;"{ „ .  United States        Office of Air        EPA 340/1-79-110
                                    July 1979
-  ""K  , .... .' ' n .  United States        Office of Air
il l(\V*~~-^  V^O^'Y  Environmental Protection    Washington DC 20460
\    I    If  Agency
vc/EPA      Executive Summary
            Implications of Ract
            for the Cutback
            Asphalt Industry
            July 1979

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                                              EPA 340/1-79-110
           EXECUTIVE SUMMARY

       IMPLICATION OF RACT FOR THE

        CUTBACK ASPHALT INDUSTRY
                   by


          Robert W. Elfstrom, Jr.

                  and

          James A. Commins,  P.E.
                JACA Corp.
             550 Pinetown  Rd.
        Fort  Washington,  EA  19034
         Contract No.  68-01-4135
               Tasks 40-41
              Prepared for


  U.S.  Environmental Protection Agency
Division of Stationary Source Enforcement
          Washington, DC  20460

     Task Manager:  Robert L. King



              July, 1979

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                         ABSTRACT




       This  report has  been  prepared with  the objective  of

summarizing  enforcement   implications  of adopting  reasonably

available control  technology (RACT)  by the cutback asphalt

industry,  as  developed  by  the U.S.  Environmental  Protection

Agency  (EPA), to  control the emissions of  volatile organic

compounds  (VOC's)  generated  from cutback asphalt use in highway

construction.  RACT prohibits  the  use of  cutback asphalt

whenever  substitution of  emulsified  asphalt  is  possible.

However,  certain operational conditions and  technical  problems

of storage and application  limit the  extent  of  this  substitu-

tion and  the  subsequent reduction in VOC emissions.   Some  state

highway departments use  cutback  asphalt  in  maintenance  prac-

tices, but it  is predominantly  used  on  roads under local

jurisdiction  in miscellaneous  surface  and cold  asphalt mix  (as

opposed  to hot  asphalt  mix)  applications.   Consequently,

enforcement strategies  may be needed down to  the local level.

       The EPA solicits  comments  from the  reader  regarding

any positive  or  negative experiences  with  emulsions  as  well

as any additional   information that  the reader feels is perti-

nent  to this discussion.  Comments  may be  sent to:

            Robert L. King, DSSE  (EN-341)
            Environmental Protection Agency
            401 M  Street, S.W.
            Washington, DC  20460
                            11

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       This report  was submitted  in partial  fulfillment of



Contract No. 68-01-4135,  Tasks 40-41 by JACA Corp., under  the



sponsorship of the U.S. Environmental Protection Agency.   The



contents of this report are reproduced  herein  as received  from



the  contractor.   The opinions,  findings, and  conclusions



expressed are  those  of  the  authors and not necessarily  those of



the Environmental  Protection Agency.
                             iii

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                      ACKNOWLEDGEMENT








       The technical discussions and data  supplied  to  JACA  from



many sources are  gratefully  appreciated.   The authors wish  to



express  sincere  appreciation to  John  DiRenzo,  Vice  President



of Highway Materials,  Inc.,  Fred Kloiber,  Director  of  Engineer-



ing and  Operations  for  the  National Asphalt Pavement Associa-



tion,   Larry  Ostermeyer,  Vice President  of Technical Services



and Mike Guerin,  Field  Engineer,  McConnaughay,  Inc. who crit-



ically reviewed this  report.  We would also  like  to note the



assistance of  The  Pennsylvania  Department of Transportation,



The Pennsylvania Asphalt Pavement Association,  The Asphalt



Institute,  and  The Asphalt Emulsion  Manufacturer's  Association.
                             iv

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                    Table of Contents
                                                       Page
INTRODUCTION                                            *

      Process Description                               2

      Volatile Organic Compound (VOC) Emissions        10



TECHNICAL FACTORS AND IMPLICATIONS                     13

      VOC Emissions                                    13

      Storage, Handling, and Application of
      Emulsified Asphalt                               15

      Enforcement                                      19

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                 List  of  Tables  and Figures
Table No-                                               Page


    1    1977 CUTBACK ASPHALT VOC  EMISSIONS              H

    2    STATE ROAD MILEAGE AND  %  UNDER  LOCAL
         JURISDICTION                                    20
Figure No.
    1    SCHEMATIC OF AN ASPHALT PAVEMENT                 3

    2    1977 NATIONAL VOC EMISSION FROM
         CUTBACK ASPHALT USE                             22
                            VI

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                      INTRODUCTION

