CHARACTERIZATION OF HRGC/MS UNIDENTIFIED PEAKS FROM
        THE ANALYSIS OF HUMAN ADIPOSE TISSUES

               VOLUME II:   APPENDICES
                         by

                    Jon D.  Onstot
                  Randall E.  Ayling
                   John S.  Stanley
                    FINAL REPORT

             EPA Contract No. 68-02-4252
               Work Assignment No. 23
              MRI Project No. 8823-A01

                    June 30, 1987
                    Prepared for:

          National Human Monitoring Program
            Field Studies Branch (TS-798)
            Exposure Evaluation Division
      Office of Pesticides and Toxic Substances
        U.S. Environmental Protection Agency
                 401 M Street, S.W.
                Washington, DC  20460

  Attn:   Ms. Janet Remmers, Work Assignment Manager
         Dr. Joseph J.  Breen, Program Manager

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                                 DISCLAIMER
This document has been reviewed and approved for publication by the Office of
Toxic Substances, Office of Pesticides and Toxic Substances, U.S.  Environmental
Protection Agency.   The use  of  trade names or commercial  products  does  not
constitute Agency endorsement or recommendation for use.

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                                   PREFACE
          This report describes Midwest Research Institute's approach to
characterize unidentified chromatographic peaks in HRGC/MS data collected
from the analysis of human adipose tissue for general volatile and semi vola-
tile organic compounds.   This report is provided as two separate volumes.
Volume I describes the technical approach and presents a summary of the
results based on frequency of observation by age group and census region.
Volume II is an appendix to Volume I and contains additional details on
frequency of occurrence for both identified and unidentified peaks based on
census region, census division, and age.  This report focuses on the approach
to identifying compounds from the HRGC/MS spectra.  The frequency of detection
of specific compounds is presente.  The HRGC/MS data were collected for 46
samples prepared as composites from individual specimens of the U.S. Environ-
mental Protection Agency's fiscal year 1982 (FY82) National Human Adipose
Tissue Survey (NHATS) repository.  The sample collection, compositing, and
the analysis of the composites for specific volatile and semivolatile organic
compounds are described in detail in separate reports (Stanley 1986b, Stanley
1986c).

          This approach to the characterization of HRGC/MS unidentified peaks
was developed and conducted for the EPA's Office of Toxic Substances, Field
Studies Branch (EPA Contract No. 68-02-4252, Work Assignment 23, Ms. Janet
Remmers, Work Assignment Manager, and Dr. Joseph Breen, Project Officer.
This report was prepared by Mr. Jon Onstot with assistance from Mr. Randall E.
Ayling and Dr. John S. Stanley, MRI Work Assignment Leader.
                                             MIDWEST RESEARCH INSTITUTE
                                             Paul C. Constant
                                             Program Manager
Approved:
Jack Balsinger
Qua/Hy Assurance
                    ordinator
   in E. Going, Director
 lemical Sciences Department

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                              TABLE OF CONTENTS
Appendix A - Dot Matrix Table for Compounds Identified in the
               Volatile Organic Analysis Data Set; Volatile
               Organic Compounds vs.  Census Region, Census
               Division, and Age Group 	
                                                                          A-l
Appendix B - Dot Matrix Table for Compounds Identified in the 6%
               Florisil Semivolatile Organic Analysis Data Set;
               Semivolatile Organic Compounds vs.  Census Region,
               Census Division, and Age Group	
                                                                          B-l
Appendix C - Dot Matrix Table for Compounds Identified in the 15/50%
               Florisil Semivolatile Organic Analysis Data Set;
               Semivolatile Organic Compounds vs.  Census Region,
               Census Division, and Age Group	
                                                                          C-l
Appendix D - Dot Matrix Table for Unidentified HRGC/MS Peaks in the
               Volatile Organic Analysis Data Set; Unidentified
               Volatile Organic Compound Responses vs. Census
               Region, Census Division, and Age Group	

Appendix E - Dot Matrix Table for Unidentified HRGC/MS Peaks in the
               6% Florisil Semivolatile Organic Analysis Data Set;
               Unidentified Semivolatile Organic Compound Responses
               vs. Census Region, Census Division, and Age Group . .  .

Appendix F - Dot Matrix Table for Unidentified HRGC/MS Peaks in the
               15/50% Florisil Semivolatile Organic Analysis Data Set;
               Unidentified Semivolatile Organic Compound Responses
               vs. Census Region, Census Division, and Age Group . .  .

Appendix G - Listing of the ACORN Program	
                                                                          D-l
                                                                          E-l
                                                                          E-l

                                                                          G-l

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                           APPENDIX A


DOT MATRIX TABLE FOR COMPOUNDS IDENTIFIED IN THE VOLATILE ORGANIC
        ANALYSIS DATA SET;  VOLATILE ORGANIC COMPOUNDS VS.
          CENSUS REGION,  CENSUS DIVISION. AND AGE GROUP
                               A-l

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hdex
           Table A-l.   Compounds  Identified  in  the Volatile Organic Analysis
                     }	    Data Set  - West Census  Region	
                                              CENSUS REGION
                                             CENSUS DIVISION
                                                AGE GROUP
                                                                              WEST
                                               MOUNTAIN

                                             0-14   15-44  45+
    PACIFIC

0-14    15-44  45+
       Compound Class
Compound Nama (a)
I.S. Internal Standard Bromochloropropane • Internal Standard
1 Carbon Dioxide Carbon dioxide
2 Alkane 2-Methyl-butane
3 Unidentified C5.H1 0 [Cyclopentane]
4 C3 Substituted cyclopropane [Propykyclopropanej
5 C3 Substituted cyclopropane [Propykyclopropane]
6 2,3-Dimethyl-hexane
7 1,2-Diethyl-cyclobutane
8 Alkane £C10|Decan9]
9 C1 0 Alkane [2-Methyi-nonane]
10 2,2,3,3-Tetramethyl-hexane
11 Sat. akane > C11 |2-Methyl-decane]
12 Alkyl substituted hexane |Pentyl-cyck>hexane]
13 2,2-Dimethyl-decane
14 C13 Alkane [3,3-Dimethyl-undecane]
15 AStane |6-Ethyl-2-methyl-decane]
16 Alkane [2,6,7-Tnmethyl-decane]
17 Alkane >C11 [5-(1-Methylpropyl)-nonane]
18 C1 3 Alkane [2,2,7-Tn methyl-decane]
19 3,3,8-Trimethyl-decane
20 Alkane [6-Methyl-trid9cane]
21 Alkerie C5 Alkane [1 -Pentene]
22 1-Hexene
23 Unidentified C6.H12 [1-Hexene]
24 3-Methyl-1 ,4-heptadiene
25 1,6-Octadiene
26 1,3,6-Octatriene
27 Unidentified C8.H12 [3-Ethyidene-l-methyl-cyclcpentene]
28 1-Nonene
29 3-Ethyl-2-methyl-1 ,3-hexadiene
30 C10 Ringed alkane|1,7,7-Trimethyl-bicydo[22.1)h9pt-2-ene]
31 1-Methyl-4-(1-methylethenyl)-cyclohexene
32 7-(1-Methylethylidene)-bicyclo|4.1.0] heptane
33 C11Alkene[1-Undecene]
34 C11 Alkene[1-Ethenyl-2-hexenyl-cyclopropane]
35 Isomer of Undecen-3-yne [5-Undec-3-yne)
36 Isomer of Undecan-3-yne [5-Undec-3-yne]
37 Arene C2 Alkyl benzene |1,2-Dimethyl-benzene]
38 C2 Alkyl benzene 11,2-Oimethyl-benzene]
39 C3 Alkyl benzene [1 ,2,4-Trimethyl-benzene]
40 C3 Alkyl benzene [1 -Methylethyl-benzene]
41 Propyl-benzene
42 C3 Alky! benzene [1-Methyl-2-ethyl benzene]
43 Isomer of tetramethyl benzene [1 ,2,3,4-Tetramethyl-benzene]
44 1-Methyl-3-(1-methylethyl-) benzene
45 Naphthalene
46 1-£thylpropyl-benzene
47 Saturated Alcohol 3-Methyl-1-butanol
48 1-Hexanol
4 9 Isomer of ethyl hexanol [3-MethyM -hexanol]
50 2-Ethyl-1 -Hexanol
51 Isomer of octanol |1 -Oclanol]
52 Isomer of octanol [1-Octanol]
53 UnidentfiedC13H280[1-Tridecanol]
54 Unsaturated Alcohol Isomer of Octen-ol [3-Octen-2-ol]
55 Isomer of Octen-ol (3-Octen-2-ol)
56 Saturated Aldehyde Unidentified C5.H10 0 [Pentanalj
57 UmdentifedC6.H12.0[Hexanal]
58 C7 Aldehyde [Heptanal]
59 Nonanal
60 Decanal
61 Unsaturated Aldehyde 2-Methyl-propenal
62 Isomer of Hexenal[2-Hexenal]
63 Isomer of Hexenal[2-Hexenal]
64 C7 Unsat. aldehyde (2-Heptenal)
65 C7 Unsat aldehyde i2-Heptenal)
66 2,4-Heptadienal
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                                              A-2

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                                                          Table  A-1   (concluded)
hdex
                                                                   CENSUS DIVISION

                                                                        AGE GROUP
                                                                       MOUNTAIN

                                                                   0-14     15-44  45*
      PACIFIC

0-14      15-44    45+
           Compound Class
Compound Nam* (a)
67 2,4-Nonadienal
6B Isomer of decanal [2-Dacenal]
69 Isomar of decanal [2-Decenal]
70 Unsat aldehyde [2-Decanal]
71 Unsat aldehyde [2-Decenal]
72 Unsat. aldehyde [2-Decenal]
73 Diene aldehyde [2,4-Decadienal]
74 Diene aldehyde [2,4-Decadienal]
75 Diene aldehyde [2,4-Dodecadienal]
76 Saturated Katone C7 Ketone 12-Heptanone]
77 4-Heptanone
78 Unidentfied C7.H12.0 [2,2,3-Trimethyl-cyclobutanone]
79 C8 Ketone [3-Octanone]
80 Sat. ketone [2-Decanone]
81 Unsaturated Ketone Isomer of Oaten-one [3-Octen-2-one]
82 C8 Ketone [3-Octen-1-one]
83 3,5-Octadien-2-one
84 C9 Unsat ketona |3-Nonen-2-one]
85 Saturated Ether Dimethoxy methane
86 Saturated Ester Propanoic add, ethyl ester
87 C5 Methyl ester [Butanoic acid, methyl ester]
88 Propanoic acid, prop/I aster
89 Pentanoic add, methyl ester
90 C7 Methyl ester [Hexanoic acid, methyl ester]
91 3-Methyl butanoic add, ethyl ester
92 Propanoic acid, butyl ester
93 2-Methyl propanoic acid, 1-methylethyl ester
94 Acetic acid, pentyl ester
95 2-Methyl butanoic acid, ethyl ester
96 C8 Ethyl ester [Hexanoic add, ethyl ester]
97 Acetic acid, hexyl ester
98 C8 Ester [3-Methyl butanoic acid, propyl ester]
99 C8 Ester [Butanac add, 1 -Methylpropyl ester]
1 00 C8 Ester [Butanoic acid, 1 -Methylpropyl ester]
101 Octanoic acid, methyl ester
102 Hexanoic acid, 1-methylethyl ester
103 Butanoic acid, pentyl ester
1 04 Hexanoic add, 2-methylpropyl aster
1 05 Octanoic acid , ethy I ester
1 06 C 1 0 Ester [2-Methyl-propanac acid, haxyl ester]
1 07 C1 1 Ester [Hexanoic acid, pentyl ester]
1 08 C1 1 Ester [4-Methyl pentanoic acid, pentyl ester]
1 09 C1 1 Ester [Hexanoic acid, 2-Methybutyl ester]
110 Isomar of octanoic aad (3-Methyl-butyl ester]
111 Unsaturated Ester 3-Octen-1-ol, acetate
112 Halocarbon C5Bromoalkane[1-Bromopentanel
113 3-Bromo-Pentane
114 Brommated alkane 2 C7 [1 -Bromo-heptane]
115 Dichlorobutane [1 ,4-dichlorobutane]
116 2-Bromo-2-chloro-1,1,tnfluoro-ethane
117 Phenol Isomer of ethyl-phenol [4-Ethyl-phenol]
118 Heterocycle Unidentified C9H14.0[2-Pentyl-furan
119 Sulfide Dimethyl dsulfide
120 Dimethyl trisuffide
121 Organo-Silicon Decamethyl-cydopentasiloxana
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 (a)   Tentative compound identification is based on search vs the NBS mass spectral library Confirmation has not been achieved by companng
      retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
      a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                     A-3

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                Table A-2.   Compounds  Identified in  the  Volatile  Organic Analysis
               	Data  Set  -  South Census Region	
                                          CENSUS REGION
                                         CENSUS DIVISION
                                             AGE GROUP
                                                        EAST SOUTH CENTRAL,

                                                        0-14     15-44  45*
                                                            SOUTH

                                                         SOUTH ATLANTIC        WEST SOUTH CENTRAL

                                                       0-14     15-44     45+    0-14   15-44  45+
hdac	Compound Class
Compound Name (a)
I.S. Internal Standard Bromochloropropane - Internal Standard
1 Caibon Dioxide Carbon dioxide
2 Alkane 2-Methyl-butane
3 Unidentified C5.H10[Cydopentane[
4 C3 Substituted cyclopropane [Propyl-cydopropane)
5 C3 Substituted cyclopropane [Propyl-cyclopropanej
6 2,3-Dimethyl-hexane
7 1,2-Diethyl-cydobutane
8 Alkane a ClOfOecane]
9 C1 0 Alkane [2-Methyl-nonane]
10 2,2,3,3-Tetramethyl-hexane
11 Sat alkaneaCn |2-Methyl-decane]
12 Alkyl substituted hexane [Pentyl-cvdohexane]
13 2,2-Hmethyl-decane
14 C13 Alkane [3,3-Dimethyl-undecane]
15 Alkane [6-Ethyl-2-methyl-decane]
16 Alkane [2,6,7-Tnmethyl-decane]
17 Alkane a C1 1 15-(1 -Methylpropylj-nonane]
18 C1 3 Alkane [2,2,7-Trimethyl-decane]
19 3,3,8-Trimethyl-decan8
20 Alkane (6-Methyl-tridecane)
21 Alkene C5 Alkane [l-Pentene]
22 1-Hexene
23 Unidentified C6H12[1-Hexene]
24 3-Methyl-1,4-heptadiene
25 1,6-Octadiene
26 1,3,6-Octatnene
27 Unidontified C8 H12 [3-Ethylidene-1-methyl-cyclop8ntene]
28 1-Nonene

31 1-Methyl-4-(1-methylethenyl)-cydohexene
32 7-(1-Methylethylidene)-bicyclo[4.1 0] heptane
33 C11 Alkene 11-Undecene]
34 C11 Alkene [1-Ethenyl-2-hexenyl-cydopropane]
3 5 Isomer of Undecen-3-yne [5-Undec-3-yne]
36 Isomer of Undecen-3-yne (5-Undec-3-yneJ
37 Arene C2 Alkyl benzene [1 ,2-Dimethyl-benzene)
38 C2 Alkyl benzene ]1 ,2-Dimethyl-benzene]
39 C3 Alkyl benzene [1,2,4-Trimelhyl-benzene]
40 C3 Alkyl benzene [1-Methylethyl-benzene]
41 Propyl-benzene
42 C3 Alkyl benzene |1 -Methyl-2-ethyl benzene]
43 Isomer of tetramethyl benzene [1 ,2,3,4-Tetramethyl-benzene]
44 1-Methyl-3-(1-methylethyl-) benzene
45 Naphthalene
46 1-Ethylpropyl-benzene
47 Saturated Alcohol 3-Methyl-1-butanol
48 1-Hexanol
49 Isomer of ethyl hexanol [3-MethyM -hexanol]
50 2-ElhyM -Hexanol
51 Isomer of octanol[1-0ctanol]
52 Isomer otoctanol [1-Octanol]
53 Unidentified Cl3H280[1-Tridecanol]
54 Unsaturated Alcohol Isomer of Octen-ol (3-Octen-2-ol |
55 Isomer of Octen-ol |3-Octen-2-olJ
56 Saturated Aldehyde Unidentified C5 H10 0 [Pentanal]


60 Decanal
61 Unsaturated Aldehyde 2-Methyl-propenal
62 Isomer ol Hexenal [2-Hexenal]
63 Isomer ol Hexenal [2-Hexenal]
65 C7 Unsat aldehyde [2-Heptenal]
66 2,4-Heptadienal
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                                                               Table  A-2   (concluded)
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                                                             CENSUS REGION
                                                           CENSUS DIVISION
                                                                AGE GROUP
                                                                                 EAST SOUTH CENTRAL

                                                                                0-14      15-44    45+
                                                                                      SOUTH

                                                                                 SOUTH ATLANTIC

                                                                               0-14      15-44
       WEST SOUTH CENTRAL

45*      0-14    15-44   45+
         Compound Class
Compound Name (a)
67 2,4-Nonadienal
68 Isomer of d8cenal[2-Decenal]
69 Isomer of decenal [2-Decenal]
71 Unsat. aldehyde J2-Decenal]
73 Diene aldehyde [2,4-Decadienal]
75 Diene aldehyde [2,4-Dodecadienal]
76 Saturated Ketone C7 Ketone [2-Heptanonej
77 4-Heptanone
78 Unidentified C7.H12.0 [2,2,3-Tnmethyl-cyclobutanone]
79 C8 Ketone [3-Octanone]
80 Sat. ketone (2-Decanonel
81 Unsaturaied Ketone Isomer of Octen-one [3-Octen-2-one]
82 C8 Ketone [3-Octen-1-one]
83 3,5-Octadien-2-one
84 C9 Unsat. ketone [3-Nonen-2-onej
85 Saturated Ether Dimethoxy methane
86 Saturated Ester Propanoic add, ethyl ester
87 C5 Methyl ester [Butanoic add, methyl ester]
88 Propanoic add, propyl ester
89 Pentanoic add, methyl ester
91 3-Methyl butanoic add, ethyl ester
92 Propanoic acid, butyl ester
93 2-Methyl propanac acid, 1-methylethyl ester
94 Acetic acid, pentyl ester
95 2-Methyl butanoic add, ethyl ester
96 C8 Ethyl ester [Hexanoic acid, ethyl ester]
97 Acetic acid, hexyl ester
98 C8 Ester [3-Methyl butanoic acid, propyl ester]
99 C8 Ester (Butanoic aad, 1 -Methylprapyl ester]
1 00 C8 Ester [Butanotc add, 1 -Methylpropyl ester]
101 Octanoic add, methyl ester
102 Hexanoic aad, 1-methylethyl ester
103 Butanoic aad, pentyl ester
1 04 Hexanoic acid, 2-methylpropyl ester
106 C10 Ester [2-Methyl-propanoic acid, hexyl ester]
1 07 C1 1 Ester [Hexanoic acid, pentyl ester]
1 08 C1 1 Ester [4-Methyl pentanac aad, pentyl ester]
109 C1 1 Ester [Hexanoic acid, 2-Metriylbutyl ester]
110 Isomer of octanoic acid [3-Methyl-butyl ester]
111 Unsaturated Ester 3-Octen-1-d, acetate
112 Halccarbon C5 Bromoalkane[l-Bromopentane]
113 3-Bromo-Pentane
114 Brammated alkane i C7 [1-Bromo-heptane]
1 1 5 Dichlorobutane [1 ,4-dichlorobutane]
116 2-Bromo-2-chloro-1 ,1 .tnfluoro-ethane
117 Phenol lsomGrof9thyl-ph9nol[4-Ethyl-phenol]
118 Heterocycle Unidentified C9H14.0 [2-Pentyl-luran
119 Sulfide Dimethyl disulfide
120 Dimethyl tnsulfide
121 Organo-Silicon Decamethyl-cyclopentasiloxane
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                                                                           A-5

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                Table  A-3.   Compounds Identified  in the Volatile Organic Analvsis
               	Data Set -  North Central  Census  Region
                                            CENSUS REGION               NORTH CENTRAL

                                           CENSUS DIVISION     EAST NORTH CENTRAL       WEST NORTH CENTRAL

                                              AGE GROUP     0-14     15-44   45+    0-14     15-44   45+
Mem    Compound Class    Compound Name (a)
IS Internal Standard BromochlorcipropanB - Internal Standard
1 Carbon Dioxide Carbon dioxide
2 Alkane 2-Methyl-butane
3 Unidentified C5 H1 0 [Cydopentane]
4 C3 Substituted cyclopropane [Propykydopropane]
5 C3 Substituted cyclopropane [Propyl-cyclopropane]
6 2,3-Oimethyl-hexane
7 1,2-Diethyl-cydobutane
8 Alkane 2 ClOlDecane)
9 C10Alkane(2-Methyl-nonane]
10 2,2,3,3-Tetramethyl-hexane
11 Sat. alkane 2 C11 (2-Methyl-decanej
12 Alkyl substituted hexane [Pentyl-cyclohexane]
13 2,2-Dimethyl-decane
14 C13 Alkane [3,3-Dimethyl-undecane]
15 Alkane [6-Ethyl-2-methyl-decane]
16 Alkane [2,6,7-Tnmethyl-decane]
17 Alkane 2 C11 |5-(1-Methylpropyl)-nonane]
18 C13 Alkane |2,2,7-Tnmethyl-decane]
19 3,3,8-Tnmethyl-decane
20 Afkane [6-Methyl-tridecane]
21 Alkene C5 Alkane [1-Pentsne]
22 1-Hexene
23 Unidentified C6.H12|1-Hexene]
24 3-Methyl-1,
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                                                               Table  A-3   (concluded)
                                                               CENSUS REGION                     NORTH CENTRAL

