .- 8.826 x 10" 5 N (Vt - V^) &s
Vm(std)
5^//
Pbar* AH"| 3
- 13. 6 J - A7.53^ftJ
Tm
SO. ANALYSIS DATA
3 t/ )
N • .0/0$ Ce-e
v •
t /y.O ml
Vtb « O ml
V
soln • 5QO ml
Va " /O ml
v pj jvO o.ofi * '•**
soln a • ^.j-ff/ x 10-5 ^
td) ° *
"T«fvt«r 3 f^'3 W& by V
# & .* \ MA ^*
Vji^» w* 7
- 0-3%^ Ib/hr
ioln^a^ • ^?.37ff X 10" 1
* //^'ir? J'111 ^ ^
Equation 6-1
S03 EMISSION RATE
by Volume Dry Basis
-------
( i i
SCHEMATIC OP STACK
PLANT,
AMUIEHT TCNPEHATUHE
— METER
\ ' /
CROSS SECTION
TRAVERSE
POINT
NUMBER
•
10TAL
SAMPLING
TIME
'-'.'•<•/
"\, Vr?
'••*:#?
/•c-:«;.-j
"?:•"
t/;03
If.'M
• i/;&
//;/ v
i/;z»u
ZJ '?'>
:s: *;.
'.•/;••'."
//; //T
y/v '
'/ s>
-]
.1
STATIC
PRESSURE
3X.".*-
\
\
;
b^
^
»iim«i«M«i
LOCATIOl
rjjrvs* OPERATI
STACK IN
MIUMOMI RUN NO.
S 1 ! .
fcAl 1
'* 1 SAMPLE
METER »
STACK
TEMPERATURE
II ,L •'
S~7/
/•?
/5L'<-
ft $\
iii
'
•*"
-
-"
V
X C
(~.O
7. C
9, <9
7A s"
75k o
7"?.^"
7^7 ^)
'/•- . '.; '
~/& 0
-jt.f
tf),o
/V-'. <"
^•y.^j
"^7^
AS1UMEO MOI
PROBE LEHC
NOIZLEMAI
STACK MAMI
PROBE HEAT
NEATER BOX
CAS SAMPLE T
At DRY C
INLET
.?.) *;/::>
J^'-S
., ^»y
^'•r
x"?
>V)
fc^
<7/7
^>
. ^t
»."<•
,-'.t
nuns, x X<2 ».»
Til 1. 3
1C CM vriGHT RAT
r
£, WEIGHT 01= P AH TICUL AT C COLLECT El
. SAMI'LE FILTEfl PHODI
TFR. 1.. .=?
3 FINAL WCIGIII
~Y , .. TAHEHklCllf
•CK.IM CAIH
__ .__ -|,j- .
1ETTIIIC
TOTAL
EMPERA1URE
AS MEIER
OUTLET
IT.^I.-F
'/eV
*>;/
vi
7V
7"/
7/
' ; : *
?:/
"/'•I
• V '-.
• / v
• » -rf
•• -
' '. -:
• •
SAMPLE BOX
TEMI'EHAIURE
•F
TCUPEnAIUHl!
OF CM
LI-AVIIIG
COHOEHltH OR
LAST IHCIIIGEH
•1=
"
PUMP
VACUUM
U. ll(
!••§•
... ' •_• ^—y
VI
-•
LIQUID
•AIERCOU.EC1CD
IMPIMGER
SILICA CLI
'» t»IIMIt.
101*'
'••"„"••
-------
COMPANY:
SOOICE: *"'•
CTITIOHHO:
.i.T DATZ: 3-
>»**.) S
Dry molecular weight of stack gas ^T»
0.44 (ZC02) + 0.32
0.28
XCO)
Molecular weight of stack gas, wet basis
Ms - Md (1-BWS) + 18 Bws
Fitot . tube coefficient
C (from calibration curve)
P
Average velocity head of scack gas, inches B.O
( /A p ) *vg.
Average absolute stack gas temperature
CT§) avg. -
460
alute stack gas pressure
P • P. + (Static Pres»ure/13.6)
S D .«
Stack gas velocity
avg. - (85.49) C
_lb/lb-aole
Ib/lb-mole
in. 1
/ aj wg.
Stack gas volume flow rate
607.A. •
Scack gas volume flow race, dry ba*i*
Qg - 3,600 (l-Btfa)
39.379
ft/sec.
acfm
k«td . P.
dscf/hr
-i
-------
COMPANY:
SOURCE:
REPETITION NO: /-
TEST DATE: 2-/O-f
Volume of sample at standard
conditions on dry basis
ENGLISH UNITS
(29.92 in. Hg 68*F)
mstd
• H
V
ar
A H
13.6
Volume of water vapor in sample at
standard conditions
a
A
•»
if
Vwstd
Vic
•
0.04707 cu. ft.
ml
1103 ml"
Vlc
Fractional moisture content of stack gas
T> . Vwstd ,,«
SI.
ws
V V
mstd 4- wstd
Particle concentration in stack gas on dry basis
.
1.01543
r_
2.205 10
•6
mstd
a.
mstd
Stack gas volume flow rate on dry basis
T
- 3600 (l-Bwg)
(A.
sq.ft. Vg-
lstd .
ft/s«c)
Q.QO
rrocest rate or BTO rating P
Emission rat*
Q c's
Q e's
O.O/ I
dscf
scf.
grains/dscf
x 10"6lbs.
x 10 dscf/hr
..Ibs/br
Ibs/
Isokinetic sampling rate
• 11.667 min
[0.002669 in.Hg.cu.ft.
Bl. "R
ev p A
s s n
0-OOOS3I sq.ft.)
-------
SCHEMATIC OF STACK
PLANT,
DATE .
LOCATIOtfc^Z.
OPERA10R
AMUIEHT TEMPERATURE <£,<"^
i'*/
f. MC10N ^-
PROCESS wciGiir NATE
STACK MO-
RUN HO. _
SAMPLE BOX NO.
METER BOX NO.
MAMETEH. I.. J_
STACK niAMEIEfl.U.
PROBE HEATER
i
NEATER BOX SETTING .
PRESSURE
DIFFERENTIAL
ACROSS
ORIFICE
MET EM
(AN)
•«.|l,0
ACTUAL) be SIRED
WCICIIT OF PAIIIICULAIE COLLCCTEO. ..
UUCLI:
\\\\KV hi M.MI
I iTirwi K'.IH
WLll.lll I.AIM
IILUII
I'llOIII V/
10IAL
TRAVERSE
POINT
HUMBER
SAMPLING
TIME
/37
STATIC
PRESSURE
(U.N.OI
STACK
TEMPERATURE
/?*/
VELOOTT
HEAD
GAS SAMPLE
VOLUME
IV*). hi
30.700
GAS SAMPLE TEMPERATURE
AT DRT CAS MEICH
INLET
IT..J/P
OUTLET
-/a
SAMPLE BOX
TEMPEIIATURE
•F
TEMrERATURE
OF CAl
LEAVIHC
CONOEIUEH OR
LAST lUPIHCER
•P
POMC
VACUUD
In. II,
VELO
9o
C-0
/-7C,
99
77
72
S7V
.06ft
JT9
SSL./
*/:/•?
V7V
.c
/7V
SO*
7/0
s/o
ZLL
-/o.-
/o
/o
.-P
y. /^
*/; vv
101 AL /
7 A
75: A
I/O
AVERAGE
/'•*«••
VOLUME OF LIQUID
HATER COLLECT ED
FINAL
INITIAL
LIQUID COLLEC1EO
TOTAL VOLUME COLLECTED
IMPII
VOL
1 1
I
0 U0
1
ICER
UME -1
I
SCO
.i-
.
4
SW.KA CLI.
Wl IMIT.
rlflO
'
. V
ONtAT HEASUMEMEM1 TIMfc
if.1
•
fff
CO, ll, CO II,
/^*±z i&r"'
-------
c 5
ill?
2
2 s
s; s s
c. x £ i
[ = S£
*•* -i s
^ iu N* z
55 ij
« o
.f —
* s s
o -J _.
f §
*• u
•* <
5 2 1 S
2
w
i
\* ^
u
s
\
! ?
? i
2 ™* ^ ^ W fc •*
^isi^lii
v, <>>>
s$=
s%
^ •• .
h> IU 4
-«*
r
^V
oj I j
w! ! !
I i
ei
w!
•o
= r
i"<
*
*
0
to <5 »| .
^••^ LJ <^ * '
s* i!
H
K
w I
*"l
J
o«
2-
Ow
3"
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
SAMPLE VOLIWE
m
Tm V
Pbar -
Y - 1.015
-ft
_°R
in. Hg
17.64
°R
n. g
A H "1
13.6 J -18.
Equation 6-1
S02 ANALYSIS DATA
N « .OIQfe (g-eq) /ml
•t" U.I ml
tb
ml
'sola « loop ml
V • 1 0 ml
,0)0t»
&.z
o
goo
S02 CONCENTRATION IN STACK GAS
-so.
S02 EMISSION RATE
rm (std)
Qs -
DSCFH
S03 CONCENTRAnON IN. STACK GAS
8.826 xlO
EMISSION RATE
'5
m(st nl
Ib/dscf
3/3>4 PPB by Volune Dry Basis
/. O
X 10"5 Ib/dscf
POP By Volume Dry Basis
-------
.»>«.- I
SCHEMATIC
o
CROSS SECTION
TRAVERSE
POINT
NUMBER
^
•
TOTAL
SAMPLING
TIME
Ul.-u.
/^. 9%
/«:•?
/*'./ +
&*.I7
MM-
/4;*7
//;3a
/f!)7
/tW*'
r w t if *
fff- 5^^^
/O'.fl
//:'>
//•oT
tl.t*
/r.n
OP HACK
T
. *
_L
1
j
STATIC
PRESSURE
»*-y»
"\
1
|
p
-J.I.MMCI 0
L
IWVlM f
J.IT1"
S
INfllHfMlCI H
•*»• 1 •
1 S
M
STACK
TEMPERATURE
I'll*'
S7V
AVERACP. J* : .*i
1 »MT , 4£4Z.SA
OCATIO
iPERAU
TACKNC
UN MO.
UPLEI
ETCRft
VELOCITY
MEAD
• 3^*
•
53
^**** ^c^.« >v«^
M sy***-"?
<&-
IOXHO.
01 MO.
PRESSURE
nFFEREHTIAL
AClfOSS
ORIFICE
MfTER
IXHI
ul.11,0
ACTUAl bESIREO
J2/5
mao
.*0
±a
3.O
^o
•3.0
<&o
**0
•^O
.AO
•Ac
.3.0
•?»
*
:5o
CAS SAMPLE
VOLUME
S9/072
?'*
&.t
f3. 1
w./
?y.f
9f,t^
?t>3
f-yj
07. 9
99.C*
99 Y
300. /
oo. 9
/•c
LJLIL.
I',
AMUIEHT TEN
DAIIOMEIRIC
r ASSUMED HOI
PHOBF. LEIIC
:«)IOZZLE 01 All
STACK DIANE
PROM llEAT
HEATER BOX
CAS SARPLE T
AT DRY C
IHLET
IT-.J.-P
,.^ C.C
i 79
Lr
t?
•70
70
?o
70
70
70
70
7o
70
70
~7o
-7f\
SAMPLE 00 X
TEMI'EIIAIUHE
•F
•
J? Vi
MUCH
TOIAL
TCMrCIIAIIIIII:
III CM
ii A%. mi;
COHUEIIMK Oil
LAH IHI-IHOCII
C./
Co
C.0
Co
La
(,0
C.*
$7
f9
5-9
' f~9
£7
S~f
jOT
-&
_ **
r
I'llODC:
rum-
VACIHIU
U. II,
\~ " ~ ~
»
VELI
d
VOLl'i
WATER
MBBtf
\J\f LIQUID
COLLECTED
FINAL
INITIAL
TOIAL
LIQUID
VOLUME
COLLECTED
CCH.LtCTED
1
1
IMPIHGER
VOLUME «J
1 1 4
„.!_; .
