United States
                  Environmental Protection
                  Agency
 Atmospheric Sciences Research
 Laboratory
 Research Triangle Park NC 27711
                   Research and Development
EPA-600/S3-84-106  Dec. 1984
&EPA         Project  Summary

                   Green River Air Quality
                   Model Development:
                   Meteorological  and  Tracer
                   Data—July/August  1982
                   Field  Study  in  Brush  Valley,
                   Colorado
                   C. D. Whiteman, Richard N. Lee, Montie M. Orgill, and Bernard D. Zak
                    Special  meteorological  and atmos-
                   pheric tracer studies were conducted
                   during a three-week period in July and
                   August of 1982 in the Brush Creek
                   Valley of northwestern Colorado. The
                   experiments  were conducted by the
                   U.S. Department of Energy's Pacific
                   Northwest Laboratory (PNL as part of
                   the U.S.  Environmental  Protection
                   Agency's  (U.S. EPA) Green  River
                   Ambient Model Assessment (GRAMA)
                   project. The objective of the field exper-
                   iments was to obtain data to evaluate a
                   model, called VALMET, which is being
                   developed at PNL under the GRAMA
                   project to predict dispersion of air pollu-
                   tants released from an elevated stack
                   located within a deep mountain valley in
                   the post-sunrise temperature inversion
                   breakup period. Three tracer experi-
                   ments were  conducted in the valley
                   during  a  two-week period. In these
                   experiments, sulfur hexafluoride (SF6)
                   was released from a height of approxi-
                   mately 100 m, beginning before sunrise
                   and continuing until  the  nocturnal
                   down-valley  winds reversed several
                   hours after sunrise. Dispersion of the
                   SF6 after  release was evaluated  by
                   measuring  its concentrations  in
                   ambient  air  samples  taken   from
                   sampling devices operated within the
                   valley. These samplers ware stationed
                   from the source to about 8 km down-
valley.  An  instrumented  research
aircraft was also used to measure con-
centrations in and above the valley.
Tracer samples were collected by using
a network  of radio-controlled  bag
sampling  stations,  two  manually
operated gas chromatographs, a  con-
tinuous SF6 monitor, and a vertical SF6
profiler.  In addition, basic meteorologi-
cal data were collected during the tracer
experiments.   Frequent  profiles of
vertical wind  and  temperature
structure were obtained with tethered
balloons operated at the release site and
at a site 7.7 km down the valley  from
the  release site. Experiments were
conducted in cooperation with the U.S.
Department of Energy's Atmospheric
Studies  in  Complex Terrain (ASCOT)
program. A great deal of supplementary
meteorological data is available  from
the  ASCOT program, including  addi-
tional tethered balloon data, data from a
network of  meteorological towers,
acoustic sounder data, and data  from
laser anemometers.
  This Project Summary was developed
by EPA's Atmospheric Sciences Re-
search Laboratory, Research Triangle
Park. NC. to announce key findings of
the research project that is fully docu-
mented in a separate report of the same
title (see Project Report ordering
information at back).