                                                              CENSUS DIVISION       EAST NORTH CENTRAL          WEST NORTH CENTRAL

                                                                   AGE GROUP      0-14       15-44     45+     0-14      15-44     45+
        Compound Class
Compound Name (a)
67 2,4-Nonadienal
68 Isomer of decanal [2-Decenal]
69 Isomerofdecenal[2-Decenal]
70 Unsat. aldehyde [2-Dacenal]
71 Unsat. aldehyde [2-Decenal]
72 Unsat. aldehyde |2-Dacanal]
73 Diene aldehyde [2,4-Decadienal]
74 Diene aldehyde [2,4-Decadienal]
75 Diene aldehyde [2,4-Dodecadienal]
76 Saturated Ketone C7 Ketone [2-Heptanone]
77 4-Heptanone
78 Unidentified C7.H12.0 [2,2,3-Trimethyl-cyclobutanone]
79 C8 Ketone [3-Octanone]
80 Sat. ketone [2-Docanone]
81 Unsaturated Ketone Isomer of Octen-one [3-Octen-2-ona]
82 C8 Ketone [3-Octen-1-one]
83 3,5-Octadien-2-one
84 C9 Unsat. ketone [3-Nonen-2-one]
85 Saturated Ether Dimethoxy methane
86 Saturated Ester Propanoic acid, ethyl ester
87 C5 Methyl ester [Butanoic acid, methyl ester]
88 Propanoic add, propyl ester
89 Pentanoic acid, methyl ester
90 C7 Methyl ester [Hexanoic acid, methyl ester]
91 3-Methyl bulanoic acid, ethyl ester
92 Propanoic acid, butyl ester
93 2-Methyl propanoic acid, 1-methylethyl ester
94 Acetic aad, pentyl ester
95 2-Methyl butanoic acid, ethyl ester
96 C8 Ethyl ester [Hexanoic add, ethyl ester]
97 Acetic acid, hexyl ester
98 C8 Ester {3-Methyl butanoic acid, propyl ester]
99 C8 Ester [Butanoic acid, 1 -Methylpropyl ester]
1 00 C8 Ester [Butanoic add, 1 -Methylpropyl ester]
101 Octanoic acid, methyl ester
1 02 Hexanoic add, 1 -methylethy! ester
1 03 Butanoic acid, pentyl ester
1 04 Hexanoic acid, 2-methytpropyl ester
1 05 Octanoic acid, ethyl ester
1 06 C1 0 Ester [2-Methyhpropanoic acid, hexyl ester]
107 C11 Ester [Hexanoic acid, pentyl ester]
1 08 C1 1 Ester [4-Methyl pentanoic add, pentyl ester]
1 09 C1 1 Ester [Hexanoic add, 2-Methybutyl ester]
1 10 Isomer of octanoic aad [3-Methyl-butyl ester]
111 Unsaturated Ester 3-Octen-1-ol, acetate
112 Halocarbon C5Bromoalkane[1-Bromopentane]
113 3-Bromo-Pentane
1 14 Bromi nated alkane > C7 [1 -Bromo-heptane]
115 Dichlorcbutane [1 ,4-dichlorobutane]
1 16 2-Bromo-2-chloro-1 ,1 .trifluoro-ethane
117 Phenol Isomsr of ethyl-phenol [4-Ethyl-phenol]
118 Heterocycte Unidentified C9H1 4.0 [2-Pentyl-turan]
119 Sulfide Dimethyl disulfide
120 Dimethyl tnsuKide
121 Organo-Sikcon Decamethyl-cyclopentasiloxane
•
• •


•
•

•
• •
* *


• • •
•

• •



•
* * *
• •




• •



•
• • •

•
•
•

•

•

•


•
•
•

•

•

•
•

•
• •


•

•

•
* •

(a)  Tentative compound identification is based on search vs. the NBS mass spectral library. Confirmation has not been achieved by comparing
    retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
    a general descriptive name is reported and the best ranked NBS name is provided in brackets
                                                                    A-7

-------
           Table  A-4.   Compounds Identified  in the Volatile Organic Analysis
           	     Data Set  - Northeast  Census Region
hdex
                                           CENSUS REGION               NORTHEAST

                                          CENSUS DIVISION    DIDDLE ATLANTIC        NEW ENGLAND

                                              AGE GROUP    0-14    15-44  45*    0-14   15-44 45+
        Compound Class  Compound Name (a)
I S Internal Standard Bromochloropropane - Internal Standard
1 Carbon Dioxide Carbon dioxide
2 Alone 2-Methyl-butane
3 Unidentified C5.H1 0 [Cyctopentane]
4 C3 Substituted cyclopropane [Propyl-cyclopropane]
5 C3 Substituted cyclopropane [Propyl-cyclopropane|
6 2,3-Dimethyl-hexane
7 1,2-Diethyl-cyclobutane
8 Alkane >C10|Decane]
9 C10 Alkane [2-Methyl-nonane]
10 2,2,3,3-Tetramethyl-hexane
11 Sat. alkane a C1 1 [2-Methyl-decane|
12 Alky! substituted hexane (Pentyl-cyclohexane]
13 2,2-Dimethyl-decane
14 C1 3 Alkane [3,3-Dimethyl-undecane]
15 Alkane [6-Ethyl-2-methyl-decanej
16 Alkane [2,6,7-Tnmethyl-decane]
17 Alkane > C1 1 [5-(1-Methylpropyl)-nonane]
18 C1 3 Alkane [2,2,7-Trimethyl-decane]
19 3,3,8-Trimethyl-decane
20 Alkane [6-Methyl-tndecane]
21 Alkene C5 Alkane [1-Pentene]
22 1-Hexene
23 Unidentified C6.H12|1-Hexene]
24 3-Methyl-1 ,4-heptadiene
25 1 ,6-Octadiene
26 1,3,6-Octatnene
27 Unidentified C8 H12 [3-Ethyldene-1-methyl-cyclopentene]
28 1-Nonene
29 3-Ethyl-2-methyl-1,3-hexadiene
30 C10 Ringed alkane [1,7,7-Trimethyl-bicydo(2.2.1lhept-2-ene]
31 1 -Methyl-4-(1 -methylethenyl)-cyclohexene
32 7-(1-Methylethylidene)-bicyclo[4.1.0] heptane
33 C11 Alkene [1-Undecene]
34 C1 1 Alkene [1 -Ethenyl-2-hexenyl-cydopropane]
35 Isomer of Undecen-3-yne [5-Undec-3-yne]
36 Isomer of Undecen-3-yne (5-Undec-3-yne)
37 Arene C2Alkyl benzene [1,2-Dimethyl-benzene]
38 C2 Alkyl benzene [1,2-Dimethyl-benzene|
39 C3 Alkyl benzene [1 ,2,4-Tnmethyl-benzene]
40 C3 Alkyl benzene [1-Methylethyl-benzene]
41 Propyl-benzene
42 C3 Alkyl benzene [1-Methyl-2-ethyl benzene]
43 Isomer of tetramethyl benzene [1 ,2,3,4-Tetramethyl-benzene]
44 1-Methyl-3-(1-methylethyl-) benzene
45 Naphthalene
46 1-Ethylpropyl-benzene
47 Saturated Alcohol 3-Methyl-1-butanol
48 1-Hexanol
49 Isomer of ethyl hexanol [3-Methyl-1-hexanol]
50 2-Ethyl-1 -Hexanol
51 Isomer of octanol [1 -Odanol]
52 Isomer of octanol [1 -Octanol]
53 Unidentified C13H280[1-Tndecanol)
54 Unsaturated Alcohol Isomer of Octen-ol [3-Octen-2-ol)
55 Isomer of Octen-ol |3-Octen-2-ol]
56 Saturated Aldehyde Unidentified C5H10.0(Pentanal]
57 Unidenti!edC6.H12.0[Hexanal]
58 C7 Aldehyde [Heptanalj
59 Nonanal
60 Decanal
61 Unsaturated Aldehyde 2-Methyl-propenal
62 Isomer of Hexenal [2-Hexenal]
63 Isomer of Hexenal [2-Hexenal]
64 C7Unsat aldehyde [2-Heptenal]
65 C7 Unsat. aldehyde [2-Heptenal]
66 2,4-Heptadienal
. .

•



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•
•

•

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•






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•
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                                             A-8

-------
                                               Table  A-4   (concluded)
Index
                                                                CENSUS REGION                       NORTHEAST

                                                               CENSUS DIVISION       MIDDLE ATLANTIC            NEW ENGLAND

                                                                    AGE GROUP      0-14     15-44    45+     0-14    15-44  45+
            Compound Class   Compound Name (a)
67 2,4-Nonadien3l
68 lsomerofdecenal[2-0ecenal]
69 Isomerol decanal [2-Dec9nal]
70 Unsat. aldehyde [2-Decenal]
71 Unsat. aldehyde [2-Decenal]
72 Unsat. aldehyde [2-Decenal]
73 Diene aldehyde [2,4-Decadienal]
74 Diene aldehyde [2,4-Decadienal]
75 Diene aldehyde J2,4-Dodecadienal)
76 Saturated Ketone C7 Ketone [2-Heptanone]
77 4-Heptanone
78 Unidentified C7 H12 0 [2,2,3-Tnmethyl-cyclobutanone]
79 C8 Ketone [3-Octanone)
80 Sat. ketone [2-Decanone]
81 Unsaturated Ketone Isomer of Octen-one (3-Octen-2-one|
82 C8 Ketone [3-Octen-1-one]
83 3,5-Octadien-2-one
84 C9 Unsat. ketone [3-Nonen-2-one]
85 Saturated Ether Dimethoxy methane
86 Saturated Ester Propanoic acid, ethyl ester
87 C5 Methyl ester [Butanoic acid, methyl ester]
88 Propanoic add, propyl ester
89 Pentanoic acid, methyl ester
90 C7 Methyl ester [Hexanoic acid, methyl ester]
91 3-Methyl butanac acid, ethyl ester
92 Propanoic acid, butyl ester
93 2-Methyl propanoic acid, 1 -methytethyl ester
94 Acetic add, pentyl ester
95 2-Methyl butanolc acid, ethyl ester
96 C8 Ethyl ester [Hexanoic acid, ethyl ester]
97 Acetic acid, hexyl ester
98 C8 Ester [3-Methyl butanoic acid, propyl ester]
99 C8 Ester [Butanoic acid, 1 -Methy Ipropy I ester]
1 00 C8 Ester [Butanoic acid, 1 -Methylpropyl ester]
101 Octanoic acid, methyl ester
102 Hexanoic acid, 1-methylethyl ester
1 03 Butanoic acid, pentyl ester
1 04 Hexanoic add, 2-methylpropyl ester
1 05 Octanoic acid, ethyl ester
1 06 C1 0 Ester [2-Methy l-propanoic acid, hexyl ester]
107 C11 Ester [Hexanoic acid, pentyl ester]
1 08 C1 1 Ester [4-Methyl pentanoic add, pentyl ester]
1 09 C1 1 Ester [Hexanoic acid, 2-Methybutyl ester]
110 Isomer of octanoic add [3-Methyl-butyl ester]
111 Unsaturated Ester 3-Octen-1-ol, acetate
112 Halocaibon CSBromoalkane[1-Bromopentane]
113 3-Bromo-Pentane
114 Brominated alkane 2 C7 [1-Bromo-heptane]
115 Dichlorobutane [1 ,4-dichlorobutane]
116 2-Bromo-2-chtoro-1,1,trifluoro-ethane
117 Phenol Isomer of ethyl-phenol [4-Ethyl-phenol]
118 Heterccycle Unidentified C9.H1 4.0 [2-Pentyl-furan]
119 Sulfide Dimethyl disulfide
120 Dimethyl trisutftde
121 Organo-Silicon Decamethyl-cyclopentasiloxane
• •



•



• •

•
•



•



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•

•

•


•
• •


•
•
•

•



•
*

•
•
•

•



•


•
•
•
•
•



•

•
 (a)   Tentative compound identification is based on search vs. the NBS mass spectral library. Confirmation has not been achieved by comparing
     retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                   A-9

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                               APPENDIX B


DOT MATRIX TABLE FOR COMPOUNDS IDENTIFIED IN THE 6% FLORISIL SEMIVQLATILE
      ORGANIC ANALYSIS DATA SET;  SEMIVOLATILE ORGANIC COMPOUNDS VS.
              CENSUS REGION, CENSUS DIVISION. AND AGE GROUP
                                   B-l

-------
Index
       Table B-l.   Compounds  Identified  in the  6% Florisil  Semivolatile  Organic
       	Analysis  Data Set - West Census Region	
                                                    CENSUS DIVISION
                                                                    MOUNTAIN
                                                       AGE GROUP   0-14   15-44   45*
                                                                                        PACIFIC
                                                                                   0-14   15-44
                                                                                               45*
       Compound Class   Compound (a)
I.S Imernal Standard DiO-Anthracene
1 Alkane 2,6,10,14-Tetramethyl-hexadecane
2 2,6,1 0,1 4-Tetramethyl-nonad8cane
3 Alkane > C18 i2,6,10,14,19-Pentamethyl eicosane)
4 Saturated Ketone 1,2,4-Cyclopentatrione
5 Saturated Ester 12-Methyl-tridecanoic acid, methyl ester
6 Nonanedioic acid, bis(l-methylpropyl) ester
7 9-Octadecenoic acid, ethyl ester
8 Sulfide Methyl 2-methyH-(methylthio)butyldisuifide
9 Dimethyl tnsullide
10 Dipeptfde Glycme, anhydride
11 Alkene C5 Substituted naphthalene
[Octahydro-tetramethyl-lH-cyclopropan[A]naphthalene]
12 Hexahydro-4,7-dimethyM-(1-methytethyl)-naphthalene..
13 5-Ethyhdene-1 -methyl-cycloheptene
14 C30 Unsat. hydrocarbon [Hexamethyl-tetracosahexaene]
15 Ylangene
16 Unsaturated Aldehyde 2-Butyl-2-octenal
17 Unidentified C9.HB.O [Cyclooctatetraene-1-carboxaldehyde]
18 Unsaturated Amme N,N-Dimethyl-3-octen-2-amme
19 Unsaturated Ketone 6,10-Dimethyl-5,9-undecadien-2-one
20 Arene C4 Alkyl benzene [1-Ethyl-2,3-dimethyl benzene]
21 2-EthyH,3-dimethyl-benzene
22 C4 Alkyl benzene [4-Ethyl-1 ,2-dimethyl-benzene)
23 C4 Alkyl benzene [Diethyl benzene]
24 C4 Alkyl benzene [Methyl(1-methytethyl)-benzene]
25 Cyclohexyl-benzene
26 C3 Alkyl benzene [1,3,5 Tnmethyl-benzene]
27 C4 Alkyl benzene [1-Ethyl-2,3-dimethyl benzene]
28 C5 Alkyl benzene [1-Ethyl-4-(1-methylethyl)-benzene]
29 C3 Alkyl benzene |1-Ethyl-3-methyl-benzene]
30 C3 Alkyl benzene [1 -Ethyl-2-methyl-benzene]
31 C3 Alkyl benzene 11 ,3,5-Trimethyl-benzene
32 C3 Alkyl benzene [1 ,3,5-Trimethyl-benzene
33 C4 Alkyl benzene |1 -Ethyl-2,4-dimethyl-benzene]
34 2-Methyl-naphthalene
35 Unidentified C10.H12 [2,3-Dihydro-1-methyl-1H-lndene]
36 Unidentified C15.H24 [Hexahydro-tetramethyl-1H-benzocycloheptene]
37 Unsat. C4 alkyl benzene [4-Ethenyl-1,2-dimethyl-benzene]
38 2-Propenyl-benzene
39 Aromatic Aldehyde Benzaldehyde
40 4-Pentyl-benzald9hyde
41 Aromatic Ketone Unidentified C9 H8 0 [2,3-Dihydro-1 H-lnden-1-one]
42 1-Phenyl-ethanone
43 Phenol 2,6-Bis(1,1-dimethylethyl)-4-methyl-phenol
44 [1,1'-Biphenyl]-2-ol
45 2,2'-Methylenebis[6-(1 ,1-dimethylethyl)-4-methyl-phenol
46 Aromatic Ester Benzenepropanoic acd, ethyl ester
47 Aromatic Ether 1,1'-0xybis-benzene
48 1 -Methoxy-4-(i -propenylj-benzene
49 Aromatic Amme C2 Alkyl benzenamme (3,5-Dimethyl-benzenamine]
50 Aromatic Oxime 4-Metnyi benzaldehyde, oxime
51 Thiocyanic Ester Thiocyarac acid, phenyl aster
52 Heterocyclic Compound 2,3,5-TrimethyHH-pyrrole
53 Unidentified C8.H7.N [1 H-lndote]
5 4 Unidentified C8 H7 N [Indolizine]
5"i 2-(Methylthio)-benzothiazole
56 5-(2-Propenyl)-1,3-Benzodioxole
57 1,4-Dioxaspiro[4.6]undec-7-ene
58 2,4-Dihydro-2,5-dimethyl-3H-pyrazol-3-one
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                                               B-2

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                                                          Table  B-1   (concluded)
Index
                                                                               CENSUS DIVISION
                                                                                                        MOUNTAIN
                                                                                    AGE GROUP    0-14    15-44    45+
       PACIFIC

0-14    15-44    45*
           Compound Class     Compound (a)
59 5,5-Diethyl-2,4-imidazolidinedione
60 Steroid (5.Alpha.)-cholest-3-ene
61 (3. Beta.)- Cholest-S-en-3-ol acetate
62 Cholest-5-en-3-ol- (S.beta.)-, propanoate
63 Cholest-5-en-3-one
64 Cholest-5-ene
65 (5.Alpha.)-cholest-7-en-3-one
66 Cholesta-3,5-dien-7-one
67 (3 Beta.)-cholesta-4,6-dien-3-ol benzoate
68 Cholesterol
69 Isomer of cholesterol [5-cholesten-3-ol propionate]
70 Pregnane, (S.alpha.)-
71 (3 Beta )-26,27-dinorergost-5-en-3-ol benzoate
72 Chlorinated Hydrocarbon 1,1-Dichloro-1 -propane
73 (4-Chlorophenyl)phenyl-methanone
74 2-Chk>ro-6-methyl-benzonitrile
7 5 Dichtorobenzene [1 ,3-dichloro-benzene]
76 Lmdane
77 ODD
78 Organo-Silicon Isomer of decamethykyclopentasiloxane
79 Octamethyl-cyclotetrasiloxane
80 Isomer of decamethyl-cyctopentasiloxane
81 Phthalate Diheptyl phthalate



•



"



•

•



•
•









•
•
 (a)  Tentative compound identification is based on search vs. the NBS mass spectral library. Confirmation has not been achieved by comparing
     retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                         B-3

-------
Mac
         Table  B-2.   Compounds  Identified  in the 6%  Florisil  Semivolatile  Organic
        	Analysis  Data  Set  - South  Census Region	
                                                    CENSUS REGION
                                                                                 SOUTH
                                                   CENSUS DIVISION  EAST SOUTH CENTRAL  SOUTH ATLANTIC     WEST SOUTH CENTRAL

                                                      AGE GROUP  0-14  15-44   45*  0-14   15-44   45+   0-14   15-44   45+
       Compound Class   Compound (a)


1 Alkane 2,6,10,14-Tetramethyl-hexadecane
2 2,6,10,14-Tetramethyl-nonadecane
3 Alkane S C18 [2,6,10,14,19-Pentamethyl eicosane]
4 Saturated Ketone 1,2,4-Cydopentatnone
5 Saturated Ester 12-Methyl-tridecanoic add, methyl ester
6 Nonanedioic add, bisfl-mathylpropyl) ester
7 9-Octadecenac add, ethyl ester
8 Sutfide Methyl 2-methyl-1-(methylthio)butyl disultide
9 Dimethyl tnsulfide
10 DipepDde Glyane, anhydride
11 Alkene C5 Substituted naphthalene
[Octahydro-tetramethyl-1H-cyclopropan[A)naphthalene]
12 Hexahydro-4,7-dimethyl-1-(1-methylethyl)-naphthalene...
14 C30 Unsat. hydrocarbon |Hexamethyl-tetracosahexaene|
15 Ylangene
16 Unsaturated Aldehyde 2-Butyl-2-octenal
17 Unidentified C9 H8 0 [Cyclooctatstraene-l -carboxaldehyde]
18 Unsaturated Amme N,N-Dimethyl-3-octen-2-amme
19 Unsaturated Ketone 6,10-Dimethyl-5,9-undecadien-2-one
20 Arene C4Alkyl benzene |1-Ethyl-2,3-dimethyl benzene]
21 2-Ethyl-1,3-dimethyl-b8nzene
22 C4 Alkyl benzene [4-Ethyl-1 ,2-dimethyl-benzenej
23 C4 Alkyl benzene [Dielhyl benzene]
24 C4 Alkyl benzene |Methyl(1-methylethyl)-benzene]
25 Cyclohexyl-benzene
26 C3 Alkyl benzene [1 ,3,5-Tnmelhyl-benzen8]
27 C4 Alkyl benzene [1 -Ethyl-2,3-dimethyl benzene]
28 C5 Alkyl benzene [1-Ethyl-4-(1-methylethyl)-benzenej
29 C3 Alkyl benzene [1 -Ethyl-3-methyl-benzene]
30 C3 Alkyl benzene [1-Ethyl-2-methyl-benzene]
31 C3 Alkyl benzene [1 ,3,5-Trimethyl-benzene
32 C3 Alkyl benzene [1 ,3,5-Trimethyl-benzene
33 C4 Alkyl benzene [1-Ethyl-2,4-dimethyl-benzene]
34 2-Methyl-naphthal8ne
35 Unidentified ClOH12[2,3-Dihydro-1-methyl-1H-lndenel
36 Unidentified C15.H24 [Hexahydro-tetramethyl-1H-benzocydoheptene]
37 Unsat C4alkyl benzene [4-Ethenyl-1,2-dimethyl-benzene]
38 2-Propenyl-benzene
39 Aromatic Aldehyde Benzaldehyde
40 4-Pentyl-benzaldehyde
41 Aromatic Ketone Unidentified C9.H8.0[2,3-Dihydro-1H-lnden-1 -one]
42 1 -Phenyl-ethanone
43 Phenol 2,6-8is(1,1-dimethylethyl)-4-methyl-phenol
44 [1,1'-Biphenyl]-2-ol
45 2,2'-Methylenerjts(6-(1,1-dimelhylethyl)-4-methyl-phenol
46 Aromatic Ester Benzenepropanoic acid, ethyl ester
47 Aromatic Ether 1,1'-0xybis-benzene
48 1-Methoxy-4-(1-propenyl)-benzene
49 Aromatic Amine C2 Alkyl benzenamme[3,5-Dimethyl-benzenan«n8]
50 Aromatic Oxime 4-Methyl benzaldehyde, oxime
51 Thiocyanic Ester Thiocyanic add, phenyl ester
52 Heterocydic Compound 2,3,5-Trimethyl-1H-pyrrole
53 Unidentified C8 H7.N [1 H-lndoie]
54 Unidentified C8H7N[lndolizine]
55 2-(Methylthio)-benzothiazole
56 5-(2-Propenyl)-1,3-Benzodioxole
57 1,4-Dioxaspiro[46]undec-7-ene
58 2,4-Dihydro-2,5-dimethyl-3H-pyrazol-3-one
59 5,5-Diethy!-2,4-imidazolidinedione
60 Steroid (5.Alpha.)-cholest-3-ene
61 (S.Beta.)- Cholest-5-en-3-ol acetate













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                                                    B-4

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                                                                 Table  B-2  (concluded)
hdex
                                                                           CENSUS REGION                             SOUTH

                                                                          CENSUS DIVISION  EAST SOUTH CENTRAL    SOUTH ATLANTIC      WEST SOUTH CENTRAL

                                                                               AGE GROUP    0-14    15-44    45+    0-14    15-44    45+     0-14   15-44    45+
          Compound Class    Compound (a)
62 Cholest-S-en-3-ol- (3. beta.)-, propanoate
63 Cholest-S-en-3-one
64 Cholest-5-ene
65 (5.Alpha.)-cholest-7-en-3-one
66 Cholesta-3,5-dien-7-on8
67 (3. Beta )-cholesta-4,6-dien-3-ol benzoale
68 Cholesterol
70 Pregnane, (S.alpha )-
71 (3 Beta.)-26,27-dinorergost-5-en-3-ol benzoate
72 Chlorinated Hydrocarbon 1,1-Dichloro-1-propene
73 (4-Chlorophenyl)phenyl-metrianone
74 2-Chloro-6-methyl-benzonitrile
75 ftchlorDbenzene[1,3-dichloro-benzene]
76 Lindane
77 ODD
78 Organo-Silicon Isomer of decamethyl-cydopentasiloxane
79 Octamethyl-cyclotetrasiloxane
60 Isomer of decamethyl-cydopentasiloxane
81 Phthalate Diheptyl phlhalate
•

•
•

•
.