       This  document addresses the control of volatile organic
compounds (VOC's)  generated  from the  use of  cutback  asphalt
in road  construction  and maintenance.   Cutback asphalt  is
asphalt cement (basically  a solid  or semi-solid) which has been
diluted with petroleum solvents (VOC's) to control set up time
of the pavement mixture.  Cutbacks are  occasionally mixed with
aggregates in asphalt mix plants  to produce maintenances mixes
for pothole repair and other  types of  emergency uses.  The bulk
of cutbacks are used in cold  asphalt mixes and  in  miscellaneous
surface applications applied  at the  construction site.
       The Environmental  Protection Agency  (EPA)  has published
a  Control Techniques  Guideline  (CTG)  for  cutback  asphalt users
specifying reasonably available control  technology (RACT).
RACT prohibits the use of cutback asphalt whenever substitution
of emulsified  asphalt   is  possible.  Because an  emulsified
asphalt  is  basically a suspension  of asphalt cement in water
and  an emulsifying  agent, such a substitution has  the potential
to reduce VOC emissions significantly.
       Operational  conditions and technical  problems  of
 storage  and application limit  the extent  to which  the substitu-
 tion can be achieved.  It is helpful  to evaluate  the potential
 impact of RACT  in terms of  VOC  reductions in the  context  of
 these  limitations.
                              -1-

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       This  document provides  the reader with  necessary



 background information on the materials and equipment required



 to  construct  and maintain  an  asphalt pavement  and  specifies



 those areas where cutback and emulsified asphalts are used.  In



 addition,  it  presents technical factors of  implementing  RACT



 which involve VOC emissions,  storage, handling, and application



 of emulsified asphalt, and enforcement.








 Process Description








       The process  of constructing a  road, which  has been



 described  below,  requires  the  laying of  several  hot or cold



 mixed paving courses.  Although  the  Control  Techniques  Guide-



 line  (CTG)  is  only  applicable  to  cold  mix operations,  a



 description of hot mix processes has been  included  to enhance



 the reader's  understanding of the paving industry.




       An  asphalt pavement  is  a compacted  mixture of asphalt



 cement,   coarse  aggregate  and fine aggregate  which  have been



 sized to design specifications.  It may  consist of several



 layers or courses.   The number of courses and  the  design



 specifications  depend  on a number  of factors  such as  the



 subsoil   structure,  the average  daily traffic (ADT),  the type



 of vehicles  expected  in  the traffic mix, and the  predicted



vehicle  speeds.   An  example of  this  structure  is  shown in



Figure 1.
                            -2-

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                        FIGURE 1




            SCHEMATIC OF AN ASPHALT PAVEMENT
                                                           TACK COAT
                                                           PRIME COAT
       The subgrade  (or soil)  is  leveled and  stabilized  if



necessary.    Sub-base  material consisting of one  or  more



layers of  aggregate  is evenly  distributed  over its  surface.



A prime coat,  a  highly  penetrating low viscosity liquid bitumi-



nous material, may be  sprayed on  the  sub-grade  or sub-base,



although the latter is more common.   The prime  coat penetrates



into the course  forming a  water  resistant layer on its surface,



hardens and stabilizes the  surface,  and helps  bind  it  to the



following asphalt course.   The  base,  wearing  course, and seal



coat  sequentially  cover  the  sub-base with  aggregate  size



progressively decreasing.   The base, often referred  to as  black



base,  serves  as  the  foundation  course and is constructed in  3



to  4  inch lifts  of  aggregate  and an asphaltic binder.  The
                             -3-

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 wearing  course  is a  single  or multiple surface treatment of
 asphalt  and  aggregate,  whereas the  seal  coat  is an  optional
 final  cover applied  to waterproof  the asphalt  surface and
 improve its texture.
       The duration of  time between  spreading and rolling the
 base,  wearing course,  and seal  coat may be long  enough to
 require the use of a tack coat.  The  tack  coat,  like  the  prime
 coat,  is  also  a  low  viscosity  spray-applied preparation coat
 which  serves as  an adhesive  layer for the  succeeding cover
 material.
       At asphalt mixing plants, the asphalt cement is either
 mixed  with aggregate which has  been heated  to a  range of
 temperatures  nominally  between  270°  and 330°F  (called  a hot
 asphalt  mix)  or  with aggregate which  has been heated  to  a
 range  of  temperatures nominally  between 100°  and  150°F
 (called a  cold  asphalt  mix).  Cold asphalt mixes  may  also be
 prepared  at  the  job  site  by mixing  the asphalt cement with
 aggregate at  ambient  temperature.   Hot mixing requires melting
 of  the  asphalt  cement  to liquify it while cold mixes are
 prepared  with liquid cutback or emulsified  asphalt.  The choice
 of whether to use  a hot  or cold  mix depends  on the type of road
 construction  or  surface  treatment  required, prevailing weather
 conditions and  job site  location.   A  hot mix asphalt layer is
 the highest quality surface.
       Hot asphalt mixes are  conventionally  produced  in
batch or  continuous plants where  the various sized  aggregate