SILICA Ctl
4
IIIMMIMII.
UMSAT BEASUHEMEHI
.^_
1
1
TIME
CO
CO
-------
STACK
•
rvr'
r T
AMUIEHT
*r*-'T
METCH Ally
0
CROSS SECTION
TRAVERSE
POINT
NUMBER
".
TOTAL
SAMPLING
TIME
M.**
//'13-
JJ'Y?
I//'-*/?
'// 'f^1
//:-$"?
•
T
-I.
1
STATIC
PRESSURE
(U.N.OI
tn
t*»
AVFBice
V"
" 4
1
I
-T »
(ttlMMMCI
L(
ftMtfftlMi A
» j3*» " "
SI
ih*iw**
^}7
Sc**/fi<*J,«*7
0
IMPLE BOX NO. t
ETERM
VELOCITY
HEAD
•
S£
IK MO
PRESSURE
DIFFERENTIAL
ACROSS
ORIFICE
MEIER
(j\IU
ACTUAL be SIRED
2-0
.JL0
.30
• vo
•3-0
•2-0
3
CAS SAMPLE
VOLUME
y-7
^f * ^f
£.2^
7.0
¥
\9o
9/
91-
9^-
'
'HFSSUHE . .
IUHS; *
ii i.
FTFP In '
IFII. 1.. ... ,.
EH iFf |llir. .
IFITIIIG
EMPERATUHE
ii MEIER
OUTLET
-?/
7JS
"7<~
-?<-
7*~~
75
r. FA
riioi
Cl"'l
-1 \\ «l ir.HI Ililf _
WIICIIM'I I'AIIIU III All Mill II II II
lAuri I
1 IMAI VI II. Ill
1 AlllTwi 11.11 1
WLII.III (.Alll
SAMPLE BOX
TEMPENA1UHE
•F
I it 1 1 M rmuu •
t
iniAL
TEMPEIIAIUnC
or cAt
LEAVIMC
CONDEIIUM OR
LAST IHIMIICEH
f~f
.c~v
s~t
zrr
s~?
Co
PUMP
VACUUM
I.. II,
•
VEL.
1
•
VDLl'MC OF LIQUID
•AIER COLLECT ED
FINAL
INITIAL
LIQUID COLLECT CO
TOTAL VOLUME COLLECTED
IMPII
VOL
1 1
1
1
ICER
UME «-l
)
|
4
SILICA Ctl.
MIMII.
IIIMML'llll.
UHJAI MCASUntMFIIT
r
1
1
4
TIME
«,
CO
-------
,-**.« ?»«.
COMPANY :
SOURCE: S»i*"o 37
REPETITION NO: i-
TEST DATE: 2 -//-/•?
Volume of sample at standard
conditions on dry basis
ENGLISH UNITS
(29.92 in. Hg 68*F)
nstd
. [l,.*]
Volume of vicer vapor in sample at
standard conditions
lc
Fractional moisture content of stack gas
r
wstd -
V-lc -
0.06707
cu. ft.
ml
B
wstd
vs
V V
mstd + vstd
Particle concentration_in_ stack gas on dry basis
|0.01543
c's
« 2.205 10"6 Mn
V
mstd
Stack gas volume flow rate on dry basis
Qs - 3600 (l-Btfg) VgAg
A • sq.ft. V •
Process rate or BTD rating P
Emission rate _ ,
Q c's
lStd .
? '
' ?
.td
~ fc/««c)
Isokinetic sampling rate
I • 11.667 min ) T
TM/ "
Q.O/g
[0.002669 tn.H.eu.ft.
V, Y
ev p A
sen
dsef.
grains/dscf
10"6lb.
x 10 dscf/hi
Ibs/hr
Ibs/
(A
sq.ft.)
-------
f
r
i
i
i
COMPANY:
sonRcz:
~PETITION NO: .2- ,
TZST DATE: * -x/-/ 7
molecular weight of stack gas
M. - 0.44 (ZCO,) + 0.32 (20,) + 0.28
U i 4,
Molecular weight of stack gas, vet basis
Ms - Md d-Bwl) + 18 BWJ
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, Inches H.O
( VT7 ) *vg.
Average absolute stack gas temperature
ZCO)
lb/lb-nol«
77
Ib/lb-nole
O. 6V O
(Ta) avg.
T + 460
Absolute stack gas pressure
P - P. + (Static Pressure/13.6)
SB .
Stack gas velocity
(V§) avg/- (85.49) Cp
in. H
/(TTwf.
P.M.
.v/.
ft/sec.
I
Stack gas voluae flow race
A4= o07*7
60 7 A
s s •
Stack gas volun* flow rate, dry basis
icfm
L Q. - 3.
L
L
L
600
std . P
SSHO.
dsci
-------
ONSAI MEASUREMCMT
I
1
TOTAf
-------
V-..VA
«..I
SCHEMATIC OP SIACK
V;
>, T
- )'"!•
/ .i.
CROSS SECTION
TRAVERSE
POINT
NUMBER
// "3
•^
/
1
1
|
I
|
-.
TOTAL
SAMPLING
TIME
y^T-ZO-
AF'BJ-
//;$"?
//. */?-
// '.fl-
J/ 'S"7
/*:*o~
•
STATIC
PRESSURE
rnD
r~
|
-1
(••MM/k
-,
I««I2*
nil
• IHXH1CI
H
STACK
TEMPERATURE
y
7/
S71-
/
s 71^
/73*
S'7'2'
/71^
AVERAGE Jll>«J /72.d*
1 IMPINGER
VOLUME OP LIOWO VOLUME «J
•ATER COLLECTED ( ( }
FINAL 1
INITIAL 1
LIOWO COLLECT ED |
TOTAL VOLUME COLLECTED
4
PLANT *_
DATE _
LOCATION
OPERATO
STACK NO
RUN NO. ,
SAMPLE 1
METER Bl
VELOCITY
HEAD
I\P,I U'^l
.Vo
,4yd
r V^
. Vo
,f
.'Tt'
7^"
GAS SAMPLE
VOLUME
IV.I.1.1
4t2^
¥¥•&
77.7-
Yf.f.
£la.o
_«ry. y
£&. f
3*?' 2^
j£S.Co\
0.781 ^.^
OHiAl MEAVUREMEM1 TIME
I
i
i
4
AMUIENT TEN
OAROMEIRIC
AMUMEDMOI)
PHOBF. LEIIC1
HOIILEDIAM
STACK DIANE
PROBE llEAT
HEATER BOX
CAS SAMPLE T
AT DRT Cl
INLET
IT..J.-P
4P /«3
O sa3
o i/4,3
«•» ytf.3
*B» /"tf.3
*» sof
0 SO"?
<* So-?
•
co,
1
"i
•*••
PFIIA1IIBF UFlmAll
•HFt)UMF f FAfinu
luue, \ i...n
III 1.
riM «i iciir HA 11
F
vciciif 01 rAiincuLAic coiLr.cn ii. ,
uui'Li: riLirii rnoitr v
CTfn u -— •
tFR 1.
ER SETTING
FIIIAL WlilCIII
1AIII. MLIUII
NLIUII CAIII
SET 1IIIC
EMPERATURE
IS MEIER
OUTLET
9o
?f
c2£C;
«a^7
^LC^~
«3.6«^
«P-^y
TEMPERA1URE
OF CAS
LEAVING
COHOENSLR OR
LAM IMriHCEH
•1-
^T?
JT?
S~?
S~?
-------
j- SULFUR DIOXIDE CALCULATION FORM fie./o (2£F//u"O*-
^ (English Units) ,$>* '««.<< •xxc/*'***?**.
ltt/v.3 ^"t ««*•»«». o****5T
r SAMPLE VOLUME *-/'** 7
V • l(o.(*$O ft3
r m
k Tm - £•?.£ / °R
(•" Pbar - 30. £O in. Hg
Y - 1.013
L' Vm(-td) " 17*64 *R
E '" .
S02 ANALYSIS DATA
^ • N - ,6|OCi («-eq) /ml
r Vt" f?.Q ad
[: ' v
vtb • O B!
v
soln » /gaQal
V. - .20 ml
S02 CONCENTRATION IN STACK
C~, » 7.061 x 10 ^1
2
I SO. EMISSION RAZE
• L
S02 x ^s
Qs » ^063 . DSCFH
- so3 vxsmwx.-K.sva.
C^ " 8.826 x 10"5 N (V,.
-»5- t
S03 EMISSION RATE
v YV»rPbar* ^Cl „.„ 3
A \~ 13.6 J • /V'»?p ft Eouation 6-1
T" ^^^^
^ O 1 0 fo N>»oiefi» te-cq") /ml
^ vt- ^7 ^
^ . Vtb » ^ ml
$*° Vsoln • 600 ml
•*5 V» - /O ml
GAS - 114 - A77y *AT*
-v ). cv /vi?/^ o-C/9* '°~c
vm (std) ^w--11
TOTAL. /08.ZL PPP by Volume Dry Basis
Ci) /O7./
" Q. y ^)^ lb/hr
GAS
' vtb5 ^soln^ - /.S8V- X 10"5 Ib/dscf
vm(std) -y^.' a
• '&•« jppn By Volume Dry Basis
IOC Ibs/hr
0.
-------
r—i r
! J
U.IIERATIC OP HACK
PLAMT
—*-r " '«••»
AMUIEIIT
:_ METCIIAH.,
01
CROSS SECTION
TRAVERSE
POINT
IIUMBEft
*
TOTAL
SAMPLMC
TIME
(ttl.-U.
£.:/(•
•tt-^s
JfrM-
*}:$/
^;3£
a:Y/
ML
I'Of
tOL
z://
^Ip./
y?L
^:3/
ITATIC
PRESSURE
0
t^0
^r{&
^^^9
•>o
10
•20
.3.0
,2o
•2o
2Q
S
SSURE
•ENTIAL
l)OSS
IFICE
TEN
kill
M,o
DESIRED
CAS SAMPLE
VOLUME •
^t/tf.fb
XiT.3
st.o
• /(*.&
/7-<~
yy.3
y/o
Sir
£}/. 3
^7A O
^Z*.?
^*3'f^
py. i
-3K;i>
_fl£5.:_iL.
ASVUMED MOM
PROBF. LEIIG1
&M042LE MAM
STACK DIAME
PROBE HEAT
NEATER BOX
CAS SAMPLE T
AT DRY CJ
IIILET
IT..J.-P
9f
90
j ^
9O
90
40
90
90
96
fa
90
90
VI
??
V
h
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111 i. 3 £ _ . .
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3
TER. i.. ....3 "Sr
FA tFimir. •
tEITIIIC — "•
EMPERATURE
IS MEIER
OUTLET
~?f
•77
77
77
-,7
77
77
77
77
77
77
77
7&
?y
>3
7^
I'HOCIU WIICIII IIATI
f
WEIGHT 01 CAIMICULAIE COLLECUO
UUI'Lf:
rillAL WI.IUII
IAML Wtlblir
MCIGIII GAIII
SAMPLE BOX
TEMI'EHAIURE
•
rincn
(•Mom
ini AL
OF CAS
LF.AVIHC
COHOEIIMH OH
LAU IMIMIICER
•F
^"Z—
£o
Co
^y
f?
ff
rr
rt
sr
sir
£~f
ff
S"?
S~7
5~7
_ r.?.
PUMP
VACUUM
I.. II,
§••§•
•
VEI
-•
•
VOLMME OF LIQUID
HATER COLLECTED
PIMAL
IIUTIAL
LIQUID COLLECTED
1
1
IMPII
VOL
1
«GER
UM( -1
1
L_ —
4
SILICA GLI
WIKUIT.
«
(OUMtllll:
IISAT MCASUIICUEMT
1
1
4
IIMt
J?J.
_l'i_
CO
!'•
- )
-------
SCHEMATIC
0
CROSS SECTION
TRAVERSE
POINT
NUMBER
*•
TOTAL
SAMPLING
TIME
(»).•••.