•



•
•



•


:


•


•
• •
•






•






•
•

 (a)  Tentative compound identification is based on search vs. the NBS mass spectral library Confirmation has not been achieved by comparing
     retention with an authentic standard In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                       B-5

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Index
           Table  B-3.   Compounds  Identified in  the 6%  Florisil  Semivolatile Organic
                  	Analysis  Data  Set  - North Central  Census Region	
                                                     CENSUS REGION
                                                    CENSUS DIVISION
                                                                            NORTH CENTRAL
                                                                  EAST NORTH CENTRAL
                                                       AGE GROUP   0-14
                                                                       15-44
                                                                               45*
 WEST NORTH CENTRAL

0-14    15-44    45+
       Compound Class    Compound (a)
IS. Internal Standard 010-Anthracene
1 Akane 2,6,10,14-Tetramethyl-hexadecane
2 2,6,1 0,14-Tetramethyl-nonadecane
3 Alkane a C18 (2,6,10, 14,19-Pentamethyl eicosane]
4 Saturated Ketone 1,2,4-Cyclopentatrione
5 Saturated Ester 12-Methyl-tridecanoic acid, methyl ester
6 Nonanedioic acid, bis(1 -methylpropyl) ester
7 9-Octadecenoic acid, ethyl ester
8 Sulfide Methyl 2-methyl-1-(methylthio)butyldisulfide
9 Dimethyl trisulfide
10 Dipeptide Glycine, anhydride
11 Alkene C5 Substituted naphthalene
[Octahydro-tetramethyl-1H-cyclopropan|Ajnaphthalenej
12 Hexahydro-4,7-dimethyM -(1 -methylethyl)- naphthalene..
13 5-Ethylidene-1 -methyl-cycloheptene
14 C30 Unsat hydrocarbon [Hexamethyl-tetracosahexaene]
15 Ylangene
16 Unsaturated Aldehyde 2-Butyl-2-octenal
17 Unidentified C9 H8 0 [Cyclooctatetraene-1 -carboxaldehyde]
18 Unsaturated Amine N,N-Dimethyl-3-octen-2-amme
19 Unsaturated Ketone 6,10-Dime!hyl-5,9-undecadien-2-one
20 Arene C4 AlkyI benzene (1 -Ethyl-2,3-dimethyl benzene]
21 2-Ethyl-1 ,3-dimethyl-berc-ene
22 C4 AlkyI benzene [4-Ethyl-1 ,2-dimethyl-benzene]
23 C4 AlkyI benzene [Diethyl benzene]
24 C4 AlkyI benzene [Methylp -methylethyl)-benzene]
25 Cycbhexyl-benzene
26 C3 AlkyI benzene [1 ,3,5-Trimethyl-benzene]
27 C4 AlkyI benzene |1 -Ethyl-2,3-dimethyl benzene]
28 C5 AlkyI benzene |1 -Ethyl-4-(1 -methylethylj-benzene]
29 C3 AlkyI benzene [1-Ethyi-3-methyl-benzene]
30 C3 AlkyI benzene [1 -Ethyl-2-methyl-benzene]
31 C3 AlkyI benzene (1 ,3,5-Trtmethyl-benzene
32 C3 AlkyI benzene [1 ,3,5-Trimethyl-benzene
33 C4 AlkyI benzene [1-Ethyl-2,4-dimethyl-benzenel
34 2-Methyl-naphthalene
35 Unidentified C1 0 H1 2 |2,3-Dihydro-1 -methyl-1 H-lndene]
36 Unidentified C15 H24 [Hexahydro-tetramethyHH-benzocycloheptene]
37 Unsat. C4 alkyl benzene t4-EthenyM ,2-dimethyl-benzene]
38 2-Propenyl-benzene
39 Aromatic Aldehyde Benzaldehyde
40 4-Pentyl-benzaldehyde
41 Aromatic Ketone Unidentified C9 H8.0 [2,3-Dihydro-1 H-lnden-1 -one]
42 1-Phenyl-ethanone
43 Phenol 2,6-Bis(1,1-dimethylethyi|-4-methyl-phenol
44 [1,1'-Biphenyl]-2-ol
45 2,2'-Methylenebis(6-(1 ,1 -dimethylethyl)-4-methyl-phenol
46 Aromatic Ester Benzenepropanoic acid, ethyl ester
47 Aromatic Ether 1,1'-0xybis-benzene
48 1 -Methoxy-4-(1 -propenylj-benzene
49 Aromatic Amine C2 AlkyI benzenamine (3,5-Dimethyl-benzenamine]
50 Aromatic Oxime 4-Methyl benzaldehyde, oxime
51 Thiocyamc Ester Thiocyanic acid, phenyl ester
52 Heterocydic Compound 2,3,5-Tnmethyl-lH-pyrrole
53 Unidentified CB H7N [1H-lndole]
5 4 Unidentified C8 H7 N [ Indolizine]
5r 2-(Methylthio)-benzothiazole
56 5-(2-Propenyl)-1,3-Benzodioxole
5 7 1 ,4-Dioxaspiro[4 6]undec-7-ene
58 2,4-Dihydro-2,5-dimethyl-3H-pyrazol-3-one
59 5,5-Diethyl-2,4-imidazolidinedione
60 Steroid (5 Alpha )-cholest-3-ene
61 (3 Beta )- Cholest-5-en-3-ol acetate
62 Cholest-5-en-3-ol- (3 beta )-, propanoate
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                                                B-6

-------
                                                         Table  B-3   (concluded)
                                                                           CENSUS REGION
NORTH CENTRAL
                                                                          CENSUS DIVISION      EAST NORTH CENTRAL

                                                                               AGE GROUP    0-14      15-44      45*
               WEST NORTH CENTRAL

              0-14      15-44     45+
         Compound Class    Compound (a)
63 Cholest-5-en-3-one
64 Cholest-5-ene
65 (5.Alpha.)-cholest-7-en-3-one
66 Cholesta-3,5-dien-7-one
67 (3.Beta.)-cholesta-4,6-dien-3-ol benzoate
68 Cholesterol
69 Isomer of cholesterol [5-cholesten-3-ol propionate]
70 Pregnane, (S.alpha )-
71 (3.Beta.)-26,27-dinorergost-5-en-3-ol benzoate
72 Chlorinated Hydrocarbon 1,1-Dichtoro-1-propene
73 (4-Chk>rophenyl)phenyl-methanone
74 2-Chloro-6-methyl-benzonitnte
7 5 Dichbrobenzene |1 ,3-dichloro-benzene]
76 Lindane
77 ODD
78 Organo-Silicon Isomer o! decamethyl-cyclopentasiloxane
79 Octamethyl-cyclotetrasiloxane
80 Isomer of decamethyl-cyclopentasiloxane
81 Phthalate Oiheptyl phthalate
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(a) Tentative compound identification is based on search vs the NBS mass spectral library. Confirmation has not been achieved by comparing
   retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
   a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                 B-7

-------
        Table  B-4.   Compounds  Identified  in the  6% Florisil  Semi volatile  Organic
        	  Analysis  Data  Set  -  Northeast  Census  Region
                                                      CENSUS REGION

                                                     CENSUS DIVISION

                                                         AGE GROUP
                                                           NORTHEAST

                                                MIDDLE ATLANTIC      NEW ENGLAND
                                                                   0-14    15-44
                                                                               45+
                                                                                     0-14 15-44 45+
Index   Compound Class
Compound (a)
IS. Internal Standard 010-Anthracene
1 Akane 2,6,10,14-Tetramethyl-hexadecane
2 2,6,10,14-Tetramothyl-nonadecane
3 Alkane a C18 |2,6,10,14,19-Pentamethyl eicosane]
4 Saturated Ketone 1 ,2,4-Cyclopentatrione
5 Saturated Ester 12-Methyl-tridecanoic acid, methyl ester
6 Nonanedioic acid, bis(l-methylpropyl) ester
7 9-Octadecenoic acid, ethyl ester
8 Sullide Methyl 2-methyH -(methylthio)butyl disullide
9 Dimethyl tnsulfide
10 Oipeptide Glycine, anhydride
11 Alkene C5 Substituted naphthalene
(Octahydro-tettamethyl-1H-cydopropan[A]naphthalene]
12 Hexahydro-4,7-dimethyl-1-(1-methylethyl)-naphthalene
13 5-Ethylidene-1 -methyl-cycloheptene
14 C30 Unsat. hydrocarbon [Hexamethyl-tetracosahexaene]
15 Ylangene
16 Unsaturated Aldehyde 2-Butyl-2-octenal
17 Unidentified C9 H8 0 [Cyclooctatetraene-1-carboxaldehydel
18 Unsaturated Amme N,N-Dimethyl-3-octen-2-amme
19 Unsaturated Ketone 6,10-Dimethyl-5,9 undecadien-2-one
20 Arene C4 Alkyl benzene ll-Ethyl^.S-dimethyl benzene]
21 2-Ethyl-1,3-dimethyl-benzene
22 C4 Alkyl benzene [4-Ethyl-1,2-dimethyl-benzene)
23 C4 Alkyl benzene (Diethyl benzene]
24 C4 Alkyl benzene |Melhyl(1 -methylethyl)-benzene]
25 Cyctohexyl-benzene
26 C3 Alkyl benzene |1,3,5-Trimethyl-benzene]
27 C4 Alkyl benzene 1 1 -Ethyl-2,3-dimethyl benzene]
28 C5 Alkyl benzene |1 -Ethyl-4-(1 -methylethylj-benzene]
29 C3 Alkyl benzene [1 -Ethyl-3-methyl-benzenel
30 C3 Alkyl benzene [1-Etnyl-2-methyl-benzene]
31 C3 Alkyl benzene |1,3,5-Trimethyl-benzene
32 C3 Alkyl benzene 1 1 ,3,5-Tnmethyl-benzene
33 C4 Alkyl benzene [1-Ethyl-2,4-dimethyl-benzene]
34 2-Methyl-naphthalene
35 Unidentified C10 H12 |2,3-Dihydro-1-methyl-1H-lndene]
36 Unidentified C15 H24 [Hexahydro-tetramethyl-1 H-benzocycloheptene]
37 Unsat C4 alkyl benzene [4-Ethenyl-1,2-dimethyl-benzene]
38 2-Propenyl-benzene
39 Aromatic Aldehyde Benzaldehyde
40 4-Pentyl-benzaldehyde
41 Aromatic Ketone Unidentified C9H8.0[2,3-Dihydro-lH-lnden-1 -one]
42 1-Phenyl-ethanone
43 Phenol 2,6-Bis(l,1-dimethylethyl)-4-methyl-phenol
44 (1,1'-Biphenyl]-2-ol
45 2,2'-Methylenebis|6-(1 ,1 -dimethylethyl)-4-me!hyl-phenol
46 Aromatic Esier Benzenepropanoic acid, ethyl ester
47 Aromatic Ether 1,l'-0xybis-benzene
48 1 -Methoxy-4-(1 -propenyl)-benzene
49 Aromatic Amme C2 Alkyl benzenamine [3,5-Oimethyl-benzenamine]
50 Aromatic Oxime 4-Methyl benzaldehyde, oxime
51 Thiocyamc Ester Thiocyanic acid, phenyl ester
52 Heterocyclic Compound 2,3,5-Trimethyl-lH-pyrroie
53 UnidentifiedC8H7N[lH-lndole]
54 Unidentified C8 H7 N [Indolizine]
55 2-(Methylthio)-benzothiazole
66 5-(2-Propenyl)-1 ,3-Benzodioxole
57 1 ,4-Dioxaspiroi4.6]undec-7-ene
58 2,4-Dihydro-2,5-dimethyl-3H-pyrazol-3-one
59 5,5-Diethyl-2,4-imidazolidinedione
60 Steroid (5.Alpha.)-cholest-3-ene
61 (3.Beta.)- Cholest-5-en-3-ol acetate
62 Cholest-5-en-3-ol- (3 beta )-, propanoate
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                                                          Table  B-4   (concluded)
                                                                               CENSUS REGION                       NORTHEAST

                                                                              CENSUS DIVISION       MIDDLE ATLANTIC         NEW ENGLAND

                                                                                   AGE GROUP    0-14    15-44     45+       0-1415-4445*
Index   Compound Class
Compound (a)
63 Cholest-5-en-3-one
64 Cholest-5-ene
65 (5 Alpha.)-cholest-7-en-3-one
66 Cholesta-3,5-dien-7-one
67 (3 Beta.)-cholesta-4,6-dien-3-ol benzoate
68 Cholesterol
69 Isomer of cholesterol [5-chotesten-3-ol propionate]
70 Pregnane, (S.alpha )-
71 (3 Beta.)-26,27-dinorergost-5-en-3-ol benzoate
72 Chlorinated Hydrocaibon 1,1-Dichk>ro-1-propene
73 (4-Ch!orophenyl)phenyl-methanone
74 2-Chloro-6-m8thyl-benzonitnle
7 5 Dichbrobenzene [1 ,3-dtehloro-benzene]
76 Lindane
77 ODD
78 Organo-Silicon Isomer of decamethyl-cyclopemasiloxane
79 Octamethyl-cyclotetrasiloxane
8 0 Isomer of decamethyl-cyclopentasiloxane
81 Phthalate Diheptyl phthaJate
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 (a)  Tentative compound Identification is based on search vs. the NBS mass spectral library. Confirmation has not been achieved by comparing
     retention with an authentic standard In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                     B-9

-------
                                 APPENDIX C


DOT MATRIX TABLE FOR COMPOUNDS IDENTIFIED IN THE 15/50% FLORISIL SEMIVOLATILE
        ORGANIC ANALYSIS DATA SET; SEMIVOLATILE ORGANIC COMPOUNDS VS.
                CENSUS REGION, CENSUS DIVISION. AND AGE GROUP
                                     C-l

-------
Index
       Table C-l.   Compounds  Identified  in the  15/50%  Florisil Semivolatile  Organic
      	Analysis  Data  Set - West Census  Region	        _
                                                     CENSUS REGION

                                                    CENSUS DIVISION

                                                       AGE GROUP
                                                     WEST
                                          MOUNTAIN
                                                                  0-14
                                                                        15-44  45+
                                                                                    0-14
                                                              PACIFIC
                                                                                          15-44   454
            Compound Class
Com pound (a)
IS. Internal Standard D10-Anthracene - Internal Standard
1 Akane Unidentified C10.H20(Diethylcyclohexane]
2 Saturated Ester 1,7,7-Trimethyl-bicyclo[22.1lheptan-2-ol, exo propanoate-
3 Dodecanoic acid, ethyl ester
4 Hexariedioic atid,mono(2-ethylhexyl) ester
5 Alkyl ester (15-Methyl-heptadecanoate]
6 Saturated Polyfunctional Ethylhydrazone propionaldehyde
7 9-Oxo-nonanoic acid, ethyl ester
8 Alkene 1-Methyl-3-(1-methylethenyl)-cyclohexene
9 Unsaturated Aldehyde Trimethyl-3-cyclohexene-1-carboxaldehyde
10 2-Butyl-2-octenal
11 Unsaturated Ketone 3-Methyl-3-Buten-2-one, dirtier
12 2,4,6-Cycloheptatriene-1-one
13 5-Undecen-4-one
14 5-Ethyl-2-methyl-4-heptene-3-one
15 Unsaturated Polyfuntional Substituted cyclopentenone [Butyl-methoxy-cyclopeffien-1 -one]
16 Substituted cyclopentenone [Butyl-methoxy-cyclopenten-1-one]
17 Substituted cyclopentenone [Butyl-methoxy-cyclopenten-1 -one]
18 2-Methoxy-2-octen-4-one
19 Alkyne 5,5-Dimethyl-3-heptyne
20 Arene C3-Alkyl benzene (1 ,3,5-tnmethyl-benzene]
21 C3 Alkyl benzene |1 ,2,4-Trimethyt-benzene]
22 C3-Alkyl benzene (1 ,2,4-trimethyl-benzene]
23 C3 Alkyl benzene (1-Ethyl-3-methyl-benzene]
24 UnidentifiedC11.H10 [1-Ethylidene-mdene]
25 Aromatic Aldehyde Benzakiehyde
26 Unidentified C10.H10.0 [.Alpha, -ethyhdene-benzeneacetaktehyde]
27 Unidentified C10 H10.0 [ Alpha. -ethyhdene-benzeneacetaldehyde]
28 AromatK: Ketone 1 -Phenyl-ethanone
29 Aromatic Amide N-Methyl-1-naphthalenecarboxamide
30 Aromatic Carboxylate Derivative Benzenepropanoic acid, .beta.,.beta -dimethyl-
31 2-(acetylamino)-benzoic adid.methyl ester
32 Benzenepropanoic acid, ethyl ester
3 3 Benzenepropanoic acid
34 Phthalic Acid Derivative Butyl decyl phthalate
35 Isomef of diheptyl phthalate
3 6 Isomer of diheptyt phthalate
37 Butyl phthalate, ester with butyl glycolate
38 Unidentified phthalate
39 Phenol Methyl phenol |2-Methyl-phenol]
40 [1,1'-Biphenyl]-2-ol
41 2-Naphthalenol
42 Aromatic Polyfunctional 1 ,3-Dimethoxy-benzene
43 1-Phenyl-1,2-butanediol
44 2-Ethoxy-benzaldehyde
45 Unidentified C7 H5 0 N S [Thiocyanic acid, 4-hydroxyphenyl ester]
46 Drug Methaqualone
47 Unidentified barbiturate [5-Ethyl-1 ,3-dimethyl pyrimidinetnone]
48 Alkyl substituted pyrimidinetnone [Mephobarbital]
49 Alkyl substituted pyrimidinetnone [Pentobarbital]
50 Alkyl substituted pyrimidinetrione [PhenobarbitalJ
51 Alkyl substituted pyrimidinetrione [Metharbital]
52 Alkyl substituted pyrimidinetnone [Metharbital]
53 Heterocyclic Compound 1 ,7-Naphthyridine
54 Isomerof dimethyl-piperidine [1,4-Dimethyl-piperidine]
55 3-Pyridinecarboxaldehyde, oxime
56 4-Pyridinecarboxaldehyde
5 7 Unidentified C8 H7 N [Indolizine]
58 C2 Alkyl pyrazine |2,6-Dimethyl pynzine]
59 2-Methoxy-3-methyl-pyrazine
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                                             C-2

-------
                                                             Table  C-l   (concluded)
Index
                                                                               CENSUS REGION

                                                                              CENSUS DIVISION

                                                                                  AGE GROUP
                                                                               WEST
                                                               MOUNTAIN

                                                           0-14     15-44   45+
      PACIFIC

0-14      15-44    45*
                  Compound Class
Compound (a)
60 1 ,2-Benzisothiazote
61 Unidentified C7.H11.N.S [ 2-Methyl-4-propyl-thiazole]
62 Alkyl thazote [4-Ethyl-5-methyl-thiazole]
63 4-Propyl-thiazole
64 1,3-Banzodioxol8
65 4,7-Dimethyl-3(2H)-benzofuranone
66 Unidentified C11 H16.02[Tetrahydro-trimethyl-2(4H)-benzofiiranone]
67 5-(Butylimino)-2(5H)-furanone
68 2H-1-Benzopyran-2-one
69 1,3,5-TrimethyMH-pyrazole
70 Isomer of thienyl-ethanone [1-(3-Thienyl)-ethanone]
71 1 -(4-Hydroxy-3-thienyl)-ethanone
72 2,3,4-tnmethyl thiophene
73 2-Methyl-5-propyl-thiophene
74 2-t-Butoxy-thiophene
75 Steroid Isomer of cholest-en-ol (Cholest-5-en-3-ol,acetate]
76 Isomer of cholest-en-ol [Cholest-5-en-3-ol,acetate]
77 Chol8st-5-en-3-ol (3.beta.)-, propanoate
78 Cholest-5-en-3-one
79 Cholest-5-ene
80 Isomer of cholest-en-ol [4-Methykholest-8(14)-en-3-ol]
81 Cholesta-3,5-dien-7-one
82 Cholesta-4,6-dien-3-ol (3 Beta.), Benzoate
83 Cholesta-5,7-dien-3-ol, (3,beta)
84 Isomer of cholestanol [Cholestanol]
85 Methyl-cholestan-3-ol, (3 beta ,5 alpha., e.beta.)-
86 3-(Acetoxy)-cholestan-6-one, (3.beta,5.alpha.)-
87 Chotestane-3,5-diol, (3.beta ,5 alpha.)-
88 Cholestanol
89 Cholesterol
90 Halogenated Hydrocarbon 1-Chloro-4-(Methylsulfonyl)-benzene
91 Isomer of fluoro-methyl-benzene [1 -Fluoro-2-methyl-benzene]
92 Carbonochlondothioic acid, S-methyl ester
93 1,1-Dichlora-ethene
94 4-Chloro-2-(phenylmethyl)-phenol
95 Organo-Silicon 1-Butynyl-trimethyl silane
96 Tnmethyl|(1 -methyl-2-propynyl)oxyl-silane
•
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 (a)   Tentative compound identification is based on search vs the NBS mass spectral library Confirmation has not been achieved by comparing
      retention with an authentic standard  In cases where more than one reference compound successfully matched the unknown spectrum,
      a general descriptive name is reported and the best ranked NBS name is provided in brackets
                                                                  C-3

-------
Index
              Table  C-2.   Compounds Identified  in the 15/50%  Florisil  Semivolatile  Organic
             	Analysis  Data  Set  -  South Census  Region
                                                  CENSUS REGION                       SOUTH

                                                  CENSUS DIVISION   EAST SOUTH CENTRAL    SOUTH ATLANTIC
                                                     AGE GROUP
                                                                0-14   15-44   45+   0-14
                                                                                     15-44    45+
                                                                                                 WEST SOUTH CENTRAL
                                                                                                   0-14  15-44  45+
       Compound Class
Compound Name (a)