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Introduction
A Atmospheric tracer experiments were
conducted in the Brush Creek Valley in
the oil  shale region of  northwestern
Colorado during a three-week period in
July  and August  1982. This  report
presents the resulting data, which were
collected to evaluate the initial version of
an  atmospheric transport and diffusion
model,  called VALMET,  developed  for
individual valleys. The VALMET model is
being developed for the  U.S.  Environ-
mental Protection Agency (U.S.  EPA) at
the U.S. Department of Energy's (U.S.
DOE's) Pacific Northwest Laboratory. The
U.S. EPA tracer experiments were con-
ducted as a supplement to a large mete-
orological field study that was designed
by the U.S. DOE's Atmospheric Studies in
Complex Terrain (ASCOT) program.
  The Brush Creek Valley is a 25-km long
valley located about 50 to 70 km NNE of
Grand  Junction  in northwestern
Colorado. Brush Creek is a tributary to
Roan Creek, a major valley draining  the
south side  of Colorado's  Roan Plateau,
located  at  the southern edge  of  the
Piceance Basin. The Brush Creek Valley
is a nearly  linear, unobstructed valley,
draining from NW to SE. The  valley is
deep  (—650  m), narrow  3 km  or  less
between the upper sidewalls) and, other
than short box canyons on the east side,
has  no  major  tributaries;  average
sidewall slopes are 30 to 40 degrees. The
topography of Brush Creek is unusual in
that the valley floor  has a rather steep
slope and the altitude of the ridgetops
changes little with up-valley distance.
The lowest 10 km of Brush Creek has a
slope of about 14 m/km. Upvalley from
the release site,  the valley  floor rises
more steeply, sidewalls become steeper,
and the valley attains a "v-shaped" cross
section.
  The Brush Creek tracer experiments
were designed to provide the initial data
required to  evaluate  VALMET.  The
approach   taken   was  to  collect
meteorological and tracer data to test the
full range of meteorological assumptions
and parametenzations used in modules
within the model. For example, the model
predicts that convective boundary layers,
will grow  over  heated  surfaces after
sunrise, that upslope flows will  develop
within  these  boundary  layers,  that
pollutants from the  elevated  nocturnal
plume will fumigate into the convective
boundary layers, and that they will be
transported  out of the valley  by  the
upslope flows. Thus, within the restraints
of  the  resources   available,   it  was
necessary to observe the development of
convective  boundary  layers  over the
slopes,  the  upslope  wind  systems,
fumigation of pollutants, and transport of
pollutants up the slope. This required a
continued,  elevated tracer  release
within the valley during periods when a
strong nocturnal temperature inversion
had  formed, and  observation  of the
subsequent transport and diffusion of the
tracer plumes as the valley temperature
inversion broke up the following sunrise.
Multiple  experiments  were run  during
clear weather periods with  a  variety of
measurement  systems  to  record the
changing  meteorological   and  tracer
plume structure  in  the   valley.  The
experiments  focused  on  the  plume
breakup during  the short post-sunrise
inversion breakup  period Good  spatial
time resolution of the observations was
necessary  to  record  features  of the
inversion breakup adequately. Manually
operated portable  gas chromatographs
and  a continuous tracer gas analyzer
were used to provide this time resolution
Good spatial  resolution  of  the
instruments was necessary on a valley
cross  section  to  view  the  expected
convective  boundary  layer and tracer
plume structure. To meet this  need, a
network of surface-based bag samplers
was  located  throughout  the  valley,
including the valley sidewalls.  Vertical
profiles were made through  the elevated
plume using a vertical sulfur  hexafluoride
(SF6)  profiler  balloon-borne  sampling
device. A continuous tracer gas monitor
was operated from an aircraft to momtoi
tracer gas  concentrations  in  the  upper
valley  atmosphere.   Finally,  tethered
balloon systems were  used to  make
observations   of  the  changing
atmospheric structure within the valley.
  This report describes the experimental
design and presents the meteorological
and tracer data collected in the U.S. EPA's
tracer experiments  conducted  in the
Brush Creek Valley of Colorado during
July  and  August,  1982. First, recom-
mendations  for   future  work are
presented. Next is an initial evaluation of
the VALMET model. Then, the experi-
mental  design  is  discussed, including
information  on the topography of Brush
Creek Valley, the types and location of
instrument  systems  used,  and  the
weather conditions encountered during
the  field  experiments.  A  chapter  is
provided on each  of the data collection
and  analysis  systems,  including  the
tracer  release  system,   the   mobile
analysis  laboratory,  the  bag sampling
system, the vertical SF6 sampling system,
the   tethered   ballon  data  collection
system, the portable gas chromatograph
system,  the  continuous  tracer  gas
analysis  system,  and the aircraft  data
collection system.
  Special features of the SF6 tracer data
set include:

  •  use of a vertical SF6 profiling system
     to  determine   how  the  vertical
     structure of the SF6 plume varied
     with time

  •  extension of the bag-sampling net-
     work to include tracer observations
     high (150 m)on the valley sidewalls

  •  use of portable gas chromatographs
     and SF6 monitors  to observe rapid
     variations in tracer concentrations
     that occur during  the post-sunrise
     period  when fumigations of the
     elevated nocturnal plume occur on
     the  valley sidewalls

  •  use of a research aircraft to deter-
     mine how pollutants are dispersed
     into the upper reaches of the valley
     following sunrise

Conclusions and
Recommendations
  There  were  several  advantages  to
choosing the Brush Creek Valley for the
initial evaluation of VALMET. First  , the
valley  has a rather simple topography.
The  narrow, 25-km-long valley has no
major changes in valley orientation along
its length. It has nearly equal sidewall
inclinations. The valley drains a plateau,
so that  the ridges are at  a constant
altitude regardless of location along the
valley axis. The valley has no major tribu-
taries. Second, the valley axis is oriented
from NW to SE so that the sidewalls will
be exposed  to  quite different isolation
during  the  post-sunrise  temperature
inversion breakup period. The effect of
this   unequal   heating  was  a major
uncertainty in the model formation On
the basis of meteorological data collected
in wider  Colorado valleys, and numerical
model results, the VALMET model was
developed  under an   assumption  of
horizontal homogeneity of  atmospheric
structure on a valley cross section. This
assumption could be readily tested in the
Brush   Creek  Valley,  where  the
narrowness of the valley and the  NW-
SE orientation of the valley would clearly
maximize any  horizontal  gradients  in
atmospheric  structure  between  the
sidewalls. Third, the  Brush  Creek Valley
was   heavily  instrumented  with
meteorological  sensors by the ASCOT