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is  combined, dried and  heated,  separated as  to  size,  recom-
bined,  and then mixed with  asphalt  cement. Almost 85%  of  new
plants,  however,  use a technique known as drum  mixing,  which
combines  drying,  heating  and mixing  operations.    This  elimi-
nates the  need  for hot elevators,  screens,  and bins  of  the
conventional  plants,  but  requires  sophisticated cold feed
blending  systems  and surge  or storage bins to  store  the drum-
mixed  product.
       Conventional operations in  the  hot  mix  process are:
       1.   Cold aggregate  (which includes coarse aggregate up
to 2-1/2  inches  in  diameter  and fine aggregate  consisting of
a  natural sand  and/or  finely crushed  stone,  slag,  gravel
or synthetic aggregate  such as expanded shale or clay)  is
proportioned on the  basis of  size  according to the  design
specifications  and transported by a common  conveyor  and/or
bucket elevator to the  inlet  of the dryer.  Mineral  filler
consisting of  very  finely  crushed  stone, hydrated  lime,  fly
ash,  Portland cement, and other non-plastic mineral  filler
may also  be mixed with  the cold aggregate (proportioned on
the basis of weight).
       2.  The rotating dryer has a series of  internal  flights
which cause  the  aggregate  to form  a  curtain across the cross-
section  of the drum.  Aggregate temperature is  raised to a
range  of temperatures  nominally  between 270°  and  330°F in
order to  remove surface moisture and to  improve  the subsequent
asphalt  coating.   The capacity of  the  dryer  is dependent on
                            -5-

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cold aggregate  characteristics.   As  the percentage of fines and
moisture  increase/  fuel  consumption  increases and  aggregate
cold feed rates decrease.
       3.   The aggregate  is discharged  at  the  end of  the
dryer  into  a  bucket elevator which  transports the material
to a set of vibrating screens  which separate the aggregate
by size and  drop  it  into appropriate  hot storage bins.
Aggregate  from these  bins is  weighed  in  the  weigh hopper
according  to  mix  specifications  and  job  mix  formulas  and
discharged  into the pugmill.
       4.   The pugmill  mixes   the dry  aggregate  for a  few
seconds and then  a  spraybar,  an "asphalt  bucket",    or  other
metering  device  adds  asphalt  cement  (approximately 5%  by
weight).   After 20 to  40  seconds of further mixing  the product
is discharged  into  waiting  trucks  or surge or  storage  bins.
       Hot  mix  plant operators occasionally reduce  the temper-
ature on the aggregate dryer to  between 100°   to  150° F  and
run  cutback or emulsified asphalt  through  the  pugmill  to
produce what is known  as a cold  mix.   (Cutback and  emulsified
asphalts will  be  described in  more  detail later.)   Cutback
asphalts  are  used with  a  nominal  aggregate  temperature  of
110°F  while some  emulsified  asphalts are  used  at slightly
higher  temperatures.   The temperature of the aggregate in  the
dryer is lowered when  cutbacks  are used to  prevent the  vola—
tiles in the asphalt mixture from  escaping  and  to  reduce  tha
chance  of fire  and explosion in the  pugmill.
                            -6-

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       Cold  mixes are commonly mixed at  the  construction  site
by traveling  pugmills  or mixed  on  the surface being  treated
(in-situ)  by motor graders.   There  are  two  types  of  traveling
pugmills.   One  mechanically gathers  a prepared  aggregate
windrow,  adds and mixes cutback or emulsified asphalt  with
the aggregate as  it  progresses,  and then discharges  onto the
roadbed a mixed  windrow  for  aeration,  spreading,  and  compact-
ing.    The second type of  traveling  pugmill  contains  a hopper
which  accepts aggregate  from  a  haul  truck,  adds and  mixes the
cutback or  emulsified asphalt with  the  aggregate,  and spreads
the mix on the roadbed.
       In-place  mixing  is  performed with a motor grader
which, after  scarifying  the bed, moves along the road surface,
grinds it  with  a series of tines and  adds  the emulsified
asphalt  (which  may  require  extra  water) or  cutback  asphalt,
leaving the  combined  mix in  the same basic  position  but in an
uncompacted state.   To  simplify mixing, this procedure may be
modified  by attaching a  mixing  blade to  the  scarification unit
to produce windrows.   The motor  grader  would  then move  longitu-
dinally over  each windrow and perform the  mixing.
       Some  states  have central maintenance  facilities   (low
volume central   mixing   plants)  which are  responsible for
small-scale  repairs  and maintenance  of   state  and  county
roads.  At  these facilities pugmills are  often  replaced by
mixing platforms where  the  aggregate  and  cutback  or  emulsi-
fied  asphalt  are blade-mixed and front-end   loaded into stock-
piles for storage or into trucks for  immediate use at  ambient
                             -7-

