United States
           Environmental Protection
           Agency
            Environmental Researc'
            Laboratory
            Athens GA 30613
           Research and Development
vEPA
Planning Guide for
Evaluating Agricultural
Nonpoint Source
Water Quality Controls

-------
            PLANNING GUIDE FOR EVALUATING AGRICULTURAL
              NONPOINT SOURCE WATER QUALITY CONTROLS

                                by

     Paul  D.  Robillard, Michael  F. Walter, and Linda M. Bruckner

                        Cornell  University
                      Ithaca, New York 14853
Project Members:

     Cornell  University

       George L. Casler
       Douglas A. Haith
       Marian 0. Harris
       Earl A. Lang
       Raymond C. Loehr
       John H. Martin, Jr.
       Christine A. Shoemaker
       Lawrence J.  Tubbs
Washington State University

   Scott G.  Matulich
   Brian L.  McNeal
   Vincent F.  Obersinner
   William Pietsch
   Norman K.  Whittlesey

Colorado State University

   Wynn R.  Walker
                     Grant Number R804925010
                          Project Officer

                         Thomas E.  Waddell
          Technology Development and Applications Branch
                 Environmental  Research Laboratory
                      Athens, Georgia  30613
                 ENVIRONMENTAL RESEARCH LABORATORY
                OFFICE OF RESEARCH AND DEVELOPMENT
               U.S.  ENVIRONMENTAL PROTECTION AGENCY
                      ATHENS, GEORGIA  30613

-------
                                 DISCLAIMER

      This report has been reviewed by the Environmental  Research Laboratory,
U.S. Environmental Protection Agency, Athens, Georgia, and approved for pub-
lication.  Approval does not signify that the contents necessarily reflect
the views and policies of the U.S. Environmental Protection Agency, nor does
mention of trade names or commercial products constitute endorsement or
recommendation for use.

-------
                                  FOREWORD

      As environmental controls become more costly to implement and the
penalties of judgment errors become more severe, environmental quality
management requires more efficient management tools based on greater know-
ledge of the environmental phenomena to be managed.  As part of this
Laboratory's research on the occurrence, movement, transformation, impact,
and control of environmental contaminants, the Technology Development and
Applications Branch develops management and engineering tools to help
pollution control officials achieve water quality goals through watershed
management.

      Pollutants in runoff and seepage from urban, agricultural, and forested
areas contribute significantly to water pollution problems in many areas of
the United States.   Control strategies for reducing nonpoint source pollution
require a body of knowledge and set of analysis methods that reflect the
complex nature of the problem.   This manual  was developed as a guide for
water quality planners who must design cost-effective nonpoint source con-
trols for irrigated and nonirrigated cropland as part of areawide water
quality management strategies.


                                       David W. Duttweiler
                                       Director
                                       Environmental  Research Laboratory
                                       Athens, Georgia
                                     m

-------
                                  ABSTRACT

    This manual is designed to serve as a guide for the evaluation and
selection of agricultural  nonpoint source controls.  Such controls are
specified in water quality management plans developed in response to Section
208 of the 1972 Federal  Water Pollution Control Act Amendments.  Control
practices are described for both irrigated and nonirrigated cropland.  The
evaluation methodology presented is applicable to areas ranging in size from
individual farms and sub-watersheds to large regions,.

    The manual contains five sections including the introduction, and six
appendices.  Section 2 presents the physical and chemical nature of nonpoint
source pollutants  and the pathways by which these pollutants are trans-
ported from field to water body.  Pollutants discussed include nutrients,
sediment, animal wastes, salts, and pesticides.

    Controls involving tillage methods, cropping practices, and methods of
fertilizer and pesticide application are described in Section 3.  Control
options are categorized  according to the relative permanence of the
measures into three groups:  structural, vegetative, and managerial.

    Section 4 presents the actual  evaluation methodology, which involves the
following seven steps:  1)  Description of the watershed, 2) Identification
of the problem, 3) Determination of applicable control measures, 4) Choice
of the unit of analysis, 5) Establishment of the base condition, 6) Evalua-
tion of control measures, and 7) Development of an optimal control strat-
egy.  Problem  identification, Step 2, is actually  beyond the scope of the
manual and is assumed to have been completed in earlier planning stages.
The end-product of these steps is a ranking of the cost-effectiveness of
specific practices controlling pollutant pathways  in a region.

    Two case studies described in Section 5 demonstrate the application of
the evaluation methodology to watersheds in Ohio and Washington States.  A
single farm is evaluated as part of the Washington State case study.

    The planning manual is supported by the following six appendices which
provide details of pollutant transport processes and methods of evaluation:

    A.  Estimating Nonpoint Source Sediment and Nutrient Loadings
        from Non-Irrigated Croplands
    B.  Sediment and  Nutrient Loss Estimates from  Irrigated
          Agriculture
    C.  Estimating the Effectiveness and Costs of  Salinity Control
          Measures

-------
    D.  Nonpoint Source Water  Quality  Problems  Related  to Animal
          Agriculture
    E.  Water Quality  Impact and  Control  Alternatives Associated  with
          the Use of Insecticides
    F.  Economic Perspective and  Evaluation  Methods  for Agricultural
          Nonpoint Source Water Quality  Management

    This report was submitted  in  fulfillment of  Grant No.  R804925010  by
Cornell University under the sponsorship  of  the  U.S.  Environmental
Protection Agency.  This report covers the period  February 1,  1979  to
February 1, 1980, and  work was completed  as  of  February 1, 1981.

-------
                                  CONTENTS

Foreword   	  i "> i
Abstract	   }y
Acknowledgements  	,	  vii

    1.  Introduction	    1

    2.  The Problem	    3
            Agricultural Practices and Their  Impact on  Water  Quality...    3
                Guidelines  for Water Quality  Improvement 	    3
                Point and Nonpoint Sources of  Pollution  	    3
                Natural  (Base) Loads 	    4
                Water Use Impairment 	    4
                Physical Factors Affecting Degree  of
                Water Quality Impact 	    8
                     Stages  of Pollutant  Transport  	    8
                     Precipitation and Temperature  	    8
                     Topography 	   10
                     Soil Type 	   10
                     Cropping Practice 	   11
                     Irrigation Applications 	   11
                     Stream/Lake Characteristics  	   13
            Agricultural Nonpoint Source  Pollutants:
            Factors  Related to Their Control  	   13
                Nitrogen 	   14
                Phosphorus  	   15
                Sediment 	   16
                Animal  Wastes 	   17
                Salinity 	   18

    3.  Nonpoint  Source  Control Practices  	   20
            Criteria for Grouping Nonpoint Source  Controls  	   20
            Candidate Measures for the Control of  Nonpoint
            Agricultural Sources  	   21
                Non-Irrigated Agriculture	   21
                     Management Controls  	   25
                     Vegetative Controls  	   28
                     Structural Controls  	,	   29
                Irrigated Agriculture	   30
                     Management Controls	   38
                     Vegetatative  Controls  	   42
                     Structural Controls	   42
                     Institutional Controls 	   46
                                     VI

-------
    4.  Methods for the Evaluation and Selection of Agricultural
        Nonpoint Source Controls 	  47
            Step 1:  Description of Watershed  	  47
            Step 2:  Problem Identification	  47
            Step 3:  Determining Applicable Control Measures  	  50
            Step 4:  Choosing the Unit of Analysis 	  54
            Step 5:  Establishing the Base Condition  	  54
            Step 6:  Evaluating Candidate Control Measures  	  60
            Step 7:  Developing an Optimal Control Strategy  	  62
            Evaluation of Pesticide Controls 	  68
            Factors Influencing Successful Implementation of  NPS
            Control Practices 	  74
            Summary 	  77

    5.  Examples of the Agricultural NPS Selection Process  	  78
            Purpose of Case Studies 	  78
            Case Study I:  Honey Creek, Ohio 	  78
                Description of Watershed 	  78
                Problem Identification 	  79
                Determining Applicable Control  Measures  	  82
                Choosing the Unit of Analysis  	  83
                Establishing the Base Condition  	  83
                Evaluating Control Measures 	  91
                Developing an Optimal Control   Strategy 	  93
            Case Study II:  Yakima River Basin, Washington  	  100
                Description of Watershed 	  101
                Problem Identification 	  101
                Farm Model 	  102
                Watershed Model 	  Ill

References 	  122
Appendices

    A.  Estimating Nonpoint Source Sediment and  Nutrient Loadings
          from Non-Irrigated Croplands 	  124
    B.  Sediment and Nutrient Loss Estimates from Irrigated
          Agriculture  	  326
    C.  Estimating the Effectiveness and Costs of Salinity  Control
          Measures 	  364
    D.  Nonpoint Source Water Quality Problems Related to Animal
          Agriculture  	  430
    E.  Water Quality  Impact and Control  Alternatives Associated with
          the Use of Insecticides 	  485
    F.  Economic Perspective and Evaluation Methods for  Agricultural
          Nonpoint Source Water Quality Management 	  655

Glossary  	  720
                                     vn

-------
                            ACKNOWLEDGEMENTS

     The compilation of material in this report would not have  been
possible without the assistance of a number of individuals.  Dr.  Steven
Yaksich and Mr. John Adams of the U.S. Army Corps of Engineers,  Buffalo
District, Dr. Terry Logan, Dr. Samuel  Bone and Dr.  Lynn  Forster  of Ohio
State University, and Mr. George Stem with the Soil Conservation
Service, Medina, Ohio all provided important data and suggestions for
case study analyses.

     Ms. Karen McCombe, Cornell University, skillfully directed
editorial and format changes from which evolved tihe final report.
Mrs. Sandra Bates, Ms. Dorothy Clarke, Ms. Deena  Dunn, Mrs.  Sue
Fredenberg, Mrs. Terry Kinsman, Mrs. Marion Ogden and Mrs.  Ruth  Stanton
all contributed to the typing of the report.
                               Vlll

-------
                                  SECTION I

                                INTRODUCTION
     Excessive growth of aquatic plants in Lake Erie decreases game fish
populations, increases the level of treatment necessary for municipal drink-
ing water supplies, and discourages recreational use of the water.  High
salt concentrations in the Colorado River make the water unfit for irriga-
tion purposes, drinking water, and other municipal/industrial  uses.  These
are both nationally publicized cases of serious, long-term water pollution
problems.  The major source of pollution in these cases is not industrial
and municipal discharges, considered to be the cause of most serious water
pollution problems in the country.  The source rather is runoff and seepage
from urban, agricultural, and forested areas.  Pollution such as this, which
originates from an unconfined source not from a localized source such as a
pipe, is referred to as nonpoint source (NPS) pollution.

     In  1972, the Federal Water Pollution Control Act Amendments (FWPCA)
were passed in response to a recognition of the seriousness of both point
and nonpoint water pollution problems.  The national objective for water
quality  improvement as set forth in section 101(a) of the 1972 Amendments,
is "to restore and maintain the chemical,  physical and biological integrity
of the nation's waters."  The act states that by 1985, pollutant discharges
into navigable waters from point and nonpoint sources shall be eliminated.
An interim goal of this act is to provide for the protection and propagation
of fish, shellfish, and wildlife, and to permit recreation in and on the
water, wherever feasible, by July 1, 1983.

     Section 208 of the FWPCA amendments calls for areawide water quality
management plans to be developed and implemented by each state to insure
adequate control  of both point source and nonpoint source pollution.  These
plans must identify water quality problems and possible sources of
associated pollutants, and propose methods for pollution control.  Although
the development and implementation of these plans is the primary
responsibility of each state, financial  and technical  assistance is
available from the federal government.

PURPOSE  OF MANUAL

     The purpose of this manual is to serve as a guide for the development
of agricultural nonpoint source controls called for in 208 water quality
management plans.  Step by step procedures outlined in the manual provide a
basis for the cost-effectiveness ranking of specific practices controlling
pollutant pathways in watersheds.  Criteria and computational  methods for
evaluating different control strategies are presented.  The manual is

                                      1

-------
designed to be used in preliminary planning stages, not in the  final  stages
of site-specific design.

SCOPE OF MANUAL

     The material presented in this manual is oriented towards  water  quality
planners involved with nonpoint source pollution control programs.   It  is
assumed that the planners are familiar with the problem and the geographic
area to be evaluated.  Knowledge of typical farm enterprises  in the  region
and the engineering feasibility of control practices is assumed.   The plan-
ning team may have to consult with various federal, state, or local  groups
to gain this familiarity.  The Soil Conservation Service (SCS/USDA) and
State University Departments of Agronomy, Agricultural  Engineering,  and
Agricultural Economics can provide valuable assistance.

     The methodology presented in this manual is appropriate for the  design
of nonpoint source controls for all irrigated and nonirrigated  cropland.   It
can be used to evaluate areas ranging in size from individual farm fields to
large regions.   With such broad applicability, specific soil, crop,  pre-
cipitation and other physical as well  as economic data are not  supplied. The
case studies presented in Section  5 demonstrate how the methodology  is
applied in specific situations.  The accompanying technical reports provide
details of computational methods and data collection procedures.

     This manual focuses on three  key pollutant categories:   crop  nutrients,
sediment, and salts.  Methods of estimating losses of these pollutants are
presented.  Livestock waste and pesticides are covered  as  separate pollutant
categories.  Evaluation methods for estimating losses of these  pollutants
are less well developed, thus these pollutants are treated in less detail.

USE OF MANUAL

     Because nonpoint source pollution is both a relatively recent concern
and a complex phenomenon, many unknowns remain.  The extent to  which  agri-
cultural sources contribute to the total pollutant load, the  extent  to  which
various control   practices decrease this load, and the effects of reduced
pollutant loads  on water quality are generally not easily  determined.   The
manual  makes certain assumptions concerning how this information is to be
derived.  The manual assumes that:

     1)   Water  quality problems have been defined and.  associated  pollutants
          have been identified in  previous stages of planning,
     2)   The relative contribution of agricultural sources to  the total
          pollutant load has been estimated,
     3)   The pollutant load delivered to the waterbody will  be reduced  by
          reducing edge-of-field losses,
     4)   Physical and economic mathematical models used to estimate  cost-
          effectiveness of practices are sufficiently accurate  to use for
          the purpose of comparing the relative cost-effectiveness of dif-
          ferent control strategies, and
     5)   Some field data collection may be required.   The manual  lists  data
          required for the various steps of the evaluation, and indicates
          where  field studies may  be necessary.

-------
                                  SECTION  2'

                                 THE  PROBLEM''


AGRICULTURAL PRACTICES AND THEIR IMPACT ON WATER QUALITY

Guidelines for Water Quality  Improvement

     The Environmental  Protection Agency (EPA) Guidelines for State and
Areawide Water Quality Management Program Development  (EPA,  1976)  suggest
that "Best Management Practices" be identified and implemented for categor-
ies of pollutants.  A Best Management Practice (BMP) is defined  as "a  prac-
tice or combination of practices that is determined by a state (or desig-
nated areawide planning agency) after problem assessment, examination  of
alternative practices, and appropriate public participation to be the  most
effective, practicable means  (including technological, economic, and  insti-
tutional  considerations) of preventing or reducing the amount of pollution
generated by nonpoint sources to a level compatible with water quality
goals".  EPA advises that wherever possible, practices should concentrate on
controlling each pollutant at its source.  Since collection  and  treatment of
polluted water is generally complex and expensive, treatment is  to be
resorted to only in situations where preventive measures will not  result in
the attainment of desired water quality standards.

     Cost sharing for the implementation of BMPs was authorized  by the Rural
Clean Water Act of 1977.  BMPs to control nonpoint source pollutants are
installed and maintained under 5-10 year contracts with cooperating land
owners.

Point and Nonpoint Sources of Pollution

     Whereas point source pollutants have a localized identifiable source,
typically a pipe, nonpoint source pollutants originate from  an unconfined
source, typically a relatively large area of land.  Sources include land
used for agriculture, silviculture, mining, and construction.  Urban  land
over which stormwater flows is another source.  Transport of pollutants from
nonpoint sources to water bodies is by overland flow, percolation, and
erosion and sedimentation.  Pollutants which may originate from  agricultural
land include nitrogen, phosphorus, sediment, manurial organic matter,  salts,
and pesticides.

     The unique characteristics of nonpoint source pollution pose special
problems which require a body of knowledge and set of methods very different
from point source pollution problems.  Whereas identifying the origin  and
measuring the discharge associated with a point source involves  well-estab-

-------
1ished techniques which are accurate and easily applied, identifying  and
assessing the magnitude of nonpoint source contributions requires new and
very different techniques.

     The complexity of control strategies required for  nonpoint  source  pol-
lution reflects the complex nature of the problem.  Nonpoint pollutants are
not transported or delivered to water bodies in a confined manner, there-
fore there is no efficient and economical means of monitoring.   The use of
effluent limitations is thus generally not applicable for nonpoint source
control.  Control  strategies, on the other hand, must be developed from a
consideration of the many variables controlling pollutant transport.  An
understanding of the dynamics of chemical cycling in soil and water is
required to effectively identify nonpoint sources, assess impacts, and
develop appropriate control  strategies.

Natural (Base) Loads

     Many pollutants, including nitrogen, phosphorus, organic matter, patho-
gens, salts, and sediment are present to varying degrees in all  aquatic
systems.  It is important to estimate the magnitude of  natural pollutant
loads before implementing control measures.  Where the  base load is rela-
tively large, the improved management of adjacent agricultural lands  may
not significantly improve water quality.

Water Use Impairment

     Although nitrogen, phosphorus, organic matter, salts and sediment  are
natural components of all aquatic systems, in excess they can offset  criti-
cal  environmental  balances.  Table 1 summarizes how nutrients, sediment,
animal wastes, salts and pesticides can affect the quality of receiving
waters.

Nutrients--

     Nutrients, such as nitrogen and phosphorus, are generally present  at
relatively low concentrations in the aquatic environment (i.e.,  below 0.3
and 0.05 ppm for nitrogen and phosphorous, respectively).  When  man augments
the quantities of nutrients in a stream or lake, aquatic productivity can  be
increased dramatically.  This process, referred to as cultural eutrophica-
tion, may reduce the value of the water to humans.  Decaying  organic  matter
may produce unpleasant odors and deplete the oxygen supply for aquatic
animals.  Excess plant growth may interfere with  recreational activities
such as swimming and boating.  Decreased oxygen levels, especially in the
cold bottom waters where decaying organic matter tends  to accumulate,
reduces the quality of game fish habitats.  The lake or stream waters can
become turbid and noticeably colored.  When used as a water supply by
municipalities and industries, the level of pre-treatment often  must  be
increased.

     Cultural eutrophication is not the  only water quality problem caused  by
nutrient enrichment.  Dissolved ammonia  at concentrations of  more than  0.02
ppm of NH3 may be toxic to fish.  Nitrates in drinking  water  are potentially

-------























i
_j
d
a.
to
|
CXL

>-
0
to

s
£
1
o.

*—
UJ
S
at
Ul
i


UJ

CO
h-

«
i





« u
p





fr*.

flo
a.
^jf






Q_ *""





S
V) 3
O O
U- O.

o



c >>



£3
. ftf 14.
-0 >£ 0
C **- IO 4-> VI
2-5 °" * cn
.c "Jo o •* -a •"
w t. • u ai •»-»
at *j o -M *
U C -O l/> 10 3
.c 4i c vi (- cr
c
— u
U) C -C ID 4- O
oioi-u->ua>o4-> u a.
O»-i- O *T C C •-- * O
itJ-MM-ACnmC-r- JO O> Ul
r- 1. IB •— C O O C U C -C
i— 3 •— +J 3 Cn-*- *O J- .C i1'-Q- T3 *J"DinO
CCOECCi- CXOJ<~ Ci~S~
OCOIQ.-P003:OE  O Cr— > C -M
uo^ai Q.OIL. co«+-3 a'^-TS-M
ID Ol/lt->»0)P~Vl^'*- -r--f-OV> t-OC
•r- •— - CD •»- 4-> f— 4J ID "*-. •*-" Q C i- —
O Q. C 'OD.l-'OUlOai *— E O C i. •- 1- Q.T3
EO.-'-OJO»34-»'*--r--f-UC 3 t. -r- 
5eMOlS«COI 0.10"- 0)*t-0ifl is) C E 0) •<-
OjC(7>CnOIL-^L.L.+J4J L.V>30) >, r- TO (J >,
j: • vi c i i- i- ot x: oiOv>3 c-ac roeais
f^Sl^sl-SlsIl aSli Sssll
c
O
»— C 3
ai g («-
»— 3 *5

Stss ti.
x o ai o •— o
O *— 4-» -i- C i—
O (0 •*-" 3 O
•o u u n vi u
0) -4-* S- Ol V.
O VI -r- 4-> (S1V1 U4->O
 k. V> V) UJ •*-
Ol£ Ol C J <4- Q j; ID o 1/1 i— m^-oioi -_ J C -S ^
(JOV •<- -r- ^ H- (— 3O l/)OX Ol (O Q.
•iJCTOIW *O>+J C *O4-' Z iciD-*-1! — CU
f+jai cnl-oi-'-'ew if-oi >-c:oia- v>
C**-r— ID 4-> VI O)O- OJ- Q£ -t- -^- r— H- O fc- 3 OJJ^1*-
«l-(O C  fc. in 1-WO
0 i— 01 C -^UOli- vivlOl ID «0<+--0*-> i*-^
ll C -r- UulT3(O-t->OlV)a.Vl^fc. OlL-iQCOlO) £ O
C(J-'-+J "O-MCjr— W>Otg O'r-VlOl (/^l/)UO> •»- wl +J Cu r-
'•|3j=a> vioi v)t^ai->-o.oi u ro 01 i- 3 «— *o 01 3 j§ •£ •£ o vi
Ol iS)Q) U J2 t-4->Q13Z UJL- H3 0> •*-> S- iDCt-Ol
to cr-c ot '^'a'aJr— CC3CCOJI— Oi>4- 5 oicoioioco ra CT-— o r-
...
E,
o
o *->
H- 0-
ZZ Q. ^ 0.
3E i t Q- I "a O +J
I 01 rO I O) "O «-
|Q L. O ID ^ Q.-I- OOQUUO
Oi-EOO DO CDt-JZU-lj-
K- Z S K- (/) LO CO
en
c
"O XJ
c tr
to uj vi E •— 6
3 J— 3 Ol Cl-C3''-C E
LOOIO eCO)Ot-O> O
h- cnj= I- 3 oi£ c 01 en >- u
zoo. z oo.ai4->o »—

1— 1 4J O Z < •*-* O >v3L +J Z r~

^—ZQ- Q H^ZQ-OQ- _Ji-O
=) UJ Z <






JT
+J
S 0§
c o>
O 01 4->
iD 3 E

•r- C O
C .C 01 >
CTi U *J O)
r- O O C

£
£
(J I .
«*-
(LI

fp n

Oi -
JD
2



+-1 V.
0 4^
O fT3
U**- ^

01 •*-> ^ d
1- C VI
J Ol r- U
to O TJ
>! 01 -M 3
8*0. r~ ^
1- O 3 O C

(

- VI VI 0 "? S
-2 QJ "^ "a. c ^ ^

o'- '^^S'o"2™-S£
i- 'OCi-.col-'-^
O O'-Oa.'-t—UQ.


ai QJ v
a G u --


1 — fl> 3 •-
UJ
Q-

-------
toxic to humans, especially young infants, since their digestive systems are
less acid than those of adults and contain bacteria capable of reducing
nitrate-nitrogen to nitrite-nitrogen.  Nitrite accumulation in the digestive
tract can, in turn, cause brain damage or even death, by reducing the
oxygen-carrying capacity of the blood  (methemoglobinemia).  Consequently,
the Environmental  Protection Agency (EPA) has set a limit of 45 ppm nitrate
for drinking water.  Ruminants can also be affected by nitrates via the  same
chemical processes.  Tolerance levels for ruminants have been set somewhat
higher than for humans.

Sediment--

     Sediment affects the use of water in a variety of ways.   Total sus-
pended solids can reduce the amount of sunlight available to aquatic plants,
cover fish spawning areas and food supplies, and clog the gills of adult
fish.   This reduces fish, shellfish and plant populations and decreases the
overall productivity of a lake or stream.  Recreation is limited because of
the decrease in fish and shellfish populations and because of the water's
unappealing, turbid appearance.

      Sediment also fills road drainage ditches, culverts, and stream
channels and shortens the economic life of reservoirs and farm ponds.    It
can plug water filters, erode power turbines and sprinkler nozzles, and
damage pumping equipment.  Maintenance costs are increased and additional
treatment may be necessary before the water can be used  for drinking or
industrial purposes.

     Much of the sediment transported to waterways originates from agricul-
tural land.  Valuable topsoil is thus  removed and an increased application
of nutrients is required to maintain soil productivity.

     Chemicals such as pesticides, solid phase phosphorus, ammonium and
organic nitrogen are also transported with sediment in an adsorbed state.
Changes in the aquatic environment can cause the release of these chemicals
from sediment.  Thus, although adsorbed phosphorus transported by the  sedi-
ment may not be immediately available  for plant growth it may serve as a
long-term and continual contributor to lake eutrophication.

     The reverse may also occur; chemicals already present in the water can
be scavenged by suspended solids.  A pesticide adsorbed  to sediment will not
necessarily become less toxic, but much of it will settle out of solution at
least temporarily.

Animal Wastes--

     Animal wastes can contribute nutrients, oxygen-demanding materials, and
pathogens to receiving streams.   The  composition of most manures is such
that if enough is applied to meet the  nitrogen needs of  a crop, phosphorus
will be applied in excess of crop needs.  Surface runoff from fields to
which manure has been applied thus may carry substantial quantities of
phosphorus.  Leaching of soluble or organic forms of phosphorus from manure
application sites  is generally negligible because of the soil's capacity to
adsorb phosphorus.
                                      6

-------
     The oxygen demand exerted by carbonaceous materials  individually  or  in
combination with nitrogen can deplete dissolved oxygen  supplies  in water,
and may result in anaerobic conditions.   When the decomposition  process
becomes anaerobic, methane, amines and  sulfide are produced  in addition to
the carbon dioxide, sulfate, ammonia and nitrates that  result from aerobic
decomposition.  The water acquires an unpleasant odor,  taste and  appearance
and becomes unfit for drinking and recreational purposes.  Treatment is
often required for industrial use.

Salinity--

     Water used for irrigation accumulates salts.  In some areas  of the
country, water and land quality has been seriously degraded  due  to salin-
ity.  The total salt burden of western  streams may be as  much as  40 percent
man-caused (Law and Bernard, 1970).

     Excess soil salinity can delay or  prevent crop  germination  and substan-
tially reduce the rate of plant growth.  High osmotic pressures  that develop
between the soil solution and the plant root  impair  the plant's  ability to
absorb water.  Other possible adverse effects of salinity include nutri-
tional imbalances, toxicities caused by specific ions such as boron which
can be toxic in small  quantities, and poor soil aeration  and water transmis-
sion if excess sodium accumulates and disperses the  soil.  The addition of
saline irrigation water to surface water bodies limits  potential  downstream
usage for drinking, irrigation or industrial  purposes.    High salt concen-
trations in streams and lakes can harm  fresh-water aquatic plants just as
excess soil salinity damages crops, although  salt levels  rarely  reach  such
levels except in land-locked bodies such as the Salton  Sea (50,000 mg/1) or
the Great Salt Lake (270,000 mg/1).

Pesticides--

     Pesticides include insecticides, herbicides, mitacides, nematocides,
rodenticides, fungicides, plant growth  regulators, and  desiccants, all of
which are used extensively in agriculture and silviculture.  The  utilization
of pesticides in agriculture has greatly increased since  they were first
used in the 1940s.  According to USDA,  in 1976, 1015 million pounds of pes-
ticides were used in this country.  Of  this quantity, about 65% were used on
farms (von Rumker, et al., 1975).  Approximately 56% of all  nonpasture
cropland was treated with herbicides and 18% was treated  with insecticides.

     Although the benefits of pesticide use are substantial, there are also
environmental risks related to its use.   Some types of pesticides or  their
metabolites are resistent to degradation.   Degradation products  may persist
and accumulate in aquatic ecosystems.   The entire food  web including man can
be affected.

     Sublethal effects include those behavioral and  structural  changes in an
organism which jeopardize its survival.  For  example, certain pesticides
have been found to inhibit bone development in young fish or affect repro-
duction by inducing abortion.

-------
     Herbicides typically degrade quickly, however can destroy non-target
vegetation in the aquatic environment that serves as a food source for
higher organisms.   Indirect effects of herbicide use thus include the
disruption of food chains and the addition of organic material to waters
promoting eutrophication.

     Biomagnification is a phenomenon which occurs if a pesticide is  taken
in by an organism but not excreted.   An organism will accumulate a higher
pesticide concentration than is present in the organisms upon  which it
feeds.

Physical Factors Affecting the Degree of Water Quality Impact

Stages of Pollutant Transport--

     The process by which a substance is delivered to a stream can be des-
cribed in terms of three stages: availability at the field site, detachment,
and transport (Figure 1).  Only when a pollutant is available  in some form
at a site, becomes detached, and is transported to a receiving body does it
constitute a potential pollution hazard.

     Factors which determine the nature of the pollutant delivery process in
a given situation include precipitation, temperature, topography, soil
type (including antecedent moisture conditions), cropping practices and
irrigation applications.  Physical characteristics of the receiving water
body affect the actual impact of the pollutant after it is delivered.

Precipitation and Temperature--

     Temperature, rainfall pattern, and snow melt are important climatic
variables that affect infiltration, surface runoff, and soil  erosion.  At
lower temperatures, the  rate of nutrient uptake by plants decreases.   More
nutrients in the soil may thus be available for detachment and transport,
however less nutrients will be taken up by plants in the receiving water
bodies.  The effects of any increase in nutrient transport are further off-
set during cold weather  by the capacity of cold water to hold  more oxygen
than warm water.

     High intensity storms generally increase the runoff of water and the
dislodgement and transport of pollutants.  Over shorter periods of time  (for
the same total rainfall) the water will have less opportunity  for infiltra-
tion.  The high kinetic  energy of raindrops causes larger soil particles to
be dislodged from the surface and transported with runoff waters and  smaller
particles to become cemented, sealing the  soil surface.  Raindrop impact of
high intensity storms also tends to seal the soil surface.

     Melting snow can contribute significantly to the runoff-erosion  pro-
cess.  An increase in  runoff, which often  results from  rapid  snow melt,
provides greater energy to dislodge and transport soil and associated
adsorbed substances and  increases the volume of water for transporting
soluble materials.

-------
 fO
 O)
 S-
4->
 to

 o
 
 O
 O
 Q.
 O)
 O)
 O)
Id
cr
i—
CO


O
I-

Q
_l
UJ

>-
O
a
cr
o
a.
CO
z
<
cr
i-
LJ
2
I
UJ
Q
CD
4

-------
Topography--

     The capacity of water to dislodge and transport material  increases  with
its velocity.  As water moves downslope its velocity increases.  The steeper
the slope, the faster the increase, and the longer the slope,  the  greater
the water volume and velocity at the bottom.  With higher velocities, ero-
sion and overland flow are promoted and infiltration inhibited.

     Shape of the slope is also important, with concave hills  generally
delivering fewer pollutants to a stream or lake than convex hills.  Trans-
port capacity decreases at the bottom of a concave slope, allowing  some  of
the suspended pollutants to settle.  The reverse is true of convex  hills.

Soil Type--

     The rate at which water infiltrates soil affects the ratio of  surface
to  subsurface flow.  With an increase in the  infiltration rate of  a soil,
the pollutant load associated with runoff should decrease.  Both the solu-
bility and adsorptive nature of a pollutant will determine whether  it be-
comes adsorbed to soil particles or percolates through the soil.

     A soil's infiltration rate and its ability to adsorb pollutants depends
on  soil characteristics.  Prior moisture content markedly affects  the amount
of  water which can infiltrate into a soil.  The amount of organic  matter and
clay particles largely determines the adsorption capacity of the soil.
Sandy soils  generally have high infiltration  rates, because the large soil
particles result in relatively large pores, through which water can perco-
late readily.  Because total surface area and the negative charge  of these
soils are less, their adsorption capacity is  generally much less than clay
soils.  Soils that are both well drained and  contain a sufficient  amount of
clay and organic matter will absorb the most  pollutants.  Subsoil character-
istics may either retard or enhance drainage, thus influencing the  parti-
tioning between surface and subsurface flow.

     Soil fertility can influence pollutant flux.  An increase in  fertility
may increase evapotranspiration due to increased plant growth.  This will
decrease both runoff and subsurface flow.  The increased crop  canopy will
provide for  greater protection of the soil surface from  raindrop impact, and
the larger, deeper root system will increase  soil stability during  runoff
events.  The eroded soil, however, will have  a greater content of  nutrients.

     Soil type affects the polluting potential of an area by limiting the
fundamental choice of cropping practice and/or irrigation system options.
For example, poorly drained soils require certain cultivation  practices  and
often allow only limited cropping choices.  Excessively drained soils
require shorter, more frequent irrigations, and frequent  fertilization,  and
often cannot be efficiently irrigated with conventional surface irrigation
methods.
                                     10

-------
Cropping  Practice--

     Crop cover protects the  land  from  rainfall  impact, thereby  decreasing
soil erosion and  increasing infiltration.   In  general, the  potential  for
soil erosion and  runoff will  be smaller the denser the crop  cover,  the
longer the crop is on the land, and the greater the quantity of  residue left
after harvesting.

     Root growth  increases soil stability.  In addition, crops with deep
roots generally require less  frequent irrigations.  Both enhanced soil
stability and  reductions in irrigation  frequency  help to minimize pollutant
losses from croplands.

     Certain cropping practices can reduce the need for pesticide applica-
tions.  For example, using more resistant crop varieties may allow  reduced
pesticide application rates,  and mechanical weed  control techniques  may
decrease the need for herbicide use.

Irrigation Applications--

     In arid regions, which dominate much of the  western United  States,
agricultural land is commonly irrigated.  Irrigation not only increases
productivity (by  2- to 3-fold), but also provides flexibility by allowing a
farmer to grow a  variety of valuable crops such as corn, cotton or  sugar
beets.  However,  as irrigation water moves across and through the furrow-
irrigated fields, salt concentrations are increased through  evapotranspira-
tion, and other pollutants are leached  from the  soil.

      The degree  of impact that leachate and return flows have on the
quality of receiving water is determined to a  large extent  by the method of
irrigation.    Irrigation volume and efficiency will vary markedly among
furrow, basin, border, sprinkler and trickle irrigation methods.  Given a
specific method,  different system  design and operating practices result in
widely different  efficiencies.  For furrow-irrigated fields, for example,
the magnitude of  runoff and percolation depends on stream size (quantity of
water delivered per unit time to the head of each irrigation furrow), furrow
slope (steepness  of the irrigation channel) and length, frequency of irriga-
tion, set time (length of time each furrow is  irrigated during a given irri-
gation), uniformity of water  application, and  intake rate (Figure 2).

     An increase  in either stream  size or furrow  slope generally increases
the detachment and transport  capacity of the irrigation flow.  Flow
decreases as the  furrow is traversed, however, so midfield deposition of
sediment eroded from the head of the field is  common.  Usually irrigators
reduce stream size as the slope is increased,  but the reduction is  rarely
enough to compensate completely for the slope  increase.  Set time is often
determined by tradition or convenience to the operator, though longer set
times coupled with less frequent irrigations generally lead  to decreased
losses of sediment and adsorbed pollutants.  Increased set times, however,
may increase percolation.
                                      11

-------
                Frequency of Irrigation
                Set  Time
                                                   Uniformity of
                                                   Furrow Applications
                                                            Leaching
                                                         Return
                                                         Flow
              Figure 2.   Variables influencing pollutant  losses
                         from irrigated fields.
     Furrow  irrigation  is  characterized by considerably less uniformity  of
water application than  sprinkler  irrigation.   Because there is a nonuniform
depth of application, the  soil  below the furrows receives more water  than do
other areas  of the field.   Long furrows (larger lengths of run) further
decrease uniformity,  because  the  portion of the field near the lower  end of
the furrow receives a smaller  stream flow for less time than do those areas
near the upper end of the  field.   Consequently, less water infiltrates the
lower portion of the  field.   Nonuniformity is disadvantageous because it
results in over-application to some portions  of the field and/or under-
application  to other  portions.  Over-irrigation causes excessive percola-
tion, whereas under-irrigation causes plant stress and decreased crop
yields.
                                      12

-------
Stream/Lake  Character!'stics--

     The quantity  of  pollutants that may be adequately assimilated  by  a
water body is determined  by  many factors which cannot be easily controlled.
Physical characteristics  of  the receiving waters, such as size, rate of  flow
(turnover rate), base  load,  temperature, and pH all  affect the degree  to
which a substance  actually  impairs water quality (Figure 3).  The larger  the
volume of the receiving water  and the shorter the turnover rate, the less
sensitive the water body  will  be to an influx of pollutants.  Volume and
turnover rate are  especially important in irrigated  regions.  If the base
stream flow  is  large,  the pollutant concentration which results after
irrigation return  flows have been mixed with the stream may not be  large
enough to adversely affect  usage.
   Figure 3.  Factors influencing  the  assimilative capacity of waterbodies.
                                                 Base Load
                              Load from
                              Non-Point Sources

                             Point Source Load
                                  Water  Quality
                                  Impact
                                                  Temperature
Size
                                              Turnover Rate
               Characteristics of Lake
               Bottom Sediments
AGRICULTURAL NONPOINT  SOURCE  POLLUTANTS:  FACTORS RELATED TO THEIR CONTROL

     A nonpoint source  control  can  be evaluated in terms of both the stage
of the pollutant delivery  process during  which  it is operative and the
pollutant pathways  it  affects.   A pollutant may undergo many physical and
biological transformations  between  the time it  becomes available in the
                                      13

-------
field and the time  it  is delivered  to  a  stream,  lake,  or groundwater reser-
voir.  Substances initially strongly adsorbed to  soil  particles,  for exam-
ple, may later be detached and  become  dissolved  in  runoff waters.   The
transformations that a pollutant undergoes determines  which  pathway(s) it
will take between cropland and  receiving water.   A  pollutant can  be moved
suspended or dissolved in water, or attached to  soil particles  in  overland
or subsurface flows.   Figure 4  illustrates the  pathways  pollutants may
follow as they move to a water  body.
                             Figure  4.   Pollutant  pathways.
                                                              Drift
     Percolation1     Volatilization
            Overland
SubsurfaceN^Flow
   Flow
                              Base  Flow
                                                         Evapotronspiration
                                                                 s
Nitrogen

     Although  nitrogen  (N)  is  naturally  present  in soils,  it must be added
to most croplands  in order  to  increase their  productivity.   Manure spread-
ing, application  of commercial  fertilizers,  and  incorporation of crop resi-
dues all contribute nitrogen to the  soil.   Not all  of  the  nitrogen present
on or  in the soil  at a  given time  is available  for plant uptake.  Organic N
(primarily in  particulate form) normally constitutes the bulk of soil  nitro-
gen.   It is only  slowly  converted  to the more readily  available inorganic
forms  of nitrogen  (inorganic ammonium and  nitrate).
                                      14

-------
     Because of its mobility  in soils, nitrate  is the  form  of  nitrogen most
commonly used by plants.  Plants may also use ammonium nitrogen as an addi-
tional source.

     Nitrate-nitrogen  is highly soluble and will  readily  percolate below  the
crop root zone.  It may also  be transported with  surface  runoff,  but  not
generally in high concentrations.  Organic-nitrogen and ammonium, on  the
other hand, become adsorbed to soil and are lost  primarily  with eroding
sediment.  Organic nitrogen generally converts  to inorganic  nitrogen  with
time, thus all transported nitrogen is a potential contributor to eutrophi-
cation.

     Three microbial  transformation processes relate to the  control of
nitrogen.  The first two, ammonification and nitrification,  are part  of the
mineralization process which  converts nitrogen  from its organic to its
inorganic form, making it available for crop uptake.   The last reaction,
denitrification, causes nitrogen to be lost to  the atmosphere.  Denitrifica-
tion may reduce the quantity  of nitrogen lost via percolation  and runoff,
however, it also means that some fertilizer is  wasted.

     Nitrogen may be lost in  the gaseous form by processes which do not
require the presence of microorganisms and are  strictly chemical.  Such
losses of nitrogen as  ammonia can occur especially with heavy  surface
applications of urea or ammonium fertilizers.

     Practices which cause anaerobic soil conditions promote denitrifica-
tion, especially when accompanied by a source of soluble carbon to serve as
an energy source for the denitrifying organisms.  Such conditions are
especially prevalent at waste application sites and beneath  animal feed lots
and corrals.  Practices which increase either the oxygen  content  of the soil
or soil drainage (to remove the products of mineralization)  increase  miner-
alization, thereby allowing more nitrogen to become available  for plant
growth or for leaching.  Also, if fertilizers or manure are  not incorporated
into the soil, the potential  for nitrogen loss  via volatilization to  the
atmosphere and via surface runoff will be greater.  Finally, the  timing of
fertilizer and manure  applications to meet crop needs  is  critical.  The
closer an application  is made to the period of  maximum crop  growth, the
smaller the potential  for losses.  For example, the use of  split  applica-
tions, at time of planting and just before the  peak growth  period, is
usually recommended.

Phosphorus

     The total phosphorus (P) content of most soils is low,  between .01 and
.20 percent by weight  (Brady, 1974).  Since much of this  phosphorus is un-
available for plant growth, manure and fertilizers are used  to increase the
level of available phosphorus in the soil.  Some of this  applied  phosphorus
can reach nearby water bodies with runoff and erosion.  In addition, phos-
phorus that may be unavailable in the soil system may  still  erode with soil
particles and become  available when the bottom  sediment of a stream or lake
becomes anaerobic.   It may then cause water quality problems.  Estimating
the potential  impact  of phosphorus loss on water quality is  difficult at

                                     15

-------
present, because the relationships between various forms of phosphorus in
the soil and sediments, water, and biota are only poorly understood.  The
dynamics of phosphorus adsorption by bottom sediment are particularly ill-
defined.

     Phosphorus can be classified as either organic or  inorganic.  Available
inorganic phosphorus, which serves as the intermediary  between the bulk of
the total P, the organic P and the soluble fraction immediately available to
the plant is of most concern.  Inorganic phosphorus can be either dissolved
in surface or subsurface waters or associated with sediments  (particulate).
Although much of the particulate fraction acts as if it were  permanently
fixed by the soil, some of the particulate inorganic phosphorus  (the labile
fraction) serves as a source of the dissolved form.  The labile pool is com-
monly several hundred fold larger than the soluble fraction at any point in
time.  The fracton of the total particulate inorganic phosphorus which is
labile  is generally not known.  The equilibrium between labile particulate
and the dissolved inorganic phosphorus depends in part  on the chemical and
biological characteristics of the limnological system.  The amount of dis-
solved  phosphorus changes during transport from cropland to streams and
lakes as well.

     Losses of particulate inorganic phosphorus from croplands occur via
erosion since this form is associated with sediment.  Rainfall events tend
to cause a higher particulate phosphorus loading of streams than do snowmelt
events  because the former tend to be more erosive.

     Although dissolved inorganic phosphorus is found in all  surface and
subsurface flows, a decrease in runoff may not necessarily decrease the rate
of dissolved inorganic phosphorus loading to a particular stream or lake.
Labile  particulate inorganic phosphorus already present in the lake or
stream  sediments may continue to be converted to soluble form.   In other
words, a decrease in runoff may decrease total phosphorus loss but may have
little  short-term effect on the levels of available phosphorus in  receiving
waters.   If the amount of pre-existing labile phosphorus in bottom sediments
is small, however, then controlling runoff may reduce dissolved  phosphorus
concentrations and substantially improve water quality.

Sediment

     Eroded soil may either be redeposited on the same  field  or transported
from the  field  in runoff waters.  Sediment is that  soil which leaves a field
and is  subsequently deposited in streams, lakes, roadside ditches or other
off-field areas.  In nonirrigated regions, the sediment delivery process
starts  by the detachment of soil particles either as a  result of raindrop
impact  or overland flow.  Erosion can be classified either as interrill or
rill erosion.   Interrill erosion is that erosion caused mainly by  raindrop
impact  and  subsequent  shallow  flow toward rills.   It is thus  independent  of
slope position and occurs over relatively small areas.  When  the runoff from
interrill areas becomes sufficiently concentrated,  small but  well-defined
channels  or rills are  formed.  Rill erosion can contribute substantially to
suspended sediment loads since channelization of water  increases flow  velo-
city, which in turn increases the ability of the runoff to dislodge and

                                      16

-------
transport soil particles.  Gully erosion is an advanced  stage  of  rill
erosion where field operations are often impaired.

     In irrigated  regions, soil particles are detached both  by raindrop  or
sprinkler drop impact, and by the surface application of irrigation  water.
Significant amounts of soil are eroded by the flow  in irrigation  furrows
since the volume and velocity of such flows are relatively large.  These
flows not only contribute to the detachment process, but also  provide  the
means for transport of detached particles.  Because irrigation  water per-
colates along the  length of the irrigation furrow however, flow volume and
velocity decrease and mid-field deposition of sediments  eroded  from  the  head
of the  irrigated field is common.  Much of the sediment  eroded  from
furrow-irrigated fields actually originates in the  bottom 1/2  to  1/3 of  the
field,  particularly if water velocity increases toward the end  of the  field
as the  streams approach a relatively deep return flow collection  ditch.

     Sediment from cropland usually contains a higher percentage  of  finer
and lighter particles than the soil from which it originates.   Although
large particles are more readily detached from the  soil  surface because  they
are less cohesive, they will  also settle out of suspension more readily.
Clay particles and organic residues on the other hand, once  detached,  will
stay suspended for longer periods of time and will  be transported more
readily in slower  flowing water.  They are thus apt to be transported  for
greater distances, and a larger portion of them will leave the  field.  This
selective erosion  process can increase overall pollutant delivery, because
small particles have a much greater adsorption capacity  for  other pollutants
than do larger particles.

     The quantity and type of adsorbed pollutants in sediment  is  largely
determined by the  nature of the soil from which it  originates,  and the type
of erosion.  Rill and interrill erosion moves soil  particles from the  sur-
face (plow) layer  of the soil.  Gully and streambank erosion can  move  par-
ticles  that were part of the lower soil strata as well.   Topsoil  is  usually
richer  in nutrients and other chemicals than the subsoil  because  of  normal
nutrient cycling in the soil  profile and past fertilizer and pesticide ap-
plications.  Topsoil is also more likely to have a  greater percentage  of
organic matter.  Sediment originating from surface  soils thus  will have  a
higher  total chemical enrichment than sediment from gullies  or stream  banks.

     Sediment delivery can be reduced by either controlling  detachment or
transport.  Since  clay and organic matter are easily transported,  it may be
easier  to control these potential pollutants through practices  that  control
detachment.  Sands or coarse silt particles are very easily  detached,  thus

Animal  Wastes

     Manure is a source of organic matter, nutrients and pathogens.    Manure
applied on the soil surface will be more easily lost in  runoff than  manure
incorporated into  the soil.  As discussed in the sediment section, organic
matter  is not easily detached from the soil surface because  of its cohesive
properties, but it is easily transported because of its  low density.   There-
fore, practices which control detachment will probably be more effective in
reducing the loss  of organic matter than practices  which control  transport.

                                     17

-------
     Losses of manurial organic matter can also be reduced by controlling
the rate, location, and timing of applications.

     Although animal diseases may be transmitted to humans through contact
with animal feces, applied manure Is rarely a public health problem.  The
pathogens present in manure are filtered by soil particles and rarely infil-
trate farther than a few centimeters into the soil  profile.  Consequently,
fecal ground water contamination is usually not a problem following animal
waste application to soil.  Although erosion and runoff can detach manure
particles and transport them to streams and lakes,  the number of pathogenic
organisms reaching surface waters is generally limited and their survival
rate low.  Low soil moisture levels, low pH values, high temperatures, and
direct solar radiation can all  cause pathogenic populations to decrease
rapidly with time.  Manure storage facilities may represent an exception,
since the manure-slurry environment enables the survival of many organisms.
Composting of the wastes prior to application is normally quite effective in
decreasing the numbers of active pathogens in the material.

     Two aspects of animal waste disposal that have received special atten-
tion are problems related to runoff from barnyards, and winter spreading of
manure.  Both are suspected to be relatively concentrated sources of nutri-
ent loading to surface waters.  Barnyards are areas of intensive use by
livestock characterized by the absence of vegetative cover and the presence
of appreciable accumulations of manure.  Direct runoff through the barnyard
from upland drainage areas and direct precipitation on the barnyard will
detach and transport animal wastes from the disposal area.  The wastes con-
tain nutrients, and in addition, are characterized  by high biological oxygen
demand (BOD) and nitrogenous oxygen demand (NOD), thus if delivered to a
water body, will impact water quality.

     Spreading manure on frozen ground or snow cover can lead to relatively
high concentrations of nutrients during subsequent runoff events.  Such high
losses have been generally associated with critical periods such as spread-
ing on saturated ground after a rainfall, or on actively melting snow.

Salinity

     The accumulation of salts in agricultural soils is an undesirable con-
sequence of supplying the land with irrigation water needed to sustain or
enhance agricultural production.  Since irrigation water is generally de-
rived from ground water supplies or river sources,  it has a natural  (base)
load of dissolved salts.  As Irrigation water is consumed by the plants or
lost to the atmosphere via evaporation, salts (and other pollutants) remain
in the soil.  High salt concentrations are created within the soil profile,
especially in the root zone where most water removal occurs.  Salt crusts
may form on the soil surface between irrigation furrows or where the land is
left fallow, and accumulations of soluble and exchangeable sodium  lead to
soil dispersion and structure breakdown.   Increases in soil and water sal-
inity can be quite substantial, since  70 to 80 percent of the applied water
is lost through evapotranspiration.  Fortunately, a tripling or quadrupling
of the salt concentration of most irrigation waters still leaves soil solu-
tions which are not lethal to the growth of normal  crop plants.

                                     18

-------
     In order to maintain productivity in irrigated agriculture, accumulated
soil salts must be moved periodically below the root zone to prevent the
impairment of plant growth.  Therefore, the quantity of water diverted for
crop use must exceed actual plant water requirements to allow for the leach-
ing of these soluble salts.  Although this procedure promotes improved plant
growth, it also increases the environmental impact of irrigation by increas-
ing the transport of salts and mobile nutrients (e.g. nitrate) to receiving
waters.   As excess water percolates downward, its salt load is increased by
the leaching of natural salts arising from soil mineral weathering, atmos-
pheric deposition, or former marine or lacustrine (lake-deposited) sub-
strata.  If the quantity of leaching water is not excessive, some salts may
react with other ions in the soil and precipitate, lowering once more the
salt load of the percolating waters.

     Seepage losses from unlined delivery canals and laterals are high in
many irrigated areas.   The combination of these seepage losses and deep
percolation losses can cause groundwater levels to rise near the soil sur-
face (water logging).  Water and salts are supplied to the root zone by up-
ward movement of groundwater due to capillarity.  The water moves to the
soil surface and evaporates, leaving its salts behind.  This process can
result in extensive soil salination if allowed to operate for any apprec-
iable length of time.

     Irrigation return flows provide the vehicle for conveying accumulated
soil salts to receiving streams or groundwater reservoirs.  If the salt con-
centration of the return flow is small in comparison to total  river flow or
groundwater capacity, water quality may not be degraded to the extent that
use is impaired.  However, the process of withdrawing water for irrigation
and the return of saline water is frequently  repeated many times along the
course of a river.  Eventually, the salt concentration of the water can
become high enough to impair water use for irrigation or other purposes.

     Salinity control is complicated because  salts are present both in
receiving waters and in contributing soils, and also because control prac-
tices may interfere with crop production.  The quantity of irrigation water
should not be decreased without increasing the efficiency of application, if
the level of production is to be maintained.  Generally, salt problems from
irrigated agriculture can be most effectively dealt with by increasing the
efficiency of irrigation.

     In summary, consideration of the physical and chemical  characteristics
of  pollutants is the basis for the design of  control measures.  An effective
practice is one which prevents the delivery of a pollutant to a water body
by  controlling the availability of a pollutant in the field, its detachment,
or  its transport to a receiving body of water.  The extent to which a mea-
sure controls a pollutant pathway will often  be dependent on physical vari-
ables such as precipitation, soil type and topography.
                                      19

-------
                                  SECTION 3

                      NONPOINT SOURCE CONTROL PRACTICES


CRITERIA FOR GROUPING NONPOINT SOURCE CONTROLS

     The control of nonpoint source pollution ultimately involves the selec-
tion and design of practices on a site-specific basis.  Before this is done,
however, candidate practices must be identified and screened.  Candidate
BMPs are grouped in this section according to pathway control mechanisms and
practice permanence to serve as an aid in preliminary design stages.  Both
of these grouping criteria are compatible with NPS evaluation and analysis
methods described in Section 4.

Source and Pathway Control Mechanisms

     Pollutants may be controlled at their source or point where they become
available, during detachment, or during transport.  Source control of pollu-
tants, if practical, can be a very efficient form of control.  Source con-
trol is the management of a potential pollutant when placing it in the field
environment.  Crop nutrient and pesticide management practices are examples
of practical and efficient source controls.

     Control mechanisms which act during detachment and transport are also
effective in reducing pollutant delivery.  Practices which control the soil
eroision and sedimentation process will be effective in controlling pollu-
tants that are  strongly adsorbed to soil.  Practices which control overland
flow and subsurface flow will be effective in controlling weakly adsorbed
and non-adsorbed substances.  Examples of pathway control practices are con-
tour farming and conservation tillage.

Practice Permanence

     Given the  lack of water quality monitoring data, data quantifying
edge-of-field losses, and data quantifying losses between field and stream
or lake, controls considered should be conservative.   Nonstructural prac-
tices which are of relatively low cost to landowners and are related to
efficient use of farm resources should be given emphasis in the early stages
of NPS planning and implementation activities.  As the NPS program evolves,
land management practices which are more intensive and permanent may be
required.  This sequence of practice selection is analagous to the point
source control  program where treatment processes  have evolved over the past
sixty years from primary to secondary and tertiary treatment levels.
                                      20

-------
     Candidate measures can be grouped according to their degree of per-
manence into three types of practices:  management, vegetative, and struc-
tural.  Management practices involve changes in timing, chemical application
rates, and tillage systems.  They usually do not involve separate  field
activities.1  Crop rotations and area devoted to each crop remain  constant;
only certain farm management decisions are affected.  Vegetative practices
involve changes in cropping systems.  They generally must be renewed annual-
ly.  Structural practices necessitate capital investment and construction
activities.  The risks may be high because of this initial  investment.  Once
implemented, structural practices can affect farm production for substantial
periods of time.  However, they also assure more permanent pollution con-
trol.
CANDIDATE MEASURES FOR THE CONTROL OF NONPOINT AGRICULTURAL SOURCES

     Soil and water conservation practices (SWCPs) were originally designed
to conserve the land resource rather than to control water pollution.  They
represent candidate measures for the control  of agricultural  nonpoint source
pollutants, since losses of these pollutants are always associated with  soil
water movement or erosion.  There is a tendency to use SWCPs as best manage-
ment practices since these practices are already familiar to most farm oper-
ators and there is an established institutional framework.  This section
will include a discussion of 1) those SWCPs that double as potential water
quality  improvement practices, and ?) some additional measures which may be
used to  control agricultural nonpcint r.ource pollutants.

     The following discussion of candidate measures  has been divided into
two sections: those practices relevant to nonirrigated agriculture, and
those concerned with irrigated agriculture.  Although certain candidate
measures are applicable to both systems, irrigated agriculture has unique
pollutant control  options because water application  is controlled.  Many
candidate measures applicable to nonirrigated  agriculture are ineffective or
unnecessary on irrigated lands.  Practices discussed in the two sections are
grouped  according to the management, vegetative, and structural control  cat-
egories  related to practice permanence.  Within these categories, practices
are further grouped, although not explicitly,  according to affected pollu-
tant pathways.

NONIRRIGATED AGRICULTURE

     Precipitation quantity, intensity, and seasonal distribution are signi-
ficant determinants of pollutant loading.  Control or manipulation of these
factors  are not current options for farmers.    Wastewater collection and
treatment are also generally impractical due to the  diffuse nature of runoff
flows from nonirrigated fields.   Table 2 lists some general  candidate
control  measures for nonirrigated agriculture  according to the three cate-
gories:  management, vegetative, and structural.
^•Exceptions are split applications of fertilizers and pesticides.
2The exceptions are, livestock waste collection and storage systems.
                                     21

-------
             £
g
1 >> 1 01
i — (J 4- QJ 1/1
3 -r- l/> *f- I/I 1/1
O •— Q) 1, (D O
t/) O. l/> *r-
 "O i-
4-> 1- TJ TJ (J
TO Z) C T3 •—
I- C TO C Z) T3
§(O O Ol
i/> .c 4->
O 4-> C t/) TO
•»- t. c o a.
4-> o o; •*- (/)•!-
fO H- -r- 4-> C O
O i- TO O •'-
• — C Z> •<- 4-> C
CL+J -r- U
(O C T) 4-> •!- T3
ZJ QJ TO r- C
i- O N •— Q. TO

•r- TO TO C
r- 1- - QJ O
•r- */> QJ 4- -O •«-
+-> -O c: 4- -.- 4->
i- QJ -t— O O TO
QJ a> E c T- . —
H- C ZJ 4-> 3
r— 1- i/l Q.
r- Q.T- QJ O
tD O O "Q. Q.
r- 1_ (/I CT1
DO C • 4-»
1- *••- C W
QJ .C in JZ O •*»
E u c u T- ex

5 TO •r- i TO. c:
C_J E -M •— O O

o
4->

a>
E

4->
5
TD

'zi
o
JZ
(/t
in
o
4J
(O

^1
a.
CL

-t->
c
QJ

s_
13
c

CL.

1_
CJ


en
c
M- C
•r- C
i — fO

•*-> 'o.
u
01 C
in a>
c .c


s.
• o
a> 4-
ru -a
CL-4->
3 C
=3 I
CL O E

O  T
O- -r
in in t
a> a> •••
S- r— +

0 >> <
•u u t






(O

u
u
E
o
o

».
ai
n
fO
E
n
- **-

-» c
D O
•!->

3. i.
i- O
D Q-
1_
I) O
D U
C
J ••-

J r—

IJ O
X l/l




4-
O> O
t/}
 •*->
"O TO
u


•r- Q.
5 CL

C Ul
TO  at

at o
4- a.
i
i.
QJ
CL
OJ
•4-1

"O
c
TO
T3
C

J

S^
o

c
3
O
(J

TO
T3

O C
JZ O
V) •!-

I/I •!-
ai -o
•o c
•i- O
0 U

4-> QJ

a> zi
Q.-I-J

, 	

o
t/>
en
c

TO
OJ
s_
o
c


T3
C

T3
O
5^
CL

J
O

TO
4-

cn
c
Nl

E


f
i
i_)

4J QJ
QJ •,—
CL+J
U
"D (O
C t-
TO CL
at 
i- QJ

c
4-J


C S-
O O
<- CX
^> U
TO -r-
t_
O O)
CL t,
1- rt)
o

C QJ
••- -o
4-> i-
m "O O C
rt) • — \ +
QJ 3 "O i
i— O c: c
QJ "in" re +
-C QJ i
•*-> c; • — a
O -Q -+-
^ -r- Z» n
4-> 4-1 , — q
•«~ TO O '
J -o t/> c
TO
o; t- " o
"O CD -*-* J
•"— Ol C: -I
u -a QJ
•i— +j (
Ln 4_> ..- n
CLr- t.
QJ 3 CX 1
-C O" T
4-> - r
" QJ TO •>-
QJ 4-> t- 4-
i — TO OJ L
-O i C I


i/> O t
O 4- C -r
Cu >— • >
i — C
1- (T3 * 4-
ai i— T3
> 4-> Ctt -
at c oo r-
C OJ 3 -C

JT o aj -r
3: 0.-Q -C

J
j
D "O
1. 01
J TO
n Oi
U 5-
j U
3 C
U <~
5i QJ
>
» TO
: . -^
j >.
4J -C
U -^ tJ
3 TO -C
cr
n t/>
us- a>
3 QJ -f~
- 4J 4->
~ 3 r"
j * j.
1 QJ "O

V C1-
J cn O
- a) !-
<. TD ^
-> O <-n
4^ C
^1 "*~
- ,— -t-1
r TO c
ri r— TO
- 4_> i —
: c o.
QJ
Z)
-Q
QJ
*"

in
ai
in
 • -
a>
in
c

o
4-> -

OJ
U
TO

in

in i )
QJ . :




TO
E

4->
a.
o
4-*
TO -t-1

in Q
CL D
O
i_ 4-
<-> O
C •—
•!- U
•+-> >1
at
1- 4-

^3 f—
-n C
? o
C
t> T3
O)
°>!5
C j}

4-J I/I
C QJ

 QJ  O3
 >  U

 ££
 CL Q.
 E  Q.
                                                                     *.l
                                                                     -O +3
o -o  o
I_i— -r-
   tQJ •I-J
   r-  TO
                                                                                                       C 4->
                                                                                                       •i- in
                                                                                                       in at
                                                                                                                              TO 4->  in
                                                                                                                               i   in  a>
                                                                                                                              4J  r- -,-
                                                                                                                              o  1/1 4->
                                                                                                   fO  O
                                                                                                   -C.  t-
                                                                                                   U 4->
                                                                                                   QJ  c
•i-  a» •*->
 in  a> QJ
^33:
                                                                                 22

-------
t
^^




£•5
3 cr
•(-> V
X <-
i-o
"Q.
CT> D.
O) 3
p — in

i QJ C
in .5 C
in T
(O r-
t. r—
^'5.
m c
 (1)
•r- CO
o
X> 1-
o •*-»

c •
+j as .
V 0



CT>
c

CL
CL
O
L. i-
3 O"-
O
-P CL +
C 'f C
0 1- C
O -M C.
lO^-

ID

1
ro
•L.

(O •—


•— C
.c ro
CT O 
•(- -i- in
-d r- tO •
CL. QJ C
 C
r- 0 O
r- •«- L) >%
SS-oS
«k°^

•*-» fc- 3

QJ -C 3 C
O O •*—
Q. +J C
•o c o
4- d O •*-

S-
Q)
>
O
O
.M QJ
C >
QJ ••-
C •»->
m m
J 6 4J
r C QJ
3 QJ Ol
J CL, QJ
-> >

l£>

1
>> •*->
r— C Cn-D QJ
QJ QJ OJ C C ^C
4-> in JT T3 ••- «J -40
m « h- c i-
3 QJ QJ -C C
CT C • D- 4-> -M -r-
QJ O  t7> 2 
•o c a> ••- o QJ o
QJ 3 r- JZ 0

^ i— O 4J
O -4-> QJ -i- 4- T3 C
i_ «J -f- 4_) O C (13
+j ^ <+- o ro i —
C +•» tJ J= CL
O -M t- ^-> >»
 CU QJ O. O
Q «r~ T3 in ^ fO

& -M O -C X» O14J
t! *" ^ i5 Q.f^
ifl in CL4— O 13
in o >»+-> 3
m to QJ -t-> O"
+j i- ^ m -i— o>
C en in (j -C T3 ITJ
(D C OJ O •!-> C QJ
4-» " ro C i — *D L.
3 QJ U QJ QJ «  > m >^
r— i. tn -i- QJ 4-> T3
CLOQJO-C(TJ4Jin
(/i +-> QJ +J c in
4- i — 4- "O 
nJ l/>

r>-

1
Qi r^

i — in o
•r- -r- O,
u_
tn -t^ *o
in
fD "(/)
L U QJ
QJ 3
01 J 0
o o 
t- &-
CL QJ £
•D O
QJ S- C
> O 4-
Em t.
m TD QJ
QJ QJ +-»
4-> U_ 3
4-
o -o
•*-* C >.

i- i —
r^ Q. t-
-•--(- OJ -
•r- -M QJ 0



4-J QJ C
to I- o


QJ ,—
4- CTi fO
4- C L
30 n

 O
O 3 C

**/i 1^ t- C
QJ in O
QJ +-> 1- QJ •—
•^ 2* 0 § C
•*-> ••-> in o
U 4- C
QJ 4- O I -O
4- O U O C
4- C •— <0
QJ 3 X) f—
V C 10 W>
XJ TJ • —
C T3 •— O -r-

QJ CL^: >-,
CL +J r— O-
O "O +-> QJ
»— C J JZ QJ
in *o O ore

QJ T: •— •— c
x: c o m o
+J (O 4-
i— "D >>
QJ >> QJ r—
Ol QJ QJ "O C
C -C -C (D O
(tJ •*->•»-> W
.C Ol QJ
U 4- >> .—
O i— QJ -Q
O CL S^ ro •
-M U •«- QJ
in OJ U o Q.I —







in
QJ
U
(O
L
L


QJ 4-
•<- O
4-
-C
fO -4->
01
QJ C
O r~
-D
rO OJ
O.
c • —
•t- I/I
4->
m QJ
c >


t- U
L. OJ
O 4-
4-
4- QJ
4-
O CD
C .E
3 -M
S_
in
in C
S- +J T3
•^ j: -^
in
c
TJ
"O 1-
c o
ft}
c
in o
C -t-
o +-*
••- CL
m QJ
t. 'J
QJ '-
> QJ

O C


CD
CM
1
                        23

-------
                                                                                                                                                                                        4_ (— M-. r—
                                                                                                                                                                                        -(->  13 -M
                                                                                                                                                                                        *T3 f --  ITS r
                                                                                                                                                                                        U t—
                                                                                                                                                                                               §-r-  O M
                                                                                                                                                                                              -r-  D-M
                                                                                                                                                                                                    5-  nj
                                                                                                                                                                                                    O  -i-
                                                                                                                                                                                                    OJ  U
                                                                                                                                                                                         OJ  O  OJ  C OJ
                                                                                                                                             9/1
L.

-------
Management Controls

Reducing Excessive Chemical Application Rates (NIA-1)--

     If fertilizer is not a major production cost relative to other inputs,
it is often applied in excess to insure maximum yields.  Fertilizer rates
however, should be based more closely on crop needs, taking into account the
residual nitrogen content of the soil, past nitrogen additions (from
legumes, manures, and commercial fertilizer applications) and prior and
anticipated nitrogen removal (to crops, in deep percolation, through deni-
trification, or with eroding soil).  If all these components are considered
in a nutrient budget, a fair estimation of present nitrogen needs can be
made.  Manure and manure handling systems directly affect the nutrient (and
especially nitrogen) content of wastes, and therefore manurial nutrient con-
tent should be estimated before developing a land application schedule.

     Pesticide requirements vary from year to year, depending on climate,
insect and weed populations, and other factors.  Consequently, application
rates of pesticides may at times also exceed what is needed, particularly
for high value crops where financial losses can be large if pests are not
controlled.

Timing of Application (NIA-2)--

     Applying nutrients and pesticides at times when they are most needed by
the crop can be very effective in reducing pollutant losses.  Fall fertili-
zer applications of nitrogen can be completely leached below the crop root
zone before the growing season begins in areas of considerable winter pre-
cipitation.  Early spring applications can also result in appreciable losses
if heavy rainfall follows.  The availability of machinery and labor has a
marked influence on fertilizer application schedules.  Also, crop cover may
limit fertilizer applications during the growing season.   Fall applications,
where necessary, should utilize ammoniacal (NH^) nitrogen to minimize leach-
ing, and should be applied after the soil has cooled to less than approxi-
mately 50°F to prevent microbial conversion to the mobile nitrate formed
during warm fall weather.

     Pesticides should be applied to achieve maximum effectiveness and mini-
mum loss.  Insecticides, for example, are more effective at particular
stages of a pest's life cycle and applications can be timed accordingly.   In
areas where pesticides are used extensively, the timing of applications can
be linked to weather forecasting.  Critical periods when even extremely low
concentrations can influence fish spawning should be avoided.

Improved Method of Application (NIA-3)--

     The incorporation of manure and fertilizers in the soil reduces
losses.   Incorporation can control losses in surface runoff (especially for
early spring applications when rainfall events closely follow fertilizer
application).  Incorporation also makes nutrients more available to plants
                                    25

-------
and reduces volatilization losses by nitrogen, thus increasing the effi-
ciency of application.  The method of applying pesticides can also strongly
influence potential losses.  Pesticide losses through drift and volatiliza-
tion can occur with aerial applications of some pesticide formulations or
with certain types of spray equipment.

Improved Timing of Field Tillage Operations  (NIA-4)--

     The timing of tillage operations can markedly affect pollutant deli-
very.   If the soil is tilled soon after chemicals have been applied, the
quantities of those chemicals lost in surface runoff can be reduced.  While
those fields having a low sediment delivery potential  can continue to be
fall plowed, those with high sediment delivery potentials should probably be
plowed in the spring, or a form of reduced tillage considered where possi-
ble.

Using Alternative Pesticides (NIA-5)--

     The persistence, adsorption characteristics, toxicity, form, and method
of application all interact to determine the effect a pesticide will eventu-
ally have on water quality.  In general, persistent, soluble, and/or highly
toxic pesticides have the greatest potential to impact water quality.

     By alternating pesticides, the effectiveness of each application can
in some cases be increased, the amount needed reduced, and development of
resistance among the  insect or weed population minimized.  Biological con-
trol and integrated pest management programs (combinations of biological,
chemical, and cultivation control) have gained popularity in recent years.

Using Insect-and-Disease-Resistant Crop Varieties (NIA-6)--

     If a crop is more resistant to disease  and insects, it will require
less application of insecticides and herbicides.  Although yields may be
somewhat less for such varieties, the decrease in cost of chemicals may
compensate somewhat for the decreased production.  These resistant varieties
may be useful in combination with other practices, such as reduced tillage
or zero tillage, which might otherwise require additional pesticides.

Optimizing the Time of Planting (NIA-7)--

     Insect or disease damage can sometimes  be reduced, and/or pesticide
application rates decreased, if a crop is planted at the appropriate time.
The life cycle of the pest will determine appropriate planting dates in such
situations.  In some  cases, it is advantageous to plant the crop at the
earliest possible date.  This is generally true, for example, in dealing
with many of the plant diseases found in the nation's extensive winter wheat
crop.

Using Mechanical Weed Control Methods (NIA-8)

     Employing mechanical methods to control weeds will decrease the need
for herbicides, but labor and machinery costs will be increased.   In addi-

                                      26

-------
tion, these methods may damage soil structure.  Pulverization of the soil
can lead to decreased infiltration, increased erosion, and increased losses
of sediment and associated chemicals.  Creation of "tillage pans" due to
increased compaction can decrease crop root penetration and nutrient uptake
by crops.

Reduced Tillage Systems (NIA-9)--

     Conventional tillage can destroy intrinsic soil structure, decrease
infiltration, and increase surface runoff.  It also incorporates most crop
residues into the soil, leaving the surface exposed to raindrop impact and
to maximum runoff energy.  Reduced tillage systems include a spectrum of
practices, from conventional moldboard plowing with fewer land smoothing
operations to minimum soil disturbance.  The effectiveness of these prac-
tices does not depend as much on the tillage operations per se, but rather
on the amount of surface residue remaining on the field following tillage.
 The increase in surface residue reduces the loss of sediment, and hence the
loss of soil-associated nutrients and pesticides.  It also assists markedly
in wind erosion control.  The increased mulch and improved porosity of the
surface associated with reduced tillage, also significantly increases infil-
tration.  Deep percolation losses of nitrate and of mobile pesticides may
actually be increased by this practice in some cases.  Reduced tillage can
be used for most fields where crop seedbed preparation is needed.  Limiting
physical factors in the suitability of reduced tillage systems are climate
and soil drainage.  A higher variabilty in crop yield (and, thus higher  risk
to the farmer) can be expected than with conventionally tilled fields.

No Tillage systems (NIA-10) —

     No tillage (or zero-tillage) is most adaptable to well drained soils in
areas where the length of growing season is relatively long.  As with re-
duced tillage, no till is very effective in reducing surface runoff and con-
trolling soil erosion.  However, additional pesticide applications may be
needed to control weeds or insects which would not be needed with conven-
tional  or reduced tillage systems.  An even greater variability in crop
yield is evident for no-till planting than for forms of reduced tillage.

Contour Farming (NIA-11)

     Tillage and planting operations which follow hillside contours increase
surface storage and water, increase infiltration and decrease runoff, sedi-
ment, and total pollutant losses.  These practices are generally not imple-
mented on poorly drained soils, and are difficult to implement if the topo-
graphy includes complex slopes.  They have little effect on level land, on
slopes greater than 12%, or on slopes longer than 130 meters.  Intense
storms  may break across the contoured rows and greatly reduce the effec-
tiveness of contouring.  Contouring may also be more difficult when wide
equipment is employed.

     If tillage and planting operations are performed across the field slope
but not on the contour, it is sometimes referred to as graded rows.  The
slope of the grade is usually less than 1 percent.  The effects on water

                                     27

-------
conservation, soil erosion and control of pollutant pathways are similar to
contour farming.  Although graded rows would affect pollutant movement less
than contouring, where soil drainage is a problem this practice acts as a
compromise measure.

Vegetative Controls

Meadowless Rotations (NIA-12)--

     Crop rotations can be effective in reducing the need for pesticides,
since insect population cycles will be disrupted if host crops are elimin-
ated from the local area.  In particular, by employing a meadowless  rota-
tion, different high value row crops can be continuously grown in an area,
and certain insect pests controlled or eliminated as well.  For example, a
corn-soybean rotation is commonly used in areas of the midwest where corn
rootworm persists.  The rotation not only breaks the insect life cycle but
the nitrogen-fixing soybean decreases nitrogen requirements for the  subse-
quent corn crop.

Sod-Based Rotations (NIA-13)--

     Sod benefits the soil in many ways.  It improves soil structure, which
in turn increases infiltration and decreases surface runoff.  It can also
reduce the amount of fertilizer needed for following row crops because
grass-legume sods act as a source of nitrogen.

Winter Cover Crops (NIA-14)--

     Crops which cover a field during all or part of the nongrowing  season
influence pollutant loss in two ways.  First, increased crop cover and sur-
face residue decrease soil erosion by water and wind.  Second, a well estab-
lished winter cover crop can take up nutrients which would otherwise be
lossed via overland flow, erosion (from rainfall and snowmelt events) or
leaching.  The  main disadvantage of the practice is that the winter  cover
crop usually must be seeded in the early fall, amd plowed under or chemi-
cally killed in the spring.  This requires more labor, fuel, seeds and
chemicals for the overall farm operation.

Contour Strip Cropping  (NIA-15)--

     If greater effectiveness is needed than can be achieved by contour
cropping alone, alternating contour strips of row crops with strips  of sod
can  further  reduce soil  losses and associated pollutants.  This practice  is
particularly useful on  long slopes or in areas of particularly erosive rain-
fall.  In these situations, surface flow can accumulate enough energy to
render normal contours  ineffective.  By reducing the rate of surface flow
and  increasing  infiltration, soil detachment is decreased and surface stor-
age of water is increased.  In sod-covered areas, the soil is protected from
raindrop  impact,  so fewer  soil particles are detached from the surface.
Soil structure  is also  improved, and nitrogen is added to the soil if a
legume is included as part of the mixture.
                                      28

-------
Permanent Vegetative Cover  (NIA-16)--

     If the potential for pollutant loss from a particular field  is high and
there is no other cost-effective management practice available, it may be
necessary to leave the field grass-covered on a permanent basis.  This pro-
tects and stabilizes the soil, and decreases surface runoff and erosion.

Field Borders and Grass Filter Strips  (NIA-17)--

     If pollutants are not  being controlled adequately at the source, grass
strips can be placed at field edges.   These areas function as filters where
sediments and associated pollutants become trapped.  Potential pollutants
can then either decay, infiltrate the  soil and/or be taken up during plant
growth.  In order for the areas to be  effective, they must slow the rate of
run off sufficiently to allow some of  the sediment-borne pollutants to be
removed.  The effectiveness of a field border or grass filter is dependent
on the velocity and depth of flow entering the sod area, the topography, the
width, and the quantity and quality of plant cover in the grassed area.

Buffer Strips Along Streams (NIA-18)--

     Buffer stips along streams serve the same function as field borders,
but are generally farther from the source of pollution.  Again, the charac-
teristics of the buffer strip and of the runoff water passing over the buf-
fer strip determine the settling rate  of pollutants and hence, the effi-
ciency of the control practice.

Structural Controls

Terraces (NIA-19)--

     Terraces can be used to change the effective slope length of the land.
Most terraces are graded to facilitate runoff.  Runoff may be routed to
grassed waterways or to ponding areas where it can be discharged through a
tile system (PTO terraces).  Although  terraces do not significantly reduce
losses of mobile pollutants and may increase infiltratation somewhat, they
effectively reduce erosion  losses to less than 10 percent of losses incurred
with up-and-down hill fanning.  Terraces primarily reduce soil loss and
associated pollutants by decreasing runoff velocities.  Terraces  are gener-
ally appropriate on fairly deep soils and long slopes of less than 12 per-
cent.  Their initial cost is high.

Diversions and Interceptions Drains (NIA-20)--

     Runoff originating above a field  can often be diverted away  from that
field.  Such diversions shorten the effective slope length of the field,
decreasing soil detachment  caused by surface flow.  Any pollutant reaching a
diversion ditch, however, is also more likely to reach a stream.  Diversions
can be useful  for protecting fields that are highly erosive or that are par-
ticularly hazardous because of high chemical application rates.   Subsurface
diversions (interception drains) can prevent the movement of subsurface
flows.

                                     29

-------
Grassed Waterways (NIA-21)--

     Stabilizing channels with sod can greatly reduce the amount of erosion
occuring within the channels.  This practice is commonly used where channels
remove runoff from contoured or graded rows, or from terraced channels.

Subsurface Drainage (NIA-22)--

     The principal water quality benefit of subsurface drainage systems  is
increased soil water capacity.  By lowering the water table and increasing
percolation, lower antecedent moisture conditions can reduce runoff.   For
soils with low permeability, or during high intensity storm events, however,
the influence of tile drains on runoff is greatly diminished.

     For repeatedly wet soils, subsurface drainage may improve plant  growth,
which in turn may reduce surface runoff and erosion.  The net result,  how-
ever, may be an increase in nitrate losses from the area due to a  reduction
in denitrification associated with anaerobic conditions.

Detention Ponds (NIA-23)--

     Detention ponds collect runoff from agricultural fields.  They enable
sediments, and pollutants adsorbed to the sediments to settle out  of  solu-
tion.  Available phosphorus and nitrogen can then be taken up by aquatic
plants and non-persistent pesticides will have an opportunity to degrade
before the water is released.

IRRIGATED AGRICULTURE

     In arid regions, the timing and intensity of water applications  are
determined by the irrigation method.  Deep percolation and runoff  losses can
be reduced by controlling various aspects of the irrigation system.   Table
3 lists some of the measures that can be used to decrease pollutant loading
from irrigated fields.

     Many of the soil and water conservation practices for nonirrigated
agriculture listed in Table 2 are not compatible with irrigated agricul-
ture.  For example, grassed waterways are not utilized in arid regions
because of the water demand associated with them, and because of the  removal
of valuable irrigated land from production.

     Current legal and institutional mechanisms for allocating water  between
irrigation districts and farms are responsible for much of the inefficiency
of irrigation, and associated pollution.  Institutional changes should thus
be viewed as primary control mechanisms.  Most institutional controls, how-
ever, should generally be considered only relative to a longer planning  hor-
izon.
                                      30

-------
  _

§
CJ

o
LJ

S
o>       r-
                                                                                                                  °?
                                     CJ  C    -r- ••—
                                  c -r-  re
                                  •r-  l/>  O
                                  O  I/) •»-
                 CU i—

   u               u
   •r-           -O •*-
   E             QJ  c:         >  QJ c
   S^  O         O -C O
   c_j -r-         S_ (_) .1-

                                                                                 •i—    i—i  QJ  re
                                                       31

-------
c
o

4-J
ro
O) CD
N •!-
E i-

4J *~
O.4J
O C
01
O ••-
4-> (J

-0 «4-
Ol <+-
i- QJ

3 1-
CT O
OJ H-
s-
•a
O) C
.0 »f—
E >



r^ ^ -°

•i- 4-> m
4J -r- 0
C •!-
Q_.r- ^_
O) .— a.

0 oo ro

QJ
O 1
•r- I-
o at
-C CL
LJ O
OJ
4-> X) QJ



Q. CDi—
2.5 p
S.S,-


O
4->
C
s~
ai
rsj



4->
1-
O)
H-

Ol •
4->
rt3
1-
0
CL

a
o
c

o


O!
£><
i — C



at £













i/i
c
o
-M

-o -
T3 C i/i
QJ IQ at
4-> (0
(0 -0 to
.^S°
i. ZJ
i. ~o at
•F- at 10
en ai
X jc.
O • 4J
i i. */i
J- a* at
3 fcO u
M- i/J 3
C 1^"°

o *"~ t^
4_>
c c c
O Ol ra

4-> ••-
fcO (O -O 10
ai s- aj E
J to QJ to a*
O O to to
r— ,
at to vt
C CD (O
jo to 01 at
E -r- ,— (^ CD
3 4-> r- U (0


. O -i-
- a. ^: T3 4->
- TJ U C 1
D > m m o
rt Ol LU •— C
to
ai

QJ to
CD >^
ra I/)






QJ E T-
(J QJ |—
1 s.i
QJ

E >vt-»


**- ro o
^ QJ e
i+~ Of~
QJ4->.,-
•— O
L- (/>
QJ C
zi -i- cr
-D i- c

tO Q. C
OJ 3 T-
i«- IO ffl

r- tO C
0-r- -^
>- 10
4J QJ p
C1 CT>



C ••- 4-J
•r- 1 Cn
to o -r-
0 C i-
S- L.
O

c -o c
•r- QJ O1
1 U 3
^ cr
i- ~a QJ
o at i~
LL. i- «+-









































to












a>
c



•o



13
O
4-J
C
O
C-J
3
&

u






at
JD

T3

13
O
.c



c
o


(O
(J
o

m


4->
5
en
c
E
c

E




TJ
O


QJ
Q.



fO





01
>

00

u
X
a>

4-J
o
c
-a
1



a>
-o
u
0

c


QJ



O-

O
4->

-o
QJ

O

rO

e



o
c
c
c.

a.

•a
c


CD
d


=3
~TD
QJ
^:
u


s_
QJ


Ol
jQ

Ol
^->

•t^


U
<4-
scheduling

to
QJ


e

X

e

en
C


at
-o

O


QJ
4-J


•a
c:
i
OJ
-o

c
o
at
i/i
at
CD

S_

o

c




-C




QJ
>


O



^
-Q CTi
r- C
-Q -r-
•r- C
X C
QJ tJ
M- Q.
QJ
M






Ol
O

>

QJ


CT
C



-o
Ol

u


0

4->
CD

S-
«
1 moisture

o


-C
4->



C
o

4J



0

c




(J

u*
o

'o
1_
o
at
4->
at
E
to
c
o

4-1

cn


V-


a>
i_




4_)







O

00

Ol
>
at
c



»+-


C

at

0

4->

QJ
a.




0


t.
at
to

to

^
4->




O


4->

o>

1

5

0

^
 Oi  ra  i- 3 cn
 > £  ai     c
 o    a. x> -^
 i-  t,     c s-
 CL at F—  
-------
    (O  
 i/> 13  QJ •+->
 S C  *->  «>
 o ro  ^     "D   •
<—     ~o  cn  o>  QJ
r- cn QJ  c  cn i-
                           .."S
 (/) ,—
                   a
            en
          -  cn ,w  —
          •>  o ~o  QJ
 (/> I- •»-  O <4-
 O 4->  O     O TD
 CL c  ro  i/>     c
 QJ o  CL4-> i-  ro
-O O  ro  C -r-
        O  QJ ro  C:
4->         > CL O
r— ,— r—  QJ QJ •-
•i— O  ro  1- S-  (/»
 ui S-  c  CL     O
    •*-»  ro     QJ
4- C  O "O -C
 o o      c t—
    U  */>  ro
 QJ     C
 QJ I- •(-  C 
 s- QJ  ro  o QJ
4- 4-> 4-> -r- 1-
    ro  c +J ^
 i/> j -f-  ro 4->
r-     ro  s- u
 ro -o  E •»- ^
 c: QJ      ex s-
 ro >  c:  »/i -»->
 u o  o  c: w
    s- -i-  ro
 tr> Q. -•->  t- .—
 c E  ro +J o
.,_ .,- 40  O t_
 CL     QJ  CL4->
 QJ i-  cn ro c
 QJ O  QJ  > O
b^ 4-  >  QJ U
E   •
    c:
QJ  O
                                         QJ ro
                                         LO QJ
                                        ~i
                                        4-  -O
                                                    O  QJ
                                                       -O
                                                    QJ  QJ
                                                                                                QJ O
                                                                                                s- s-
                                                                                            ro  U) C  C
                                                                                                   O  O
                                                                                            en c •!- T-
                                                                                    y     ^)  O  QJ  •-
                                                                                            "D       1~
                                                                                    -o         ro "o  i-
                                                                                     C     "D  QJ  C *r-
                                                                                     ro     i—  crt ••-
                                                                                            QJ      S  C
                                                                                    t\J     -i-  cn
                                                               -  c' g  wi
                                                                 •i- O  ^-  >,
                                         ro t.     i—  -r-  wi
                                         1-3      i/> QJ 4-
                                         C.            E
                                         O Ul      U> -i~  C
                                         O t/>     i— -4-)  t-
                                                                                                       QJ
                                                                                            -C  QJ  QJ
                                                                                            u x: .c  >,
                                                                                            • r- 4-> *->  -Q
                                                                                            ^
                                                                                            S 4- -»->  c:
                                                                                                O  O  O
                                                                                            i/i      d>  -r-
                                                                                            CL 4-> *->  ^
                                                                                            O  1-  O  O
                                                                                            i_  ro  i-  *-
                                                                                            O  Ct  CL QJ
                                                                                                                             L^;  OJ
                                                                                                                             >  o  E  TJ
                                                                                                                             .  13 -r-  OJ
                                                                                                                             )  i/> -a  +->
                                                                                                                                   QJ  c
                                                                                                                             )  t/l  l/l  ro
                                                                                                                             •  a     f—
                                                                                                                               O  0  Q
                                                                                                                               cn 4-> X3
                                                                                                                                  u  c
                                                                                                                               QJ  QJ  ro  QJ
                                                                                                 .  r- ,_       (U     r- -r- r
                                                                                              T     4-1 JD QJ
                                                                                              - T3  -    34-
                                                                                              J C  C  O 4-
                                                                                              3 ro  O "O QJ
                                                                                                    "O
                                                                                              3i^       " C
                                                                                              i  -Q
                                                                                              • ro  ro  QJ
                                                                                              J 4-J  4-  5 ^
                                                                                              - O  •—  O   O
                                                   "O  C <—
 c  c: 4-»  c
 o  ro  c ••-
o  x:  QJ  ro
    o  E z:
                                                    i- cn i-
                                                    d ro  3
                                                    E c  4-»
                                                   -^ ro  QJ
                                                                                     O     4->  CL
                                                                                     1-     CO
                                                                                    <_>     -r-  ^
                                                          33

-------
 4-> t-
rB •>- E 0*

cr> u 4-» E
C QJ 3 0)
£ 4- ^ o
tO QJ O +•*
c a.
cn-c »r-


O V) > -r-
E a» i—
4- QJ J
4- 4-> o ai
O I- I fc.
C 0 0
i. (/) "D
>— 0)
4-> 4-* QJ L-
U ••- T- <0
a> 4-
i- ~a «/>
-o > i/>
C <0 4- t.
O X O OJ
•<- ro > •
t/) -C •- E
J- T3 4J -O ro
QJ •-•• C7> QJ
VI
E
ro



O Q-
•r- QJ
i/l U
S- L-
QJ QJ
•r- C
Q >-«
O
CSJ
^

i- E C
-O *-> -r-
S-  (0
S-
t- -o >>
ZJ QJ 4->
4- r- -r-
1- > E
0 dJ O
•4-1—4-
"0 I/) C
C -r- 3
CO
•— 4-> C •
•r- O -O
(U ••- Q>

O. CTi QJ
L. C (- 0
Q- O J- C
O 4->
4-> rO * O>
CTl QJ ^J
s'Els




ai
c


QJ
>
QJ
__»

•a
E
«O
_J
CM
X
> 4->
C O
O E
o o •
4-» a. c
S- QJ
SSJ
C T3
O S- QJ
CJ QJ CO
O I- "O


•a •»- o
QJ L.
01 (/) QJ
3 OJ
Q.4-
QJ O O
i-^ ^_
W C
C O
(0 (D ••-
U > 4J
«J -.-
rjl O W1
-^00.
OJ -O
> O
Q> +-* "O

• QJ '1—
o 0.4-
t/l O I
i — i — cr

















QJ
4- yi t- TJ 4J •

4-* ra 3 QJ "O
(/I E*rO O"OX)wiQJ
r— E CU ]C •*-> QJl — C^.C


(/l^1*- (/) C l/i '1— (/)«/> l-O
QJ i- 01 QJ co I-EOro
4->QJ QJ E i/l QJ 3QJ -i— C  QJ */>
(Q CL T3 r— LJ (/I > U) *o QJi/iQJ
i-t- t- C 1_"O QJt-QJ •!— 3
{J Q. QJ QJ QJ QJ Q_>c >!_.—


•i- i- t- »• .,- O-CD4-1 QJ T»
C>>4-> £ OJ  ^ -^* QJ >i— t-rtjj 1 	 • 	 r~
OJE C1*-*-1 T3 QJ *-»J S OJ'*-1*
P— roQJQJrO •— C'OO1'—
£ -Q J •• J3i/> tozjl-

QJU -r- ro 4— CT •(— 4~> t-OQJO i-*O
> Q.r— 4- E ro Z) •»— U 1- QJQJi/i
SO rOO C3E4-1  QJ
a. c i- —
O 3 O
C O i/> V
O rO 4->
•i- QJ QJ C
4J CT) E O
C ro t_J
QJ CL J
4-> QJ 0-0
QJ QJ t— C
a: t/i ii- /o
csj m ^f
OJ OJ OJ
34

-------
I
 C
0 Q. >> 0>


U
irt >>••- -0
•r- 1_ 3 C
O> O* *O
(U >

l3^ " °
o-o 2 t.
> 03
t. r- 4-
204-
O Of
»— -C 
.C
•O O>
IO 01 .C

C7> VI
C 3 O
.,- -r-j+J
vi -o
0)
£_>>.£ u
V)
*/»

£ 0)
t— v>


O) t-




2 O
O 4-J
4- •>
= C
CD O
C i/>
iii
o
V) S-

Q 4->
O
O
4J en
C
= o

(j 15
5 .
3 C
="-§
•<- C



0) *r-
(J

•o o

1- 4-»

-D E
C
IO VI
c .c
0 4->
IO (~
u at
•i- >


O- O
(O 31
4- •
O 4-
4-


O t-
•r- 4J
3 2

VI
l/l
O

U


C
ai

u

4-
«
0)
t-


^_

0)

.a
fO
o *
•r- O>
a. o
Q-r-
IO t/1
c
o
a>
JT "O
40 C
to
4-
O V)

V) 0)

I- t/)
3 >»

£ ^
4- U
O) 5
£ +->
W3
V)
ai -o
c c
•r- IO

1?
(J &-
s-
T3 3


l|
•r- Q.



0)

a.
3
O •



C ,—
IO •!-
"O IO
ai T—
r- tO
o >
i- tO
C 1-
O 0)
U 4-1
IO
>> 2
1o c
U IO
4J §


O C
+-> O
3

O) -f
-O 5








4-
0


£
3
fO
0>
4-
o!
C
f1"

o

o
-C

a>
E

1—
C
J




4-> Q c
t. CL
O 3
^ VI
VI


t-
•i- 1C
B c '
V) I/I ^
>» 3

>,
Ic
1- 3
5s-
4-
•o o
O 4-1 t
a. c c
E OJ -r
s

i
J

r ?-
i 4.
'


'








c
'


Oj 1
4V <
§t

-3 4
i. >
- 4)

j !B
D ia
- OJ
3 c
- ai
-• CL
E
4"


C







^f
W
4->
£


(J
ro
4-
o 
o
at s-
rjo at
4-> 4-1
4-
o

c
o


O 
£ S
A)
IO
(U

*O 4J O
t: c u
t) C

«,°u
•— 4- O
•^ 4-
< It3 S
S J- In
• — 13 >,
           5S,
                           35

-------
















































TJ
4V
C
3

fO
LU
s






























































4->
U
T3
a
£
4->
C
4-1
3
r—
o
a.


















c
o
4->
a.
t-
o
i/i
s









asure
QJ
^
QJ
4V
tJ
•i-
•o
C
re
o
•o
QJ
(/>
.c
4V
a.
o
o
CO
in
re
Ul
1/1
OJ
0.
s

QJ
Q.
<


1
>0 1-
4-> 4->
•r- QJ
*— t3 -Q
re QJ
3 i/> C
CT 3 re
U
-O QJ
O J3 i-
O QJ
Cn c +J
re 

Sin 4V fo
1- Cn
en o QJ ••-
O •*-* L.
QJ4V 5 i_
54V *'^
O QJ I-
U- C .C O



*-* QJ
E en
QJ O3
4-> C
S_ l/l T-
QJ >> re
-M l/> J_
re o
X OJ
- a E
m QJ 3
K- or a
r^.
OJ
i
<







i















*
4J
>,
H-S
5 c
^S
-o »
o •—
en o
in
4-
O QJ
,c
4-> 4->

c E
(/i p
*~ 4-
L.
aj -o
w^
S|
•o o,
c
^ en
o =
en QJ •
-Q T3
QJ QJ
J= I~ 4->
4V OJ
*»- M- i-
•— re 4->








i i






i i









i i
i i

i i


in o >> r-T
, — 4J 4V r— |
•i- -r- O ^^
O ~O E t. C 4->
in c C i -r- c
QJ O QJ t. QJ
CL 4- TD a.—
QJ QJ -r- -i- I/) O
QJ C C (/)••-
T3 O 13 4J **-
. . O) k|_
i — re > QJ i
QJ p -O T3 QJ
> TJ C 3 •.- t-
•r- QJ O. ,— r- O
•*-> -^ E O O E
re *i— ••— c tn
i— -O -r- QJ
QJ ^ « T3 t-
l_ -Q C C C C rt3
c re o o re
•o re •-- ••- in c
C M- 4-> 4J QJ E O
re-oM-re recS-r-
QJ O O en-.- 4J 4->
w ,— c -r- •«- i — tn re

Q. > S 'o. u i ui*-?
re QJ a. -r- o t.
U »— QJ re 4-t L- t.
W U 4- QJ -r-
•o QJ re c o "i —
C -O H- O 4-> .* QJ
^ C 3 +J § > -^ m
ra in re -M T- t- *4—
•MO en m o. CL i-
(O 4-> •!- >, t tO 13
• — tn c t- in i- tn
U- T3 QJ i- QJ .
r— > -i— I/) 4V l/> C
I- QJ QJ -i- C 1- re
O-r-I-V- -C QJ QJ _C
LL.4-Q.O 1— U^-4->
i-
0
(/)
a ^
o c
i- ••- C
i- m i- o
3 re QJ -.-
LJ_ OQ i— 4V
w f«
r- T3 C Cn
QJ QJ •(-•!-
QJ •*- Q. i-
	 I CT1 tO n
CO Cf>
C\J OJ
I i
 (/) *O
1/1 t_ C
Q> t! > ;i .
*3 re 0' re
o i wi
^ i _ s *" S •
-g*5 ° S0.
j- o'S "- B^
^SS | gg
•— C C • 43 4J Jn
QJ -r- re QJ m ^
"° ' — "~~ ^ i- i. to
Q. 3 Q .,_
"* -^ "M QJ 1 1 ,rt -
•r- 0. 0. 1^ S "^ ^
5|bi t ?«
ra +j^^ ^ ra?

m •*" O -Q i_ 4_> -
in: s r«
iCT; ° J9 Q> o QJ
^> ^ E u
l/l O •!— m U_ -n
r--M Z £ ^^
m re a. IT m
•r- 3 S- 0 3 -a
-c TJ QJ ^ S ^
•M -r- -O >> j^ ^ .^
j= £ o T 3 ° ^
5-5 ° re w S-f
•r C C QJ 4_ .£ ^
3 — '•- c »- TD 0
C C
0 S-
•M 4->
t> QJ
cr -o o;
I^ » (Q 14-
s- co
—• O 4-*
QJ 4-> QJ re
-^ QJ -M O in
0 r- « Q.»
•i- i — QJ in o
1- O 1- -r- I —
t^- (. ) t- r-i LI
o , —
rO m
i i

-------
                                                                                                         C  d>  C  HI
                                                                                                         O  i/l  O  VI
                                                                                                         O  Wl  U  */>
                                                                                                             O      O
                                                                                                         fO r—
                                                                                                         O i—

                                                                                                        r- Q.
  I 4->  QJ
  :  «3  t/i
  1  S  3


  i  O  C

  ]  I/)  fr-
  )  QJ  U
 :  1/1 cu
 -  QJ S_
    Q. Q
    t-  
 t. 4-> •«-

 CT> E  -o i-   •
                                     wi    >^
                                     QJ  QJ 3 r-
                                         C C 4->
                                     QJ         U
                                            -
                                     QJ
                                    C£.  r
^-  'Q  3  L
 iD  I/I     •*->
     U  -•->  C    -O
 1/1   o *—  QJ    '*~
 3  JT      C7) QJ  U
 S-   Q. c:  O T3 -^
 O   Wl  tt^  t- -I— 4->
-C   o  cn+J o  t/i
 cxx:  p  •- •«-  -•

 o

 CX  OJ
                                                                                                            -g     -
                                                                                                         QJ O  QJ
                                          37

-------
Management Controls

Reducing Excessive Chemical Application Rates (IA-1)--

     As discussed in the section on nonirrigated agriculture, tailoring
nutrient applications to crop nutrient needs can minimize nutrient loading
to streams.  Pesticide application rates should also match estimated needs
with due consideration given to economic risks and uncertainties.