1 Alkane Unidentified ClOH20[Diethylcyclohexane]
2 Saturated Ester 1,7,7-Tnmethyl-bicyclo(22.1]h9ptan-2-ol, exo propanoate-
3 Dodecanese add, ethyl ester
4 Hexanedioic aad,mono(2-ethylhexyl) ester

6 Saturated Polyfunctional Ethylhydrazone propionaldehyde
7 9-Oxo-nonanoic acid, ethyl ester
8 Alkene 1-Methyl-3-(1-methylethenyl)-cydohexene
9 Unsaturated Aldehyde Tnrmthyl-3-cydohexene-1-carboxaldehyde
10 2-Butyl-2-octenal
11 Unsaturated Ketone 3-Methyl-3-8uten-2-one, dimer
12 2,4,6-Cycloheptatnene 1-one
13 5-Undecen-4-one
14 5-Ethyl-2-methyl-4-heptene-3-one
15 Unsaturated PolyfunConal Substituted cydopentenone[8utyl-methoxy-cydopenten-1 -one]
16 Substituted cydopenterione[Butyl-methoxy-cydopenten-1-one]
17 Substituted cydopentenone [Butyl-methoxy-cydopenten-1-one]
18 2-Methoxy-2-octen-4-one
19 Alkyne 5,5-Dimethyl-3-heptyne
20 Arena C3-Alkyl benzene [1,3,5-tnmethyl-benzene]
21 C3 Alkyl benzene [1 ,2,4-Tiimethyl-benzene]
22 C3-Alkyl benzene [1 ,2,4-trimethyl-benzene]
23 C3 Alkyl benzene [1-Ethyl-3-methyl-benzene]
24 Unidentified C11 .H10 [1-Ethylidene-indene]
25 Aromatic Aldehyde Benzaldehyde
26 Unidentified C10.H10 0 [ Alpha.-ethylidene-benzeneacetaldehyde]
27 Unidentified C10 H1 0 0 j Alpha.-ethylidene-benzeneacetaldehyde]
28 Aromatic Ketone 1 -Phenyl-ethanone
29 Aromatic Amide N-Methyl-1-naphthalenecarboxamide
30 Aromatic Carboxylate Derivative Benzenepropanoic acid, .beta.,. beta.-dimethyl-
31 2-(acetylamino)-benzoic adid.methyl ester
3 2 Benzenepropanoic acid, ethyl ester
33 Benzenepropanoic acid
34 Phthalic Acid Derivative Butyl decyl phthalate
3 5 Isomer of diheptyl phthalate
36 Isomer of diheptyl phthalate
37 Butyl phthalate, ester with butyl glycolate
38 Unidentified phthalate
39 Phenol Methyl phenol [2-Methyl-phenol]
40 [1,1'-Biphenyl]-2-ol
41 2-Naphthalenol
42 Aromatic Polyfunctional 1 ,3-Dimethoxy-benzene
43 1-Phenyl-1,2-butanediol
4 4 2-Ethoxy-benzal dehyde
45 Unidentified C7 H5 0 N S (Thocyamc acid, 4-hydroxyphenyl ester]
46 Drug Methaqualone
47 Unidentified barbiturate [5-Ethyl-1,3-dimethyl pynmidmetnone]
48 Alkyl substituted pynmdmetrione [Mephobarbital]
49 Alkyl substituted pynmidmetnone [Pentobarbital]
50 Alkyl substituted pynnudinetnone [Phenobarbital]
51 Alkyl substituted pynmdinetrione [Metharbital]
52 Alkyl substituted pyrimidinetrione [Metharbital]
53 Heterocydic Compound 1,7-Naphthyndme
54 Isomer of dimethyl-pipendine [1 ,4-Dimethyl-pipendme]
55 3-Pyndmecarboxaldehyde, oxime
56 4-Pyndmecarboxaldehyde
57 Unidentified C8H7N|lndolizine]
58 C2 Alkyl pyrazme (2,6-Dimethyl pyrizine]
59 2-Methoxy-3-methyl -pyrazme
60 1 ,2-Benzisothiazole
61 Unidentified C7 H1 1 N S [ 2-Methyl-4-propyl-thiazole]
62 Alkyl thazole [4-Ethyl-5-methyl-thiazole]



















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                                                    C-4

-------
                                                                         Table  C-2.  (concluded)
Wax
CENSUS REGION
CENSUS DIVISION
AGE GROUP
EAST SOUTH CENTRAL
0-14 15-44 45+
SOUTH
SOUTH ATLANTIC
0-14 15-44 45+
WEST SOUTH C
0-14 15-'
          Compound Class
Compound Name (a)
63 4-Propyl-thiazole
64 1 ,3-Benzodioxde
65 4,7-Dimethyl-3(2H)-benzofuranon8
66 Unidentified C11.H16.02 [Tetrahydro-trimethyl-2(4H)"benzofuranone]
67 5-(Butylimino)-2(5H)-furanone
68 2H-1-Benzopyran-2-one
69 1,3,5-TrimethyMH-pyrazole
70 Isomer of thienyl-ethanone |1-(3-Thienyl)-ethanone]
71 1-(4-Hydroxy-3-thienyl)-ethanone
72 2,3,4-tnmethyl thiophene
73 2-Methyl-5-propyl-thiophene
74 2-t-Butoxy-thiophene
75 Steroid Isomer of cholest-en-ol [Cholest-5-en-3-d,acetate]
76 Isomer of cholest-en-ol [Cholest-5-en-3-d,acetate]

79 Chdest-5-ene
80 Isomer of cholest-en-ol [4-Methyl-cholest-8(14)-en-3-ol]
81 Cholesta-3,5-dien-7-one
83 Cholesta-5,7-dien-3-ol, (S.beta)
84 Isomer of cholestanol [Cholestand]
85 Methyl-cholestan-3-ol, (3.beta.,5.alpha.,6.beta)-
86 3-(Acetoxy)-cholestan-6-one, (3.beta,5.alpha.)-
87 Cholestane-S.S-did, (3.beta ,5 alpha.)-
88 Cholestanol

90 Halogenated Hydrocaiton l-Chloro-4-(Methylsulfonyl)-benzene
91 Isomer of fluoro-methyl-benzene [1 -Ruoro-2-methyl-benzene]
92 CarbonocNoridothioic acid, S-methyl ester
93 1,1-DicWoro-flthene
94 4-Chloro-2-(phenylmethyl)-phenol
95 Organo-Stlicon 1-Butynyl-tnmethyl silane
96 Trimethyl[(1-methyl-2-propynyl)oxy]-silane

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     retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                            C-5

-------
hdex
        Table C-3.   Compounds  Identified in  the 15/50%  Florisil Semivolatile  Organic
       	Analyses Data Set  -North CentraJ  Census Region	
                                                  CENSUS REGION
                                                 CENSUS DIVISION
                            AGE GROUP
                                                                          NORTH CENTRAL
                                                                EAST NORTH CENTRAL

                                                                0-14     15-44    45+
 WEST NORTH CENTRAL

0-14     15-44    45+
          Compound Class
Compound Name (a)
IS. Internal Standard DiO-Anthracene - Internal Standard
1 Alkane Unidentified C1 0 H20 (Diethyl cyclohexane]
2 Saturated Ester 1,7,7-Tnmethyl-bicyclo[2.2.1]heptan-2-ol, exo propanoate-
3 Dodecanoc acid, ethyl ester
4 Hexanedioic acid,mono(2-eihylhexyl) ester
5 Alkyl ester [15-Methyl-heptadecanoate]
6 Saturated Polyfunctional Ethylhydrazone propionaldehyde
7 9-Oxo-nonanoic acid, ethyl ester
8 Alkene 1-Methyl-3-(1-methylethenyl)-cyclohexene
9 Unsaturated Aldehyde Trimethyl-3-cyclohexene-1-carboxaldehyde
10 2-Butyl-2-ocienal
11 Unsaturated Ketone 3-Methyl-3-Buten-2-one, dimer
12 2,4,6-Cycloheptatriene-1-one
13 5-Undecen-4-one
14 5-Ethyl-2-methyl-4-heptene-3-one
15 Unsaturated Polyfuntional Substituted cyclopentenone |Butyl-methoxy-cyclopenten-1 -one]
16 Substituted cyclopentenone [Butyl-methoxy-cyclopenten-1-one]
17 Substituted cyclopentenone [Butyl-methoxy-cyclopenten-1-one]
18 2-Methoxy-2-octen-4-one
19 Alkyne 5,5-Dimethyl-3-heptyne
20 Arene C3-Alkyl benzene [1,3,5-tnmethyl-ben2ene]
21 C3 Alkyl benzene [1 ,2,4-Trimethyl-benzene]
22 C3-Alkyl benzene |1,2,4-tnmethyl-benzene]
23 C3 Alkyl benzene [1-Ethyl-3-methyl-benzene]
24 Unidentified Cl1.H10[1-Ethylidene-indene]
25 Aromatic Aldehyde Benzaldehyde
26 Unideraified C10.H10.0 [.Alpha. -ethylidene-benzeneacetaldehyde]
27 Unidentified C10 H10 0 [ Alpha.-ethylkJene-benzeneacetaldehyde]
28 Aromatic Ketone 1 -Phenyl-ethanone
29 Aromatic Amide N-Methyl-1-naphthalenecarboxamide
30 Aromatic Carboxylate Derivative Benzenepropanoic acid, beta., beta.-dimethyl-
31 2-(acetylamino)-benzoic adid.methyl ester
32 Benzenepropanoic acid, ethyl ester
33 Benzenepropanoic acid
34 Phthalic Acid Derivative Butyl decyl phinalate
35 Isomer of diheptyl phthalate
36 Isomer of diheptyl phthalate
37 Butyl phthalate, ester with butyl glycolate
38 Unidentified phthalate
39 Phenol Methyl phenol [2-Methyl-phenol|
40 [1,1'-Biphenyl]-2-ol
41 2-Naphthalenol
42 Aromatic Polyfunctional 1,3-Dimethoxy-benzene
43 1-Phenyl-1,2-butanediol
44 2-Etnoxy-benzaldehyde
45 Unidentified C7 H5 0 N S [Thiocyanic acid, 4-hydroxyphenyl ester)
46 Drug Methaqualone
47 Unidentified barbiturate (5-Ethyl-1 ,3-dimethyl pyrimidinetrione]
48 Alkyl substituted pyrimidinetrione [Mephobarbrtal]
49 Alkyl substituted pyrimidinetrione [Pentobarbital]
50 Alky] substituted pyrimidinetrione |Phenobarbrtal]
51 Alkyl substituted pyrimidinetrione (Metharbital)
52 Alkyl substituted pyrimidinetrione (Metharbital)
53 Heterocyclic Compound 1,7-Naphthyridme
54 Isomer of dimethyl piperidme [1,4-Dimethyl-pipendme]
55 3-Pyridmecart>oxaldehyde, oxime
56 4-Pyndinecarboxaldehyde
5 / Unidentified C8 H7.N [Indolizme]
58 C2 Alkyl pyrazine [2,6-Dimethyl pynzme]
59 2-Methoxy-3-methyl-pyrazine
. .




. .

•

•



•

•

•
•
. • .




. .

•


•


•



• •

• • •

•


• •



•




•


•

,




.

•





•
•


•
•
.


















.
•

,



•






•
•

•

                                              C-6

-------
                                                            Table  C-3  (concluded)
Index
                                                                        CENSUS REGION                     NORTH CENTRAL

                                                                       CENSUS DIVISION       EAST NORTH CENTRAL           WEST NORTH CENTRAL

                                                                            AGE GROUP      0-14       15-44     45+      0-14       15-44     45+
               Compound Class
Compound Name (a)
60 1,2-Benzisothiazote
61 Unidentified C7.H1 1 .N.S [ 2-Methyl-4-propyl-thiazole]
62 Alkyl thazote [4-Ethyl-5-methyl-thiazole)
63 4-Propyl-thiazote
64 1 ,3-Benzodioxole
65 4,7-Dimethyl-3(2H)-benzofuranone
66 Unidentified C11.H16.02 [Tetrahydro-trirnethyl-2(4H)-benzofuranone]
67 5-(Butylimino)-2(5H)-furanone
68 2H-1-Benzopyran-2-one
69 1,3,5-Trimethyl-1H-pyrazole
70 Isomer of thienyl-ethanone [1-(3-Thienyl)-ethanone]
71 1 -(4-Hydroxy-3-thienyl)-ethanone
7? 2,3,4-trimethyl thiophene
73 2-Methyl-5-propyl-thiophene
74 2-t-Butoxy-thiophene
75 Steroid Isomer of cholest-en-ol [Cholest-5-en-3-ol,acetate)
76 Isomer of cholest-en-ol [Cholesl-5-en-3-ol, acetate)
77 Cholest-5-en-3-ol (S.beta.)-, propanoate
78 Cholest-5-en-3-one
79 Cholest-5-ene
80 Isomer of cholest-en-ol [4-Methyl-cholest-B(14)-en-3-ol]
81 Cholesta-3,5-dien-7-one
82 Cholesta-4,6-dien-3-ol (3.Beta.), Benzoate
83 Cholesta-5,7-dien-3-ol, (3.beta )
84 Isomer of cholestanol [Cholestanol]
85 Methyl-cholestan-3-ol, (3.beta,5.alpha.,6 beta )-
86 3-(Acetoxy)-cholestan-6-one, (3.beta,5.alpha.)-
87 Cholestane-3,5-diol, (3 beta.,5 alpha.)-
88 Cholestanol
89 Cholesterol
90 Hatogenated Hydrocarbon 1-Chloro-4-(Methylsullonyl)-benzene
91 Isomer of fluoro-methyl-benzene [1 -Fluoro-2-methyl-benzene]
92 Carbonochloridothioic acid, S-methyl ester
93 1,1-Dichloro-etnene
94 4-Chk>ro-2-(phenylmethyl)-phenol
95 Organo-Silicon 1 -Butynyl-trimethyl silane
96 Trimethyl[(1 -methyl-2-propynyl)oxy]-silane

• •
•
*
•
• •

.
•



•
•



•
•

•
•
• •

 (a)  Tentative compound identification is based on search vs. the NBS mass spectral library. Confirmation has not been achieved by comparing
     retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets.
                                                                C-7

-------
    Table  C-4.   Compounds  Identified  in the 15/50% Florisil  Semivolatile Organic
   	Analysi^ Data Set - Northeast Census  Region	
Index
                                                   CENSUS REGION                NORTHEAST

                                                   CENSUS DIVISION     MIDDLE ATLANTIC       NEW ENGLAND

                                                      AGE GROUP    0-14   15-44   45+    0-14 15-44 45+
           Compound Class
Compound Name (a)
IS. Internal Standard DIO-Anthracene - Internal Standard
1 Alkane Unidentified ClO.H20[Diethylcyclohexanel
2 Saturated Ester 1,7,7-Trimethyl-bicyclo[2.2.ljheptan-2-ol, exo propanoate-
3 Dodecanoic acid, ethyl ester
4 Hexanedioic acid,mono(2-ethylhexyl) ester
5 Alkyl ester [15-Methyl-heptadecanoate]
6 Saturated Polyfunctional Ethylhydrazone propionaldehyde
7 9-Oxo-nonanoic acid, ethyl ester
8 Alkene 1-Methyl-3-(1-methytethenyl)-cyclohexene
9 Unsaturated Aldehyde Tnmethyl-3-cyclohexene-1-carboxaldehyde
10 2-Butyl-2-octenal
11 Unsaturated Ketone 3-Melhyl-3-Buten-2-one, dimer
12 2,4,6-Cycloheptatriene-1-one
13 5-Undecen-4-one
14 5-Ethyl-2-meihyl-4-heptene-3-one
15 Unsaturated Polyfuntional Substituted cyclopenlenone [Butyl-methoxy-cyclopenten-1-one]
16 Substituted cyclopentenone [Butyl-methoxy-cyclopenten-1-onej
17 Substituted cyclopentenone lButyl-methoxy-cyclopenten-1-one]
18 2-Methoxy-2-octen-4-one
19 Alkyne 5,5-Dimethyl-3-heptyn8
20 Arene C3-Akyl benzene [1,3,5-trimethyl-benzenel
21 C3 Alkyl benzene |1 ,2,4-Tnmethyl-benzene]
22 C3-Akyl benzene [1 ,2,4-tnmethyl-benz8nel
23 C3 Alkyl benzene [1 -Elhyl-3-methyl-benzene]
2 4 Unidentified C1 1 .H1 0 [1 -Ethylidene-indene]
25 Aromatic Aldehyde Benzaldehyde
26 Unidentified C1 0.H10 0 [ Alpha, -ethylidene-benzeneacetaktehyde]
27 Unidentified C10.H10.0 [.Alpha.-ethylidene-benzeneacetaldehyde]
28 Aromatic Ketone 1-Phenykthanone
29 Aromatic Amide N-Methyl-1-naphthalenecarboxamide
30 Aromatic Carboxylate Derivative Benzenepropanoic add, .beta , beta.-dimethyl-
31 2-(acetylamino)-benzoic adid.methyl ester
32 Benzenepropanoic acid, ethyl ester
33 Benzenepropanoic acid
34 Phthalic Acid Derivative Butyl decyl phthalate
35 Isomer of diheptyl phthalate
36 Isomer of diheptyl phthalate
37 Butyl phthalate, ester with butyl glycolate
38 Unidentified phthalate
39 Phenol Methyl phenol [2-Methyl-phenol]
40 (1,1'-Biphenylj-2-ol
41 2-Naphthalenol
42 Aromatic Polyfunctional 1,3-Dimethoxy-benzene
43 1-Phenyl-1,2-butanediol
44 2-Ethoxy-benzaldehyde
45 Unidentified C7 H5 0 N S (Thiocyanic acid, 4-hydroxypt18ny! ester]
46 Drug Methaqualone
47 Unidentified barbiturate [5-Ethyl-1 ,3-dimethyl pynmidinetrione]
48 Akyl substituted pyrimidinetrione [Mephobarbital]
49 Alkyl substituted pyrimidinetrione |PentobarbitalJ
50 Alkyl substituted pyrimidinetrione [Phenobarbital)
51 Alkyl substituted pyrimidinetrbne [Metharbital]
52 Alkyl substitutsd pynmidinetrione [Metharbital)
53 Heterocyclic Compound 1,7-Naphthyndine
54 Isomer of dimethyl-pipendine [1 ,4-Dimethyl-piperidme]
55 3-Pyridinecarboxaldehyde, oxime
56 4-Pyridinecarboxaldehyde
57 Unidentified C8.H7.N [Indoliane]
58 C2 Alkyl pyrazine [2,6-Dimethyl pynzme]
59 2-Methoxy-3-methyl-pyrazine
. .




.
•


•





•
•
•
;
. .




.



•

•



•



, .

•


.
•
•


•
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•
•
•
•
,




.
•
•







•


:
,




.









•



.




•
•
•







•
•


                                                 C-8

-------
                                                          Table  C-4  (concluded)
Index
                                                                           CENSUS REGION                       NORTHEAST

                                                                          CENSUS DIVISION       MIDDLE ATLANTIC          NEW ENGLAND

                                                                               AGE GROUP       0-14     15-44   45+      0-14  15-44  45+
                Compound Class
Compound Name (a)
60 1,2-Benzisothiazole
61 Unidentified C7.H1 1 .N.S 1 2-Methyl-4-propyl-thiazole]
62 Akyl thazole [4-Eihyl-5-methyl-thiazolel
63 4-Propyl-thiazole
64 1,3-Benzodioxote
65 4,7-Dimethyl-3(2H)-benzofuranone
66 Unidentified C1 1 .H1 6.02 [Tetrahydro-trimethyl-2(4H)-benzofuranonel
67 5-(Butylimino)-2(5H)-furanone
68 2H-l-Benzopyran-2-one
69 1,3,5-Tnmethyl-1H-pyrazol8
70 Isomer of thienyl-ethanone [1-(3-Thienyl)-ethanone]
71 1 -(4-Hydroxy-3-thienyl)-ethanone
72 2,3,4-trimethyl thiophene
73 2-Methyl-5-propyl-thiophene
74 2-t-Butoxy-thiophene
75 Steroid Isomer of cholest-en-ol [Cholest-5-en-3-ol,acetate]
76 Isomer of cholest-en-ol [Cholest-5-en-3-ol, acetate]
77 Cholest-5-en-3-ol (3 beta.)-, propanoate
78 Cholest-5-en-3-one
79 Cholest-5-ene
80 Isomer of cholest-en-ol |4-Methyl-cholest-8(14)-en-3-ol]
81 Chotesta-3,5-dien-7-one
82 Cholesta-4,6-dien-3-ol (3. Beta.), Benzoate
83 Cholesta-5,7-dien-3-ol, (3.beta.)
8 4 Isomer of cholesterol |Chotestanol]
85 Methyl-cfiolestan-3-ol, (3.beta.,5 alpha.,6.beta.)-
86 3-(Acetoxy)-cholestan-6-one, (3 beta.S.alpha.)-
87 Cholestane-3,5-diol, (3.beta.,5.alpha )-
88 Cholestanol
89 Cholesterol
90 Halogenated Hydrocarbon 1-Chtoro-4-(Methylsulfonyl)-benzene
91 Isomer of lluoro-methyl-benzene [1 -Ruoro-2-methyl-benzene]
9 2 Carbonochlondothtoic acid, S-methy! ester
93 1,1-Dichbro-ethene
94 4-Chloro-2-(phenylmethyl)-phenol
95 Organo-Silicon 1 -Butynyl-trimethyl silane
96 Tnmethyl|(1-methyl-2-propynyl)oxy]-silan9

•
•

•
•
•

•
•
•


•


•
•


•
•

*
 (a)  Tentative compound identification is based on search vs the NBS mass spectral library. Confirmation has not been achieved by comparing
     retention with an authentic standard. In cases where more than one reference compound successfully matched the unknown spectrum,
     a general descriptive name is reported and the best ranked NBS name is provided in brackets
                                                                       C-9

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                              APPENDIX D


DOT MATRIX TABLE FOR UNIDENTIFIED HRGC/MS PEAKS IN THE VOLATILE ORGANIC
ANALYSIS DATA SET; UNIDENTIFIED VOLATILE ORGANIC COMPOUND RESPONSES VS.
             CENSUS REGION, CENSUS DIVISION. AND AGE GROUP
                                  D-l

-------
Table D-l.  Unidentified Peaks in the Volatile Organic Analysis
                  Data Set - West Census Region
CENSUS REGION
CENSUS DIVISION
AGE GROUP
WEST
MOUNTAIN
0-14 15-44 45+ 0-14
PACIFIC
15-44 45+
Index Average Total Number.,
Number RRT of Occurrences
I.S. 1.000 46
1 0.481 46
2 3.216 46
3 3.114 45
4 2 659 44
5 4.213 43
6 0 370 41
7 2 398 41
8 0.405 34
9 2.890 30
10 4353 28
11 3.862 24
12 0.286 23
13 3.322 21
14 3.314 18
15 2771 14
16 2.689 13
17 1.997 12
18 3.384 12
19 3.873 12
20 2.666 11
21 4390 11
22 2.570 10
23 3.962 9
24 4142 9
25 0 335 8
26 2.369 8
27 2.619 8
28 3.364 8
29 3.812 8
30 1.488 7
31 2.572 7
32 3 177 7
33 4159 7
34 2.053 6
35 4.388 6
36 4 573 6
37 0 802 5
38 1.744 5
39 2.495 5
40 2.867 5
41 2.906 5
42 3.308 5
43 3 501 5
44 4319 5
45 0 277 4
46 0 408 4
47 1 719 4
48 3 064 4
49 3.159 4
50 3.513 4
51 3 881 4
52 3.908 4
53 4317 4
54 0 381 3
55 1 141 3
56 2.721 3
57 3 482 3
58 4.146 3
•
*
*
"

•
•


.
.