3-36
"1IY/
:*j;«/6
&' <7
*3'.£~L
V;o/
Yioy
'
*
OP STACK
V
T*
t
j_
STATIC
PRESSURE
|
PLANT ._
-, DATE _
MMriMMCI
LOCATIO
|
'
PEHATVME . . l"1
nacttiiua F f
ERAlly -
irinu
ITUME. X PMKCtt*l:ICIir MATE
... . VCICIITOFPAIIIICULAIECOLLCCIEI
SAMI'LC FILTEH PHOIIf.
TER. In
ER SETTINC _
1 ' FIIIAL wciuiii
TAMt ktlLllt
NEIUII1 CAIN
» I flue
EMPERATUME
IS MEIER
OUTLET
tU^I.-F
7-2_
7J
7P-
73-
72-
*7T^
•
SAMPLE BOX
TEMPENAIURE
•F
•
TEMPER A 1 UNI:
OF CAt
LEAVIMC
COHDEMUN OR
LAST IMI'UICEH
•F
'ST*
.£"""?
^T?
<~~?
if-?
g-~?
PUMP
VACUUM
1.. H,
•
.
VI
-•
1
VOll'ME OP LIQUID
WATER COLLECTED
FINAL
IIMTIAL
LIQUID COLLECTED
T< VOLUME COt.LtCTED
IMPINGER
VOLUME -1
t ! 1 4
1
SILICA CLI.
MldlT.
•
UHSAT MEAVUMCMK
TIME
J?J.
J'»_
CO
.!'?
-------
COMPANY:
SOURCE:
REPETITION NO: 3 -
TEST DATE: *- •v**-/' 7
Volume of sample at standard
conditions on dry basis
rased
H
A H
TT6
Volume of vater vapor In sample at
standard conditions
used
v.lc
0.04707 cu. ft.
ml
ml."
le
Fractional moisture content of stack gas
vstd
vs
V V
mstd + wstd
Particle concentration in stack gas on dry basis
o.01SA3 ~
L -ll ^Mtd
. 2.205 10"* Mn
7
mstd
Stack gas volume flow rat* en dry basis
• 3600 (1-B ) V A
vs s s
(As • 0.0747sq.ft. V§-
Process rate or BTU racing P
lstd . rs
-------
p
F
COKPAKT:
SOORCE:
'TETITICW HO: a?—
TEST DATE: ?>-//-
molecular weight of s tack gas
M. • 0.44 (ZC02) + 0.32 (ZOj) + 0.28 (ZHj + XCO)
r
Molecular weight of stack gas. wet basis
Ms - Md (1-B^) * 18 B^
Pitot tube coefficient
C (from calibration curve)
P
^ Avaraga velocity haad of stack gas, iachas
( /A p ) «*f -
Avaragt absolutt stack gas taoparacura
(T ) avg.
*F + 460
r*
r
Absolute stack gas pressure
P • P. + (Static Pressure/13.6)
Stack gas velocity
(V ) avg. - (85.49) C
L
L
L
L
L
L
L
Stack gas *olus» flow rate
60 7 A
Stack gas voluae flow rate, dry basis
Q§ - 3,600
lb/lb-mole
Ib/lb-nole
Q. /£
in. H
/ (T>) ^g.
ft/sec.
207.
acfa
std . P.
• P
.td .
dscf/1
-------
ll
UN1AT UGAiUMEMFJII
AVERAGE
1
VOIUME Of LIQUID
MAIE« COLLECTED
HUTIAL
LIQUID COLLECTED
int.i wni nuF COLLECTED
IMPIMCER
VOLUME "«
1 1 ) <
r~
r
rr
//?^
^
i
lll.ICA CLI
*»IIMII.
»
r^OO
-
-------
..i I _j•. "I
V;
SCHEMATIC OP STACK
y
CROSS SECTION
1
TRAVERSE
POINT
NUMBER
t
TOTAL
SAMPLING
TIME
"?*36
3 ; *//
^'t/C
j:rv
y;o/
v.oy
••
•
T
. 4
i
STATIC
PRESSURE
(U.H.OI
&»/>
^
|
PLANT
_ DATE
LOCATIOt
l-jrte- OPERATO
STACK IM
MNMMMI RUN HO. .
s • i
*"*• 1 SAMPLE 1
METER B<
STACK
TEMPERATURE
S73~
/7O
/7O
/7JL
/7Z
/7/
•
•
AVERAGE IOfh.iD lTL*G-
VELOOTT
HEAD
,£o
y-<2_
.yc>
•y/
.^r
?<
*'//•*"?
« - --
• •
3 —2_
lfl% IM V
MHO
pRf
INFFE
AC
Of
M
1
• fe
ACTUAI
,70
f&
^^*
• f £±
•€fl
•*u
iSURE
IEHTIAL
iloss
PICE
TER
kHI
.M,o
DESIRED
,
CAS SAMPLE
VOLUME
/<4^7
s.y
~7.^
°S&.f~
S1.J
SS~ "7
&*o
BAROMETRIC
ASSUMED MCM1
PROBE LEMC1
NOZZLE WAM
STACK WAME
PROBE HEAT
HEATER BOX
GAS SAMPLE T
AT DRY C
NILET
IT-..1/P
,.O /&£'
«» y*5"
<* \/df
.ft. /Of
ri /Of
.ft. S*f
<~-
k
'
PRESSUnf . e FACTOR .
nuav, x .„__ fnoc v\ \ »rir,i"
\
r-T-
rl| f VEICHT OF PAHIICULATE COLLECTED.
SAMPLE
ETER U i
TER. U,
ER SETTING
FINAL VEICIII
TAHC VEiaiT
NEIGIM GAIN
*
IE T tine
EMPERATUME
IS METER
OUTLET
IT.^I.-F
9o
9o
?A
to
?J>
9o
•
SAMPLE BOX
TEMPERATURE
•F
£L£^*^
^*f~^
urT)
&5~/
£Lf/
*3f~/
FILTER PnOOE •
*
TOTAL
TEMPERATURE
OF CAS
LEAVING
COMOENSLH OR
LAST INHNGCR
•P
15^7
x5""£
r*r^
^c
£~(*
fTTC
PUMP
VACUUM
u. n«
9
f*~^
r
9
9
?
•
b.i»Ji> * s?f {••r-'fof • tt.3.
VEL(
VOIUME OF LIQUID
•ATEM COLLECTED
FINAL
INITIAL
LIQUID COLLECTED
TOT
UUME COI.LtCTED
. Wff- -.»
1114 •
1
1
1
J
ONSAT MEASUREMENT
Tint
.CO
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
SAMPLE VOLUME
E
[.
[
[
F-
v»
Tm
- //.573ft3
-5i!6.3 'R
Pbar - 30.^0 in. Hg
Y
Y V IP. * a H I
m 1 K»T " " t T
...^•17.64 -R X m LOK 1$.(>J -/a.OSlff* Eouation 6-1
n(— / in. Hg
SO, ANALYSIS DATA . SO. ANALYSIS DATA
Z , .,-N i -s .IM 3 / i ^
N •
V
1 -QiQk C£'*O /»! r fMOfe " * * Q > 6 ^ C£-«0 /ml
^.1- ml ^ j Vt " 3.8 ml
vtb « o ml o vtb • ^ ml
VSOU. - J10fi_«l 500 VsoUi.500 ml '
\
E
L
L
L
L
L
v,
so2
so2
Ca
<^
so3
a3
<3,
- £O ml 2-S V. • is\ _,
OCWCENrRATION IN STACK GAS . (il /oS4V/d-^
- 7.061 x 10'5 N CVt - V^ C^ja/Vy (liH) «^* *^* ^^
2 vm (std) TOTJ^ /'OW X 10 lb rf
T&TAL ^V.iT ppm by Volume Dry Basis
MSSIONRATE ^a) ^3,J
x Q. - a.OXTlb/bf
Z ^ V'Vl? ~
" -5"/&V . DSCFH
CONCENTRATICN IN. STACK GAS
T.- 8.826 x 10'5 N (Vt - V^ (Vsoln/Vt) . / v?£ x 1Q-S lb/dscf
V
EMISSICNRATE
3 x Qs • 0.07d- Ibs/hr
5"|l*M DSCFH
-------
&
Ft
51
11
•- e
i s
3 i
-• s «•
I : S
s a i
^ M* O
! I E
? s
&
r
V
§ i«=
3
— HI
3 5 » i 2
x i
w .
1 b
», i.j
US?
..
3S- F
e. •< £ i
x
•si
Sib
3(r Bl-
w« j -
«UJ f *
8
--
at
V
\
M
EJT
*
1.4 ^
y«i ^
l
5-2
i
v*vj
>C
r\
5V
V,
cf
SJV3
>
r^
^
'CU
v.
vj
r>V«i
f;
s
*&
\
i Ji
i ^ ^
w
\
cTl
5- I
i"
Ovj
£^
K/U
-i
-------
r
r
r
COMPANY:
SOURCE: SH>*tv T~c.»
'PETITION NO: V — S*-'"
DATE: J-/V-/-7
Dry molecular weight of stack gas
M. • 0.44 (ZCO,) + 0.32 (20,) + 0.28 (ZN, + ZCO)
d Z Z 2
Molecular weight of stack gas, vet basis
Ms • Md d-Btfs) + 18 Btfg
Pitot tube coefficient
\_ C (from calibration curve)
Average velocity bead of stack gas, inches H.O
( /A p ) «vg.
'f Average absolute stack gas temperature
•
(t» T * 460
r
(T$) avg.
Absolute stack gas pressure
P « P. + (Static Pressure/13.6)
\ '* b
Stack gas velocity
&
-------
c
«"•»
REPETITION NO:
TEST DATE: 3-// '97
Volume of sample »t standard
conditions on dry basis
mstd
• H
L
L
L
L
Volume of water vapor in sample at
standard conditions
Vwscd
•M^H
0.
•Vlc - L
04707 cu
^5-3
. ft.
ml
v
1C
ml.
Fractional moisture content of stack gas
Vwstd
ws
V V
mstd + vstd
Particle concentration in stack gas on dry basis
— -i r- M
• 01543 jr MSi
cs
•E"
mstd
. 2.205 10"* Mn
Vmstd
'tack gas volume flow rate on dry basis
Qs « 3600 (l-Btfs) VsA§
(A - sq.ft. V »
Process rate or BTU rating P
Emission rate _ ,
Q c's
P
std . s
TS) avg . P
— ft/sec)
.td
Isokinetic sampling rate
• 1.667 min
ENGLISH UNITS
(29.92 in. Hg 68*F)
0.002669 in.Hg.eu.ft.
ev p A
s s n
O OOO3?2. sq.ft.)
dscf.
scf.
grains/dscf
x 10~6lb
x 10 dscf/hr
Ibs/hr
Ibs/
-------
i :
SCHEMATIC OF STACK
CMS! SEC1ION
AMUIEIir TEMPERATURE
BAROMETRIC PRESSURE —2L&.
AMUMEO MOH1UR.E. X Y°
PROBF. LENGTH. U. "3 L
f. FAC10H
PlIOCUH •CICIII HATE
MAMETEH. I.. _L
DIAMETER. U
MEIER MX NO.
PROBE llEATERSETTIHG.
IIEMERBOXSETTIIIG
WCICIII Ol: I'AIIMCULATE COLLCCTEI
UUI'Li:
rilUL WI.ICIII
TAMt MtlCIIT
HCICIIl CAIII
1'iiour
TOIAL
101 AL VOLUME CM.LICTCO
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
f «io
[
f
E
r -
r
i
L
L
SAMPLE VOLUME
vm " I7>1QI ft3
Pbar - j?0.27 in. HE
V .176* 1 X VV»[P^*
V rf+l\ A« . W*t J\ A *•
in. Hg .