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 temperature.
       The  time  for  the hot or  cold  mixed asphalt product to
 harden is a  key  factor  in product handling since it influences
 workability  and  subsequent  product quality.   It  is  referred
 to  as curing  time.    Hot asphalt  mixes  set-up strictly by
 cooling down  to  ambient temperature.     In hot asphalt mixes,
 the  laying  temperature of  the mix  must be  within  15°F of
 the  plant's  mixing  temperature  (based on refinery recommenda-
 tions).  The  hot mix  may also  be transported  on  heated trucks
 or,  as in Pennsylvania, be stored  in  uninsulated surge or
 storage bins for  a maximum of 3  to 4 hours, stored in partially
 heated and  insulated  storage silos  for  a maximum of  24 hours,
 or stored in  completely  heated  and  insultated  silos  (possibly
 sealed with  inert  gas)  for  longer  than  24  hours depending on
 product characteristics.   Storage equipment and times  may vary
 in each  state.  In cold asphalt mixes  which  are stored  and
 applied  at  ambient temperatures and in prime and tack coat
 applications where a  low viscosity  asphalt  is  required,  it is
necessary to treat  the asphalt cement  in  some way.  The asphalt
cement may  be diluted  with a volatile organic solvent producing
a cutback  asphalt  or blended  with  a  surfactant  and water
producing an asphalt emulsion.  Generally, cutbacks cure by  the
evaporation  of solvents whereas  emulsions cure  by the  evapora-
tion of water  which is  freed when  the asphalt  particles  coal-
esce.
       There are  three types of cutback asphalts.   They include
                            -8-

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rapid curing cutbacks  (RC)  where  highly volatile gasoline or
naptha is the  solvent;  medium  curing  cutbacks  (MC)  where the
less volatile kerosene is the solvent;  and  slow curing asphalt
(SC) where a low to non-volatile oil is the solvent.  Average
evaporation  percentages for RC, MC   and SC cutback have  been
estimated to be  80,  70 and 25  percent, respectively. Solvent
concentrations  in cutbacks  may  be as  high  as  50% by volume;
however,  a  reasonable  average  is  20%.   This  figure is  based
on  the  approximate  average of  solvent  concentrations in  four
grades of  cutback  most  commonly  used  in  cold mix  operations
including RC 250, RC 800, MC 250 and MC 800.   At  this average,
the  percent of  solvent by weight for  SC,  MC  and RC cutback
asphalt is 17.8,  17.0,  and  14.6, respectively.
       Emulsified  asphalt,  on  the other  hand,  is processed
by  running  molten  asphalt  cement  and  treated water  through  a
colloid  mill  which imparts enough shear  stress to produce
very small  asphalt particles.  A surface active ingredient
 (surfactant)  in the  mixture  provides a  wetting action and
results  in the  asphalt particles  assuming a charged  state.
Consequently,  emulsified  asphalts  are  classified by  this
charge  and  the  time  for the emulsion  to  coalesce  - separate
into asphalt  and  water constituents.   The  terms  rapid set
 (RS),  medium set (MS)  and  slow set (SS) are used to designate
set-up  time.   The  terms cationic, anionic and nonionic desig-
nate the  charge of  the  asphalt as  positive,  negative,  or
neutral,  respectively.
                             -9-

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       According  to  state  emulsified asphalt  specifications,



volatile  organic  solvents are  ingredients in  some  asphalt



emulsions.   The specified  maximum oil distillate ranges from



0  to  20%.   Average evaporation percentages,  for the  solvents



used in these emulsions have not been determined.







Volatile Organic Compound (VOC) Emissions







       The asphalt paving industry has been cited  as a  signifi-



cant VOC  source  of emissions  because of  its extensive use of



cutback asphalt.  The amount of VOC's emitted  into  the air



from  cutback  asphalt use  is,  in  part,  determined  by the



volatility and quantity of  the solvent used in  "cutting-back"



the asphalt  cement. Other variables are the  length  of time



the  cutback  asphalt  is  exposed  to the  atmosphere  during



storage,  handling, and road  surface  applications,  as  well  as



any methods employed by the plant to  control emissions  (i.e.,



impermeable tarps  over  the  long-term storage  piles  and haul



trucks);  the  temperature; and the relative  humidity.



       In   1975  cutback asphalt  paving and sealing operations



across the nation generated  nearly 4% of the VOC's  emitted



from stationary  sources, and  in some east  central  states  it



accounted  for about  15%  of  each  state's  VOC total.   1977



regional  VOC emissions  resulting from  cutback asphalt use



are shown  in Table 1.  That  year,  approximately  30% of the



nation's  VOC emissions  were  emitted from  one region,  50%
                            -10-

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              Table I
1977 CUTBACK ASPHALT VOC EMISSIONS

State
EPA Region JL
Connecticut
Maine
Massachusetts
New Hampshire
Rhode Island
Vermont
Total
Region II
New Jersey
New York
Total

Region III
Delaware
feryland (DC)
Pennsylvania
Virginia
West Virginia
Total
Region IV
Alabama
Florida
Georgia
Kentucky
Mississippi
North Carolina
South Carolina
Tennessee
Total
Hcg^on V
Illinois
Indiana
Michigan
Minnesota
Ohio
Wisconsin
Total
(1,000
VOC Emissions
1.3
1.8
1.9
2.5
Z.I
776
3.9
9.8
13.7