•
•

*
.

•


.
•

•
•
•



•
•
•


•
                               D-2

-------
                          Table D-1  (concluded^
                    CENSUS REGION

                    CENSUS DIVISION

                    AGE GROUP
             WEST

   MOUNTAIN             PACIFIC

0-14   15-44  45+      0-14   15-44   45+
Index Average Total Number
Number RRT of Occurrences 9
59 0.285 2
60 0.573 2
61 2.141 2
62 2.892 2
63 3.012 2
64 3.551 2
65 3 564 2
66 3.700 2
67 3.963 2
68 4.113 2
69 0.313 1
70 1.036 1
71 1.511 1
72 1.672 1
73 2.028 1
74 2.239 1
75 2.262 1
76 2.271 1
77 2.301 1
78 2.407 1
79 2.671 1
80 2.891 1
81 2.907 1
82 2.988 1
83 3.073 1
84 3.100 1
85 3.175 1
86 3.314 1
87 3.371 1
88 3.453 1
89 3.461 1
90 3.494 1
91 3.650 1
92 3.782 1
93 3.829 1
94 3.975 1
95 3.993 1
96 4.192 1
97 4.635 1
98 4.812 1
99 5.004 1
















•









•



aTota1  number  of occurrences  from all  sample  analyses  (four  census  regions
 and  nine census divisions).
                                       D-:

-------
Table D-2.   Unidentified Peaks in the Volatile Organic Analysis
                Data Set - South Census Region



Index
Number
CENSUS REGION SOUTH
CENSUS DIVISION EAST SOUTH CENTRAL SOUTH ATLANTIC
AGE GROUP 0-14 15-44 45* 0-14 15-44 45+
Average Total Number
RRT of Occurrences 9

WEST SOUTH CENTRAL
0-14 15-44 45+










9 2.890 30
1C 4353 28
11 3.862 24
12 0286 23
13 3.322 21
14 3314 18
15 2771 14
16 2689 13
17 1997 12
18 3384 12
19 3873 12
20 2666 11
21 4390 11
22 2570 10
23 3.962 9
24 4.142 9
25 0.335 8
26 2.369 8
27 2619 8
28 3 364 8
29 3.812 8
30 1.488 7
31 2.572 7
32 3177 7
33 4.159 7
34 2.053 6
35 4388 6
36 4573 6
37 0 802 5
38 1 744 5
39 2 495 5
40 2867 5
41 2 906 5
42 3 308 5
43 3501 5
44 4319 5
45 0 277 4
46 0.408 4
47 1.719 4
48 3.064 4
49 3159 4
50 3.513 4
51 3.881 4
52 3 908 4
53 4317 4
54 0.381 3
55 1141 3
56 2721 3
57 3 482 3
58 4.146 3









•
•
•













• •
•
*
;
•









> t
, .













p
• •
. .
•
•










•
. .
. . .
•
.










•
1
. .

•
•









t

•
*

•









• •
•
•
*
•
•









•

•
•


                              D-4

-------

CENSUS REGION 	
CENSUS DIVISION
AGE GROUP


Table
D-2 (concluded)
— SOUIH
EAST SOUTH CENTRAL SOUTH ATLANTIC
0-14 15-44 45+ 0-14 15-44 45+



WEST SOUTH CENTRAL
0-14 15-44 45+
Index Average Total Number
Number RRT of Occurrences"
59 0.285 2
60 0 573 2
61 2.141 2
62 2.892 2
63 3012 2
64 3.551 2
65 3 564 2
66 3 700 2
67 3 963 2
68 4.113 2
69 0313 1
70 1.036 1
71 1.511 1
72 1 672 1
73 2 028 1
74 2 239 1
75 2.262 1
76 2271 1
77 2.301 1
78 2 407 1
79 2671 1
80 2891 1
81 2.907
82 2 988
83 3 073
84 3.100
85 3.175
86 3314 1
87 3371 1
88 3 453 1
89 3.461 1
90 3.494 1
91 3 650 1
92 3.782 1
93 3 829 1
94 3975 1
95 3.993 1
96 4.192 1
97 4635 1
98 4.812 1
99 5 004 1





















•

•


•





. .

•











'




•


Total number of occurrences from all sample analyses (four census regions
and nine census divisions).
                                  D-5

-------
Table D-3.   Unidentified Peaks in the Volatile Organic Analysis
            Data Set - North Central Census Region
CENSUS REGION
CENSUS DIVISION
AGE GROUP
NORTH CENTRAL
EAST NORTH CENTRAL WEST NORTH CENTRAL
0-14 15-44 45+ 0-14 15-44 45+
Index Average Total Number
Number RRT of Occurrences 3
IS. 1.000 46
1 0.481 46
2 3.216 46
3 3.114 45
4 2.659 44
5 4.213 43
6 0.370 41
7 2.398 41
8 0 405 34
9 2 890 30
10 4.353 28
11 3862 24
12 0.286 23
13 3.322 21
14 3.314 18
15 2.771 14
16 2689 13
17 1.997 12
18 3.384 12
19 3.873 12
20 2.666 11
21 4.390 11
22 2.570 10
23 3 962 9
24 4.142 9
25 0 335 8
26 2.369 8
27 2.619 8
28 3.364 8
29 3812 8
30 1.488 7
31 2 572 7
32 3177 7
33 4.159 7
34 2.053 6
35 4.388 6
36 4 573 6
37 0 802 5
38 1.744 5
39 2 495 5
40 2.867 5
41 2.906 5
42 3.308 5
43 3 501 5
44 4.319 5
45 0.277 4
46 0.408 4
47 1719 4
48 3 064 4
49 3159 4
50 3513 4
51 3.881 4
52 3.908 4
53 4.317 4
54 0 381 3
55 1.141 3
56 2.721 3
57 3 482 3
58 4.146 3
• •
•
•
•
•

. . .
•
•
•
•

. . .
• •
•
•
•
•
•
•
.
•


•
•

•

•
•
• •

•

•
                             D-6

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                              Table D-3 (concluded)
                  CENSUS REGION                       NORTH CENTRAL


                  CENSUS DIVISION          EAST NORTH CENTRAL        WEST NORTH CENTRAL


                  AGE GROUP          0-14       15-44      45+      0-14  15-44    45*
Index Average Total Number
Number RRT of Occurrences 3
59 0.285 2
60 0.573 2
61 2141 2
62 2.892 2
63 3.012 2
64 3.551 2
65 3.564 2
66 3.700 2
67 3 963 2
68 4.113 2
69 0.313 1
70 1.036 1
71 1.511 1
72 1.672 1
73 2 028 1
74 2.239 1
75 2.262 1
76 2271 1
77 2.301 1
78 2.407 1
79 2.671 1
80 2.891 1
81 2.907 1
82 2.988 1
83 3.073 1
84 3.100 1
85 3.175 1
86 3.314 1
87 3.371 1
88 3.453 1
89 3.461 1
90 3.494 1
91 3 650 1
92 3.782 1
93 3 829 1
94 3.975 1
95 3.993 1
96 4.192 1
97 4635 1
98 4.812 1
99 5 004 1

•




•
.

•








,

•
"



•

•


Total  number of occurrences from all  sample  analyses (four census regions
and  nine census divisions).
                                        D-7

-------
Table D-4.   Unidentified Peaks in the Volatile Organic Analysis
              Data Set - Northeast Census Region
CENSUS REGION
CENSUS DIVISION
AGE GROUP


NORTHEAST
MIDDLE ATLANTIC
0-14
15-44
45* 0-


NEW ENGLAND
•14 15-44
45*
Index Averag* Total Number
Number RRT of Occurrence* "
IS 1.000 46
1 0.481 46
2 3216 46
3 3.114 45
4 2.659 44
5 4.213 43
6 0.370 41
7 2.398 41
8 0.405 34
9 2 890 30
10 4.353 28
1 1 3.862 24
12 0.286 23
13 3 322 21
14 3.314 18
15 2.771 14
16 2.689 13
17 1.997 12
18 3.384 12
19 3.873 12
20 2.666 11
21 4.390 11
22 2.570 10
23 3.962 9
24 4.142 9
25 0.335 8
26 2.369 8
27 2.619 8
28 3.364 8
29 3.812 8
30 1 488 7
31 2.572 7
32 3.177 7
33 4159 7
34 2053 6
35 4.388 6
36 4 573 6
37 0.802 5
38 1.744 5
39 2.495 5
40 2.867 5
41 2.906 5
42 3.308 5
43 3.501 5
44 4.319 5
45 0.277 4
46 0.408 4
47 1.719 4
48 3 064 4
49 3.159 4
50 3.513 4
51 3.881 4
52 3.908 4
53 4317 4
54 0.381 3
55 1.141 3
56 2 721 3
57 3.482 3
58 4146 3
•
•
•
• •


•
• •
.
•
•

•
•

•


•
•
•



•
•
.
.


•
•
*
.
'

                            D-8

-------
                              Table D-4  (concluded)
                   CENSUS REGION                    NORTHEAST

                   CENSUS DIVISION      MIDDLE ATLANTIC            NEW ENGLAND

                   AGE GROUP       0-14   15-44   45+      0-14  15-44  45+
Index Average Total Number _
Number RRT of Occurrences
59 0.2B5 2
60 0.573 2
61 2.141 2
62 2.892 2
63 3.012 2
64 3.551 2
65 3.564 2
66 3.700 2
67 3.963 2
68 4113 2
69 0.313 1
70 1.036 1
71 1.511 1
72 1.672 1
73 2.028 1
74 2.239 1
75 2.262 1
76 2.271 1
77 2.301 1
78 2 407 1
79 2.671 1
80 2.891 1
81 2.907
82 2.988
83 3.073
84 3.100
85 3.175
86 3.314
87 3.371
88 3.453
89 3.461
90 3.494
91 3.650 1
92 3.782 1
93 3.829 1
94 3.975 1
95 3.993 1
96 4.192 1
97 4 635 1
98 4.812 1
99 5.004 1


•


•



•



















•






Total  number  of occurrences from  all sample analyses  (four  census  regions
and  nine census divisions).
                                         D-9

-------
                            APPENDIX E


DOT MATRIX TABLE FOR UNIDENTIFIED HRGC/MS PEAKS IN THE 6% FLORISIL
 SEMIVOLATILE ORGANIC ANALYSIS DATA SET;  UNIDENTIFIED SEMIVOLATILE
           ORGANIC COMPOUND RESPONSES VS.  CENSUS REGION.
                  CENSUS DIVISION,  AND AGE GROUP
                                E-l

-------
 Table  E-l.  Unidentified Peaks in  the 6%  Florisil  Semi volatile
	Organic Analysis Data Set  -  West  Census  Region	
         CENSUS REGION

         CENSUS DIVISION

            AGE GROUP
                                    WEST
MOUNTAIN
                   PACIFIC
                       0-14   15-44  45+
                                         0-14   15-44
                                                    45+
Number of
Average Occurrences
Index RRT In Samples "
I.S 1.000 44
1 0.924 42
2 1.600 42
3 0 759 38
4 1.027 38
5 1 023 35
6 1.117 34
7 1 706 34
8 1.129 32
9 0 879 31
10 0702 30
11 0.919 30
12 0.990 29
13 0.838 28
14 0.912 26
15 1.481 26
16 1.760 25
17 0.985 24
18 1.059 24
19 0.673 23
20 0 993 23
21 0.982 22
22 1.533 22
23 1.063 21
24 1.199 21
25 1 374 21
26 0.726 19
27 1.741 19
28 0.952 17
29 1.237 17
30 1.629 17
31 1.5B6 16
32 0.493 15
33 1 002 15
34 1 065 15
35 0839 14
36 1.070 14
37 1 728 14
38 0.574 13
39 0.665 13
40 1.178 13
41 1 280 13
42 1.297 13
43 0190 12
44 0.666 12
45 0.310 11
46 0.603 11
47 1 082 11
48 1 131 11
49 1 146 11
50 0411 10
51 0.780 10
52 1.009 10
53 1.160 10
54 1 219 10
55 1.224 9
56 0 220 8
57 0.670 B
•
•

•
•
:
•
•

•
•

•
•
•
•
.
•
•
•
•

•







•
•
•
•
•
•
                                   E-?

-------
                    Table  E-l   (continued)
' CENSUS REGION~~~             WEST




 CENSUS DIVISION        MOUNTAIN                PACIFIC




     AGE GROUP    0-14   15-44   45+       0-14    15-44    45+
Number of
Average Occurrences
Index RRT In Samples &
58 0.959 8
59 1.178 8
60 1.197 8
61 1 .626 8
62 1.638 8
63 0.360 7
64 0.674 7
65 0.897 7
66 0.932 7
67 1.051 7
68 1.094 7
69 1.427 7
70 1 475 7
71 1 681 7
72 1.773 7
73 0 337 6
74 0 662 6
75 0.8BO 6
76 1 177 6
77 1.253 6
78 1 681 6
79 0.278 5
80 0.472 5
81 0 736 5
82 0 991 5
83 1.057 5
84 1 069 5
85 1 073 5
86 1 085 5
87 1.195 5
88 1 407 5
89 0.399 4
90 0 651 4
91 0 730 4
92 0 965 4
93 1 068 4
94 1.144 4
95 1 195 4
96 1 222 4
97 1 326 4
98 1 355 4
99 1 389 4
100 1.411 4
101 1.538 4
102 0316 3
103 0.608 3
104 0662 3
105 0747 3
106 0.754 3
107 0.855 3
108 0893 3
109 0.918 3
110 0967 3
111 1.019 3
112 1025 3
113 1.041 3
114 1045 3
115 1050 3





•

•
*
•
•

•

•

•

•
•


•
•
•
•










•
•
•
•


                               E-3

-------
                   Table  E-l   (continued)
 CENSUS REGION                     WEST




CENSUS DIVISION        MOUNTAIN               PACIFIC




    AGE GROUP    0-14   15-44   45+       0-14    15-44    45+
Number of
Average Occurrences
Index RRT In Samples 3
116 1.055 3
117 1.076 3
118 1.107 3
119 1.109 3
120 1.186 3
121 1 244 3
122 1.251 3
123 1.414 3
124 1.457 3
125 1.585 3
126 0325 2
127 0.356 2
128 0.747 2
129 0.754 2
130 0817 2
131 0.823 2
132 0.855 2
133 0.896 2
134 0.898 2
135 0.905 2
136 0.933 2
137 0.976 2
138 0982 2
139 0.985 2
140 1.020 2
141 1.038 2
142 1.053 2
143 1.080 2
144 1 106 2
145 1.120 2
146 1.124 2
147 1 143 2
148 1.152 2
149 1 158 2
150 1.179 2
151 1.221 2
152 1.252 2
153 1 336 2
154 1.345 2
155 1.360 2
156 1.382 2
157 1 542 2
158 1.577 2
159 1 589 2
160 1 600 2
161 1 680 2
162 1.727 2
163 1.731 2
164 0.229 1
165 0255 1
166 0.266 1
167 0 269 1
168 0 279 1
169 0.293 1
170 0.300 1
171 0329 1
172 0.357 1
173 0 406 1









•



•


"
.

.






•









*

•



                              E-4

-------
                    Table  E-l  (continued)
       Average
Index     RRT
 CENSUS REGION

CENSUS DIVISION

    AGE GROUP

   Number of
   Occurrences
   In Samples
                                               WEST

                                  MOUNTAIN                PACIFIC

                              0-14   15-44   45*       0-14   15-44    45+
174 0.406 1
175 0.463 1
176 0.499 1
177 0.539 1
178 0.575 1
179 0.672 1
180 0.676 1
181 0.708 1
182 0.724 1
183 0732 1
184 0.732 1
185 0 734 1
186 0742 1
187 0.743 1
188 0.747 1
189 0 749 1
190 0.799 1
191 0.829 1
192 0830
193 O.B55
194 0892
195 0.911
196 0.914
197 0.973
198 1.011 1
199 1.018 1
200 1.035 1
201 1.051 1
202 1.053 1
203 1.060 1
204 1.064 1
205 1.075 1
206 1 078 1
207 1.084 1
208 1.107 1
209 1117 1
210 1.117 1
211 1 118 1
212 1 121 1
213 1.122 1
214 1.134 1
215 1 134 1
216 1 138 1
217 1.140 1
218 1 140 1
219 1 152 1
220 1 161 1
221 1.170 1
222 1.189 1
223 1.208 1
224 1 217 1
225 1.226 1
226 1.262 1
227 1.288 1
228 1 .289 1
229 1.304 1
230 1.348 1
231 1 349 1










•
•


•
•


























                                E-5

-------
                               Table  E-l  (concluded)
    Index
    CENSUS REGION

   CENSUS DIVISION

       AGE GROUP

      Number of
      Occurrences^
RRT    In Sam pies
                                           WEST

                                MOUNTAIN              PACIFIC

                             0-14   15-44  45+      0-14   15-44
                                                           45+
232 1.349 1
233 1.350 1
234 1 356 1
235 1.375 1
236 1 379 1
237 1.394 1
238 1.407 1
239 1.534 1
240 1.588 1
241 1.590 1
242 1.596 1
243 1.624 1
244 1.634 1
245 1.646 1
246 1.659 1
247 1.676 1
248 1.678 1
249 1.701 1
250 1.709 1
251 1.718 1
252 1.721 1
253 1.731 1
254 1.734 1
255 1.734 1
256 1.740 1
257 1.804 1
258 1.889 1


















Total  number of  occurrences  from  all  sample  analyses (four census  regions
and  nine  census  divisions).
                                           E-6

-------
  Table  E-2.   Unidentified Peaks  in the  6% Florisil  Semivolatile Organic
                   Analysis Data Set  - South Census  Region	
CENSUS REGION

 CENSUS DIVISION

    AGE GROUP
                        SOUTH

 EAST SOUTH CENTRAL      SOUTH ATLANTIC          WEST SOUTH CENTRAL

0-14     15-44    45+    0-14     15-44     45+     0-14    15-44   45+
Number of
Average Occurrences
Index RRT In Samples 9



3 0 759 38
4 1 027 38
6 1117 34
8 1 129 32
9 0 879 31
10 0702 30
11 0919 30
12 0990 29
13 0838 28
14 0912 26
15 1481 26
16 1 760 25
17 0985 24
18 1 059 24
19 0673 23
20 0.993 23
21 0 982 22
22 1 533 22
23 1.063 21
24 1.199 21
25 1 374 21
26 0726 19
27 1 741 19
28 0952 17
29 1 237 17
30 1 629 17
31 1 586 16
32 0493 15
33 1 002 15
34 1 065 15
35 0839 14
36 1 070 14
37 1 728 14
38 0574 13
39 0665 13
40 1 178 13
41 1 280 13
42 1 297 13
43 0190 12
44 0656 12
45 0310 11
46 0603 11
47 1 082 11
48 1 131 11
49 1 146 11
50 0411 10
51 0780 10
52 1 009 10
53 1 160 10
54 1219 10
^5 1 224 9
56 0 220 8
57 0670 8




.

•
•
•
•
•





•
•
•
•
•
•
.






•




.





•
•
•



* *
f




. . .
	
....
•
. . .

•





• • • •

....
. i •
. . .
• •
•
• •




•
•
•
•
•
,
*







• •
* "
•







•
•
•
.
•
f


                                       E-7

-------
                                  Table  E-2  (continued)
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
                            SOUTH




  EAST SOUTH CENTRAL        SOUTH ATLANTIC




0-14     15-44    45+     0-14      15-44      45+
WEST SOUTH CENTRAL




0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples 3
58 0959 8
59 1.178 8
60 1,197 8
61 1 626 8
62 1 638 8
63 0.360 7
64 0 674 7
65 0 897 7
66 0 932 7
67 1.051 7
68 1 094 7
69 1 427 7
70 1.475 7
71 1 681 7
72 1 773 7
73 0.337 6
74 0662 6
75 0.880 6
76 1.177 6
77 1 253 6
78 1 681 6
79 0.278 5
80 0 472 5
81 0.736 5
82 0 991 5
83 1.057 5
84 1 069 5
85 1 073 5
86 1.085 5
87 1.195 5
88 1.407 5
89 0 399 4
90 0661 4
91 0730 4
92 0.965 4
93 1.068 4
94 1 144 4
95 1 195 4
96 1 222 4
97 1.326 4
98 1 355 4
99 1.389 4
100 1411 4
101 1.538 4
102 0316 3
103 0608 3
104 0 662 3
105 0747 3
106 0754 3
107 OB55 3
108 0 893 3
109 0918 3
110 0967 3
111 1019 3
112 1 025 3
113 1.041 3
114 1 045 3
115 1 050 3

.
•


•







•
•

•
.
•
•
•
•

•
•
•
.

• •

"
•
*
.
'
'
' *
*
•
•
.
•

•
,

.


•
•







*




                                             E-8

-------
                                   Table  E-2  (continued)
 CENSUS REGION




CENSUS DIVISION




    AGE GROUP
                            SOUTH




  EAST SOUTH CENTRAL        SOUTH ATLANTIC            WEST SOUTH CENTRAL




0-14     15-44    45+     0-14      15-44      45*       0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples a
116 1.055 3
117 1 076 3
118 1 107 3
119 1 109 3
120 1 186 3
121 1 244 3
122 1 251 3
123 1.414 3
124 1.457 3
125 1 585 3
126 0 325 2
127 0356 2
128 0747 2
129 0.754 2
130 0.817 2
131 0 823 2
132 0855 2
133 0 896 2
134 0898 2
135 0905 2
136 0 933 2
137 0976 2
138 0.982 2
139 0985 2
140 1 020 2
141 1 038 2
142 1 053 2
143 1 080 2
144 1 106 2
145 1 120 2
146 1 124 2
147 1.143 2
148 1 152 2
149 1 158 2
150 1 179 2
151 1 221 2
152 1 252 2
153 1 336 2
154 1.345 2
155 1 360 2
156 1 382 2
157 1.542 2
158 1 577 2
159 1 589 2
160 1 600 2
161 1 680 2
162 1 727 2
163 1 731 2
164 0229
165 0255
166 0266
167 0269
168 0279
169 0 293
170 0300
1 71 0329
172 0.357 1
173 0406 1

,










.