Improved Timing of Chemical Application (IA-2)--

     Fertlllzer application should not be followed by excessive water appli-
cation.  This practice assures maximum nutrient uptake and minimum nutrient
losses via deep percolation and surface runoff.  Fertilization in fall or
winter should be  avoided if possible since large leaching losses of nitrate
can occur with winter rainfall.  Irrigation techniques, such as sprinkler or
trickle irrigation, are well suited to tailoring fertilizer applications to
crop needs, for they enable farmers to apply a mixture of fertilizer and
water throughout  the growing season.

Improved Method of Chemical Application (IA-3)--

     Refer to the nonirrigated section above for a discussion of incorpora-
tion (NIA-3).   Application through the sprinkler or trickle irrigation
lines offers considerable  promise in certain areas, though fertilization
rates must be modified from traditional levels, and better estimates of
localized salinity effects associated with such practices are needed.
Sprinkler-applied pesticides or fertilizers must not be applied excessively
to portions of the field where sprinkler patterns overlap, and must be
flushed from the  lines before the lines are allowed to drain as pressuriza-
tion eases at the end of the sprinkler operation.

Using Alternative Pesticides (IA-4)--

     Refer to nonirrigated section above (NIA-5).

Using Insect and  Disease-Resistant Crop Varieties (IA-5)--

     Besides using crops that are resistant to insects and diseases  (as dis-
cussed in the nonirrigated section), salt tolerant crops can also be grown.
This reduces the  need for  excessive water appliation to remove salts from
the root zone.  Total salt and nutrient losses  (both from subsurface and
surface flows) will thus be reduced, with only a slight decrease in produc-
tion if any.
Optimizing the  Time  of  Planting  (IA-6)--
     Time of  planting  is  often more  flexible  for  irrigated  than  for  nonirri-
 gated agriculture.   Early  planting of warm season crops in  cold  climates
 should  be avoided  if it results  in a long period  of near-dormancy, or  when
 added nutrients can  leach  and/or be  eroded from the unprotected  soil sur-
 face.   Refer  to the  nonirrigated section for  additional discussion  (NIA-7).

                                     38

-------
Using Mechanical Weed Control Methods  (IA-7)--

     Refer to the nonirrigated section above  (NIA-8).

Appropriate Timing and Choice of Tillage Operations, Reduced Tillage Systems
and No Tillage Systems (IA-8, IA-9, IA-10)--

     Proper cultural  practices are important if crops are to be grown suc-
cessfully in hot, dry regions.  This is especially true under  irrigated con-
ditions, where weed and insect pests proliferate.  To optimize both salinity
removal from the root zone and efficiency of irrigation applications, deep
tillage may be required to permit greater percolation, greater water storage
capacity, and deeper root penetration  into less permeable soil layers.  Til-
lage operations also incorporate surface-applied fertilizers into the soil^
reducing volatilization losses and making the fertilizer more  available for
plant uptake.  This process also tends to decrease nutrient leaching losses
by increasing the degree of contact between nutrients and the  soil.  Exces-
sive or unnecessary tillage, however,  can be detrimental to soil structure
(resulting in crusting, for example) and can increase evaporative losses at
times when crop moisture demand is high.

     Each tillage operation on furrow-irrigated fields increases sediment
losses, so decreased tillage of such fields is often desirable.  Reduced and
no tillage (zero tillage) systems decrease detachment of soil  by raindrop
impact and overland flow.  For wind erosion control they are required in
many irrigated areass.  The alternative, frequent early-season irrigations
to keep the soil surface moist, leads to excessive erosion and deep percola-
tion of nitrates.  Although surface residues are effective in  reducing ero-
sion from irrigated fields, some problems in controlling furrow flow rates
and in obtaining adequate uniformity of application may result f^om residue
accumulation in furrows.  Thus, the advantages of water conservation and
sediment control may be offset somewhat by decreased efficiency in irriga-
tion water application.

Contour Farming (IA-11)--

     Contouring is generally not applicable in irrigated areas, although
contour irrigation is frequently proposed in furrow-irrigated  areas with
steeply sloping fields.  Limitations with respect to field size, turn-around
areas, and compatibility with existing equipment, are even more stringent
for irrigated than for nonirrigated areas.  Refer to the nonirrigated sec-
tion for additional discussion (NIA-11).

Improved Water Management (IA-12)--

     The predominant form of surface irrigation in the western states is
furrow irrigation.  Historically, most irrigating was done on the basis of
fixed rotation or visual crop symptoms rather than by scheduling the irriga-
tion to meet predicted crop demands.  Where an ample supply Of water exist-
ed, many of these systems operated inefficiently.  Often farmers have used a
relatively small stream size in order to minimize visual  runoff losses.  As
                                     39

-------
a consequence, they induced relatively large deep percolation losses because
of nonuniform water application between head and tail  portions of the field.

     Uniformity of furrow irrigation is maximized when the "intake opportun-
ity time" at both ends of the field are equal.   Since water is conveyed from
the head end to the tail end of the field, equal intake opportunity times
along the furrow are not possible.  The least watered area of the field is
at the bottom end, so under existing management practices, the highest
attainable irrigation efficiency is achieved when the root zone in this area
is just refilled.

     There are two "operational" wastes which occur under furrow irriga-
tion.  The first is the water percolating below the root zone; the second is
the runoff from the lower end of the field.  Efforts to reduce one often
increase the other.  Salinity control practices which reduce deep percola-
tion, for example, will often cause high runoff to control one type of waste
without excessively increasing the other may thus require some system modi-
fication.

Call Period or On-Demand Watering Ordering  (IA-12)--

     To optimize crop production while minimizing water quality impact,
water allocation systems must provide sufficient, but not excessive,
quantities of water to farmers upon request.  Insufficient amounts reduce
crop production, whereas excessive amounts can  increase the water quality
impact of return flows.  The use of a call period, a minimum length of time
prior to the next irrigation during which an irrigator could place an order
for water with the canal operator, would improve water deliveries.  Call
periods allow for better scheduling by canal operators and encourage farmers
to carefully plan their irrigations.

     Although on-demand scheduling provides maximum flexibility of irriga-
tion scheduling, it encourages less planning of irrigation operations by the
grower.  Such scheduling is desirable when center-pivot irrigation systems
are established on irrigated lands designed for surface water deliveries.
Otherwise, unused irrigation water can rapidly  fill storage ponds and lead
to substantial erosion on its way to natural or artificial drainage ways.
This is particularly a problem because center pivot systems are normally
designed to begin and complete revolutions at a different time each day  (to
avoid systematic crop water stress patterns in  the field).  Ditch riders, on
the other hand, normally make thier rounds to increase or decrease farm unit
diversions at the same time each day.

Irrigation Scheduling  (IA-12b)--

     Irrigation scheduling is a well established practice.  Irrigation
scheduling services, both public and private, generally combine
meteorological data or evaporation pan information with soil moisture data
to forecast irrigation  requirements.   Both the  appropriate depth of water
application and the proper timing of the irrigations are estimated.
                                     40

-------
     Most commercial services also combine pesticide and fertilizer
recommendations with the irrigation schedule.   Increases in farm
productivity and reduced pollutant problems are benefits of the service.   In
addition, irrigation forcasts allow the farmer to more effectively schedule
farm duties.

Conveyance Channel  Maintenance (IA-13)--

     Improper canal maintenance causes wide fluctuations in water levels
along the canal length which make it more difficult for farmers to apply
water uniformly.  Uniformity of application,  as discussed previously, is  a
key factor in maximizing the benefits of applied  water and minimizing water
quality impacts.  Canals must be kept free of silt deposits and protected
from scour to permit free movement of irrigation  flows.  Aquatic vegetation
in and along canals needs to be controlled periodically to maintain canal
capacity, reduce unnecessary evapotranspiration losses, and prevent clogging
at control structures.  Canal banks, damaged  by burrowing rodents or breaks,
must be repaired to prevent excess erosion or seepage losses.   Structures
employed in canal systems must also be properly maintained against leakage,
settling or general wear.  Improper canal maintenance causes wide fluctua-
tions in water levels along the canal length  which make it more difficult
for farmers to apply water uniformly.

Improved Management of System Storage (IA-14)--

     Measures to improve system storage assist water managers  in timing
irrigations to decrease over-application.  Although system water storage
provides operational flexibility and more efficient water use, it should be
minimized to keep seepage and evaporation losses as small as possible.   If
water storage is needed throughout a river basin, water should be stored
only as high in the basin as practicable, so  that water surface area evapor-
ation losses are reduced and flexibility in diversions is increased.

Improved Management of Return Flows (IA-15)--

     Seasonally, many irrigation systems have a larger volume  of water
available than is necessary to adequately supply  crop demands.  Instead of
properly cutting back diversions at the river or reservoir in  such cases, it
is common to operate canals at capacity at all times with unneeded water
spilled into wasteways.  High flows between irrigations are especially true
for canals that are relatively long and have  slow response times.  This cus-
tom produces an unnecesary soil  erosion from  unlined canal  ways, and high
pollutant concentrations.

Land Retirement (IA-16)--

     A large part of irrigated pasture provides only small returns to pro-
ducers.  Most of this irrigated pasture land  is unsuitable for more inten-
sive crop production.  Retirement of this irrigated land from production
would appreciably improve water quality at a  relatively small  cost.
                                     41

-------
Vegetative Controls

Crop Rotations (IA-17)--

    Use of crop rotations permits the use of deep-rooted crops to  "scavenge"
residual soil nitrogen remaining from shallow-rooted crops of high nutrient
and water requirements.  Rotations also provide greater economic flexibility
when adopting management systems, permit control of many insects and  plant
pathogens, and permit periodic establishment of soil conditioning  or  salt-
tolerant crops in particular problems areas.  Refer to the nonirrigated  sec-
tion for additional discussion (NIA-12 and  13).

Winter  Cover Crops  (IA-18)--

     Although not traditionally  regarded as applicable to irrigated agricul-
ture, this practice is now used with increasing frequency in sandy areas
where winter and spring wind erosion is a serious problem for unprotected
soil, and during early-eseason furrow irrigation when excessive  erosion may
occur.  The cover crop may also  "scavenge"  nitrate which leached below the
root zone of sha 11ow-rooted crops the previous season.

Field Borders (IA-19)--

     Field borders  or filter strips are a common sediment-control  measure in
furrow-irrigated settings.  This practice is not well-suited to erosive
crops such as potatoes and close-grown crops such as alfalfa.  With erosive
crops,  the filter strip rapidly  becomes covered and ineffective, and  with
close-grown crops,  the fine sediment which may be eroded is not filtered by
the grassed strips.  Double and  triple-planted wheat has been used effec-
tively  as a filter  strip material for furrow-irrigated fields.  Refer to the
nonirrigated section for additional discussion (NIA-12 and 13).

Structural Controls

Diversions and Interceptor Drains  (IA-20)--

     Subsurface diversions by interceptor drains may be used to intercept
groundwater bearing substantial  loads of salinity or nitrates.  See non-
irrigated section for a discussion of these control practices (NIA-20).

Land Leveling (IA-21)--

     Land leveling  is commonly used to prepare land for furrow or  border
irrigation.  Irrigation uniformity can be increased when land is at a con-
stant grade.   This practice, however, can  have negative impacts on the
soil.   Calcium carbonate accumulations, for example may exist at relatively
shallow depths in the native soil, and distribution throughout the soil
would reduce its quality.
                                     42

-------
Retention Ponds (IA-22)--

     This control  practice is common throughout the irrigated west.  It
appears to be one of the most cost-effective practices for sediment control
in furrow-irrigated areas.   Refer to the nonirrigated section for addition-
al discussion (NIA-23).

Seepage Control (IA-23)--

     Many unlined canals, ditches, laterals, and watercourses traverse long
distances between  the point of diversion and the farm.  Where soils are well
structured and permeable, seepage losses may be considerable.  Tradition-
ally, canals with high seepage loss have been lined with a variety of alter-
native materials,  including concrete, asphalt, bentonite, compacted earth,
and plastic.  The  economic justification of such lining has been based on
the value of water saved.  Converting to a closed conduit of concrete,
asbestos-cement or plastic is a relatively costly yet an effective alterna-
tive that offers advantages of less friction, reduced evaporation, better
maintenance of pressure due to gravity, and improved aesthetics.  The salt
contribution from conveyance seepage often exceeds that leached from the
irrigated land, thus conveyance linings can frequently decrease salt loading
significantly.  Seepage water does pass through recently fertilized soil, so
its nitrate content is generally lower than that of percolation losses from
cropland.

Flow Measurement and Control  (IA-24)--

     Poor water management leads to application inefficiencies, which reduce
yields and/or impair water quality.  Under-application may lead to localized
salinity problems, whileover-application may cause excessive runoff of sedi-
ments and associated pollutants as well as leaching of salts and nitrates.
The purpose of flow measurement and control in irrigation systems is to
ensure an adequate application of water to croplands, while preventing un-
necessary and wasteful diversion which may result in poorer water quality.

     In order to control the flow of water in canals or ditches, structures
referred to as checks and drops are used.  These structures control the
slope and elevation of water surfaces.  They are also critical in dividing
water, as well as  distributing water to each field.  Other control struc-
tures include culverts and field inlet devices.

Optimizing Furrow  Advance Rate (IA-25)--

     The flow in surface furrows should be such that the advance time for
the field is about 25% of the total set time, assuming a uniform slope.  If
this practice is implemented and strictly adhered to, deep percolation
losses may be greatly reduced.   Flow rate and volume can be adjusted to
furrow slope and length to satisfy these criteria.

Cutback Irrigation (IA-25a)--

     With this method, the head ditch or delivery pipe is adjusted so that a

                                     43

-------
large "wetting" furrow stream is introduced to quickly advance the flow to
the end of the furrow.  The flow is then "cutback"  to a "soaking"  flow rate
in order to complete the irrigation.  Benefits of this practice include
increased uniformity of application, reductions in tailwater runoff, and low
labor costs.  This method is applicable, however, only if sufficient cross
slope is available.

Gated Pipe System  (IA-25b)--

     Gated pipe irrigation systems combine features of both the improved
furrow and the cutback systems.   The gated pipe system can in turn be
controlled by a time clock or a  master control panel.  When coupled with
on-demand water availability, irrigations can be scheduled according to crop
needs.  Length of set can be automatically controlled, so that uniform set
times are no longer required.  Stream size can be automatically cut back
when the stream reaches the end  of the field.
Multi-set Irrigation System (IA-25c)--
     The automatic multi-set irrigation system combines features of the
improved furrow system with a shorter length of run, by having several
lateral supply pipes across each irrigated field.   Irrigations can be
started automatically and can be scheduled to meet crop needs.  Length of
set can be automatically controlled, and the shorter length of run reduces
the period of furrow advance.  This in turn increases uniformity and
decreases deep percolation.  In addition, a shorter length of run allows for
the use of a smaller stream size, which reduces runoff.

Subsurface Drainage (IA-26)--

     Any expansive area upslope from existing irrigated lands may cause
waterlogging of downslope areas.  If the underlying strata are sufficiently
permeable, tile drainage is an effective means of lowering the water table
and facilitating salt movement from the root zone.  In addition,  tile
drainage allows for the collection of surface return flows into a master
drainage system for ease of control and/or treatment.

Pump Drainage (IA-27)--

     Pumps have also been used effectively for lowering the water table in
many areas.  If the water is not too saline, it can be reused directly, or
after mixing with surface water supplies by discharging the flow back into
laterals.  For good quality groundwater supplies, pumping serves the dual
purpose of alleviating waterlogging and providing additional  irrigation
water.  With poor quality supplies, however, disposal of the pumped water
may constitute a major problem.

Level Furrows or Diked Basins  (IA-28)--

     For flat landscapes and relatively deep soils, fields can be levelled
and diked at one end to prevent surface runoff, and to improve uniformity of


                                     44

-------
application.  With this system, irrigation efficiencies greater than 90%
have been achieved in some instances.

Sprinkler Irrigation (IA-29)--

     Sprinkler irrigation, if properly designed, installed and operated,
results in both water quantity and quality benefits.  Relatively uniform
water application is generally possible on various types of soils, thereby
minimizing deep percolation losses.  Little or no tailwater runoff
results, except when infiltration rates are exceeded on fine-textured
soils.  Sprinkler systems commonly used include side-roll, center-pivot,
tow-line and solid-set sprinklers.  The last two are frequently used in
orchards and vineyards.

     There are disadvantages to sprinkler systems, however:  (1) poor quality
irrigation water may cause salinity damage to crops and leave undesirable
deposits or coloring on leaves or fruit, (2) sprinkler-irrigated crops are
more susceptible to certain diseases, and (3) the high capital costs associ-
ated with the sprinkler and the fuel and/or energy costs to run the system
may make sprinkler irrigation economically impractical for certain crops.

Trickle Irrigation (IA-30)--

     The concept of trickle irrigation is to provide crop plants with near-
optimal soil mositure by conducting water directly to individual plants
through lines or emitters.  In widely spaced crops  (especially orchards),
losses are reduced because only a small portion of the soil  surface is
wetted and subject to evaporation.  Little water is lost via deep percola-
tion, since only the plant's root zone is supplied with water.  The only
irrigation return flow is associated with the occasional leaching necessary
to prevent excessive salt buildup in the root zone.  Because of continual
leaching of salts and nutrients to the periphery of the wetted area, nitrate
concentrations of these return flows can be exceptionally high.  There is no
surface runoff, and little water is consumed by weeds with this system.

     Trickle irrigation systems are easily automated, but they usually
require skilled technical assistance for estimating nutrient balances and
fertilizer applications.  Irrigation waters should be relatively high
quality.  Filtration and chlorination are often required to prevent clogging
of emitters.  Emitters are economically practical for widely spaced crops if
the average distance between emitters is more than 3 meters.  The capital
cost of trickle irrigation is relatively high.  Trickle irrigation systems
are particularly adaptable to perennial high valued crops, such as orchards
and vineyards.

Collection, Treatment and Disposal of Return Flows  (IA-31)--

     In many cases, subsurface and surface return flows from irrigated lands
may be so brackish that no further use of the water is possible.  Such flows
can be collected and either disposed of or treated before they enter receiv-
ing waters.  Reverse osmosis and electrodialysis are two desalination pro-
cesses that can be used to reduce salt concentrations in irrigation return

                                     45

-------
flows.  Major disposal alternatives include deep well injection and
evaporation ponds.  In general, the cost of collection, desalination and
brine disposal for salinity control exceeds the costs required to achieve
the same level of salt reduction through improved irrigation efficiencies.

Institutional Controls

Tax on Farm Inputs --

     Charging a farm operator in excess of the market price for fertilizer,
pesticide, or water would theoretically decrease the amount used by encour-
aging more efficient use.

Discharge Regulation --

     Since the amount of water, nutrients, and sediment leaving a farm in
surface flow can be monitored, it is possible to estimate pollutant dis-
charges.  Based on these estimates, loading limits can be established for
farms or irrigation districts.

Regulating Farm Inputs --

     Nutrient and water requirements for maximizing crop yields can be esti-
mated based on agronomic research and experience of local growers.   Irriga-
tion and fertilizer applications can be regulated to conform with agronomic-
ally sound recommendations.
                                     46

-------
                                  SECTION  4

                  METHODS FOR THE EVALUATION AND SELECTION
                  OF AGRICULTURAL NONPOINT SOURCE CONTROLS
     The selection of agricultural nonpoint source  (NFS) controls  involves  a
series of steps and calculations.  This section presents methods by which
nonpoint source controls can be evaluated.  Application of the methodology
to two case study watersheds is described in Section 5.

     The selection process presented  in this section involves an evaluation
of two basic factors: 1) NPS practice effectiveness  in controlling a  par-
ticular pollutant pathway, and 2)  farm costs associated with the practices.
The steps outlined in this section generally apply to all agricultural
systems.  The seven steps of the BMP  selection process are shown in Figure
5.
STEP 1:  DESCRIPTION OF WATERSHED

     In order to develop and evaluate NPS control strategies, physical,
hydro!ogic, and crop/livestock  information will  have to be compiled.
Physical data includes maps of  land use, topography and soils for the study
area.  Available hydrologic data,  including  rainfall,  runoff, and ground-
water records, should be located.  The types and extent of agricultural
enterprises in the area should  also be noted.  The technical appendices
document specific, data needs and collection  methods.
STEP  2:  PROBLEM  IDENTIFICATION

     The identification of impaired water uses and associated problem
pollutants, determination of the relative contribution from agricultural
nonpoint sources,  and calculation of the extent to which these  pollutants
should be controlled are of primary importance.  This information
establishes the basis for the implementation of control practices.  Although
methods for determining the existence of a pollution problem and the
necessary level of control are beyond the scope of this manual, the general
approach is briefly described below. 3

     Impaired water use provides the first indication of problem pollutants
and their sources.  Cause and effect relationship must then be  established
3The reader is referred to Chapra  (1980), Thomann and Segra  (1980), Di Toro
 (1979), Wineman et_ _al_. (1979), Heaney and Ammon  (1979).

                                     47

-------
               Figure 5.  Steps  of  the BMP evaluation process,
                     Step l: Description  of  Watershed
                                      I
                     Step 2:   Problem  Identification
                     Step 3: Determining Applicable Control  Measures
                                      I
Step
4:
Choosing
the
Unit
of
Analysis
                                      i
Step
5:
Establishing
the
Base
Condition
                                      I
Step
6:
Evaluating
the
Control
Measures
                                      I
                     Step 7- Developing an Optimal Control Strategy
between water  uses,  water quality indicators, and contributing pollutants
(Figure 6).  Water quality monitoring data is in all cases  required.   The
extent of monitoring will vary considerably with the availability of project
resources.  Proper design of  limited grab sampling programs  can yield
valuable data.

     The relative contribution of point and nonpoint sources to pollutant
loads above background  or natural  levels must be estimated.   If the
NPS load is small compared to the point source load, NPS  control may have
little impact  on water  quality.   If, however, the NPS  load  is  significant,
then the relative contribution of various nonpoint sources  must be
estimated.  In evaluating loads  from agriculture, a  'manageable1
agricultural load must  first  be determined; a manageable  load  is defined
here as the component of  total  agricultural  load.  If  the manageable
agricultural load is small relative to other nonpoint  sources  relative to
other nonpoint sources, controlling agricultural  NPS pollutants may not
                                      48

-------
Figure  6.   Water uses, water  quality  indicators,  and pollutants  involved
             in nonpoint pollution.
                                             IMPAIRED WATER USES
                                               Primary Contact Recreation
                                               Secondary  Contact  Recreation
                                               Wildlife and Aquatic Life
                                               Drinking Water Supply
                                               Agricultural Use
                                               Industrial Use
                             WATER QUALITY  INDICATORS
                                Human  Sickness
                                Algal Blooms
                                Turbidity
                                Fish  Kills
                                High  BOD
                                Low  Biological  Diversity
             POLLUTANTS
                  Sediment
                  Phosphorus
                  Nitrogen
                  Pesticides
                  Animal Wastes
                  Salts
                                         49

-------
improve water quality significantly.  Figure 7 shows the steps involved in
determining the controls necessary to meet water quality goals.

     Since the determination of a control strategy is ultimately based upon
an analysis of cost-effectiveness, in the early stages of planning
rudimentary cost comparisons of controlling the various possible pollutant
sources should be developed.  These comparisons will help determine which
sources should be treated first.
STEP 3:  DETERMINING APPLICABLE CONTROL MEASURES

     The process by which alternatives can be selected and evaluated, once
specific water quality problems have been identified, can be generalized for
all problem areas.  Four basic screening criteria are involved:

     1.   The practices chosen must have the potential to control the
pathway of the problem pollutant  . The primary pathway of nutrients  strongly
adsorbed to soil and sediment is  the soil erosion and sedimentation  process,
whereas the pathway of moderately and weakly adsorbed pollutants is  soil
erosion and overland flow.  The primary pathway of nonadsorbed pollutants  is
deep percolation and subsurface flow.  A practice which acts to control one
or more pollutant pathways is termed a candidate measure.  Candidate
measures can be ranked according  to their ability to control the primary
pathway(s) of the pollutant(s) of concern.  Figure 8 shows elements  involved
in agricultural  nonpoint source pollutant delivery; factors affecting
the three major pollutant pathways are indicated.

     2,   Candidate practices must be compatible with the farm management
system.  Candidate measures have  been classified in Section 3 as managerial,
vegetative, or structural controls.  These categories reflect differences  in
the permanence of practices;  managerial  and vegetative controls must be
renewed annually while structural controls generally involve a much  longer
time horizon and some capital investment.  The nature of water quality
management suggests the application and re-evaluation of progressively more
permanent measures.  There are two principal reasons for this approach:

          (a)  It is likely in the early stages of water quality
               management that specific nonpoint source contributions
               will not be precisely established.
          (b)  Many water quality problems are reversible processes
               providing the time for incremental practice application
               and evaluation of  resulting water quality improvements.

     3.   Candidate practices must be technically and economically  feasi-
bile in the area of study.  In most instances management controls will be
appropriate.  Certain structural  and vegetative measures may not be  suitable
because of topography, soil characteristics, climate, equipment limitations,
or marketing factors (see Table 4).  For example, contour farming (NIA-11)
is a widely used and effective soil erosion measure, but excessive  slope
lengths limit its effectiveness.  Contouring, in addition, is difficult to
implement on complex slopes or with certain large modern farm machinery.   If

                                     50

-------
Figure 7.   Steps involved in  determining  the  levels and types of  controls
             necessary to  meet  water  quality goals.
                                Water  Quality  Goals
                                        i
                             Pollution  Problems  Defined
       Water  Quality  Standards I	*f*"           1 Desired Beneficial Water Uses;


                          Load   Reduction  Needed  to  Meet
                              Water  Quality  Standards



                                       f

                                   Load  Estimates


                                         •


                      I

                 Point  Sources             ^"^   Non-point  Sources


i   Control  Costs   i—•»!           Non-agricultural         I    I Background  Load

                      T           	          T	
                Treatment Costs
                                          ^™"    Agricultural  Load

                                     Agricultural            I
                                     Base Load           ^

                                                 Manageable  Agricultural
                                                        Load

                                f  Control Costs     ""	*l
                                                         i
                                                   Treatment  Costs
                                          51

-------
TABLE 4.  DEGREE TO WHICH VARIOUS PHYSICAL VARIABLES LIMIT THE USE OF
          CANDIDATE MEASURES













CANDIDATE MEASURES





















Soil and Topography




























0)
ft
o
r-t
CO





















r^I
| 1
60
a
0)


a
ft
o
rH
CO



















en
0)
ft
o

CO

X
cu
r-H
ft
e
o
u




















en
rH
•H
o
to

*j
o
rH
,— (
cd
rC
CO













en
rH
•H
0
CO

13
0)
a
•H
cd
S-i
Q

K^
t-H
J-i
0
O
PX,


















r^
O
•H
4J
O
cd
ft
B
o
u

rH
•H
O
CO
Equipment
4-1
a
0)

ft
•H
3
cr
W


, — 1
3
0)
a)





03
'Ct
,—J
Q)
•H
p&4

rH
|— {
flj
s
CO

}H|
O


0)
rH
o
cd
4J
•H
3
CO

4J
O
2


u
o

K^
o
(3
OJ
-iH
O
•H 4-1
IM C
MH OJ
w s
ft
4J -H
ti 3
0) cr
a w
ft
•H &
3 a)
cr ss
W
tn
03 (1)
a) J-i
0 -H
3 3
ij cr
CD C1J

Managerial Controls
Improved method of application
NIA-3
Improved timing of field tillage
operations NIA-4
Optimizing time of planting NIA-7
Using mechanical weed control
methods NIA-8
Reduced tillage systems NIA-9
Contour farming NIA-11
Vegetative Controls
Sod based rotations NIA-13
Contour strip cropping NIA-15
Structural Controls
Terraces NIA-19
Diversions and interception drains
NIA-20
Grassed Waterways NIA-21


+

0
0

+
0
*

0
*

0

0
0


0

0
0

0
0
*

0
*

0

0
0


+

0
0

*
0
*

0
*

*

+
+


0

0
0

0
0
0

0
0

*

0
0


0

*
+

0
*
*

0
0

0

0
0


0

*
0

+
+
0

0
0

0

0
0


0

0
0

0
0
+

0
*

*/+

+
+


0

0
0

0
0
*

0
*

0

0
0


0

0
0

0
0
*

0
*

+

+
0


*

0
0

+
*
0

+
+

0

0
0
0 = Not limited;   + = Minor limitation;   * = Major limitation
                                    52

-------
   Figure 8.  Elements of  the agricultural  NFS pollutant delivery process.
   FACTORS
   AFFECTING
   AVAILABILITY
   OF  POLLUTANT
   AT  FIELD SITE
   POLLUTANT
   CATEGORIES
   POLLUTANT
   PATHWAYS
                           Land  Use
                        1 Material Inputs  i
                  , Management  ,
                  • Practices    '
                  i	,	j

| % ORGAN
i MATTER
Strongly
Adsorbed
1C ' _ ~n.. •*
__— 	 L SOIL pH
i 	 »-SOIL-« — ____ r~~ey~~rfXv~
i 	 1 % CLAY


Moderately 1
Adsorbed |
Weakly
Adsorbed

Non-
Adsorbed
SOIL EROSION
     AND
SEDIMENTATION
OVERLAND
FLOW  >
   FACTORS
   AFFECTING
   TRANSPORT
   IN  SOIL AND
   WATER
       Soil Erodibility
       Slope and Slope Length
       Rainfall Intensity and
         Distribution
       Vegetative Cover
       Irrigation
                              Topography         f- -


                              Distance to Water Body I— *•
LEACHING  AND
SUBSURFACE
FLOW
           Rainfall Intensity and
             Duration
           Soil Moisture
           Infiltration Rate
           Infiltration Capacity
           Vegetative  Cover
           Slope
                                                   •*—"1 Enrichment
                              •«	1 Concentration in Water
                                             | WATER  BODY |
poorly  drained  fields  are contoured,  surface drainage may be  even further
decreased.   Certain practices, such as terraces (NIA-19) may  not be
well-suited  for modern  farm equipment or  areas where  shallow  topsoil
overlays less permeable  subsoils.   Although  terrace design may  be modified
to  overcome  these limitations  in  some cases, additional  costs and risks
should  be noted.

      4.   Candidate measures must be screened according to their fundamental
socio-economic  feasibility.  It  should be emphasized  that the effectiveness
of  most NPS  controls and the economic impact of practices are strongly  in-
fluenced by  crop  rotations.  The  fact that certain crop  rotations exist  in a
                                         53

-------
particular area often reflect both long term and short term market adjust-
ments by farm operators.  Changing rotations or introducing new crops as a
control measure such that farm crop production is decreased should,  in most
cases, be discouraged.  Where these changes are technically necessary or
more profitable than a structural alternative, a comprehensive study of the
marketing implications should be undertaken.

     Using the four criteria discussed above, a list of candidate measures
can be assembled for a given watershed or sub-watershed.  This list  is the
end product of Step 4.  In Step 5 below, this list is screened further.

STEP 4:  CHOOSING THE UNIT OF ANALYSIS

     The watershed is a logical unit of analysis where pollutant  load esti-
mates and water quality data can be related.  Monitoring problem  pollutants
and evaluating candidate practices is very much simplified if the analytical
unit is a watershed rather than a political boundary.  However, none of the
analytical methods described in this section or the case studies  in  Section
5 require application to the total watershed.  All of the computational
methods used simply apply to a defined land area, not necessarily draining
to the same stream.

     A watershed can be divided Into subwatershed areas.  This allows com-
parisons to be made between subwatershed areas concerning the need for and
effect of Implementing nonpoint source control measures.  Program emphasis
can then be directed toward those areas where nonpoint source controls are
most efficient.

     Although a watershed is an appropriate unit of analysis with respect to
the evaluation of nonpoint source controls, there are some important limita-
tions.  First, soil groups, farms and even fields can overlap more than one
watershed.  Second, much of the soil and agricultural statistics  and data
needed to evaluate practices are not collected on a watershed basis.  These
limitations are discussed in Appendix F; they have, in part, been accounted
for in the following analyses.

     In evaluating NPS controls at the watershed level it is generally
assumed that controls do not affect the prices paid or received by farmers.
This assumption is not valid for large areas  (eg., corn belt) where  widely
adopted NPS controls would significantly reduce the market's supply  of com-
modities or farm inputs.
STEP  5:   ESTABLISHING THE  BASE  CONDITION

     The  choice of efficient  nonpoint  source  controls  requires  that  the
cost-effectiveness of candidate practices or  sets of candidate  practices  be
compared.   For the methods  presented  in this  manual, cost-effectiveness is
defined as  the change In farm income  compared to the change  in  delivered
pollutant load caused by practice  Implementation (Figure 9).
                                      54

-------
          Figure 9.  Steps  involved in determining cost-effectiveness.
BASE CONDITION
Estimate Pollutant
Delivery
Estimate Net
Income
POST-CONTROL CONDITION
Estimate Pollutant
Delivery
Estimate Net
Income
             Calculate  Difference
             Between Two Delivery Estimates
             (Change in Delivery)
        Calculate Difference
        Between Two Net Income  Estimates
        (Change hi  Net Income)
                             \           /
                           Calculate
Change in Net Income

Change in Pollutant Delivery
     To  determine the cost-effectiveness of a particular candidate measure,
the pollutant loading and farm  income before and after practice implementa-
tion must  be determined.  The present farm management system  and the assoc-
iated  pollutant load should serve  as  the basis for the comparison of alter-
native systems.   For example, if fall  plowing is the common practice in  the
watershed,  it should be considered as one of the base management practices.
Since  costs  and impacts of applying most BMPs will  vary widely  depending on
the productivity, slope and drainage  of soil, cost effectiveness must be
determined  for each important soil  or for groupings of similar  soils.

Calculating Pollutant Loading

     To  determine pollutant loading from a watershed, overland  and subsur-
face water  flows  and the soil loss for each soil group in the watershed  must
be approximated.   Conceptually, the movement of surface and subsurface water
from cropland to  streams can be described as follows:

                Uu + Ou  = Pu + Iu - Eu  + Bu + Du

Where:     Uu  = subsurface flow  (cm) during time interval t
          Ou  = overland flow (cm)
          Pu  = precipitation (cm)
          Iu  = irrigation application  (cm)
          Eu  = evapotranspiration  (cm)
          Bu  = change in surface storage  (cm)
          Du  = change in subsurface storage (cm)
                                      55

-------
     The amount of soil loss can be estimated using the universal soil loss
equation (USLE) or some modification of USLE:

          Au = RK(LS)CP

Where:    Au = soil  erosion (kg/ha) during time interval t
          R  = rainfall erosivity factor
          K  = soil  credibility
        (LS) = slope length factor
          P  = conservation practice factor

     A number of factors strongly influence the distribution and quantity of
the soil and water losses.  Soil drainage and hydrologic condition, precipi-
tation duration and intensity, soil credibility, slope and slope length,
field capacity, crop and cropping practices and conservation practices are
examples of these factors.   After water flows and soil loss have been esti-
mated, pollutant loading calculations can be made by assuming a level of
pollutant availability, of mixing with the soil and water components, and of
transport to a water course.   Appendices A, B and C include a more detailed
discussion of techniques which can be used to estimate  soil, water, and
related pollutant losses.

     As discussed in Section 2, pollutant availability and transport involve
complex processes.  For example, inorganic nitrogen (N) is made available
from soil  each year and the decay or mineralization of manurial  organic
matter of crop residues add to the pool of inorganic N.  In addition, the
actual concentration of inorganic N in a particular soil may change after
precipitation events,  as transformations take place between different forms
of N and as volatilization and denitrification losses occur.  A set of
particular crop, soil, and climatic conditions determine plowing, planting,
and emergence dates as well as fertilizer needs, crop uptake, and yield.
These conditions determine fallow periods, rate of canopy development,
amount of surface residue and, consequently, the availability of nutrients,
pesticides, and salts  for transport.

Pollutant Delivery --

     Pollutant delivery to streams can be defined as the fraction of a pol-
lutant leaving a defined area  (e.g., field) which actually  reaches a certain
point in the stream in the time interval under consideration.   In the case
of sediment, the delivery ration is given as the quantity of suspended
solids at the mouth of the watershed.  It is a function primarily of the
topographic and vegetative character of the terrain.  Where opportunities
for redeposition are greatest, the pollutant delivery ratios are lowest.

      In applying the concept of pollutant delivery to substances being
transported with overland or subsurface flows, the receiving stream must
first be defined.  A receiving watercourse can be defined as any channel
where concentrated flow is evident, even if  intermittent.   This  is a broader
definition than merely a stream where water quality is  monitored or where
the quality of water has a direct  impact on designated  water use.  Figure
10 illustrates examples of points that might be designated as receiving

                                      56

-------
watercourses.  Point A, at the mouth of the watershed,  represents  the  cumul
ative contribution of the entire drainage area from both overland  and  sub-
surface flow.  Point B designates a point where a  roadside  drainage  ditch
contributes intermittently to main stream flow.  Point  C is the  location
where overland flow from Field 1 drains into  a roadside ditch.   Point  D
represents direct field discharge, and Point  E represents discharge  across
an intervening land surface.  Overland flow leaving Field 2 near Point D,
has a greater opportunity for infiltration, ponding and redeposition of
suspended solids than does flow leaving Field 3 near  Point  E.
                                     INTERMITTENT
                                   ''STREAM
           BRANCH
          TRIBUTARY
              MONITORING
             STATION
                                                              ROAD
                                        MAIN
                                        TRIBUTARY
     Figure 10.   Examples of alternative points for the designation of a
                 receiving water course.
                                     57

-------
     In the case of subsurface flow, the definition of a receiving stream or
watercourse becomes more ambiguous.  Although much of the water infiltrating
soil may eventually reappear as surface flow, the pathway and time frame for
this process can vary greatly.  Infiltrating water can reappear as interflow
(Pathway A of Figure 11) or can percolate to the underground water table and
flow to a stream (Pathway B).  Some subsurface flow may percolate to
aquifers, as Pathway C in Figure 11, but only reach a water course after
considerable time.   The final form and quantity of highly soluble, conserva-
tive substances like chlorides are not significantly affected by the  partic-
ular pathway taken.  For substances that are either weakly retained by the
soil or that degrade over time, however, the length and transit time  of dif-
ferent pathways may affect actual pollutant delivery markedly.
                 Figure 11.   Pathways of subsurface flow.
                                      58

-------
Estimating the Cost of Practices

Perspective of Cost Estimates --

     Estimates of the cost of nonpoint source pollution controls differ
according to the perspective taken.  Control costs should Include instal-
lation, operation and maintenance expenditures.  From the farm operator's
perspective, control costs should also include reductions in farm income
resulting from farm investment in water pollution controls.  From society's
viewpoint, increased prices of agricultural products resulting from nonpoint
source controls, as well as costs of administering programs by public agen-
cies and changes in tax revenues, represent costs of improving water qual-
ity.  In all cases there are opportunity costs associated with alternative
investment options.  For example, water quality may be improved more per
unit of expenditure by investing in either point or non-agricultural non-
point source controls.  Likewise, a farm operator's income may be reduced
more with certain practices than with others, or the social  cost of in-
creased prices of agricultural commodities may be less desirable than the
increased product prices associated with point source controls.

     The level of analysis used for this manual does not incorporate
national, regional or other social cost perspectives.  It is assumed that
prices paid to farmers for agricultural commodities and paid by farmers for
goods and services do not change with implementation of nonpoint source
pollution controls.  All cost estimates generated with this methodology
include direct installation and maintenance costs, as well as estimated
changes in farm income.  By estimating farm income effects, practices which
are more likely to be accepted by farmers can be selected.  Cost estimation
is discussed in more detail in Appendix F.

Base Income Level --

     A base level of farm income must be established so that the relative
cost of candidate practices can be compared. Because the implementation of
nonpoint source control measures does not affect all aspects of a farm
enterprise, only certain returns and expenditures must be budgeted.  This
technique of partial budgeting can save both time and planning resources.
Appendix F describes these budgeting procedures in detail.

     The fixed and variable costs of production which are most affected by
practice implementation include machinery, irrigation, labor, pesticide, and
fertilizer costs.  These costs are quantified for the base condition for
each area studied since they vary from farm to farm as management practices
and machinery compliments vary.  Since each crop has different management
requirements, cost estimates are conveniently done on a crop basis.

     The base farm management system should be set up to achieve the maximum
level  of net income possible given the site conditions and current techno-
logy.  The base condition generally approximates profit maximizing farm
operations.  Losses of pollutants are estimated for this level of farm
income and farm activity in the watershed.  The relative changes that occur
from this base condition are then used to evaluate the cost-effectiveness of
control practices.
                                     59

-------
STEP 6:  EVALUATING CANDIDATE CONTROL MEASURES

     Qualitative evaluations do not enable one to compare and choose NPS
control measures which are best suited for a particular farming enterprise
or set of field conditions.  Some quantitative estimates of the effective-
ness and costs of the measures, therefore, are needed.  Analytical proce-
dures to predict sediment, nutrient and salt losses with implementation of
selected control practices have been developed and are described in this
manual.  It is difficult, however, to quantify pesticide losses because of
inherent characteristics of such chemicals.  The selection of candidate
measures for the control of pesticide losses has therefore been approached
qualitatively.  Persistence, toxicity, drift, and volatilization vary for
different pesticides and for varying soil, water, and wind conditions.  In
many cases, the quantity, destination and toxic effects of pesticide volati-
lization and drift are unknown.  Quantitive methods which may be used to
estimate pollutant loads include the Universal  Soil Loss Equation (USLE) for
sediment losses, SCS Curve Number for runoff leaching losses, and simulation
modelling for nutrient losses.  Partial  budgeting and linear programming are
used to estimate net income.  These methods are discussed below.
Sediment Loss From Non-Irrigated Fields

     Sediment loads to a stream can be estimated by calculating  gross  field
erosion and an appropriate sediment delivery ratio (SDR).  A common method
for estimating rill and inter-rill erosion is the Universal Soil Loss  Equa-
tion (USLE).  The USLE predicts, for a specific area, the average annual
rill and inter-rill soil erosion created by rainfall and associated runoff.
The land area being evaluated can consist of either a single field or  a
larger area.  The predictive accuracy of the USLE, however, decreases  for
slope lengths greater than 122 meters.  Details of the USLE and  how it can
be used to predict erosion and adsorbed pollutant losses are given in  Tech-
nical Report A.

Sediment Loss from Irrigated Areas

     Although irrigation practices are designed to result in greater control
over water use and movement, soil erosion and sedimentation are  evident  on
all furrow-irrigated lands.  Sprinkler irrigation systems can result in
localized runoff and erosion problems, such as when heavy application  occurs
near the periphery of center-pivot sprinkler systems of moderate to fine-
textured soils.  However,  such runoff generally accumulates in the same
field or in nearby depressions.

     Applications of the USLE in irrigated areas are limited.  One approach
for estimating sediment loss was developed by Gossett  (1975).  A base-level
combination of crop, irrigation, and  soil conditions is assumed, for which
sediment loss has been measured.  Other crop, irrigation, and soil condi-
tions are then treated as  adjustments, in the form of multipliers, to  the
base-level estimate.  This approach was used to predict erosion  for the
                                      60

-------
Yakima case study  in Section 5.  Computational methods  for estimating  sedi-
ment loss from irrigated cropland can be found in Appendix B.


Estimation of Runoff and Leaching Losses

     Runoff from non-irrigated cropland can be determined using a number  of
computational methods.  One method is the curve number  approach.  Soil
moisture is computed by quantifying all significant  inputs and outputs  of
water.  When a precipitation event occurs, water infilitrates into the  soil
until soil water capacity is exceeded.  The remaining rainfall is runoff  or
is temporarily stored  in surface depressions.  The partitioning of water
between surface and subsurface flows  is determined using the curve number,
an index reflecting the potential for runoff  as determined by soil hydro-
logic group, crop, soil management practices  and antecedent moisture condi-
tion.  This method is  described in Appendix A.

     Runoff from irrigated cropland can be predicted with greater accuracy
than non-irrigated cropland.  Water application, evapotranspiration and sur-
face return flow can be estimated directly.   The quantity of water which
percolates is usually  assumed to be the residual loss.  Runoff volume  can be
determined in a way similar, to sediment loss  in irrigated agriculture.  That
is, a base level of runoff is assumed and multipliers are used to account
for stream size, length of set, soil  type and field  slope.  Runoff estimates
for these different conditions can be found in Appendix B.

Nutrient and Salt  Losses from Non-Irrigated and Irrigated Croplands

     Once soil and water movement have been calcultated, nutrient and  salt
loading estimates  can  be made.  These calculations account for the availabi-
lity of different  forms of nitrogen (N) and phosphorus  (P) in the soil  pro-
file, equilibrium  concentrations of N and P either associated with the soil
or in solution, and changes in concentration  during  storm events.  Loading
estimates are typically made by multiplying average  or  flow dependent  con-
centrations by the calculated runoff  or leaching volume.  Detailed examples
of nutrient loss estimates are made in Section 5 and further details are
given in Appendices A, B and C.

Economic Evaluation of a Farm Enterprise

     Farm operations are generally made up of a number  of enterprises.
Cropping enterprises may include the  production of corn silage, corn grain
or winter wheat.   Livestock enterprises may include milk, beef or swine
production.  Each  of these enterprises has a  particular cost structure.
That is, all  crops have variable growing expenses (seed, fertilizer, equip-
ment), whereas building use, land cost, insurance and interest are fixed  for
a given farm and do not vary appreciably among crops or for a particular
year.  A livestock enterprise will have a different  set of variable and fix-
ed costs.  Bedding, breeding and veterinary charges are examples of variable
costs, and manure  disposal and feed storage are examples of relatively  fixed
expenditures for a typical livestock  operation.
                                      61

-------
     Implementation of nonpoint source pollutant controls changes the cost
structure of farm enterprises.  It may also reduce total production.  Calcu-
lation of farm Income changes thus involves an estimation of changes in cost
structure and total production.

     Changes in management and vegetative practices require little or no
capital in the form of construction or equipment.  Since all management
practices apply only to existing operations, minimal  direct costs of imple-
mentation, operation, or maintenance should be required.  Establishing
vegetative cover usually requires only tillage, growing, and harvesting
expenditures.  These expenses may be considered to be indirect costs of the
practice if they are associated with sod or grain grown in rotations as part
of existing crop enterprises.  Structural practices, on the other hand,
usually necessitate earthmoving and/or construction activities, which
involve installation, operation, and maintenance costs.

Programming Method

     Whether total or partial farm budgeting methods are used to estimate
the cost of nonpoint source pollutant controls, the many enterprise and
practice combinations can present a bewildering array of options.  Compu-
tational assistance is now available through a number of standardized pro-
gramming techniques.  One of the most common methods used is linear pro-
gramming (LP).  Linear Programming methods are particularly appropriate for
comparing agricultural investment decisions, since numerous combinations of
crops, tillage methods, fertilizer management and other activities may be
evaluated for each field.  This technique is discussed in detail in Appendix
F as well as illustrated in the examples of Section 5.
STEP 7:  DEVELOPING AN OPTIMAL CONTROL STRATEGY

     Calculating cost-effectiveness for each individual practice and combin-
ation of practices for each subwatershed unit is generally not feasible.
Time and analytical resources usually limit the number of options that can
be evaluated.  In order to insure the evaluation of a variety of realistic
control options, sets of practices can be assembled from those screened  in
Step 3.  Subjective judgment concerning the compatability of certain prac-
tices to farming conditions in the study watershed must be used to  reduce
the number of alternatives considered.  It is important to encourage the
consideration of a range of practices.  The grouping of practices in Table
2 into management, vegetative and structural controls illustrates the  range
that might be considered.

     The cost-effectiveness evaluation of these sets of practices for  dif-
ferent subwatersheds is the basis for developing an "optimal" NPS control
strategy.  There are a number of techniques which can be used to compare
practice sets.  Three techniques which can be used are: 1) the marginal
adjustment cost method, 2) additive optimization, and 3) the efficiency
frontier method.  They are discussed below and are demonstrated in  the case
studies presented in Section 5 and in the accompanying Technical Reports.
                                     62

-------
Marginal Adjustment Cost Method

     For a particular load reduction or level of pollutant load, the mar-
ginal cost to change or adjust farm activities can be estimated.  The
marginal cost (MC) is defined as the additional cost incurred by reducing
pollutant load one more unit.  For example, if the total cost of load reduc-
tion is $500 for x units but $510 for x + 1 units, the marginal cost at x +
1 units is $10.   Figure 12 illustrates this graphically.  Point A corres-
ponds to a pollutant load reduction of B and a change in farm income of C.
The slope of the curve at Point A is the marginal cost of control.  This
particular curve shows a constantly increasing MC; as pollutant loading is
restricted to lower and lower levels, cost increases at an increasing rate.
The average unit cost (OC/OB), defined as total change in farm  income divid-
ed by total  change in pollutant load, thus increases as pollutant loading is
reduced.
       Figure 12.  Marginal and average adjustment cost of pollutant
                   load adjustments.
            o
            I-
            o
                                                           o>
                                                           >
                                                           o
                                                           0.
                                                           o
                                                           w
                                                           O
                                                           Jt
                                                           o
                                                           o
                                                           CD
                      POLLUTANT LOAD  REDUCTION, APOLL
                                     63

-------
     Marginal adjustment costs  can  be  expected  to vary for different water-
sheds, subwatersheds and sequences  of  practice  treatment.   Consider Figure
13.  Marginal cost curves  have  been generated  (after screening practices to
determine those appropriate for the watershed)  for three sets of practices:
managerial  (M), vegetative (V)  and  structural  (S).  In order to optimize the
allocation of water pollution control  funds, each unit of pollutant
reduction should be achieved at  least  cost.  This is accomplished by
treating first those subwatersheds  with  the  lowest marginal  costs.  In Fig-
ure 13 these would be managerial  controls  in subwatersheds 1 and 4.
        Figure  13.   Marginal  cost curves for sets of practices on a
                    subwatershed basis.
                                                S: Structural
                                                V: Vegetative
                                                M: Management
                                      64

-------
     The cost-effectiveness of practices  also  depends  on  the desired level
of control.  Certain practices have large  initial  implementation  costs,  but
the unit control costs decrease  at higher  levels  of  pollutant reductions.-
If a relatively large pollutant  load reduction  is  needed,  these practices
can be more cost-effective than  practices  with  a  low initial  cost since
the average cost may be lower.

     The effectiveness of practices in an  area  may be  influenced  by other
factors such as precipitation.   For example,  in Figure 14,  practice "A"
(contouring) may be highly effective during  rainfalls  of  low intensity
whereas practice "B" (terracing)  is not as cost-effective.   However, a more
intense precipitation event may  show practice  "B"  more effective  than "A"
(other things being equal).
     Figure 14.  Relationship between cost-effectiveness  and  rainfall
                 intensity for two different practices.
                 o
                 o.
                 CO
                 CO
                 LO
                 z
                 UJ
                 o
                 ID
                 U_
                 U.
                 LU
                 CO
                 O
Practice A
                                             Practice B
                            RAINFALL INTENSITY
Additive Optimization Method

     The approach of determining  optimal  control  investments is best exem-
plified with respect to salt control  in  irrigated  areas.   The approach  is
demonstrated in the Grand  Valley  case study  of Appendix C.
                                      65

-------
     The steps involved in the additive optimization process are given in
Figure "15.  Alternative 1 is a particular set of practices applied to a
given subwatershed area.  Alternative strategy 2 is a set of practices
applied to another area.  Alternative 1 might involve canal levelling and
lining measures while alternative 2 might involve the application of on-farm
irrigation scheduling and changes in irrigation systems for a particular
irrigation district in the watershed.  Level 1 practices are specific
practices, while level 2 and 3 are combinations of practices.  The cost of
implementing alternatives at various levels of effectiveness are estimated.
The minimal cost of aggregate reductions in pollutant load can then be
determined as a combination of level 1 practices.  Subsequent load
reductions for levels of practice implementation are determined in the same
manner (levels 2, 3, and 4).  This procedure assumes independence between
practices and subwatershed units; it is assumed that the application of one
practice alternative in a given area does not change the cost or
effectiveness of other practice applications.

Efficiency Frontier Method

     The efficiency frontier technique involves plotting the minimal cost of
control associated with different levels of pollutant load reduction.  An
efficiency frontier is a locus of points drawn from the evaluation of alter-
native NPS controls.  The curve defines least costly practices at different
control levels.  A rough approximation can then be made of total pathway
control costs for a given level of load reduction.  The Yakima Valley case
study in Section 5 demonstrates the use of this technique.  Figure 16 shows
examples of cost-effectiveness functions.  Points A-E are alternative
control strategies; A might be contouring and strip cropping and B no-
tillage and reduced tillage on selected soils.  The efficiency frontiers can
be used to evaluate each control  strategy with respect to effectiveness in
reducing soil loss, overland flow, nitrogen loss, and phosphorus loss
simultaneously.  Efficiency frontiers result in an estimated cost for each
control level.  Curve BE in graph 1 of Figure 16 represents the most
cost-effective practices considered.  Whereas practice E is relatively
distant from the efficiency frontiers for controlling overland flow and
nitrogen loss, practice B is relatively effective at all phases of control.
Thus, for the pollutants and practices considered, practice B is the most
efficient control strategy for complete pathway control.  The simulation
modeling and linear programming methods presented in the case study
watersheds of Section 5 appear particularly well-suited to this evaluation
methpd.

     Although the proceeding sequence of data collection and evaluation
methods are suitable for all water pollutants, pesticides have peculiar
characteristics and therefore are treated separately.  Computational methods
for the estimation of pesticide losses exist, but are generally not as well-
established and to a large extent remain unvalidated.  The reader is
referred to Davidson (1975) and Bailey (1974) for examples of pesticide
evaluation methods.
                                     66

-------
Figure  15.   Steps  in the  additive  optimization process.
          Desired Level
          of Salinity ,
          Control     ;
ALTERNATIVE I  ,level 3

COST-EFFECTIVENESS
FUNCTION
                    LOAD REDUCTION
                             .'

           ALTERNATIVE  I  , ^vel 1
                                         alt.l.level 2 investments


                                          lt.2,  level 2 investments
                   /
                          Level  I
                           --Costs
            LOAD REDUCTION  (A Poll)
 Optimal Level  2
 Cost  from level 3
                                        ALTERNATIVE 2, level  2
              LOAD REDUCTION  (A Pol I)
        Optimal level  2
        Cost from  level  3
              *  LEVEL 1  COSTS ARE SPECIFIC  PRACTICE COSTS
                                 67

-------
         Figure  16.   Efficiency  frontiers  showing  costs  of  five  control
                     strategies  for  four different pollutants.
        A SOIL LOSS
AOVERLAND FLOW
A PHOSPHORUS LOSS   A NITROGEN LOSS
EVALUATION OF PESTICIDE CONTROLS

     Agricultural use of pesticides includes control of plant disease,
insects, mites, nematodes and weeds which damage crops.  Like crop nutri-
ents, residual amounts of pesticide can be transported from treated fields
to receiving streams in overland or subsurface flow.  Similarly, as in the
case of nutrients, a precise relationship between agricultural use of pesti-
cides and subsequent changes in water quality is difficult to establish.  It
is particularly difficult since thousands of registered pesticides are
used.  Also, in general, relatively small quantities are applied to cropland
making detection and monitoring impractical.  Toxicity, persistence, and
other chemical properties, in addition to soil adsorption, and solubility
interact to influence a pesticide's impact on water quality (Figure 17).
     The influence which these properties have on
transport is briefly described below.  Appendix E
Losses) provides additional details.

Grouping Pesticides
                          pesticide availability and
                          (Control of Pesticide
     In order to begin considering the control of pesticide losses from
cropland, it is necessary to systematically characterize the many chemical
compounds which are used to control crop pests.  Table 5 lists common
chemicals used to control major target pests.  Although general statements
                                     68

-------
can be made regarding the  behavior  of pesticides from a specific group, the
characteristics of an individual  pesticide  are  unique and properties of each
group will not necessarily  apply  to every  pesticide in that group.  In addi-
tion, some controls will be limited in  their  use.   For these reasons, the
individual properties of each  specific  pesticide to be controlled should be
evaluated, prior to initiating a  management program,  in order to insure that
the management practice that  is  selected  is best suited to control the
existing or potential problems.
         Figure 17.   Factors affecting the transport and water Quality
                     impact of a pesticide.
           toxicity
       persistence
     soil adsorption
          solubility
     other chemical
        properties
                            drift
PESTICIDE
                           GROUND WATER
                           (receiving water)
                                       LAKE
                                       (receiving water)
Persistence

     One important characteristic  of a  pesticide is its persistence.  One
definition of persistence is  that  period of time necessary for the complete
degradation of the material  into harmless products.  Since the primary mode
of degradation is generally  biochemical,  factors which reduce biological
activity decrease the  rate of degradation.   These factors include low soil
moisture, oxygen content,  temperature and organic matter content, and ex-
treme pH (Figure 18).   The relative  influence of each factor depends on the
specific pesticide and the site  conditions.
                                      69

-------
                            [DEGRADATION PROCESS^>
                   PH
                                                       Matter
                                               i          i
                                               i Temperature i
                                               I          i
                                               i	J
                                  |  Oxygen   J
                                  i  Content   i
                                  I	J
             Figure 18.  Factors affecting pesticide persistence.
     Strongly adsorbed pesticides are relatively  immobile  in the  soil  pro-
file.  The attenuation of pesticides by  soil  particles  allows  for degrada-
tion and dissipation of  its toxicity.  Strong adsorption of  pesticides to
soil particles will generally keep  pesticides close  to  the surface where
they were applied.  The  soil surface is  the area  of  greatest biological  ac-
tivity and therefore pesticide degradation  rates  are likely  to be greater.


     Organochlorines are, in general, some  of the most  persistent pesti-
cides.  Organophosphates, carbamates and most herbicides are more easily
degraded.  The triazine  herbicides  are degraded mainly  by  chemical  action
but can persist for substantially longer periods  of  time.   Table  6 lists the
half-lives of some common pesticides.  Half-life  is  defined  as the amount of
time required for 50% of the original material to disappear.   For
approximately 94% of the material to degrade,  it  would  take  four  times as
long.  Half-lives vary under different biological, chemical  and physical
conditions.  For example, a microorganism population  may adapt to the  pres-
ence of a certain pesticide, thus causing an  increase in the degradation
rate and a decrease in the pesticide half-life.   This phenomenon  of adapta-
tion can increase the need for multiple  applications.
                                      70

-------
TABLE 5.  SELECTED GROUPS OF INSECTICIDES. MITICIDES AND FUNGICIDES
INSECTICIDES AND MITICIDES
     Organochlorines
 Chemical Compounds
      Trade Name
     Organophosphates
     Carbamates



     Farmamidines

     Organotins

FUNGICIDES

     Inorganic

     Organic
DDT

Cyclodienes


Polychloroterpenes

Phosphonodithioates
Phosphonothioates
Phosphorothioates


Phosphorodithioates
Coppers

Dithiocarbamates
Phthalimides
Other
Methoxychlor
Chiorobenzilate
Eudosulfan
Chlordane
Aldrin, Dieldrin
Toxaphene

Fonofos, Terbufos
EPN
Parathion, Methyl
Parathion, Diazinon
Dursban, Demeton
Ma lathion,
Azinphosmethyl
Dimethoate, Phofate
Disulfoton
Methomy1

Carbofuran
Carburyl
Aldicarb

Chlorodimeform

Cyhexatin
Copper sulfate

Maneb, Ferbam
Captan, Difolatan
Benomyl, Chlorothalonil
                                     71

-------
 TABLE 6.  HALF-LIVES OF SOME COMMONLY USED PESTICIDES	

 Pesticide                                      Approximate Half-Life (Weeks)

 Lead, arsenic, copper, mercury                          500 - 1500

 Dieldrin                                                100 -  200

 Triazine herbicides                     •                 50 -  100

 Benzoic acid herbicides                                  10 -   50

 Urea herbicides                                          15 -   40

 2,4-d; 2,4,5-t, herbicides                                5 -   20

 Organophosphate insecticides                              1 -   10

 Carbamate insecticides                                    1 -    5
Toxicity

     Pesticides often are toxic to non-target organisms as well as target
organisms.  The quantitites of pesticides reaching the nontarget area, the
likelihood (or risk) of exposure of organisms, and the sensitivity of the
organism coming into contact with the pesticide must be considered.  The
impact on specific organisms must be seen within the context of their posi-
tion within a food web.  Although a pesticide may be only moderately toxic
to a fish species, high toxicity to organisms serving as fish foods may have
an equally detrimental effect on the fish populations.  The dose-response
impact of a pesticide must also be seen within the context of environmental
conditions normally encountered by the test organism.  Temperature extremes,
nutrient levels and unusual pH may all render an individual pesticide more
or less toxic to the test organism.  Such synergistic toxic effects are
possibly the rule rather than the exception in nature.  These effects, how-
ever, are poorly understood and extremely difficult to define since the
possible combinations of environmental conditions are practically  infinite.

Solubility, Adsorption and Transport Characteristics

     Solubility is also an important characteristic of a pesticide.  Certain
pesticides are fat soluble while others are water soluble.  Most organophos-
phates, for example, have low fat solubility.  Pesticides which are fat
soluble, such as some organochlorines, become concentrated in the  fatty
tissues of organisms, often in higher concentrations than present  in the
surrounding environment.  Animals which are higher in the food chain are
more likely to accumulate pesticides because fat soluble compounds tend to
concentrate at higher levels in a food chain.  This process of biomagnifica-
tion can cause severe problems of survival for a species.
                                      72

-------
     Pesticides move from agricultural fields or dumping areas to streams
and lakes by drift, volatilization, in the surface flow (suspended or dis-
solved), attached to eroding sediment, and dissolved in subsurface flow.
Accidental spills or dumping of excess chemicals into surface waters also
contribute substantially to pesticide levels in the water.

     The quantity of pesticide lost by drift is dependent on the method of
application; small liquid drop or dust applications increase losses whereas
granular applications tend to decrease losses.  Climatic conditions at the
time of application are also important; high winds tend to disperse pesti-
cide molecules rapidly.  Volatilization depends on certain physical and
chemical properties of the pesticide  (i.e., vapor pressure, water solubil-
ity, adsorption coefficient), and on the moisture content and temperature of
the soil.  Volatile pesticides are frequently regarded as more desirable
since they infiltrate soil pores more eaasily, and thus more effectively
reach the target pest.  However, from the viewpoint of total environmental
quality, volatile pesticides may present a greater environmental  risk.
Volatilization increases pesticide loading to the atmosphere and the possi-
bility of eventual redeposition to streams and lakes.  In addition, the loss
of pesticides by the volatilization process can be considered an economic
loss since the farmer is paying for chemicals which do not end up in the
target area.  It has been estimated that half of the pesticides applied to
field crops enter the atmosphere through vaporization from plant and soil
surfaces.

     Soil incorporation, cover crop,  high clay and organic matter content,
and deep plant penetration reduce volatilization.  However, the rate of
degradation of a pesticide may be decreased (the persistence increased) if
the applied chemical  is incorporated into the soil.

     Surface and subsurface losses are determined by the adsorption and
solubility properties of the pesticides, the characteristics of the site,
and the timing, mode, placement, and  rate of chemical application.  Many of
these factors can be manipulated to reduce the impact that the agricultural
usage of pesticides has on water quality.

     Pesticide mobility is determined in part by various factors which
encourage soil adsorption.  Soil adsorption tends to increase under higher
soil moisture content and lower ph.   In general, herbicides tend to have
lower adsorption coefficients than insecticides or fungicides, although
pesticide solubility varies considerably within groups.

     The adsorption characteristics of the pesticide determine the mode of
transport.  Soluble and weakly adsorbed pesticides usually percolate down-
ward through the soil profile.  Although this is the most common pathway for
these pesticides, intense rainfall, steep topography or saturated soil con-
ditions may cause them to be lost via runoff flow.  Moderately adsorbed
pesticides are primarily transported  in surface flow but are also lost with
eroded sediment.  Very strongly adsorbed pesticides like trifluralin and
toxaphene are transported primarily on eroded sediment.  Appendix E
describes adsorption characteristics  of a number of commonly used insecti-
cides.

                                      73

-------
     The method of application affects pesticide transport processes and
thus pesticide losses.  Applying a moderately adsorbed pesticide on the soil
surface as opposed to below the surface increases the potential for loss.
In contrast, soluble pesticides are more likely to be leached if they are
incorporated into the soil surface.  The timing of an application is also
important; chemicals applied shortly before precipitation events have a
greater potential for loss.
FACTORS INFLUENCING SUCCESSFUL IMPLEMENTATION OF NPS CONTROL PRACTICES

Social Costs and Benefits

     The impetus for the implementation of measures to prevent or reduce
water pollution lies ultimately with the public.  It is through public input
that legal  measures such as effluent standards, effluent taxes, and
subsidies are instituted.  These measures are the result of a cost-benefit
analysis, in which social costs associated with implementation and with any
decreases in production, and social benefits resulting from improved water
quality have been weighed.  Appendix F discusses these trade-offs and
describes in greater detail alternative agricultural pollution control
policies.

Farm Profit Maximization

     Cost effectiveness analyses have typically assumed that the farm
manager is maximizing short-run profits (MSRP).  He adopts a particular
control practice or set of practices based upon the immediate opportunity
cost (i.e., the perceived value of how the money could be used elsewhere) of
abatement.   That is, the MSRP approach assumes the decision to adopt and
implement various control practices is made on the basis of their short-run
profitability.  At any level of abatement, other things being equal, the
efficient practice, from the farmer's standpoint is that which impacts
profit least.

     The MSRP approach does oversimplify the producer's decision of adoption
or nonadoption by relying solely upon a static concept of production
efficiency.  It is clear that not all farms adjust to and adopt new
technology or environmental controls equivalently.  Such considerations as
financial structure of the farm, managerial objectives and capacity, farm
size, legal organization of the farm, tax treatment, and ability to bear
risk may figure prominently in the actual control practices adopted and
the speed of adoption.

     The fact that a producer's net worth, disposable income, time horizon
and other single factors affecting decision-making are oversimplifications
has led to attempts to quantify investment decisions using what have been
called multi-variable methods.  For example, Carter and Cocks  (1975) devel-
oped a model which included both short term and long-term objectives.  The
seven objectives included:
                                     74

-------
     1.   Maximization of the present value of future consumption.
     2.   Maximization of the present value of future profits, where
          profits are withdrawn each period.
     3.   Maximization of the present value of future profits, where
          profits are reinvested each period.
     4.   Maximization of the discounted cash flow rate of return.
     5.   Maximization of the present value of future cash flow.
     6.   Maximization of terminal net worth.
     7.   Selection of the most preferred point on an efficient locus
          showing present consumption versus terminal net worth.

Different results were found for all seven goals leading Carter and Cocks to
conclude that the choice of goals is critical in modeling farm behavior,
i.e. farmer decision-making.  This they found to be particularly true of a
consumption net worth tradeoff goal.

     Choosing the appropriate objective or criteria will influence the
cost-effectiveness ranking of practices.  For a single watershed, the size,
financial structure, and investment options may be reasonably similar for
all farms.  However, when this is not the case, the variation in decision
criteria should be recognized if implementation efforts are to be success-
ful.  The economic implications of choosing a particular criteria are dis-
cussed in detail in Appendix F.

Farm Characteristics

     Farm investment decisions are often Influenced by tax laws.  These laws
bias investment decisions depending on the objectives of the  farm operator.
Three common strategies taken by farm operators include:

     1.   Reduction of actual  out-of-pocket costs,
     2.   Deferment of income taxes,
     3.   Conversion of ordinary income to capital gain.

     Farm size can also be an important factor influencing tax strategy and
the types of NPS controls farmers are likely to invest in.  Capital inten-
sive controls may be more appealing to large farms with tight labor con-
straints while labor intensive practices may be more appealing to small
farms.   In addition, a weak equity position may discourage both large and
small farms from investing in capital intensive controls.  Figure 19
illustrates factors affecting farmer adoption of BMP's.

Risk and Uncertainty

     Individual producers will exhibit widely varying perceptions of the
risk associated with different control practices.  Changes in technology,
legal and institutional structure of farm services, yield and price varia-
tions can all  influence the profitability over time.

     The extent to which tax strategy, farm size, and risk preference can be
incorporated into NPS control  program are not clear.   Appendix F discusses
these factors in detail.

                                     75

-------
             Figure  19.   Factors  affecting  the  adoption  of a  BMP.
Equity
Position
Tax
Laws
Labor
Intensive
                                   DECISION
                                     TO
                                  ADOPT BMP
Cost-Sharing Incentives

     One common method of encouraging the implementation of NPS controls is
through subsidy payments.  This system has been used for some time in con-
trolling soil erosion.  These payments usually share in the cost of practice
construction or installation with the farmer expected to bear the full cost
of maintenance.

     Cost-sharing formulas can be designed to account for some of the fac-
tors which influence the successful implementation of NPS controls.  For
example, cost-sharing arrangements directly affect decision criteria such
as short-run profits, net worth and debt/equity ratio.  In addition, factors
such as farm size, tax strategy and risk/uncertainty preference can be
strongly influenced by different cost-sharing formulas.  Despite opportuni-
ties for using cost-sharing as a means to account for different financial
preferences of farmers, little has been done in the past to incorporate
these preferences into subsidy payments for practices.  Generally, cost-
sharing percentages have been uniform for all farms with strong bias toward
capital investments.  In addition, cost-sharing formulas are always based on
installation and maintenance cost and not changes in income.  An obvious
advantage with such cost-sharing rules is the small cost of administration
and practice monitoring.  The principle disadvantage is that the cost-shar-
ing program may elicit adoption patterns not commensurate with the problems
to be solved.
                                      76

-------
     Perhaps the major limitations to current cost-sharing criteria are that
they generally exclude management practices.  As demonstrated in Section V,
these types of practices are often the most cost-efficient NPS agricultural
controls.  Therefore, limiting cost-sharing to structural controls can only
lead to an inefficient water quality program.

     A complete discussion of the advantages and disadvantages of alterna-
tive cost-sharing programs can be found in Appendix F.
SUMMARY

     The options available to water quality planners are numerous.  The con-
trol practices described in Section 3 are general categories; many vari-
ations are possible.  Cost-effectiveness, suitability, and likelihood of
practice acceptance are extremely important considerations in control
strategy selection.  The nature of water quality mangement and the limita-
tions of data availability suggest an incremental program where practices
are implemented, their effects are monitored, and then practices are refined
over time.  This approach is consistent with water quality goals for a num-
ber of reasons, two of which are:

     1.   Many water quality problems are reversible processes.
     2.   The complex interaction of physical and biological processes
          in the transport of pollutants in space and time limit our
          knowledge of the cause-effect relationship between practice
          implementation and changes in water quality.

     The steps outlined in this section are a logical progression of prac-
tice screening, evaluation, and selection for a particular watershed.  Many
of these steps will require field work or contact with water quality mana-
gers who have access to estimates of loading concentrations and soil,topo-
graphic, and farm data.  In addition, the analytical techniques, simulation
modeling, and linear programming described later in this manual may require
assistance from specialists.  This forced interdependence between groups
working to improve water quality underscores the comprehensive and complex
nature of the task.
                                     77

-------
                                  SECTION 5

             EXAMPLES OF THE AGRICULTURAL NPS SELECTION PROCESS
PURPOSE OF CASE STUDIES

     This section demonstrates the methodology presented in Section 4.  The
areas selected are from both non-irrigated and irrigated agricultural
regions.  Entire watersheds, sub-watershed areas and farms were modelled.
In each case combinations of control practices were evaluated with  respect
to total pollutant load reduction and associated control costs.

     Different control strategies were developed for each case.  Although
the techniques used to optimize levels of pollutant control and select
treatment areas differed somewhat for each case study, the objective of the
practice evaluations was to develop cost-effectiveness curves, as outlined
in Section 4.
CASE STUDY I:  HONEYCREEK, OHIO

Description of Watershed  (Step 1)

     The Honeycreek Watershed is within the Sandusky River Basin,  located  in
north central Ohio (Figure 20).  The watershed 'drains into Lake  Erie.
Considerable interest has been expressed in the watershed because  of the
deterioration of water quality in Lake Erie over the past few decades.

     The Honeycreek watershed comprises 47,144 hectares of which over 80%
are cropped.  Because of  this intensive agricultural use and due to its
soils, Honeycreek can be considered representative of the glaciated, once
forested areas of the cornbelt.  Honeycreek soils are generally  of fine
texture with somewhat poor natural  drainage on slopes of less than 3%  (see
Table 7).  The distinctive soils and topography of the watershed are   a
result of glacial activity, and include areas of glacial drift,  outwash,
ground and end moraines,  in addition to lacustrine sediments, flood plain
alluvium and organic sediments.  As shown in  Figure 20, the watershed can be
subdivided into  four sub-watershed areas (A,  B, C, D) based primarily  on
these physiographic characteristics.  Subwatershed A is composed primarily
of glacial drift and dissected ground moraine while the soils in B are
derived from ground moraine (dissected and undissected) with glacial outwash
terraces.  Much  of the soils in subwatershed  C are ground moraine
(undissected) and flood plain alluvium.  Subwatershed D is primarily ground
moraine (dissected) and end moraine.  The watershed has been subdivided  into
18 distinctive sub-areas.  Table 8 lists land use and physical
characteristics  for each  of the four main subwatersheds (A-D).
                                      78

-------
                     Figure 20.   Honey Creek watershed.
Problem Identification (Step 2)

     Agricultural land uses In Honeycreek and other watersheds draining Into
Lake Erie contribute organic matter, nutrients and sediment.  The water
quality problem most often cited in Lake Erie is the excessive growth of
algae which has been attributed primarily to phosphorus loading.  The annual
production of algae in Lake Erie has increased twenty-fold in sixty years
(Honeycreek Report, 1979).  Algae growth can interfere with recreational
uses of the water when it occurs near shore areas and can deplete dissolved
oxygen supplies.  In addition to these nutrient enrichment problems, sedi-
mentation of navigable channels in the lake results in significant public
expenditures for dredging.

     Although there has been considerable study of the water quality of Lake
Erie, the precise relationship between nutrient enrichment of the lake and
agricultural runoff and sedimentation has not been determined.  Thus speci-
fic target load reductions from watersheds including Honeycreek have not
been established.  For this case study analysis, a wide range of pollutant
load reductions are evaluated.
                                     79

-------
   TABLE 7.   SOIL AND TILLAGE GROUP  DESIGNATION  OF  HONEY  CREEK  SOILS

Soil
Group
1
2
3
4
5
6
7
Soils in
Group
Bono
Lorain
Luray
Chagrin
Papakating
Lenawee
Millsdale
Belmore
Haney
Digby
Belmore-
Morley
Marengo
Toledo
Wallkill
Shoals
Pewamo
Pewamo-Urban
Gallman
Hennepin-Ale .
Haskins
Mi 1 ton
Tillage
Group
4
5
4
1
1
2
1
                        Condit
9

10

Carding ton
Glynwood
Bennlngton
Blount
Mori ey
Ri tchey
Tiro

1

2


 Source:   Becker andForster (1978) .
* Tillage Group 1  -- naturally well-drained soils where yield is expected
 to be equal  to or greater than conventional  moldboard plowing.
  Tillage Group 2  -- response equal  to or greater than conventional
 when surface or subsurface drained.
  Tillage Group 3  -- poor internal  drainage is not improved by artificial
 drainage measures so significant yield decreases are expected with  reduced
 tillage systems.
	Tillage Group 4  -- these soils may yield less with no-till  practices
 even when surface or subsurface drained.  Unlike group two these soils
 have a high organic matter content which will decrease the yield varia-
 tion between extremely wet f> dry years as compared to the expected
 yield variation usiny a conventional plowing system.

  Tillage Group 5  -- includes organic soils,  recent alluvium strip mined
 land and certain  fine textured soils.  Experience with changes  in tillage
 practice has not  been sufficiently documented to determine the general
 response by these soils to no-tillage.
                                80

-------
TABLE 8.  SOIL AND LAND USE CHARACTERISTICS, HONEYCREEK WATERSHED

                                SUBWATERSHED
Land Use
Row Crops
Field Crops
Other Agr.
Forested
Other

Slope
Categories
0-2%
2.1-4%
4%+

Soil Drainage
Well & Mod.
Well
Somewhat
Poor
Poor & Very
Poor
Not Available

A
HA* (%)**
2964
2080
124
864
428
6460
4336
1104
1020
6460
1560
3968
732
200
6468
45.9
32.2
7.9
13.4
6.6
100.0
67.1
17.1
15.8
100.0
24.2
61.4
11.3
3.1
100.0
B
HA* (%)**
6044
3556
52
1372
676
11700
8512
2100
1088
11700
1820
7660
1924
296
11700
51.7
30.4
.5
11.6
5.8
100.0
72.7
18.0
9.3
100.0
15.6
65.5
16.4
2.5
100.0
C
HA* (%)**
9668
5420
124
1992
1352
18556
15360
2448
748
18556
848
12732
4632
344
18556
52.1
29.2
.7
10.7
7.3
100.0
82.8
13.2
4.0
100.0
4.6
68.5
25.0
1.9
100.0
D
HA* (%)**
4880
3516
72
852
1104
10424
8236
1556
632
10424
1348
4204
4648
224
10424
46.8
33.7
.7
8.2
10.6
100.0
79.1
15.0
5.9
100.0
12.9
40.3
44.6
2.2
100.0
*(HA) = Hectares
**(%) = Percent of Subwatershed
                                   81

-------
Determining Applicable Control Measures (Step 3)

     The management, vegetative, and structural control measures  listed  in
Section 3 were screened to identify measures which would be appropriate  for
the designated problem, and compatible with the soil and crop/livestock
systems of the watershed.

     Any measure that affects phosphorus movement is a possible candidate
measure since phosphorus has been identified as a limiting nutrient  in algae
production in the lake.  Both soluble and adsorbed forms of phosphorus are
known to contribute to the pollution problem.  Because in-stream  and  lake
transformations of phosphorus are difficult to trace or predict,  the  rela-
tive contribution from soluble and adsorbed forms and any equilibrium rela-
tionship between the two forms have not been determined.  Therefore,  both
overland flow and soil  erosion/sedimentation pathway controls were evalu-
ated.  The effect of control practices on substances leached from the root
zone is also reported because the control  of overland flow may contribute to
excessive leaching of non-adsorbed nitrate nitrogen.

     Poor drainage of many Honeycreek soils limits the application of a
number of the candidate measures listed in Section 3.  Some of the practices
which are of limited potential use in the watershed are listed below;
limitations are discussed.

Improved Timing of Field Tillage Operations (NIA-4)4--

     Many of the heavier soils in Honeycreek are fall plowed because  it
allows winter freeze-thaw cycles to help break up the soil and improve early
spring drainage.  In fact this fall  plowing may be accompanied by a  network
of "dead furrows" which can increase surface drainage.

Using Mechanical Weed Control Methods (NIA-8) --

     Most of the farming in the watershed is cash cropping with a distinct
trend to larger units  (Venice Township, 1976).  Since these types of  opera-
tions have a high opportunity cost for labor, herbicide treatment of weeds
is used.

Reduced Tillage (NIA-9) and No Tillage Systems (NIA-10) --

     Yield responses to reduced tillage are strongly influenced by soil
drainage, degree of tillage, and mulch cover.  Poorly drained soils  in
colder climates tend to decrease no tillage yields as compared with yields
obtained using coventional moldboard plowing.  A number of soils  in
Honeycreek would probably not respond well to no-tillage practices.   Table 8
groups Honeycreek soils according to expected tillage responses (Triplett et
al.  1973).
     Table  2 for description of practices.

                                      82

-------
Contour Farming (NIA-11) and Contour Strip Cropping (NIA-15) --

     Although contouring is possible on most soils in the watershed, it
tends to aggravate drainage problems where they exist.  Also the complex
slopes in many areas of the watershed make contouring difficult and decrease
the efficiency of field operations.

Sod-Based Rotations (NIA-13), Permanent Vegetative Cover (NIA-16),  Field
Borders (NIA-17) and Buffer Strips  (NIA-18) --

     Because cattle and dairy operations in the watershed are of minor
importance, the uses and markets for hay crops are limited.  In addition,
the trend has been to increase corn relative to hay in most feed rations
which further decreases the need for hay.

Terraces (NIA-19) --

     Both complex topography and poor soil  drainage discourage the use of
terraces.

Choosing The Unit of Analysis (Step 4)

     The Honeycreek watershed has been conveniently divided into four
physiographic regions.  These areas are independent drainage units, thus
water quality management can focus  on each sub-watershed.  The following
study analyses effects of applying  control practices to both the entire
watershed and to each sub-watershed area.  The objective in choosing these
areas is to demonstrate the difference between uniform and non-uniform
levels of control within the watershed (see Appendix F).

     The unit of analysis could be  broken down even further to the farm or
field level.  Case study II, the Yakima River Basin, will demonstrate this
approach.

Establishing the Base Condition (Step 5)

     Establishing the base condition has both physical and economic dimen-
sions.  Base physical conditions involve the variables described in Section
III:

     a.   Precipitation and Temperature
     b.   Topography
     c.   Irrigation Requirements
     d.   Soil Type
     e.   Cropping Practice
     f.   Stream/Lake Characteristics

     Each of these parameters and its effect on base pollutant losses are
discussed below.  Data sources and alternative ways of collecting the data
are also given.
                                     83

-------
Precipitation and Temperature --

     The Cornell Nutrient Simulation (CNS) model used in this case study to
estimate overland flow requires daily precipitation and temperature data.
Data used for Honeycreek were taken from a data file with information for 27
climatical  areas in the eastern United States (refer to Appendix F).  Figure
21 shows these regions.  For each region the data included:

     1.   Average monthly precipitation and number of days with
          precipitation .01" .
     2.   Average January and July air temperatures.
     3.   Average dates of planting and harvest of principle crops
          in each region.
      Figure  21.   Climatological  areas  in  Eastern  United  States  with
                  similar  precipitation and  temperature patterns.
     The data  for  Honeycreek,  included  in  Region  17,  is  presented  in  Tables
9 and 10.
                                      84

-------
TABLE 9.  PRECIPITATION AND TEMPERATURE DATA, HONEYCREEK WATERSHED
          (REGION 17)

Month
January
February
March
April
May
June
July
August
September
October
November
December
Total
TABLE 10.
Precipitation Number of Days Average Temperature
(cm) >.0254 cm °C
6.45
4.50
8.03
8.26
8.74
9.04
8.33
7.11
7.80
6.65
6.15
5.74
86.89
, CROP DATA FOR
14 -3.2
11
13
13
12
11
10 23.1
8
7
8
10
12
129
HONEYCREEK WATERSHED (REGION 17)

Crop
Barley
Corn
Hay
Oats
fsp.)
Rye
(fall we)
Soybeans
Winter
Wheat
Planting
Dates(P)
(Spring) No Appl
5/1-6/15
5/15-5/25
4/1-5/10
9/10-10/20
5/10-6/20
9/10-11/T5
Average Average
Harvesting Planting Harvesting
Dates (H) Dates (P) Dates (H)
i cation
10/10-11/30 5/25 11/5
9/5-10/5 5/20 9/20
7/10-8/5 4/20 7/25
6/20-7/15 10/1 7/1
9/30-10/30 6/1 10/15
6/30-7/25 10/5 7/15
                                   85

-------
    TABLE 11.  PROPERTIES OF HONEYCREEK SOILS
Soil Texture Hydrologic
Group # Class Group
1

2

3

4

5

6

7

8

9

10

silty clay D
loam
silt loam C

silty clay C
loam
loam B

loam B

loam C

loam, C
silt loam
silt loam 0

silt loam C

silt loam C

Depth (ft) . ....
To Seasonal permeat>ili ty
High W.T.
0 - h .6-2

2-4 .6-2
floods
0 - h .6-2

> 6 2. - 6

1% - 3 .6-2.

3/4 - 2 .6 - 4.5

4 to > 6 2. - 6.

0 - h .6-2

lh - 3 .6-2.

f - 14 .6-2.

Available „ ,, _ , . ., .,
PH Water Bulk Total Available
Capacity Density P P
IB/ft 3 lb/ft3 ug/g ug/g
6.6
7.3
6.1
7.6
5.2
7.3
5.6
7.3
5.6
7.3
5.4
7.3
5.6
7.3
5.1
6.5
5.6
7.3
5.1
7.1
.17 - .22

.20 - .24 1.5

.17 - .22 1.5

.14 - .18 1.5

.14 - .18 1.7

.16 - .18 1.7

.14 - .18 17

.17 - .21 1.4

.17 - .21 1.6

.17 - .21 1.7

ug/g ug/g

685



848.08 23.90











455.38 15.87

Topography --

     Estimates of slope  and  slope  length  for  the  Honeycreek  watershed were
made using Conservation  Needs  Inventory  (CNI)  estimates  (CNI,  1967).   These
estimates for the Honeycreek watershed were improved  by  an expanded sample
and field verification during  Lake  Erie  Wastewater  Management  Study (LEWMS)
activities (Stem, 1978).

     Appendix F provides  estimated  slope  and  slope  length for the Honeycreek
case studies and describes other methods  of estimating  slope and slope
length, data sources  and  examples  of each approach.

Soil Type --

     In the Honeycreek watershed many of the  44 soil  types have similar
credibility, expected corn yield,  and drainage characteristics.  Table 11
lists the ten groups  which were used and  the  principle  soil  series in each
group; properties of  each of these  ten soil groups  are  indicated.  These
properties and values were used in  simulating nutrient  losses.

     The principal  criteria  used  in grouping  soils  were drainage character-
istics and response to no-till planting.   Much of the information included
in  Table 11 was extracted from county soil  surveys.   The number of soil
groups and criteria for  grouping were influenced  by the types and number of
practices evaluated.


                                      86

-------
     Once the  soils were  grouped  it  was  necessary  to  determine  the  amount  of
land in each soil group for each  watershed.   Since county  soil  surveys  do
not compile data  by drainage  areas,  this  information  is  generally not  avail-
able.  The least  time-consuming method of making this estimate  is by grid
sampling from  soil maps.   In  the  Honeycreek watershed 500  single  hectare
cells were sampled to determine the  incidence of each soil type (Table  12).
The number of  grid cells  sampled  and their size can  vary.  The  criteria used
in determining the number  of  cells to be  sampled and  some  examples  of  data
derived for Honeycreek are included  in the Appendix  F.

TABLE  12.   HECTARES  OF CROPLAND  IN  EACH  SOIL/SLOPE GROUP FOR EACH
           SUBWATERSHED

Soil
Group
1
2
3
4

5

6

7


8
9


10


Other

Slope*
Category
1
1
1
1
2
1
2
1
2
1
2
3
1
1
2
3
1
2
3


Subwatershed
A
63
583
157
94
274
58
72
422
63
-
5
143
368
58
305
313
1144
2127
_
211

B
198
383
60
5
8
5
_
13
18
77
288
-
1527
_
259
310
4031
3733
190
597

C
737
835
158
24
71
-
-
228
187
-
_
-
2913
_
512
6
8224
4001
_
662

D
1451
33
868
-
_
_
-
_
_
-
_
-
830
_
1059
185
2040
1351
_
2606

Total
2249
1834
1243
123
353
63
72
663
268
77
293
143
5638
58
2135
814
15439
11212
190
4076
47T43
*Slope  Categories:   1  =  0-2%;  2 =  2-4%;  3 =  4+%
Cropping and Livestock Systems --

     Knowledge of crops grown, common  rotations and  livestock  systems are
critical to understanding both the economic structure of  farms and  soil/
water movement on cropland.   Vegetative cover and crop  residues  strongly
influence erosion and runoff  potential.
                                      87

-------
     No published data exist from which crops grown on specific soil manage-
ment groups can be determined.  For any given year, field sampling could be
used.  (This approach would be particularly attractive if slope length were
to be determined in the field also.)  The crop grown on a particular field
or the rotation planned for a field, however, is subject to change.  In
livestock areas where feed rations are not changed greatly from one year to
the next, crop acreages will not vary much.  In cash crop areas similar to
those near Honeycreek, annual decisions made on crop acreage are based on
previous year's prices and expected changes in market conditions during the
next year.  These price variables make crop acreages in cash crop areas
difficult to predict, so only rough approximations of expected crop acreages
can be made.

     A realistic portrayal of crop acreages in the watershed can be based on
county statistics showing the ratio of crop acreage to total production in
the county.  Table 13 shows the livestock estimates derived from published
agricultural statistics.


TABLE 13.   NUMBER OF  LIVESTOCK  IN HONEYCREEK WATERSHED	

County       Beef Cattle  and  Calves        Milk  Cows and  Heifers          Hogs
Crawford
Huron
Seneca

2778
441
3883
7102
410
132
850
1392
4142
760
5965
10867
     In the Honeycreek area a survey was recently conducted  in a  represen-
tative area of the watershed (Venice, 1976).  Data from this survey were
used to determine approximate acres of each major crop, and  also  livestock
numbers (see Appendix F).  This type of information is not available in most
watersheds but a survey to collect these data can be performed by  project
personnel.  Assistance can also be gained by contacting coopera- tive and
county extension, ASCS and SCS offices.

Stream/Lake Characteristics --

     The  relationship between agricultural  nonpoint source loads  and  in-
stream or lake pollutant concentrations is  often unclear.  As discussed
in Section 2, this missing link in water quality management  generally does
not allow precise estimates of the water quality benefits which will result
from nonpoint source controls.

     Analysis of alternative practices in the Honeycreek watershed focuses
on the decrease in edge-of-field phosphorus, nitrogen  and sediment loads.
Because the watershed is intensively farmed it  is assumed that control  of
these pollutants will decrease their concentrations in the stream.  However,
the precise nature and extent of the change is  not now known.
                                     88

-------
      Previous  LEWMS research  efforts  in  the  Honeycreek  watershed have
 resulted  in  the  collection  of a  significant  record  of water  quality  data
 (Water Quality Data,  1978).  Although  these  data  do not solve the problem of
 relating  agricultural  nonpoint source  controls  to lake  or  stream quality
 improvements,  they  are useful  for problem identification and hydrologic
 model  calibration and  validation.

 Farm  Economic  Structure --

      For  the Honeycreek region,  the costs and returns associated with live-
 stock and crop production were estimated (Tables  14 and 15).  Production
 costs included both fixed and variable costs.  Capital  investments,  such as
 machinery purchases,  are examples of  fixed costs; labor, feed and fuel  are
 variable  costs.   A  detailed discussion of all  cost estimates is found in
 Appendix  F.
TABLE 14.  DAIRY  BUDGETS  FOR THE  HONEYCREEK  WATERSHED


Variable Costs
Cone. Protein (SB)
Minerals
Salt and Dicol
Milk and Starter
Sub-Total Feed Costt
Vet. and Med.
Breeding (DHI)
Utilities
Bedding
Mi sc. and Suppl ies
Market Costs
Interest on Operating Capital
Total Variable Costs
Fixed Cost
Labor
Interest
Cow/Calf Replacement§
Total Costs
Da i ry*
Cows
($)
41.00
14.00
4.00
59.00
24.00
27.00
26.00)
20.00)
20.00)
72.00)
22.00
270.00
270.00
69.00
215.00
554.00
824.00
Da i ry t
Replacement
($)
138.00
6.00
2.00
36.00
182.00
15.00
25.00
15.00
47.00
284.00
135.00
95.00
100.00
330.00
614.00
*Production  13,000 #/cow,  receipts $1683/yr
tReplacement period birth to freshening, 36 mo.
tCorn/hay feed  requirements accounted for separately as part  of  farm  group
  production
§Cow replacement = 0.35 x $614
                                     89

-------
TABLE 15.  SOYBEAN BUDGETS FOR THE HONEYCREEK WATERSHED
                                        Soybean
                                      Conventional
                                          ($)
                                       Soybean
                                       Minimum
                                         ($)
                     Soybean
                     No-Till
                       ($)
Variable Cost
    Seed
    Chemicals
1
    Fuel, Oil,  Greasy
    Repair and  Misc.'-
    Labor2
Sub-Total Operating Cap.
Interest on Operating Cap.
    Trucking^-
    Fertilizer5
Fixed Cost
    Management  Costs
13.00

 8.00
21.00
15.00
57.00
 2.71
13.00

 7.36
19.32
13.80
53.48
 2.54
13.00

 7.20
18.90
13.50
52.60
 2.50
Machinery Depreciation
TOTAL
Chemicals
Lorox
Lasso
30.00
89.71

7.50
7.50
27.60
83.08

7.50
7.50
27.00
82.10

7.50
7.50
 Chemical - cost added in LP and interest
p
 Source:  N. Rask and D.L.  Forester, "Corn Tillage Systems  -  Will  Energy Cost
          Determine the Choice", Agriculture and Energy.  Academic Press, Inc.
          1977.  (Base price = Conventional till, Base price  x .92 minimum
          till, Base price x .90 = no-till).
 Interest on Operating Capital - 9.5% for 6 mo.  = .0475

 Trucking cost = $.01 per bu.  Cost added in LP

 Fertilizer function of yield.  Cost added in LP
    P905 (Ibs) = 26.06 + .555 (yield) - .355 (P  Test)
    KgO  (Ibs) = 80.556 + 1.333 (yield) + .75 (CEC) -  .33 (K  Test)

 Management - 29.5<£ per bu.  Cost taken out in LP
                                      90

-------
Evaluating Control  Measures (Step 6)

     Cost and effectiveness of control measures were the major basis of
evaluation.  Initially, practices were screened for suitability in terms of
physical and economic limitations and in terms of compatability with the
present farm systems of the Honeycreek watershed.

Effectiveness --

     Effectiveness was determined by comparing edge-of-field gross pollutant
loading after practice implementation to that loading occurring under the
base condition.  No effort was made to estimate pollutant loadings entering
the water body itself.  This would require assessing the transformations of
pollutants as they move from the field to the stream which would be
extremely difficult.  Once pollutants moved from the field they were assumed
to reach the receiving water.

     Field losses were estimated using the Universal Soil Loss Equation
(USLE) for gross soil erosion, and the CNS model for average annual overland
flow and nutrient losses.  The commonly used USLE (Wischmeier and Smith,
1978) estimates average annual soil  erosion based on a regional rainfall
factor, the intrinsic erodibility of the soil, slope and slope length of a
given field, the crop management system, and soil conservation support prac-
tices.

     The Cornell  Nutrient Simulation (CNS) Model developed by Haith and
Tubbs (1978) consists of a hydrologic subroutine to calculate runoff and
leaching losses and a loading  subroutine to estimate losses of adsorbed
phosphorus (P) and nitrogen (N), as well as losses of dissolved P and N to
surface and subsurface flows.   The CNS model computes daily soil moisture
concentrations and monthly soil nutrient budgets by quantifying all signi-
ficant measurable inputs and outputs of water, nitrogen and phosphorus.
Daily precipitation and temperature data are replaced by probabilistic
inputs corresponding to the appropriate geographic area.   Runoff is cal-
culated from these temperature and precipitation inputs by use of a modified
form of the SCS Curve Number Equation.  It is assumed that soil drainage is
not limited by either a high water table or impermeable layers.

     In the CNS model, two soil layers are modelled separately:  a top layer
of soil  10 cm thick and the 20 cm soil layer directly below this top layer.
Organic nitrogen and total P are modelled for the top layer; inorganic
nitrogen is modelled for both  layers.  Runoff losses, which include surface
and subsurface losses, are assumed to occur from only the top layer of soil
whereas percolation losses take place within both layers.

     Nitrogen losses in runoff and percolation are calculated as the product
of concentration and water volume, where concentration is determined from
the average nitrogen level in  the soil during the month.  Because this model
assumes that no losses of N via ammonification or denitrification occur
after application,  it will over-predict N losses in runoff or percolation
over the long term.  However,  adjusting the initial fertilizer input to
compensate for ammonification  and denitrification losses may yield more
accurate results.
                                     91

-------
     Phosphorus losses in runoff are modelled  in much the same way as N
losses except that the adsorption coefficient  (Ka)  of the soil  must also be
considered.  The coefficient affects soluble phosphorus availability.  Phos-
phorus losses are typically underpredicted (particularly for intense storms)
since the model does not account for the increase in quantity of soluble P
associated with an increase in  water volume.

     The CNS model is applicable to any land area.   It does not develop pol-
lutant delivery ratios nor does it estimate in-stream quality parameters.
However, it is a useful  tool  in comparing pollutant pathway control as a
result of the implementation of nonpoint source control practices.

Cost --

     In addition to the cost to install and maintain control measures, costs
should include reductions in farm income resulting from investment in water
pollution controls.  While other industries are able, at least partly, to
pass on cost increases to consumers, individual farm operators cannot (Nicol
et al., 1974).  For this reason it was important to look closely at how pol-
lution control influences a farm's cost structure.   These changes in cost
structure may mean appreciable decreases in income for certain farming
regions or even place farm producers at a serious competitive disadvantage.