.1
3.8
18.6
8.3
1.3
32.1
4.8
5.7
4.0
2.9
.4
4.4
1.9
1.8
25.9
38.6
13.7
7.7
12.6
34.9
15.8
123.3
tons)
State
EPA Region VI
Arkansas
Louisiana
New Mexico
Oklahoma
Texas
Ibtal
EPA Region VII
Iowa
*£msas
Missouri
Nebraska
Total
EPA Region VIII
Colorado
Montana
forth Dakota
South Dakota
Utah
Wyoming
Ibtal
EPA Region IX
Arizona
California
Rawa i i
Nevada
Total

EPA Region X
Alaska
Idaho
Oregon
Washington
'fbtal

National Total
-11-

VOC Emissions
8.0
2.4
5.2
19.5
10.7-
4 5 . 81
9.1
11.0
22.0
5.1
47.2
5.4
5.7
5.8
4.8
4.2
5.0
30. .9
6. 0
25.3
.3
2.4
34.0

1.0
5.2
2. 0
9.5
17.7

378.2


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from three  regions and  75% from six  regions.



       As  previously  stated,  the  Environmental  Protection



Agency  (EPA)  has published  a Control  Techniques Guideline



(CTG)  for  the  cutback  asphalt industry  specifying  reasonably



available  control technology  (RACT).   Because  an  emulsified



asphalt  (which  is water-based)  contains significantly  less



VOC' s than  a  cutback  asphalt  (which  is  solvent-based),  RACT



prohibits  the  industry from  using  cutback asphalt whenever



substitution of  emulsified asphalt is possible.



       The   implementation  of  RACT  will   reduce  VOC  emissions



because the amount of  solvent  used  in the emulsified  asphalt



is less  than that  used  in  cutback  asphalt;  also, solvent



evaporation may  be less although  this has  not  been  quantita-



tively  determined.   Furthermore,  energy  can  be conserved.



In 1975,  for  example,  approximately 10 million barrels  of



petroleum  solvents were  used  in  cutback asphalt.   If  the



crude  oil  used  in  making this  amount  of  solvent  had  been



used  to  produce  gasoline,  about  4-1/2  million  gallons  of



gasoline could  have  been produced.   This  total energy savings,



however,  must be reduced somewhat due to  the energy expended in



hauling  more  weight of emulsions  than  cutback for a given



bitumen  content.   (See page  18  for bitumen  content explana-



tion) .
                            -12-

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         TECHNICAL  FACTORS AND IMPLICATIONS  OF RACT

VOC Emissions

       In  order  to  evaluate the  effectiveness  of RACT  in
terms  of a reduction  in VOC emissions,  it is necessary  to
compare  emissions  generated  from  cutback  and  emulsified
asphalt use.   Emulsions may contain varying  amounts of volatile
organic  solvents,  so  whenever  a cutback  is  replaced  by  an
emulsified asphalt, this must be  accounted  for  in estimating
VOC emission reductions. Use data  such as the quantity and
grade designation of the cutback and emulsified  asphalt  used,
type of  surface  treatment, meteorological  conditions,  and  any
deviation from normal  operations  which  would effect  VOC  emis-
sions  should be  included in the  analysis.  Also, a maximum
concentration of  solvent in emulsions should be set  to  avoid
the predicament when the emulsion is,  in  essence, an  emulsi-
fied-cutback  asphalt.
       Based  on  state  cutback asphalt  sales  data  (supplied
by the  U.S.  Department  of  Energy),  it  is  possible  to  arrive
at  an  estimate  for VOC emissions  generated  from cutback
asphalt  use.   As  an  example,  suppose 100 tons  of SC, 450
tons of  MC,  and  326  tons of RC cutback asphalt were sold  in
a state.   Using  the appropriate multipliers  (see  page 9),
state  VOC  emissions would  be  calculated  in  the following
manner:
                            -13-

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          SC  = (100)  (.178)  (.25) =  4.4 tons



          MC  = (450)  (.170)  (.70) = 53.5 tons



          RC  = (326)  (.146)  (.80) = 38.0 tons



                           Total = 95.9 tons








       These  calculations only  reflect those  VOC emissions



particular to cutback  asphalt  and do  not  take  in  to  account



any of the necessary  use data  (referred to on page 13).



       As RACT is implemented, data on  national  sales  figures



of cutback asphalt and asphalt emulsions will  serve as  a  check



of emission  reductions.   While getting these data  on  a  state



level basis  is  easy,  it  would be preferable to have use  data



from  individual  hot  and   cold  mix  asphalt  companies and  mis-



cellaneous surface applicators.  Since it will be impossible to



do this  on a national  basis,  a stratified  random  sample  tech-



nique should  be  used.  This  method  would  involve  dividing the



population (i.e., the  50  states)  into  strata  or  subsets  based



on certain  criteria  (i.e., climatological  factors such  as



temperature,  relative humidity, and  precipitation).   From each



stratum  equal  amounts  of  subsamples  (i.e.,  asphalt companies



and  surface  applicators)   would randomly be selected for  data



collection.



       Once  area data is collected,  net VOC  emissions  for



that area  during   a  prescribed  time  can  be  estimated.



