Evaluation Of Chemical Waste Management, Inc Emelle, Alabama

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Hazardous Waste Groundwater Task Force
Groundwater Monitoring Evaluation
Chemical Waste Management
Emelle, Alabama
Update
From September 15-25, 1986 the Hazardous Waste Groundwater Task Force
conducted an investigation at the Chemical Waste Management (CWM),Emelle
Alabama facility. One main objective of the Groundwater Task Force is
to determine compliance with interim status groundwater monitoring
requirements of 40 CFR Part 265 as promulgated under RCRA or the state
program. The CWM-Bnelle groundwater system is unique from other facility's
in that the chalk monitoring well system has a waiver from 265 requirements.

A consent agreement between EPA and CWM was signed December 19, 1984. It
includes a waiver of the groundwater monitoring requirements set out in
40 CFR §265.91 (a)(2). The basis for the waiver is the low potential for
migration of hazardous wastes or constituents from the CWM-Emelle facility
via the uppermost aquifer to water supply wells or surface waters. The
waiver states that the time of travel for waste constituents to reach the
Eutaw Formation or the nearest surface waters exceeds one thousand years.

This update chronicles compliance activities that have taken place since
the time of the Groundwater Task Force Investigation at Chemical Waste
Management - Emelle (CWM).

On January 28, 1987 EPA conducted a Comprehensive Evaluation Inspection at
CWM. No class I violations resulted.

*From May 4-6, 1987 ADEM conducted a sampling inspection of 32 shallow
monitoring wells. Analysis revealed that all parameters were less than
10 micrograms per liter. This sampling is to be included with the compre-
hensive groundwater inspection done by ADEM earlier this year.

On May 14, 1987 ADEM issued CVM a warning letter for late certification of
closure of trenches #8 through #18 and trench #20.

Fran May 27-28, 1987 ADEM conducted a sampling inspection of nine additional
shallow monitoring wells in the independent study area. Significant results
are as follows:

Well # Constituent Contamination
SM-19 1,2 - Dichloropropane 40.7 - 56.4 micrograms/L
SM-21 1,2 - Dichloropropane 18.8 - 22.1 micrograms/L
SM-22 1,1 - Dichloroethane 14.4 - 20.5 micrograms/L

ADEM intends to resample SM-19, SM-21 and SM-22, and additional assessment
activities are in process.

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On May 20, 1987 ADEM reported problems with CWM's 4th quarter sampling  in
a letter from ADEM to CWM.

1.  When sampling well #5a CWM only showed volatile compounds and field
    parameters in their results.  ADEM requested a more complete set of
    results.

2.  Barium was found in all wells.  CWM stated that this is due to the  fact
    that barium is found in the chalk.  ADEM stated that the barium was also
    found in the field blanks.  ADEM asked CWM for an explanation.

On July 8, 1987 ADEM issued an NOV for inadequate Waste Analysis, Closure
Plan and Cost Estimate for Closure.

On July 14, 1987 CWM certified closure of trenches #8 through #18 and trench
#20.

On July 28, 1987 EPA conducted a Comprehensive Evaluation Investigation at
CWM.  No class I violations were discovered.

Subsequent sampling done by ADEM since the time of the Task Force investigation
included the sampling of SM 2, SM 5, and SM 8.  ADEM did not detect any of
the compounds sampled for during the task force investigation.  Well SM 8
showed 15 microgram/L of methyl butyl-ketone during the Groundwater Task
Force investigation

CWM's Sampling and Analysis procedures have been addressed by EPA's permit.
The permit states that organic and total ttetal samples will not be filtered.
The Task Force recommends the use of gloves while sampling.  This issue has
not been addressed in the permit.

Groundwater sampling took place at CWM-Emelle on July 20-23 1987.  The
sampling was conducted by ADEM.  They split samples with CWM.  They received
results September 9, 1987.  All the shallow wells around trenches 8 through
18 and 20 were sampled.  All the shallow wells around trenches 1 through 7
(the old study area) were sampled.  They sampled for pH, specific conductivity
and volatiles.  Methylene chloride was found in some of the wells.  The old
study area showed 1,2 dichloropropane in SM 19, SM 21, and SM 22.  The
wells were resampled in August 1987.  They were sampled again during the
week of October 26-30, 1987.  CWM feels that contamination is from some
contaminated soil in this area.  Follow up studies are going on right now.

The final permit for CWM - Emelle was issued on May 27, 1987.  The permit
was to be effective July 11, 1987.  Prior to this date petitions against
the permit were filed for review with the EPA administrator.  EPA Region IV
Response To Petitions For Review was completed on September 11, 1987.  A
copy of this response can be obtained by contacting the Region IV Public
Affairs Office.  Because of the petition for review the permit has not
become effective yet.

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* Sampled for the following parameters:

Methylene Chloride
Trichlorofluoro-Methane
1,1 Dichloro-Ethene
1,1 Dichloro-Ethane
Trans - 1,2 Dichloro-Ethene
Chloroform
1,2 Dichloro-Ethane
1,1,1 Trichloro-Ethane
Carbon Tetrachloride
Bromodichloro-Methane
1,2 Dichloro Propane
Trichloroethylene
Benzene
Dibrcmochloro - Methane
1,1,2 Trichloro-Ethane
2 Chloroethyl vinyl etherl
Bromoform
1,1,2,2 Tetrachloro-Ethane
Tetrachloro-Ethylene
Toulene
Chlorobenzene
Ethyl Benzene

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UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
HAZARDOUS WASTE GROUND-WATER TASK FORCE
GROUND-WATER MONITORING EVALUATION

CHEMICAL WASTE MANAGEMENT, INC.
Emelle,  Alabama
November 1987
Donald Hunter
Project Coordinator
Region IV, USEPA, Environmental Services Division
Athens,  Georgia

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                              EXECUTIVE SUMMARY


INTRODUCTION 	 1

BACKGROUND 	 2

SUMMARY OF SIGNIFICANT COMPLIANCE ACTIONS 	 2

     Administrative Orders/Consent Agreements 	 2
     Interim Status Closure of Landfill 	 3
     Hazardous Waste Ground-Water Task Force 	 3
     Permitting 	 3
     Ground-Water Monitoring 	 4

SUMMARY OF FINDINGS AND CONCLUSIONS 	 4

  Compliance with Interim Status Standards 	 4

     Hydrogeological Characterization 	 5
     Monitoring System 	 6
     Indadequate Sampling and Analysis Plan 	 6
     Ground-Water Quality Assessment 	 7
     Laboratory Evaluation 	 7
     Monitoring Data Analysis 	 8

  Compliance with 40 CFR Part 270 and Potential
     Compliance with 40 CFR Part 264 	 8

TASK FORCE RECOMMENDATIONS 	 9


                      TECHNICAL REPORT

INVESTIGATIVE METHODS 	11

     Records/Document Review 	11
     Facility Inspection 	11
     Laboratory Evaluation 	12
     Ground-Water and Leachate Sampling and Analysis 	12
          Ground-Water Sampling 	12
          Leachate Sampling 	13

WASTE MANAGEMENT UNITS AND OPERATIONS/
     WASTE CHARACTERISTICS AND TRACKING 	15

     Primary Waste Management Processes 	15
     Background and Past Landfilling Activity 	16
     Current and Proposed Landfilling Practices 	16
     Types and Quantities of Waste 	16
     Landfill Cell Design 	17
     Waste Characterization and Tracking 	18
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GEOLOGY/GROUND WATER 	19
     Stratigraphy 	19
     Structural Geology 	19
     Ground Water 	20

ADEQUACY OF HYDROGEOLOGICAL, GEOLOGICAL AND
     GEOTECHNICAL CHARACTERIZATION 	22

     Published Literature 	22
     Previous Site Investigations 	22
     Colder Associates 	23
     Adequacy of Characterization 	23

GROUND-WATER MONITORING PRIOR TO AND
     DURING INTERIM STATUS  	25

     Pre-Interim Status 	25
     Interim Status Ground-Water Monitoring 	25
     Consent Agreement Wells 	28

GROUND-WATER MONITORING UNDER 40 CFR PART 264 	30

CWM GROUND-WATER SAMPLING AND ANALYSIS 	31

     Current Sampling and Analysis Plan 	32
     Quality Assurance/Quality Control 	33
     Analytical Procedures  	34

LABORATORY REVIEW 	35

     Ground-Water Sampling  and Analysis Plan 	35
     Sample Handling, Preservation and
          Field Measurements 	36
     Laboratory Sample Analysis 	36
     Quality Assurance and  Data Documentation 	37

TASK FORCE ANALYTICAL DATA  EVALUATION 	38

     RCRA Wells (Eutaw System) 	38
     Consent Agreement and  PCB Wells 	39
     Leachate Samples 	41

REFERENCES 	43

LIST OF FIGURES 	iii

LIST OF TABLES 	iii

LIST OF APPENDICES 	iii
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List of Figures

1 - Facility Location Map
2 - Site Diagram
3 - CWM PCS, Chalk Wells and Chalk Potentiometric Map
4 - Eutaw Aquifer Potentiometric Surface
5 - Original RCRA Ground-Water Monitoring System
6 - April, 1984, Revised RCRA Ground-Water Monitoring System
7 - Current (September, 1986) RCRA Ground-Water Monitoring System
8 - Shallow Well and Leachate Sump Locations
List of Tables

1 - Sampling Summary, HWGWTF Evaluation
2 - Sample Bottles and Preservatives, Preferred Order of Collection, HWGWTF
    Evaluation
3 - List and Description of Trenches T-l through T-20; Trenches Filled Prior
    to February 24, 1986.
4 - RCRA Waste Landfilled at CWM, Emelle
5 - CWM Sample Parameters,  Containers and Preservatives
6 - Analytical Methods for Part 265 Ground- Water Monitoring
7 - HWGWTF Analytical Data Summary, Ground- Water Samples. Eutaw Wells
8 - HWGWTF Analytical Data Summary, Ground-Water Samples, Chalk Wells
9 - HWGWTF Analytical Data Summary, Leachate Samples
List of Appendices

A - Field Sheets, HWGWTF Sampling
B - HWGWTF Sample Parameter List
C - Trench Line.: and Sump Design Drawings
D - Eutaw (RCRA) Monitoring Well Construction Records
E - Consent Agreement Well Construction Records
F - RCRA Permit Requirements, Ground-Water Monitoring Parameters and
    Analytical Procedures
G - Field Sampling Overview Checklist
H - HWGWTF Complete Data
I - Selected Historical RCRA Ground-Water Data
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INTRODUCTION

      Concerns have recently been raised about whether commercial hazardous
waste treatment, storage and disposal facilities (TSDFs) are complying with
the ground-water monitoring requirements promulgated under the Resource
Conservation and Recovery Act (RCRA).   In question is the ability of existing
or proposed ground-water monitoring systems to detect contaminant releases
from waste management units.  To evaluate these systems and determine the
current compliance status, the Administrator of the Environmental Protection
Agency (EPA) established a Hazardous Waste Ground-Water Task Force (Task
Force).   The Task Force comprises personnel from the EPA Office of Solid Waste
and Emergency Response (OSWER),  National Enforcement Investigations Center
(NEIC),  Regional Offices and State regulatory agencies.  The Task Force is
conducting in-depth on-site investigations of commercial TSDF's with the
following objectives:

     o  Determine compliance with interim status ground-water monitoring
        requirements of 40 CFR Part 265 as promulgated under RCRA or the
        State equivalent (where the State has received RCRA authorization).

     o  Evaluate the ground-water monitoring program described in the facil-
        ity's RCRA Part B permit application for compliance with 40 CFR
        Part 270.14(c).

     o  Determine if the ground water at the facility contains hazardous
        waste constituents.

     o  Provide information to assist the Agency in determining if the TSDF
        meets EPA ground-water monitoring requirements for waste management
        facilities receiving waste from response actions conducted under the
        Comprehensive Environmental Response, Compensation and Liability Act
        (CERCLA, Public Law 91-510).

     To address these objectives, each Task Force investigation will determine
if:

     o  The facility has developed and is following an adequate ground-water
        sampling and analysis plan;

     o  Designated RCRA and/or State required monitoring wells are properly
        located and constructed;

     o  Required analyses have been conducted on samples from the designated
        RCRA monitoring wells; and

     o  The ground-water quality assessment program outline (or plan, as
       appropriate) is adequate.

     During September 15 - 25, 1986, a Task Force team conducted an evaluation
at the Chemical Waste Management Incorporated (CWM) facility (EPA I.D. No.
ALD000622464) at Emelle, Alabama (Figure 1) .   The inspection was coordinated
by US-EPA Region IV Environmental Services Division (ESD) and consisted of
personnel from ESD as well as US-EPA Headquarters,  the US-EPA Region IV


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Residuals Management Branch, the Alabama Department of Environmental
Management (ADEM),  and GCA Corporation, who was the sampling contractor for
this evaluation.  In general the inspection involved review of state, federal,
and facility records, facility inspection, laboratory evaluation and ground-
water and landfill leachate sampling and analyses.

BACKGROUND

     Based primarily on geological criteria, a group of investors, known as
Resource Industries of Alabama (RIA) acquired a tract of land which would
become the Chemical Waste Management, Inc. facility at Emelle, Alabama. Under
the authority of the Alabama Solid Waste Disposal Act No. 771, Regular
Session, 1969, the Director of the Division of Solid Waste and Vector Control
(Environmental Health Administration) issued a permit to RIA for construction
and operation of a hazardous waste disposal facility on May 4, 1977.
Permitted waste types were solids and liquids categorized as potentially
hazardous or toxic, except radioactive wastes and normal domestic and
commercial waste.  After meeting the conditions of the permit, RIA was given
final approval for operation of a landfill on August 24, 1977.  Immediately
thereafter, the site began receiving waste.

     Effective February 23, 1978, the RIA site was repermitted as Waste
Management of Alabama, a subsidiary of Waste Management, Inc.  They then filed
a formal application with US-EPA dated March 10, 1978, for a landfill disposal
permit for polychlorinated biphenyls (PCBs).  This application was approved
and accordingly issued by US-EPA on June 28, 1978, and modified in October, 1979
to allow disposal of liquid PCBs.

     Hazardous waste permit responsibilities reverted to US-EPA on November 19,
1980 when federal regulations under the Resource Conservation and Recovery Act
of 1976 became effective.  On November 14, 1980, Chemical Waste Management Inc.
obtained Interim Status under ilCRA by filing a complete Part A application form
prior to November 19, 1980.

     US-EPA Region IV requested the Emelle facility's Part B application on
February 8, 1983.   In response, Chemical Waste Management made their original
submission on September 9, 1983, and final revisions were accomplished in August
1986.  The application was deemed complete in July, 1986, and at the time of the
Task Force evaluation, a draft permit was on public notice.

SUMMARY OF SIGNIFICANT COMPLIANCE ACTIONS

     The following is a list of administrative orders and consent agreements,
as well as significant actions related to interim status landfill closure, the
Hazardous Waste Ground-Water Task Force inspection, permitting, and ground-
water monitoring at the facility.  This summary was prepared by ADEM Jtaff.

Administrative Orders/Consent Agreements

March 1983 - (#002-LP) Pertaining to leachate collection in Trench 17

December 1984 - (TSCA #84-H-03) Pertaining to PCB storage greater than one year

December 1985 - (#86-02-HW) Pertaining to an August 1985 spill


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February 1986 - (#86-19-R) Pertaining to LOIS action on Truck Wash Impoundment

July 1987 - (#87-054-HW) Pertaining to waste analysis

Interim Status Closure of Landfill

September 1984 - CWM submits closure plan for Trenches 8 through 18 and 20

February 1986 - EPA/ADEM approve closure plan for Trenches 8 through 18 and 20

April 1986 through March 1987 - CWM conducts closure of Trenches 8 through 18
and 20

May 1987 - CWM certifies closure of Trenches 8 - 18 and 20


Hazardous Waste Ground-Water Task Force

September 1986 - HWGWTF conducts evaluation at the Emelle, Alabama CWM facility


Permitting

May 1977 - RIA Solid Waste Disposal Site permit issued

August 1977 - RIA Solid Waste Disposal Site permit effective

February 1978 - WMI of Alabama acquires RIA

June 1978 - WMI of Alabama obtains PCB disposal permit

November 1980 - CWM files for interim status at Emelle facility

February 1983 - Part B called for CWM, Emelle facility

September 1983 - CWM Emelle submits initial Part B application

September 1985 - CWM Emelle submits second Part B application

July 1986 - CWM Emelle facility Part B deemed complete

September 1986 - Draft Permit issued for CWM Emelle

September through December 1986 - Draft permit comment period

November 1986 - Public hearing on draft permit

May 1987 - EPA RCRA permit issued

Pending - ADEM RCRA permit
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Ground-Water Monitoring

1960 through 1978 - Wells 1 through 4 are established

November 1982 - CWM proposes addition of well 5

January 1983 - Well 5 is installed

April 1983 - CWM proposes wells 6, 7, and 8

Spring 1983 - Wells 6, 7, and 8 are installed

June 1984 - ADEM requests a ground-water assessment plan

June 1984 - CWM submits a ground-water assessment plan for wells 1 through 8

January 1985 - CWM submits ground-water monitoring waiver request to EPA

August 1985 - Ground-water assessment is concluded

August 1985 - ADEM approves results of ground-water assessment

September 1985 - EPA approves results of ground-water assessment

Winter 1985/86 - CWM installs shallow (Consent Agreement) monitoring wells

February 1986 - CWM plugs wells 2 and 3

April 1986 - First Quarterly sampling of shallow wells

April 1986 - Begin assessment of 1,1-dichloroethane in well SM-5

October 1986 - Conclude assessment of 1,1-dichloroethane in well SM-5



SUMMARY OF FINDINGS AND CONCLUSIONS

COMPLIANCE WITH THE INTERIM STATUS STANDARDS (40 CFR PART 265, SUBPART F)

     The Task Force investigated the interim status ground-water monitoring
program implemented by CWM at the Emelle, Alabama facility.  The consensus
opinion of the Task Force is that the program, with the exceptions and
inadequacies noted below, substantively complies with the standards at 40 CFR
Part 265, Subpart F and the State's counterpart regulations, Rule 335-14-6-.06,
ADEM Administrative Code of Rules.

     This investigation revealed that a hydrogeological characterization of the
site had been prepared which is very thorough and generally adequate with
respect to the applicable standards, although additional work is recommended to
describe in further detail shallow ground-water flow patterns in the chalk.

     This investigation also revealed that there are currently three ground-
water monitoring systems in operation at the facility, two RCRA systems and one
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TSCA system.  Pursuant to the 1984 consent agreement CWM;   1) installed a
system of shallow ground-water monitoring wells in the chalk along the
periphery of the interim status disposal trenches;  2) conducted a workover
re-screening of Eutaw Well 5 to provide a screened interval consistent with
the other wells in the Eutaw; and  3) produced a ground-water monitoring
waiver demonstration consistent with the requirements at 40 CFR Part
265.90(c).  The wells comprising the interim status RCRA ground-water
monitoring system do not comply, with respect to the adequacy of their numbers
nor their locations relative to waste management areas, to the standards
described at 40 CFR Part 265.91.

     Several inadequacies were noted regarding the ground-water sampling and
analysis plan used by CWM.  Although these problems are not necessarily
regulatory deficiencies, they involve sampling practices which need to be
changed to improve their program.

     Sampling of the RCRA and Consent Agreement ground-water monitoring
systems have on two different occasions indicated the presence of hazardous
waste or hazardous constituents in ground water.  Thorough assessments,
conducted by CWM, and overseen by ADEM and EPA, indicated that the sources of
these compounds were related to well construction and were not the result of
operations at the facility.

     The investigation included audits of the on-site and off-site labora-
tories.  Problems were identified with sample filtration,  field preservation
QC procedures, exceeded holding times for extractable and volatile organic
samples at the off-site laboratory, analytical methods with higher than
acceptable detection limits, improper phenol analyses, and out-of-date sample
preservation and holding times in the WMI Manual for Ground Water Sampling.

     Ground-water samples from the deep RCRA wells indicated that operations at
the facility have not affected the Eutaw formation. Samples from the shallow,
chalk wells indicate the possibility that some migration from the trenches
through near surface fracture networks may be occurring.  Additional work will
have to be done to resolve this issue.

     The following is a more detailed summary of the inspection findings and
conclusions.

Hydrogeological Characterization - 40 CFR Part 265.91

     The hydrogeological characterization submitted by CWM for in support of
its ground-water monitoring system is generally adequate.   It describes the
Selma Chalk and underlying Eutaw Formation (the uppermost aquifer) in
sufficient detail to support the design and, with respect to ground-water flow
direction, the location of the facility's  RCRA monitoring wells.

     Even though the chalk is not considered an aquifer, it is, because of its
saturated condition throughout much of its thickness, considered a hydrogeo-
logically significant unit at the site.  The characterization, while adequate
for the Eutaw well system, does not define ground-water flow patterns in the
saturated chalk in sufficient detail to fully support the well construction
criteria used in developing the system of shallow wells around the perimeter
of the interim status and permitted landfill trenches.  Lacking detailed
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information of this type to aid in screen location and depth determinations,
the chalk wells were installed at a depth of twenty-five feet below the base
of the adjacent trench, as specified by the Agency.

     Since these wells are being used in lieu of the Eutaw wells, more detailed
flow information, i.e., detailed flow nets, needs to be developed to define the
optimum screened interval for wells located at each trench.  If detailed flow
nets for any existing areas indicate improper screening, new wells should be
installed which are appropriately screened.

Monitoring System - 40 CFR Part 265.91

     The RCRA interim status ground-water monitoring system has evolved since
the effective date of the referenced regulations (November 19, 1981).  The
original system did not consist of any wells which were installed specifically
as ground-water monitoring wells.  All wells were water supply wells and
construction details are unknown for three of the four wells.  In November,
1982, a new well, Well 5, was installed in the Eutaw Formation and later, in
April, 1983, after new information indicated that ground-water flow in the
Eutaw was in a different direction than suspected, additional wells, Wells 6,
7, and 8, were installed.  This resulted in a completely different system than
originally implemented.  Well 8 was designated the upgradient well and Wells
5, 6, and 7 were designated the downgradient wells.  After it was determined
that Well 5 was screened lower than the other wells, it was reworked,
relegated to use as a piezometer, and was replaced in the system by a new
well, Well 9.  All wells are four-inch carbon steel casing, with two-inch
diameter stainless steel screen.  The annular space in each well was sealed
with a low shrink cement grout and protective covers were installed at the
surface.  The construction of these wells is acceptable.

     The number of wells and their location, do not meet the "immediate
detection" standard for a detection monitoring system.  However, Region IV EPA
and ADEM have long been concerned with installing any wells that penetrate the
Eutaw Formation in the immediate area of the trenches.  This issue was
addressed as a result of the December 1984 Consent Agreement, which, in part,
resulted in the installation of the shallow, chalk ground-water monitoring
system.

Inadequate Sampling and Analysis Plan (SAP) - 40 CFR Part 265.92

     Although the SAP used by CWM is acceptable with respect to several major
areas (i.e., sample preservation and shipment, analytical procedures, and
chain-of-custody control), one area, sample collection, was found to be
inadequate or in need of improvement, with regard to several procedures used
during sampling activities.

1.  CWM filters all samples except for those collected for purgeable organic
(VGA) and total organic halogen (TOX) analyses.  The only condition under
which filtration is normally acceptable is when samples are excessively
turbid, and then only the metals samples should be filtered.  Occasionally,
turbidity will interfere with the equipment used for some organic analyses and
filtration, usually in the laboratory, can be performed to mitigate the
problem.  CWM should modify their SAP to specify that filtration will only be
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performed under approved conditions,  such as those described in this
paragraph.

2.  CWM should verify with the laboratory providing radiological analytical
services that the one liter samples are adequate for the analyses being
performed,  if indeed, these analyses  are still part of the monitoring program.
EPA guidance indicates that one liter is not enough for the extremely low
levels expected.

3.  CWM personnel do not wear gloves during sampling.  While this is not a
regulatory deficiency, gloves, such as latex or vinyl physician's examination
gloves (preferably without powder), have been proven effective in preventing
cross-contamination of samples during handling.  Although washing hands with
distilled or de-ionized water may provide short term protection, gloves,
particularly when changed frequently, offer added assurance that perspiration,
etc., does not carry contamination to the hands then to the sample.  EPA
strongly recommends that the CWM SAP  be modified to include the use of gloves
when sampling.

Ground-Water Quality Assessment - 40  CFR Part 265.93

     After the first semi-annual sampling occurred for the original system
(Wells 1-4) in May, 1983, there was a significant difference in the indicator
parameter data from these wells.  However, instead of submitting an assessment
plan and, subsequently, conducting an assessment, CWM officials attributed the
difference to lack of quality control in sampling procedures.   Also, because
of the general lack of construction information for Wells 1, 3, and 4, it is
not valid to statistically compare data from these wells.

     Partly because of the problems noted in the previous paragraph, the new
system (Wells 5-8) was installed.  The first semi-annual samples from this
syste»n (as well as the old one) occurred in July, 1984.  Once again, a
significant difference, in pH and specific conductance, was noted at Well 4.
This time,  CWM officials questioned the validity and appropriateness of the
required statistical test and concluded that the "hits" were false positives.
ADEM responded by requiring CWM to conduct Appendix VIII analyses on all wells
in the old and new systems.