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program. Access to their meteorological
data was a  great benefit to the model
evaluation effort.
  Along  with the  above  advantages,
there  was  a major disadvantage  to
conducting  an  initial  evaluation  of
VALMET with data from the Brush Creek
Valley. This disadvantage was related to
the short segment of the valley that was
accessible  for tracer instrumentation.
VALMET is  a two-dimensional  model,
predicting concentrations   on  a  cross
section oriented perpendicular  to  the
valley  axis some distance  down-valley
from a source. Restrictive assumptions
are  present  in  VALMET   regarding a
required homogeneity of the temperature
and  wind structure in the  along-valley
direction.  The   Brush  Creek   Valley,
however, is  a short tributary valley that
flows  into  the  Roan  Valley   a  few
kilometers below the valley cross section
where most  measurements are made.
Consequently, tracer plume carried down
the Brush Creek Valley during the night is
carried into Roan Creek. Reversal of the
down-valley winds (to up-valley)  after
sunrise results in a large part of the tracer
plume being carried up the Roan Creek
Valley, rather than being carried back up
the Brush Creek Valley as assumed in the
model.  Evaluation  of  VALMET  was
complicated  by this violation of a major
assumption in the model, which had been
designed for longer valleys.
  The nocturnal plume was carried down
the valley, as expected. The nocturnal
plume,  although  released  above  the
valley center, was found to  be displaced
towards  one  sidewall   as  it  was
transported down the valley. The valley is
not strictly linear, but turns slightly with
down-valley distance. Because the plume
was displaced towards the  "outside" of
the turn  , it is conceivable that  mertial
effects  were   responsible  for   the
displacement of the plume from the valley
centerline. The  nocturnal  plume  was
carried down the valley in a rather strong
"jet" of down-valley winds, with the  level
of maximum winds at about  release
height. The  nocturnal model, based  on
the Gaussian formulation, is incapable of
treating  vertical  shears  in  transport
winds  but it approximates transport and
diffusion  along the  valley direction fairly
well when winds at  release height are
used for transport.
  Assumptions in the daytime portion of
the model were verified with actual mete-
orological and tracer data. The post-
sunrise period was characterized by the
growth of convective boundary  layers
over the sunlit valley surfaces. The tracer
plume fumigated the valley sidewalls as
convective   boundary  layers   grew
upwards  into  the remnants  of  the
nocturnal  temperature  inversion
containing  the elevated  tracer plume.
Tracer  was  carried from the valley by
upslope flows, which  developed  within
the growing convective boundary layers.
Corresponding subsiding  motions  over
the valley  center were  noted in  the
temperature  profiles at several  of the
tethered balloon  sites, but  the limited
vertical resolution of the tracer plume did
not allow this feature  to be seen in the
tracer concentration analyses.
  Due   to  the  northwest-southeast
orientation  of the  deep,  steep-walled
valley,  very  significant differences
occurred in  the  timing  and  rates  of
convective boundary layer growth on the
opposing sidewalls following  sunrise. As
a result  of the unequal heating  of the
different sidewalls, a  cross-valley flow
developed,  carrying the elevated plume
towards the warmer sidewall. Due to the
cross-valley advection, tracer concentra-
tions were higher on this sidewall than
predicted by the model. A future modifi-
cation  of the VALMET model  will be
required to handle this situation properly
in narrow  valleys where post-sunrise
insolation on the opposing sidewalls is
quite different. The Brush Creek  tracer
experiments were the first direct experi-
mental confirmation of the importance of
this  physical  effect on  tracer  plume
dispersion
  The short length of  the Brush  Creek
Valley, as expected, affected the results
of the  tracer experiments. The primary
effect, from initial analyses, seems to be
that the tracer  concentrations  in the
valley fell  more  rapidly  than  expected
after the post-sunrise wind reversal. This
is thought to be due  to the nocturnal
plume   being  carried   largely up  Roan
Creek after the wind reversal rather than
reversing direction to come  back up
Brush Creek
  The  experiments  described  in  this
report  should be  considered as  initial
experiments designed to provide a better
understanding of  the  basic physics of
valley meteorology. The VALMET model
appears to have promise in predicting air
pollution concentration in deep valleys.
Further work  is recommended  to
complete a full analysis of the data from
the 1982 experiment, and to evaluate and
improve the VALMET model with these
data.

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     C. D. Whiteman, Richard N. Lee, andMontieM. Orgill are with Pacific Northwest
       Laboratory, Rich/and,  WA 99352; and Bernard D. Zak is with Sandia National
       Laboratory, Albuquerque. NM 87185.
     Alan H. Huber is the EPA Project Officer (see below).
     The complete report, entitled "Green River Air Quality Model Development-
       Meteorological and Tracer Data—July/August 1982  Field Study in Brush
        Valley, Colorado," (Order No. PB85-125 490; Cost: $ 16.00, subject to change}
        will be available only from;
             National Technical Information Service
             5285 Port Royal Road
             Springfield, VA22161
             Telephone: 703-487-4650
     The EPA Project Officer  can be contacted at:
             Atmospheric Sciences Research Laboratory
             U.S. Environmental Protection Agency
             Research Triangle Park, NC 27711
      US GOVERNMENT PRINTING OFFICE, 559-016/7866
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
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Penalty for Private Use $300

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