Emission  rate  factors   specific  to each  type  of surface



treatment  (i.e.,  Ibs.  VOC's emitted/hr) when  applied  to  the
                             -14-

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reported quantities used  and  adjusted  for  the  prevailing
temperature and  humidity  at the time  of  the operation  (i.e.,
via  a nomograph) should  yield  reasonable VOC  emission esti-
mates.   Presently,  there  are no such emission rate factors or
nomographs, which suggests the  need  for  future research  in this
area.
                      and Application of Emulsified  Asphalt
       It  is   imperative  that the emulsion manufacturer be
intimately involved in the  selection of the emulsion as well as
provide technical assistance in storing, handling, and applying
the emulsion.   Of primary concern  is matching the emulsion with
the job aggregate;  however,  one major  issue remains unresolved.
Technical  representatives   from   agencies  such  as  the
Asphalt Institute, the  Federal Highway  Administration (FHWA) ,
the Asphalt Emulsion  Manufacturer's Association  (AEMA) and some
state highway departments believe that the key to matching the
aggregate with the emulsion  depends on  their respective  elec-
trical charges.   They feel  that if an  emulsion of one charge is
mixed with aggregate  of the same charge, the  asphalt may not
adequately coat  the  aggregate,  resulting  in  a  very  poor seal
coat or mix.   In contrast  to this opinion,  McConnaughay, Inc.
and several  of  their  customers,  including  the  Indiana  State
Highway Commission, explain  that  the  coating effectiveness of
the emulsion on the aggregate  is based on emulsion formulation
                            -15-

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and not  ionic classification.    A discrepancy in  opinions  as
stated indicates that emulsion technology needs  to be further
developed and  properly  transferred to  those  who  use  the  ma-
terial.
       The selection of the  emulsion  for  the  job aggregate is
based  on prescribed  tests provided  by the asphalt  emulsion
manufacturer.   The  emulsion  manufacturer  should  also provide
some type of  certification which states that their emulsion is
compatible with  the  aggregate.   Additionally, premature coal-
escence of the emulsion  can occur in feed  lines,  storage tanks,
and  tank trucks if  differently  charged  emulsions  are mixed,
rendering   the emulsion useless  and requiring costly clean up
of  the equipment.  Therefore, it  is necessary to  employ proper
handling  and  storage  procedures  when  using asphalt emulsions.
The Asphalt Institute, FHWA, and  AEMA  assisted by state highway
departments and  many  industrial  technical representatives will
be  conducting  a new round of educational programs in the use of
asphalt  emulsions in the Fall of  1979.
       Even with these precautions  it has been customary to
avoid  application  of  emulsified  asphalt  under   the  following
conditions:

          •   When  the  temperature  of the  road surface or
              ambient air  approaches  a  level   which impairs
              the workability  of  the  mix  or  the subsequent
              product quality  -  a cut-off  temperature (50°F)
                             -16-

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             has  been  cited  in draft SIPs  and  state DOT
             specifications;
          •  When  long-term  stockpile  storage  is required
             (i.e., cold patch reserves); and
          •  When a prime coat is to be applied.

       The  first two conditions involve  either application
 temperature  or  storage  time.   The third condition  stems  from
 the  actual  size of the asphalt particle in the  emulsion.   In
 an  emulsion,  asphalt  cement  particles are suspended in  water
 and a surfactant.  If these  particles are too large,  penetration
 into the surface voids may be inadequate which  will  weaken the
 effect of the coat.
       These  limitations  on  the  use  of  asphalt  emulsions
 reduce  the  substitution potential  of asphalt  emulsion for
 cutbacks by  about  25%  and  perhaps  more in some of  the colder
 states.    However,  ongoing  development of  emulsion  technology
 may overcome some  of these  limitations in the  future.
       For  example, several  hot and  cold mix  operators  in
 Pennsylvania and  Delaware  have been  successfully  mixing,
 storing  for  extended periods  of time,  and  applying  emulsified
 asphalt  cold patch material in cold weather.   The  highway
 departments  in  Alabama,  Indiana,  South Carolina,  and Tennessee*
 have also succeeded  in using it in prime coating.  An effort  153
 underway to find out what special  techniques or  feedstocks
 these operators  employ and to  evaluate their extension to other
areas of  the country.

                            -17-

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       In constructing an  asphalt  pavement,  residual  bitumen



content  (including  the  asphaltenes and  maltenes)  is  another



technical  factor.  According  to  the American Society  for



Testing  and  Materials  (ASTM)  specifications,  the  permissible



minimum  residual bitumen  content in the  most commonly  used



grades  of  cutback  asphalt (referred to  on page  9)  is  65%.



However, for some grade of  asphalt emulsions  residual  bitumen



content  as  low as 55%  is  permitted.   As  indicated  by authori-



ties from the National  Asphalt Pavement Association (NAPA), the



Pennsylvania  Asphalt  Pavement  Association   (PAPA), AEMA,



state  highway and  transportation departments,  and  several



asphalt  plant  operators,  this difference  in  residual  bitumen



content  may  entail  the  use  of more emulsion  than  cutback when



laying  certain  road surface treatments.  In  essence  there may



not  be a one for one  volumetric  substitu  tion.   This affects



the  potential  VOC   reductions and  has economic  and energy




implications.