     After negotiating an acceptable  analytical protocol, this assessment
began.  It consisted of an iterative  series of events which identified several
problems with well installations and sampling procedures.  The result,
confirmed by EPA and ADEM joint participation, was that no hazardous waste
constituents had migrated to the Eutaw as a result of operations at the
facility.

Laboratory Evaluation

     Both the on-site laboratory/field analytical and off-site laboratory
capabilities were evaluated for this  report.  The on-site capabilities were
reviewed while on site. The off-site  laboratory was audited by NEIC
and Region V EPA during a previous Task Force evaluation.  The findings of the
audit are summarized below.
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1.  Procedures for obtaining field measurements (calibration,  operation,
documentation, and reporting) were acceptable.

2.  CWM routinely filters all samples except for purgeable organic compounds,
total organic halogens (TOX), and field parameters.   This is inappropriate
(see discussion of the SAP).

3.  CWM does not verify that appropriate pH levels have been reached after
preserving samples.  They need to institute QC procedures for this.

4.  The laboratory does not routinely meet holding times for some
types of samples.  The paper work trail for three sampling events was pulled
during the audit.  In two out of the three events, the holding times for
extractable organics had been exceeded.  Holding times for volatile organic
samples were also exceeded on several occasions.

5.  The laboratory needs to implement analytical methods which have
lower detection limits for pesticides, PCB's, cadmium, chromium, and lead.

6.  The laboratory had not been readjusting the sample aliquot pH during
analyses for phenols.  All of these analyses are suspect.

7.  The sample preservation and holding times listed in the WMI Manual for
Ground-Water Sampling are out of date.

Monitoring Data Analysis

     Ground-water samples were collected from monitoring systems installed in
the Eutaw Formation and in the Selma Chalk.  The wells in the Eutaw Formation
constitute the RCRA interim status monitoring system.  The wells in the chalk
were installed as part of a consent agreement and as conditions of approval
for disposal of PCB's.

     Samples collected from the Eutaw wells contained no indication of
contamination by operations at the facility.  This can't be said with the same
degree of confidence for the samples collected from the Consent Agreement
wells.   Trace to low concentrations of purgeable organic compounds, arsenic,
cobalt, and selenium were detected in samples collected from chalk wells.
Although these compounds were detected in both deep and fracture chalk wells,
the abundance and concentrations of these compounds is greater in the fracture
wells,  indicating that fractures associated with certain trenches may be
active pathways for migration of leachate. The Task Force recommends that
additional sampling and geochemical studies of the chalk and chalk ground
water,  and a detailed review of all data from these wells be conducted to
resolve this issue.

COMPLIANCE WITH 40 CFR PART 270 AND POTENTIAL COMPLIANCE WITH 40 CFR PART 264

     Upon issuance of the Part 264 permit, Region IV EPA will no longer
require CWM to monitor ground-water quality of the Eutaw formation.  This will
be accomplished via a waiver from the ground-water monitoring requirements at
40 CFR Part 264.  In lieu of a Part 264 monitoring program, the facility will
be required to monitor the wells installed in response to the December 1984
Consent Agreement.  The permit will specify the elements of this monitoring


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program, i.e., the parameters, frequencies, permit maximum concentration
limits, and specific sampling and analytical do's and don'ts.

     CWM Emelle is in substantive compliance with the applicable standards and
requirements at 40 CFR Part 270.14 (c).   Some additional work, as previously
described (see Summary of Findings and Conclusions, Compliance with Interim
Status Standards, Hydrogeological Characterization) is needed to fine-tune the
understanding of flow in the shallow saturated chalk, particularly with
respect to flow in fractures.


TASK FORCE RECOMMENDATIONS

     Based on the above findings and conclusions, the Task Force has the
following recommendations.  In making these recommendations,  the Task Force
understands that the RCRA permit will already have been issued by Region IV.
As such, some issues prompting those recommendations may have been resolved.
Where they have not, certain limitations may exist with respect to mechanisms
for obtaining additional information, etc.

     1.  CWM should more fully characterize the hydrogeology and geochemistry
of the site with respect to permeability and flow in the shallow chalk ground-
water system.  This characterization should include detailed flow nets through
the portion of the site currently monitored using the Consent Agreement well
system.  These flow nets should be of sufficient number and orientation to
provide the information needed to determine the appropriateness of the
screened intervals at each of the Consent Agreement wells or well clusters.

     2.  A part of this characterization should also include an evaluation of
recharge in the chalk wells.  This evaluation should attempt, where the
information is available, to evaluate differences in recharge rates with
respect to the presence or absence of fractures.

     3.  Because wells in the chalk recover so slowly, there is some doubt
regarding true static water levels in the chalk.   The Task Force recommends that
several dedicated piezometers be installed across the site to be used strictly
for obtaining water levels for the chalk water table so that accurate
potentiometric maps for this surface can be established.

     4.  The Task Force also recommends that CWM use water from existing on-
site wells which are completed in the Eutaw for construction of any future
ground-water monitoring wells at the facility.  This should prevent any
problems, such as those experienced with using the Livingston city water
supply, in the future.

     5.  To aid in identifying when a monitoring well is ready to sample,
i.e., when adequate water has recovered after evacuation to make up the
sample, the Task Force suggests that CWM establish recovery times for
individual wells.  After each sampling event, for at least several quarters,
the wells should be evacuated to dryness after samples are collected.  The
recovery of the wells should be monitored to determine how long it takes for a
full sample volume to recover.  This information is necessary, given the large
number of wells to be sampled and their generally slow recovery times, to
create a sampling schedule which would increase the likelihood that wells do
                                    -9-

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not await sampling an inordinate amount of time after recovery, jeopardizing
the integrity of samples collected for purgeable organic analyses.   Wells
which are determined to have extremely long recovery times may have to be
sampled in stages, so that the samples collected for purgeable organic
analyses do not remain in the well long enough to allow outgassing of these
compounds, if they are present.

     6.   The Task Force recommends that CWM Emelle amend its ground water
sampling and analysis plan.  Specifically two items need to be addressed.  The
most critical item is that of sample filtering.  CWM should avoid filtering
any samples.   The plan should provide only for filtering metals samples,  only
when samples are extremely turbid.  No samples collected for organic analyses
should be filtered.  The other item is the use of gloves.  We recommend that
CWM require their personnel wear disposable gloves, such as physician's
examination gloves, whenever sampling.

     7.   The Task Force recommends that, using existing local and regional
geological publications, as well as logs of boring investigations,  the
feasibility of using the Arcola Limestone as a zone to monitor for vertical
migration of contaminants in the chalk be evaluated.
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(sPL
          INVESTIGATION METHODS

               The  Task Force  investigation of the  CWM Emelle,  Alabama,  facility
          consisted of:

               o Reviewing and  evaluating records  and documents  from EPA Region IV,
                 the Alabama  Department of Environmental  Management  (ADEM)  and CWM

               o Conducting an  on-site facility inspection September 15-25,  1986;

               o Evaluating on-site and off-site analytical laboratories;

               o Sampling and analyzing data from  selected ground-water monitoring
                 wells and leachate collection sumps.

          Records/Documents Review

               Records and documents from EPA Region IV and the ADEM  offices,  compiled
          by PRC, an EPA contractor, were reviewed  prior to and during the on-site
          inspection. Additional ADEM records were  copied  and reviewed by Task Force
          personnel concurrently with the on-site inspection.   On-site facility records
          were reviewed to verify information currently in Government files  and
          supplement Government  information where necessary.  Records were reviewed to
          obtain information on  facility operations, construction details of waste
          management units, and  the ground-water monitoring program.

                Specific documents and records that were reviewed included the ground-
          water sampling and analysis plan(s),  outline of  the facility ground-water
          quality assessment program, analytical results from past ground-water
          sampling, monitoring well construction data  and  logs, site  geologic reports,
          site operations plans, facility permits,  waste management unit design and
          operation reports, selected personnel position descriptions and qualifications
          (those related to the  required ground-water  monitoring  program) and operating
          records showing the  general types,  quantities and locations of wastes disposed
          of at the facility.

          Facility  Inspection

               The  facility inspection conducted in September,  1986 included identifying
          waste management units (past and present), waste management operations,  and
          verifying the location of ground-water monitoring wells and leachate collection
          sumps.

               Company representatives were interviewed to identify records  and documents
          of interest, discuss the contents of the  documents,  and explain (1)  facility
          operations (past and present), (2)  site hydrogeology,  (3) the ground-water
          monitoring system, (4) the ground-water sampling and analysis plan,  and (5)
          laboratory procedures  for obtaining data  on  ground-water quality.   (Because
          ground-water samples were analyzed by off-site laboratories,  personnel from
          these facilities were  also interviewed regarding sample handling,  analysis  and
          document  control.
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Laboratory Evaluation

     The on-site and off-site laboratory facilities handling ground-water
samples were evaluated regarding their respective responsibilities under the
CWM ground-water sampling and analysis plan.   Analytical equipment and
methods, quality assurance procedures and records were examined for adequacy.
Laboratory records were inspected for completeness, accuracy and compliance
with State and Federal requirements.  The ability of each laboratory to
produce quality data for the required analyses was also evaluated.


Ground-Water and Leachate Sampling and Analysis

     During the inspection, Task Force personnel collected samples for
analysis from sixteen ground-water monitoring wells and two leachate
collection sumps.  Table 1 contains a summary of sampling data including date
sampled, location of the well or sump, and a list of the sample bottles
submitted for analyses at each well or sump.   The field data sheets for each
station, completed by GCA, are found in Appendix A.  The wells that were
selected are a mix of deep RCRA Eutaw Formation monitoring wells and shallow
TSCA and Consent Agreement chalk monitoring wells.  Several of the shallow,
chalk wells were selected for sampling based on data from recent sampling
which indicated the presence, at low levels,  of several purgeable organic
compounds.  Additional wells were selected which would provide up- and
downgradient water quality in the Selma chalk surrounding and within the past
and current landfill areas. Leachate sumps were selected to provide leachate
data from both an older and a more recent trench.  CWM was offered and
accepted sequential duplicate splits of all ground-water samples, declining
the offer for leachate sample splits.

Ground-Water Sampling

     The shallow wells are equipped with dedicated Well Wizard R bladder
pumps.  The deep wells are equipped with a double pump system consisting of an
upper, high rate pump (Grunfos R ) for purging and a Well Wizard R for
sampling.

     At each well CWM personnel operated the control equipment and GCA
personnel collected the samples.  The following protocol describes the
procedures used at each well:

     1.  CWM determined the depth to water in each well. GCA concurrently
performed well head air monitoring (i.e., Hnu, geiger counter).

     2.  Using the measured water level and recorded total depths for each
well, Task Force personnel calculated three water column volumes for each
well.  Total depths could not be verified because of the close fit of the
pumps in the shallow wells and because the depth of the deep wells exceeded
the capability of all available measuring devices.

     3.  The pumps were activated.  The shallow, chalk wells were quickly
evacuated to "dryness" (water level at pump intake).  The deep wells were
purged a minimum of three water column volumes.  Field measurements of in-situ
parameters were periodically recorded during purging at the deep wells to


                                    -12-

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monitor purge adequacy.  At the shallow wells, single sets of these
measurements were recorded during sampling as measurements of record for the
well.

     4.  The deep wells were sampled immediately after purging.  The shallow
wells were not sampled for several days because of the slow rate of recovery
for these wells.  This waiting period exceeds the 24 hour maximum waiting
period recommended in the HWGWTF Protocol.  However, because of the
relatively large volumes of water required for the minimum two-way split for
all parameters and the known slow recovery times for the chalk wells, a
decision was made to evacuate the wells on a schedule that would allow a one-
time visit for sampling at each well during the first several days of the
second week of the evaluation.  To have broken down the sampling into several
periods of recovery and sampling could potentially have resulted in numerous
logistical problems with regard to all of the required paper work, sample
tracking, and shipping.

     One concern raised during discussions about this approach was the effect
of the waiting period on the detectability of any purgeable organic compounds
that might be present.  Because water moves through the screen and up the
casing in these wells during recovery, the freshest water is always at the
screen, which is where pump intakes are located.  Assuming, based on facility
records, that the wells had either just finished or had recently, i.e. within
24 hours, finished recovery, the first sample collected could potentially meet
the less than 24 hour requirement in the HWGWTF Protocol.

     5.  GCA collected all sample sets.

     6.  Samples were placed on ice in coolers immediately after they were
collected.

     7.  Samples were transported back to the GCA truck where turbidity was
measured and appropriate samples were preserved (Table 2).

     8.  Sample splits were transferred to CWM.

Leachate Sampling -

     1. GCA and CWM personnel donned Level B protection while collecting
leachate samples.

     2. All samples were bailed from the sump using CWM's dedicated PVC
bailers.

     3. Samples were transferred directly from the bailer to the sample
bottles, which were placed on ice.

     4. Samples were transferred to the GCA truck for processing.


     At the end of the day, samples were packaged for shipment to the two EPA
contract laboratories and the ESD laboratory in accordance with applicable
Department of Transportation (DOT) regulations (40 CFR Parts 171-177).  Aqueous
samples from monitoring wells were considered "environmental" and those from


                                    -13-

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leachate collection system sumps were considered "hazardous" for shipping
purpose.  In no case were samples held beyond the following afternoon's Federal
Express pickup.

     Each day of sampling, the EPA contractor prepared field blanks for each
analytical parameter group (e.g., volatiles,  organics,  metals)  in an area near
the days sampling events by pouring J. T.  Baker  HPLC (High Performance Liquid
Chromatography) water into sample containers.  Equipment blanks were not
needed since no equipment beyond that dedicated at the wells was used.   One
set of trip blanks for each parameter group was also prepared and submitted
during the inspection.  The blanks were submitted with no distinguishing
labeling or markings.

     Samples were analyzed by the EPA contractor laboratories for the parameter
groups shown in Appendix B.
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WASTE MANAGEMENT UNITS AND OPERATIONS/WASTE CHARACTERISTICS AND TRACKING
Primary Waste Management Processes

     The Emelle facility employs a minimum of eight waste handling processes
and utilizes numerous regulated units in the course of treating, storing and
disposing of hazardous wastes.  Separate processes and units are used for PCS
management with the notable exception of commingling of PCB waste and
hazardous wastes in the landfill trenches, where approved.

     Listed below by US-EPA handling code are the primary processes employed
and a brief description of each process.  This is followed by a discussion of
other waste management processes or units which are not directly regulated
activities.   The locations of these waste process areas can be found on Figure
2 for all areas except landfill trenches.   The trench locations can be found
on Figure 8.

     Storage in containers (SOI) - Container storage of hazardous waste
is permitted in Buildings 700, 702, and 604.  PCB's are stored in containers
in Building 604 and 600.

Storage in tanks (S02) - Tank storage of hazardous wastes is permitted in the
decant tank farm adjacent to Building 700, the stabilization tanks adjacent to
Building 1100, the leachate tanks associated with the synthetically lined
trenches 19 and 21, solvent storage tanks associated with PCB transformer
flushing, and the solvent recovery tanks adjacent to the thin film evaporator.
Tank storage of PCB's is allowed in Tank Farm #1, Tank Farm #2, and formerly in
Buildings 602, 603, and 604.

Storage in surface impoundments (S04) - Hazardous wastes are stored in two
separate impoundments designated as Lagoon 3 and the Truckwash impoundment.
Lagoon 3 is excavated into the native chalk with a recompacted chalk dike above
grade.  This impoundment stores and neutralizes inorganic acids and bases.  The
Truckwash impoundment stores rinsate collected primarily from the tire washing
of waste hauling vehicles which entered the active trench.  Storage occurs
prior to solidification and landfilling.

Solidification/Stabilization (T21) - Bulk liquids with an organic content of
less than 10% are stabilized in either the liquids stabilization unit
(Building 1100) or the semi-solids stabilization unit (Building 1200) using
cement kiln dust.

Neutralization (T31) - Inorganic acids and bases are neutralized in Lagoon 3
under controlled conditions.

Decanting (T38) - In association with container storage in Buildings 700 and
702, liquids are decanted out of and into containers to facilitate
solidification of free-standing liquids and elimination of void spaces in
containers prior to landfilling.
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Landfilling (D81) - The final disposition of the majority of the waste stored
or treated at the facility is landfilling. This applies to hazardous wastes
and PCB wastes which are not subject to any regulatory bans (i.e., liquids in
landfills, PCB's greater than 500 ppm,  etc.).   A notable exception to this
generality is the solvent-type wastes which are suitable for the fuels program
discussed below.  The historical and present landfilling operations are
discussed more fully later in this section.

Other waste processes/units which are not directly regulated - Numerous site
related support buildings exist on the facility which are not regulated units.
Examples are the heavy equipment repair shop and office building.  Other
processes exist which are not hazardous waste treatment, storage or disposal
processes but are part of the waste management scheme at the facility.  They
include solvent recovery, fuels blending for off-site burning, solidification
in  containers through the use of absorbents,  and draining and flushing of PCB
containing transformers.


 Background and Past Landfilling Activity

     This section reviews landfill disposal practices at the CWM Emelle
facility for trenches 1 through 20.  These practices are no longer in use at
the Emelle facility and are described here only to present a comprehensive
review of the history of landfill operations at the facility.

     At the time of the Task Force evaluation, the facility was operating in
Trench 21 and had previously filled twenty-one other trenches.  A list of these
trenches, their number designations, and sizes are provided in Table 3.

     Six of these trenches, referred to collectively as the Old Study Area,
and Trenches 8 and 9,  were operated before November 19, 1980, and are not
considered to be land disposal units subject to interim status standards.  The
other 14 trenches--trenches T-10 through T-21--received hazardous wastes after
November 19, 1980.  Trenches T-10 through T--20 are considered to be interim
status land disposal units subject to the applicable requirements of 40 CFR
Part 265 and are equipped with leachate collection and removal systems, and
have been or are being closed.

Current and Proposed Landfilling Practices

     This section describes both the types of waste disposed at the facility
and the method that CWM is currently using and will be using in the future,
for the landfill disposal of wastes at the facility.  This method employs
double-lined landfill cells as opposed to the deep, unlined trenches used in
the past.

Types and Quantities of Wastes

     Many types of industrial and site clean-up wastes, including virtually all
listed hazardous wastes from 40 CFR Part 261,  are landfilled at the facility.
Table 4 presents a list of the major waste codes disposed in the landfill.  The
following exceptions are the only wastes which are not landfilled:
                                    -16-

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     1.   Radioactive wastes;

     2.   Extremely hazardous  wastes (as determined by the General Manager);

     3.   Infectious wastes;  and

     4.   Reactive wastes.

     In 1985, approximately 350,375 tons of hazardous wastes were landfilled
at the facility.  It is expected that the quantity of hazardous wastes
received and landfilled will  increase to 598,000 tons per year in the future.
The quantity of wastes actually landfilled is larger because some wastes are
stabilized (which doubles the volume of waste),  and because residues from
treated wastes are also landfilled.  The landfill designs for Trenches 22, 23,
and 24 developed for the 10-year permit allow for disposal of 16,000,000 cubic
yards over 10 years.  This does not include the  capacity of Trench 21.

     The chemical properties  of the wastes landfilled at the facility vary
considerably.  These properties are determined by pre-acceptance and incoming
load analyses before disposal,  and a record thereof is maintained in the
facility operating record.  In particular, those chemical properties critical
to the proper landfilling of wastes are determined.  The chemical properties
of wastes landfilled at the facility are limited as follows:

     1.   They are nonreactive with respect to the definition of reactive in 40
CFR Part 261.23.

     2.   All wastes disposed in the landfill are compatible, or are made
compatible by stabilization,  with respect to Appendix V of 40 CFR Part 264.

     With respect to the physical properties, all of the wastes landfilled
at the facility are solid materials.  Liquid wastes and wastes containing free-
liquids are stabilized with kiln dust prior to being landfilled. (1)

Landfill Cell Design

     Landfill cells are laid out in continuous trenches, each cell measuring
from 500 to 800 feet by 800 to 1,100 feet at the ground surface.  Appendix C
contains design drawings depicting this construction, as described further.  As
currently planned, each cell  will have side slopes of 2.5 horizontal:! vertical
on three sides, and a low berm (about 10 to 20 feet high) on the fourth side.
Cell construction within any trench will be phased such that as waste is
disposed in one cell, the adjacent cell is being excavated, lined, and prepared
for waste placement.  Thus,  as each cell is filled and closed, another is ready
to receive wastes.  The progression continues until several cells in a trench
are filled, at which point final closure of the  cells is commenced.

     Each landfill will be lined with a composite double liner system
consisting, of a primary leachate collection and removal system, a top
membrane liner, a secondary leachate collection  system, and a bottom liner
consisting of a membrane liner and a low permeability soil liner. (1)
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Waste Characterization and Tracking

     Waste characterization before receipt at a TSDF and tracking after receipt
are required under both RCRA and State interim status regulations.  These are
important in determining the constituents that could potentially be released
from waste handling units.  To determine whether CWM, Emelle (1) sufficiently
characterizes waste it receives and (2) records the disposal location of these
wastes, a review of preacceptance and tracking records for twenty waste loads
was conducted.

     The twenty waste loads, from random dates, were selected from the
manifests kept on site.  These manifests represented different waste
categories, including bulk liquids, drummed liquids, bulk solids and drummed
solids.  Final selection was based on whether the wastes should have required
a detailed waste analysis during preacceptance testing.

     This records review indicates that tracking procedures used by CWM,
Emelle, are sufficient to identify hazardous waste constituents in the wastes
received.
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(sP
GEOLOGY/GROUND WATER

Stratigraphy

Geologic formations of interest include the Selma Group and the Eutaw
Formation. The CWM facility is located in the Selma Group of geologic
formations, which is subdivided geologically into the Prairie Bluff Chalk,
Ripley Formation, Demopolis Chalk, and the Mooreville Chalk. The Eutaw
Formation is stratigraphically below the Selma Group. These formations are of
the Cretaceous Period and deposition is thought to have occurred from
approximately 63 to 135 million years ago (2).

The CWM facility is developed in the Demopolis Chalk. This formation has
a thickness at the site ranging from 335 feet at the northern end to 500 feet
at the southern end (1). Monroe mapped two members of the Demopolis Chalk in
the Epes Quadrangle, an area located two miles east of the CWM facility. The
lower member consists of 270 feet of compact chalk described as blue-gray,
where fresh, and glaringly white where slightly weathered. This member was
described as being composed predominantly of finely divided particles of
calcium carbonate, as well as residual clay, very fine sand and silt, and
abundant pyrite concretions. Monroe also mapped within the lower member a
distinctive marker bed 8 inches thick containing abundant biotite flakes and
scattered pyroclastic minerals. This bed is believed to be volcanic ash
deposited with the chalk. (3)

The upper member of the Demopolis chalk, is a very clayey chalk at the
base and a calcareous sandy clay at the top. The base of the upper member is
conformable with the lower member, but an abrupt change occurs from massive
chalk in the lower to a clayey chalk in the upper member. Monroe stated "the
top of the upper member is sandy and grades imperceptibly into the overlying
Ripley Formation." The Mooreville Chalk lies below the Demopolis Chalk. The
Arcola Limestone member separates these two formations. The Arcola, in its
outcrop area, is a dense solutionized limestone. It ranges from 5 to 15 feet
in thickness and could possibly be used for a domestic water supply in the
area. The total thickness of the Selma Group at the site is about 650 feet.
(D(4)

The Eutaw Formation is approximately 400 feet in thickness and consists of
light gray to yellowish-brown fine to medium-grained glauconitic sand and light
gray to green micaceous laminated clay and shale. The upper part of the Eutaw
Formation is composed of a massive bed of very fine to medium grained
glauconitic sand containing fossil shells and local thin beds of light gray
glauconitic sandstone and sandy chalk. Thin to massive beds of fine- to
coarse-grained glauconitic sand interbedded with layers of light gray to gray
laminated slay and shale comprise the lower part of the Eutaw Formation. This
is mapped locally as the McShan Formation. Sand beds are thin or absent in the
middle of this formation. (5)

Structural Geology

The rocks mapped in the Epps Quandrangle strike generally north 60° west
and dip 30 feet to the mile to the southwest. Monroe mapped dips as steep as
5° in the Demopolis Chalk. These features were interpreted to be associated

-19-

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with minor normal faulting.  He indicated that this faulting, mapped in the
Epes Quanrangle, occurred after deposition of massive chalk on sands and clays
of the underlying formations.  Displacements of less than 10 feet to 30 feet
can be observed at Jones Bluff on the Tombigbee River at Epes.   At this
location the faults are separate, alternate blocks of chalk, and the fault
traces are commonly curved.

     A major zone of reverse faulting trending north 60° west was mapped by
Monroe (3) north of Livingston, Alabama.  The area having the largest
displacement is along a fault just south of the middle of Section 3, T.19N,
R.2W.  Monroe indicates that 90 feet of displacement occurs at this location.
He states further that this "belt" of faulting represents an anticline that
grew during deposition of the Ripley and later collapsed.  This resulted in
strata showing medium angle reverse faults, possibly accompanied at depth by
normal faults not observed in the surface.  Monroe also hypothesizes that this
structural feature could have been caused by salt bed flows.  Monroe further
indicates that faulting occurred after deposition and partial consolidation of
the Prairie Bluff Chalk.