•




.
•
•






•


•



'



•



.
•
•
'
•




•













                                              E-?

-------
                                  Table  E-2  (continued^
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
                       EAST SOUTH CENTRAL




                     0-14     15-44    45+
      SOUTH




  SOUTH ATLANTIC




0-14     15-44     45+
WEST SOUTH CENTRAL




0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples a
174 0.406 1
175 0.463 1
176 0499 1
177 0.539 1
178 0575 1
179 0672 1
180 0.676 1
181 0.708 1
182 0.724 1
183 0.732 1
184 0732 1
185 0.734 1
186 0742 1
187 0.743 1
188 0.747 1
189 0749 1
190 0 799 1
191 0.829 1
192 0830 1
193 0 855 1
194 0.892 1
195 0911 1
196 0.914 1
197 0973 1
198 011 1
199 .018 1
200 035 1
201 051 1
202 053 1
203 1.060 1
204 1 064 1
205 1.075 1
206 1.078 1
207 1.084 1
208 1.107 1
209 1.117 1
210 1.117 1
211 1.118 1
212 1 121 1
213 1 122 1
214 1 134 1
215 1 134 1
216 1.138 1
217 1.140 1
218 1.140 1
219 1 152 1
220 1 161 1
221 1 170 1
222 1 189 1
223 1 208 1
224 1 217 1
225 1.226 1
226 1 262 1
227 1 288 1
228 1 289 1
229 1 304 1
230 1 348 1
231 1 349 1























•





.




.

,

•


•
•



,






•


















                                             E-10

-------
                                           Table E-2  (concluded)
Index
       CENSUS REGION

      CENSUS DIVISION

          AGE GROUP

       Number of
Average   Occurrences
 RRT    In Samples 5
                                EAST SOUTH CENTRAL

                               0-14     15-44    45+
     SOUTH

  SOUTH ATLANTIC

0-14     15-44      45+
WEST SOUTH CENTRAL

0-14     15-44   45+
232 1 349 1
233 1.350 1
234 1 356 1
235 1 375 1
236 1 379 1
237 1 394 1
238 1 407 1
239 1 534 1
240 1 .588 1
241 1 590 1
242 1 596 1
243 1 624 1
244 1 634 1
245 1 646 1
246 1 659 1
247 1 676 1
248 1 678 1
249 1 701 1
250 1 .709 1
251 1 718 1
252 1 721 1
253 1.731 1
254 1 734 1
255 1 .734 1
256 1 740 1
257 1.804 1
258 1 889 1






.





•
•
•

•






•



           Total  number of occurrences  from  all  sample analyses (four  census regions
           and  nine  census divisions).
                                                  E-ll

-------
Table E-3.   Unidentified  Peaks in  the 6%  Florisil  Semivolatile
   Organic  Analysis  Data  Set - North Central Census Region
           ~ra™   "GfdS"NORTH CENTRAL
           CENSUS DIVISION
                          EAST NORTH CENTRAL
               AGE GROUP  0-14
                               15-44
                                         45+
                                               WEST NORTH CENTRAL


                                                0-14  15-44   45+
Number of
Average Occurences
Index RRT In Samples a
IS. 1.000 44
1 0.924 42
2 1.600 42
3 0.759 38
4 1 027 38
5 1.023 35
7 1.706 34
9 0.879 31
10 0.702 30
11 0.919 30
12 0.990 29
14 0.912 26
15 1.481 26
16 1.760 25
17 0.985 24
18 1.059 24
19 0.673 23
20 0.993 23
21 0.982 22
22 1 .533 22
23 1.063 21
24 1.199 21
25 1.374 21
26 0726 19
27 1 741 19
28 0.952 17
29 1 237 17
30 1.629 17
31 1 586 16
32 0.493 15
33 1 002 15
34 1.065 15
35 0839 14
36 1.070 14
37 1.728 14
38 0.574 13
39 0.665 13
40 1.178 13
41 1 280 13
42 1 297 13
43 0190 12
44 0 666 12
45 0.310 11
46 0.603 11
47 1.082 11
48 1 131 11
49 1.146 11
50 0.411 10
51 0.780 10
52 1.009 10
53 1 160 10
54 1 219 10
55 1.224 9
56 0 220 8
57 0 670 8

•
•
•
•
•
*
•
• •
:;

• •
• • •
. . .
•
•
• •
•
•
•

• •
. . .
. : :
. . .
. . .
. . .
•
. . .
. . .


•

•
•
•

*
•


•
•
•
•





• •
• •
; :
: :
• •
• •
•
.
•
                                E-l?

-------
                               Table E-3  (continued)
                CENSUS REGION                     NORTH CENTRAL

               CENSUS DIVISION      EAST NORTH CENTRAL         WEST NORTH CENTRAL

                   AGE GROUP   0-14       15-44        45+       0-14   15-44    45+
Index
          RRT
Number of
Oceurences
In Samples a
58 0 959 8
59 1.178 8
60 1.197 8
61 1.626 8
62 1.638 8
63 0.360 7
64 0.674 7
65 0.897 7
66 0.932 7
67 1 051 7
68 1 094 7
69 1.427 7
70 1 475 7
71 1.681 7
72 1 .773 7
73 0 337 6
74 0.662 6
75 0.880 6
76 1.177 6
77 1.253 6
78 1.681 6
79 0.278 5
80 0 472 5
81 0 736 5
82 0.991 5
83 1.057 5
84 1.069 5
85 1.073 5
86 1 085 5
87 1.195 5
88 1.407 5
89 0 399 4
90 0 661 4
91 0.730 4
92 0 965 4
93 1 068 4
94 1.144 4
95 1.195 4
96 1.222 4
97 1 326 4
98 1 355 4
99 1 389 4
100 1 411 4
101 1.538 4
102 0316 3
103 0608 3
104 0.662 3
105 0747 3
106 0.754 3
107 0855 3
108 0893 3
109 0918 3
110 0.967 3
111 1019 3
112 1 025 3
113 1041 3
114 1.045 3
115 1050 3

•
"
" *
•
•

•
•
•
•
•
•

•
•
. . .
. .
•
f


.
•

.

•

•





• •
.
•
•
m

•
                                          E-13

-------
               Table  E-3  (continued)
 CENSUS REGION
CENSUS DIVISION
NORTH CENTRAL
                  EAST NORTH CENTRAL
    AGE GROUP  0-14
                       15-44       45+
          WEST NORTH CENTRAL




           0-14  15-44    45+
Numbs: of
Average Occurences
Index RRT In Samples"
116 1.055 3
117 1.076 3
118 1.107 3
119 1.109 3
120 1.186 3
121 1.244 3
122 1 251 3
123 1.414 3
124 1.457 3
125 1.585 3
126 0.325 2
127 0.356 2
128 0.747 2
129 0.754 2
130 0.817 2
131 0.823 2
132 0.855 2
133 0.896 2
134 0.898 2
135 0905 2
136 0.933 2
137 0.976 2
138 0.982 2
139 0.985 2
140 1.020 2
141 1.038 2
142 .053 2
143 .080 2
144 .106 2
145 .120 2
146 .124 2
147 .143 2
148 .152 2
149 .158 2
150 1.179 2
151 1.221 2
152 1.252 2
153 1.336 2
154 1.345 2
155 1.360 2
156 1.382 2
157 1.542 2
158 1.577 2
159 1 589 2
160 1.600 2
161 1.680 2
162 1 727 2
163 1 731 2
164 0.229 1
165 0.255 1
166 0.266 1
167 0.269 1
168 0.279 1
169 0.293 1
170 0.300 1
171 0329 1
172 0.357 1
173 0.406 1




*





'


.



• •

.
• •
•
•


















•

.
•
*


                         E-14

-------
               Table E-3  (continued)
CENSUS REGION  "NORTH CENTRAL




CENSUS DIVISION      EAST NORTH CENTRAL         WEST NORTH CENTRAL




    AGE GROUP   0-14      15-44        45+      0-14  15-44   45+
Number of
Average Occurencss.
Index RRT In Samples"
174 0.406 1
175 0463 1
176 0.499 1
177 0.539 1
178 0.575 1
179 0.672 1
180 0.676 1
181 0708 1
182 0.724 1
183 0.732 1
184 0.732 1
185 0 734 1
186 0742 1
187 0.743 1
188 0747 1
189 0.749 1
190 0.799 1
191 0.829 1
192 0.830 1
193 0855 1
194 0892 1
195 0911 1
196 0914 1
197 0.973 1
198 1011 1
199 1.018 1
200 1 035 1
201 1.051 1
202 1 .053 1
203 1 060 1
204 1 064 1
205 1.075 1
206 1 .078 1
207 1 084 1
208 1 107 1
209 1.117 1
210 1.117 1
211 1.118 1
212 1 121 1
213 1122 1
214 1.134 1
215 1.134 1
216 138 1
217 140 1
218 .140 1
219 152 1
220 161 1
221 .170
222 1.189
223 1 208
224 1 217
225 1 226
226 1 262
227 1 288 1
228 1.289 1
229 1 304 1
230 1 .348 1
231 1 349 1


•


•





"







•


•




,
•









•




•
•



                          E-15

-------
                                Table  E-3  (concluded)
                    CENSUS REGION
                                                NORTH CENTRAL
                   CENSUS DIVISION
                                   EAST NORTH CENTRAL
      Index
                       AGE GROUP  0-14
                                        15-44       45+
                                                         WEST NORTH CENTRAL

                                                         0-14  15-44   45+
       Number of
Average   Oceurences
 RRT    In Samples 9
232 1.349 1
233 1.350 1
234 1.356 1
235 1.375 1
236 1.379 1
237 1 394 1
238 1.407 1
239 1.534 1
240 1 588 1
241 1.590 1
242 1 .596 1
243 1.624 1
244 1 .634 1
245 1 646 1
246 1.659 1
247 1.676 1
248 1.678 1
249 1.701 1
250 1.709 1
251 1.718
252 1.721
253 1.731
254 1.734
255 1.734
256 1.740 1
257 1.804 1
258 1.889 1






•
*

'





•


3Total  number of occurrences from all sample  analyses  (four  census regions
 and  nine  census divisions).
                                          E-16

-------
Table E-4.   Unidentified  Peaks  in the  6% Florisil  Semivolatile
       Organic Analysis  Data Set - Northeast  Census Region
        CENSUS REGION

        CENSUS DIVISION

           AGE GROUP
                                      NORTHEAST
 MIDDLE ATLANTIC

0-14    15-44   45+
  NEW ENGLAND

0-14   15-44  45+
Number of
Average Occurenees
Index RRT InSamplesd
IS 1.000 44
1 0 924 42
2 1 .600 42
3 0.759 38
4 1.027 38
5 1.023 35
6 1.117 34
7 1.706 34
8 1 129 32
9 0 879 31
10 0 702 30
11 0919 30
12 0.990 29
13 0.838 28
14 0912 26
15 1.481 26
16 1.760 25
17 0 985 24
18 1 059 24
19 0.673 23
20 0 993 23
21 0.982 22
22 1.533 22
23 1.063 21
24 1 199 21
25 1.374 21
26 0.726 19
27 1.741 19
28 0 952 17
29 1 237 17
30 1.629 17
31 1.586 16
32 0.493 15
33 1.002 15
34 1.065 15
35 0839 14
36 1.070 14
37 1.728 14
38 0.574 13
39 0665 13
40 1 178 13
41 1 280 13
42 1.297 13
43 0190 12
44 0 666 12
45 0.310 11
46 0603 11
47 1 082 11
48 1 131 11
49 1 146 11
50 0.411 10
51 0.780 10
52 1 009 10
53 1 160 10
• •
•
•
•
* *

• •
*
•
*
•

• •
*
. .
•
,
f
•
"
•
•
*

•

•
•


•
•
•
•
,

                                E-17

-------
                   Table  E-4  (continued)
 CENSUS REGION                       NORTHEAST




CENSUS DIVISION        MIDDLE ATLANTIC              NEW ENGLAND




    AGE GROUP      0-14    15-44    45+        0-14   15-44  45+
Number of
Average Occurences
Index RRT In Samples
54 1.219 10
55 1.224 9
56 0.220 8
57 0.670 8
58 0.959 8
59 1 178 8
60 1 197 8
61 1 626 8
62 1.638 8
63 0.360 7
64 0 674 7
65 0.897 7
66 0.932 7
67 1.051 7
68 1.094 7
69 1.427 7
70 1.475 7
71 1.681 7
72 1.773 7
73 0.337 6
74 0 662 6
75 0.880 6
76 1.177 6
77 1.253 6
78 1 681 6
79 0.278 5
80 0.472 5
81 0.736 5
82 0 991 5
83 1.057 5
84 1 069 5
85 1 073 5
86 1.085 5
87 1.195 5
88 1.407 5
89 0.399 4
90 0 661 4
91 0 730 4
92 0 965 4
93 1.068 4
94 1.144 4
95 1 195 4
96 1 222 4
97 1.326 4
98 1 355 4
99 1.389 4
100 1.411 4
101 1 538 4
102 0316 3
103 0608 3
104 0662 3
105 0747 3
106 0754 3
107 0855 3
• •
•





•
•


•
•
.
.
•


•
•





•
•



•
•

•
•
•
                                E-18

-------
                     Table  E-4  (continued)
'  CENSUS REGlOrJNORTHEAST




 CENSUS DIVISION        MIDDLE ATLANTIC              NEW ENGLAND




     AGE GROUP      0-14     15-44    45+       0-14   15-44  45+
Number of
Average Occurences
Index RRT In Samples 9
108 0.893 3
109 0.918 3
110 0.967 3
111 1.019 3
112 1.025 3
113 1.041 3
114 1.045 3
115 1.050 3
116 1.055 3
117 1.076 3
118 1.107 3
119 1109 3
120 1 186 3
121 1.244 3
122 1.251 3
123 1.414 3
124 1.457 3
125 1 585 3
126 0.325 2
127 0.356 2
128 0.747 2
129 0754 2
130 0.817 2
131 0.823 2
132 0.855 2
133 0.896 2
134 0898 2
135 0905 2
136 0.933 2
137 0.976 2
138 0.982 2
139 0.985 2
140 1.020 2
141 1.038 2
142 1 053 2
143 1.080 2
144 1 106 2
145 1 120 2
146 1 124 2
147 1.143 2
148 1.152 2
149 1 158 2
150 1 179 2
151 1.221 2
152 1 252 2
153 1.336 2
154 1 345 2
155 1 360 2
156 1 382 2
157 1.542 2
158 1 577 2
159 1 589 2
160 1.600 2
161 1.680 2

.


•



.
.
•





•

•
•



*





,


•



*
.
•



                               E-19

-------
                                                (continued)
Index
     CENSUS REGION

    CENSUS DIVISION

        AGE GROUP

          Number of
Average     Occurences
 RRT      In Samples 9
                                                   NORTHEAST

                                  MIDDLE ATLANTIC                NEW ENGLAND

                                0-14     15-44     45+         0-14   15-44  45+
162 1 727 2
163 1 731 2
164 0.229 1
165 0255 1
166 0266 1
167 0269 1
168 0279 1
169 0.293 1
170 0.300 1
171 0329 1
172 0357 1
173 0406 1
174 0406 1
175 0.463 1
176 0499 1
177 0539 1
178 0 575 1
179 0.672 1
180 0.676 1
181 0.708 1
182 0.724 1
183 0.732 1
184 0.732 1
185 0.734 1
186 0.742 1
187 0743 1
188 0747 1
189 0.749 1
190 0.799 1
191 0.829 1
192 0830 1
193 0.855 1
194 0.892 1
195 0.911 1
196 0.914 1
197 0973 1
198 1.011 1
199 1.018 1
200 1 035 1
201 1.051
202 1 053
203 1 .060
204 1 .064
205 1 075
206 1 078
207 1 084 1
208 1 107 1
209 1117 1
210 1.117 1
211 1118 1
212 1 121 1
213 1 122 1
214 1.134 1
215 1.134 1

.


•









•



•


•









•

•


                                             E-20

-------
                              Table  E-4 (concluded^
              CENSUS REGION                    NORTHEAST

              CENSUS DIVISION      MIDDLE ATLANTIC           NEW ENGLAND

                 AGE GROUP     0-14    15-44   45*       0-14   15-44 45+
Number of
Average Occuranees.
Index RRT lnSamplesd
216 1138 1
217 1 140 1
218 1140 1
219 1.152 1
220 1.161 1
221 1.170 1
222 1.189 1
223 1.208 1
224 1.217 1
225 1.226 1
226 1.262 1
227 1.288 1
228 1.289 1
229 1.304 1
230 1.348 1
231 1.349 1
232 1 349 1
233 1.350 1
234 1.356 1
235 1.375 1
236 1.379 1
237 1.394 1
238 1.407 1
239 1.534 1
240 1.588 1
241 1.590 1
242 1.596 1
243 1 624 1
244 1 634 1
245 1 .646 1
246 1 659 1
247 1 676 1
248 1.678 1
249 1.701 1
250 1.709 1
251 1.718 1
252 1.721 1
253 1.731 1
254 1 734 1
255 1.734 1
256 1 .740 1
257 1.804 1
258 1 889 1

'


•








•







•






,

Total  number  of occurrences  from  all  sample analyses (four census regions
and  nine census divisions).
                                     E-21

-------
                              APPENDIX F


DOT MATRIX TABLE FOR UNIDENTIFIED HRGC/MS PEAKS IN THE 15/50% FLORISIL
   SEMIVOLATILE ORGANIC ANALYSIS DATA SET;  UNIDENTIFIED SEMIVOLATILE
             ORGANIC COMPOUND RESPONSES VS.  CENSUS REGION.
                    CENSUS DIVISION,  AND AGE GROUP
                                  F-l

-------
Table F-l.   Unidentified Peaks in  the 15/50% Florisil Semivolatile
           Organic Analysis  Data Set - West Census  Region	
                  CENSUS REGION
                 CENSUS DIVISION
                    AGE GROUP
                                             WEST
   MOUNTAIN

0-14   15-44  45+
    PACIFIC

0-14    15-44  45+
Number of
Average Occurrences
Index RRT In Samples"
IS 1.000 46
1 1 920 44
2 0.419 42
3 1 052 41
4 1 007 40
5 0.452 38
6 1.616 38
7 0.402 37
8 0.633 35
9 1 742 35
10 0 449 34
11 1.569 34
12 2.034 34
13 1.692 33
14 1.682 32
15 1 710 32
16 0.437 29
17 0.606 29
18 1 238 29
19 1.657 28
20 1.1 B7 28
21 1.453 28
22 0.839 27
23 1.665 27
24 0.647 26
25 1.128 26
26 2.059 26
27 1.953 25
28 1.440 25
29 1.490 24
30 1.722 23
31 1.430 22
32 0.932 21
33 1.115 21
34 1.223 21
35 2.009 20
36 0.589 20
37 1.147 20
38 1.567 20
39 1.235 19
40 1.178 18
41 0 555 18
42 0 990 17
43 1.319 17
44 1.629 16
45 0876 16
46 0.680 15
47 0.912 15
48 1.086 15
49 1 089 15
50 1.556 15
51 1 980 15
52 1.929 14
53 0.982 14
54 1.809 14
55 1 027 13
56 1.210 13
57 1 500 13
•
•
•
•
•

•
•
•
•
•
•
•
•
•
,
•

•
•

•
.

•
.
•
*


•
•

•


                                     F-2

-------
           Table  F-1  (continued^
 CENSUS REGION



CENSUS DIVISION



    AGE GROUP
               WEST
   MOUNTAIN




0-14   15-44  45+
     PACIFIC




0-14    15-44   45+
Number of
Average Occurrences
Index RRT In Sampled
58 1 950 13
59 0586 12
60 0.858 12
61 1511 12
62 1.961 12
63 2.014 12
64 2.088 12
65 0.996 11
66 1.027 11
67 0.218 11
68 0.398 11
69 1 475 11
70 1.522 11
71 1.542 11
72 1.980 11
73 0.745 10
74 0904 10
75 1.105 10
76 1.359 10
77 0.429 9
78 0.673 9
79 0 897 9
80 1.548 9
81 1.989 9
82 0.226 8
83 0.243 8
84 0 989 8
85 1.149 8
86 1.351 8
87 1 973 8
88 2.151 8
89 2.174 8
90 0 301 7
91 0 392 7
92 0.520 7
93 0 672 7
94 1.198 7
95 1.675 7
96 1.889 7
97 0.492 6
98 0.758 6
99 1 175 6
100 1 202 6
101 1.308 6
102 1 472 6
103 1 531 6
104 1.966 6
105 2137 6
106 1 531 5
107 0374 5
108 0450 5
109 0540 5
110 0547 5
111 0.559 5
112 0573 5
113 0762 5
114 0918 5
115 1 062 5

•
•
1
"

'

*

•
•
•

•
•
•
.
•
•


•

1





•
•
•









                      F-3

-------
           Table  F-1   (continued)
 CENSUS REGION




CENSUS DIVISION




    AGE GROUP
                                 WEST
MOUNTAIN
                  0-14
                        15-44  45+
                                       0-14
                       PACIFIC
                                              15-44  45+
Number of
Average Occurrences
Index RRT In Samples 9
116 1 070 5
117 1.105 5
118 1.138 5
119 1.175 5
120 1.288 5
121 1.460 5
122 1.716 5
123 1.729 5
124 0.475 4
125 0.507 4
126 0.520 4
127 0.667 4
128 0 721 4
129 0.832 4
130 0.936 4
131 1.061 4
132 1 109 4
133 1.153 4
134 1.173 4
135 1.277 4
136 1.328 4
137 1.580 4
138 1.927 4
139 1.979 4
140 2.000 4
141 0.319 3
142 0.375 3
143 0.609 3
144 0.307 3
145 0.346 3
146 0.353 3
147 0.487 3
148 0.727 3
149 0.739 3
150 0.790 3
151 0.821 3
152 082B 3
153 1.083 3
154 1.119 3
155 1.123 3
156 1.195 3
157 1.309 3
158 1.404 3
159 1.448 3
160 1 538 3
161 1,856 3
162 1.953 3
163 2.084 3
164 2.091 3
165 0.512 2
166 0572 2
167 1 809 2
168 1 900 2
169 0237 2
170 0.261 2
171 0.337 2
172 0341 2
173 0.342 2

•

•



1


•
•



•
•






.
•













•



                     F-4

-------
           Table  F-l  (continued)
 CENSUS REGION                     WEST




CENSUS DIVISION         MOUNTAIN                PACIFIC




    AGE GROUP      0-14   15-44  45*       0-14    15-44   45*
Number of
Average Occurrences
Index RRT In Sample^
174 0.382 2
175 0.413 2
176 0.435 2
177 0.450 2
178 0489 2
179 0.496 2
180 0.552 2
181 0.599 2
182 0.614 2
183 0.677 2
184 0.758 2
185 0.791 2
186 0908 2
187 0.921 2
188 0957 2
189 1.059 2
190 1.261 2
191 1 283 2
192 1.291 2
193 1.297 2
194 1.353 2
195 1 463 2
196 1 507 2
197 1 516 2
198 1.525 2
199 1.586 2
200 1 594 2
201 1 673 2
202 1 866 2
203 1 931 2
204 2 030 2
205 2.102 2
206 0 333 1
207 0 544 1
208 0.199 1
209 0.203 1
210 0.216 1
211 0.221 1
212 0.239 1
213 0240 1
214 0.241 1
215 0254 1
216 0266 1
217 0268 1
218 0283 1
219 0.285 1
220 0 293 1
221 0 300 1
222 0.327 1
223 0.344 1
224 0.352 1
225 0.353 1
226 0.358 1
227 0 359 1
228 0.362 1
229 0 365 1
230 0 370 1
231 0.371 1








•





•


•

:
•





















                        F-5

-------
            Table  F-1  (continued)
 CENSUS REGION                      WEST




CENSUS DIVISION         MOUNTAIN                PACIFIC




    AGE GROUP      0-14   15-44  45*       0-14    15-44   45*
Number of
Average Occurrences
Index RRT InSamptad
232 0.372 1
233 0.394 1
234 0.405 1
235 0.414 1
236 0.419 1
237 0.421 1
238 0.422 1
239 0.455 1
240 0.463 1
241 0.465 1
242 0 504 1
243 0.507 1
244 0.510 1
245 0.516 1
246 0.545 1
247 0.575 1
248 0.584 1
249 0.652 1
250 0.653 1
251 0.678 1
252 0 683 1
253 0.711 1
254 0.744 1
255 0.745 1
256 0.767 1
257 0.771 1
258 0.775 1
259 0.779 1
260 0.786 1
261 0.787 1
262 0.821 1
263 0.915 1
264 0.929 1
265 0.945 1
266 0.960 1
267 0.988 1
268 1 017 1
269 1.018 1
270 1.037 1
271 1.046 1
272 1.061 1
273 1 063 1
274 1.070 1
275 1.089 1
276 1.091 1
277 1.112 1
278 1.121 1
279 1.140 1
280 1.174 1
281 1.180 1
282 1.197 1
283 1.204 1
284 1.204 1
285 1.218 1
286 1.223 1
287 1.226 1
288 1.243 1
289 1.248 1

.