SO, ANALYSIS DATA
* 17^ / 7 |A
N ».QiP& (£-«0 ^Bl ,QJOC*
V « -5 >i , ^^
t ^.^ ml O
w
vtb • O ml ^
V A
sola • SoO ml £OO
7 » 2.S ml £•£
S02 CONCENTRAnON IN STACK GAS
.c u AT • v ^ nr AJ
C^, - 7.061 x 10 * n ™t tbj tvsoln/v
2 va (std)
S02 EMISSION RATE
QS • 4H&fa DSCFH
S03 CONCENTRATION. IN. STACK GAS
CgQ .« 8.826 x 10"5 N (Vt - Vtfe) (Vsoljl/Va]
vm(std)
S03 EMISSION RATE
Cen X 0
5°^ V.
AH~| ,
irrt - nm ft3
S03 ANALYSIS DATA
N - rOSAL (2-ea
Vt " 3.1 ml
v
tb « &> ml
«»
soln • 50O ml
va " ^ 5" ml
ce) oJtf x /^"5"
J 3 U ) O
r ^ Wf ''
*^ * O-lb% x 10*^ Ib
. * /^, J ppm by Vo
^^/^ O
• O.^O7 Ib/hr
1 - 0. }£5 X 10"2 Ib
- /£7 pun By Vc
« 0.0/4- Ibs/hr
Equation 6-1
/ml
DSCFH
-------
pra* firaj n~ni I-1 • a^J easi
INTERFERENCE ivfSPONSE TEST
DATE OF TEST JANUARY IB. 1980
ANALYZER TYPE IQA/K Mnge 0 - 2.5 PPM
SERIAL NO. 10 A/R - 0KB-80
TEST GAS TYPE
CONCENTRATION PPM
ANALYZER
OUTPUT RESPONSE
I OF SPAN
CO
500
< .1 PPM
< .1 Z
SO,
CO.
201
10X .
< .1 PPM
< .1 PPM
< .1 X
< .1 X
20.9 X
< .1 PPM
< .1 X
-------
26
I
24 -
22 -
20 -
ia -
16 -
14 -
12 -
1Q -
e -
6 -
4 -
2 -
o
FIGURE WF1-2
GALBRAflH ELEMENTAL ANALYSIS DATA
PONFO1 PBMFQ2
PMMFD1
'SS/SSA
PJWR}1
WF I.D.
XH-CORR
PJMTR12 PMWTO1 PMWF02
XS
-------
WBGHTX
3]
Q
m
c/i
I
"
-------
O.4
FIGURE WF1-4
OALBRAITH ELEMENTAL ANALYSIS DATA
0.35 -
O.3 H
0.25 -
0.2 -
O.15
O.1
O.O5 -
PENVFO1 PEMFO2 PIWFO1 PMVFO2 PJMfFOI PJWFD2 PMWFD1 PMWFD2
f7~7\ XS/XC
WF I.D.
XORO 0/%C
-------
SHIRCO ANALYTICAL LABORATORY
TEST REPORT
DATE OF REPORT; FEB. 2, 1987 DATE SAMPLE RECEIVED; JAN. 27,1987
REPORT NO. ; 87-006 DATE SAMPLE ANALYZED; JAN. 27-30/87
PROJECT: BRIO OIL
1. Pit B 3. Pit J 5. Pit Q
2. Pit I 4. Pit M3
HEAT VALUE
DRY SOLIDS \ VOLATILE SOLIDS (BTU/LB. VOLATILE SOLIDS)
HEAT VALUE
DENSITY(q/ml) PH
1. 1.39 4.5-5.5
2.
3.
4.
5.
0.68
1.39
1.16
1.58
4.5-5.5
4.5-5.5
4.5-5.5
4.5-5.5
BTU/LB.
Incomplete
Ignition
3,848
1,851
Did Not Ignite
Incomplete
Ignition
Pit I flowed in TGA tray, but not through belt! All other materials
stayed solid.
ANALYST:
Jeff Weiss
-------
SIIIKCO IN.'KAKEU SYSTEMS. INC.
THERMOGRAVIMETRIC ANALYSIS
DATA SHEET
MATERIAL:
TEST NO.:
TIME: '(.
GAS FLOW:
WT. CALIB.:
CHART SPEEC
SPAN CAL.:
FINAL TEMP.
MAXIMUM TEf-
COMMENTS:
ha4eri«
ft % \
RR|0
REFIWERV (
7HIC
> ; ££ -
AIR
0
): I C
0-
(°F):
IP. (°FJ:
•fUr
ft*
&'ft g'»
3:\3 2C
4-0 SCFH
- )00q
j
n /HIM
2.000'
ICO^
\£0$
f\ urLn ktf
^.er;ft\ f c
:nflMSAMTfl) Pi-V I Repeat
DATE: 2? TAN ?7
> OPERATOR: 3" lO
TEMP. SETPOINT (°F): 1 COO
SAMPLE WT. (GRAMS): °( G . 2
SPAN (VOLTS):
SUPPRESSION:
FINAL WT. (GRAMS): T^. 0
A/R TFnp • 1770
fi»n ^ ^,0J D^,o'
.Ij Lii-t- JlJ nnf •f-'l-yr 4%.
\^ \ \ d ' ^ Ij.
tjrcJ/' rclea^J from 3 e_[±
jj, —
-------
:8RIO R^FIWEKY Pit B
tl JAW1 17 70|
-------
SlilKCO INFrtAKF.D SYSTEMS, INC.
THERMOGRAVIMETRIC ANALYSIS
DATA SHEET
TEST NO.:
TIME: 1
GAS FLOW:
WT. CALIB.:
CHART SPEED
SPAN CAL.:
FINAL TEMP.
70)9
£:£$-
AIR
0-
1
AR
CF):
MAXIMUM TEMP. (°F):
COMMENTS:
BfHd
• 1:15
gfl
4n SC.FH
- 100 «
en /him
0-2.000
/
1COO
ICOO
K s-H-otw
1
0
Tr^v .
DATE: 2T T/IM n
OPERATOR: TW
TEMP. SETPOINT (°F): (£00
SAMPLE WT. (GRAMS): 7 k 2.
SPAN (VOLTS):
SUPPRESSION:
FINAL WT. (GRAMS): 60. I
AR TP np • |^f,o
h T C j_ J » N -- '
h Uh 1 o o-h^fldy LJ e i <•
-------
-------
-------
LMIrtCO INFRARED SYSTEMS, INC.
THERMOGRAVIMETRIC ANALYSIS
DATA SHEET
MATERIAL: RRIfl REFlAiEW
TEST NO.: 7fl I 7
TIME:
- 1:00
GAS FLOW: AlR 40 £CFH
WT. CALIB.: 0 " I 0 0 .1
en
CHART SPEEDj
SPAN CAL.: AR 0^2.000
FINAL TEMP.(°F):.
MAXIMUM TEMP. (°F):.
COMMENTS:
Tf^Q \
Pit J
11
OPERATOR:
TEMP. SETPOINT (°F):
SAMPLE WT. (GRAMS): 1 I . Q
SPAN (VOLTS):.
SUPPRESSION:
FINAL WT. (GRAMS):
A/6 TEHP :
j .
raft
un
>$f£ftj - (J & i
-------
QRIO
El' JAU
o
f\<
I
o
I
V
REFIUE&Y Pit J
1? 70'I7 KOO/ZO
-------
liMlRCO INFRARED SYSFLMS, Kit.
THERMOGRAVIMETRIC ANALYSIS
DATA SHEET
MATERIAL: BRIO REFiMEHV f PMMSAAITA^
TEST NO.:
TIME: 3
GAS FLOW:
WT. CALIB.:
CHART SPEED:
SPAN CAL.:
FINAL TEMP.(8
MAXIMUM TEMP.
COMMENTS:
Did h 0
702!
:££ -
/IIP,
0-
)
4B
F):
(°F):
Mir.
t- ^ pi
•*f:/£ 20
40 SCFH
• 1/7 Oft
en /NIM
0- 2,OJO°
r
ICOI
J J. 44. „ T, ,
J •'
^^ OM* or run i ^
DATE: ?. "1 JAM ?"/
OPERATOR: T t()
TEMP. SETPOINT (°F): ) £ 0 v3
SAMPLE WT. (GRAMS): 100 ,0
SPAN (VOLTS): , /L
SUPPRESSION:
FINAL WT. (GRAMS): Q^. &
A & ~f~F n f • soo
Run Ta ^f^ L]a.
t ray *
-------
r-'
r--
-------
SHIRCO INFRARED SYSTU'S, IMC.
THERHOGRAVIMETRIC ANALYSIS
DATA SHEET
MATERIAL: RE)0 EFFfMFRV CPIQMSAMTfl)
TEST NO.:
TIME: 10
GAS FLOW:
WT. CALIB.:
CHART SPEED:
SPAN CAL.:
FINAL TEMP.(e
MAXIMUM TEMP.
COMMENTS:
D 1 a 1\n
•2.0
AIR
1
AB
F):
CF):
fW)
I
11
-l(h 40 20
tO SCFH
o- ion.
s)
en/ n i M
0- 2 000*
/
I£OI
ICfll
^J R.*0. Tr
tVPh(p4. 40 ru
DATE: 2^ JAM <*7
OPERATOR: TW
TEMP. SETPOINT (°F): ! C^O
SAMPLE WT. (GRAMS): )00 . 20
SPAN (VOLTS): . 2
SUPPRESSION: ' —
FINAL WT. (GRAMS): Q€>» £
rt* ^% ^^
RT O i 1 M •
Un /o o T £ a a \j uL)
-------
SHIRCO MOBILE INCINERATOR TRIAL BURN TEST
BRIO REFINING : FRIENDSWOOD, TEXAS
APPENDIX D
Test Equipment Calibration Data Sheets
I
L
E
-------
APPENDIX 0
SHIRCO INFRARED SYSTEMS LABORATORY
PROXIMATE AND THERMOGRAVIMETRIC ANALYSIS REPORT
-------
APPENDIX C
GALBRAITH LABORATORIES INC.
LABORATORY ANALYSIS REPORT
ULTIMATE ANALYSIS OP PIT FEED SAMPLES
-------
V «A*.««4IT« •« O CCMMCTH • «00«« •»!«. • MUTCM
QUANTITATIVE MICROANALYSCS
*.0. BOX SICtO ORGANIC - INOMOANIC MM •TCAMOIIK OH.
•MOXVIkkC. TN »7MO-««10 «lf/»M-l*aS KMOXVILLC. TM •7«*fl7fO
Mr. David McKenzie February 26, 1987
Monsanto Companu U4F
800 North Lindbergh Boulevard
St. Louis, Missouri 63167 Received! February 16th
Dear Mr. McKencie:
Analysis of your compounds gave the following results:
Your I, Our f, Analyses, As Received, Dry Basis,
PIW F01, Pit I S-«255 % Carbon 20.59
% Hydrogen 3.77
% Sulfur 3.31
% Chlorine 0.13
% Chloride 0.057
% Copper 0.054
% Ash 57.00
% Karl Fischer Water 17.52
% Phosphorus 0.0091
% Oxygen 6.00
PJWFOl.PitJ S-«25I % Carbon 9.16
% Hydrogen 3.21
% Sulfur O.S9
% Chlorine 0.51
% Chloride O.OM
% Copper 0.034
% Ash 67.49
% Karl Fischer Water 21.22
% Phosphorus 0.0041
% Oxygen 5.06
riN AH* •NIPMtNT* «T W.*. MAIL • ».«. »M tttMh «M«IVIUJ. TM »9W*MMk •TMCM «Afl«CM • MM *TCAMO«C
-------
Mr. David McKantia
Page)
February 26, 1917
Your I,
PJW F02, Pit J
Our I, Analyses,
S-6257 % Carbon
% Hydrogen
% Sulfur
% Chlorine
% Chloride
% Copper
% Ash
% Kari Fischer Watar
% Phosphorus
% Oxygen
As Received,
7.24
2.67
0.31
0.21
0.12
0.040
69.27
20.46
0.011
Dry Basis,
4.08
PMW F01
S-6783 % Carbon 1.75
% Hydrogen 1.62
% Sulfur 0.097
% Chlorine 0.056
% Chloride 0.0061
% Copper 0.0044
% Ash 62.36
% Kari Fischer Watar 27.69
% Phosphorus 0.011
% Oxygen
7.03
PMW F02
S-6764 % Carbon 2.24
% Hydrogen 3.66
% Sulfur 0.15
% Chlorine 0.094
% Chloride 0.0096
% Copper 0.0049
% Ash 62.70
% Kari Fischer Water 27.36
% Phosphorus 0.014
% Oxygen
6.08
PIW F02
S-6785 % Carbon 12.19
% Hydrogen 2.15
% Sulfur 2.19
% Chlorine 0.066
% Chloride 0.055
% Copper 0.029
% Ash 58.77
% Karl Fischer Water 14.32
% Phosphorus 0.099
% Oxygen
12.55
3.04
7.78
OAiMAflM LAOOJUTDWU.