     The method used for estimating the income effects of control practices
was linear programming (LP).  Linear programming methods are particularly
helpful in the evaluation of nonpoint source controls since both single
practices and sets of practices can be evaluated.  In addition, constraints
can be established to limit runoff or erosion in certain subwatersheds or
soil groups as well as the watershed as a whole.

     A base  LP solution maximizes or minimizes an objective function under
certain restrictions  (constraints) on the amount of land, labor and capital
available to the  farmer.  For this study, the objective function was to
maximize net farm income.  The options for use and management of land are
referred to  in this analysis as  'activities'.  The activities chosen for the
LP model of the Honeycreek region reflected realistic alternatives available
to the farms in the area.  The number of choices was minimized since
consideration of  too many options creates an unwieldy array of alterna-
tives.  Net  farm  income was maximized by varying three sets of activities
(management, vegetation, and structural controls) according to the following
equation:

                         Y = k 1 m n  (Aklmn - Nklmn)

Where:    Y  =  net farm  income

          k  =  combination of  soil group and slope.  Ten distinct
               soil groups were considered and three slope
               categories  (0-2%, 2-4%, 4%+).

          1  =  tillage practices: conventional moldboard, chisel
               plowing and no-till planting.

                                     92

-------
          m =  crops:  corn grain,  soybean,  wheat and meadow.

          n =  conservation practices:  contour farming, crop
               rotations and diversion  waterways.

      Aklmn =  hectares of land with conservation practice  (n)
               applied to crop (m) and  field type (k) using
               tillage system (1).

      Nklmn =  annual  net revenue  after producing one hectare of
               crop (m) for a particular combination of field type
               (k), tillage method (1)  and  conservation practice (n).

Constraints on sediment and nutrient losses can be expressed as:

                         (Aklmn -  Pklmn) <^ loadklmn

Where:
      Pklmn =  pollutant loss (kg/ha) for a specific combination
               of field type, crop,  tillage and practice applica-
               tion.

   loadklmn =  residual losses of  sediment  or nutrients for a
               particular combination of k, 1, m, n.

     Linear programming was used to  compare the relative economic efficiency
of alternative nonpoint source controls.  These calculations were performed
without consideration of cost-sharing.   No  changes in the price received or
paid by farmers were assumed with  the implementation of nonpoint source
controls.   In each case partial  budgeting methods were used to determine net
return (see Appendix F).

Developing an Optimal  Control Strategy  (Step 7)

     There are a wide variety of control options ranging from traditional
soil and water conservation structures, such as terraces and diversions, to
changes in tillage systems, fertilizer  application rates or crop rotations.
In order to Insure that a wide range of practices was considered, while at
the same time minimizing the nunber of  alternatives, practices were selected
from each of the three categories  mentioned earlier—management, vegetative
and structural.  Management options  included changes in tillage practice and
contour farming.   Vegetative controls allowed one of four crops rotations to
meet soil  loss restrictions.  Structural alternatives were reflected by the
use of diversions to reduce slope  length and thus, meet erosion restric-
tions.

     To establish the relative improvement  by a control practice set, it was
compared to the base condition.   Both loading estimates and income levels
were calculated for the base conditions.  It was assumed that for the base
condition, those cropping systems  which maximized profits would be
selected.  As pollutant loss constraints were placed on the watershed, the
objective function continued to maximize profits using nonpoint source con-

                                    93

-------
trols to reduce pollutant losses.  These new income levels were compared to
the base solution to determine pollutant control costs.

     The linear programming model and the estimates for overland flow and
leaching were linked in the following manner.  The quantity of land in each
soil management group having a certain tillage system, crop and conservation
practice was determined for the base condition and for increasingly strin-
gent levels of soil  erosion control  using linear programming methods.   Total
runoff, nitrogen and phosphorus losses were then estimated using the simula-
tion model  for each combination of activities at all  levels of erosion con-
trol.  The results indicated the change in farm income, associated reduction
in gross soil erosion, reduction in runoff losses, and the associated losses
of fixed and soluble nutrients.

Results --

     Figure 22 illustrates the change in income with application of the
three different control sets to meet soil  loss restrictions in subwatershed
A.  A base solution for each linear programming (LP)  run establishes the
profit maximizing case with no soil  loss restrictions.  Base solutions dif-
fer depending on the type of tillage system assumed.   Since reduced tillage
systems greatly reduce erosion and have a relatively low cost they become
part of the profit maximizing base solution for managerial controls.

     From Figure 22, it is apparent that management controls, particularly
changes in tillage practices, are a very efficient control strategy.  At
increasing levels of erosion control, vegetative and structural controls
reduce income appreciably.

     Figure 23 indicates how different management practices entered LP
solutions.   As soil  erosion is limited, the area in subwatershed D which is
treated with various tillage options changes.  Both spring plowing and con-
touring enter the LP solutions at relatively high erosion limits while
no-tillage enters at relatively low limits.  Thus spring plowing and
contouring are relatively more cost-effective than no-tillage in this case.
However, in other watersheds with well drained soils one would expect the
opposite.

     Vegetative controls appear the most costly alternative since increased
areas of wheat and meadow were needed to meet soil loss constraints (Figure
24).  These lower value crops, although effective erosion control measures,
result in appreciable decreases in return as shown in Figure 22.   Struc-
tural controls5 have a relatively high capital cost and result in some
cropland taken out of production.  Thus, although high value crops (corn and
soybeans) can continue to be grown, this advantage is offset by capital
charges and decreases in total production.  Figure 25 shows the area of
cropland with diversions as erosion constraints become more stringent.
5A1though only evenly spaced diversions (or "cross-slope drains") were
considered, these controls act like graded terraces and are representative
of practices which reduce slope length.
                                     94

-------
Figure  22.   Relationship between gross farm income and  soil loss
              constraint levels for  three erosion  control  strategies,
        320
        260
        240
     Z
     or
     (T  200
        160 -
        120
   EROSION  CONTROL TECHNIQUE

      a Vegetative

      • Structural

      o Managerial
                               I
                               12     10      8


                               SOIL LOSS,  MT/ha
   Figure  23.  Management practices entering  linear  programming
                solutions  - Subwatershed D.
       100
       80
       60
   Q.
   O
   £   40

