EPA-600/3-77-039
April  1977
Ecological Research Series

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                RESEARCH REPORTING SERIES

Research reports of the Office of Research and Development, U.S. Environmental
Protection Agency, have been grouped into nine series. These nine broad cate-
gories were established to facilitate further development and application of en-
vironmental technology.  Elimination  of traditional grouping was  consciously
planned to foster technology transfer and a maximum interface in related fields.
The nine series are:

      1.  Environmental  Health Effects Research
      2.  Environmental  Protection Technology
      3.  Ecological Research
      4.  Environmental  Monitoring
      5.  Socioeconomic Environmental Studies
      6.  Scientific and Technical Assessment Reports (STAR)
      7.  Interagency Energy-Environment Research and Development
      8.  "Special" Reports
      9.  Miscellaneous Reports

This report has been assigned to the ECOLOGICAL RESEARCH series. This series
describes research on the effects of pollution on humans, plant and animal spe-
cies, and materials. Problems are assessed  for their long- and short-term influ-
ences. Investigations include formation, transport, and pathway studies to deter-
mine the fate of pollutants and their effects. This work provides the technical basis
for setting standards to minimize undesirable changes in living organisms in the
aquatic, terrestrial, and atmospheric environments.
This document is available to the public through the National Technical Informa-
tion Service, Springfield, Virginia 22161.

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                                               EPA-600/3-77-039
                                               April 1977
MUSKEGON, MICHIGAN INDUSTRIAL - MUNICIPAL WASTEWATER

        STORAGE LAGOONS:  BIOTA AND ENVIRONMENT

                          by
                 W. Randolph Frykberg
       Northeast Michigan Council of Governments
                Gaylord, Michigan  49735
                 Clarence Goodnight
              Western Michigan University
              Kalamazoo, Michigan  49008
                   Peter G. Meier
  The University of Michigan,  School of Public Health
             Ann Arbor,  Michigan  48104
              Contract Number  04J1P01534
                    Project Officer
                    Leslie P.  Seyb
          Ecological Effect Research Division
      Corvallis Environmental  Research Laboratory
              Corvallis,  Oregon  97330
      CORVALLIS  ENVIRONMENTAL RESEARCH LABORATORY
          OFFICE OF RESEARCH AND DEVELOPMENT
         U.  S. ENVIRONMENTAL PROTECTION AGENCY
              CORVALLIS,  OREGON  97330
                               A

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                             DISCLAIMER
     This report has been reviewed by the Corvallis Environmental
Research Laboratory, U. S. Environmental Protection Agency,  and
approved for publication.  Approval does not signify that the con-
tents necessarily reflect the views and policies of the U. S. Envi-
ronmental Protection Agency,  nor does mention of trade names or
commercial products constitute endorsement or recommendation for use,
                                 11

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                               FOREWORD
Effective regulatory and enforcement actions by the Environmental
Protection Agency would be virtually impossible without sound scientific
data on pollutants and their impact on environmental stability and human
health.  Reponsibility for building this data base has been assigned to
EPA's Office of Research and Development and its 15 major field instal-
lations, one of which is the Corvallis Environmental Research Laboratory,
(CERL).

The primary mission of the Corvallis Laboratory is research on the effects
of environmental pollutants on terrestrial, freshwater, and marine eco-
systems; the behavior, effects and control of pollutants in lake systems;
and the development of predictive models on the movement of pollutants
in the biosphere.

This report describes the results of a two year limnological study of the
largest industrial-municipal wastewater storage lagoon in the United
States.  It is important to have a better understanding of how such waste-
water can be treated and utilized in an efficient manner.  This report is
a major step to identify elements of effective wastewater management.
                                                A.F.  Bartsch
                                                Director,  CERL
                                111

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                               ABSTRACT







     A limnological investigation was carried out on two 344 hectare




(850 acre) industrial-municipal wastewater storage lagoons from




August 1973 until August 1975.  Besides monitoring physical and




chemical parameters during the period of the initial filling,




the biological community was critically examined for the purpose




of documenting ecological succession over this two year period.




     In general, the lagoons remained aerobic, well mixed vertically




and slightly alkaline.  The low transparency within the lagoons




was an important factor which limited the phytoplankton population




and excluded rooted aquatics and benthic algae.  Ample nutrients




were present for algal demands.




     The lagoon's phytoplankton-protozoan assemblage was extremely




variable with respect to both total abundance and distribution.




The zooplankton community was composed of fourteen species of free




living crustaceans and four species of rotifers.  The benthic fauna




consisted of a small number of organisms representing only a few




taxonomic groups.




     This report was submitted in partial fulfillment of order number




04J1P01534 by Western Michigan University, Biology Department, under




the partial sponsorship of the U. S. Environmental Protection Agency.




Work was completed as of August 1976.
                                  IV

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                      TABLE OF CONTENTS







SECTION                                             PAGE







   I.   INTRODUCTION 	   1




         The Muskegon Wastewater Management System.   1




         Background Literature 	,	,   3







  II.   CONCLUSIONS 	   5







 III.   RECOMMENDATIONS 	   7







  IV.   STUDY DESIGN AND METHODOLOGY 	   9







   V.   RESULTS AND DISCUSSION 	  19







         Wastewater Flow Pattern 	  19




         Biological Parameters	  21




           Benthos 	  21




           Zooplankton 	  31




           Plankton	  40




             Trends and dominants .,..,...	  40




             Implications 	  47




           Chlorophyll a. 	  47




           Primary productivity 	  51




         Primary and Chemical Parameters ..........  53







  VI.   REFERENCES 	  72
                             v

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                     LIST OF FIGURES
FIGURE                                                 PAGE
   1.  MUSKEGON WASTEWATER LAGOONS 	  10
   2.  CHANGES IN ABUNDANCE AND COMPOSITION OF
       BENTHOS AT E-l AND W-l 	  22
   3.  DAPHNIA AS A PERCENTAGE OF THE TOTAL
       ZOOPLANKTON POPULATION 	  34
   4.  CYCLOPOID COPEPODS AS A PERCENTAGE OF THE
       TOTAL ZOOPLANKTON POPULATION 	  36
   5.  NUMBER OF PLANKTON IN THE MUSKEGON LAGOONS ....  41
   6.  CHLOROPHYTA AS A PERCENTAGE OF THE TOTAL
       PLANKTON POPULATION 	  44
   7.  MASTIGOPHORA AS A PERCENTAGE OF THE TOTAL
       PLANKTON POPULATION 	  48
   8.  QUANTITY OF CHLOROPHYLL a_ IN THE MUSKEGON
       LAGOONS	  50
   9.  PRIMARY PRODUCTIVITY IN THE MUSKEGON LAGOONS ..  52
                          VI

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                      LIST OF TABLES
 TABLE                                                 PAGE
 1.   CONVERSION OF CPM TO CARBON FIXED 	 15
 2.   WASTEWATER FLOW PATTERNS 	 20
 3.  PERCENTAGE COMPOSITION OF BENTHIC POPULATION 	 23
 4.   SPECIES DIVERSITY INDICES 	 29
 5.  PERCENTAGE COMPOSITION OF ZOOPLANKTON 	 32
 6.   PERCENTAGE COMPOSITION OF PLANKTON	 42
 7.  COMPARISON OF TEMPERATURE, DISSOLVED OXYGEN,
     AND BIOCHEMICAL OXYGEN DEMAND IN THE MUSKEGON
     LAGOONS 	 54
 8.  COMPARISON OF TURBIDITY, SECCHI DISK TRANSPARENCY,
     pH, CONDUCTIVITY, AND TOC IN THE MUSKEGON LAGOONS . 59
 9.  COMPARISON OF NUTRIENT AND ANION LEVELS IN THE
     MUSKEGON LAGOONS 	 63
10.  COMPARISON OF METAL AND CATION LEVELS IN THE
     MUSKEGON LAGOONS 	 68
                          Vll

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                            ACKNOWLEDGEMENTS







     Many individuals have had important roles in assisting the




research program reported herein.  The authors wish to express their




appreciation to Professors Joseph G. Engemann, George G. Mallinson




and Richard W. Pippen for their advice and general assistance.  A




special note of appreciation is extended to Diane K. Frykberg, Susan




Ramirez and Nancy DeGroot for their typing and editing efforts.  Sin-




cere thanks also go to graduate students Frank D. Hallow, Roderick J.




Morrison, Wolfgang Schroeder and Julie Scott, for their assistance in




the laboratory; Andrew Rollins for the use of his facilities; Richard




Wember and Greg Cioe from the Muskegon County Wastewater Management




Project, for their aid in collection of the samples; Dr. Y.A. Demirjian,




Tim Westman, Pat Kelly, and the rest of the staff from the Muskegon




County Wastewater Management Project, for their assistance in the physical-




chemical aspects of the study;  and to Marie Goodnight and Nancy Blum




for their assistance with editing.




     The partial financial support of this study by the United States




Environmental Protection Agency is greatly appreciated.
                                 Vlll

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                              SECTION  I



                             INTRODUCTION







THE MUSKEGON, MICHIGAN, WASTEWATER MANAGEMENT SYSTEM






     As the demands on water resources increase, the need for more




effective wastewater management becomes apparent.




     The Muskegon County, Michigan, Wastewater Management System is




an alternative to conventional wastewater treatment and disposal




methods.  Rather than discharging the nutrient-rich wastewater to a




river, stream, or lake, the Muskegon System uses it as irrigation water,




allowing the soil and plants to "polish" the effluent.




     This land treatment wastewater system does more than just clean




the polluted water which is receiving treated effluents, for it is




a biological system that recycles nutrients; reclaims water to meet




drinking water standards; and retains wastewater constituents not




suitable for recycling.  The Muskegon facility was modeled largely




on a 570 million liter per day  (MLD)  [150 million gallon per day  (MGD)],




8094 hectare  (ha)  (20,000 acres) land treatment system in Melbourne,




Australia  (Ward, 1975) and the Pennsylvania State University forest




land application experiments  (Boyer and Reid, 1973).




     This system treats both domestic and industrial wastewater from




the greater Muskegon area.  The major contributors to the system are,




in decreasing magnitude of flow, a paper mill, 14 municipalities,




three chemical companies, an engine manufacturing plant, a metal




casting and plating firm, and over 150 smaller industries.

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     The 100-125 MLD  (25-33 MGD) of combined wastewater is pumped




17.7 km  (11 miles) to the  4,371 ha   (10,800  acre)  treatment  site where




it is discharged into three treatment cells.  The biological activity




in these cells is aided by mixing and aeration.  With an average




detention time of three days, these cells produce an effluent comparable




in quality to that achieved by secondary treatment.




     From these cells the wastewater is discharged into one or both




of the storage lagoons for further stabilization or directly into the




outlet pond.  Throughout this investigation, except for a few weeks




during high irrigation demands, the semi-treated wastewater was




discharged into the lagoons prior to being used as irrigation water.




Each storage lagoon covers 344 ha (850 acres), for a combined storage




capacity of 19.3 billion liters  (5.1 billion gallons).  In order to




prevent seepage from entering the groundwater outside of the treatment




site, a drainage or interception ditch encircles both lagoons.  Water




collected from this ditch is returned to the West Lagoon.




     In late May 1973, a small amount of industrial and municipal




wastewater effluent was being discharged into both Muskegon lagoons.




At that time, there was also some rainwater in the basins  but the




bottoms of the lagoons were not covered, due to evaporation and




seepage, until August 1973.  At this time, the flow had increased to




about 106 MLD (28 MGD) and the constituents of the wastewater, notably




waste paper and pulp fiber and waste clay filler, had helped to seal




the bottom.

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BACKGROUND LITERATURE






     Little information exists on a world-wide basis concerning lim-




nological investigations of storage ponds, especially large lagoons such




as those described in this project.




     This study is an attempt to gain greater insight into the intri-




cate relationships that exist between the aquatic community and its




environment.




     The great majority of reports on wastewater lagoons deal with the




design, engineering, and performance aspects of these facilities.




Fewer are concerned with the physical-chemical aspects, and only a




very limited number of studies discuss the biological aspects of com-




bined municipal-industrial wastewater lagoons.




     In an extensive study of the wastewater lagoons of the world,




Gloyna (1971) devoted only a 15 page annex to their limnology.  The




organisms discussed were limited to bacteria, protozoa, and algae.




The dominant and sub-dominant algae of an oxidation pond in




Ahmedabad, India, over a seven month period of 1962 were reported




(Jayangoudar and Ganapati, 1964)„  In a study concerned mainly with




the physical-chemical characteristics of domestic sewage oxidation




ponds, Lakshminarayana et al (1964) found that algae and zooplankton




populations were small.  Davis, et al (1964) investigated the




bacteria and algae of ten small wastewater lagoons in Oklahoma and




found that the  green  algae  (Chlorophyta)  predominate  during  the  winter




months whereas the blue-greens  (Cyanophyta) were most prevalent during

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the summer and early fall.  The flagellates (Euglenophyta) appeared




intermittently throughout the year.  Davis  (1964) also  reported on




oxidation ponds in Texas, in which he described the biota in only one




paragraph.




     In a report on the experiences with wastewater lagoons in the




United Kingdom, Potten  (1972) referred to several genera of plankton




as being "typical" lagoon inhabitants.  A more complete report on




municipal wastewater lagoon phytoplankton is a doctoral dissertation on




algal periodicity and primary productivity  (Raschke, 1968).  The lagoon




studied, however,  was quite small (0.05 ha)  and the detention time




was only a few days.   A summary of this study was later published




 (Raschke, 1970).  Silva and Papenfuss  (1953) investigated the phyto-




plankton of small wastewater lagoons in California.