     It should be noted that the discussion presented above is for the area
several miles east and southeast of the CWM facility.  It is important,
however, because fractures and joints having similar strike have been mapped
in the exposed trench highwalls and at surface outcroppings at the CWM
facility. These structures probably have similar origins.  They are also
ground-water migration pathways, as evidenced by observed low volume seepages
and wet spots in trenches at CWM.  As a part of their permit, ADEM is requiring
the mapping of all fracture and joint systems in the highwalls of new
trenches.  This will allow for the locating and drilling of chalk and fracture
monitoring wells if the leachate collection system fails.

Ground Water

     Ground water exists in the Selma Group as a zone of saturation, or a zone
where the chalk pore space is filled with ground water.  The water content in
of the chalk has been measured to be from 15% to 25%.  This formation cannot,
however, be classified as an aquifer because it lacks permeability or the
capacity for transmitting water.  The permeability of the Demopolis Chalk has
been measured to range from 1x10   cm/sec, to 1x10   cm./sec. (6).  The Selma
Group has therefore been recognized by the U. S. Geological Survey and the
Alabama Geological Survey as a confining unit and not an aquifer. (5) (7)

     There have been some reports of shallow dug wells in the chalk that are
used for residential supply (8).  Further evaluation of these wells was
conducted on January 27 and 28, 1987, by ADEM, EPA, and USGS.  None of the
wells or cisterns identified were completed in the Demopolis Chalk Formation.
All were completed above the Demopolis, in the Prairie Bluff Formation, the
Ripley Formation or alluvium associated with terrace deposits.

     The most significant ground-water discharge from the chalk has been
associated with localized fractures and joint systems, some of which flow in
response to precipitation.  These fractures and joints are not developed
sufficiently to store the volumes of ground water necessary to be of use as a
supply.  These features could, however, provide pathways of migration from old
                                    -20-

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closed trenches.  These joints have therefore been cored and wells installed
to monitor these potential migration pathways.

     The Eutaw Formation contains interlayered sands, silts, and clays.  These
sediments contain ground water which is used for supply on many farms
surrounding the CWM facility.  The Eutaw Formation therefore is recognized by
the U. S. Geological Survey and the Geological Survey of Alabama as being an
aquifer (5) (7). Artesian conditions occur as a result of pressure within the
Eutaw Formation. The pressure is sufficient to cause ground water to rise
above the level at which it is encountered by a tightly cased well.  Ground
water does not always rise to or above the surface of the ground to cause a
flowing well.   Wells in the Bodka Creek floodplain, however, will flow if they
are open to the surface.

     At the CWM facility the water levels measured in the Eutaw monitoring
wells are below the level of the chalk saturated zone.   This results in a
vertical downward gradient.  As you move away from the CWM site toward Bodka
Creek, the ground-water gradient is vertical upward.  This is the result of a
decrease in topographic elevation and associated saturated zone elevation to
below the Eutaw Aquifer piezometric surface of approximately  140 feet mean
sea level.  This upward gradient also occurs in the Tombigbee River Valley.

     Additional information on the regional ground-water flow is documented by
Gardner (9) and, more recently, by Williams, et. al. (7).  Site ground-water
flow characterization is contained in the CWM Part B permit application, and a
recently completed report by Colder and Associates which used a computer model
to construct flow nets within the Selma Group.   Figure 3 and 4 show ground-
water elevations and associated contours at the CWM site. Figure 3 is a
saturated chalk potentiometric map and was constructed from data collected by
the EPA Ground-Water Task Force.  Data collected for this map included ground-
water levels in both the deep and fracture chalk wells.   Figure 4 is a
potentiometric map of the Eutaw Formation based on data collected by ADEM
during October, 1985.
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ADEQUACY OF HYDROGEOLOGICAL CHARACTERIZATION/GEOLOGIC AND GEOTECHNICAL
EVALUATION

     Since the site's inception as a waste disposal facility, several firms
have been employed by Chemical Waste Management and its predecessor companies
to evaluate various aspects of the geology and hydrogeology of the region and
site.  In April 1982, Colder Associates was retained by CWM as their
geotechnical consultant.  Among their primary duties was the preparation of
the hydrogeological characterization for the facility RCRA Part B.  This
material,  as well as supplementary information presented to the Task Force
during the inspection, represents the extent of hydrogeological data that had
been developed at the time of the evaluation.

     The hydrogeological characterization developed by Colder Associates
utilizes data and information presented in several major papers, as well as
reports detailing on-site geotechnical studies performed by themselves and
predecessor consultants.  The following is a summary of the contribution by
each source to the characterization.

Published Literature

     The characterization cites and utilizes portions of two publications,
"Water Availability and Geology of Sumter County, Alabama" by M. E. Davis,  et
al (5) and "Model of the Ground Water Flow System of the Gordo and Eutaw
Aquifers in West-Central Alabama" by R. A. Gardner (9).  The report by Davis,
et al, was useful in supplying general characteristics, including stratigraphy
and ground-water yield of the primary aquifer beneath the site, variation of
ground-water quality across the county and a generalized water budget for the
county.  The Gardner report includes an assessment of the manner in which the
Gordo and Eutaw aquifers react with one another, as well as with the overlying
Selma Chalk and surface water, it includes estimate of net precipitation
infiltration into the Selma chalk and presents a potentiometric surface for
the Eutaw aquifer in the vicinity of the site.

Previous Site Investigations

     Tuscaloosa Testing Laboratory (TTL) performed several site investigations
during 1977-1979.  These efforts included soil borings, monitoring wells and
laboratory tests on samples of Selma Chalk and resulted in the following
pertinent hydrogeological data:

     1. The numerous soil borings verified the existence of the Selma chalk
throughout the Emelle site and gave indications of the thickness of overburden.

     2. Water levels were observed in some of the boreholes after a period of
24 hours.   It was unclear whether these water levels were measuring a water
table in the underlying chalk or were due to perched water in the overburden.

     3. The hydraulic conductivity (coefficient of permeability) of recompacted
chalk is approximately 1.0x10   cm./sec.

     Following the work of TTL, Woodward-Clyde Consultants (WCC) was retained
during 1979-1980 to conduct studies to provide additional site specific data.


                                    -22-

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The conclusions of these studies incorporated into the hydrogeologic
characterization are:

     1. In the majority of packer permeability tests conducted in borings, no
measurable flow was observed.  In those tests where measurable flow was
observed, the reported values of hydraulic conductivity ranged from 5.5x10"
cm./sec. to 4x10"  cm./sec.

     2. Discontinuities observed near the surface of the Selma chalk and in
cores obtained by WCC have a hydraulic conductivity which is very low, and is
no higher than the massive chalk itself.


     3. Laboratory tests performed on undisturbed chalk cores and recompacted
samples of chalk cuttings produced a hydraulic conductivity of about 1.2x10"
cm./sec. for both materials.

     4. A lineament study located several linear features in the vicinity of
the Emelle site but backhoe excavation showed no joints or faults in the
chalk, indicating that the Livingston Fault Zone does not pass through the
Emelle site.

Colder Associates

     Colder Associates consolidated all the previous work, extracted the
pertinent data presented in the preceding paragraphs and conducted additional
field  investigations to verify previous data and generate additional
geotechnical data in the next area of trench development (60 acres south of
Trench 16).

     The additional work conducted by Colder Associates in 1982 consisted
specifically of the following:

     1. Verification that at least 500 feet of massive chalk occurs across the
entire site.

     2. Mapping of exposed faults, joints and other discontinuities in Trenches
15 and 16.

     3. A deep hole drilling program to evaluate the chalk south of Trench 16.

Adequacy of Hydrogeological Characterization

     The characterization as presented in the Part B and during the meeting
with Colder Associates appears to be generally adequate.  Most areas which are
of concern in designing a ground-water monitoring system or in developing a
site operations plan have been investigated and reported.

     One area in which additional work would be beneficial is in defining
vertical flow paths in the vicinity of the trenches.  Modeling performed to
define flow paths and interactions in and between the Selma Chalk and the
Eutaw formation indicate vertical downward flow in higher elevations where
saturated chalk levels have a greater elevation than the potentiometric level
of the Eutaw and vertical upward flow along major discharge areas, such as


                                    -23-

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Bodka Creek.  This is acceptable as a description of what is happening in a
general sense, however, in order to assure that screened intervals for current
and future chalk monitoring wells are properly located, flow nets must be
developed for the chalk monitoring system.  These flow nets should be
developed using data from appropriately screened piezometers.  Until this data
is generated and verifies the screened interval depth of the chalk wells,
there will always be some doubts as to their real usefulness.
                                    -24-

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GROUND-WATER MONITORING PRIOR TO AND DURING INTERIM STATUS

Pre-Interim Status

     Initially, ground-water monitoring at the Chemical Waste Management,
Inc., Emelle facility, was conducted under the conditions of an interim permit
based on the Alabama Solid Waste Disposal Act, 1969 (Title 22, Chapter 16,
Sections 346-351).  Under this permit, as issued in 1977 to Resource
Industries of Alabama, wells were to be placed around the perimeter of the
original site.  These wells were to be constructed to a depth of 30 feet below
the maximum depth of waste disposal trenches.   Solid waste permit conditions
required semi-annual sampling of these wells for the following constituents:

          COD                          volatile solids
          specific conductance         chlorinated
          acidity                      zinc
          total alkalinity             copper
          chlorides                    arsenic
          pH                           cadmium
          TOG                          chromium
          cyanide                      lead
          phenols                      mercury

     State files contain no additional information as to how or where these
wells were located or constructed.  Similarly, analytical data from these wells
is not available in State files.

     The Environmental Protection Agency, Region IV, issued TSCA approvals for
the site (now under the name of Waste Management of Alabama, Inc.) for PCB
solids, in June 1978, and PCB liquids in October 1979.  These approvals were
issued unaer the authority of 40 CFR Part 761.  A condition of this approval
was the location of shallow chalk wells located adjacent to each of the
trenches approved for PCB disposal.


Interim Status Ground-Water Monitoring

     As a land disposal facility, Chemical Waste Management, Inc. in Emelle
became subject to the 40 CFR Part 265, Subpart F ground-water monitoring
requirements on November 19, 1981.  CWM's initial interim status monitoring
system consisted of Wells 1, 2, 3, and 4 (see Figure 5).  Little information is
available on the construction, total depth, or screened intervals in these
wells.  CWM's Part B permit application summarizes the data on these wells as
follows:

Well 1     Located on private property east of the intersection of Highway 17
           and 116.  A free-flowing artesian well reportedly drilled 940 feet
           below land surface prior to October 1964.  Depth of screening and
           other construction details are unknown.
                                    -25-

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Well 2     Located east of office-laboratory building.  Drilled 1,085 feet
           below land surface during first quarter, 1978.  Well is cased with
           PVC pipe for upper 25 feet, with annular space sealed with cement.
           Well is uncased below 25 feet.

Well 3     Located approximately 3,700 feet south of the office building and
           west of Highway 17.  The well was reportedly drilled to a depth of
           670 feet below ground surface in 1960.  No record of construction
           is available.

Well 4     Located approximately 3,900 feet west of Well 3.  A free-flowing
           artesian well drilled approximately 700 feet below land surface in
           1960.  No record of construction is available.

     Based on Geological Survey of Alabama Map 158, flow in the Eutaw Aquifer
was assumed to be to the south-southwest.  Therefore, CWM designated Well 1 as
the upgradient well.  CWM began quarterly sampling of this system, in
accordance with 40 CFR Part 265.92,  in February 1982.  The first inspection
of the RCRA system was performed in June 1982, by representatives of the
Alabama Department .of Environmental Management (ADEM).  No violations of
Subpart F (or the state regulatory equivalent thereof) were found during the
inspection, however the inspection files note that CWM was performing a
hydrogeological evaluation of the site at that time.  An EPA inspection of the
facility conducted prior to the effective date of the Subpart F requirements
noted the presence of 23 monitoring wells (presumably those required by the
old solid waste disposal permit), but did not verify any violations of the
RCRA regulations in effect at that time.

     During a September 1982, facility inspection, ADEM inspectors tentatively
determined that Well 1 may not be hydraulically upgradient, and Wells 2 and 3
were of questionable construction.  Shortly thereafter, a meeting was held with
CWM representatives to discuss these findings, and in November 1982, CWrf
proposed installation of an additional RCRA monitoring well.  The proposed well
was located in the Eutaw Aquifer along the eastern property line.   This well
(designated as Well 5) was constructed under the supervision of Colder
Associates, geotechnical consultant to CWM.   Elevations taken from Well 5, when
compared to the elevations taken from Wells 1-4 during 1982, indicated that
Eutaw Aquifer flow in the vicinity of CWM was from west to east.

     Also, in November 1982, CWM requested and received a waiver from ADEM for
monitoring for coliform bacteria (as required by Part 265.93(b) (1)).

     Placement of Well 5 provided CWM with a ground-water monitoring system
consisting of one downgradient and four upgradient wells.  CWM proposed
additional wells (Wells 6, 7, and 8) in April 1983.  This new system resulted
in new Well 8 as an upgradient well, and Wells 5, 6, and 7 as downgradient
wells (see Figure 6).  ADEM requested at this time that CWM continue
monitoring Wells 1-4 while developing background quality data from Wells 5-8.

     The construction and completion details for Wells 5-8 are well docu-
mented.  The wells consist of four-inch diameter carbon steel casing (grouted
in place) and a two-inch diameter stainless steel well screen.  Originally,
each well (except Well 8, which is a free-flowing artesian well) was equipped
with a dedicated dual pump system consisting of Middleburg-type bladder pumps


                                    -26-

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with PVC casings and Teflon bladders.  Boring logs for the wells are presented
in CWM's original Part B permit application (September 1983).

     As a result of statistically significant differences in data from Wells
1-4, ADEM requested that CWM perform a ground-water quality assessment in
accordance with the State equivalent of Part 265.93.  As CWM accepts most of
the hazardous wastes identified in Part 261, and since the facility was
preparing a complete Part B application, it was determined that analysis of
Part 261 Appendix VIII constituents was required.  During preparations for
this sampling, several events occurred:


          1.  CWM, EPA, and ADEM decided that Wells 2 and 3 should be plugged
              upon completing the assessment.  Lack of information on
              construction details made these wells unacceptable as RCRA
              monitoring wells.

          2.  CWM completed the first statistical evaluation of data from
              Wells 5-8, and found statistically significant changes in
              indicator parameters using the Student's t-test.  Application
              of John Skinner's 11/30/83 "Guidance to EPA Regions on
              Student's t - test for Indicating Ground Water Contamination at
              Land Disposal Facilities" identified these as "false"
              positives.  It was agreed that the Appendix VIII analysis of
              data from these wells could be used to resolve this issue.

          3.  Evaluation of elevation data from all eight wells showed that
              the Eutaw aquifer has an extremely flat gradient.  Evaluation
              of Well 5 construction details showed that it was completed in
              a lower zone of the Eutaw aquifer than Wells 6-8.  CWM, EPA,
              and ADEM agreed that one (possibly two) additional wells were
              required, but that more studies were needed in order to properly
              locate any new RCRA wells.  A procedure for locating this well
              was agreed upon in a meeting between all parties on
              September 19, 1984.

     CWM conducted Appendix VIII sampling during November of 1984.   Very low
concentrations of certain compounds were detected.  As the results were
inconclusive, it was decided that the wells should be resampled.  ADEM and EPA
split samples with CWM during this phase of the assessment.  Four subsequent
sets of samples were taken, however, consistent data was not obtained.
Toluene and acetone were consistently detected, therefore efforts focused on
determining the source of these compounds in the wells.  A review of well
construction records revealed that acetone had been used to rinse cutting oil
from pipe threading.  The pipes had subsequently been steam cleaned, but
apparently this precaution did not remove all the acetone from the threading.
Samples of archived acetone from this operation were tested and found to
contain high levels of toluene.

     It was hypothesized that these compounds remained in the wells and were
detected after the wells had been purged using inadequate purging procedures.
This hypothesis was tested by replacing the pump system in Well 7 with a high
rate submersible pump.  Three well volumes were then removed using these pumps
                                    -27-

-------
placed at the top of the water column.  No toluene or acetone was detected in
the samples collected with a bailer after this purging procedure.

    The conclusion was that the CWM facility had not affected the Eutaw
aquifer.  However, as the result of the assessment, CWM replaced the pumping
systems in the RCRA wells with a high rate (10 gpm) submersible pump coupled
with a bladder-type sampling pump, both of which are constructed of stainless
steel with Teflon fittings.  CWM also modified its interim status monitoring
program to sample for chloroform, trichloroethylene, tetrachloroethylene,
toluene, chromium, and nickel, in addition to the parameters required under
Part 265.92.

     Upon completion of the assessment, CWM proceeded with plugging Wells 2,
3, and 4.  The facility ceased using Well 1 as a RCRA monitoring well.  CWM
proceeded with installation of a new well, Well 9, as agreed upon earlier.
Also, as required by the December 1984 consent agreement, Well 5 was recased
into the proper zone of the Eutaw aquifer.  It's sole use is for determination
of water level elevations.  The current Eutaw Formation monitoring system thus
consists of Wells 6, 7, 8, and 9 (Well 8 being the upgradient well)(see Figure
7).  Appendix D to this report contains pertinent construction details for
these wells.

     The numbers and locations of these wells do not meet the "immediate
detection" standard for RCRA detection monitoring systems.  However, it is
important to note, at this point, that the December 1984 consent agreement, in
part, required CWM to submit a demonstration for a waiver from the ground-
water monitoring requirements at 40 CFR Part 265, Subpart F.  This waiver
specifically applies to the Eutaw ground-water monitoring system.  Given the
unique site characteristics, which are the primary basis for the waiver
demonstration, the Task Force does not think it appropriate at this time to
require any additional monitoring effort in the Eutaw.

 Consent Agreement Wells

     CWM installed a series of "shallow" monitoring wells around Trenches 8-21
in late 1985 (see Figure 8), as required by a consent agreement between EPA
and CWM (please see discussion below).  The wells were located for the purpose
of verifying CWM's request in January 1985 for a waiver from Part 265.91(a).
Data from these wells was to be used to verify that the time for waste
constituents to travel from a RCRA disposal unit to the Eutaw Formation or the
nearest surface water would exceed 1,000 years.

     The shallow well system consists of two types of wells.  "Fracture" wells
are screened at intervals where fractures were detected during coring of the
well.  "Companion" wells are screened and completed deeper than the fracture
wells (25 feet below the bottom of the adjacent disposal trench).  These wells
are located 20- 50 feet from the edge of the adjacent landfill trench wall.
These wells are constructed of two-inch threaded PVC pipe, with screens
consisting of slotted PVC pipe.  Additional construction details are described
in the "Proposed Final Plan and Protocol for Consent Agreement Ground Water
Monitoring Program," April 1985 and are contained in Appendix E.  These wells
are monitored for specific parameters of concern as agreed upon in the
December 1984 Consent Agreement.
                                    -28-

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     Quarterly sampling of these wells began in April 1986.   Data from the
initial sampling event indicated the presence of chloroform in several wells,
but this was traced to the city water used for flushing the newly completed
wells.   A few wells contained very low concentrations of volatile organic
compounds, but further investigation was not conducted at that time due to the
low levels reported.

     The second quarterly sampling event detected 1,1-dichloroethane at very
low levels in one shallow well.  Resampling of the well indicated a detectable
amount of the compound was still present.  Further investigation was conducted
at the request of ADEM because:

     1.  The well in question, Well SMS, is located near one of the older
         trenches, therefore contamination would more likely be detected
         there (older trenches were built under less stringent construction
         guidelines.  Also, the trench adjacent to Well SMS had operated
         prior to January 1983 and therefore received free liquids, and the
         leachate from the trench was known to contain 1,1-dichloroethane);

     2.  The well data showed the presence of 1,1-dichloroethane during each
         sampling event at levels of 127, 75.6, and 41.2 ppb, respectively;
         and

     3.  Well SMS is screened across a fracture.  ADEM and EPA geologists
         feel that, should hazardous constituents escape from a trench, they
         would be likely to be detected along a fracture in the chalk, as the
         fracture may present a "path of least resistance".

     The investigation of Well SMS consisted initially of a resampling of the
well in August 1986.  The resampling detected 1,1-dichloroethane at a level of
30.6 ppb.  Four additional wells were then constructed around Well 5 in an
effort to relocate the fracture screened in Well 5 and to determine if a flow
path or rate of flow could be calculated between any of the wells and the
adjacent disposal trench.  Sampling of these "rate wells" did not detect the
presence of 1,1-dichloroethane.  Further, an examination of the data shows that
the concentration of the compound dropped in the well over time:

       Sampling Date - Well SMS         1.1-Dichloroethane fug/I)

                04/03/86                            127.0
                07/09/86                             75.6
                07/31/86                             41.2
                08/25/86                             30.6
                10/24/86                              5.5

     This data could indicate that the compound was introduced to the well
during construction, and that additional purging of the well has served to
eliminate this outside source of contamination.
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GROUND-WATER MONITORING UNDER 40 CFR PART 264

     Upon issuance of their Federal RCRA permit, CWM will no longer be
required to conduct monitoring of the Eutaw Formation as they have been under
interim status.  The State permit, however, will require CWM to continue to
monitor the Eutaw.  CWM submitted a waiver request in their Part B
demonstrating that there is virtually no potential for migration of hazardous
wastes or hazardous waste constituents to the Eutaw Formation (uppermost
aquifer) within the active life and 30 year closure and post-closure period.
The transit time through the Selma chalk was estimated by CWM to be 10,000
years.  Independent EPA estimates of transit time using conservative estimates
for equation variables were 330 years and 3,000 years for estimates using
Darcy's Equation and a 2-D solute transport model, respectively.  The very
conservative 330-year estimate is considerably longer than the end of the
post-closure period.

     CWM's Federal RCRA permit will require that the consent agreement
monitoring wells be monitored in lieu of the Eutaw wells to determine if there
is migration of hazardous waste constituents and confirm the rate of migration
should it be detected.  Under the permit, these wells will be monitored semi-
annually and will be evaluated for contamination using specific, objective
criteria.

     Each six months samples will be collected at each well and analyzed for 30
purgeable organic constituents and three metals --nickel, chromium, and arsenic.
A complete list of compounds is found in Appendix F.  A well will be considered
contaminated if any of the following criteria are met:

          Purgeable Organic Constituents

          -- 1 compound detected greater than 50 ug/1
          --2 compounds detected, each greater than 30 ug/1
          -- 3 compounds detected, each greater than 20 ug/1

          Metals

          -- Nickel, chromium, or arsenic detected greater than 30 ug/1
                                    -30-

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CWM GROUND-WATER SAMPLING AND ANALYSIS

     In order to evaluate the sample collection and handling procedure
utilized by CWM at the Emelle facility,  two documents - the Corporate Manual
for Ground Water Sampling and the CWM Emelle Site Specific Plan were reviewed.
In addition to the document review, a sampling overview of the CWM ground-
water sampling crew was conducted during October 14-15, 1986.

     In addition to the two previously mentioned plans, several other ground
water sampling plans were documented in the PRC information package developed
for this evaluation.  These include unidentified draft sample handling
procedures which may or may not have been used and several sampling plans which
were developed for non-routine sampling events, including the ground-water
quality assessment conducted in 1984 and 1985.

     Insofar as the historical and current RCRA ground-water monitoring
systems are concerned, there are three important technical aspects to consider
regarding sampling procedures and, subsequently, the degree of confidence with
which ground-water data developed from major modifications to the system can be
compared.  These are summarized below:

     1.  In addition to the fact that there was little or no construction
         information for the original system (Wells 1 - 4), there was
         significant variation in sampling methodology for samples collected
         at different wells in the system.  Well 1, for example, is a
         flowing stock supply well and was sampled directly from the
         discharge.  No purging was necessary.  Wells 2, 3, and 4 were
         sampled with bladder pumps.  Prior to sampling, the wells were purged
         three water column volumes or more, then sampled. Because of the slow
         pump rates and the great yield of the wells, there may have been
         little removal of water above the pumps, resulting in a sample
         comprised of mixed formation and stagnant water.

     2.  The current RCRA system (Wells 6-9) utilizes dual pump systems for
         purging and sampling.  This system has itself undergone modification,
         primarily during the assessment period.  Prior to the assessment, the
         purge and sample pumps were both low rate bladder pumps.   During an
         iterative program, developed from week to week in March and April of
         1985 and jointly developed with Region IV EPA and ADEM, it became
         clear that the wells were not being adequately purged.  The problem
         was similar to that previously discussed with the original system.
         The pumps were underrated for the yield of the wells, allowing
         stagnant water to remain in the upper portion of the casing (more or
         less above the purge pump). This stagnant water apparently mixed with
         formation water in the interval occupied by the sampling pump,
         contaminating the sample with acetone and toluene.  As described
         earlier in the report, following the assessment all pumps were
         removed from the wells, followed by complete purging with high rate
         pumps at the top of the water columns.  The dual pump system was then
         reinstalled with a higher rate purge pump above the sampling pump.
         During sampling, the purge pump remains on to prevent any movement
         downward of water to the sampling pump.
                                    -31-

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     3.   During discussions related to the assessment,  the question was raised
         regarding sample pumps and tubing purging procedures used prior to
         sample collection.  It appeared that volumes of water discharged from
         the sample pump and line prior to sample collection may have been
         inadequate, resulting in a situation where portions of some samples
         may have contained water that resided in the pumps or tubing for
         weeks or months.  Standard procedures used by CWM for purging the
         sample lines were revised to provide for adquate line purging.