   u.
   o
       zo
~~~~ Spring plow

	 Foil plow
— — Minimum tillage

	 No tillage

_ o — Contour
                            SOIL LOSS,  MT/ho
                                 95

-------
Figure 24.  Linear programming solutions giving cropping  areas
            for different  soil loss constraint levels  -
            Subwatershed A.
          so r
                CORN
                         14             10

                           SOIL LOSS, MT/ho
Figure 25.  Linear programming  solutions giving cropping  areas
            for different  soil  loss constraint levels -
            Subwatershed A.
         100 r
                \6    16
                          14    12    10    8

                           SOIL LOSS, MT/ho
                                             642
                              96

-------
     Runoff reductions are  shown  in  Figure 26.   They follow a trend similar
to that of soil loss  reductions:  as  control  increases (i.e., return
decreases) runoff decreases, with vegetative practices being less effective
than management controls.   Nutrients transported either with sediment or in
surface runoff are effectively  treated by  both  management and vegetative
practices although management options are  the least costly (Figures 27 and
28).
   Figure  26.   Changes  in  income for different levels of runoff controls.
                336
                272  -
                192 -
                112
                                              Management
                                        Vegetative
                                   j	I
                                               I	I
                   20
                        18
                                      12
                                          10
                                RUNOFF, I08m5/yr
     The simulation model used to  estimate  runoff  was  not  sensitive to the
implementation of diversions  so  they  were  not  evaluated as a management
option.

     Soil loss limits can be  placed on  the entire  watershed as well as
individual watersheds to allow for greater planning flexibility.  In the
latter case, for the same average  soil  loss,  returns for a specified sub-
watershed can be greater or less than those  returns received when it is
individually constrained.  Figure  29  shows  the variation in return for the
four sub-watersheds at different soil loss constraint  levels.   One would
expect this variation to increase  appreciably  for  smaller  sub-watershed
units or where crop and livestock  activities differ more.
                                     97

-------
Figure 27.   Changes  in income for different  levels of  dissolved
              phosphorus control.
            336 r
            272
        z
        o:
        3
                                                    Manogamtnt
                               Vegetative
              1100
                         1000       900         800


                         DISSOLVED P IN RUNOFF, kg/yr
                                                        700
Figure  28.   Changes in  income for different levels  of solid phase
             nitrogen control.
            336 r
            272
         u
         K
            192
            112
                                               • MMogommt
                                          'Vogttatlvi
                    I   I  I   I  I   I  I   I   I  I   I   I  I   I  I
                 ISO
                              100           50

                             SOLID PHASE N, MT/yr
                                    98

-------
     Figure  29.   Control  cost variations among subwatersheds.
UJ

-------
        Figure  30.   Changes  in  income for different levels of dissolved
                    nitrogen control.
               336 r-
              272
            LJ
            at
               192
               112
                                      Monogtrlol -
/ V«g*!otiv«
                            I
                               _L
                                     I
                                       I
                                         _L
                                                     I
                 750     700      660      600      550

                          DISSOLVED N IN PERCOLATION, MT/yr
                            500
     As shown in Figure  30, those  nutrients  which percolate down through the
soil profile, specifically nitrate  nitrogen,  were increased when practices
designed to reduce surface losses  were applied.   With increasing soil loss
constraints, dissolved N losses  increased  especially  for vegetative
controls.  The implementation  of the  management  options was less dramatic
since crop residues do not increase infiltration  as  much as a sod cover.


CASE STUDY II:   YAKIMA RIVER BASIN, WASHINGTON

     Two models  were developed to  evaluate control  alternatives for the
Yakima River Basin - a farm model  and a watershed model.  The watershed
model characterizes the  Yakima Basin  in terms of seven subwatersheds.  Agri-
cultural, hydrological,  and water  quality  simulation  submodels are used to
analyze the cost-effectiveness of  control  alternatives for the basin as a
whole.  The farm model characterizes  soils and cropping practices on a farm
scale and is used to evaluate  the  cost and effectiveness of different irri-
gation systems.  Steps 1 and 2 below, Description of  the Watershed and
Problem Identification,  include information which is  relevant to both the
watershed and the farm model.   The rest of the evaluation process, Steps 3
to  7, is carried out for each  model separately.
                                     100

-------
Description of Watershed  (Step  1)

     The Yakima River  Basin  lies  in south central Washington and encompasses
about 6,000 square miles  (Figure  31).   The basin contains approximately
450,000 acres of  irrigated  land,  most  of which was originally developed
through a series  of  Bureau of Reclamation irrigation projects.  There are
many fruit orchards  of less  than  25 acres.  The average farm size  is less
than 200 acres.

               Figure  31.  The  Yakima  River Basin, Washington.
           Kachess

     Keechelus   *  f'Cle El urn
     Lake
                                               IRRIGATION AREAS

                                               REACH  TERMINUS
                                                                  COLUMBIA
                                                                  RIVER
Problem Identification  (Step  2)

     Water quality  in the  Yakima  River generally has been excellent above
the city of Yakima.  River  nitrogen  concentrations have remained below the
algae bloom level of .30 mg/liter during most of the year.  Temperature  has
usually remained below  the  Washington  Department of Ecology Class A standard
                                     101

-------
of 65°F.  Sediment loads have generally been small except during periods of
heavy snow melt or precipitation.  The Naches River has also generally met
water quality standards.

     Approximately one-half of the 288,000 ha-meters  (2.4 million acre feet)
of water diverted annually from the river is used above Yakima and one-half
below Yakima.  There is a considerably higher per hectare use of water along
the upper reaches of the river.  Below Yakima, water  quality grows progres-
sively worse as a result of major irrigation diversions and large return
flow volumes.  It is estimated that 80 to 90 percent  of the water in the
lower reaches (6 and 7 of Figure 31) during the late  summer months is return
flow from the upper reaches.  These return flows carry a higher con-
centration of nitrogen and suspended solids than are  contained in virgin
river water.  Consequently, nitrogen concentrations exceeding 1.0 mg/liter
and water temperatures exceeding 80° are frequent during the summer.  Tur-
bidity caused by suspended sediments and algal blooms afflict the lower
reaches during most of the irrigation season, with effects being most pro-
nounced between mid-July and mid-September when water flow is lowest and
irrigation use is highest.  During this period, low water quality inhibits
fish passage and recreational activities, and turbidity causes problems with
downstream sprinkler systems.


FARM MODEL

Determining Applicable Control Measures (Step 3)

     Existing water quality problems in the Yakima are associated with
nitrogen and sediment delivery to the Matches and lower Yakima basins.  Thus
control of erosion and leaching pathways are of primary concern.

     Because of the low irrigation efficiencies in the watershed, a number
of practices appear to be realistic control options in the Yakima.

— Cutback Irrigation System (IA-25) and Improved Water Management (IA-12)

       This system employs additional labor to reduce stream size once the
stream has reached the field bottom, plus an improved level of management.
The improved management includes optimal  timing of irrigation, and length of
irrigation set time.  It is estimated that total water loss from this system
will  be 50 percent of the loss from current irrigation practices.

— Tailwater Reuse System (IA-26) and Improved Water  Management (IA-12)

     This set of practices modifies the current system by reusing the tail-
water and employing an improved level of management as described for the
above irrigation system.  It is estimated that total  base water losses can
be reduced by 80 percent and that runoff losses will  be negligible.
                                    102

-------
-- Automated Tailwater Reuse System  (IA-26) with Gated Pipe  (IA-25) and
Remote Water Control (IA-12)

     The practices included in this  system are automatic reuse systems using
gated pipe and remote sensing devices to control stream flow and  set time.
With these practices total water losses can be reduced by 80 percent from
the base situation, and runoff losses will be negligible.

Side-Roll Sprinkler System  (IA-29) With Improved Water Management  (IA-12)  —

     See discussions in Section 3.

Solid Set Sprinkler System  (IA-29) Operated with Improved Water Management
(IA-12) -

     See discussions in Section 3.

     The farm model developed for the Yakima was also used to evaluate less
traditional policy options.  Although some of the options considered are
contrary to existing legal and institutional practices in the watershed,
they do provide a means of observing optimum adjustments to meet  water
quality standards  (see Section 3, and Appendix B).  Although some  of these
options are not practical at this time,they should be considered  as possible
future measures which could evolve over a long-term to meet water  quality
standards in a cost effective manner.

     The policy options evaluated by the farm model include:

     1.   Constraining total nitrogen outflow from the farm.
     2.   Placing a per unit tax on nitrogen losses leaving the farm.
     3.   Making payments to the farmer for nitrogen and sediment
          pollution abatement.
     4.   Constraining total sediment outflow from the farm.
     5.   Placing a per unit tax on  sediment outflow from the farm.
     6.   Constraining the total use of N fertilizer on the farm.
     7.   Constraining the total use of irrigation water on the farm.
     8.   Placing a per unit tax on  N fertilizer applied.
     9.   Placing a per unit tax on water applied.
    10.   Paying the farmer for every hectare of close-growing crops
          produced.

     The first five policies are administratively or legally infeasible at
present, unless all return flow waters can be collected by a common drainage
system and monitored.  The policies can still  be used, however, to determine
a norm to which other policies can be compared.  Taxing or constraining
sediment loss remains potentially feasible, but difficult to implement for
individual farms.

Choosing the Unit of Analysis (Step 4)

     The farm model is convenient for demonstrating the effectiveness and
cost of a number of different irrigation systems.  The differences in soils
and cropping practices in the Yakima are evaluated by sensitivity  analyses.

                                    103

-------
Establishing the Base Condition6  (Step 5)

     The more than 2,000 farms in the basin are organized  into several
independent irrigation districts.  Existing water  rights in  the basin have
normally been sufficient for crop production.   Thus,  few incentives have
been provided by water costs or supplies to improve irrigation efficiency
through better management and/or capital expenditures (a notable exception
being the drought period of 1976-77,  when  several  irrigation districts  were
programmed to receive only enough water to keep perennial  crops and a few
annual crops alive).  Consequently, surface or furrow irrigation is used on
60 to 70 percent of the irrigated land.  The remaining acreage is irrigated
by sprinkler irrigation methods adopted primarily  in  response to growing
labor shortages and higher wages.  A large proportion of the tree fruit
acreage is irrigated with solid set sprinkler systems.

     While some 80 different crops are commercially grown  in the Yakima
Basin, the economic returns and hydrologic characteristics of the basin can
be represented adequately by 6 to 10 crops.  A typical farm  would grow  no
more than 3 to 5 crops.

     Regions 1 and 2 (Figure 31)  are dominated by  forage crop production
which supports an extensive livestock industry.  In Region 2, small grains,
sugarbeets, and vegetables are also grown.  Region 3  is a  relatively small
area above the city of Yakima in which diversified crop production pre-
vails.  Region 4, lying along the Naches River, is dominated by sprinkler
irrigated tree fruits.  Regions 5, 6 and 7 are the largest and most inten-
sively cultivated areas in the basin.  Level land, rich deep soil, and
favorable weather conditions make these regions suitable for almost all
irrigated crops.  Relatively large tracts  of less  productive land are never-
the less used for forage crops and pasture.

     Gossett (1975) developed a linear programming model  (see Appendix  B) to
represent an individual model farm in the  Yakima River Basin.  The model
predicted the seasonal quantity of nitrogen leaving the farm in subsurface
drainage and the amount of sediment carried by surface runoff.  These losses
were predicted for each of 5 crops, 4 fertilization rates, and 6 irrigation
systems.  Each crop therefore could be produced 24 possible  ways.

     A total of 560 acres of gently sloping land and  a deep  silt loam soil
was assumed for the model farm.  The crop mix included potatoes, sugarbeets,
wheat, spearmint, and alfalfa.  The farm model established a base irrigation
system consisting of conventional surface irrigation  methods using open
ditches, siphon tubes and furrows.  The model  was  then used  to evaluate
nitrogen and sediment losses for each of the control  and policy options.
Control alternatives were evaluated with respect to the effectiveness of the
measures in controlling pollutant pathways and the farm costs associated
with these controls.  Costs included expenses for land and operator labor.
Constraints were imposed to control crop rotations while maximizing net farm
revenue for a single production year.
6Physical and economic details of the watershed can be found in Gossett
 (1975).

                                    104

-------
Evaluating Control  Measures (Step 6)

     The capital and annual operating cost of the base irrigation system and
the five alternative control measures are summarized in Table 16.

     Deep percolation loss was assumed to be a constant percentage of the
amount of water applied for the base system and option a.  It was assumed to
be the total loss for systems b and c, which used a form of pump-back irri-
gation.  Deep percolation under sprinkler irrigation was assumed to equal
the total loss minus 10 percent of water applied, which represents the loss
to wind and evaporation.  Table 17 shows the estimated irrigation effi-
ciencies and deep percolation losses which were used in the farm model.

     A base solution was obtained  (see Table 18) when the farm was irri-
gated by the existing system, free of contraints.  The only internal con-
straints were restricted crop acreages in order to represent realistic crop
rotations.  These constraints were:  potato acreage 32 ha (80ac.); sugarbeet
acreage 57 ha (140 ac.); alfalfa acreage 40 ha  (100 ac); and spearmint acre-
age 57 ha (140 ac.).

     When sediment and nitrogen outflows were unconstrained, the 560 acre
farm produced a net revenue of $87,095 or $155.53 per hectare (Table 18).
Total nitrogen leached through the root zone was calculated at 58.9 Kg/ha
(52.5 Ibs. per acre), producing a nitrogen concentration in the subsurface
drainage water of 21.3 ppm.  The base solution  also had 1744 tonnes of sedi-
ment leaving the farm, or 7.69 mt/ha.  A total  of 160 cm of water was
applied per ha. of farm land, with resultant deep percolation and runoff
losses of 28.7 and 55.4 ha-cm., respectively.

     The effects of alternate irrigation systems are compared with the base
solution in Table 19.  These solutions imposed  no constraints or economic
incentives to influence pollution abatement beyond those provided by the
irrigation system.  The solutions thus emphasized the marginal value of
management, labor, and capital in reducing nitrogen and sediment waste
loads.  Comparing the existing system with system a, one can see that
improved management would reduce nitrogen leaching by 25 percent and sedi-
ment yield by 62 percent at a total farm cost of $3,477, or $15.31 per ha.
This cost arises because the additional labor costs more than the savings in
fertilizer use.  The 3,900  hours required to irrigate the 227 ha (560 acres)
with system a would require 3 to 4 full time irrigators.  Operators would
generally adopt more capital intensive irrigation systems in order to reduce
required labor.

     Surface tailwater reuse, system b, was able to further reduce nitrogen
leaching losses below those of system a, and to completely eliminate sedi-
ment discharge.  The reduced nitrogen losses may have been an artifact
because deep percolation was assumed to be a constant proportion of the
amount of water applied.  With this particular  system, water remains in the
irrigation furrows for the  same length of time  as for the base siutuation,
even though total water use is less because of  the "reuse" of normal runoff
losses.  Total net revenue was increased slightly for this set of assump-
tions, because nitrogen fertilizer savings were greater than the increased
costs of the tailwater reuse system.

                                    105

-------

LU
>
1—!
U-
LU
n:

Q
<
5:
1 1 1
f=
GO
•w
^~
GO

LU
GO
-, <
{-CQ

'2s
< -
Q
•Z. "
cC GO
LU
1— >
z: i— i
LU I—
2T<

GO ct:
LU LU
E> 1—
E: —i
-HCC
CAPITAL
CONTROL


•
•J3
LU
I
— J
CQ
<:
CD
CJD
•i— f
r- 4-> to
to to
3 S- 4->
C d) CO
E Q. O

C
r— £

4-> 00
••- O)
Q. >
to c
O 1— I


























I?
CU
4->
CO
£>

c
O
4J
to
CD
•r™
s_
1 — 1



<& 10 CvJ
C3 O CO
LO i r*i /TV
l-I J Q^
1 — 1


n3
,c
^^
v>


« K S
00 CO ^
«— ' I—I ^j-








1
o a> i — ro
•I— > fQ
•*-* o c: -a
fTj C O ^-
a> S..2 o
•r— f~* i ^ ^T
, fc 4-1 Q_
« S- •!-•!-
CO S- "O • E
CU -r- S- T3 CU O
-C O  O 3 CU O
CU CU X r- i- U
O-i — CU O 4-*
O C t/l /r<
CU E -r=
-E CO CU 2 jr S-
-»-> to 4-> « s £ 5;
•"— -O CO 4-> i- T- 4->
5 >, E S- s re
*O (/) rtj ^ •>
C E 4- C r^
O "O CJ CU O T-
•J- E -i- CDjii .,- ra
T~"^ *o (/) (O t-J -4~J *t~^
03 IO E IO IO
CD •> J3 to JO CD CU
T °° E 4J -^ co
J- CU CU =3 S- !3
i •§ E 5 § u i £
+J C^ -r- 0
CU E CO 4-> 4-> CU O
o E a> to to o +->
(O O CD CD S- to
M-^IfO OJ-r-O M-Q.
^-Q-C Ei-^ ^H"
~^ — *••- k— ~ I"- .ij >~ ^
3 -i-nj tos-to 33
GOtOE GO-F-i— GOO.

LU
GO
2 * -°




co r-» co
CTl CTl IV.
• • •
IO IV, r-l
LO •* CO
i 1






LO O
i— 1 CM
• •
CO LO CO
LO cn CTI
ro oo LO
i — i



E
OJ
4-5
CO
>, CO E E
co O> O o
0 .,- .,-
CL) •!- 4-> 4->
CO > fO tO
3 oj cn cn
CD "O -i— -r—
s- s- s-
CD S- S-
0 E .r- .,_
4-> CO 4-> 4->
tO C E c"
E CD CU CD
O CO i — , —
I \ ^ ^_
^ — .C i—
5 i if if
5T3 S S

c i- S-
c: to CL> cu
O i — i —
•r. X •* -^
4J Q. c: c
fO *r~ «i— «|—
cn a. s- j_
••-0.0.
J- T3 on oo
S- O) +J 40
•r- 4-> i— c 4-> C
tO i — CL) CD CU
 O5 O E co E
Uc fl i tr:
*- CU 1 CD
to CD i Q> T3 CD
II C~ fit _w -
^ t- CD to •!— to
*- '•- "O C r— E
3 CO T- to O to
GO 3 GO E GO E


0 -0 OJ

to
4->
•r—
Q.
IO
O
CO
O)
"O
13
o
c
•r~
4->
•^
JO

CO
4->
CO
O
O
S-
CL)

0
Q.
CJ
•r^
S-
j i
T— '
O
O)

 C
to a
2 4-
£Z
•\ >|_
e iri
^— '<_
0 E
J2
to ~a
i — C
to
c
O CO
•r- 4->
4J CO
IO O
CD O
£ C
S- O
•r— «r—
4J
CO to
CU N
T3 -r-
3 4->
< C
0 C
X E
LU to
to































)
>
)
,


CO

cu
>
cu

O)
0
•i—
s_
Q.
•vl-
r^
CTl
r— 1
4->
O
CU
i —
M-
2!
CO
i ^
•f~*
CO
o
0
_a
106

-------
00

OO
00
UJ
00
00
o
8
o:
LU
UJ
O

O
UJ


O Z
»—( I—I
H oo

O CO
a ce
LU
§
                       r— O 00 «t LO
                       t^ co i-- r— co
                       ^J- lO Lf) CVJ I—
                       01 co o «t n
                       m i^ i^ ^o oo
                       o 10 c\j o cj
                                          i— «a- ro ro vo

                                          Ol r— •* CO LO
                                           i— 00 VO CO f
                                           oo o i^ «fr cn
                                           OO C\J    CO
                                           CO CVJ 00 r— CVJ
                       CM UD LO CM O   E
                      • CO GO CO CO Cft   O i— r—
                                        O
                                        U
                       01 o> c\j n ro
                       l~* CM r-
                       rv. oo co
                                        CD i— 00 113 LO IO
                                        CD CM i—    CM i—
                                        O
                       r^  co r^ co
                       LO \£> vo LO r^
                       in CM oo LO m
                                          CSJ CO O CO ^~
                                          oo fo i-~ co ro
    co
   •M    J->
 «  01     C
 CD  01    >f-  IQ
 O J3     E M-
+J  1- <->  C r-

+->  Dl Q)  0) **-
 O  3 J=  Q-r—
D- 00 3 00 «I
                                             5
                                              cn
                                              3 J
                                             00
                                                  1  01 <4-
                                                    0.1—
                                                   00 «C
                             107

-------
 TABLE 18.   BASE SOLUTION FOR THE 227 HA.  MODEL FARM, YAKIMA RIVER BASIN
                             UNITS         TOTAL           PER HA
Net revenue
Nitrogen losses
Sediment yield
Nitrogen applied
Water applied
Irrigation labor
Deep percolation
Runoff
$
Kg
tonnes
Kg
ha-cm
hrs
ha-cm
ha-cm
87,095
13,337
1,744
63,265
36,297
1,990
6,533
12,580
155.53
58.82
7.69
279.04
160.12
3.55
28.72
55.41
     A surface automatic reuse method, system c, would allow significant
reductions in nitrogen fertilizer, water, and labor use, while maintaining
constant production.  More efficient use of inputs would allow system c to
be adopted at the relatively small cost of $3*026, or $13.34 per ha.  This
is despite a required capital investment of at least $371 per ha., because
nitrogen leaching was assumed reduced to 48 percent of the base level with
this system.  The net income position would be slightly less than the base
condition.

     The side-roll sprinkler, system d, proved to be uneconomic.  Similar
abatement reductions could be obtained at smaller private costs with other
irrigation systems.   Adoption of system d would cost over $9,000, while
still producing 11,029 kg (24,319 Ibs) of leached nitrogen.  The solid set
sprinkler, system e, could reduce leached nitrogen by 50 percent, but only
at a cost of $32,899, or $146 per ha.  Both of the sprinkler systems would
be inefficient in reducing nitrogen losses.

     The above comparisons are valid only under the conditions assumed for
this model.  Increases in the value of fertilizer, water, or labor could
cause some shifts in comparative advantages among the various irrigation
systems.  Also, changes to more sandy soils or steeper slopes would  auto-
matically reduce the advantage of surface irrigation systems over sprinkler
systems.  Under the conditions assumed, a fanner operating in the Yakima
Basin with full technical and economic knowledge and complete mobility of
resources would elect to irrigate with system b, the surface tailwater reuse
system, which maximizes his  net revenue.

     The model was also used to look at additional soil types and slope
conditions.  Figure 32 summarizes the marginal abatement costs for estimated
nitrogen leaching on alternate soil types in the Yakima region.  Costs of
abatement can quickly reach  $4/kg of nitrogen loss abatement if nitrogen
                                    108

-------










UJ

t— l
i—

Qi
UJ
1—
— 1
-
UJ
Z. _J
0 -1

1— >

CD <
C£ I-H
rv \/
"— '  O
i — i y_

c3^ OO
o: s:
*Si UJ
0- r—
2! 00
O >-
0 00


•
CTl
.—l

UJ
	 1
CO
c^
I—

























































































SI
1—
00

00

-^
o
t— 1
I—
3
2
o;






















t- 4->
i — t/>

C "O
•1— •!—
£_ , —
Q. O
00 00
OJ •—
i — O
\S If
C 1
•r- OJ
t- TD
Q.-1-
00 00



o
QJ •!-
O +-> O)
ro ro to
4- E 3
£_ 0 OJ
^ -I-J Di
00 3




c_
CD CU
O -^ CU
ro ro t/)
4- S 3
l_ r- QJ

OO ro
i
r~^



CU O
O ro
ro J3
4- 1
t— 1^
rs ^
00 O




^ 	 ^
QJ
x 	 *




^ — ^
TD










,^ — ^
O
^-^










^ — ^
JO
* — ^







^ — ^
ro
N — ^






cu
to
ro
CQ


























^j- r~~ to CTI
O • CTl CTl
r~~ to o O •— i co
»CM •» -
tO <=)- CM
LO OO

CTl CO «d- •— 1
CM • 00 <-O
O 00 O O O C
*CM « "
^-1 CO CT.
1 — 1 1 —





O1 OO CD to
tO • tO CM
CTl "vl- O O O O
*CM « r.
to «d- oo
CO







OO CTl t— 1 to
to • O O
CTl OO O O CO f^-
«CM •.
CO r-.
CO




r^ oo co co co t^-
o • to o i— i r-~-
C~*l t—H tO ^^* tO ^J"
«CM « « "
O i— 1 OO OO
,-H CO




r^ oo «* co LO

oo «— i r- oo o o
f\ CM « n *»
oo t— i t— i r-
,-H CO



^^ ^-^
CD. 	 tO ^~~
-^ E c E
^ — " D- O Q.
D_-(-> Q. -K
~o * 	 ^^ — ^^ — ' • — ^
cu *~~^ to
_C . T3 •*'»• 	
0 O i— O - —
ro C QJ C +-> QJ
O) O -r- O QJ to to
_i o >-, o 3 o :r>
C C_)
C C 4-> +-> Ol O)
QJ CU C C > i— O
CD CD CU CU CU O £_
O O E E O^ 5- ^
C ^_ >| — if— ^_> Q
-!-> -I-J T3 T5 4-> C tO
•i- -i- CU  *
tO i-H
OO






. 	 »
en
-^

0
^D • — .
0 E
^H O 	 	 ~
— i to
ro c_
C r- c-
CU — '---
CD
0 t_ S-
1- CU O
+->+-> JO
•i— ro ro
•Z. 3 _J

























•
QJ
to
>}
to
C
0
•1 —
+J
ro
en
•1 —
£-
•r-

cu
-p
CT)
C
•1 —
01
C
ro
.C
o

o
QJ
^3
-o

QJ
3
C
O)
cu

t —
ro
•r~-
-l~>
•1 —
c:
•r—

c
•r—

c
o
•r—
-I-J
o
33
~C3
QJ
ce
-K
109

-------
leaching is to be reduced below 50 percent of current  levels  for  the model
farms.  These estimated abatement costs are based on most efficient combina-
tions of new irrigation methods, management inputs, and crops  for each  level
of abatement (see Appendix B).


     Figure  32.   Long-run marginal  cost function for the abatement of
                 nitrogen leaching  for various  soil  types  in the
                 Yakima  Valley.
               co
               t-
               V)
               O
               o

16.0


14.0


12.0


10.0


 8.0



 6.0


 4.0


 2.0
                                                  Loamy  Sand
                            Clay Loam
                    14    II     9    7521

                        NITROGEN RESIDUALS, 1000 kg
Developing an Optimal Control Strategy  (Step 7)

     The ten policy options were first  imposed on the farm assuming short-
term planning, with investment in additional irrigation equipment  not  being
allowed.  The policies were also examined assuming long-range planning where
irrigation system changes would be feasible.

     Production costs were derived from cost studies conducted  by  the
Cooperative Extension Service of Washington State University.   Costs for
irrigation labor, nitrogen fertilizer, and electric power were  entered in
the programming model at rates of $3.00 per hour, $0.44 per  kg, and $0.082
per ha-cm ($0.085 per acre inch) of water, respectively.  All costs and
prices used for this analysis were representative of the mid-1970s.
                                     110

-------
     Sediment yield is a function of only one production input - water.
Thus, controlling water use is the most economically effective method  of
controlling most sediment losses.  Under any policy to  induce sediment
abatement, such as taxing sediment, constraining sediment, constraining
water use, or taxing water, the farmer would probably make the following
adjustments:  As allowable sediment loss levels were reduced, the farmer
would first convert his total acreage to system a, thereby reducing sediment
outflow by 60 percent.  This adjustment would have a total cost of about
$3,000.  To reduce sediment loss still further, the farmer would find  it
most profitable to substitute close growing crops for row crops.  A subsidy
to the farmer would probably be required to induce such substitutions  among
crops.  A sediment outflow from the farm of 363 tonnes  (80 percent reduc-
tion) would cost about $17,000 for the combination of practices.  Minimum
outflow from the farm for the conditions examined (26 tonnes) would be
obtained by eliminating row crops.  If sediment were the primary focus of
abatement, it would be less costly in the long-run to turn to tailwater
reuse systems or sprinkler systems.

     A policy of subsidizing the farmer for increasing acreage of close
growing crops at the expense of high value row crops would necessitate an
unreasonably large subsidy.  Due to the greater returns from row crops as
compared to close growing crops in this case, the farmer would probably
not be willing to alter his crop mix until subsidies exceeded $346 per
hectare (current return for row crops).  Even this level of subsidy would
not be particularly efficient in reducing sediment yield.  As discussed in
Section 3, it is probably not practical to attempt crop pattern adjustments
through subsidy programs of this type.


WATERSHED MODEL

Determining Applicable Control  Measures7(Step 3)

     Applying NPS controls to the entire watershed enables consideration of
a wider range of control practices and an overall assessment of control
strategies to achieve water quality objectives.  Water quality criteria of
concern in the Basin include a maximum nitrogen concentration of .3 mg/
liter, a maximum river water temperature of 70°F in August, and a maximum
sediment loss of 22 Mt/ha (1 ton per acre) throughout the basin.  Where
improved irrigation efficiency was needed to solve water quality problems,
investments in new irrigation systems, improvement in irrigation management,
or changes in crop mix or location of crop production within the basin were
required.  The options include:
7The watershed evaluation of nonpoint source controls is based on work by
 Pfeiffer (1975).

                                    Ill

-------
Tailwater Reuse (IA-27)8, Sprinkler Irrigation (IA-29) and Improved Water
Management (IA-12) --

     This alternative would increase surface irrigation efficiency by 10%
due to improved water management.  The increases in efficiency are largely
achieved by a 5% increase in tailwater reuse and sprinkler irrigation sys-
tems.

Tax on Nitrogen Fertilizer (IA-32) --

     This policy was chosen because nitrogen loss is primarily a function of
nitrogen application rate.  The varying tax ranged from $0.22 to $1.54 per
kg ($0.10 to $0.70 per pound) of nitrogen fertilizer.

Water Charge (1-33) —

     This option imposed a charge on the use of irrigation water ranging
from $0.62 to $3.08 per ha-meter  ($5 to $25 per acre foot).  Use of water
for irrigation reduces river flow, which in turn increases both the effec-
tive concentration of pollutants and the river water temperature.  Moreover,
nitrogen loss is functionally related to the volume of deep percolation
water, and sediment loss is functionally related to the volume of runoff
water.

Uniform Reduction of Water Rights (IA-34) --

     This practice imposed a uniform percentage reduction of water rights to
all regions, with the reductions varying from 10 percent to 60 percent of
current levels.  Sales or exchanges of water rights between regions were not
permitted.  This policy would result in efficient resource allocation only
if the demand for water is the same in all regions before and after water
rights are reduced.  The major advantage of reducing water rights is the
fact that the policy does not require a direct income transfer from agricul-
ture to the public sector.

Nitrogen Tax (IA-32) and Charge on Water (IA-33) --

     This alternative combined a tax on nitrogen ranging from $0.44 to $0.88
per kg  ($0.20 to $0.40 per Ib. ) with a charge on water ranging from $0.62 to
$2.46 per ha-meter ($5 to $20 per acre foot).  Since both water and nitrogen
are contributors to pollution through irrigation return flows, it was ex-
pected that a combination of policies would be more efficient than policies
directed at either individually.

Nitrogen Tax (IA-32) and Reduction in Water Rights  (IA-34) --

     Like the above option, this  alternative combined a tax on nitrogen
ranging from $0.44 to $0.88/kg  ($0.20 to $0.40 per Ib.) but with a reduction
in water rights from 10 percent to 50 percent throughout the area.
8Refer to Table 3.2 for a description of practices.

                                     112

-------
Change all Furrow Irrigation Systems to Either Sprinkler (IA-29) or Reuse
Systems (IA-27)

     See discussions on Sprinkler and Reuse Systems above.

Choosing the Unit of Analysis (Step 4) --

     The watershed model characterizes both the agricultural system and the
water quality of the entire Yakima River Basin.  The river  is divided into 7
reaches (Figure 31) with an associated land area corresponding to each river
reach.  In most cases,  return flows from the farming region drain into the
respective reach.

Establishing the Base Condition (Step 5) --

     Table 20 shows two solutions that were used in the watershed model9 to
establish a basis for comparison of environmental improvement policies.
Solution B! (base condition) constrained the crop area in all regions to
existing levels.  This  solution most accurately reflects current conditions
in the basin.  Solution B2 permitted regional crop production specializa-
tion, by allowing a 25  percent increase in row, fruit and vegetable crop
area, a 50 percent increase in field crop area, and an unlimited increase in
forage crop production  for each region.  Basinwide areas of each crop were
still constrained to existing levels, however.  The results of solution 82
were used as a base with which to compare all remaining policy results.

Evaluating Control Measures (Step 6)

     The cost effectiveness analysis of control practices utilized three
mathematical models - an agricultural submodel, an hydrology submodel and a
water quality simulation model.  The agricultural model limits crop acre-
ages, pollutant losses  and practice application rates.  These implicit con-
straints lead to abatement cost estimates.  The hydrology submodel is a
watershed mass balance  of water flows including precipitation, runoff, and
irrigation diversions for each subwatershed.  Finally the water quality
simulation model relates agricultural and irrigation practices on cropland
to gross pollutant loading.  Figure 33 shows inputs arid outputs of each
model and how they are  linked when used to make policy decisions.

The Agricultural Submodel --

     The agricultural submodel for the river basin included 10 crops, 3
irrigation systems, 11  regions and subregions, and 4 levels of nitrogen
application for most crops.  In order to permit some degree of regional
specialization, row crop and fruit crop acreages were permitted to increase
25 percent and 50 percent, respectively, within each region.  The total area
of these crops within the basin, however, was constrained to present
levels.  The area of forage crops was not specifically restricted.  The
model reflected surface and subsurface return flows from crop activities
within each region.
 'For details of the model and input data used see Pfeiffer  (1976).
                                    113

-------
=z
oo
03
a:
LU
1 — 1
rY*

y

i — i




































































o 01 oo =3- CM LT> r-~ <=}- o
r*~ CO ^v. ^3" OO O^ ^^ CD CO ^~ O""> OO
O^i 00 iQQ CO ^J~ C\J • • l"*™1^ • •
*» r— * c\j r^- o o oo ^d"
^O CNJ C\J
o <3-
r™





C? ^" CO ^O OO ^3 OO CD ^"
LO OO O^ ^~ 0s! CT) r— r^ O"^ r— CO r—
O^ 00 CO OO ^f CSJ vO . .
** r~~ ** CVl P^- fTi CD CO *sj*
LO CM CM
O 'd-
1 —




E S
r i
L4_>
CD re re ZEZ
re O) NX c~ c** i — r^ re
-E ^ re -~^ \ o -E
-E O O O CT> O5 O - —
OOO^^OOO EEO-t->U
OOOCDOOO "2!o
OOO^i — i — i — r —







re re
E i ^
0 tO
-P 00 3
co re cj> i —
rs  CO =t -P S-
3 O 3
r^ ^C " " -P "P
CO re E E re
E "O ~P "O ** O O *^ S-
O QJ O r" • CU re *r— gr- CO (/) D
o -p -P re -p E -p ~P co co Q-
E re -p t- o re re o o E
•i-Cn " "OCU-i-S-S-i — i — CU
Q.S-CDCU T- EE-P-P
os- -r- -r- "•O-PCUOJEEE
S--I— r— i — +J reoogj
-------
     Nitrogen loss functions, sediment loss functions, and irrigation
efficiency relationships  (see Appendix B) for various irrigation systems are
examples of the data requirements for this type of analysis.  Sediment
losses were adjusted for  factors such as crop cover, tillage practices,
method and rate of irrigation, slope and soil type, and overall management
level.  Water rights in the river basin were assumed to represent maximum
allowable diversions of water.  In most cases, water quantities are more
than sufficient to supply crop needs under current irrigation practices.  By
imposing constraints and/or higher prices on inputs used by the agricultural
sector, abatement effectiveness and the distribution of abatement costs
resulting from alternative policies could be estimated and compared.

Hydrology Submodel ~

     The linear programming model developed included a hydrology submodel
representing river flows  in the basin.  This hydrology model reflected
effects of water demands  and  return flows from the agricultural submodel on
river flows.  Irrigation  diversions and deliveries at each reach terminus,
and irrigation return flows carrying pollutants to the river, were included
in the model.  The net flow of water at each reach terminus was taken as the
sum of water inflows minus water outflows for that reach.  Natural inflows
were included by individual river reach, and diversion rights were allocated
by canal for each irrigation  system of the river basin.  In cases where
canals serve more than one region, the activities were appropriately sub-
divided.  Water flows in  each major reach of the river were input for the
period April through September.  August, the period of lowest flow and most
serious water quality problems, was used to meet the water quality stan-
dards.

Water Quality Simulation  Model --

     The water quality simulation model was linked with the linear pro-
gramming model as illustrated in Figure 33.  This model measured, for
example, the effects of nitrate concentrations contributed by irrigation
return flows.  It was demonstrated that not all nitrogen entering return
flow channels from individual farms arrives at the river.  Some nitrogen is
lost through denitrification or by transformation to organic forms during
plant and phytoplankton consumption (see Section 2).  Once in the river,
phytoplankton use of nitrogen continues.  Part of the nitrogen is diverted
with the irrigation water for additional use on farm land, and part remains
in the river as inorganic nitrate nitrogen.  Thus, the nitrogen concentra-
tion in the river depends upon nitrogen losses from upstream farms, denitri-
fication, plant and phytoplankton uptake, subsequent irrigation diversions,
and the volume of water in the river itself.

     The simulation model measured the flow of water and nitrogen throughout
the various reaches of the river, adding and subtracting nitrogen and water
as they were discharged into and diverted from the river.  A pollutant
delivery ratio (PDR) of .32 was estimated, reflecting the nitrogen lost from
farms which actually enters the river in nitrate form during the irrigation
season.  During August, the PDR is reduced further to approximately .24,
because of plant and phytoplankton uptake.

                                    115

-------
 CO
 re
CO
 O)
 re
 re
>-

 OJ
 co

 O

+J
 c:
 o
 o

 ai
 re
 E

 O)
 re

 





or.
<
UJ
z
_i
^

x. *
XT

O
P*
g§
O ^™
z o
X"
>X
1
























0
z
V
5
^1 tf
1











^

)-
J ;
< <
3 -
Qf 1
(E .
uj :
^ I
*«
j
































z
3

j
JJT
2^
!c
02






















V




S











i






















—f '
xt
X


-
ij
3 (O
LJO
0) -J
X
V
1


































•v




s













s.







X
































t
"k

0
LU
„ ^™
ft*
~>
$ 0
s.
Js.
|X



















































X




a
u
x
c
X




























>-
ts
o
J
o
or
o
1

.._ _ .
1

oc
^
5
Ei-
K
jvi












t
x^^
o
i
u.

Z UJ
33
UJ O
or >
X.



e>
z
_i ^
UJ ^
/V rf
5 < or
TUJ o
mzo
co^Q-
t
	 1
i
i
i
i
i
i
i
i
i
i
i
1
1
i
i


i
i
i
i
i
1
i
ixf :
^X, '
1
1
1
1

SI 1
E u. i
X^ i
1s — ,
r1
i
i
i
i
i
i
i
i
i
i
i
j i
i
                                                     116

-------
Results --

     Table 21 summarizes the policies evaluated which met the prescribed
water quality standards.  The table includes base solution 2 (B2) for com-
parison.  Two measures of abatement costs were used.  "Producer cost" mea-
sured the reduction of farm income caused by abatement policies, reflecting
the immediate and direct impact on agriculture.  "Net social cost" measured
the public or total cost of abatement policies.  The two differed if a
transfer of income from agriculture to the public (a tax) or from the public
to agriculture (a subsidy) was involved.  Comparing the social  costs of
alternative policies is a more realistic measure of their relative economic
efficiencies (see Appendix F for a further discussion of this topic).

Tax on Nitrogen Fertilizer (IA-32) -- As expected, nitrogen application
rates declined as the tax increased.  Fertilizer use was reduced on all
crops at the higher tax rates, but reductions on the irrigated pasture (a
relatively low-value crop) were most pronounced.  A nitrogen tax above
$0.88/kg ($0.40 per Ib.) resulted in no nitrogen fertilization of pasture in
the basin.  Water diversions declined with irrigated acreage, so less pro-
duction of low intensity pasture caused August river flow volume to
increase.  Nitrogen concentration and water temperature goals were finally
met with a nitrogen tax of $1.32/kg ($0.60 per Ib.).

Water Charge IA-33) — Irrigated pasture was once again the crop most
affected, though alfalfa acreage also declined sharply at the $162/ha-m ($20
per acrefoot) rate.  The area of other crops remained relatively unchanged,
despite changes to more efficient irrigation methods.

Uniform Reduction of Water Rights (IA-34) -- Under this policy, as would be
expected, irrigated acreage declined rapidly as water rights were reduced,
primarily affecting crops in the order of their value.  Water conserving
irrigation systems were also implemented with increasing frequency as water
rights were reduced.  Water rights reductions of 30 percent or more even
caused fruit production to decline in some areas.

Prohibiting Surface Runoff (IA-29, IA-27) -- The result was almost no change
in cropping pattern and only a small reduction of income compared with the
base solution.  Sediment loss was completely eliminated, but river flow
volume, nitrogen concentration and water temperature changed little.  This
solution illustrated a policy directed at a single effluent, sediment,with-
out affecting other major pollutants in the river basin.  This demonstrates
that it is possible to completely abate one pollutant in such a river basin
without significantly affecting other water quality parameters.  The major
shortcoming of this policy was the fact that it had almost no impact on
either nitrogen concentration or water temperature, which are also serious
problems in the basin.

Developing an Optimal Control  Strategy (Step 7)

     Optimal abatement is possible either with taxes or with constraints on
inputs which contribute to a particular pollutant.  Nitrogen content of
return flows, for example, would be most efficiently controlled with a


                                    117

-------
              B
o
i
                                                                coooo
8
                                    it—   en  ro  tn   i —
                                        < —   CTiCM^OtJDCM
                                        I —   o»—  cr»cr>
                                                                     oroLO
                                    IVOr^CTt*—   ^•COCM*C> —
                                    iOrotDtncnCf>CMCr>co
                                    l< —  LOCTiCJvCOCQ' —   IDi —
             1—      CO
             m      c\j

                     o
                                        O*3-CMCO'!j-OLO
                                                 vo
                                                 o
I—  Q.

u_  LU
O  I—
                            f
                       01   *o
                                        §   s
g
                                                                                       O       CJ1
                                                       SO
                           C7>-*-»COl
                            Ot-UUfOOOU-r-'r-     ""U
                                    3fO(/1   (-   S-   O<—  <—   +->
                            at   a»  -M-4-»i_   O   O-M-M-M
                            (O   ro      S-   S_   (D   OJ   OJ
                                                                                                     ro       O      O -O   O CU   E
                                                                                                     l_      r-     •— O)  r- »—   Ol
                                                                                            •*->  fO               +->      JD   -4->
                                                                                            C  C    C-*™*^     4-»(O+J'O
                                                                                            a>o    cuvi    cr—   coiccnE
                                                                          118

-------
 policy  affecting  both  nitrogen fertilizer and irrigation water use.  Water
 temperature,  on the  other hand,  is a function primarily of river flow
 volume, thus  policies  reducing water diversions would be most efficient in
 affecting this quality parameter.   Sediment loss, a function of surface
 water runoff, would  be most  efficiently controlled by irrigation systems
 which reduce  or eliminate runoff volumes.

      Table 22 shows  that  improved  management (IA-27,  IA-29 and IA-12) was
 unable  to meet the water  quality standards  which were sought for this river
 basin.  Each of the  other solutions,  d  through  h, was able to meet water
 quality standards at varying levels of  efficiency.  In all cases, the net
 cost for meeting  water quality standards in the river basin were rather
 large.  The most  efficient policy  was solution  g.  It included a combination
 of water charge and  nitrogen tax in order to meet desired water quality
 standards at  a net cost of $9 million for the river basin.  The least effi-
 cient policy  in meeting all  quality standards was solution d, which taxed
 only nitrogen.  This policy  resulted in a net social  cost of over $1 mil-
 lion.   Net farm income would actually be decreased by even larger amounts
 in each case, due to the  additional charges to  farmers for water and fer-
 tilizer.
TABLE  22.  INCOME,  RESOURCE USE, AND WATER QUALITY  IMPACTS ASSOCIATED WITH IMPROVED
          MANAGEMENT (IA-27, IA-29 +  IA-12)


Item                       Unit         Base Solution B2     IA-27 + IA-29+IA-12b
Net crop income
Irrigated area
N applied, total
N applied per unit area
N lost, total
Water diverted
Flow at Kiona, August
N concentration, season
N concentration, August
Sediment loss. total
Sediment per irrigated
acre
Maximum temperature
$1 ,000
1,000 ha
1,000 kg
kg/ha
1,000 kg
1,000 ha-m
1 ,000 ha-m
mg/1
mg/1
1,000 mt

mt o
C
106,910
183
42,379
234
1,433
294
12
0.65
0.87
714

1.58
24.2
108,332
183
42,907
234
6,454
271
14
0.54
0.69
341

.75
23.3
a Maximum concentration.

b See Table  3 for description of control  alternatives and practices.
      The net social cost figures include  required  subsidies  that  must  be
 paid to agriuculture in order to meet  specified water  quality  standards.  To
 induce similar changes in cropping patterns,  nitrogen  fertilization levels,
                                      119

-------
or irrigation systems through subsidy programs would require annual costs
equal to net social costs.  It is doubtful that benefits achieved through
water quality improvements to such levels would equal the costs imposed.

     Although it had the highest social  cost, solution f had the lowest
producer cost.   It was some $8.6 million less expensive to the producers
than the next least expensive policy, solution h.   The fact that no taxes or
charges were levied accounts for the low costs to producers imposed by solu-
tion f.

     If subsidies could not be used to meet environmental standards, a
reduction of water rights (IA-34) would probably be considered the next most
acceptable solution by the farm sector, though the capital investment
required for improved irrigation systems would be large.  The only policy
not requiring extensive capital  investment for irrigation systems would be
solution d, although this policy had the highest producer costs of any
policies evaluated.  It would not likely be a politically acceptable way of
meeting the proposed environmental standards.

     Because of their relatively low value, the production of irrigated
pasture, alfalfa, and corn was the first to be reduced by all abatement
policies.  The livestock industry, which was not included in the analysis,
would decline markedly as feed production declined under such policies.
Farm income would also be affected to a larger degree than indicated by the
model results, because livestock was not included in the analysis.

     Labor employment in the farm, agricultural supply, and agricultural
processing sectors would decline under all policies analyzed.  In addition
to farm output, the adoption of improved irrigation systems would lower
irrigation labor demand.  Reduced farm income and its impact on the economy
would also diminish non-farm employment opportunities.

     The watershed model showed that it is possible to improve water quality
in such a river basin by controlling agricultural inputs or activities.
Improvement to a point where water quality is suitable for virtually all
uses of the Yakima River required a reduction of farm income ranging from  16
to 41 percent, depending on the policy employed.  In addition to reduced
farm income, these policies would impose burdens on the agricultural sector
in the form of reduced land values, diminished livestock numbers, decreased
activity employment, and increased capital investments in new irrigation
systems.

     It should be noted that the costs of abatement in this analysis are
valid only as relative values among alternative policies.  The real cost of
any policy might vary from that presented here because of changes in crop
input cost, crop prices, administrative program cost, and level of abatement
desired.  (See Section 3.)

     The historic  pattern of water use in the  Yakima River Basin has
promoted irrigation methods and practices which are not water conserving.
The policy of providing water at a fixed cost  per unit area encourages the
substitution of water for management, labor, and other farm inputs.  This

                                     120

-------
has led to unnecessarily high amounts of surface runoff and deep percolation
loss, depleting the river flow and resulting in water quality degradation.
Under these circumstances, changes in water use policies would greatly
improve irrigation efficiency and river water quality.
                                    121

-------
                                    REFERENCES
Bailey, G.W., A.P. Barnett, W.R.  Payne,  and C.N.  Smith.   1974.   Herbicide
     Runoff from Farm Coastal  Plain Soil  Types.   EPA-660/2-74-017.   U.S.
     Environmental Protection  Agency,  Washington,  D.C.

Bliven, L., e_t al_.  Statistical  Sampling to Evaluate Rural  Water Quality.
     Jour. Environ. Eng. Div., Proc. Amer.  Soc.  Civil Engr.   In  Review.

Brady, N.C.  1974.  The Nature and Properties of Soils  (8th ed.).  McMillan,
     New York.

Carter, H.O. and K.D. Cocks.  1968.  Microgoal  Functions  and Economic  Plann-
     ing.  Amer. J. Agr. Econ.  pp. 400-411.

Chapra, S.C.  1980.  Application of the  Phosphorus Loading  Concept  to  the
     Great Lakes.  In:  Phosphorus Management Strategies  for Lakes,  R.C.
     Loehr, C.S. Martin, W. Rast (eds.).  Ann Arbor Science, Ann Arbor,
     Michigan,  pp. 135-152.

CNI.  1967.  Conservation Needs Inventory.   U.S.D.A./Soil Conservation
     Service, Washington, D.C.

Davidson, J.M., G.H. Brusewitz,  D.R. Baker  and A.L. Wood.   1975. Use  of
     Soil Parameters for Describing Pesticide Movement  through Soils.   EPA
     $00/2-75-009.  U.S. Environmental Protection Agency, Corvallis, Oregon.

Ditoro, D.M.  1980.  The Effect of Phosphorus Loading on  Dissolved  Oxygen  in
     Lake Erie.  In:  Phosphorus Management Strategies  for  Lakes, R.C.
     Loehr, C.S. Martin, W. Rast (eds.).  Ann Arbor Science, Ann Arbor,
     Michigan,  pp. 191-206.

EPA Guidelines.  1976.  Guidelines for State and Areawide Water  Quality
     Management Program Development.  U.S.  Environmental  Protection Agency.
     Washington, D.C.

Gossett, D.L.  1975.  The Economics of Changing the Water Quality of Irriga-
     tion Return Flow from Farms in Central Washington.   M.S. Thesis.
     Washington State University.

Haith, D.A. and L.J. Tubbs.  1978.  Modeling Nutrient Export in  Rainfall  and
     Snowmelt Runoff.  In:  Best Management Practices for Agriculture  and
     Silviculture, R.C.Tbehr, D.A. Haith,  M.F.  Walter, C.S. Martin,
     (eds.).  Ann Arbor Science, Ann Arbor, Michigan.


                                    122

-------
Honeycreek Report (Draft).  1979.  U.S.  Army Corps of Engineers,  Buffalo
     District.

Law, J.P. Jr., and H. Bernard.  1975.   Impact of Agricultural  Pollutants in
     Water Uses.  Trans, of ASAE.  1354:474-478.

Nicol, K.J., E.O. Heady and W.C. Madsen.  1974.   Models of Soil  Loss,  Land
     and Water Use, Spatial Agricultural Structure,  and the Environment.
     Card Report 49T, The Center for Agricultural  and Rural  Development,
     Iowa State Univ., Ames, Iowa.

Pfeiffer, G.H.  1976.  Economic Impacts  of Controlling Water Quality in an
     Irrigated River Basin.  Ph.D.  Thesis.  Washington State University.

Stem, 6.  1978.  USLE Parameters.  Soil  Conservation Service.   Medina, Ohio.

Thomann, R.V. and J.E. Segna.  1980.  Dynamic Phytoplankton -  Phosphorus
     Model of Lake Ontario,  pp. 153-190.

Triplett, G.B., D.M. VanDoren, and S.W.  Bone.  Dec.  1973.   An  Evaluation of
     Ohio Soils in Relation to No-Tillage Corn Production.  Ohio  Agricul-
     tural Research and Development Center.  Bulletin 1068.

Venice Township survey, Seneca County, Ohio.  Nov. 1976.   A Summary of
     Economic Data from the Agricultural Practices Survey  by G.  Becker and
     D.L. Foster.  Dept. of Agric.  Econ., Ohio State University.

Von Rumker, R.  et al_.  1975.  Production, Distribution,  Use and  Environ-
     mental Impact Potential of Selected Pesticides.  EPA  540/1-74-001.

Water Quality Data for Material Transport Stations.   1978.  Lake  Erie  Waste
     Management Study.  Technical Report Series, U.S. Army Corps  of
     Engineers.  Buffalo, New York.

Wineman, J.J., W. Walker, J. Kuhner, D.V. Smith, P.  Ginberg and S.J.
     Robinson.  1979.  Evaluation of Controls for Agricultural  Nonpoint
     Source Pollution.  In:  Best Management Practices for Agriculture and
     Silviculture, R.D. Uoehr, D.A. Haith, M.F.  Walter and C.S.  Martin
     (eds.).  Ann Arbor Science, Ann Arbor, Michigan,  pp. 599-624.

Wischmeier, W.H. and D.D. Smith.  1978.   Predicting Rainfall Erosion
     Losses - A Guide to Conservation Planning.   USDA, Handbook  No. 537,
     Washington, D.C.
                                     123

-------
                                  APPENDIX  A

          ESTIMATING NONPOINT  SOURCE  SEDIMENT AND NUTRIENT LOADINGS
                         FROM  NON-IRRIGATED CROPLANDS
                           L.J. Tubbs  and  D.A. Haith
                                   SECTION  1

                                 INTRODUCTION
     The selection of  best  management  practices  (BMPs) for agricultural
systems should be based on  considerations  of the economic, institutional,
and water quality impacts of  each  management scheme.   This report provides a
means for estimating the  amounts  of  crop  nutrients which may enter surface
and groundwater systems from  various cropping situations in the eastern and
central United States.  These  estimates may  be used directly to predict
average, annual nutrient  loadings  from an  existing or proposed cropping
system, or they may be combined with economic models  to determine the
distribution of management  practices which efficiently meets water quality
objectives.  Although  the nutrient loading estimates  provided in this  report
are for individual fields under a single  crop and cropping practice, a farm
or watershed system may be  analyzed  by summing the loading estimates for
each field in the system.

     Several  mechanisms for nutrient loss  from cropland into receiving
waters are described in Figure A-l.   These mechanisms may be divided into
field processes, transport  or  delivery processes, and stream processes.
Nutrient simulation models  are often divided along these lines, resulting  in
separate predictions of edge-of-field  loadings,  nutrient and sediment
transport, and surface water  impacts.   This  report is concerned only with
the first two processes,  which will  be considered separately.  Referring to
Figure A-l, direct runoff  (surface runoff  plus interflow or subsurface
runoff) may contain dissolved  forms  of nitrogen  (N) and phosphorus (P), and
provides a means for transport of solid-phase N and P in eroded soil.
Percolated water may carry  dissolved nutrients below  the root zone to
underground aquifers.  Dissolved  N in  groundwater may later reappear with
baseflow in streams.   Dissolved P in deep  percolation does not usually reach
surface waters due to  the adsorption of phosphorus by soil particles below
the root zone.

     The most general  method  for  estimating  nonpoint  source nutrient losses
is through the use of  mathematical simulation models.  However, such models


                                     124

-------
can be difficult to apply  since  they  require  a great deal  of data and
intimate knowledge of the  soil and  crop  environment  being  modelled.
Furthermore, available  simulation models typically have high start-up costs
associated with specialized  computer  programs.  In order to capture the
flexibility of simulation  within  an  approach  that can be applied relatively
easily by a water quality  planner,  the  Cornell Nutrient Simulation  (CNS)
model was run for ten-year periods  using cropping and meteorologic  data from
27 climatic areas in the eastern  and  central  U.S. (Figure  A-2).  Within each
area, variations in soil water and  fertility  parameters were made,  and
the results obtained were  average annual water and dissolved nutrient losses
to edge-of-field.  To facilitate  their  usefulness, the simulation results
were summarized as predictive equations  for runoff,  percolation, and
nutrient concentrations.   Independent variables in the equations are curve
number (as in the U.S.  Soil  Conservation Service's runoff equation),
fertilizer applications, and soil nutrient levels.  These  predictive
equations are analogous to the Universal Soil  Loss Equation (USLE), although
they are based on simulated  rather  than  actual field experiments.

     Although comparable simulation  procedures could have  been used to
derive general predictive  equations  for  solid-phase  nutrient losses, simpler
methods are available for  estimating  average  annual  losses.  Since  the USLE
provides estimates of average erosion rates,  these soil losses can  be
multiplied by N and P concentrations  in  sediment to determine annual solid-
phase nutrient losses.  Concentrations  in sediment are equal to  in  situ soil
concentrations multiplied  by enrichment  ratios to account  for the selective
erosion of small  organic matter  and  clay particles which have higher
nutrient contents than  other soil constituents.  This procedure  for
estimating solid-phase  nutrient  losses  assumes that  levels of soil  N and P
do not change significantly  from year to year.

     The remainder of this report consists of three  sections and several
appendices.  Section 2  documents  the  simulation experiments and  their
results which were used to derive location-specific  predictive equations for
runoff, percolation, and dissolved  nutrient concentrations.  Section 3
combines these results  with  the  USLE  to  provide a general  methodology for
estimating nonpoint source nutrient losses and evaluating potential best
management practices for their control.   The  methodology is demonstrated in
the final chapter by analyses of selected sample fields as well  as  an actual
watershed  (Honey Creek, Ohio).   The appendices describe the CNS  model and
its application to the  27  climatic  areas.

     The methodology in this report  presumes  familiarity with, and  access
to, two primary reference  sources:
     1.  Stewart, B.A., Woolhiser,  D.A., Wischmeier, W.H., Caro, J.H., and
         M.H. Frere, Control  of  Water Pollution from Cropland -  Vol. I and
         _H, Report No. EPA-600/2-75-026a (Vol I), EPA-600/2-75-026b (Vol
         II), U.S. Environmental  Protection Agency,  Washington,  D.C., 1975,
         1976.

     2.  Wischmeier, W.H.  and D.D.  Smith, Predicting Rainfall Erosion Losses
         - A Guide to Conservation  Planning,  Agriculture Handbook No. 537,
         U.S. Dept. of  Agriculture,  Washington, D.C., 1978.

                                     125

-------
o
5
<
UJ
                                                                         CO
                                                                         uj
                                                                         w
                                                                         co
                                                                    H-   O
                                                                    co   Q:
                                                                         CL
                                                                    a:
                                                                    O
                                                                    a.
     co
     LL)
     CO
     CO
                                                                         O
                                                                    <   O
                                                                    cr   cc
                                                                    UJ
    co
    UJ
    CO
    CO
    UJ
    o
    o
    a:
    Q.
                                                                                                to
                                                                                                l/l
                                                                                                o
                                                                                                 O
                                                                                                O-
                                                                                                 oo
                                                                                                 E
                                                                                                 co
.
 O
 cu
                                                                                                 OJ
                                                                                                 S-
                                                126

-------
Figure A-2.   Climatic Regions for Model Runs.
                            127

-------
                                   SECTION  2

            USE OF THE CNS MODEL  TO  DEVELOP  PREDICTIVE EQUATIONS
                FOR WATER LOSSES  AND NUTRIENT CONCENTRATIONS
CNS MODEL DESCRIPTION

     The CNS model computes water  and  nutrient balances for two adjacent
soil layers at depth 0-10  cm  and  10-30 cm (Figure A-3).  Soil water contents
of the two layers are updated  daily, with any excess water over field
capacity in each  layer  percolating  below that layer within one day.  Direct
runoff on each day is predicted through the  use of a modified form of the
U.S. Soil Conservation  Service's  curve number equation (Mockus, 1972),  and
is a function of  soil water content, rainfall plus snowmelt, and crop curve
number (CN).  Solid-phase  and  dissolved N and P balances are maintained for
the upper soil layer and a dissolved N balance is kept for the lower soil
layer.  Nutrient  levels  are updated monthly,  and losses in runoff  and
percolation are computed as functions  of the  average soil  nutrient contents
during the month  and total monthly runoff and percolation, as obtained  from
the daily soil water model.   The  model operation is summarized in  Figure A-4,
and the model equations  are listed  in  Appendix I.

     The CNS model presented  a number  of advantages for use in this study:
1) the model may  be  adjusted  to simulate any of the major crops in the
eastern and central  U.S.;  2)  it does  not require calibration with  water
quality data; 3)  low cost  runs are possible  for simulation periods suf-
ficiently long to estimate long-term average losses; and 4) model  parameters
may be approximated  using  readily available  secondary data sources and/or  by
limited sampling  in  a study area.   The primary disadvantages of the model
are:  1) some nutrient  loss mechanisms (particularly ammonification and
dentrification) are  not included;  2)  the model is valid only for soils  not
limited in drainage  by  a fragipan or otherwise impermeable layer;  and  3) the
model has not been extensively validated, although validation studies  have
been performed for manure-spread  corn  in New York and for corn in  Georgia
(Appendix I).

     The limitations of the CNS model  also indicate limitations in the
nutrient loss predictive equations derived from the model  results.
Specifically, the predictive  equations are only applicable to soils that are
unrestricted  in drainage,  and ammonification and denitrification losses must
be subtracted from fertilizer or  manure nitrogen inputs before applying the
predictive equations.   The final  problem is  most relevant if the equations
are used to generate exact loading estimates from an existing or proposed
cropping scheme.  In this  case, field  monitoring or water quality  sampling
may be necessary  in  order  to  support  the accuracy of the predictive
                                      128

-------
PRECIPITATION
 RAIN
      V
           SNOW
           EVAPORATION  AND
         EVAPOTRANSPIRATION

          4   4       DIRECT  RUNOFF
                         MELT
        (soil water)
            SHALLOW  PERCOLATION

        ( soil water)
              DEEP PERCOLATION
                                                 10 cm
                           20 cm
 FERTILIZER     PRECIPITATION
 INORGANIC N    INORGANIC  N
           MANURE
         INORGANIC N
     (organic n)
     (inorganic  n)
  MANURE
ORGANIC N
              INORGANIC N  IN
          SHALLOW  PERCOLATION

     (inorganic n)
                       v
              INORGANIC  N  IN
            DEEP  PERCOLATION
CROP N
UPTAKE
                                     /
             INORGANIC N
             IN  RUNOFF
                           10 cm
                           20 cm
  Figure A-3.  Soil water  and nutrient balances in the CNS model.

                           129

-------
             FERTILIZER
             AVAILABLE  P
MANURE
AVAILABLE  P
 V1       >'
(available  p)
                            CROP  P
                            UPTAKE
DISSOLVED  P
IN RUNOFF
                DISSOLVED  P  IN
              SHALLOW  PERCOLATION
                                                   10 cm
                                             20 Cm
                   Figure A-3.  (Continued)
                             130

-------
 DAILY SOIL WATER MODEL
                                    MONTHLY NUTRIENT MODEL
Inputs
Daily precipitation (cm)
Daily average air temperature

Crop development dates - (Julian)

   Planting
   Emergence
   Full canopy attainment
   Harvest

Soil available water capacity(cm/cm)
Crop curve numbers
 Intermediate Outputs
    Daily soil  water levels (cm)
    Evaporation and evapotrans-
      piration (cm)
    Snow accumulation and melt (cm)
    Daily canopy development
Final  Model Outputs
    Daily direct runoff (cm)
    Daily percolation (cm)
                                         Inputs
                                         Monthly runoff and percolation (cm)
                                         Fertilizer and manure N and P
                                           (kg/ha-yr)
                                         Soil  organic  N and available P
                                           (kg/ha-10 cm)
                                         Crop  development dates - (Julian)
                                            Emergence
                                            Maturity
                                         Yearly crop N and P uptake
                                           (kg/ha-yr)
                                                                o
                                         Soil  bulk density (g/cm )
                                         Soil  clay content(%) and pH
                                         Yearly mineralization rate (%)
                                        Intermediate Outputs
                                           Average monthly soil levels of
                                             dissolved N and dissolved P
                                             (kg/ha-10 cm)
                                           Monthly crop N and P uptakes
                                             (kg/ha)
                                           Monthly organic N mineraliza-
                                             tion (kg/ha-10 cm)
                                        Final Model Outputs
                                           Dissolved N in runoff (kg/ha-mo)
                                           Dissolved P in runoff (kg/ha-mo)
                                           Dissolved N in percolation
                                              (kg/ha-mo)
             Figure A-4.  Flowchart of the CNS model operation.
                                     131

-------
equations.  However,  if  the  equations  are  to be used to judge the relative
effectiveness of alternative measures  for  reducing pollutant losses,
particularly in an economic  analysis,  this sampling may not be needed.

CNS MODEL  IMPLEMENTATION

     The CNS model as presented  in  Appendix I may be utilized directly to
generate edge-of-field nutrient  losses  given the appropriate meteorologic,
crop practice, and soils  data  for  a specific field.  However, direct
implementation of the CNS model  is  time-consuming and requires a detailed
understanding of the  model  interactions.   To overcome this difficulty, the
CNS model was run for a  large  number of cropping situations In the eastern
and central U.S., and the results  generalized into predictive equations for
edge-of-field loadings as a function of a subset of the model inputs.  In
this way, the operation  of  the CNS model  in converting the input parameters
into model results is replaced by  the predictive equations (Figure A-5).

     In order to apply the  model over a large area while retaining the
sensitivity of the model  to  local  crop  and weather characteristics,
randomized meteorologic  records  and generalized field practice data was
substituted for specific  field data inputs.  Daily values for precipitation
and average temperature  were generated  stochastically using a first-order
Markov process (see Appendix II) fitted to the meteorologic characteristics
of the 27 geographic  regions in  Figure  A-2.  These regions were selected for
both consistent meteorologic characteristics (amount and timing of precipita-
tion and average temperature)  and  agricultural  practices within each  region.
The simulation period for each run  of the  model was selected to assure
results which approximate the  long-term average losses that would be
predicted by an infinitely  long  simulation.  It was found that ten-year
simulations generated average  nutrient  loss levels that fell consistently
within _+ 5% of those  generated by  25- or 50-year runs.  Therefore, the
simulation period was set at ten years  for all  crops in each region.

     Soil organic N and  available  P levels were reinitialized to the  same
fixed values at the beginning  of each model year, whereas initial inorganic  N
levels in both soil zones were set  equal  to the ending levels for the
previous year (i.e.,  inorganic N levels are not reinitialized).  However,  the
carryover of inorganic N  from  year to year was relatively small.  The
simulation results aproximate  steady-state cropping systems and do not
reflect long-term buildup or depletion  of  soil  nutrients.

DERIVATION OF THE NUTRIENT  LOADING PREDICTIVE EQUATIONS

     Each  input parameter to the CNS model falls in one of three categories,
according  to its  effects  on  the  model  outputs:  1) parameters which are fixed
or whose variations have  a  minimal  effect  on predicted nutrient loadings;  2)
parameters which  interact according to a linear or other easily defined
function with model outputs; and  3) parameters which affect loading estimates
in a non-uniform  (but significant)  fashion.  For example, the concentration
of dissolved N in precipitation  is  fixed for any area, while fertilization
rates vary substantially from  one  cropping system to another, and directly
affect estimated  dissolved  N or  P  loss  in  runoff and percolation.

                                      132

-------
Figure A-5.   Relations  of the  CNS  model  to  the predictive equations.
fixed
inputs
                      variable  inputs
                                          \
                                           \
 individual  field
  characteristics
  field-specific
  parameter values
                                                  predictive
                                                   equations
            predicted  nutrient
                 loadings
  field-specific
nutrient loadings
                               133

-------
     Table A-l classifies  the  various  model  inputs according to this  scheme,
for any crop and geographic  region.  The  fixed parameters are not included  in
the predictive equations,  because  they are assumed not to vary significantly
between different management options for  a specific crop.  The nonuniform
parameters cannot be  related mathematically to the model results, but  have  a
substantial effect on the  levels of  nutrient losses.   Consequently,
predictive equations  must  be derived for  a range of each of these nonuniform
parameters in each geographic  region in order to capture their effects  on
edge-of-field loadings.  This  is  reflected in the organization of Appendix
III, where, for each  crop  and  region,  equation coefficients are presented for
all combinations of tillage  dates  (spring or fall), fertilizer application
dates (spring or fall),  soil hydrologic group (A, 8,  C, or 0), and a  range  of
soil available water  capacities  (.05,  .10, .15, and .20 cm of water/cm  of
soil).

     The remaining input parameters  may be related directly to the model
results for any chosen  values  of  the fixed and nonuniform inputs.  These
relationships (the predictive  equations)  were designed for simplicity  in
application and for sensitivity  to variations in local field characteristics.
Average annual runoff and  percolation  as  a percentage of yearly precipitation
is  related to crop curve number  by:
                          %R  =  a  CN  +  b
                          %P  =  a'  CN + b'
                                                                    (1)

                                                                    (2)
where %R
      %P
           average  percent  of  annual  precipitation appearing as  direct  runoff
           average  percent  of  annual  precipitation which percolates  below  30
           cm.
CN =
                   m —
                      where
                                   = crop curve number for average  soil
           moisture  (antecedent  moisture condition II)
      a, b,  a',  b'  = constants for each crop, soil, and cropping  practice

Runoff  and percolation  percentages may be multiplied by the  average  annual
precipitation  at  a  specific  location to obtain average annual  runoff  and
percolation,
                                  m
                           P -
                                    (Pr)

where R  =   average  annual  direct runoff (cm)
      iP_ =   average  annual  percolation (cm)
      Pr =   average  annual  precipitation (cm)
                                      134

-------
TABLE A-l.  CLASSIFICATION OF CNS MODEL INPUTS ACCORDING TO THEIR
            INFLUENCE ON PREDICTED NUTRIENT LOADINGS
FIXED INPUT PARAMETERS:
     Meteorologic data
     Dates of crop development
     Crop N and P uptakes
     Mineralization rates
     Dissolved N concentration in precipitation

PARAMETERS WHICH VARY MODEL OUTPUTS CONTINUOUSLY:
     Crop curve number
     Fertilization rates of N and P
     Soil organic N and available P contents
     Soil P adsorption capacity
     Soil bulk density

PARAMETERS WHICH VARY MODEL OUTPUTS NON-UNIFORMLY:
     Soil available water capacity
     Soil hydrologic group
     Timing of fertilizer application
     Timing of tillage operations
                                    135

-------
                                    ?
The coefficient of  determination (r )  between %R and CN and  between  %P  and CN
was greater than  0.99  for  all  modelled crops and regions.

     Similarly, the following  predictive equations approximate  the  relation-
ship between the  CNS model  input parameters and average annual  dissolved  N
concentrations  in runoff  and  percolation and average annual  dissolved  P
concentration  in  runoff.
         KRN =  a0  +  ajCN  + a2FN + a3SN + a4FNCN + a5SNCN           (5)


         KPN -  bg  +  biCN  + b2F|\| + b3S|\| + b4FNCN + b^CH           (6)

                        A                       >S        A
       KRP = YP(CO + qCN + c2Fp + C3Sp + c4FpCN + csSpCN)         (7)
where KR|\| =   average  concentration of dissolved N in  runoff

          =   average  concentration of dissolved N in  percolation  (mg/Jl)

          =   average  concentration of dissolved P in  runoff  (yg/Ji)
                                                                 r\
      FN  =   annual fertilizer and manure inorganic N  input  (10  kg/ha-yr)

      S|\j  =   soil  organic  N in the surface 10 cm (103  kg/ha)

      Yp  =   adjustment  factor for soil  P adsorption  capacity  (dmless)

      Fp  =   annual fertilizer and manure available P  input  (kg/ha-yr)

      Sp  =   soil  available P  in the surface 10 cm (kg/ha)

      a-j , b-j ,  c-j  = constants  for each crop, soil, and  cropping practice

     The choice  of units for FN, Fp, S|\j, and Sp are such  that  the constants
a-j, b-j,  and c-j may have  the same approximate order of  magnitude,  for ease in
presentation  in  Appendix III.   The coefficients of determination  (r2) between
KRN and  the  right-hand  terms of equation 5 and between  Kp^  and the right-hand
terms of equation 6 are  greater than 0.97 for all crops  and  regions modelled,
and the multiple  correlation coefficient for equation  7  is  always greater
than 0.99.

     The soil  P  adsorption capacity  adjustment factor yp  is  a fraction of
soil bulk density p and  the phosphorus adsorption coefficient  e,  which in
turn is  a function of soil pH  and clay content:
                                      136

-------
               g =  5.1  +  2.2(%C)  + 26.4(pH - 6.0)2                 (8)


where 3 = soil adsorption  coefficient  for available P ( •; ,„ )
                                                        mg/ X

      %C = percent  clay content  (soil  particles < .002 mm) in the  surface  10
           cm of soil

      pH = average  pH of  surface  10 cm of soil

     In generating  values  for  the coefficients in equation 7, the  CNS  model
was provided with  reference  values for soil  bulk density p of 1.3  g/cm , clay
content of 15%,  and  a  pH  of  7.0,  yielding a value for 3 of 65       .   The
                                                               my /
factor Yp captures  the  effect  on dissolved P concentrations  in  runoff  of
differences  in p  and  3  from  these reference values:


        v  -  (1.3)  (65)  _  84.5
        YP "   p  3        ~P~T
                                   Sl
Methods for  determining  values of CN,  F^, Fp, S^, Sp, and yp and  for select-
ing the appropriate equation coefficients from Appendix III  based  on field
characteristics are detailed in Section 3.

DATA USED IN  THE  CNS  SIMULATIONS

     This section details  the  data acquisition methods for all  runs performed
with the CNS  model.   The appropriate methods for selecting values  for  each
input parameter to  the  CNS model  are dependent on the relationship between
that input parameter  and the model results.  Referring back  to  Table A-l,  the
procedures for data acquisition are different for the fixed, continuous,  and
nonuniform input  parameters.

Fixed Input  Parameters

     The fixed parameters  in this application of the CNS model  do  not  vary
between simulations of  different management options, although there will  be
differences  in the  parameter values among geographic regions.

Meteorologic  Data--

     The meteorologic models in Appendix II require input data  for average
precipitation and number of  days with  precipitation by month, and  average
summer and annual air temperatures.  Data was obtained from  a single source
(National  Oceanic and Atmospheric Administration, 1974), which  summarizes the
meteorologic  characteristics of a number of weather stations in each of the
fifty states.  For  each  geographic region in Figure A-2, one station was
selected to  provide precipitation and  temperature data for that region
(Tables A-2  and A-3).
                                      137

-------
o
CD
LLJ
C£

^_
§§
i—
oo
-j_
CJ
LU
a:
O
u_
o


^
z:
Q
i — i
<
I —
i — i
a.
o
LU
a:
a.
^
-^

oo
>-
ct
a

LL*.
o

Qi
LU
^
^
—^

O
^
^ 	 ^
g
•^
p^
1 — 1
I—
1 — t
Q-
i— (
CJ
. 1 1
a;
n

1 1 1
CD

fy^
LU

^^


^
C\J
1

LU
-_J
CO
-•^^
! —


i — =3-
rO
-l-> OO OO
O «3- cn

cn
Q • LO
o
«3-
'Z. • LO
i —
cn
O • LO
CM
0
oo • to
oo
0
<: • oo


CM
•-D • cn
LO

JC LO
•4-> -O -00
C 00 r—
o
s:

21 • CM


I—
<: • co
LO

1^
s: • cn
CM

00
u_ • to
0
CM

1

0
•(— •
-(-> Q
(O
+J OO
oo

S- >,
a> -4-> to
-C •!- >>
4-> CJ (O
rC T3

S v- =t*=
Q.
fO

c
o
cn "~
(U
a:


^•O
•
P"*"* ^o
^- o
I —

LO
• CO
1 —
CM
• !*•»•
CM
CM
• to
oo
^.
• cn

cn
• cn
to

cn
• o
LO i—

^_
• f—,
r--. i—


LO
• ,.
LO r—

CO
• 00
^J-

oo
• cn
CM

1^
• CO

LO
• o








•
Q

"^ ^L
fO

o

S_
fC
u_


CM




to
•
OO LO
t~~ oo

cn
• oo
CM i —
LO
• r-~
•=t r-
LO
• cn
LO
oo
• r—
l^r-
(^
• r—
cn i—

0

cn i—

00
• oo
O r—


^*
• 00
00 •—

o
• r—
IO i —

, —
• r—
*^t" i —

^f-
• O
CM i—
cn
• CM
CM i—





•
c

• p-
21 to
>^
•> (O

1 •*
3 =tfe

~1
Q


OO




, —
t
«* oo
tocn

,^
• to
•""
CO
• LO
CM
^
• 10
oo
,_J_
• r^^-
^
00
• o
CO r—

to
• o


co
• 1 — -
O r-


to
• o
CO r—

o
• CO


«^-
• cn
oo

cn
• to
*~
CO
• LO
1

.
a
•
00

1\
to
r—
i — tO
fO >,

-a
X
3 =tt=
0
•r-
oo


•*




LO
•
00 CM
Tl

, —
• cn
oo
to
• en
"^
cn
• r~^
•=*"
rv>
• CO
cn
«_,.
• cn
00

CM
• CM
CO •—

00

cn i—


oo
• CM
CO r—

cn
• cn
LO

i —
• CM
^" r—

00
• to
CM
j 	
• CO
oo



•
o
to

"^:

" to
0) >,
tO fC
to "O
0
t- "-tfc
CJ
to



LO




to

^ cn
^t-r^

o

•~
^
• to
"~
to
• LO
CM
^_
» «^J"
"*
^.
• cn
LO

, 	
• 00
to

•vf
• cn
p^,


00
• cn
to

CM
• CO
LO

OO
• to
CM

cn
• LO
o
0
• to
1



•
.a
a;


*
 >-J
4-> rt3
fO "O
r—
Q. ^

•
z


to




LO
•
«d- to
to co

LO
• «^J-
•~
cn
• LO
CM
^f.
• to
•*
CM
• r^
to
, 	
• cn
CO

to
• 00
CO

f^
• 0
CT!5 r—
i —

CM

cn r—

1^^
• cn
LO

^J-
• r^.
oo

CM
• LO
CM
LO
• LO
1


•
to
c
to


f
IO tO
•r- >>
T3 to
i. -a
o
O =tfe
c
o
CJ


r^




cn

i^x ^j*
CO O

, 	
• psx.
^"
co
• r^*»
"^
cn
• r*^
to
_
• cn
CO
CM
• CO
cn

to
• cn
CO

1 —
. ^->
CM i —
i —

CM
• CM
0 i—

p^.
* r— ~
CO r—

cn
• 0
tO r—

LO
• I**-*
OO
CM
• f^
"*


fO
S
0
1 — 1

«>
c~
O tO
+J 2>y
cn fO
c -O
•r—
r— ^fe
i.
3
CO


00




cn

LO O
«=i- to

t^
• oo
"~
^
• 00
•"
t 	
• LO
LO
o
• LO
to
OO
• to
«3-

, 	
• 00
LO

5^-
• f-^
to


1 —
• 00
00

cn
• ''^
CM

cn
• «^-
1 —

^J-
• ^J~
1
(^
• ^~
^~





•
X
O)
I—
to
« >^
^. to
o -a
0
JO =tfe
r*t
3
_J


cn




CM
•
cn LO
LO to

CM
• ^j-
oo
co
• LO
CM
CM
• LO
1^-
00
• to
LO
^
• LO
OO

00
• LO
LO

CO
• to
to


0
• 00
r~

CO
• 1--.
LO

to
• ^J~
CM

co
. LO
CM
CM
• LO
CM





•
X
>
O) tO
C TD
^
« to
c -o
•r"
+J ^te
to
3
cC


•—
"

138

-------











































•* •»
~o
O)
Z3
C
Ir~
-I-5
£1
O
(— *,
'*—-'*

CvJ
1

LU
^j
CQ
 «3- to
0 00
t ^_ ,__
to
Q . CO
LO
O
•Z. ' CO
^
to
o • r^
cn
cc
t/i • co
cn
•=3"
eC • cn
CO
cn
•-3 • cn
cn
^ CO
•*-> ra • o
C CM r-
O r—
,3.
^* • r-~
OO i—
^.
,
+-> t|_ >
ro ea
-*: -o
S-
ro ~tfc
X
CU
f—


oo
CM
•
cn r — *
CM O
CM
• 0

oo
• CO
0
LO
• i_f")
LO
OO
» p^
LO
OO
• r^.
00
(^
• 1—
^ p~
«_J-
• cn
cn

^
• cn
0
CM
• cn
CM
CO
• 0
LO i —
r— •
cn

CM r—
cn
CM r^



•
to
to

^^
to
H ^j
c: ro
o -o
to
-M =tt=
O
ro
•"3


*

•
•— 0
to CM
to
• 0

CM
• CO
O
oo
. to
cn
CO
• o
•=3- •—
oo
• *^t"
to i—
o
• LO
CO •—
t 	
• oo
^3" r-^
•—
CO
• CT)
oo
CO

OO
^
• cn
to
to
• cn
o
r—
| 	
• O
CM t


ro
	 1

t\
to
c:
ro to

i— ro

O

S
o>
"ZL


LO
CM
•
cn r^^
r~- oo
CM

LO i—
oo
• *^}"
to i—
to
• cn
to
to

l^r-
cn
• i —
to i—
cn
• CO
to
^.
• fx^
00

00
• 00
CO
LO
• oo
r-^ •—
00
• to
LO 1 —
^
• CM
«3- r—
cn
• CM
pf- __
*^ f^^
r-
o
'£

t\
to
-o
•i—
Q. to
ro >,

•o
•o

ro
S-
CJ3


to
00
•
to cn
00 CM

• CM
LO i —
t 	
• o
to i—
^
• 00
to
CO

^
t 	
• oo

oo
• o
00 r-
o
• r-~
cn i—

^.
• CM
CO i—
oo
• oo
CO r—
o
• oo
00 r-
LO
. i—
*3- r-
LO



•o
c
1—4

*
O)
C CO

fO fO
Sg -Q

4-J ^tfe
^,
o
LJ_


^
o
•
i — OO
i— OO
00
• CM
cn r—
o
• o
00 i—
CM
• CO
to
CM
• CO
•^
to
• o
CO •—
00
• r-^
o •—
r—
^
• CM
O r-

o
• CM
cn r-
to
• CM
cn •—
oo
• oo
1— 1—
cn
• CM
CO •—
^
• oo



,
^.^
•*s

ft
c to
o >>
+-> rO
05 T3
C

><
^
to
^.
• CO
to
^
• ^—
CO i—
o
• CM
CM i—
oo
• CM
CO i—

,_
• CM
cn i—
CM

cn i—
oo
• oo
CM i—
o
• CM
CM i—
LO
• oo


s^
c—
CU
1 —

f\
cu to

i— ro
•i- "O

X =*=
o
E
^


cn

•
cn LO
•— •—

• o
^2 "~
LO
• 00
^
CM
• to
to
oo
• 1^
oo
! 	
• cn
cn
o
• CM
CM i—
f^
• 0
cn i—

0
• cn
00
•«*
• cn

to
• CM
OO r—
LO
• o
| 	 .
OO
• "—





,
ro
CD
to

ro (O
•t-> T3
C
ro =fe

40
ct


O
CM
OO
•
to oo
OO i—
LO
• o
r— '
O
• p^.
o
o
• to
to
cn
• CO
CO
, 	
• r~~
CM r—
to
• CM

cn

r~— f—
•—
CO
• CTl
CO
CM
• CO
CM
LO
• O
IO i—
0
• O
CM i—
^
• •—


ro

e-^

^
>_
S- to
CU >5

o -a
Ol
•M =«*=
c
0
s:


CM
0
•
CM i—
cn to
LO
• CO
to •—
^j.
• *^J~
to i—
CO
• r—
r^ r—
LO
• cn
^
i —
• ^~
cn i—
^.
• o
cn •—
CO
• | 	
cn .—

cn
• oo
co •—
LO
• ^~
[^ r-
oo
• to

LO
• LO
LO r—
^.
• l~~-


>!
.
^y

».
C~
O tO

E to
to ~a

O1-:fr;
C
•1 —
ca


CM
CM
139

-------















































*•""«*
-o
~i
c
•r—
j *
C
o
o
^_^

CNJ
1
<<
UJ
i
ca
ec
t-
i— CO
rd
+J CO LO
O O CM
CO
Q • r—
cn ,—
10
s: • CM
O r-
__
o • cn
CO
cn
00 • CO
CO
( 	
>
4-> C rO
rd ro "O
0) •—
3 4-> ^
^
O
Q.

C
O
•i- CO
CD CM
a>
a:

*
cn ro
CO CO

• CM
UD r—
cn
• CM
VO r-
o
• CO

t 	
• cn
cn
CO
• o
^^ n~

cn

CO ^

CO
• r—
CO r-


CO
• CO
CO i—
o
• CM
r^ r-
cn
• CM
tO r"*"
to
• ^~
LO I —
CO
• CO
tO i—





>_
z: to
^_
» ro
^} ^5
C
rO =fe
t~\
r—
>
O ro
E "O
• r—
-M =«=
i— ~
ra
ca



LO
CM


CO
•
O LO
CO i—

• cn
CO
00

f^-
to

lv-
o
• cn
to
^
• CM
1^ r—
i —
LO
• ^J-
cn •—
• —
CO
• CD
O •—
^~

cn
• cn
CO
ro
• CO
rv-
CM
• 0
O r—
^
• 0
CO r—
CM
• O



C_)
"^^

c
o to
*P ^)
CD ro
C ^D
tf_
£ ^ffr:
r*—
*r—
S



^O
CVJ


0
*
•— CO
co o
co
* ^O
•*
^
• LO
CO
t 	
• CO
^
LO
• CO
I^""
cn
• r^
O r—
CM
cn
• r~-
r^ r—
CM
LO
• CM
CO r-
r—

CM
• **o
rs"
CM
• LO
^
LO
• f^^
cn
CM
• r^
rs-
^
• to
LO





ro
I — tO
U_ >,

** "O
ro
Q_::te
E
ro
I—



I*"*",
C\J


140

-------
TABLE A-3.  AVERAGE JULY AND AVERAGE ANNUAL TEMPERATURE (°C)  FOR EACH
            STUDY REGION

Region

1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
Average
July
22.4
21.8
18.6
23.8
23.3
24.3
26.7
24.8
26.4
28.4
29.3
26.0
28.1
27.8
28.6
22.4
23.1
24.8
25.8
26.1
27.3
20.2
20.1
22,3
24.9
26.7
27.8
Temperature
Annual
8.2
4.0
2.8
6.9
7.1
9.9
12.2
10.3
15.2
17.7
19.8
13.4
17.7
18.4
20.9
8.9
9.9
12.9
15.2
16.6
18.4
7.8
7.2
8.6
13.2
17.8
22.0
                                    141

-------
Dates of Crop Development--

     Normal ranges  of  the  dates  of  planting and harvest by state for  each
crop were obtained  from  published  data (U.S.  Department of Agriculture,
1972).  The dates of planting  and  harvest for all  years of the simulation  in
each region were fixed at  the  mean  dates  for  the states contained  in  each
region (Table A-4).  Hay is  grown  continuously throughout the year, and
nutrient uptake was assumed  to occur from 30  days  before first cutting  until
the last cutting in the  fall.   Dates of crop  emergence, full canopy
attainment, and crop maturity  were  determined by adding a fixed crop  develop-