     Chlorella, Chlamydomonas, Ankistrodesmus, Scenedesmus, Anacystis,




Oscillatoria, Euglena,  and Phacus were cited as  the  dominant and sub-




dominant phytoplankton  in most of the above studies.




     Microscopic crustaceans, notably Daphnia and Cyclops, comprised




the dominant  zooplankton  in various  lagoons (Gloyna, 1971).  The




midges  (Chironomidae) dominated  the  benthic macroinvertebrate popu-




lation  of wastewater  lagoons in  California  (Grodhaus,  1967), Missouri




 (Kimerle  and  Enns, 1968),  and Michigan  (Merritt,  1976).   Additional




information concerning  the zooplankton and  benthos  of  wastewater




lagoons appears to be  lacking.




     The  primary goal  of  this  research was  to generate baseline  infor-




mation  concerning the  limnological and especially the  biological as-




pects of large wastewater lagoons.

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                              SECTION II




                              CONCLUSIONS







 1.   The  results of a  two-year limnological  study  of  the  largest




 industrial-municipal  wastewater  storage lagoons in the United  States




 are  reported herein.   This  investigation began shortly after the  con-




 struction of the wastewater facility.




 2.   In general, the lagoons remained aerobic except  for  a  few  weeks




 during ice-cover.




 3.   BOD5 values between 15  and 20 mg/1 were common.




 4.   Transparency, as  measured by a secchi disk, was  shallow and




 averaged only about 20 cm.   The rapid vertical extinction  of light




 limited  the phytoplankton population and excluded rooted aquatics




•and  benthic algae.





 5.   The lagoons remained slightly alkaline  (pH^^7.7) even during




periods of high photosynthetic activity.




 6.   Ample nutrients were present for algal demands.




 7.   The concentrations of several metals,  most notably zinc, were




relatively high.




8.   The phytoplankton-protozoan assemblage was extremely variable




with respect to total abundance and distribution.   The range of




this population was from less than 20 to more than 22,000 units/ml.




The Chlorophyta were  the dominant algae except for several weeks




each summer when the Cyanophyta reached bloom proportions.




9.  Several chlorophyll a_ and primary productivity peaks were noted,




but  in general,  values near 12 mg/1 chlorophyll ,a and 25 mg C/m3/hr




were common.

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10.  Three species of Daphnia,  the dominant zooplankter,  were routinely




collected.  Cyclops vernalis was the most common cyclopoid copepod while




Diaptomus was the only calanoid copepod recovered.  The zooplankton




community was composed of only four species of rotifers and fourteen




species of free-living crustaceans.




11.  The benthic fauna was very limited, and remained below 100 organ-




isms/0.1 m2 in 95% of the samples.  Midges (Chironomidae) accounted for




virtually all of the sparse population.  Procladius culiciformis and




Glyptotendipes barbipes were the most common benthic forms.  It appears




that the sparsity of this population can be attributed to the stressed




lagoon environment in which the concentrations of several metals, most




notably zinc, were relatively high.

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                              SECTION III
                            RECOMMENDATIONS

1.  It is important to investigate the environment and population

of the Muskegon Lagoons, the largest wastewater lagoons in the U. S.,

in order to determine what wastewater treatment is needed and to

determine how the wastewater can best be utilized.  The Muskegon

project is a pilot project, and limnological information gathered

concerning these lagoons should help in future design and management

of land treatment and/or lagoon wastewater systems.
                       V

2.  A limnological investigation of the Muskegon Lagoons should be

continued in order to further analyze the details of succession and

colonization of the lagoons and to determine if a somewhat more

stable community may be established.


3.  The following special studies are also recommended:

     a.  Benthos - Investigate why the benthic fauna is so limited.

     Even the normally ubiquitous oligochaetes were nearly absent

     during the first two years of study.  Because the present study

     points to the involvement of metals, this parameter should be

     thoroughly studied including sediment analysis.

     b.  Phytoplankton - Follow the seasonal dynamics of phyto-

     plankton, chlorophyll _a, and primary productivity.  Investigate

     heterotrophic assimilation,  which appears important in these

     lagoons, and its relationship to autotrophic production.

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c.  Zooplankton - Investigate the rate of incorporation of




heterotrophic and autotrophic carbon by the indigenous zooplankton




population.  Investigate the population dynamics of the zooplankton.

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                              SECTION IV




                     STUDY DESIGN AND METHODOLOGY







DESIGN






     The limnology of the 688 ha (1,700 acre) Muskegon combined




municipal and industrial wastewater lagoons was investigated from




the time of the initial filling in August 1973 through August 1975.




Special emphasis was placed upon the biological aspects of these




bodies of water.  Three stations were established in each lagoon




(Figure 1).  The station locations and designations corresponded




to those used by the Muskegon County Department of Public Works,




which served as manager of the system.




     Each lagoon was sampled biweekly from September 1973 through




14 May 1975.  For the remainder of the study, the samples from each




lagoon were collected on a weekly basis.  During periods of open




water, all samples were taken within 50 feet of the station using




an aluminum boat.  When the lagoons were ice-covered,  December




through March, samples were taken 50 feet from and perpendicular




to the shore and in line with the station.  For safety reasons,




Stations E-5 and W-5, the stations farthest from shore in both the




East and West Lagoons, were not sampled during periods of ice cover.




     A 2.2 liter, horizontal, opaque, non-metallic Van Dorn bottle




was used to collect samples for analysis of the following parameters:




plankton; chlorophyll; primary productivity; temperature; dissolved




oxygen (DO); five-day biochemical oxygen demand (3005); turbidity/-




conductivity; pH; total organic carbon; metals that included calcium,

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 BIO
BIO
             BIO
SET
                          OUT  -
                        -H-
                        OP

                        ww
               •
              W-5
                     EQ H
         W-9
                    ID
                                       E-l
              r EQ
  •
E-5
                                                         E-8
Figure 1  Muskegon Wastewater Lagoons

KEY

BIO = Biological Treatment Cell

OUT = Outlet Pond

SET = Settling Pond

EQ  = Equalizing Gate

ID  = Point of discharge of interception ditch water
                             OP  = Point of discharge of lagoon water to
                                   outlet pond

                             WW  = Point of discharge of wastewater to
                                   lagoon
                                 10

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 iron, magnesium, manganese, potassium,  sodium,  and  zinc;  nutrients  which




 consisted of orthophosphate, nitrate, and ammonia nitrogen;  chlorides;  and




 sulfate.  Samples were collected  from several depths  at each station.   An




 Ekman dredge was used to collect  replicate benthos  samples,  and  a number




 12 plankton net  (mesh opeings equal to  0.12 millimeter) was  employed to




 collect replicate zooplankton samples.







 METHODOLOGY







     When feasible, standard procedures and techniques, as described in




 Standard Methods for the Examination of Water and Wastewater (American




 Public Health Association, et. al, 1976)  and in Biological Field and




 Laboratory Methods for Measuring  the Quality of_ Surface Waters and  Effluents




 (Weber, 1973), were adhered to as closely as possible.  Specifics for each




 parameter are further described below.







 Benthos







     A 15.8 cm Ekman Dredge was used to collect replicate benthos samples.




 Because of the limited benthic population and since this dredge  sampled only




 0.025 square meter, results were reported as number of organisms per 0.1




 square meter.  After retrieval of the bottom sample,  the contents of the




dredge were washed through a No. 30 sieve (11 meshes per centimeter) and the




retained portion was dumped into a white enamel pan.  The organisms then were




hand picked and preserved in 70% ethanol.




     Numerous taxonomic references aided the identification  of the benthic




macroinvertebrates (Beck, 1968;  Chernovskii, 1949; Curry, 1962;  Edmondson,




1959b;  Grodhaus, 1967;  Johannsen, 1934-37; Mason, 1973; Pennak,  1953; Peterson,




1967; Robeck, 1957;  Ross, 1944;  Usinger, 1956).
                                    11

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     For species identifications of the midges,  it was necessary to prepare
head and body mounts of these organisms.  Rather than using the conventional
but very time consuming technique of clearing the midges in KOH, rinsing, and
then mounting (American Public Health Association, 1976; Mason, 1973; Weber,
1973), the midges were mounted directly into polyvinyl lactophenol.  This
substance acts as both a clearing agent and a mounting media.
     Data from replicate samples were averaged,  and the results reported as
number of individuals per tenth square meter.  The mean diversity, d, and
equitability, e, were calculated for each station using the formulas presented
in the Biological Methods Manual  (Weber, 1973).

Zooplankton

     Replicate vertical tows were taken from 0.3 m above the bottom.  Although
a number 20 net is recommended  for the capture of nauplii, protozoa, small
rotifers, and other nannozooplankton, a number 12 net  (aperture size 0.12  mm)
was used to prevent clogging by the unusually large quantities  of  suspended
matter.  The samples were preserved with Koechie's preservative, a saturated
sucrose - 4% buffered  formalin  solution.
     Several one milliliter  subsamples  were withdrawn  from each zooplankton
replicate with  a Hensen-Stemple pipette.   Each subsample was deposited in a
nine-depression glass  culture dish and  analyzed  quantitatively and qualita-
tively.  Genus  and  species  identifications of cyclopoid copepods were  based
on minute anatomical details of specimens dissected between  the fourth and
fifth  thoracic  segments  and mounted,  ventral  side up.   Several taxonomic ref-
 erences were valuable aids to  identification (Bousfield,  1958; Brooks, 1957
and  1959; Edmondson,  1959a  and  1959b;  Gannon, undated; Pennak, 1953; Torke,
 1974;  Wilson and  Yeatman,  1959).   Data from  replicate samples were averaged
and  the results were  reported  as the number  of  organisms per liter.
                                     12

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Plankton






     Throughout this report, the word "Plankton" will be used to refer to




phytoplankton and protozoa.




     Sampling depths were related to the transparency within each lagoon.




Routine sample collection was at the depth of the secchi disk reading and




also at one-half of this depth.




     At times, due to the very low transparency, collection was at the secchi




disk transparency and also at 0.45 meter.  In addition to sample gathering




at these depths, samples were also taken at 0.3 meter above the bottom from





April 1975 throughout the remaining period of the study.  With the exception



of primary productivity, all parameters collected with the Van Dorn bottle




were analyzed at these identical depths.




     The samples were preserved with Lugol's solution and allowed to settle




for several weeks.  Due to the few plankton present, the samples were con-




centrated by a factor of 16 by withdrawal of the supernatant with a suction




tube.  Centrifugation proved unsuitable as a concentration technique in this




study.  The centrifuged samples remained cloudy and microscopic examination




revealed that some species were still remaining in the supernatant.  Davis




(1966) has had similar results with centrifugation.




     A Palmer-Maloney cell, rather than the Sedgwick-Rafter cell, was used




for quantitative and qualitative analysis because of the higher magnification




required for nannoplankton.  Twenty fields were examined in each of several




slide preparations.  The results were averaged for each sample and reported as




the number of units per milliliter (ml).  The clump count was used, with all




filamentous or colonial organisms counted as one unit.




     Diatom mounts were initially made by ashing and mounting the diatoms.  Up




to 2.5 ml were evaporated through successive dryings on 18 mm circular coverslips.





                                    13

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 This  subsample  was  then ashed on  a  hot  plate  at  570°C  for  at  least one  hour.




 Hyrax,  with a refractive index of 1.82, was used as  a  mounting media.   The




 silicious  frustules were examined under oil immersion.   The concentration of




 diatoms, however, was  normally inadequate  for this technique.  The recommended




 250 cells  per slide (Weber,  1973) could not be examined.   Further  sample




 evaporation on  the  cover slip was not appropriate due  to the  high  collodial




 clay  content of the lagoons.  Crushing  and masking of  the  diatoms  occurred with




 any higher sample concentration.  Therefore,  the membrane  filter technique




 (Stoermer  e_t al, 1972)  with modifications  of  Lugol fixation,  filtration and




 subsequent clearing and embedding in clove oil was utilized for diatom  counts




 from  August 1974 through the remainder  of  the study.




      References relied  upon for the analysis  of  the  plankton  included Serges




 (1971), Drouet  (1959),  Edmondson  (1959a),  Kudo (1971), Lackey (1959), Noland




 (1959), Parrish  (1968),  Patrick (1959), Patrick  and  Reimer (1966),  Prescott




 (1962 and  1968), Thompson (1959), and Weber (1966).






 Primary Productivity







      The uptake of  inorganic carbon by phytoplankton during photosynthesis




was measured with the carbon-14 method of  Steeman-Nielson  (1952),  incorpo-




 rating only minor modifications (Jordon, 1970; Saunders, e_t al, 1962; Weber,




 1973).  The  four hour in  situ incubation depths were determined by  the  secchi




disk  transparency.  Secchi readings as low as  6  to 12 cm often dictated pro-




ductivity  incubation at only one depth.  Following incubation and filtration,




filters were air dried and their beta activity subsequently counted.  Pro-




ductivity  is expressed in the amount of carbon fixed per hour from  the equation




in Table 1.
                                    14

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              TABLE  1.  CONVERSION OF  CPM TO CARBON FIXED
Conversion equation

P

r

C


f

R
Microcuries used

Counter efficiency

Membrane absorption
factor

Disintegrations per
minute per microcurie

Final equation for
lagoons
P = - X C X f      (Saunders, et al, 1962)
    R                         -

Photosynthesis in mg C/m3

cpm counted (uptake of radioactive carbon)

19.2 X 103 mg C/m3  (available inorganic
                     carbon in the lagoons)

1.06     (Isotope conversion factor)

4.27 X 105   (total available radioactive
              carbon in cpm:  microcuries
              used X counter efficiency X
              millipore absorption factor
              X disintegration per minute
              per microcurie)
37,000
40 290  (scintillation cpm/microcurie)

0.25

0.838
2.22 X 106
P = r X 0.0477
                                 15

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Chlorophyll






     This analysis was accomplished in vitro from acetone extracts by fluo-




rometry.  The samples were drawn from the same locations and at the same time




as the plankton samples.  Immediately after collection of the sample, MgCO3




was added in the field.  After filtering 100 ml, the 0.45 micron membrane




filters were frozen until analysis at a later time.  Results were reported as




mg/m^ of chlorophyll a_ and phaeophytin.