     In light of these facts, it is not appropriate in the strictest technical
sense, to compare the historical data from the original wells and the data
from the current system.  This may even be said for all the data from the
current system, given the problems enumerated above.  Analyses for selected
hazardous consitituents conducted on samples collected from the current system
appear to indicate that the wells are not contaminated.  Follow-up sampling
after well remediation efforts and after a revision of sampling protocols have
resulted in the collection of samples that are not contaminated and are
representative of water quality in the Eutaw.

Current Sampling and Analysis Plan

     Given the preceding facts, it is appropriate to review the current
sampling and analytical methodology.  The comments below reflect a review of
the corporate and site-specific procedures and observations of sampling
personnel during the ground-water sampling overview conducted in October 1986.
A checklist completed for this overview is included as Appendix G of this
report.   Note that the corporate plan includes options for several procedures
to accomodate site-specific conditions at the large number of facilities
covered by the plan.  These comments predominately reflect observations of
sampling procedures made during the evaluation and the subsequent sampling
overview.

     1.   CWM personnel correctly calibrated the pH and specific conductance
         meters prior to going out into the field.  The corporate SOP
         requires checking calibration every 4 hours.  During the overview
         the pH meter was checked against pH7 and pHIO buffer solutions
         at each well.  These procedures are acceptable.

     2.   Water levels were determined at each well with an electric water
         level measurement device.  After removal from each well, the wetted
         portion was rinsed copiously with DI water, dried with a clean paper
         towel and placed in a bag.  These procedures in and of themselves are
         minimally adequate and acceptable.   One problem noted during the
         measurement and decontamination procedures was the failure of CWM
         personnel to wear gloves.  Although hands were washed in deionized
         water prior to handling the equipment the Task Force recommends that
         all sampling personnel touching any equipment which enters a well,
         wear clean, powderless disposable gloves such as latex physician's
         examination gloves.

     3.   CWM personnel, using measured water levels and known well diameters
         and depths, correctly determined the volume to be purged at each well
         using a calculator and the equation for the volume of a cyclinder.
                                    -32-

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         Standard volumes to purge the sample pump and line had been calcu-
         lated for each well.  Those volumes were correctly calculated and
         allow for complete replacement of stagnant water prior to sampling.

     4.   The glove issue is raised again here as a problem observed during the
         complete sampling exercise.  The same recommendation made in No.  2
         above.

     5.   The types of samples collected are listed in Table 5 along with the
         bottle types and preservatives used.  These parameters encompass all
         the required RCRA parameters.  The bottle types and preservatives
         used are acceptable.  One minor concern, however, is the sample
         volume used for the radiometric parameters.  CWM collects one liter
         of sample in a plastic bottle.  Regional guidance from the Eastern
         Environmental Radiation Facility, as well as the EPA Technical
         Enforcement Guidance Document, specifies one gallon sample volume.
         Method 9310, SW-846 does not specify a particular volume of sample
         but indicates that enough volume to provide a solids density
         thickness of 5 mg/cm2 in the counting planchet is needed.  It further
         states that for very low radioactivity samples it is essential to
         analyze as large a sample as is needed to give reasonable times.   CWM
         should make sure, in light of this guidance, that the one liter
         samples are adequate.

     6.   CWM filters all samples except those collected for purgeable organic
         and total organic halide analyses.  Filtration occurs in an in-line
         disposable Gelman R filter (0.45 micron).  Prior to sampling,
         three filter volumes are flushed through the filter, which is pressed
         on the sample discharge line.  EPA does not approve of filtering any
         samples except those collected for metals analyses when the sample is
         turbid, and in those cases, EPA guidance recommends analyzing both
         filtered and unfiltered samples.  Based on observations made by
         Region IV, ESD personnel during previous sampling efforts at the site
         and on observation made during the Task Force evaluation, the quality
         of water collected from each well is such that filtration is not
         necessary for any analytical parameter.  The Task Force recommends
         that samples collected from the RCRA monitoring wells not be
         filtered.

     7.   Samples were packed in sealed shuttles with the chain of
         custody/analytical request form and shipped via Federal Express to
         the laboratory.

Quality Assurance/Quality Control

     CWM uses the following prcedures to assure quality in analyses of
ground-water samples collected from the RCRA ground-water monitoring system.

     1.   Trip blanks - For each sampling event, CWM personnel send a
         purgeable organic (VGA) trip blank with the sample shipment.

     2.   Field Blanks - Field blanks for all parameters are prepared at
         one location for each sampling event.
                                    -33-

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     3.  Duplicates - At one well, selected at the time of sampling, a
         complete duplicate sample is collected.

     4.  Laboratory Performance Evaluation - The corporate office in Oak
         Brook, Illinois operates a performance evaluation program to
         provide quality assurance on the analyses provided by the
         laboratory, etc.

     These measures generally provide an acceptable level of quality assurance
regarding validity and acceptablity of data.

Analytical Procedures

     The analytical procedures used by CWM and their laboratories are listed
in Table 6.  Region IV ESD Laboratory Evaluation and Quality Assurrance
Section staff evaluated these procedures and determined that they are
acceptable procedures capable of providing quality data under the facility's
RCRA ground-water monitoring program.
                                    -34-

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LABORATORY REVIEW

     The on-site and off-site laboratory facilities handling ground-water
samples were evaluated regarding responsibilities under CWM's ground-water
sampling and analysis plan.  The on-site laboratory was evaluated during the
facility inspection.  The CWM contract laboratory, Environmental Testing and
Certification, Inc., (ETC), Edison, New Jersey,  was evaluated by EPA NEIC and
EPA Region V during previous Task Force inspections at other sites during
1985, and was not visited by Region IV.  See the Hazardous Waste Ground-Water
Task Force Reports for SCA Chemical Services, Model City, New York; and
Kettleman Hills Facility, Kings County, California, for comments related to the
laboratory evaluation.  Both labs were evaluated for their ability to
produce quality data for those parameters required by 40 CFR Part 265.92 and
the priority pollutants as described by EPA Headquarters on page twelve (12)
in the Kettleman Hills Report.  Analytical equipment, methods amd quality
assurance procedures were examined for adequacy.  Laboratory records were
reviewed for completeness, accuracy and compliance with State and Federal
requirements.

Ground-Water Sampling and Analysis Plan

     Under the October 1984, Consent Agreement,  CWM was to continue to
implement their ground-water quality assessment plan and analytical protocol.
CWM was to submit a Proposed Plan and Protocol to be followed whenever samples
were taken from monitoring wells at the facility.  The documents reviewed
during the inspection were:

1. "WMI Manual for Ground Water Sampling", prepared by Waste Management, Inc.,
(CWM parent company)

2. Proposed Plan and Protocol for the Groundwater Monitoring, Emelle, Alabama,
April 1985.

3. Laboratory Standard Operating Procedures, February 21, 1985, by Environmental
Testing and Certification, Inc., Edison, New Jersey.

     The WMI Manual for Ground Water Sampling is a comprehensive document and
was declared "business confidential".  It presents detailed procedures for
collecting, preserving, handling, documenting (field records and chain-of-
custody) and shipping samples.  The document is a generic plan for all WMI
related facilities and was not site specific for the Emelle, Alabama, facility.
The WMI Manual prescribes filtering of sample aliquots, except for volatile
organic carbon (VGA), total organic halide (TOX), pH, and specific conductance
parameters.  Samples for metals, extractable organics, pesticides, and total
organic carbon (TOG) were filtered in-line with disposable Gelman R 0.45 micron
filters during collection but reported as total metals, etc.  Drinking water
standards are based on total metals.  Therefore, the data reported were not
consistent with the requirements for drinking water supplies listed in 40 CFR
Part 141.23 (f).  This practice may result in data biased low for these
parameters.  Table 1-2 in the WMI Manual for Ground Water Sampling, listed
preservative and holding time requirements for some ground-water samples that
are outdated.
                                    -35-

-------
Sample Handling, Preservation and Field Measurements

     The sample containers were prepared by ETC and pre-labeled for the
required parameters from each sampling point and shipped to the facility.  The
samples were preserved immediately upon collection.  Pre-measured preserva-
tives for each sample were shipped in the sampling bottles or in small
vials.  ETC periodically checks the sample preservation where pH adjustment is
required after the samples arrive in the laboratory.  CWM does not have a QC
procedure to check the pH to insure proper adjustment prior to shipping the
sample container to the contract laboratory.

     Holding times were being met for all parameters, except volatile organic
carbon compounds and the extractable organic compounds.   The contract
laboratory did not analyze and/or extract the samples in the required holding
time as stipulated in the WMI Manual or as required in the RCRA regulations
for drinking water samples collected during the March 6-7, 1986, and November
21, 1984, sampling events.  There were three (3) separate sampling events
reviewed during the audit, and holding time requirements for extractables were
exceeded in two of the three sampling events.  These data were not flagged by
the contract laboratory or CWM as exceeding the required holding time in the
reports to ADEM or EPA.

     Field measurements (pH and specific conductance) conducted by CWM
personnel were observed by the audit team.  Meter calibration, quality control
checks, documentation and reporting for the parameters were acceptable.   CWM
quality assurance practices for these parameters had drastically improved from
practices observed during a facility audit in October, 1985.  Therefore, data
generated by CWM for these parameters are of acceptable quality.

Laboratory Sample Analysis

     The Kettleman Hills Report mentions some inadequacies found at the
contract laboratory.  Analytical methods with lower detection limits need to
be used for the pesticides, PCB's, cadmium, chromium and lead.  A review of
the data indicated that this deficiency still existed.  The analytical method
for total organic carbon (TOG) was described as inappropriate because
volatiles were stripped from the sample during the sample preparation step to
remove inorganic carbon (carbon dioxide) prior to measurement of the organic
carbon.  If TOG samples cannot be analyzed immediately,  preservation by
lowering the sample pH to less than two is required.  CWM was preserving the
samples to meet this requirement to retard any biological action during
shipping and prior to analysis.  The inorganic carbon consitituents are
normally removed by lowering the sample pH followed by purging with an inert
gas prior to measuring the TOG.  The method detection limit for TOG
(approximately 1 mg/1) is at least one to two orders of magnitude above the
concentration of the volatile organic components of the TOG.  However, these
volatiles should be detected in the VGA analysis.  Therefore, the emphasis on
organic contamination should be placed on the VGA results instead of the TOG
data.

     TOX analysis were conducted in an area where the samples could have been
contaminated with methylene chloride.  ETC reportedly moved the TOX analysis
to another area after the Task Force audit.  Data from RCRA wells used to
                                    -36-

-------
monitor the Eutaw Formation indicates the presence of chlorides (approximately
500-700 mg/L).   Chlorides can interfere in the TOX procedure when the
inorgano-halide concentration exceeds the organic-halide concentration by more
than 20,000 times.   Care should be taken when reviewing the TOX data and
greater emphasis should be placed on the organic analyses for chlorinated
organic compounds.

     Samples for phenol analysis were collected and appropriately preserved
with sulfuric acid to pH <2.  They were then analyzed by EPA Method 420.1, EPA
600/04-79-020,  a method approved for ground water.  The contract laboratory,
however,  did not raise the sample aliquot pH to four (4) prior to the
distillation step in Method 420.1, as required in Footnote 25, 40 CFR Part
136, Guidelines Establishing Test Procedures for the Analysis of Pollutants,
Federal Register, June 30, 1986.  This practice may result in data biased low
for these parameters.

Quality Assurance and Data Documentation

     The on-site laboratory has established a formal quality assurance (QA)
program that consists of a QA plan, standard operating procedures (SOP) and
includes the use of duplicates, and reference standards to verify the quality
of data for each parameter analyzed.  Instrument calibration and maintenence
were maintained and temperatures of regulated devices were checked.  All raw
data, quality control records and calculations were documented and maintained
on file as required.
                                    -37-

-------
TASK FORCE ANALYTICAL DATA EVALUATION

     Samples of ground water were collected from two RCRA monitoring wells,
ten Consent Agreement wells and two TSCA PCB monitoring wells.   In addition to
the ground-water samples,  leachate samples were collected from the sumps at
Trenches 9 and 15.  All samples were to be analyzed for the constituents and
parameters listed in Appendix B, however, because of problems with obtaining a
complete sample within a reasonable time from some wells and because the oily
nature of the leachate sample from Trench 15 prevented a complete analysis,
all constituents and parameters could not be analyzed for all wells or
trenches.   The analytical data summary tables for all analyses are included as
Tables 7,  8, and 9 of this report.  These data are discussed in the following
section.  The complete data is included as Appendix H.  Some analyses reported
in these tables are estimated values and are noted with a "J".   Several
compounds are reported because there was sufficient presumptive evidence to
warrent their inclusion.
RCRA Wells (Eutaw System)

     Inorganic elements/compounds - A total of eight metals - barium, lead,
aluminum, manganese, calcium, magnesium, iron and sodium - were detected in
the samples collected at Wells 7 and 8.  Lead and aluminum were not detected,
at MQL's (minimum quantification limits) of 4 ug/1 and 94 ug/1, respectively,
in the sample from Well 7.  Calcium was not detected in the sample from Well 8
at a MQL of 3 ug/1.

     None of the metals concentrations reported exceed any primary or
secondary drinking water standards.  Although the concentration of barium in
the sample collected at Well 8, 500 ug/1, is only one-half of the National
Interim Primary Drinking Water Standard of 1.0 mg/1, it is an order of
magniturde higher than any historical values reported by CWM for samples from
the Eutaw well sytem (see Appendix I, Historical Ground-Water Data).

     Sodium was detected at concentrations of 510 mg/1 and 420 mg/1 at Well 7
and Well 8, respectively.  These values are consistent with historical data
reported by the facility.

     Conventional parameters - Ammonia and chloride were the only parameters
within this category present at detectable levels.   Ammonia was measured at
1.3 mg/1 and 1.1 mg/1 in Wells 7 and 8, respectively.  Chloride was measured
at 510 mg/1 and 410 mg/1 in Wells 7 and 8, respectively, exceeding the
Secondary Drinking Water Standards of 250 mg/1.

     General comments - Both sodium and chloride were detected in these
samples at concentrations ranging from approximately 400 mg/1 to 500 mg/1. In
each well the concentrations were measured at a near 1:1 ratio. These
concentrations are generally indicative of the salinity in the upper portion
of the Eutaw Formation.  Water in this portion of the formation is considered
marginally potable, therefore most drinking water supply wells are completed
in lower portions of the Eutaw or the deeper Gordo Formation.
                                    -38-

-------
     Based on these data, it does not appear that waste disposal practices at
the Emelle facility have affected ground-water quality in the Eutaw Formation.


Consent Agreement Wells and PCB Wells

     Thirteen consent agreement and PCB wells,  all completed in approximately
the same zone (25 - 50 feet below bottoms of trenches), were sampled and
analyzed, as sample volume allowed, for the same parameters as the RCRA deep
wells (see Appendix B).  A number of inorganic elements/compounds, purgeable
organic compounds and conventional parameters were detected in these samples.
These data are summarized in Table  8, and are discussed below.

     Inorganic elements/compounds - Thirteen metals were detected in these
samples (no sample contained all of the metals).  Of these thirteen, barium,
zinc, aluminum, manganese, calcium, magnesium and iron have been shown, by
chemical analysis of the chalk by Region IV, BSD, to be chalk constituents
(8).  Sodium, detected in all thirteen samples, and potassium, detected in ten
samples, could be derived from clay minerals associated with the chalk and/or
bentonite used as an annular space sealant in well construction.

     The remaining metals - arsenic, cobalt, nickel and selenium - are all
present at trace levels.  Of these, nickel is present at the highest
concentrations, 29 ug/1 and 25 ug/1, in wells SM-5 and M-58 respectively.
Concentrations of the other metals are all less than 11 ug/1.

     Purgeable Organic Compounds - A total of six purgeable organic compunds
were detected in four of the thirteen wells that were sampled.  Three of the
wells (SM-2, SM-5, and SM-9) are Consent Agreement Wells and one (M-56) is a
PCB well.  The compounds detected, in order of decreasing concentration, are
methyl butyl ketone, chloroform, 1,1-dichloroethane (presumptive evidence
only), trichloroethene, toluene, and benzene.  Except for methyl butyl ketone,
which was reported at a concentration of 14 ug/1, no compounds were detected
at a concentration greater than 6.3 ug/1.

     Conventional Parameters - This group of parameters consists of phenols,
total organic carbon (TOG), total organic halogen (TOX),  cyanide, sulfate,
chloride, nitrate - nitrite nitrogen, and ammonia.  Because adequate sample
volumes had not recovered at some of the wells sampled, a priority list (see
Table 10) was established identifying the types of samples most important to
the Task Force evaluation.  The purgeable organic, extractable organic and
metals samples were thought to be the most important.  As a result, samples
for most or all of the conventional parameters were not collected at some of
the wells.  The anlytical data summary table, Table 8,  clearly indicates
which samples were or were not collected.  The following is a brief
description of the occunence and concentrations of these parameters in
samples collected at the Consent Agreement and PCB wells.


Ammonia - Samples were collected at Wells SM-2, SM-5, SM-7A, SM-13, SM-14, SM-
16 and M-62.  Concentrations range from 0.80 mg/1 at SM-16 to 1.4 mg/1 at M-62.

Chloride - Samples were collected at Wells SM-2, SM-5, SM-7A, SM-13, SM-14,
SM-16, M-58 and M-62.  Concentrations range from 44 mg/1 at SM-5 to 490 mg/1


                                    -39-

-------
at M-62, which is the only value to exceed the secondary drinking water
standard of 250 mg/1.

Nitrate-Nitrite Nitrogen - Samples were collected at SM-2, SM-5, SM-7A, SM-13,
SM-14, SM-16 and M-62.  Concentrations ranged from below detection (at a MQL
of 0.05 mg/1) at SM-5 and M-62, to a high of 1.3 mg/1 at SM-14.  None of the
concentrations exceed the National Interim Primary Drinking Water Standard of
10.0 mg/1.

Sulfate - Samples were collected at SM-2, SM-5, SM-7A, SM-13, SM-14,  SM-16, M-
58, and M-62.  Concentrations range from below detection (MQL of 0.10 mg/1) at
M-62 to 650 mg/1 at SM-14.  The Secondary Drinking Water Standard of 250 mg/1
was exceeded at Wells SM-5, SM-7A, SM-14, SM-16, and M-58.

TOG - Samples were collected at all wells except for SM-9 and M-567.   TOG was
not detected at a MQL ranging from 2 mg/1 to 5 mg/1 at any of the wells
sampled except for the background well, BG-02, where an estimated 55 mg/1 was
detected.

TOX - Samples were collected at wells BG-02, SM-2, SM-5, SM-7A, SM-13, SM-14,
SM-16, M-58 and M-62.  TOX was measured only in the background well,  BG-02, at
a concentration of 250 ug/1.  Because of the remote location of this well with
respect to the facility, and the fact that no chlorinated purgeable organics
were detected at this well, the TOX value is highly suspect.  MQL's in all
other samples ranged from 10 ug/1 to 120 ug/1.

     It is difficult to draw any firm conclusions about possible shallow
saturated chalk contamination using data from the Task Force evaluation.  Of
all the data reported from analyses of samples collected at the Consent
Agreement and PCB chalk wells, the data for selected metals (arsenic, cobalt,
nickel and selenium) and purgeable organic compunds are the most useful.  TOC
and TOX were the priority conventional parameters and analyses was obtained
for these paramters from 11 of 13 and 9 of 13 wells, respectively.  These
data, however, do not appear to be useful indicators for this evaluation,
since the samples from the background well, Well BG-02, were the only samples
in which TOC and TOX were detected.  It should be stated that this well
appears to be located properly with respect to its function as a background or
control well, and no explanation can be offered at this time for these
apparently anomolous values.

     The selected metals data does not indicate a clear pattern with regard to
fracture-screened or deep-screened wells. Of the five wells adjacent to
trenches in which these metals were detected, two are deep wells, two are
fracture wells and one is a PCB well.  The PCB wells were generally sited with
respect to observed fractures and were completed at depths approximately 25
feet below trench bottoms.  If the PCB well in question, M-58, were indeed a
fracture well equivalent, then the data might indicate a trend towards higher
metals concentrations and greater number of metal compounds occurring in
fracture wells.

     Of the six purgeable organic compounds detectable in samples collected
from Consent Agreement wells, four, two each in wells SM-5 and SM-9,  were
detected in fracture wells.  If the reasoning in the previous paragraph is
followed, the compound detected in the sample from well M-56 could also be


                                    -40-

-------
considered to be from a fracture well sample,  indicating that possibly five of
six occurrences of purgeable organic compounds were from fracture wells.

     It would be unusual, however, if these fractures (e.g. Well SM-5 and SM-9
fractures) are indeed active conduits, that so few organic compuonds were
detected at the low levels measured (all less  than 15 ug/1).   The leachate in
these trenches is a virtual soup of inorganic  and organic compounds.  One
would expect, given the low levels of detection utilized in these analyses,
that more than two purgeable organic compounds would be detected and that
extractable organic compounds would have been detected as well.

     The Task Force recommends that the following tasks be completed to
evaluate the significance and probability of the fractures as conduits for
leachate migration.

     1.  Conduct a trace element geochemical study of the Selma Chalk
         in the vicinity of the Emelle facility.  Samples should be collected
         from on-site and off-site locations with utmost regard for obtaining
         pristine samples.  The study should include, at a minimum, analysis
         for the trace metals arsenic, chromium, cobalt, nickel, and selenium.
         These analyses should look at both total and leachable (e.g. EP
         Toxicity procedure) concentrations. It is critical that the
         occurrence and mobility of these metals in the chalk be understood if
         decisions regarding contamination are to be made on the
         concentrations of arsenic, chromium and nickel in ground water
         collected from the Consent Agreement wells.  This study should be
         performed by either EPA or ADEM.

      2. Sampling the purgeable organic compounds in the vicinity of active
         trenches, particularly downwind should be conducted with the
         highest regard for field quality control and quality assurance.
         Field blanks should be prepared for purgeable organic analyses
         at each station where odors and wind blown dust are present
         during sampling to help evaluate the low level concentrations of
         organic compunds such as reported for Task Force samples.   This
         task should be performed jointly by CWM and either EPA or ADEM
         during several regularly scheduled sampling events at CWM.  Ideally,
         samples should be split at the "hot wells" sampled during the
         Task Force evaluations and any other wells at which purgeable
         organic compunds have been recently detected or which are in active
         areas.

     These conclusions are speculative and are based on observations made
during the Task Force Evaluation.  While they are by no means conclusive, they
do indicate that some fractures may be conduits for leachate migration from
certain trenches.
Leachate Samples

     Although samples of leachate collected from Trenches 9 and 15 were to be
analyzed for the complete list of parameters (see Table 9), a complete set of
analyses could be obtained only for the sample collected from Trench 9.   The
                                    -41-

-------
oily,  concentrated nature of the sample from Trench 15 created sample prep-
aration problems which prevented the organics laboratory from conducting any
analyses,  therefore,  only metals and conventional analyses was performed and
reported for this sample.   Table 9 contains the analytical summary for the
leachate samples.

     Inorganic elements/compounds - Eighteen metals were detected in the two
samples (all eighteen were detected only in the sample from Trench 15).   With
few exceptions, the sample from Trench 15 had the highest concentrations of
detected metals.

     Extractable organic compounds (including chlorinated compounds) -
Twenty-one extractable organic compounds were detected in the sample from
Trench 9 at a total concentration of 786,430 ug/L.

     Purgeable organic compounds - Eight purgeable organic compounds were
detected in the sample from Trench 9 at a total estimated concentration of
430,000 ug/L.

     Conventional organic parameters - Purgeable organic halogen, phenol
(4AAP), total organic carbon and total organic halogen analyses were conducted
on samples from both trenches.   The results generally show approximately an
order of magnitude higher concentrations in the samples collected from Trench 15,

     Conventional parameters -  Ammonia and chloride were detected in samples
from both trenches.  As is the case for most other samples collected and
analysed for both trenches, the values for Trench 15 are higher.   Cyanide was
not analysed for the sample from Trench 9 and was detected in the sample from
Trench 15 at an estimated concentration of 11 mg/L.  Sulfate was detected in
the sample from Trench 9 at an estimated concentration of 1400 mg/L, but was
not detected in the sample collected at Trench 15.

     The analyses appear to be typical of what would be expected for leachate
developed in trenches at the facility.
                                    -42-

-------
REFERENCES CITED

1. Chemical Waste Management, 1983, RCRA Part B Permit Application,  Chemical
   Waste Management, Marietta, Georgia.

2. Foster, R. J., 1971, Physical Geology, Merrill Publishing Co.,  Columbus,
   Ohio.

3. Monroe, W. H., 1955, Preliminary Geologic Map of the Northwest Part of the
   Epes Quadrangle, Sumter and Green Counties, Alabama, U.  S. Geological Survey,
   Washington, D. C.

4. Scott, John, Personal Communication,  U. S. Geological Survey,  Montgomery,
   Alabama.

5. Davis, M. E., T. H. Sanford, Jr., and P. 0. Jefferson, 1980, Water
   Availability and Geology of Sumter County, Alabama, Map 158, Geological
   Survey of Alabama, University of Alabama.