ment period for each crop  to the date of  planting.  For example, crop
emergence for corn  in  each  region  occurs  approximately 14 days after  planting
in that region, and full  canopy is  reached 75 days after planting.  Further
crop development data  is  given in  Table A-5.   The  variation in time to
maturity for corn by region  is due  to the use of shorter-season hybirds  in
the northern U.S.

Crop Nutrient Uptakes--

     The CNS model  computes  dissolved N and P uptakes by month as  a function
of total yearly crop uptake  and  a  crop development curve fitted to the  dates
of crop development (see Appendix  I).  Average crop yields by region  were
obtained from a recent agricultural  census (U.S. Department of Agriculture,
1977) and were combined  with crop  nutrient contents (Martin and Leonard,
1967) to determine  the yearly  nutrient uptakes presented in Table  A-6.   For
corn, the yields for silage  were used to  determine crop uptakes.   If  corn  is
harvested for grain, the N and P remaining in the  stover will return  to  the
field in both organic  and  inorganic  forms.  Consequently, all N and P  remain-
ing on the field in crop residues  are to  be added  to the amount of these
nutrients applied in fertilizer  or  manure in  each  year.  A substantial  frac-
tion of the nitrogen needs  of  leguminous  crops is  met through fixation  of
atmospheric N.  It  was assumed in  the operation of the model that  a legumi-
nous crop will utilize any available inorganic N before fixing atmospheric  N.

Mineralization Rates —

     The rate of nitrogen  mineralization  from organic to inorganic N  is
roughly proportional to  average  temperature,  and ranges from 2% to 4%  per
year  (Brady, 1974).  Therefore,  mineralization rates were chosen for  each
region which reflect the average annual temperature of the station represent-
ing that region.  The  rates  used in the CNS model  runs are summarized  in
Table A-7.

Dissolved N in Precipitation--

     The amount of  dissolved N in  precipitation, although small, will  affect
the concentrations  of  N  loss in runoff and percolation for crops which  are
fertilized at low levels.   The total yearly loadings shown in Figure  A-6
(McElroy, _et _al_., 1976)  were divided by average annual precipitation  in each
region to determine the  average concentration of dissolved N in precipitation
in each  region.  The dissolved N input from precipitation in each  month  of
the simulation was  then  equal  to the total precipitation for the month  times
the average concentration for  the  region.

                                      142

-------











o
CJ3
LU

O
^
O
•-3
a:
o
LL_
| —

LU

o:
^
O
^
Z

1 —
eC

GI-
LL.
0
oo
LU
1
LU
1
__J
ff^
h-
QJ
i > ^
-T— * ^
(C i-
Ol 
00 C
D.
O
i"V +J
O CO
"O CD
C >
LU S-
ra
31
«*
:n
-|_>
C CO
•i- Ol
Cn >
01 S-
CQ n3
^

i^
QJ


1C
c:
S-
o
4J
fO

O
LU

V^^ |
CO 00


LO LO

fT\ ON
\J » W t
LO LO O
,—_ rm. ^\j
Of — i t — i
*^-J IM*





^O ^«O ^.D



0 0
CM CXI LO

'CTi CTi CTt



0 0
i — 1 — LO
^\ " — *^>»
tO IO U3




---,^.^.




LO
^~ r-~ C\j


r— CM CO


1 1 \ v~,^~-
r-r^r^


LO
CM CM ^^

LO O O O O
Of — \ ( — \ ( — \ f—\
k_^ l»_J \^^f \^_J









LO J — i— LO
I— r— "**+^ ^^^ n—
~-^^o o ^^
en cy> i — i — cr>



OOO
i — LO CM CM CM
"^^ ^^* "^^ ^^ ^^
CO U3 LO LO LO









O O O O LO


<^- LO  1^ CO

O O LO O O LO LO

10 lo^oioio r--i^


LO LO

O O O O O 1 1 O O
LO LO LO LO






000



LO
r— r— O
*^* " — CM
1 1 1 O I i I O ~-^
i — i — CTl



LO O
i — i — CM
1 1 1 -^^ 1 1 1 -"^ -^^
LO l£> LO



O 00
Of""} t — 1 f"~l f~"} t — 1 t — 1 r— ^~
**— J \~-J ^-/ ^__J (^ J \^J ^^ ^^



LOLOLO LOLOOLOLO


CTlOi — CMCO^-LOW3I —

LO LO O
f— . f/\j p |— f—ff f— _

f^s, V.Q ^Q oo r**^ r**^


OOO LO O
r^ C\J OJ CD C\J r—

CD CD CD 1 "^». 1 1 CD CD 1
LO LO LO LO LO
r— . ,__ f\j f— tO f~" r—
CD i — CD CD 1 1 1 n— r-— CD





o o
LO i LO i-~* C\J r-~ r—



o
LO i— i— O O 00 i—
^™* "*^s^ **^s. r~~ OJ "^-s^. **^^
^--x CD l 1 CD *"*»*. "*^x. CD CD I
o^ i — r— cr» cr^ i — i —



LO LO LO
r^ I — C\J LO I"- i — CM
"^V. "^^s. 1 1 *"*^N "***^ "^^ '"*fc^. """^ 1
LO LO LO VO  (— \ —^ _^_ * — \ y— \ «.s.
t_j ^_j i^^ ^_j ^™ r^~ t^^ ^j ^^.



LO LO O




143

-------
o:
O-

O
LxJ
Q-

O
   co
  « t/0

UJ   •

O ZD
03 • O
   CSJ
      un
                 co
                   o
                   o
                                                      o
                                                      o
                t_3
LU
Q-
O
o;
o
                       i.
                       o
                    to
                    c
                    03
                    CD
                   .0
                                                    a>
                                                                        c
                                                                        o
                                                                        O)
                                                       TD

                                                        E
                                                        n3
                                                                        fC
                                       CD
                                                              CM
                                                              IO
                                                              CTi
                                                                               rC
                                                                              CM
                                                                    LO
                                                                    r^
                                                                    01
                                                                                    00
                                           144

-------
TABLE A-6.  AVERAGE ANNUAL NITROGEN (N)  AND PHOSPHORUS (P)  UPTAKES  (KG/HA-YR)
            FOR MAJOR CROPS IN EACH STUDY REGION

REGION
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
Corn
N
38
38
68
68
83
75
75
90
112
112
105
75
83
90
83
83
105
112
105
90
83
98
98
105
105
98
83
P
9
9
16
16
20
18
18
22
27
27
25
18
20
22
20
20
25
27
25
22
20
23
23
25
25
23
20
Hay-
Alfalfa
N
80
80
150
150
160
150
150
165
-
-
-
-
-
-
-
145
160
-
-
-
-
150
125
145
-
-
-
CROP
P
7
7
12
12
13
12
12
14
-
-
-
-
-
-
-
12
13
-
-
-
-
12
11
12
-
-
_
Soybeans
N P
70
70
75
80
95
70
70
85
90
90
85
75
80
80
80
80
115
90
80
80
80
-
-
-
80
75
90
7
7
8
8
10
8
8
9
10
10
9
8
9
8
9
9
12
10
8
9
9
-
-
-
8
8
10
Winter
Wheat
N
38
38
-
-
-
38
38
40
25
25
28
40
34
-
-
48
50
40
40
32
-
45
-
-
40
38
-
P
8
8
-
-
-
8
8
8
5
5
6
8
7
-
-
10
10
8
8
6
-
9
-
-
8
8
-
                                     145

-------
 o
 I—I
 CD
            LU

            <
            a:
ca

00
LU
O
o
Q
LU
oo
o
CD
C£
O
O
oo

C£L
O
            LU
            o:
            LU

            <
            o;
                                     Ln
                                           un
                                                                   o
LU
            _
            LU
            o;


(NJ
tn
CM
o
oo
            LU
            o;
                                        146

-------
Continuous  Input Parameters

     The parameters  in  this  group may assume continuous values  and  will  vary
model outputs  in a continuous  and well-defined fashion (the predictive
equations).  For each combination of the fixed and nonuniform  input  para-
meters, the CNS model was  replicated for a number of combinations of  the
continuous  inputs  sufficient to determine the predictive equations.   Because
the predictive equations  varied uniformly with the independent  variables,  it
was necessary  to repeat  the  model runs for each cropping situation  for  only
two values  of  curve  number (CM),  fertilization rate (F^, Fp),  and soil
fertility level (S|\j, Sp)  to  determine the predictive equation  coefficients.
Soil P adsorption  capacity and bulk density were not varied between  runs,
since their effects  on  dissolved  P loss in runoff are inferred  directly from
the model equations  in  Appendix I.   The effect of variations in these factors
on dissolved P loadings  is contained in the variable yp, as computed  by
equation 9.

     In summary, for each  cropping alternative in each region,  the  CNS  model
was run eight  times, representing all combinations of two curve numbers, two
levels of fertilization,  and two  soil fertility levels.  Curve  numbers  were
set at CNjj =  60 or  CN  jj= 90,  soil  organic N was initialized  at  1000 kg/ha-
10 cm or 10,000 kg/ha-10  cm  at the beginning of each model year,  and  soil
available P was initialized  at 10 kg/ha or 200 kg/ha at the beginning of each
model year.  Annual  fertilizer N  and P inputs were set at 50%  or  at  200% of
the normal  fertilization  rate  for each crop.  For corn, this range  translates
to 50 kg/ha-yr or  200 kg/ha-yr of inorganic N in all  regions,  and 10  kg/ha-yr
or 70 kg/ha-yr of  available  P  in  all regions.  Hay fertilization  rates  were
10 kg/ha-yr or 70  kg/ha-yr for both inorganic N and available  P.  Soybean
fertilization  rates  were  0 kg/ha-yr or 30 kg/ha-yr for incorganic N  and 10
kg/ha-yr or 50 kg/ha-yr  for  available P.

Non-uniform Input  Parameters

     As mentioned  previously,  the non-uniform parameters have  a substantial
effect on the  levels of  predicted nutrient loadings,  but cannot be  related
directly to the model results.  Soil hydrologic group is a categorical
variable (A, B, C, or D),  and  determines the magnitude of direct  runoff under
fallow conditions, independent of crop curve number.   Soil water  capacity,
although a  continuous variable, exerts a nonuniform effect on  nutrient  loss.
Discrete values for  soil  water capacity of .05, .10,  .15,  and  .20 cm  of
water/cm of soil were modelled for all combinations of the continuous and
other nonuniform variables.

     Timing of tillage  and fertilizer application were both related to  the
times of planting  and harvest  in  each region.  Fall plowing was assumed to
occur two weeks after crop harvest,  and spring plowing occured one month
before planting.   Fertilizer N and  P were added to the nutrient budget  in  the
month after harvest for  fall  fertilization and in the month previous  to
planting for spring  fertilization.   Hay was assumed to be fertilized  in the
month previous to  first  cutting.   No-tillage was modelled as continuous  cover
(no bare-soil  periods).

                                     147

-------
148

-------
SUMMARY

     The CMS model was  used  to estimate edge-of-field loadings of dissolved  N
and P for a number of combinations of crops, soils, and field practices.
Loading estimates were  condensed into predictive equations for water  and
nutrient loss  as a function  of soil  and crop characteristics.  The  coeffi-
cients for the predictive  equations  for each modelled crop are presented  in
Appendix III.  Table A-8 summarizes  the various crops, soils, and field
practices modelled.
                                     149

-------
TABLE A-8.   CROPS AND PRACTICES  SIMULATED  WITH THE CNS MODEL

CROP
Corn





Hay
Soybeans





Corn with
Winter Wheat

TIME OF
PLOWING
Spring

Fall

Reduced Tillage

No Tillage
Spring

Fall

Reduced Tillage

No Tillage

TIME OF
FERTILIZATION
Spring
Fall
Spring
Fall
Spring
Fall
Spring
Spring
Fall
Spring
Fall
Spring
Fall
Spring
Fall
GEOGRAPHIC
REGIONS
all
all
all
all
all
all
1-8, 12, 16-19,
22-26
1-21, 25-27
1-21, 25-27
1-21, 25-27
1-21, 25-27
1-21, 25-27
1-21, 25-27
1, 2, 6-13, 16-20,
22, 25, 26
1, 2, 6-13, 16-20,
                                                             22,  25,  26
                                    150

-------
                                   SECTION 3

                A GENERAL  METHODOLOGY  FOR ESTIMATING NONPOINT
                            SOURCE  NUTRIENT LOADINGS
     In this section, the  predictive  equations derived in Section 2 for
runoff, percolation, and dissolved  nutrient loadings from cropland are
combined with the USLE  to  produce a methodology for predicting average annual
edge-of-field water and nutrient losses  for several major field crops in the
eastern and central U.S.   Methods are also presented for obtaining
approximate estimates of average nutrient delivery from edge-of-field to
surface waters.

     Three objectives may  be  met through  application of the methodology
presented in this section:

     1.  Dissolved and  solid-phase  pollutant loading may be estimated for a
         specific field, given  certain crop characteristics,

     2.  The effectiveness  of a specific  management practice in reducing or
         eliminating pollutant  loading as compared to base conditions (say,
         the present cropping system) may be evaluated, and

     3.  Two or more control  practices may be ranked according to their
         effectiveness  in  reducing  the loading of each pollutant.

Each of these objectives requires the computation of pollutant loading based
on particular field characteristics for  each alternative practice.  Table A-9
summarizes the required data, predictive  equations, and the resulting pol-
lutant loading estimates for  both dissolved and solid-phase pollutant
loadings.

     Some field practices  cannot be evaluated using the methodology presented
in this section.  For example,  changes in the average time of planting of a
crop may increase or decrease average pollutant loading; however, variations
in the time of planting or  harvest  are not included in the methodology.  In
general, a practice may be  evaluated  if  it can be represented by changes in
the input data parameters  listed in Table A-9 for each pollutant.  A number
of soil water and nutrient  control  practices are evaluated in Table A-10 for
their effect on each input  parameter.  In each case, a (+) indicates that use
of the practice will increase the level  of that parameter in the predictive
equations, a (-) indicates  a  decrease in  that parameter, and a blank
indicates that the practice will not  affect the level of that parameter.
                                     151

-------
TABLE A-9.  INPUT DATA REQUIREMENTS, COMPUTATIONAL PROCEDURE, AND RESULTING
	LOADING ESTIMATES BY USE OF THE PREDICTIVE EQUATIONS     	
POLLUTANT:

INPUT DATA
PARAMETERS:
COMPUTE
EDGE-OF-FIELD
LOADINGS:
ESTIMATE
NUTRIENT DELIVERY:
     SOLID-PHASE N

Total soil N concentration
       SSN (mg/kg)
USLE factors:
     K
     Slope (%)
     Slope length (m)
     C
     P
Enrichment ratio for soil
N in eroded soil

1) Compute average annual
   soil erosion by eq. 10
   (T/ha-yr)
2) Compute average annual
   total N loss in eroded
   soil by eq. 11 (kg/ha-yr)

Compute sediment delivery
by eq. 16 or 18
      SOLID-PHASE P

Total soil P concentration
      Ssp (mg/kg)
USLE factors:
     K
     Slope (%)
     Slope length (m)
     C
     P
Enrichment ratio for soil
P in eroded soil

1) Compute average annual
   soil erosion by eq. 10
   (T/ha-yr)
2) Compute average annual
   total P loss in eroded
   soil by eq.
   12  (kg/ha-yr)
Compute sediment delivery
by eq.  16 or  18
POLLUTANT:

INPUT DATA
PARAMETERS:
    DISSOLVED N

Inorganic N in fertilizer
FN  (102 kg/ha-yr)

Soil organic N Sw (10
kg/ha-10 cm)    N
      DISSOLVED P

Available P in fertilizer
Fp (kg/ha-yr)

Soil available P Sp  (kg/ha-
10 cm)            v
                     Curve number CN
                                     II
                              Curve number CN
                                              II
                     Soil available water
                      capacity AW (cm/cm)

                     Soil hydrologic  group
                     Average annual 	
                      precipitation Pr (cm)
                              Soil available water
                               capacity AW (cm/cm)

                              Soil hydrologic  group

                              Average annual 	
                               precipitation Pr (cm)
                                                       o
                              Soil bulk density p(g/cm )

                              Soil pH

                              Soil clay content %C  (%}
  (cont.)
                                      152

-------
TABLE A-9.   (Continued)
 COMPUTE
 EDGE-OF-FIELD
 LOADINGS:
 ESTIMATE
 NUTRIENT
 DELIVERY:
1) Compute annual runoff by
   eq. 1  & 3 (cm/yr)

2) Compute annual perco-
   lation by eq. 2 & 4
   (cm/yr)

3) Compute average dis-
   solved N concentration
   in percolation by eq.
   6 (mg/1)

4) Compute average dissolved
   N concentration in perc-
   olation by eq. 6 (mg/1)

5) Compute average annual
   dissolved N loadings in
   runoff and percolation
   by eq. 13 & 14 (kg/ha-yr)

Average annual stream
  dissolved N loading
  = runoff N plus
  percolation N
1) Compute annual runoff by
   eq. 1 and 3 (cm/yr)

2) Compute 3 from pH and %C
   by eq. 8 (I/kg)
                                               3) Compute ypfrom 3 and p
                                                  by eq. 9   (dnless)
                                               4) Compute average dissolved
                                                  P concentration in runoff
                                                  by eq. 7  (mg/1)

                                               5) Compute average annual
                                                  available P loading  in
                                                  runoff by eq.  15  (kg/ha-yr)
Average annual stream
  dissolved P loading
  - runoff P
                                     153

-------
 oo
 t^>
 o
D-
 oo
 a:
 QC
  0 0-0
I— i. -r- -r- -r-
CD T- O) 4-> -l-> to
E CO 4J q- ro ro CU
•r- E O S- S-
S- T- T3 -O v- O
3 O CU  S- 3 3 Q. O 5-
E i- XJ T3 ro O O
O CU CU CU E
o i— cc a£ i—i

















1 1








1 1










~*~ '








-"" **








' '






















to
1 to to E
E i- 0.0
O> 
O O -r- U ro
1— 4->
E S- ••- i- O
O O +-» CU i-
•r- 4- S- >
4-> CU O "O
3 O) q- O O)
4-> i- tO
•r- 3 i— S- ro
4-> E ro CU -Q
10 rO CJ 4-> I
-Q E "- E -0
3 -r- O
00 S 00


































































































sx
E
(O
S -D
CU
(13 ^—
•o -^
E +->
ro
S
•> O
CU S-
to i
ro -4->
cu ^:
i- cn
u -i-
cu ro
-a s-
i ^
ro to

to ro
0)
4-> O
ro 4->
O
•r- -a
-a cu
E i.
•r- rO
D.
I E
O
ro O

r. (/)
CU (O
O
•i- CU
1 ^ f
O ro
ro
S- 10
o CU
O
a> •!-
c~* ^_J
4_) (j i_
ro CU
^: i- >
+-> a. o
•r- O
^ s-
S- et CU
CU -I-J
4-* E
CU • •!-
E S- 2
rO CU
S- 4-> O
(O CU E
Q- E
ro -E
CU i- 4J
.c ro -i-
4-> CX S

E CU CX
•r- .E O
4-> S-
CU O
to E
rO O T3
CU CU
i- 4-» N
O CJ •!-
E CU i—
•r- 4- -r-
M- 4-)
E CU i-
rO CU
0 4-
tO E
cu >,
4-> to •—
ro (U i—
U 4-> ro
•r- ro O
T3 O -i-
E -I- E
• i— ~O CU
E -E
+ •- 0


•
F—
to
a>
u
•>-
o
ra
i-
D-
E
cu
E
O)
cn
ro
E
CO
E

a.
o
S-
CJ

O)
to
0)
£

>^
<^i

•a
cu
-f >
o
cu
q-
q«
ro
E
~"^

CU
i-
rO

to
E
O
•r-
-)._>
ro
73
cr
cu

cu
>
• r-
^_)
O
•r—
T3
a>
i.
Q-



E
• r-

to
i-
a>
4^
cu
E
ro
i-
ro
Q-

^
O)
-E
I '
O

^~
^_
^^


•
OJ
                                                154

-------






















to
c
5
-Q
Q
CO
S-
o

E
S-
0

































0)
2 O
0 E
/1 1
r~~ UJ
Q_ C£

CD (/)
c o>
•i — Z3
e T~1
>- \J
f^ •!—
CO 
OJ
o:



5"£!
O  O
Ofl 1
\U
r— CC
Q-
l/l
r— CU
frt "^~j
ly -~.t
U. t-
<1>
o:



+j
OJ
2;
o to
r— CD
D. 3
T:
^^ t/)
03 O)
u. o:




^~
p™"
h^
i
0







c~
O
o>
a;

Louni— cvjooocsjr— ooo^j-coc3-i<£>CTi<^-LncMr~.Lnioroio<4D^-i—
Lnirja^LnLnLnLnu^^Lnuni^LOLnLOL^in^LnLOLOLnLnLnunLn

i i i i i i i i i i i i i i i i i < i i i i i i i i

CSJ C\J ^^ O1 O1 LO CO ^^ CVJ LO i^ ^" VO CNJ ^^ f") C\J ^~* ^j" C\J CSJ O^ OO CO CZ5 ^O
<^cncxic\)c\jCMC>jcjc\jc^coco<^^oooo(^^cv7(v7focvjO O^ CO CXJ LO C\J LO CO CO CO n~" CO C\J ^^3 ^^" ^^" r~ ^if* ^^~ i~™ • CO
LO LO *^^~ LO LO *«J* *^~ "5^ ^t" ^^" LO LO LO LO LO LO LO ^.O LO LO LO LO LO LO LO "^1"

i i i i i i i i i i i i i i i i i i i i i i i i i i

i-o in co r~- r~™ r^s co co r— - LO oo r^ (~"i f~~i co CM LO LO r**» LO *^ c\j to LO co co
•=J-^-oo«a-^j-co^i-cococo<-^LOLOLo^t^-Lo^-i — coi — uococoi — <*«d-i — oo
•*«d-co«d-^f-co^i-cococO'=i-^-^}-^-^i-^-^-Lo«*^-^-^«5i-co

i i i i i i i i i i i i i i i i i i i i i i i i i i

LOLOOCMl— CTlr— CTlLOI^i— «*^J-^^C\JCOI^CMOC\l
JO








































































.
to
cu
3
•r-
to
cu
%-
CD-
CD
<*.
01
E
•p-
a.
to
•4-
o
to
CL>
>
CU
"~
J-
O5
!E r^
Csl
E C
03 O
•r~
2 CT
o cu

o o
M-
>,
4-> CD
> JD
•r- 03
0 ^
!3 ITS
O 03
S- E
a. 3

JE 03
f-rv j\
^^7 T-^
•r- 03
-E TD
"O i—
03 O3
•S E
0 •!-

"~ S-
ai o
to
d.*»—
ai •»->
S- 3
-Q
to -i—
O)4->
E 10
03 -r-
i:ci
•^-^,
155

-------
TABLE A-ll.   (cont.)
No tillage
Strip-till,
 straight row

Strip-till
 on contour

Turn-plow
  Corn with
Winter Cover

 0.07 - 0.15


 0.12 - 0.21


 0.11 - 0.18


 0.28 - 0.43
            Continuous
               Hay

Grass and   0.004 - .010
 legume mix
Clover

Alfalfa
0.015

0.020
 'Ranges represent low and high productivity or low and high levels  of spring
  crop residues
                                     156

-------
PREDICTION OF SOLID-PHASE  EDGE-OF-FIELD NUTRIENT LOADINGS

     Solid-phase nitrogen  and  phosphorus  losses in runoff are dependent  on
the detachment and transport of  soil  particles from the field.  The primary
mechanism for soil detachment  on the  field is rainfall impact, although  small
amounts of erosion may  result  from  snowmelt movement.

     Gully and channel  erosion may  also contribute to stream sediment
loading; however, these are  off-field effects, and form part of the sediment
delivery process.  The  present discussion concerns only rainfall erosion.

     Average annual  soil erosion to edge-of-field under a specific practice
is predicted through  application of the USLE (Wischmeier and Smith, 1978):

                        A = 2.24  R K LS C P                         (10)

where A = average annual soil  erosion (T/ha-yr)
      R = rainfall-runoff  factor
      K = soil erodability factor
     LS = slope-length  factor
      C = crop cover  and management factor
      P = support practice factor

Methods for obtaining  field-specific  values of R, K, LS, C, and P  are  given
in Wischmeier and Smith (1978).   The  crop cover factor C may also  be obtained
from the generalized  values  in Table  A-ll.  These factors were determined  by
estimating an average  time period for each crop stage  (fallow, seedbed,  crop
establishment, crop  development, maturing, and post-harvest) for each  crop
and region, based on  the average dates of plant and harvest (U.S.  Department
of Agriculture,  1972)  and  the  crop  development rates given in Table A-5.   For
each crop stage, a C  factor  was  picked for both low and high productivity  (or
low and high levels  of  crop  cover).  These C factors were multiplied by  the
average fraction of  yearly erosion  which  occurs in each crop stage, and  the
products were summed  over  all  crop  stages to obtain an average annual  C
factor which is  reflective of  both  crop management and the distribution  of
erosive rainfall during the  year.

     In addition to  soil erosion estimates, prediction of solid-phase
nutrient loss requires  an  estimate  of the nitrogen and phosphorus  concentra-
tions in the eroded  soil.   The level  of these nutrients will depend on the
parent material, additions to  fertility through manure applications or
plowing under crop residues, or  other factors.  It is therefore impossible to
estimate these nutrient levels for  specific field without some form of
sampling, either directly  in the field, or by monitoring nutrient  concentra-
tions in sediment carried  in  runoff water.  If soil sampling is used,  the
soil  nutrient concentrations should be multiplied by an appropriate enrich-
ment ratio because eroded  soil particles  are commonly lighter and  higher in
organic matter and clay than the remaining surface soil, and will  therefore
contain higher concentrations  of both solid-phase N and P.  Suggested  ranges
of the enrichment ratio are  2.0  and 4.3 for soil N and 1.5 to 3.4  for  soil P
(McElroy _et _al_., 1976).  Specific values  of 2.5 for soil N and 2.0 for soil  P
are used in the  examples in  Section 4.

                                     157

-------
     Edge-of -field loadings of N and P in eroded soil are computed by
combining the USLE with soil nutrient concentrations and enrichment ratios
for N and P:
                     SN = 0.001 ERN A SSN
                                                                   (11)
                     SP = 9.001 ERp A SSP
                                                                   (12)
where SN
      SP
             average annual solid-phase N loss in eroded soil  (kg/ha-yr)
             average annual solid-phase P loss in eroded soil  (kg/ha-yr)
           ERp  = enrichment ratio for soil N and P  (dmless)
             average annual soil erosion  (T/ha-yr)
             concentration of organic N in surface soil (mg/kg)
             concentration of solid-phase P in surface soil  (mg/kg)
PREDICTION OF DISSOLVED EDGE-OF-FIELD NUTRIENT LOADINGS

     Through repeated application of the CNS model  (see Section  2), the
following predictive equations for dissolved nutrient  losses  in  runoff and
percolation were derived for the crops and practices listed in Table A-8:
Runoff and Percolation Volume
                          %R = a CN + b

                          %P = a  CN + b
                                                                   (1)

                                                                   (2)
where %R = average percent of annual precipitation appearing as direct  runoff
      %P = average percent of annual precipitation which  percolates  below  30
           cm.

      CN = - where CNir = crop curve number for  average soil
           100 - CNH         u
           moisture  (antecedent moisture condition II)
      a, b, a  , b  = constants for each crop, soil, and cropping practice
             and,
                                                                   (3)
                            P -
                                    IDD
where R
      P
     Pr
          average annual direct  runoff  (cm)
          average annual percolation  (cm)
          average annual Precipitation  (cm)
                                     158

-------
Dissolved Nutrient Concentrations  in  Runoff  and  Percolation
         KRN = aO + alCN + a2FN +  a3sN  +  a4FNCN   +  35SNCN         (5)

         KPN = bg + t>iCN + b£FN +  b3$N  +  b4FNCN  + bsS^jCN          (6)
                        A                       A        A
           = yp (Co + ciCN + C2Fp  + C3$p  +  C4FpCN + C5$pCN)        (7)
where Kp^ =  average concentration  of  dissolved  N  in  runoff (mg/£)
          =  average concentration  of  dissolved  N  in  percolation (mg/Jl)
          =  average concentration  of  dissolved  P  in  runoff (yg/A)
      F|\j  =  annual fertilizer  and  manure  inorganic N input (102 kg/ha-yr)
      SN  =  soil organic N  in  the  surface  10  cm (103 kg/ha)
      Yp  =  adjustment factor  for  soil P  adsorption  capacity (dmless)
      Fp  =  annual fertilizer  and  manure  available P input (kg/ha-yr)
      Sp  =  soil available  P in  the  surface  10  cm (kg/ha)
      a-,-, b-j, c-j = constants for  each  crop,  soil,  and cropping practice

                                  84.5
where p = soil bulk density  in  the  surface  10  cm (g/cm3)
      3 = soil available P adsorption  coefficient  ffl/  9)
                                                    mcj / X
                                                     2
and              3 = 5.1 + 2.2  (%C)  +  26.4  (pH  - 6.0)              (8)

where %C = percent clay content  (soil  particles  <  0.002 mm in diameter) in
           the surface 10 cm
      pH = average pH of surface  10  cm

Dissolved Nutrient Loading in Runoff and  Percolation

     Average dissolved nutrient  loading  to  edge-of -field  is found by com-
bining the runoff, percolation,  and  nutrient concentration estimates:

                         DNR = 0.1  (R) (KRN)                       (13)

                         DNP = 0.1  (P) (KPN)                       (14)

                        DPR = 0.0001 (R)  (KRp)                     (15)
                                     159

-------
where DNR = average annual dissolved N loading in runoff (kg/ha-yr)
      DNP = average annual dissolved N loading in percolation  (kg/ha-yr)
      DPR = average annual dissolved P loading in runoff (kg/ha-yr)

IMPLEMENTATION OF THE NUTRIENT LOADING PREDICTIVE EQUATIONS

     The procedure to be  followed to implement the predictive  equations may
be broken down into four steps for dissolved nutrient loadings and three
steps for solid-phase nutrient loadings.

Dissolved Nutrient Loadings

1)   Obtain values for input parameters (CM, Pr, FJ\J, Fp, SN, Sp, AW, p, %C,
     pH)
     a)  Curve number factor CN is equal to  100/(100-CNjj), where CNjj is  the
         SCS curve number for the crop for average moisture conditions (AMC
         II).  Curve number is obtainable from Volume II of Stewart et a1.,
         (1976), or Ogrosky and Mockus (1964).
     b)  Fertilizer application levels F^ and Fp include all inorganic N and
         crop available P applied per year.  If manure is applied, the amount
         of inorganic N in the manure that is volatilized before incorpora-
         tion in the soil must be subtracted from F^.  Average fertilization
         levels, which may be used in the absence of specific  field data,  are
         given in Table A-12  (Beaton and Tisdale, 1969).
     c)  Soil organic N and available P levels must be determined by soil
         sampling in the  field under study.
     d)  All other input  parameters  (Pr, AW, p, %C, and pH) are constants  for
         the particular field under study.   Values of p, %C, and pH are
         needed only if an estimate of average dissolved P  loading  in  runoff
         is desired.  Soil bulk density, soil available water  capacity, and
         clay content are usually available  from soil surveys, whereas soil
         pH should be determined by sampling in the field.

2)  Compute average annual runoff and percolation

     Given  field-specific values for CN and  Pr, equation 1  through  4 may  be
used to estimate average  annual runoff and percolation given the appropriate
values  for  a, b, a  , and  b  from Appendix III.  The coefficients  in Appendix
C are chosen by crop, time of plowing, soil  hydrologic group,  geographic
region, and soil available water capacity  (AW, as a percent of soil  volume).
The appropriate table may be most easily located by reference  to the list  of
tables  at the beginning of Appendix  III.  Average runoff and  percolation
estimates for available water capacities intermediate to those listed  in
Appendix  III should be determined by interpolation.

3)  Compute average dissolved N concentrations  in runoff and  percolation  and
    dissolved P concentrations in runoff

     Nutrient concentrations are determined  in a manner similar to  that  for
runoff  and  percolation volume.  Given  values for CN,  F^, and  S^,  dissolved


                                     160

-------
00
Q.
O

(_)

CC.
O
•-D
e^£


o;
o
:r
CD
^5
1 1 1

i i

	 i
t — i
LU
U_
l— i
oo cr>
•Z CO
O O1
1 — 1 1 —
<:
c_> cu
1 	 | , 	
_1 n3
Q- TD
Q- (/)
 T3
rv* c~
O rO

Q. E
oo o
O -I-3
1 fQ
IX -
Q
	 1 ^3
=C I—
^D OO
z in
• LU
LU
:> z.
CM
1
LU
	 1
GO

























































•4-^
(C
^: CD

•i- 3
^
^~
E CD
i- +->
O E
is

l/l
OJ
JD


oo


D- JC
O
o:
c_>







O)
E 0)
i- to
O i —
O •!-
oo





e
E T-
s- ro
0 1-
C_) CD


o
i — i
CD
LU
CC





LOLO. .LOLOOOOOOO . OLDLDO
D- CMCM OJCXJLO'd"^^'*'^ 'tOLO^LT}



oo OOOUILOLOOO LOUOOLO
~f^ c~~t f~*t i i i co co c? LO LO co (^ ^- i i r*^- cTi oo ^«


LO LO LO f~*l ("^ f^ f"s f"~) f~^ c i c~^ LO LO LO LO f~^ ^__j LO LO


CD CO CD LO CD LO LO CD CD CD LO LO LO LO CD CO LO CO CO



OOLOOOOOLO. . ,LO. . .OOLOO
Q. CMCMCMCMCOCMCMCM ' ' *CM ' ' 'OOOO<=J-CO

LOLOOOLOOOO, . tO. . .OOOO
^^. CO CO l(vj" cj* ^J" ^^ i**~ CO 111 u~j iii ^^. u~j JY"J fyj







l-O LO LO C""l C~^ LO LO LO LO LO LO LO LO LO LO LO UO LO LO
D. i — i — CMCMCOi — i — CMCMCMC\JC\JCMC\JC\l*3-OOrOCO



OOLOOOOOOOOOOOOOLOLOOO
^ CO CO O CO CO O O •vt" i — r— OJ i — CM *^~ ^ r^ LO LO CO




LOLOOOLOLOLOLOOOLOOOLOOLOLOOO
O- i — i — CMCMCMi — i — CXICMCMCVJCMCMOJCMCMCXJCOCO



LOLOLOLOLOOOOOOLOOOOOOOOO



r— CMCO^I-LOCOI^COCTlOr— CMOO 1 1 CO CO 1
CM r-~ CM CM


o o , . ,000
CM CM CO CO CO


o o , . .000
III ^_!


. . LO O O LO O .
1 ' CM CM •* CM «* '

. . LO LO O O , .
1 ' CM CO LO CO ' '








COCMCOCMLOCMCMLO



OOOLOOOLOO





oooooooo
COCMCOUDCMCMCO«^-



OOOLOOOOLO



Oi — CMco^j-iocor^
CM CM CM CM C\J CM CM CM

161

-------
N concentrations  in  runoff  and  percolation may be computed from  equations  5
and 6 given the appropriate  values  of a  and b  from Appendix  III.   Dissolved
                                        i       i
P concentrations  in  runoff  may  be  computed from CN, Fp, Sp, p, %C,  and  pH
using equations 7, 8,  and 9  and  the appropriate values for c-j  from  Appendix
III.  The coefficients  in Appendix  III  are selected by crop, time of plowing,
time of fertilization,  soil  hydrologic  group, geographical region,  and  soil
available water capacity  (AW).

4)  Compute average  annual  dissolved N  and P loadings

     Average annual  dissolved N  loadings  in runoff and percolation  and  dis-
solved P  loadings  in runoff  are  found by combining average annual runoff  and
percolation estimates  from  step  2  with  the average nutrient concentrations
from step 3, according  to equations 13, 14, and 15.

Solid-phase Nutrient Loading  in  Runoff

1)  Obtain values  for  input  parameters  (S$N, S$p, R, K, LS, C, P, ER|\(,  ERp)

     Soil concentrations  of  solid-phase N and P (5$^, S$p) should be obtained
by soil sampling  in  the field or by analysis of eroded soil.   Factors for  the
USLE (equation 10) may  be taken  from Wischmeier and Smith  (1978), or
generalized C factors may be  taken  from Table 11.  Enrichment  ratios for  soil
N and P are variable,  but may be chosen as ER^ = 2.5 and ERp = 2.0.

2)  Compute average  annual  soil  erosion

     Average annual  soil  loss to edge-of-field is computed using  the USLE  and
the values derived for  R, K,  LS, C, and P for each study field.

3)  Compute average  annual  solid-phase  nutrient loss

     Average annual  solid-phase  N and P loss to edge-of-field  is  found  by
substituting the  computed value  for average annual soil erosion A from  step  2
and the soil nutrient  concentrations and enrichment ratios from  step I  into
equations 11 and  12.

Examples  of each  of  these procedures are given in Section 4 of this  report.

DELIVERY  OF CROP  NUTRIENTS  FROM  EDGE-OF-FIELD TO SURFACE WATERS

     Once estimates  of  edge-of-field nutrient losses have  been obtained,  it
may be necessary  to  determine the nutrient fraction which  will reach surface
waters through direct  runoff  or  baseflow.  The various pollutant  transport
mechanisms may be  separated into 1) dissolved pollutant transport  in direct
runoff; 2) sediment  and solid-phase pollutant transport in direct runoff;  and
3) dissolved pollutant  transport in groundwater  (Figure A-l).  Practices
designed  to control  pollutant transport may affect one or  more of these
mechanisms.
                                     162

-------
Solid-Phase  Pollutant  Transport in Direct Runoff

     After  leaving  the field in surface runoff, sediment  and  associated
pollutants may  be  removed  from runoff by filtration and deposition.   Sediment
may be  deposited  in grassed waterways, field borders, or  buffer  strips, or in
forest, pasture,  and cropland downslope of the field.  The  effectiveness
(percent  reduction  in  sediment loading) of sediment control  practices will
depend  on the specific application of that practice, and  is  not  easily
predicted from  secondary information.  Sediment loading reductions  through
the use of  individual  off-field practices must therefore  be  determined on  a
local level, by observing  the effectiveness of each candidate  practice in  an
existing  management scheme or through monitoring of sample  fields.

     Sediment deposition on intervening land surfaces may be  approximated  by
a simple  distance-to-stream function if the location of the  field  relative to
the nearest  permanent  water body is known, or by a watershed  drainage density
model in  the absence of field location data.  The first method requires the
computation  of  a  delivery  ratio (Sd-j) for each field in a study  area,  and
combines  with the  USLE to  estimate the sediment contribution  of  each  field to
the receiving waters:

                             YT = Sdi Ai                            (16)

where Y-j  =  in-stream sediment loading from field i (T/ha-yr)
      A-,-  =  sediment loading to edge-of-field for field i  (T/ha-yr)
     Sd-j  = sediment delivery ratio for field i (dmless)

                                 -0.36
and                  Sdi = 2.5di                                    (17)

where d-j  = distance from center of field i to receiving water  (m)  (Smith,  et_
al., 1979).  The  second method computes an average watershed  delivery ratio
as a function of  drainage  density (the ratio of the sum of permanent  channel
lengths in the  watershed to total  watershed area), and assumes a relatively
homogenous soil texture in the watershed:
                            Yi = Sd Ai                              (18)


where Sd  = average  watershed sediment delivery ratio (dmless)
Average sediment  delivery  ratio "ScT is obtainable from Figure A-7 (McElroy  et
                                                           n         n
al., 1976), given the  reciprocal  of drainage density in km /km or mi  /mi and
the predominant soil texture in the watershed.

Dissolved Nutrient  Delivery in Direct Runoff

     The  fraction of runoff which  reaches  surface waters  depends primarily on
the location of the field  relative to the  nearest conveyance channel.   If  the
field drains directly  into a stream or unimproved drainage ditch, we  may
assume that all runoff will  enter  the surface water system.   If  the field  is
separated by forest, pasture,  or  other cropland,  some or  all of  the runoff

                                     163

-------
                                                       o
                                                       o
                           III  I  I  I  I    I
                                                       o
                                                       o
                   o
                   oo
                                                                          o
                                                                          oo

                                                                          LU
                                                                          Q

                                                                          UJ
                                                            en
                                                            z
                                                            UJ
                                                            o
                                                                          o

                                                                          o
                   oo ^->
                   D
                     r^.
                   >- cr>
                   Qi r—
                                                                          2: o
                                                                          I—I QL
                                                                          Q _l
                                                                          UJ UJ
                                                                          oo
                                                                          oo o;
                                                                          H- x
                                                                          
-------
may be captured in the  intervening  area  through  ponding and subsequent
infiltration.  However, diffuse  runoff  from the  field may quickly coalesce
into small intermittent streams  of  higher velocity,  which may reach a
permanent channel without  significant  reduction  in flow volume.   A reasonable
assumption is that 100% of  direct  runoff will  reach  a surface water body,
unless diversions or detention ponds  are used  to redirect the flow to a place
where infiltration can  occur.  Dissolved nitrogen is generally conserved in
runoff,  and hence all dissolved  N  lost  from the  field in runoff will  enter
the surface water systems.   Dissolved  phosphorus may be partially adsorbed by
suspended sediment during  transport  or  after deposition in the stream.  The
dissolved P trapped by  sediment  may  reappear in  the  stream if the deposited
or trapped sediment is  detached  by a  later storm event.  Complete delivery to
the stream of dissolved P  in runoff  is  a conservative assumption, although
this is  not a highly reliable estimate.

Dissolved Pollutant Transport in Groundwater

     Percolation below  the  root  zone  will  travel  to  the groundwater table,
and may appear as baseflow  in streams  or lakes.   The transport process may
occur over a long period,  during which  time the  nutrients carried in
percolation may be diluted  or changed  in form.   Dissolved P in percolation
will reach equilibrium  with  the  adsorbed phase  in deep soil layers before
reaching surface waters.   The equilibrium concentration in groundwater
reaching the stream or  lake  will therefore be  close  to background levels.
Conversely, dissolved N is  essentially  conserved in  groundwater, and field
losses of dissolved N   may  reappear  in  baseflow.   Although the eventual
destination or timing of reappearance  of percolated  N from each field may not
be known, the total watershed N  flux  reaching  surface waters in baseflow
should be well predicted by  the  sum  of  the individual field loadings in
percolation, as determined  by the  predictive equations for dissolved N in
percolation.
                                     165

-------
                                   SECTION 4

                    DEMONSTRATION OF THE USE OF THE NUTRIENT
                          LOADING PREDICTIVE EQUATIONS


      Implementation of the nutrient loading equations is best demonstrated
through  examples  of their use.   In this section, two situations are consid-
ered:  first,  runoff and nutrient loading estimates are computed for  a
hypothetical cropping scheme in three different geographic regions; and
second,  the  predictive equations are utilized to predict average annual
nutrient loadings  for the Honey Creek watershed in northern Ohio.

LOADING  ESTIMATES  FOR A HYPOTHETICAL CROP SITUATION

      Consider  a straight-row corn crop on a soil of hydrologic group  C,
fertilized in  the  spring and turn or moldboard plowed after harvest in the
fall.  The crop practice and soils data necessary to use the predictive
equations  are  given in Table A-13.  In order to demonstrate the variation  in
nutrient loading  between locations, loading estimates are computed for this
crop  in  three  geographic regions:  southern Minnesota (region 4), central
Texas  (region  10),  and Pennsylvania (region 22).  Within each region, two
management practices, contouring and no-tillage, are analyzed for their
effects  on nutrient loadings as compared to base conditions.

Base  Conditions (straight-row,  fall-plowed, spring-fertilized)

Solid-phase  Nutrient Loadings--

      Solid-phase  nutrient loss  is predicted by combining the USLE (equation
10) with soil  nutrient concentration data, according to equations 11  and 12.
Rainfall-runoff factor R as  obtained from Wischmeier and Smith (1978) is
approximately  equal  to 125 for  region 4, 250 for region 10, and 125 for
region 22.   Crop  cover factors  (C) for each region are obtained from  Table
A-ll,  for  fall  plowing with  residues removed, assuming average crop cover.

Average  annual  soil  loss is  then computed as:

TABLE A-14.  COMPUTATION OF  AVERAGE ANNUAL SOIL LOSS UNDER BASE CONDITIONS
Region
2.24
LS
A
4
10
22
(2.24) (125)(.25) (,354)(.45)(1 .0)
(2.24) (250)(.25) (.354)(.40)(1 .0)
(2.24) (125)(.25) (.354)(.46)(1 .0)
= 11.2 T/ha-yr
= 19.8 T/ha-yr
= 11.4 T/ha-yr
                                     166

-------
TABLE A-13.  FIELD CHARACTERISTICS FOR SAMPLE CROP
FIELD CHARACTERISTIC
VALUE
Soil total phosphorus content

Soil organic N level

Soil available P level

Fertilizer N application

Fertilizer P application
                             a/
PARAMETER VALUE
Soil erosivity
Slope length
Percent slope
Soil available water capacity
Percent clay content
Soil pH
Soil bulk density

Soil total nitrogen content
0.25
61 m
3%
.15 cm/cm
10%
6.5
1.5 g/cm3

1330 mg/kg
K =

LS
AW
%C
PH
p =
3 =
YP
SSN
0.25

= 0.354
= 15
= 10
= 6.5
1.5
33.7
= 1.67
= 1330
333 mg/kg         Ssp = 333

2000 kg/ha-10 cm  SN = 2.0

50 kg/ha-10 cm    Sp = 50

100 kg/ha-yr      FN = 1.0

25 kg/ha-yr       Fw = 25
  a/  In most cases  solid-phase  N  and  P must  be  approximated  by  total  soil  N
     and  P.
                                     167

-------
Average  annual  solid-phase  N and  P loadings are then computed by equations  11
and 12:
TABLE A~15 COMPUTATION OF AVERAGE  SOLID-PHASE NUTRIENT LOADINGS

Region Nitrogen:
4
10
22
Region Phosphorus:
4
10
22
.001 ERN A, SSN
(.001) (2.5) (11.2) (1330)
(.001) (2.5) (19.8) (1330)
(.001) (2.5) (11.4) (1330)
.001 ERp Ab Ssp =
(.001) (2.0) (11.2) (333) =
(.001) (2.0) (19.8) (333) =
(.001) (2.0) (11.4) (333) =
SN
= 37.2 kg/ha-yr
= 65.8 kg/ha-yr
= 37.9 kg/ha-yr
SP
7.5 kg/ha-yr
13.2 kg/ha-yr
7.6 kg/ha-yr

Dissolved Nutrient Loadings—
     From Stewart et_ _a1_.  (1976)  crop  curve number equals 88 (CN = 8.33) for  a
straight-row crop in poor hydrologic  condition (residues removed) on  a  C
soil.  Average annual  precipitation  for the three locations was set equal to
the  levels used  in the  CNS  model  simulations.   Because the crop is fall
plowed, Table (A)III-IO  contains  the  appropriate  values for a, b, a1, and b1
Nutrient coefficients  are obtained  from Table  (A)III-ll, for a fall-  plowed
corn crop fertilized in  the  spring.   The following table shows the steps to
be followed to compute  average  annual  runoff and  percolation from the data
given and equations  1  through 4:

TABLE A-16.  COMPUTATIONAL  PROCEDURE  FOR DIRECT RUNOFF AND PERCOLATION
Runoff
region
4
10
22
Pr
(cm/yr)
64.1
59.2
92.0
ti
8.33
8.33
8.33
a
1.60
1.33
1.32
b %R
12.67 26.
10.63 21.
21.42 32.
R
(cm/yr)
0 16.7
7 12.8
4 29.8

-1
-1
-1
a1
.44
.01
.32
Percolation
b1
30.23
20.73
39.79
%P
18.2
12.3
28.8
P
(cm/yr)
11.
7.
26.
7
3
5
                                     168

-------
Average annual dissolved  nutrient  loadings for base conditions  are  computed
similarly, using the  crop  practice  and soils data from Table A-12,  the  coef-
ficents a-j, bj,  and c-j  from  Table  (A)III-ll, and equations 5-7  and  13-15:

    TABLE A-17.  COMPUTATIONAL  PROCEDURE FOR DISSOLVED NUTRIENT LOADINGS


Runoff N
Percolation N Runoff P
R P KRN RN KpN PN KRp RP
region (cm/yr) (cm/yr) (mg/1 ) (kg/ha-yr) (mg/1 ) (kg/ha-yr) (yg/1 ) (kg/ha-yr)
4
10
22
16.7
12.8
29.8
11.7 4.8 8.0
7.3 6.5 8.3
26.5 2.2 6.6
55.7 65.2 116.3 0.19
99.0 71.7 106.3 0.14
20.9 55.4 107.5 0.32

Contouri
ng as
a Management Practice

     Contouring will  affect  both  soil  loss levels and dissolved  nutrient
losses.  The only effect  of  contouring  on soil  loss is through the change  in
the support practice  factor  P,  which  is equal  to 0.5 for contouring  on  a 3%
slope.  Soil loss and  resulting  solid-phase nutrient loadings are therefore
cut in half for all regions:

       TABLE A-18.   SOIL AND SOLID-PHASE NUTRIENT LOSS WITH  CONTOURING

region
4
10
22
Soil Loss
(T/ha-yr)
5.6
9.9
5.7
Solid-phase N Loss
(kg/ha-yr)
18.6
32.9
19.0
Solid-phase P
(kg/ha-yr)
3.8
6.6
3.8
Loss




The effect of contouring  on  dissolved  nutrient  loss is expressed through  a
change in the curve  number from  88  to  84  for contouring (CN = 6.25).  The
same values for a, b,  a', b',  a-j,  b-j,  and c-j are used to predict runoff,
percolation, and  nutrient loadings:
  TABLE  A-19.   COMPUTATION OF DISSOLVED NUTRIENT  LOADINGS  FOR CONTOURING

region
4
10
22
R
(cm/yr)
14.5
11.2
27.3
P
(cra/yr)
13.6
8.5
29.0
Runoff
N
Percolation N
Runoff P
KRN RN KpN PN KRp RP
(mg/1) (kg/ha-yr) (mg/1) (kg/ha-yr) (yg/1) (kg/ha-yr)
6.2
6.1
1.9
9.0
6.8
5.2
50.7
89.0
19.8
69.0
75.7
57.4
113.7
104.7
106.1
0.16
0.12
0.29
                                     169

-------
 No-Tillage as a Management Practice

      Tillage elimination will affect both  soil  loss  and  dissolved  nutrient
 loadings.   In this case, soil loss is decreased through  a  reduction  in the
 crop C factor.   Therefore, both soil and solid-phase  nutrient  losses  will  be
 reduced by the  ratio of the no-tillage C factor to the fall  plowing C  factor.

  TABLE A-20.   SOIL AND SOLID-PHASE NUTRIENT LOSSES UNDER REDUCED TILLAGE  	

region
4
10
22
Soil loss
(T/ha-yr)
2,7
5.9
3.0
Solid-phase N loss
(kg/ha-yr)
9.1
19.7
9.9
Solid-phase P loss
(kg/ha-yr)
1.8
4.0
2.0
      Dissolved nutrient loss is computed  using  the  predictive  equation
 coefficients in Table (A)III-l and (A)III-2 for^a no-tillage corn  crop
 fertilized in the spring.   Curve number factor  CN is equal  to  8.33.   Estima-
 ted runoff,  percolation, and dissolved nutrient  losses  are  presented  below:

TABLE A-21.  RUNOFF,  PRECOLATION, AND  DISSOLVED NUTRIENT LOADINGS FOR REDUCED
             TILLAGE
             R
Runoff N
l\r\kt
RN
Percolation N
          PN
Runoff P
         RP
                                             PN       
-------


Q_
O
OL
O
LLJ
	 1
Q_
^-

i — i
a
LU
a;
a.

oo
oo
o
	 i

f—
2:
UJ
KH
a:
H-
^
-*
~*^
a
2:

a;
1 1
o

>-
cn.

00

.
CM
CM
=£
L-U
— 1
CO
=C
1—


















































































CO
O)
CO
CO
o
_J
0)
CO
rO
~c
Q.

X)
•r~

o
oo





CO
cu
co
CO
o
, 	 1

-o
a>
j_^
0
CO
CO
•1—
Q















































1?
>.
•-O
0 J*
•"*" fO
_c
cn
_M
.^ 	 x
i.
^^^
>1
ro
^ jz

cn
^^
V 	 '

CX S-
«*- ^
It- (0
o .c:
c: ~-^
zs cn
rv ^;


2:

TD i-
OJ >)
•M 1
(D fC
i — _C
O ~\
O cn
i- -^
0) — '
Q_
i_
Z >,
1
M- ra
<<- -C
O ~~-
c cn
Z3 -V
a: —

CO • — -
CO S-
O >i
" i
•>
r— "^
0 E
o o

CD
a_

C|_ , 	 ,
M- S-
i 1*
>~- £^
3 (J
o; ^_-
fd
01
u

-J3
o
tocnoo
i—i—i— CM CM OO





l~-~Lnr— ODCMCMCOOOOO
to^J-oocMi — ocnr-^cM





Q; C£ C£ C£. C£. C£.
OOC_)OOOOC_)OOOOC_30O

Q.Q.I — D_ D_ I — Q-O-I —
LJ_U_CC:U_U_CC:LI_IJ_Q:




'd- O CM
t— CM


























-o
a>

^
0
-(->
c
o
o

II
CJ

r>
S
o


4-J
^:
cn
rO
S-
-I-J
CO

II
a:
oo
O)
en
(O
1
•r™
+-)
•o
CU
u
13
XI
OJ
i-
II

£

A
2
0

a.
^^
^_
rO
ti-
ll

a.
u_
^^^
fO
171

-------
 CD
 UJ
 UJ
 CC
 O
  UJ
  z
  O
  X
TD
O)
 ro
 CD
 OJ

 O
 O)

 O
 00
 O)
 S-
                                          172

-------
are computed for each  subwatershed,  and are then combined to determine total
watershed losses.

Soil N levels are derived  from  soil  organic matter data obtained from local
soil surveys (Soil  Conservation Service,  1975),  assuming a 20:1 carbon to
nitrogen ratio  (therefore  organic  matter  is 5% nitrogen).  Available P and
solid-phase P data  is  averaged  over  all  soil  groups, since specific data was
only available  for  three or  four  soil  groups.   Fertilizer N and P levels are
set equal to the recommended  levels  for each  crop in Ohio (Beaton and
Tisdale, 1969), as  given in  Table  A-12.   Consequently,  the nutrient loss
estimates computed  in  this example are rough  approximations,  although the
reduction in nutrient  loading  by  the  use  of alternative practices should be
well predicted.

     Base conditions for the  watershed are defined as fall plowing for corn
and soybeans (except when  grown with  a winter  cover crop, in which case
no-tillage is assumed),  and  all  crops planted  straight-row.  Hay is grown
continuously without tillage.   The areas  of the  various crops and rotations
in the four subwatersheds  are  given  in Table  A-24.  Nutrient loadings were
estimated by applying  the  predictive  equations to each  crop in each rotation,
and averaging over  all  crops  in the  rotation  to  obtain  average annual
loadings.

     In addition to base conditions,  three management options were analyzed
for their effects on nutrient  loadings to edge-of-field: 1) contouring on  all
crops 2) spring plowing  rather  than  fall  plowing for corn and soybeans, and
3) no-tillage rather than  conventional tillage for corn and soybeans.
Nutrient loadings were  predicted  for  both spring and fall fertilization, to
represent the expected  range  of loadings  in the  watershed.  Contouring
affects the value of CN  for  each  crop, while  variations in tillage requires a
shift from one  set  of  predictive  equation coefficients  to another, without
any change in the input  parameter  values.  The additional data necessary to
implementing the predictive  equations is  as follows:

            average precipitation   =   95.3 cm/year
            fertilizer  N applications:  corn  = 150 kg/ha-yr (F^ = 1.5)
                                         soybeans = 5 kg/ha-yr (F^ = 0.05)
                                         hay =  50 kg/ha-yr (FN = 0.5)
                                         corn  with winter cover = 200 kg/ha-yr
                                         (FN =  2.0)
            fertilizer P applications:  corn = 30 kg/ha-yr (Fp = 30)
                                         soybeans = 20 kg/ha-yr (Fp = 20)
                                         hay =  30 kg/ha-yr (Fp = 30)
                                         corn  with winter cover = 60 kg/ha-yr
                                         (Fp =  60)

Solid-Phase Nutrient Loadings

     Average annual soil loss  by  subwatershed  and soil  group as determined by
the USLE is given in Table A-25.   These soil  loss data  are combined with the

                                     173

-------
soil nutrient data  in Table  A-23  to  provide an estimate of average annual
solid-phase nutrient loadings to  edge-of-field in each subwatershed under
base conditions.  Enrichment ratios  for soil  nutrients were set at 2.5 for
soil N and 2.0 for  soil  P.   A similar  procedure was followed for nutrient
loading under each  alternative  management  option, given the expected average
annual soil loss under each  practice.   Table  A-25 contains the estimated
nutrient fluxes for each  subwatershed  and  practice.

Dissolved Nutrient  Loadings

     Estimates for  dissolved N  and P loading  for each management alternative
are computed in two steps.   First, average  annual runoff and percolation are
predicted based on  crop  curve numbers  and  soil available water capacities for
each rotation and soil group.   These estimates are then combined with
dissolved nutrient  concentrations  in runoff and percolation based on soil and
crop management characteristics,  resulting  in average annual nutrient loading
estimates to edge-of-field.

     Runoff and percolation  estimates  for  base conditions in subwatershed A
are contained in Table A-26.  The  average  runoff and percolation estimates
(in cm/year) for each rotation  in  Table A-26  are multiplied by the crop
acreage data for subwatersheds  B,  C,  and D  to obtain average annual water
movement for these  subwatersheds,  as presented in Table A-27.  The effect of
varying management  practices on water  movement in each subwatershed is
estimated in Table  A-28,  for combinations  of  contouring and spring plowing or
no-tillage.

     Dissolved nutrient  concentrations  in  runoff and percolation are
presented for subwatershed A in Table  A-29.  The predictive equation coef-
ficients listed in  the appropriate table  in Appendix III for each crop and
practice are combined with the  values  of  the  input parameters given
previously, to determine  the average nutrient concentrations for each crop
and rotation in Table A-29 (assuming spring fertilization for all crops).
These same concentrations are combined  with the predicted average annual
runoff and percolation for the  other subwatersheds to determine the average
annual loadings in  Table  A-30.  Predicted  nutrient fluxes under various
management practices are  summarized  in  Tables A-31 and A-32.  The ranges for
each nutrient represent  the  levels of  loss  expected for spring fertilization
vs. fall fertilization for all  crops.   The  actual loadings should fall near
to or within this range.  Dissolved  N  loadings are usually greater for fall
fertilization, as is expected.  However,  dissolved P loadings are higher for
spring fertilization than for fall fertilization.  This is due to the
reinitialization of soil  available P at the beginning of each model year.
Because soil available P  levels generally  increase over the year due to
fertilization, the  spring applied  fertilizer  will have a longer period over
which it may contribute  to runoff  losses,  whereas fall applied phosphorus may
only contribute for a few months  before the soil P levels are reduced by
reinitialization.   Phosphorus  loadings  are  rough approximations, and the
decrease in P loadings due to changing  the  time  of fertilization is not
intended to be modelled  by the  predictive  equations.  Rather, the ranges in
Table A-31 and A-32 for  available  P  more  closely represent the normal range
to be expected for  either time  of  fertilization.


                                     174

-------














O
iTERSHE
=3.
LU
LU
C£.
LU
o
LU
re
1—
1 — 1
00
(— (
h-
oo
1 — 1
LU
h-
2
DC
(~J>

^J
1 — 1
o
oo


oo
CM
 c
o r— re
i— -r- 0
CO i —
H-> E
n —t
tn T- o
CO r—

•M E
i— re
CO T- 0
CO i —

E*-t-> E
re r— re
h- o -r- o
i — CO i —

E
re
to o
E
re
LO O
E
re
^ o

.
-M >> E
oo i — re re
•r- I— O
to o i—


CM r— re
•r- O
CO i —

.O "^ £Z
•r^ ^»") cz
i— T- r— O
CO O i —


C"
O
•r-

U
• r-
ll-
CX CO
3 CO
o re
CD O

r— r— ••
•r- •!—
O 0
oo oo
CM
o en
i — r—
CM
IN^
o en

en
LO
Q en

LO
c_> to

CM
° £ r^

to
DQ IO
to
CO to •
r— r— —

OO
LO
0 0
CM i—


LO
0 CM
CM i —
OO
LO
0
O CM r—

„ 	 i
OO
E
o
r~i 	
0 ^
i~
0) >,
O T-
•r- CO
oi c
O 0)
•— TD
O "— -
S— ^^ -^
•a - 	 i —
nr >=c DQ

i —
to

^t"
to


oo
LO


to


OO

2
to


CM
to


en

•vi-
to











rn
Q.

r—
•n-
o
oo

LO


LO


LO


LO


O
CM

O
CM
0
CM


LO
00


LO

LO
00








>j
re
o

tu
0
i.
tu
a.

0
oo

LO



0
oo


0
oo


0
oo

LO
LO


o
to


o
oo

o
to



— ^
^5

^
eu
+j
ID
E
o
•r—
c.
re
O)
o

LO
CM


LO
CM


LO
CM


LO
CM


LO
CM

LO
CM
LO
CM


LO
CM


LO
CM

LO
CM


^ 	 s
O)
^

0>
<* 	 *

°-


o
0
LO


O
o
LO

o
0
LO


o
o
LO

o
o
LO

0
o
LO
o
o
LO


o
0
LO


o
o
LO

o
0
LO

0)

^^
O)

^
0_

tu
re
CL
1
-a
•r-
r—
o
00

00
oo


CM


en
oo


CM


LO

OO
LO
oo
LO


oo
00


en
LO


CO











O)
*^^_
•0}
^^*
ca

en
CM


^
r-1

to
00
<—

tn
oo
r-'

to
en

LO
en
LO
tn


to


CM
tn

•=3-
to















o_

to
CM

oo
r—


CM


CM
CM


to
CM

OO
OO


to


OO
CM

to







*• — ^
re
^
O)
oo
o

s^^ f

•z.
oo

oo


oo


o


to
OO


oo

CM
CM


CO
OO


en
oo

00
oo









^
re
0)
-^
**— *

oo

o
o
LO
*
r—


O
LO
^

O
o
LO
r*

O
0
LO

o
o
LO
n

o
LO
o
LO


o
o
o
**
oo
o
o
LO
ft

o
o
0
oo








0)
-^
a>
^-^

*s^
oo
oo

o
o
LO


o
o
LO

o
o
LO


0
o
LO

o
o
LO

o
o
LO
o
o
LO


o
o
LO


o
o
LO

o
0
LO









01
-^
o>
v~""*

Q
I/
oo
175

-------

























Q.
ID
O
o;
CD
i — i
O
C/)

>-
03
^
LU
1 1 1
111
o;
LU
•^
o

^SZ.
o

oo
,
+-> O CU
O 4- C
r— 0
n:
-O
CU
"55
S-Q
CU
4-J
03
-o
CU
.C
I/)
— • i-CJ
O3 CU
-E -i->
	 O3

1/5
ro
CU

-o
O)
JC
CO
S_CQ
Ol
^0
2


-D
cu

CO

CU

ro
S


c E
••- 0

CO *t— )
O fQ
i- 0
oct:





•r—
O
OO





00 «3- OO COLO i— OOOO OO
^j- oo . co i— ^ CTI LO
CM









oo oo o COLO r— LOI^. LO
CTlCOCOi — OOCOCMCNJ
r— OO CO LO








CM oo r^ coo LO coco co
co oo LO coco co «=J-co r~x
LO i — OOl — •* i — OO CO



ro ro ro ro
co co cocu , S. >, S~ S->>i->>
OO OO OO O OO OO O O03 O03
oco oco (Jco o Oco uco O O-C u^:






i — CM OO «^-LO CO I~^.OO CTl






*d" vl- CM 1 "3-
CO CO C\l
•—i— CO


o3 03 O3
cu to cu cu
.C E JZ JZ.
S 03 S 2

E E -O E C
O O O O 03 O
O O CO O -E O T3
cu
> a.
n
03 1
0 -(-> -Q
r— O 3
1— CO
176

-------
0.
oo
oo
o
1
—1
oo
rs
fV
LJl.
O
— 1—
ml—
D_
oo
O
n:
ex
LU
oo
et

Q-
1
O
i— i
—i
O^^^^
"^^"
OO S-
Q \
i-
E
"•i—
z. oo
— 'OO
o
oo _i
oo
O h-

LU
Z. i—i
LU CC
C!3 I—
0 5
o: z.
h-
i — i •>
z. s.
>,
LU \
oo h-
<
:r:co
Q- 0
Q "~
1-1 z.
| | !
0
oo oo
oo
«o
-—N_I
— i
OO _!
*•— ^* I-H
o
oo oo
oo —
O~,
_l ±£
LU
J 1 1 1
i— i a:
O 0
oo
^~
O LU
LU Z.
\— O
< 1
|_J 5"
^^ ^-«
I— O
oo a:
LU LU

U~l
CN
k


LU
_l
ca
<:
i—




to


H3
CU
O

-(->
O
ta
i.
Q.

CMLOCNjco^-r^ooi—
cr>c\icococo^-oooo
tOlOCOCMOOOOi — i —

cMCM«d-r--«3"cy>oooo
r— LOCOi— r— VDi— O
r^» ^~ CM o*& LO co r^ LO
CM CM r— i— r—

CMLDCMCO-vt-r^-COi—
cncMcocooo-vfooco
VOlOCOCMCOOOi — i —

LD^Dr^.^t-CMI^U3C7l
criCO<*coLn^t-cMi—



UDCVjr^LDtDi — COCO
LOi— r— UDLOOOCMCO
•^- <=J- CM i— CM CM i—

Lr)co-=i-coLnLncor-~Ln
CM CM i— r— i—



i~v.Lrjio^-co«Di-^o
COr— Or^-CMr— LO«sf
CM CM i— i— i—


CO n— CT> CM 
CnCO^COLD^t-CvJr—


CMr~-.ooco^t-uDO
to c\j co f^o O") r^« o^ ^s*>*
CO CO ^- r— i— i—


oococni-ocMr^uDcyi
a^oo^i-coLn«^-oji —










CC dL C£ C£
oooooooooooo

r*f*r\t\rtn*\r,
Q-Q-1— h- D-D-h-h-
Luoocc:2:LuooQi2:





























































































cu
co
to
r—
,f_
•)->

o
c


II
1—
z.
cu
CO
(T3

^
•r-
+->

-a
O)
o
3
-a
O)

•a
cu
H ~S-
0

h- "OL
o:
&_
3
O
•4-J
2 c
O 0
i — O
Q.
II
co
c
•i- O
i.
Q.
to
•a
II CU
I
Q- i —
oo a.
2
o
i_
2
O -(->
Q. CO
•r-
i— ra
r- S-
n3 -t->
M- to

II II


a. D;
Lu OO

r3"
177

-------



1
_l

cn t- -r- ^
re o -MOO
s- 4- re E

> Q. O O
•=C ct: i—

^
i.
^j O_ C^j
ro o
'o ^1-
o
CO -^
Q_ i-
Q. ~^
E
(J

f\


^ 	 s
E i.
CU O >-
CD S- T- \
ro o -MOO
i- 4- re E
CU 4->VO
> CC O O
< cc: i—
N^.*.

^_^
b
-<
 4->
CL ro
O -I-)
t- 0
0 CC
CL
r— ^3
•r- O
0 i-
00 C3



p_
•
o




, — , 	
0 O




1 — 1 —
r~~ r^^


CO CO
, — , 	
r- r-




C\J
•
o






CM CM
O O





CO CO
CO OO

CO CO
en en
oo oo

-— n-
, 	 ,__
r~* r~


co en
r— CO
i i
o o



(/)
E
re
cu
E J2

O 0
O OO


r-




r—
.
r—




r- r-
r— •—




00 CX)
r~" i—


o o
en en
<— <—




p^.
.
f-^






r^. r^.
i — i — •





en en
CM CM

IT) LO
CD O
CO OO

CO CO
CO CO



O UD
r— CO

O O



c/)
c~
re
^
E JD

O 0
0 00


CM




OO ^~ '-O r— ^" r^» CO "'J" LO
• •« • •• • |> • |
CD ^— ^~ r— f~^ CD r-~ CO ^"




rooo ^ LO uo r-r- *• ^ oo cocn ^-^ ^-r^
O O i — O O i — i — O O O i — i — CO OO ^J- "vt"




oo t*-. LOUO CMCM co cncM i^cn r~. oo r~~.cn rv.
CMCM OO COCO CMCM CM i— CM CMCM CM CMCM CMCM CM


1010 I*-, coco oo Is*- oocn ^i-oo LT> ^t- ^s- ^j-co ^j~
oo co ovo coco en OCM coo co •— •— ooo oo
CMCM CO COCO CMCM CM CMCM CMCO CM CMCM CMCO CM




LO CO CM ^~ CO CD r—* 00 CO
• •• • •• • (• • i
OOO r— Oi — r— *3"CM






u->LnoocMCM^-«d-ooocnooo oo oo r— to
O O O O O i — i — • O i — O i — i — ' ^t" *^~ CO CM





cncn en r-^r~^ cncn en i^<* cn^o en cncn cnvo o~i
CMCM i — i — CMCMi — CMCMi — i — i — CMCMr — i — i —

vo vo co ^ vo co co ^ "^" ^ vo oo ^j~ r^ r^ vo co vo
OCD en f^-t^. OCD en co«d- CD +-> -t->
ro ro re re ro ro ro
cocu to tocucu cu cu tooi cu
E.E E E-E^= J= -E E -E JE
ros re re22 2 2 re2 2
QJ ^^^ Qj fL) ~~^ ~-^, *^« 	 *^s^ QJ ^^ "^^
C-QEEJDE-QEE E EEJDE E

oo o oo oo o ore ore o oo ore o
ooo o ooo ooo o o:n o:n o ooo o:x o


oo«3-Lnvor^oocn o

                                        CO
                                        uo
                                         re
178

-------
1


1— 1
fc
o
§
(_>
LU
•S
CO
g-^

Cw
0
CO

8
LU
i
ijj


-at
i
S
*?
LU
LU
O
LU
§
X

DC
O
LU
HH

^
LU
I—I
t
LU
Q.
O
Lu
CM
*t-
LU
_l
3
r-
0*0

11
£
at

s
c
o
4-1
ro
I'R 1
§fO* «
•00 o o
CO U
*•— XI J-
«-*- £4
"Sg S2
§'F- flj  •*-><«-


r— p 3
fl t ^
C i-
= tg
fc §
> -r-
ro
CO *O

^ C
01 Ol
^z o
I/I
**S

3


•-!
0. ro



F- Q



toooo r^moo ino>
• • «ii i i* *i*t ••
F— OF— F— ro CM into

in o LO F-CMO ooi—

LO O CM CMCMV fOO
CM






OOLOCO* O O^- 00 COO
• . 1 1 . 1 . 1 .
O'-oo F- IOF- vo ocn
F~* ^~ CO

O^^F— CM COcn O tOO>
« • • *| .|. .|*| ••
COCMOO F- r»o «* r^to
CM , £ >, E E^ E >, £
8000000 oooooorooroooooroo
VI UM O IO U Ul/l UVI U U JT Uf U UVI O -C U


t/l

i— CM co^into^^oocft o (O
o
I—
179

-------
A-
^
O
1
^
UJ
UJ
tx
O
UJ

o
IT
1—

1
U_i
>
I—H
1—

^— •
QL
Ll_l
i
1 —
— 1
t—
UJ
LU
cs
r^
^
Q.
O
o:
o
o
u_
z:
o
i
1 —
, J
O
rv1
1 1 i
J-LJ
Q_
Q

 QJ
0 C
1— O
n:


Q

T3
CU
r~
to
53
^_>
to
3

O
T3
Q
c~
s2
to

CQ

X3
O)
-C
CO
S-
CD
1o
s




1^^

-o
J=
CO
S-
CL)
^_}
to
2







"^
f







o
o
S-
dl
M-
4—
0
c
J_

•
"o
o
i-
cu
Q.
4-
4-
O
C
3
•
O
O
i-
OJ
Q.
runoff

r—
O
o
s-
CD
a


4-
o
c
3
^

•
O
(J
s-
OJ
Q.


tf«
4-
O
C
3
S-





^
0
o
•r—
+J
0
tO
s-
a.

CM CO r— O O i—
•* O CM r- 00 r—
a> i— i— i— co sr

CO CM CO CO CM CTl

CM co ^~ ^~ r^ co



CT> i — CO CM CM VO
• •••••
CO CTt CT» O *^" ^J"
r— i— i— CM CM CM


t— oo co LD uo o
• •••••
o r-v r^ co CM CM
CM 1— 1— 1— p- r—

o LO co «* co co
CJ> LO CO CO F^~ OO
CO >3- **• •=* LO LO

O") ^J* ^O O^ O f**"*1
• •••••
CO O Ol CO 00 CO
"=f ^ CO CO CM CM

i — LO i — o en o
co oo CTI r-x LO r^
Cx) CM CM CM CO CO




o co CT> oo oo rv.
r— LO ^f co r~. co
CO CM CM CM r- r-



co CM ^J- ^t- LO en
• •••••
LO r-> r^ r~~- o o
r— r- r— r— CM CM




co ^j- CM o en LO
• •••••
^- CM CM CM OO OO
r—* r— r~~ r^*









a: a: a:
OO CO CO C_) O O

•N *\ « «* »1 *»
Q. a. 1— a. a. I—
LI_ oo a: LL. co a:










































i ^
c
to
0) r-
C71 CJ> Q.
C fO 4->
0) -i- r- 2 E
C 5 r— O 10
•r- O T- S- i—
2 r- 4-> 1 Q.
o a. -(->
•— -a j= i-
CL Q) CD C7) 3
C O -r- O
i— T- 3 IO •»->
r- S- -0 S- C
IO Q- QJ 4-> O
4- CO i- to O

II II II II II


a. o- i— a:
u_ oo a: c/> cj
tC
180

-------
a

§
u
a
LU
0£
O
in 1-1
UJ I—
C9 N4
Z -H
ae ac
  • a.
  i 
§
            in  t-   .
            ui    cn
           •i-  C   '
   u
 • f.
Vt 01
ut
           U> 3 •
           Ut Cl


           5 C
             cu  «r
            Q-   O
             O
             c
              in
              a.


              65
                              CM
                              00
                                                     ^-  in     co       i   CM     to       i   CM
                                                     CM  oo     cn          mm          CM
                                                                            n     CM          o
           m      to

           i—      m
               CM     O


               CM     r-^
                                                         rocvjcvj^-
                                                                coroin
                                                                                       in
                                                                                       o
                                                                        co
                                                                        •a-
                       OO>— i—  OOr—  OOf— i—  OOOr-r—       rOCO
           CM CM

           o o
               in in  n   CM CNJ

          i-^  o o  o   o d
   n  o CM   no      oooo   r— vo
	i     •   •    •
                              oooo  * •*   vo  pji—   ml-  o  i~^i~.   inr-,  ir
                                     roro   10  mm   mm  01  cr>oo   cor-~  oo   ^ tx  cnoo  en
                              coo   rom  ^  r^c>u   o< —  oo
                       oromi—   r^cvjcocvi      m •—  «t   in r-  «*•
                                                                        CM  cxii —   cvim  CM
                                                                        •*  m ^   m i—  m
                       vo CM  mo  r— ^   o  coco   r*. o  0%  CM r^   cn f**  cri   i— r—  oo^j-  co

                       cn n  mi—  i*- CM   n  CMO   «3-1—  ^  ^ i—   ^-o  ^   mr—  mf*-  m
           r~ r™*   CO CO  CO CO  CO  CO CO  CO CO   CO  r— t-~  CO ^x   CO  CO CO   CO ^^  CO

           r-^ i-^   coco  0003  m  mm  coco   oo  r-^ cn  oo ID   co  cocci   co 10  co
                          10
                          ai
                      u>     in   co     u>
                              ~  J=     c
                                 ^     s
                                                                                           S  i
           10     ,   £  >>  E  £ •§,  E  >,  £
35  35  35  3   35  35  3   35  35  3  35  35  3
                                                     181

-------


-
Lu
3;

cr
c
U_
^
o

I—

§
h-
CO
LU

CO
to
o
_]
J—
z
LU
O£
1—
ID
z
O
CO
<:
LU
_J
CO
?




o
1
w
L.
•
io.'S
3 -*
C£ -~-
.
*o IT
uz >,
t- ^-
CO 1—
a. —

i»- -— •
t- t.
o z >,
C ~v
3 1—
a -—
<4- S.
t- X
o •--,
c a. a
3 ^
a •—

" ^^ ^
o s-
u >,
I- Z -v.
0) 1—
a. ~—

it- ^~N
M- S.
O >i
c z ^
3 1—
ee —







CO
•o
Ol
.c
10
(.
01
+J
S




<*- t.
ti ^
o -C
§0. a
-*
a: ^-«

•
"o IT

i-z <;
0) 1—
Q. —

t- !-
0 >,
C Z ~^
3 I—
a: *—



C C
•r- O
10 +->
Q. fd
£+J
O
u a:



•"^ 3
o o
5 °
o

$



co
r— •




^_

in
CO


CM
CT>





r>.
in



o\

r~.






«*
CM





in




co

^~




to
S
Ef,
35



i-


•* !fi ~
oo ii i i en
r-


r— CO O
00 II 1 1 to




«• 1— l-~

o CM ii i i en



in <• in i in i oo
•— i— to r~
i— to




VO <• CM 1 IO l<±
* i— i— CM i—
CM


O CM CO «t r-

00 CM O CO 1 •»
CO





CM in •— o ^ i— in
in to in
CO




»— in n- o r— en CM
CM * i—
r-~


t-* 00 ft O CO CO to

co o o o o co r-.
^~


•<-> •<->•!->
Id Id Id
VI to Ol IO to CD 4)
c c -c c c x: .c
•d id X id a X X
at 0) ~^ 01 ai ~x. ~^
If 1"! 1 If If 1 Is
<_> 00 O OO O O OO O OO O OX



CM co «i- in to r-» oo


f^ 1 00
I— CM


CM to
00 1 00




CO CO

to 1 CM



r— 1 CM
p~ r~-
r^
*—



CO 1 r—
CO CO
in


l~» 1-

CM i in
i^.





CM P~ •!»•
oo o
r>.
•—



CM CO 00
tO i—
in


CM O CO

o in CM
r-~


+J +J
id id
„ „ „
Z ^ S
£>> £ £f,
O Id O O O
o :r <_> o oo



o» o


in r~
i to oo
CO CM
^~

o in
i en i—
CM r^



r— O

1 CM 00
CM O!


1 r— CO
O i—
r~- in
CO



i CM in
to en
in w


i- «•

i co r^
•3- CO





i i in
en
CM
CM



i i r^
oo
r-x


•3-
i i
00
o


+•> •«->
Id Id
J ^
X X
^^ "E
O id O
o z o


(/)
Id
1 '
0
1—





































c
o
4J
Id
N
^
+J
s-
ai
t-

cn
c
U
a.


•»
2
e
4->
.C
Ol
Id
(.
+J
V)
§"

'a.
r-
Id
1 1
S-
182

-------













*T^"

,^>

•—
z
LU
8
cc.
1—
z
1
LU
1 1 1

O
1 1 1
g
^
r~
^^
.___

UJ
UJ
en
1



Q_
O
o
Qf

Q

^
1
1
00
ll J

I/)

O
_J
1—
21
UJ

o;
I—

z
r—
ro

^.

UJ

CO
rf
?





•2
o
K-







Q

•a
•c
CO
1



u
T3
1
CO

ro
3E





CO


ai
V)
S-
cu

(0





«£

TJ


O
Ol
s
00
CO
LO
1
CO

•*

o
in
co
i
0
CM


r—
ol
Ol
§

1
o
o
in
CM
CO
i

CO


o
CO

1
0
Ol

01
CO
r^
\
co
0
8
1




CM
to
1

^f








oo


Q_
Lu
o

1
0
in
CO
oo
o
^f
i
CO
o


0
o
01
1

^

oS
co
o
Ol
i
o
10
LO
„.
p^
f*-.
1
00



o
CM
O


0
§



01
1
Ol
01
o
10
1
o
0


00

10
^f











a_
oo
o
o
in

§
X
CO
o

1
Ol

oo

o
o
Ol
1
o
•^

1 —
oo
i
§
o
CM
Ol
1
O
00
LO
^
fX,
,__
1

IT)


8
0

1
o
in
co



Ol

ro
co
0
vo
i
o

in

CO
i
0








ce
oo



cz
o
00
5
i
o
vo
n
o
CO
^f
1
in

00

o
oo
Ol
i
§


in
CO
10
vo
o
oo
Ol

o
CM
^
f^
^^
i

CM


O
CO
Ol
1
0
§

1*^

f—
1
00

o
1
o

LO

in
i

oo








CJ


a.
LU
O
LO
01
1
O
0
CM
*SJ-
CM
1

VO
CO
O

o

1

CO

CO
LO
A
LO
g

CM
1
O
CM
tv.
CM
O

1

^2


CO
r—


o
CM
Ol



^^
LO
1
CO
o
Ol
vo
t
o
•a-
LO

Ol
INI
1

CO











Q-
00
O
8
LO
1
O
vo

CM
^f
CM
1
CM
Ol

O

O

1
8
CO

LO
1
OO
o

CO
o
s
CO
o

1

CO


0
^—


0
Ol



f1^
LO
1

o
0
1
o
in
in

Ol
CO

CO
CM









O


ce

















































» 1

cn 01 Q.
c: ra
cn •- ^- s S
C 5 i— O O
§'"" ,2 +S ^" "o.
Q. +J

CL Ol CO Ol 3
C (J -r- O
I— -r- 3 tO •!->
i— V- T3 i. C
ro Q.  o
VH t/t i- to u
n ll n it n


o. CL. i— o:
LU oo o: oo cj




fO
183

-------
 oil
oo

o:
o
:r
O_
oo
o

Q_
LU
LlJ
>-
I-U
z
o
oo
CD

<

<
D.
O
o;
            •o
             o>
             to
             S-
             cu
oo
oo
oo
o
CN
p-> I
CQI



1 —
ro
•!->
O
1—




Q







O








CD










<









n3
CU
O
•i —
•4->
O
re
S-
Q-
0
00
CM
to
t
O
CM
^—
CO
o
LO
o->
1
o
CTl
CM
O
CTl
to
CM
1
O
r—
LO
OO
o
LO
CO
p"^
1
o
o
oo
CM



o
CTl
r-v
o
CM
o










C£
oo

r,
D_
U_
O
OO
OO
LO
f
0
LO
CM
l~^
O
«=f
00
1
0
cr>
•~
o
CTl
CM
CM
1
O
LO
^-*
OO
o
o
LO
r—
1
O
00
CTl




O
CTl
to
1
O
CM
CTl










a;
oo

ft
Q-
00
0

CM
LO
1
0
to
CTl
to
0
**
00
|
O
r~-
1
o
^t
CM
CM
1
O
OO
o
oo
o
LO
«tf-
I—1
I
o
r^.
CO




O
r-^
to
I
O
CTl
OO










C£
oo

•\
1—
o;
o
*d-
00
LO
i
o
LO
LO
to
o
r-.
i~^
i
o
CTl
CTl
O
to
CM
CM
1
O
o
CO
CM
0
oo
to
r—
1
o
«3-
CTl




O
00
to
1
0
OO
00











(_>

t*
o_
LJ_
o
to
r~v
OO
i
o
CTl
o
LO
o
o
to

o
00
CO
o
o
to

1
o
CTl
^_
CM
o
to
o
p-_
1
o

5-




o
o
LO
1
0
l^s
10











o

ft
a.
oo
o
to
LO
oo
1
o
00
to
^~
o
CO
LO
1
o
CO
r»».
o
CM
LO
r~
1
o
o
o
CM

o
00
CTl
1
o
*3-
CM




0
CO
^~
1
o
CM
to











o

ft
t—
01


































2
o
CU r—
CD Ol Q.
C ro
CT -r- 1— ^ S-
C g — 0 0
•1— O T- i- 1 	
•g i— 4-> t Q-
O Q. 4->
r- T3 -C S-
O. CD CU CD 3
C O -r- O
i— T- 3 n> -M
r- S- -V S- C.
(C Q. O) +J O
M- to S- to CJ
II II II II II

a. a. \— cc
u- oo cc: oo c_>



^^^^
ro
                                          184

-------
                                  REFERENCES
Barnett, A.P.  1977.  A Decade  of  K-factor  Evaluation  in the Southeast.  _In_:
     Soil Erosion:  Prediction  and  Control.   Soil  Conservation Society of
     America.  Ankeny,  Iowa.  97-104.

Beaton,  J.D. and  S.L. Tisdale.   1969.   Potential  Plant Nutrient Consumption
     in  North America.  The  Sulphur  Institute,  Washington,  D.C.

Brady, N.C.  1974.  The Nature  and  Property  of  Soils  (8th  ed.) MacMillan, New
     York.

Bureau of Reclamation.  1978.   Drainage Manual.   U.S.  Department of Interior,
     Washington,  D.C.

Enfield, C.G. and B.E.  Bledsoe.  1975.   Kinetic  Model  for  Orthosphosphate
     Reactions in Mineral  Soils.   EPA-600/2-75-002.   U.S.  Environmental
     Protection Agency, Corvallis,  Oregon.

Haith, D.A.  1973.  Optimal  Control  of  Nitrogen  Losses from Land Disposal
     Areas.  Journal  of the  Environmental  Engineering  Division, American
     Society of Civil Engineers.   99 (EE6):   923-927.

Haith, D.A., A. Koenig  and D.P.  Loucks.   1977.   Preliminary Design of Waste-
     water  Land Application  Systems.   Journal  of the  Water Pollution Control
     Federation 49(12):  2371-2379.

Haith, D.A.  1979.  Effects  of  Soil  and Water Conservation Practices on Edge-
     of-Field Nutrient  Losses.   In  D.A. Haith and R.C. Loehr, editors.
     Effectiveness of Soil and  Water Conservation Practices for Pollution
     Control.  EPA-600/3-79-106.   U.S.  Environmental  Protection Agency,
     Athens, Ga.  72-105.

Hamon, W.R.  1961.  Estimating  Potential  Evapotranspiration.  Journal of the
     the Hydraulics Division, American  Society of Civil  Engineers.  87(HY3):
     107-120.

Hanway,  J.J.  1962.   Corn  Growth and Consumption in  Relation to Soil
     Fertility.   Agronomy  Journal  54(2):   145-148.

Hershfield,  D.M.  1970.  A Comparison of Conditional  and Unconditional
     Probabilities for  Wet-  and Dry-Day Sequences. Journal of Applied
     Meterology.  9:  825-827.
                                     185

-------
Hill, L.D.  (ed.).  1976. World Soybean  Research:   Proceedings  of the World
     Soybean Research Conference, Champaign,  111.,  1975,  Interstate Printers
     and Publishers, Danville, 111.

Jones, G.D. and P.J. Zwerman.  1972.   Rates and  Timing  of  Nitrogen
     Fertilization in Relation to Nitrate-Nitrogen  Outputs and Concentrations
     in the Water from  Interceptor  Tile  Drains.   Search  2(6):   College of
     Agriculture and Life  Sciences,  Cornell University,  Ithaca,  N.Y.

Klausner, S.D., P.J. Zwerman, and D.R.  Coote.   1976a.   Design  Parameters for
     the Land Application  of Dairy  Manure.  EPA-600/2-76-187.   U.S.  Envrion-
     mental Protection  Agency, Athens,  Ga.

Klausner, S.D., P.J. Zwerman and D.F.  Ellis.   1976b.   Nitrogen and Phosphorus
     Losses from Winter Disposal of  Dairy  Manure.   Journal  of  Environmental
     Quality. 5(1):  47-49.

Langdale, G.W., R.A. Leonard, W.G.  Fleming and  W.A.  Jackson.   1979.   Nitrogen
     and Chloride Movement in Small  Upland Piedmont  Watersheds.   Journal of
     Environmental Quality.  8(1):   49-57.

Lauer, D.A., D.R. Bouldin  and S.D.  Klausner.   1976.   Ammonia  Volatilization
     from Dairy Manure  Spread on the  Soil  Surface.   Journal of Environmental
     Quality.  5(2):  134-141.

Martin, J.W. and W.H. Leonard.   1967.   Principles  of Field Crop  Production.
     MacMillan Co., New York.

McElroy, A.D., S.Y. Chiu,  J.W. Nebgen,  A.  Aletti  and F.W.  Bennett.  1976.
     Loading Functions  for Assessment  of Water  Pollution  from Nonpoint
     Sources.  EPA-600/2-76-151.  U.S.  Environmental  Protection  Agency,
     Washington, D.C.

Mockus, V.  1972.  Estimation of Direct Runoff  from Storm  Rainfall.   National
     Engineering Handbook, Section  4,  Hydrology.   U.S.  Soil  Conservation
     Service, Washington,  D.C.

National Oceanic and Atmospheric Administration.   1974.   Climates of the
     States, Vol. I and II.  Water  Information  Center,  Port Washington, N.Y.

Ogrosky, H.O. and V. Mockus.  1964.   Hydrology  of  Agricultural  Lands.   In:
     V.T. Chow  (editor).   Handbook  of Applied Hydrology.   McGraw-Hill, New
     York,  Chapter 21.

Smith, C.N., R.A. Leonard, G.W.  Langdale and  G.W.  Bailey.   1978.  Transport
     of Agricultural Chemicals  from Small  Upland Piedmont  Watersheds.   EPA-
     600/3-78-056.  U.S. Environmental  Protection  Agency,  Athens, Ga.

Smith, E.E., E.A. Lang, G.L. Casler,  and R.W.  Hexem.  1979.  Cost-Effective-
     ness of Soil and Water  Conservation Practices  for Improvement of Water
                                     186

-------
     Quality  In:  Haith, D.A.  and  R.C.  Loehr  (eds.)   Effectiveness  of Soil
     and Water Conservation Practices for  Pollution  Control,  EPA-600/3-79-
     106.  U.S. Environmental  Protection Agency,  Athens,  Ga.

Soil Conservation Service.  1968.   Soil Survey  Clarke  and Oconee  Counties,
     Georgia, U.S. Department  of Agriculture, Washington,  D.C.

Soil Conservation Service.  1971.   Soil Survey,  Cayuga  County,  New  York.
      U.S. Department of Agriculture, Washington,  D.C.

Soil Conservation Service.  1972.   National Engineering Handbook:   Section  4,
     Hydrology.  U.S. Government Printing  Office,  Washington,  D.C.

Soil Conservation Service.  1975a.  An  Inventory  of  Ohio  Soils-Crawford
     County.  U.S. Department  of Agriculture  and  the Ohio Department of
     Natural  Resources, Columbus,  Ohio.

Soil Conservation Service.  1975b.  Soil Taxonomy.   Agriculture Handbook  No.
     436, U.S. Government Printing  Office, Washington,  D.C.

Stewart, B.A., D.A. Woolhiser,  W.H. Wischmeier,  J.H.  Caro and  M.H.  Frere.
     1976.  Control of Water Pollution  from Cropland.   Vol.  II.   Appendix A.
     EPA-600/2-75-026b, U.S. Environmental Protection  Agency,  Washington,
     D.C.

Tubbs, L.J. and D.A. Haith.  1977.  Simulation  of  Nutrient Losses from Crop-
     lands.  ASAE Paper 77-2502.   American Society of Agricultural  Engineers
     St. Joseph, Michigan.

U.S. Department of Agriculture.  1972.  Usual Planting  and Harvest  Dates.
     Agriculture Handbook No.  283.  U.S. Government Printing  Office,
     Washington, D.C.

U.S. Department of Agriculture.  1977.  Agricultural  Statistics.  U.S.
     Government Printing Office.   Washington, D.C.

Walter, M.F., R.D. Black and P.J.  Zwerman.  1979.  Tile Flow  Response in  a
     Layered Soil.  Transactions of the American  Society  of  Agricultural
     Engineers.  22(3):  577-581.

Williams, J.R.  1975.  Sediment-Yield Prediction  with  Universal Equation
     Using Runoff Energy Factor.   In:   Present  and Prospective  Technology for
     Predicting Sediment Yields and Sources.  U.S. Department  of  Agriculture,
     Agricultural  Research Service, Washington,  D.C.   244-252.

Wischmeier, W.H. and D.D.  Smith.   1978.  Predicting  Rainfall  Erosion Losses,
     A Guide to Conservation Planning.  Handbook  No.  537.   U.S. Department  of
     Agriculture,  Washington,  D.C.
                                     187

-------
                                  APPENDIX  I

                  MATHEMATICAL  DESCRIPTION  AND VALIDATION OF
                    THE CORNELL  NUTRIENT  SIMULATION MODEL
                                  INTRODUCTION

     The Cornell Nutrient Simulation  (CNS)  model  is a mathematical model
which can be used to estimate  edge-of-field nutrient losses from croplands.
Earlier versions of the model  have  been  described by Tubbs and Haith  (1977)
and Haith (1979).  The current  version,  as  used  in this study, includes
several major changes from  its  predecessors:

     1.  Water  and nutrient  budgets  are  computed  for two soil layers  (0-10
         cm, 10-30 cm depths)
     2.  Snowmelt is computed  by  a  simple  degree-day method.
     3.  The detention parameter  for  the U.S.  Soil Conservation Service
         Runoff  Equation  is  adjusted  on  a  continuous basis according  to  soil
         moisture.
     4.  Soil evaporation and  plant  transpiration are computed separately.
     5.  William's (1975) modification of  the  Universal Soil Loss Equation  is
         used to compute  sediment losses.
     6.  Concentrations of  dissolved  nutrients in runoff are assumed  to  be
         determined by the  available  nutrients in the surface cm of soil.

     The pverall effect of  these  and  other  minor  changes have been to make
the CNS model less empirical.   The  overall  structure remains similar  to
earlier versions, however.   Soil  moisture  balances are computed with  a daily
time step and nutrient budgets  are  computed at monthly intervals.  The model
is deterministic; i.e., it  is  based on  readily available soil, crop and
meteorologic data and contains  no calibration  parameters.  This appendix
describes the mathematical  details  of the  CNS  model and summarizes the
results of validation studies  for Watkinsville,  Ga.  and Aurora, N.Y.

                               SOIL  WATER BALANCE

     The soil water balance component of the CNS model provides daily
estimates of direct runoff  (surface and  subsurface), erosion and percolation
from the surface  (0-10 cm)  soil  layer and  percolation from the subsurface
(10-30 cm) layer.  The general  structure of the mositure balance is shown  in
Figure (A)I-l.   The soil  is assumed to drain to field capacity in one day  and
hence the CNS model is limited to well-drained soils without near-surface
water tables or impermeable layers.   The general  water mass balances  are
                                     188

-------
                       Figure 1-1.   CNS soil  moisture model.
                                    RAIN
                    PRECIPITATION
   SNOW
ACCUMULATION
                    SNOWMELT
                 EVAPORATION
 EVAPOTRANS-
   PIRATION
                  TRANSPIRATION
                                                 EROSION
SOIL   MOISTURE
  0-10  cm
       TRANSPIRATION
                     t^DIRECT
                       RUNOFF
                                              SHALLOW
                                              PERCOLATION
                                       SOIL  MOISTURE
                                        I 0 - 30 cm
                                          DEEP
                                       PERCOLATION
                                189

-------
         Surface layer  (0-10 cm):

            dlel,t+l  = d16lt +  Rt  +  Mt  -  Qt  -  EU  - Plt          (A.I)

         Subsurface  layer  (10-30  cm):

                 d292>t+1  = d2e2t + PH  -  E2t -  P2t               (A. 2)
where    Rt  =  Rainfall, day  t  (cm)
         Mt  =  Snowmelt, day  t  (cm)
         Qt  =  Runoff, day t  (cm)
         Ejt =  Evapotranspiration,  layer  j,  day t (cm)
         Pjt =  Percolation, layer  j,  day  t (cm)
         6jt =  Available soil moisture,  layer j,  at beginning of day t
                (cm/cm)

     The available soil mositure  cannot  exceed 9j,  the available water
capacity (field capacity minus wilting  point)  of layer j  (cm/cm).  Rainfall
Rt is assumed equal to  recorded  precipitation  during day  t provided the mean
temperature Tt (°C) exceeds zero.   Otherwise,  the  precipitation is considered
to be snowfall.  The soil layer  depths  dj  are  d]  = 10 cm and d2 = 20 cm.

Snowmelt

     Snow accumulation  (cm of  water)  is  modelled as

                        St+1 =  St  +  ASt  - Mt                       (A. 3)

where St is the snow on the ground  at  the  beginning of day (cm) and ASt 1S
the new snowfall (cm) during the  day.   Snowmelt is computed using the degree-
day equation from Stewart et_ aj_.   (1976):

                    Mt  = (St,  0.45Tt),  Tt  > 0                      (A. 4)

Evapotranspiration

     Evapotranspiration  (ET) consists  of three sources,  EVt, evaporation from
from the soil surface on day t (cm)  and  TR]t and TR2t> plant transpiration
or water demand from the surface  and  subsurface layers on day t  (cm).  Thus

                          Elt  =  EVt +  TU                          (A. 5)

and since there is no evaporation from  the subsurface layer,

                               E2t =  T2t                            (A. 6)

     Both evaporation and transpiration  are based  on Ramon's (1961) formula

                                     190

-------
for potential evapotranspiration  on  day t,  PEt(cm).

                                0.021  D?
                            PE   = 	— e                        (A.7)
                              t   T   + 273  st
     where  Dt  -  daylight  hours  during  day t
            est =  saturation  vapor  pressure,  day t (mb)

Evaporation and transpiration  are  weighted  by  CPt,  the fraction of soil
surface covered by crop  canopy on  day  t.   Evaporation is assumed to be a
linear function of soil  moisture:

              EVt = Min  [(eu/9!)  (l-CPt)  PEt;  di8lt]             (A. 8)

Transpiration from the surface layer is  equal  to PEt, provided sufficient
soil water is present.
                  Tlt =  Min  (CPtPEtjd^t-EVt)                      (A. 9)

                  T2t =  Min  (CPt  PEt  -  Tlt;d2e2t)                   (A. 10)

Runoff

     Direct runoff  is computed  by the U.S.  Soil  Conservation Service's Curve
Number Equation  (Mockus,  1972;  Ogrosky  and  Mockus,  1964):
                                            2
                          (Rt  +  M+  - 0.2 Wt)                       ,
                    Qt=  Rt + 0.8Ht                             (A-U)


The detention parameter  Wt (cm) in equation A. 11 is determined from a curve
number
Curve numbers are usually  selected  from  one  of three values CNj, CNjj,
corresponding to three different  antecedent  precipitation conditions.  How
ever, in the CNS model cold- weather  detention  parameters are always based
on the wettest antecedent  moisture  conditions; i.e.,

             CNt = CNju,  for  Tt  <  0 or  Mt  > 0                    (A. 13)
During other periods, curve  numbers  are  selected  as  continuous functions of
soil moisture in the surface  10  cm  by  the  method  shown in Figure (A) 1-2.
This method is based on curves developed by  the  Bureau of Reclamation (1978)
which assign CNj and CNjji to  soil  moisture  wilting  point and field


                                     191

-------
Figure  1-2.  Curve number  selection as a function of soil moisture.
z
o
DC
U
CO
z

UJ
                              0.56,

                SOIL  MOISTURE IN  SURFACE  SOIL  LAYER

                              9    (cm/cm)
                                192

-------
capacity, respectively and CNjj  to  the  midpoint  between wilting point and
field capacity.  The function  in Figure (A)I-2  is  given by
      CNj; + eu (CNn - CNjVO.S  9"!          ,  eu  <  0.5 "§"1
CNt =                                                            (A. 14)
      CNn +  (9lt - 0.5^)  (CNm  -  CNII)/0.591,  9lt >_ O-

Percolation

     Percolation  is computed  as  the  excess  soil  water above field capacity:

      Plt = Max [d19lt + Rt + Mt - Elt  -  Qt -  d^i;  0]            (A. 15)

      P2t = Max [d2e2t + Pit  - E2t -  d2*2'>  °J                      (A-16)

Sediment Loss

     The modified Universal Soil Loss Equation proposed by Williams (1975) is
used to estimate  edge-of-field sediment loss X-^  (T/ha) due to rainfall
erosion.
                                     0.56
                      =        (>      K(LS)C    P
where K, (LS), C^ and P  are  the  standard  soil  credibility,  topographic, cover
and supporting practice  factors  (Wischmeier  and  Smith,  1978), A is the field
area (ha), Vt is runoff  volume  (m3 )  given by 100 AQt, and qt is peak runoff
(m3/sec).
     Peak runoff can be  estimated  by assuming  a  runoff hydrograph as shown in
Figure  (A)I-3.  In the figure D^ is  the  rainstorm duration (hr), Dc is the
time of concentration (hr)  and Da  is the  duration of initial  abstraction
(hr); i.e. the time from the start  of rainfall until runoff begins.  Since
total runoff  is equal to the area  under  the  hydrograph,
             Q t = qt' DC +  qt'  (Dt  -  Da -  DC)  = Qt'  (Dt - Da)        (A. 18)

where q  is peak runoff  in  units  of  cm/hr (q  = 0.028 q '  A).  To determine
       t                                     t           t
Da, it is assumed that the  duration  of abstraction is proportional to the
amount of abstraction  (0.2W^  in  equation A. 11).  Hence Da/Dj- = 0.2W^/R^-, and
equation A. 19 can be  re-arranged  to  give

                      ,t -  0.028A (Jt) (Rt  .Qt^.,Ut)                (A. 19)
                                     193

-------
                                          o
                                         Q
                                                                                       UJ
                                          o
                                         Q
                                                                                                 I/)
                                                                                                 cu
                                                                                                 03
                                                                                                 
-------
Equation A. 19 weights  average  rainfall  intensity (Rt/Tt) by the ratio  of
runoff to precipitation  excess  which  is  available for runoff.

Canopy Development

     Evapotranspiration  and  sediment  loss computations require estimates  of
CPt, the fraction of the  soil  surface  covered by crop canopy.  In the  case
sediment, the cover factor C^  is  a  direct function of canopy (Wischmeier  and