Dissolved oxygen







     The DO samples were fixed in the field immediately after collection and




were titrated in the laboratory.  The azide modification of the iodometric




method was used.  Results were reported as milligrams  (mg) DO/1,







Biochemical oxygen demand







     The five day BOD test was used with incubation in the dark at 20°C.  Re-




sults were reported as mg BOD5/1.






Secchi disk transparency






     A 20 cm diameter black and white secchi disk was used.  Results were re-




ported in centimeters.







Turbidity







     A Hach Model 2100A Turbidometer was used for direct measurement of  tur-




bidity by the Nephelometric method.  Results were reported  in Formazin Tur-




bidity Units  (FTU), equivalent  to Jackson Turbidity Units.
                                     16

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pH







     A hydrogen ion selective glass electrode in combination with a satu-




rated calomel reference electrode were used to determine pH by the electo-




metric method.  Results were reported in standard pH units.







Conductivity







     A platinum electrode type specific conductance cell with a cell constant




of 1.0 + one per cent was used.  Conductance measurements were taken at




ambient temperature utilizing a Barnstead Conductance Bridge.  Results were




reported in micro-mhos per cm.              ,







Nitrate nitrogen







     The concentration of nitrate nitrogen was determined through a copper-




cadmium reduction of nitrate to nitrite.  The nitrite thus produced was quanti-




fied using sulfanilamide  (diazotizer) and N-1-naphthyl-ethylenediamine (couplet).




The resulting highly colored dye was measured colorimetrically and the results





were reported as rag NOj-N/1.







Ammonia nitrogen







     The concentration of ammonia nitrogen was determined by distillation




followed by nesslerization.  Results were reported as mg NH4/1-







Or thopho spha te







     The concentration of orthophosphate was determined by colorimetry, with-




out preliminary filtration, digestion, or hydrolysis, using ammonium molybdate




in the vanadomolybdophosphoric acid method.  Results were reported as mg PO4-P/1.
                                    17

-------
Sulfate







     The concentration of sulfate was determined using the Barium-Methythymol




Blue colorimetric procedure.  Results were reported as mg SOg/1.







Chlorides







     The concentration of chloride was determined by liberation of the thiocya-




nate ion from mercuric thiocyanate, followed by a reaction with the ferric ion.




Results were reported as mg Cl~/l-







Total organic carbon







     The concentration of total organic carbon  (TOC) was determined using a




Beckman Model 915 Total Carbon Analyzer.  Results were reported as mg carbon/1.







Metals







     The concentrations of calcium (Ca), iron (Fe), magnesium (Mg), manganese




(Mn), sodium (Na), potassium  (K), and zinc (Zn)  were determined using flame




ionization photometry and atomic absorption spectroscopy.  Results were re-




ported as mg of the specific metal/1.
                                    18

-------
                                 SECTION V




                          RESULTS AND DISCUSSION







     The data gathered during this investigation are presented in the appendices




and only summary data appear in this section.  The results of each parameter will




be discussed individually and the trends, or relationships, among parameters




will be elucidated where appropriate.





     The water depths in the lagoons fluctuated from approximately one meter





to 3.5 meters.  The only exception was at W-9, which, due to a depression




was 2.5 meters deeper than the other stations.







WASTEWATER FLOW PATTERNS DUE TO GATE OPERATING POSITIONS







     During this investigation, the operating positions of the gates that




controlled inflow, outflow, and mixing between lagoons were altered as indi-




cated in Table 2.




     From 18 August 1973 through 26 September 1973 the wastewater was dis-




charged into both lagoons, with the exception of three days when it was used




directly for irrigation water.  From 27 September 1973 through 3 March 1975




the wastewater was discharged only into the East Lagoon, with the exception




of 13 days when it was employed directly for irrigation water.  On 4 March 1975




there was a major change in the flow pattern, with the wastewater being dis-




charged into the West Lagoon for the first time since September 1973.  The West




Lagoon received the wastewater throughout the remainder of the study, with the




exception of a two-week period and a one-week period when the wastewater was




used directly for irrigation water.  In summary, the East Lagoon received vir-




tually all the wastewater throughout the first 18 months of this investigation.
                                    19

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  TABLE 2.  WASTEWATER FLOW PATTERNS AND GATE OPERATING POSITIONS
  GE = Gate to East Lagoon
  EL = East Lagoon
 EQU = Equalizing gate between East
OUTE = Outlet gate from East Lagoon
OUTW = Outlet gate from West Lagoon
WMDS = Outlet gate from West Lagoon
       West Lagoon
  GW = Gate to West Lagoon
  WL = West Lagoon
and West Lagoons
to irrigation
to irrigation
to Mosquito Creek (draining the
DATE
8-13-73 - 8-17-73
8-18-73 - 9- 4-73
9- 5-73 - 9- 7-73
9- 8-73 - 9-26-73
9-27-73 - 3-29-74
3-30-74 - 4-29-74
4-30-74 - 7- 5-74
7- 6-74 - 9-19-74
9-20-74 -11-13-74
11-14-74 -12-13-74
12-14-74 - 3- 3-75
3- 4-75 - 4-11-75
4-12-75 - 6-24-75
6-25-75 - 7-18-75
7-19-75 - 8- 6-75
8- 7-75 - 8-13-75
8-14-75 - 8-19-75
FLOW TO
Irrigation
EL, WL
Irrigation
EL, WL
EL
EL
EL
EL
Irrigation
EL
EL
WL
WL
Irrigation
WL
Irrigation
WL
OPEN

EQU
EQU
EQU

EQU
EQU, OUTW
OUTE
OUTE

WMDS

OUTW
OUTE
OUTW

OUTW
CLOSED
EL, WL
OUTE, OUTW
EL, WL
OUTE, OUTW
OUTE, OUTW, EQU
OUTE, OUTW
OUTE
OUTW, EQU
OUTW, EQU
OUTE, OUTW, EQU
OUTE, OUTW, EQU
OUTE, OUTW, EQU
OUTE, EQU
OUTW, EQU
OUTE, EQU
OUTE, OUTW, EQU
OUTE, EQU
                                20

-------
During this period, the West Lagoon received mainly the interception ditch




water.  During the last six months of study the wastewater was discharged




predominantly into the West Lagoon, while the East Lagoon did not receive




any discharge.  In the analyses that follow, the estimation of 18 months




wastewater flow into the East Lagoon followed by six months wastewater flow




into the West Lagoon was used for comparing results during periods of waste-




water flow with those during periods of no wastewater flow.








BIOLOGICAL PARAMETERS






Benthos







     There were variations in bottom substrate types in the lagoons.  Sludge




accumulated appreciably only at E-l where about 20 cm of mainly paper pulp




and detritus accumulated on the medium-sandy type bottom.  The other sub-




strates varied from a' fine-sand at E-5, a hard-clay at E-8, a coarse-sand




at W-5, to a medium-sand at W-l and W-9.




     During this two year investigation, 360 benthos samples were collected




and analyzed.  The macroinvertebrate population was very limited.  This commu-




nity consisted of only a few organisms representing only a few taxonomic groups.




As shown in Figure 2, the benthos remained below 150 organisms per tenth square




meter throughout this investigation, and in 94.6% of the samples the population




was less than 100 organisms.  Thus the number of benthic organisms remained




quite low throughout this study, in sharp contrast to the more common values of




1,000 to 16,000 Chironomidae per tenth square meter in other wastewater lagoons




(Kimerle and Enns, 1968).




     Table 3 indicates the percentage composition of the major taxa in the




benthic population, as well as the number of samples per station.  The eight
                                    21

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                                               zz
*J
I
                Ul
                        UJ
                        o
*.
Ul
ORGANISMS PER  0.1 m


                     M
             O       Ul

Ln
(Ti
O
          \ \  \X  \\\  \\N
                                                O

                                                o
                                                        M
                                                                                      LO
                                                                                      o

-------
                 TABLE 3.   PERCENTAGE COMPOSITION OF BENTHIC POPULATION, MAJOR TAXA ONLY
T = TOTAL STUDY
                     KEY




WW = PERIOD OF WASTEWATER FLOW
NWW = PERIOD OF NO WASTEWATER FLOW
TAXA
No . of samples
T
ARTHROPODA, INSECTA WW
NWW
T
Diptera, Chironomidae WW
(larvae) NWW
T
a) Chironomus plumosus WW
NWW
T
b) Glyptotendipes spp. WW
NWW
T
1) G. barbipes WW
NWW
STATIONS
E-l
76
97.2
97.2
100
96.0
95.4
100
2.4
0.9
11.5
5.5
2.8
21.8
4.0
1.7
18.2
E-5
46
100
100
100
99.1
98.7
99.7
17.5
21.0
10.7
71.6
75.9
63.2
54.3
58.6
45.8
E-8
62
100
100
100
97.9
97.5
100
17.1
19.2
6.5
45.6
53.4
5.2
33.9
39.4
5.2
W-l
70
99.8
100
99.6
96.8
97.8
96.6
0.1
0.0
0.2
25.7
12.5
28.6
19.7
9.5
22.0
W-5
46
99.9
100
99.8
96.9
99.5
96.2
2.2
0.7
2.5
44.4
2.1
55.3
42.1
2.1
52.4
W-9
60
100
100
100
98.2
100
97.9
0.1
0.2
0.0
3.1
0.0
5.2
3.0
0.0
5.0
EAST,
TOTAL
184
99.2
99.0
100
97.9
97.4
99.9
12.2
12.9
9.9
40.5
40.7
39.7
30.4
30.6
29.7
WEST,
TOTAL
176
99.9
100
99.8
97.3
99.3
96.6
0.8
0.3
0.9
24.0
3.4
31.4
21.2
2.7
27.8

-------
TABLE 3 CONCLUDED

TAXA

T
2) G. lobiferus WW
NWW
T
c) Procladius culiciformis WW
NWW
	
STATIONS
E-l

1.5
1.1
3.6
85.0
90.7
63.8
E-5

17.3
17.3
17.4
5.5
1.2
15.0
E-8

11.7
14.0
0.0
27.2
18.2
74.2
W-l

6.0
3.0
6.6
69.0
83.9
64.5
W-5

2.3
0.0
2.9
50.0
95.3
38.4
W-9

0.1
0.0
0.2
92.8
99.8
88.4
EAST,
TOTAL
10.1
10.1
10.0
40.5
40.6
40.4
WEST,
TOTAL
2.8
0.7
3.6
70.7
94.9
62.0

-------
species of chironomids that were recovered accounted for virtually all, 98.6%,




of the benthos.  Of these eight species only four, Procladius culiciformis,




two species of Glyptotendipes,  and Chironomus plumosus, were common and they




accounted for 95.5% of the total macroinvertebrate population.  The non-biting




midges have been found to be the most common organisms of other wastewater




lagoons (Grodhaus, 1967; Kimerle and Enns, 1968; and Merritt, 1976) .   However,




the populations are usually not limited to chironomids and other forms are also





common.




     During the first year of this investigation, Glyptotendipes barbipes was




the dominant benthic form at all stations in the East Lagoon.  P. culiciformis




was sub-dominant at E-8, but rare at E-l and E-5.  C. plumosus was sub-dominant




at E-5, and common at E-l and E-8.  The predominant form during the second year




changed to P. culiciformis at E-l and E-8, while G. barbipes remained dominant




at E-5.  The change in dominance occurred at the start of the second year at




E-l, immediately after the depositional phase for midges, but not until three




months later at E-8.  Clear population shifts could not be discerned during the




last six months of this study when the wastewater flow to this lagoon was elimi-




nated .




     In the West Lagoon, the benthic community was dominated by P. culciformis




at W-l and W-9, while G. barbipes was dominant at W-5 and also common at W-l.




However, G_._ barbipes was the most prevalent form in the West Lagoon during the




first year.  C. plumosus was a rare form in this lagoon throughout the study.




At the start of the second year, the population shifted and P. culiciformis




became dominant while G. barbipes became only a common form.  With the onset




of wastewater discharge to this lagoon during the last six months of study, the




composition of the benthos had changed further.  The occurrence of P. culiciformis




increased, but G. barbipes became rare.  The variety of incidental forms was




greatly reduced.  The greatest change in the benthos occurred at the station




                                     25

-------
closest to the point of wastewater inflow, W-l, where the number of species




dropped from 11 prior to discharge to only 4 after discharge.  C. plumosus,




a species known for its ability to survive for a considerable length of time




under low dissolved oxygen concentrations, (Chernovskii, 1949) may become




more common in the West Lagoon as the sludges accumulate.




     A change in the composition of the benthic population, due to an alteration




of the wastewater flow, occurred for several reasons in the West Lagoon but not




in the East Lagoon.  The East Lagoon received the majority of the wastewater dur-




ing the first 16 months of this study.  The wastewater input was eliminated




only during the final six months of study, a period of time probably too short




for recovery.  Also, the depositional phase for the insects had passed when the




flow was shifted.  New forms in this system cannot appear until the next repro-




ductive cycle, but organisms can be eliminated almost immediately by the addition




of pollutants, as was the situation in the West Lagoon.