6. Williams, J. S., S. S. DeJarnette, and M. Planert, 1986,  Potentiometric
   Surface and Water-Use Map of the Tuscaloosa Aquifer in Alabama, Fall 1982, U.
   S. Geological Survey Water Resources  Investigation Report 85-4174,
   Tuscaloosa, Alabama.

7. A.C.E., 1986, Alabamian For a Clean Environment, Public Hearing Statements,
   Livingston, Alabama.

8. Gardner, R. A., 1981, Model of the Ground Water Flow System of the Gordo and
   Eutaw Aquifers in West-Central Alabama, U. S. Geological Survey in
   Cooperation with the Geological Society of Alabama, Bulletin 118, University
   of Alabama.

9. Agency Report, 1984, Environmental Sampling Investigation, Chemical Waste
   Management, Inc., Sumter County, Alabama, U. S. Environmental Protection
   Agency, Region IV, Environmental Services Division.
                                    -43-

-------
FIGURES

-------
   CHEMICAL
    WASTE
 MANAGEMENT
                                           N
            FIGURE 1
     FACILITY LOCATION MAP
CHEMICAL WASTE  MANAGEMENT. INC.
        EMELLE.  ALABAMA

-------
                                         Impoundment No. 3


                               Tank Farm No. 2
        x/.   Employee
      /   ''..Parking    f

    --*         *«           "--
            LANDFI
                       KEY TO BUILDING/AREA NUMBER COOES
 200
 201
 300
 301

 401
 402
 404
 406
 407
 600
 602
 603
604
Office,  lab, Receiving
Scales,  Lab, Offices
Heavy Equipment Maintainence
Site Operations Materials
   Storage Building
Paint and Wash Building
Transportation Shop
Shower and Locker
Loaded Truck Parking
Site Operations
PCB Processing w/RCRA Tanks
PCE Tank Storage
PCB Tank Storage
Special Projects
 700
 701
 702
 703
 900
 901
1100
1200
RCRA Drum Storage and Processing
Bulk Load Lab
RCRA Drum Storage
Re-loading Dock
Truck Wash Area
Re-fueling Station
Liquid Stabilization Unit
Semi-solids Stabilization Unit
                       Area of Sice
                          Diagram
                                                                                1200
                                                                                     Dh
                                                                                           1100
                                       Figure  2
                                    Site Diagram
                       Chemical  Waste Management,  Inc.
                                   Emelle,  Alabama

-------
NOTE:  CONTOURS ARE FEET ABOVE MSL AND ARE BASED ON
            SEPTEMBER 1986 GWTF DATA.
                   FIGURE  3
            CWM  PCS,  CHALK WELLS
          CHALK  POTENTIOMETRIC  MAP
       CHEMICAL WASTE MANAGEMENT, INC.
               EMELLE, ALABAMA

-------
      	I
r"
i
i

-------
s
01
a
                r"

-------

-------
TABLES

-------
                                          TABLE  1
                                     SAMPLING SUMMARY
                                     HWGWTF EVALUATION
                              CHEMICAL WASTE MANAGEMENT,  INC.
                                      EMELLE, ALABAMA
                                   SEPTEMBER 15-25,  1986
WELL
NO
BG-02
SM-2
SM-5 >
SM-6
SM-7A
SM-8
SM-9A
SM-9A dup
SM-11
SM-13
SM-14
SM-16
Eutau 7
Eutaw 7 dup
Eutau 8
M-56
M-58
M-62
L-9
L-15
TB-1
TB-2
FB-1
FB-2
FB-3
PE-01
DATE
SAMPLED
9/23/86
9/22/86
9/23/86
9/23/86
9/23/86
9/22/86
9/23/86

9/23/86
9/22/86
9/22/86
9/22/86
9/17/86

9/18/86
9/23/86
9/23/86
9/23/86
9/19/86
9/19/86
9/22/86
9/22/86
9/17/86
9/22/86
9/23/86
9/22/86
LOCATION
4500 FT SOUTH OF TRENCH NO 21
EAST SIDE OF TRENCH NO 18
EAST SIDE OF TRENCH NO 9^
EAST SIDE OF TRENCH NO 10
EAST SIDE OF TRENCH NO 11
EAST SIDE OF TRENCH NO 20
SOUTH SIDE OF TRENCH NO 20

WEST SIDE OF TRENCH NO 16
NORTH SIDE OF TRENCH NO 15
WEST SIDE OF TRENCH NO 13
WEST SIDE OF TRENCH NO 8
PROPERTY CORNER EAST OF TRENCH NO 17

ONE MILE WEST OF HWY 17
NU CORNER OLD STUDY AREA
EAST SIDE OF TRENCH NO 9
SW CORNER OF TRENCH NO 8
LEACHATE SUMP, TRENCH NO 9
LEACH^TE SUMP, TRENCH NO 15






BOTTLES SUBMITTED
FOR ANALYSIS
E(2), Tm,Tc,Tx,P,C,V
F
F
E(4), Tm,Tc,Tx,P,C,V
F
E(2), Tin, V
E(2), Tm,Tc,P,C,V
E(2), Tm,Tc,P,C,V
E(2), Tm,Tc,P,C,V
f
F
F
F

F
E(3), Tm,V
E(4),Tm,Tc,Tx,P,C,S,V
E(3), Tm,Tc,P,V
F
F
F
F
F
f
F
F
BG -    Background chalk well          TB - Trip blank
SM -    Consent Agreement chalk well   FB - Field blank
Eutaw - Deep RCRA well                 PE - Performance Evaluation Sample
M -     TSCA chalk well
L -     Leachate sump
E = Extractable Organic (2 = sample bottles) (3 = sample bottles)  (4 = sample bottles)
F = Full Sample Set
Tm = Total Metals
Tc = TOC
Tx = TOX
P = Phenol
C = Cyanide
S = S0
          C1
V = 2 P&T Vials, 1 POC Vial, 1 POX Vial

-------
                           Table 2
              SAMPLE BOTTLES AND PRESERVATIVES
                PREFERRED ORDER OF COLLECTION
                      HUGUTF EVALUATION
               CHEMICAL WASTE MANAGEMENT, INC.
                       EMELLE, ALABAMA
No.     Parameter. Container. Preservative.

 2      Purge and trap, 40 ml vials
 1      Purgeable organic carbon, 40 ml vial
 1      Purgeable organic halogen, 40 ml vial
 4      Extractable organic, 1 liter bottles
 1      Total metals, 1 liter bottle, HNOj pH < 2
 1      Total organic carbon, 250 ml bottle, H^SO, pH < 2
 1      Total organic halogen, I liter bottle
 1      Phenols, I liter bottle, HjSO^ pH < 2
 1      Cyanide, I liter bottle, NaOH pH > 12
 1      Sulfate and chloride, I liter bottle
 1      Nitrate and airmonia, I liter bottle, H-SO, pH < 2
             All samples also iced to 4°C

-------
                       TABLE 3
    LIST AND DESCRIPTION OF TRENCHES T-l THROUGH T-20;
       TRENCHES FILLED PRIOR TO FEBRUARY 24, 1986
            CHEMICAL WASTE MANAGEMENT, INC.
                  EMELLE, ALABAMA
Trench
Number
T-l
T-3
T-4
T-5
T-6
T-7
T-8
T-9
T-10
T-ll
T-12
T-12A
T-13
T-13A
T-14
T-15
T-16
T-17
T-18
T-19 '
T-20
Approximate
Aerial Dimensions
(feet)
50
50
150
120
120
170
200
'320
270
280
300
210
330
200
280
320
390
250
500
300
510
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
700
800
340
340
340
340
400
400
440
44.0
500
290
550
41^
550
520
640
500
610
400
600
Approximate
Average Depth
(feet)
30
40
60
60
65
'65
80
80
100
100
100
50
50
50
50
50
90
50
110
40
120
Notes:

1.  Trench  T-2  was never developed.

2.  Trench  T-19 no longer receives  wastes, and  is  in
    the process of being closed.

3.  Trenches  T-l through T-9 where  active prior to
    November  19/ 1980, but did  not  receive hazardous
    wastes  after that date.

4.  Trenches  T-10 tnrGsnh T-20  were  active between
    November  19, 1980, and September 8,  1985, (there-
    fore are  interim status units) but  did not receive
    hazardous wastes after the  later.date.
Source:  Chemical Waste Management Part B

-------
                                 TABLE 4
                  RCRA WASTE LANDFILLED AT CWM,  EMELLE
                    CHEMICAL WASTE MANAGEMENT,  INC.
                            EMELLE, ALABAMA
Process
Code
D81 D001
D002
D004
F001
F002
F019
K001
K002
K003
K004
K005
K006
K007
K008
K009
K010
K014
K015
P001
P002
POOS
P004
POOS
P007
POOS
P010
P011
P012
P014
P015
P016
P017
P018
P020

Waste Identification
D005
D006
D007
F003
F004
F028
K016
K017
KOlg
K019
K020
K021
K022
K023
K024
K025
K026
K028
P023
P024
P026
P027
P028
P031
P033
P034
P037
P038
P039
P040
P041
P042
P043


D008
D009
D010
F005
F006

K029
K030
K031
K032
K033
K034
K035
K036
K037
K038
K039
K040
P044
P045
P046
P047
P048
P049
P050
P051
P054
P056
P057
P058
P059
P060
P062


D011
D012
D013
F007
F008

K041
K042
&343
K046
K048
K049
K050
K051
K052
K060
K061
K117
P063
P064
P066
P067
P068
P069
P070
P071
P072
P073
P075
P076
P077
P078
P082

•
Codes
D014
D015

F009
F010

K062.
K069
K071
K073
K083
K084
K085
K087
K093
K094
K095
K118
P084
P085
P087
P088
P089
P092
P093
P094
P095
P096
P097
P101
P102
P103
P105

P108

D016
D017

F011
F012

K096
K097
k'098
K099
K100
K101
K102
K103
K104
K105
K106
K136
P109
P110
Pill
P113
P114
P115
P116
P117
P118
P119
P120
P123





  *This unit may accept wastes with cyanides  at  low  concentra-
   tions exhibiting no reactivity.
Source:   Chemical Waste Management Part B
                                                             REVISION 2
                                                             5/5/86

-------
TABLE 4
(Cont.)
Process
Code
D81 U001
(cont'd.) U002
U003
U004
U005
U007
U008
U009
U010
U011
U012
U014
U015
U016
U017
U018
U019
U021
U021
U022
U024
U025
U026
U027
U028
U029
U030
U031
U032
U034
U035
U036
U037
U038
U039
U041
U042

Waste Identification Codes
U043
U044
U045
U046
U047
U048
U049
U050
U051
U052
U053
U055
U056
UQ57
U058
U059
U060
U061
U062
U063
U06A
U066
U067
U068
U069
U070
U071
U072
U073
U074
U075
U076
U077
U078
U079
U080
U071

U082
U083
U084
U085
U086
U087
U088
U089
U090
U091
U092
U093
U094
U095
• U097
U098
U099
U101
U102
U103
U104
uios
U106
U107
U108
U109
U110
Ulll
U112
U113
U114
U11S
U116
U117
U118
uny
U120
U121
U122
U123
U124
U125
U126
U127
•U128
U129
U130
-. .U131
U132
U134
U136
U137
U138
U139
U140
U141
U142
U143
U144
U145
U146
U147
U148
U149
U150
U151
•U152
U153
U154
U155
U156
U157
U158
U159
U161

U162
U163
U164
U165
U166
U167
U168
U169
U170
U171 '•
U172
U173
U174
U176
U177
U178
U179
U180
U181
U182
U183
U184
U185
U186
U187
U188
U190
U191
U192
U193
U194
U196
U197
U200
U201
U202
U203

U204
U206
U207
U208
U209
U210
U211
U212
U213
U214
U215
U216
U217
UZ18
U219
U220
U221
U222
U225
U226
U227
U228
U235
U236
U237
U238
U239
U240
U244
U247
U248
U249






             Site-generated industrial and Clean-up wastes
             (after'stabilization) including:
             Sanitary wastes
             Sump drainage
Floor drainage
Contaminated rainwater
Source:   Chemical Waste Management Part B
                                                            REVISION 2
                                                            5/5/86

-------
                                         Table 5
                     SAMPLE PARAMETERS,  CONTAINERS AND PRESERVATIVES
                             CHEMICAL WASTE MANAGEMENT,  INC.
                                      EMELLE,  ALABAMA
Sample Type
Bottle Type
                                     Preservative
Extract able Organics
   (Pesticides and Herbicides)
Volatile Organics
Metals
TOX
Phenols, TOC, Nitrate/Nitrite
Sulfate
Ammonia
Conventional
Gross Alpha/Beta
2 L amber glass (baked)

40 ml(2) baked vials w/septun lid
1 L plastic
1 L amber glass
125 ml amber glass
125 ml amber (baked)
500 ml amber glass
500 ml (DI rinse) plastic
1 L plastic
                                     Cool,  4 C
                                     Cool,  4°C
                                     Nitric,  < 2
                                     Sulfuric,  < 2
                                     Cool,  4°C
                                     Sulfuric,  < 2
                                     Cool,  4°C
                                     Nitric, < 2

-------
                              TABLE 6
           ANALYTICAL METHODS FOR PART 265 GROUNDWATER MONITORING
                   CHEMICAL WASTE MANAGEMENT, INC.
                          EMELLE, ALABAMA
Parameter
                Method'
                                Reference"
Arsenic
Barium
Cadmium
Chromium
Fluoride
Lead
Mercury
Nitrate (as
N)
Selenium
Silver
Endrin
Lindate
Methoxychlor
Toxaphene
2,4-D
2f4,5-TP
Radium 226
Radium 228
Gross Alpha
Gross Beta
Chloride
Iron
Manganese
Phenols
Sodium
Sulfate
Total organic carbon

Total organic halogen
Specific conductance
PH
         AA
         ICP
         ICP
         ICP
   Distillation Probe
         ICP
         AAl
     Brucine Sulfate
      Cd Reduction
         AA
         ICP
         GC
         GC
         GC
         GC
         GC
         GC
   Proportional Counter
   Proportional Counter
   Proportional Counter
   Proportional Counter
 Automated Ferricyanimide
         ICP
         ICP
Distillation Colorimetric
         ICP
     Gravimetric
  Distillation Infrared
       Detection

    Wheatstone Bridge
      Electrometric
EPA 600
EPA 600
EPA 600
EPA 600
EPA 600
EPA 600
EPA 600*
EPA 600
SM 370
EPA 600
EPA 600
AM
AM
AM
AM
AM
AM
SM 706
SM 707
SM 703
SM 703
SM 271
EPA 600
EPA 600
SM 513
EPA 600
SM 436
SM 1974

EPA 450.1
SM 70
EPA 239
 AA:  Furnace Atomic Absorption; ICP:  Emission Spectrpmetry;
 AAl:  Cold Vapor Atomic-Absorption; GC:  Gas  Chromatography

^EPA'600:   "Methods for Chemical Analysis of Water  and Wastes,"
 EPA 600/4-79-020, March,  1979; EPA 600*:   "Methods for Chemical
 Analysis  of Water and Wastes," EPA 600/4-79-020, August,  1979;
 SM:  "Standard  Methods for the Examination of  Water and Waste-
 water," 15th Edition, 1980; AM:  "Manual of Analytical Methods
 for the Analysis of Pesticides in Humans and Environmental
 Samples,"  June,  1980, EPA; EPA'450:  EPA Method 450.1,
 November  1980,  Identical  to EPA Method 8.66 in SW-846,
 Rev B.4/81,  40  CFR265.92.

-------
                               TABLE 7
                    HHGHTF ANALYTICAL DATA SUMMARY
                  GROUND HATER SAMPLES, EliTAH WELLS
                      CHEMICAL WASTE MANAGEMENT
                           EMELLE, ALABAMA
                                                  HELL 7    HELL 3
                                                  EUTAX     EUTA«
                                                  WELL      HELL
                                                  09/17/86  03/19/36
INORGANIC ELEMENT/COMPOUND	               U8/L      UG/L

     BARIUM                                       38"        500
     LEAD                                         -        6.6
     ALUMINUM                                     --        120J
     MANGANESE                                    10        7

                                                  MG/L      MG/L

     CALCIUM                                      4.4
     MAGNESIUM                                    1.5       1.1
     IRON                                         0.13J     0.21J
     SODIUM                                       510       420

CONVENTIONAL PARAMETERS	               MG/L      MG/L

     AMMONIA                                      1.3       1.1
     CHLORIDE          .                           510       410

t*** ************************************************************

mFOOTNQTES***
  J   - ESTIMATED VALUE
  --  - MATERIAL WAS ANALYZED FOR BUT NOT DETECTED

-------
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-------
                               TABLE 9
                    HH6HTF ANALYTICAL DATA SUMMARY
                           LEACHATE SAMPLES
                      CHEMICAL  HASTE HANAQEtlENT
                           EfiELLE, ALABAMA
                                                 L-3       L-15
                                                 LEACHATE  LEACHATE
                                                 TRNCH 9   TRNCH 15
                                                 03/22/86  03/18/86
RCRA HASTE CHARACTERISTICS

     PUR6EABLE ORGANIC  HALOGEN

INORGANIC ELEIOT/CQHPOUKD

     ARSENIC
     BARIUM
     COBALT
     COF'PER
     NICKEL
     LEAD
     ANTIMONY
     SELENIUM
     THALLIUM
     ZINC
     MERCURY
     ALUMINUM
     MANGANESE
     CALCIUM
     MAGNESIUM
     IRON
     SODIUM
     POTASSIUM

SELECTED CHLORINATED  COMPOUNDS

     ALPHA-BHC

EUP.ACTABLE ORGANIC COMPOUNDS
UG/L
UG/L
43000R .  680000R
UG/L
     1,2-DICHLQROBENZENE
     PHENOL
     4-NITROPHENOL
     HETHYLCYCLOPENTANONE
     HETHYLBENZOIC ACID
     OKYBISBEKZENE
     BENZENEAMINE
     11  UNIDENTIFIED  COMPOUNDS
     4-METHYLPHENDL
     BENZOIC ACID
HG/L

110
55J
0.65J
1000
1600

UG/L

50JN

UG/L
UG/L
120J
140
18
84
450
—
—
16J
—
220
—
230J
300
550J
410
1100
300
3800
2500J
560J
55J
260J
320
0.4JH
1000J
340
MG/L

1500
24
2.1J
6500
1100

UG/L

NAI

UG/L
560J      NAI
28000     NAI
320JN     NAI
57000JH   --
35000JH   ~
22000JN   --
7900JN
300000J   --
15000J
320000J   --
                (Continued  on next page)

-------
                               TABLE 9
                    HH6HTF ANALYTICAL DATA SUMMARY
                           LEACHATE SAMPLES
                      CHEMICAL HASTE MANAGEMENT
                           EMELLE, ALABAMA
                                                  L-3       L-15
                                                  LEACHATE  LEACHATE
                                                  TRNCH 9   TRHCH 15
                                                  09/22/85  09/13/86
PUPGEAELE ORGANIC CQ'fPQUND?

     1,1-DICHLQRQETHANE
     BENZENE
     TOLUENE
     ETHYL BENZENE
     TOTAL XYLENES
     DIMETHYLDISULFIDE
     CARBON DISULFIDE
     METHYL ETHYL KETONE

CONVENTIONAL PARAMETERS

     AMMONIA
     CHLORIDE
     CYANIDE
     SULFATE
     PHENOL (4AAP)
     TOTAL ORGANIC CARBON
     PURGEABLE ORGANIC CARBON
     TOTAL ORGANIC HALOGEN
UG/L

4000J
5300;
43000
2300 J
9200
42000 JN
4200J
230000J

MG/L
                                                            UG/L

                                                            NAI
                                                            NAI
                                                            NAI
                                                            NAI
                                                            NAI
                                                            MG/L
75
900
NA
1400J
UG/L
25000
mn
2300J
210J
UG/L
4500R
140
12000J
11J
~
UG/L
390000
MG/L
9900J
1600J
UG/L
76000R
*«FQOTNOTESH*
  NA  - NOT ANALYZED
  NAI - INTERFERENCES
  J   - ESTIMATED VALUE
  K   - PRESUMPTIVE EVIDENCE  OF PRESENCE  OF  HATERIAL
  --  - HATERIAL WAS ANALYZED FOR BUT  NOT DETECTED

-------
APPENDICES

-------
APPENDIX A

-------
                               VERSAR WELL MONITORING SHEET
                Date:   Beg.
                                                         End
1.
Site Name/Cas6 No.
Well No. /Location
SMO No./Fac. No.
Well Measurements
Well Diameter (inner)
Inner Casing Ht.
Outer Casing Diameter
DTW
Total Depth
Water Column Length
3 Casing Vol
Vol . Purged
6t$a'*1 • Time Beq. (Jx^Cj End Ocl3>^>
S"T« IT ^ • Depth Sampled V>\ /-». cAcV-^ CNCL-I.T>'
9"7- ^ _fjX./M!A/'> « Sample Volume '^^^ ^ ^ ^y
)
Sediment
Color
Odor
                   T- C(
3.  In Situ Measurements
           (Time)   1
    Temperature
    Conductivity
    Turbidity
      (Time)  3 (^•#$?>   4
Temperature     Qc^'^'c
Conductivity
pH
Turbidity
                                          5.  Notes
                                    (XTW
                                        \
                                              •  Well Security
                                                   •   Disposal  of Purge Water
•  Nonaqueous Phases   —•
                                                   •   Casing Material
•  Weather Conditions
      % ."-T/I A   Vrrrs-f.