Smith, 1978).   If L-t is  the  fraction  of  the time period between crop
emergence and full canopy which  is  associated with day t, the canopy factor
     is estimated as


                          CPt ' r


This function is shown in Figure  (A) 1-4.

                                 NUTRIENT MODEL

     The nutrient component  of  the  CNS model  has a monthly time step.  The
monthly runoff, percolation  and  sediment loss values required for nutrient
mass balances are obtained by  summing  the daily values predicted by the water
balance component.  The  nutrient  balance model estimates monthly losses of
dissolved and solid-phase nitrogen  (N)  in runoff, dissolved N in percolation,
dissolved phophorus  (P)  in runoff and  solid-phase P in runoff.  It  is  assumed
that all dissolved nutrients are  in the  inorganic form and that solid-phase N
is organic.  Losses of solid-phase  nutrients  are assumed to be fixed or
adsorbed to soil particles.

Nitrogen

    Characteristics of the CNS  model's  soil N computations are shown in
Figure A-5.  Separate  inventories of  inorganic N are maintained in  the top
and bottom soil layers,  while  an  organic N inventory is computed for the
surface layer only.  Nitrogen  in  either  layer is assumed to be perfectly
mixed.  Only inorganic N in  the  top cm  of the surface layer is considered
available for runoff loss.   The  model  neglects denitrification and  other
volatilization  losses.   Since  nitrification is rapid in well-drained soils,
and the model time step  is large  (1 mo),  the  nitrification step is  not
modelled.  Nitrogen fixation is  not included  explicity.  When legumes  are
modelled, it is assumed  that the  plants  will  scavenge the soil for  inorganic
N and fix their remaining needs.  Fixed  N is  not considered available  for
loss in runoff or percolation  as  inorganic N.

     The inorganic N balances  are given  by

              Iln + pNn + MIn + RNn + mnOn -  UN1n - QNn - PN1n    (A. 21)
and               I2in+1 =  I2n +  PNm  -  UN2n - PN2n               (A. 22)
                                     195

-------
                  Figure 1-4.  Canopy growth function.
      1.0 ••
o
<
u.
o:
3
V)
   <
   o
u.
o
     0.5
   >•
   CD
o
<
K
U.
0.
u
   tr
   UJ
   >
   O
   o
                                      0.5                           1.0

               Lfl  FRACTION  OF  TIME  TO  FULL   CANOPY
                                     196

-------
  N  IN  PRECIPITATION
FERTILIZER  N
          SOIL  N ,
          0 - 10 cm

          mineral! -
DISSOLVED  N
 IN  RUNOFF

  SOLID-PHASE
   IN  RUNOFF
                                                      N
        PLANT
        RESIDUES
                   DISSOLVED  N  IN
                     SHALLOW   PERCOLATION
                    INORGANIC  N ,
                      0-30  Cm

                  DISSOLVED  N  IN
                  DEEP  PERCOLATION


         Figure 1-5.  CNS nitrogen model.
                     197

-------
In these equations,
         Ijn  =  soil inorganic N  in  layer j  at  beginning  of month n (kg/ha)
         On   =  soil organic N in  layer  1  at  beginning  of month n (kg/ha)
         FNn  =  fertilizer N during  month  n  (kg/ha)
         MIn  =  inorganic N from  manure  or  other  organic  residues during
                 month n  (kg/ha)
         RNn  =  inorganic N in precipitation  during  month n (kg/ha)
         mn   =  fraction of soil  organic N  mineralized  during  month n
         UNjn =  crop N uptake from  layer j  during  month n (kg/ha)
         QNn  =  dissolved inorganic  N  in runoff during  month n (kg/ha)
         PNjn =  dissolved inorganic  N  in percolation from layer j during
                 month n  (kg/ha)

The organic N balance is

                        On+1 = On(l  - mn) +  M0n  -  X0n              (A. 23)
Where
         M0n =  addition  of stabilized  (humus-like)  manure or plant residue
                organic N during month  n  (kg/ha)
         X0n =  solid-phase organic  N in  runoff  during month n (kg/ha)

     The parameters  FNn,  MIn, RNn  and M0n are  model  input  values.   The  para-
meter MIn includes  not only the inorganic N  in manure applied during month n
but also the readily degraded manure  organic  N which  has mineralized during
the month.  The remaining model parameters  are computed  by a series of
submodels.

Mineralization

     The mineralization rate, mn is  assumed  temperature- limited, and can be
modelled by the Van't Hoff-Arrhenius  relationship  (Haith,  1973).  Within the
typical range of soil temperatures  (0-20°C),  a linear approximation is
possible (Haith et__al_., 1977):
                      mn = moV!Tn        for Tnl 0               (A-24)

     where m0  =  yearly mineralization  rate as a fraction of the average
                  soil  organic  nitrogen  content
           Tn  =  average  air temperature  in month n (°C)

Equation A. 24  apportions the yearly  mineralization to the various months on
the basis of degree-months.  Mineralization  is assumed zero during any month
in which the average  air temperature is  less than or equal to zero.

Crop Uptake

     Total uptake of  N  in  month  n, UNn (kg/ha) is approximated by the sigmoid

                                     198

-------
function shown in Figure  (A)I-6.   If  sufficient  inorganic  N is present in the
top layer, all crop N uptake  is  assigned  to  the  layer;  i.e. UN]n = UNn.
Otherwise, the remaining N  requirement, UNn  -  UN-|n,  is  taken from the second
layer.  If UNn exceeds total  inorganic N  in  the  two  layers it is assumed that
plant needs will be satisfied from N  below the 30  cm depth in the soil
profile.  The relevant equations  are

            UN1n = Min[UNn;  Iln  + FNn + MIn  +  RNn  +  mnOn]          (A. 25)

            UN2n = Min[UNn  -  UNln;  I2n + PNln]                    (A. 26)

Runoff Losses

     Both runoff and percolation  losses of inorganic N  are based on Tjn, the
average inorganic N in layer j during month  n  (kg/ha):

                                                                   ,..„,
Since only the N in the top cm  of  the  surface  10  cm  layer is considered
available for runoff loss, the  "runoff  available"  inorganic N is 0.1Tj_n.

The portion which  is actually  lost  is  determined  by  the fraction of available
water Rn + Mn which runs off (Qn),  and  hence
     Runoff losses of solid-phase  (organic)  N  are  a  function of sediment loss
and are given by

                                      ERfjXnOn
                                Xn  =   -___  ''                      (A pq\
                                xun     lOOOp                        lA^yj

where
            P  = bulk density  surface  (10 cm)  soil  layer (g/cm )
         ERfl   = N enrichment  ratio

An enrichment ratio of ER^ = 2.5 has  been used  in  all  applications of the
model.  The average soil organic N is

                               TTn • °" V"*1                      (A.30)


Percolation Losses

     Percolation losses of N are computed similarly  to runoff losses and are

                                     199

-------
                 Figure 1-6.   Crop nutrient function.
o.  75 4-	
    emergence
  100
maturity
                PERCENT  OF  GROWING   SEASON
                                200

-------
based on the fraction of  available water  which  percolates:
                              Pin
                  PNln = - _  Iln                       (A. 31)
                         Rn + Mn
                                                                   (A. 32)
                         Pin
Computational Sequence
     Organic N levels are computed  by  substituting  equations  A. 29 and A. 30
into A. 23 and solving for On+i.  A  comparable  procedure  is used  for inorganic
N.  Equations A. 25, A. 27, A. 28  and  A. 31  are  substituted  into  equation A. 21
which is solved for \i n+i.  Similarly,  I2  n+i  is  determined  from equation
A. 22 using equations A. 26 and A. 32.  These  two  steps  may give negative Ii>n+i
and/or I2 n+1-  When this occurs, the  negative  values are set to zero and
runof and percolation losses computed.   Crop uptakes  are then determined from
available inorganic N minus the runoff  and  percolation losses.

Phosphorus

     The soil P model is based  on an inventory  equation  for available P;
i.e., that small portion of total soil P  which  in  principle is  available to
plants.  Interactions between available  and  either fixed or organic P are not
considered.  The model is shown schematically  in Figure  (A)I-7.   Primary
concern is with P runoff losses and only the surface  soil layer  is modelled.
The following mass balance  applies  in  principle to the total  available P.
However, since most of this P is adsorbed,  total available P  is  approximately
equal to adsorbed P.  Thus,

         APn+l = APn + FPn + MPn -  UPn -  QPn -  PPn -  XPn          (A. 33)

in which

         APn =  available adsorbed  soil  P in surface  soil layer  at beginning
                of month n  (kg/ha)
         FPn =  fertilizer  available P  during month n (kg/ha)
         MPn =  available P from manure  during  month  n (kg/ha)
         UPn =  crop P uptake during month  n (kg/ha)
         QPn =  dissolved P in  runoff  during month  n  (kg/ha)
         PPn =  dissolved P in  percolation  during  month  n (kg/ha)
         XPn -  adsorbed available P in  runoff  during month n (kg/ha)

The average adsorbed P in the soil  during month n  is
                           TF -  W" *                              (A.34)
                                     201

-------
-a
 o
 E

 to
 3
 s_
 o

-i.
 to
 o

-------
As with the N model,  fertilizer  and  manure  P inputs are input parameters and
the P ouput terms  in  equation  A. 33  are  computed.

Crop Uptake

     The sigmoid growth  function  from  Figure (A) 1-6 is used to apportion P
uptake over the growing  season.

Losses of Dissolved P

     The concentration  of  dissolved  P  in the soil  solution is determined by a
linear equilibrium  isotherm:

                                  an =  3dn                         (A. 35)

in which

            an = average concentration  of adsorbed available P in the soil
                 during  month  n  (mg/kg)
            dn = average concentration  of dissolved available P in the soil
                 solution  during  month  n (mg/1)
            g  = P  adsorption  coefficient


Since the concentration  an is  APn/p, the concentration of P in the soil
solution is


                                  '                                <*•*>
The adsorption coefficient  is  determined  by a  regression equation (Haith,
1979) based on data  from  Enfield  and  Bledsoe (1975).   The equaiton has % clay
(%C) and pH as independent  variables:
                                                  2
                 3 =  5.1  +  2.2(%C)  +  26.4(pH - 6)                  (A. 37)

     Concentration of  dissolved P in  runoff and percolation are assumed to be
the same as that of  the soil  solution.  However,  as with the modelling of
dissolved N losses in  runoff,  only  the  P  in the top cm_of soil is considered
available for runoff  losses.   Hence  in  computing  QPn, APn in equation A. 36 is
replaced by 0.lAPn,  and the  runoff  losses  converted to kg /ha are

                                  AP
All available P in the surface  layer  is  susceptible to percolation loss and
hence

                                  AP
                      PPn =  O-1   FT   Pn                           <

                                     203

-------
Losses of Solid-Phase P

     As indicated  in  Figure  (A)1-7,  solid-phase runoff losses of P consist  of
both adsorbed and  fixed  P.   Adsorbed  losses  are
                                           (A.40)
                    Total  solid  phase  P  losses  during
                         yp   -
                           n     TUUDp
A P enrichment  ratio  of  ERp  =  2.0  is  used
month n, XSPn  (kg/ha)  are
XSPn =
                                             PF)
(A.41)
where
            PF =  fixed  P  in  surface  layer (kg/ha).

Computational Sequence

     The simulation  calculations  are similar to those used for N.  Loss  terms
are substituted in equation  A.33,  and  APn+i is computed.  Runoff and

percolation losses are  subsequently  determined based on APn.  Whenever APn+]
is driven  negative it  is  replaced  with APn+i = 0.


                               VALIDATION STUDIES

     The CNS  model was  tested using  data collected in two previous field
studies  in Georgia and  New York.

Description of Testing  Sites

     The Georgia  sites  are two small fields in Watkinsville, Ga., that were
monitored  for runoff,  sediment and nutrient loss  in runoff from  May,  1974
through  September, 1975.   Percolation data was not collected.  The two fields
have predominantly well-drained Cecil  sandy loam  soil.  Field P2 is  1.3  ha in
area and had  no conservation practices other than cross-slope cropping.   The
second field  (P4)  is slightly larger (1.4 ha), terraced and  had  a winter
cover crop.   More detailed descriptions of these  fields and  their associated
management practices are  given in Smith j^t jj_. (1978) and Langdale et al.
(1979).  Sampling  and  analytical  procedures are described in Smith et al.
(1978).

     The New  York testing sites are six 0.3-ha plots  in Aurora,  N.Y.  from
which runoff, percolation and nutrient loss data  were collected  from January,
1972 through  December,  1973.  Sediment data was available, but due to
deposition in interceptor collection ditches  it was not considered reliable.
The 6 Aurora  fields  (A5,  A8, A9, A15, A20, A21) are a sub-set of 24  plots to
which manure  was  applied  at rates of 35, 100  or 200 T/ha  in  either winter,
spring or  fall.   The denitirification losses  which are  possible  at high
                                     204

-------
manure application  rates  are  not  included in the CNS model and  hence  the  100
and 200 T/ha plots  were  not  used  in validations.

     The Lima and Kendaia  silt  loam soils at Aurora are moderately to  poorly
drained and are characterized  by  a relatively impermeable glacial till  at  1-m
depth.  This produces  slow drainage and  occasional  high water tables  which
are not adequately  described  in the CNS  model.   However 12 of the Aurora
fields are tile-drained,  including 6 of  the 35  T/ha plots.  These six  plots
were assumed to be  reasonably  consistent with the assumptions of the  CNS
model  and were hence  used  for  model  testing.

     The plots were equally  divided into "poor" and "good" water management.
The former (A5, A8, A15)  were  harvested  for corn silage, hence  removing  all
crop residues, while  the  latter (A9, A20, A21)  were harvested for grain  with
the residues left on  the  field.  Management practices, sampling and
analytical techniques  are  described in Klausner et_ aj_.  (1976a, 1976b).
Drainage characteristics  of  the Aurora fields are also discussed by Walter j3t
aj_.  (1979).

Model  Parameters for  Validation Runs

     Although the CNS  model  relies on standardized input data which is  in
principle available from  secondary sources, the determination of model
parameters often requires  interpretation and judgement.  For example,  the
assignment of curve numbers  and crop cover factors is  not straightforward
even though this information  is readily  available in tabular form.  Field
conditions seldom correspond  exactly with the standard descriptions given  for
table entries and hence  assumptions and  interpolations are often necessary.
The model parameters  used  in  the  validation runs are given in Tables  (A)  1-1
through (A) 1-5.  The  following discussion outlines data sources and  any
assumptions required  to  obtain the specific values.

Soil and Field Parameters  (Table  (A)I-l)

     With the exception  of 9j,  K,  Ij0 and m0, all parameters for the
Watkinsville fields (P2  and  P4) were taken from Smith et_ _al_.  (1978).   The
available water capacity  6j  was obtained from the soil survey (Soil Conserva-
tion Service, 1968) and  soil  credibility K was  given by Barnett (1977).   Bulk
density p is the value at  15  cm,  and the (LS) and P factors for the USLE  are
computed based on field  slopes  and slope lengths.

     For the Aurora fields p,  6j,  %C and pH are all soil survey values  (Soil
Conservation Service,  1971).   Organic N  (00) and available P (AP0) data  were
provided by S.D. Klausner, Department of Agronomy,  Cornell University.   Soil
loss factors were not  determined  for Aurora since sediment and  solid-phase
nutrient losses were  not  tested for these fields.

     Initial values of soil  inorganic N  (Ij0) were not based on field
measurements.  In both locations,  the model was run from January 1, and  the
soil contains relatively  little inorganic N at  that time.  The  values  of  Ij0

                                     205

-------























00
Q
1 1 1
n:
00
py
LU
•
§
2
o
1 — 1
h-
Q
p-H
^
^>

py_
o
U_
oo
ct
1 1 1
LJLJ
h-
LU
1^
**v
e^
O.

Q
	 1
LU
I — i
U_

Q
2:
^^

	 1
i — i
O
OO


1
.
. 1


LU
i
OQ
^£
L—












































































r~
CM
**

o
CM
<


cr>
*^C




LO
n~
"^


00
•=£




LO
«=c



^J-
0-



CM
CL.



























i-
0)

cu
£
(13
S-
ro
O_













o-
C
















^

p-


O

p-
























*-
t
s
**.

1
(
i
c


e













0 f
3 r-
















}• •=;
•
— i—


0 «;
•
— p-













*-
CO
£
(
-s
C
x-


4
•r
-» I
o :
- c
— T

0 -i
1J P;
— .
X. A

ft
X.












u:
•> r-
- c















u
i- r-
•
- C

u
t r-

- C


^~

*•"»
£
c
•"^


4
•p
C
r
•^ I
e
= C
J
^ s
T> C
-* 4
r
>> :
^
c
O p-
: ^
1J r
3 p-
•r
<: r
- :
3 r
3

n
a c












3
~ r"
3 P-
P™














•)

• U
3 r-

0

O
3 p-


^s

^.
3
_^

>>
j

j
0
D.
O
J


i;
j
o :
s <
t-
u (

3 4
o :
(
(
0 !
> (
O i

f\

D S













- l~
- «
















1-
•)
- y


0
0
u




















>>
o

J

J

V
J

[j
2-

n
J I
•9 !



1 1 1



1 1 1



1 1 1

s.
• C
3



1 1 1



1 1 1





1 1 1

oo r^.
- CM CM LO
• • • •
3 O 0 0 C

CO r-
0 CM CO ID

-> o o o c



„
r —
i.
OJ
i- >>
O ro
4-J P—
(J
ro •>
S- <4- -Z.
0
4-> O) O
0 0 T-
ro T- C
>, f- 4-> (O
4-> U C7)
•P- 0 ro S-
i— -r- S. 0
•i- -C a. c
_f!) p> »r—
fO ^0 O}
•a s- c r—'-
O O) -r- ro r
S_ o 4-> T- J
O) Q. i- 4-> •»
O O T- I
p— 4J Q. c J
•p- a. .p- ^.
O "3
CO ' — » CO •>
oo o
C » _l •> r-
3_ M — - D. p- 1













^ f~
j c_
p-


















3 U




3 U



„
CM
S-
OJ

ro


rt
^^

CJ

c
ro
CD

O
c~
• r-i

^* p— ^*
O ro i
Z T- J
^ 4_) ^
DO *P~
«: c _
^ «P— «•*

«\
O
CM
»— •*
O
CM

CM
O
LO
i —
CM
0
LO
r-s
CM
o
c
3
C
O
co
00
CM
O
00
CM
CM


O

p^
CO

o
0 C

0 ID C

o
o c

o *d- C






i — C
4
i- r
CU !
>^
ro I
i — (
•r
« 4
Z. r
t
<_> -r
•p- p-
E <
(0
CD
1-
O
~*s *• — x
O r— ro
~ (O -C r
•^ -r- "~s^
31 4J CD
^ -r- ^:
-^ c —
•p-

*»
o
0


p^^
1


ai



LO
i
j
3
3


CO
1 i —


O
i co




00
1 CM

0
D O O
• O CO
3 CM

0
3 O O
• t£) ^J-
3 CM





rO
1J -C
_j ^^^
O CD
_ ^.
* — "

5 Q-

-> CU
O i —
M -C
— * — ^ rO
- ro r—
O ^= -r-
!>. ^^ ro
D CD >
r -^ rO
— »^^
^ P—
D_ rO
— •! —
O "O 4->
3 CU •!—
= X C
[Z *P~ 'P-
•o <+-
«*
« »\ Q
o u_ o.
E a. <
206

-------
















































UJ
^^
^£
H-
O_
ID

O_
O
py
O

Q
^^
^£

oo
i<"
0
1— 1
1—

1 — 1
— 1
o_
Q_
— 10 f^^
re O T- O-
Ol T- ro
>- r— >
<""> ec£
CX
CJ
•r"
rO_Q
cn
s- z:
o
E
l — i


CU
-i*; c.
rO
-P
O.
' — i

O.
0
s- z:
CJ



zr  fC-Q
03 ~ 1— >.
f) C^
Q.
e^
(J
•r~
C\
t- ^^
0
E
i— i


•a
cu
-E
CO
i_
CU
4->
ro
3£

i —
CM






^~.
O







1







•=J-
, 	
co





^- r^
1 CM CM
1 CM r-
^~
ro
-^
cn
\s
J**^
r—






CTl
fv»








1







^ — ^
LO
CO
CO





•^^
O
LO LO
00 O
CO O
r—









CM
0.

co ai
^—

cu c
>> s-
a: o
o

i— LO
i— cn







i







^?
, —
CM





*d- r~-
CM CM
CM r—
r-~




co o
CM

CU E
>> s-
a; o


r— *3~
i— cr»








i







^ — %
LO
CO
CO







LD ^£>
oo r^.
co o
f—









^~
Q_

r^
^«






^j-
00



*— ^
^j-
v.^-*
00
LO
^—






^- LO
00 .—
CM r—





<- LO
CM LO
CM





LO
^~






CO
r —




, — »
LO

^J-
^~
t-~






f^-^^—^
LO IO
CO •—
^— r—







LO LO
•CTl LO
CM










LO
«=c

r-.
r—






*N^"
00



^-^
LO
•^**
o
r*-.
r^—






LO
^
CO





LO
r-^
CM





LO
i~-






co
^>^




. — ^
LO

CM

r—






^-^
LO
O
CM







LO
*3-
CO










OO
«C

l^s.
t-~






^-
CO



x-^
r^
**_*-
CO
CO
1— .






1— (T)
CTi •—
i— i—





i— LO
«3" LO
CM





LO
r—






CO
p^»




, 	 N
CM

CO
co
^~






^•^^"^
CM LO
^j- ,_
r^ r—~







CM LO
CO LO
CM









LO
P—
cC

r*^.
r—






^J"
00



^^^
<^J-
^ 	 -•
co
LO
r—






•^f- LD
LO i—
CM r—





<* LO
CM LO
CM





LO
r—






CO
r^.




, — «
LO

CM
CO
r~«






^~N.^-^
LO LO
CO i—
i^ r-~







LO LO
CO LO
CM










a-i


r^» r^*
r— r~~






^" ^J"
00 00



* — x ^~^
LO 1—
*^~* *-~*
LD LO
LO «tf-
i — r—






LO <— LO
LO LO i —
CO r— r—





LO i — ID
r~ LO LO
CM CM





LO LO
i — i —






co co
r^ f"^




, — ^ ^^»
LO CM

CM CM
^f O







^•^ *~^^^*
LO CM LO
O CO i —
CM i — i —







LD CM LO
CO «d- LO
CO CM









O i—
CM CM








































































































s_
cu
"O
E
ro
E

S-

t-
o
(4—

co
r^»
CTl
i —
»
o_

~^3
E
ro
CM
O_
S-
o
t-

LO
^^
O1
"~

• •
CM

s_
ro
CU
>-

• ^
&_
CU
T3
E
• r~
ro
E
CU
S-

S-
0


CM

CTl
^-.

^jT
o_

«\
CM
O_

S-
o
ll
^r~
^
o^
^«


• .
r_

S_
ro
CU
>-

ro -£















































E
O
•r—
I '
ro
O
•r-
r-—
JC. Q.
•P CX
C ro
O
E «H
o
cn
c to

il -P
3 E
T3 Q

T3
CU CU
i — fO
a.
O. i/i
ro cu
to
CU CU
S- JZ
3 -P
C C
/rt (1 1
>U UJ
E U
+ o.

i- C
a> -r-
N
•(- tO
r— S-
•r* CU

s- E
cu 5

•**. ^"s.
2 0
207

-------
given in Table  (A)  l-l  are  based  on  values obtained by long-term  (10-25  year)
CNS model runs.  Hence  they are  roughly equivalent to long-term average  or
steady state values.  Annual  mineralization rate is the most  uncertain
parameter in the CNS model.   The  values of m0 given in Table  (A)  l-l  are
based on general values  given by  Brady (1974).

Nutrient Applications and Crop Uptake  (Table (A)1-2)

     Applications of nutrients were  obtained directly from Smith  et  al.
(1978) or Klausner _e_t _al_.  (1976a).   At Aurora,  based on experiments  by  Lauer
et_ a/L (1976),  it was assumed that  85% of manure ammonia-N would  volatilize
shortly  after  application  and hence,  the inorganic N applications  in Table
(A) 1-2  include only 15% of manure  ammonia-N.  Available P in manure  was
assumed  equal  to the dissolved P  content.  Crop nutrient uptakes  at  Watkins-
ville were estimated from yields  given in Smith et_ aj_. (1978) while  Aurora
values were  obtained directly from  Klausner _ejt _al^ (1976a).

     The organic N  in manure was  considered to mineralize much more  rapidly
than soil organic N.  Based on the  soil N balance given in Klausner  et  a!.
(1976a)  for  the 35  T/ha plots, a decay series of 50%^25%-10%  was  determined.
Thus 50% of  the manure  organic N  is  mineralized during the first  year follow-
ing application, 25% of the remaining  organic N is mineralized in the second
year after application,  etc.   This  decay series was combined  with  monthly
temperature-dependent mineralization rates  (equation A.23) to determine  the
manure inorganic N  inputs  MIn in  equation A.21.

Cropping Dates, Curve Numbers and Cover Factors (Tables (A)  1-3,  (A)  1-4,  (A)
1-5)

     The cropping sequences given in the tables are based on  plowing,
planting and harvesting dates given in Klausner _et_ jal_.  (1976a) and Smith et
al.  However,  the estimated crop  emergence, 100% canopy and  maturity dates
are guesses  based on typical  values for the two regions.  Cover factors  are
linked to canopy development and  were  taken from Wischmeier  and Smith (1978).

     The CNS model  is very  sensitive to curve numbers and attempts were  made
to make  the  selections  as  objective as possible.  In  both locations, fallow
curve numbers  were  used from plowing to 10% canopy.  The only fields with  a
history  of organic  matter  build-up were A9, A20, and  A21 at  Aurora and these
were considered to  have "good"  hydrologic conditions.  The remaining 5 fields
were  all "poor".  The Watkinsville soil  is  in hydrologic group B, while at
Aurora the groups change from plot to plot.  Plots A5 and A9  are  predomi-
nantly Kendaia (Group C) and Lima (Group B)  is  the major soil on  A8, A15,
A20, A21 (Jones and Zwerman, 1972).  However, tile drainage  artificially
changes  these  groupings, increasing drainage and reducing runoff.  Each field
was thus assigned to the next lower runoff  group, A for A5 and A9 and B  for
A8, A15, 20  and A21.
                                      208

-------
CM
D.
O.
LU
GO
CC
O
O
O
LU
CO
LU

o;
ZD
o
GO
LU
03


D-

o
m
 i
LU
—I
CO
 S_
 O
           U
           OJ
           O
          O
           £
           O) O
          O
              Q.
              O
              (T3
    CD
 n. CD
 o  w
 s-.  +->
c_>  GO
    CD
    O_
    O

   O
                          CO tQ     lOLO^CMCMCMCO
                         00
                                    O O O O O  O O
                                                               CO

                                                               o
                                                                     to CM en o o o o
                                                                     CO CO CM CM CM CM CO
                                                                     o o o o o o o
                         CTl
                             co
                                    oo
                                         i CTl
                                         . r-.
                                                               co
                                                                     co
                                                                         CTl CTl
                                                                                  i CTt
                                                                                          CTl
                         o o
                             o
                                    o o o o o  o o
                                       r- in co o  o
 Ol
 o

 CU                C1J  (/)
 CD               i-  CD
 i-                3  >
 Ol               -MS-
 £EE                ("0  fO
LU               s in
                                                           0000000
                                                               r— LO CO O O
                                                               s
                                                               o
 CD
 u

 CD
 CD
 s_
 cu

Lf,
   -p
 CD  CO
 S-  CD
 3  >
-M  S-
 fO  fO
                             CM
                                   CO


                                   LO
                                    S-
                                    o
                                   CJ>
                                       i— i— i—    CM

                                       r*"^ 0*1 o"^    ^^~
                                                                                         . co
                                                                     UD
                                  s-
                                  o
                                  o
                                             209

-------
TABLE  1-4   CROPPING DATES,  CURVE NUMBERS AND COVER FACTORS FOR WATERSHED P4
Crop
Rye



Corn






Rye







Corn






Date
1/1/74
2/20/74
3/24/74
4/23/74
5/3/74



7/1/74
9/1/74
9/16/74
11/2/74



12/1/74
1/21/75
4/15/75
4/24/75
5/24/75



7/1/75
9/1/75
9/16/75
Crop
Stage

Mature
Harvest
Plow
Emergence




Mature
Harvest
Emergence




Mature
Harvest
Plow
Emergence




Mature
Harvest
°/
Jo
Canopy
100
100
0
0
0
10
50
80
100
100
0
0
10
50
80
100
100
0
0
0
10
50
80
100
100
0
Curve Number
CNn
72
72
72
86
86
74
74
74
74
74
74
74
72
72
72
72
72
72
86
86
74
74
74
74
74
74
Cover Factor
ct
0.05
0.05
0.46
0.46
0.46
0.42
0.38
0.22
0.22
0.22
0.47
0.47
0.30
0.15
0.05
0.05
0.05
0.36
0.36
0.36
0.32
0.29
0.20
0.20
0.20
0.45
                                    210

-------












00
o
LU
00
CC
LU
I—
2
^£
cc
o
^>
o;
o
Lu

OO
rv
LU
CQ
s:
^
LU
o:
o
Q
j|

OO
1 , 1
1—
<^
Q
crs
•z.
i — i
Q.
Q.
O
C£
(_)

to
1


LU
—1
CQ
2
CM

O
CM
<


i — i
l — i
o un
-<
OJ
-Q
£
^^
CO
CU ,
0.
o
c
ro
O
^














CU
CD
rO
4->
00





CU
4->
ro
Q
^ ^, r>. r^ r*.
to P"» r*^ to to

I**** r^« r**« r^- r^«
to r~« r». to to
oo to to oo co


r-^ r^» r~- CM CM




r~» i-~. t^« CM CM
r^. r--. r-^ r~- 1^


to to to •— •—
CO 00 CO CO CO






o o ooo
r— O
r—




s-^
CM
•=C

O
CM

e^ C
	 QJ
CD
S S-
O QJ
i— . g
Q_ LU


CM CM
CM r^* r^*
f^Sfc ^^ ^v^. ^^
^ — . co rji r^-
r— CM i— i—
i — LO IO CO
r^ r>. i-v r-^ r^ r^ r--


p^. i^^, p^ r*>» r^^. ^^ ^*
to to to r^ r^s to to
CO CO CO to to CO CO


CM CM r^ r^. r^ CM CM




CM CM r~- r>. r^ CM CM
r». r--. r--. r-v r^ r^ r^


n- UD to UD r- ,—
00 CO 00 00 CO CO CO






o o o o ooo
O i—O





^-,
Lf) CM

 en o
4-> eC =a; c:
CU (/) ^— ^ ^— ' CU
S- O) CD
~^ j> ^ ^ y
4-> S- O O O)
ro ro •— •— E


CM CM CM
r*-. i — * r*-* co co co
^^ ^^ ^ — * ^- r^ r^.
r"~ tO tO "^^ ^^^ ^^^
i— CM CM Lf) CM i—

o o o -^. ^Z. \
r— i—i— ^- to 00
1-^ I-- 1-^
to to to

p^ ^^ r^^
to to to
00 CO 00


CM CM 1^




CM CM r^»
i^ t~^ r^


^to
CO 00 00






0 00
o
^~





LD

 ^
LO CTt O^
i— CM C\J

O O O
211

-------
ValIdation Results

Watkinsville, Ga. Sites

     Measured nutrient,  water  and  sediment losses are compared with CNS  model
predictions for the  17-mo  period May 1974 through September, 1975  in Table
(A) 1-6.  Precipitation  during  this  time was 123 cm on field P2  and 97 cm  on
field P4.  Observed  losses  were  taken from Smith et_ a1_.  (1978).  Runoff  pre-
dictions exceed observations  by  substantial  amounts on both fields, although
errors were smaller  on P4.  Dissolved N  and  P  are over-predicted by
approximately the same degree  as  runoff  on P2, indicating that errors  in
these predictions are more  likely  due to faulty hydrologic parameters  than
serious  errors  in nutrient  balances.   Sediment and solid-phase nutrient
predictions are quite reasonable,  particularly considering the crude and
somewhat arbitrary  nature  of  model  predictive  equations and parameters for
these losses.

     The most critical problem  is  in the simulated losses of dissolved P in
runoff.  Although the magnitudes  of  these losses approximate the
observations, the large  predicted  reduction  from P2 to P4 was not  seen in
observations.   As indicated  in  Table (A) 1-7,  this was the only  substantial
difference in losses between  the two fields  that was not accounted for by  the
model.   The probable sources  of  error is the absence of a source term  in the
CNS model for leaching of  P from plant material during the colder  months.
January, February and March  accounted for 56%  of the observed dissolved  P
loss from P4 which  had a rye  winter  cover crop.  The comparable  figure for
P2, which had no winter  plant  cover, was 29%,

Aurora,  N.Y. Sites

     The six New York fields  are  far from ideal as a basis for model
testing.  Not only  are the  sites  artificially  drained, but the primary
nutrient sources are manure  applications.  The CNS model is not  well-suited
for either of these  characteristics.  Nevertheless, the Aurora validation
studies  were considered  essential  since  the Georgia simulations  provided no
testing  of either the percolation  or snowmelt  portions of the CNS  model.  The
two-year testing period  at Aurora  had 189 cm of precipitation, 14% of  which
fell in  June, 1972,  when Hurricane Agnes passed over the sites.

     Observed and predicted  losses for the six New York fields are shown in
Table  (A) 1-8.  Observed values  were provided  by S.D. Klausner.  Examination
of percolation  observations  revealed another problem with these  sites.
Percolation was  improbably high  on two of the  fields  (A5 and A9) suggesting
that water flows were not  independent.  For this reason, comparisons of  the
mean losses shown in Table (A)  1-8 are more relevant than comparisons  of the
separate fields.  On this  basis,  runoff  and percolation predictions are
relatively accurate.  Dissolved  N  in runoff is underpredicted,  indicating
that more manure N  was  available for runoff than had been estimated for  model
input  values.   Observed  dissolved  P  losses were  nearly  an order  of magnitude
greater  than predictions.   The CNS model assumed that manure available P can
be described by the same equilibrium relationships as P  in  the  soil.   The
assumption appears  to be untenable.   The overprediction of dissolved N in

                                      212

-------
h-
^-—~
LU Ln
2: r^
p — i en
Q i—
LU
co "
s-
*• cu
U_ JD
u. E
o cu
"^ -i ^
^-. •+— '
ZD Q.
Qi CU
CO
Q 1
LU ^r
> r~-
a; en
LU i—
CO
CQ «
o >,
(C
31 s
1 »,^ f
r— ^—*
I-H
S CO
LU
00 I—
*^. l-H
o co
i— i
i— <:
C_> l— l
i— i C3
Q C£
LU O
Oi LU
Q- CJ3

_j cc:
LU O
Q Lu
o
s: co
UJ
co co
•z^ co
0 O
_l
u_
O 1—

•Z. LU
O i— i
CO CXL
, . i
»— i t
a: ZD
< ^
Q.
^ Q
O Z
0 <



vC
1
M

UJ
— 1
CQ
<
h-





































































•o
O)
-(->
O
• r-
•o
cu

a.
i
^^
D.

•a

cu ~a
r- CU
U_ >
S-
CU
to
.a
o




T3
0)
-t->
o
• r^
-c
a;

D.
CM
a.

•o

cu
•r- -o
u_ cu
>
i-
cu
to
JO
o




















•

en
ro UD "^ i — i — <£>
• • • • • •
(D i— CM CM O O
CM






•^^
"* — — *-. O "* —
fC JD ^J" "O
r--x en o Ln ro 10
• • • • • •
CD i — CM CO O i —
1 —







l£>
CM Ln LO CM ^f- Ln

o en Ln co o ^j-
•tf-








-^
"~^s *^^ (J **^
03 JD i— -a
o co UD •* ro oo
• • • • • •
co r-> ro en o Ln
CM






c: c

fQ C <*"~^11 **"** £Z ff~~^' *~~~*'
_c -i- ro "z. re -i- re rx re
^ _c: J= -c: .c
^-~ i— -zz — oi-^. D---^. m-^.
E — en to en en to en
O "O-^ to -^ -O.^ rd-^
^ — 4-> O) 	 -C 	 (1) 	 	 JT 	 	
C > Q- > Q.
M- O) i— M- 14- i— M- i *t-
M- E OH- T34- O"4- "04-
O •<— to O -r— O to O T— o
c T3 toe i— c: toe i— E
3 CU -r-3 O3 'r-;3 ors
o: co QQ; coo; act: coo;















































































































c:
o
•r~
+J
3

"o +•>
to c
(D
^_ t—-
C i=
•r- +-) •!-
E "O
2: cu cu
i E to
*3- •!—
DC T3 c:
^ 
O^COO
s: t— Q- i—

>s^-, ^"-* ^^. *^*^
to JD O -O
213

-------
oo
Q
	 1
LU
Lu

Z
LU
| ! j
s
1—
LU
CO
oo
^y*
«£_
O
1—
<
C£
<
>

Q
LU
t—
O
Q
LU
C£
D_

Q
Q
LU
a;
LU
oo
CQ
o
Lu
o
z:
o **
00 Q-
o; -a
rf" ( —
*•*. t^
a. re
5»"
O CM
C_3 Q_


P^*
1
1
\~4

LU
	 1
CQ
<
1—





















































•o
O)
1 j
o CM oo r-- ^j- CTI
•r- ^j- co un r^ uo
"Oil I i |
a>
c
E o_
O

M-
CU
O^ ^"
c a.
T3
-c o
0 -P
4-> CM
C Q-
O)
O
s-
O)
Q_ T3
O
s- o <=i- ^- oo o
aj oo r^. ^- 10 i—
CO 1 1 1 1 +
_a
o












c:
Z •!-
s: a> Q-
to
-o M-  d) <+- -C 4- O)
c > o a. o >
l|_ aj , — c 1C i — «4-
«*- E O3 T33 OM-
O -r- tO DC T- O£ tO O
c "o to i — to c
3 O) T- C O C -i-3
oi oo Q •!- oo -i- Q D;


r^
CO
i

















CM
1 — .
1















Q-
a>
to
to <*-
j= 1-
Q- O
1 C
•a 3
•r- a;
r—
O C
00 T-
214

-------
I—
^^
^_
LU
I-H
oi
h-
2:

Q
LU
>»
_J
O
CO
co
z.
e^C

Z.
o
1— i
h-
2
o
CJ>
("y^
LU
U_ 	 	
U_ CO
o ^
Z. CTi
ID r-
CtL
«
Q S-
LU HI
tt. E
LU CD
CO O
CQ O)
O 0
1
z: CM
H- r-
i—i CTi
co "
"^ >-
O i.
I-H (O
1— 3
c_> c
i — i (O
Q o
LU — -
f^S
Q- CO
LU
—1 1—
LU I-H
Q CO
O
^- \s
co o
z. >-
0
3
LU LU
o z.
Z. C£-
0 0
CO U_
0£ CO

O) (O
•— 'o
o o
to i-
to o>
•r- 0_
Q
c—
., —

=

O-

-O
0)
O
to
to
•r-
Q

c:


"^

-o
a>
| 	
o
10
to
•r-
(^ ^





C
o
•r—
4_>
03

"o
O
S-
O)
o_








q-
o
c

D;















X — *
ro
\
a>

* — ^





re
j^
s — ^
ai
\x
" —
M-
O

-^
Q£

^ 	
fO
c*
-^
a>

—
ii_
^f—
0

^
o:









.. — *
E
O
**«^












E
o














•
cu
St_
0-




•
to
.a
0


•a
a>
^.
D_



.
to
jQ
O

,
~o
a>

a_




.
to
JQ
O



.
•a
CL)
s-
o_





.
to
JD
O



•
-a
cu

a.



.
to
o
O




-a
f—
cu
•i —
Lu
•—
<^
LO
, —




CM
•
CO

p— ~

to
CM
•
O



CO

.
o


CM
.
r--





o
.
00





CTi
.
«^J-
IO




CTl
.
to
to
f-^




to
,
LO
CO



^J.
•
LO
CM







LO

PX^




o

LO

1 	




r — ,
,
•=3-
CM



CO

LO








cn

CM
to
o





to
•
CTl



CM
O
•
0



c^
, —
.
1


0

, —





to

CM





CO

CTi
CO




o

CO
LO





to

o




LO

CO
CM






o
CM
•zf.
r-
00
CTi





CM
•
i—
, —
f—

co
0
•
o



LO
cn
.
o


00
*
0





, —
•
LO





CO

CTi
CO




o

LO
00





to
.
CD




CO

00







, — .
CM
=3;
cn
r-1
«^-
r—




«^j-
•
f—
CTi



^~
•
o



1^^
cn
.
0


CM

CO





co
.
r\





CM

f^
cn




CM

cn
cn





CO
,
CO
CM



CM

cn






c
(O
CD
s:
215

-------
percolation is not as serious  as  it  may appear.   Measured N losses  are  based
on tile drainage at  100-cm  depths, while  predicted values are for percolation
from the top 30 cm of soil.  Additional  N losses due to plant uptake  and
denitrification are  likely  in  the  downward  movement of N to the 100 cm
depth.  Also, this movement  is  not  instantaneous,  and substantial amounts  of
inorganic N will have remained  in  the  soil  profile between 30 and 100 cm.

Validation Summary

     The credibility of a mathematical  simulation  model  is largely  subjec-
tive.  No model is a complete  picture  of  reality.   Rather, models are sets  of
hypotheses concerning the fundamental  aspects  of physical and biochemical
phenomena.  Given the unavoidable  errors  in data collection and analysis  as
well as the judgement required  in  estimating model parameters, models cannot
be proven to be correct.  Comparison of model  predictions with field  measure-
ment can however, provide some  indication of consistency and
accuracy.  Based on  these validation studies,  the CMS model appears to  be a
reasonable means of  estimating nutrient losses from croplands.  It  accounts
for differences in crop,  soil  and  weather characteristics and reflects  the
impacts of management practices such as runoff and erosion control  and
fertilizer applications.  However,  the model is not a satisfactory  means  for
estimating the effects  of manure  management.  Neither is it useful  in
comparing dissolved  P losses from  fields  with  substantially different plant
covers.
                                     216

-------
                                  APPENDIX II

              GENERATION  OF  DAILY PRECIPITATION AND TEMPERATURE
                               FOR THE  CNS MODEL
     The daily precipitation  and  temperature models are independent  lag  one
Markov processes, fitted  to the meterologic characteristics of the area  being
modelled.  The precipitation  model  utilizes a binary distribution to  deter-
mine whether precipitation  is  greater  than a threshold value (.025 cm).   The
binary distribution  is  fitted  to  the  average number of days in each  month
with rain, and is affected  by  whether  the  previous day was dry or wet.   The
conditional probability of  rain on  day t was computed from the unconditional
probability by use of a regression  equation presented by Hershfield  (1970).
The amount of precipitation on a  day  is predicted using an exponential
distribution, fitted to best  approximate the mean monthly precipitation.  The
model  was found to slightly underpredict the number of large storms  as
compared to historic data.

     The temperatures model includes  the effects of seasonal and local
variations in average air temperature.   Temperature on day t is  a function of
the expected mean temperature  on  day  t, the temperature on the preceding  day,
and a random noise term.  From inspection  of historic records, it was found
that the correlation of the previous  day's temperature with the  current  day
is roughly constant  over  time  and location, and that the variation in the
random noise term may be  approximated  by a function of mean temperature.

Precipitation Model

     Define a wet day as  Pr£_ .025  cm
           (if Prt < .025 cm,  the Prt  = 0)

     then Pn (W)  =  unconditional probability of rain on any day in  month n  =
                     (#  days with  Prt>  .025 cm)/(# days in month)
          Pn (D)  =  unconditional probability of no rain on any  day  in month
                     n = 1 - Pn (W)
          Pn (D/D)   = conditional probability of a dry day following  a dry
                      day in  month  n  = .1718 + .8462 Pn (D)(Hershfield,  1970)
     then Pn (W/D) = 1  -  Pn (D/D)
     and  Pn (D/W) = Pn(D)  •  Pn(W/D)/Pn(W)
                   (this  is due to  the equal number of W-D and D-W sequences
                   in any long record)
          Pn (W/W) = 1  -  Pn(D/W)


                                     217

-------
     Finally, define  6n  =  average  daily precipitation on days with rain  in
                           month  n  (cm)
                         =  (av. monthly  precip.)/(# days with rain)

     To generate a value for Pr^ on  any day,  choose two independent uniform
0-1 variates X^- and Y^;  then

         if  [*t < Pn(W/D)  and Prt_i  <  .025  cm]

         or  [Xt < Pn(W/W)  and Prt_l  >_  .025  cm]

         then Prt =  .025 - 6n£n  (Yt)
         else Prt =  0

Temperature model

     define:  T^ = average air temperature  on day t (°C)
              y-t = expected value  of T^ on  day  t  (°C)
              Ct = correlation of  temperature on  day t-1 with temperature on
               2   day t (dmless)
              a  = variance of temperature  expected on day t (°C)
              V  = random  normal variable  of  mean 0 and variance 1; may  be
               t
                   generated from  uniform  0-1 variates by
              Vt - (-2 £n  Xt) 1/2  cos(2Tr Yt)

     then

              Tt = H +  Ct (Tt-l -ut-l) +  Vt  (1 - St2)1/2

By inspection of historic  records,

     a) Mt varies sinusoidally over  the year, and may be described by

        nt = T + TD  sin  (.01745  (Jt  -  105))

     where   T = average yearly  temperature (°C)
             TD = (average July  temperature)  -  T   (°C)
             Jt = Julian date of day t

     b) ?t ranges from  .60 to  .70  for  most  seasons and locations,  and  is
           therefore  fixed at  .65

     c) a-j- varies consistently with  y^, such  that

                                     218

-------
          ot2 = 33.412 -  1.169  yt

           from analysis  of  twenty-five  year records at Ames, Iowa, Aurora,
           N.Y., and Athens,  Ga.

     The data necessary to  implement  the meteorologic model is then average
precipitation and number  of  days with precipitation by month, and  average
summer and annual  air temperatures,  as  given in Section 2.
                                    219

-------
                                  APPENDIX  III

                 RUNOFF, PERCOLATION,  AND  DISSOLVED NUTRIENT
                        PREDICTIVE  EQUATION  COEFFIENTS
     The tables in this  appendix  are  arranged  first by crop, secondly by
timing of tillage, and lastly  by  soil  hydrologic  group.   Within each of these
categories, predictive equation coefficients  are  first presented for runoff
and percolation (a, b, a1,  and b1)  for each  geographic region modelled,
followed by coefficients  for the  nutrient  concentration equations  (a-j, b-j,
and c-j) for spring or fall  fertilizer  applications.  The following  index  may
aid in the quick  location  of a specific table:
                                      220

-------



4-
o
QJ

o
ro
r—


































































to
+->
C
O)
•i —
O
q_
4-
O>
0
O














4-
O

CD
i — •
-0
ro
r—











































~^j
Ol
r—
O
to
•r-
~o

S-
o
4-

4-
O
CD
E
• i — •
£
•r^
i—

to
4_>
E
OJ
•T—
O
•r^
4-
4-
0)
0
u












































E
OJ

l_>
~^
E



i-
0)
N
|^
.71
40
S-
O)
4-
"O
E
ro

4-
4-
0
E
"^
s-

s-
0

o
s_
"a
>^
-c:

^~
•r~
o
CO

^
•4-^




T3
CU
^~
r^
a>
-o
o
E








CL
O
&-
'-J





OJ
1







CD
E
S_
Q.
CO









r—
1
CJ






Q
•>
CJ
f
CQ
n
e3^

OJ
CD
ro
n—
i —
•r—
+J

O
E


r — .
C\J

p—
ro









E
S-
0
CJ





i — oj -=t LO r^ co
i i i i i i i i i i i







CD CD CD CD CD
E E E E E
r- S-r— S-r— i-i— i. r— i. r—
rOQ-rOCLrOQ-rOQ-rOCLro
4— to 4 — to 4^ to 4— to 4— co 4—








O OO CD
^t" f — • i — ' r-~ n—
1 1 1 1 1
CJ CJ CJ CJ CJ








CQ

« CJ CJ <;
CJ ** **
CQ CQ
f\ n
< <
aj ai
CD CD 2
ro ro O

^ i— "CL
•r— "r-
4-3 4-3 r^
^~
O O ro
E E 4-
oj r~-
1 OJ
OJ 1
OJ LO
OJ »OJ
i— CTi "
co i oj
1 CO 1
1 — 1 — 1 —



to
E
ro
O)

^} ^1
ro O
-E tO





OJOOLOCDCOCTli— OJ^LOr^
1 1 1 1 1 1 1 1 1 1 1
CJCJCJCJCJCJCJCJCJCJO






CD CD CD CD CD CD
E E E E E E
i-r-i-r— i-r-i-r-i-r— i,
CLro CLro CLro CLro Q_rO CL
to4- tO4- to4- to4- co4- to








i — ^J~ r^v o oo CD
OO OO OO "3- «d- •*
1 1 1 1 1 1
CJ O CJ CJ CJ CJ







r~\
CQ Q "
CQ O Q " •> O

<
O CD
•— CD
CL ro

CD ^
E -i-
•i- 4->
S-
CL O
to E

ft
OO
i —
1
CD
ft
OJ

i —


.C
4-3
• i —
2

E

0
O





CO
I
CJ








, 	
(O
4-





































r.
OJ
OJ

o
OJ
i

• —
s_
0)
0
CJ

S-

-------
oo
O
CO
CO
CD
o:
o
o
03
X
o
rt rt rt o
in o mo
o
rj
o n N ci
o> TH »,n
CK N 03 n
>o in *r «r
N',n «r o
V ft OO-
n n mr<
I I I I
in N -o -o
0* N N *0
-0-0-0-0
1 1 1 1
n N -ooo
in v on
n n nn
in o in o
0- O 0303
O 0- M-O
-o «r ^ ro
rv n oo-
o- oo rs IIT
IM n n n
i i i i
o- -o n-o
O 0- 03 111
-o in iii iii
i i i i
-< w o
ro ro to ro
mono
03
03 03 "O to
03 0- to O
CO 0- T O
-o iii n n
o- TH o- rs
03 0- CO 03
(III
iii co TH ro
iiii
TH -c O O
0- 0- O O
mono
rs
n
o- o- r* n
o- 
-------
O
oo


O
  «\

C_5
  n

CO
Q-
CO
a;
o
CJ)
CM
 i
CQ
<
in
u. t
o
z
ce
n
Q n
SSOLUE
1 (
-H CJ
a
o
CJ
OH
2
o
h- fl-
 ro o TH in t>>
rs TH ro ro

TH TH CM ro
iiii
TH CJ CO O
0- O O TH
1 1 1
in CD TH «r
O O TH TH
o o o o
cj fl- rs co
o o o o
ro cj in ro
TH cj ro in
o o o o
•o o in TH
ro in co N
0 0 O TH
o in o- ro
o o o o
IIII
ro ro cj -o
TH fl- CO TH
O O O T-»
IIII
in o in o
o o o o
o o o o
o o o o
ro fl- fl- fl-
o o o o
o o o o
in >0 SD -0
CO CJ TH N
CJ CJ CJ -1
o o o o
is o ** ro
o o o o
IIII
o ro rs iii
IIII
o o o o
is ci fl- -o
o TH cj ro
cj rj cj ci
TH co in TH
ro ro fl- in

iiii
co ro TH o>
fl- in -o -o
0 O O O
0 O O O
TH cj ro fl-
o o o o
fl- fl- fl- ro
o o o o
o o o o
CJ O TH IS
0 0 0 O
1
0 TH TH CJ
o o o o
IIII
~o cj o in
o o o o
o o o o
1 1
in o in o
TH TH CJ
ro
oo o o
o o o o
oo o o
THTH 0 0
o o o o
o o o o
1 t 1
>o o* in TH
co rs rs rs
o o o o
-oo o o
oo o o
IIII
rs o co co
iiii
in N o* ro
oo o TH
cj ci ro o
O ^ N CO
o TH o* ro
CO O TH CJ

iiii
rs cj cj cj
IS C*. TH CJ
i i
ro >o o* ci
O O O TH
o o o o
ocj ro in
oo o o
cj cj cj n
0000
rs TH o co
>o rs >o in
-o fl- n in
o TH cj ro
oo o o
iiii
OO CO O
•»•» ro fl-
00 0 O
fill
mo in o
TH TH CJ
O 0 O O
o o o o
o o o o
ro ro fl- ^
o o o o
o o o o
in *o -o *o
co o rs
CJ -0 CJ O
TH o O 0-
•o rs CD rs
TH O O Ci
o o o o
1 1 1
co in ui ro
i i i i
rs fl- o ci TH
0000
fl- fl- -O CO
o o o o
o o o o
1 1 1
ci iii ro ci
co rs rs rs
iiii
o TH TH ro
TH o* cj ro
111 CD O *0
111 fl- 0- Ci
TH -o o ro
fl- co in ro
iiii
TH -o n rs
o ro rs CN
iiii
fl- CO Ci 0*
O O TH TH
o o o o
TH CJ fl- -0
o o o o
o ^ rs ro
fl fl- yj co
o o o o
o -o c- in
CJ -0 -H CO
TH TH rj cj
•o in a> ~o
0 TH CI T
o o o o
iiii
in ro co ex
in -o co -i
O O O TH
iiii
in o in o
TH TH CI
rs
o o o o
o o o o
O 0 0 O
o o o o
o o o o
iiii
CJ ro n ro
fl- -H O CO
o o o o
TH TH o- ro
CJ CI TH CJ
o o o o
IIII
fl- in is co
o o o o
fl 0- 111 0
TH ro fl lil
ro ro ro m
fl- fO O fl
TH ci ro ro
o in o fl-
iiii
tn ci co CJ
*o rs fs en
ro fl- -o co
o o o o
o o o o
o -H n n
o o o o
co cj in co
-H CJ Cl CI
0000
fl ro 
-------
O
o
oo
 i
Ill

U- o
o o o o
1 1 1 1
m o in o
o
o oo o
o o o o
o o o o
0000
1 1 I 1
rt CMtO tO
OK O- 0- O
0- 0- 0- O
0 00 rt
-^ oo in OK
T ro to ro
o o o o
0- MO- 03
CO DO- tO
IX N O N
lilt
rx *H in CM
O rf n n
 O- 0-
o o oo
o o oo
in -o too-
n
D CM « 10
o o oo
1 1 1 1
in o in o
CM
o o o o
o o o o
o o o o
o o o o
1 1 1 1
0- O- O rf
O O -I rt
rH ri CM rt
CD 03 03 CO
o o o o
o -o rx o
o o o o
1 1 1 1
in o in o
rx
o o o o
O O 0 O
o o o o
o o o o
1 1 1 1
CD in ro *H
-0 -0 -O -0
o o o o
CM n CM o-
to to ro ro
0 O O O
ri -i rx co
fs -0 
-------
o
o
CM

 I
GO

<
in

IL «r
o
2
^3
it.
W
M
fl-
ea (N
SSOLVI
1 (
Q
O


OS
z
o
:RCOLA
B
OL A
»
Q
Ul
:>
_)
co ra
CO
»-4
a
a>
Hi
u. «r
o
D
&
2 «
M
Z
QPJ
[SSOLVE
U C
o
o
REGION
AU A
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
O O rf rH
CM o o rs
rv IS rs -0
o o o o
ts PJ n n
rr in in in
o o o o
»• in oo in
PJ co o- o
If) If) If) -0
i i i i
•r in >o rs
o o o o
•H «t -o ct-
a* ~< n ^>
PI n n n
*o n m CM
rs CD co o-
o- n in N
O iH i-t T-<
1 1 1 1
o- <• •* ~o
* If) -0 -0
1 1 1 1
n t -o fs
o o o o
o o o o
CO * O N
o n n M
o o o o
*-< n n Cii
0 O O O
O M n 0-
n PJ PJ ^
o o o o
If) &• TO N
O O rt r<
o o o o
1 1 1 1
O N * t
PI PJ to «r
oo o o
1 1 1 1
If) O If) O
«H rt (M
0-
o oo o
o oo o
o oo o
o oo o
o o o o
1 1 1
O r-t «-< M
CD -CT PI
~0 -0-0 -0
0000
PJ -M CK 0*
o oo o
O 0- tt- -0
-1 0-fs CO
-1 O O O
1 1 1 1
m -003 0-
o o o o
PI -o o r if) IIT
1 1 1 1
n if)N o-
o oo o
o o o o
CO W O CD
o .-IIN n
o oo o
O OO 0
CO Mlf) 03
n »p> n
o oo o
«r con o-
O O-i -1
o oo o
1 1 1 1
(M ncM m
0 00 0
1 1 1 1
mono
-I-H (••<
o
w
-4 rt O O
o o o o
o o o o
o o o o
o o o o
III)
o> o* o *-<
o> o* rs -o
•0 -0 O •<)
0000
01 co •cm
o o o o
M n iii r-i
&• O' rs -o
0- 0- 0- 0-
IT) N 0- ^
o o o -<
-H -o »H in
0 rt ^ rf
M n M ro
UT 03 O -H
-o -o r^ rs
oo n N -H
o »H -< rj
I i i i
P-J T If) ~0
M M M M
lilt
tn in N o*
O O 0 O
o o o o
N r-i oo «
o ^H »-• n
o o o o
o o o o
^ 03 O 111
n n n M
o o o o
» N rt -O
O O *H ^
O O O O
1 1 1 1
M «T If) Pv
O O O O
1 1 1 1
mono
-< -< n
*H
CN
OO O O
oo o o
oo o o
oo o o
oo o o
nn n o
» in in n
vH v-4 iH ^4
rs o to rs
>o N rs rs
rs o rn n
o <-i -i r<
i i i i
n -o -i -o
to to «r «•
i i i i
n ro O 03 O fO
in in -o -o
i i i i
to T 111 <
o o o o
0 t K O
*Q 03 03 0s
pin n PI
con rs o
rs 03 co o*
co -> «r s
O *H »•< »~l
i i i i
•fl PJ 111 N
T iii iii in
i i i i
to t 111 ^0
O O O 0
o o o o
03 PI 03 r iii iii
0 O O O
o
o oo o
M >0 03 •*
P-I to to >t
o o o o
T r-. -H n
0 0 ~ ~i
o o o o
1 1 1 1
in to ts PI
PI n to •»•
o o o o
1 1 1 1
mono
rfrf PJ
•0
PJ
o o o o
o o o o
o o o o
0000
o o o o
1 1 1 1
0- O -< PJ
O •-* r4 -*
fs N IS ts
o o o o
PI O -0 03
PI PI 1H TH
0 O O O
o ct> PI «r
N >0 to O
m n iii in
1 1 1 1
is M -o n
O -H r< PI
to to o PI

-------
oo
O
to
CO
Qi

O
O
CO
in
u. «r
0
Z
U
<£
ro
CL
Q CM
[SSOLYE
:i c
Q"
o

OQ
z
o
1-1
i «
_i
o
u
CL
u. ifi
Z
TH
z r-i
n
Q
Ul
r>
_j
en at
en
W
Q
at
in

LI. i
o
z
D
CC
ro
t-n
z
a ri
ISSOLV
U
Q
O
REGION
AU f
O O O O
o o o o
o o o o
o o o o
o o o o
o o o o
~o rs rs rs
o o o o
o o o o
ro n o o
o o o o
o o o o
1 1 1
THO. o in
is -o cs o-
i i i i
•o (s in o-
o o TH CM
TH co in rs
TH
in ro TH m
N CK TH tM
1H TH
O-O CK IN
•T o oo in
ro 
N in n is
ro •*• m m
-0 rt 00 -0
o TH TH rj
o o o o
i i i i
I- 00 N -0
o orj T
o o o o
1 1 1 1
iii o in o
TH TH n
o
O O O -H
o o o o
o o o o
N o TH n
n n n n
o o o o
1 1 1 1
o oo rs in
»• •« -o in
i i i i
n M «r *r
o o o o
T in •<> IN
TH TH TH TH
o- to n n
n •»• «r o -o >o
M3 -o rs rs
o o o o
o o o o
>o cs r-i n
ro ro «r «r
o o o o
i i i i
in o- v ro
TH co rs r>
o \ii in
o o o o
0 O O 0
•o n TH ».
-i m o -H
ri iii co rj
O 0 O -H
o o o o
1 1 1 1
•H n rs r-i
O O O -H
o o o o
1
in o in o
TH TH CJ
in
o o o o
o o o o
o o o o
o o o o
o o o o
o o o o
iii -o -o rs
o o o o
o o o o
1 1 1 1
-o rs co rs
TH o o n
o o o o
1 1 1
rs *r  ro o
-o rs 03 o-
o o o o
o o o o
«r 
TH TJ- CK O
1 1 1 TH
o in f «»
TH n T -o
TH r-i n in
i i i i
03 O O f 1
o TH ro to
o o o o
O O 0 -H
ro rs TH ro
ro ro 
-------
O
o
oo
in
u. *
0
z
3
CC
ro
M
0.
O CM
SSOLVE
1 C
a
o


0Q
Z
O
tH
»- ^
:RCOLA
S B
GL 01
Z
tt
Ul
>
_J
U}0)
U)
a
a
in
u. t
0
z
3
cc
M
Z -I
M
z
a r-t
SSOLVf
«1 /
Q
0
REGION
AU t
O O O O
o o o o
o o o o
M M PI  nos
o
o o oo
PI ro *o os
o o o o
o o oo
1 1 1 1
*• -o -o«r
*^ *4 vH ^4
O O OO
1 1 1 1
in o mo
*H ^H r-i
n
r*
TH «H TH O
OO O O
oo o o
pi PI ci rg
o o o o
o o o o
1 1 1 1
OsOs 0 -i
O O «H T*
ri M 0 00
O O O O
o o o o
PS os o n
o o ~* ^
o o o o
o n in -o
0000
Ps O » N
03 O -I M
O -« rt rt
PI n -o o-
o o o o
0000
1 1 1 1
00 O OS -0
0 -00
o o o o
1 1 1 1
in o in o
rt rt ri
n
-. -. ^. o
o o o o
o o o o
n PI PI PI
o o o o
o o o o
i i i i
0- 0- O **
O O ••< -I
CM n «r n
in in iii in
o o o o
in in r*) PI
o o o o
rf rf n o
in in ro ri
ro n ro fo
i i i i
in PS oo o
o o o -H
•H «r -o o-
03 Os Os O
n n n n
Os * 00 O
Ps 03 03 Os
» PS -i in
O O -H ^
1 1 1 1
* PI o- in
-i rf O O
i i i i
M «r -o o-
o o o o
o o o o
PS ON n «r
O O -H -1
o o o o
o- pi ro fl-
o o o o
Ps V PI -0
N 0- O 0 TH
-0 -0 » fl
ri PI- n PI
^ n -«in
•o ~o -on
» Ps rt -0
O O rf *H
i i i i
r^ 03 ^ rt
^ O O O
1 1 1
n in -oos
o o oo
o o o o
PS o- rf 
o o o o
^ Os M M
in in x) -o
o o o o
PI V >0 O
O O O rf
o o oo
1 1 1 1
PS if) f -i n
o o oo
o o oo
1 1 1
in o no
r* ^ PI
in
r*
O O O O
o o o o
o o o o
o o o o
o o o o
0 0 0 O
1 1 1
* «r in n
n PS oo os
rt 1-1 ~1 TH
o o o o
n N PS y>
PI ri ri n
o o o o
1 1 1 1
IIT in o- o «r to n
o oo o
o oo o
1 1 1 1
in o in o
^ «M PI
Ps
*4
O O OO
o o oo
o o oo
n n PI ri
o o oo
o o o o
1 1 1 1
O -* -HCI
in rs co o-
«r o 03

i i i i
n to «r in
o o o o
O f 1 T -fl
03 OS OO
-< -^ PI PI
03 to ~00-
00 0- Os 0-
rj T in oo
o o o o
i i i i
Os 0- COO
o o oo
1 1 1 1
ri to * in
o o o o
o o o o
03 Os o ^
o o »»•*
o o oo
ro T in -c
o o oo
03 Ps V -0
». -i rom
O •* -4-1
^ n T >o
o o o o
o o oo
i t i t
CO Ps N -0
o o oo
o o oo
till
in o in o
-« -i M
03
                                 227

-------
O
o
ca
in

u. 
in nrs CD
00 0-0- 0-
T rs rt m
O OrH rt
1 1 1 1
n n *H o-
rt rtrf O
1 1 1 1
PI «r-o co
o oo o
o oo o
•0 COO- ^
o o o o
co •-» CM n
•< N ri CM
o oo o
O Tin N
•H HM «r
N «r fs o
O OO -i
o oo o
1 1 1 1
-o -on o
o oo o
o oo o
1 1 1 1
in oin o
o
CN
rf rt O O
O O O O
o o o o
o o o o
o o o o
1 1 1 1
0- Ct- O .H
00 03 O- 0-
o o o o
co oo o in
o o o o
N rj in rj
0- 0- N -0
0- 0- 0- O-
H
1 1 1 1
M -i oo »r
rf rt o O
1 1 1 1
n in -o o-
o o o o
o o o o
o o o o
oo o -< ri
rt n rj rj
o o o o
rf O- T 0
CO CO 0- O
O O O rf
N ^- N O
O 0 O -1
o o o o
fill
-o rx in CM
o o o o
o o o o
1 1 1 1
in o in o
*H
rj
oo o o
O 0 O O
o o o o
oo o o
OO 0 O
1 1 1 1
M PI ro «r
COO O -I
OO O 0
03 O -I -I
o o o o
1 1 1 1
030- rH o -o -o
o o o o
o o o o
CM is in o
CM ^T -0 03
-H «-t *H ft
•H n in N
o o o o
o o o o
1 1 1 1
* CM on
o o o o
o o o o
1 1
in o in o
5T
r-j
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
O- 0- 0- O
o o o o
^ ro to in

in -o -o -o
o o o o
*t o- n ri
in t in in
O O O 0
«• -«o in
o- 03 ro 0
(N
O O O O
O O O O
0 O O O
o o o o
O O 0 O
CK O TH H
O iH -< -^
0» CN OD 00
o o o o
f J O -O CD
rj rj tH ^
o o o o
o o- n  
-------
o


00
o
oo
o
o
o
	I
Q-
,
«T


3
 i
TH tn •<• rs
s> » M TH
S3 S3 S3 S)
ro ro o oo
in o in o
-1 TH N
0-
IH
o o ro in
o s) rs ro
* o- o ro
in ro ro CM
00 H o OK
.H TH TH o
i i i i
CM O O 00
rs rs si in
o o o o
in TH o oo
^- v ro CM
n o in o
TH rH CM
0
*H
S3 -H in S3
00 TH » 00
rs si fs o>
ro TH ro oo
-o n «• ro
o o o o
1 1 1 1
CM * S3 o
O O O O
OK CM rs TH
-o -o n in
o o o o
in o in o
•4
M 00 0- »
S3 O CM *
TH to rs CM
s) in «  n * I-
in N S3 CM
ro M cv CM
i i i i
S3 tH iH -0
03 S3 «r CM
rs rs rs rs
rs TH o co
ro ^ «r ro
mono
TH iH CM
TH
CM
o- rs rs «r
* -o o n
-o m tn ^
rs oo «r oo
S3 S3 S3 n
i i i i
CM 0- CM 03
S3 IO CM 0-
CM CM CM TH
O -0 0- 0-
rs rs rs is
in o m o
"1 r* CM
CM
iH
CM •* o n
ro oo -o o-
M rs «• -j
o- TO 
in *• -o rs
i i t I
CM S3 00 TH
TH O 0- 0-
n o n o
S3
n o- * o-
oo ro ro ro
S3 o-  m n 4r
*• O S3 S)
OK 0- 00 00
o o o o
till
CM o o in
03 rs S3 T
n ^ CM o
0-0-0-0-
o o o o
n o in o
TH TH CM
00
TH
O iH * O
S) O S3 CM
in o TH in
rs ro n o
tO O OK OK
IIII
TH n » S3
iiii
0- OK rO S3
«r ro ro CM
mono
0-
                                      229

-------
o
co

<



o
a:
a.
co
o
o
o
_i
o.
CQ
in
u. «•
0
z
D
cc
ro
M
0.
o CM
SSOLVE
1 (
a
o

a
z
o
M

in

L.  r<
M *0 -0 >0
0000
I i i i
»< -o n M
o ro co n
o o o •*
i i i
in o in o
•4 -1 (N
r4
o o o o
o o o o
o o o o
1 1 1 1
fx N N CO
o o o o
o o o o
rx r> N rv
rs in ^ CJ
o o o o
o o o o
co ••< ro »
o o o o
i i i i
ro n c* IIT
n ro ro <*•
o o o o
o o o o
in rv rv rv
o o o o
N O (N t
n ro ro n
-o in o- r<
rx o> o ri
*-l »^ Cl (N
ro «r in in
o o o o
1 1 1 1
r< in o- -<
rs co o- r-t
i i i -<
i
tO » 111 -0
O O O O
o o o o
^ n M to
o o o o
•< n » in
o o o o
o o o o
N CO (N CO
» ri ri ^
o o o o
0* to fs O
o o o o
1 1 1 1
o o rv n
•H ^1 O O
o o c o
mono
rt -H CM
ro
o o o o
o o o o
o o o o
1 1 1 1
rx N is co
o o o o
o o o o
rx PN N fs
0- -O « O
n n n n
o o o o
n r- o- —
o o o o
i i i i
o o- *-t rj
~o to « rj
0000
1 1 1 1
rj rJ ro *
o o o o
CO ^ » 03
O ^ -H -1
O O 0* CO
UT ^O -O N
CO * O ^
n rv N -o
rj n to ro
in co o n
0 0 - -<
i i i i
111 CO O CO
o to rv o
^ v^ *H rj
i i i i
in -o N co
o o o o
0 O O O
-1 (M M T
o o o o
CN o *-» in
*H rJ ro ^r
o o o o
CM in fs «•
o o- o *
r< O --1
IO CO CM -0
O O O O
1 1 1 1
co » in o
o o ti -o
0000
i i i
in o mo
»« ^ CM
V
O O O O
O 0 0 O
o o o o
1 1 1 1
rs rv co co
o o o o
o o o o
rs rs rx N
ro ** e>* o-
,« rt o O
o o o o
o n o rs
o o o o
iH *H iH 1-4
1 1 1 1
rs rs rs r j
N -0 111 >0
o o o o
III)
-i CM rj to
o o o o
-0 CO O -i
O O -1 TH
^ rs ro co
^ o
1 *-4 *-t ^
i i i
m -o is o>
o o o o
o o o o
r-i f j ro «•
O 0 O 0
CM -0 O -0
O O »-» •-!
o o o o
v rt in ro
ro M -i M
o o o o
ro co ro co
o o o o
i i i i
O CO -i <•
tl ** n O
o o o o
1
in o in o
»H *•! W
n
o o o o
0 O 0 O
o o o o
till
«• iii in -o
0 O O O
o o o o
fs fs 05 CO
>o co iii ro
•c in iii in
o o o o
o- ri t rs
ro o o o
o ** ** *~*
i i i i
-i  r j tii
CO -< -< CO
f ro CM n
r) ro «r in
rs n co -o
O -i •-< CM
i i t i
<• 111 PO CO
rJ co in to
*-< ^ rj to
i i i i
ro ro CM rf
o o o o
o o o o
O O O -I
o o o o
t
ro n -o ui
O O -< 10
o o o o
1 1 1
111 0 bl O
^ r-t rg
03
0000
o o o o
o o o o
rj rj ri ri
o o o o
o o o o
Ll 111 >0 S3
n -o co *H
0- O O O
o c o -<
i-« r-i t rs
rj «r I,T I/T
O O r^ o
N -0 n ri
Ch C> T -•<
-i ro in «
Cl ri r i f i
I'll
-o -• o n
o <•« r j to
N co ro rs
•1 n in on
T ri rs 03
t "• rs t-i
-H ri n n
ro r-~ ^ n
co m t bi
to bi r- o-
iii -n o- o
rf n -3 03
i i i i
o t *o n
0- is T -i
ci «r >o co
i i i i
n ri ci to
o o o o
O O 0 O
cj «• n --o
O O O 0
•r oo o ci
CO to Cl CJ
0 r\ Cl to
bl 03 CO bl
•H tO Is t
-< " n bi
in 03 PS IH
o o o o
1 1 1 1
r o rs a-
S3 co r. ro
o ^ ro S3
i i t r
bl O bl 0
•-< ••< r-j
o-
                                           230

-------
	
CO
REGION DISSOLVED N IN RUNOFF DISSOLVED N IN PERCOLATION DISSOLVED P IN RUNOFF
AW AO Al A3 A3 A4 A5 BO Bl B2 B3 B4 B5 CO Cl C2 C3 C4 C5
o o o o
o o o o
o o o o
CM n ri n
o o o o
o o o o
•r m in -o
in so rx o-
o o o o
T ri o 
O- 0- 0- rt
rx o- rt 
o o o o
in o- T m
O O 0 O
ro o
i
o
0
c
«r
o-
-0
000
o o o
o o o
1 1 1
O O 0
o o o

o o o
co o- ri
o o o
1 1 1
rx o- »
ro ro ro
l l i
0 O O
o o o
«r in in
0- ri f
ro ro ro ro
o
t
in
CO
i
o tn
ro ro
0 C
1 1
ro o-
i i
 moo
a- o rv r>
ttii
O O 0 0
-* ri c; r j
0 O 0 C
T ro "•< iji
ro ro i 
-------
o
o
ca
in

ii. <*•
0
z
a.
fO
0.
o CM
SSOLVE
1 C
M O
Ci
o

in
a
z
o
IRCOLAl
5 B'
(L a
z
M
z ri
a
tu
_j
O T-)
Ul «
01
o
01
in

o
z
u:
n
z
a (N
Ul  cj cj cj
o o o o
n rs n •si
o 0"
0 0 0 O
iiii
s] T-. ro -o
o o .H cj
0 0 O 0
t I 1
in o in o
0-
0 O O O
o o o o
o o o o
1 i ! 1
o o o o
0 O 0 0
O- 0 CO Ps
ro ro ro ro
o o o o
o o o o
IIII
"0 rs rs in
Ell)
o o o o
cj ro ro ro
O 0 O O
•o ro o ~*Q
 ^o -^ iii

o o o o
1 ! 1 1
111 ^0 CO 0*
IIII
ro ^r ui in
o o o o
o o o o
^ cj co ro
O »H T-> CJ
o o o o
o in ^ rs
cj cj ro ro
o o o o
CD CJ CN CJ
O O O O
0 0 C 0
IIII
ui c«j in in
0 O O »f
o o o o
i i
in o in o
z
0
o
o
1
o
o
in
R
o
o
1
in
o
0
o
 0 0
-r _< r J
III O SO
1 1
U) -> ro
0 T IT
i ' i
C C *-"
o ro in
-O -0 -0
o -« Is-
o n IN
T ~* T
I j »-.
»H r j ro
O O O
o o o
a- t co
i-« rj fi
000
^O r . ft)
0 O 0
fO T Ul
COO
ooo
r>oO
1 1 1
C Ul O

                                   232

-------
o
00
cf

M
o
o
o
_j
o.
CQ
Ill

LL «T
O
Z
D
ct
ro
M
LL.
O CN
kJ U
>
_l
O
en
en rn
o
o

0)
z
o
:RCOLAI
S B*
z

u
CO CD
en
tH
Q
CQ
in

o
z
cc
ro
z
QM
SSOLVE
1 t
a
o
REGION
AU (
o o o o
o o o o
o o o o
I i 1 i
o o o o
o o o o
1 1 1
rs rx oo oo
Iii iii n iii
o o o o
o o o o
CO O O CX
ro «r >r ro
o o o o
1 1 1 1
cx fl- o in
•H CM CM -"
o o o o
rH IN N «T
O O O O
•o co rj ex
O O rH TH
O 03 CN in
CX rH 111 O
rH rH n
in CO rH O
cx o -o ex
rH r J *f -O
o o o o
1 1 1 1
rx IN co ix
rx roo o>
1 TH (N (N
1 1 1
•O 0- O TH
O O rH rH
O O O O
rH CX IX 00
IN IN ro ro
o o o o
1 1 1 1
oo r
O rH rH rH
O O O O
1 1 1 1
CN CN 10 *T
o o o o
0 O O 0
•o ri cx  111
rH r-i r» ri
o o o o
1 1 1 1
ri ro ix ro
rH rH n rO
O O O 0
ro in rx rn
rr ro
rH O O O
1
to in ix n
O O O rH
n CX O rH
rH rH rO 111
«r ix ri ro
O- rO O 111
rH rH ri
(N -0 -0 tO
o ro ri ro
to ro n o
o o -i ro
till
ix ro o ro
cx o- f ro
1 rH rO 111
i i i
ro ro ro o
o o o o
o o o o
ro 
rH rH ri rO
•o o- m «r
•0 CO rH o
in rj LI rx
T 111 111 111
O O O O
-H ro o 03 ^ ex
TH ri iii ro
in ro -o ro
n o- -o n
TH TH ri ro
in cx rx co
CO rH |X V
03 CX rH O
O -H t IX
1 1 1 1
rH O lil IX
«• TH o ro
TH ro in -o
i i i i
rn TH ri ro
o o o o
o c o o
rs ro in rx
ro 
in -o co o
O O rH -H
0 O O 0
i i i <
lil in ri ro
«r o in f>
o -< ri «
i i i i
111 O 111 O
cx
                                          233

-------
in

L. -<
a

z
o
M
RCOLAl
B'
0_  »
03
a

I

0
z
ro
IH
z
QCM
:>
_J
O
03
03 -<
a
0
REGION
AU (
0.0 o o
0 O O O
o o o o
o o o o
o o o o
IIII
t in in -o
in in in in
o o o o
n ro * *r
o o o o
rx o ro CM
m o- in-o-
O O -1 *H
M n PI CM
iiii
ro so oo ro
O O O -1
o- ro o- n
o TH ^ ro
in ro N o
o* ro N ro
-i rt CM
in CM in «r
•o ro o- o
ro rx * in
o o •-< CM
iiii
03 CM 00 •»
rs «r ro -o
i i* CM ro
i i i
o o o o
0000
in CM o -a
CM ro ro CM
o o o o
IIII
03 --I * *«
>o o roco
0 -< rH -H
O M 0- 00
o -nn -i
ro n in -o
V S3 0* V
o o o -<
0000
IIII
rx ro rx o-
n in o- fx
000*4
iiii
in o in o
o
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 H
r
o o o o
10 -0 N 03
OO O O
-o co o ro
*-» 03 03 C>
rx o ro -o
»j CM ro in
o o o o
iiii
rx -I CM in
1 1 -H rt
i i
o o o o
o o o o
in rx rf T
•H *-t CM CM
o o o o
IIII
o- CM o in
V S3 00 O
O 0 O -1
O CM -0 CM
in o -o ro
CM ro ro t
^ S) GO O
0 0 0 ->
0000
IIII
oo vi 03 ro
o ~> PI in
0000
IIII
in o in o
•1 rt CM
o o o o
o o o o
o o o o
iiii
o o o o
o o o o
IIII
^  rx
o o o o
o o o o
IIII
-i » OD «r
o o o -i
o o o o
IIII
in o in o
M
iH
O O O O
0 O O O
o o o o
1
o o o o
o o o o
IIII
ri n ro ro
•o *o rs rs
o o o o
CM CM n ri
o o o o
IIII
in o o* N
rx 03 rs is
00 03 00 00
iiii
o o o o
CM ro ro ro
o o o c
•t   a> >o
Ch --< ro in
n «• ui -o
o o o o
o o o o
IIII
^ o -H ro
o o o o
o o o o
1 1
m o in o
TH T-< n
in
O 0 0 0
o o o o
o o o o
IIII
o o o o
o o o o
in -o ^o -o
n n to ro
o o o o
!C K £ aJ
O O 0 O
IIII
o~ rs &. T
rJ »H ,H rj
ro ro ro ro
i i t i
o o o o
*t t in -o
o o o o
rj rx rj >o
ro ro  0 o
o o o o
0 0 O O
O O O 0
IIII
o o o o
O 0 O O
till
in in *o  0 0 O
O ^ •-» iH
IIII
o^ o tn «-<
t-< 0- 0- O
«r ro M ^~
1111
o o o o
o o o o
rj rj ro ro
o^ ^r in ^o
 o *o
a- oo i> o
o o- a- o-
iiii
O O O -"
o o o o
rj TJ ro ro
o o o o
-o o* TJ in
n rJ m ro
o *-» o CD
n ro T 
-------
o
o
"JO
CO

<£.
in

u.  B
U)
M
a
a
in
u.  i i
in co « n
•H -H (N [M
O 0 O O
rs rs ro rs
r> ^ ro «r
-i IN tM (M
to in *o is
o o o o
o o o o
1 1 1 1
r-i rt n- rs
o o o o
o o o o
1 1 1
in o in o
— ** CM
0-
*H
O 0 O O
O 0 0 O
O O O 0
1 1 1 1
o o o o
o o o o
1 1 1 1
1*1 ro * «r
n n to ro
ro IO rO rO
O O O O
-0 T -0 IS
O O O O
1 1 1 1
-o rs rs in
ts rs X3 >0
i i i i
o o o o
ro n  o ~i n
O »-l »H yH
o o o o
i i i i
O- rO CO *T
•H rj N ro
o o o o
o- n <>• «r
rs o r
o o o o
o o o o
1 1 1 1
rn in (x in
n IN ri n
O O 0 O
^ o in r J
IPT rs co o
TH »H TH CJ
n in •« rs
o o o o
o o o o
1 1 1 1
 •« is
N n n CM
o o o o
M o
n ri rj n
iiii
O 0 O O
o o o o
CM n n ro
O O O 0
in •« rs co
»H i-l TH *-l
in -H in CD
^ (N eg n
O O O ft
o o o o
IIII
O M -0 O
rH rJ ,-( M
IIII
rf rj rj ro
o o o o
o o o o
O O M -1
o o o o
O O O 0
IIII
1-4 iH *H *H
O O o O
o o o o
o ro f -o
o
o o o o
IIII
«r rs o ro
rf •* ri (M
o o o o
co ri in co
o ro tn is
ri ra r-i n
ro 0 ill 0- »O
o o-  CO rs -O
r i ro T iii
iiii
o o — ri
o o o o
o c o o
i
-o c^ o rj
O 0 TH rf
o o o o
IIII
C- -i rj ri
^- >0 N 03
O O o O
N is ro C*
ro rs ,-• 
-------





	 1
o
oo
— 1
( — 1
o
CO
•ZL
o:
o
o
0
	 i
Q_
j
	 1
<
u_
1
H— 1
1 — 1
fl -o
ro o n -o
CM ro ro ro
in o in o
rH rH CM
•0
CM
co «r o o-
rH N fl *!• ^
ro n ro ro
mono
rH rH CM
rs
-o -o CM ro
rs 03 in m
n rs CM 03
00 0- -0 -0
n n n n
i i i i
ro CM rs rs
in CN o- -o
co co rs rs
CM CO O O
-o -o is rs
mono
rH rH CN
CO
rs rH CD CO
CO O T O
m n «r r
o co rs -fl
rH O O O
o- o- ro -o

-------
 o

 GO
 O
 oo
 Qi

 0-

 GO
 o
 o
 o
 	i
 CL.
CO
 I
CQ


_j
en n
01
M
Q
B)
in
u. «r
o
z
ro
n
z
a CM
SSOLVE
1 t
w «
a
o
z
0 3
O
U
a
o o o o
o o o o
o o o o
i i i i

rH TH 1-H CM
in *• in -i
IS rH O CM
4T SQ CD *H
rH
CM ro If) 00
o o o o
1 1 1 1
rs CM ^ SQ
in o so *o
rH CM CM ro
1 1 1 I
*• in so rs
o o o o
o o o o
•O -O -0 CM
rH CM n «r
o o o o
f O- V i
O O -IN
oo o N in
rs CM TH *•
CM T -OO-
0* O TH O
o o o o
lilt
«f CO CO ^
IO CM TH to
O rH CM rO
1 1 1 1
in o in o
T-t
0 O 0 0
o o o o
o o o o
1 1 1 1
in in n in
o o o o
o o o o
CO CO CO CO
ro CM TH- -i
o o o o
00 00 N N
CM CN CM CN
o o o o
1 1 1 1
in -a co in
o o o o
o o o o
CM ro o N
o o o o
1 1 1 1
fM * CM M
M -0 O »
rt rH CM CN
1 1 1 1
in >o rs co
o o o o
o o o o
« m «• ^
CM M «r in
o o o o
^ n •<> o~
o o o o
in -H •-< -<
o rs oo ^~
*4 *+ C4 *•
O CM CM n
o o o o
1 1 1 1
M rv ro CM
i-t >0 CM C0
O O rH -1
1 1 1 1
mono
CM
o o o o
o o o o
o o o o
1 1 1 1
in in m in
o o o o
o o o o
N IX N N
M CM rH O
O O O O
rt n T -0
o o o o
o in o- -o
in so rs N
in -o rs oo
oo n rs -o
v o in o
n n n 0 -o >0 sQ
o o o o
o o o o
N rs is rs
so in >r n
o o o o
co o- -i ro
IS N CO CD
0 O O O
till
OQ ro rs o
0- Os 00 Os
o o o o
1 1 1 1
CM CM ro «r
o o o o
03 -H IO »0
O -H *H rf
•c n !>• in
T in in ^
T o n r-i
o t rs o
n CM n ro
n co o CM
O O ^ *H
i i i i
N in CM 1-1
o ro ^ o-
i i i i
•t in so rs
o o o o
O O 0 0
CM CM iH Os
»-i CM ro ro
o o o o

O O O 0
o so ro rs
so in so co
o o o o
-! in o T
0 0 O O
1 1 1 1
in in 1-1 in
i« o ^< ro
o o o o
1 1
in o IIT o
in
o o o o
o o o o
o o o o
i i i i
>T in in in
0 O 0 O
o o o o
03 03 03 CO
111 -H 0- CO
in in f *•
o o o o
rs OD co oo
o o o o
1 1 1 1
in OD in T
o «r in so
o o o o
1
 in
o o ^ ro
i I I I
mono
rs.
0 0 O O
o o o o
o o o o
iiii
in so so so
o o o o
o c> o o
sO -0 sQ sO
n -< o o-
N u n ~4
O C) O O
rH n  rs
OD rs in EN
rs co o- o
rH rH rH OJ
IIII
rs ro so os
o r-t ri ro
o in o- in
CM ro so o
rH sQ in SO
in n Os «r
rH n rt ro
t in o- o
O CM (N 0*

-------
o
o
oo
CO
1 O OOO
in i o o oo
1 O OOO
i
u.  i o ooo
0 1
en i rf ino«r
at «-< i o o^^
a i o ooo
i i
1 00 111 WOO
O 1 CM -O O*
1 1 1 1 1
1
i in OOCMCN
a i o O-ICN
i
Z 1
O 1
M I o tvtvco
_i i
O 1
U 1
a. a i 
Z 1
M 1
A 1 -0 00 O-O
LU 1
^ 1
in 01 i o rtM»
U) 1 1 1 1 I
a i
i CM ino-o
m i o o CN'O
i i i i i
i
i
i
in i o o oo
1 O O OO
i
i
i n * to *
U. * 1 *-i CN tO *
0 1 0 000
Z 1
a: i N oo oin
i
Z 1
i n 
0- 0- 0- 0-
N M 0- -0
nrvo-cN
O O O i
1 1 1 1
1 1 1 1
oooo
oooo
T-I t-l CM M
OOOO
O O «H «H
^ •« -o 
o to to <»•
O 0 0 -H
1 1 1 1
in o in o
«H
OOOO
oooo
oooo
1 1 1 1
oooo
oooo
in in n -o
o o o- oo
mint v
oooo
n n -o tv
oooo
1 1 1 1
in to » to
0- O O O
i i i i
oooo
•O 00 O CM
in *  o
IO -0 00 0-
oooo
1 1 1 1
-0 00 O CM
1 1 -1 rt
1 1
oooo
oooo
r* rv to oo
O O *H -1
oooo
oooo
« n o- t
t n to in
-O 0- CM »
O O rt -H
OOOO
1 1 1 1
O O CM *
OOOO
1 1 1
in o in o
CM
oooo
oooo
oooo
oooo
oooo
O-O-O-O-
o o o o
CN ** *4 *-)
CN CM CM 04
oooo
1 1 1 1
o n n *
O-O-O-O-
1 1 1 1
•H CM CM CM
oooo
oooo
n m CM <-c
n...
M in rs o
«*«••*
oooo
1 1 1 1
1 1 1
oooo
oooo
oo n N CM
O rt rt CM
oooo
is n »r T
CM n * in
oooo
in in CN -o
n n v n
oooo
-0 00 O M
O O -I rt
oooo
1 1 1 1
O 0- F> -H
O O CM »
OOOO
1 1 1
in o in o
n
oooo
oooo
oooo
1
oooo
oooo
CN CN 01 *H
oooo
N -0 -0 -0
CN n CM CM
oooo
1 1 1 1
CM <• 71 -Q
O O O 0-
00 CO 03 N
1 1 1 1
oooo
oooo
r-, o- o- o-
n -o rs oo
o- o rs «r
CN -0 00 
-------
oo
 i
CQ
in

a. »
o
z
D
or
M
M
0.
a IN
SSOLVE
:i c
a
0

in
n
z
0
h-t
H
rs o CM in
i i i
CM M ^- in
o o o o
0000
in -H -o -i
O rH rt M
o o o o
O O 0 O
00 If) 03 M
in tn in is
o o o o
-0 0- (M »
O O T-( ~»
O O O O
1 1 1 1
» M rx N
O O *-l M
o o o o
1 1 1
mono
o
(N
O O O O
o o o o
0000
1 1 1
0000
o o o o
M * ^ in
00 00 CO rs
M M M M
o o o o
o o o o
M M M M
o o o o
1 1 1 1
N rx -o •«•
in in in in
i i i i
(N CM M M
O O O O
«t- in -o rs
o o o o
« 0- IS V
tn in •<) rs
f -o is rs
n M in is
M in -o rs
o o o o
1 1 1 1
in M OD -o
-0 00 0- •*
1
CM M <• in
o o o o
o o o o
in o in o
O •* ~* CM
O O O O
0 O O O
« -o rv o
in «• T in
o o o o
•0 03 rt M
O 0 1 TH
O O O O
1 1 1 1
n * in o-
O O -1 CM
o o o o
1 1 1
in o in o
CN
o o o o
o o o o
0 O O 0
1 1 1 1
o o o o
o o o o
in iii -o -o
M (N CM IH
M M M M
O O O O
N N rx oo
«!•«••»••«•
o o o o
1 1 1 1
M .H CN CM
in in in in
i i i i
O o o o
+ v nn
o o o o
o M in rx.
M M M M
Ox in -0 CD
M in -o ix.
CM M ^ in
o o o o
1 1 1 1
«r -o -orx
rx. 03 o- o
CM M M «T
o o o o
o o o o
0- * o in
O rf CM CM
O O O O
o o o o
oo rs 03 in
in m in -o
o o o o
rs o (M v
O rt -I rt
o o o o
1 1 1 1
-0 O M IS
O O rt N
O O O O
1 1
in o in o
CM
CM
O O O O
o o o o
oo o o
i i i i
o o o o
0 O 0 0
in in in in
oo rx. rs rs
*H *H 1-4 r-l
O O O O
CM t -o rs
in in in in
o o o o
1 1 1 1
*-< TH *H TH
M M M M
1 1 1 1
o o o o
M V * *•
O O O O
•0 00 O CM
CM CM M M
in co ox co
CM M T in
CM M M M
O<5 O O
1 1 1 1
rs -H ^ in
-0 00 0- O
1
CM CM M *•
O O O O
o o o o
in o- «• oo
o o -i -<
o o o o
O O 0 0
rs in CM ^>
CM CM CM CM
O O O O
in 03 -H M
O O -i ^
o o o o
1 1 1 1
rs -o CM M
o o o o
o o o o
1
in o in o
M
CM
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
•0 -O -0 -0
in » r
^ o -o -c
o o o o
-o o- n in
O O -H ^
o o o o
1 1 1 1
^ IS -o O-
o o rt n
o o o o
i i i i
in o in o
•0
CM
0 O O O
o o o o
o o o o
o o o o
o o o o
M «r «r tn
in 
-------
 O


 00
 o
 oo
o
C_5
o
_i
D.
CTl

 I
UJ
	i
CO
•=c
in

U. V
0
z
ct
M
o.
Q CM
D I
smoss
Q
o

CQ
O
:RCOLAI
I B^
CL m
z
a
a
en a
en
a
a
in
u. *
o
•z.
D
a.
n
z
Q CM
UI 1
>
_l
O
cn
U) TH
Q
0
REGION
AU t
O O O O
o o o o
o o o o
1 1 1 1
o o o o
o o o o
1 1 1 1
rs rs oo oo
in in in -o
o o o o
0000
CM CM CM CM
o o oo
1 1 1 1
in in oo n
O O O TH
o o o o
i i i i
CM CM n -0
o o o o
rs TH rs o
0 TH THCM
o ro rs oo
o ro rs «r
TH TH TH CM
CO 0- (N -0
CM -0 -0 -0
«r in rs o
TH
CN to in 0-
0 0 OO
1 1 1 1
o o CM ro
o- -o in -c
i TH CM ro
i i i
r
o o o o
o o o o
o CM ro T
o o o o
1 1 1 1
in NO oo o
O O O TH
o o o o
o ro *o °o
ro ro «r «r
ro ^° ~o rs
o o o o
o o o o
i 1 1 1
CM CM TH CM
O O O O
o o o o
1
in o in o
TH TH IN
ro
0 0 O 0
o o o o
0000
1 1 1 1
o o o o
0000
1 1 1 1
rs rs N rs
rs co co oo
o o o o
o o o o
TH CM «r in
•0 -0 -0 -0
o o o o
1 1 1 1
 to
TH n ro »o
i i i l
IN IN TH TH
o o o o
o o o o
1
TH o in is
in rs co es
o o o o
i i i i
rs o CM in
O -H -H tO
is TH 
TH rs o CN
O O IN «•
1 1 1 1
in o in o
TH TH (N
•o
o o o o
0000
o o o o
1 1 1 1
o o o o
o o o o
1 1 1 1
rs rs N rs
M ro » o
N in «• »
i i i i
to *o ON ^
0 O O TH
TH O IN fO
TH N to in
o -o in rs
N o n in
TH TH
TH o. in in
in o co m
CN ro to ^
O O TH to
l l l l
to o in rs
-o TH rs in
i TH TH rj
t i i
N CN TH TH
o o o o
0000
^ co ro TH
<• in rs co
o o o o
1 1 1 1
o -o o in
in a) 0 -0
in in in ~o
o o o o
TH IN «r -o
o o o o
1 1 1 1
T o in in
O 0* CO 00
n IN CN CN
1 1 1 1
TH CN CM tO
O O O O
rs o> TH t
0 0 rH TH
in TH -o IN
to  O
TH TH TH CN
TH CM 
-------
O
o
cr>
 i
ca
i oooo
n i ooo o
0 ! oooo
1
U. V 1 OOO 0
O 1 OOO O
Z 1 1 1 1 1

1
i «rfsCMx
at i oo*< CM
i
Z 1
O 1
M | -irsrs CM
« a i »H -H CM n
-i i
0 1
U 1
a i rocoovro
a. n i 0*0- -o
( .H *H «H CM
Z 1
hH |
i o^m m
n i co in M *o
U 1
:> i
0 -« 1 • • • •
0) £0 1 O " i «r -o rs co
-i i
O 1
in i ^ «o CK 10
U) M 1 O O O -<
a i o o o o
i i i i i
! o- m n 10
O 1 CM •« ro •«
* ! 00 -IN
1 1 1 1 1
03 i in o in o
U 1
Ul 1 O
K 1 -i
oooo
oooo
oooo
i
oooo
oooo
i i i i
in in -o <
M CM M M
oooo
in CM CM ro
ro to ro ro
oooo
1 1 1 1
o* CN 0 00 O CM
O O -I 1H
O *0 CM O
* v in m
* o n *H
n n -o N

oooo
1 1 1 1
CM o in n
n 
t in\n in
r*i o >o
CM CM CM CM
OOOO
•» n -o co
n n n in
oooo
1 1 1 1
-o »H «r rs
n n ro n
ro ro ro ro
i i i i
oooo
n *o *o CD
oooo
•o ro o- •«
ro ^ «r n
o> cj o rj
co ^ n •«•
-* ^H n ro
oooo
1 1 1 1
-o o- in n
CM ro n rs
i i i i
CM ro «r n
oooo
oooo
rs co o* o
o o o -i
oooo
1 1 1 1
in *H CM CM
OOOO
oo CM ro in
o in o- ro
ro ro ro «r
ro o *o *c
00-1-.
N CM CM CM
OOOO
•T rs 0- rH
N rs N 00
oooo
1 1 1 1
rs CM n rs
•« n n in
ro ro ro ro
I i I i
oooo
n ~o rs co
oooo
o- 0
00 CM -0 O
n ro ro T
CM 
till
oooo
ro ro ^ 
-------
CT>
 I
CO
in

u. «r
a
z
3
Lt
M
M
a.
a CM
>
_i
o
in
in TH
a
o

in
0)
z
0
M
0
O TH TH TH
o o o o
TH in M3 o*
CM in co TH
M n n 0 N N rs
o o o o
1 1 1 1

o rs co
o o o o
TH -0 0 «•
ro ro ^ *•
«r rs -a ro
N ro r in

ro «r «r ^~
ct. rs o CM
0- O TH TH

o o o o
1 1 1 1
rs *r TH o-
I I I I
TH CM ro 0
CM
O O O O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
ro * «r in
T v ro ro
ro ro ro ro
o o o o
<• N TH ro
-o >o rs rs
o o o o
i i i i
co rs ro CM
i I i i
O O -H TH
o- * o o
o TH CM ro
CM rs TH TH
in in -o -o
rS CM 0* TH
O TH O O
ro N CM o
O O -H CM
1 1 1 1
CM CM CM O
1 1 1 1
TH .H O CM
O O O O
o o o o
1 1
o- ro o 03
0 O 0 O
1 1 1 1
rs v TH co
-0 CO O TH
O O TH TH
oo TH -o «r
OK NO CM 00
TH n r*} ro
ro in co CM
0 O O TH
o o o o
1 1 1 1
in o N *o
O -H -H CM
o o o o
1 1 1 1
in o in o
TH TH CM
rs
CM
                                       242

-------
O
oo
O
O
O
_l
D-
*


o ^ rs in
TH o o* CK
- -io o
i i i i
CD rs TH rs
o- rs m -H
in in in in
CN CM CN CM
ro ro o CD
in on o
-I** CM
o
TH
-H o ro CM
CN ••* rs o
ro o* o ro
CD «T TH O
ro -HO oo
I I I i
-H -iro is
in 01 o CM
M M (N CM
0* £N ts *H
-o -on in
o o o o
in oin o
-
 CO
TH »H O O
1 1 1 1
co n O
•o ro rs rs
«T CN T CO
>o «r TH CM
CM o o- 00
I t i i
o* >o in ro
(N O 111 O
co co rs rs
TH in M o
n (N CN (N
in o in o
TH O rs -O
o co in M
oo is o in
in n n in
O 0- 00 IS
r-i O O O
i i i i
in o T o-
o o co *o
>o *o in in
0* (N *0 0*
O 0 0- CO
•H « O O
in o in o
(N
00 00 M) -0
M CN 00 fs
nin o- in
in n -o 01
M n n r-i
i i i i
rs M in IH
fl- r^ rs ^i
•o ~o in in
n (N n 0 IS M fS(
co -o — rs
O. -H •« -I
rs co T oo
•o -o •« in
i i i i
-0 "i -H CO
(N 0- -0 rt
fs -0 -0 -0
O -0 0- 0-
rs rs rs fs
mono
N
r*
O 0* O ^
00 M M OD
IS N 0- -0
o- fi v n
«r in m in
i i i i
oo n * o-
rj o- rs *r
o »• o> tx
o «• ^ M
in in in in
in o in o
ro
n rs o- o
UT O rs CM
03 M CK Pv
o -* rj CM
n PI M ro
i i I i
n co n CN
oo n o
CM ro oo ro
o- oo in in
-4 o 0- 00
i i i i
•0 -0 0* -0
ro rj o* •«
CK {> CO CO
to CM O 03
CM N CM ^
mono
to
to N ro o-
O N CM tO
•o •« o in
rs to t v
i i I I
n in rs rs
ro CK >o ro
M (N CM M
o to o -o
~o ~o -o n
mono
^
o -o n
•o oo ro o>
CM 0- 0- 00
i i i i
to ro CM ro
(N O N t
*o >o in in
» IS -0 -0
in n n n
n o n o
n
•o rs o- *
•oo -o «r
n ro ^ *•
ro ro ro ro
i i i i
O T O -0
rj o- rs 0 O CM CM
co o ~a
rj -o co o
— 00-0-
n o in o
•0
•o -H ro o-
00 ^ -0 CM
O CO O C*
n ^-n ^
i i i i
CM in CN rs
n o is to
CM CM *H *-(
IN M CM TJ
r-j ro n in
in n n in
in o n o
i ~ «
n
CN
n oo rs n
in CM o ro
T IS CM 00
0- CM IS CD
o o o- o*
i i i i
n o- •« •«
ro o co n
rt rf 0 0
CN o 03 rs
-H ^ O O
mono
•0
TH
rs 03 o- 05
*c -o -H n
* **m -a
ro *H n >o
n » n o
i i i i
o -o n n
rj rs ro o
fs •<> -0 'O
o «r -H rs
>o *o *o in
n o n o
rs
" ro n »
•o n •« oo
ro in -H rs
-H n o CM
n n ro ro
i i i i
o- rn co n
O -0 O N
v n ro CN
to o n >o
CM ro ro ro
mono
-H -1 CM
-0
CN
o- oo «r o>
CO O- CM ^
•o »• n *«
CN o oo rs
ro ro CN n
i i I i
ro o- n n
CN CK rs *•
O 0- 0- 0-
» •« v »
ro ro ro ro
n o n o
N
TH
03 ro o o-
03 O IS 00
rs o » o
00 0- -0 O
n n n n
i i i i
o rs rs
n o n o
CO
TH ro co n
co ro VH ^
to n o >o
>o TH ro "O
in MJ -o ~o
i i i i
TH r , rs *o
n co o ro
03 N N *0
co -o 
-------
o
o
00
 CJ3
 o:
 D-
 co
 a:
 o
 03
in

u. o -o
o o o o
in in T o in o- rH
-o CM in -i
CO rH 
CM in &• CK
-o rs oo c-
O £D in CD
CD t rt ^O
n n T O 0
o o o o
»H » M 0-
^ »0 CM »H
-H ^ rg M
O * O -0
rH TH n CM
o o o o
i i i i
«r n o> •<>
o T o- rs
o o o -i
i i i i
m o if) o
-1 rt CM
»
O O 0 O
o o o o
o o o o
1 1 1 1
o o o o
o o o o
rs rs rs rs
o- co rs rs
o o o o
o ^ ro T
-0 >0 -0 -0
o o o o
i i i i
n CM n CM
^ ,H rH *-4
i i i i
CM *r in rs
o o o o
•H -0 f) O
CM rH 0- >0
in  O 0- CO
if) -o in in
o o o o
1 1 1 1
CM O O O
O O O O
1 1
in o o- rs
o ^ ^ ro
o o in is
rH
CO -H -0 O
n o- N co
rH rH CM rO
to o- in o»
O -0 rH 111
in rs rn in
rH rH
ro co CM o-
1 1 1 1
rs CK T ro
rs -o CM ^~
1 1 1 rH
0 0 O O
o o o o
0- O CO W
O O O rH
O 0 0 O
* rH Os CM
oo rs oo f
O rH CM *
rs *> rs ^i
if) n rH co
in rs rH -o
rH rH
&• rn CM ro
O rH rH rH
0000
1 1 1 1
O -0 IN O
o «r in oo
o CM in o-
i i i i
in o in o
rH rH CM
-0
o o o o
o o o o
o o o o
i i i i
o o o o
o o o o
rs rs co co
o- rs in T
o o o o
o- rH CM ro
in -o -o -o
o o o o
1 1 1 1
v ro n n
i i i i
in o* in o-
O O rH CM
>o ro «r o-
N -0 00 rH
oo rH »r oo
oo -o •
i i i i
rs ^ in f
in ro CM CM
l i l i
O 0 O O
o o o o
rs f n -o
O O rH CM
O 0 O O
rs oo -o «r
•0 rH CD -V
O rH rH CM
CM o -o in
a) ro rs o
ro T in oo
o* n "O n
O rH rH CM
0000
1 1 1 1
in oo oo  rH O

-------
O
o
ca
REGION DISSOLVED N IN RUNOFF DISSOLVED N IN PERCOLATION DISSOLVED P IN RUNOFF
AU AO Al A2 A3 A4 AS BO Bl B2 B3 B4 B5 CO Cl C2 C3 C4 C5
O O O O
O O 0 O
0 O O O
CN CN CN CN
O O O O
O O O O
*o -o rs is
-o rx oo o
o o o o
CN rs o in
rH CN CD CN
CN CN ro f
rs CN CD CO
O rH T-t TJ
i i i i
in ro rH CN
i i i i
O O O 0
o o o o
CN in ro CN
o ^ CN ro
o o o o
O rH rH rH
CD O M rH
O O rH CN
CO rH in rH
O rH rH IN
O O O O
1 1 1 1
oo -o o o o
i i i
o o o o
o o o o
Ps CN N CN
O rH rH CN
O O O O
0 O 0 O
rn ro *o o
^ HT in oo
o o o o
in CD rH <«•
O O rH rH
O O O O
1 1 1 1
0 CO CN rs
O O 0 O
•o CN «r CD
ro ro in rs
o o o o
in CD CN >o
O 0 -H rH
0 0 O O
1 1 I 1
ro 03 rH oo
O O O 0
1 1 1 1
in o in o
rH rH CN
0
o
o
1
ro
0
0
O N N
in v T ro
o o o o
o o o o
1 1 1 1
co <>• CN in
in o
0 CN O-CN
O O O O
o o o o
1 1 1 1
CD 00 CN in
in in ^o -o
CD CD 00 CD
1 1 1 1
rH CN rN n
O O O 0

-------
O
o
co
<
n
u. T
o
z
"n
M
a.
QM
ISSOLVf
:i (
a
8

a
z
o
:RCOLAI
t B'
0.01
z
M
z«
s
(00)
(A
t-»
a
O)
n
u. j
I
M
Z
a CM
SSOLVE
>1 *
a
o
REGION
AM (
OO O O
OO 0 0
oo o o
1
NCM N M
OO O O
oo o o
nn -o -o
oo o o
nn n n
OO O 0
09 CO 09 0»
MM MM
OO 0 O
1 1 1 1
rsM -o oo
n< * »
rsrs rs N
i i i i
MM n n
oo o o
nrs rs 09
oo o o
0-0- 0- OK
n-o rs co
co •« n n
no- CM n
nrs co o-
oo o o
i i i i
09 00 0* CD
on -o o«
1 1 1 1
Mn » -o
00 0 O
oo o o
S28R
oo o o
N-O -0 •«
Mn * n
OO 0 0
OM N «•
MM n n
oo o o
-00- (N -0
OO -I -•
OO O O
1 1 1 1
TN -0 «H
OM » rs
oo o o
1 1 1 1
no n o
~ -H M
Cf
V4
O OO O
o oo o
0 OO O
1 1
N MN M
O OO O
O OO O
n n-o -o
09 oo oo rs
n nn n
0 OO 0
N ON rs
M MM N
O OO O
1 1 1 1
N 0- CO 00
0-0-0-0-
n nn n
i i i i
M n » n
o oo o
•fl COO ~
0 0~* •*
*• o-n o-
•0 N 0- O
«•«
ONTO
•O O» 0-
T NO- -H
ooo •*
1 1 1 1
0. »0 rH
o- nN -
1 1 1
M n* -o
o oo o
0 OO 0
n o-o n
O **•* N
o o o o
n n n o
n Tn N
0000
»H -N 09
fs N 00 O
O OO -i
n o>M n
O O T< TH
ooo o
1 1 1 1
§T-O n
*n •«
o oo o
1 1 1 1
n on o
•4 >4 N
o
M
§s§§
0 O O O
1
N n nn
o o o o
o o o o
T n in >o
oo oo N N
n n n n
0000
T T » T
N N NN
0 O 0 0
1 1 1 1
0- M 03 in
«r n  OK
N OK 0900
M -0 0- M
T oo M n
0 O - -
i i i i
•< T -0 N
03 0 M in
i i i
N n «• -o
o o o o
o o o o
n o •« N
O rt ^ (N
o o o o
•o n •« o-
n T n •«
o o o o
N CD T O
•« in -o co
o o o o
809 ~in
O ri rt
o o oo
1 1 1 1
T< -1 030-
O ^ CM*
o o oo
1 1 1 1
mono
IH ^N
*H
CM
OO 0 O
oo o o
o o o o
1 1 1 1
nn n n
0000
0000
-0-0-0-0

oo o o
no> CM n
nn T T
nrx n oo
•fl 03 O n
*n N oo
oo o o
i i i i
04 o n
o- o CM n
i i i
CMn n  n n r^
n n n n
n n n n
i i i i
«-4 ft lH T4
O O O O
n -o N N
0 OO 0
N -003 -I
n n n *
» *• o. CM
n is oo o
* nn n
0 00 O
1 1 1 1
•0 IS *• 0-
09 0 CM n
1 1 1
CM CM n »
o o o o
0000
m o-  n
0 OO ^
o o o o
i i i
n on o
«•« »H CM
n
CM
o o o o
o o o o
o o o o
1 1 1 1
n n n n
o o o o
0000
-o -o -o r-
oo rs *o -o
CM CM CM CM
O O O O
M » n -o
n n n n
o o o o
i i i i
03 o- o  CM »
n N oo o
o o o •<
i i i i
O 09 CM CM
o CM nrs
1 1 1 1
CM n * n
o o o o
0 O OO
•fl CM O -O
O <1 CM CM
O O O O
CM -0 CM 09
n rt CM CM
O O O O
*« » •« n
09 09 09 O
O O O -i
N n n 00
0 rt -I *
O O O O
1 1 1 1
n rs  *• n t
i i i
Mn » in
o o o o
OO 0 0
NM oo n
O *•< •-• CM
o o o o
»O N -0
CMn n *•
o o o o
O- IS 09 03
» » « n
oo o o
r-o T N
O 
o - M
•« -o •« rs
o o o o
1 1 1 1
O 0- 030-
o rs » n
rs -o -a -o
i i i i
•o o •an
O •< *« M
M -H CM -«
•H M n »
00 M CMn
n -o -on
^ ^ n»
•H M M •<
co -o in -o
o -< Mn
i i i i
o> 09 no
•0 rs 09 09
^ o »* *
o o o o
o o o o
1 1
rt » «O
O O rH CM
o o o o
1
rs M N 09
oo n n r>
o «-< *^ —<
n •« »• »
» n -o co
—1 «4 *H *H
rs o n CM
O -H — (N
o o o o
1 1 1 1
•o o rs »
o CM n n
o oo o
i i i i
n o no
rf Tt M
N
CM
                                    246

-------
O
OO
LJ_
la-
o
o
o
_1
0_
CM
r—
 I
in
u. «r
0
z
D
oc
M
t-t
fl.
Ci CN
SSOLVE
1 C
Q
o

03
§
M
-to,
0
u
QC
L4- ID
z
M
0)
Q
UJ
:>
_i
tn to
en
M
Q
0)
in
u. «
a
1
to
VH
Z
a N
SSOLVE
»1 I
Q
O
REGION
AU <
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
o o o o
1 1 1
rs 00 OD 00
in in in -a
o o o o
o o o o
in in  o n
OO TH TH
OO O O
1 1 1 1
O IN 0- M
MTH «r M
o n CM O M
•H in rf o
O O»< CM
1 1 1 1
iii o n o
T* !-< (N
(M
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
0000
1 1 1 1
N rv r* N
-0-0-0-0
o o o o
o o o o
0- O -< CM
o o o o
1 1 1 1
rf -0 111 M
«r M to to
o o o o
1 1 1 1
rt (N N N
o o o o
o- CM « r-
O ** T^ 1-»
00 M N O
 -c r
-0-0-0-0
o o o o
1 1 1 1
N <• -H to
CM CM M CJ
»H *H *H i-<
1 1 1 1
CM to in -o
o o o o
O «T O O
•^ ** r-4 to
CM »H O 0-
«r in -o -o
in r< IO rf
^ » m -o
CM CM CM CM
to m o in
O O  -o -o
0000
1 1 1 1
^ *H oo rs
-o -o in in
CM n n CM
i i i i
CM (O f ~0
o o o o
o- to rs to
o *H *-< rj
o co -o to
 o o
TH rt n cj
CM «f 00 CM
o o o •*
1 1 1 1
o in n in
« in rs o-
i i i i
CM to ^ in
o o o o
o o o o
» rs oo o
~< ^ ^ n
0 0 O 0
1 1 1 1
-H 00 N 00
n M to «•
o o o o
tO 00 CM 0-
^ oo in -H
 CM
o o o o
1 1 1
in o in o
-> « CJ
00
0 O O O
o o o o
o o o o
n n n CM
o o o o
o o o o
1 1 1 1
oo o- o n
to ro » *
o o oo
0- to CJ O
M n CJ CM
0000
1 1 1 1
V 10 0- »
0- ^ 0- -0
» in in •<>
1-1 *H TH T-t
1 1 1 1
o- o- in -H
o — ro »
» oo rs in
CM 
-------
O
CJ
CNJ

 I
QQ
in

ii_ ^r
o
z
3
a.
ro
M
CL
Q CM
SSOLVE
:i c
Q
O


in
a
z
o
IRCOLA1
S B'
CL 0)
Z
M
ID
LU
^
_j
u) a
in
HI
a
CQ
111
h_ «r
c^
ro
Z -i
Z
a CM
l\
rnoss
a
0
z
0 3
a
u
tL
o o o o
0000
o o o o
o o o o
o o o o
1 1 1 1
•o o rs rs
ro ro ro o ^
in in in •«
t f i i

i i i i
0- «• (M fM
O CM N «T
rf (N ro in
1 1 1 1
O O M N
O O O O
O O O 0
*T O O iH
CM ro ro CN
o o o o
1 1 1 1
IS *T lH iH
o >o *r in
-1 rt CM n
oo rs •»• o
co o- m ^r
IH
^ rs (N n
o o -< CM
o o o o
1 1 1 1
•0 0- ** rs
n co o o
o o r-i o o o o
«r in in in


o o o o
in N co ^
O O O -I
co fi rs (o
in rs co o
n o- CN -o
O O* rH
CM ro IIT -o
o o o o
1 1 1 1
-o in o- o-
«r ^3 co »H
i i i -«
CN n 
o IH rj ho
o o o o
1 1 1 1
in o in o
n
o o o o
o o o o
O 0 O O
O 0 O O
o o o o
1 1 1 1
«r in in -c
CD CO CO CO
ro ro n ro
0 0 O 0
T* TH TH 1H
CM CN CM CM
o o o o
1 1 1 1
>0 CD >0 M
-0 -0 -O -0


O O 0 O
in N co o
o o o *-»
t -< CO CO
-0 CO 0- 1-1
1-1 CJ CO 111
in co o ro
CN ro in -o
o o o o
1 1 1 I
o in 0 O
*H n TJ rj
rj *r o oo
o o o o
O 0 O O
1 1 1 1
ro o -H -o
o " n ro
o o o o
1 1 1 1
in o in o
t
o o o o
o o o o
o o o o
0 O O O
o o o o
1 1 1 f
•r t in in
ro 10 ro ro
o o o o
CO CO O~ IH
ro ro ro o *o
CM ro o fs
ro n so o*

n ro t n in
ro ro ro ro

o o o o
rs o- ^ «r
O O -i rt
in CM o- -o
ro » *• in
1-1 -H rs o-
co o -i n
rf ro n rs
o o o o
1 1 1 1
o in ro >o
ro ^ -o co
i i i i
n ro T in
o o o o
o o o o
>o rs rs rs
0 O 0 0
o o o o
1 1 1 1
in o- «• o
o o o o
-< o o -i
in o t co
ro v v «r
CM * *0 CO
o o o o
o o o o
1 1 1 1
V CM CM O
O O O O
o o o o
1 1
in o in o
IS
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
in in 'O -o
in in in in
ro ro ro ro
0 0 O O
-0 -0 -0 -0
o o o o
1 1 1 1
co co CM in
in in -o *o
CO CO 00 CO

o o o o
T -o rs oo
o o o o
o- ~o ro ~
ro «• in -o
ro n o* v
-0 CO 0- rf
T-I n CM «r
o o o o
1 1 1 1
-i 
-------
O
o
C\J
00
in

u.«r
o
z
D
ro
0.
QCM
SSOLYE
1 C
o
o

z
o

O O O O
o o o o
o o o o
1 1
0000
o o o o
1 1 1 1
in UT •o -o
rx rx rx rx
n CM CM n
o o o o
N -0 N IX
CM CM CM CM
O O O O
1 1 1 1
rx o- oo m
0-0-0-0-
n n n in
i i i i
CM ro «• n
o o o o
n co o ro
o o -i -i
oo CM -o ro
n ix co o
—i
-0 rf -i O
t rx o- CM
CM V -0 ix
0 0 0 O
1 1 1 1
0- 0 IX O
«f ix o- ro
i i i -i
i
CM ro ^- iii
o o o o
o o o o
•« rx fx -o
o o o o
o o o o
1 1 1 1
ro -i CM -o
o o o o
10 0- -" t
•o o- ro -o
CM CM ro ro
ro t -o o>
o o o o
o o o o
1 1 1 1
-I Nix IO
o o -i n
o o o o
1 1 1 1
n o n o
rf -i N
O
CM
O O O O
O O O O
o o o o
1
o o o o
o o o o
1 1 1 1
r
o o o o
1 1 1 1
ro -o o- ro
o o o o
0- CO •» O-
03 CM -0 0-
ro » T f
CM ro ^ in
oo o o
o o o o
1 1 1 1
<• CM CM N
O O O O
oo o o
1 1
mono
»H -t CM
CM
CM
O O O 0
O O 0 O
o o o o
1 1 1 1
o o o o
o o o o
•0-0-0-0
rx ix rx rx
o o o o
o rn CM ro
o o o o
i i i i
o- m n fx
ro ro ro ro
ro ro ro ro
i i i i
O O O 0
in -o -o N
o o o o
ro -o o- N
n CM n ro
-1 1H -0 0-
m -o -o -o
rt CM CM rO
O O 0 0
1 1 1 1
* n ro «r
CM ro •»• in
i i i i
-i CM CM ro
o o o o
o o o o
0 0 0 -i
o o o o
o o o o
o rx oo o-
O 0 0 O
o o o o
> to o ^
CM » -o rx
CM CM CM CM
~ n «r n
o o o o
o oo o
1 1 1 1
» 10 n o
o o o o
o o o o
n o n o
ro
CM
0 O O O
O O O O
o o o o
1 1 1 I
o o o o
o o o o
1 1 1 1
-o -o -o rx
0-0-0-0-
o o o o
t-i t \n -o
n in in n
o o o o
1 1 1 1
03 0- O *
-1 o -i -1
1 1 1 1
-1 CM CM M
O O O 0
IX 0- O M
0 0 <-"*
o •<> o n
ro ro * i-
CM 0- CO CM
N CO 0- O
rf ro t •<>
0000
1 1 1 1
o ro m rx
ro  -o -a
i t t t
CM CM ro 
ro «• n in
•0 O O 03
ro n -o -o
-i ro in ro
o o o o
1 1 1 1
CON fx »
PI » n rx
i i i i
-H n n T
o o o o
o o o o
0- o -i «H
O O 0 O
1 1 1 1
» oo  CMIO
o o o o
1 1 1 1
mono
*4 — CM
rx
CM
                                       249

-------
O
oo
a:
O
o
o
_i
o.
co

 I
LU

_l

CO
-
0 00
O O O- CO
TH .H 0 0
111 O 111 O
•H rf CJ
CJ
rx -o -o TH
111 V TH CJ
N 0- T 0
P) CJ CJ CJ
111 CM -0 CM
P) P) CJ CJ
1 1 t 1
CJ 0- 111 TH
CJ TH TH TH
rx .H o co
111 O 111 O
.H TH CJ
CJ
O O -0 0-
o- rx cj o.
T -0 TH -0
fx CO *f CO
-o -o -o in
i i i i
CJ CO 111 O
CJ CJ CJ CJ
O -0 0- 0-
in o in o
O 0- 00 TH
O 111 111 CJ
0* PI PJ PI
T 111 111 111
1 1 1 1
O -0 CJ CJ
TH rx LI! eg
iii 
TH 111 TH P-
«T CO PJ 03
co rx rx -o
O- O P3 -O
111 O U") O
TH .H CI
0-
                                        250

-------
o
oo
a;
a.
to
a:
o
o


o
jj
a.
CQ
•=c
Ill

li. »
0
z
3
K
M
M
£L
on
SSOLVE
1 C
M U
a
o

a
z
o
HH
IRCQLAl
S B'
a. a
z
M
a
a
u
>
*TH
W 0)
U)
M
Q
pa
in
u. *
o
z
3
Ct
M
w
z
o rj
SSOLVE
a A
a
o
REGION
AU I
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
CO 0} GO CO
» T in in
o o o o
CM N TH TH
o o o o
1 1 1 1
ro n -o C-
n ro n n
o o o o
i i i i
n •« in oo
00 TH TH
in to -o -o
»H N -o is
in co is o-
«r o TH -o
<-i M n in
CM Is Is 0 -O ^ *T
O «T 0- 03
TH (M n in
i i i i
in o bi o
TH TH (N
TH
0000
O O O O
O O 0 0
1 1 1 1
0000
o o o o
CO CO 00 CO
0- O 0* O
O TH O TH
o o o o
Ix fx -0 -0
o o o o
1 1 1 1
o- o -1 io
IN M M M
0000
1 1 1 1
o rx in
•O 0- -i M
(N  rj co »
«n n «• co
o- n is -i
-0 CO 0- O
T-l
co M rf rs
IH o> ~o m
tin 
i i i i
M in *o co
o o o o
o o o o
-< N M in
M M «• in
o o o o
--< in ^< rj
ro in co ^
O O O -1
in in co rj
o o -< n
-H -a n o-
rf « rj M
o o o o
1 1 1 1
O M -0 0-
-< rs » n
o o -< n
i i i i
in o in o
-> rt IN
»
O O O O
o o o o
o o o o
1 1 1 1
o o o o
o o o o
N rs rs is
0- 0- O- 0-
o o o o
o o o o
io ^ in is
in in in iii
o o o o
1 1 1 1
•0 0 IS
o o o o
o o o o
N >o *• n
r< n n r
o o o o
0- O 03 03
» in » v
o o o o
1 1 1 1
o » M n
T n n n
o o o o
1 1 1 1
>o in ^ is
o TH n in
•c •* -a n
M o n CM
•< n
^ Is O O
^ r^ *-< rH
•H n n 
o TH rj N
M n * -o
T * -O 0-
C* » TH CJ
o TH n M
O 0 O O
1 1 1 1
n o- -o n
n CM co o-
o TH n *•
i i i i
n o n o
TH TH M
IS
O O O O
o o o o
o o o o
1 1 1 1
o o o o
o o o o
IS IS IS IS
TH TH O 0-
CN n n TH
o o o o
TH n M in
in n in in
o o o o
1 1 1 1
in n TH o
n in in n
n n ri n
i i i i
M in N o
O O O TH
(N 0- IS IS
TH TH oi n
«r n TH in
n -o is ix
» n -o TH
O V N O
a n M ro
CO 111 TH O
i i i i
00 -O TH TH
n in co o
i i i i
ri •»• n is
o o o o
o o o o
0- 03 CO IS
o -H CM n
o o o o
n oo TH iii
CM n in -o
0000
in co >o o>
O O O TH
oo n co M
O -H TH (N
o o o o
1 1 1 1
O IN TH IS
o n n 03
O O O 0
1 1 1
n o in o
TH TH [N
03
o o o o
o o o o
o o o o
o o o o
o o o o
Is rs Iv 03
o -H n t
•0 -0 -0 -C
o o o o
TH is >o in
M CJ M CM
o o o o
1 1 1 1
TH o n in
o n is n
o
M IS M M
TH 1
M *o in >o
N *o TH m
TH n M m
r< o o- TH
is o TH n
» Is 0- -0
TH
03 o is n
1 1 TH
1
•r 03 o- rs
•o .H in .H
1 1 1 TH
i

-------
O
CJ
CQ
in
u. o *o >o
o o o o
^- O rs in
* rf O O
O O O O
1 t 1 1
«r <«• -o o-
CN in rs o
0 TH
•H M CM M
n o in n
ro o -o ro
ro m >o co
rs o ^^ 1-4
.-1 * 0- in
1 1 1 r-t
1
-o in oo M
in o ^ o*
i i i i
O T-l » tO
O O O rf
o o o o
CNCN CO <0
•-> CN M -o
o o o o
O ••« IH 00
ro -< M in
VH CN ro »
o- -< o o-
» o in rf
*-i CN ro --o
a> * M M
O «i (M T
o o o o
1 1 1 1
CNO N rs
-0 0>  CN rs
ro ^ rs O
CM M  N N (N
oo o -o r^
O *-t ^ (N
00 0 r< O
si -a oo i
-< rf -i IN
*o o* v oo
O O lH rf
o o o o
1 1 1 1
in M in -o
O CN V fs
o o o o
1 1 1 1
mono
-H T-l CN
fN
v4
O O O O
o o o o
o o o o
CM CN rj CM
o o o o
o o o o
iii in -o -o
•0 >0 *0 *O
o o o o
rs -o in -o
o o o o
i i i i
t is rs co
n M n n
rs fs fs ts
M in rs o-
o o o o
0- M N O
O «H r* f J
ro M n m
rs o- «H M
1-( v^
rs >o ^ o
fs « o- in
»-l CI CN M
rs M •« o*
o * ** *->
i i i i
o- co >r CD
o in o in
i i i i
CN M in rs
o o o o
o o o o
rs CN en -o
O •<•< •* CN
o o o o
•H n o oo
«r in rs co
o o o o
in co rs co
^ «• ^o ch
o o o o
in oo CN rs
O O -H TH
o o o o
i i i i
rs » o- CN
0 CN » CO
O O O O
1 1 1 1
mono
T-l «H CJ
n
*-4
O O O O
o o o o
o o o o
CN CN CM CM
O O O O
o o o o
in in o •a
i-< *H r-l TH
O O O O
O. 0- 0- CD
O O O O
till
•« oo N n
m in in in
rs rs is is
M in N o
O O O rf
oo n rs o
CN rS rH 0-
co o ro m
o o o- oo
0- -0 CM O
rt M n 
M M M ro
rj M < n
o o o o
O M -0 -1
rt in N N
>o rs co c>
rs oo -o CN
m * N IN
CN M n o ^
O <-< >< CM
o o o o
1 1 1 1
O CN CM <0
o CM n oo
o o o o
1 1 1
n o in o
•^ T* n
•o
T1
O O O O
o o o o
o o o o
i i i i
n n n n
o o o o
o o o o
>o N rs rs
*o in n n
IN CM CM T<
o o o o
0- O rf to

0 O O 0
o- is n «r
*H w fo *
o o o o
to >o o o
0* 0* ^ tO
O O ^ 1H
co to N n
O ^ *-t CM
o o o o
1 1 1 1
n » rs -e
o -< M -o
O O 0 0
1 1 1
n o in o
-4 ** r-i
IS
»•«
o o o o
o o o o
o o o o
n n r-i CM
o o o o
o o o o
n -o -o -o
o o o o
V t t t
o o o o
V t f t
r* r* r* r*
O O O O
1 1 1 1
oo o. ro -o
ro ro v *
CO 00 CO 00
CN ro to t
o o o o
O CO O- .-i
0 0 0 -<
00 0- 0- 0-
m -o N co
O CN CN 00
CO CN -0 0-
^ CM n CN
in CD o CN
0 0 -< rH
1 1 1 1
rs in ^ -o
•i n o- CM
i i i i
CM ro t n
o o o o
o o o o
•0 CN CO M
O ^ -* CN
o o o o
CO 0- CM *
CN n n >o
o o o o
rs N n to
-o rs o CN
o o o ^*
•o o- -< «r
o o •< -«
o o oo
i i i i
» o ro rs
1 » N O
0 0 O^
1 1 1 1
mono
x xf-1
CO
                                     252

-------
in

U-f
o
2
3
cc
n
t-H
a.
QN
[SSOLVE
:i (
a
Q

ffi
2
p
M
:RCOUA:
5 B-
a. o
2;
ca
p
UJ
_i
U) A
cn
M
a
CQ
llT
U. »
0
Z
3
cc
n
M
Z
a CM
SSOLV
1
a
o
z
0 3
1-1 «
O
UJ
0£
O O O O
o o o o
o o o o
o o o o
0000
in -o -o -o
o o o o
w n M m
o o o o
in m in -o
n N N N
o o o o
i > i i
n is TH n
TH TH CM (M
rs rs rs rs
1 1 1 1
ro ^ in *o
0000
03 TH to -43
O TH TH TH
rs TH «r rs
MJ 00 0- O
TH
N IS 1H TH
oo N rs .H
TH 
o o o o
r> « n n
(N N M tN
0000
1 1 I 1
n ^ 
o -i .H (M
0000
o n oo N
i1 in -o oo
o o o o
•H V N rs
oo oo o n
O O -1 -1
lf> OK f) OK
O O -> TH
o oo o
1 1 1 1
tr n o rs
o CM m a)
o o o o
1 1 1 1
in o m o
TH -I CM
o
r»
o o o o
o o o o
o o o o
o o o o
o o o o
in in -o -o
00 03 CO 00
r*i M n ro
o o o o
(N TH M N
M N M N
O O O O
1 1 1 1
«r -o n TH
«• o in
OK N «• fS
i i i
M n in rs
o o o o
o o o o
in rf m -o
O T-I TH M
o o o o
M in o- «•
t 111 -0 CO
o o o o
"< 0- 00 O
rs ^) rs o
0 0 O rf
in o- n oo
O O -H -<
o o o o
1 1 1 1
n oo o- in
O *H M »0
o o o o
1 1 1 1
in o in o
-H ^ ri
r4
M
O O O O
O O O O
o o o o
1 1
o o o o
o o o o
•o -o •« rs
in t T o >o >o >o
M n CM n
M CM (M CM
o o o o
•o N co ci-
io n ro to
o o o o
1 1 1 1
CM OK OK T-I
o 
-------
o
oo
r-J
 a:
 o
o
_i
Q.
 LCI
 CO

 «=E
in
u. *•
o
z
D
CK
ro
M
0.
cm
SSOLVE
1 C
Q
O

CO
z
o
M

„ \
CO CQ
cn
n
o
A