     The change in the dominant form for both lagoons from G. barbipes to P.




culiciformis may be due, in part, to the changes that occurred in the zooplankton




and phytoplankton, and the decay of the terrestial vegetation that was growing




in the lagoons prior to filling.  Immature glyptotendipeds are phytophagous




and probably fed on both aquatic plants and terrestial vegetation that had fallen




into or was growing in the basin.  The young larvae of P_._ culiciformis are mainly




carnivorous but also feed on some large diatoms (Chernovskii, 1949).  During the




second year appreciably more organisms from the zooplankton and zoobenthos were




captured in the benthos samples, especially Hyallela azteca and Daphnia spp.




In the zooplankton samples during the second year, rotifers were much more abun-




dant, notably Keratella and Brachionus.    The phytoplankton population declined




dramatically, with the exception of the large diatom Stephanodiscus niagarae




and a summer blue-green bloom.  These changes appear to favor £_._ culiciformis







                                    26

-------
 cit the expense of G.  barbipes.   Station E-5,  the only location where G. barbipes




 remained dominant during the second year,  had a very high density of terrestrial




 vegetation remaining  as compared with all  other stations.  The different dominant




 and common benthic forms at the stations may  also be attributed to the varying




 substrates and water  quality,  two factors  which play an important role in deter-




 mining the benthic population (Hynes, 1960).




      The type of midges found in the Muskegon storage reservoirs appear to be




 representative of a normal lagoon fauna.  In  a study of 18 Missouri lagoons




 (Kimerle and Enns, 1968) G. barbipes, C. plumosus, and Tanypus punctipennis




 comprised more than 94% of the  total number of insects collected in all lagoons.




 T.  punctipennis is in the same  sub-family,  Tanypodinae, as is  P. culiciformis.




      Based on Bureau  of Vector  Control records of larvae collected from 22




 localities, nine species of chironomids are considered to be common inhabitants




 of lagoons in California.  These species are  Procladius sp., Cricotopus sp.,




 G.  barbipes, two species of Tanypus, and four species of Chironomus (Grodhaus,




 1967) .




      Contrary to expectations,  the oligochaetes never became established.




 Limnodrilus was found on only two occasions,  both within the first four months




 of this two-year study.  No other oligochaetes were recovered.  The gastropods




 were represented only by Physa,  which was  found on two occasions.  Leeches,




 namely Helobdella stagnalis,  were noted in only one sample.  The only other




 organisms that were recovered from the lagoons were immature insects.   They




 were rare and included, in decreasing order of abundance, four other species




.of chironomids (Dicrotendipes modestus,  Tantarsus lobatifrons, Parachironomus




 sp.  and Cricotopus sp.); Trichoptera (Hydroptilidae, only in the West Lagoon,




 and 95% of them prior to wastewater discharge);  Ephemeroptera (Baetidae, only
                                      27

-------
in the West Lagoon prior to wastewater discharge) and Odonata (Coenagrionidae).




     Species diversity indices were calculated for each station, using the




monthly averages of the number of organisms in each species.  As recommended




by the United States Environmental Protection Agency (Weber, 1973) , the




Shannon-Weaver index was used to evaluate mean diversity  (d) and the Lloyd




and Ghelardi index, in which a broken stick model is used, was employed to




determine equitability  (e).  This index of diversity is based on information




theorgy and takes into account the number of species (i.e., richness of species)




as well as the numerical distribution of individuals among the species  (i.e.,




the relative importance of each species).  The indices are presented in Table




4.




     Organic pollution usually results in the depression  of diversity in the




biotic community, while relatively undisturbed environments have a higher




diversity index.  Aquatic ecosystems without environmental perturbations




usually support communities having large numbers of species without individual




species present in overwhelming abundance.  Thus, if all  individuals belonged




to the same species, the diversity would be minimal; whereas if each individual




belonged to a separate  species the diversity would be maximal.  Wilhm  (1970)




and Wilhm and Dorr is  (1968) report that values for  (d_) of less  than 1 are




usually obtained  in heavily polluted aquatic environments, values between  1




and 3 in areas of moderate pollution, and values above 3  in unpolluted  waters.




     At stations  E-l, E-5, W-l, and W-5,  (d) was much lower during the  period




of wastewater flow as compared with that during  the period of no  wastewater




flow.  At stations E-8  and W-9 the opposite was  true.  These stations,  however,




are farthest from the point of wastewater discharge in each lagoon.  The hardest




substrate was at  E-8  and  the  deepest  station was W-9, which was also the closest




station to  the  inflow of  the  interception ditch  water.  W-9 probably received
                                    28

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TABLE 4.  SPECIES DIVERSITY INDICES THE BENTHIC MACROINVERTEBRATE COMMUNITY
STATIONS
TIME PERIOD
TOTAL STUDY

NO
WASTEWATER
FLOW
WASTEWATER
FLOW
E-l
No. species
d
e
No. species
d
e
No. species
d
e
9
0.89
0.24
6
1.09
0.43
7
0.64
0.26
E-5
8
1.93
0.62
7
2.34
0.98
5
1.47
0.70
E-8
8
2.27
0.81
6
1.39
0.54
7
2.40
1.03
W-l
11
1.56
0.34
11
1.66
0.36
4
0.47
0.39
W-5
5
1.29
0.60
4
1.30
0.75
4
0.32
0.35
W-9
7
0.56
0.24
6
0.66
0.30
2
0.89
0.55

-------
organisms that normally live in the ditch.  These complicating factors must be




taken into account when interpreting the meaning of the indices.  In the East




Lagoon (d) increased as the distance from the point of discharge of wastewater




increased.  The low diversity indices in the West Lagoon, even prior to the




inflow of wastewater, reflect the severity of the natural environment within




this lagoon.




     Equitability is calculated by evaluating the component of diversity that




is due to the distribution of individuals within the species.  This index is




reported to be more sensitive than d, and in fact very sensitive to even slight




levels of degradation  (Weber, 1973).  Its range is normally from 0 to 1.




Organic wastes reduce equitability below 0.5 and generally in the range of 0.0




to 0.3.  Values between 0.6 and 0.8 are indicative of water not affected by




oxygen demanding wastes.  In the East Lagoon, equitability also increased as




the distance from the point of wastewater discharge increased.  This relation-




ship held during the period of wastewater flow as well as during no flow.  When




the wastewater flow ceased,  (e) increased at all stations in the East Lagoon.




The relationships are not so clear for the West Lagoon.  Equitability increased




rather than decreased at W-l and W-9 during the period of wastewater flow.




     It may not be appropriate in this study to calculate diversity and equit-




ability, to compare the results with those from historical work, and to compare




the results during periods of wastewater flow to those during periods of no flow.




The periods of flow and no flow were greatly unequal in  time.  Almost all reports




in which  (d_) and  (e_) were used have been in studies with over 100 individuals per




sample, in established lotic communities, and in communities receiving predomi-




nantly organic wastes.   These conditions were not met in this  investigation.




Industrial wastewater, especially paper mill waste, accounts for 60% of the




wastewater flow into the lagoons investigated.  These lagoons also represent a
                                     30

-------
 new  aquatic  habitat,  one which was  not present  just weeks prior  to this  investi-




 gation.   They were man-made  and covered with  terrestial vegetation prior to




 September 1973.  From the beginning,  the East Lagoon has been  a  very  heavily




 stressed  aquatic environment.  Colonization of  the  benthic  community  may take




 much longer, due in part to  the relatively long generation  time,  than for




 the  development of the planktonic community.






 Zooplankton







      A total of 392 zooplankton samples were  analyzed during this  investigation.




 Fourteen  species of free-living crustaceans and four species of  rotifers  were




 found to  compose the  known zooplankton community of  the Muskegon Wastewater




 Storage lagoons (Table 5).   Due to  their small  size,  a portion of  the  rotifers




 may  have  escaped capture and therefore they are included only in the quali-




 tative and not in the  quantitative  analysis.




      Although there was considerable fluctuation in  numbers, and various  taxa




 were  dominant throughout this investigation,  certain trends can be  noted.   The




 zooplankton population remained at  a minimum during  both winters of investigation,




 rose  during the spring and summer,  and peaked in late July to early August.  In




 the  lagoon receiving wastewater during the spring and summer, there was a more




 rapid decline in the population after the summer maxima than in the lagoon  not




 receiving the wastewater.  During periods of ice cover, the abundance of  zoo-




plankton  in the lagoon that received wastewater throughout both winters of  study




was less  than that of  the other lagoon.   This phenomenon was apparently caused




by the reduced DO levels during periods  of ice cover.




     Three species of Daphnia were routinely collected, D.  magna, D. galeata,




 and D. Pulex.  Large seasonal fluctuation were noted in this cladoceran  (Figure




3).
                                     31

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                                      TABLE 5.   PERCENTAGE COMPOSITION OF ZOOPLANKTON
                                                       KEY
                 WW = Period of wastewater flow
NWW = Period of no wastewater  flow
TAXA
No. of samples
WW
A. Copepoda, Cyclopoida NWW
WW
1. Cyclops NWW
WW
a. C. vernalis NWW
WW
b. C. sp. NWW
WW
c. C. excilis NWW

STATIONS
E-l
72
44.2
15.8
30.0
15.6
18.7
12.6
6.3
2.2
5.0
0.8
E-5
54
32.3
13.7
21.1
13.4
12.0
11.7
6.3
1.4
2.9
0.3
E-8
66
52.0
24.1
34.5
23.0
19.3
17.2
9.4
5.1
5.8
1.0
EAST,
TOTAL
192
41.0
18.1
27.3
17.7
16.0
14.0
7.0
3.0
4.3
0.7
W-l
74
52.3
19.6
45.9
10.4
31.9
5.1
11.0
4.4
3.0
0.9
W-5
54
49.5
15.3
44.3
9.1
32.1
5.2
9.1
3.4
3.1
0.5
W-9
72
55.8
11.2
41.5
7.5
35.2
2.5
4.2
3.1
2.0
1.9
WEST,
TOTAL
200
52.0
15.5
43.9
9.1
32.9
4.4
8.2
3.6
2.8
1.1
U)
K)

-------
          TABLE 5 CONCLUDED
TAXA
2. Mesocyclops WW
NWW
a. M. edax WW
NWW
b. M. sp. WW
NWW
c. M. dybowskii WW
NWW
B. Copepoda, Calanoida
1 . Diaptomus WW
(3 species) NWW
C. Cladocera WW
NWW
1 . Daphnia WW
(3 species) NWW
2. Bosmina WW
longirostris NWW
3 . Chydorus WW
sphaericus NWW

E-l
14.2
0.2
8.3
0.2
5.9
0.0
1.1
0.0

6.1
24.9
49.7
59.3
49.3
59.3
0.2
0.0
0.2
0.0
E-5
11.2
0.3
8.3
0.3
2.9
0.0
0.5
0.0

4.7
28.3
63.0
58.0
63.0
58.0
0.0
0.0
0.0
0.0
E-8
17.5
0.8
12.7
0.7
4.8
0.1
0.0
0.0

10.6
35.0
37.4
40.9
37.2
40.9
0.0
0.0
0.2
0.0
STATIONS
EAST,
TOTAL
13.7
0.4
9.3
0.4
4.4
0.0
0.6
0.0

6.5
29.6
52.5
52.3
51.3
52.3
0.1
0.0
1.1
0.0
W-l
6.4
9.2
6.1
6.3
0.3
2.9
0.0
0.0

33.4
27.4
14.2
53.1
14.1
43.3
0.0
0.0
0.1
9.8
W-5
5.2
6.2
5.2
3.9
0.0
2.3
0.0
0.0

35.4
25.3
15.1
59.4
15.1
51.4
0.0
0.4
0.0
7.6
W-9
14.5
3.7
14.3
3.6
0.2
0.1
0.0
0.0

32.3
23.9
11.9
64.9
11.8
60.0
0.0
0.0
0.0
4.9
WEST,
TOTAL
8.1
6.4
8.0
4.6
0.1
1.8
0.0
0.0

34.1
25.6
13.9
58.9
13.9
51.3
0.0
0.1
0.0
7.5
U)
u>

-------
                                                                               PERCENTAGE
(D

U)



D



f
H-
O)

O)
cn

CD
o
(D

ft-
0
Hi
ft
O
ft
(1)
N
0

•8
M
9)

W
ft
O
3
0)
ft
H-
O

-------
     In the West Lagoon the fluctuations in the numbers of Daphnia were much




less marked as the population remained below 100 Daphnia.   The general trends




in this lagoon, however, were quite similar to those in the East Lagoon.




     Daphnia  comprised 51% of the zooplankton in the East Lagoon during the




18 month period this lagoon received wastewater, and 52% during the period of




no wastewater flow.  The cessation of wastewater influent to this lagoon during




the last six months of study had little apparent effect on the Daphnia  assem-




blage.  The population change in the West Lagoon before and during wastewater




flow was somewhat different.  During the 18 month period of no wastewater in-




fluent to this lagoon Daphnia accounted for 51% of the zooplankton.  However,




with the onset of wastewater discharge into this lagoon, the abundance of this




cladoceran declined, comprising only 14% of the zooplankters during the remaining




six month period.  This may be due to the dramatic change in water quality with




the onset of wastewater discharge as compared to the slow recovery after the




cessation of wastewater inflow.




     The only other cladoceran commonly recovered was Chydorus sphaericus.




This cladoceran comprised 7.5% of the total zooplankton in the West Lagoon




during the period of no wastewater flow, but was virtually eliminated during




the period when wastewater was discharged into this lagoon.  The greatest abun-




dance of C. sphaericus was noted during August and September 1974 when about




20 per liter were recovered. This cladoceran never became a common form in the




East Lagoon.  Bosmina longirostris remained scarce in both lagoons throughout




this investigation.