        In  some  operations approximately 3%  (by weight)   addi-



tional  water  is  required  from field service when using emulsi-



fied asphalt.  This could be a limiting  factor  in arid  regions.



Finally,  there  is  a  potential  for adverse environmental  side



effects  which  have  not  yet  been examined.  The amino compounds



present  in  some  surfactants used  in emulsions  can  leach out or



 run off  from inadequately cured  road  surfaces,  especially



during heavy precipitation, resulting  in poor  road quality and



possible nitrogen contamination  of ground and  surface waters.
                             -18-

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 Thus,  upon further  research  into  these  side  effects,  topogra-




 phic  features  in  conjunction with  weather  conditions may



 present more application limitations.








 Enforcement








       When  an enforcement  agency  undertakes  to  implement



 RACT guidelines  it  must deal with certain  practical situa-



 tions.  The substitution must be  agreeable to  state DOTs and



 preferably be incorporated  in highway construction  specifica-



 tions.  Enforcement would be comparatively  easy   in those



 instances  where  state  specifications  require  emulsified



 asphalt,  and the state has  direct ability  to enforce these



 requirements on  all levels  of highway construction.   Many



 state  DOTs are now  specifying the  use of  emulsions rather



 than  cutback  except  for winter  storage and prime  coats.



 The  major problem   is  the limitation  of state control  in



 local  areas where most  cutback asphalt  is used  (i.e., parking



 lots,  local and city streets, farm-to-market  roads,  and misc-



 ellaneous  surface  applications).  In Table 2, state road mileage



 in each EPA region and the percentage  under local jurisdiction



 are shown.  As an example, the  New  York State's  highway depart-



 ment in 1977  (see Table 2)  practically  eliminated  the use  of



 cutback asphalt,  but  state  VOC  emissions  from  the use  of



cutback asphalt  (including SC,  MC,  and  RC types) were estimated



 to be  10,000 tons (see  Table  1).   This  large remaining  value






                           -19-

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r
           TABLE II
STATE ROAD MILEAGE AND % UNDER
LOCAL JURISDICTION

State
EPA Region 1
Connecticut
Maine
Massachusetts
New Hampshire
Rhode Island
Vermont
Ibtal
Region II
New Jersey
Kaw York
Total
Region III
Delaware
Maryland (DC)
Pennsylvania
Virginia
West Virginia
Total
Region IV
Alabama
Florida
Georgia
Kentucky
Mississippi
North Carolina
South Carolina
Tennessee
Total
Region V
Illinois
Indiana
Michigan
Minnesota
Ohio
Wi scons in
Total

Total
Mileage*
18.9
21.5
31.3
15.2
5.5
13.8
106.2
32.7
108.9
141.6
5.2
28.6
114.9
62.4
36.5
247.6
86.4
98.1
100.6
69.9
67.0
88.6
60.6
81.1
652.3
131.1
91.4
118.6
128.1
110.3
104.7
684.2

%
Local
79
44
88
70
76
78
73
91
83
83
12
80
57
12
8
40
74
83
81
63
83
13
37
86
66
87
87
90
89
82
88
87

State
EPA Region VI
Arkansas
Louisiana
New Mexico
Oklahoma
Texas
Total
EPA Region VII
Iowa
Kansas
Missouri
Nebraska
•total
EPA Region. VIII
Colorado
Montana
North Dakota
South Dakota
Utah
Wyoming
Total
EPA Region IX
Arizona
California
Hawaii
Nevada
Total
EPA Region X
Alaska
Idaho
Oregon
Washington
Total
National Total

Total
Mileage^
78.2
53.5
70.2
108.4
253.7
564.0
112.8
134 . 7
67.0
97.8
412.3
84.3
78.2
105.9
82.6
48.4
31.9
431.3
52.1
169.6
3.7
49.7
•Z757I"-
9.8
56.5
103.3
81. 5
251.4
3766.0

jfc
Local
77
71
72
88
12
76
91
92
83
89
89
88
79
92
87
52
71
"82
54
69
70
£Q
64
23
50
40
61
48
74
         *Units in 1000 miles (ARTBA,  Highway  Statistics,  November, 1975)
                                               -20-