«

U. «t
O
z
gro
TH
2
O CM
SSOLVE
u e
a
o
REGION
AW f
O O O O ,
o o o o
o o o o
1 1 1 1
o o o o
o o o o
o o o o
1 1 1
CD 09 CO CO
in in i/> in
o o o o
o o o o
CM PI TH -H
O O O O
1 1 1 1
ro ro -o o*
to ro ro ro
0000
1 1 1 1
to -o in oo
0 0 -H TH
in o TH o
TH ro IN o-
THfN -0 0-
* O TH -0
TH CM lO in
TH TH 0- rN
•0 t IN IN
TH PI
mono
O TH PI PI
i i i i
N IN CO -0
in o- -o CM
TH CM «T CD
i i i i
IO «• IN O
O O O TH
O O O O
-i -i o O
o o o o
1 1 1
0- 0- l«l 00
rs in m IN
O TH PI IO
CM TH o n
o- ro «• IN
CO « -0 TH
TH TH CM
«• IN pj m
O O TH TH
o o o o
i i i i
t V 00-
» -o ro T
o TH ro in
i i i i
n o in o
TH TH CM
TH
O O O O
o o o o
o o o o
1 1 1 1
o o o o
o o o o
o o o o
1 1 1
00 00 00 00
•o -o -o IN
o o o o
o o o o
IN IN -o -o
o o o o
lilt
0* O TH rO
CM ro 10 ro
o o o o
1 1 t 1
» Is  *o rs ^~
n -o o in
o o •< -<
-H CM <»• rf
CM CO 00 0>
CO 0* ^4 tO
*H rH
•0 O » 0
O iH *^ *H
o o o o
1 1 1 1
oo o o <-i
-< IN m in
O O ^ CM
1 1 1 1
in o in o
-I -I IN
CM
O O O O
o o o o
0000
1 1 1 1
o o o o
o o o o
o o o o
1 1 1 1
IN IN IN 00
-0-0-0-0
o o o o
o o o o
«?• in -o IN
to to to to
o o o o
1 1 1 1
to co rs -o
in 
«H r-(
o> o f T 00 SJ
in oo o -o
oo -i in -o
r-l »H r-t
in ro Pr 
-------
O
o
LT)


 I
CO
n

u. 
CM n rs o
«r t «r in
i i i i
oo oo o- in
O rH tO -0
03 rs rH tO
-IM o- in
rs  «r in o
-oo- -H «r
rH rH
t oo rs n
O O rH 10
o o o o
1 1 1 1
f rH 00 -0
o rn N n
1 1 1 1
no n o
rH rH CM
O
0 0 O O
0 0 O O
o o o o
0 0 O O
o o o o
1 1 1 1
•0 -0 N N
oo rs TS rs
ro to to ro
o o o o
•o «r «r «r
CM CM CM CM
o o o o
1 1 1 1
CM «r o n
rH rH rH O
O O O O
1 1 1 1
in o N ro
O rH rH tO
rH oo in t
CM 00 00 O
o «o- n
rH rH rH CM
oo o- in oo
rH ts Hf CM
n to rs o>
o rn CM in
1 1 1 1
o- rs rs o-
t rH CM ro
i i i
rH CM n o-
o o o o
o o o o
rH CM CM 00
O O O O
1 1 1 1
oo o n N
00 CM -C CM
O rHrH CM
tO O n rH
ro «r n rs
 i i
» •• in 0-
f t ro n
in in n in
o
o o o o
o fi in o
o M rn n
O 0- 03 03
o -o
ro ro ro to
0 O O O
««*«
O O O O
III!
oo o- ro -o
ro ro T  t
rj ro «r in
o o o o
ro o^ o D-
ri ri ro ro
r-i w \nr**
o o o o
O O O 0
lilt
O' *H N *
o o o o
III)
in o in o
00
                                         255

-------
O
o
LO
UJ
_l
CQ
in

U- 
_i
o
01
CO rt
a
o

CQ
o
IRCOLA1
5 B'
0_ CQ
Z
a
Ul
en n
tn
M
a
in
u. «•
o
z
cc
z
QCM
SSOLV
U
o
o
REGION
AU t
O O O 0
o o o o
o o o o
o o o o
o o o o
1 1 1 1
in -o -o -o
03 03 00 00
CM n CM n
o o o o
m in in -o
cj CM n ci
o o o o
1 1 1 1
fM N rt rO
rt rt CJ CJ
rs rs N rs
i t i i
CM «• in -o
o o o o
is o- rt rs
O O rt rt
oo rt in o
in rs oo o
rt
ro o o CM
•0 O. rt CM
ro -o o- CM
OO O rt
1 1 1 1
ro i- -o r rt o-
cj ro r
o o o o
IIII
in o m o
rs
CI
                                          256

-------
oo
o
oo
GO


o
a:
o
o
o

Q_


C3
•z.
I—I

o;
CQ
V

v





3
 CD 00 N
(M CM CM CM
n o n o
1^ CM
-
N » -o n
N » 09 rf
09 09 O n
n ^ V M
tn -H o ^
•a n«r M
(N CMfM CM
i i i i
N n OK i-*
N •<> n »
» » T »
1 1 1 1
oo -IM n
•o -o n *
CM CM CM CM
n on o
«•• ** CM
CM
N n O n
OK N o n
» -OrH -0
N -o -o n
in * t N
O- OK 00 N
MMMM
1 1 1 1
M O O CM
rt M » »
n n n n
i i i i
CO OOO M
OK O OK OK
M * M M
n o n o
rH rt CM
CM
M oo -o n
00 •* N 0
n m N M
rs -o in m
09 00 * -0
CM CM CM rt
MMMM
1 1 1 1
TH CMN CM
N OKO CM
» « n n
1 1 1 1
X N OK N
MMMM
MMMM
n on o
*1 •* CM
CM
V CM O CM
-1 •«•» N
M N » rt
N -0 -O -0
n oo co N
V <• » »
MMMM
1 1 1 1
•o •" rs N
O MM •»
n n n n
i i i i
n OK 00 N
MMMM
n on o
** ~* CM
M
M -0 CM 03
» OK n •«
•0 O N*
N N *Q -0
O •< -1^
n n nn
MMMM
1 1 1 1
00 O M CM
O M M »
-0-0-0-0
1 1 1 1
O CM CM -1
n n nn
MMMM
n o n o
* ** CM
CM
CM
CM -0 * rt
» N 00 "
in -o o-o
rs -o -o m
00 N CM *
N -o n »
MMMM
1 1 1 1
-H o n-o
N N N 03
MMMM
till
CM rt N «•
CO 00 NN
MMMM
n o no
~t * CM
M
iH
00 M rf 00
M OK CM O
» t 03 M
-o n *• »
09 <• » »
CO CD N N
CM CM CM CM
1 1 1 1
~ -O CMN
O CM MM
n n nn
i i i i
* » o -e
OK OK OK 03
CM CM CM CM
n o no
-H  n H
1 1 1 1
09 ¥5 CM -0
n 03 o- co
1 1 1 1
00 M 09 N
M » M M
CM CM CM CM
n o n o
r* 14 CM
N
CM 0 » N
M -< «r N
M n o -o
rs -o -o in
o <• N N
09 09 03 09
MMMM
1 1 1 1
CM -0 CM »
•0 OK N CM
niffo-o
1 1 1 1
CM OK CM rt
CO 09 OK OK
MMMM
n on o
-« rH CM
•0
CM
n ^ -o «•
rH CM CM OK
n -o ^ -o
N ~c ~e n
rt OK -0 «•
» M M M
MMMM
1 1 1 1
» -0 M 00
O CM M M
-0-0-0-0
1 1 1 1
CM » CM *H
MMMM
mono
-< TH CM
N
» O N M
09 OK * M
OK « -0 CM
-o -o in in
N 09 n »
CM CM CM CM
MMMM
1 1 1 1
<• T* 09 »
n 09 OK rH
n n n -o
i i i i
T* 00 OK CO
MMMM
MMMM
n o n o
-t .H CM
09
•O N 09 OK
-0 N 1 09
N 03 M 00
•o nn v
CM » M CM
•fl -0 -0 -0
MMMM
1 1 1 1
t cMn n
M -0 OK *
in in in -o
i i i i
» OKM n
•0 -0 N N
MMMM
n o n o
•1 * CM
N
CM
O O OK n
o- 1 n n
03 CM N M
N N -0 <0
OK » 00 n
OK 0« 00 09
MMMM
1 1 1 1
CM M M 00
09 OK OK OK
-0-0-0-0
1 1 1 1
OK 09 M O
OK OK OK OK
MMMM
n on o
rt rt CM
CO
oo n n CM
^ * OK *
09 CMM N
 QK N •«
rt O OK IS
» » M M
1 1 1 1
•0 CM M CM
rt O OK 09
CM CM ** •<
n o n o
rt -• CM
OK
                                            257

-------
 oo
 	i
 i—i
 O
 <=c
 M
 UJ
o:
o_
o;
o
o
o
_i
Q.
o:
Q-
OO
LLJ
_J
CO
<:
m

u. *
o
§
cc.
n
M
0.
Q N
tSSOLV
;i
Q
O

a
z
Q
M
4 0)
-1
o
u
ot
a. a
z
w
IB
s
3 ,
en oo
tn
M
a
A
n
u. »
r
i
n
M
z
a CM
SSOLVE
»1 (
a
o
REGION
AW t
00 O O
o o o o
OO 0 0
o o o o
OO 0 0
1 1 1 1
•o-o r\ rs
HIM N N
OO O O
l"t rH rH rH
O-O O- 00
rH CM i* rH
OO O O
1 1 1 1
O » rH •H CM
i i i i
co xi o r-
CMn o> w
rH rH rH CM
1 1 1 1
is n » »
o •* CM n
oo o o
TH 00 QK SI
(MO » 0-
OO 0 O
1
rs rH rs rH
CM CM rH CM
o o o o
(NO n CM
rs rs n <
inn n in
•« -i «r o
rHM «• -O
o o o o
1 1 1 1
-0 03 O •«
rH CM M CM
O O O O
n o n o
•1 X (M
«H
o o o o
o o o o
O 00 0
o o o o
o o o o
is rs rs rs
OK in o, oo
» » n n
o o o o
*• » -o in
N CM (M CM
O O O O
1 1 1 1
•O N CM 00
rH O rH O
0 OO O
1 1
in rs o *
0 OrH rH
•Q co in »•
CM n in is
«• CM o- n
n -c ~a is
oo CM o n
oo M rs OK
CM M M n
OB CM is n
O rH rH CM
i i i i
IO O CM rH
o- r< CM n
1 rH rH rH
1 1 1
n oo CM n
o OrH *
o o o o
n o M n
0 CMT -0
0 OO 0
in o o rH
rH CM CM »
o o o o
» fs OK CM
«• -ooo in
CM CM CM n
-< 0- » O
-i »< CM n
o o o o
1 1 1 1
CM -o o in
o -< <• -o
o o o o
i i i i
mono
^ o -o in M
»H T-l TH rt
rs ^ -o -<
O rH rt CM
O O O O
1 1 1 1
» x » 00
o o o o
o o o o
1
n o n o
-i -< N
n
o o o o
o o o o
o o o o
oo o o
o o o o
i i i i
in in in -o
o o 03 -o
0- O- 00 00
o o o o
in o- o CM
n M <• <•
o o o o
1 1 1 1
M < » n
-0 CM CM r*
CM CM CM CM
1 1 1 1
v -o rs o
o o o -H
oo rs in rs
•rf CM M 0 O M
O O X 1
O O O O
CM o in *
^ o ^H ro
0 0 O 0
1
CM O Cf. »•
o o o o
rH CD CM O
CM CM CM CM
n m nn
OK rs OD O
O rH CM *
O O O O
1 1 1 1
N -0 » *
rH O O rH
O O O O
1 1
in o in o
rH rH CM
*
o oo o
o o o o
o o o o
o o o o
o oo o
in in -o -o
in CM o- oo
in in  T OK »
O rH -H CM
1 1 1 1
-0 O- O (N
rS 000 rH
1 1 rH rH
1 1
M nrs o
O O O rH
o o o o
<«• -O 00 rH
O O rH rt
O O O O
1
rH rH O rH
O O O O
< rH oo rs
oo 03 in »
r-l rH T* rH
oo in CM o
O rH CM M
o o o o
1 1 1 1
M » O rH
O O rH rH
O O O O
1
in on o
rHrH CM
in
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
-o rs rs rs
o- in n n
0000
03 o- n o
rt m *o rs
o o o o
1 1 1 1
03 T CM 0>
rs in o rn
M rH rH O
1 1 1 1
•o o co n
O rH rH M
n n m o-
CM * rs n
rH
0. » rH 0
o- M rs o
rH rH CM
N n N -o
co n oo n
M in -o oo
in o- •< *
rn CM in o-
1 1 1 1
•o in CM •»
o. o CM n
rn n T in
i i i i
•o » n m
O — M n
o o o o
rH CM O O
CM rH CM -0
O 0 0 O
1 1
n 03 O rH
hi CM M V
o o o o
CM O -0 0-
T o- in »
in -o rs co
M in CM -0
i n-oo-
o o o o
i i i i
n rs o- o
CM rH CM CM
o o o o
i
in o in o
rH rH CM
•0
0000
o o o o
0000
o o o o
0 O O O
1 1 1 1
in -o -o -o
o> rs in ro
o o o o
m CM rs CD
M V ^ ^~
o o o o
i i i i
rH rH » 03
o n o- co
in » n n
i i i i
n o- «• n
O O rH CM
03 n rH CM
rn M in oo
m «• rH in
•0 00 0 rH
rH rH
» CM O 0>
CM 03 T 00
CM CM M M
rH CM M -0
.H CM M in
1 1 1 1
O 10 rH -0
rH n o «r
rH rH CM TJ
1 1 1 1
in o> » -H
O O rH M
O 0 O 0
N M CM *O
-H O rH M
O O O O
1 1
-0 O O M
n «r in -o
O 0 O O
in CM rs rs
ro co n o
n n * «r
OD o^ ro «-*
o -i M m
o o o o
1 1 1 1
rH 00  o o o
O rH rH rH
00 rH <0 -0
rH 0 rH rH
O O O O
1
•o M n rs
rs -o » o-
N 0* rH rH
rH rH CM CM
1 1 1 1
0 O -0 rH
rH CM M »
»• in o CM
CM in o CM
rH rH
rH » rs 0-
n oo CM o
rH rH M n
noon
* O- CM »
n t ~o a>
» 00 03 rH
CM » 030
1 1 1 rH
1
o in n rn
-o o CM <•
CM » in rs
i i i i
CO » *• rH
O rH CM V
0 O O 0
» -0 rH CM
O CM -0 rH
O O O rH
rs in n »
* -0 O- rH
O O O rH
03 00 n CM
rs in -o o
CM CM CM M
oo in on
rH M -0 O
O O O rH
1 1 1 1
» rs in »
» -o CM rs
O O rH rH
1 1 1 1
n o in o
rH rH CM
0-
                                            258

-------
UJ
_i
OQ
i oooo
m i oooo
1 OOOO
i
b. « 1 OO OO
O 1 OOOO
Z 1
oc i »nn-o
i
CL 1
i MM nn
Q N 1 »OK 0-0-
:> 100 00
ei !
in i 03* oo-
at * \ MM M-«
Q IOO OO
i i i i i
i
i -o-o noo
o i nrs Ttn
i inn -o-o
i M* rf»n
i i i i i
i
i on «Hfs
A 1 O-< MM
i
Z 1
O 1
M 1 03 M N t-o
t *4 »«»*
Z 1
M 1
i nfs nM
A i r*rx no
UJ I
s i
_i i moo •«-<
U) A 1 <*M »00
(n i i i i i
t-4 1
a i
I o-x 00-0
« 1 nM fsM
1 r*M nn
1 OO OO
Z i ' ' ' '
03 I mono
1-4 4 1 r4 *H N
O 1
Ul 1 O
tC 1 "1
OOOO
oooo
oooo
oooo
oooo
n » » n
o- o- CD m
fs IS rs rs
oooo
o- -in in
4) tsrs Is
OOOO
1 1 1 1
rs «r fs oo
n 0- » n
oo rs. rs is
i i i i
ID CD-I IT)
O O rt Tt
M 00 » n
rt rt (M M
•0 O t-l N
•0 00 0- O
«H
M M 00 »
n •« 03 .
1 14 »4 T4
i i i
n o- n co
0 0 rt ,-.
oooo
0- « 0- »
O O O M
oooo
1 1
M -0 00 M
n n n »
oooo
o- -«n o-
M fOM •<
M M M (N
o rv •« o-
*4 IH N ro
oooo
i i i i
N n N -o
oooo
oooo
1 1
n o n o
« 
oooo
oooo
n o in o
000-
oooo
1
O rt M -H
M M M M
OOOO
rs o o- rs
o — o o
n 09 M 41
O O  03
n « M 
M CM N M
^ 0" » O-
rs N 00 00
•« o- •< n
O O — •"<
1 1 1 1
n o- -o n
»  — n in
«i M CM M
oooo
» » rs N
n » n M
» co M n
o o «-i •«
oooo
1 1 1 1
in rs r< -o
-i rf M M
oooo
1 1 1 1
n o n o
rf — N
CO
                                     259

-------
ca
n
u. »
0
or
m
M
a.
a CM
[SSOLU
:i
a
o


IB
Z
0
:RCOLA
t B
a. a
z
a
a
Ul
^
j
in n
in
M
Q
a
n
u. »
o
z
m
M
Z
QCM
Ul 
_J
O
to
in TH
a
o
REGION
AU (
OO O O
o o o o
oo o o
CM TH TH TH
oo o o
o o o o
1 1 1 1
OO TH CM
10 CM TH OK
rsrs rs o rs o.
o o o o
o HT oo CM
CM *r •« rs
n m mm
o n oo CM
rs rs rs co
O TH TH TH
1 1 1 1
rs CM » on
m <• w 
o o o o
1 1 1 1
ro TH n rs
o o o o
1 1 1 1
n o n o
TH TH CM
CM
o o o o
o o o o
o o o o
CM TH TH TH
O OO O
O O O O
1 1 1 1
0 TH TH CM
TH TH TH CM
00 00 00 00
O O O O
CM » n OD
o o o o
0 O O 0
o m v o-
M V N O
CM CM CM h)
1 1 1 1
m t n -o
o o o o
O M -0 OK
N OK O TH
CM CM m m
O -O TH <•
00 00 OK 0-
rs OK CM n
0 0 TH TH
1 1 1 1
o -o o »
n n -o -o
i i i i
CM m » -o
o o o o
o o o o
n CM ro o
0 0 0 TH
o o o o
i i
CM n CD TH
CM CM CM M
O O O O
n n n o
+ n n -o
«• oo TH n
O O TH TH
OO O 0
1 t 1 1
00 <• CM CM
TH CM m »
0000
1 1 1 1
n o n o
TH TH CM
n
CM
TH O TH O
o o o o
o o o o
CM M CM CM
O O O O
0000
1 1 1 1
00 OK 0 0
n n n n
0 00 O
ro CM M »
CM CM CM CM
o o o o
OD ro n n
•o in oo o
n n n -a
i i i i
t -0 CO O
O O O TH
o n o- »
CM » n v
m mm m
<• -0 -0 
o o o o
n rs CM CM
-1 TH CM CM
o o o o
1 1 1 1
n -o n n
•o in TH ro
CM CM CMM
1 1 1 1
•o o * o>
0 TH TH TH
ro -H o o
TH CM ro »
•0 N -0 TH
» -0 10 -fl
oo CD oo rs
co n ro TH
o TH CM ro
i i i i
rs o o N
» n T «•
i i i i
«• -o o. CM
O O O TH
o o o o
ro o -o »
O O O TH
o o o o
OK » -CIS
CM ro ro to
o o o o
O TH O. 00
m «r * 
-------
 oo
 	i
 p-H
 O
 oo

 CD

 O
 •ZL
 
_i
en a
U)
M
a
m
Hi
u. *
a
z
3
ac
to
z 
m «• n -o
•O TH -0 H>
o TH •< (N
I I I i
to ro -o co
-0 O -0 N
1 TH TH (M
1 1 1
-at m v
o TH CM ro
o o o o
ro -0 ~0 03
-o oo TH in
O O TH -1
a> TH rs o
CM CM TH CM
o o o o
ro in o CN
-o » n TH
o o o o
1 1 1 1
rs o- in -o
o TH ro in
o o o o
1 1 1 1
v CN N in
O CM M  in
CM ro «r -o
o o o o
in co •« CD
*H TH CM ro
o o o o
in o. is -o
M 00 
O TH CM CM
o o o o
1 1 1 1
-i n CM -o
o o o TH
o o o o
1 1
in o m o
TH -< CM
CM
o o o o
O O 0 O
o o o o
o o o o
o o o o
in in -o ~o

o o o o
o o o o
1 t 1
-0 0- O TH
M IO «• ^~
o o o o
1 1 1 1
O. O O CM
CM n ~ O
iH »H TH *H
1 1 1 1
CM M M M
o o o o
-1 T -O CO
in -o oo CK
-o CM n f
t in in in
rH TH in i-l
^- •« co o
O O O *i
1 1 1 1
O CM -0 -H
rf rf rf CM
1 1 1 1
tn M o o* c-j *r
0 O -H TH
CN in CD CM
O O O TH
o o o o
1 1 1 1
CN -H -0 -1
O O O TH
o o o o
1
in o in o
TH TH CN
in
o o o o
O 0 O O
o o o o
o o o o
o o o o
*0 N IS N

o o o o
o o o o
1 1 1 1
co o- no
n in -o is
o o o o
i i i i
00 t CM 0>
is in o -H
ro TH TH o
i i i i
in o N to
o TH TH n
CD Is CD O
TH M -0 W
in CM o is
CD CM S) 0-
TH TH TH
•H tO CM CM
co oo -H in
to ^ >o rs
CD O IO CD
O CM f 00
1 1 1 1
CM O IS *
co o in -o
i TH n to
i i i
in CM CM to
O TH CM IO
o o o o
TH IS O* O
in -o CD CM
O O O -H
to CD 03 O
0 0 O 0
*o ^- co to
~o TH «r n
O O O TH
1 1
*0 CO &• "0
o -i to -o
o o o o
1 1 1 1
is -o ^- in
-H O CM CM
o o o o
1
in o in o
TH TH CN
-0
o o o o
o o o o
o o o o
o o o o
o o o o
in -o •« -o

o o o o
o o o o
in CM rs co
to ^- •» v
o o o o
1 1 1 1
.H .H  rs in
.H O O O
o o o o
1 1 1 I
in o in o
TH TH CM
03
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
in in -o -o

rj to to to
o o o o
03 .H O -0
.H 0 -H rt
o o o o
1
-0 n to rs
IS -0 » O-
rs Os TH TH
TH TH CM CN
1 1 1 1
o o in o-
TH CN fO fO
i- N «r oo
CM «r o- o
CM 0- 00 TH
TH -0 -H O
TH TH fN fO
O -0 O CN
-o in in CD
to i- in is
•0 0- IS -0
TH ro rs oo
i i i i
00 03 CN O
•H CN 10 -0
1 1 1 1
rs n to o
o TH CM 
-------
o
o
00


 I
CQ
1
in i
i
i
i
u. «• i
a >
Z 1
D 1
a i
ro i
" 1
1
LL 1
1
a CN i
:> i
_i i
a i
CO 1
en x i
a i
i
i
O 1
f
i
i
i
i
SO 1
1
Z 1
O 1
K- * 1
RCOLA
B
a. 03 i
i
Z 1
t-t t
i
a i
U 1
^ i
j i
en a> i
en i
M t
a i
i
dO 1
i
i
i
i
i
i
in i
i
i
i
u. o CK in o
1 1 -1 CN
i i
in o N oo
O x rH CN
oooo
IH co CK ro
oooo
CK CK >r ro
oooo
ro *o co **
~< m *c CK
TH TH X TH
in CN in rs
o ^ ™ «•
oooo
1 1 1 1
N 00 -0 O
X X 1 (N
OOOO
1 1 1 1
in o in o
X IK (N
O
OOOO
oooo
oooo
oooo
oooo
ro «f ^ iii
0- 0- 0- O
-H rt X CN
oooo
o- ^ in in
>o rs rs rs
oooo
1 1 1 1
rs T rs co
ro CK T in
CO N rs is
i i i i
in co -< in
0 0 « -i
o t oo is
TH rH « CN
00 O O CN
m rs co CK
rt CD rs -o
in rs CK o
incK-o -o
O O x (N
1 1 1 1
in >o rs in
ro r o- in
oooo
CN 0 x o
O O O rf
oooo
1 1
in o m o
oooo
oooo
oooo
oooo
oooo
CN ro ro ro
in in in in
oooo
oooo
O CD CK O
ro CN CN ro
oooo
1 1 1 1
ro T-I co -o
in rs N rs
in in in in
i i i i
ro 
i i i
ro * >o
ooo
ooo
ooo
0- CN CM
ooo
CD CK in
o
ooo
ro ro ro
x ro CM
N rs rs
•o en CM
O O -1
i i i
^ CN O
1 1 1
•T •« CO
OOO
ooo
ooo
M -1 O
ooo
to rs oo
ro ro ro
000
o o -<
ooo
1 1 1
x CM rs
ooo
ooo
1
o in o
X »-» CN
oooo
oooo
oooo
oooo
oooo
i
oooo
CM ~o rs -o
in in in in
oooo
III!
in CN rs o
rt CO CO O
ro CM N ro
i i i i
CN ro 
-------
O
o
00

 I
in
u. *
0
z
D
a.
n
tH
o.
SSQLVE
:i c
Q
o


n
z
o
M
h- t
RCOLA
B
0. «
Z
n
«
Ul
:>
-I
co n
(0
M
a
a
*!
u. <•
U. 1
o
z
o
n
M
Z
a M
1 T*
jmoss
a
o
REGION
AW t
o o o o
o o o o
o o o o
•1 M (M (N
O O O O
00 O 0
1 1 1 1
O O « M

o o o o
NX » «
CMM n n
oo o o
co is ^ m
no » in
rco o* -o
W n *0 IS
IH *H TH TH
(N M in 00
o o o o
o o o o
1 1 1 1
o o o o
*H vi «4 iH
oo o o
1 1 1 1
mo in o
•H •< (N
0-
H
O O O O
o o o o
o o o o
o o o o
o o o o
0000
1 1 1 1
i ** CM CM

o o o o
0- O M M
-I CM CM CM
O O O O
1 1 1 1
*r o- IT n
-0 * (N (M
is rs rs rs
«r in -o m
o o o o
0- -1 M -0

M M M rO
•H o in o
CK 0- 0 n
o
»•( 1-1 TH »*
o o o o
1 1 1 1
o oo o- in
n CM o o-
ix is rv •«
T *0 N 0-
o o o o
oo rf « rs

CM M M n
N (M >0 ID
fx CO 00 CO
» sO 0- M
O O 0 -1
1 1 1 1
in in t CM
i i i i
m ^ >o oo
o o o o
O O 0 O
O ^ M in
o o o o
CM CM Cv| CM
O O O O
oo *• co in
in -o -o rs
o o o o
CM 5T rs O
o o o -<
O O O 0
1 1 1 1
«»• n -i CM
o o o o
o o o o
1 1 1
n o in o
rt rt CM
*H
CM
O O O O
0 0 O O
O 0 O O
o o o o
o o o o
o o o o
nn n t

o o o o
If) »• CD 00
M M M ro
o o o o
till
in 1-1 o o
o rs oo o
-o in in *o
rf CM CM W
o o o o
03 O rt CM

n o~ M in
rH rt CM CM
-< m » >o
o o o o
1 1 1 1
IS -0 -0 N
O O O O
1 1 1 1
r-t -H CM M
O O O O
O O O 0
in in >o is
o o o o
-1 rf -. M
o o o o
-< * 0- O
o -i CM in
o -< -i «
TH CM n t
o o o o
o o o o
1 1 1 1
-o in » n
o o o o
0000
1 1 1 1
in o in o
-1 •< CM
CM
CM
0000
o o o o
o o o o
o o o o
o o o o
o o o o
M M « m
n n n t
o o o o
00 •-< CM CM
M o rs N
o o o o
o is -o in
CM CM CM CM
o o o o
1 1 1 1
o o CM n
M 00 O CM
oo rs co 03
CM n n t
o o o o
o CM «• in

— < TH 1-4 T-l
t^ V CO ^
-1 CM N n
CM t ~0 0-
o o o o
1 1 1 1
00 00 CC 0*
o o o o
1 1 1 1
** CM n «•
o o o o
o o o o
rv co o* o
o o o o
-1 -,-,-.
o o o o
r-i CM 00 M
a- rn CM *r
O -I -1 -<
-H M in rs
o o o o
o o o o
1 1 1 1
•O *• »H ^H
0 O O O
0 0 0 O
1 1 1
in o in o
« rf CM
»
CM
O O O O
o o o o
o o o o
o o o o
o o o o
0000
O r* n CM
in in in in
o o o o
CM t 111 CO
O O O O
o o o o
o M 
O O O O
1 1 1 1
-< o o- rs
-i -< O O
i i i i
-1 CM M in
o o o o
o o o o
CM * in N
o o o o
CM CM CM CM
O O O O
CM o- co rs
•o -o rs co
o o o o
« (N » -0
O O O O
O O 0 O
1 1 1 1
rs oo oo oo
O O 0 O
o o o o
1 1 1 1
in o in o
-« -1 CM
in
CM
-10^0
O O O 0
o o o o
o o o o
o o o o
o o o o
03 0- O O
n 1 1 T
o o o o
M CM n »
CM CM CM CM
O O O O
co M in m
-o in co o
in in in o
i i i i
«• •« co o
O O O -f
c<- n -o o
» O 0- CK
CM M CM N
-< in in M
00 00 00 CO
M -o o in
O O ^ ~!
i i i i
•0 IS. V «
«-l «-l 1H «H
1 1 1 1
CM T in rs
o o o o
o o o o
o ••< n -o
o o o o
CM CM CM CM
O O O O
r< CM -o GO
M ^ ^ ^~
o o o o
CM n -o ct-
o o o o
o o o o
1 1 1 1
CM * M CM
o o o o
1 1 1 1
in om o
rf -H CM
•0
CM
O O O O
O O O O
o o o o
«H iH *-l *H
o o o o
o o o o
-< T-l IN M
in in » «•
o o o o
in is CM CM
rf -1 CM CM
O O O O
1 1 1 1
in «o in in
-o in -I m
CM CM CM CM
i i i i
•0 O » 0-
O rf "i rf
rf -0 » N
CM n CM oo
*• v «• n
CM in in rs
0- 0- 00 -0
in o co oo
O -1 ** CM
i i i i
-1 O N M
CM CM *H -4
1 1 1 I
^ -0 0- N
O O O rf
O O O O
CM < 00 M
O O O O
CM M n M
o o o o
o- «r •« »
n M fn *•
o o o o
M in o •«
O O « -I
o o o o
1 1 1 1
n T CM rs
0 0 OO
1 1 1 1
in o in o
-< t CM
IS
CM
                                  263

-------
 00
 o
 oo
ce:
o
o
	I
0.

C.D
Z
i—i
o:


oo




CTl

 I
„



3
0 >0 GO 1*1
in » M n
in VH o -H
-0 I/) » M
CM CM CM CM
1 1 1 1
-< 0" >r o
n TH (N CM
CM CM CM CM
1 1 1 1
ao -< n in
•Q *e \n T
CM CM CM CM
in o in o
CM
~0 -O iH CM
•T CM -0 CM
CM * CD »
rs >o in in
in -< * rs
o- o- 03 rs
nm m m
i i i i
CM in o -o
-0 00 O O
(N CM n n
i i i i
oo o oo n
0. o 0- 0-
n t nm
in o in o
-H T-I CM
TH
CM
CM -O rH O
< T* in o-
00 O » 0-
•o -o in  n M
n o in o
n
«r TH in ro
n co in N
is -o -a -a
O TH TH O
in in in in
ro M ro ro
i i i i
o- in in ro
in oo o- TH
ro ro ro  o. in
ro CM TH o
o o o o
CM TH N HT
oo a) is rs
ro ro ro ro
in o in o
TH TH CM
ro
CM 00 CM -0
N oo ro 10
TH TH m o
-o in v r  03
CM CM CM CM
in o n o
«r
IS -H «f TH
TH rs  •« O
00 00 03 03
ro ro ro ro
in o in o
TH TH CM
t
03 00 &> CO
•O 0- 03 •«
in rs CM co
-o in in T
TH co is in
M TH TH TH
ro ro ro ro
I I i I
o- -o o to
o CM in -o
M ro ro ro
i i i i
ro in «r ro
CM CM CM CM
ro ro ro ro
in o in o
in
03  -o
•o oo -H in
o- TH rs ro
-o -o in in
O 00 IS -0
0- 00 00 03
ro ro ro ro
i i i i

-------
 oo
 o
 oo
 a

 a
 o
 o
 a:
 a.
 a:
 o
o
_i
Q.
a:
o_
oo
o
C\J
 i
ca
<:
in
u.*
|u
cc
n
rH
CL
a CM
SSOLVE
1 C
O
o

m
at
z
o
rH
1 <:
o
0
si
a
UJ
o o o o
oo o o
oo o o
Tin in m
oo o o
o o o o
1 1 1 1
-o -o N rs
rH rH rH rH
rH rH rH rH
O O O O
CM CM N CM
OO O 0
1 1 1 1
(Nin T CM
o o o o
in 03 T 00
OO -H CM
CM in TH »r
CMM -0 CM
rH
O CM -0 T
O- rH n -0
rH rH rH
M to T in
OO- O CM
T «r -o is
rs rH O O
O TH CM T
1 1 1 1
in oo «r is
n -o o T
rH rH CM CM
i i i i
•On -H rH
o rn CM n
o o o o
OTTO
M O M 00
o o o o
1 1
T 0- -0 Is
M CM CM CM
o o o o
o- o TH rs
IS O O- O
is co rs oo
in 03 o in
rH CM T in
o o o o
1 1 1 1
in rH 0- O
CM T T in
o o o o
in o in o
rH TH CM
TH
o o o o
O 0 0 O
O 0 O O
o o o o
o o o o
i i i i
MJ -0 N rv
CM CM O O
0-0-0-0-
0 0 0 O
T T in in
CM CM CM CM
o o o o
1 1 1 1
CM -0 T rH
O O O O
in CD CM oo
O O rH rH
CM T -0 0.
in n o-  1*1
T rv o- o
ho n ho T
rn -o in CM
in -a is oo
rH -0 CM 03
rH TH CM CM
1 1 1 1
o- n «r T
rv o- o -H
1 1 -H TH
i i
CM in rs o-
o o o o
o o o o
T in T O
CM rH O rH
o o o o
1 1 1
TH o oo rs
CM CM TH rH
o o o o
CM o in -o
T in n CM
o- rs «r n
o TH CM r*)
0 O O O
1 1 1 1
in rs co in
o o o o
in o in o
rH -H CM
in
o o o o •
o o o o
0000
1
CM CM CM CM
O O O O
o o o o
1 1 1 1
rs N is rs
O 0- 0- O-
rH O O O
-o r*i r*i T
o o o o
1 1 1 1
oo rs CM o
0 CD 0 CM
O O rH rH
O rH CM T
-o rH M rs
CM in o- -o
r*i o 03 -o
O T rs rH
rH rH rH CM
CM in 03 rH
o in o -c
T in rs oo
rs m in in
rH M -O rH
1 1 1 1
1
CM CD 0- 0-
TH CM T -0
CM M T in
1 1 1 1
-0 M rH CM
O rH CM l*>
O O O O
M in CM O
in r*) o T
o o o o
1 1 1
•0 T CM rH
r*i r*) T •HS
o o o o
T T rv (N
O- in rH CM
O- O rH CM
-o in CM in
TH M -0 0-
O 0 O 0
1 1 1 1
rH 00 rH rH
rH M T rH
O O O O
in o in o
rH rH CM
-0
o o o o
o o o o
o o o o
i
CM CJ CM CM
o o o o
o o o o
1 1 1 1
-o -o N rv
CM rH O 0-
o in o- o
IS IS IS 03
o o o o
1 1 1 1
-o in -o n
•0 CM 0 rH
o o o o
I 1
O rH rH CM
O 00 O CM
CM n -o o
rH
O IS M CM
rs 03 O rH
rH rH
O 03 M O
1*1 03 T 03
CM r 4 M r*i
1*1 -0 1*1 rH
TH CM T rs
1 1 1 1
0- M 0- 0-
TH -0 O T
rH rH CM CM
1 1 1 1
T o- in 1*1
O O rH CM
o o o o
T ro TH TH
o o o o
1 1 1
03 -0 03 T
o o o o
O- •« -0 CO
rs rs CD CD
rH I*) O TH
rH CM T -0
o o o o
1 1 1 1
rH rs rH 1*1
o TH r*i 1*1
0 O O O
in o in o
TH rH CM
rs
o o o o
o o o o
0000
rH rH rH rH
o o o o
0 0 0 O
1 1 1 1
M T T T
rs -o -o -o
0 O 0 0
CM 1*1 T T
in in in in
0 O O 0
1 1 1 1
rs CM n is
in in in -o
n r*i r*i M
i i i i
r*i in -o oo
o o o o
r*i o- T o
TH rH CM r*!
n -a oo o-
r*i r*i 1*1 1*1
TH CM o in
CM M T T
rH rH rH rH
o- TOO n
O TH rH CM
1 1 1 1
T n o in
IS 00 O- 0-
i i i i
CM T -0 00
O OO O
o o o o
O CM CM 0-
CM rH O O
O O O O
1 1 1
•o -o in in
CM CM CM CM
O O Q O
rH rH 0- 00
N rs m T
M r*i t*i m
rs pi o rs
O rH CM CM
o o o o
1 1 1 1
O T T 0-
.H O O O
O O O O
1 1
in o in o
rH rH CM
03
O O O O
o o o o
o o o o
1 1
r*i 1*1 ro ho
0000
o o o o
rs is rs rs
rH O O rH
o o o o
oo o- o- w
CM CM CM I*)
1 1 1 1
TH oo CM rs
m o «r in
in in in in
i i i i
rH hO CM O
TH CM T in
rH CM 03 -O
hO -O rH T
rH rH
T 03 O 0-
n co n o
rH rH CM M
TH rv in T
in o CM T
ro in -0 oo
is m T T
CM in o CM
1 1 rH TH
i i
o- is CM in
-o TH n T
CM T in rv
i i i i
-0 O- 1*1 T
O O rH CM
o o o o
rH rs in N
hO rH O T
o o o o
i i
-0 0- 03 rH
rs CM CM in
O rH CM M
O CM 00 T
0- -o T M
~o rs o- CM
rH
o in CM T
CM n in GO
o o o o
1 1 1 1
CO T rs T
rn N in CM
o o CM in
i i i i
in o in o
rH rH CM
0-
                                            265

-------
o
o
o
Csl
 I
CQ
 1 OO O O
_J 1
O 1
to i -o«r » CM
1 1 1 1 1
t
1 O-IS rs CM
O 1 -0 -0 -0 0*
I «•«• *r  i
_l 1 isn CM 0-
UJ A 1 *H ro -0 i-4
en i i i i -.
M 1 1
a i
i oo CM ro o
A 1 -0 W CO 0-
1 ,-4 CM CM CM
1 1 1 1 1
1
1
1
t -0 *-4 rs IS.
in i ox H CM
i oo o o
i
i
1 CM O- CM ^T
L. * 1 CMO •<  m -<
M 1 O O O rt
i
Z 1
i o- n in -4
o CM i m co oo o
:> i»»vin
_j t
a i
en i «r t>« » o
to ^ i »H CM *• rs
Q 1 O O O O
i i i i i
i
1 in CM -0 0-
o i o o ~ \ei
1 O O O O
ii ii
Z 1
o 3 i mono
1-4 « 1 -1 •« CM
O 1
U 1 O
K 1 **
O OO O
0 OO O
o o o o
r4 «H CM (M
o o o o
o o o o
in in -o -a
-o --c -o
o o o o
*• 10 •« rs
i i i i
» IS «T CO
o a> in »
i i i i
•0 O » *H
O rH -< CM
n r* -i »
rH CM rO *
O- M * CM
•O 00 0- O
«H
N con in
M -0 0- -i
•H 0- 0- CM
•-4 IH CM 
,-t r4 r-t *H
1 1 1 1
n oo n o
o o •< •*
o o o o
rs o M o
»n .-4 O CM
o o o o
1 1
in o. o CM
n n » »
O 0 O O
ro in o- ~o
in in n CM
M n n n
o oo oo n
T* iH CM »
o o o o
1 1 1 1
«• n -o CD
o rH CM n
o o o o
mono
rt -< CM
iH
r*
O O O O
O 0 OO
o o o o
TH r4 »-( O
0000
o o o o
i i i i
T o M
CM -H O O
0000
1 1 1
-< O 0- -0
o o o o
oo o» in o-
rs < -o n
M n ro M
*0 O *0 CM
o ^ 1-1 rv
o o o o
1 1 1 1
o *o to ^
O O ^ CM
0000
n o n o
^ ^ CM
CM
i-<
O O O O
o o o o
o o o o
o o o o
o o o o
o o o o
CM CM CM n
rs rs rs N
•0 -0 <0 *0
o o o o
n n in -o
in in in in
0000
1 1 1 1
0- CO 0- 0-
OD co rs -o
n n n n
i i i i
n -o m o-
o o o o
•H -0 0. CM
^ •-» *H (M
n co « n
n n » *
m N n CM
rs co o- o
OD M -O CO
O 1-1 *-4 rH
1 1 1 1
•O -0 T -<
«• n -o N
1 1 1 1
^ in rs o
o o o -H
o o o o
oo t n t
O O O TH
o o o o
i i
CD 03 N n
0000
*H ** *r «o
O O 0> CO
rxi CM IH ^
>o ch in ^
O O ~«M
o o o o
1 1 1 1
o n oat
0 0 « rt
o o o o
1
mono
^ *s CM f
M
O O O O
o o o o
o oo o
o o o o
o o o o
o o o o
1 1 1 1

» in in in
o o o o
1 1 1 1
M CM -0 in
o o- rs m
IT) » » ^1
till
n rs co o
o o o -i
CM •« o n
•H -1 CM CM
-o o- »n n
n n v »
•0*0-0
rs oo o> o-
o- M rs o
O rt rt CM
1 1 1 1
o- rs «r o
» n -o rs
i i i i
M n oo o
O O O rf
o o o o
»* -0 CM 0-
«H O O O
o o o o
1 1
CM M CM rt
CM CM (M n
O O O O
CM in o ro
-1 .H O O
CM CM CM CM
in o -a CM
O r-l rt (N
o o o o
1 1 1 1
N CM 0- rs
0 O O -<
o o o o
1
n o n o
•H ^ CM
<•
O O O O
o o o o
o o oo
O H l-t iH
O O O 0
o o o o
O "I -< (M
oa rs -o -o
M3 -0 -0 -0
o o o o
•0 CO IH W
n in -o -o
o o o o
i i i i
» CM rs co
rs in CM **
m « n n
i i i i
in rs o- ^
OOO-i
* in o »
CM M M CM
M n M P3
o * » n
•O -0 -0 <
03 (M -0 O
O iH ••« CM
1 1 1 1
r n
CM CM CM CM
o o o o
co ro ro o-
03 0- 0- CO
n o- n oo
o o •« ~
o o o o
1 1 1 1
r< -a CM o-
o o -i ~
o o o o
in o n o
1-4 TM CM
in
1-1
0 0 O O
0000
o o o o
M CM (M CM
O O O O
o o o o
1 1 1 1

-------
O
o
o
CM
 I
CQ
n

b. «r
o
z
D
OC
n
CL
Q CM
SSOLVE
1 C
a
0

a
z
o
M
RCOLA
! B
O.CD
Z
M
Q
UJ
CO A
to
a
n
to

u. «•
o
z
3
n
i-i
z
Q CM
SSOLVE
\l C
o
o
REGION
AU A
OOOO
oooo
oooo
oooo
oooo
i i i i
«H «-* *<4 CM
•HO O 0-
Ps Ps N -0
OOOO
03-0 V T
*H -4 TH *-<
OOOO
1 1 1 1
o rs M] n
•ook CM m
00 CO Ok Ok
1 1 1 1
•r in M) ps
oooo
* t -0 0-
^ n » in
MM tO M
oo * o in
rs 00 O Ok
03 CM * Ps
O -< r4  O
co n -a o
O rt *•« CM
i i i i
oo rs »r ^
» in -o PS
i i i i
CM in rs o-
oooo
oooo
•H TH O O
oooo
1 1 1
•o -om in
CM CM CM CM
oooo
rs o in o
O O Ok Ok
n to CN CM
in o MJ CM
O -1 -< CM
oooo
1 1 1 1
•H -e ro Ok
O 0 -c -c
oooo
1
n o in o
rf « CM
o
CM
oooo
oooo
oooo
oooo
oooo
1 1 1 1
r* rt O Ok
N rs rs -o
oooo
o o CM ro
T T » »
OOOO
1 1 1 1
co in o oo
O O 0- Ps
< v ro ro
i i i i
in rs oo o
o o o *•<
n -0 O in
•* •* CM CM
ro «r in -o
o » rs o
ps PS rs oo
00 CM Ps rf
0 -i -* CM
1 1 1 1
Ok CM ^ rs
n 1 1 1
i i i i
ro in rs Ok
oooo
oooo
-< o o o
oooo
i i i
•o -a in in
CM CM CM CM
oooo
Ok o rs in
^ ^ ro r*i
CM CM CM CM
in Ok <• Ok
O O o rs
i i i i
rt CM ro *
oooo
oooo
CM CM M ^
oooo
1 1 1 1
ro 
-------
 co
 o
 CO
o:
LU
LL.
o:
o
o
	I
D_

C3
•z.
\—I



oo
CO
 I
in

U. fl-
o
2
CC
M
0.
Q CN
SSOLVf
:i c
Q
O

01
z
o
eRCOLAT
3 B4
Cu CD
Z
t-l
CQ
U
cn A
en
a
on

li. «
O
Z
D
n
z
a CM
SSOLVE
il ;
Q
0
Z
0 3
O
Ul
a
o o o o
o o o o
oo o o
o o o o
oo o o
~o ~o rs is

o o o o
o o o o
1 1 1 1
O 0 O O
n CN CM CN
oo o o
1 1 1 1
CM in «r N
0000
in co * CM 
o o o o
TH .H N tO
-0 00 0- O
n CM CN n
in rs ro -o
-o rs CD rs
o o-
TH — 1 — 1 — 1
1 1 1 1
•H n in is
o o o o
o o o o
o n rs .H
o o o o
CM CM TH rt
O O O O
o TH ro -»•
o o o o
1
CM in oo n
O O O TH
o o o o
i i i i
TH n oo -o
O O O -H
o o o o
1
in o in o
in
o o o o'
O O 0 O
O O 0 O
1
o o o o
o o o o

o o o o
o o o o
1 1 1 1
-o rs rs rs
o o o o
1 1 1 1
oo rs CM o
O CO O CM
O O -I *
••0 CM CM TH
o -H CM •»•
CN T 03 -0
o- oo rs •*
03 CM -0 O
TH TH CN
•o TH m rs
o- o n rs
o- in in CD
o CM in o
i i i -i
rs TH CM ro
oo rs rs 03
l -i CM ro
i l i
in -i o o
O TH CN M
o o o o
^- o- o- -i
O O O -H
ro ro ? °
0 O O 0
in rs o* -i
M CM O TH
O O TH CM
1
rs o- oo in
o -i n -o
o o o o
1 1 1 1
-i oo o o
o -H n CN
o o o o
1
in o in o
•0
o o o o
o o o o
o o o o
1
o o o o
o o o o

o o o o
o o o o
o in o- o
rs rs rs 03
o o o o
i i i i
•o in ~o ro
•4 CN O TH
o o o o
1 1
in TH N o*
O -H TH CN
•H ro in o>
-i rs in o rs rs >o
l i i i
TH n T -o
o o o o
0 0 0 O
 ro
O O -H CM
o o o o
O O » T
CN TH 0 CN
O O O O
rs CM -H T
O TH CN M
.H N o in
o rs in n
CM «T 03 fN
0- -H O O
O CN -T fs
o o o o
1 1 1 1
O 0- "0 CO
CM -T N O
O O -H T
1 1 1 1
mono
o*
                                              268

-------
O
o
C\J
 I
CO
 1 OO OO
_J 1
O 1
U) 1 -0«r 1-CM
1 1 1 1 1
1 0-rs fsCM
O 1 -0-0 -00-
1 • Hf«r
1 1 1 1 1
1
1
1 00-0 OOCM
a> i o « run
i
Z 1
a i
M | 000 O-tO
 i
_J 1 0- -0 CMO-
uim i ON no
Ul 1 1 1 1 «1
M 1 1
a i
i  i o rn CMIO
_i i
O 1
ai i -o * OD r)
01 -i i o » CM n
a i oo oo
i i i i i
i o -o n o
O 1 rH 0 ON
1 O O O O
i i i i i
03 i mono
M « 1 rH .H CM
C9 1
Ul 1 0
Ct 1 rH
o o o o
o o o o
o o o o
o o o o
o o o o
iii n -o -o
n n n n
o o o o
o o o o
«r n -o N
i i i i
«l- IS* 00
o oo n «t
1 1 1 1
-0 0- «T rH
O O rH CM
CM 00 «T O
rH rH CM «T
0 CM CM CM
•O Is 03 0-
is n rn -i
n oo o o
n CM CM -o
O rHCM (0
i i i i
is oo o -o
ro «r -o rs
i i i i
•r rs •-< N
O O rH rH
o o o o
CM -0 CM 00
CM CM n M
O O O O
-0 O rH CM
O O O O
CM oo in o-
O O CM T
o o o o
«t oo n -o
O O ^ CM
o o o o
1 1 1 1
n CM CM oo
O O rH IN
o o o o
1
n o n o
n X CM
T-4
T-l
O O O O
o o o o
o o o o
o o o o
0000
fl- fl- «r  ^
1 1 1 1
X CM « M
CM CM CM CM
1 1 1 1
CM » -0 05
O O O O
o o o o
o- rf v rs
* CM (N CM
O O O O
n o o- -o
O 0 0 0
»H IN CM -0
* O O O
o o o o
i i i
M n oo CM
o o o -i
o o o o
1 1 1 1
CM H in CM
o o o -<
o o o o
1
mono
rf .H CM
CM
iH
o o o o
o o o o
o o o o
o o o o
o o o o
rM (N n n
-0-0-0-0
^ *-« rH ^
O O O O
n n IIT -o
in n in in
o o o o
1 1 1 1
0- 00 0- 0-
oo 03 rs -o
M ro n ro
i i i i
v -o rs o-
o o o o
o- M n oo
»< to in N
nn nn
oca f to
o- o- o o
» rs o to ,
O O - in CM r<
n n ro n
i i i i
LO IS 0- ^
O O 0 n
o- n -o -"
0- O 0- 03
CM M CM OJ
0- CM CM IS
-0 IS N -0
T N rt in
O O -H •-<
1 1 1 1
T n o -o
i i i i
M t -0 0-
o o o o
o o o o
i-l 10 -0 0-
o o o o
n fl- 
-------
O
o
in

k. «•
0
z
3
a.
n
(-1
a.
a CN
SSOLVE
:i c
a
o

0)
z
o
M
1- *•
:RCOLA
i B
a. a
z
M
a
Ul
>
_j
a) co
10
n
a
»
in
U. f
li. «
O
Z
=)
QC
n
M
Z
a CM
SSOLUE
11 <•
a
o
REGION
AU *
o o o o
0000
o o o o
oo o o
o o o o
i i i i
*H 1H rH CM
in -o a> oo
CNCM CN CM
O O O O
oo -o *•  n 
*H
§000
o o o
0 OO 0
o o o o
o o o o
CM CM CM PO
CM CM CM CM
O O O O
W ro in ~o
in n in in
o o o o
1 1 1 1
o- oo oo n
in ^ CM CM
n nn n
i i i i
» •« fs 0>
0000
OK ro in o-
O «H T-l T-t
o CM » m
M M N M
n »< rs r>
OK OO O
««• N i in
O O -< rt
i i i i
•0 IS -0 -0
i i i i
CM * -0 CD
O O O O
o o o o
» NJ 0. rl
O o O O
•o  rs
» v n m
i i i i
V -0 
o o o o
•o in in »
CM CM (M CM
O O O O
OD M N CM
CM n n v
o o o o
n in oo rt
o o o -H
o o o o
1 1 1 1
CM -< in o
o o o -H
O 0 O 0
1
mono
1 « CM
1-4
CM
O O O O
o o o o
0 0 O O
o o o o
o o o o
mn t *
in in in -o
o o o o
0000
-o o- o- o
•0 -0 -0 N
o o o o
i i i i
-0 0- T CM
CM O- O -1
CM "  » -o
CM CM (N CM
O O O O
» in in «•
CM CM CM CM
o o o o
ao is in in
IH IN n *
o o o o
»n CM « in
o o o o
0000
1 1 1 1
-oin » o
o o o o
o o o o
1 1 1 1
in o in o
- ^ CM
(M
CM
O O O O
o o o o
o o o o
o o o o
o oo o
CM CM n M
0- 0- 0- 0>
o o o o
o o o o
CO -1 CM CM
* in in in
o oo o
1 1 1 1
O * "H O
CD -O IS 00
CM CM CM CM
1 1 1 1
CN CM M M
O O O O
o -H CM ro
0- 0- 0- 0-
o o o o
•0 030- 0
03 00 00 O-
CM T in rs
o o o o
1 1 1 1
fO CM rH r<
o o o o
1 1 1 1
O -< CM CM
o o o o
o o o o
fs 00 0- O
r< rH rt CM
O O O O
ro ro CM N
r* TH T* .H
O O O O
» O -0 CM
ro » T in
o o o o
rf CM ro *
o o o o
o o o o
1 1 1 1
(M rt CM »
O O O O
o o o o
1 1
in o in o
** *-* CM
to
CM
O O O O
0000
o o o o
o o o o
o o o o
ro ro T T
tx N CO 00
o o o o
o o o o
rs ro * T
in -o -o -o
o o o o
i t i i
CM T 10 *
o in -o oo
T ro ro ro
i i i i
CM ro t  o ro
r< CN ro ro
M in N o
o o o •<
1 1 1 1
ao oo oo oo
o o o o
till
O -" CM 10
o o o o
o o o o
1
CM ^ ^0 CO
CM CM CM M
O O O O
rs oo N rs
CM CM CM CN
o o o o
rs in * «r
CM ro ^ in
o o o o
•H ro in rs
o o o o
o o o o
1 1 1 1
0> -0 CM CN
O O O O
o o o o
i i i
in o in o
* rt CM
*•
CM
O O O O
O O O O
O O O O
o o o o
o o o o
-1 CM CM CM
rs fs rs rs
o o o o
o o o o
CM O O CO
tn in in  O CO -0
-< -< o o
i i i i
o rt CN «r
o o o o
0000
•0 00 O CN
-1 ^ M (N
O O O O
«r in -o rs
n ro ro ro
o o o o
o- ro o. rs
•H CM CM ro
0000
^ ro in rs
o o o o
o o o o
1 1 1 1
•o M) in ro
o o o o
o o o o
1 1 1 1
in o in o
•4 rt (N
in
CM
o o o o
o o o o
o o o o
o o o o
o o o o
O -H r4 (N
00 0- 0- 0-
o o o o
o o o o
fo 4- ^ ro
(N CN CM CN
0 OO O
1 1 1 1
O O » -H
in «• in oo
o o o o
*H «M *H «H
1 1 1 1
» -o aj o
O O O *i
o- ro rs rt
r> o CK OD
CM ro CM CM
CM •« n H
00 00 00 00
» rs H rs
O O l-< rl
i i i i
N >o ro o*
— rf rt O
1 1 1 1
CN ro m rs
o o o o
o o o o
•H ro * N
0 O O O
CM » -o rs
ro ro to n
O O O 0
CN 000 -0
CN ro ro *
o o o o
CN «r N O
o o o ^
o o o o
1 1 1 1
O O N »
rt -10 0
o o o o
1 1 1 1
in o in o
rf -H CM
•0
CN
0000
o o o o
O 0 0 O
o o o o
o o o o
ro n v v
oo m is N
0000
o o o o
*-t o -a N
o o o o
1 1 1 1
o o in rs
ro ^ -o -o
rs rs MJ MJ
i i i i
-0 -H ~0 CN
O rf -< (N
CM CO O* T
CM CM O T
«• «r «r ro
» » O -0
o o- oo in
in n CM in
o -< CM ro
i i i i
>H co 0
0000
o o o o
1 1 1
in o in o
-H •« CM
rs
CM
                               270

-------
 oo
 _i
 >—i
 o


 a



 03
>-
•=c
oo
=1
o
Ovl

C\J
 I
CQ
s
n



>' REGION AU 1



REGION AU (
(M -0 O -0
o- mm n
n -o CM o
in «r CM in
•H O 0- 0»
M M (M CM
i i i i
iv -H rvin
•H r -o CM o
o- CM M co
CM CM -1 O
M M n m
i i i i
n in CM »
* 00 O O
•O -fl IV IV
i i i i
in * 03 o
n » 4- in
n MM n
in o in o
•H ,1 CM
r\
*4
0- 0- N M
N N IS •»
IV IV CM 0-
» W M CM
IN M W CD
w M -H o
CM CM CM CM
1 1 1 1
N -0 <0 0>
M M CM O
n n in in
till
o- w OK CM
•« -o w w
M N N O(
mono
»H *-l 04
N
<«• 
*H
M -0 CO 0-
CO IV O CO
» M 00 *•
in » ro M
to •< * in
03 rv in *
(N (N (N (M
1 1 1 1
N O O -0
-< in iv -o
-o-o-o-o
i i i i
in » -o »
0-000
tM M M M
in o in o
* 1 N
»
» M -0 CM
«H rt 0- M
CO CM 0- 0-
in M -o »
M M M M
1 1 1 1
-o -o * to
•0 0 
«r in iv rt
» T t t
1 1 1 1
«f  rv o
oo -H iv in
•T in co n
in -o -o -o
m mm n
i i i i
in -- oo »
t>- «r -o rv
-0 N N IV
1 1 1 1
co iv o- in
in iv oo o-
m m m m
in o in o
rf -H M
in
CM
T in o- --r
CM -o in -H
-< CM CO -0
-o in t 
-------
 o
 oo
 O
  A

 CQ
o
1—I
I—
<
a:
o_
oo
oo

o
ro
C\J
 i
CO

J
tn a
co
n
Q
(0
IT)

u.  00 05
rf O O O
1 1 1 1
o o- in n
-I ti CM M
i-f rs co o-
*r rs o* CM
TH
T rs M n
-<  r-» tO 111
o IN ro fl-
o o o o
! 1 1 1
CD -0 -0 0-
V ID N 0*
O O O O
1 1 1 1
mono
*H
O O O O
o o o o
o o o o
1 1 !
H iH
o o o o
1 1 1 1
TH o- M n
TJ o o o
o o o o
i i
co n -a o
o •* ** CM
ro in rs o-
is -o n n
in -o rs rs
r-4 n o- o
-o o n  -o o
n ro M in
*H »-f »H 1-1
ro co «• o~
o o -i -*
o o o o
1 1 1 1
in o o- M
v in » iii
o o o o
1 1 1 1
in o m o
«r
o o o o
0 0 O 0
o o o o
ro *r *r ^r
o o o o
o o o o
in -o o -o
v 03 iii rs
ro f j rj rj
o o o o
r o ri
o o o o
o o o o
1 1 1
111 O 111 O
in
o o o o
O 0 O 0
o o o o
rj ^ o in
o o o o
o o o o
I 1 1 1
-o ~o is rs
n ^- *r o*
^H O 0* 0-
rf rf O O
iii ri ^ ro
o o o o
0 O O O
t
«T 03 CM 0
111 -i O 111
ri ri n -<
1 ! 1 1
n o- t iii
*-< rj 1*1 rn
^j M
n rs o co
rj 03 -o »-•
•i n n n
o 
-0 111 -0 0
o *H ri  i i i
n o •*• ro
-0 0- M HI
0 O -I •-<
1 1 1 1
iii o in o
fs
O O O O
0000
o o o o
TH rf O O
0 O O O
o o o o
1 1 1 1
rj ro M *^
 i i
•T ~0 ^ 03
O O O O
o  o- o-
O 0 0 O
T *o r** -si
0 C O O
o o o o
rv u") fl- -o
o n ro rj
hi n r*i ^
! I i 1
T ^ a) o
o o o o
o rj ro LI
O TH ^ -t
ro r» n n
h O 00 -0
CK O i> 0-

-------
O
o
CVJ
 i
CO
in

u. v
o
z
D;
ro
a.
SSOL^E
:i c
o
o
(J

2
O
H
ERC3LA
3 B
2
M
_ 01
UJ
en aa
to
o
o
a
in
u. v CN o
CN CN CN O
111 N CO CN
o o o o
i i i i
co rj -o o-
i < i i
o c o o
o o o o
CN in o 
o o o o
o o o o
i i i '
O O O 0
1 1 1 1
in o in o
CO
o o o o
o o o o
0 O O O
o o o o
o o o o
I'll
^ n 0- O
rv TV -o rv
o o o o
•o rv rv co
0 O O O
o o o o
rt o in 03
r-1 fl TH ri
lilt
O O O O
co o ri ro
O -H -1 *H
t in r- CD
ro r*i ro ro
CN -0 *H CN
rv rs fv -o
-0 CN O O
00-i-<
i i i i
o n -o ro
i i i i
o o o o
o o o o
IV rH -fl 0-
O -i ^ -i
o o o o
n -o co ^
rj n n ro
0 0 0 O
co in IIT co
rj fi n ri
o o o o
0 0 0 rf
0 O O O
iiit
o -i * rv
o o o o
1 1 1 1
111 O 111 O
CN
o o o o
0 0 0 O
o o o o
o o o o
o o o o
CD ri n CN
111 111 111 T
O 0 O O
ro fl- iii tii
O 0 O O
o o o o
1 1 1 1
 -< ^
rv CN o- CN
CN O O CN
03 0- CN CO
o o o o
1 1 1 1
o to iii in
iiit
O O O 0
o o o o
CN V CO ri
O — ri ri
o o o o
CO 03 0- 0-
o o o o
o o o o
•* i-t «r ri
O O O 0
(N in rv co
o o o o
o o o o
i i i i
o o rj r-i
o o o o
I i i i
in o in o
n
o o o o
o o o o
o o o o
o o o o
o o o o
^ 0- CO CN
CI t-< T-( -rH
o o o o
r-i rj n n
o o o o
i i i i
rl -1 r-l ri
till
rJ ro ro to
o o o o
CO CN CN CN
o o o o
n to ro to
 o n n
03 0- O n
n^n
OD 0} CO 00
If) CD O  in TI o
O C 0 -H
O 0 O O
1 1 t 1
•H n o n
n CJ ri n
o o o o
i i i i
IP O 1*1 O
in
n
o o o o
o o o o
o o o o
O 0 0 0
i i i \
CD O C O
0 0 -••« -»
0000
0) 0 O rH
o o — *-»
o o o o
in  '
0000
o o o o
•O > *T 01
o o o o
O f O r-
f-i r M" * r j
O O <"> O
t ) IjT -* 0-
f: n «r T
o c o
M Id QD «--
c o o -H
O 0 0 O
1 1 1 1
T .-» M «r
rj n ro M
o o o o
i i i i
IT O IT O
•0
rj
                                       273

-------



^^
_J
t— i
O
CO
o
0
00
z:
0
HH
1—
1— 1
1 —
LiJ
U_
£
„
>-
re
CO
o
CONTINl
^
I
*— <
LiJ
CO
K



n

u. »
o
z
0.
0 ft
SSOLVE
:i (
o
o

0)
z
o
IRCOLA1
5 B-
a. 
u
en «
CO
a>
n

a
z
cc
ro
M
Z
a (N
O
CO
 in to
.< .< ft ro
^ 1-1 o* rs
ro *o co CM
«H
n o- co co
o to -o co
ro a) in -o
03 0- 111 0-
n rs -o is
till
0- >0 111 fO
o* ^ o* ro
i .-< ^ ri
i i i
rs  o- fs n
in o n o-
O  ft in
O O TH rt
•* -a «• o
co ro *o co
to V fl" 
o o o o
03 O ft IS
ft to to n
O 0 0 0
r-l -0 0- O
ft ft ft ro
o o o o
^4 ro to ft
03  o ro
** rt ri ft
o o o o
111 111 111 -0
o o o o
o o o o
rs ** rs *r
ft rs o ft
rj v m fs
o o o o
o o o o
IIII
o ^ to *
o o o o
o o o o
1
in o in o
n
o o o o
o o o o
o o o o
o o o o
o o o o
1 1

o o ^ «
o o o o
111 ft ^ IO
o o o o
o o o o
1
* 03 ft -0
iii ^ o in
ft ft ft rf
IIII
ft o iii in
-i ft to ro
-o fs  -o is
ft in 03 o
^ ~o rs fs
rs 03 o- ft
ri rt M it
is ft iii r>
ft Hi iii iii
iiii
0* •*  ro o to
ft ro to T
O 0 O 0
O 03 O CO

<* ft ft ft
in fs co co
ft ri ft ri
to v o- -<
 CO O
rs -i v is
O -< -> —
ft M 111 -0
o o o o
0000
IIII
-i to ro iii
o o o o
IIII
in o n o
03
0000
o o o o
o o o o
o o o o
o o o o
IIII
rH ft ft ft

ft ft to to
o o o o
•t -a rs o
o o o o
o o o o
is in 
-------









h-
0
o
*±
CM

i — i
i — i
i— i
ciT
LU
	 1
CO
<






in

-»
RUNOFF
3 (
<_J
z
0-
CM
UJ
>
_l
to .—
Q
O
LA
O
1—
< -3-
_J CD
O
2
UJ
CO
z
CO
LkJ
>
_J
to co
CO
o
o
CO

t*
o
z
K <
z
2 <-i
<
0
UJ
>
_l
O CM
I/)
O
o
25
o
UJ
a:
o o o o
0 O O O
o o o o
O 0 O O
o o o o
1 1 1 1
CO O O O
<~ CM CM CM
o o o o
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1
_3- LA vO \O
o o o o
\o — r-. r-*
— CM CM CM
oo • — a- -3-
en -3- -3- -3-
LA en o CM
LA \D OO CO
— — — CM
o o o o

en u\ r-.co
o o o o
o o o o
en en LA csl
o o o o
\D LA CO CM
_ _ _ oj
o o o o
en LA r--. en
\D O — en
— CM CM CM
_ _ o —
o o — o
o o o o
en rn-3- -3-
o o o o
o o o o
LA O LA O
— .— fM
M>
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
CO CM LA LA
CM m en fvj
O 0 O O
o o o o
o o o o
1 1 1 1
CM m m-3-
CM CM CM CM
1 1 1 1
en en -3- .3-
o o o o
-3- en o —
— CM en-31
CM CM CM CM
oo en p-. CM
rn-3- LAvO
m -3" LA \O
o o o o
1111

1 1 1 1
CM m -3- LA
o o o o
o o o o
\r> r-*. r--. .
CM m -a- -3-
CM CM CM CM
CM vO O r*"i
00^^
r^\j- LA\O
o o o o
1111

1 1 1 1
rsi c^v -T LA
o o o o
o o o o
en o o o
o o o o
LA r*-* en •—
— — — CM
o o o o
LA CM vO CO
 CM -4- v£i
o — — —
CM f*-\ -3- LA
o o o o
o o o o
1 1 1 1
oo co en  en
CM CM CM CM
o o o o
_S- LA CM OO
CT\ CM -3- MD
o — — —
CM -3" \D OO
o o o o
o o o o
1 1 1 1
CM -y LA\£>
o o o o
1 I 1 1
LA
 VO
o o o o
o o o o
1 1 1 1
IA O LA O
— — CM
CM
CM
o o o o
0 O O O
o o o o
o o o o
o o o o
(V\ J- LA LA
o o o o
_ — — —
o o o o
lilt
CM \D -3" LA
1 1 1 1
CM CM CM CM
o o o o
o m-a- ^r
cr\ ^ en en
o o o o
en — — —
oo en 
o — — —
) V 1 1
-3- CM O ^
CM CM CM —
en -3- -*O OO
o o o o
o o o o
o o o o
— CM CM CM
o o o o
— o co r-.
CM -3- LAUD
o o o o
CM "en \o CO
o o o o
o o o o
1 1 1 1
r- o o o
— CM CM CM
o o o o
1 t 1 1
LAO ^ 0
^ — CM
vO
CM
275

-------
             TABLE  A(III)-25.   SOYBEANS,  NO  TILLAGE  (A,B,C,D SOILS)
Region AW   A
B
A'
Region AW   A
A1
Region AW
B
A1
  1      5  2.23 -5.16  -2.17  33.94
       10  2.13 -4.99  -2.02  47.04
       15  2.03 -4.79  -1.87  32.04
       20  1.92 -4.52  -1.76  25.19

  2     5  3.01 -6.09  -2.83  60.09
       10  2.93 -5.96  -2.83  49.74
       15  2.84 -5.82  -2.70  42.08
       20  2.74 -5.56  -2.59  36.28

  3     5  3.88 -6.81  -3.87  74.88
       10  3.91 -7.02  -3.87  64.33
       15  3.89 -7.01  -3.89  66.04
       20  3.87 -7.04  -3.86  63.28

  4     5  3.36 -6.99  -3.33  66.36
       10  3.38 -7.19  -3.28  56.86
       15  3.32 -7.15  -3.16  50.04
       20  3.26 -7.11  -3.13  44.82

  5     5  3.56 -6.93  -3.54  69.50
       10  3.58 -7.05  -3.51  61.74
       15  3.55 -7.06  -3.44  56.40
       20  3.52 -7.02  -3.44  51.93

  6     5  2.10 -4.70  -2.00  48.79
       10  2.01 -4.69  -1.75  34.62
       15  1.90 -4.49  -1.54  25.75
       20  1.79 -4.25  -1.41  19.11

  7     5  2.68 -5.70  -2.61  57.56
       10  2.70 -5.91  -2.47  44.34
       15  2.63 -5.91  -2.24  35.40
       20  2.56 -5.78  -2.05  28.30

  8     5  3.65 -6.96  -3.61  71.26
       10  3.70 -7.21  -3.61  63.29
       15  3.70 -7.28  -3.56  57.78
       20  3.67 -7.35  -3.53  53.54
                    9     5  2.36 -4.86 -2.27 52.44     U    5
                        10  2.20 -4.61 -1.99 37.07          10
                        15  2.10 -4.48 -1.81 26.98          15
                        20  1.99 -4.31 -1.57 19.42          20

                   10     5  2.94 -5.64 -2.89 63.31     18    5
                        10  2.85 -5.48 -2.68 49.85          10
                        15  2.73 -5.29 -2.54 39.90          15
                        20  2.63 -5.13 -2.41 31.77          20

                   11     5  3.51 -6.79 -3.47 71.71     19    5
                        10  3.43 -6.69 -3.32 60.40          10
                        15  3.38 -6.69 -3.21 52.05          15
                        20  3.30 -6.62 -3.09 44.97          20

                   12     5  3.88 -7.21 -3.86 75.74     20    5
                        10  3.91 -7.39 -3.85 67.97          10
                        15  3.93 -7.49 -3.82 62.32          15
                        20  3.89 -7.56 -3.76 57.48          20

                   13     5  4.49 -6.97 -4.47 80.28     21    5
                        10  4.46 -7.95 -4.37 72.43          10
                        15  4.44 -7.06 -4.30 66.64          15
                        20  4.41 -7.13 -4.19 61.46          20

                   14     5  4.47 -7.06 -4.45 79.44     25    5
                        10  4.45 -7.13 -4.38 72.04          10
                        15  4.40 -7.14 -4.30 66.25          15
                        20  4.35 -7.24 -4.23 61.43          20

                   15     5  4.57 -6.65 -4.56 78.53     26    5
                        10  4.58 -6.90 -4.56 71.79          10
                        15  4.57 -7.04 -4.55 67.00          15
                        20  4.55 -7.04 -4.53 63.03          20

                   16     5  3.55 -6.72 -3.53 72.58     27    5
                        10  3.52 -6.85 -3.45 65.22          10
                        15  3.48 -6.79 -3.37 59.71          15
                        20  3.45 -6.81 -3.36 55.67          20
                                                           3.72 -7.26 -3.71  74.36
                                                           3.74 -7.46 -3.68  67.41
                                                           3.70 -7.42 -3.63  62.35
                                                           3.67 -7.40 -3.59  57.94

                                                           4.25 -7.91 -4.24  79.99
                                                           4.24 -8.03 -4.20  73.49
                                                           4.18 -7.97 -4.13  68.62
                                                           4.14 -7.97 -4.09  64.52

                                                           4.06 -7.49 -4.03  76.32
                                                           4.07 -7.65 -3.99  69.41
                                                           4.02 -7.61 -3.91  64.24
                                                           3.97 -7.62 -3.86  59.96

                                                           4.21 -7.47 -4.20  78.42
                                                           4.20 -7.56 -4.15  70.96
                                                           4.17 -7.60 -4.10  65.22
                                                           4.12 -7.62 -4.02  60.24

                                                           4.49 -7.27 -4;47  90.01
                                                           4.49 -7.40 -4.45  72.83
                                                           4.47 -7.46 -4.41  67.41
                                                           4.41 -7.45 -4.36  62.74

                                                           4.08 -7.92 -4.06  78.11
                                                           4.13 -8.04 -4.07  70.54
                                                           4.13 -8.07 -4.06  65.37
                                                           4.11 -8.04 -4.00  61.12

                                                           4.03 -6.66 -4.02  74.75
                                                           4.08 -6.90 -4.05  67.48
                                                           4.10 -7.07 -4.09  63.14
                                                           4.10 -7.07 -4.08  59.55

                                                           3.97 -6.68 -3.96  71.65
                                                           4.01 -6.94 -4.00  63.99
                                                           4.03 -7.21 -4.03  58.88
                                                           4.03 -7.30 -4.01  54.75
                                                  276

-------
c
o
C\j
CQ
in

LL ^T
o
z;
a
K
ro
LL
C. CJ
_i
o
en
en '-f
Q
0

a,
2:
o
i~i
K- 
_J
CO 1X1
01
t-H
Q
CD
in

U. 1
0
"Z.
Z3
ro
-z.
a r-j
SSOLVE
U f
Q
O
1
2
0 3
CD
UJ
cc
o o o o
0 O O O
O O O 0
O 0 0 O
o o o o
•o rx rx N
«H 03 rx O-
rx in  o ix
o o n n
O 0 0 O
1 1 1 I
UT O U") O
n
o o o o
O O O 0
o o o o
0 O O 0
o o o o
in -o *o -o
co n ~H N
rj rj rj T-I
o o o o
ro IJT LIT o
O 0 0 0
1 1 1 1
til *T rn r-
o co CD N
o o o o
1 1 1 I
O O O 0
o i-» rj u
*T in \n -o
-o in ro T-I
0 0 O O
rj ro M o
o o o o
o o o o
III!
ro IH o rj
0 0 O O
0000
1 1
LI") o in o
M
O O O O
O O 0 0
o o o o
O 0 0 0
0 0 O O
 
n rj rj rt
r-j ro -i rx
,-t TH TH O
n *r -o co
o o o o
iii]
-- rj rj rj
i i i i
n ^ 'O rx
O 0 O 0
o oo o
0000
o o o o
o o o o
ro i> O LI")
«r n ro rj
0000
n T -o o rj *-» cs
o T-« rj ro
*T S3 fx ^0
ro 03 ri ^
co o ro in
iiT »-• co ro
ii") o O CO Ch- O
in o rx o-
O -H »-» CJ
1 I i 1
0- -r-i T 0-
1 1 1 1
 &> CO O
0 0 C 0
0000
n d~) \n ix
T *T *T 0 -H M -H
O T -O r j
— .H ^-< rj
O * n ^H
CD O rj *-
o a- o 'i
o -• i- 1*1
r-- co o -o
N — m < •.
o -o en ".
0 - rj rf
o o o o
o o o o
n ro ro in
0000
o -o rx ui
ro in o t>
ci rj rj *M

-------
10
CNJ
CQ
in

u. «r
o
z
3
uC
ro
1— «
Q.
a 
_l
CO A
cr>
(— ,
Q
O
m
in

U. ^1
o
2
3
K
fO
Z
an
> I
mioss
a
o
REGION
AW A
o o o o
o o o o
o o o o
o o o o
1 1 1 1
CN ro v in
•o co rs N
o o o o
o T ro rs
ro ro n ro
o o o o
in in o-  in TH
rsrs rs 03
i i i i
N ro ro in
O -H CN 
o -H ri 
O -H TH O
ro ino- in
o oo i
o o o o
i i i i
ro »m -<
o oo o
1 1 1 1
in oin o
•H TH CN
O O O O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
TH rs ri n
t n n o
CD 03 CD CD
O O O O
in -o rs N
o o o o
o o o o
03 0- O -O
T -0 CO CD
to to n ro
1 1 1 1
ro » ss rs
o o o o
03 03 OK TH
O O O .H
00 0- O -H
n ri ro ro
TH S3 N S3
00 03 03 03
ro «r -o oo
o o o o
1 1 1 1
o- o r-i ro
i i i i
ri  o -i
O O "H ^
o o o o
i i i i
mono
IH * r-j
^~
ft
0 O 0 O
O 0 O O
o o o o
o o o o
N 03 0- 0-
o o o o
•^ o rs rs
-o -o in in
o o o o
S3 rs S3 S3
o o o o
o o o o
in ro ss o-
00 OK 00 00
»o ro ro ro
i i i i
 i
ro in S3 co
o o o o
o o o o
O -1 -H -I
O O O 0
OK 0- 0- 0-
O 0 O O
ro o o- o-
r-i rj IH M
o o o o
CN ro in rs
o o o o
o o oo
1 1 1 1
N N S3 in
o o o o
o o o o
1 1 1 1
n o in o
^ r* ri
n
o o o o
o o o o
o o o o
o o o o
o o o o
1
t «r in in
t co rs ro
-o in in in
o o o o
o ri M ri
1H T-4 V4 T-l
O O O O
1 1 1 1
1(0 r-i «r o-
«r ro ro «r
rj n CN M
i i i i
roro » in
o o o o
03 O- O CN
O O r< rt
in oo o i
ri r-i ro ro
-H -i ri .H
o o o o
ro  0- 03
in in H TH
o o o o
i i i i
in o ino
TH TH r-i
03
                                        278

-------
o
o
xQ
CM
 I
UJ
	I
CO
in
u. f
o
z
o
a
ro
M
a.
a CM
SSOLW
1
" U
a
0

CQ
z
o
HI
IRCOLAl
S B4
a. m
z
t_i
A
a
u
:>
_i
U) »
10
VH
a
o
0)
in
L. »
o
z
3
to
t-i
z
a CM
SSOLVE
a *
Q
O
REGION
AW A
o o o o
0000
0000
oo o o
oo o o
1 1 1 1
OO n -<
rJO »• IX
ix rx -o -o
oo o o
I/TO rx rx
oo o o
0-03 -0 10
inr- oo o-
i i i i
to «r in -o
0000
IX IX 00 0-
0000
rx rj. o TH
CM CM ro to
(X O O 0-
-0 rx rx -0
M *r in rx
o o o o
lilt
rx o- T-I to
T* TH CM CM
1 1 1 1
M «r in rx
oo o o
0000
rx CM in o-
Q TH *-t T*
OO O O
— (M CM CM
O O O O
in CM CM o
CM CM CM (N
o o o o
CM to in -o
o o o o
o o o o
1 1 1 1
o CM «r rx
TH «-l TH TH
o o o o
i i i i
no in o
0-
—
o o o o
o o o o
o o o o
TH O O O
o o o o
o o o o
i i i
O i TH CM
CM 0- rx 111
x) in iii in
o o o o
0 -10 «
o o o o
f J -0 CO M
rt rt ^ M
1 1 1 1
v in -o CD
o oo o
rv r. to o
0 00 «
0- O-H CM
CM M M M
CM «rn o
N fs N K
ro in >o co
o o o o
1 1 1 1
fs o^ o r-j
i i i i
M T-0 CO
O O O O
o o o o
r-. -nn o-
o -<»< •<
o o o o
•-t CM CM TJ
0 O 0 O
-i -1 CO CM
n n rj u
o oo o
CM M« IX
o oo o
o oo o
till
00 COO- O
O OO -1
o oo o
1 1 1 1
in om o
*H *« CM
o
CM
-I rt O O
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1
0- 0- 0 -H
to n o o-
~o *o  0-
10 n to to
lilt
f in rx m
o o o o
-0 IX CO 0-
o o o o
rx co co oo
n n ct oj
in in to Ti
-0 -O ~0 -0
to in >o co
o o o o
till
^- o oo
O O O 0
o o o o
00 O M -0
0 -< «-<
o o o o
-1 CM CI CM
0 O O O
o- «r T rx
CM n to 10
o o o o
CM n in rx
o o o o
o o o o
lilt
CO 0- 0- O
o o o "1
o o o o
1 1 1 1
in o in o
«-t ~t CM
»H
CM
o o o o
o o o o
o o o o
VH *H *H 1-(
o o o o
o o o o
1 1 1 1
O TH ^ rt
•o in ~o oo
rx rx rx rx
o o o o
CM M fO T
O O O O
^ to *o o
to *r in >o
o o o o
1 1 1 1
in rx co o*
iiii
n to in •«
o o o o
o o o o
IX O to -0
O-rf -rf •*
o o o o
-H -i N rj
O O O 0
o in o  oo rj rx
O O •" TJ
o o o o
c-i rj rj rj
O 0 0 O
in -o o- o
CO 0- 0- O
o o o «
N * N —
o o o -H
o o oo
iiii
to to o^ in
o o o o
iiit
in o in o
-« — CM
N
n
                                 279

-------
oo
o
oo
CQ
UJ
CD
O

t/l OQ
W
M
d
CQ
in

RUNOF
3 A
1C.  CM
o o o o
1 1 1 1
in o in o
CM
O 0 0 O
o o o o
o o o o
o o o o
o o o o
o o o o
in *o *o *o

o o o o
o o o o
M in LI -o
o o o o
1 1 1 1
in  0- O
o o o **
tiff
n n tn *r
o o o o
o o o o
cs o rj o

o o o o
o o o o
n in in in
o o o o
o o o o
i i < i
0 O
O O O O
01 CM in
CM CM CM TJ
o o o o
rs o- ro >o
ui o- o co
o o o o
o o o o
IIII
in in v *
1-( 1H i-l TH
o o o o
IIII
in o in o
0
o o o o
o o o o
-o n M o*
-H in o- -i
CM M T o
in *M rj ro
o ^H n «r
III!
o o is co
co is ro ^
rt in o- ~i
0 IS CO
ro ro *r in
o o o o
IIII
in o in o
N
0000
o o o o
o o o o
1-4 *H TH i-t
o o o o
o o o o
IIII
rj ro ro ro

rt ^rt ^
o o o o
O 0* CO 0*
O O 0 O
o o o o
T* n ^ CM
IIT in in is
fl- v o N 03
ri M n ri
^ n *o K
r< ro ro to
n ro in *o
o o o o
iiii
in is co co
iiii
CM ro in -o
o o o o
o o o o
o o o o
•o o- -H ro
o o o o
^ in ^r o^
n n in rs
rn rj o 1-1
-< *-4 -^ ri
n -i 
-------
I—
CM
 I
CQ
o ro
0 0 0 O
o o o o
o v ro N
ro ro ro ro
oo o o
o in IIT -H
IS N IS CO
1 1 1 I
IS CM N in
o rt CN ^r
co in co in
*~i n ro -o
rs o- o o
•0 V -i N
•i in rs in

O n CN V
i i i i
^ co rs o*
*• in -c in
i i i i
rs rf o N
o »* CM )o
o o o o
o o o o
o o o o
ro ~< CN rs
in *o ro IH
o o o o
1
ro TS in TS
O O rt CM
O O O O
1 1 1 1
oo o o
fill
mo in o
-< rf PI
o
o oo o
o oo o
TH T-( rH tH
o oo o
o oo o
1 1 1 1
•1 CNTO TO
o OTH ro
M PI n n
o oo o
ro CN ro *o
o o o o
•O 111 IS -t

0 Orf -t
N rsro o
TH rfn ro
in MIS co
in -o~o -o
TO ^TO o
TO in~0 rs

0 0-< .H
i i i i
CO MX) CO
CN ro ro ro
i i i i
IIT NT* is
o o-> *
o o o o
•H -O iH IS
o oo o
o oo o
 i i i
ro  O O
O O -H ^
ro ro in LI
ro ro ro ro
o o o o
o is rs co
o o o o
CN O ^ TO
^ in in in
i i i i
f in N co
0000
o. n «r N
rs o- »- o
n n CN ro
•o o ^ rs
rs co co co
tOT -0 IS
o o o o
1 1 1 1
TO «r in in
i i i i
M 
o oo o
o- PI in rs
00 O -i -I
n TO TO ro
•o o n in
^ CO CO 03
ro in o co
o o o o
1 1 1 1
ro o in
in in in in
o o o o
CN n ^ -«
o o o o
o o o o
1 1 1 I
rs x) in *•
O O 0 0
o o o o
1 1 1 1
in o in o
^ -H CN
tn
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1

n in in in
i i i i
TO TO t in
o o o o
o- ri ro in
•< PI CN ro
ri n n CN
rs ri o o-
CO 0- O-CK
CN ro ro «r
o o o o
1 1 1 1
•H tN TO V
1 1 1 1
ri ro 
-------
CQ
•=£
in
LL ^"
O
ce
n
LL
a rj
SSOLVE
1 C
P


2
O

-j
o
u
CL flQ
a
Ul
en CD
CO
a
o
P5
in
u.  o
CN CN rj ro
ro «r o- rj
03 0- O- O
ro «r in S3
oo o o
1 1 1 1

o o o o
o oo o
1 1 1 1
in o til o
TH TH CM
o
.H TH O O
0000
o o o o
o o o o
o o o o
1 1 1 1
0- 0- O TH
rx ro 03 ro
0 O O 0
0- O O 0-
o o o o
03 0* 0* 0*
ro ro M ro
i i i i
«r LI N ro
o o o o
0- CN «T N
IX IX 0303
n rj rj n
o ro >o rx
rx rx rx rx
ro ^ >o rx
o o o o
1 1 1 1
n ro rj TH
i i i i
ro ^ *Q ro
o o o o
o o o o
rx r> TH n
0 0 -H -H
0 O 0 O
ro o M ro
TH CJ IN (M
o o o o
O IX THfX
ro oo o* o-
O 0 O O
n ro ^ ^o
o o o o
o o oo
1 1 1 1
N r> 0> O
O O O TH
o o oo
1 1 1 1
in o mo
TH .H CM
M
o o o o
o o o o
o o o o
0000
o o o o
oo o o
1 1 1 1
O TH .H TH
03 0* O TH
o o o o
rj rj ro T
o o o o
ix ro o- -H
0 IX Os
O O O O
o^ ro *o PS
0- O O O
n ro ro ro
-o ro rx o
ix rx rx ro
ro c >o ro
o o o o
1 1 1 1
1 1 1 1
ro *r ~o ro
o o o o
O O 0 O
TH ro in ro
O O O 0
o* CN ro *•
TH r-i CN ci
o o o o
in >o in f i
o o o o
TH CN 
-------
>-
— 1
z
o
oo
_J
1— t
o
oo
«=c
00
LU
03
0
00
0
0_
—I
£
00
(M
1
KH
I — r
I — i
•=r
UJ
_J
CO
15
in
01
«
3

rx N -0 in
o o o o
in ** ro co
«r *r n rj
in o iii o
o
•a -i in ~o
00 ** ^" CO
ix ^o rx o^
t nri ^
m •« n CD
•o in  T
-o o n v
r* ro rx n
-0 in «• o o in
i i i i
O ^0 CK CK
rx rx rx rx
in o in o
rj
rj T-t o in
ro rx ^- *-i
•o iii in in
*r in in in
i i t i
•o n
in CN o o
-0  03
o ro
•o ui
•O OT
1 1
rx n
rx  10 -o
CK -O TH fO 03 fl1
^ fx CK CJ rx 03
^ ^ r* ^ o O
II lilt
fj ri co r; fx ro

r^coosco THTHOO
in o
in
tH
N n
in T-*
ro TH
O CO
»HO
UT T
I |
n ^
TH O
in o
-o
LIT o in o in o
•o
o CK n 03 TH n
in o ro ^ ^ in
rj -o ro o TH O O in
in o in o in o
rx
TH in
ro ^
>o in
n o
i i
O TH

ro ro
in o
rx
CK in
0- o
^ fl-
-o in
03 CK
in in
ro o
rj r i
n co
in o
CO
ro in
in n
TH rx
in «r
03 N
i i
O *"*

ro ro
in o
in 03
•o in
co 
-------
 o

 oo
 o
 oo
 o
 a;
 LlJ

 U-
 <
 LU
 cn

 o
 00

 s
 o
 —i
 D_
en
CM
 I
CO

-------
O
cr>
CM
 i
03
in
u. »
o
2
3

_i
O rt
en n
en
>-t
a
o
in
u. v
u. -i «
C9
LU
Ct
oo oo
oo oo
oo oo
CMCN cgCM
OO 00
oo oo
^ in UTO
^-1 rf-l
INT mis
rs rs rxrs
00 00
O>M in-o
O »H ^^
oo oo
CM IS rstN
so rs O"H
rx rs NO)
1 1 1 1
roin COM
OO O-"
t -o o-m
oo o~<
M rs »CM
O M rsCM
*4 rl ,HCN
in
-O *H X) CM
roin oo ro
o o o^
1 1 1 1
r* rs CD CM
a> •* m**
1 *H rH IN
1 1 1
-1 rt CM*
00 00
OO 00
in »• ro-o
CM CN ro ro
o o o o
is o >r oo
O T4 *4 **
0- (N O T
o CM rs «•
O O O •"
(
in >o rs oo
o o o o
o o o o
1 1 1 1
rs so .H o
CM in o- t
O O O *H
1 1 1 1
in o m o
o
•H
O O O O
o o o o
o o o o
* o in
0- 0- 0- 0-
n m n n
i I i i
o o o o
^ rt O O
o o o o
CN 0- t O
o
»H o CD 

o o o o
1 1 1 1
ro o •<> CN
i i i i
ro ro T in
o o o o
o o o o
CN in co o
o o o o
CN CN ro ro
o o o o
rs rs *• co
«H *-l T-4 O
o o o o
1 1 1 1
^ in -o rs
o o o o
o o o o
1 1 1 1
CM n in O
o o o **
o o o o
1 1 1
in o in o
<•
o o o o
0000
0000
1 1 1
in in in in
o o o o
0 0 O O
*H CM ro ro
O 0- CO IS
ro CN n CM
o o o o
^ T in *o
CM CM CN CM
O O O O
1 1 1 1
oo in rs ro
rs rs -o ^o
(N CN CM CN
1 1 1 I
O O O O
o o o o
o- in co CM
ro o ro -o
*o rs rs rs

o o o o
1 1 1 1
in o in o-
i i i i
CN ro ro »
o o o o
o o o o
o ro >o co
o o o o
CN CN ro ro
o o o o
ch ro ^r ro
o ^ T-< r-<
o o o o
rill
o
rs in   rs
0 0 O O
O O O 0
1 1 1 1
 CD
•T ro ro ro
o o o o
o o o o
o o o o
1 1 1 1
rs in is c-
•0 * -0 -0
ro ro ro ro
1 l 1 l
O O *-"*-»
O O O 0
•H r-» O O
o o o o
o ro -o o-
is ^r CD CN
CO O- O- O

o o o o
1 1 1 1
ro is ^ in
CM CM Hi ro
i i l l
CN ro ^ T
o o o o
o o o o
o- ro -o o*
o o o o
.-< ~4 »H CM
o o o o
ro ^ CM «r
CM IN n CM
o o o o
ro T in in
O 0 O O
o o o o
1 1 1 1
o ro *o o
0 0 O -i
o o o o
1 1 1 1
in o in o
CO
                                     285

-------
O1
CM
 I
LU
—I
CD
in

u. <
o
z
M
M
0.
a N
SSOLVE
1 C
M O
a
0

o
z
a
M
H
en a
en
M
a
a
in
u. v
u.  o> o> o>
CM CM CM CM
1 1 1 1
O O O O
**o o o
o o o o
0-M 03 CM
M «r *• m
03 0" 0> OK
o o o o
1 1 1 1
-IS3 -t"0
MM » »
1 1 1 1
M«T in -o
o o o o
o o o o
MN rt »
•H -< CM M
O O O O
no- M rv
rt-H CM CM
o o o o
CM -0 N »
o o o o
00 0 O
1 1 1 1
* -0 N 03
00 0 O
o o o o
1 1 1 1
rt CM S) 0
OO O -i
oo o o
1 1 1
in o in o
rH rt CM
O
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
M M *• »
oo oo rv S3
CM CM CM CM
o o o o
OK 00 OK OK
0 OO 0
1 1 1 1
rv rv M CM
rv rv rv rv
CM CM CM CM
1 1 1 1
O O O O
O O O 0
o o o o
CM OK Id «
* » in s>
S3 -H rv M
00 OK OK O
O O O O
1 1 1 1
i* 03 V «H
M M «• in
1 1 1 1
M » r> in
o o o o
O 0 0 O
M oo CM in
* •< CM CM
o o o o
0- M 03 «
rf CM N M
O O O O
o o o o
i i i i
* S3 rv 03
0000
o o o o
1 1 1 1
» CN rt rv
o o o o
o o o o
1 1
in o in o
•H — CM
0
CM
§OOO
O O O
o o o o
1 1 1 1
0 O 0 0
o o o o
CM M M V
O OK 0303
M CM (M CM
O O O O
o o o o
1 1 1 1
CM <• o rv
CD oo oo rv
CM CM CM CM
1 1 1 1
0 O O O
-< o O «H
o o o o
•i rv CM rv
* » in in
rv M oo «
rv oo oo 0-
o o o o
1 1 1 1
03 » o in
CM n * t
III!
n n T in
o o o o
0 O O 0
CM S3 OK CM
O O O O
•H in o in
CM CM M M
o o o o
o «• <• ~
o o o o
1 1 1 1
v n s) rv
o o o o
0000
1 1 1 1
CM o M rs
o o o o
0 O OO
1 1
in o m o
•H -« CM
CM
o o o o
o o o o
o o o o
1 1 1 1
o o o o
O 0 0 0
•o  rv
o o o o
o o o o
1 1 1 1
*• CM O *
0 O O O
o o o o
1 1
in o in o
-< -H tM
in
N
o o o o
o o o o
O 0 O O
o o o o
o oo o
SSSS
o o o o
O rt n rt
o o o o
1 1 1 1
in *• oo M
N CM CM M
T o s)
in in in in
o o o o
CM CM M M
O O O O
1 1 1 1
M oo v rv
o cs rv rv
w *r ^" «•
I i i I
V S) 03 -H
0 0 0 -
T in rv o
o o o 
-------
o

GO
o
oo
a:
Ll_l
U.
00
CQ
5-
O
GO
O
CO
 I
GO
•a:
in

u. »
o
z
D
(E
n
M
0.
a CM
SSOLVE
u c
Q
o

in
«
z
o
t- ^
i a
o
u
a:
o. a
z
(-H
a
u
O TH
en a
tn
a
o
01
in
u. «r
a
z
3
M
Z
a CM
_j
a
U)
en «
a
0
REGION
ftU C
oo o o
0000
oo o o
1 1 1 1
oo o o
oo o o
1 1 1
rs rs oo oo
nin in in
oo o o
o o o o
O-H TH O
torn ro to
oo o o
i i i i
» co in CM
o o o o
TH TH CM ro
oo o o
•Ors o- CM
00 0 TH
HT «r TH in
rso- CM -o
T-4 TH
MTH o a>
OK 00 N CO
TH TH CM ro
o o o o
i i i i
in is o to
in rs TH *o
i i
n rs co o-
o o o o
o o o o
TH o o- in
 O
o o o TH
o o o o
1 1 1 1
CM o- co ro
0 -i f 0-
o o o o
1 1 1 1
mono
TH TH CM
o o o o
0000
o o o o
1 1 1 1
o o o o
o o o o
00 00 CO 00
o o o o
o o o o
TH TH CM TH
to ro ro to
o o o o
1 1 1 1
TH ro 00 rs
ro ro ro ro
o o o o
TH TH CM N
O O O O
oo o -i ro
O 1-1 TH TH
N 0- CM -0
T n rs co
 HT
«r o- CM >o
CM CM ro ro
CM ro ro t
o o o o
o o o o
1 1 1 1
CM n ro CM
o o o o
O O 0 O
m o in o
TH TH CM
n
0 O O O
o o o o
oo o o
1 1 1 1
o o o o
o o o o
1 1 1 1
rs is is rs
is rs co co
o o o o
o o o o
rs o- o -H
ro ro T HT
o o o o
i i i i
o 0- in TH
rO T< TH T-4
o o o o
i i i i
TH CM CM IO
o o o o
co TH ^ rs
a> in TH CD
ro «r in m
0- TH 0 10
TH in rs o N
o o o o
o o o o
1 1 1 1
* CM ro o
O O O TH
o o o o
1 1
in o in o
o o o o
o o o o
o o o o
i i _i i
o o o o
o o o o
1 1 1 1
N rs is N
TH TH CM n
o o o o
o TH ro *
in in in in
o o o o
1 1 1 1
o* ro co TH
ro ro CM n
o o o o
1 1 1 1
o o o o
•0 COO CM
o- ro ~o o
CM ro ro *
in -o o CM
co o n ro

o o o o
1 1 1 1
D- ro rs CM
i i i i
to «r in x)
o o o o
o o o o
CM in o* CM
TH TH TH CM
o o o o
1 1 1 1
O O O -H
0 O O O
03 N CO to
CO ^ O X)
CM ro 
o o o o
o o o o
1 1 1 1
O- 0* CD *fl
o o o o
o o o o
in o in o
TH TH CM
in
o o o o
o o o o
o o o o
i i i i
O O O 0
o o o o
1 1 1 1
rs r\ co co
in *o rs rs
o o o o
0 0 O O
o- in o oo
o o o o
1 1 1 1
0 rs rs is
ro 0 N 00

o o o o
1 1 1 1
TH in o o ro in &•

CM CD HT O
TH TH CM tO
O CO -0 T
•« in TH o
in o- CD o
o o -H ro
i i i i
o- rs o ro
o- -o «r -<
i TH CM ro
o o o o
O O 0 O
CM o o- in
CM CM TH TH
o o o o
1 1 1 1
V 00 00 0.
CO CM O- CO
O --• TH CM
co ro «r v
o- rs o rs
CM ro in x)
•r in in rs
o o o o
o o o o
i i i i
ro ro ro *o
*r co in in
O 0 -H tM
i i i i
in o in o
-f -< CM
                                              287

-------
10
CO
 I
CO
H
a
u
•>
_i
Ul »
(n
M
a
a
in
u. t
a
z
D

_i
o
en
en ^
a
o
REGION
AU I
o o o o
o o o o
o o o o
i
o o o o
o o o o
1 1 1 1
in in -o -o
0- 0- 0> 0-
IN CN (N CN
0 0 O O
0- 0- 0- 0*
o o o o
o o o o
1 1 1 1
X) N 0- 0.
n m m n
M CN CN (N
1 1 1 1
CN CN CN M
o o o o
in -o m o-
o o o o
n n * o
in -o rs oo
••« rt fs O
n rs oo o
rf CN CN n
o o o o
i i i i
0-0-0-0-
rn * n -0
1 1 1 1
CN n T in
O O 0 0
o o o o
*• ^ M n
o o o o
o o o o
1 1 1 1
rs in n •*
CN PO H n (N
o o o o
1 1 1 1
n on o
rt ••« (N
0-
*H
O 0 O 0
o o o o
o o o o
1 1
o o o o
O 0 0 O
1 1 1 1
in in -o -o
rs rs rs rs
CN CN CN CN
o o o o
o o o o
1 1 1 1

CM n M ro
n ^ in rs
o o o o
o o o o
1 1 1 1
n oo ro o
O O -" CM
o o o o
1 1 1 1
in o no
-i rf CM
•0
CN
O O O O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
•T  in *o
ro t*) ro m
o o o o
1 1 1 1
00*0.
in « CN -«
n m m n
i i i i
in o f -<
O O *H CM
TH -O Y* 00
m rs >o o
in n n in
~o n IN »
0- 0- CO -O
n is CN o
O O rt M
i i i i
ro o ro ^
M * «r ^>
i i i i
CM ^ O CN
o o o o
o o o o
1 1
-H in to CD
CN CN CM CM
o o o o
1 1 1 1
rs o- n CM
oo o M in
O <-< *-< *H
-H is o in
in n CN rs
m «r in in
ro in rs -*
O O O -H
o o o o
1 1 1 1
-0 CN O 0-
O r* CN CM
O O O O
1 1 1 1
no in o
rt rt CM
rs
CM
                                 288

-------
o
o
o
ro
 i
i ooog
in i oo o o
I OOOO
i
u. «r i oo o o
o i oooo
Z 1 1 1 < >
 I 0000
_l 1
O )
in i o.Min-0
Q 1 OOOO
i
| MIsrsM
O t -Ofs O- x
i rsrsrsoo
i i i i i
i
i
! WinOOrM
in i • • • •
ffi I OO Ox
i i
M i ehOJ *O*N
« at i o<-< ^w
d !
U 1
tn \ o-v xo-
CL a 1 O-IO rsx
| ~t xM
Z 1
*•* 1
I MM moo
at i inx no
U 1
_l 1 NT fsM
co a i oo o»<
U) 1 1 1 1 1
M 1
Q ! rsxNis
at i -oo TO-
i | rt rfrt
i iii
i
i
! rtrf MM
in i oo oo
I OO OO
i
! MIS MIS
u. «r i MM MX
u. 
»H | O X X -<
i o x in rs
Q M t T* X M -0
5 1 M» T T
-J 1
O 1
co i ^ T in rs
en x i oooo
O 1 OO O O
i i i i i
i .0 M M rs
o i CM in a) M
I 00 Ox
1 1 1 1 1
03 i mo m o
0 1
Id 1 O
a, ( x
oooo
oooo
oooo
oooo
oooo
1 1 1 1
 o M
»H TH
in OK -o M
•a o* M in
x M M M
OOOO
1 1 1 1
H «* ,H
M CM M M
1 1 1 1
X (N| M M
OOOO
in >o 03 o-
oooo
~o o in OK
M T T T
T 0* x *-<
M M in -0
X *4 ^4 M
oooo
1 1 1 1
in o T a)
M M n M
t 1 1 1
M M T in
oooo
oooo
M in is o-
X IH X ^H
oooo
1 1 1 1
fs IN is 0 O
M (N (N M
r<) T in *o
oooo
oooo
11)1
x T co n
O O O x
oooo
1 1 1 1
in o in o
M
oooo
oooo
oooo
1
oooo
oooo
1 1 1 1
CN M ro ro
T t in in
M n M n
oooo
(N X rf rH
OOOO
1 1 1 1
T *o >o in
0- 0- 0- Ct-
fO n ro ro
i i i i
oooo
ro ro m ro
oooo
x fs (O CO
T T in in
in o- x M
o x M 
M M ro ro
oooo
in CM o- in
-0 00 0- x
~l *H TH CN
ro T in in
oooo
oooo
1 1 1 1
O T CO M
O O O X
oooo
1 1 1 1
in o in o
ro
*4
OOOO
oooo
oooo
1 1
oooo
oooo
1 1 1 1
M ro ro ro
CO CO 0- 0^
ro ro ro ro
oooo
M M CM M
OOOO
1 1 1 1
M ro o is
M M (N X
ro ro ro ro
i i i i
oooo
M ro ro ro
oooo
T x 03 «r
T in in -o
oo «r -c rs
o M ro «r
• O X rt *4
oooo
1 1 1 1
rs ro OD ro
M ro ro T
i i i i
ro ro T in
oooo
oooo
rs co co o-
oooo
oooo
1 1 1 1
** rs CM cr*
M n ro ro
oooo
M x rs «•
-0 CO 0- x
** tH .H M
ro t in -o
oooo
oooo
1 1 1 1
x CM in o
O O O X
oooo
1 1 1
in o in o
T
V4
OOOO
oooo
oooo
1 1 ]
oooo
oooo
1 1 1 1
x CN ro ro
o >o
M CN CN CN
1 1 1 1
x M CM ro
oooo
ro in -o rs
oooo
CK T rs x
ro » T in
x o «r oo
GD O* O> 0*
X r* CM O*
oooo
1 1 1 1
M ~0 O T
M CN ro ro
1 1 1 1
CN ro ro o o 
-------
O
o
o
ro
co
in

U. V
a
z
3
DC
to
M
CL
Q IN
SSOLVE
1 C
M U
a
o

in
a
z
o
0 O T O-
CM ro ro ro
i i i i
ro » in •«
o o o o
o o o o
rs rs 00 CD
o o o o
OO 0 0
1 1 1 1
in o- CM N
y-t in N M
o o o o
rs rs (O rs
0- TH rO »
-H CM CM CM
«• in -o -o
o o o o
o o o o
1 1 1 1
o CM -o o>
o o o o
0 O O 0
1 1 1
no in o
rt •* M
»•
*H
O O O O
o o o o
o o o o
1 1 1 1
o o o o
0 0 0 O
1 1 1 1
n n * «r
M M M n
ro n ro M
o o o o
0- CD 0- CN
O 0 0 0
1 1 1 1
r- N ro CM
N N iv rx
CM fM CN CM
1 1 1 1
O O O O
ro ro 
CM (O f) CM
o o o o
N N rs rs
o o o o
1 1 1 1
CM » o rs
CD oo co rs
CM CM CM CM
1 1 1 1
O 0 O 0
ro  o
O O O -I
N CM in rs
ro * ^ »
^ on *
0- O O O

o o o o
1 1 1 1
ro rs o ^
CM CM ro ro
i i i i
CM CM IO »
o o o o
o o o o
.-i CM ro ro
o o o o
1 1 1 1
•o CM rs CM
CM ro ro v
0000
t "1 -0 0
in rs co o-
rt rl T* tH
ro » in in
o o o o
o o o o
1 1 1 1
in oo ^ in
0 0 rt rf
o oo o
i i i i
in o in o
*•* T-» CM
>O
CM
O O O O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
CM CM ro 
CD -H I 03
O tH TH *H
oo T rs co
v in in in
» o o in
OK o O 0>

o o o o
i i i i
rs to oo CM
CM ro ro *•
i i i i
O O •-" CM
o o o o
o o o o
1
* -0 0- 0~
o o o o
1 1 1 1
0- 0 rt «
•»• M) rs co
0000
OK rs rs o
rs ^ in oo
.H CM CM IM
ro *• in rs
o o o o
o o o o
1 1 1 1
oo ^ in o
O rf rt CM
0 O O 0
1 1 1 1
in o in o
rt rt CM
rs
CM
                             290

-------





	 1
•z.
o
I/)
1 — 1
o
t/0
OQ

LU
O
O
— 1
Q_
	 1
	 1
et
U-
oo
1
1— 1
t— 1
t— I
 T -H Cl
CJ O CK 03
1 1 1 1
rs -o no-
O- 0- 0- 03
-H iii ro o
ro cj cj cj
in o iii o
O -0 0- CJ
«r — -o rf
iii iii rs cj
iii ro cj iii
o CK cots
« o o o
i i i i
o ro 03 -r
03 CD CO CO
0- CJ •<30-
O O 0- 00
in o in o
-H T-l CJ
CJ
rs to o o
n T o- in
in rr ro ro
in rj -o CJ
ro ro ci cj
i I i i
rs co o CD
rs rr ci o-
•o -o -o in
N -H O 00
ro *r *r ro
in o iii o
CJ
-0 O 111 0-
rso-'^o-
rs CO ^ CO
I 1 1 1
•>-* CO *C M
0- 00 00 CD
O S3 O- C*
Lf) O til O
rj
T-*
111 CO *H *H
CJ rv *o o
•o o is in
CN M o
to o in -o
n ro ro ro
tn o in o
*o
n
•o r-j ro TH
O *H 1O '-t
CJ O O -H
O OK CO rs
r^ O O 0
1 1 1 1

o o- CKQD
O O O O
in o in o
^~
co rs sa m
CO I-H O CO
ro o -H -o
M CK CN CO
in 0
fl- o rs
rs rs rs rs
i i i i
rj co tn n
in o co «H
TH o O- CK
in o in o
tH ^ CJ
^






r-t o co ro
ro -o TH r\
CK Ci is CO
O O CK CK
^ ,H O O
1 1 1 1
CK rs sQ fl-
^ TH ^ -H
rj o co rs
»H iH O O
in o tn o
-0
rs co ro rj
CK CO f J t
CK -O CO T-t
ro i-« ci rs
UT *r n o
iii)
CK in CO LI
co in rj .-<
o ^ ^ rs
••o MD ^o in
in o in o
«H »H Ci
rs






CO fl- O CK
•o CK 0 N fs
in o in o
*-«*-( rj
CO






*•« V O *0
n co rj ro
v is to CK
fl- O -O -O
CK CK CO CO
O O O O
1 1 1 1
rs -o 
-------
 >-
 —I
 •z.
 o


 _J
 I—I
 o
 oo

 CQ


 2:
 O
 I—I
 I—
 •=t
 a:
 Q_
 00
 CQ
 O
 oo
 O
 _ I
 Q_
C\J

OO
 I
CQ
«=C
in
u. «r
a
z
ce
ro
M
a.
Q CN
SSOLVE
:i c
a
0

at
0
M
:RCOLAI
i BJ
a. a
z
a
>
a> a
en
HH
a
o
0)
in
u. 
CM CI CM TH
o o o o
O TH (N CN
ro ro ro ro
o o o o
1 1 1 1
rs CN o oo
TH TH TH O
o o o o
1 1 1 1
CN CM ro u")
o o o o
in rs o CN
O O O TH
ro TH o rs
^ in S3 -o
rs S3 * o
rs o- TH ro
CM ro ro in
o o o o
1 1 1 1
O O -H CM
1 1 1 1
ro ^ 
-------
CNJ
OO
 I
CO
1 OO OO
in i oo oo
1 OO OO
i
i
u. » i oo oo
O 1 OO OO
Z 1
D 1
o: i in*o 'ON
i
0- 1
Q CN 1 WTO -0*0
:> 1 OO OO
_J 1
O 1
co i OCN ^"in
CO TH 1 OO O O
a i oo oo
i i
i
1 O» 00*
o t Tin *o oo
I -0-0 -O-O
i i i i >
i
i
1 -TN TH O
in 1 • • • •
to 1 OO TH CM
1
Z 1
0 1
•H i noo ro*
•x at i oo THCN
_i i
0 1
U 1
a: i oo -TTH
a. a i rHin oif)
I *H*H T-4 CN
Z 1
M 1
1 ON 09 00
at i com o- N
W 1
•> i
_l 1 -T-O TH O
O -H 1 . . . •
en at i oo TH CM
in i i i i i
M 1
a i
1 OTH O -0
a i con oo «r
i i .H THC-I
i ill
i
i
1 OO THM
If) 1 OO O O
1 OO O O
1
i on ran
U. •»" 1 CNCN (N ro
O 1 OO O O
Z 1
3 1
(<> i mm oo if)
M | 0 -H .H CM
1
Z 1
i m ro T ro
a N i o ro o o
I> 1 OO TH M
-i i i
O 1
0) 1 * If) *0 00
U) -1 1 O O O O
a i o o o o
i i i i i
i
1 O *0 00 O
o i ro -o TH e>.
I o O -H TH
i i i i i
Z 1
O 3 1 If) O If) O
O 1
Ul 1 O
CZ 1 -1
o o o o
0 O O 0
O O 0 0
1
o o o o
o o o o
\n in -o -o

«r * «r «r
o o o o
M M CN (N
TH TH TH TH
O O O O
1 1 1 1
o- o- rx CD
a> o- o* a*
n M ro ro
i i i i
n n v -a
O O 0 O
M ro n •
N N 00 [X
*H T-l ^-4 TH
1 1 1 1
n (N ro ro
0 O O O
M ro ro «r
o o o o
0 -0 -< N
o rx
O O O 0
o o o o
1 1 1 1
o *• o o-
O O ^ rf
o o o o
1 1 1 1
in o in o
(N
o o o o
0 0 0 O
O O O 0
o o o o
o o o o
ro «r ^- T

ro ro ro ro
o o o o
O 0- 0- 0-
T-I O 0 O
o o o o
1 1 1 1
in oo oo rv
in in in in
i I i I
^ (N rvi (N
O 0 O O
t-H .-* *H t-»
o o o o
(h 00 "O *
T in •« rs
ro in •<> -o
0) 0- O *H

o o o o
1 1 1 1
CD X) ^ CM
ro * if) *0
1 1 1 1
(N ro ro ^-
o o o o
0 0 O O
0- (N * *0
O -H -1 rH
o o o o
(N ro ^- in
0 O 0 O
^ IX o 0
^ o o •-»
o o o o
n *r in *o
0 O O O
o o o o
1 1 1 1
(N *o ro *H
O O rt (N
o o o o
1 1 1 1
in o in o
ro
o o o o
o o o o
0 O 0 O
1
0000
o o o o
ro * ^ in

ro ro ro ro
o o o o
O O O 0-
rt rf ^ O
o o o o
1 1 1 1
^ (M iH O
1 1 1 1
•H rf (VI fN
0 O O 0
*-t r-t *H O
O O O O
ro * ro rsi
in -o rv oo
in o- o CM
00 0- -1 (N

o o o o
1 1 1 1
o o o o
* in in >o
i i i i
CM ro o rx
O 0 O O
o o o o
1 1 1 1
T CN CM CO
O O O O
o o o o
1 1
If) 0 If] 0
^0
o o o o
o o o o
o o o o
1 1 1 1
0000
o o o o
-fl -0 -0 -0

CM n CM CN
o o o o
>0 N 00 O
ro ro ro ro
o o o o
1 1 1 1
~0 0- O CM
rx -a rx rx
i i i i
o o o o
CM ro ro ro
o o o o
03 CN in CK
CN ro ro ro
CM rx -H ~o
CM n ro ro

o o o o
1 1 1 1
«r o- T o
CM CN ro ro
I i i i
CN ro » «r
o o o o
0 0 0 O
rx CM *o o-
o •* •* -•
o o o o
rH -< TH CM
O O O O
00 -<.H 0
in -o -o -o
o o o o
ro ^ in >o
o o o o
o o o o
1 1 1 1
in v -< ro
O O 0 0
o o o o
1
in o in o
rx
0 O O O
0 O 0 O
O 0 O O
1 1 1
o o o o
o o o o
T «r in in

t ro ro n
o o o o
GO CO 03 CD
O O O O
O O O O
1 1 1 1
in T -a rx
ro ro ro ro
i i i i
O 0 O O
•H .-< O O
o o o o
in o t rx
ro 
-------
o
o
CM

OO
CQ
in
u. »
o
z
D
or
n
M
CL
Q CM
SSOLVE
1 C
wo
Q
O

0)
Z
o
w
:RCOLAT
! B4
0. 
§000
o o o
o oo o
1 1 1 1
M M M M
0000
o o o o
» «r in in
rx -o -o -o
CM CM CM N
0000
0000
1 1 1 1
CN M rt <-l
in in if) in
CM CM (N N
1 1 1 1
— CM CM CM
O O O O
o o o o
CN GO -O in
«r in -o rx
o o> rx rx
O O -4 CM

o o o o
1 1 1 1
rx -o in in
M » in -o
i i i i
CM M » in
o o o o
0000
ON M >0 OK
0 O 0 O
in -H oo OD
CN, m n *
o o o o
M in o o
o o o ^
O 0 0 0
i i i
M «• m rx
o o o o
o o o o
i i i i
CM 0400 -0
O 0 0 -H
0000
1 1 1
in o in o
*4 -4 CM
o
CM
o o o o
o o o o
o o oo
i i i
0000
o o o o
M * v n
rx rx «o *o
CM CM 
o o o o
o o o o
1 1
in o in o
^ ^ IN
in
CM
o o o o
0 OO O
o o o o
in in in in
o o o o
o o o o
CM M M ^1
in «• M r in
o o o o
i i i i
0> in OK CM
CN M M »
1 1 1 1
rt CM M »
O 0 O O
O O O O
OK M -0 03
O O O O
*• o rx in
M *• » tn
o o o o
*• — T* in
o o o o
M * -o rx
o o o o
o o o o
1 1 1 1
M -0 O -0
o o -* -<
o o o o
1 1 1 1
in o in o
^4 -4 CM
•0
CM
O O O O
O O O O
0 O OO
in in in -o
o o o o
o o o o
M T «T in
CM VH 0- CN
O O O O
CM M -0 rx
M M M M
O O O O
1 1 1 1
 »* rx in
O •* *-4 CM
o o o o
1 1 1 1
in o iii o
TH rf CM
rx
IN
                                  294

-------
 O


 00
 o
 I/O
 o
 I—I


 
-J
U) 00
Ul'
M
a
IB
n
U. T
o
z
3
cc
w
z
a (N
SSOLWt
U ,
a
0
REGION
AU t
oo o o
oo o o
oo o o
1 1 1 1
OO 0 0
oo o o
1 1 1 1
rs rs oo m
in in in ~o
oo o o
OO 0 O
0,0, 0- CO
TH T* TH TH
OO 0 0
1 1 1 1
» «• < o
00 0 TH
o o o o
1 1 1 1
TH CM M H
o o o o
NO- (M 00
O O TH TH
TH -0 CM i-l
CO O » O
-1 -IN
m-o «r in
n M n a>
-1 CM M in
OO 0 0
1 1 1 1
 03
n oo TH -o
10 rs o (N
TH TH
» 10 -o rs
o o o o
o o o o
1 1 1 1
O-O- 0- TH
O ro rs »
0 0 0 TH
i i i i
in o in o
.H TH CM
TH
0000
o o o o
o o o o
1 1 1 1
0000
o o o o
CO CO CO GO
in in in in
o o o o
0 00 O
M TH TH TH
N M (N N
0 0 O 0
1 1 1 1
«r T o T
o o o o
o o o o
TH M n v
o o o o
o- n -o o
O TH TH (M
n oo in «•
n -o co o
TH
0- O 0- N
M O IO TH
TH (N n 10
0000
1 1 1 1
M CM IO N
V -ODD -1
1 1 1 TH
1
n » 10 -o
o o o o
o o o o
rs o- TH o
•H TH CM CM
o o o o
1 1 1 1
CM IO M -0
n CM » -^
O O O O
N « rs rs
•0 CO O TH
in -o co o-
» \n rs
o o o o
o o o o
1 1 1 1
TH n TH -o
o TH p> n
o o o o
1 1 1 1
n o 10 o
TH TH CM
CM
o o o o
o o o o
o o o o
1 1 1 1
o o o o
o o o o
1 1 1 1
rs rs rs rs
in in in in
o o o o
O O 0 O
10 -o rs rs
CM CM CM CM
o o o o
i i i i
in TH o CM
o o o o
o o o o
1 1 1
•-I TH T* 1-t
o o o o
•0 CO 0 0-
o o o o
o CM M in
M CM CM CM
"0 *0 CO CO
CO Q, 0, 0,
O *-l ** *H
o o o o
1 1 1 1
«r rs o CM
"1 -H CM CM
1 1 1 1
•H CM n n
o o o o
o o o o
o CM ro *•
*H iH iH TH
o o o o
1 1 1 1
in -c co o,
O O O 0
o o o o
o- CM M) rs
N CO CM -0
M n  o
•H CM n »
O O o O
1 1 1 1
o rs N -45
MM «r 10
1 1 1 1
M n «r 10
o o o o
o o o o
D, >0 TH ,0
TH CM M M
o o o o
1 1 1 1
>o in rs TH
TH CM M IO
o o o o
CM o n -o
^- rs c*, TH
* IO -O 00
n in in rs
o o o o
o o o o
1 1 1 1
IO TH 0- -H
O O O CM
o o o o
1 1 1
IO O 111 O
TH TH CM
«r
o o o o
o o o o
o o o o
1 1 1* 1
o o o o
o oo o
1 1 1 1
rs rs rs rs
CM CM CM M
TH TH TH rH
o o o o
0> O- TH rH
n ro«r «r
0 OO 0
1 1 1 1
o- -o <• in
o oo o
fill
TH TH CM n
o o o o
co o n -o
CM rs TH in
n n v «r
CO -H -0 -0
o> CM m v
TH TH CM CM
o o o o
1 1 1 1
TH rs CM co
M CM n «
1 I 1 1
CM n v in
o o o o
o o o o
CM -O CO TH
TH TH TH M
O O O O
1 1 1 1
CO CM fs CM
o -H TH n
o o o o
•o -o in co
,0 W O *0
n «r in in
n * in •«
o o o o
o o o o
1 I 1 1
co rs «r o
o o o o
o o o o
10 o in o
TH TH CM
IO
O O O O
O O O O
o o o o
1 1 1 1
o o o o
o o o o
1 f 1 1
CO CO CO 03
•o rs rs rs
0000
o o o o
10 rs rs N
n n m n
o o o o
1 1 1 1
CM TH m co
O CM CM CM
O O O O
1
r«> in co in
O O O TH
0 0- TH 111
rs TH co -o
1 TH TH CM
i i i
CM TH o CM
O O O O
o o o o
1
TH TH rs O
in rs co o
O O O TH
1 1 1 1
CO O CM O,
in -i co rs
O TH TH CM
0- •« CMO
,0 TH m TH
rs TH »r co
o o -o
o o o o
i i i i
M in co M
O O O TH
T< 0, -0 -0
o TH 10 «r
N 0* TH ^>
TH TH
03 N TH TH
 0> o  o TH
TH CM CM n
CM in n TH
rs rs M *o
in -H ro 10
o TH CM n
i i i i
IO -H O T
O CO SI CM
-H TH CM M
1 1 1 1
TH CM 
-------
CO
CO
 I
CO
in

u_ «•
o
z
D
LC
ro
a.
a CM
SSOLUE
1 C
a
o

in
A
z
0
M
IRCOLr.1
I B<
o_ CQ
z
M
CQ
UJ
a TH
en a
en
a
a
in
u. «r
U. 1
o
z
a:
ro
t-H
Z
a CM
SSOLVE
U f!
a
o
z
03
O
UJ
ooo o
oo o o
ooo o
ooo o
ooo o

NINTH TH
oo o o
oo o o
oo o o
1
OTOO f
-0-0 "O -0
IIII
«rrs TH o
OOrt CM
TH-O CM rO
THTH CM ro
rs rs TH CD
THTH TH CM
OOCM O O
-oro rs «r
ro -o o o
OO -H (N
IIII
*r «r *r o
rsTH -o ro
l TH TH CM
l l l
OO O CM
oo o o
o o o o
1
mo oo in
CM ro CM CM
oo o o
IIII
oo *• -o IN
co ro oo in
O TH TH IN
-oco o rs
IN *o in *r
«r in •o rs
ro «r in rs
oo o o
o o o o
IIII
o, TH -o ro
CM -o o rs
O O TH TH
IIII
in o in o
o
ooo
000
ooo
1
ooo
ooo
1 1 1
in in -o

CM CM CM
ooo
ro IN IN
ooo
1 1 1
o. o- rs
0-0-0-
ro to ro
i l i
CM ro ^
000
•O 00 0>
ooo
o r o- -o
O O O TH
o o o o
IIII
in o in o
N
o o o o
o o o o
o o o o
o o o o
o o o o
IIII
ro «r -r «r

ro fo ro ro
o o o o
o o- o- o-
-H O O O
o o o o
IIII
in co oo rs
in n in in
ro ro ro ro
III!
TH TH CM CM
O O O O
•r - o-
IN CM IN
1 1 1
TH TH CM
000
ooo
CM n TH
in -o rs
CM rO 00
IN T in

ooo
1 1 1
ro TH o
ro -f in
i i i
CM ro ro
ooo
ooo
ooo
ooo
1 1 1
oo in ro
CM ro T
ooo
o TH n
c*. TH ro
TH Ol CM
IN ro <»•
ooo
ooo
1 1 1
TH in TH
O 0 TH
ooo
1 1 1
in o in
„
o
o
0
o
o
1
in

ro
o
0-
o
o
o
CM
1
IN
O
in
o
TH
00
rs

o
i
0*
in
l

-------
O
o
oo
oo
CO
in

U.T
a
z
3
or
n
M
a.
a M
a
u>
U) «-l
M U
a
o

n
z
a
IRCOLAI
! EU
a. a
z
a
Ul
o «
in a
U)
a
a
in
u.  to
in in in in
CM CM CM M
i i i i
oo o o
ro«r *• in
oo o o
too in «
«• in in xj
CM rs o »H
PI «• -0 rs

00 O 0
1 1 1 1
OX) CM 0>
roro «r «r
i i i i
CMIO  0- 0-.
CM CM CM CM
O O O O
o o o o
1 1 1 1
CM ro *H «
in in m n
CM CM CM CM
i i i i
o o o o
o
to ro ^ v
 ro
r-t CM CM ro
i i i i
CM to to »
o o o o
o o o o
O -< CM tO
o o o o
1 1 1 1
th ro rs CM
^ N CM n
o o o o
rt o oo in
V IS 0- CM
CM CM CM ro
ro ro » iii
o o o o
O 0 O O
1 1 1 1

-------
>-
_l
z
o
o
oo
oo
LU

CO
O
oo
 o
 _l
 CL.
 n



 I—I
 I—I
 I—(


  0-
rt rt O O
1 1 1 1
oo NX rs
0- rs n T-I
in ion in
CM MM CM
n ro o oo
in on o
*4 1* CM
0-
iH
T* O rO CM
CM -irs o-
rO 0* O rO
» CM CM •*
03 n- -1 o-
tt >J O 00
1 1 1 1
TH »-i 10 ls
n (M -0 o
TH TH O O
n THM oo
<• «r 10 CM
n on o
o
TH
(N CD V n
in o- 03 CD
n ron oo
M (N n
ro -H ro co
•o n «c M
o o o o
1 1 1 1
o- n o- o-
CM -HS> N
rO rOCM CM
o> Mrs «
•o -on n
o o o o
none
•H W CM
TH
< o- n o
n oo n *o
M M 00 M
<• n CM CM
n -o oo co
TH O 0- 00
.H TH O O
i i i i
oo n » -o
M -H on
o -o nin
(N (M CM CM
•0 N -O N
IO O IO O
TH TH CM
o
(N
oo *• TH s)
s> M rs is
«T N T 03
T M CM TH
•0 «• TH CM
(M O 9- 03
1 1 1 1
o. j rg (N
IO O IO O
•-i
« o rs -o
O 00 IOP>
OD N O IO
M N CJ rt
n M nn
o o- oo rs
v* O O O
i i i i
n o T o-
o o CD <
o -o nn
0- M -00-
o o o-oo
rt rH OO
n o no
*H «^ f 4
CM
0000 -0 •O
n CM oo rs
n 10 o* n
V M CM (N
n N o n 10
IN CM fM N
N rf 0 00
n «r o N N rj
m*o ^ rs
0. r-l -0 rt
«• V M M
rs oo «r oo
-o ~o ~o n
i i i i
•O *-4 v^ 00
CMO- -0 i
IS -0 -0 -O
O S3 0* C*-
ts rs rs N
100 n o
n
O 0* O -H
COM fO 00
N CM 0- -O
T v n f)
0-M * f)
»n n n
i i i i
COM » 0-
Mfr N *
O 0* 0* 0*
o» «r M
nn n n
no n o
•4 
o rs CM n
•o -o o n
» n n CM
rs n «• »
i i i i
n n is rs
n o- *on
n (M CM CM
0 100 -0
•o -o -o in
n o n o
.* « CM
»
** ro n 
-o rs -o-<
o o o o
n o n o
T
n -o »oo
ro 
i i i i
ro ro (Nio
o >o -o
CMS) 00 O
TH O 0* 0-
no n o
r< rt CM
-0




n oo is n
n CM o ro
V N CM CO
v ro n CM
O CM N 00
o o o- o-
i i i i
CM 0- S) <0
ro o oo n
-< 
00 0- CM -<
•o o n -
» ro ro 10
CM 0 0>fs
ro ro CM CM
•H — 1-1 TH
1 1 l 1
ro o> r-j n
CM O N ^>
O 0> 0> 0-
•«• -o » »
10 ro ro ro
n o n o
N
oo ro 03 o^
03 o rs oo
is o » o
» » roro
00 0- -0 -0
n n n n
i i i i
CM si v n
» o rs ro
si si nn
CM 0) OO
s> s> rs rs
n o n o
T< T-ICM
00




^- o- si —

0- O- CO CO
o o o o
1 1 1 1
s> 9. N n
sj » rj oo
0- 0- 0- CO
n« M o
D. 0- 0- 0-
OO 0 0
no n o
00
1H
TH n * CM
COS) N -0
03 ro 10 o
IO CM »-• -H
rs ro * n
IO O 0- CO
1 1 1 1
oo ro -a n
-ifs M O
n » » »
Ok 0> 10 SJ
» ro ro CM
n o n o
-i -* n
0-
                                            298

-------
o

oo
_i
i—i

00




•z^
o
i—i

•<
LU
u_
a:
Q_
00
oo
UJ

CO
o
00
o
— I
D-
ur>
ro
 I
CO
«=t
in
ii. «r
D
cc
to
M
0.
a CM
SSOLVE
1 C
M U
a
0

a
z
0

pH
...
O]
in
u. «r
i
i
to
M
Z
a CM
:>
_i
o
en
en TH
a
o
REGION
AU f
0000
o O O o
0000
1 1 1 1
fO CM CN CN
O 0 0 0
o o o o
N 00 00 00
N rs -o -o
to ro to ro
o o o o
CM CN TH TH
O O O O
1 1 1 1
•H -H M •«
CNNCN CN
O 0 O 0
1 1 1 1
CN 10 -O t
O O O TH
00 -H to
O 0- CO N
o ro o- o
TH TH TH tO
o to to in
is m o- rs
to «r in oo
CN tO IS so
00 0 TH
i i i i
rs is CM OK
0* V CM to
1 TH CN IO
1 1 1
CM to n •<
o o o o
o o o o
rs to o- in
O TH TH tN
o o o o
•o rs o- m
in o -o in
O TH -1 CN
•» TH «T TH
TH to 03 (M
to T in oo
to in rs o-
o o o o
o o o o
1 1 1 1
•o to CD -o
H CN
to ro to to
o o o o
1 1 1 1
«T CN TH CN
•0 -0 ~0 -0
0000
1 1 1 1
CN to •» in
o o o o
•C 00 TH •«•
O O TH TH
co iii o in
to «r in in
CO CN tO CN
-0 CO 0- O
TH TH TH CN
CN to <-r -o
o o o o
1 1 1 1
•o in •«• CN
to o «r
TH -H CN tO
o o o o
O O CN tO
O O TH tO
O TH TH TH
to in -o rs
o o o o
o o o o
1 1 1 1
o- in -H o
O O O TH
o o o o
i i
in o in o
TH TH CM
in
o o o o
o o o o
o o o o
i i i i
o o o o
O O 0 0
00 CO CO 00
•H co rs rs
TH o o o
0000
CN CN CN CM
o o o o
1 1 1 1
N -H O TH
•H O O O
o o o o
1 1
•T CO >0 CM
0 0 TH to
OK CO •»• 00
O TH IO -0
n -o co o-
TH ~0 fO CM
TH TH CN IO
in CD to o
tO •»• -0 GO
•«• o- co *o
O O TH to
1 1 1 1
oo N -H in
o rs -o is
TH TH CN IO
1 1 1 1
TH TH 0 0
o o o o
o o o o
in TH 
-------
O
o
LO
00
 I
in
u. ^
0
z
a:
zu
0.
a CN
SSOLWE
1 C
W U
a
o

a
z
o
M
RCOLA1
B4
a. at
z
flQ
-J
cn flo
en
a
0
0)
U. V
U.  n -o
O O TH CN
i i i i
in o in o
TH TH N
o
TH
OOOO
oooo
oooo
ro ro ro ro
oooo
oooo
in -o -o rs
03 03 00 00
ro ro ro ro
oooo
TH O O O
oooo
1 1 1 1
CN ro TH o
ro ro ro ro
i i i i
«r -o co ro
O O O TH
*r n rs CN
O O O TH
n CD CN in
0- CN -0 O
TH TH CN
rO -O CN "0

-------
O
o
Lf)

CO
 I
CO
in
u. *
1°
D
LC
n
M
0.
Q (M
:>
_i
o
U)
CO T*
s°
0

«
z
o
M
•X a)
_l
0
u
a:
a. m
z
M
A
U
^
_l
M a
Ul
w
a
«
ID

U. t
a
z
3
a:
n
M
z
a CM
CSSOLVt
U '
a
o
REGION
AU I
o o o o
o o o o
o o o o
1
N CM (N (N
O O O O
o o o o
nn -a -o
o o o o
M ro ro ro
o o o o
0- 0- 0- 0-
o o o o
o o o o
1 1 1 1
•o r- o- o-
to M M M
CM CM M CM
1 1 1 1
CM CM M M
O O O O
M CM M N
O O O O
 -o r-. m
0- -0 0- -I
TH n «r •«
CM (N M M
o o o o
1 1 1 1
•QP* CD O
•»• in -o co
i i i i
CM n t in
o o o o
o o o o
0 rf -i ~>
o o o o
r-. in M CN
CM M «r in
o o o o
n oo -o N
CM CM M «T
o o o o
n «r in -o
o o o o
o o o o
1 1 1 1
«r -H o- OK
O T< -i N
0 0 O O
1 1 1 1
in o in o
i-l »H CM
o-
1H
O O O O
o o o o
O O O o
1 1
n n M M
O O O o
o o o o
in in •<> -o
N -0 -0 •«
CM CM CM CM
O O O o
0 00 O
1 1 1 1
* in * in
CM CM CM CM
1 1 1 1
CM n «• «r
o o o o
CM CM n n
O O O o
o- CM in o
in N co o
*-(
n o» n CM
CM n in N
CM n n t
o o o o
1 1 1 1
is CM -o n
i i i i
CM n v m
o o o o
o o o o
O «H -1 »<
o o o o
n CM n -o
M •»• in -o
O O O o
in N N CM
O O rt M
O O O O
M fl- in N
o o o o
o o o o
1 1 1 1
»H rs -o o*
O O ^ CM
O 0 O O
1 1 1 1
tn o in o
•H r* CN
o
CM
o o o o
o o o o
o o o o
1
M M M «
0000
o o o o
c- in in *o
rx -o -r in in
r-. in -i o-
O rt CM CM
-< CM M »'
o o o o
1 1 1 1
1 1 1 1
CM CM M ^
o o o o
o o o o
O O -1 rt
o o o o
» O -0 M
CM M M ^~
O O O O
^ M N -0
in in in -o
o o o o
M o
O 0 O O
o o o o
1 1 1 1
n o in *«
o o o ^
o o o o
1 1 1
in o in o
•H « 01
in
CM
o o o o
O O O 0,
o o o o
^ 0 ^ -0 CM
CO 0- 0- O
M f N 0-
o o o o
1 1 1 1
1 t 1 1
*H CM M - rx N N
»H *n ^H r^
o o o o
M ^ ^0 00
O O 0 O
O O 0 O
1 1 1 1
n oo n ^
O O TH (N
o o o o
1 1 ) 1
in o in o
»-* *-H CM
•0
CM
o o o o
o o o o
o o o o
in in in in
o o o o
o o o o
v <* in in
in T M n
M M M n
o o o o
rf n in -o
o o o o
I I I I
o o  M O
O O rf N
i i i i
o tn co in
i i i i
•-I i-( O f*>
o o o o
O O 0 O
1 1
o ^ *H rg
o o o o
rs o« n n
GO o n in
0 rt vH rf
o rs -o in
o o ^ CM
O O 0 O
1
v in oo CM
o o o -H
O O O 0
1 1 1 1
-o n CM ^
o *H n M
o o o o
i i i i
Ul O 111 O
,-H TH CM
rv
N
                                   301

-------
 O

 oo
00
•
CQ
O
oo
sD
00
 I
CQ
in
b. T
o
z
2
DC
ro
M
a.
a CM
SSOLWE
1 C
M U
a
o

a>
z
o
M
i a
_i
o
u
en
0. a
Z
M
a)
Q
U
:>
_i
ui a
tn
M
a
a
in
u. *•
u. ^
a
z
D
cc
ro
z
a IN
>
_i
a
en
at -<
a
o
REGION
AU t
O O O O
0000
o o o o
1 1 1 1
o o o o
0000
o o o o
1 1 1
ps, 00 CO CO
in in in -o
o o o o
0000
N CM rt rt
O O O O
1 1 1 1
rt rt n -o
CM 
rt O rt rt
CD O -O rt
V -0 N O
CM n -a in
o o o -i
i i i i
rx o o in
rx 
rt CM CM n
CM M 0- N
•o oo o n
rt rt
0- .-I -0 -0
-o » rt a>
ro » in in
o o o -«
i i i i
ro o *• M
in co •-* in
1 1 rt rt
i i
ro* in -o
o o o o
o o o o
rx rx -o *•
o o o o
1 1 1 1
o o- •»• in
CM ro -o o-
o o o o
n H »< CM ro
o- n rs rs
ro oo CM •«
T in rs CD
ro oo rs in
o o *H m
i i i i
00 -0 CM -0
co ^ ro «r
i -H CM ro
i i i
rt rt O O
o o o o
o o o o
CM 0- 00 ^~
o o o o
1 1 1 1
o- rt o- rs
rs in *• rs
O rt CM M
in oo rs in
in -o -o oo
O T 00 CM
rt rt rt CM
T T ^- *•
o o o o
o o o o
1 1 1 1
rs oo 
I I I I
CM ro  rs rs
CM CM ro *
o o o o
ro oo CM o-
rt oo in rt
v * \n -a
CM M in -0
o o o o
o o o o
1 1 1 1
ro CM o- rs
O O O rt
O 0 O 0
1 1 1
in o in o
rt rt TJ
00
0 0 0 O
o o o o
o o o o
rt rt rt rt
o o o o
o o o o
1 1 1 1
•o rs rs rx

0000
rt o. m rx
rt O O O
o o o o
1 1 1 1
ro CM CM •e
in rs OK rt
in m in -o
i i i i
co rs ro o-
o rt ro ro
CM rs oo rx
n ro in in
«r rt in o-
» CM oo ro
rt CM CM rO
in oo in o
oo oo ro CD
n » in in
rs -o ro rx
o rt ro ro
lilt
00 -0 rt O
rt o 0- "O
rt CM (N rO
1 1 1 1
CM V in CM
o o o o
o o o o
1 1 1 1
*• CM o- in
o o o o
1 1 1 1
» rt rs »
in in o o
rt CM ^ -0
o- o rs rs
in ro o ro
OK CM in o-
ro ro v rs
o o o o
o o o o
1 1 1 1
N o- in in
in ro o- rt
o rt CN in
i i i i
in o in o
rt rt n
o-
                                         302

-------
o
o
sO

OO

 I
CQ
in

u. 
CO
M
a
0)
in
u. v
1*
3
M
Z
a M
[SSOLVi
U (
a
o
z
O 3
C9
U
CC
O O O O
o o o o
o o o o
0000
o o o o
1 1 1 1
•o -o is rs


o o o o
<• P) -« O
o o o o
o o o o
1 1 I 1
in rs co o-
in in in in
i i i i
•o rn IH n
O •< CM  in o in
» o o >r
O »H CM »
1 1 1 1
•0 CO M CD
co n o N
1 ^ M N
1 1 1
O O ^l -O
O O O O
o o o o
1
-0 O O- »
CN n CM CN
o o o o
1 1 1 1
-i rs v v
T-I *4 CM ro
-1 CM * O-
rs in co ro
in N CD o
n v >o •*
O O O -H
o o o o
1 1 1 1
in rs CN *H
ro rs ^r *•
O O *H CN
1 1 1 1
in o in o
o
«-4
O O O O
O O O 0
o o o o
o o o o
O 0 O 0
1 1 1 1
in -o -o rs

CN CM (N (N
o o o o
-< o o o
o o o o
1 1 1 1
rs is rs rs
ro ro ro ro
i i i i
«• -0 a) n
o o o IH
CD EN -0 rO
O -< •* CM
n in o CM
O- CM -0 O
** *4 CN
in r* o -i
»• H
1 1 1 1
CM M T S)
O O O O
oo ^ in CD
0 -i ^ -I
V CN CO T
•r in in -a
PI rt vH 05
* -o rs rs
CM n  rs m
M «• T in
i i i i
CM n » in
o o o o
O 0 O 0
M in *o N
o o o o
1 1 1 1
CM n «r in
O 0 O O
M rs o- -<
*• o- o
O O 0 O
o o o o
1 1 1 1
CM co in  -0 CO 0-
M -0 00 O
IH CM ro ro
O 0 O O
1 1 1 1
n co ^ CN
T in rs o
III!
CM ro o  o o o
CM o rs rs


o o o o
rs oo CD o-
o o o o
i i i i
rs vo •« rs
1 I I I
•H TH CM N
O O O O
rs o- rf v
O O r-l TH
rf -o 
-------





>^
— 1
•z.
O
I/)
	 1
t — i
O
oo
o
00
•z.
-
o
oo
s
o
— 1
CL
— 1
_J
•=c
u_
r^~
oo
i — i
i — i
i — i
•=r
LU
_J
CO
eC




.



o co
o o o- co
-1 .H o 0
in o in o
•H « n
IN
rs >o ^o tH
LI *r ^H rj
N o- «r o
ro r< M M
in r-i -o rg
M n n rj
TH *-4 T-t ^H
1 1 1 1
0- -0 rt rt
M o* in r*
CM 1-1 lH *H
rs IH o co
n o -o in
i i i i
n co o o
n co in o
n *< »< -H
CJ (M (M n
o o o- o>
N rs rs rs
in o in o
r-j
o c* co ^
o in tn rj

 rs
^- n n ri
O 00 O 0-
in T in T
i i i i
m ni o ^- o ^~

in n o
o ro o o
NO >0 -0 liT
in o in o
t-» »-i n
 CO fl- CO
^ >0 --« CO
(N O O O
o o- co rs
TH O O O
1 1 1 1
n rs ^ rs
-o n o in
-o -o ~o in
ro m n ro
~o rs n ^
o o o o
in o in o
o
in in in in
iii o in o
rt -i CM
in
co in -o -H
ro ON ON in
O *H NQ M
in  i i i
NO M n rs
o. rs «r o
Nfl -0 -0 NO
CM n ri CM
CM O CO N
rf rt O O
in o in o
NO
*-*
O 05 t f
ON ON NO NT

in «• CM o
i i i i
^ n -H in
o in o in
^ O 0 0-
O ^ ~" N
NO -o -o in
in o in o
-1 -H N
rs





rs ON in *r
CM n rs o-
T
co NO ro ON
in in in  in ~< n
«r m n 03
co rs rs NO
o- o- n -o
v n n cj
in o in o
-I rH CJ
0-
304

-------
 O

 oo
 o
 OO
 o;
 UJ
 QC
 Q-
 oo
 oo
 z
 •=£
 LU
 CO
 >-
 o
 00
o
_l
Q_
00
oo
 I
in

u. 0
O O rH -H
rH 00 ^ OK
ro o to to
rs o to rs
rH rH rH
in co rs o
^ rn o ro
to » in -o
* rs v o
O O rH CM
i i i i
rs o o N
O O -H rH
1 1 1 1
CM -0 rH 0-
m -o GO oo
1 1 1 1
o o o o
o o o o
0 -H CM CM
o o o o
rs «r  to ro oo
-o o> to oo
«r in rs o
O O O rH
O O O O
1 1 1 1
N ro «• o
o rH ro -o
o o o o
1 1 1
in o in o

o o o o
o o o o
o o o o
1 1 1 1
0 0 O 0
o o o o
N rs N rs
rH O O 0-
CM CM CM rH
0000
^0 N 00 CO
CM CM CM CM
O O O O
1 1 1 1
co rs -o rs
,0 -o -0 -0
0000
1 1 1 1
CM to in co
o o o o
oo rH -o ro
O rH rH CM
rH o- in o>
* v in in
oo in rs n
tS OK O rH
-H rH CM CM
CM «f *0 OK
o o o o
i i i i
O CM rH GO
*• in o -o
i i i i
o o o o
o o o o
IS CM fs CM
O rH rH C^
o o o o
-0 ro tM -H
o o o o
CM in ro rs
rH CM ^ *0
ro in *o oo
o o o o
o o o o
1 1 1 1
o- -r  o
in
o o o o
o o o o
0000
lilt
0000
o o o o
CO 03 CO CO
ro o o OK
o o o o
CM CM rH rH
n CM CM CM
o o o o
1 1 1 1
03 rH O O
o o o o
1 1 1 1
in ro o- o
o rH CM in
CN CO * -0
rH CM -0 O
ro oo ro in
CM oo is in
rH rH CM rO
t -4 O CO
•0 0 -H 0
n in rs o-
>o ^ ro ro
o rH ro in
i i i i
-H o rs co
CM O O rH
•H CM ro *•
i i i I
o o o o
o o o o
to a- *o CM
-H rH CM n
o o o o
O rH CN  ^ n in
ro » in OK
CM rs CM in
CM CM ro 10
in CM n OK
O rH CM ^I
till
N o in rs
rs rn o
CM to » in
o o o o
CO <0 00 -0
IS. CO 0* rH
O O O rH
ro 
-------
O
O
00
CO
CO

_j
a
Ul
Ul 4-4
a
0

n
z
o
RCOLAl
B'
ui n
a. CD
z
M
B
U
Ul CO
Ul
4-4
a
0)
u. T
o
z
cc
10
M
Z
O CM
SSOLVE
(1 t
o
o
REGION
AU t
O O O O
O O OO
O O O O
CM CM CM CM
0 O O O
O O O O
•c rs is rs
0-0 "CM
Tin in in
o o o o
in T ro CM
o o o o
o o o o
1 1 1 1
rs CD rs o-
CM IO T in
in in m in
i i i i
00 IS IS CM
O " 10 -0
OCM 0 T
•HCM in co
CM O CM IO
10 0- T 0-
" " CM CM
ro ro co CM
CM " 0- 00
rs rs o- in
o " ro -o
i i i i
TIS T "
"" CM 10
1 t 1 1
O " 10 CM
OO O "
0000
1
r> o -o o
" CM CM T
o o o o
" T " rs
!O O O CM
"CM tO T
ION -0 CM
" rs o- -o
00"IO
T in o- o-
O O O "
o o o o
1 1 1 1
TIO CO N
T O 0- 10
O " *• 4 IO
1 1 1 1
ui o in o
" " CM
o
o o o o
o o o o
o o o o
CM CM CM CM
o o o o
o o o o
•43 -O IS IS
CO 03 IS Is
ro 10 ro ro
o o o o
0-0-0-0-
o o o o
0 0 0 O
1 1 1 1
T in ro CM
-0 -0 -0 -0
10 IO IO IO
1 1 1 1
in o- -o CM
O O " IO
•0 0 -0 T
O " " IO
•0 CO 10 "
0 TO- T
" " " CM
in ro rs -a
•0 CM 03 in
T 03 -0 CM
o o " ro
1 1 1 1
TO-""
CO CM CO T
1 " " CM
1 1 1
" CM in o-
o o o o
o o o o
O T O- -0
" " " CM
0 00 O
o 10 is m
0- CM -0 CM
O " " CM
o " CM in
O CM -O CM
O O O "
1
T in oo 10
000"
o o o o
1 1 1 1
0- tO " IS
" T 00 tO
0 O 0 "
1 1 1 1
mono
" " CM
1-4
o o o o
o o o o
o o o o
1 1
10 T T T
O O 0 0
o o o o
•0 -0 -0 N
•o -a in in
M CM CM CM
O O O 0
T T in in
o o o o
1 1 1 1
0 " CM 10
is N rs is
1 1 1 1
ro in rs o-
0 O O 0
in 03 " T
O 0 " "
o- co in "
T in -o rs
O IO 10 T
10 T in -o
to in is o
o oo "
1 1 1 1
T T 10 "
T in ~e rs
1 1 1 1
CM ro T -o
o o o o
0 0 O 0
00 CM is "
O " " CM
o o o o
10 CM T N
to T in -o
0000
o- CM " rs
to T in -o
o o o o
10 T •<> 03
O OO 0
o o o o
1 1 1 1
O " CM tO
O 0 O 0
1 1 1 1
n o m o
" " CM
CM
"
o o o o
o o o o
o o o o
CM CM CM CM
o o o o
o o o o
in in -o -o
in in in in
ro to to to
0 O 0 0
rs is rs rs
0000
o o o o
1 1 1 1
O CM CM CM
to to ro to
10 ro to to
1 1 1 1
to in -o co
o o o o
T in -o o
0000
rs in to to
•0 03 O CM
O 0- N 03
CM T N 0
10 T -0 CO
o o o o
1 1 1 1
•0 T T IS
in rs o- "
III"
1
CM 10 T -0
O O 0 O
0000
N 0- 10 -0
O O " "
0000
" to rs to
T in -o oo
o o o o
in ro -o in
O O " IO
0 O O O
1
ro T in oo
0000
0000
1 1 1 1
•0 T -0 "
0 " CM T
o o o o
1 1 1 1
in o in o
" " CM
10
o o o o
o o o o
o o o o
CM CM CM CM
o o o o
o o o o
in in -o -o
CM CM CM CM
IO 10 10 10
o o o o
Is N IS Is
o o o o
o o o o
1 1 1 1
in -43 in T
rs rs is is
CM CM CM CM
1 1 1 1
to m rs o.
o o o o
T in -o oo
o o o o
rs o- CM T
" "
o- in co T
CM -0 0- 10
10 T -0 0-
o o o o
1 1 1 1
CM -0 " "
•0 03 " T
II""
1 1
CM ro in is
o o o o
o o o o
-0 0- IO -0
o o o o
10 •« CM O
T in rs o-
o o o o
T m o o
O O CM T
0 O O O
1
10 T -0 03
o o o o
o o o o
1 1 1 1
in in oo T
O " CM T
o o o o
1 1 1 1
in o in o
" " CM
"
o o o o
o o o o
o o o o
10 10 10 10
o o o o
o o o o
T in in •«
•o -o -o in
(M CM CM CM
o o o o
in -o -o -o
o o o o
1 1 1 1
in to " oo
T T T 10
CM CM CM CM
1 1 1 1
T IS " -0
00""
in rs o in
00""
in -o -o -o
•0 0- T "
0- O " "
T N O -0
O O " "
1 I 1 1
" O -0 CO
T in in in
1 1 1 1
" ro T rs
O O 0 O
o o o o
rs o ro rs
o o o o
0- 03 0- O"
T in -o rs
o o o o
M CM " -0
o o o o
o o o o
1 1
to in is o
o o o "
o o o o
1 1 1 1
" -0 " 00
O O " "
o o o o
1 1 1 1
in o in o
" " CM
in
o o o o
o o o o
o o o o
1 1 1 1
CM CM CM CM
o o o o
o o o o
N rs is rs
T T T IO
to n to ro
o o o o
in in -o -o
o o o o
1 1 1 1
to to in -o
in iii in in
i i i i
M CM 10 T
o o o o
in -o rs o
000"
in -o N N
to T in o-
rs o- " CM
CM to to in
o o o o
1 1 1 1
-o o in N
T -0 IS 00
1 1 1 1
CM 10 T in
o o o o
o o o o
in o- to -o
O O " "
o o o o
" oo -o in
CM CM IO T
o o o o
" in T -o
IO T *O CO
to T in rs
o o o o
o o o o
1 1 1 1
T CM O O
O O " CM
O O O O
1 1 1
in o in o
" " CM
"
o o o o
o o o o
o o o o
1 1 1 1
to to to ro
o o o o
o o o o
•« rs rs rs
•o in in in
CM CM CM CM
o o o o
ro T in in
CM CM CM CM
o o o o
i i i i
03 in IS 03
•O -0 -0 X)
1 1 1 1
01 CM IO T
0000
in is oo "
000"
ro T T in
o o o CM
T -0 N 03
CM CM IO in
o o o o
1 1 1 1
T IO CM O
ro T in -o
1 1 1 1
" CM 10 in
o o o o
o o o o
-0 O T 00
O " " "
o o o o
00 CM 03 T
" CM CM 10
O O O O
in -o rs CM
0- O " IO
CM T in N
o o o o
o o o o
1 1 1 1
O O O "
o o o o
1 1
in o in o
" " CM
IS
"
O O O O
o o o o
o o o o
CM CM CM CM
O 0 0 0
o o o o
in -o -o -0
o o o o
T T T T
O O O O
in in in in
o o o o
o o o o
i i i i
o " CM n
ro to ro to
i i i i
CM CM n T
o o o o
to ro to T
o o o o
in -o -o rs
rs o -o is
T rs 03 0-
CM CM IO T
O O O O
1 1 1 1
T -0 00 O
T in •« 03
1 1 1 1
CM CM 10 T
O O O O
O O O O
in co " T
O O " "
o o o o
oo rs -o is
CM IO T in
o o o o
o to 03 in
rs m o- "
O 0 O "
CM IO T in
0 0 0 O
o o o o
1 1 1 1
is in in rs
O " fM IO
0000
1 1 1 1
in o in o
" " CM
CO
                                      306

-------
00
OO
CO

_i
in a
O)
w
o
00
n
u. *•
o
z
3
£C
M
M
Z
a n
CSSOLVE
»1 (
a
o
REGION
AW t
OO O O
O o o O
o o o o
CMCM N (N
OO O 0
O O O O
10 -0 -0-0
OO OO
MM MM
OO 00
CO 00 CD 00
o o o o
o o o o
1 1 1 1
00 O »H **
(MM M M
CMCM CM CM
1 1 1 1
CVM » >C
OO 0 0
» * in -o
OO OO
MO NOO
•0 N 00 OK
rv ^ O 03
M o
o o o o
n » -o N
0000
O O OO
1 1 1 1
-o in -o oo
O •* CMM
o o o o
i i i i
mono
*4 v4 (N
0-
•H
O O O O
o o o o
o o o o
M CM N CM
O O O O
o o o o
in -o •« -o
rv N xj -o
N CM N CM
0 O 0 O
O 0- O O
o o o o
1 1 1 1
CM n M n
» » » «•
CM CM N CM
1 1 1 1
n in-o a
0 00 O
n n N a-
o o o o
rv m « ^
•0 O O CM
«H »-t
•-< *• in in
* -a 00 -i
M 
o o o o
O O 0 0
1 1 1 1
n —n o-
o »* CM n
o o o o
1 1 1 1
mono
•< -< CM
0
(M
O O O O
o o o o
o o o o
N MM M
O O O O
o o o o
in in -o -a
rv rs  o> n
O OO 
M n a CM
OOO-i
i i i i
ok n •a o*
t < rx a>
i i i i
CM M in N
o o o o
0 OO O
rv o T co
0^4*4^
O OO 0
M n in o-
«r in -o r\
o o o o
0- 0 rv CK
O *H ^ CM
O O O O
M ^ •« OK
O OO O
O OO O
till
M O O CM
O >-ICM n
o o o o
1 1 1 1
in o in o
***<(*
i+
CM
0 O OO
o o o o
o o o o
1
nnnn
0 O 00
0000
in -o -o -o
CM (V CMfM
nnnn
o o o o
n n f «•
o o o o
i i i i
OJ O rt M
OK O O O
rf CM CM CM
till
CM n in N
o o o o
in -o o- TH
O 0 O •<
•0 » O *
«• in MI MJ
N r% o -o
-« CM n 
-------
o


00
o
oo
o
t—H


<:
a:
LU
LU

03
o
00
o
—i
o_
CTl

OO

 I
in
u. *r
o
z
K
n
0.
a CN
[SSOLYE
:i c
a
u
CQ
z
o
t- o rs oo co
CN c-i ri rg
o o o o
iiii
o o o o
IIII
rg 10 in N
o o o o
rg oo in ro

ro o rs rs
o o o o
o o o o
IIII
o o o o
o o o o
4 1
m o in o
m
o o o o
o o o o
O 0 O O
IIII
0 O 0 0
o o o o
o o o o
IIII
CO CO CO CO
o o o o
o o o o
rg ri *-« -<
n rj rj CN
o o o o
1111
o o o o
IIII
tn ro o o-
o »H n v
-* ro o rg
rg T rs .-«
*-» co ^o  is, o* ro
o i-< rj 
•H *H rg rg
n ^ -o o
t in in -o
f "-• -i CO
rg n in co
o o o o
IIII
•T rg o -o
ro v in m
i i i i
ri ro T in
o o o o