                                                   •  Other
                                                                          re
                                                      Dedicated Equipment   /-^ //
                                                                                tf "

-------
                                   VERSAR WELL MONITORING SHEET
             Date:  Beg.
Site Name/Case No.
 Well No./Location
  SMO No./Fac
                                        ? //-'  ^
           End
                                                                J 2
                                              i 3 <'•"-/  //?7     CtAJM —    /lM ( ^
                                    5V*7 - ^    ____
                          . No.   C \ "" I 5 . ^  / M ^P1 ~ k ^^ /
I    1.  Well Measurements
        Well Diameter  (inner)
        Inner Casing Ht.
        Outer Casing Diameter
        DTW
        Total Depth
        Water Column Length
        3 Casing Vol
        Vol. Purged
4.  Sample Methods
    •  Bailer  	
       Bladder 	
       Other   _
       Lot No.
                                               •  Time Beg.
                                               •
                           End
       Depth Sampled  vpV
       Sample Volume
    2.  General Observations
        Organic Vapors  (HNu,  OVA,  TIP)
5.  Notes
Sediment   /\/ '"V
Color
Odor
                           CA.QJ3M
     3.   In Situ Measurements
         Temperature
         Conductivity
         pH
         Turbidity
               (Time)-  3_
        Temperature    -^-C -C.'
                     -HSVV:
        Conductivity "
        pH
        Turbidity
               (Time)   1 /<
-------
                               VERSAR WELL MONITORING  SHEET
                                                          End
                                   -*
I.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged
                             2
                               . Q	>	
          SMO No./Fac. No.    Q I  ft(% 4/Vv\(VA (c^l'jf^ G~ iQ
                           1&3
                                          />
                                               4.   Sample Methods
                                                   •  Bailer  	
                                                      Bladder _
                                                      Other   _
                                                      Lot No.
                Time Beg.
                                                                         End  J 1 1  ,
                                                      Depth Sampled
                                                   .  Sample Volume   Jel.
                                                                                 a.
2.  General Observations
    Organic Vapors (HNu, OVA, TIP)
         /}
    Sediment
    Color 	
    Odor
                  A/A
                    jy-i.
3.   In Situ Measurements

          (Time)  1 // y<"    2_
    Temperature    _^Z_2LJL.
-------
                               VERSAR WELL MONITORING SHEET
                Date:   Beg.
   Site Name/Case  No.   	<
    Well No./Location
      SMO No./Fac.  No.   ___t
                                                          End
                                            <* •'--'•/
                                                             C Jy\MA -
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
                              -1

/Q| .C
                              /jO >
                            //
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged

2.  General Observations
    Organic Vapors (HNu, OVA, TIP)
                        ib (   /t_.^.V
    Sediment
    Color
    Odor
3.   In Situ Measurements

          (Time)  1 /# j? ->
    Temperature    /7 f • T
    Conductivity   / 6 V (9
                           <•
Turbidity

      (Time)  3_
Temperature
Conductivity
PH
Turbidity
                                          4.  Sample Method!
                                              •  Bailer
                                                 Bladder
                                                 Other
                                                 Lot No.
                                                 Time Beg.  fo/3
                                                 Depth Sampled
                                                 Sample Volume
                                                                         End
                                                                               6>
                                                                        -.^   /6 A.
                                               5.   Notes
                                                   •  Well Security
                                                   •  Disposal of Purge Water  f^-f, .L-,. .,(
                                                     Nonaqueous  Phases
                                                      Dedicated Equipment
                                                   •  Casing Material
                                                  Weather Conditions   ^ -^ ,: -,  ,}-/,_-/
                                                                        "
                                                   •  Other

                                                               S'o. .  /c f
                                                                                     U'./.o //I
-------
                           VERSAR WELL  MONITORING SHEET
                                                           °\
                     Date:  Beg.      /,/- __   End
        Site Name/Case No.    / '? * Q    /7   "Z-A _______ 4
          SMO No./Fac. No.   Q ~ /33O   jW$A  63Q/   Q-
                                                                -F:A\C(U
1.   Well Measurements
    Well Diameter (inner)    O<
                t           ~ '
    Inner Casing Ht.       	
    Outer Casing Diameter    g
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged
                        (r;5t-Cf
                                             I  •  Time Beg.     .     End
                                             , •  Depth Sampled  TN&*I h
                                             '' «  Sample Volume    rri   V ^ «•
                                             ''                            ^-J
                                 U
2 .   General Observations
Organic Vapors  (HNu, OVA, TIP)
             A   /
             /V  -^
    Sediment 	
    Color     C  [r _(.-j-~
    Odor
3.  In Situ Measurements

           (Time)   1
    Temperature
    Conductivity    ( (~ rS
    pH
    Turbidity
                   > - 1,
                n~>. T" yj ^ ;
       (Time)  3 /Tc4   4_
Temperature
Conductivity
pH
Turbidity
                       US -
                                           5 . ,  Notes
                                                 '' »  Well Security   [OCJC
                                                  Disposal of Purge Water
                                               »  Nonaqueous Phases
                                               •  Dedicated Equipment  V\)\LlA   (_}\
                                                  Casing Material
                                                   »  Weather Conditions
                                                          .QSV
                                                      .
                                                  Other
                                                         VV
-------
                            VERSAR WELL  MONITORING SHEET
Date:
Site Name/Case No.
Well No. /Location
SMO No./Fac. No.
Well Measurements
Well Diameter (inner)
Inner Casing Ht.
Outer C. sing Diameter
DTW
Total Depth
Water Column Length
3 Casing Vol £
Vol. Purged
General 'Observations
Beg.  M '- F mp f ( i A L
.y' v'
(\_ \ '^1- / p\Q (\-- ^^-/ Cv -1 (^
4. Sample Methods
., XA
X • Bailer
Bladder I/"
"X " S-U.C I Other
•70 v O 0 ~--\OC_ Lot No.
fo??).O " G» *^ • Time Beg. \rV^<^T End |(4f. • Depth Sampled \o\c.cVU'— rV-v"
?v Mv Yo - \A\va,\S « Sample Volume <\s / lO^//0(^'i
^,...//i< ' 0
^
5. Notes
Organic \Vapors  (HNu, OVA, TIP)
                                                                          /    /- f
                                                       Well  Security    > .-.,.-/ ...
                        s
    Sediment    Aj
    Color     (?A£..
    Odor      .'\)
                                                   Disposal  of Purge Water
                                                        --•  r
                                                       ^UAfrtsCjl—	
                                                •  Nonaqueous Phases
3.  In Situ Measurements

           (Time)   1  />"2.:
    Temperature    ^ 4, />'
    Conductivity     // • ?/
Turbidity
                                                   Dedicated Equipment   /.^s^ ///(^ ,-
                                                •  Casing Material
                                                •  Weather-Conditions   /?   /-/ _, ^, '
                                                    •  Other
                                                              A •(•   \^
                                                           .9.    iTVC-r.x    .9  ^

                                                                         \ - v. --• K
          (Time)   3 \ ; ^;
    Temperature    J (^-^<
    Conductivity    \.-j--)-^
    pH              ^.."!j
    Turbidity       ^» \  'V
                                            ^'
                                             \
-------
                              VERSAR WELL MONITORING SHEET
                    Date:  Beg.
       Site Name/Case No.  	
        Well No./Location  	
         SMO No./Fac. No.  __
                                                     End
1.  Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged  />./

                                    jfi
                                   /f'.
                                       ;* <•/\. ?J-.r.jf.«.:/
                                                   •  Other
                                                                                           «•
                                                                                          -a
                                                                                        A'H_
                                                          T*-/-
                                  ,-,0 ,\
-------
VERSAR WELL MONITORING SHEET
                     Date:  Beg.
        Site Name/Case No.  	,
         Well No./Location
          SMO No./Fac. N<
                           End
                                   >;    .'
                             vl'M '   ^A\-l(X.C
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged

2.  General Observations
    Organic Vapors  (HNu, OVA,  TIP)
    Sediment
    Color 	
    Odor
3.   In Situ Measurements

          (Time)  1 /.*? ?
    Temperature      ,' •?. / t"
    Conductivity     *? •
                                          End
                5.  Notes
                    •  Well Security    L-- ^  &/?

                    •  Disposal of Purge Water   /^- ..  .^, /_
                       Nonaqueous  Phases
                       Dedicated  Equipment
                     •  Casing Material
                     •  Weather Conditions
                     •  Other  / F^. //
-------
                              VERSAR WELL MONITORING SHEET
                    Date:  Beg.
       Site Name/Case No.    £'??>S''~
        Well No./Location
         SMO No./Pac. No.
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged

2.  General Observations
                                      .
                            }£j  ~fr  .-,-..,/
                            /  ^   7^   ~f~^ *
 )rg,anic V;
 JCL
    Organic Vapors (HNu, OVA, TIP)
              ^M' '
    Sediment
          '~V"
Color    L,/^ ?//•

    Odor
3.   In Situ Measurements

          (Time)  1 I b (  j
    Temperature     r\\
    Conductivity    \ "^ \ O

    Turbidity
          (Time)  3
    Temperature
    Conductivity   \ V IS
    pH             __""). 3.
    Turbidity
                                                     End
                                                   jCi!

                                             4.  Sample Methods
                                                 •   Bailer
                                                     Bladder
                                                     Other
                                                     Lot No.
                                              •  Time Beg.
                                                                        End   |%3C
                                                     Depth Sampled   /3/A.t/fS  /&/*•
                                                                     **          «--r
                                                  «  Sample Volume
                                                                          r    &
                                              5.   Notes
                                                                      /   /' r   /
                                                  •  Well Security   / <.;,>/
-------
                               VERSAR WELL MONITORING SHEET
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol . Purged
             Date:   Beg.
Site Name/Case No.
 Well No./Location
  SMO No./Fac. No.
                              5~*y*7
                               1
                            &„
                                                        End
                                                       C
                                                             ^) //
                                                       $? / <
                                             4.
                                                rr
                                          Sample Methods

Bafi
Bl|
Ot»
jler
l.dder
|er
                                                               V
                                                     Lot No.
                                             Tinje Beg.
                                             Depth Sampled
                                             Sarnple Volume
                                                                        End
14> ^
2.  General Observations
    Organic Vapors (HNu, OVA, TIP)
                                              5.   Notes'*
                              U, .
    Sediment""
    Color   C". \ :.;
    Odor

3.   In Situ Measurements

          (Time)
    Temperature
    Conductivity    /MSQ
    pH
    Turbidity

          (Time)  3
    Temperature
    Conductivity    \ j?3.3
    pH
    Turbidity
                                              Well  Security
                                                                       /    -  t    j^~^
                                                                       ^-,  /,,..   (  <- ^
                                                     Disposal of Purge Water
                                                   •   Nonaqueous  Phases
                                                   • . Dedicated Equipment  A/-.*// -'
                                                      Casing Material
                                                   •  Weather Conditions
                                                                           .-.-;./
                                                      ~~~~   X  <— 7
                                                   •  Otherr   /-»//
-------
                              VERSAR WELL MONITORING  SHEET
                    Date:  Beg.
       Site Name/Case No.
        Well No./Location
         SMO No./Fac. No.
                                                         End
                                         yy /-/>;
1.   Well Measurements
    Nell Diameter (inner)
    jinner Casing Ht.
                               ''iJk-
i                       rv ('( c /    i
Outer Casing Diameter   &   J-f-gg. (
!'                      *7^— -7 /   T~
DTW
Total Depth
Water Column Length
ii
;p Casing Vol
yol. Purged
                                   ^ S> 7T
                            '~|
                                TJ
    i
2.  General Observations
    Organic Vapors  (HNu, OVA, TIP)
      ff A) c)  A
     Sediment
     Color  	(
     Odor
3.  In Situ Measurements

           (Time)  ijj
    Temperature
    Conductivity
    pH
    Turbidity
           (Time)  3
     Temperature
     Conductivity   M T~^
     pH
     Turbidity
                          c
                          .C
4.  Sample Methods
    •  Bailer  	
       Bladder 	I
       Other   	
       Lot No.
                                                     Time Beg.
                                                     Depth Sampled
                                                     Sample Volume
                                                                        End   1^30
                                                                           ''\^. JU->

                                              5.  Notes
                                                     Well Security   /~,?- (<">-,.
                                                      Disposal of Purge Water
                                                     Nonagueous Phases    /?
                                                    - Dedicated Equipment
                                                      Casing Material     A/
                                                   •  Weather Conditions
                                                      Other
-------
                                  VERSAR WELL MONITORING SHEET
Date:  Beg.
                                                             End
        Site Name/Case No.    ,£ ^ * (J " / /j
t
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol       3*
    Vol. Purged

2.  General Observations
                                  G? "/"' ^
                                      0
    Organic Vapors  (HNu, OVA, TIP)
     •fr.Aij   .   A'H' '
        Sediment
        Color 	
        Odor
                                       J
 3.   In Situ Measurements

                     ; r- 1~>
           (Time)   1 ((. S^    2
     Temperature     \c"\ ^ Vc_
     Conductivity   ) >06
     PH             1.^
     Turbidity       H 0  .'J i 'J
               (Time)   3  11 -- ^>    4
        Temperature     Al •• [ C
^P     Conductivity
         Turbidity
                                    (AJM-
                                                                                   AL
                                                                               7
                                                  4.  Sample Methods
                                                      »  Bailer  	
                                                         Bladder
                                                         Other    /[Tr ///"/
                                                         Lot No.
                                                         Time Beg.  J 3<^f     End
                                 Depth Sampled-
                                                                i    ,
                                                       «   Sample Volume  .
                                                   5.  Notes
                              •  Well Security
*
•
• ,
•
^./
Disposal of Purge Water

Nonaqueous Phases — —

Dedicated Equipment ^c/s
-> S >T£SS!1
Casi'ng Material ^ /*
+ ' *>\/
-------
                              VERSAR WELL MONITORING SHEET
                 Date:   Beg.
    Site Name/Case No.     fa
     Well No./Location
                                                         End
      SMO No./Fac. No.
1.   Well Measurements
Well Diameter (
Inner Casing Ht
Outer Casing Di
                   Inner)
                   ameter
DTW
Total Depth    f
Water Column Length
3 Casing Vol
Vol. Purged
                                 /?? - S~ G      I J A!M ^ "V vVsi_
3. In Situ Measurements
(Time) 1 |\4.M ZC^MT-^
"^\ if / /
Temperature «-nXj-A ( "j • b /
Conductivity (iRl iMO, S PUTf^
d \ -V "t \ J
Turbidity >V, ^ J\f\ I
--, — /
(Time) 3 /U^M 4 "^
Temperature ^C- \ o (
( ~~\ <~~ \ ° rl
Conductivity \? ~r 3 Vjy\(^\U\'
PH C\.^~ }
• • Dedicated Equipment ^ -Y * ,'/• '
^ x~/^i
• Caiinq Material ?"/>1 ^7^~ . ^
f),7fc7-- P\f'c
• Weather Conditions ^ "sisl-f ?/? $
/),"/> ^
/ r~ // s^- / x*
• Other ' >/(/// )s- A..- 
' ' " x., x' y
'P%+,:,/'. ^ ' * J
1 J
e.

Turbidity ;< ^ Aj |(y — /
-------
                              VERSAR WELL MONITORING_SHEET
             Date:   Beg.
Site Name/Case No.
 Well No. /Location
  SMO No./Fac. No.
                                                         End
   1.  Well Measurements
       Well Diameter  (inner)
       Inner Casing Ht.
       Outer Casing Diameter
       Total  Depth
       Water  Column  Length
       3' Casing Vol    3$. /3
       Vol. Purged
                                                                         ill  AC-
                                  -
                                 < '  "»'     "^ ' //
                               0-
                             / S V
                                       4.   Sample  Methods
                                           •   Bailer   	
                                              Bladder 	-
                                      (        Other
                                              Lot  No.
                                           •   Time Beg.
                                                     Depth Sampled
                                                     Sample Volume
                                                                             /
                                                                            End

2.
        General Observations
        Organic Vapors (HNu, OVA,  TIP)

                            t
        Sediment _^^_
        Color    C^.f£
        Odor
    3.  In Situ Measurements

              (Time)  1
        Temperature
        Conductivity    ( C' S 0
        pH             "7- 3
        Turbidity       ^ j  •ij'
                          c-
               (Time)  3
        Temperature
^^     Conductivity
        PH
        Turbidity
                     3 J ^vjT
                                              5.  Notes
                                        -J
                                                                     J     l^(
                                                   •  Well Security  ./ S>f'J^/*<>   Si
                                                                    r       is
                                                      •  Disposal of Purge Water   ':
                                                      Nonagueous  Phases
                                                          Dedicated  Equipment
                                                                               ^     /  *~ ' -~l -
                                                                              }/    s^-tlT~r
                                                sin
                                                      Casing Material
                                            •  Weather Conditions
                                            •   Other
                                                                                      *_


                                                               Act
-------
                               VERSAR WELL MONITORING SHEET
                    Date:  Beg.
       Site Name/Case No.  __
        Well No./Location
          SMO No./Fac.  No.  (2_
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged

                            2
                                                         End
                                              2.
4.  Sample Methods
    •  Bailee  	
                                                    Other
                                                    Lot No.
    •  Time Beg.  / / ^ j.
    •  Depth Sampled
    «  Sample Volume    fa
                                                                        End

                                                                               cV tHiW
    General Observations
    Organic Vapors (HNu, OVA, TIP)
    Sediment
    Color
    Odor
3.   In Situ Measurements

          (Time)  1 tfif
    Temperature     /?-.£'
    Conductivity    /'/W.
    Turbidity

          (Time)  3
    Temperature
    Conductivity

    Turbidity
                     2,
                              4  A ^ '_
                               >?/
                               Jj 20
                                              5.   Notes
                                                  •  Well  Security
                                                                            s~
                                                     Disposal of Purge Water
                                                     Nonaqueous Phases
                                                      Dedicated  Equipment
                                                   •   Casing Material
                                                      Weather  Conditions
                                                      Other
-------
                              VERSAR WELL MONITORING SHEET
                     Date:   Beg.
        Site Name/Case No.   	
         Well No./Location  	
          SMO No./Fac. No.
<2_L
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
    DTW
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged

2.  General Observations
    Organic Vapors  (HNu, OVA, TIP)
                                    J-f
       /?
        7
        fe?; )
    Sediment
    Color 	
    Odor
                    C
3.   In Situ Measurements
           (Time)
     Temperature
     Conductivity
     pH
     Turbidity

           (Time)
     Temperature
     Conductivity
     pH
     Turbidity

                                                         J
                                                       (-, 3 6  - 4
              4.  Sample Methods
                  •  Bailer  	
                     Bladder 	f;
                     Other   	
                     Lot No.
                  •  Time Beg.
                                                     Depth Sampled
                                                     Sample Volume
                                                                        End  /O
                                              5.  Notes
                                                  •  Well Security
                   •   Disposal  of  Purge Wa^er 	O
                         £t (it>t/,i^tX.__
                                                   •  Nonaqueous Phases
                                                                                •A
                                                   • .  Dedicated Equipment
                                                   •   Casing  Material
                                                      Weather  Conditions
                                                   •   Other   F?/.i'/    }
-------
          VERSAR WELL MONITORING SHEET
Date:
                                    End
Site Name /Case No. X^ V / - Y^f/^
Well No. /Location jL.~ if
/
SMO No./Fac. No. (1 1 3 4# /7//}1/ %>
<•(/ ' ' / I
/
1. Well Measurements 4.
Well Diameter (inner) % /7^E//fo-^- \
/ \
Inner Casing Ht. — ' jl
-t- I \
Outer Casing Diameter -? rith' / \\
DTW./^tA^€- 3?-^
Total Depth $-/t 5 f
Water Column Length CyO- / |(
ft /) .trn'Vh jLc^#^-"Tk> //^ - ~^O !
•^^ ,i
Vol. Purged /) f/1 — '.;
2. General Observations 5:
Organic Vapors (HMu, OVA, TIP.)
• UO fS/->i — fie •c/-£l
n //.^,^ - /^.-// /t^,.£-*
y/

/ JZ,:/.tT n-l
// /
Sample Methods
• Ba i 1 e r £* tf V VC &«' 'cS~ * ^/fc //C^
Bladder
Other
Lot No.
• Time Beg. / ? V< End /'/'Zt
• Depth Sampled jb>) // *-a //* - X'-' /*-/ ^ ,/
» Sample Volume ^ ^p //'*»'•
'X
Notes
• Well Security /?£'/} - ^/?fsi~
-/-.-,/• \/-s /-: 7* / /"' /{./< < 	
• Disposal of Purge Water /?.,-/. /C
1^ A ^-- s'J\ss /•*— -•*/>.'. /?Tc
/
3. In Situ Measurements — /l^/l J^.^'i\.
(Time) 1 2
Temperature
Conductivity
oH
Turbidity
(Time) 3 4
Temperature
Conductivity
PH
• . Dedicated Equipment # ' /VXC' /j!,//;

• Casino Material ./7-/T/ ; /<[/Cl_
^
• Weather Conditions ^>/x; ;> X.x^/^
5"^x-7X7-X
• Other ' /^y// <^ /"






Turbidity
-------
                               VERSAR WELL MONITORING SHEET
             Date:   Beg.
Site Name/Case No.     /?
                    	&< i
 Well No./Location  	
  SMO No./Fac. No.   _c2_

                                                         End
                                        L -
                                /I  3<*  /  Ms?A  6 I
1.   Well Measurements
    Well Diameter (inner)
    Inner Casing Ht.
    Outer Casing Diameter
            A-jt^€-
    DTW-
    Total Depth
    Water Column Length
    3 Casing Vol
    Vol. Purged
                     /V " /?!/
                     J14.
                                          4.  Sample Methods
                                              •  Bailer/ 
-------
APPENDIX B
-------
                            B-l
     dous  Substance List
VCLATILES

chloromethane
bronomethane
vinyl chloride
chloroethane
methylene chloride
acetone
carbon disulfide
1,1-dichloroethene
1,1-dichloroethane
trans-1.2-dichloroethene
chloroform
1,2-dichloroethane
2-butanone
1,1,1-trichloroethane
carbon tatrachloride
vinyl acetate
bromcaichioromethane
1.1.2,2.-: etrachloroethane
1,2-dichloropropane
trans-i,3-dichloropropene
trichloroethane
dibromochloromethane
1,1,2-trichloroethane
benzene
bis-1,3-dichloropropene
2-chioroethylvinyiether
bromoform
2-hexanone
4-methyl-2-pentanone-
tetrachloroethene
toluene
chlorobenzene
ethyibenzene
stvrene
SEMIVOLATILE COMPOUNDS

acenaphthene
2,4-dinitrophenol
bis(2-chloroethy1)ether
2-chiorophenol
1,3-dichlorobenzene
1,4-dichiorobenzene
benzyl alcohol
1,2-dichlorobenzene
2-methylphenol
bis(2-chloroisopropyl)ether
4-methylphenol
n-nitroso-di-n-propylamine
hexachloroethane
nitrobenzene
isophorone
2-uitrophenol
2.4-dimethylphenol
benzoic  acid
bis(2-chloroethoxy)methane
2,4-dichlorophenol
1-2.4-trichlorobenzene
Naphthalene
4-chioroaniline
hexachiorobutadiene
^~chloro-3-methyiphenol
2-methylnaphthalene
^exachlorocyclopentadiene
21 4,6-trichlorophenol
2•4,5-trichlorophenol
4-nitrophenol
•iibenzofuran
'1, 4-dinitrotoluene
2,6-dinitrotoluene
diethyIphthalate
4-chlorophenyl-phenylether
fluorene
4-nitroaniline
4,6-dinitro-2-methylphenol
n-nitrosodiphenylamine(1)
4-bromophenyl-phenylether
hexachlorobenzene
pentachlorophenol
phenanthrene
anthracene
di-n-butylphthalate
flucranthene
benzidine
pyrene
butylbenzylphthalate
3.3-dichlorobenzidine
benzo(a)anthracene
bis l. 2-ethy Ihexyi) phthalate
chryaene
di-n-octyl  phthalate
benzo(b)fluoranthene
benzo(k)fluoranthene
benzo(a)pyrene
-------
                                    B-2
      1-chloronaphthalene
     2-nitroaniline
     dimethyl phthalate
     acenaphthylene
indeno(1,2,3-cd)pyrene
dibens(a, h)anthracene
benzo(g,h,t)perylene
                                                                                 -9':
3-nitroaniline
     PESTICIDES/PCS'S

     alpha-BHC
     delta-BHC
     heptachlor
     heptachlor epoxide
     dieldrin
     endrin
     4,4-DDD
     endosulfan sulfate
     methoxychlor
     chlordane
     aroclor-1016
     aroclor-1232
     aroclor-1248
     aroclor-1260

     METALS AND OTHERS

     aluminum
     antimony
     arsenic
     barium
     beryllium
     cadmium
     calcium
     chromium
     cobalt
     copper
     iron.
     lead
     cyanide
     ammonia
     chloride
     nitrate
     purgeable organic  carbon
     purgeable organic  halide
beta-BHC
gamma-BBC(lindane)
aldrin
endosulfan I
4,4-DDE
endosulfan'II
endrin aldehyde
4,4-DDT
•rndrin ketone
toxaphene
2roclor-1221
arocior-1242
aroclor-1254
magnesium
manganese
mercury
nickel
potassium
selenium
silver
sodium
thallium
tin
vanadium
zinc
percent solids  (%)
=ulfates
total organic carbon
total organic halide
total phenols
1 -9?.
                 Meld Parameters

                 pH

                 Specific  conductance

                 Temperature

                 Turbidity
-------
APPENDIX C
-------
-------
    oi O  oa
    ^ 
-------
APPENDIX D
-------
FROM CWM RCRA Part B
      February 1986                -18-                    853-3107

      3.0  EUTAW AQUIFER MONITORING WELL NETWORK
           3.1  Previous Well Network
           Prior  to September,  1985,   the  Emelle  Facility Eutaw
      Aquifer  monitoring  well network consisted  of eight wells,
      one of which was located off-site (RCRA Well 1). Wells 1, 2,
      3, and 4 were originally drilled  as  domestic or stock water
      supply  wells  before  or  shortly after  the   facility  was
      opened. There is  no documentation  of  the  construction of
      Wells 1, 2,  3,  and 4 , however,  indications are that these
      wells were completed with a short section of surface casing
      (typically about 20  feet)  in the soil  and weathered chalk,
      an open borehole through  the  Selma  Group,  and  possibly  a
      section of  perforated pipe  set in the Eutaw Aquifer.

          .Wells  5,  6,  7  and  8  were  installed between  December
      1982  and May 1983 by Graves  Well  Drilling  Co. under  the
      supervision of  Colder Associates.    The  installation  pro-
      cedures  for these wells  are outlined  below:
          1.   The  4"  diameter steel  casing  joints are  washed
               with  acetone to  remove  threading lubricant.   All
               casing  is then  cleaned  with high temperature  and
               pressure steam.
          2.   Rotary  drill a 6 in. diameter hole,  with water as
               the circulation  fluid,  to the first  sand stringer
               of the  Eutaw Formation.
          3.   Backfill the  drillhole  with  3   ft.  to  5  ft.  of
               drill  cuttings  to  prevent  grout clogging  of  the
               Eutaw  sands.
          4.   Ins-tall the  4 in. diameter steel casing.
          5.   Inject   Portland   cement   grout  under   pressure
               through the  4, in. casing  and up the  well bore.  A
               1  ft.  to 2 ft.  grout plug is left in the bottom of
               the casing.
                                                           New Page
                                   Auociotw      .            February 24,1986
-------
FROM CWL RCRA Part B
       February 1986                -19-                    853-3107
            6.    After the grout sets,  drill through the grout plug
                 with a  4 in.  rotary  tricone  bit  and  thoroughly
                 flush the drill cuttings.

            7.  ..  Advance  the 4  in.  drillhole  40  ft.  to  50  ft.
                 beneath the  end  of the 4  in.  casing  or until the
                 upper sand zones of the aquifer are encountered.

            8.    Install 40 linear ft. of 2 in.  diameter continuous
                 wrap  stainless  steel  screen  (0.008  in.  slots).
                 The well screen is joined to the 4 in. casing with
                 a lead swedge seal.

            9.    Develop the well by air lifting until the water is
                 clear  (2  to 6 hrs.).   Development  collapses the
                 Eutaw sands around the screen,  producing a natural
                 sand pack.

            10.  Cover the  well head with  a 6 in.  diameter steel
                 locking  cover  set in  a  2  ft.  by  4  ft. concrete
                 pad.

       Well locations are presented in  Figure 8 and well construc-

       tion details  are  presented in Figures 9 and  10.   WMI Moni-

       toring Well  Information Forms  are presented as  Appendix C

       and appropriate data  on  each  well  is summarized in Table 2.