•



























                         F-6

-------
                                Table  F-1  (concluded)
     Index
              RRT
 CENSUS REGION

CENSUS DIVISION

   AGE GROUP

  Number of
  Occurrence^
  In Samples
                                                   WEST
                                        MOUNTAIN

                                      0-14   15-44  45+
    PACIFIC

0-14    15-44  45+
290 1.289 1
291 1.291 1
292 1.296 1
293 1.309 1
294 1.311 1
295 1.335 1
296 1 342 1
297 1.346 1
298 1.348 1
299 1.350 1
300 1 363 1
301 1 366 1
302 1.377 1
303 1 384 1
304 1.386 1
305 1.390 1
306 1.403 1
307 1.421 1
308 1.422 1
309 1.427 1
310 1.433 1
311 1.435 1
312 1.457 1
313 1.481 1
314 1.492 1
315 1.495 1
316 1.499 1
317 1.523 1
318 1.525 1
319 1 531 1
320 1.545 1
321 1.562 1
322 1 583 1
323 1 584 1
324 1.589 1
325 1.596 1
326 1.602 1
327 1 606 1
328 1.607 1
329 1.671 1
330 1.695 1
331 1.740 1
332 1.761 1
333 1.762 1
334 1.776 1
335 1 839 1
336 1 907 1
337 1 964 1
338 1 973 1
339 1 980 1
340 1 991 1
341 2 053 1
342 2 063 1
343 2.107 1










































aTotal  number of occurrences  from  all  sample  analyses (four census  regions
 and  nine  census divisions).
                                          F-7

-------
Table F-2.   Unidentified  Peaks  in the  15/50% Florisil  Semi volatile Organic
                     Analysis  Data  Set -  South  Central Region	
             CENSUS REGION

            CENSUS DIVISION

               AGE GROUP
EAST SOUTH CENTRAL

0-14     15-44   45+
      SOUTH

   SOUTH ATLANTIC

0-14      15-44
                                                              45+
WEST SOUTH CENTRAL

0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples 3
IS 1 000 46
1 1.920 44
2 0.419 42
3 1.052 41
4 1.007 40
5 0.452 38
6 1 616 38
7 0.402 37
8 0 633 35
9 1 742 35
10 0 449 34
11 1 569 34
12 2.034 34

15 1710 32
16 0.437 29

19 1.657 28
20 1.187 28
21 1 .453 28
22 0 839 27
23 1.665 27
24 0.647 26
26 2 059 26
28 1.440 25
29 1.490 24
30 1.722 23
31 1.430 22
32 0 932 21
33 1115 21
34 1 223 21
35 2009 20
36 0589 20
37 1 147 20
38 1.567 20
39 1 235 19
40 1.178 18
41 0 555 18
43 1.319 17
44 1 629 16
45 0876 16
47 0912 15
48 1.086 15
49 1 089 15
50 1 556 15
51 1 980 15
52 1.929 14
53 0982 14
54 1 809 14
55 1.027 13
56 1.210 13
57 1 500 13

•
•

.

t
•
•
•
•

*
•


•
•

.

m

•
•
'
•
•

•

•
•

• •

f >
f m
•
•
•

•
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•

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f t
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•
•
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t

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•

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•
•
•
•


•
•
                                          F-8

-------
                                         Table  F-2  (continued)
Index
         RRT
- CENSUS REGION

 CENSUS DIVISION

     AGE GROUP

    Number of
   Occurrences
    In Samples 9
                                                                  SOUTH

                                    EAST SOUTH CENTRAL          SOUTH ATLANTIC

                                   0-14     15-44    45+      0-14       15-44       45+
WEST SOUTH CENTRAL

0-14     15-44   45+
58 1.950 13
59 0586 12
60 0.858 12
61 1511 12
62 1.961 12
63 2.014 12
64 2.088 12
65 0996 11
66 1 027 11
67 0218 11
68 0398 11
69 1.475 11
70 1 522 11
71 1.542 11
72 1 980 11
73 0.745 10
74 0.904 10
75 1105 10
76 1 359 10
77 0 429 9
78 0.673 9
79 0897 9
80 1 548 9
81 1.989 9
82 0.226 8
83 0.243 8
84 0989 8
85 1.149 8
86 1 351 8
87 1 973 8
88 2151 8
89 2174 8
90 0 301 7
91 0.392 7
92 0 520 7
93 0 672 7
94 1.198 7
95 1 675 7
96 1.889 7
97 0492 6
98 0 758 6
99 1.175 6
100 1 202 6
101 1 308 6
102 1.472 6
103 1 531 6
104 1 966 6
105 2.137 6
106 1 531 5
107 0.374 5
108 0450 5
109 0540 5
110 0547 5
111 0559 5
112 0573 5
113 0762 5
114 0.918 5
115 1.062 5
•
•
•
*




•
•
.
•


•
'
•
.
•
•
•
•
• •
•
1
' *
• •
•
•
. .
• •
•
. . .
• •
•

•
•
•
,
*
•
•
•
.






•
•
•
•
•
•
•
•
•
•

•
                                                       F-9

-------
                       Table  F-2  (continued)
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
                  EAST SOUTH CENTRAL




                 0-14     15-44   45+
       SOUTH




    SOUTH ATLANTIC




0-14      15-44      45*
WEST SOUTH CENTRAL




0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples ^
116 1 070 5
117 1.105 5
118 1.138 5
119 1.175 5
120 1.288 5
121 1 .460 5
122 1 716 5
123 1.729 5
124 0.475 4
125 0.507 4
126 0520 4
127 0667 4
128 0.721 4
129 0.832 4
130 0936 4
131 1 061 4
132 1.109 4
133 1 153 4
134 1.173 4
135 1.277 4
136 1.328 4
137 1.580 4
138 1 927 4
139 1.979 4
140 2.000 4
141 0.319 3
142 0375 3
143 0.609 3
144 0307 3
145 0.346 3
146 0.353 3
147 0.487 3
148 0.727 3
149 0739 3
150 0.790 3
151 0.821 3
152 0828 3
153 1 083 3
154 1.119 3
155 1 123 3
156 1 195 3
157 1 309 3
158 1 404 3
159 1 448 3
160 1.538 3
161 1.856 3
162 1.953 3
163 2.084 3
164 2091 3
165 0512 2
166 0.572 2
167 1.809 2
168 1.900 2
169 0.237 2
170 0.261 2
171 0.337 2
172 0.341 2
173 0342 2

•
*

.










*
•
"
•
•



•
•
•
•
.
*
•
.
.
*


•
•

.
•
•



•


•


•
•


•

•
'

*

,

                                   F-10

-------
                        Table  F-2  (continued)
 CENSUS REGION




CENSUS DIVISION




    AGE GROUP




   Number of
                              SOUTH




EAST SOUTH CENTRAL          SOUTH ATLANTIC




0-14     15-44   45+      0-14       15-44      45+
WEST SOUTH CENTRAL




0-14     15-44   45+
Average Occurrences-
Index RRT In Samples"
174 0.382 2
175 0413 2
176 0.435 2
177 0.450 2
178 0.489 2
179 0.496 2
180 0552 2
181 0599 2
182 0.614 2
183 0.677 2
184 0.758 2
185 0.791 2
186 0.908 2
187 0.921 2
188 0.957 2
189 1.059 2
190 1.261 2
191 1.283 2
192 1.291 2
193 1.297 2
194 1.353 2
195 1.463 2
196 1.507 2
197 1.516 2
198 1.525 2
199 1 586 2
200 1 .594 2
201 1.673 2
202 1.B66 2
203 1 931 2
204 2.030 2
205 2102 2
206 0.333 1
207 0.544 1
208 0.199 1
209 0.203 1
210 0.216 1
211 0.221 1
212 0.239 1
213 0 240 1
214 0.241 1
215 0254 1
216 0266 1
217 0268 1
218 0.283 1
219 0285 1
220 0.293 1
221 0 300 1
222 0.327 1
223 0.344 1
224 0.352 1
225 0.353 1
226 0.358 1
227 0 359 1
228 0.362 1
229 0.365 1
230 0.370 1
231 0.371 1


•

•









•
•

'




• •

•
•




*




•

•
•

•

•


.





.












                                    F-ll

-------
                       Table  F-2  (continued^
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
EAST SOUTH CENTRAL




0-14     15-44    45+
       SOUTH




    SOUTH ATLANTIC




0-14       15-44
                                                           45+
WEST SOUTH CENTRAL




0-14     15-44   45+
Number of
Average Occurrences
Index RRT In Samples a
232 0.372 1
233 0.394 1
234 0.405 1
235 0.414 1
236 0.419 1
237 0.421 1
238 0 422 1
239 0 455 1
240 0.463 1
241 0.465 1
242 0 504 1
243 0.507 1
244 0.510 1
245 0516 1
246 0 545 1
247 0.575 1
248 0.584 1
249 0 652 1
250 0.653 1
251 0.678 1
252 0.683 1
253 0.711 1
254 0.744 1
255 0.745 1
256 0.767 1
257 0.771 1
258 0.775 1
259 0.779 1
260 0.786 1
261 0.787 1
262 0.821 1
263 0.915 1
264 0.929 1
265 0.945 1
266 0.960 1
267 0.988 1
268 1.017 1
269 1.018 1
270 1.037 1
271 1.046 1
272 1.061 1
273 1 063 1
274 1.070 1
275 1.089 1
276 1,091 1
277 1112 1
278 1.121 1
279 1 140 1
280 1 174 1
281 1.180 1
282 1 197 1
283 1.204 1
284 1 204 1
285 1.218 1
286 1.223 1
287 1 226 1
288 1 243 1
289 1.248 1
•














*
•
•
.
•
•
•
*





•

•
•


•
•
















.

                                   F-12

-------
                               Table  F-2  (concluded)
            CENSUS REGION
           CENSUS DIVISION
              AGE GROUP
             Number of
EAST SOUTH CENTRAL


0-14     15-44   45+
      SOUTH

   SOUTH ATLANTIC


0-14      15-44      45+
WEST SOUTH CENTRAL


0-14     15-44   45+
Average Occurrences
Index RRT In Samples"
290 1 289 1
291 1.291 1
292 1.296 1
293 1.309 1
294 1 .31 1 1
295 1 335 1
296 1.342 1
297 1.346 1
298 1.348 1
299 1.350 1
300 1.363 1
301 1.366 1
302 1.377 1
303 1.384 1
304 1.386 1
305 1.390 1
306 1.403 1
307 1.421 1
308 1.422 1
309 1 .427 1
310 1.433 1
311 1.435 1
312 1.457 1
313 1.481 1
314 1.492 1
315 1.495 1
316 1.499 1
317 1.523 1
318 1.525 1
319 1.531 1
320 1 545 1
321 1.562 1
322 1.583 1
323 1.584 1
324 1.589 1
325 1.596 1
326 1.602 1
327 1 606 1
328 1.607 1
329 1.671 1
330 1.695 1
331 1.740 1
332 1 761 1
333 1.762 1
334 1 776 1
335 1.839 1
336 1.907 1
337 1.964 1
338 1.973 1
339 1.980 1
340 1 991 1
341 2.053 1
342 2.063 1
343 2.107 1










•

.
•

*
•
.

*
















•



•









,












Total  number of  occurrences from all  sample  analyses  (four  census  regions
and  nine  census  divisions).
                                          F-13

-------
Table F-3.   Unidentified Peaks  in the 15/50% Florisil  Semivolatile
	Organic AnAl/3^ DataJSeJ: - North Central  Census  Region	
                 CENSUS REGION
NORTH CENTRAL
                CENSUS DIVISION        EAST NORTH CENTRAL          WEST NORTH CENTRAL

                   AGE GROUP    0-14       15-44       45+        0-14  15-44   45+
Number of
Average Occurrences
Index RRT In Samples 9
IS. 1.000 46
1 1 920 44
2 0419 42
3 1.052 41
4 1.007 40
5 0.452 38
6 1.616 38
7 0.402 37
8 0.633 35
9 1.742 35
10 0.449 34
11 1.569 34
12 2034 34
13 1.692 33
14 1 682 32
15 1.710 32
16 0437 29
17 0.606 29
18 1.238 29
19 1.657 28
20 1.187 28
21 1 453 28
22 0.839 27
23 1.665 27
24 0.647 26
25 1.128 26
26 2.059 26
27 1.953 25
28 1 440 25
29 1.490 24
30 1.722 23
31 1.430 22
32 0.932 21
33 1.115 21
34 1.223 21
35 2 009 20
36 0.589 20
37 1.147 20
38 1.567 20
39 1.235 19
40 1.178 18
41 0 555 18
42 0.990 17
43 1,319 17
44 1 629 16
45 0.876 16
46 0680 15
47 0912 15
48 1 086 15
49 1.089 15
50 1 556 15
51 1 980 15
52 1.929 14
53 0982 14
54 1.809 14
55 1.027 13
56 1.210 13
57 1 500 13
•
•
•
•
• •
• •
• •
. . .
. . .
•
"
•
• •
• •
• • 1
• •
•
•
. . .

.
•
•
.
•

,
•
•
•
•
•
*
• •
• •
" *
:
                                     F-14

-------
             Table  F-3  (continued!
 CENSUS REGION                        NORTH CENTRAL




CENSUS DIVISION         EAST NORTH CENTRAL            WEST NORTH CENTRAL




    AGE GROUP    0-14        15-44        45+         0-14  15-44   45+




 Number of
Average Occurrences,
Index RRT In Samples3
58 1.950 13
59 0 586 12
60 0.858 12
61 1.511 12
62 1.961 12
63 2.014 12
64 2.088 12
65 0.996 11
66 1.027 11
67 0.218 11
68 0398 11
69 1.475 11
70 1.522 11
71 1.542 11
72 1.980 11
73 0.745 10
74 0.904 10
75 1.105 10
76 1.359 10
77 0.429 9
78 0.673 9
79 0.897 9
80 1.548 9
81 1.989 9
82 0.226 8
83 0.243 8
84 0.989 8
85 1.149 8
86 1.351 8
87 1.973 8
88 2151 8
89 2.174 8
90 0.301 7
91 0.392 7
92 0.520 7
93 0.672 7
94 1.198 7
95 1.675 7
96 1 889 7
97 0.492 6
98 0.758 6
99 1.175 6
100 1 202 6
101 1.308 6
102 1.472 6
103 1.531 6
104 1 966 6
105 2137 6
106 1.531 5
107 0.374 5
108 0.450 5
109 0.540 5
110 0.547 5
111 0.559 5
112 0.573 5
113 0.762 5
114 0.918 5
115 1.062 5
•
,
. .
•
*

'
'
•
•
• •
•

.

•
•
•
•
•
•
• •
•
"
.
'


•

•
•
•
•
*

•
•
•
, .
•
•
•
                       F-15

-------
             Table  F-3  (continued)
 CENSUS REGION                        NORTH CENTRAL




CENSUS DIVISION         EAST NORTH CENTRAL            WEST NORTH CENTRAL




    AGE GROUP    0-14        15-44        45+         0-14  15-44   45+
Number of
Average Occurrences
Index RRT In Samples 3
116 1.070 5
117 1.105 5
118 1.138 5
119 1.175 5
120 1.288 5
121 1.460 5
122 1.716 5
123 1.729 5
124 0.475 4
125 0.507 4
126 0.520 4
127 0.667 4
128 0.721 4
129 0.832 4
130 0.936 4
131 1 061 4
132 1.109 4
133 1 153 4
134 1.173 4
135 1.277 4
136 1 328 4
137 1.580 4
138 1.927 4
139 1.979 4
140 2.000 4
141 0.319 3
142 0.375 3
143 0.609 3
144 0.307 3
145 0.346 3
146 0.353 3
147 0.487 3
148 0 727 3
149 0.739 3
150 0.790 3
151 0.821 3
152 0828 3
153 1 083 3
154 1.119 3
155 1.123 3
156 1.195 3
157 1.309 3
158 1.404 3
159 1.448 3
160 1 538 3
161 1 856 3
162 1 953 3
163 2.084 3
164 2 091 3
165 0512 2
166 0.572 2
167 1 809 2
168 1 900 2
169 0237 2
170 0261 2
171 0337 2
172 0341 2
173 0.342 2
.
•

•
.
•
.'
.

.




• •
•
• •

• •



•










•

•
"
• •
*
'
'

                        F-16

-------
             Table  F-3  (continued)
 CENSUS REGION                        NORTH CENTRAL




CENSUS DIVISION         EAST NORTH CENTRAL            WEST NORTH CENTRAL




    AGE GROUP    0-14        15-44        45+         0-14  15-44   45+
Number of
Average Occurrences
Index RRT In Sample* °
174 0.382 2
175 0.413 2
176 0.435 2
177 0.450 2
178 0.489 2
179 0.496 2
180 0.552 2
181 0.599 2
182 0.614 2
183 0.677 2
184 0.758 2
185 0.791 2
186 0.908 2
187 0921 2
188 0.957 2
189 1.059 2
190 1.261 2
191 1.283 2
192 1.291 2
193 1.297 2
194 1.353 2
195 1.463 2
196 507 2
197 .516 2
198 .525 2
199 586 2
200 .594 2
201 .673 2
202 .866 2
203 .931 2
204 2.030 2
205 2.102 2
206 0 333 1
207 0.544 1
208 0.199 1
209 0.203 1
210 0.216 1
211 0 221 1
212 0.239 1
213 0.240 1
214 0.241 1
215 0.254 1
216 0.266 1
217 0268 1
218 0.283 1
219 0.285 1
220 0 293 1
221 0.300 1
222 0 327 1
223 0.344 1
224 0.352 1
225 0 353 1
226 0.358 1
227 0.359 1
228 0.362 1
229 0.365 1
230 0.370 1
231 0.371 1





•




•







•
.
•






"






.






'

•




                       F-17

-------
             Table  F-3  (continued)
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
                    NORTH CENTRAL
     EAST NORTH CENTRAL




0-14        15-44        45+
WEST NORTH CENTRAL




 0-14  15-44    45*
Number of
Average Occurrences
Index RRT In Samples
232 0.372
233 0.394
234 0 405
235 0.414
236 0.419
237 0.421
238 0.422
239 0.455 1
240 0.463 1
241 0.465 1
242 0.504 1
243 0.507 1
244 0.510 1
245 0516 1
246 0.545 1
247 0.575 1
248 0.584 1
249 0.652 1
250 0.653 1
251 0.678 1
252 0 683 1
253 0.711 1
254 0.744 1
255 0.745 1
256 0.767 1
257 0.771 1
258 0.775 1
259 0 779 1
260 0.786 1
261 0 787 1
262 0.821 1
263 0.915 1
264 0.929 1
265 0.945 1
266 0.960 1
267 0.988 1
268 1.017 1
269 1.018 1
270 1.037 1
271 1.046 1
272 1.061 1
273 1.063 1
274 1 070 1
275 1.089 1
276 1.091 1
277 1.112 1
278 1.121 1
279 1.140 1
280 1 174 1
281 1.180 1
282 1.197 1
283 1.204 1
284 1.204 1
285 1.218 1
286 1.223 1
287 1.226 1
288 1 243 1
289 1 248 1










•













*

















                        F-18

-------
                               Table  F-3 (concluded)
                    CENSUS REGION

                    CENSUS DIVISION

                       AGE GROUP

                    Number of
                 NORTH CENTRAL

    EAST NORTH CENTRAL          WEST NORTH CENTRAL

0-14       15-44       45+       0-14  15-44    45+
Average Occurrences.
Index RRT In Samples
290 1.289
291 1.291
292 1.296
293 1.309
294 1.311
295 1.335
296 1.342
297 1 .346 1
298 1.348 1
299 1.350 1
300 1.363 1
301 1.366 1
302 1.377 1
303 1.384 1
304 1.386 1
305 1.390
306 1.403
307 1.421
308 1.422
309 1.427
310 1.433
311 1 435
312 1.457 1
313 1.481 1
314 1.492 1
315 1 495 1
316 1.499 1
317 1523 1
318 1.525 1
319 1.531 1
320 1 545 1
321 1.562 1
322 1.583 1
323 1.584 1
324 1.589 1
325 1.596 1
326 1.602 1
327 1.606 1
328 1.607 1
329 1 671 1
330 1.695 1
331 1 .740 1
332 1.761 1
333 1.762 1
334 1 776 1
335 1.839 1
336 1.907 1
337 1 964
338 1 973
339 1 980
340 1.991
341 2 053
342 2.063
343 2.107



.
•
•











.
'


,
'
.






