-------
Mr. David McKenzie
page 3
February 26, 1987
Your I,
PBW F02
PBW F01
Our I, Analyses,
S-6786 % Carbon
% Hydrogen
% Sulfur
% Chlorine
% Chloride
% Copper
% Ash
% Karl Fischer Water
% Phosphorus
% Oxygen
S-7369 % Carbon
% Hydrogen
% Sulfur
% Chlorine
% Chloride
% Copper
% Ash
% Karl Fischer Water
% Phosphorus
% Oxygen
As Received,
1.15
3.41
0.2?
0.39
0.0083
0.012
67.50
19.74
0.020
1.72
3.34
2.S3
3.53
0.17
0.4<
0.27
0.014
65.30
23.34
0.0017
2.55
3.54
0.29
0.49
0.27
0.017
11.36
15.76
0.0071
Dry Basis,
7.62
5.91
5.29
Sincerely yours,
QALBRAJTH LABORATORIES, INC.
Exec. Vice-President
GRHac
OAUMAITM
TOfttlS,IMC
-------
FIGURE WF1-1
GALBfWIH ELEMENTAL ANALYSIS DATA
PBWFO1 PBWFO2 PMVFD1
PIWFO2 PJWPD1 PJWF02 PMWFO1 PMWFD2
XC
XH-CORR
WF I.D.
XS
PTXI XH20
-------
r
METER BOX CALIBRATION DATA AND CALCULATION FORM
(English units)
r
r
P
n
'
Date
> 11*
Meter
number
Barometric pressure, P. = C 7* 3v in. H| Calibrated by
Orifice
nanometer
setting
(AH),
in. H20
O.S
1.0
1.5
2.0
3.0
4.0
Gas volume
Wet test
meter
(Vtf),
ft3
10
10
10
10
Dry fas
meter
(vd),
ft3
10
Temperatures
Wet test
meter
"7/.C
7/0
7/-0
Dry gas meter
Inlet
ioi.5
ns.o
117.0
Outlet
(td),
o
(td),
Time
(8),
mia
MO
Avf
y.ceo
Aoo|
/.on
A
AO/I
in. H:O
AH,
in.
H20
O.S
1.0
1.5
2.0
3.0
4.0
AH
13.6
0.0368
0.0737
0.110
0.147
0.221
0.294
T , 'vV^*460'
"' V'b * &i> ^ * "°>
•
_ _ 0.0317 AH f^v * "» 612
1 Pb (td * 460) 1 Vw
. •
If there is only one theraoaeter on the dry fas
under t..
acttr, rtcerd the temperature
Quality Assurance Handbook M5-2.3A (front side)
-------
METER BOX CALIBRATION DATA AND CALCULATION FORM
(English units)
Date /-
Meter box nuabcr i b 6
Barosetric pressure,
in. H| Calibrated by ^77"
Orifice
nanometer
setting
(AH),
in. H.O
Gas volume
Wet test
•eter
(Vtf),
ft3
Dry
•eter
(vd),
ft3
Teoperatures
et test
•eter
(tw),
Dry tas meter
Inlet
Outlet
(t),
*.$
4/.0
li.0
2.0
10
19.$
3.0
10
79.
+6
1.6/9
4.0
10
IQ-QH1
70.O
7.S
&H.
*_
B20
0.5
1.0
1.3
2.0
3.0
4.0
AH
13.6
0.0368
0.0737
0.110
0.147
0.221
0.294
i AH
Vd(Pb + 13*5) (tw •»• 460)
- •
^ . 0.0317 AH r(tv+A60)8l2
^^i Pb (t4 + 460) [ Vw
. .
If there is only one thernoaeter on the dry fas aeter, record the temperature
under t..
Quality Assurance Handbook M5-2.3A (front side)
-------
Date
METER BOX CALIBRATION DATA AND CALCULATION FORM
(English units)
Meter box number
1 f
Barometric pressure, P. - 23-3O in. HI
Orifice
manometer
setting
(AH),
in. H20
0.5
1
1
2
3
4
.0
.5
.0
.0
.0
Gas volume
Wet test
meter
(vw),
ft3
5
5
10
10
10
10
Dry gas
meter
(vd),
ft3
%*£'*&
$"0OQ£f
>o,3z4
\Q*ys&
/0.&3
/O.S3O
Calibrated by ~J/
Temperatures
Vet test
meter
-------
SPI
DIFFERENTIAL PRESSURE GAUGE CALIBRATION DATA FORM
Gauge type
Serial or ID number
Scale
O — £>. 35"
Gauge-oil manometer Ap
O.I7
O •OS'
o - /• 7
Differcntial pressure
gauge Ap
Pressure
difference
Calibration: initial
posttest
Date calibrated
by
-------
DIFFERENTIAL PRESSURE GAUGE CALIBRATION DATA FORM
•r.
\
Gauge type
Serial or ID number K* 1
Scale O - O-
Gauge-oil nanometer Ap
0,31
.1*
Calibration: initial
Date calibrated
Differential pressure
gauge Ap
O. /5~
0^7
Pressure
difference
posttest
by
•v
-------
fc
DIFFERENTIAL PRESSURE GAUGE CALIBRATION DATA
FORM
Serial or ID number
Gauge-oil manometer Ap
Differential pressure
gauge Ap
/•or
Pressure
difference
Calibration: initial
posttest
Date calibrated
— *? ft -
-------
PITOT TUBE CALIBRATION DATA
r
r
Calibration pitot tube: type 5rp size.(OD) *v/ ID number** J
e S pitot tub
ibration: da
A- Side
cm (in. )
H20
O i./
J. V/
e ID number £j
te a-2--*"7
Calibration
cm (in. )
H20
O 3-3
o , 4 1
/.
-------
PITOT TUBE CALIBRATION DATA
I
L
L
I
I
calibration pitot tube: type 5TO sixe.(OD) Vs- ID number *f* I
9\3
o.qq
alibration: da
A-Side
cm (in. )
H20
G.3.*
Ct.foO
/.aa.
B-Side
cm (in. )
"V
0.3^
& 6^
/ • ^JT
^^«^^.^— — *i^— •
ar - r
*•*,*, / *• \ ~ **«k / ^^«l
P(S) P(StQ
bcE7 = CP(S) "
5«(A) - CW(B)
te 3-3-F-7
Calibration
cm (in. )
HjO
0.0ft
tf>.«3
Average
s Calibration
cm (in. )
V '
^•31*
^»*.u;
performed by
C *
£>.%37
o.Asa.
O . HM 1
0.?V£>
CP(S)*
o-ft37
o.rvY
o.t-sa
O.dH/
)
>e 5.0.01).
-TT
DEV.b
o .00^5
0*0^0.
^.OO 1
o.ooa
DEV.b
O-ooy
«.^«>3
A .OO 1
0.003
Quality Assurance Handbook M2-2.5
-------
STACK TEMPERATURE SENSOR CALIBRATION DATA FORM
Date
Thermocouple number
Ambient temperature
Calibrator ~> /'
*? Barometric pressure
-------
SJAGK TEMPERATURE SENSOR CALIBRATION DATA FORM
I
r-
r
L
Date
_ Thermocouple number foe. S3 9 6
Barometric pressure &1'?J in. Hg
Ambient temperature 7O *
Calibrator "J / Reference: mercury-in-glass
other
Reference
point
number
B
h*Tt*
L
Source
(specify)
/C£
V
Reference
thermometer
temperature,
9*3
Thermocouple
potentiometer
temperature ,
Temperature.
difference,
0-3
'Type of calibration system used.
(ref temo. *£
) - (test thermom temp. V
ref temp
Quality Assurance Handbook M5-2.5
L
L
L
-------
TEMPERATURE SENSOR CALIBRATION DATA FORM
Date
Thermocouple number Lv5""97
Ambient temperature Jo *& Barometric pressure ^^. 7/ in. Hg
Calibrator 3"T" Reference: mercury-in-glass _
other
Reference
point
number
,-r i
2.
•Ltr i
-2.
Source*
(specify)
ue. BAT*
*.,.-,*<>
ICC 4«TH
0:\,^ M, 0
Reference
thermometer
temperature,
3**-
a«
»T-r
•
Thermocouple
potentiometer
temperature,
sr
a/4
ir
•
Temperature
difference,
X
o-r
^ t/
O ' i
0.3
e of calibration system used.
ref temp, *P '.• ) - (test thermom temp, *f
ref temp, "j
Quality Assurance Handbook M5-2.5
-------
STACK TEMPERATURE SENSOR CALIBRATION DATA FORM
__ Thermocouple number P 1.3
Barometric pressure
Date 2L~b
Ambient temperature "7O
Calibrator TT Reference: mercury-in-glass
other
in. Hg
Reference
point
number
Source0
(specify)
Reference
thermometer
temperature ,
Thermocouple
potentiometer
temperature,
3*0
Temperature.
difference,*
o.
of calibration system used.
temp, *F . ) - (test thermom temp,
ref temp
>]
L
L
L
100^1.5%.
Quality Assurance Handbook H5-2.5
-------
Date
STACK TEMPERATURE SENSOR CALIBRATION DATA FORM
Thermocouple number Pi
Ambient temperature
Calibrator Ol
Barometric pressure ai.7 I in. Hg
Reference: mercury-in-glass ^^
other
Reference
point
number
I
2-
3
Source*
(specify)
Reference
thermometer
temperature,
•32/T
Thermocouple
potentiometer
temperature ,
Temperature.
difference,
0.3
o.y
0-3
of calibration system used.
(ref teao. *P ._ ) - (teat thermom temp.
ref temp, •
Quality Assurance Handbook H5-2.5
n
-------
KT ' '-"
-^ EC-ii^
SCOTT ENVIRONMENTAL TECHNOLOGY. If
PUUM0TK AOVILLK. rCNM0VI.VANIA !••«•
•*«.*• »•*»
PttASSFAY FHOtl THIS
invoice AMD *furr TO
•COTT •NVINONMKNTAk T«CMNOU>OV INC
r.o. •*« MW-IM
11177 0120
IT- • V
-• SAM
ASI EH7IRO«fflHTAL
c eaojiouH rnsr BAK
CUSTOMER^ bobE
DATE IMIPf CO
CUCTOMCR AUTHOMITY
NET 30 WX!
PROOUCT'OOOE
.«. -V, t •«,-.! «dTiv»;-.
±21 CKITIFIEO
MASTE1 GAS
MED6/VIA SHZBffiHT
. ^O.: .-V: .
WE HE«E8V CERTIFY THAT THESE OOOOS WEMt PROVIDED INCOMPLIANCE WITH ALL APPLICABLE REGULATIONS OF
SECTIONS •. 7 AND II OF TH« FAIR LABOR STANDARDS ACT. AS AMENDED, AND OF REGULATIONS AND ORDERS Of
THE >"
-------
Scott Specialty Gases
PLUMSTiAOVILLE, PA. 18949 PHONE: (215) 766-3861 TWX: 510-665-9344
Date:
12. 1983
Our Project No -905003
ARI ENVIRNMENT INC. Your P O No- 101-83
ATTN: LARRY GOLDFINE ~* - ' -
600 N. FIRST BANK DR.
PALATINE, ILL 60067
Gentlemen:
Thank you for choosing Scott for your Specialty Gas needs. The analyses for the gases ordered, as
reported by our laboratory, are listed below. Results are in volume percent, unless otherwise indicated.