     Cyclopoid copepods were more common during the period of wastewater flow




than during the period of no flow  (Figure 4).  in the East Lagoon during the




first 18 months of study, cyclopoids accounted for 41% of the zooplankton popu-




lation, but when the discharge of wastewater to this lagoon ceased, their abun-
                                      35

-------
                                                                PERCENTAGE
U)
en
                             I     I     I     I     I     I     I

-------
dance dropped to 18% of the population.  Similarly, cyclopoids comprised only




15% of the zooplankters during the period of no wastewater flow into the West




Lagoon.  They rapidly increased in number during the last six months of study




when wastewater was discharged into this lagoon and comprised 52% of the zoo-




plankton during this time.




     Cyclops vernalis remained the dominant cyclopoid throughout this study.




The abundance of this cyclopoid was also greater during periods of wastewater




flow than during no flow.  An abundance of over 50 C_. vernalis per liter was




common during the summer months.  Mesocyclops edax was a common cyclopoid,




followed in decreasing order of abundance by C_. sp., C_. excilis, and M. sp.




Mesocyclops dybowskii remained scarce.




     Cyclopoid copepods were most common from May through September during




both years of investigation.  The population quickly plunged after September,




remained at a minimum throughout both winters, and increased rapidly during




May.




     Diaptomus was the only common calanoid copepod noted during this study.




The seasonal population fluctuations of this copepod were very similar to the




cyclopoid fluctuations.  The abundance of Diaptomus increased greatly after




the elimination of wastewater flow into the East Lagoon in March 1975.  During




the summer of 1974, the Diaptomus population in the East Lagoon generally re-




mained below 10 per liter, but during the summer of 1975 an abundance of over




100 was frequently noted.  The abundance of this calanoid also increased in




the West Lagoon during the summer of 1975, although not as much as in the East




Lagoon.




     The shifts which occurred in the cyclopoid population upon alteration of




the direction of wastewater flow correspond well to the general trend for
                                     37

-------
 changing zooplankton composition as waters go from oligotrophic to eutrophic.




 The proportion of calanoids decreases  while the predominance of cyclopoids




 increases (Patalas,  1972) .





      Rotifers appeared  to  form only a  minor component of  the lagoon zooplankton.




 Because  rotifers  are largely sessile organisms  and are associated  with substrata




 (Wetzel,  1975), they are mostly littoral  inhabitants.   Rotifers are commonly




 found only  in waters of low organic content,  for they require an environment




 containing  several mg/1 of  DO.   In  these  respects,  the Muskegon lagoons do  not




 appear to offer a favorable environment.   However,  the diet  of  rotifers con-




 sists primarily of bacteria and small  algae,  and may  also include  small organic




 particles.  A rich food source  appears to exist in these  reservoirs for the




 rotifers.   Filinia longiseta was recovered only during the first few months of




 study.   Keratella quadrata,  Brachionus calyciflorus,  and  B_.  urceolares were




 rare  forms  during the first year but were more  common  during the second.  It has




 been  suggested that  certain algae,  such as some species of Chlorella,  may be




 inhibitory  to planktonic rotifers (Hutchinson,  1967).   Chlorella was a major




 component of  the  phytoplankton  throughout the first year  of  this investigation,




 but rapidly diminished  in numbers after that  time.




      K. quadrata  was common in most  of the collections from  December 1974




 through June  1975.  A slight increase  in  abundance was noted during the period




 of wastewater discharge to  this lagoon.   It was  surprising to note  K.  quadrata,




 a cold stenothermic form,  as a common  taxa  in June.





      It is apparent that at  times zooplankton,  as a result of direct cropping,




 can have  appreciable effects on phytoplankton populations.   Through selective graz-




 ing,  they can influence the  seasonal succession of the phytoplankton (Wetzel, 1975).




 There does not appear to be  any clear  relationship between the  zooplankton  and




phytoplankton populations  in the Muskegon  lagoons, however.   This could be  caused
                                     38

-------
partly by the methods used to enumerate the zooplankton and phytoplankton  since




numbers were determined and not biomass.  There are several other difficulties in




determining a relationship among the plankters.  There is a difference in  the di-




gestibility of the various algae, depending upon the thickness and other properties




of the cell wall.




     A major component of the zooplankton was composed of cyclopoid copepods.




The two genera present, Cyclops and Mesocyclops, are largely carnivorous forms.





The food of these carnivores in the Muskegon lagoons included microcrustaceans




and dipteran larvae, and therefore they had little direct effect upon the phyto-




plankton.  Although the collection of fine particles appeared to be a prevalant




mode of nutrition for the calanoid copepods, they also seize small animals, espec-




ially other zooplankton (Mullin, 1966).  In the Muskegon lagoons the filter-




feeding Daphnia probably consume the greatest quantities of algae, particularly




the unicellulars.  Daphnia are among the most efficient filter-feeders of the




zooplankton (Brooks, 1969), and show a preference for Chlorella vulgaris and




£. pyrenoidosa (Hutchinson, 1967).  If it is desirable to reduce the algal con-




tent of the lagoon effluent,  studies on the Daphnia assemblage should be continued.




     With the absence of predators by planktivorous fish,  the small planktonic




herbivores such as the rotifers and Bosmina will continue to be reduced competi-




tively in numbers by the larger more efficient food gathering zooplankton.  Thus,




it appears that Daphnia and Diaptomus will continue to be among the dominant zoo-




plankton of the Muskegon lagoons.   The blue-green algae inhibit either mechanically




or chemically the filtering rate of these zooplankton (Saunders,  1969).  Since the




dominant zooplankton do little grazing upon the Cyanophyta,  an increase in the




abundance of Daphnia and Diaptomus may give a competitive edge to the blue-green




algae over other algal forms.
                                     39

-------
Plankton







     A total of 541 samples were analyzed, identified, and enumerated dur-




ing this two year investigation.  Perhaps the most striking feature of these




data is the extreme variability of this assemblage, both with respect to




total abundance and to the distribution of particular entities (Figure 5) .




This variability is attributed to the diverse assemblage of organisms with




differing physiological requirements and variations in terms of limits of




tolerance to physical and chemical environmental parameters.







Plankton trends and dominants




     The percentage composition of this group is found in Table 6.  Although




the water quality differed greatly between the two lagoons because of the




discharge of wastewater into only one lagoon, the green algae clearly domi-




nated the plankton population of both lagoons during the first year of study.




It is interesting to note that the percentage of this population comprised of




green algae increased in the East Lagoon as the distance from the point of




wastewater discharge increased.




     Several Chlorophyta blooms were noted during the winter, spring, and




summer of 1974  (Figure 6).  After the August 1974 pulse, the green algae




population rapidly plummeted and remained reduced in number during the rest




of this study.  Smaller numbers of the three most abundant green algae, C_.




vulgaris, C. pyrenoidosa, and Chlamydomonas spp., account for most of this




reduction in the Chlorophyta population.  These species were frequently the




cominant forms during the first year of study, but were only common components




of the green algae during the second.  Their continued presence is important.
                                      40

-------
                                                          UNITS/ML X  102
c

(D

U1
O
Ml
0)

^
rt
O
3

H-
3

rt

(D
cn
X
(D
U3
o

-------
                       TABLE  6.   PERCENTAGE COMPOSITION PLANKTON




                                      KEY





WW = Period of wastewater flow             NWW = Period  of  no  wastewater flow
TAXA
No. of samples
A. Chlorophyta, Chlorophceae WW
NWW
B. Cyanophyta, Myxophyceae WW
NWW
C. Chrysophyta, WW
Bacillariophyceae NWW
1 . Pennate WW
NWW
2. Centric WW
NWW
D. Euglenophyta, WW
Euglenophyceae NWW
STATIONS
E-l
103
38.5%
5.3
4.7
17.3
21.1
2.3
0.4
0.2
20.7
2.1
6.5
1.5
E-5
70
46.5?
14.4
6.2
19.7
27.0
9.3
0.8
0.2
26.2
9.1
5.4
4.7
E-8
98
66.8%
11.4
2.9
15.6
10.3
5.7
0.6
1.2
9.7
4.5
2.3
2.5
EAST,
TOTAL
271
53.4%
8.4
4.2
17.3
17.0
4.4
0.6
0.5
16.4
3.9
4.3
2.3
W-l
100
11.9%
82.2
7.9
j 11.1
i
16.2
3.1
6.5
0.8
9.7
2.3
10.8
0.6
W-5
70
10.0%
41.3
7.0
34.7
19.1
7.2
7.0
1.4
12.1
5.8
4.8
2.7
W-9
100
14.9%
68.0
5.8
18.5
23.2
6.1
13.6
1.4
9.6
4.7
5.3
2.3
WEST,
TOTAL
270
12.5%
72.3
6.9
16.6
19.6
4.4
9.3
1.0
10.3
3.4
7.1
1.4

-------
TABLE 6 CONCLUDED
TAXA
E. Ciliophora WW
NWW
F. Mastigophora WW
NWW
STATIONS
E-l
9.5
0.3
20.4
73.1
E-5
2.8
1.5
12.2
50.3
E-8
3.7
1.3
13.9
63.4
EAST,
TOTAL
5.4
0.8
15.7
66.8
W-l
27.2
0.9
26.0
2.1
W-5
11.7
0.9
47.3
13.2

W-9
6.3
1.3
43.8
4.0

WEST,
TOTAL
15.2
1.0
38.6
4.3

-------
o
2:
w
w
                   JFMAMJJASOND

                                 1974
    FLOW:
    Figure 6  Chlorophyta as a percentage of the total plankton population
                                    44

-------
since they are significant in maintaining a desired free oxygen level in the




lagoons, especially during periods of ice cover when the numbers of other




oxygen producers are greatly reduced.  It appears that C. vulgaris, C. pyrenoi-




dosa, and Chlamydomonas spp. will remain common forms in the Muskegon lagoons




in the future.  These algae have been among the first genera to have become




established in other lagoons worldwide, and they have remained typical com-




ponents of the Chlorophyta throughout the year  (Davis, 1964; Davis, et al,




1964; Gloyna, 1971; Jayangoudar and Ganapati, 1964; Potten, 1972; Raschke,




1968, Silva and Papenfuss, 1953).




     The above authors also cite Ankistrodesmus and Scenedesmus as common lagoon




phytoplankton.  In the Muskegon lagoons, these genera together with Golenkina




and Pediastrum were common green algae during the summer months.




     The Cyanophyta were more abundant during periods without wastewater dis-




charge than during periods of wastewater flow.  During the  first 18 months




of study, when wastewater was discharged into the East Lagoon, the blue-greens




accounted for 4.2% of the population in the East Lagoon and 16.6% in the West




Lagoon.  During the next six months, when wastewater was discharged into the




West Lagoon, the blue-greens comprised 17.3% of the protistan population in




the East Lagoon and 6.9% in the West Lagoon.




     O. rubescens was the dominant blue-green in late spring, followed by




Anabaena spp. in early summer.  A.(Microcystis) aeruginosa  and A. flos-aguae




bloomed in late summer.  Although not numerically dominant, A^  (Chroococcus)




dispersus and A_._  (Chroococcus) minor were common cyanophytes throughout the




year.




     Greater numbers of diatoms, euglenophytes, and ciliophores were noted




during periods of wastewater flow than during those periods without.  The




only diatom noted by Gloyna  (1971) as being  typical of the  lagoon biota was
                                     45

-------
 Nitzschia.   N.  palea  is  also  the  only diatom included  in  a  list  of  over  200




 organisms common  in trickling filters (Cooke,  1967).   The four dominant  centric




 diatoms  in  the  Muskegon  lagoons are  all  common representatives of the  diatom




 population  in eutrophic  waters  (Hutchinson,  1967; Schelske  and Roth, 1973).




      Euglenophytes were  noted in  greatest abundance during  the summer  months,




 decreased during  the  fall, remained  at or near zero during  ice cover,  and  in-




 creased  in  numbers during the spring.  Trachelomonas,  Euglena, and  Phacus




 were  the principal euglenoids in  the  Muskegon  lagoons.  The latter  two genera




 are common  dominants  of  the Euglenophyta in  other lagoons (Davis, et al,




 1964; Gloyna, 1971) whereas all three  genera are common in  polluted waters




 rich  in nitrogenous organic compounds  (Hutchinson, 1967).




      During the winter months, the ciliophore  population was at  or  near  zero




 in the lagoon not receiving wastewater but was  near the summer maximum in  the




 lagoon that was receiving wastewater.  Cyclidium, Glaucoma, and Vorticella




 were  dominant.  The latter genus  is often the dominant protozoan present in




 secondary wastewater  effluent (Yarma, et al, 1975), and all three genera are




 common Ciliophora in  trickling filters (Cooke,  1967).   These three  genera can




 grow well in greatly  reduced  oxygen or anaerobic conditions (Wetzel, 1975).




 This microaerophillic ability allows for their development  in the organic-rich




 and polluted lagoons,  even during periods of ice cover when free oxygen was




 almost lacking.




     The ciliophores of the Muskegon lagoons apparently feed mainly on algae




and supplement this nutrition by feeding on bacteria and particulate detritus.




Due to their small size and limited numbers, however,  the ciliophores are not




expected to have appreciable effects on the algal population in the Muskegon




lagoons.
                                    46

-------
     The abundance of mastigophores was not noted to be related to the




direction of wastewater flow, but rather greater numbers were present in




both lagoons during the spring and summer of 1975 (Figure 7).  Bodo, Chilo-




monas,  Trimastigamoeba, Chroomonas, and Cryptomonas were the common micro-




flagellates.  Several monad blooms were noted in the East Lagoon during the




last six months of study while Trimastigamoeba and Bodo remained common in




the West Lagoon.