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  (even  after  state adoption of asphalt emulsion) may  be  due  to
  the  fact that nearly  83% of the  road  mileage is under  local
  control.
        In  developing  an  enforcement  strategy  a decision  must
  be made as  to  what level of jurisdiction  (i.e.,  regional,
  state, or  local)  legal  attention and related effort  is  neces-
  sary  to minimize VOC  emissions by  substituting  emulsified
  asphalt  for  cutback  asphalt.   In Figure  2  1977  national VOC
 emissions from cutback  asphalt use have been  sectored  according
 to EPA  regions.  With  the exception of Region  I and  II,  which
 contribute  approximately  6%   of.  the  emissions,  those regions
 which are significant  contributors also have a large amount of
 mileage under local control  (see  Table 2).   Although  too many
 elements  enter into the  picture to compare road jurisdiction to
 VOC  emissions on  a  rigorous statistical  basis,  it can  be
 surmised  from  the  information contained   in  Figure  2  that  an
 enforcement strategy is needed down to the local level.
        An  overall  enforcement   strategy  would involve  the
 monitoring  of  state cutback and  emulsified asphalt sales.  This
 can be  readily accomplished since  these data  are already  being
 collected.   In those  instances  where a  state  DOT has strong
 indirect influence on  local construction practices, enforcement
 is also relatively simple.  As an  example,  the Pennsylvania  DOT
 (PennDOT)  indirectly affects  the  behavior  of county  and  local
officials by  placing  construction  restrictions on  funds  re-
ceived  from gasoline tax sharing.   The $.09 per gallon state
                             -21-

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                       FIGURE 2




1977 NATIONAL VOC EMISSIONS FROM CUTBACK ASPHALT USE
                             -22-

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 gasoline tax provides for $.015  to  be  returned  to  county  and
 local governments  if  construction is carried out in accordance
 with  PennDOT specifications.    In  those  states  where such
 indirect  control  through construction specifications  and
 funding  are  not  in force,  random  sample enforcement  is  indica-
 ted to be  the only tangible, and  feasible alternative.
       Because there are production and application  differences
 with asphalt  emulsions, technical exchanges  between  government
 construction officials and  producers  and  applicators will
 improve  acceptance  of the substitution.   Regional  technology
 transfer  seminars  or  workshops  could  educate  personnel from
 state and local highway  and  transportation departments and
 from industry in  the proper  ways to convert  to,  store, mix
 and  apply  emulsified  asphalt  and  associated  asphalt mixtures.
 These  seminars  would  vary in  intensity  from state  to  state.
 For  example, Pennsylvania,  Indiana, Virginia,  and New York
 have  accepted emulsified  asphalts and  each  has several years
 experience,  so  training  needs  may  be relatively  light.  On
 the  other hand,   Illinois,  Missouri,  and Wisconsin  which
 have  had  bad encounters  with emulsified asphalts, may need
 more attention.
       The foregoing discussion of highway  jurisdiction
 implications  on  the  cutback-to-emulsion  switch  suggests  that
 several  different  enforcement  strategies  may need  to  be
developed  for local areas.  The  problem  is  compounded  by the
difficulty in isolating the  relative  impact of cutback VOC
                            -23-

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emissions  for  each local  area considered on  the basis  of



attainment  or non-attainment.   A possible solution to minimize



the  enforcement  difficulties  is to  require the  switch  (with



consistent  exceptions based on  technical inabiity)  everywhere



irrespective of the VOC  attainment  status.
                              -24-

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  ( BIBLIOGRAPHIC DATA
  {SHEET
  A T;ri..
1. Report No.
   EPA  340/1-79-110
  4. Titlv and Subtitle

    Executive  Summary:   Enforcement Implication of RACT
    for the Cutback Asphalt Industry
   . Authar(s)Robert W.Elfstrom, Jr.
    JACA Corp.  James A.  Commins,  P.E.
   . Performing Organization Name end Address
    JACA Corporation
    550 Pinetown  Road
    Fort Washington> PA  19034
   2. Sponsoring Organization Name and Address

    Division  of Stationary Source  Enforcement
    U.S. Environmental Protection  Agency
    Washington, DC   20460
  15. Supplementary Notes
3. Recipient's Accession No.
                                                5. Kcpo/c Date
                                                fc. Performing Organization Rci.;.
                                                  No.                  '
                                                10. Projcci/Tasli/U'ojk Unh No.
                                                11. Contract/Grant No,

                                                68-01-4135  Task 40-41
                                                13. Type of Ucj»ou & Period
                                                   Covered

                                                App Ijed Keseare!;  1978-79
                                                1-5.
  16. Abstracts

       ,
                              been PrePared  W1'th the objective of summarizing enforcement

                                                ^
 17. Key Cords and Documcr' Analysis. I7a. Descriptors
       Cutback Asphalt  Users
       Surface Treatment
       Surface Applicators
       Hot Mix Processes
       Cold Mix Processes
       Cutback Asphalt
       Emulsified Asphalt
       Volatile Organic Compounds
       Emission Estimates

17b. Weiitifiers/Open-Ended Terms
                Technical Factors of  RACT
                Enforcement Strategy  of  RACT
>7c. COSATI Field/Group

18. Availability Statement
                    ENDORSED BY ANSI AND UNESCO.



19. Security Chiss (1 Jiis
lU;,r,,0
20. Sccucity Class ( t his
21. No. ot Pages
23
22. Price
                                                   THIS FO11M MAY «£ RKPKODUCKD     UICOMVI.DC »Jos.>-7*

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