ANALYTICAL REPORT
ryi
CAL-7739
Component
Analytical
Accuracy _i2JL_
Concentration
CABBON MONOXIDE^
.OS PPM
NITROGEN
BALANCE
ACUBLEND MASTER QAS
rri M~
Component
Analytical
:-
nration
CARBON MONOX
PPM
NTTROOEN
BALANCE
AC
EMD MASTER OAS
Cvl.
CAL>78gS
Component
Analytical
Aeeuraey -»-2t
Concentration
CABBQM
NTTOQQEM
PPM
BALANCE
MASTER
Component
Analytical
Accuracy_±il
Concentration
CAUBQM MOMQTTPg
PPM
BALANCE
ACTTBLEMP MASTER GAS
Analyst
//...a all I.
•~T"~~1~1™^^^^^T115—"'"~^
Approved By
CIRTIFIEO MEFIMf NCC MATtftlAU IPA MOTOCOL QASU
ACUBUf NO* CALIBRATION ft SMCIAUTY QAS MIXTURIS PUMI QASf 3
ACCESSORY PRODUCTS CUSTOM ANALYTICAL SERVICES
THOT. MICHIGAN / SAN eCMNAAOlNO. CAUCOANIA / HOUSTON. TlXAS
-------
ANALYTICAL REPORT - cont'd
CAL11A06 Analytical ±2%
Cyl. No. „• Aeeuraey
Component Concentration
CARBON MDNDDODE
235ppn
HCF AJR
BALANCE
Cyl. No.
Component
Analytical
Accuracy.
Concentration
vnalyst
ENCE!
\
T>irt. CCIOBER 27, 1986 .
Our Project No.: .
Your P.O. No.:_
r . _. CAL1140A
Cyl- N«
Component
CARBON MONOXIDE
HCRAXR
705541
402-86
Analytical ±2Z
Aegurary
Concentration
—>—_________
470ppa
BALANCE
Cyl NA
Component ,___t
% ^
•n ^
V
ajgL..
k
Cyl N«
Component
Analytical
Aeetifagy
Concentration
/'I
^?
AppravecLB
CIWTlFlf 0 MEM HENCE MATERIALS EPA PROTOCOL OASES
AGUE-LEND* CALIBRATION It SPECIALTY OAS MIXTURES PURE GASES
ACCESSORY PRODUCTS CUSTOM ANALYTICAL SERVICES
-------
ocott specialty Gases
PLUMSTEADVIILE. PA. 18949 PHONE: (218) 7864861 TWX; 510465*347
5/23/86
Our Project N* ... 917393
Your P.O. No.:-J!__!L_
Gentiemen:
Thank you for choosing Scott for your Specialty Gas needs. The analyses for the gases ordered, as
reported by our laboratory, are listed below. Results are in volume percent, unless otherwise indicated.
ANALYTICAL REPORT
Cyl. No..
CAL-11486
Component
Nitric 0x1d«
Analytical ...
Aceur»CY__I£__
Concentration
•••iMHHM^BMM^HMM
56.54 PPM
KOx
57.28 PPM
Nitrogen 01ox1dt
.74 PPM
Nitrogen
Balance
ACUBLENO MASTER 6AS
Cyl.-~ CAL-11489
Analytical
Component
Nitric Oxide
198.9 PPM
NOx
199.2 PPM
..
Nitrogen Dloxldt
.35 PPM
N1trooen
Balance
ACUBLENO
ER GAS
Cvi N« CAL-11488
Component
N1tHc Oxide
NOx
Nitrogen Dioxide
Nitrogen
Anaiyucai .-
Accuraey_iiL.
Concentration
123.2 PPM
123.9 PPM
.7 PPM
Balance
' ACUBLENO MASTER GAS
fyl M*
Component
Analytical
Ae^ui-^y
Concentration
Approved By
Cf KTIPIID MIPIKINCS MATWULS IPA PROTOCOL QAXIS
ACUBLENO* CALIMATIOW* VICULTYOA4MIXTUHU ttjftl QAJIS
ACCtMOB Y PRODUCTS CUSTOM ANALYTICAL UKVICIS
. MICHIGAN / SAN alANAAOlNO. CAU»0*NU / HOUtTOM. TtXAS
-------
i Thermo
r ,,— Bectron
I CQ«»O*ATION
Thermo Electron Instruments
10i SM* 80Mt 1*30 S. feu Cfftywt M.
lliN^n". MMUChuMtti 0174* Oiamend ftw. CA it7*8
•17I43»4321 (71
TWX
r
r
r
April 16, 1985
L ARl DWnOWEHtAL QiXBFGBAIED
600 North First Back Drivt
60067
m: Mr. Back Taylor
ft Subject: EPA Interference Test Report •
Dear Mr. Taylor:
. «
In response to our recent conversations, I an pleased to enclose
Interference Faspcns* Test for the Tfaeznc Electron Model 10A/R.
B'
After reviewing this informer!an, should you require any further
assistance, please do not hesitate to contact ne.
Sincerely,
TSEBtO mCIBCN UbIKLtffNES ECDRPORAIBD
a Ken
-d
VJ
-------
APPENDIX E
SHIRCO INFRARED SYSTEMS
PORTABLE UNIT OPERATING LOGS
-------
r
3
I
a -o *> t> -D
» » ar w m
f
1
Hillli
mw
fflflT
HH+lt
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S-O'V'VV'OIV'V'O'^-O'O ^
32323222223
| i i i i i i I i i i
•— lAaV^V-CJI-^l-trOM
m
4O
CA
-<
tn
S
s
-------
SHlftCO IffRMCO SYSTEBS, INC. OPERATIONS DATA 106 SHEET
o*t»: .-?J*
CliMt: .Jc
Optrrton ..
Hour* ttttr
Conviyor
•»M
Mfiflht 04 prop«M cylinder
LP
( Itagnttitlii
1. firnKO draft
2. fifMCi nhant
3. ifttrknrnir draft
4. tftirittrMr coHMtiot tir
S. vtntvri dtffirNtitl prMOori
Find |«i nialytiii
cirlofl NMiidt (CO) ppt
. cirkM dioiidt (C82) p«cmt
^if • oiyft* (02) ptrcort
nit row oiidn (Mk) ppi
(6
"W****W"'
UK flNE TIHE TflC tilt TINE UKE TIIC
(24 hrt.1(24 hrt.)(24 hrt.)(24 hrt.)(24 hrt.I(24 hrt.)(24 hrt.)(24 hrt.)
. 321 J
--
JttlZ 'H*L 125
JLL
111. ULL-
JILL.
^
MTCtlM. Tin
(111.) (24kri.)
*p.*r*
,.
-------
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SHIRCO INFRARED SYSTEMS, INC. OPEMTIONS MTA 106 SHEET
Ditct sL-JAz
Client: ._
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SMIRCO INPMKO SISTERS, INC. OPERATIONS MTA UK SHEET
Page 1
Ottei
Locition: ,
Charge Nuaber: ___
Op«ntor: _____
Hourt Mttr readings
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SNIKO INFRAKO SYSTERS, INC. OPERATIONS DATA LK SMEET
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SHIKO INFMKD SYSTEKS, INC. OKRATIONS DATA LM SHEET
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APPENDIX F
SAFETY PRQggDO'RgS AMP EQUIPMENT
Safety precaution* applicable for this type operation were
taken for personnel and equipment protection. All
appropriate personnel protection equipment was worn and
maintained.
1.0 Personnel Protection Ecruipnant
The personnel protection equipment included:
A. Respiratory protection: full faced
respirator with organic vapor/acid cartridges
and dust filters. Level B protection with
supplied air was worn by Shirco feed handling
personnel when organic vapors exceeded the
capability of the respirator, as determined
by site personnel using an organic vapor
analyzer.
B. Dermal protection: Saran coated Tyvek full
body suit, inner lightweight PVC or latex
gloves along with buna-nitrile rubber outer
gloves, and neoprene steel-toed shanked work
boots.
2.0 Equipment Application and Degpn^ajination
Shirco Infrared Systems personnel established the
site areas designated for use of protective
equipment and areas where such protective
equipment could be removed for personnel rest
breaks. In addition, Shirco set up an
intermediate area for decontamination of the
protective equipment.
Prior to working with the feed material or
entering the designated test area, working
personnel put on the respiratory and dermal
protection as described above and specified by the
sits safety officer. Temperature conditions were
such during the test program that overheating was
not experienced. However, all workers took a 15
minute break after a maximum one hour period.
Upon leaving the test area, a worker passed
through a decontamination station to wash and
rinse boots and gloves. Subsequently, the outer
gloves were removed and set out to dry if they
were usable. The workers would then remove the
Tyvek suit and place it in the designated
container. The respirator was then removed.
Finally, the inner gloves were also removed and
discarded. Respirators were washed as required
throughout the day and at the end of each day.
All workers and observers thoroughly washed hands
and faces before eating or smoking.
-------
3.0 Emergency ProemAurmm
With the hslp of ths Brio Task Fores personnel,
ths Shirco Infrared Syatem* Tsst Coordinator
designated a minor injury first aid station in
close proximity to the tsst arsa. Emergency phone
numbers wers postsd and all worker* briefed upon
entering the sits.
4.0 Stress Monitoring and Breeke
The ambient temperature did not excesd 75°F during
ths tsst psriod, thsrsfors temperature and
psrsonal vital signs were not rsad and recorded.
Bach vorksr was urgsd to monitor his ovn condition
and rsst accordingly. Rsst brsaks vsrs taken
aftsr a working intsrval. Anyons suspsctsd of
tiring was told to rsst.
5.0 Peraonnel Training'
To assurs continuity among all rsssarchsrs on site
and assurs correct uss of ths protsctivs equipment
and facility, ths Shirco Znfrarsd Systsms Tsst
Coordinator prsssntsd a brisfing prior to ths
initiation of tasting. This brisfing includsd a
dsmonstration of ths uss and application of ths
protsctivs squipmsnt, a dsscription of ths sits
including ths arsa whsrs safsty squipmsnt must bs
worn and ths dscontamination arsa and procsdurss,
and sBsrgsncy procsdurss and phons numbsrs.
Ths portabls pilot equipment dscontamination and
rsssarch arsa clsanup was conductsd with
participating parsonnsl in Lsvsl C protsction.
All looss squipmsnt was transportsd to ths
dssignatsd concrsts pad and drain squippsd
dscontamination arsa adjacsnt to ths tsst arsa.,
All trash (Tyvsk suits, glovss, taps, shsst
plastic, and papsr towsls) wars baggsd, drummed,
and corrsctly labslsd as hazardous wasts. Ths
dscontamination of ths tsst trailsr was performed
in its tsst location.
Ths furnace fssd metering conveyor was the only
itsm which rsquirsd removal from the insids of the
trailsr for dscontamination. Ths convsyor was
removed and sufficiently disassembled to snable it
to bs thoroughly washsd with a high pressure steam
cleaner spray.
Ths axtsmal surfacss of all squipmsnt and the
walls, csiling, and floor of ths trailsr wsre
decontaminated next. This was dons by first
vacuuming with a KEPA type vacuum and then washing
with a soap and watsr brush. Ths external
surfacss of ths primary chamber, exhaust ducting,
secondary chamber, control panel, scrubber, and
-------
pover diatribution ayatea vere washed with a
portable steam cleaner. Car* was taken not to gat
tha internals of tha control panal and povar
diatribution syatema vat. Tha ateam vend vaa than
uaad to rinaa tha valla and floor of tha trailar.