       Wells 6,  7, and  8 were screened  in the uppermost  (Tombigbee
       Sand Member) "sand unit in  the  Eutaw Aquifer,  while  Well. 5

       was screened  in  an  intermediate  sand  unit  about  150 feet

       lower.   Wells 5,  6,  and 7 are  downgradient of  the  Erne lie

       site waste disposal areas while Well 8 is upgradient.


            3.2  Modifications  to  Eutaw  Aquifer  Monitoring  Well
                 Network

            In  Septsaber, 1985, a  program was undertaken to modify
       and upd*t» th«*. Eutaw^Aqyifer monitoring well network.   The
       effort-'tflMC; to include the following tasks:


                 Seal and abandon inactive,  uncased wells 2,  3, and
                 4.
                                                          New Page
                                                          February 24, 19«<
-------
FROM CWM RCRA Part B
         February  1986
-20-
853-3107
                                               TABLE  2

                           EUTAM AQUIFER MQHiTQRIHS MELL IKFGnnATlGH, EJ1ELLE FACILITY,ALABAHA

                      HELL »            WELL 5      MELL 6     HELL 7     MELL 8     HELL 9
NORTHING
(FT)
EASTING
(FT)
UP/DOWN
GRADIENT
COLLAR
ELEV.(l)
6RQUNO
ELEV.(l)
TOP OF
EUTftKU)
TOP OF
SCREEN (1)
BOTTOM OF
SCREEN U)
HELL
DEPTH 12)
TOTAL
QEPTH12)
6432.00

13:04.00

DOWN

211.43

211

-451

-480

-520

732


937
15729.30

7821.60

OOUM

162.94

164

-446

-442

-482

645


650
13121.90

8187.00

DOWN

207.62

206

-453

-476

-516

723


708
11168.40

550.10

UP

140.93

131

-514

-537

-577

718


692-
13266.18

9345.02

DOUN

211.37

209

-453

-482

-522

733"


725
                            (1)  ELEVATION IN FEET HSL

                            (2)  TOP OF CASING TO BOTTOM OF SCREEN

                            (3)  BftOUNB SURFACE TO 80TTON OF BORINS
                                                                                      New Page
                                                                                      February 24, 19P«
-------
FROM CWM RCRA Part B
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-------
FROM CTM RCRA Part B


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9* CTAIMI COC CTCCI
WIRE WRAPPED SCREEN, 0.008" SLOTS
MONITORING WELL
CONSTRUCTION DETAILS
\ Golder Associates CHEMICAL WASTE MANAGEMENT, INC. FIOU" 10
-------
FROM CWM RCRA Part B
        February  1986                -24-                    853-3107

            -    Rework Well 5 to reset the  screen in the uppermost
                 sand  unit of  the Eutaw  Formation, so  that head
                 levels  in  that  well  would  correspond   to head
                 levels  in  the  other  Eutaw  Aquifer  monitoring
               • • wells.
            -    Install  a  fourth  downgradient  monitoring  well,
                 Well 9.
                 Assemble  geologic,  hydrogeologic  and well com-
                 pletion information  in  support of the certificate
                 of compliance.
            This report contains  the  information  assembled for the
       final task.  Of  the other tasks, all  are  complete  with the
       exception of sealing and abandoning wells  2 and 3,  which is
       currently planned to take place in late February, 1986.

                 3.2.1  Sealing Well 4
            Well  4 is a flowing artesian well which is adjacent to
       Well 8,  an active monitoring well.   Special precautions were
       therefore  required for sealing this we*l. Prior to grouting,
       a 4" bit  was run to the bottom of  the hole  to  insure that
       the entire open  interval could be grouted.   Near the bottom
       of the Selma Group,  the bit encountered what is probably the •
       top  of  the  perforated  pipe  which  extends  into the  Eutaw
       Aquifer.  A plug  was  set at the  top of the  pipe  to  insure
       that the  cement  did not  invade the  aquifer and the adjacent
       monitoring well.   The hole was then grouted by  the  tremie
       method.  Similar  procedures  will be  used in  sealing wells  2
       and  3 except that  the plug will not  be  used. Detailed well
       sealing procedures are presented below:

            1.    Mobilize workover rig to the well site.
            2,    Complete required  information on the Well Sealing
                 Form except depth which will be  measured with the
                 tremie pipe.
            3.   Photograph the well  head.
-------
FROM CUM RCRA Part- R .,._
       February 1986  .              -25-                    853-3107


            4.    Remove  the  steel protective  cover and  all  other
                 surface appurtenances.

            5.    Install the grout tremie pipe to the full depth of
                 the well; record depth.

            6.    Pump the computed  volume  of  low shrink  cement
                 grout into the  well  while maintaining submergence
                 of the end of the tremie  pipe at all  times.   Pump
                 additional grout as  required to  show  good return
                 at the surface.

            7.    Allow grout to  settle for about  12 hours and add
                 grout to fill the hole to the surface.

            8.    Remove all  surface  fixtures,  grade  the  area to
                 drain away from the  well and take  a  final photo-
                 graph .

            9.    Complete  remaining  information  of Well  Sealing
                 Form.


       The well  sealing  form  completed  following the  sealing of

       Well 4  is  included as  Appendix D.   Similar forms  will be

       completed for Wells 2 and 3,  when sealed.
                 3.2.2  Reworking Well 5

            In order to insure that head levels measured in Well  5

      were  comparable to head levels  measured in other wells,  the

      screen  was removed and reset  in the upper  sand  unit  of  the

      Eutaw Aquifer.   The procedure was as follows:


            1.    Mobilize equipment  to  well  site  and  run  tubing
                 into  hole with  left hand threaded nipple on bottom
                 of  tubing and screw into 4 in. X 2 in. lead seal.

            2.    Pull   screen,  riser  pipe  and  lead  seal  out  of
                 hole.

            3.    Run tubing  back into  hole and  inject  16  sacks of
                 cement from 937  ft.  to 740 ft..

            4.'   Withdraw tubing to 747  ft. and wash with  water to
                 remove grout from  interval to be screened.
                                                              New Page
                                                              Fehman/ ?*
-------
FROM CWM RCRA Part B
      February 1986                -26-                     853-3107


           5.   Allow  cement to  cure overnight.   Measure bottom
                depth the next morning.

           6.   Re-install  screens  and  lap. pipe  with  new  lead
                seal.

           7.   Swedge lead seal and  develop well by  airlifting.


           The procedures  used to  rework Well  5  required  signi-
      ficant use of downhole tools which  have a  high  potential for

      introducing  oil  and  grease  into  the -well.   This  well  is

      therefore  suitable  for  obtaining  water  level  information

      only, and should not be used  for water quality  assessments.


                3.2.3  Installing Well  9

           After  reworking  Well  5,  an  additional   downgradient
      monitoring  well was  installed.    Well  9 was  installed  to

      provide additional water quality  data and  to define areas of

      eastward and northward gradients in the Eutaw Aquifer beneath

      the  site.    Figure  10  shows  the  completion  details  of

      RCRA  Well  9.   Well 9  was installed  by  the following  pro-
      cedure:
            1.    Wash  the casing with high pressure water to remove
                 dirt  and  rust.    Swab  the casing  inside  and  out
                 with  reagent  grade  acetone  to  remove  threading
                 lubricant.    Immediately  follow  with  a  potable
                 water rinse.  Finally,  wash  with  high temperature
                 and pressure steam.

            2.    Rotary  drill  a  6  in. diameter hole  with water as
                 the circulation  fluid,   to the top  of  the  Eutaw
                 Formation

            3.    Backfill  the  drillhole  with 3  ft.   to  5 ..ft.  of
                 drill cuttings  to prevent  grout  clogging of  the
                 Eutaw sands.

            4.    Install  the 4 in.  diameter steel casing.

            5.    Inject   low  shrink  grout   (Halliburton   50/50
                 poz/mix) under pressure through the  4  in. casing
                 and up the well bore.
                                                             New Page
                                                             February 24,1986
-------
FROM CWM RCRA Part B
       February 1986                -27-                    853-3107
            6.   After  the  grout  sets,  drill  through  the  4-in.
                 steel pipe  with a nominal 3 3/4 in. rotary tricone
                 bit and thoroughly flush the drill cuttings.

            7.   Advance the drillhole  to  about 50 ft.  beneath the
                 end of the  4 in.  casing.

            8.   Install 40  ft. of 2 in.  diameter  continuous  wrap
                 stainless steel screen (0.008 in.  slots)  and about
                 20 ft.  of  2 in.  stainless steel  lap  pipe.   The
                 well screen and lap pipe  are  joined to the 4 in.
                 casing with a  lead swedge seal.

            9.    Develop the well  by  air  lifting using  filtered
                 compressed  air  until the water is  clear (about 1.5
                 hrs.).   Development  collapses  the  Eutaw   sands
                 around the  screen,  producing a natural  sand  pack.

            10.   Cover the  well head with a  6 in. diameter  steel
                 locking cover  set  in   a  2 ft.  by 4 ft.  concrete
                 pad.

            11.   Survey the  plan location  and  MSL  elevation  of the
                 well.

      Following  the  installation  of   Well  9,  water  levels  were

      measured  in  all 5 of the  active  monitoring  wells in  the

      Eutaw  Aquifer.    These  water   levels  and  the  resulting

      potentiometric contours  are  shown on Figure  7.


                 3.2.4  Proposed Well 10


            To provide a well on the downgradient  side  of proposed

       landfill  trenches 23  and 24, Well 10 will be installed prior

       to disposal of waste  i,n  these trenches.  This well will be

       located generally as  shown on Figure 7 and will be installed

       and constructed in the same manner  as  Well  9.   The borehole

       will be geophysically logged prior to placement of the steel

       casing and  after drilling  the   final  depth into  the Eutaw

       Formation. These  logs will  include electric logs,  gamma log

       and neutron log.
-------
t
                                 MCNTTDHING WELL INFOPJIATICN FOPM



               Emelle  Facility,  Sumter County,  Alabama
...
Sate:
Well Nuntoer;    RCRA 5  _ iDate In^all^d:  reworked 9-13-85
Location:   See Drawing 00-150-21
   — Drilling Co./Driller:    Graves Well Drilling
   I
      Supervising CO. : Colder ..Associates	Leg By:  Driller
              Method:  Air/Water  Rotaqfetal Dspth.  937'	^^ pia;6"/4

      Ground El;:   211	;	Standpipe El.:   211.63
                         A II                    (L -I O
      Casing:  Diameter:   	Length:  °  	Material:	

      Screen:  Diameter:  2"	Length:  41'	Slot Si2e:  o.oos"
   —. Water Level:  Initial:  		 24-hour:	         Other:  	
           (Water levels are:   -—    d^pth from ground surface or  ---     elevation msl)

                 This well has  been reworked  and the  open  interval  below the	

                 screen grouted.   The well  ia not suitable for water quality
                 assessment.
                                 Description of Screened Interval



      From*      To*                      Soil Description

       691         73 2              Tomblt?beg Sand ^e^nber. Eutaw  Formation.   Spg

      	      _____„              drillers log for  detailed description of  strata,
                                    *See drawing 107  for well completion details
      *Values are:  x   depth fron ground surface or	elevation msl.
                                                                            New Page
                                                                            February 24, 19*6
-------
August 1983	A-l	824-1308
                                WELL  5
 Depth  (ft.)      	Description	
  0-7      Surface Clay
  7   -  620      Chalk  (Soaps-tone - SS)
620   -  "662      Chalk with Pepper
662   -  680      Eutaw Sand No Cap Rock
680   -  690      Greenish Blue Sand and Scne Soapstone
690   -  699      Soapstone all Way.  Some Fine Sand in Sample
699   -  703      Sand Cut Even
703   -  705      Soapstone Snug Cut
705   -*  708      Sand
708   -  709      Pock 12" Medium Hard
709   -  717      Streaked Sand and Soapstone More Sand in Last - Medium
                  Fine Blue
717   -  719      Soapstcne
719   -  720      Sand
720   -  731      Soapstcne
731   -  733      Sand
733   -  738      Soapstone
738   -  743      Sand
743   -  747      Streaked Sand and Soapstone
747   -  749      Stresksd Soapstone and Sand
749   -  757      Sand Cut Pretty Good in Mica in Sample
757   -  761      Streaked Sandstone and Sand
761   -  765      Streakad Sand and Sana Soapstone
765   -  769      Soapstone
769   -  775      Soapstcne with Small Sand Streaks
775   -  778      Sand with Soapstone Streaks
778   -  787      Sand Fair Cutting. Sana 2" Soapstone Streaks
787   -  797      Sand - Flakey Soapstone in Wash
797   -  810      Soapstone Snug Cut.   Sons Fine Sand in Wash
810   -  811*1     Rock 18" Soft
ail's  -  315      Soapstcne Snug
815   -  817      Sand
817   -  824^     Even Cutting Sand - Medium Fine
824h  -  827      Reck 2V Hard
827   -  845      Blue Medium Sand Lots of Pepper
845   -  857      Soapstone and Sand Streaks
857   -  867      Soapstcne Sore Fine Sand
867   -  877      Soapstcne
877   -  879      Soapstcne
879               Itock 4" Medium Hard
879   -  889      Sand and Soapstone Streaks
889   -  897      Medium Sand
897   -  907      Pock at 903' 2" Soft Rest Sand
907   -  917      Good Cutting Medium Sand
917   -  921      Good Cutting Madium Sand
921               Feck 3" Medium Hard Chattery
921   -  927      Good Cutting Sand Medina
927   -  937      Good Cutting Sand Medium
937               Total Depth
-------
t
MONITORING WELL INFQPMATICN FOPM
    Site:  Emelle  Facility,  Sumter County,  Alabama
    Well Nuntoer;   RCRA 6	Data Installed;    5-24-83
    Location:   See  Drawing 00-150-21	
 -  Drilling Co./Driller:  Graves  Wel1 Prilling
    Supervising CO.:  Colder Associates	Loj By;  Driller
    Drilling Method;   Air/Water RotarTfrtal Depth:   65Q	Boring Dia: 6"/4"
    Ground El;;   164	Standpipe £1.:   162.94
    Casing:  Diameter:_J^	Length;   65°	Material:   9teel
    Screen:  Diameter:   2"	  Length:     40'	Slot Size:   0.008"
— Water Level:  Initial:   ——	24-hour;  -—        Other: ....._--—
         (Water levels are:  ---    cispth iron ground surface or         elevation msl)
                Downgradient well
                               Description of Screened Interval

    From*      To*                      Soil Description
     606       64 6             Tombigbee Sand Member,  Eutaw Formation.   See
                                 drillers  log for detailed description of  strata,
                                 *See Drawing 107 for  well completion details
     *Values are:  x  depth from ground surface or	elevation msl.
                                                                           New Page
                                                                           February 24,
-------
t
                  August  1983
    A-2
824-1308
                                                  WELL 6
                   Depth, (ft.)

                    0.00- 1.75
                    1.75- 64.65
                   64.65-317.00
                   317.00-604.75
                   604.75-606.75
                   606.75-609.58
                   609.58-612.08
                   612.08-615.00
                   615.00-619.58
                   619.58-621.83
                   621.83-628.08
                   628.08-630.40
                   630.40-634.00
                   634.00-639.00
                   639.00-649.58
                Baserlotion
yellow clay
white chalk sticky some brittle
chalk brittle sane sticky
chalk sticky changed to fluid at 400'
chalk sandy with pepper specs
chalk sandy with pepper specs
sand medium loose
sand with chalk
chalk
sand with chalk seams
sand medium loose to loose
chalk with sand seams
sandy chalk
sand medium loose to loose with tight  spots
yellow clay
                                              GolcUr
                                     New Page
                                     February 24,
-------
                               M3JITORING WELL INFORMATION FOFM
   Site:    Emelle Facility, Sumter County,  Alabama'
   Well Nuntoer;   an? A  7	Date Installed;  5-30-83
   Location;  See Drawin8 00-150-21	
- Drillim Co./Driller:  Gravea Wel1
   Supervising CO.;  Colder Associates      Log By;  Driller
   Drilling Method:  Air/Water Rotar^otal Depth;  708	Boring Diai
   Ground El:;  206	Standpipe El.:   207.62
   Casing:  Diameter:  4"	Length:	Material: steel
   Screen:  Diameter;  2"	Length;    40'	Slot Size:  0.008"
	 Water Level:   Initial:   ——	 24-hour;      	Other;  		
        (Water levels are:  — -    depth from ground surface or   	    elevation msl)
   Cairoents;     Downgradient well	
                               Description of Screened  Interval


   From*      To*                      Soil Description

    682         722             Tombicfpee  Sand Member. Eutaw  Format-Inn

                                log for detailed description  of strata
                                 *See drawing 107  for  well completion  details
                 v
   *Values are:	depth fron ground surface or	elevation msl.
                                                                            w Pace
-------
August  1983
    A-3
824-1308
                                WELL 7
 Depth (ft.)

  0.00-  3.50
  3.50-175.00
175.00-230.50
230.50-463.00
463.00-576.00
576.00-626.00
626.00-655.04
655.04-659.04
659.04-667.04
667.04-669.62
669.62-671.00
671.00-676.00
676.00-685.51
681.51-687.50
687.50-693.50
693.50-697.00
697.00-699.00
699.00-708.25
                Description
white chalk sticky
blue chalk brittle some sticky
blue chalk with greenish color brittle
chalk greenish gray sticky changed to fluid
chalk greenish gray sticky
white chalk sane brittle
hard chalk
pepper in clay sandy
hard clay
sand with clay
sand with clay
chalk with clay
medium loose sand
clay
sand madiuca loose
tight sand
clay
tight hard sand
                                                                 Februa
                                                                       ry 24.
-------
                               MCNITORING WELL INFOK1ATICN FORM
                Emelle  Facility,  Sumter County, Alabama
    Well Hunter:    RCRA 8	Data Installed;
    Location;   See Drawing 00-150-21
— Drilling CO./Driller:   Graves  Well Drilling
I    Supervising Co.;    Colder Associates     Log By;     Driller
   Drilling Method; Air/water Rotaryiptal Depth;   692	Boring Dia;6"/4"
   Ground El;;    *3l	Standpipe El.;   140.93	
    Casing:  Diameter;    &"	Length:	Material:
    Screen:  Diameter;     2"	Length:   40>	Slot size; 0.008"
—  Water Level:  Initial:    	         24-hour:  	        Other:
         (Water levels are:         depth fron ground surface or	      elevation msl)
   CaimentS:    Up gradient well	
                               Description of Screened Interval

   From*       To*                     Soil Description
                ?np             Tombigbee Sand  Member.  Eutaw Formation.  See
               	            Driller's log for detailed  description of strata,
                                *See Drawing 107  f nr na 1 I  /%,-imn 7 <> tJ^an  A n f T
   *Values are;   x  depth from ground surface or	elevation msl.
                                                                         New Page
-------
August 1983
    A-4
824-1308
flowing 1/2 GPM
                                WELL 8
 Depth, (ft.)

  0.00-  4.00
  4.00-  7.80
  7.80- 61.89
 61.89-360.00
360.00-379.00
379.00-500.00
500.00-564.00
564.00-620.00

620.00-623.00
623.00-623.25
623.25-627.50
627.50-628.50
628.50-638.00
638.00-651.50
651.50-660.50

660.50-664.00
664.00-679.41

679.41-636.91
686.91-688.00
688.00-688.25
688.25-691.50
691.50-692.41
                Description
clay with brown hard sand
blue clay
white chalk seme brittle some sticky
white chalk some brittle some sticky
chalk sticky - changed to nud pump
chalk sticky
chalk some sticky some brittle
chalk sane  sticky same brittle-sand  seam @
595'
brittle - hard pyrite seam at 612.00'
rock seam
chalk sticky
sandy chalk with pyrite
chalk
chalk with black specs no sand
sand  tight  with medium  least  spots with
green black spots clay
s£ULll reck seams at 669.50' & 675.00'
sand green  with clay  looks  more like blue
marl
sandy chalk
tight chalk
rock seam
sandy chalk
tight sticky chalk
-------
                              MCNTTORING WELL INFORMATION FOFM
   Sitei     Emelle Facility,  Sumter  County, Alabama
   Well Nontoer:    BTBA Q                Date Installed;  10-15-85
   Location:      See Drawing 00-150-21	
- Prilling Co./Drillert     Graves Wel1
   Supervising CO.;  Colder  Associates       Log Byi  Driller
   Drilling Method:  Air^acer Rotariotal Depth:   ?25	Boring Diai 6"/4'
   Ground El;:    209	Standpipa El.:   211.37	
   Casing:  Diameter;    4"	Langth;  673'	Matprial;  steel
   Screen:  Diameter:    2"	  Length:    41*	Slot Size: 0.008"
	 Water Level:  Initial:   		24-hour:   		Other;      	
         (Water levels are:  ~—    dapth frcra ground surface or   	   elevation msl)
                T>n•^J•n^TTnf^^on^• rjgll
                               Description of Screened Interval


    Fran*       To*                      Soil Description

     684        725              Tombigbee Sand  Member.  Etuaw Formation.

                                 Driller's log for detailed description of  strata
-------
November 1985
                     A-5
                         853-3107
                            WELL 9
  Depth (ft.)
   0.00-
   2.50-
 207.00-
 246.00-
 309.00-
 390.00-
 394.00-
 412.00-
 489.00-
 574.00-
 614.50-
 666.75-
 668.50-
 670.75-
 672.75-
  2.50
207.00
246.00
307.00
390.00
412.00

489.00
530.00
614.50
666.75
668.50
670.75
672.75
677.50
 677.50- 682.00

 682.00- 690.20
 690.20- 704.95

 704.95- 718.00
 718.00- 722.00

 722.00- 725.30
                              Description
white chalk
blue chalk brittle
blue white chalk
blue white chalk
chalk gummy
chalk w/ some sea shale
switched to fluid drilling
gummy sticky chalk
gummy sticky chalk
brittle chalk or gummy  chalk
sticky chalk
hard chalk
brittle chalk
green salt Sc pepper sand
med. tight  to tight green  salt  &
pepper clayey sand
med. tight to med loose green salt
Et pepper clayey sand
rock seam
salt Sc  pepper sand  med.  tight  to
med. loose
med. tight  to tight green  salt  Sc
pepper clayey sand.  med. to fine
sand
salt S«  pepper sand  clayey  w/some
shells, med.  to fine sand
med. to tight shaley chalk
                         Gold.tr A*»ociotK*
                                              New Page
                                              February 24.
-------
            WELL  SEALING   FORM
JOB NUMBER_
COLDER  INSPECTOR.
                                 DATE
                  WELL  INFORMATION
DESIGNED WELL DEPTH
DEPTH TO WATFR
CASING TYPE'
                         ft.
          MEASURED DEPTH (H)
          CASING STICKUP	Q.
                              INSIDE  CASING DIA.(D).
.ft.
.ft.
.In.
                    GROUT  VOLUME
            TO
^
                              COMPUTED VOLUME
                 REQUIRED VOLUME
                                     D2 (In.) x H (ft.)
                                          133.4
                             ACTUAL VOLUME
                 BAGS OF CEP-1ENT.
                 GALLONS OF WATER
                 GROUT VOLUME
                 GROUT SETTLEMENT.
                 ADDED  GROUT VOLUME
                      COMMENTS
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-------
t
                                          APPENDIX E
-------
NOTE:  CA designations for wells in this appendix
       are synonymous with SM designations used for
       the shallow, chalk wells in the report.
-------
MONITORING WELL INSTALLATION LOG
             Goldtr  A*sociat*t
                                                 New Pag-:
                                                 Way 19. :
-------
MONITORING WELL INSTALLATION LOG
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Colder AstociatM
New Page
May 19, 1985
-------
MONITORING WELL INSTALLATION LOG
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              Colder  At«ociot«»
                                                   New Page
                                                   May 19. 19'
-------
MONITORING WELL INSTALLATION LOG





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             Gold«r  A»«ociotn
                                              New Page
                                                  19, 19fi;
-------
MONITORING WELL INSTALLATION  LOG
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Go.d.r A..oe,ot., New PagO
May 19, 191
-------
                          MONITORING  WELL  INSTALLATION  LOG
JOB MO
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                                             WELL/:.
                                                                  WELL NO
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WELL CASING.