Implications of lagoon plankton —




     The plankton remove a good portion of the various nutrients and trace




elements from the lagoons by incorporating them into protoplasm.  Research




of many workers has shown that these organisms can accumulate more of these




substances than they need for growth (Patrick, 1969).  This luxury consumption




results in this group exerting a significant effect on the improvement of




water quality in the lagoons.  However, the use of a biological-lagoon system




alone can not be expected to be a dependable method of water pollution control




at this time.  It appears that this community will remain rather unstable and




will experience population pulses and crashes, as well as seasonal changes.




These large fluctuations hinder the system's manageability.  Other difficulties




also exist.  Upon death, the protistan cells sink to the bottom, retaining




nutrients and trace elements within the water body.   Harvesting of the con-




centrated components, in the form of live or dead protistan cells, is not yet




feasible.  The food web in the Muskegon lagoons is not complex enough to




control the periodic protistan blooms.







Chlorophyll a_







     In aquatic plants, as in terrestial plants,  chlorophyll is the initiator
                                     47

-------
                                                                                       PERCENTAGE
03
              H-

              c

              CD

              ~J
              cn
              rt
              O
             K
              3*
              O
              cn

              &)
O
fD
3
rt
              rt

              n>

              rt
              O
              rt
              rt
              0
              3
              rt
              H-
              O
              3
                                                                                           CD
                                                                                           O
                                                                                                            t-0
                                                                                                            O
OJ
O
in
O
                                                                                                                                                             O
CO
O
                                                                                                H
                                                                                                cn

-------
in a series of physical-chemical changes which are responsible for the cul-




mination of the flora and fauna.  Due to chlorophyll's importance in photo-




synthesis, chlorophyll measurements may be used as indirect indices of po-




tential productivity  (Prescott, 1962; Odum, 1971).  Since the amount of




chlorophyll increases in bodies of water as the water becomes more eutrophic,




chlorophyll measurements may also provide comparative data on eutrophication




 (Mackenthun, 1973).  Chlorophyll a_ is the most abundant and important pig-




ment in algae  (Vollenweider, 1974) and hence was measured.




     A total of 574 chlorophyll a_ samples were analyzed during this investi-




gation.  As indicated in Figure  8,  there was a great deal of variability in




the quantity of chlorophyll £ present in the Muskegon lagoons.  Although a




few of the chlorophyll a_ peaks occurred during algal blooms, in general a clear




relationship between  the two parameters was not evident.




     During the winter of 1973-1974  a major peak occurred in the  level of




 chlorophyll a  in  the  West Lagoon but not in the East Lagoon.  On  13 February




1974, 43 mg/m3 of this pigment were  present at W-l, and 58 mg/m3  at W-9.  On




this date the  algal population was approximately 9,400 units/ml at  W-l but  only




4,400 at W-9.  By 27  February  1974 the  level of chlorophyll a_ increased to  56




at W-l and decreased  sharply to 9.7  at  W-9, yet the number of phytoplankton re-




mained fairly  constant at W-l  and increased sharply to over 11,000  at W-9.




Since the environmental conditions did  not fluctuate greatly during this  two




week period and because the same  species,  C. vulgaris, was dominant, it appears




 that the viability of the algal cells varied during this  period.  Due to  this




 large variation in a short  period of time, the use of  chlorophyll measure-




 ments  as  indices  of  productivity,  biomass  and/or eutrophy should be cautioned,





 at least  in the Muskegon lagoons.
                                      49

-------
o
s
                       • E-l, W-l
                                                      I   »   I   I   I   I  »
         0   N  D
          1973
JFMAMJJASOND
              1974
JPMAMJJA
      1975
                                           O    EAST
    6   —
    3   ~
   FLOW:
   Figure 8  Quantity of chlorophyll a. in the Muskegon Lagoons
                                  50

-------
     No peak in chlorophyll a. was noted in the East Lagoon during ice cover




in 1974, although a green algae pulse did occur.  During August 1974, a diatom




and green algae bloom in the East Lagoon and a blue-green algae bloom in the




West Lagoon were reflected in chlorophyll a_ pulses.  The concentration of




chlorophyll a_ again peaked in both lagoons during August of the following year,




although no phytoplankton bloom was noted at this time.




     The levels of chlorophyll a_ are not exceedingly high compared to natural




waters.  Caution must be exercised, however, in making comparisons since the




quantity of chlorophyll per unit of algae present is influenced by various




environmental, nutritional, and internal factors as well as the species and




age or viability of the algal cells present  (Vollenweider, 1974; Weber, 1973) .







Primary productivity






     The basic aim of these measurements was to provide an estimate of the




quantity of organic matter which was produced from inorganic substances within




the lagoons.  It is assumed that during  photosynthesis one molecule of oxygen




is released for each atom of carbon assimilated  (American Public Health As-




sociation, et al, 1976).  These measurements, therefore, also provided infor-




mation concerning the rate of oxygen production, an important consideration  in




the heavily stressed lagoon environment.




     As shown in Figure  9 , there was  a great deal of variability in the primary




productivity in the Muskegon lagoons,  and,  as was  the case with chlorophyll  a_




and the plankton population, there was little similarity from one year to the




next, with greater values occurring in 1974  than in 1975.  During 1974 the rates




of carbon fixation ranged from lows of less  than 1 mg C/m /hr during spring  in




both lagoons to highs in August of 137 in the East Lagoon and 126 in the West




Lagoon.  The maxima occurred concurrently with  the summer 1975 highs for chloro-







                                     51

-------
 45

Figure 9  Primary productivity in the Muskegon Lagoons
                               52

-------
phyll a_ levels or number of phytoplankton.








PHYSICAL AND CHEMICAL PARAMETERS






Dissolved oxygen







     Only minor differences in DO concentrations were noted with depth.  This




homogeneous distribution with depth was apparent in most of the physical and




chemical parameters investigated, and indicates a lack of stratification in




the Muskegon lagoons.  The shallowness of the lagoons, combined with wind action,




aided in keeping the waters vertically mixed.




     Dissolved oxygen is one of the more indicative and affected parameters




of biological interactions in aquatic systems.  The DO levels in the lagoon




receiving wastewater consistently remained lower than those levels in the other




lagoon, with the exception of several weeks following the change in direction




of wastewater flow in March 1975  (Table 7).  During the first few months of




investigation the DO levels at E-l, the station nearest to the point of waste-




water discharge in the East Lagoon, were much lower than at E-8.  During the




same time period, 6005 and ammonia nitrogen were much higher at E-l than at




E-8.  By February, these large differences between stations had decreased and




the DO had dropped at E-8.  The distribution of DO remained more uniform




between stations in most subsequent samples.




     During the first 18 months of study, free oxygen was never abundant in




the East Lagoon.  Peak values were noted only in October and November 1974




when the wastewater was used directly as irrigation-water rather than being




discharged into the lagoon.  At this time DO values of 7 mg/1 were common,




whereas during the other 16 months of wastewater flow, 4 mg DO/1 and less




were frequent in the East Lagoon.  There were three periods of especially low




DO in this lagoon, during ice cover of 1974 and 1975 and during the summer of






                                     53

-------
     TABLE 7.  COMPARISON OF TEMPERATURE, DISSOLVED OXYGEN, AND BIOCHEMICAL OXYGEN DEMAND IN THE
         MUSKEGON LAGOONS.  DATA ARE PRESENTED AS THE MONTHLY MEAN +_ ONE  STANDARD  DEVIATION.


                                                KEY

TEMP = Temperature,  °C = Dissolved Oxygen,  mg/1  BOD = Five Day Biochemical Oxygen  Demand,  mg/1
  DATE
LAGOON

10-73
11
12
1-74
2
3
4
5
6
7

TEMP
10.3 + 0.3
8.7 + 0.8
0.8 + 0.3
1.6 + 1.0
1.9 + 0.5
3.4 + 0.6
10.5 + 2.4
15.8 + 2.4
10.8 + 0.0
25.6 + 1.9
EAST
DO
3.1 +_ 1.9
6.7 + 4.0
3.7 + 2.5
2.3 + 2.3
0.2 +_ 0.1
5.1 + 0.6
2.8 +_ 0.7
2.1 + 0.2
2.1 + 1.0
0.0 + 0.1
BOD5
14.7 + 13.3
23.7 + 23.0
34.5 + 27.5
13.1 +_ 5.9
16.9 + 3.4
16.7 + 1.4
12.2 + 7.3
12.5 + 3.3
31.3 +_ 3.4
17.4 + 4.7
WEST
TEMP
10.0 + 0.0
8.6 +_ 0.9
0.5 + 0.0
0.5 + 0.7
0.8 + 0.3
2.3 + 1.1
9.3 + 4.7
13.5 + 3.5
23.3 + 0.7
25.6 + 0.2
DO
8.4 + 0.2
11.3 + 0.7
11.3 + 0.1
12.2 + 0.7
11.5 + 0.3
13.7 + 0.9
9.4 + 0.3
7.7 + 0.5
5.4 +_ 0.2
6.4 + 0.3
BOD5
3.7 + 2.5
2.2 + 0.3
6.5 + 0.7
7.0 + 0.0
6.5 + 3.1
4.9 + 0.5
5.8 + 1.4
3.2 + 0.1
7.3 +_ 1.2
3.6 + 0.9

-------
TABLE 7 CONCLUDED
    DATE
LAGOON

8-74
9
10
11
12
1-75
2
3
4
5
6
7
8
EAST
TEMP
24.9 + 0.1
16.5 + 4.2
12.0 + 0.0
8.0 + 2.8
3.0 + 2.8
1.3 + 1.8
2.3 + 0.3
1.7 + 1.4
11.2 + 0.8
20.0 + 4.7
21.3 + 2.3
28.3 + 1.7
23.0 + 2.8
DO
2.0 +_ 1.6
2.5 + 1.5
7.4 + 0.4
7.6 + 0.7
4.8 + 0.4
6.1 + 2.5
0.4 + 0.1
0.6 +_ 0.1
6.3 + 0.4
2.5 + 0.4
4.0 +_ 0.1
5.4 + 0.2
6.1 + 0.7
BOD 5
13.5 + 5.1
4.1 + 1.0
5.6 + 2.3
5.1 + 1.5
21.3 + 8.9
17.7 +_ 8.4
16.7 + 5.9
17.7 + 0.4
8.1 + 0.3
20.0 + 1.0
8.1 + 3.0
3.8 +_ 0.5
3.7 + 1.0
WEST
TEMP
23.1 + 0.2
17.0 + 3.5
9.0 + 0.0
7.5 + 2.1
0.6 + 0.5
0.6 + 0.9
0.9 + 0.5
1.5 + 0.3
10.2 + 3.5
19.9 + 6.0
22.6 + 2.2
27.3 + 1.0
23.5 + 3.5
DO
9.1 + 0.3
8.0 + 0.3
10.6 -f 0.2
10.9 + 0.2
11.7 + 0.3
12.3 + 0.1
9.1 + 2.5
4.1 + 2.6
5.0 + 0.8
1.0 +_ 0.1
1.2 + 0.6
1.0 + 0.4
0.7 + 0.1
BOD5
3.0 + 0.4
3.4 + 0.3
2.3 + 0.2
4.6 + 3.0
4.3 + 1.2
5.3 +_ 0.3
2.6 + 0.1
10.2 + 6.6
16.2 +_ 7.7
10.9 + 6.7
8.8 + 5.6
10.9 + 1.3
15.4 + 4.5

-------
 1974.  During these periods less than 1 mg DO/1 was frequently noted, especially




 at E-l.  After the cessation of wastewater flow to this lagoon in March 1975,




 the DO levels slowly increased and a summer minimum did not occur in the East




 Lagoon in 1975.





      The oxygen demanding wastes in the heavily stressed East Lagoon environ-




 ment masked any DO pulses that may have occurred due to phytoplankton blooms.




 Such was not the case in the West Lagoon that did not receive significant




 amounts of wastewater until March 1975.   A green algal bloom in this lagoon




 during ice cover in 1974 kept the DO levels at or near saturation during this




 period.   A decline in DO was noted as the water temperature rose and the




 phytoplankton population decreased greatly during the  spring.   A minimum of




 5.5  mg DO/1 was reached in June,  coinciding with the smallest phytoplankton




 population in the  West Lagoon during this study.   The  DO levels increased




 to over  9 during the  blue-green  algal bloom in August,  and  remained  near




 saturation until March 1975.   The DO levels in the West Lagoon quickly plum-




 meted  when wastewater flowed  into this lagoon,  and from May through  August




 1975 remained close to 1.





     Although periods of  low  DO were  noted  in  the  Muskegon  lagoons,  on the




 whole  they  remained aerobic.   It  appears  that  this situation will continue




 and possibly  the DO minima will become less severe as the phytoplankton  as-




 semblage becomes better acclimatized  to this wastewater  lagoon  environment




 and become more diverse.







 Biochemical oxygen demand  (6005)







     Because of the high amount of organic matter in wastewater, the BOD5




was consistently greater in the lagoon receiving wastewater than in the other





 lagoon (Table 7).  Similar to the situation for DO, there were large differences
                                     56

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in the BOD5 at E-l, 5, and 8 during the first several months of this study.




By February, however, the wastewater constituents had obtained a more homo-




geneous distribution within this lagoon and smaller differences in BOD5 from




station to station were noted.




     Large variations in BOD5 through time were apparent, especially in the




East Lagoon.  The levels at E-l initially increased to a high of 54 mg/1 by




December 1973, but then quickly plummeted to 17 early in January.  BOD5 re-




mained near this level for the next four months throughout the East Lagoon be-




fore increasing to over 30 mg/1 in June 1974.  6005 then decreased to its




pre-June level for the next two months before reaching a minimum of 4.1 mg/1




in September.  At this time the direction of wastewater flow was directly to




irrigation.  From December through March BOD5 remained near 20 mg/1 and con-




tinued to fluctuate while on a general downward trend after the flow of waste-




water to this lagoon ceased in March.