Tha fluoraacant light bulba in tha trailar vara
than removed. Thaaa vara carafully vaahad with
aoap and vatar and plaead in thair boxea. While
tha vacuuming of tha trailar vaa in process, tha
looaa equipment auch aa toola, exhauat stack,
portabla etairs, ladder, drain hoaa, ate., vaa
vaahad vith a ateaa apray. All auxiliary
equipaent vaa than plaead back in tha trailar in
preparation for tranaport.
Whan all equipaent vaa in tha trailar, ita doora
vara lockad. By noon on February 14, 1987, tha
trailer vaa removed from the aita.
In addition to the Shirco equipaent, all ARI
eaiaaiona teat equipaent uaed at the teat area vaa
decontaminated by vaahing vith aoap and vater or
aethylene chloride.
7.0 Furnace Operating Safety
Procedurea for obtaining, transporting, and
feeding the vaata material to the furnace primary
chamber minimized contamination of intermediate
routea.
Considering the potential health hazard*, tha
primary concern during operation vaa not to
pollute the atmoaphere. In accordance vith the
test plan, no aaterial vas fed to the primary
chamber unleaa the secondary temperature vaa at or
above 1800°P.
In order to prevent local atmospheric pollution,
the operators continuously monitored the secondary
chamber temperature to assure it remained above
the designated test temperature. During the teat
program, the secondary chamber temperature did not
fall belov 2100°F.
-------
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».'
— I
*;«
>•'
Dry noltcular vaight of stack gas
2
0.4A (ZC0) + 0.32 (ZOj) + 0.28 (ZN + ZCO).
Molacular vaight of stack gas. vat basis
Ms • Md U-Bws) + 18 Btfg
Pitot tuba coafficiant
C (from calibration curva)
P
Avaraga valocity baad of stack gas, inehas H.O
( r^ZT ) «*f •
Avaraga ababluta stack gas taaparatura
_*T + 460
Ab«oluta stack gas prasaura
(Tf) avg. - / 7A /
P - P, + (Static Prassura/13.6)
so
Stack gas valocity
\. - (85.49)
Ib/lb-aol
in. H
": Stack gas
60
flow rat*
- Stack gas Tolua* flow rat*, dry basis
- 3,600
kstd .
ft/sac.
acfa
cscf
J
-------
L. . 1 I
SCHEMATIC OP STACK
CjSi
PLAIIT,
DATE
•
.L
«*Uf"
J«j*
^s
LOCATION
OPERATOR
STACK NO.
•UN 110. _
AMUIEIIT TEMPEIIATURE .
•AROMETRIC PREISUNE .,
ASSUMED MOISTURE. It
METE* All, —
c iflcW *•'* '
PMOCCJt wriCIU HATE .
PROBE LEHCTII. I..
'4~ HOI 1LE DIAMETER. I..
STACK DIAMETER. U.
SAMPLE Ml Ma i.
CROSS UCTION
METER MX HO.
I
PROBE HEATER SETTING .
NEATER Ml SETTING.
pRds
FP«l
VEICIIT Ol< I'ANIICULAIE COlLfCIE
SAMfLC
FIMAL HCICIII
•CICIII CAIII
FILTER
PIIOlll
TOTAL
TRAVERSE
pomr
IIUMIER
SAMPLING
TMC
STATIC
STACK
TEMTfRATMC
VCLOCITV
«FPC
ACTUA
SUM
EMTIAL
S
ice
TCH
beSMEO
CAS SAMP1K
VOLUME •
GAS SAMPLE TEMPERATURE
At DRY CAS MEIER
llUfT
IS Zi
.. f/
OUTLET
SAMPLE Ml
TEMPER AIURC
•P
rr
TEMPERAIUNE
OF CAS
LEAVIMC
CONOENSI-R OR
LAST IMI'IIICEN
•F
£.0
PUMP
VACUUM
1. II,
VI
it i 9o
fO
S70
Po
/70
»? 99
ST
7
<**
.¥•
433
rr
SY
f.Jf
*
SoP
Jio
7/8
73.
K. //o
91
.60
TOTAL
•J7.it
r?
AVENACI!
L-2t.j
-------
' t " t~~~ ; 1 !
ttllCRAIIC OF HACK
Ol
CROSS SEC1NN4
!• AVERSE
POINf
ItUMftER
3
5
/
j
.
\
101AL
SAMPLN4G
IH.-U.
/?-/o
/Z-'t/f
/ft \30
/a *it5
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f ^ *&XA
_r „> 'j fO
/j.:yr
/ZL'Vf
'
- *
i
SfAIIC
PHESSURe
fe*»
AVERACe 1 * 8
I
VOLUME OF LIOtMO
•AIE4COLLEC1EO
FINAL
IIM1IAL
LIQUID COLLEC1CO
mni uni nuF Mil 1 ICIf D
V
\
.',
^•HMW*
t5 — 1
1 . ' V -
PL All
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Ml
LOCA1IOI
t
1 OPERA1Q
SIACK IK
MI RUN NO.
SAMPLE 1
MEIER m
HACK
1EMPERA1URI
iM'i1
y?/
/73-
,
7f
2~7lL
/~?£
/'Z?
/~>&-
/7D-
n/.i
IMPINCER
VOLUME •)
1 1 1
f~ —
-
1
4
VELOC11V
NCAO
Aay
A2t
on
63*
6 3-\
9-t*-^
9.JL)
43.1
•^
«M%
SILICA Gil
Mldll.
•
i • i i - , 1 '• •»
-^ '/^i'f7
j ^
•
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in« MA .
91 NO. .
PRlisSURC
MFFEMEHIIAL
ACROSS
ORIFICE
MEIER
IPHI
ACIUAt bE SIRED
TQ
.40
* «^
^T"^
*57)
« _5^^
>
^
CAS SAMPLE
VOLUME
?orV
/«P. "7
ffy ^
' ffy. ^**
jj> a *^
^». JL
^y.39 V
ONSAI MCASUHEHflll IIME
I
,
i
<
AMuieur IEM
•AROMEIRIC
ASSUMED MM
PR05E LEIIC
imilLE MAM
SfACK NAME
PROSE llEAl
NEA1ER ROI
CAS SAMPLE 1
At DRV C
IMLET
II-.J.-P
57 SO/
11 SO/
f-> i y/?f
.?«•-
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17 SOY
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f
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ER SET1IIIC
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... . . lAMUltlLIII
KCIMII GAIIl'
min
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US MEIER
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9f
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1AMPIF. BOX
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•F
*£L£. D
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LAll lurillGEM
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e* o
t>0
to
£ 6
£ a
£0
_$~?
PUMP
VACUUM
U. II,
-7
"7
7
C
~p
"7
?
7
VI
• llmuiiiu.
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
SAMPLE VDIIME
bax
in. Hg
/. c
m(std)
•R
In. Hg
S02 ANALYSIS DATA
N - ,QlQ(o Cg-eQ /ml
V Q.g ml
tb - ^ ml
sola -250 ml
.^ .^^^
ml
-01 Ob
e
-------
.1 • 1 l-
I
i
UJIEMAIIC OP HACK
T
A
_L_
»
_L
^a
CROSS 1CC1IOM
AMUIENT TENPEHATURE .
BAROMETRIC PRESSUIIE 3*-
MOISTURE. X £
?£
/-.
MEUH Ally
c f AcTolJ ^ iiz.
rnociu »i iciir IIAIE
mOBE LEHCTII. 1^
IIOIILEOIAHEIEN. I.
STACK MAHEIEM. I.. .
METER MX HO.
PROBE llEATER SETTING.
HEATER BOX SETTING
TRAVERSE
p«Hr
INJURE*
tAMPLIMC
IMt
M.-U.
STAflC
PME1UMHI
IU.M.OI
HACK
UMPERA1IMC
VELOCITY
HCA0
PRdSSUME
MPPEMENIIAL
ACROSS
ORjMCE
•I""
ACIUAl
.M,o
DESIRED
CAS SAMPLE
VOLUME
fa
• IICIII Ol: l-AIMItULAIC COLL tCH
lAUHll:
»nuir
MClklll (.AIM
nucn
riiom
CAS SAMPLE TEMPERATURE
At DRY CAS MEIER
HILET
OUTLET
tt
iAHPLE BOX
TEHI'EHAIURE
•f
TEHrEHAIUIII:
Of CA\
LliAVIMC
COHDCIIMH OA
LAif IHI'IIICEH
•F
CO
60
PUMP
VACUUM
VI
XL
t?7.
P.3
ft
/o
or
rr
TO?
soe.
101 AL
v^n
AVERACB
«OU>HC OP LIQUID
•AIERCOLI.ECIEO
PIMAL
IIM1IAL
LIOINO COLLECIEO
101 AL VOLUME COLLECTED
IMPIMCER
SILICA GLI
, MIM4II.
&S.
;i^s
HJ^
'*•
ONSAIHEAiUMCMCMI
r
1
TIME
CO
-------
-------
SOURCE .-
REPETITION NO: &
TEST DATE: 3 -/i-
Volume of sanplt ac standard
conditions on dry basis
nstd
Y
17.
A H
Volume of water vapor in sample at
standard conditions
vscd
Vlc
0.04707 cu. fc.
ml
ml.
Ic
Fractional ooiscura content of stack gas
vstd
vs
V V
mstd + wstd
Particla concentration in stack gas on dry basis
e's
.01543 jr
mstd
2.203 10"* Mn
V .
mstd
Stsck gas voluaa- flov rata on dry basis
T
3600
sq.ft.
7 •
• p
.td
ft/s«c)
Procass cata or BTU rating P
Emission rata
Q c's
Q c's
Isokinatic aaxpllag rat*
->
..667 Bin | T
ENGLISH UNITS
(29.92 in. Hg 68*71
72-T27
.o %
Q 730
O
1.002669 in
dscf.
grains/dsi
x 10 dscf/
lb»/hr
Ibs/
.Ht.cu.ft. VjJ •»• V^ Y JPtM ^ ^ H
-------
COMPAKT:
SOURCE:
' TIIIIOM 1*0:
TEST DATE: *-
X^ Dry aolacular vaight of stack gas
Md • 0.44 (IC02) + 0.32 W^ + 0.28 (ZH2 + ICO)
- Molacular waight of stack gas, wat basis
Ms • Md U-BW1) * 18 1^
Pitot tuba coafficia&t
*• c (from calibration curva)
L. p
r Avaraga valocity baad of stack gas. inchas
(/A p ) «vg.
Avaraga absoluta stack gas taaparatura
(T§) avg. -
T + 460
. Absoluta stack gas prassura
p » p. + (Static Prassura/13.6)
s o
icack gas valocity
.'- (85.49) C
•/s
Ib/lb-aola
Ib/lb-aoia
•R
in. H.
'•ack gas voluaa flow rata
60 Vs ^s
Stack gas voluaa flow rata, dry basis
Q§ - 3,600 (l-Btft)
std .
(I.)
acfa
dscf/
-------
IUIEMA1IC Of HACK
*-^S
CMHi IKCTNM
AMIIIEHT TEMPEHAIURE
BAROHEIRICPREiiUIIE .
AiiUMEO MOIiTURE. X _
PROBE LEIICIII. I.
_ METtnAll,,
r. FACIOM 0»
/*t>
— i —
4
^e
ill.ICA CLI
MIMII.
*...—
•&00
I I'MHI Mil.
f?
UNiAl MCAiUIICMFni
CO
-------
r
r.'
5
ib
u ft.
-t
i i
5 •• •> »-
2 w S S
•- « * 2
^ 2 o -<
< ».
S *
i C i
.r s s
* s 5 «
5?22
* §
s *
S s
|
i
1
I S
S i
S 8
•» _
,-
il
in ik
S. SI-
52^1
si «f
M
81--
*
iv^pn
«3^
>P
(N r«*
^IxoM
5<
NfH
C-^
-------
.-1
CIIEMAIICOF STACK
o
crass SECTION
TRAVERSE
POINT
NUMBER
>r"yz.
•r*7
•^* -i^^
laf^.
.