CASING TYPE_



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-------
MONITORING WELL  INSTALLATION LOG
              Gold«r  A»»ociot»»
                                                     New Page
                                                     May 19. 19.
-------
                           MONITORING  WELL  INSTALLATION  LOG
                  PROJECT.
                                                                   WELL
                                                                               - SA
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-------
MONITORING WELL  INSTALLATION  LOG
              Gold«r  Attociatet
                                                 New Page
                                                 May 19, 1986
-------
MONITORING  WELL  INSTALLATION LOG
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             Goldir  Attociatet
                                               New Page
                                               May 19. 1935
-------
MONITORING WELL INSTALLATION LOG
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Gold.r A».ociot.t New Rage
May 19, 19.
-------
MONITORING WELL  INSTALLATION  LOG
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              Goldtr  Ai»ociot»»
                                                New Page
                                                May 19, 1985
-------
MONITORING WELL INSTALLATION LOG
             Colder  Ai«ociote»
                                            New Page
                                            May 19, 1935
-------
MONITORING WELL  INSTALLATION LOG
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              Colder  Associate*
                                              New Page
                                              May 19, 1985
-------
MONITORING  WELL INSTALLATION  LOG
X6M0.551
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             Gold«r  A$tociat««
                                             New Page
                                             May 19. 1936
-------
                          MONITORING  WELL  INSTALLATION  LOG
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                                             New Page
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MONITORING WELL INSTALLATION LOG
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MONITORING WELL  INSTALLATION LOG





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             Goldtr  A»«ociot»t
                                            New Page
                                            May 19, 1986
-------
MONITORING  WELL INSTALLATION  LOG
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                                              New Page
                                              May 19. 19SC.
-------
MONITORING WELL INSTALLATION LOG
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MONITORING WELL INSTALLATION LOG
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Gold.r A..oeiot.. New Page
May 19. 1986
-------
MONITORING WELL  INSTALLATION LOG
              Colder  A»»ociot*s
                                                 New Page
                                                 May 19. 1986
-------
                           MONITORING  WELL  INSTALLATION  LOG
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                                                                                              New Page
                                                                                              May  19. 19£5
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                                            May 19. 1986
-------
                          MONITORING  WELL  INSTALLATION  LOG
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INSTALLATION METHOD _&^_


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                                             Goldtr   A»«ociot»«
                                                                                           Mew Page

                                                                                           May 19.  1
-------
MONITORING  WELL INSTALLATION LOG
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Colder Aitociottt
New Page
May 19. 1986
-------
MONITORING WELL  INSTALLATION  LOG
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-------
MONITORING WELL INSTALLATION LOG
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              Colder  Aisociam
                                            New Page
                                            May 19, 1985
-------
MONITORING WELL INSTALLATION LOG
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Gold«r Astociat*i
New Page
May 19. 1985
-------
                                                 MONITORING WELL INSTALLATION  LOG
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                                              MONITORING WELL  INSTALLATION LOG
                    JOB NO.


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                                                                                                            New Page
                                                                                                                 1Q  TOPS
-------
MONITORING WELL  INSTALLATION  LOG
              Gold«r  Aitociat**
                                               New Page
                                               May 19. 1986
-------
                        MONITORING WELL  INSTALLATION  LOG
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                                                                         INSTALLATION  NOTES
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                                          Goldtr   Attociotct
                                                                                  New Page
                                                                                  May 19, 1986
-------
                                MONITORING WELL INSTALLATION LOG
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WELL DEVELOPMENT NOTES





















                                              Gold«r  Anociot»»
                                                                             New Page
                                                                             May 19. 1986
-------
MONITORING WELL INSTALLATION LOG
              Colder  AttociotM
                                            New Page
                                            May 19. 1986
-------
APPENDIX F
-------
        MONITORING PARAMETERS AND ANALYTICAL PROCEDURES


Monitoring Parameters                Analytical Procedures

Volatile Organic Compounds

Benzene                                  8240* or 6242
bis(Chloromethyl)ether                         "
Bromoform                                      "
Carbon tetrachloride                           "
Chlorobenzene                                  "
Chlorodibromomethane
Chloroethane
2-Chloroethylvinyl ether
Chloroform
Dichlorobromomethane
Dichlorodifluoromethane
1,1-Dichloroethane
1/2-Dichloroethane
1,1-Dichloroethylene
1,2-Dichloropropane
cis-1,3-Dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-Tetrachloroethane
Tetrachloroethylene                            "
Toluene                                        "
1,2-Trans-dichloroethylehfc
1,1,1-TriChloroethane
1,1,2-Trichloroethane
Trichloroethylene
Trichlorofluoromethane                         "
Vinyl chloride                                 "
trans-l,3-Dichloropropylene                    "


Metals

Arsenic,  total                           7060* or 206.23
Chromium, total                          6010^ or 200.73
Nickel, total                            60101 or 200.7^
1. Test Methods for Evaluating Solid Waste:  Physical and
   Chemical Methods, SW-846

2. Guidelines Establishing Test Procedures for the Analysis of
   Pollutants, 40 CFR Part 136

3. Methods for Chemical Analysis of Water and Wastes (EPA 600/4-
   79-020)
n

n

it

n
-------
APPENDIX G
-------
                     ("
                                                                      4/1/86
Site Name  £.hst

Location
Study Date(s)  loIj
                 r
                                     UNIVERSAL
                                   FIELD OVERVIEW
                                     CHECKLIST
                            s"/V
                                    6.
                                        T
Facility Contact  W^rtl
Phone Number  3-£>$""
                             7 ^ \
Contractor/State Personnel

Address                	
Phone Number
Project Leader  H u HT€
Other Contractor/State Personnel

ESD Overview Personnel
Other Personnel and Affiliation
-------
                     C                  _2_           C              4/1/86
PLANNING AND PREPARATION
                                                                          Y or N

1)  Was a study plan, work  plan,  site operations plan, etc. issued
    for this investigation?

    Date Issued	

    If YES:

    Was the study plan reviewed  by ESD?

    Was the study plan acceptable?
SAMPLING

General Procedures

1)  Were sampling  locations  properly selected?

    If No, explain	
2)  Were samples  collected  starting with the least likely contaminated       i
    and proceeding  to  the most  likely contaminated?            ,   .        A/A
    Remarks
           /
3)  Were new disposable  rubber gloves worn during collection of all          ^
    samples? ^                 .                          ,  ,            .    N
    Remarks
                                            T
4)  Was sampling  equipment  wrapped in aluminum foil and protected from      / ,.
    possible  contamination  prior to sample collection?                    f\J fr
-If  Mo,  explain_
                                             y.^//>i
                                                ~*
5)  If equipment  was  cleaned  in the field, were proper procedures used?    /V
    (This includes  storage method for rinse water and solvents)
    If No, explain_
6)  What^field  instruments  were used during this invesjiigation?_
             n f i Cf S\ {   £ n^-ixt^/n/. isi^.-rf~l~*.	;?K  -
-------
                                                                        4/1/86
                                                                             Y or N
 7)  Were field instruments  properly calibrated?                             \
                                                                              /
     If No, explain _
8)  Were calibration  procedures  documented in the field notes?
    Remarks
                                                                              [\s
 Well Sampling


 1)  Was depth of well determined?
      kPif  •*  ^ . ^-.. .  t   *      . . r i  .  _i
     as depth or well  determined.'    -,       i ^  y\       /•
     ^4<4 *i ^ttT*^vtU X-^f -iv'MCM$ril£T*0*~ ftttlrj £-*flk Kt^A  yV CUrty
        <^fc4^-h^). 6rn*f^tuyi,& ^^jU^.^o ^-^IcJbj *+*+y>,.^J-.
     common to all wells?

     Describe how the depths  were determined
 4)  How was the volume  of  water  originally present in each well deter-
     mi ned ?
                                           7
     Was the well over-purged?
 9)  Were the samples chemically field preserved?                         ..   J
     If No, explain _ ($**7f


10)  Were the samples iced?  g^ /^  ^  ^j^&jbs                         V

11)  Were samples for selected  parameters field filtered?                     y

     If Yes, list parameters and describe procedures .
 3)  Were the above depths J:o  water  converted to water level elevations       \/
 5)  Was the volume determined  correctly?

 6)  How was completeness  of  purging determined?                             _
                    Volume
                     Measure _
                     Time/Flow  rate
                    Cond./pH/T
                                                                                V
 7)  Was a sufficient volume  purged?
-------
                                         -4-
                                                                       4/1/86
 -  - '  -      _                 - -    -         - .                               Y or N —
 8)  Was a dedicated (in-place) pump utilized?    -                  "       ~  \J
                                            ,                                «
     If no, describe the method of purging  (bailer -  include type and     s.,£/^o/.^  f )
     construction material, pump - include  type) _
 9)  How were the samples collected?
                    Bailer	
                    Pump  \^~**~
                    Combination
     Construction material of bailer:
     Design of bailer
                    Open Top      /
                    Closed Top
                    Other
10)  If a pump was used, describe how it was cleaned  before  and/or  between
     wells.  -
11)  Was the sample properly transferred from btiilui1  to  sample  bottle  (i.e.,  > /
     was the purgeable sample agitated, etc.)?                                f
12)  Was the rope or line allowed to touch the ground?                       /V//-T

13)  Was any wetted rope or line discarded after use'at  each  well?

14)  How many wells were sampled?
 Surface Water Sampling

 1)  What procedures and equipment were used to cqjLiect  surface water
     samples?
     Who collected samples?
                                  sJErrea
2)  Did the samplers wade in the sJErream during  sample  collection?

    If Yes:

    Did the sampler face upstream while collecting  sample?
    -Did the sampler insure-that roiled sediments were not coITecteTl
     along with vater sample?               ?                   .
-------
                     C        .  ~   ~~_5_ .."       0              4/1/86
                                                                            Y or N
3)  Note any deficiencies observed during the collection of the surface
    water samples 	
Waste, Sludge. Soil/Sediment Sampling

1)  What procedures including equipment/were used to collect soil/sediment
    s ample s ?	
2)  Were the soil/sediment sample^ well mixed prior to placing the sample
    in the sample container?

3)  Note any deficiencies observed during the collection of the soil/sedi-
    ment samples
    Total number of samples collected
Other Sampling

1)  What other tyt/es of samples were collected during this investigation?
2)  What procedures were used for the collection of these samples?
    Who collected samples?


QUALITY ASSURANCE/QUALITY CONTROL  -                                      Y or N

    (While all of these QA/QC procedures are not necessarily used,
    please identify the specific techniques which were employed by
    sampling personnel.)
 —                                           —
1)   DidTThe sampling personnel utilize any field trip blanks?
                                                                          \/
                                                                        '~'X
-------
                      C
                                                                      4/1/86-
                                                                          y. OT N
                                                         —             —
2)  Did the sampling personnel  utilize  preservative blanks?             -
-------
                                         -7-
                                                                      4/1/86
 8)  Were all gample  ftaga  and  chain-of-custody forms  signed  by sample col-
     lector(s)?
 9)  Were sampling locations  adequately documented?

    _L£Not explain


10)  Was sampling documented  with  photographs?

     If Yes,  was  a photolog maintained?

11)  Were the samples  shipped to a contract  laboratory?

     If Yes:

     Were the traffic  report  forms filled  out properly?

     Were the samples  properly packed  for  shipment?
                                                   A4-
 STATE REGULATORY  AGENCY PERSONNEL

 Qualifications of investigative/sampling personnel  (training and
 experience)  by names
                   \
 Have investigative/SJ
 equipment  training?
piing  personnel  received  sampling  technique  and
 Have personnel  received safety training?

 If  yes  to  either  of  the above questions, list where and when the
 training was  received  and who\ provided the  instruction. 	
                                                  Y or N
 Do the investigative/sampling personnel undergo periodic refresher
 training  regarding safety?

 Did the investigative/sampling personnel have appropriate safety equip
 ment in their  possession during this inspection?

 If YES, describe__the equipment which wasNavailable and/or used during
 this Inspection, 	~
 If  NO,  list  the equipment which was needed
-------
                                        _8_           (                4/1/86
                                                                         Y or N
Have  the investigative/sampling personnel been categorized  as to  the
type  of inspection}! they can conduct?

Have  the investigative/sampling personnel had comprehensive physicals?

Do the sampling personnel participate in a medical monitoring program
(i.e., periodic follow-up physicals)?

If yes, how often?	

Do the investigative/sampling personnel perform the entire  RCRA Interim
Status Inspection or merely collect samples? 	

                          \

If the personnel only collecu, samples, how are their sampling efforts
coordinated with the rest of Ghe inspection?  	

                              \

If state personnel did not collect samples, did they thoroughly evaluate
sampling procedures used by facility? 	

                                   \

If facility collected samples, did srate representatives accept a split
sample(s)? 	\	
	                           \
                                       \

SOP (Applies only to state overviews)

Has the state developed an SOP for RCRA fikld sampling?

Did the state personnel have a copy of the S\)P with them during this
inspection?

What does the SOP Cover?

    field inspections in general (sampling techniques, etc.)
    Sample handling 	
    Sample I.D. and chain-of-custody
    Uses "and limitations of various types of bailees and pumps
    Equipment cleaning 	
    Field measurements (cond., pH, T, etc.) 	
    Calibration of field instruments 	
    Other 	         	        _

Did they follow, their SOP during this inspection?
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-------
                                          APPENDIX I
t
-------
     FROM CWM RCRA Part B
                                             TABLE 1-6
                           INTERIM STATUS GROUNDWATER MONITORING RESULTS
                            FOR INDICATORS OF GROUNDWATER CONTAMINATION
                                          EMELLE FACILITY
                                             19B3-198U
             Parameter/Quarter
Well 5
Well 6
Well 7
Well 8
t>
1st
2nd
3rd
l*th
Mean
Standard Deviation
Specific Conductance
1st
2nd
3rd
Uth
Mean
Standard Deviation
TOC (ing/liter)
1st
2nd
3rd
Uth
Mean
Standard Deviation
TOX (ug/liter)
1st
2nd
3rd
l»th
Mean
Standard Deviation
8.68
9.11
8.61
9.05
8.86
0.251*
(u mhos)
2,000
2,850
2,700
2,500
2,562.5
280.995

1*6.5
1*.95
7.3
1.55
15.08
21.08

139-75
81*. 65
85.98
51.50
90.1*7
36.52
                                                      8.90
                                                      8.68
                                                      8.39
                                                      8.77
                                                      8.69
                                                      0.216
 1,693
 2,100
 1,800
 2,063
                                                      198.858
                                                      117.25
                                                         5.13
                                                      '16.75
                                                         1.1*3
                                                       35. Ik
                                                       55-128
                                                       50.1*8
                                                       32.30
                                                       21
                                                       3»*.59
                                                       ll*.87
                                9.20
                                9.UO
                                9.1»3
                                9.15
                                9-30
                                0.137
 1,900
 2,1*00
 2,100
 2,200
 2,150
 208.167
                                 39.25 .
                                 11*
                                 28.75
                                  5.25
                                 22.1*0
                                 13.108
                                 61.25
                                 30.30
                                 72.05
                                 29.50
                                 1*8.28
                                 21.67
                                8.20
                                8.1*9
                                8.1*5
                                8.1*7
                                8.1*0
                                0.136
                                                1,823
                                                2,300
                                                2,100
                                                2,213
                                                2,109
                                                207.50U
                                 9!*. 25
                                 23.75
                                 13.25
                                  9-0
                                 35.063
                                   <5
                                 8U..65
                                 1*6.08
                                 15.08
                                 1*8.60
                                 3U.85
  3
                                                                            Revision 1
                                                                            2/24/86
-------
FROM CWM RCRA Part B
                                       TABLE 1-7

                     INTERIM STATUS GROUNDWATER MONITORING RESULTS
                                FOR GROUNDWATER QUALITY
                                    EMELLE FACILITY
                                       1983-198U
       Parameter/Quarter
Well 5
Well 6
Well 7
Well 8
       Chloride (ug/liter)

         1st
         2nd
         3rd
         Uth
       Mean

       Manganese (ug/liter)

         1st
         2nd
         3rd
         Uth
       Mean

       Sodium (ug/liter)

         1st
         2nd
         3rd
         Uth
       Mean

       Sulfate (ug/liter)

         1st
         2nd
         3rd
         Uth
       Mean

       Phenol (ug/liter)

         1st
         2nd
         3rd
         Uth
       Mean
675,000
700,000
713,000
6UO,000
682,000
32U.OOO
U30.000
UU8,000
390,000
398,000
675,000
570,000
589,000
530,000
591,000
U33.000
U90.000
U75,000
U30.000
U57,000
  12
<100
  <5
<2,000
<9,000
16,000
 2,000
  80
 <50
 <50
 <50
  16
 <6
  6
<2,000
<9,000
 3,000
<2.000
   90
  <50
  <50
  <50
  <8
  <5
  ND
  j
600,000
.600,000
U90.000
U80.000
5U2,500
360,000
Uoo.ooo
U20.000
370,000
387,500
U50,000
500,000
U50.000
uoo.ooo
U50.000
 <2,000
 <9,000
 <2,000
 <2,000
   <50
   <50
   <50
   <50
   33
   29
    7
                                               U6,ooo
                                             .500,000
                                              U20,000
                                              380,000
                                              336,500
  <2,000
  <9,000
  10,000
  12,000
    100
    <50
    <50
     70
       ^•These statistics  were not  calculated when any values were  "below the minimum
        detection limit.
                                                                     Revision 1
                                                                     2/24/86
-------
      FROM CWM RCRA Part B
•
                                           TABLE 1-8
                            INTERIM STATUS GROUNDWATER MONITORING RESULTS
                                      FOR DRINKING WATER QUALITY
                                           EMELLE FACILITY  .
                                              1983-1984
              Parameter/Quarter
                                    Well 5
                                        Well  6
Well 7
Well 8
 t
i)
              Arsenic (ug/liter)

                1st
                2nd
                3rd
                4th

              Barium (ug/liter)

                1st
                2nd
                3rd
                4th
Cadmium (ug/liter)

  1st
  2nd
  3rd
  4th
                                      <5
                                       5
                                      ND
                                      ND
                                      29
                                    <100
                                      21
                                      32
                                         <5
                                         ND
                                         ND
                                         <50
                                          <5
                                          ND
                                          <5
                                          <6
                                          26
                                          16
                                                     <6
                                                     ND
                                                     ND
  <3
  <3
  ND
  ND
  10
  10
  19
  17
  <8
  <5
  ND
  ND
 <5
  6
 ND
 ND
 <6
 41
 18
 <6
 ND
 ND
              Fluoride (ug/liter)

                1st                    2,800
                2nd                    2,800
                3rd                    2,900
                4th    .                3,100
                                                   3,200
                                                   2,300
                                                   3,000
                                                   3,600
                                                       2,600
                                                       2,800
                                                       2,800
                                                       3,300
               3,000
               2,500
               2,900
               3,400
              Lead (ug/liter)

                1st
                2nd
                3rd
                4th
                                       8
                                    <100
                                      ND
                                       6
                                           <7
                                           <6
                                           <5
                                            6
   <4
    5
   <5
   37
    7
   <6
   <5
   13
 .
                                                                             Revision
                                                                             2/24/86
-------
FROM CVIM RCRA Part B
                                   TABLE  1-8 cont'd.
        Parameter/Quarter	Well 5	   Well 6	Well 7	  Well 8
       Mercury  (ug/liter)

          1st                     0.2             <0.2           <0.3          <0.2
          2nd                    <0.2             <0.1           <0.3          <0.1
          3rd                     ND               ND             ND             ND
          4th                     ND               ND             ND             ND
       Nitrate  (ug/liter)

         1st                     <40            <40          '  <40            <40
         2nd                     <40            <40            <40            <40
         3rd                     <40            <40            <40            <40
         4th .                    <40            <40            <40            <40
       Selenium^ (ug/liter)

         1st                      <5             <5             <4             <5
         2nd                      <5             <5             <4          ..  <5
         3rd                      ND             <5             <5      .       ND
         4th                      <5             <5             <5            . ND
       Silver (ug/liter)

         1st      •               <10            <10            <20
         2nd                     <25            <10            <10
         3rd                      ND            <10             ND
         4th                      ND             ND             ND             ND
       Endrin  (ug/liter)

         1st
         2nd
         3rd
         4th
                                                                       Revision  1
                                                                       2/24/86
-------
FROM CWM RCRA Part B

                                    TABLE  1-8  cont'd.
        Parameter/Quarter
Well 5
Well 6
Well 7
Well 8
        Lindane (ug/liter)

          1st
          2nd
          3rd
          4th
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
<2.0
         Methoxychlor (ug/liter)

          1st                    <50
          2nd                    <50
          3rd                    <51
          4th                    <50
               <50
               <50
               <50
               <50
               <50
               <50
               <50
               <50
               <50
               <50
               <50
        Toxaphene (ug/liter)

          1st                     <2.5
          2nd                     <2.5
          3rd                     <2.6
          4th                     <2.5
                <2.5
                <2.5
                <2.5
                <2.5
                <2.5
                <2.5
                <2.6
                <2.5
               <2.5
               <2.5
               <2.5
               <2.5
        2.4-D (ug/liter)

          1st
          2nd
          3rd
          4th
 <50
 <50
 <50
 <50
  <50
  <50
  <50
  <50
  <50
  <50
  <50
  <50
 <50.
 <50'
 <50
 <50
        2.4.5-TP Silvex (ug/liter)

          1st                      <5
          2nd                      <5
          3rd                      <5
          4th                      <5
                  <5
                  <5
                  <5
                  <5
                  <5
                  <5
                  <5
                  <5
                 <5
                 <5
                 <5
                 <5
                                                                       Revision 1
                                                                       2/24/86
-------
•v   FROM CWM RCRA Part B
                                            TABLE 1-12
                          •INTERIM STATUS GROUNDWATER MONITORING RESULTS
                           FOR INDICATORS OF GROUNDWATER CONTAMINATION
                                         EMELLE FACILITY
                                            1983-198U
            Parameter/Semi-Annual    WELL 5         WELL 6         WELL 7         WELL 8
              1st                     8.78           8.6U           8.92           8.65



            Specific Conductance (u rnhos)^-

              1st                .    2,600          1,71*5          2,1*15          2,220

                     .•

            TOC ( ing/liter )1

              1st                    1.1*3             U            9.33         V;3.l»



            TOX (ug/liter)1

              1st    -          •     Ul*.75           27.75         ^3.75           ^7.25


            lrFhe values given for the first semi-annual are the means of four
             replicate values
                                                                           Revision 1
                                                                           2/24/86
-------
     FROM CWM RCRA Part B
                                             TABLE 1-13

                           INTERIM STATUS GROUNDWATER MONITORING RESULTS
                                      FOR GROUNDWATER QUALITY
                                          EMELLE FACILITY
                                             1983-198U
•
PARAMETER /SEMI-ANNUAL WELL 5 WELL 6
Chloride (ug/liter)
1st 690,000 UlO.OOO
Iron (ug/liter)
1st ND ND
Manganese (ug/liter)
1st ND <5
Sodium (ug/liter)
1st 590,000 1*50,000
Sulfate (ug/liter)
1st 28,000 <2,000
Phenol (ug/liter)
WELL 7 WELL 8

1*10,000 1*1*0,000

ND <100

ND ' <5

520,000 1*60,000

<2,000 <2,000

               1st
,<50
                JL
<50
                 data
                                                                          Revision  1
                                                                          2/24/86
-------
FROM CWM RCRA Part B
                                     TABLE I-14

                    INTERIM STATUS GROUNDWATER MONITORING RESULTS
                               FOR DRINKING WATER QUALITY
                                       1983-1984
Parameter/ Serai-Annual WELL 5
Arsenic (ug/liter)
1st ND
Barium (ug/liter)
1st 22
Cadmium (ug/liter)
1st ND
Fluoride (ug/liter)
1st 2,500
.'
Lead (ug/liter)
1st <5
Mercury (ug/liter)
1st ND
Nitrate (ug/liter)
1st <100
Selenium (ug/liter)
1st ND
Silver (ug/liter)
1st ND
WELL 6 WELL 7 WELL 8
ND ND ND
26 28 20
ND ND ND
2,900 3,100 • 3,400
<5 <5 ND
ND ND ND
'<100 <100 ' <100
ND <5 <5
ND ND ND
                                                                     Revision  1
                                                                     2/24/86
-------
FROM CWM RCRA Part B
                                TABLE 1-14 cont.'d
Parameter /Semi -Annual WELL 5 WELL 6 •
Endrin (ug/liter)
1st NO ND
Lindane (ug/liter)
1st ND ND
Methoxychlor (ug/liter)
1st ND ND
Toxaphene (ug/liter)
1st " ND ND
2,4-D (ug/liter)
1st ND ND
2,4,5-TP Silvex (ug/liter)
WELL 7 WELL 8
ND ND
ND ND
ND ND
ND . ND
ND ND
                                                           ND
ND
                                                                 Revision 1
                                                                 2/24/86
-------
FROM CWM RCRA Part B
                                  TABLE 1-18  cont'd.
                            GROUNDWATER  SURFACE ELEVATIONS


                                        1984
       Well
      Number


        5


        6

        7


        8
First Semi-Annual
   July 1984

    136.63

    136.61

    138.12

    140.35
                            GROUNDWATER  SURFACE ELEVATIONS


                                     1983 - 1984
Well
Number
5
6
7
3
First Quarter
July 1983
138.69
137.32
138.56
139.63
Second Quarter
October 1983-
135.48
136.86
138.12
138.42
Third Quarter
January 1984
137.15
137.24
138.42
139.73
Fourth Quart "
Aoril 1984
136.72
137.27
" 138.52
139.55 '
                                                                     Revision 1
                                                                     2/24/86
-------
FROM CWM RCRA Part B
                                        TABLE 1-19

                                       GROUNDWATER
                                     SAMPLING EVENTS
                                          DATES
        WELL NOS. 1 THRU 4:
                 First Quarter                  .    February,  1982
                 Second Quarter                     April,  1982
                 Third Quarter                      July,  1982
                 Fourth Quarter                     October,  1982
                 First Semi-Annual                  May,  1983
                 Second Semi-Annual                 July, 1983
                 Third Semi-Annual                  January, 1984
                 Fourth Semi-Annual                 July, 1984
        WELL NOS. 5 THRU 8:
                 First Quarter                      July,  1983
                 Second Quarter                     October,  1983
                 Third Quarter                      January,  1984
                 Fourth Quarter                     April,  1984
                 First Semi-Annual                  July,  1984
                                                                       Revision 1
                                                                       2/24/86
-------

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