     The fluctuations of BODs in the West Lagoon were not nearly as large and




therefore a mean is more meaningful.  During the 18 month period without waste-




water flow to this lagoon, the mean was 4.48 mg/1 +_ 1.68.  However, the BOD5




quickly increased when wastewater was discharged into the West Lagoon for the




next six months.  The mean BODs during this period was 12.1 mg/1 +3.0.  BOD5




was highest at W-l compared to W-5 and 8 because of this station's proximity to




the point of discharge.







Temperature






     Water temperature followed air temperature in a normal manner, with little




response to transient climatological phenomena  (Table 7).  Thermal stratification




was not evident which indicated vertical mixing.




     Generally, temperatures were slightly greater in the lagoon receiving waste-
                                      57

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 water.  This relationship was most evident at the station nearest the point




 of wastewater discharge.  Heat budgets are complex and even just one phase of




 this budget, the absorption of solar energy by the lagoon water, is influenced




 by an array of physical, chemical, and,  under certain conditions, biotic proper-




 ties of the water.   However,  it appears  that a combination of three factors,




 each taking on different importance during the year,  account for the difference




 in temperature between the lagoons.  The higher content of dissolved organic




 matter in the lagoon receiving wastewater increases the absorption of light




 energy.   During cooler weather the temperature of the incoming wastewater was




 above ambient.   Greater biological, especially microbial,  activity occurred in




 the lagoon receiving wastewater.





      Of greatest significance  to  the water quality and biological productivity




 of  the lagoons  is the fact that the water temperature maintained levels  in the




 20-24° C  range  over  essentially a four month  period each year.






 Secchi disk transparency







      The  transparency in the East Lagoon  during  the period of wastewater  flow




was  small  and consistently remained much  less  than  in the West  Lagoon  (Table  8).




During this  time  period, the mean in  the  East  Lagoon,  17.0 cm,  was only 14.5%




of the mean  in  the West  Lagoon, 117.5 cm.  The lowest values were at E-l  on all




but  one occasion, 9 August  1974.  On  this date the  exit  to the  outlet lagoon




 (Figure 1) was open and  it  appears, from  these and  from  other chemical data,




that the incoming wastewater was  not mixing completely with the lagoon waste-




water but rather was short-circuiting directly to the outlet.




     After the flow of wastewater was shifted to the West Lagoon in March  1975,




the transparency slowly increased in the  East Lagoon but rapidly plummeted in




the West,  especially at W-l.
                                     58

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       TABLE 8.  COMPARISON OF TURBIDITY, SECCHI DISK TRANSPARENCY, pH, CONDUCTIVITY AND TOG IN
              THE MUSKEGON LAGOONS.   DATA ARE GIVEN AS THE MEAN + ONE STANDARD DEVIATION.
       WW = Period of wastewater flow
                                                 KEY
NWW = Period of no wastewater flow
PARAMETER
   STATIONS
Turbidity WW
NWW
Secchi Disk WW
Transparency, cm NWW
pH WW
NWW
Conductivity, WW
micro-mho NWW
TOC, mg/1 WW
NWW
E-l
17.3 + 8.7
7.5 + 2.0
14.4 + 5.4
27.3 + 16.2
7.69 + 0.18
7.84 + 0.32
1030 + 225
1030 + 85
40.0 + 13.3
54.8 + 23.4
E-5
10.6 + 7.0
6.4 + 0.9
21.9 + 5.1
31.0 + 10.0
7.76 + 0.13
7.86 + 0.23
1170 + 215
1020 + 91
35.6 + 13.3
44.4 + 18.9
E-8
12.0 + 7.1
6.7 +_ 1.1
21.7 + 5.1
31.2 + 17.9
7.77 + 0.20
7.87 + 0.30
1010 + 214
1020 + 94
33.9 + 8.4
49.2 + 17.9
W-l
21.7 + 2.9
3.1 + 1.0
22.6 + 8.0
112.6 + 32.9
7.61 + 1.40
8.13 +0.27
949 + 117
776 +_ 171
73.0 + 43.2
21.2 + 4.5
W-5
6.9 + 1.1
3.1 + 1.0
24.6 + 8.0
121.5 + 41.6
7.68 + 0.90
8.24 + 0.38
954 + 108
876 + 129
56.4 + 49.1
20.9 + 4.5
W-9
6.8 + 2.0
3.1 + 0.9
41.3 + 21.0
119.3 + 36.0
7.68 + 0.08
8.18 + 0.29
907 + 137
754 + 157
64.2 + 42.8
21.3 + 8.3

-------
      No seasonal trends were evident and the plankton pulses did not appear




 to reduce transparency.




      The limited transparency,  and hence the rapid  vertical  extinction of




 light in the lagoon receiving wastewater,  has several implications.   The very




 narrow photic zone limits  oxygen  production  and  productivity,  at least auto-




 trophic productivity.   It  gives a competitive advantage  to heterotrophic and




 mixautrophic organisms  over  the obligate photoautotrphs.  Most phytoplankton




 fall  into the latter category.  The limited  transparency  excludes rooted




 aquatics,  plants that could  be  managed  and harvested  more easily than the




 algae.   It also  excludes benthic  algae  and periphyton and is one of  several




 factors keeping  the lagoon food web or  chain relatively short  and unstable.






 Turbidity







      Turbidity was  consistently greater  in the lagoon receiving  wastewater




 than  in the other  lagoon (Table 8).  Values  were similar  at  each depth and




 among stations in  the same lagoon,  with  the  exception of  higher  turbidity at




 stations  E-l and W-l.   Fluctuations were noted, however,  through time.   During




 the periods  of wastewater  discharge, the range at E-l was from 4.2 to 34  FTU




 and from  3.7  to  22  FTU  at  E-5 and 8, whereas  the range at W-l  was  from 14 to




 34 and  4.0  to  10 at W-5  and  9.  During the periods without wastewater  dis-




 charge, the mean in the  West Lagoon was  3.1 FTU ^0.9  and 6.9  FTU +  1.2  in  the




 East  Lagoon.





      Since  turbidity and transparency did not correspond with  the fluctuating




 plankton population and  because the lowest transparency and highest  turbidity




 was at W-l  and E-l during wastewater flow, it appears  that suspended particulate




matter  such as clay, silt and finely divided organic and inorganic detritus,




rather than aquatic organisms, exert the greater influence upon these parameters.
                                     60

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Conductivity







     The specific conductance of both lagoons was quite high and remained




greater in the East Lagoon than in the West Lagoon, even during the final




six months of study when wastewater was discharged only into the latter




lagoon (Table 8).  The mean conductance during the first 18 months of study




was 1020 micro-mhos +_ 217 in the East Lagoon and 768 + 156 in the West Lagoon,




The mean in the West Lagoon increased to 925 +_ 128, but remained at 1020 +




86.7 in the East Lagoon during the final six months of study.  As evidenced




by the large standard deviation, a wide range of conductance was recorded




through time.  The lowest values in both lagoons, 800 micro-mhos in the




East and 549 in the West, occurred in March 1974.  A high was reached in




the East Lagoon during September 1974, 1,480 micro-mhos, and in the West




Lagoon during July, 1,037.







pH







     The lagoon receiving wastewater was slightly less alkaline than the




lagoon not receiving wastewater (Table 8).  Only very minor variations




occurred among stations and depths within each lagoon.  Little variation




was noted through time, other than when the flow of wastewater was altered.




Periods of high photosynthetic activity usually elevate the pH in natural




bodies of water due to photosynthetic removal of CC>2-  This phenomenon was




not experienced in the Muskegon Lagoons, indicating a good buffering capa-




city in these waters.  Due to the abundance of bicarbonate and calcium, it




is unlikely that the pH will change greatly in the future.







Total organic carbon (TOG)







     TOC levels were generally greater in the lagoon receiving watewater than




                                      61

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 in the lagoon not receiving wastewater (Table 8),   During the first 18 months




 of study the mean TOG was 37.36 mg/1 + 10.25 in the East Lagoon and 20.75 + 7.80




 in the West.  During the last six months of study the mean increased to 64.16 +




 41.23 in the West and to 51.98 + 21.30 in the East Lagoon.  Large fluctuations




 in TOC occurred throughout this investigation, with monthly means ranged from 24




 to 82 in the East Lagoon and from 11 to 133 mg/1 in the West Lagoon.  The pulses




 did not correspond with any plankton pulses and apparently are due to bacteria,




 detritus,  and the re-suspension of sediments.







 Ammonia nitrogen







      High  levels of ammonia nitrogen are  present in domestic and industrial




 wastewater,  and the level of this parameter was generally much higher in the




 lagoon receiving wastewater than in the lagoon lacking this  input (Table 9).




 In the West  Lagoon during the first 18  months  of study the concentration of




 ammonia nitrogen consistently remained  less than 0.4 mg/1 and was often below




 0.1.   The mean  concentration during this  period was 0.15  mg  NH4  - N/l + 0.12  in




 the West Lagoon and 3.1  + 1.7 in the East Lagoon.




      In the  East Lagoon  from January through June  1974 there was a general




 increase in  the amount of ammonia nitrogen  from a  low of  1.0 mg/1 to a high




 of 5.6.  During August and October  the  wastewater  flow pattern was altered




 for short periods  of time and the levels  of ammonia nitrogen plummeted to less




 than  0.6 mg/1.   From the  flow of  surface  foam  and  from the color pattern that




 developed when  the gate to  the outlet cell  was  opened,  it appeared that the in-




 coming wastewater was short-circuiting  and  flowing  out of the  East Lagoon before




 appreciable mixing with the  lagoon water  occurred.   There was  also a  short period




when wastewater was used  directly for irrigation and did not  flow into  the lagoons.




Ammonia nitrogen was the  only parameter related to a great extent  to  these tempor-







                                      62

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        TABLE 9.  COMPARISON OF NUTRIENT AND ANION LEVELS IN THE MUSKEGON LAGOONS
                    DATA ARE GIVEN AS THE (mg/1) +_ ONE STANDARD DEVIATION.

                                          KEY
WW = Period of wastewater flow
NWW = Period of no wastewater flow
PARAMETER
Ammonia nitrogen, WW
NH4 - N NWW
Nitrate nitrogen, WW
NO3 - N NWW
Or thophosphate, WW
P NWW
Sulfate, WW
SO4 NWW
Chloride, WW
CL NWW
STATIONS
E-l
3.39 + 1.97
2.76 + 2.76
1.04 + 0.85
2.38 + 2.08
1.48 + 0.33
1.54 + 0.35
97 + 12
99 +_ 7
166 + 16
168 +_ 24
E-5
2.55 + 2.16
2.02 + 2.63
1.70 + 0.99
2.83 + 1.79
1.51 + 0.37
1.43 + 0.28
89 + 8
92 + 9
162 + 9
160 + 23
E-8
2.62 + 1.87
2.50 + 2.84
1.31 + 0.96
2.35 + 1.86
1.39 + 0.43
1.52 + 0.32
97 + 12
95 + 6
163 + 15
166 + 24
W-l
4.32 + 1.91
0.15 + 0.12
0.76 + 1.17
0.52 + 0.35
1.24 + 0.50
0.13 + 0.11
79 + 8
74 + 11
140 + 23
105 + 18
W-5
4.56 + 1.91
0.13 +_ 0.13
0.93 + 1.25
0.58 + 0.41
1.25 + 0.33
0.16 +_ 0.10
76 + 9
68 + 9
139 + 22
109 + 10
W-9
3.87 + 2.42
0.15 + 0.13
0.93 + 1.35
0.47 + 0.33
1.14 + 0.65
0.11 + 0.10
76 + 9
75 + 11
131 + 23
106 + 12

-------
 ary changes  in  flow patterns.   This probably  resulted  from  the  rapid  oxidation




 of  this  parameter  to  nitrite and  then  to  nitrate  nitrogen,  or its  release  to




 the atmosphere  as  ammonia gas.  Therefore a continual  influx was required  in




 order  to ma-.ntain  the high  levels of ammonia  nitrogen  that  were present.   With-




 out constant replenishment, the concentration of  this  form  of nitrogen declined.




 Most of  the  other  physical-chemical parameters do not  change form  so  rapidly  and




 thus their levels  did not fluctuate as quickly.  During the last six  months of




 study  when wastewater was discharged only to  the West  Lagoon, the  ammonia  nitro-




 gen levels decreased  to a minimum of 0.3  mg/1 in the East Lagoon and  rose  to  a




 maximum  of 6 mg/1  in  the West Lagoon,







 Nitrate  nitrogen







     The levels of  nitrate nitrogen fluctuated greatly with time (Table 9)„




 In  the East Lagoon  the range of monthly means was from 0.05 to  2.94 mg NO3 _  N/i





 during the six month  period without such  flow.  In the West Lagoon, the range




 was  from 0.15 to 1.47 during the 18 month period without wastewater flow and




 from 0.09 to 3.60 during the six month period with such flow.   As  indicated in




 Table 9,  however, the nitrate nitrogen concentration was generally greater




 in  the East Lagoon  throughout this study.   Highest levels of this nutrient




generally occurred during the summer months.




     Although nitrate nitrogen is the principal source of nitrogen for algal




growth, the supplies of nitrate were not depleted during phytoplankton blooms.




Ample amounts of both ammonia nitrogen and nitrate nitrogen were present in the




Muskegon Lagoons to allow for algal  demands,  and it appears that nitrogen will




not become a limiting factor in the  near future.
                                     64

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Orthophosphate






     The most available and important form of phosphorus for plan nutri-




tion is orthophosphate, which is found in great quantities in wastewater.  The




mean concentration of orthophosphate was quite high, 1.44 mg P/l +_ 0.39, in




the East Lagoon during the 18 month period of wastewater flow.  It also re-




mained near this level during the six-month period without wastewater dis-




charge into this lagoon due in part to the rapid biotic cycling of phosphorus.