•

Total  number of  occurrences  from all  sample analyses  (four census  regions
and  nine census  divisions).
                                        F-19

-------
Table F-4.   Unidentified  Peaks  in  the  15/50%  Florisil  Semivolatile
         Organic Analysis  Data Set  - Northeast  Census  Region	
                CENSUS REGION
               CENSUS DIVISION
                   AGE GROUP
                                                  NORTHEAST
   MIDDLE ATLANTIC

0-14      15-44     45+
  NEW ENGLAND

0-14   15-44  45+
Number of
Average Occurrences
Index RRT In Samples 3
I.S. 1.000 46
1 1 920 44
2 0.419 42
3 1.052 41
4 1 .007 40
5 0.452 38
6 1.616 38
7 0 402 37
8 0.633 35
9 1.742 35
10 0.449 34
11 1.569 34
12 2034 34
13 1.692 33
14 1 682 32
15 1710 32
16 0.437 29
17 0.606 29
18 1.238 29
19 1.657 28
20 1.1 87 28
21 1.453 28
22 0.839 27
23 1.665 27
24 0.647 26
25 1.128 26
26 2 059 26
27 1.953 25
28 1.440 25
29 1.490 24
30 1.722 23
31 1.430 22
32 0 932 21
33 1115 21
34 1.223 21
35 2.009 20
36 0 589 20
37 1.147 20
38 1.567 20
39 1 235 19
40 1.178 18
41 0.555 18
42 0.990 17
43 1.319 17
44 1.629 16
45 0.876 16
46 0.680 15
47 0912 15
48 1 086 15
49 1.089 15
50 1 556 15
51 1 980 15
52 1.929 14
53 0.982 14
54 1 809 14
55 1 027 13
56 1.210 13
57 1.500 13
• •
•
*
.
•
•
•
•
•
• •
*
:
•
• •
*
•
*

•
•
•
•
.

•
•


•

•
•
•
•
•

                                      F-20

-------
              Table F-4  (continued)
 CENSUS REGION                              NORTHEAST




CENSUS DIVISION           MIDDLE ATLANTIC                   NEW ENGLAND




    AGE GROUP       0-14      15-44      45+           0-14   15-44  45+
Number o<
Average Occurrences
Index RRT In Samples a
58 1.950 13
59 0586 12
60 O.B58 12
61 1.511 12
62 1.961 12
63 2.014 12
64 2.088 12
65 0.996 11
66 1.027 11
67 0.218 11
68 0.398 11
69 1475 11
70 1.522 11
71 1.542 11
72 1.980 11
73 0.745 10
74 0.904 10
75 1.105 10
76 1.359 10
77 0.429 9
78 0.673 9
79 0.897 9
80 1.548 9
81 1.989 9
82 0.226 8
83 0 243 8
84 0.989 8
85 1.149 8
86 1.351 8
87 1 973 8
88 2.151 8
89 2174 8
90 0.301 7
91 0.392 7
92 0 520 7
93 0.672 7
94 1 198 7
95 1 675 7
96 1.889 7
97 0.492 6
98 0.758 6
99 1 175 6
100 1.202 6
101 1.308 6
102 1 472 6
103 1.531 6
104 1.966 6
105 2137 6
106 1 531 5
107 0.374 5
108 0.450 5
109 0.540 5
110 0547 5
111 0559 5
112 0573 5
113 0.762 5
114 0.918 5
115 1.062 5
•
.
. .
"
• •
•


•
*


.

•
•
•
•
•
•


•

*

















                        F-21

-------
              Table  F-4  (continued)
 CENSUS REGION
CENSUS DIVISION
    AGE GROUP
   Number of
                                          NORTHEAST
   MIDDLE ATLANTIC




0-14      15-44      45+
   NEW ENGLAND




0-14   15-44   45+
Average Occurrences..
Index RRT In Samples3
116 1.070 5
117 1.105 5
118 1.138 5
119 1.175 5
120 1.288 5
121 1.460 5
122 1.716 5
123 1.729 5
124 0.475 4
125 0.507 4
126 0.520 4
127 0667 4
128 0.721 4
129 0.832 4
130 0.936 4
131 1.061 4
132 1.109 4
133 1.153 4
134 1.173 4
135 1.277 4
136 1.328 4
137 1.580 4
138 1.927 4
139 1.979 4
140 2.000 4
141 0.319 3
142 0.375 3
143 0.609 3
144 0.307 3
145 0.346 3
146 0.353 3
147 0.487 3
148 0.727 3
149 0739 3
150 0.790 3
151 0821 3
152 0.828 3
153 1 083 3
154 1.119 3
155 1.123 3
156 1.195 3
157 1.309 3
158 1.404 3
159 1 448 3
160 1 538 3
161 1.856 3
162 1.953 3
163 2084 3
164 2.091 3
165 0.512 2
166 0572 2
167 1 809 2
168 1 900 2
169 0.237 2
170 0.261 2
171 0.337 2
172 0.341 2
173 0342 2
.
•


.


.
•
"



•
.

•
•



•












•
•
•





                          F-22

-------
              Table  F-4  (continued)
 CENSUS REGION




CENSUS DIVISION




    AGE GROUP
                                         NORTHEAST
MIDDLE ATLANTIC
                               NEW ENGLAND
                   0-14
                            15-44
                                     45+
                            0-14   15-44   454
Number of
Average Occurrences
Index RRT In Samples 9
174 0.382 2
175 0.413 2
176 0.435 2
177 0.450 2
178 0.489 2
179 0.496 2
180 0 552 2
181 0 599 2
182 0.614 2
183 0.677 2
184 0.758 2
185 0.791 2
186 0.908 2
187 0.921 2
188 0.957 2
189 1 059 2
190 1.261 2
191 1.283 2
192 1.291 2
193 1.297 2
194 1.353 2
195 1.463 2
196 1.507 2
197 1.516 2
198 1.525 2
199 1.586 2
200 1 .594 2
201 1.673 2
202 1 866 2
203 1.931 2
204 2 030 2
205 2.102 2
206 0.333 1
207 0 544 1
208 0199 1
209 0.203 1
210 0.216 1
211 0.221 1
212 0.239 1
213 0240 1
214 0.241 1
215 0.254 1
216 0.266 1
217 0268 1
218 0.283 1
219 0285 1
220 0.293 1
221 0.300 1
222 0.327 1
223 0.344 1
224 0 352 1
225 0 353 1
226 0.358 1
227 0.359 1
228 0.362 1
229 0 365 1
230 0.370 1
231 0.371 1



•
.



*






*
.
















•



•




                       F-23

-------
             Table  F-4  (continued)
 CENSUS REGION                             NORTHEAST




CENSUS DIVISION          MIDDLE ATLANTIC                   NEW ENGLAND




    AGE GROUP       0-14      15-44     45*           0-14   15-44  45+
Number of
Average Occurrences
Index RRT In Samples^
232 0.372 1
233 0.394 1
234 0.405 1
235 0.414 1
236 0.419 1
237 0.421 1
238 0.422 1
239 0.455 1
240 0.463 1
241 0 465 1
242 0 504 1
243 0.507 1
244 0.510 1
245 0.516 1
246 0.545 1
247 0.575 1
243 0.584 1
249 0.652 1
250 0 653 1
251 0.678 1
252 0.683 1
253 0.711 1
254 0 744 1
255 0.745 1
256 0 767 1
257 0.771 1
258 0.775 1
259 0.779 1
260 0.786 1
261 0.787 1
262 0.821 1
263 0.915 1
264 0.929 1
265 0.945
266 0 960
267 0 988
268 1 017
269 1.018
270 1.037
271 1.046 1
272 1.061 1
273 1.063 1
274 1 .070 1
275 1.089 1
276 1.091 1
277 1112 1
278 1.121 1
279 1 140 1
280 1.174 1
281 1 180 1
282 1.197 1
283 1 204 1
284 1.204 1
285 1.218 1
286 1.223 1
287 1 226 1
288 1.243 1
289 1.248 1
















•

.























                           F-24

-------
                              Table F-4 (concluded)
                   CENSUS REGION

                   CENSUS DIVISION

                      AGE GROUP

                      Number*
                   NORTHEAST

   MIDDLE ATLANTIC                NEW ENGLAND

0-14      15-44     45+          0-14   15-44  45+
Average Occurrences
Index RRT hi Samples
290 1.289 1
291 1.291 1
292 1.296 1
293 1.309 1
294 1.311 1
295 1.335 1
296 1.342 1
297 1.346 1
298 1.348 1
299 1.350 1
300 1.363 1
301 1.366 1
302 1.377 1
303 1.384 1
304 1.386 1
305 1.390 1
306 1.403 1
307 1.421 1
308 1.422 1
309 1.427 1
310 1.433 1
311 1.435 1
312 1.457 1
313 1 481 1
314 1.492 1
315 1.495 1
316 1.499 1
317 1.523 1
31 B 1.525 1
319 1.531 1
320 1.545 1
321 1 .562 1
322 1.583 1
323 1.584 1
324 1.589 1
325 1.596 1
326 1 602 1
327 1 .606 1
328 1 607 1
329 1 671 1
330 1.695 1
331 1.740 1
332 1.761 1
333 1.762 1
334 1 .776 1
335 1 839 1
336 1 .907 1
337 1 .964 1
338 1 973 1
339 1 980 1
340 1 991 1
341 2 053 1
342 2.063 1
343 2.107 1


•







































Total  number of occurrences from all  sample  analyses (four census regions
and  nine census divisions).
                                        F-25

-------
         APPENDIX G





LISTING OF THE ACORN PROGRAM
             G-l

-------
Trace of procpduro ACORN

   * C   *:**  PROCEDURE ACORN. . .  J. ONSTOT
   -:;•
   * LATEST REVISION 7/25/86
   * 3
   •* EDLL *<-; W; E)
   * SET1 !tl;SET7 *i;SET3  *1
   * IS
   * F7P
   -> PHEAO/KX
   * DOONE
   * PRTN/KX(F; E)
   * FTPCOfc:; 1: *1. 91/N.; RE; 1: PRIN. 91i 1 : *1. 91; E)
   EDLL $  (-; Wi E)
   SET1 ft I
   SJTT7 *1
   SETS SI
   iS
      *
      * E  FIND THE INTERNAL  STANDARD. . . MUST BE THE FIRST  ENTRY IN  LIBRARY 51
      # 3
      ->
      * S^TL  SE; SET? $8; SETS  TEMPiOETL
      Jr CHKQ/0< I; Ri Fl; #; *, &; Q-30, 30; N3, 3; Al<; D-30, 30; E)
      •t 131.
      * CO«L  , *9(U*100; W* E)
      ^ EDQL  $9, FOUND(W; E)
      * SETS  $9
      •- -I'-'A^fD. R; S; T; E)
      S:-:TB  TEMP
      vl"TL
      CHKU   < I; R; Fl; #; *; &; G-30. 3O; N3, 3; Al<; D-30, 3O; E)/Q

         •:t  {S2
         :;  EKASE; C    THE  INBTERNAL STANDARD WAS NOT FOUND! ! !
                                         6-2

-------
         *  IF  IS2:28,
         *  RETU  IS1
         *
         IF IS2!2S, ISlttl
         RETU  IS1
      r.RASE
      QUIT
      Trare of  IS1  aborted.
   EDQL ,$9 (U*100;W; E)
   EDQL *9.FOUND (Wi E)
   SET8 $9
   QUAN  (D;R;S;T;E>
FTP   (OF; 1: PRIN. 91/N; E)
FHEAD /KX
   * PR EN(SHE)
   •»
   PRIN  (@HE>
   SHE

        T;  ACORN  LIBRARY SEARCH  RESULTS; T20i  ; T;FILENAME:  ;#i;C;C
        T8; PEAK; T8; SCAN; T8; PEAKS; T9; BEST; T9; BEST; T9; BEST; T13; LIBRARY; T12; CU
        TS; NO. ; T8; NO. ; T8; /SCAN; T9; NS3; T9; NBS; T9; NBS; T13; CHOICE; T12; ENTRY; C
        T24;  ; T9; FIT; T9; PURITY; T9; ENTRY; C; C
        E

      T; ACORN  LIBRARY SEARCH RESULTS; T20;  ; T; FILENAME:  ; #1; C; C
      TS; PEAK; T8; SCAN; T8; PEAKS; T9; BEST; T9; BEST; T9; BEST; T13; LIBRARY; T12; CURR~
      TC; NO. ; TB; NO. ; TS; /SCAN; T9; NBS; T9; NBS; T9; NBS; T13; CHOICE; T12; ENTRY; C
      T24;   ; T9; FIT; T9; PURITY; T9; ENTRY; C; C
      E


DOONE
   * GETS;SET12  !1;SET11  !7
   *  C SAVE CURRENT SCAN**  IN  ! 12,  . SL ENTRY NO.  IN  ill
   *  3
   •* EDLL  FOUND<-; W; E)
   * DGMAS   C  PRINT NO. OF MASS PEAKS TO STATUS REPORT
                                    G-3

-------
*  3
* SET4 SE:LIBTEST
* INLIB  C MAIN  LIBRARY SEARCH ROUTINTE  3
* ERASE; C  ADD  THE CORRESPONDING SE ENTRY NO.  TO *. LL
* 3
* EDLL *(*; W; E)
* SET1  ! 12; SETS *; SET7 111
* LOOP
«•
GETS
SET12 11
SET 11 !7
EDLL FOUND <-; W; E)
DOMAS
   ft ENMA/OV
   * SET13 !IS
   «•
   FNMA  /0V
   S[-T13  !18
SET4 SE
LIBTES
   K- SETL FIT
   «• LIBFIT/V
   # IF  !26
   «• GETL PURITY
   s- LIBPUR/V
   * IF  i26
   «• RUN  INSED
   K-
   SETL  FIT
   LIBFIT /V
      *  LIBR(T800; X2<; D; E)
      •*
      LIBR   (TSOO; X2<; D; E)
   IF !26
   SETL  PURITY
   L1BPUR /V
      *  LIBR(T400; X<; 0; £)
                                  G-4

-------
      LIBR  (T400; X<; D; E)
   IF !26
   RUN INSED
INLIB
   «•
   * INSEED
   * 1NNB
   * C  NOT FOUND IN SEED  OR  NB  LIBRARY.  ADDING TO SEED. . .  U
   «• LIBR (ED; Di #SE;  I'i UNIDENTIFIED PEAK; ; i ;;;;;; i ; SE* 1; ;> E; E)
   * NOTFND
   * SET4 SE
   * SET4 !24
   * LINEEND
   * UPRES
   K-
   JNSEED
      #
      * TF ! 4
      # ERASE;C THE PEAK WAS  LOCATED IN THE SEED LIBRARY!!!
      * j
      * SET10  !4
      * EDLB ,  ZZ(I!1; E)
      * DOMAS
      * LIBR/V<*ZZ;  X; Jli D;E)
      * SET4 !10
      * SEEDFND
      *'SET8 TEMP
      * CHRQ/Q«*DC)
      * IF !28
      * EDQL ,*(U*100;A;E)
      * SETS $
      z KETU INLIB
      *
      IF  !4
      FRASE
      SET 10 14
      t£DLB ,11 (I ! 1; E)
      DOMAS
         * ENMA/OV
         * SET13  !18
                                 6-5

-------
      ENMA /0V
      SET13  !18
   LIBR  (*ZZ; X; J1;D; E)/V
   SET4 !10
   SEEDFN
      * PRIN/KX(@FS)
      *
      PRIN   (SFS//KX
      @FS
            !11,4;T4;  i!12,4;T4;  ; ! 13, 4; T4;  ;!18,4;14;  ; ! 17, 4; T4;  ;
           T12;  i T; SEED; T10; ;  ! 4, 3i C; E
         !11,4;T4;  ;!12, 4; T4; ;  ! 13, 4; T4;  ; ' 18, 4; T4;  ; ! 17, 4; T4;  ;
         712,  ;T;SEED;T10;  ;!4,3;C;E
   SETS TEMP
   CHRO  <@DO)/0
      :  I; #; G-2, 2; Ml, 1; U20, 2; Ai<; D-20, 20; E

      I; #; G-2, 2; Nl, 1; U20, 2; Al<; D-20, 20; E
   IF !28
   EDQL , $  
-------
* SET4 SE; SET4 !24i
* LINEEND
* UPRES      CUPDATE RESPONSE  FACTOR FOR NEW SE  ENTRY
* 3
*
* RETU INLIB
*
SETL FOUND
SET4 NB
LIBNB /V
   * LIBR(X; D; J1O E)
   *
   LIBR   (X;D;J1<;E)
IF INNB! 26, INNB
IF INNB!18, INNB#900
IF INNB!17, INNB#60O
SETL
GETL
NBSFND
   * PRIN/KX<@FN)
   •«•
   PRIN   <@FN)/KX
   SFN
         !ll,4i-T4;  ;  ! 12, 4; T4;  ; ! 1.3, 4; T4;  ; ! 18, 4; T4;  ; ! 17, 4; T4;  ;
         !4, 5; T8;  ; T; NBC; E
       !11,4;T4;  ; ! 12, 4; T4;  ; ! 13, 4; T4; ;  ! 18, 4; T4;  ; ! 17, 4; T4i  •
       14, 5; T8i  iTiNDSiE
EDLB  , SE (D; I '; ;;;;;;; > ; ; ; SE, 1; ; ; Ei E)
SET4  SE
SET4  !24
LINEEN
                            G-7

-------
      * PRIN/KX(@FE>
      #
      PRIN   
      * FDQL ,$(U*100;A;E)
      *
      * SETS $
      •#•
      SETS  TEMP
      CHRO   (I; #; Nl. 1; G-2> 2; U20. 2; Al<; D-10* 10; E)/O
      IF  !28
      EDQL  .FOUND  (U*100; A; E)
      QUAN  FOUND (D;R;S;T;E)
      EDQL  FOUND (-2; W; E)
      EDQL  ,*  (U#100;A; E)
      SETS  *
   RETU INLIB
LIBR  (ED; D, #SE; I '; UNIDENTIFIED PEAK; ;;;;;;;;;; SE, 1; ;; E; E)
NOTFND
   s- PRIN/KX(@NF)
   s
   PRIN   (@NF)/KX
                               G-8

-------
         !U,4iT4i ;!12, 4; T4;  ; ! 13, 4; T4;  ; ! 18, 4; T4;  ; \ 17, 4; T4;  ;
         !4, 5; T7;  ; T; UNKN; E
       !il,4;T4;  ;  ! 12, 4; T4;  ; ! 13, 4; T4;  ; ! 18, 4; T4i ;  ! 17, 4; T4;  ;
       !4, 5; T7;  ; T; UNKN; E
SCT4 SE
SET4 !24
I.INEEN
   * PRIN/KX(@FE>
   •«•
   PR IN   (@FE)/KX
   @FE

      :  TIC;  ; : 24; C; E

      TIG;  ; !24; c.. E
UP RES
   *
   * 3ET8 TEMP
   # CHRO/0 *(U*10C; A; E)
   *  SETS $
   *
   SETS TEMP
   CHRO  ( I; #i Nl, 1; G-2, 2; U20, 2; Al<; D-iO, 10; E) /O
   IF !28
   EDQL , FOUND  (U*1OO;A;E)
   QUAN FOUND (D;R;S;T;E)
   EDQL FOUND <-2i W; E)
   EDQL , $ (U*100; A; E)
                                6-9

-------
         SETS  $
   ERASE
   EDLL *  <*; W; E)
   SET1 !12
   SETS $
   SET7 !11
   LOOP
PRTN   (F;E)/KX
FTP  (DE; 1: *1. 91/N; RE; i: PRIN. 91; 1: *1. 91; E)
                                     G-10

-------
                                   TECHNICAL REPORT DATA
                            (Please read lastrnctions on the reverse before completing)
 7. REPORT NO.
 EPA-560/5-87-002B
                                                           3. RECIPIENT'S ACCESSlOf*NO.
4. TITLE AND SUBTITLE
Characterization of HRGC/MS Unidentified Peaks  from
the  Analysis of Human Adipose Tissue, Volume  II  -
Appendices	
5. REPORT DATE
 .limp 30. 1QR7
6. PERFORMING ORGANIZATION CODE
                   Tnsf'
7. AUTHOR(S)
                                                           8. PERFORMING ORGANIZATION REPORT NO,
 J.  D.  Onstot, R. E. Ayling, 0. S. Stanley
 8823-A(01)
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Midwest Research Institute
425 Volker Boulevard
Kansas  City, MO  64110
10. PROGRAM ELEMENT NO.
 Work Assignment 23
11. CONTRACT/GRANT NO.
 68-02-4252
 12. SPONSORING AGENCY NAME AND ADDRESS
 U.S.  Environmental Protection Agency
 Office  of Toxic Substances (TS-798)
 Field Studies Branch, 401 M Street, S.W.
 Washington. DC  2Q46Q	
13. TYPE OF REPORT AND PERIOD COVERED
 Final Report 1/86-1/87	
14. SPONSORING AGENCY CODE
 EPA/OTS/FSB
 15. SUPPLEMENTARY NOTES
 16. ABSTRACT
 The  National  Human Adipose Tissue Survey  (NHATS), administered by EPA/OTS, is an on-
 going  chemical  monitoring network designed to detect  levels  and prevalences of toxic
 substances  in the adipose tissue of the general U.S.  population.   Adipose specimens
 collected  in  fiscal  year 1982 were analyzed as composites  for volatile and semivola-
 tile organic  compounds via HRGC/MS as part of a previous effort.   The data files were
 then processed  using a method developed to automatically identify unknown HRGC/MS
 peaks.   The method consisted of automatic identification of  unknown spectra via com-
 parisons to reference mass spectra, transfer of the results  of the identification
 step to  a  microcomputer, compilation of the data  into a spreadsheet program and gen-
 eration  of compound  identification tables from the spreadsheet.   Application of the
 method  to  the adipose data resulted in the identification  of volatile compounds from
 18 separate chemical classes and semivolatiles from 29 chemical  classes.   Compound
 classes  included saturated and unsaturated hydrocarbons, aldehydes, ketones, steroids,
 heterocyclic  compounds, drugs, aliphatic  and phthalate esters, phenols, halocarbons,
 and  methyl-substituted organosiloxanes.   Volume I (EPA-560/5-87-002A) describes the
 technical  approach.   Volume II (EPA-560/5-87-002B) provides  supplemental  data.
17. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
Adipose Data transfer
Computer program Characterization
Mass spectrometry
GC/MS
Volatile
Semivolatile
13. DISTRIBUTION STATEMENT
b.lDENTIFIERS/OPEN ENDED TERMS

19. SECURITY CLASS (THu Report)
Unclassified
20. SECURITY CLASS (This page)
Unclassified
c. COSATI Field/Group

21. NO. OF PAGES
95
22. PRICE
EPA Form 2220-1 (R»v. 4-77)   PREVIOUS EDITION is OBSOLETE

-------