1OTAL
SAMPLING
TIME
F~A>o f
V
r
*
L
1
I
i '
STATIC
PRESSURE
Ite.H.OI
C
|
1
PI
L<
S^JjTli?* 0
SI
»!»•••«•*< Rl
"** 1 s;
M
STACK
TEMPERATURE
CT.l'l"
/(•K
jCa
/L£
/6&"
i^X
*V»AC* /f-<^ /6A'i
AMf if-ls^O
KATKM
rERATO
FACKNC
UMNO.
kMPLEI
ETERBI
VELOCITY
MEAD
•IL
•If
•?r
•If
^
.
K — y
|
•
£ - ^
iniun
iinun :
PRESSURE
MfFERENTIAL
ACROSS
ORIFICE
METER
(A HI
U.M.O
ACTUAL) be SIRED
,"ff
•ft
*'<
rfl
• iff
CAS SAMPLE
VOLUME
IV-I.IH
6/. t
fc? ^
•^r.5"
^7.V
^? 3
r7/./o3T
AMUIENT TEM
BAROMEIRIC
A\SUNEO MtM!
PROBE LENC
IM21LE DIAH
STACK OIAME
PROBE llEAT
HEATER BOX
CAS SAMPLE T
AT DRV Cl
INLET
/Of
lut
ttvf
to 7
/»7
PEMATURE
HURE X
III, I. .
EIFB 1. '
TFR. 1.
ER IF IIIIIC
SET1IHC
EMPERA1URE
IS METER
OUTLET
Cf |r
tju
11
£l1
Hi
MET
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PRO
ER Ally
Lr|fii^
LtUWULIIT RAH
u
«IGHI OF PARIICULAIE COLLECTED. -,
SAMPLE
FINAL VEIGII1
TARE VEICIIT
•EIGHT GUM
SAMPLE BOX
TEMPEHAIUME
•F
-l£t>
>6<5
I6o
2^0
^^
•
o P^ (y r& -) f , r <— /„/ /
FILTER
IOIAL
TEMPERATURE
OF CAS
LEAVING
CONDENSER OR
LAST IMPINGER
•F
£>O
toQ
(00
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60
PROBE WA
PUMP
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1. M,
7
7
1
\
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'
VElOtl.
IM
VOLUME OF LIOWO
HATER COLLECTED
FINAL
INITIAL
i iruim rnn
IMPINbER
VOLUME -«
CO
-------
SULFUR DIOXIDE CALCULATION FORM
(English Units)
SAMPLE VOLUME
v - I7.fa?2 ft3 £y/« 7 St~bk
T • 5?5:? °R
Pbar • 3.P- 2~f **• HB
Y - ;.0/5 j-
V_,_^ - 17.64 »R X VJB LTbar *
jji< nj ••
S02 ANALYSIS DATA f3^
N • . Q)0fe (g*eq) /ml .otO6
V Af ml O.2
v ^^.
tb • Q ml ^
,oln «^5^ ml 5"^^
- «2£ ml i5T
~
A H~l
TTrt • /7.5S7
SO. ANALYSIS I
3 // )
vt- ,0.-t
Vtb- 0
«
sola • %0O
V •
ft Equation 6-1
1ATA
(g-eq) /ml
ml
ml
j
ml
ml
S02 QQNCEKIRAIiai IN STACK GAS
- 7.061 x 10
S02 BCSSICN RATE
"S N
"m (std)
U) 0.077 X
^v^qx 10"
L g.fe PPP by Voltane Dry Basis
9.0
y.e
lb/hr
DSCFH
CDNCENIRATION. IN.STACK GAS
* 8.826 x 1Q-5 N V - V
m(std)
*\
t S03 EMISSION RATE
' Q,
DSCFH
10"5 lb/dsc£
ppa By Volxaae Dry Basis
tA Jibs/hr
-------
r
r
r
MPL
v
r
L i 1
^ w •
i it t
w • g
M w a
»• s I
e J
13
ui
£
!
S
^
M
I
S'
11 •
z 5 2
i i !
« 2 !!f
S e 5
Z 5 iu
S a. s
- !
H
§ i
i*
_ IM
I!
Si
\
N*
0
\J
2« 3 B
JSJ S,*
«J<
*•«
IIIl!^ 1
«
• to. 5
iU
r
t
oJ*^
vn
Is
N(*
M>»T
ctcv
V
NN&«
U
OVvj
k.f -IV1
i
c
I
z
u
*
ILL
oj I
TT
o"! i
S I
— ^-'i
5 ;
-i
3-
-------
-------
i
o
o
r*
O
MM
•
S
S
^M
X
-
II-
mi
?'
Sc
29
si
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1 "* a"
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||
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TT|«
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9
t
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ii
VS
4*8
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F
8 2
rjj ^
f
I
1 5 *
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% 8 >
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5 i S » i
- •• S s •
m m * ^ »
i ? I 5 i
* 2 5 « s
S 5 S 2 .=
i 5 ? * T
« 3 F F
j
'..'J
i i
— ^»
! s
I i
S M
.*• s
]
•».-»*
i I a
2 - "
j
-------
COMPA.VY :
REPETITION NO:
TEST DATE: 3 -tf - X 7
Volume of sample at standard
conditions on dry basis
mstd
Volume of water vapor in sample at
standard conditions
ENGLISH UNITS
(29.92 in. Hg 68*n
17.64J 7my
i
*•< + !&
m _
dscf.
vstd
Vlc
0.04707 eu. ft.
MBBH
ml
lc
. 5V
stf.
Fractional moisture content of stack gas
B
vstd
vs
V V
mstd + vstd
Particle concentration in stack gas on dry basis
c's
.01543 jr
2.205 10
M
mstd
mstd
grains/df<
Stack gas volume flow rate on dry basis
T
(A,
3600 (l-Bwg)
sq.ft.
• p
.td
ft/s«c)
O.OOV'J/Q
x 10
Process rate or BTU racing P
Q c's
c's
Emission rate
Isokinetic saapllaf net
I » fl.667
6, O'O
IbsAxr
Ibs/
"\
mln t
sec/
.002669 in.Ht.cu.ft,
ml. '\
97 P A
s s n
(A.
-------
COMPANY:
SOURCE: *»••**
REPETITION NO: 7
1. i DATE: a - #- 9" 7
'j'
Dry molecular weight of stack gaa
Mj - 0.44 (ICO,) + 0.32 (20.) + 0.28
fl «. *
? 7 1>0
Molecular weight of stack gaa, vet baaia
Ms • Md (>BVS) * 18 Bwg
Pitot tube coefficient
C (from calibration curve)
P
Average velocity head of stack gas, inches 1
( /ST ) «*!•
Average absolute stack gaa temperature
(Tf) avg.
460
Absolute stack gaa pressure
F • P. + (Static Praasura/13.6)
SD
: gaa velocity
(V§) avj. - (83.49) Cp
ICO)
/ (T }
rrg.
lb/lb-aola
Ib/lb-aola
in. S
Stack gas volume flow rate
60 Vs As
Stack gas volume flow rate, dry baaia
Q§ - 3,600
ft/sec.
acfm
latd . f.
• P
.td .
dscf/h:
-------
-------
t I t
J I • I
tCNEMATK OP STACK
PLANT,
DATE .
•
•
J_
LOCATION .
OPERATOR.
STACK NO. .
RUN HO. _L
i i • i I
AMMEHT TEMPERATURE
BAROMETRIC PRESSURE .
ASSUMED I
METER All,
r. i
PROBE LENGTH. U.
MOHLE DIAMETER. !•. -1
STACK DIAMETER. U
CMU SECTION
SAMPLE BOX NO. X
MITER BOX NO. J
PROBE HEATER SCTTINC.
NEATER BOX SETTING.
•EIGHT OP PANIICULATE COLLECTED. .,
SAMPLE
FINAL VEIGIII
TANEVklCIIT
•EIGHT GAIN
FILTEfl
PIIOUC W/
TOTAL
AVCMACC
•
«Ol*UME OP LIQUID
•AtER COLLECTED
PINAL
INITIAL
LIQWO COLLECTED
10
OLUME CCM LICTID
"S^"- tSW
1114 ,
1
1
J_
IOMMCMM:
UMSAT MEASUHEMEMI
T"
1
TIMt
CO
-------
r
F
[•
.
L
I:.
L
I
c
L
SAMPLE VOLUME
SULFUR DIOXIDE CALCULATION FORM
(English Units)
££/0 (Z£F/A>'*J*
m
m
ft
Pbar - 3Q.:n in. Hg
Y - 1-OlS
Vm(std) ' 17-W
'R
Y V
in. Hg
SO, ANALYSIS DATA
2
N * OfOfe C£-«0 /ml
«1
tb
solji
n>l
^S nl
S0 ODNCENIRATION IN STACK
^2-
S02 HUSSION RA3E
S03 CONCENTRAnON.IN.STAaC GAS
- 8.826x 10"5 N (Vt - V^
m(std*
S03 EMISSION RATE
DSCFH
* A H ~|
TTFl - »«.
727ft Equation 6-1
S03 ANALYSfS DATA
PPI by Voluni Dry Basis
X 10*5 Ib/dscf
By Volw Dry Basis
O.OQ96lbs/hr
-------
HEMATIC OF STACK
PLAI.
DATE
LOCAT
OPERATOR.
STACK NO. .
RUN NO
bMTA
AMUIEHT TENPEHATURE
MAHOMET NIC PRESSURE .
T~~
jf.- ASSUMED MOISTURE. I _
PROiF. LENGTH. I. 3£
NOZZLE DIAMETER. I. '
i /•
METER Ally
Cl
PROCESS WIGHT RATE
STACK DIAMETER. U
CROSS SECTION
SAMPLE MX NO.
METE* MX NO. .
PROM HEATER VETTING.
NEATER MX SETTING
•EIGHT OP PAMTICULATE COLLECTED. •.,
SAMPLE
FINAL VEICNT
TARE HEICHf
•EIGHf CAIN
FILTER
PHOOE w*
TOTAL
TRAVERSE
PUNT
NUMBER
SAMPLING
TIMC
STATIC
PRESSURE
STACK
TEMPERATURE
ITI. -P
VELOCITY
HEAD
PIIESSUM
DIFFERENTIAL
ACROSS
ORIFICE
METER
ItNl
I«..N,0
ACTUA OESMEO
GAS SAMPLE
VOLUME
OM.M
GAS SAMPLE TEMPERATURE
At DRV CAS MEIER
INLET
IT..J.-F
OUTLET
SAMPLE MX
TEMPERATURE
•P
TEMPERATURE
OF GAS
LEAVING
CONDENSER OR
LAST IMPINCER
•P
PUMP
VACUUM
UN,
VELOCI
•f.
Vt
&
J&o.
_££
-££_
w.
01
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-------
-------
M M
P
g
*
8
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a
p.
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uck
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ty
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pr*i«ur«
W
0
*
2
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cr PH
<• 1
o t> 1
'
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ft
c
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e
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nc
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a"
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n
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r.
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COHPAJTf:
SOURCE:
REPETITION NO:
TEST DATE: 3 "/3~
Volua* of saapl* «t standard
condition* on dry basia
mstd
D4CI1SH UNITS
(29.92 ia. Ht 68*F)
Volunt of wactr vapor ia sanplt at
standard condition*
c
E
Vwstd
Vlc -
Fractional i
Bw. •
0.04707 cu. ft.
•1
"?// •!.
7lc
Boistur* content of stack gaa
Vw»td
Vm*td -t- Vwstd
___•_ __ *
Partiela concantration ia stack gas oa dry basis
o.01543 [" Ma"[
pa.
e's
L
2.205 10
3-077
'mstd
Stack gas volua* flow rat* ea dry_ basis
T.
3600 (1-1J
• •
(A.
_s • sq.ft. V§-
Procass rat* or BID racing 1
Esdssioa rat*
ft/s«c)
Q e'a
0 «'•
tsokiaatie
I •
rat*
(0.002669
v.
•» » A.
• • a
dscf.
scf.
_train*/c
x 10"6lb
x 10 die:
.Ibs/nr
Ibs/
X,-Y C
j "$r\.
E
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