Only minor spatial and seasonal variations were noted in the East Lagoon (Table




9).




     Larger fluctuations occurred in the West Lagoon.  Without the input of




wastewater during the first 18 months, the orthophosphate levels in this lagoon




varied from a below detectable level in February 1974 to 0,32 mg P/l in July




1974.  Higher values were continually noted during the summer months.  In




September the concentration of this nutrient declined rapidly in the West




Lagoon and remained less than 0.8 mg P/l throughout February 1975.  When waste-




water was discharged into this lagoon in the following month, the concentration




increased quickly, reached a high of 1.6 by June, and remained near this level




through the remainder of this investigation.




     Compounds containing phosphorus play major roles in nearly all phases of




metabolism, particularly in energy transformation associated with phosphory-




lation reactions in photosynthesis„  Phosphorus is required in the synthesis




of nucleotides, phosphatides, sugar phosphates, and other phosphorylated




intermediate compounds.  Further, phosphate is bonded usually as an ester in




a number of low molecular weight enzymes and vitamins essential for algal metabo-




lism  (Wetzel, 1975).  Despite the importance of phosphorus in algal physiology,




phytoplankton blooms were not reflected in reduced levels of orthophosphate.
                                     65

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 This nutrient was present in the lagoon in amounts far beyond the needs of




 algae.  Therefore, unlike the situation in many natural waters, it appears




 that phosphorus will  not limit phytoplankton growth or control standing




 crops in the Muskegon lagoons.
 Sulfate
      High levels of sulfate,  an abundant anion in natural bodies of water,




 were common in both Muskegon lagoons (Table 9).   Small spatial and seasonal




 variations were noted in the levels of this anion,  even before and after the




 discharge of wastewater.   During the first 18 months of study the mean was




 97 mg SO4/1 + 12 in the East Lagoon and 74 + 10  in  the West Lagoon.   Only minor




 changes  were noted during the final six months of study when the West Lagoon




 received the wastewater.   During this period the mean decreased to 95 + 4




 in the East Lagoon and increased to 77  + 8 in the West Lagoon.
 Chloride
     The  concentrations of chloride remained high  in  each  lagoon  throughout




this study with a rather homogeneous  spatial and seasonal  distribution  (Table




9).  The  lack of major fluctuations partly result  from the fact that chloride




is a conservative ion and metabolic utilization or biotically mediated changes




in the environment do not cause large variations in its level.




     The  concentration of this ion was consistently higher in the East Lagoon




than in the West Lagoon, even during the period of wastewater flow to the




West Lagoon.  During the first 18 months, the mean chloride level was 165 mg/1




+ 13 in the East Lagoon and 105 + 15 in the West Lagoon.  During the six month




period of wastewater flow to the West Lagoon, the mean chloride level increased




to 135 + 30 in this lagoon,  but remained near the previous average in the East
                                     66

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Lagoon, 166 + 23.  Wastewater normally contains a high concentration of




chloride ions since sodium chloride passes unchanged through the digestive
system.
Calcium






     Only minor variations in the concentration of calcium occurred verti-




cally and among stations, with no apparent seasonal trends (Table 10).




Throughout this investigation, the concentration of calcium in the East




Lagoon, approximately 60 mg/1, remained slightly higher than the concentra-




tion in the West Lagoon of 55.  Calcium is not present in high concentrations




in wastewater, and the levels of this cation in the Muskegon lagoons  are




largely controlled by the mineralogical characteristics of the basins and




the surrounding land.







Magnesium






     Magnesium is required universally by  the algae as the porphyrin  component




of the chlorophyll molecules.  It  is also  needed as a micronutrient  in  enzymatic




transformations of organisms, especially in  transphosphoralations of  algae,  fungi




and bacteria  (Wetzel, 1975).  Only minor fluctuations  in  this  cation  were  noted




during this study, because  the demands for magnesium  in metabolism are  minor




in comparison to  the  quantities  available  (Table 10).




      This  cation  is a common  constituent in  natural waters,  and  levels  remained




slightly higher in the West Lagoon than  in the  East Lagoon due to  the inflow




of interception ditch water into the West  Lagoon.  The concentration of magnesium




in both  lagoons remained near 16 mg/1.
                                      67

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                         TABLE 10.  COMPARISON OF METAL AND CATION LEVELS IN THE MUSKEGON LAGOONS
                                  DATA ARE GIVEN AS THE MEAN (mg/1) + ONE STANDARD DEVIATION.

                                                            KEY
WW = Period of wastewater flow NWW - Period of no wastewater flow
PARAMETER
Calcium WW
NWW
Magnesium WW
NWW
Sodium WW
NWW
Potassium WW
NWW
Manganese WW
NWW
Zinc WW
NWW
Iron WW
NWW

E-l
64.3 + 6.6
59.3 + 1.6
16.0 + 1.5
15.7 + 1.3
248 + 13
161 + 8
11.5 + 1.6
9.7 + 0.6
0.21 + 0.05
0.21 +_ 0.04
0.13 + 0.03
1.07 + 0.32
1.17 + 0.07
STATIONS
E-5
62.0 +_ 7.9
58.4 + 2.3
17.0 + 1.1
15.7 + 1.1
141 + 9
163 + 9
11.3 + 0.5
9.8 + 0.6
0.18 + 0.09
0.17 + 0.05
0.11 + 0.01
1.06 + 0.40
1.10 + 0.08
E-8
63.5 + 6.6
59.8 + 3.3
16.0 + 1.5
15.3 + 1.4
147 + 11
161 + 9
11.5 + 1.9
9.7 +_ 0.7
0.20 + 0.72
0.21 + 0.04
0.11 + 0.03
1.15 + 0.36
1.10 + 0.09
W-l
58.7 + 2.4
53.3 + 8.7
16.8 + 1.6
17.0 + 1.0
137 + 16
93 + 12
8.3 + 0.7
5.9 + 1.0
0.04 + 0.02
0.11 + 0.03
0.09 + 0.03
0.79 + 0.30
0.68 + 0.33
W-5
57.8 + 3.7
54.5 + 2.3
16.0 + 0.6
17.3 + 0.6
137 + 14
98 + 8
8.2 + 1.0
6.0 + 0.7
0.03 + 0.18
0.09 + 0.03
0.08 + 0.04
0.77 + 0.33
0.51 + 0.17
W-9
57.5 + 4.3
53.9 + 5.5
16.0 + 1.4
16.7 + 1.2
130 + 22
92 + 10
7.9 + 1.2
5.8 + 0.9
0.04 +0.02
0.09 + 0.03
0.07 + 0.03
0.78 + 0.31
0.71 + 0.40
00

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 Sodium






     Throughout this investigation the levels of sodium remained higher in




the East Lagoon than in the West Lagoon  (Table 10).  The concentration of




this cation in the East Lagoon was less during the period of wastewater flow,




148 mg/1 +_ 12, than during the following period without such flow, 161 +_ 9,




yet the level of sodium increased from 93 +_ 11 prior to wastewater flow, to




133 +_ 18 during the flow in the West Lagoon.




     The high concentration of sodium in wastewater is probably caused by




synthetic detergents and domestic sewage.  The sodium input to domestic sewage




comes from sodium chloride passing unchanged through the digestive system.







Potassium







     Potassium was distributed uniformly throughout the lagoons with little




seasonal variation, indicative of the conservative nature of this cation




similar to sodium and magnesium (Table 10).  The levels of potassium were




elevated in each lagoon during the period of wastewater flow.  Although the




concentration of this cation declined in the East Lagoon and increased in the




West Lagoon when the flow of wastewater was changed from the East to the West




Lagoon, the concentration remained greater in the East Lagoon.






Manganese







     Higher levels of manganese, an essential micronutrient, were present in




the East Lagoon than were present in the West Lagoon (Table 10).  The mean




during the period of wastewater flow to the East Lagoon was 0.24 mg/1 +_ 0.02




in the West Lagoon.  Because of these low concentrations, manganese data were




not collected after February, 1975.
                                      69

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      It appears that manganese will not reach levels inhibitory to phyto-




 plankton in the Muskegon lagoons, since the highest value during this period




 was only 0.27 mg/1, and toxic effects do not appear until levels are over 1




 mg/1 (Patrick, et al, 1966).
 Iron
      The concentration of iron was high in each lagoon and fluctuated through




 time (Table 10).   During the first 18 months of study the levels of iron ranged




 from 0.64 to 1.8  mg/1 in the East Lagoon and from 0.35 to 1.4 in the West Lagoon.




 Because of the high content of iron in Muskegon industrial wastewater, the




 levels  remained greater in the East Lagoon than in the West Lagoon.  The large




 variations in time mask much of the difference that was apparently related to




 wastewater flow patterns.





      Iron levels  in the Muskegon lagoons are more than adequate to allow the




 biota to use this essential micronutrient.
 Zinc
     Due  to  industrial waste pollution, high  concentrations  of  zinc,  greater




than 0.25 mg/1, occurred  in the East Lagoon during the period of wastewater




flow to this lagoon  (Table 10).  During the same time period, levels  of  zinc




less than 0.08 mg/1 were  common in the West Lagoon.  After March 1975, the zinc




levels decreased to a mean of 0.12 in the East Lagoon and rose  to a mean of 0.09




in the West Lagoon.





     The zinc levels in the Muskegon lagoons are in the toxic range for many




organisms.  Levels exceeding 0.2 mg/1 are toxic to many invertebrates  (Hynes,




1960),  whereas levels exceeding 0.1 constitute a hazard in the aquatic environ-




ment (Committee on Water Quality Criteria, 1972).  The above cited Committee
                                      70

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found zinc in concentrations as low as 0.1 mg/1 to be toxic to Daphnia.




     It should be noted that there is a synergistic effect when other heavy




metals, such as copper and cadmium, both of which are components of the




Muskegon lagoons, are present with zinc (La Roche, 1972).  Bioaccumulation of




zinc through the food web, with high concentrations occurring particularly in




the invertebrates, may also increase the zinc toxicity problem in the Muskegon




lagoons.
                                      71

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                                 SECTION VI

                                BIBLIOGRAPHY

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Curry, LaVern L.  1962.  A key for the larval forms of aquatic midges
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Hutchins, W.A.  1939.  Sewage irrigation as practiced in the western states.
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La Roche, G.   1972.   Biological effects of short-term  exposure to hazardous
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                                      74

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Mullin, M.M.  1966.  Selective feeding by calanoid copepods.  In_ Some
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                                       77

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                                   TECHNICAL REPORT DATA
                            (Please read Instructions on the reverse before completing)
 1. REPORT NO.
  EPA-600/3-77-039
 4. TITLE AND SUBTITLE
  Muskegon,  Michigan Industrial-Municipal  Wastewater
  Storage Lagoons: Biota and  Environment
              3. RECIPIENT'S ACCESSION-NO.
                                                           5. REPORT DATE
                            April 1977
             6. PERFORMING ORGANIZATION CODE
 7. AUTHOR(S)
   W.  Randolph Frykberg, Clarence  Goodnight, and
   Peter  G.  Meier
                                                           8. PERFORMING ORGANIZATION REPORT NO
 9. PERFORMING ORGANIZATION NAME AND ADDRESS

  Northeast Michigan Council  of  Governments
  Gaylord,  Michigan 49735
              10. PROGRAM ELEMENT NO.

                1BA608
              11. CONTRACT/GBALII NO.

                04J1P01534
 12. SPONSORING AGENCY NAME AND ADDRESS
  Corvallis Environmental Research  Laboratory
  U.S.  Environmental Protection Agency
  Corvallis,  Oregon 97330
              13. TYPE OF REPORT AND PERIOD COVERED
                Final   8/73-8/75
              14. SPONSORING AGENCY CODE
 15. SUPPLEMENTARY NOTES
  To  be  published in Ecological  Research Series of EPA
 16. ABSTRACT
  A  limnological  investigation was  carried out on two 344  hectare (850 acre)
  industrial-municipal wastewater storage lagoons from August  1973 until August 1975.
  Besides  monitoring physical and chemical parameters during the period of the
  initial  filling, the biological community was critically examined for the purpose
  of documenting  ecological succession  over this two year  period.

  In general,  the lagoons remained  aerobic, well mixed vertically and slightly
  alkaline.   The  low transparency within the lagoons was an important factor which
  limited  the  phytoplankton population  and excluded rooted aquatics and benthic algae.
  Ample  nutrients were present for  algal  demands.

  The  lagoon's phytoplankton-protozoan  assemblage was extremely  variable with respect
  to total  abundance and distribution.   The zooplankton community was composed of
  fourteen  species of free living crustaceans and four species of rotifers.  The
  benthic  fauna consisted of a small  number of organisms representing only a few
  taxonomic groups.
                                KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
  Lagoons
  Waste  Treatment
  Limnology
  Municipal  Wastewater
  Industrial  Waste Treatment
                                              b.IDENTIFIERS/OPEN ENDED TERMS
   Stabilization  Ponds
   Waste disposal
   Sewage disposal
   Phytoplankton
   Zooplankton
                                                                         c.  COSATI Field/Group
06/F

08/H
 3. DISTRIBUTION STATEMENT

  Release  Unlimited
19. SECURITY CLASS (This Report)

  Unclassified
                           21. NO. OF PAGES
                                              20. SECURITY CLASS (This page)

                                                Unclassified
                                                                         22. PRICE
EPA Form 2220-1 (9-73)
                                           78
                                                         U- S. GOVERNMENT PRINTING OFFICE: 1977—797-588/102 REGION 10

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