o o o o
«r rs rs co
o o o o
IIII
in T t in
ri ro T in
O 0 O 0
co o- o rg
rs u") ro o
 CO
in -o -o in
0 O O O
IIII
^ fs, 00 *O
co o o- rj
co c- ro in
rs ri in ri
* 10 CN ro
-• ^ ^H r-j
O 0 0 -i
o o o o
IIII
•o rs rs rg
O ~* ro -o
iiii
VI o in o
o
                                               308

-------
en
ro
 i
in

u.  RUNOF
*3 ft
t-H
Q CN
SSOLV
U
a
o
REGION
AU (
o o o o
o o o o
o o o o
0 0 O 0
o o o o
till
^ rs rs rs

THTH TH TH
o o o o
O 0 0 O
O O 0 O
till
fs CD fs t>
IN ro «r in
in in in in
i i i i
rs N rs CN
o TH ro *o
rv TH rs ro
TH ro in CD
0- IS O O
CN co  CN
n ro ro ^
 ro
ro o CN CN
TH fN fN T
co t> rs is
-0 00 0 CN
-H TH
ro in oo ts
O O O TH
o o o o
1 1 t 1
 i i i
in o in o
TH TH CN
o
O O O O
o o o o
o o o o
0 0 O O
0 0 O O
1 1 1 1
•O -0 fs |S

(N CN (N tN
O O O O
0 0 0 O
0 0 0 O
1111
c
tN  CN in co
CN ro ro ro
n ro in rs
o o o o
o o o o
o T-I 0 O O
in is o CN
1 1 -H TH
1 1
n ro 
•T tn rs co
o o o o
oo TH m oo
r J ro ro ro
CN ro in rs
0000
O 0 O O
1 t 1 t
o TH IN 
0 0 0 O
i i i
1)1 O 111 O
TH TH CN
-0
o o o o
o o o o
o o o o
1 1 1 1
O 0 O 0
o o o o
1 1 1 1


o o o o
CN CN CN n
o o o o
1 1 1 1
co in N oo
•O -0 -0 -0
1111
o o o o
00 tN LI O-
O -« -< »«
in TH TS n
ro  rs
till
TH ri ro v
o o o o
o o o o
in in in in
o o o o
o o o o
i i i i
CD rj rs ro
-H n rj ro
o o o o
o- T oo ro
rj ro t- m
o o o o
o o o o
1 1 1 1
o o o o
0 O O O
1 1
in o r» o
TH *H tN
rs
0 0 O 0
O O 0 0
o o o o
o o o o
o o o o
1111

CN EN tN tN
0000
o o o o
O O 0 O
1 1 1 1
o •-* IN ro
lilt
o o o o
•o co o ro
O O TH TH
O 0* 00 *0
in in -o rx
* T 03 -O
-0 00 0- O
»-< (N N ro
O O O 0
till
rs co c- o
i i i i
TH CN ro «r
0 O 0 O
o o o o
•o in in *
o o o o
o o o o
1 1 1 1
ro is -o -o
CN ro 
-------
01
en
co
•=C.
in

u. t
o
z
D
cc
n
H
CL
a n
SSOLVE
1 C
M O
a
o

a
z
a
RCOLAl
B<
lu n
a. ID
z
M
a,
UJ
^
_j
o -i
en a
in
IH
a
A
n

u. *
0
z
3
a
M
t-t
Z
a (N
:>
_i
o
en -i
a
o
REGION
AU A
o o o o
o o o o
o o o o
o o o o
e> 0 O 0
1 1 1 1
in -o -o -o
03 05 00 00
(M (N CM IN
O O O O
CD 03 CO 00
O O O O
O O O O
t 1 1 1
CO O -H rf
rj n t*> n
rj N r*i (M
1 1 1 1
N n «T *o
o o o o
N o* -» 0 >0
 o o -<
i i i i
* •« CO O
•f in -c oo
i i i i
M n «• -o
O O O 0
o o o o
o o o o
o o o o
IIII
rt n in c^
^ iii *o rs
o o o o
rf O * O
co r4 in o-
(M n n n
o o o o
o o o o
till
M 0- CO O
o o o o
IIII
r) o in o
r* ^ (N
*-1
rj
0 O O 0
o o o o
o o o o
i
o o o o
o o o o
iiii
in -o -o •$
n n M n
N (M rj r<
o o o o
M n f o
in •« rx oo
o o o o
NOON
111 0 * N
n o n r; ^
n *• q- M
iiii
n -i — m
o o o o
o o o o
r-i rj r-j n
O 0 O O
IIII
«r n o o
o n -o co
r* r* ** ^*
N M N O
rj M ri CD
«r in ~o -o
0 0 O -"
• o o o o
iiii
N -c r* -c
o o o o
IIII
n o in o
-H x rj
IS
(N
                                        310

-------
O
I/O

CO

Q
Z
•=£
oo
•z.
<:
LLJ
CO

O
00


O
	I
O-
a:
D-
O
«*
 I
CO
s
N


3' REGION AU *

*-»
0- CO T O
» O CM CM
«H CO CO O
•o * M n
o- o- oo ~a
+ CM "1 O
M CM (N CM
1 1 1 1
CM-CM*
CD rs -o n
ro n n n
i i i i
in -t -o oo
in v n CM
CMCM CM CM
n o in o
f« rt CM
o
 n rs
CM M in rs
CM O *H f)
in » M CM
M oo rs rs
rs in* n
— — TH *H
1 1 1 1
M * -0 00
* M CM O
M ro ro ro
i i i i
0- O CMM
rs rs -am
1H — — —
mono
— »« CM
n o- o co
-< -0 0 0
rs o>  >o in
•< rs M -0
o- oo oo rs
M m to r1)
I i i i
co OK oo *
-< CM to *
•O -0 -0 -0
1 1 1 1
CM rf o- in
OK 0- CO CO
to to ro ro
in o in o
— -< CM
o
CM
N r< CM in
o- rs * *
OK CO O M
•o in in o -o
CO O O -0
is oo oo rs
nmnm
i i i i
*([)•<>*
N CD 0- O
•o -o -o rs
i i i i
o n N -o
CO CO 00 CO
ro ro ro ro
n o in o
*•< »•< CM
in
CM
oo oo m CM
rs OK CM ^H
co o in o
N N -0 •<
-0 -0 O rf
rt O O 0-
1 1 1 1
rs o> n rs
«• * 0 is
in in n in
i i i i
co in * n
* •* * t
n o n o
T* !•« CM
M
*H
oo ro «H oo
n o- CM o
^- «r oo n
•o n *• <•
oo * » *
oo oo rs is
CM CM  O
in in in -o
i i i i
N CM in -0
rs oo oo co
M n M ro
in o in o
<-* w CM
~o
CM
O CM -0 03
 -a
0- rf -0 N
•0 >o in in
•H * oo rs
in in in in
f*l M P) M
1 1 1 1
in »< -H «r
» rs o -<
* r »
oo * «r n
-o o in *<
rs rs -o -o
t-i rf o O
CM CM CM CM
1 1 1 1
co co rs »
o- CM ^- n
* in in in
i i i i
^H ro ro ^
CM fM CM CM
in o in o
~ -t fM
n
iH
n » « rs
•o n rs rf
rs ro o n
*-l 1H t^ iH
n o in o
•H « CM
o




in CM co CM
•o ro o> o-
o to rs ro
rs ~o in in
-< » 00 0-
rf O O- 0-
i i i i
o- n -o n
rs o- o- o
* T 
ro -o ^ 0
rs -o ~o n
rt 0- •« T
v ro ro ro
ro ro ro n
1 I I I
f -o ro to
o CM ro ro
•0 M) -0 -0
i i i i
CM •«• CM rf
^ 
00 0* Os 0*
*o -o  oo ro o
OK 0- 0- OK
to ro ro to
n o n o
*H ** CM
00
o OK n »
n •< CM o-
o in n rs
n ro CM IH
n o- » -o
co n * CM
«-t vH *H iH
1 t 1 1
CM n * to
CM CM CM CM
1 1 1 1
» O- CM »
o- rs rs ~c
r* T^ *H *H
in o in o
•H *H rj
O-
                                                311

-------
oo
o
oo
CO


CO
Qi

UJ
n.
oo
<
UJ
CO
o
oo
o
	i
D-

CJ3
D;
n_
oo
CO
o in >o
o rt CN ro
O 0 O O
1 1 1 1
O 0 rt rt
o o o o
1
in o in o
-
o o o o
o o o o
0 0 0 O
O O 0 O
o o o o
o- in o- co
O O 0 O
03 O- O O
o o o o
1 1 1 1
ro in o "O
0 0 O O
f in 03 rt
O O O rt
111 0 03 0
o N ro -o
•T i- in in
o- CN *o in
0- rt rt rt
<• -o o 
i i i i
c~ co n co
0 0 TH TH
o o o o
o o ** rj
o o o o
in o co o
o o o o
fs N TH CN
IN O CN 
-------
UJ
_l
CO
in

U- ^
o
M
M
M CN
SSQLVE
1 C
a
o

A
2;
O
_J
O
tJ
a:
LL. ffl
"Z
ffl
Q
Ui
-I
cn oa
tn
Q
o
m
in
U- 
o
CO
U) TH
o
z
O 3
M 
oo oo rs rs
o o o o
iii -o rs rs
o o o o
o o o o
-o o- in TH
O TH CN »

CN CN CN CN
O O O 0
N ro ro o-
f> o O D-
CN ro in rs
o o o o
o o o o
IIII
rs o- o- o
O O O TH
o o o o
IIII
in o iii o
1-4 TH CN
TH
O 0 O 0
o o o o
o o o o
o o o o
IIII
000-4
o o- rs rs
rs o -o -o
o o o o
ro ri ro ro
o o o o
o o o o
IIII
in TH iii TH
TH n TH CN
ro ro ro ro
iiii
•T 111 O CD
O O O O
rs rs GO o-
o o o o
(0 0- 0- 0-
CN CN CN fl
^- -o in ro
in in in in
ro v in rs
o o o o
tilt
^ in -o in
tilt
ro t in rs
o o o o
o o o o
ro n o ro
o o o o
0000
1 1
«• in -o -o
ri CN N CN
o o o o
o ro * iii
o o o o
CN ro in rs
o o o o
o o o o
till
N -0 111 *•
o o o o
o o o o
IIII
in o in o
-H TH n
in
o o o o
O 0 0 0
o o o o
o o o o
o o o o
1 I 1 1
•r 
-------
O
o
co
REGION DISSOLVED N IN RUNOFF DISSOLVED N IN PERCOLATION DISSOLVED P IN RUNOFF
AU AO Al A2 A3 At AS BO Bl B2 63 B4 B5 CO Cl C2 C3 C4 C5
0 0 O O
o o o o
o o o o
(M IN fV (M
o o o o
o o o o
1 1 1 1
O O -H -I
•« >o in ro
O O 0 O
00 0 O ~<
O rt -I -<
O 0 O O
-o CN f r*
o CM ro *r
i i i i
M o m -o
ro ««• in
o o o
1 1 1
CO O rf
1 1 1
rj ^ in
o o o
o o o
*r ~* (N
o o o
o o o
1 1
in rx o*
(N CN CN
o o o
(N o
o o o o
O 0 0 O
o ni in ri
ro ro in rx
i i i i
 1 1
o in o
^ ^ CM
                              314

-------
 oo
 _j
 i—i
 o
 oo

 CD

 Q

 -
 O
 LSI


 c
 _J
 a.
a:
a.
oo
co
If)

U. • in intn
rt rt rt rt
rt CM CM CM
O O O O
lilt
o- o rt n
0 rt rt rt
till
rt c-j ro ro
o o o o
o o o o
ro in rs o-
CM CM CJ CI
o o o o
co rs y) o
o o o o
o o o o
ro -<3  N rs

till
T 00 CM O
o o rt rj

-------
o
o

co -o *r o-
i i i i
in o rs o-
o -H -H n
o o o o
rs o ro t-i
o o o o
rj co is co
o o o o
r-j rj rs  in o- ^~
IS 03 00 0-
ro «r in ~o
o o o o
IIII

«• ri ri ro
ill)
ri ro n *r
o o o o
-O 03 O M
ri rj ro ro
rs o o -o
^r -o rs rs
ri ri ro fl-
o o o o
iiii
iiii
rH ro r f f
l l i i
n ro ro 
-------
CNJ
*±
 I
LU
CQ
•=C
in
u_ 
_j
en a
in
M
a
«
in
u. «r
u.  n ro m
i i i i
n «c ~o tx
o o o o
co « n in
o- -m *r
N to M n
CD n oo M
CD 0-0- 0
tH
n nin -o
o o o o
i i i i
•0 CO O n
** rt rj CM
i i i i
r-i n in >o
o o o o
O 0 O O
o -i to in
o o o o
•o coo n
0000
^ rj CN o
CO 0- 0- -H
O 0 O rf
n to in -o
o o o o
o o o o
1 1 1 1
[X IX fX (X
o o o o
O O 0 O
1 1 1 1
IIT o in o
« ** n
o
rj
o o o o
O O 0 O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
CN O O •-<

rj rj rj rj
o o o o
0 rt 00
o o o o
o o o o
n N tx rs
i i i i
to in >o rx
o o o o
co o rj *r
co cr> o *H
n (N to n
* a> rt*
fx N CO CO
r-j ro UT >o
o o o o
1 1 1 1
«• in in in
i i i i
(N ro in N
o o o o
o o o o
o ^ ^ ~o
o o o o
to -o co o-
o o o o
o* in tx n
in -o -o ix
o o o o
n ro o
o o o o
O 0 O O
o n in ri
ro ro in rx
i i i i
^ in *o co
o o o o
co ^ 
-------
 OO
c
oo
o
o
oo
LU
CQ
O
OO
Q_
oo
oo
«~t
 I
LU
	I
CO
K



)' REGION AU t



1* REGION AU *



REGION AU t
V O IX n
CMM CM.-*
*rx CMOO
rx >0 -0 m
in i-* ^ o
00 03 rxrx
n n n ro
lilt
0- M OM
ro n -orx
in n in in
i i i i
03 OK Ifl i«
00 CO 00 00
M M M M
in o no
iH rt CM
OK
iH
•« *• » in
OK in oo OK
co n in rx
n » ro CM
o- o» oo -a
•» (M ^O
CM CM CM CM
till
*< -o fx rx
CM 14 iH K<
1M 1-t 1-4 iH
1 1 1 1
n-o -«rx
n *• MCM
CM CM CM CM
no no
1-1 i*N
0
*H
CM CM •« -0
txO- CMtx
00 -0 03 O
» 10 CM CM
ro OD rx N
rx in <• ro
*4 «H vH r*
1 1 1 1
OK -a rx oo
o *< o o
oo oo
0- O CM M
rx rx •« in
*4 *< T* *-l
in o in o
M X CM
rx in »* OK
iH fS rt CM
in ix CM N
rx -o-o in
n N n -o
o> oo a> rx
M P) M M
i i i i
o n N o
CM n » -o
» V T +
i i i i
CM IM CM*!
Ok OK 00 03
M to M n
n o in o
rt rf CM
o
CM
T o- rx in
•o ro n n
rx -o oo IH
o in v «•
o -o -o -o
IH OK co rx
ro CM CM CM
i i i i
o- rx o> rx
•o « rx oo
CM CM CM CM
1 1 1 1
» -o n •«
T< O O OK
rO 10 1 CM
in o n o
^ -H CM
1-1
•H
V O 09 00
n o n o
•o -o oo ro
n «• ro ro
n n o *<
•o in » to
CM CM CM CM
1 1 t 1
-< o- v o
ro •« CM CM
CM CM CM CM
1 1 1 1
oo - M in
•o •« n <•
CM CM CM CM
in o in o
il »< CM
CM
o. com •«
rf OK-O ~*
•o mm o-
rx •«< in
n rtix *
t ^O 0
T *V *
1 1 1 1
CM CMfx "H
«r ins) OD
M MM n
i i i i
* mf) o-
rt rt»J O
•«• »» »
in on o
rt^ CM
i-l
CM
00 0-P) CM
O CMrx -i
O (N-0 CM
fx -oin in
in TIN co
n nn CM
n nn n
i i i i
*• o-o ^
in -ooo 
N -o -o n
•o in in n
00 CO CO 00
n n nn
i i i i
ro •» in o
oo o- -H n
* » n n
i i i i
03 O O CO
00 OK ». 00
n n nn
mono
»H -< CM
n
CM
•H n in *
ao o n n
-o o- n co
rx -o -o n
•0*00-1
-1 O O 0"
<• * » M
1 1 1 1
o- n -o «•
* in rx o-
n M n n
i i i i
oo in »M
•» » » »
n o n o
»H ^ CM
n
*-(
CM 00 CM -9
Ha nn
•* *t n o
•o in » »
03 » * *•
oo co rx rx
(M CM CM CM
1 1 1 1
n * CM o
00 CM V -0
rt CM M CM
1 1 1 1
rt » O -0
0- OK O- 00
CM CM CM CM
n o n o
** rt CM
«r
in o in o
ai -« ro o-
rt 0 OK OK OK
•0 00 M >
•o in in r
rt » 0} N
in in in n
n n n n
i i i i
^ N .-1 IH
>0 00 CM »
rt -< CM CM
1 1 1 1
M in oo m
in in n in
n nnn
in o n o
•« rt CM
rx
CM
O -< ^ OK
•« OK IN ro
* rx n OK
rx -o -c in
rt rt o O
CM (N CM CM
» » * »
1 1 1 1
OK 00 O »
•0 OK CM M
CM CM M M
1 1 1 1
•< ro ro r<
CM CM CM CM
» » » »
in o in o
rf rH CM
n
»-4
CM OK 0- -0
n ro -o n
in -H CM -o
» n CM rt
o co rx s3
rx ^ CM ^H
*4 v4 *M i-l
1 1 1 1
OK rt in  OK OK
ro ro ro n
in o n o
•< rt CM
CO
iH
in ro OK rx
rx n rx n
rx CM M n
^ ro CM T*
n o. v -i
co in ^ CM
i i i i
n n ro oo
-j o CM ro
oooo
i i i i
«T OK CM »
OK rx rx -o
n o n o
•H IH CM
O-
                                             318

-------
 O
 CO
 a
o
I—I
I—
o *o rv is

o-o-o-o.
o o o o
0- 0- 0- O-
o o o o
1 1 1 1
O- M 0- is
0000
«• -o o o 03 n o
m « in o-
TH TH TH
in rs -j- -.
CD CM CD rs
in o- OD  o ro TH
o o o o
1 1 1
in ro TH TH
o o o o
r*) o N rs
IS -3- -0 0-
rs co co co
is •«•«•
CM 
-------
O
o
CQ
in
u. 
_l
o
en
en TH
o
REGION
AU t
o o o o
o o o o
o o o o
o o o o
o o o o
1 1 1 1
in in -o -o
O -H TH O
CM CM CM CM
ro ro in in
CM CM CM CM
o o o o
1 1 1 1
ro ro o- OK
-0 N -0 fx
1 1 1 1
rx CM n in
o TH CM ^
TH rx o- o
TH TH CM -O
eo oo «r -H
CO O CM CM
in m CM o-
00 0- O 00
•o -H ro GO
O TH CM ^
1 1 1 1
00 TH O CN
in oo o o
1 1 TH TH
1 1
« GO -o 03
O O -H N
o o o o
-0 TH TH •»•
ro ro CM o
o o o o
1 1 1 1
ro o in CN
-o rx rx co
o o o o
o N .H ro
T rx o TH
-0 -0 IX Tx
in o o- CM
O "H —4 IO
o o o o
1 1 1 1
r in in
1 I i I
rj in o- in
o o o -H
o o o o
* ro o ro
ro ro ro CN
o o o o
1 1 1 1
C". T 0- -H
O O O O
^ ^ o ro
CN -O O TH
in in -o -o
* rx *H co
O O TH TH
o o o o
1 1 1 1
» O -0 CM
O O O -H
o o o o
1
m o m o
o o o o
o o o o
o o o o
ro ro ro ro
o o o o
o o o o
1 1 1 1
CN M M M
CM TH TH TH
O O O O
-H CN CN (O
CM CN CN CM
O O O O
1 1 1 1
o M ro o
CO CO CO 00
o o o o
1 1 1 1
ro «• in rx
o o o o
IX CD O CN
0 0 -H TH
TH ro in -o
ro ro ro ro
00 CO CO 00
ro * -o N
o o o o
1 1 1 1
CN in oo ^
n CN CM ro
i i i i
TH ro in rx
o o o o
o o o o
o o o o
1 1 1 1
o o o ci-
io to ro  -o o- in
rj 
-------
ca
 rv 
o o o o
O O O O
o o o o
1 1 1 1
O M -O CO
o o o o
OD co rs rj
in co o rj
ro n ^r «r
CJ  O
O O O TH
Ch O -t tH
r-j M ro M
(N O1 f^ liT
•o in u") in
ro jj-3 NO co
o o o o
I 1 i 1
O (X CO 0-
1 1 1 1
CN M < ^3
O O O O
o o o o
o o o o
1111
*r co o N
M ro 0 CO
o o o o
0 0 O 0
1 1 1 1
in ^ r-J o
O 0 O O
o o o o
4 t 4
in o in o
TH TH CM
iH
rj
0 O O O
o o o o
o o o o
CM r* TH TH
o o o o
o o o o
1 t t 1
TH rj r-j rj
w n t*j n
00 CO CO CO
0 0 O 0
rx --o ^ in
o o o o
i i i i
co o rs co
r-J rj f'j n
N 
-------
 OO
 o
 oo
 Q
 00
 •z.
 <:
 LU
 ca

 o
 oo

 2
 o

 a_
a_
oo
QQ
in

u. *•
o
z
0.
Q CM
3 t
jfnoss
a
o
u
CQ
Z
O
M

z
«
Ui
in a
in
a
n
u. ^-
o
z
ce
to
z 0 CK T
O O O rH
o o> o *•
(M CM «r n
o- in OM
ro o o *•
O O rn rH
o o o o
1 1 1 1
* rH CM rH
o o o o
o o o o
1 1
n o in o
rH rH CM
CM
o o o o
o o o o
o o o o
o o o o
0 0 0 O
in in in in

o o o o
o o o o
1 1 1 1
rH CM CM M
CM CM CM CM
O O O O
1 1 1 1
o o o o
i i i i
(M CM CM lO
O O O O
CM n >o >o
rH rH i-t rH
o -o
rH CM (M tO
o o o o
1 1 1 1
0- O rH CM
1 1 1 1
rH rH CM rO
O O O O
o o o o
rs o- CM O
O O O O
rH CM ro «r
o o o o
o o o o
1 1 1 1
n ro CM rH
o o o o
o o o o
till
n o in o
o o o o
o o o o
o o o o
o o o o
o o o o
in •«> -o *o

o o o o
o o o o
1 1 1 1
in >o rs co
CM n CM CM
o o o o
1 1 1 1
n in ro o*
o o o o
1 1 1 1
to in rs o
O 0 O rH
•o to o o-
2™
to ror rs rn
O O O rH
till
to «o ^ o
CM CM M to
1 1 1 1
O O O O
o o o o
rs » CM o
ro ^- n -0
o o o o
-o * ro r<
o o o o
«r o- -o oo
^ to CM O
o o o o
1 1 1 1
CM n rs o
O O O rH
O O O O
1 1 1 1
to o to rs
o o o o
o o o o
1 1
n o n o
rH rH CM
Hf
O O O O
o o o o
0000
0000
o o o o
in in in -o

o o o o
o o o o
in >o N rs
to to to to
0000
1 1 1 1
fO ^ CM 03
O O O O
1 1 1 1
to to m *o
o o o o

"O rs 03 03
CM to T 0
0000
11)1
n rs oo co
iiit
rH CM ^- n
o o o o
0000
o- to rs o
o o o o
(M N -I rH
O O O O
O CM 0* -C
o rH oi o
ri ro -o -o
rs ri ri -o
rH -0 O 00
rH rH fl CJ
rH (S -0 0-
rs •
1 rH rH CI
1 ! 1
in O rH 0*
o rH ci ro
O O 0 O
<• to rn in
to «r -o co
o o o o
-< rs ci co
IS 03 0 CI
O O -H ->
•0 O rH -0
O 0- CO O
O O —* fO
O rH Tl V
o o o o
till
rH ri M n
O O O rH
O O O O
1 1 1
n o in o
rH rH Tl
0-
                                                322

-------
o
o
LO

•51-
CQ

<
in

LL. 
_j
U) O>
to
t-t
o
o
«
in
u. »
u.  o M rt
rt rt rt
NO CM * rt
ro CD o o-
in o CM rs
O rt (M *
i i i i
o o- -o co
in -o a> oo
i i i i
v oo -o rs
O O "• CM
O O O O
000-0-0
CM M in -o
0000
n ••< in rt
-o rs rs aj
o o o o
ro is rs o-
rt o n •«
0000
1
* O- IS O
o o rt n
o o o o
1 1 1 1
» rt in »•
0 O O O
o o o o
1 1
mono
rt rt CM
o
rt
O O O O
o o o o
o o o o
o o o o
o o o o
n ro «• v
in in in in
o o o o
o o o o
rt CM ro CM
CM (N CM CM
o o o o
1 1 1 1
^ rs -o n
CM •-< rt CM
i i i i
n co CM o-
o o -< rt
CM -0 CM 0>
rt rt CM CM
0- 00 » 00
in -o rs rs
» n O CO
 -1
O O O O
1 1 1 1
» o in rt
o o o -H
o o o o
i i
mono
T-I rt CM
•H
O O O O
o o o o
o o o o
o o o o
o o o o
n M M M
iH *H ~4 »H
o o o o
o o o o
^ n rvi n
CM CM [M CM
o o o o
1 1 1 1
o CM n o
00 00 00 CO
o o o o
1 1 1 1
n T in is
o o o o
o m -o o-
O CM T in
M n M n
(N O N ^
^H CM CM n
CM n n -o
o o o o
i i i i
00 -< CM *
** CM CM CM
1 1 1 1
.-< n » -o
o o o o
o o o o
o- CM in o-
••< CM CM M
o o o o
O O -H O
nmn n
o o o o
rs oo rs in
*•< TH TH TH
o o o o
1 1 1 1
CM n n rs
o o o o
o o o o
1 1 1 1
n n o *
o o o o
o o o o
i i
in o n o
** -c CM

i i i i
^ m ^- *o
o o o o
o o o o
CM » -0 0-
o o o o
in co a- o
n M n »
o o o o
rs CM ~o a
n v «• »
o o o o
rf M in rs
o o o o
o o o o
1 1 1 1
rv N n <•
o o o o
o o o o
1 1 1 1
n o in o
•H 1 CM
n
*4
^i ^ O O
o o o o
o o o o
o o o o
o o o o
1 1 1 1
0- O O rt
in -o rs is
n CM CM r •!
o o o o
to n CM n
o o o o
o o o o
1 1 1 1
rv rn CM in
-o rs N rx
rt CM CM CM
i i i i
o o o o
0- CM «T N
o ** M n
M n ro ro
o- ^ rs o
rs ro co o-
ro » -o oo
0000
1 1 1 1
in -o m oo
i i i i
CM ro in rs
o o o o
o o o o
•H m in oo
o o o o
n co o -<
n ro » *•
o o o o
n o 01 -o
in -o -o -a
o o o o
CM ro n rs
o o o o
0 O 0 O
i i i i
rs -o -o «•
o o o o
o o o o
1 1 1 1
n o in o
~> -< n
»
*-i
o o o o
o o o o
o o o o
o o o o
o o o o
0- 0- O 0
00 0- CO 00
o o o o
o o o o
CM CM ro ro
O 0 O O
till
ro ro rs rt
O O 0- O
n n -* CM
i i i i
o o o o
ao rt ro iii
oo oo oo rs
n n CM CM
ro -o rs co
-o-o-o-o
ro ^ -o co
o o o o
i i i i

-------
O
o
LO

_i
(n »
en
M
o
o
m
IfJ
u. 1 (i
a
o
REGION
AU £
o o o o
o o o o
o o o o
o o o o
o o o o
o o o o
1 t 1 t
O rf rt N

in in -0 -O

till
n «r tn -o
o o o o
o- r-i n in
O « ^ rt
rx CN O **
(N p ro oo
IX GO CX t*
o o o o
TH M *• -0
o o o o
o o o o
1 1 1 1
o o o o
o o o o
1 1 1 1
in o in o
TH TH IN
o-
»-(
o o o o
o o o o
o o o o
O 0 O 0
o o o o
o o o o
o •-* ^ r-j
n in -o -o
o o o o
rf  0s 0-

i i t i
it in *o CD
O O O 0
o- n in rs
O rf n-l -<
o n ro ^~
m n fo M
tx » o- fl-
00 0- 0- O
TH
n «r in N
o o o o
1 1 1 1
-0 O- O ->
1 1 1 1
-H o *o in
o o o o
1 1 1 1
CO ^- CN O
0- 0 -1 CM

1 1 1 1
n f in -o
0 O 0 O
o- n in ix
O -1 •-< TH
fl- in -o ix
rj rj CN n
in rt 0
o o o o
o o o o
CM t -0 03
O O O O
rx n m rx
O 0 O O
o *r rx ^
O 0 0 -<
o o o o
CM M m IX
o o o o
o o o o
1 1 1 1
-1 « ^ o
o o o o
1 1 1 1
in o in o
-1 -1 CN
-0
CM
o o o o
o o o o
0 O O 0
o o o o
o o o o
o o o o
n to to T
o o o o
o o o o
0000
1
in ij") *o >o
N CN CN CM
o o o o
1 1 1 1
O O t 0-
fO CN ~H *H

1 1 1 1
in CD rf r T
rH tO tO &•
0- O 0- O
^ *0 &- PI
O O O -i
1 1 1 1
CN ^ rj ^H
.-< Ci CN CM
1 1 1 1
M If) 03 n
O O O TH
o o o o
to rx TH rx
o o o o
•O 0- O O
n to 1
O O O -I
o o o o
1 1 1 1
o o o o
o o o o
1 1
in o in o
•^ ** r-i
rx
P-I
                                    324

-------
 oo
 o
 GO
 CO
  Ci

 ' REGION AU *



REGION AU f
in M o- -o
•o o- n CM
N o. -o H » O-
r> in o -o
W CM CM t-(
in M o o
» (M -1 O
•H »-* »H *H
1 1 1 1
co rx «H o
•«-»••»• «
n w m M
I I i I
•« I- -H ix
in •»• * M
•M *H *H *H
in o in o
TH «H CM
CM rx o N
n in o •«
•*• N «• n
•o in in in
«<• ix CM -H
co rx rx rx
CM CM CM CM
1 1 1 1
0> 0. 0. o
»• t* CM n
in -0 -o -o
i I I i
00 (N -0 O
to o- o- o
(M rurj n
in o in o
•H -H CM
•0
rx o in -o
» * o n
co oo n o-
•a" w r-3 CM
o- in in n
m *o* m
CM CM rf .H
i i i i
w rxrx co
n CM -< o-
in in in ^
i i i i
03 •* in CD
* » M CM
CM CM CN CM
in o in o
»H »H CM
CM
o- rs oo o-
oo CM -o n
* 00 * CM
•o in in n
-< oo  CM CM CM
1 1 1 1
01 rs M o>
ro ^o oo co
•0-0-0-0
i i i i
•o CM in oo
O *H TH TH
n nn n
in o in o
rt r< CN
rs
00 -0 *• CM
CM 00 O O
» o in rvi
W fM »H t-»
O CD M m
in rf o- oo
* rfO 0
1 1 1 1
0- W fx ^H
in K> * n
n n w M
till
CM -0 *0 CO
•o in » M
in o in o
iH rt CM
•o
M M O •-<
rf in in in
03 CN 0- FS
 to in rv
^ TH in *
» O M O-
• -0 »
*• O 1 O
* oo in n
•o in n m
CM -0 -0 *•
o o o o
M n to n
I i I i
03 <• 0- -0
n oo o CM
-o -o (x rx
i i i i
N n N co
0 CM M n
ro M rt w
in o in o
rt r* CM
o>
1-f
CM O M »
n in -o oo
CM r o
•H CM n v
n n n n
i i i i
oo n n CD
•-I N *H CM
in in -o -o
i i i i
oo rx o- ix
rf M T in
n nn n
mono
-H -< r.
•o
CM
co n in rx
o CM ix in
CM in -H o
-o in in 
-------
                                  APPENDIX  B

        SEDIMENT AND  NUTRIENT  LOSS ESTIMATES  FROM  IRRIGATED AGRICULTURE
              B.  L. McNeal,  N.  K.  Whittlesey  and V. F. Obersinner
     Unlike the humid areas of the  continental  United  States, methods and
parameters for estimating soil  erosion  in  the  irrigated West are not well
developed.  Because of the diversity of crops,  slopes, irrigation  systems, and
soils which exist, no attempt has been  made in  this  report  to provide
generalized sediment and nutrient loss  estimates  for the entire region.
Instead, a simple methodology for estimating losses  is presented which
provides a basis for comparing projected losses from different irrigated areas
with or without changes in management.Where  verification  data are^available,
the report alscFpfripoTnts situations where current predictions are  inadequate
so that sediment and nutrient loss  estimates can  be  refined as the  data base
and our knowledge of basic processes improves.

DETERMINING IRRIGATION REQUIREMENTS

     Estimation of runoff and deep  percolation  water losses is essential to
the prediction of sediment and nutrient losses  from  irrigated lands.  A key
parameter in this regard is the on-farm irrigation efficiency, which can be
defined as the fraction of water applied to an  irrigated field that is stored
in the crop root zone.  The remainder of the water is  lost  to evaporation,
runoff, or deep percolation.   In other  words,

     r _ Qa -  Qe - Qr - Qd  _ QC_
     E "         ^         " Qa

where E  = on-farm irrigation efficiency
      Qa = quantity of water applied
      Qe = quantity of water evaporated during  application
      Qr = quantity of water which runs off
      Qd = quantity of water deep percolated
      Qc = quantity of water evapotranspired from the  crop  root zone
           (i.e., the net irrigation requirement).

Efficiency values are commonly expressed as percentages, but the fractional
basis is more  convenient for our purposes.  This  form  of efficiency function
differs from the overall system efficiency, which includes  seepage  losses from
delivery canals, laterals, and on-farm  ditches.  Such  losses, which are
operationally  difficult to distinguish  from deep  percolation, can  be extremely
important in terms of project-wide water requirements, localized groundwater
accumulation,  and salinity pickup (see  Grand Valley  Case Study, Planning
Manual, Section V).  Canal seepage losses  are  relatively unimportant with
respect to sediment, phosphorus, or nitrogen pickup, however.  Their main
effect on nitrogen values, for example, is to  dilute the nitrate


                                     326

-------
concentrations of subsurface return flows from irrigated fields.

     Values of Qe usually range from 5 to 15 percent for sprinkler-irrigated
fields.  A level of 10 percent has been assumed for this report.   Evaporative
losses during application have been assumed negligible for furrow-irrigated
fields.  Evaporative losses from the surfaces of recently wetted  (but empty)
furrows are included in the Qc values for a given crop and area.   Values of
Qr are assumed negligible for sprinkler-irrigated fields, though  localized
runoff can be substantial when water is applied at high rates to  soils of low
intake capacity.  A common example of such runoff can be observed near the
periphery of center-pivot irrigation systems on fine-textured soils.   It may
contribute to localized differences in Q^ for such fields, due to water
ponding as a result of the runoff.  Values of Qr are generally assumed to be
more easily measured for furrow-irrigated fields than are values  of Q^,
though this may not be true where well-designed subsurface drainage systems
intercept virtually all deep percolation from an irrigated field  without
appreciable pickup of canal seepage or deep percolation from adjacent fields.
In some cases, Qj values can be estimated for sprinkler-irrigated fields as
the difference between water applied and water calculated as evapotranspired
by the growing crop.  Still another method of estimating or cross-checking Qj
values, that of using parameters related to the uniformity and adequacy of
irrigation, will be discussed later in this section.

     On-farm irrigation efficiency is a concept widely used throughout the
irrigated West.  Efficiency estimates are commonly available for  the  major
crops and irrigation systems of a given physiographic region.   Validity of the
estimates ranges from carefully-researched numbers to values which may be
little more than educated guesses.  Reliable values will depend upon  crop,
irrigation system, slope, soil depth, soil texture, set time,  length  of run,
and irrigation stream size.

Rooting Zone, Depletable Moisture, and Number of Irrigations

     The crop root zone can be defined as the depth of soil  which is
penetrated by crop roots.  It may or may not include a limited depth  of soil
from which water is removed by upward flow into the actual root zone.   Typical
rooting depths for common irrigated crops range from 0.7 m (2  ft.) for peas,
beans, and potatoes to 1.3 m (4 ft.) for irrigated alfalfa (USDA, 1973).
Tabulated values generally assume that no obstructions to root growth are
present, such as hard pans, chemically indurated layers, or dry soil.

     Deep percolation is defined as that quantity of water which  moves
vertically through the soil below the crop root zone.  Though subsequent
upward movement is common under nonirrigated conditions, deep percolated
water is normally unavailable for crop use in well-irrigated areas.  The same
would not be true where deficit irrigation is practiced.

     Coarse-textured soils allow more rapid infiltration and percolation of
water than do fine-textured (high-clay) soils.  For this reason,  coarse-
textured soils have a larger potential for deep percolation, and  fine-textured
so1T_s_h_ave a larger potential  for surface runoff and erosion^   Soils  that are
extremeTy coarse-textured may even result in such large percolation losses


                                     327

-------
that furrow irrigation is no longer practical,  so sprinkler  irrigation  must be
used.

     Fine-textured soils hold more water than  do coarse-textured  soils.
Typical  water holding capacities for major soil  texture  classes range from
0.08 cm/cm (1 inch/ft.) for sands to 0.3-0.4 cm/cm (4  inches/ft.)  for clay
loams (USDA, 1973).   These water holding capacities are  derived from "field
capacity" measurements, with "field capacity"  defined  as the amount of  water
remaining in a soil  24 to 48 hours after a heavy irrigation  under  conditions
of free drainage.

     Depletable soil  moisture can be defined as the quantity of moisture  which
may be wfthdrawn from the root zone without resultant  crop moisture stress.
At its maximum, it would be the water held between "field capacity" and the
"permanent wilting point."  At the permanent wilting point,  however, soil
water moves so slowly that it becomes insufficient to  supply daily crop water
requirements.  For sustained economic crop production  under  irrigated
conditions, only about one-half of the total moisture  range  should be regarded
as truly depletable.   Unacceptable moisture stress would result  if the  wilting
point were approached prior to each irrigation.

   Table  B-l  presents  depletable  soil moisture  values for major crops and  soil
types of the Magic Valley, Idaho, and the Umatilla Area,  Oregon  (see case
studies A and E, Planning Manual, Section V).   The values were computed using
the relationship:

     D = k(r)(w)

where D = depletable soil moisture in cm (inches)
      k = a constant equal to 0.5 for all crops except potatoes,  where  it is
          set equal  to 0.33
      r = crop rooting depth in meters (feet)
      w = soil water holding capacity in cm/meter (inches per foot).

     Irrigation frequency and number of irrigations per season are determined
by the time required for depletable moisture to be extracted from the crop
root zorie^  Under ideal conditions, shairow-"Footed crops or~crops grown in
coarse-textured soils would be irrigated more  frequently than deep-rooted
crops or crops grown in fine-textured soils.  The relationship for determining
number of irrigations (F) is:

     F = QC/D
where Qc =
       D =
seasonal  net irrigation requirement of the crop in cm (inches)
depletable soil  moisture in cm (inches).
     In practice, factors such as water needs by other crops on the same farm
or in the same area, water availability, needs of water for wind erosion
control or for promoting selective crop or weed emergence, individual
preference for light irrigations versus heavy irrigations, and availability of
irrigation labor are also important in determining irrigation frequency.
Although scientific irrigation scheduling is becoming increasingly more common

                                      328

-------
 TABLE  B-l.    ESTIMATED DEPLETABLE SOIL MOISTURE VALUES FOR MAJOR CROPS AMD
              SOIL TYPES  IN THE MAGIC VALLEY  (IDAHO) AND UMATILLA (OREGON)
              AREAS  (SEE  CASE STUDIES D & E,  PLANNING MANUAL, SECTION V)


Crop

Alfalfa
Small grains
Pasture
Peas
Field corn
Sugar beets
Dry beans
Potatoes



Silt loam
or loam

15.85 (6.24)
11.89 (4.68)
11.89 (4.68)
7.92 (3.12)
13.87 (5.46)
13.87 (5.46)
7.92 (3.12)
5.28 (2.08)


Soil type
Sandy
loam

10.36 (4.08)
7.77 (3.06)
7.77 (3.06)
5.18 (2.04)
9.07 (3.57)
9.07 (3.57)
5.18 (2.04)
3.45 (1.36)



Sand

5.49 (2.16)
4.11 (1.62)
4.11 (1.62)
2.74 (1.08)
4.80 (1.89)
4.80 (1.89)
2.74 (1.08)
1.83 (0.72)

NOTE:  Based on an assumption that 50  percent  of  soil water  holding capacity
       is readily available for all  crops  except  potatoes, for which  the value
       is only 33 percent.


throughout the irrigated West,  there remain  considerable  differences  between
growers as to when a given  crop is judged  ready for  irrigation.  At present,
irrigation frequency generally  remains a highly subjective determination.

Length of Set, Stream Size, and Length of  Run

     The time period over which water  is continuously applied to the  field by
furrow or sprinkler (not including center-pivot)  irrigation  can be defined as
the length of set.  Coarse-textured soils  or shallow-rooted  crops normally
require a shorter length of set (but more  frequent irrigations) than  do fine-
textured soils or deep-rooted crops.

     In practice, the length of set is determined as much by convenience as by
exact field needs.  The most common lengths  of set are  12 or 24 hours, so that
irrigation lines, or siphon tubes, can be  changed at a  specified time or times


                                     329

-------
each day.  A less common length of set,  for fine-textured soils,  deep-rooted
crops, or sprinkler lines which apply water at uncommonly low rates,  is 48
hours.  For center-pivot systems,  care is usually  taken to ensure that a
single revolution is completed in  other  than a 12-,  24-,  36-, or  48-hour
period.  This is done to prevent recurring application of water to a  given
part of the field at the same time each  day.  Less water remains  in the root
zone following mid-day irrigation  (because of concurrent evaporation)  than
following irrigation at other times.

     Stream size normally refers to the  size of irrigation water  stream
delivered to the head of irrigation furrows.  Because of infiltration  along
the furrow, it differs markedly from the size of stream flowing from  the
tail-end of that same furrow.  Stream size is an important factor affecting
furrow advance rate (the velocity  at which the initial water stream moves
down a previously dry furrow).  A  larger stream size results in a faster
furrow advance rate at a given site,  other factors remaining constant.

     Fields with steeper slopes, finer-textured soils, or relatively  smooth
furrow surfaces all result in greater furrow advance rates.   Conversely,
recently tilled furrows result in  slower furrow advance rates.  A shorter
period of furrow advance to the end of the field results in less  deep  plFrco-
lation, since the head of the field is then being  irrigated for IT shorter
time in relation to the total length of  set.Hence, the uniformity of appli-
cation isTnc~reased~.A faster furrow advance rate also results in greater
runoff, however.  The optimal furrow advance rate  is one which minimizes the
sum of deep percolation and runoff losses.  This is  commonly established as
the advance rate for which the total  advance time  is approximately one-fourth
of the length of set (e.g., 5 to 7 hours for a 24-hour set).  An  alternative
approach is to use cut-back irrigation,  where a large stream size is  used to
push the stream through to the end of the furrow in  minimal  time, and  therf
the stream size is cut back to minimize  runoff and erosionT

     The length of an irrigation furrow  from top to  bottom of the field is
termed the length of run.  The shorter the length  of run, the shorter  the
furrow advance time, other factors remaining constant.  Use of a  shorter
length of run also allows the use  of a smaller stream size,  which implies a
slower furrow advance rate and reduced runoff losses.  Hence, the use  of a
shorter length of run can reduce both deep percolation and runoff, and
increase irrigation efficiency.

Coefficient of Uniformity and Adequacy of Irrigation

     Any system of irrigation, whether it be furrow  or sprinkler, results in
nonuniform application of water over the field surface.  In practice,  for
example, considerably more deep percolation occurs immediately beneath
irrigation furrows than beneath adjacent crop rows,  particularly  on coarse-
textured soils.  In addition, the  top portions of  furrow-irrigated fields
generally receive more water than  do the bottom portions, producing greater
deep percolation.  Under sprinkler irrigation, overlapping sprinkler  patterns
result in double applications to some parts of the field, while other  portions
receive less than a full irrigation.   Variations in  sprinkler application
uniformity are often described by  the ^coefficient of'uniformity", with~a


                                      330

-------
value of 100 percent denoting completely uniform water application.   Vallies
for existing sprinkler systems are commonly in the range 60  to~8CTpercent.
Though the concept is less commonly used for furrow-irrigated fields,
uniformity coefficients in this case may be 50 to 60 percent or less.
Improving the uniformity of water application results in a reduction in runoff
and deep percolation losses, and increased irrigation efficiency.

     The concept of "adequacy of irrigation" is not used extensively at
present for irrigation water management in the West.  With current emphasis
on variability of water application and nutrient leaching, however,  it is a
concept which may be used with increasing frequency in the years ahead.   The
term can be defined as the percentage of the root zone throughput a  field
which~is restored to field capacity during each irrigation.Obtaining an
adequacy level of 100 percent is not possible at present without incurring
substantial  percolation losses.   In order to meet crop water needs,  most
fields are irrigated to an adequacy level of 75 to 87.5 percent.  The  latter
level is commonly cited in Water and Power Resources Services (U.S.  Bureau  of
Reclamation) design criteria, but is rarely met in fields for which  variations
in water application are normally distributed.  The value of the crop, the
importance of uniform field appearance to the grower, and the availability  of
water and nutrients all interact to determine the appropriate adequacy level
for a given irrigated setting.

     Uniformity coefficient, adequacy level, and deep percolation (for
normally-distributed variations irfwater application! are uniquely inter-
rel a ted,~~~           ~            ~  ~~   ~~~~    If adequacy levels of 50
percent, 75 percent, and 87.5 percent are roughly equated to severely  under-
irrigated, "adequately" irrigated, and somewhat over-irrigated conditions,
respectively, the interrelationship can be used as an alternative method of
estimating deep percolation losses for nitrate leaching estimates.

     In assigning a proper adequacy level, careful  consideration should be
given to portions of the field which are never irrigated to  mid-row  due to
convex field ends or inadequate set times.  Consideration should also  be given
to areas with reduced vegetative growth because of poorly designed or  wind-
distorted sprinkler patterns.

Irrigation Efficiency Estimates

     Sample estimates of furrow irrigation efficiencies for  major crops and
alternative irrigation systems in the Magic Valley (Idaho) area are  presented
in Table B-2  (see Planning Manual, Case  Stuay, Section'V).   I he base  for tnese
estimates was the "improved management"  efficiency estimates of Gossett (1975)
for a comparable area of south central  Washington.   It was felt that the 10-
year time span between Gossett1s data base and recent studies (Obersinner
1979; McNeal, Whittlesey, and Obersinner 1980) warranted use of Gossett1s
"improved management" values over his "present management" estimates.
Gossett1s values also constituted a more complete data set than the  data
available from other sources (Whittlesey and Allison 1971; Kraft 1975;
Fitzsimmons et al.  1978).  Gossett1s values represented approximately  the
mid-range of published estimates for the areas and crops in  question.
                                     331

-------
TABLE B-2.    ESTIMATED IRRIGATION EFFICIENCIES FOR MAJOR CROPS AND ALTERNATIVE
             IRRIGATION SYSTEMS IN THE MAGIC VALLEY (IDAHO) AREA
                                      Irrigation system*
Crop
PFRW
IFRW
CTBK
PMPBK
GPIPE
MLTST
SDRL

Alfalfa
Small grains
Pasture
Peas
Field corn
Sugar beets
Dry beans
Potatoes


57.5
50.0
50.0
47.5
45.0
45.0
37.5
32.5


62.5
55.0
55.0
52.5
50.0
50.0
42.5
37.5
- - - - fr
\\
72.5
65.0
65.0
62.5
60.0
60.0
52.5
47.5
)erce
77.1
66.7
67.6
62.7
69.2
69.2
57.0
50.0
n±\ ' - - - -

77.5
70.0
70.0
67.5
65.0
65.0
57.5
52.5


92.5
85.0
85.0
82.5
90.0
90.0
82.5
77.5


75.0
70.0
70.0
62.5
72.5
72.5
62.5
60.0

NOTE: Assumes
* PFRW - Pre<
silt loam
;ent furrov
and loam
\i 5v stem
soils with
r
0.5
CTST
percent to 2
- Automatic
percent
mul ti-se
slopes.
?t svstem
    IFRW - Improved furrow system
    CTBK - Cutback irrigation system
   PMPBK - Pump-back furrow system
   GPIPE - Automatic gated pipe system
                           SDRL - Side-roll  sprinkler system
     Having an estimate of efficiency also gives an estimate of total  water
loss.  The difficulty comes in dividing losses between runoff and deep perco-
lation.  Runoff losses are at least measurable for verification purposes
(though often not conveniently), so values of runoff will  commonly be esti-
mated and deep percolation will  be taken as the remainder of the total loss
value.  Carter (personal communication) estimates that runoff values asso-
ciated with furrow irrigation in the Magic Valley (Idaho)  area are typically
in the range of 30 to 40 percent, whereas Worstell (personal communication)
estimates runoff values for the same area at 20 percent for close-growing
crops and 30 percent for row crops.  Based on these values, runoff estimates
of 25 percent and 35 percent were used in this report for close-growing crops
and row crops, relp'ectively.  Different values could be substituted for other
areas, soil typ~efsV etc.  WTth few exceptions, attempts will not be made to
                                      332

-------
refine estimates of efficiency,  runoff,  or deep percolation  to  closer  than  -^5
percent, because of the uncertainties of existing  data.

     Runoff estimates were next  deducted from irrigation  efficiency  estimates
(expressed as percentages) to give estimates of deep  percolation.  Deep
percolation should increase,  however, as crop rooting depth  decreases.   It  was
necessary to slightly adjust  some of the efficiency  values in order  to yield
this desired relationship with crop rooting depth, while  still  keeping the
efficiency estimates within the  overall  range of values reported  by  Gossett.
The efficiency estimates were adjusted instead of  the runoff values  since more
confidence was felt in the latter.  Resultant runoff  and  deep percolation
values for the Magic Valley (Idaho) area are given in the first column of
Table B-3.

     Efficiency values for an "improved" furrow (IFRW)  system were obtained
from the base-level values by adding 5 percent to  each  furrow efficiency
estimate in order to arrive at a corresponding value  for  an  "improved" furrow
system.  It was assumed that  the decrease in losses  was divided evenly between
runoff and deep percolation.

     Efficiency values for the cutback (CTBK) system  were estimated  in the
same manner, with a 15 percent increase  in efficiency over the  base  level
efficiency being assumed.  Two-thirds (10 percent) of the increase was
attributed to decreased runoff losses, and 5 percent  was  attributed  to
decreased deep percolation.

     Changes in efficiency and losses for the gated  pipe  (GPIPE)  system were
assumed to be the sum of those for the improved furrow  and cutback systems,
since the gated pipe system has  features of each.  Therefore, the irrigation
efficiency, runoff, and deep  percolation estimates for  this  system were
changed by 20 percent, 12.5 percent, and 7.5 percent, respectively.

     For the multi-set (MLTST) irrigation system,  according  to  Worstell
(1976), irrigation efficiencies  above 90 percent are  possible.   In order to
achieve at least this level for  several  crops, 35  percent and 45  percent were
added to the efficiency values of the present furrow  system  for close-growing
and row crops, respectively.   Runoff losses for multi-set systems were esti-
mated to be 5 percent of the  water applied, with deep percolation assumed  to
account for the remainder of  the losses.

     Gossett (1975) used U.S. Bureau of Reclamation  data  from central
Washington to derive estimates of efficiencies for various crops  when  using
side-roll sprinkler systems.   Between-crop variations arose  primarily  from
differences in crop rooting depth.  Published efficiency  estimates for side-
roll systems range from 65 to 75 percent, which is close  to  Gossett1 s  range of
59.3 to 74.7 percent.  On this basis, Gossett1s estimates for a well-managed
side-roll system were used in this report.  Runoff losses from  sprinkler-
irrigated fields were assumed to be zero, and 10 percent  of  the app1ied~water
was assumed to be lost as spray  evaporation and wind  drift.  Deep percolation
was estimated by deducting wind  and evaporation losses  from  total losses for
the sprinkler systems.
                                     333

-------
TABLE B-3.    ESTIMATED PERCENT RUNOFF AND DEEP PERCOLATION FOR MAJOR CROPS
             AND ALTERNATIVE IRRIGATION SYSTEMS IN THE MAPIC VALLEY
             (IDAHO) AREA

Irrigation
Crop
Row
PFRW IFRW

35.0 32.5
Close-growing 25.0 22.5
Alfalfa 17.5 15.0
Small grains 25.0 22.5
Pasture
Peas
Field corn
Sugar beets
Dry beans
Potatoes
25.0 22.5
27.5 25.0
20.0 17.5
20.0 17.5
27.5 25.0
32.5 30.0
CTBK

25.0
15.0
12.5
20.0
20.0
22.5
15.0
15.0
22.5
27.5
PMPBK
- Runoff
0.0
0.0
Percolati
22.9
33.3
33.3
37.3
30.8
30.8
43.0
50.0
sy stem*
GPIPE
m_ _ _ _
22.5
12.5
nn (°/~\ - -
10.0
17.5
17.5
20.0
12.5
12.5
20.0
25.0

MLTST

5.0
5.0
2.5
10.0
10.0
12.5
5.0
5.0
12.5
17.5

SDRL

0.0
0.0
15.0
20.0
20.0
27.5
17.5
17.5
27.5
30.0

NOTE: Assumes silt loam and loam
* PFRW -
IFRW -
CTBK -
PMPBK -
GPIPE -
soils
Present furrow system
Improved furrow system
Cutback irrigation system
Pump-back furrow system
Automatic gated pipe system
with 0.5
MLTST
SDRL
percent to 2
- Automatic
- Side-roll
percent
slopes.
multi-set system
sprinkler system
     The range in estimated efficiency values for center-pivot systems  is
commonly from 75 to 85 percent, with a large  number of estimates  concentrated
in the range from 80 to 82 percent.   On this  basis, an efficiency value of 80
percent was used for present center-pivot systems in the  Pacific  Northwest.
Field runoff was assumed to be zero  for such  systems, with spray  evaporation
and wind losses assumed equal  to 10  percent.   The remainder of the losses
(i.e., 10 percent) were attributed to deep percolation.
                                     334

-------
     Shearer (1978) indicated a variance of 7 percent in center-pivot system
efficiencies, part of which is due to differences in  management.   Busch (1978)
gave a range of 3 percent for center-pivot efficiencies, reflecting  differ-
ences in management.  An intermediate value of 5  percent was  assumed for the
improvement in efficiency as improved management  techniques are  applied to
center-pivot systems.  Spray evaporation and wind losses were assumed to
remain unchanged.

     The discerning reader will have noted an inconsistency between  the
technique used for assigning irrigation efficiencies  to the side-roll  and the
center-pivot sprinkler systems.  In one case, crop-specific differences
(largely due to differences in crop rooting depth)  were introduced;  in the
other, they were not.  One or the other of these  approaches should be adopted
consistently by personnel of a given planning group.   In the  absence of
definitive data, center-pivot irrigation efficiencies could be assumed to vary
from 85% (for alfalfa) to 75% or 70% (for potatoes),  by arranging  the crops
in the relative order of efficiencies listed for  side-roll  systems (Table B-3).

Effect of Texture and Slope on Irrigation Efficiency

     Since various soil  textures exist throughout the irrigated  West, it is
necessary to have some feeling for the effects of texture on  efficiency,
runoff, and deep percolation.

     Gossett1s (1975) estimates of furrow irrigation  efficiencies  show
negative adjustments (i.e., greater losses) for more  coarse-textured soils.
This is because his efficiency values were calculated as a positive  linear
function of depletable soil moisture, which decreases for coarse-textured
soils.  However, Gossett1s adjustments do not include texture-dependent
variations in infiltration rate or runoff losses.  Runoff losses decrease for
coarse-textured soils, which tends to offset the  increase in  deep  percolation.
Apparently, the Hagen (1978) efficiency estimates (based on data from Cali-
fornia) and the USDA (1973) estimates (based on data  from central  Washington)
already took into consideration these offsetting  trends, for  no  adjustment in
irrigation efficiency with soil texture was proposed.  Since  it  is felt that
the increase in deep percolation tends to be greater  than the decrease in
runoff as soils become more coarse-textured, however, a negative adjustment in
efficiency of 5 percent was used in this report as the dominant  soil  texture
was changed from silt loam to sandy loam.

     Hence, all efficiency values for base-level  (silt loam)  soils of the case
study area were reduced by 5 percent in order to  obtain corresponding irriga-
tion efficiency values for sandy^ loams.  The deep percolation values for silt
Teams or loams were also adjusted "upward by 5 percent in order to  obtain
corresponding values for sandy loams.  No soil-texture dependent adjustment
of runoff losses was required, though the sandy loam  soils were  treated as
less erosive per unit of runoff volume than their silt loam counterparts.

     Estimating the effects of field slope on irrigation efficiency,  runoff,
and deep percolation is also important.  Published values suggest  that
efficiencies of both furrow and sprinkler systems generally decrease as slope
increases, though sprinkler system efficiencies often do not  vary  until  after


                                     335

-------
the slope has been increased by 5 to 10 percent.   The  trend toward decreased
efficiencies is probably due to an increased probability of runoff from
steeper slopes.

     Control of furrow stream size is more difficult on steeper slopes, and
the grower tends to be generous in the stream size allocated,  so the  percent
runoff tends to increase.  The stream tends to run down the furrow more
rapidly on steeper slopes, however, resulting in  a smaller wetted cross
section.  This should operate to decrease deep percolation, and may in some
cases approximately balance the increased runoff.   For this report, furrow
irrigation efficiency was assumed to remain unchanged  in going from a 0.5-2.0
percent slope class to a 2-5 percent slope classT   Likewise, no adjustment in
efficiency is generally reqifired for sprTnkl~er~Trrigation systems experiencing
this same change in slope class.  Therefore, efficiency values for the 0-2
percent slope class were assumed to remain valid  for slopes of 2-5 percent in
all cases.  However, the runoff and deep percolation values for the base-level
(0-2 percent slope class) conditions were respectively'increased by 5 percent
and decreased by^~^rcenfTdFTLrrro~v7~irrTgation  systems on slopes of 2-5~
percent.

Net Irrigation Requirements

     Crop consumptive use is defined as the amount of water transpired during
plant growth plus that evaporatecT from the soil stTrface and foliage of the
area occupied bY~the~growing plant (Sutter and Corey,  1970).The net irri-
gation requirement is commonly defined as crop consumptive use less seasonal
precipitation (Watts et al., 1968).  It does not  consider moisture stored in
the root zone at the beginning of the growing season.   As a result, estimates
of net irrigation requirement somewhat overstate  seasonal crop needs for
irrigation water, especially if "deficit" irrigation (using previously stored
soil moisture) is to be practiced.  Despite this, net irrigation requirement
estimates are commonly used, because other appropriate water-use data are
limited.

     Net irrigation requirements are often based  upon a modified Blaney-
Criddle procedure, which considers mean daily temperature, hours of daylight,
and crop characteristics.   Estimates commonly reflect mean seasonal net
irrigation requirements, requirements for the eighth driest year out of ten,
or maximum net irrigation requirements for the period of record.

     According to Wright (personal communication), the Blaney-Criddle method
underestimates crop consumptive needs because the formula underestimates
evaporation.  Such underestimation occurs because differences in elevation are
not considered in the approach (with more evaporation occurring at higher
elevations) and also because the method uses mean daily temperatures, whereas
daytime temperatures alone  tend to determine the  amount of evaporation.

     Our  study made use of  Wright's irrigation requirement estimates for
alfalfa,  spring grain, peas, and  dry beans (Table B-4).  As Wright did not at
the time have estimates for other crops of the Magic Valley (Idaho) study
area, Blaney-Criddle maximum estimates for the period of record were used
since they were closest to  Wright's estimates for the above four crops (Sutter


                                      336

-------
 TABLE B-4.   SEASONAL NET  IRRIGATION  REQUIREMENTS  FOR  MAJOR CROPS  IN  THE
             MAGIC VALLEY  (IDAHO)  AND THE  UMATILLA (OREGON) AREAS
Crop
Magic Valley
Umatilla
                                         ha-cm/ha  (acre-inches/acre)
Alfalfa
Spring grain
Winter grain
Pasture
Peas
Field corn
Sugar beets
Dry beans
Early potatoes
Late potatoes
94 (37)
56 (22)
64 (25)
64 (25)
41 (16)
56 (22)
74 (29)
51 (20)
-- (--)
66 (26)
104 (41)
- (-)
64 (25)
-- (--)
- (--)
74 (29)
- (-)
53 (21)
71 (28)
94 (37)
and Corey 1970).  For the Umatilla area (Oregon)  study  area,  Vomocil's (1976)
irrigation requirement estimates were chosen to represent the best currently
available values for the area.   They are Blaney-Criddle estimates  for  the
eight driest years out of ten.

Estimates of Water Application  Requirements

     Once estimates are available for the quantity of water to be  applied  and
for the percent runoff and deep"percolation, it is ppssib1e~to obtain
estimates of the amount of runoff and the amount of deep percolation by simply
multiplying the appropriate terms together^Estimated  seasonal  water  appli-
cation requirements for major crops and alternative irrigation systems in
the Magic Valley (Idaho) and Umatilla (Oregon)  areas are presented in  Tables
B-5 and  B-6.

     To estimate efficiency, deep percolation,  and water application require-
ment values for pump-back (PMPBK) irrigation systems (which were not dealt
with earlier in this section),  quantities of deep percolation (Q,j)  were
assumed to be equivalent to those for the present furrow system.   These
                                     337

-------






<
LU
OO QC
Q- <£
O
C£ ' — •
O O
2C
o: ct
O Q
•-D i— i

^—
"~ >-
fy* 1 1 )
c 	 i
u — i
g:
i —
'Z. CJ
1 1 1 1 — 1
2: CD
1 1 1 -
Q_ OO
CL

f— i
DC i — t
1 1 i | —


"^C ' — '
LU | —
00 }

•r-
S-
S-
I-H











































*-yX
r r
oo






(/^ !
v /
I—
_i
2:






LU
f\
l_l_
t— 1
Q_
CD








N^*
CO
CL
21
Q-








•y^
CO
1—
^_5




,-y--
Li.
u_
KH







11^
tJl.
Li-
CL,
















CL
O
S_
o
1 CTiCMVOU3>OOOCMOO
^J-OOOOCOCMOO^J-OO«d-
1 «d"i-Hi— li— liOlOCMi— ICTi
CMCOCTiCTivOr^OOOO
1 i-H i-H i— 1
1

1
1 O
CCOOOr^r^LOrH^HLOCM
•i-«d-OOCOOOCMOO^l-OOLO
1 ^_» ^v- ^_^ **— ' •*_* *~^ - - •*~* ••— •
 O^ *^  CD O CU C -P
re) cu o -O re) o
<4- CD i- S- CU CL
i— c cu 3 -o s- aa
re ..- -P -p re>cucn>>-P
r — O--i- -p -p
>, to to
^ ^> ^>
to to
cu
• fl 1 \ C
to •!— cu cu
CU CL I/) , —
*— ^ | ^s
LJ- 1 —1C
O T3 T- C
1— CU -P •!-
tO 4-> t— S.
(O 3 CL
4-> CD E «/>
c~
CU O O i —
O T- T- i—
J- -P -P O
cu re) re) ^-
CL E E I
O O CU
CM -P -P T3
3 3 -r-
O < < 00
4_>
i i i
+j
C LU 1— _l
CU CL, OO Di
(_> 1— 1 |— Q
S- Q 	 1 00
CU CD 2!
CL

LO
•
O
.c
•p
'5
to
•^
to E
E -P E
O E CU ^> -p
i — CU 4-> to tO
•P i/> >,
T3 tO >, c tO
c >, to o
re)  -i— 3
f -P 0
E"» rt frt r
^ \J  M_ ••- j^
i— "O O
•i- -p cu -i C > 0 JD
cu o ret i
to t/> i_ ^3 CL
O) CU CL-P E
§S- E 3 3
Q- >— i O O-
to
to i i i i
^t
^g ^g NX NX
rv rv m m
LJ_ U- 1— Q-
LU Q- HH O 2:
1— 0-
O
Z -K
338

-------
 TABLE  B-6.   ESTIMATED  SEASONAL  WATER APPLICATION  REQUIREMENTS  FOR MAJOR  CROPS
             AND THE  CENTER-PIVOT
                                            Irrigation system
Crop
  PCP
ICP
Alfalfa

Winter grain

Field corn

Dry beans

Early potatoes

Late potatoes
- - ha-cm/ha (acre-inches/acre)  - -

130 (51)                    122 (48)

 79 (31)                     76 (30)

 91 (36)                     86 (34)

 66 (26)                     61 (24)

 89 (35)                     84 (33)

117 (46)                    112 (44)
NOTE:  Assumes sandy soils.


estimates were added to net irrigation requirement (Qc)  values in  order to
obtain water requirement values (Qa)  for the pump-back  system.   Hence,

     Qa = Qc + Qd

Efficiency values for the pump-back system (E)  were then obtained  as

     E = Qc/Qa

Values for percent deep percolation from the pump-back  system (P)  were
obtained as

     P = 100 - E,

because field runoff for the pump-back system was assumed equal  to zero.


II.  SEDIMENT AND PHOSPHORUS LOSSES

     Most phosphorus lost from irrigated croplands is associated with eroding
sediment.   Hence, this section will  dwell  in greatest detail  on  factors
affecting sediment erosion.
                                     339

-------
     Base-level  conditions have  been  assumed  as  follows:potatoes grown on a
silt-loam soil  at 1.5 percent slope,  employing an~8  gallon per nvTnute  stream
size (at the head ditch),  and producing  35  percent runoff  for a 24-hoUr
irrigation set.   This combination  of  conditions  is assumed to yield  approxi-
mately 40 metric tons per  hectare  of  sediment loss for  the_season, with8.2 mt
per ha lost during~e_ach of the first  3 TFrigations,2.7 mt per ha "lost during"
the next 5 irrigations, and 0^4~mt per  ha lost during each of the final 5
irrigations.  Phosphorus losses  have  been estimated  at  0.14% of sedimen~t~
losses.  Changes in sediment loss  are then  based upon changes from base~-1 eve 1
conditions.  Changes in sediment:phosphorus ratios will be necessary as the
approach is applied to other furrow-irrigated areas.

Slope and Stream-Size Effects

     The relation of stream size and  furrow slope to soil  erosion was  examined
by Gardner and Lauritzen (1946), Israel son  et al. (1946),  Evans and  Jensen
(1952), and Mech (1959).  Gardner  and Lauritzen  (1946)  attempted to  derive
equations for determining  minimal  erosive stream sizes  for various furrow
slopes on silt loam soils.  Israel son et al.  (1946)  claimed that erosion
increased as the square of the slope  (i.e., as  (slope)2)  for a silty clay
loam, with a less marked dependence (as  (siope)1*5)  for a  sandy loam and a
more marked dependence (as (slope)2-')  for  a  sand.   Fitzsimmons et al. (1978)
found that erosional losses from a bean  field in southern  Idaho corresponded
to a dependence on (slope)2-1 to (slope)3-4.  The relations all seemed to
fluctuate around (slope)2, and averaged  (slope)2-2 for  the above cases.  So
that a false sense of accuracy (and hence authenticity) was not placed on the
relation adopted, ^dependence of  erosion on  (slope)2 was  assumed for  this
report.  Subsequently, the base  sediment loss would  be"jdjusted by a factor
equal to (% sldpeT^/U.S)^, whicF~is  the ratio oT~th¥ square of the  actual
slope to the square of the base-level slope (Table B-7).

     Evans and Jensen (1952) formulated  an  equation  relating soil erosion to
the product of (slope)2-3  and (runoff)1-5.   In  the Boise  Valley of Idaho,
Fitzsimmons et al. (1978)  reported that  doubling the stream size (but
maintaining the same amount of water  applied) approximately doubled  both the
amounts of surface runoff  and sediment  loss.  This would  generally be  an
unrealistic approach, however, for irrigation is usually  carried out for a
specified set time (often  24 hours) rather  than  for  a specified quantity of
applied water.   Doubling both the  stream size and the total  amount of  water
applied increased sediment losses  four-fold in  this  same  study (i.e.,  sediment
loss depended on (stream size)2-0  under  more  normal  operating conditions).
Fitzsimmons et al. (1978)  also reported  sediment yields in the Magic Valley of
Idaho for another set of conditions which would  correspond to an erosion de-
pendence on (runoff volume or stream  size)3-6.   For  still  another  study  site,
Fitzsimmons et al. (1978)  reported an erosion dependence  on (runoff)1-^5.
There is obviously a considerable  spread in erosion  dependence on  stream size
or runoff volume.  The above exponents  average  2.3.   As with the previous
treatment of slope/erosion interactions, to avoid the conferring of  a  false
sense of accuracy, a dependence on (stream  size  or runoff volume)2-0 has
been assumed for the purposes of this report.  Appropriate mu 1 tipliers are
listed in Table B-8.
                                     340

-------
TABLE B-7.   MULTIPLIERS TO BASE-LEVEL IRRIGATED SEDIMENT LOSS VALUES TO ADJUST
             FOR FIELD SLOPE

Slope (%)
0.25
0.50
1.00
1.50
2.50
3.50
5.00
8.00

TABLE B-8. MULTIPLIERS TO BASE-LEVEL
FOR RUNOFF VOLUME

Slope (%)
40
35
30
25
20
15
10
5

Mul tip! ier
0.03
0.11
0.44
1.00
2.80
5.40
11.00
28.00

IRRIGATED SEDIMENT LOSS VALUES TO ADJUST

Mul tipl ier
1.30
1.00
0.73
0.51
0.33
0.18
0.08
0.02
                                      341

-------
Tillage and Set-Time Effects

     The relation of freshly disturbed furrows (Evans and Jensen  1952)  to
increased erosional  losses has been demonstrated  experimentally.   Greater  than
ten-fold decreases in erosion were noted by  Mech  and Smith  (1967)  between
initial and subsequent irrigations following reditching  operations.
Similarly, Fitzsimmons et al. (1978)  reported that over  one-third of  the
seasonal sediment loss occurred during a single preplant irrigation,  and that
loss from a seed corn field (which was cultivated several times)  was  over
50-fold the loss from an alfalfa field (which was cultivated  very little).
These workers also reported greater erosional  losses if  furrows were  compacted
than if not, though poor water distribution  and excessive deep percolation
generally occurred if the furrows were not compacted.  Brown  et al. (1974)
reported sharply reduced erosional losses after weeding  and refurrowing of  row
crops was stopped in the Magic Valley area of southern Idaho.  Unfortunately,
cultivation between irrigations is often necessary to break surface crusts  and
to maintain adequate water intake rates.  To account for tillage  effects on
erosion losses from irrigated fields, the approach of Gossett (1975)  has been
used for this report.Gossett assumed that  erosion losses  for each of  the
first three irrigations of a potato field in the  Yakima  Valley of Washington
were three times (300 percent of) the losses from each of the next five (mid-
season) irrigations, because of tillage preceding each early  season irriga-
tion.  He assumed that sediment losses during each of five  late-season  irriga-
tions were only 15 percent of those during each mid-season  irrigation.  This
approach requires adjustment if a given crop has  more, or fewer,  irrigations
following tillage operations than assumed by Gossett.  For  a  wheat crop, for
example, only one "early season" irrigation  (i.e., following  a tillage
operation) might be assumed, with remaining  irrigations  then  assigned to the
"mid-season" and "late-season" modes.  As more sophisticated  surface-
irrigation methods are adopted, use of cutback techniques may also be adopted
for early-season irrigation to minimize tillage effects.

     Mech (1959) also reported that 78 percent of the total sediment  lost  from
a section of recently cultivated furrows during a 24-hour irrigation  was lost
during the first 32 minutes of runoff, and that virtually all  of  the  eroded
sediment was lost during the first 4 hours of irrigation.  This was true even
though flow slowly increased with time because of decreasing  water intake
rate.  Carter and Bondurant (1977) claimed that less erosion  should occur  from
fields that were irrigated longer and less frequently, though such an approach
might increase leaching losses and could be  impractical  for shallow-rooted
crops.  Consistent irrigators tend to produce a "peak" in sediment loss during
each irrigation set (Mech 1959), by having many furrow streams reach  the end
of the row at similar times.  Research in the Yakima Valley (L.G.  King,
personal communication) has shown, however,  that  flows from different furrows
tend to arrive at the tail ditch at different times under common  irrigation
conditions.  No set-length dependence of erosion  losses  has been  assumed for
this report, so a relatively constant distrilDutioTf of sediment losses wTtfh
time during any given irrigation is inherent to our approach.  A  set-length
dependence of erosion losses remains a necessary  refinement in many
situations.
                                     342

-------
Soil-Texture Effects

     Soil texture is another important variable affecting sediment losses from
irrigated lands.  Pfeiffer (1976) incorporated soil-texture effects through
the use of soil credibility ("K") factors from the Universal  Soil  Loss
Equation (USLEKAppropriate "K  values were obtaine'dTfor our studies from
nomographs in the Stewart et al. (1975) report.  Inputs included:   percent
silt plus very fine sand, and percent sand (these values were taken from the
midpoint of an SCS textural triangle for each soil textural class);  soil
organic matter content (a value of 1 percent was assumed to typify the arid
conditions under which most irrigated lands of the West have developed);  soil
structural  clss (assumed medium to coarse granular);  and soil  permability
class (assumed "moderate").  Resultant "K" values were 0.48 for silt loams,
0.28 for loams, 0.22 for silty clays, 0.18 for sandy  loams, and 0.09 for
loamy sands.  These values are assumed proportional  to sediment loss for the
respective soil types.  Since the base soil condition was given as silt loam,
the adjustment factors would be as listed in Table B-9.

     Workers for the SCS have developed "K" values for many actual  soil
series, based upon more precise soil texture, organic matter,  structure and
permeability information.  These values will generally be within 0.05 of the
values listed above, however, and relative values will often be in virtually
exact agreement.  Refinements may eventually be necessary, for silt loams in
the Yakima Valley are reportedly less erosive than silt loams in the Twin
Falls area (D.C. Larsen, personal communication).  Soil-series-specific "K"
factors may help in this regard.

Crop Effects

     Crop type is yet another important variable affecting soil  erosional
losses.  Gossett (1975) reported relative sediment losses from row crops,  as
TABLE B-9.    MULTIPLIERS TO BASE-LEVEL IRRIGATED SEDIMENT  LOSS  VALUES  TO  ADJUST
             FOR SOIL TEXTURE
       Soil Texture                                       Multiplier
       Silt loam                                             1.00

       Loam                                                  0.79

       Sandy loam                                            0.53

       Silty clay                                            0.34

       Loamy sand                                            0.30
                                     343

-------
compared to close growing-crops, of three- to ten-fold.   Fitzsimmons et al.
(1978) reported that a bean field with slope only one-half that of a seed corn
field still had three times the erosional  losses.  After the slope change is
accounted for as outlined earlier, this would correspond to roughly a twelve-
fold difference in erosional losses between the two crops.  Based upon data
generated by Fitzsimmons et al. (1978), and with consideration  of the concept
of "limited accuracy" that applies to such data, potatoes have  been assigned
an average sediment loss value of 40 mt/ha (18 tons/acre)  under base-level
conditions.  Similarly, other row crops have been assTcjned a sediment loss
value 40 percent as large (T6 mt/ha or 7.2 tons/acre)  and close-growing crops
have been assigned a sediment loss value onTy S^erceWf as large (2 mt/ha or
.9 tons/acre).  These multipliers are listed in TableTPlO.

     The extreme variations with crop type reflect in  part localized
differences in management practices.  For example,  Rasmussen (personal
communication) has observed fanners applying up to 30  cm (12 inches) of water
to wet an entire crop field in a single, preplant irrigation for beans.  This
practice would produce extremely large amounts of erosion from  the unprotected
and recently-til led soil.  Similarly, erosion often virtually ceases for many
row crops once plant leaves or stems have begun to accumulate in the irri-
gation furrows.  Such debris essentially creates a series of check dams, or
"mini sediment basins," down the length of the furrow.

     The high erosion losses from furrow-irrigated potatoes will likely
decrease as more growers convert to sprinkler systems.  It has  been estimated,
for example, that 85 to 90 percent of the potatoes in  Idaho are now sprinkler-
irrigated (D.C. Larsen, personal communication).

Phosphorus Losses

     Loss of total phosphorusJ^s generally correlated  with sediment loss,
since much of the phosphorus is attached to erodTng particles.   Fitzsimmons
et al. (1978), for example, found a correTation coefficient of  0.8 between
total P and suspended solids.  No apparent relation exists between soluble
orthophosphate and sediment concentrations (Carter et  al. 1976), however.
TABLE B-10.   MULTIPLIERS TO BASE-LEVEL  IRRIGATED  SEDIMENT  LOSS  VALUES  TO  ADJUST
             FOR CROP TYPE
       Crop type                                          Multiplier
       Potatoes                                              1.00

       Other row crops                                       0.40

       Close-growing crops                                   0.05
                                     344

-------
Greater amounts of phosphorus appear to  be  associated with  a  given weight  of
fine sediments (e.g.,  clay and silt-sized)  than  with the  same weight  of coarse
sediments (e.g., sand-sized).  Also, finer  sediments are  less likely  to settle
out in ponds or retention basins.   Carter et  al.  (1974) reported  that
retention basins removing 65 to 75 percent  of the sediment  from runoff water
removed only 55 to 65  percent of the total  P,  and Fitzsimmons et  al.  (1978)
found phosphorus-removal  levels of only  35  to 78 percent  for  sediment ponds
removing 82 to 91 percent of the runoff  water sediments.

     Carter et al. (1974) summarized a large  number of  sediment and phosphorus
loss data for two of the  main irrigated  tracts of the Magic Valley,   Total
phosphorus loss in their  stud^es_averaged 0.14 percent  of total sediment loss,
or 1.4Kg oT total phosphorus per tonne  of  eroded sediment  (2.8 Ibs/ton).

     This method of estimating phosphorus loss ignores  differences in fertili-
zation rates between crops.   Presently,  adequate data are simply  not  available
to allow such a distinction.  Similarly, no attempt has been  made in  this
report to subdivide eroded phosphorus into  soluble, "available" (extractable),
or nonextractable forms,  because of the  poor  correlation  reported by  Carter
et al. (1974) when such attempts were made.

Sample Predictions

     Sample sediment loss predictions for the Magic Valley  (Idaho) area are
presented in Table B-ll.   These values have been used  for the case  studies.
reported in Section V  of  the planning manual.

Verification of Sediment  Loss Estimates

     Data with which to verify the sediment loss model  are  limited at best.
Although agreement was reasonably good between predicted  values and values
obtained from southern Idaho and from the Columbia Basin  (Fitzsimmons et al.,
1978; McNeal et al., 1979),  this comparison provides only a limited degree of
independent verification  since the Fitzsimmons et al. (1978)  data were a major
part of the data base  used to develop the predictive model.   Unpublished data
presented by D.L. Carter  at the 1979 meetings of the American Society of
Agronomy provided a better opportunity to verify the predictive model.
Comparison of Carter's data with predicted  values produced  a  slope of .61  and
a correlation coefficient (r value) of 0.993.   Omitting the field from which
sediment loss was the  greatest, because  of  its dominance  of regression rela-
tionships, a slope of  0.73 and an r value of  0.941 resulted.  There remains
considerable room for  improvement in the sediment loss  estimates, but they
seem to be of proper magnitude and well  correlated with measured  values.


III.  NITROGEN LOSSES

     Most nitrogen loss from irrigated croplands is associated with deep
percolation.  Unless soluble "nitrogen Tas been Inetered~into the irrTglTtfon
water, the levels of soluble nitrogen in surface runoff are essentially equal
to the levels in the corresponding irrigation water.  Small but measurable
amounts of total nitrogen are also associated with eroding  sediments, due  to

                                     345

-------








UJ
1— H
i
I 	
^^
ct:
1 i 1
L-LJ
t _
— i <
eC LU
Q <
o"
00 31
LU - i— I
1
Q- >-
O LU
(** — 1
— ~f-f
rv "-i
O
o o
s: CD
•=c
0
U. LU
oo t—
OO
o 2:
~_j i — i

I op
^— ^-
LU LU
SI 1 —
1—1 OO
O >-
LU OO
OO
Q O
LU i— i
h- h-
•=C 

O.
o
t.
<_>
1 LD  CM
1 ^H .
o
1

S- O O O
tf O O O
"to
c
o -~- *~* *—
•P CM t-~ 1X5
^— ' • • i-H
CTi OO •
-C IO CO ^»
•P O CO CO
E CM
o
,


^ ^
i «d- CM r^
• • CO
1 LO VO •
r-H >~~ O

to • oo
1 • OO 00
«d- t— 1 •
1 OO O
1
1

O CM IO
00 (-^
1 .-H -— O
I «*• • CO
• vo O
O ^H
^f I— 1





to
CL
o
^
to o
O.
O CD
S- C
O 'I-
^g
? 0
10 O i-
0) J- CD
O 1
•P S~ CU
ro OJ «/>
•P -C O
O -P r-
Q- O 0







































































t
1
1
1
'
E
SEE
•P CO O>
>, to to
| to >, >,
01
Q. t/) , —
•o ••- c
•p ^- [I
—
§E i
o  S
£,+->
i— -P tO >,
•i- 10 >, C tO
O >, to o
to to T- s
S -P 0
E 5 O ro S-
<8 O S- CD S-
O S- S- -r- 3
i— i. 3 i-  j^ 10
to c > o jo
CO O (13 1
to to i_ J3 CL
CO CO O.-P E
E S- E 3 3
3 o- I-H 0 D-
to
(^ 1 1 1 1

|^ ^S **/ "*^
rv (V m po
U. U- 1 — d.
UJ Q- i— i CJ 2:
1— D-
O

346

-------
sediment organic matter and exchangeable ammonium contents and associated  crop
residues.  In humid and subhumid regions (which are generally  ignored  in this
section of the report), amounts of total  nitrogen in eroding  sediments may be
appreciable due to higher soil  organic matter contents.

     The quantity of nitrate leached below the root zone (and  hence  unavail-
able for crop use) is dependent both upon the volumes and the  nitrogen con-
centrations of the drainage waters (Adriano et al., 1972a;  Ayers and Branson,
1973).  Limiting nitrate losses from soils may therefore be approached in  two
ways:  UTTTy reducing the volumes of drainage water, and/or  C2)  by  reducing
the nitrate concentrations of those waters^

Nitrogen Budgets

     In a controlled situation, the amount of nitrogen added  to irrigated
soils each season is reasonably well  known.  Fertilizer inputs, and  inputs
with the irrigation water, are a matter of record.   Biological  nitrogen
fixation can be estimated from published work with  the crops  in a given crop
rotation, or from ethylene reduction assays.   In much of the  arid West, where
little native soil organic matter is present, net mineralization is  a  minor
contributor to the nitrogen balance and can often be assumed  equal to  zero.
Denitrification (conversion to gaseous forms such as N2 or ^0),  however,  is
not so easily determined.  Most attempts to quantify denitrification in the
field have used a nitrogen budget, attributing to denitrification that portion
of the total nitrogen losses not accounted for by other mechanisms (crop
removal, leaching, residual soil nitrogen, etc.).   If the goal  is to limit
the amount of nitrate leached below the crop root zone,  the goal  is  most
practically attained by reducing the amount of nitrogen applied,  increasing
the amounif of denitrification occurring,  or reducing the quantity of leaching
water.

Project-Wide Studies

     Nelson and Weaver (1971) studied the salt balance for a  28,400  ha (70,000
acre) subunit in the Wapato Irrigation Project in central  Washington,  with
results compared to those from a similar study during 1941-42.   Prior  to the
mid-1940s, fertility was maintained with manures and with crop rotations,
including legumes.  By 1970, however, most fertilization was  through the use
of commercial fertilizers.  During the 29 years between studies,  alfalfa
acreage was cut by 76 percent,  with increased acreage being planted  to crops
such as spearmint, peppermint,  hops,  sugar beets, and corn.  Outputs of
nitrate had increased five-fold by 1970-71, with increased use of fertilizer
nitrogen thought to be the primary factor increasing the nitrate  contents  of
drainage water from the area.  Cropping changes may also have  contributed
materially to the trends, however.  Another factor  which may  have accounted
for some of the differences is the presence or absence of aquatic weeds.
Such weeds can remove substantial  quantities of nitrogen from  the water-return
system, and were more effectively controlled in 1970-71.

     Bingham et al. (1971) investigated nitrate-nitrogen (N03-N)  leaching
losses for a 390 ha (970 acre)  watershed cropped to citrus in  southern
California.  An average of 45 percent of the applied water was leached below

                                      347

-------
the crop root zone,  with nitrate-nitrogen  levels  of  the  drainage waters
corresponding to an  average of 64  Kg  N/ha/yr (57  Ibs.  N/acre/yr.).   Nonculti-
vated lands produced an average of less than one-fourth  as much nitrate.

     Carter et al.  (1971)  calculated  the salt balance  for a 81,000  ha  (200,000
acre) irrigated tract on the Snake River Plains of  southern Idaho.   They  noted
an annual  leaching  loss of 34 Kg N/ha (30  Ibs. N/acre) of irrigated  land.
Fertilizer company  records for the area indicated that nitrogen fertilization
rates had averaged  only about 60 Kg N/ha/yr (54 Ibs. N/acre/year) in this
tract, but half or  more of the leached nitrogen may  have arisen from alfalfa
plowout, rather than from commercial  fertilizer application.

Individual-Field Studies

     Adriano et al.  (1972a) investigated a 7-year nitrogen balance  for
asparagus grown on  a sandy soil.  They noted that N03-N  concentrations of
drainage waters were higher at higher fertilization  rates and  lower  irrigation
levels (though actual N03-N loadings  generally decreased with  decreased  irri-
igation rate).  Denitrification was assumed to have  caused greater  quantities
of unaccounted-for  nitrogen at higher irrigation  rates.  Adriano et  al.
(1972b) found little evidence of denitrification  at  sites characterized  by
open, porous soil.   At sites with  restricted layers  in the upper portion  of
the profile, on the other hand, drainage water nitrogen  concentrations
estimated from a mass-balance equation (based on  nitrogen applied,  nitrogen
used by the crop, and depth of drainage water) were  overestimated by as much
as 56 percent.  At  a site where animal  manures were  used as the main nitrogen
source, estimated N03-N concentrations were overestimated by as much as  73
percent.  Appreciable denitrification appparently occurred in  each  of  these
cases.

     Pratt et al. (1972) stated that  accurate estimates  of NO^-N concentra-
tions could be made if the following  parameters were known:  (1) excess
nitrogen available  for leaching; (2)  volume of drainage  water; and  (3) the
amount of denitrification occurring.   For a sandy loam soil with no  textural
discontinuities (e.g., silt or clay lenses which  impede  downward water
movement), this approach closely estimated the N03-N concentrations of
unsaturated soil below the crop root  zone.  For two  nearby commercial citrus
groves, where the soil contained a high clay horizon at  45 to  100 cm (18  to 40
inches), fully 50 percent of the applied nitrogen could  not be accounted  for
by this approach.  It was assumed  denitrified. Unfortunately, textural
discontinuities appear to be the rule, rather than  the exception, throughout
much of the irrigated West.

     Lund et al. (1974) found that the texture of the  "profile control
section" (that zone most thoroughly controlling the  rate of water movement
through the profile) influenced both  the volume and the  N03-N  concentrations
of drainage waters.   The greater the  clay content of the control section, the
lower the N03-N concentrations on  the soil solution.  This  is  probably a
direct effect on denitrification losses.  Devitt  et al.  (1976) used changes
in the C1/N03 - ratio with depth below the root zone as  an  indicator of
denitrification, in situations were Cl  was not taken up  by  the crop.  Lund
and Elliot (1976) sampled sites having variable profile  characteristics  within

                                     348

-------
a single field,  and found that the C1/N03  ratio  correlated  highly with  the
particle size distribution of the soil  control section.   Pratt  et al.  (1976)
found a nearly linear correlation between  the  saturated  hydraulic conductivity
of the 0 to 1 m (0 to 3 foot) section  of the profile  and  unaccounted-for
nitrogen, which was presumed to have been  denitrified.

Earlier Nitrate Leaching Estimates

     One of the most comprehensive early attempts  to  provide  nitrate  leaching
estimates for a variety of cropping and irrigation  conditions was undertaken
by Regional Technical Committee W-lll  ("Nitrogen and  the  Environment")  in
1973.  Members of this committee from  throughout the  western  states were
asked to provide estimates of leaching losses  at five nitrogen  fertilization
rates for well-drained and poorly-drained  soils  at  low, medium,  and high
degrees of leaching.  Crops characterized  included  irrigated  pasture, wheat,
alfalfa, potatoes, and apples.   Most committee members assumed  that crops
removed 50 to 60 percent of the applied nitrogen,  and that  10 to 30 percent of
the applied nitrogen was denitrified.   Thus, 10  to  40 percent of the  applied
nitrogen would be lost to percolating  waters.  Most committee members assumed
that only small  losses would be incurred from  alfalfa as  a  living crop,
although losses may be substantial  after the crop  is  plowed under.  Most
appear to assumed that crop requirements for nitrogen were  met  before either
percolation or denitrification occurred.

     Nitrogen loss estimates for irrigated pasture  and alfalfa  were generally
less than 6 to 11 Kg/ha (5 to 10 Ibs/acre).  The low  leaching estimates were
largely a consequence of the low fertilization rates  assumed  for these  crops.
Substantially higher leaching losses were  estimated for  small grains,
potatoes, and apples.  Values commonly exceeded  28  to 56  Kg/ha  (25 to 50 Ibs/
acre) at the intermediate and highest  leaching fractions  and  nitrogen appli-
cation rates.  A value in excess of 112 Kg/ha  (100  Ibs/acre)  was estimated for
potatoes under conditions of greatest  nitrogen leaching.  Corresponding values
for poorly-drained soil were only about half as  high, both  because of lower
leaching fractions and because of the  greater  potential  assumed for denitri-
fication.

     Gossett (1975) developed a regression equation describing  nitrate
leaching data generated by Pratt and co-workers  in  California.   This  equation
has been tested subsequently on a wide variety of  southern  California data,
and found to quite accurately predict  nitrate  leaching losses for that  area.
The relation has the form:

     NL = 0.22 (NiD)0'712

where NL = nitrate leaching losses in  kg N/ha/yr
      Ni = nitrogen inputs in kg/ha/yr
       D = drainage water volume in ha-cm/ha/yr

There is generally poor agreement between  nitrate  leaching  values estimated
from Gossett1s equation and those estimated by members of the W-lll Regional
Committee, with leaching estimates from the regression equation consistently
the higher of the two.   One explanation for this discrepancy  might be that the


                                      349

-------
California crops for which the equation was developed were  weighted  towards
heavily fertilized vegetable crops and towards well-managed (and  hence
frugally-irrigated)  crops, whereas the Regional  Committee estimates  were
weighted towards less intensively-managed crops.   Another explanation might
be that the Regional Committee members were overly conservative  in their
estimates.

Nitrogen Fertilizer Recommendations

     In obtaining estimates of nitrogen leaching for irrigated portions of the
West, it is necessary to input probable nitrogen application  rates for a  wide
range of crop and soil  settings.   Nitrogen fertilization  recommendations  can
be obtained from fertilizer guides published by the Agricultural  Experiment
Stations of the several  western states.  It should be recognized, however,
that the actual fertilizer application may differ substantially  from ferti-
lizer guide recommendations.  At  present in the Pacific Northwest, for
example, there appears to be a consistent tendency to exceed  fertilizer guide
nitrogen application rates in irrigated areas, as a form  of "insurance" on
high crop yields and because fertilizer guides are often  viewed  by growers as
oriented towards "average" (rather than high-level)  producers.

Estimating Deep Percolation Losses

     In addition to nitrogen fertilization rates, some estimate  of the
quantity of water which deep percolates is required for nitrate  leaching
estimates.  Several  methods of estimating deep percolation  losses can be
employed.  The recommended approach for this report consists  of  estimating
deep percolation (as a percentage of the water appl icatfon  to a  give~n'~rfeT'd)
as 100 percent minus both"thei_ on-farm irrigation effic|encyTexpre~ssed as~a
percentage) and the percent runoff [for furrow-irrTgated  fields)  or  evap-
orative losses during application (for sprinkler-irrTgafed  fTeldsT.Esti-
mation of each of these parameters was dealt with in considerable~detai 1
earlier.

     For some irrigation systems, deep percolation estimates  can  be  obtained
from estimates of uniformity coefficient and adequacy level.  A  typical water
distribution is shown TrTFigure  B-l,  assuming  a  normal distribution of varia-
tions in water application.  A field net irrigation requirement  of 2.54 cm  (1
inch), a uniformity coefficient of 80 percent, and a 75 percent  adequacy
level is shown (i.e., three-fourths of the root zone soil  is  returned to
maximum water holding capacity during an average irrigation). Most  subunits
in the field (shown as 10 percent increments or 0.1 field  subunits in the
figure) must be over-irrigated to meet this adequacy level.  As  a result  deep
percolation occurs, and the tradeoff between under-irrigation and deep
percolation is readily apparent.   As less and less of the  field's root zone
area is under-irrigated, by increasing the amount of water  applied,  more  and
more of the field is subjected to excessive deep percolation. Such  deep
percolation carries soluble nutrients, particularly nitrates.

     Despite difficulties iji its  measurement, the adequacy  level  can at least
be qualitatively or semi-quantitatively estimated (as described  earlier in
this section), in order to provide nitraTe leaching estimates under  selected


                                      350

-------
                         Figure B-l.  Water distribution.
             5.1
            (2.0)

         .5  3-8
         ~ (1.5)
          E
          O
          CL
          a)
         Q

          U
          a)
 2.5
(1.0)
             1.3
            (0.5)
                                     Deep percolated

                                     Stored  in  soi1

                                     Under-i rrigated


                                            50
                                            75
100
                             Field  area  (10 percent  increments)
field conditions.   Such estimation,  though  crude,  is  still  of  approximately
the same degree of accuracy as many  of the  other  types  of estimates  available
for irrigated croplands.

     For furrow-irrigation systems the uniformity coefficient  is  commonly
unknown, at least  with our present state of knowledge.   Estimates of percent
deep percolation can be made by subtracting the percent runoff and the  percent
efficiency from 100^If the resultant deep percolation loss corresponds to an
unrealistic uniformity coefficient,  then either a different adequacy level or
a different on-farm efficiency may be required to "fine tune"  the deep  perco-
lation and uniformity coefficient estimates.

     Deep percolation estimates can  be obtained for subunits of an irrigated
fie1d~a"s well  as  for the entire field, if  water  application is assumed to be
normally distributed.Our studies'have made use  of ten subunits, each
consisting of 10 percent of the field's area.  The exact location of each
subunit within the field is not specified,  but such an  assignment is generally
not necessary.  Crop appearance and/or yield may  serve  as a useful guide to
locations of excessive leaching where necessary.   By  assigning an adequacy
                                     351

-------
level and a uniformity coefficient,  or by  knowing  one  of  these values and the
field-wide percentage of deep percolation,
     it is possible to estimate the  amount of deep percolation or  under-
irrigation for each field subunit.   Table  B-12 shows calculated values of
subunit deep percolation for various uniformity coefficients  at three adequacy
levels (the data relate equally to  sprinkler- or furrow-irrigated  settings).
The deep percolation values are expressed  as  a percent of the average amount
of water applied to the field.   As a result,  it is possible to have deep
percolation losses of greater than  100 percent for a given subunit.

     For furrow-irrigated fields, one would expect ridges of  the crop row and
the lower part of the field (especially where convex field ends occur because
of prior erosion) to correspond in  general to field subunits  that  are not
adequately irrigated.  On the other  hand,  the irrigation  furrows and the upper
part of the field should correspond  in general  to  subunits that are over-
irrigated.  For sprinkler irrigation, the  water application pattern is  non-
uniform due to design problems and/or wind distortion  of  the  application
pattern.  No specific field locations can  thus be  assigned to underirrigated
or over-irrigated subunits.  Crop growth and/or yield  may provide  clues to
such distribution, as discussed earlier.

Nitrogen Leaching Estimates

     Nitrogen in the root zone is often assumed proportional  to the amount  of
nitrogen fertilizer applied.  Several studies have also shown that excessive
irrigation can decrease crop production, with a major  factor  in such decreases
being the amount of nitrogen which  has been leached (Middleton and Roberts
1972; Kloster and Whittlesey 1971).   As mentioned  earlier, Gossett (1975)
analyzed much data generated during  extensive studies  of  nitrate leaching by
workers from the University of California.  He fit the data to an  equation  of
the  form:
     NL = 0.22 (NfQd)
                     0.712
where NL = nitrate leaching losses in kg N/ha/year
      Nf = fertilizer nitrogen inputs in kg N/ha/year
      Qd = drainage water volume in ha-cm/ha/year

This equation fit the University of California field data with an r2  value of
0.908.

     The slope of the above curve does not stand up to close scrutiny, for it
predicts relatively less leaching of fertilizer nitrogen as either the
drainage water volume or the nitrogen fertilization rate is increased.  The
former is as anticipated, for there is only a finite quantity of nitrogen
present to be leached.  Most studies, however, have found increasing  propor-
tions of fertilizer nitrogen leached as the fertilization rate is increased,
rather than the converse.  As a result, Pfeiffer (1976) used the following
equation to estimate nitrogen leaching, based upon the same data:
NL = 0.032 (Nf)1'05  (Qd)
                            0'7
                                      352

-------
TABLE B-12.  PERCENT  DEEP  PERCOLATION  FOR THE ENTIRE  FIELD AND FOR TENTH-
           FIELD SUBUNITS AT SELECTED UNIFORMITY  COEFFICIENTS  AND
                                    AND  ADEQUACY  LEVELS

Unf ormity
coefficient
(%)
100
95
90
85
80
75
70
65
60
55
50
45
40
100
95
90
85
80
75
70
65
60
55
50
45
40

100
95
90
85
80
75
70
65
60
55
50
45
40
Entire
field
2.5
5
7.5
10
12.5
15
17.5
20
22.5
25
27.5
30
„
5
10
15.5
21
26
30
36
41
46
52
58
62

_
7
14
21
28
35
42
49
56
63
70
77
84
1
10.5
21
32
43
54
65
76
87
98.5
110
121
132
_
15
30
45
60
75.5
91
106
121
137
153
168
183

_
17
34
17.5
69
86.5
104
121.5
139
157
175
193
211
2
6.5
13
19.5
26
32.5
39
45.5
52
59
66
72.5
79
_
11
22
32.5
43
54
65
75.5
86
97
108
119
130

_
13
26
39
52
65.5
79
94
105
118
131
144
157
3
4.5
9
13
17
21
25
29.5
34
38.5
43
47
51
_
8.5
17
25.5
34
42.5
51
59.5
68
76.5
85
93.5
102

_
11
22
32.5
43
54
65
75.5
86
97
108
119
130
4
Field subunit a/
5 6
7
8 9
10
50% adequacy level
2.5 0.8- •
5 1.5
7.5 2.3
10 3
12.5 4
15 5
17 5.5
19 6
21.5 7
24 8
26.5 9
29 10
75% adequacy level
_
6.5
13
20
27
33.5
40
46.5
53
60
67
73.5
80
87.5%
_
9
18
27
36
45
54
63
72
81
90
99
108
_
5
10
15
20
25
30
35
40
45
50
55
60
adequacy
_
7.5
15
22
29
36.5
44
51.5
59
66
73
80.5
88
_
3.5
7
10.5
14
17.5
21
24.5
28
31.5
35
38
41
level
_
6
12
17.5
23
29
35
40.5
46
52
58
63.5
69
_
2
4
5.5
7
9
11
13
15
16.5
18
20
22

_
4
8
12.5
17
21
25
29
33
37
41
45.5
50
_
-
-
-
-
-
-
-
-
-
-
-
-

_ _
2.5
5
7
9
11.5
14
16.5
19
21
23
25.5
28
-
-
-
-
-
-
-
-
-
-
-
-
-

_
-
-
-
-
-
-
-
-
-
-
-
—

 a/ Each field subunit Is defined as 10 percent of the field's area.  Deep percolation for subunlts 9 and 10
   equals zero for all uniformity coefficients and adequacy levels listed.  Percent deep percolation for each
   subunit is defined as a percent of the overal1 water application requirement.
                                          353

-------
This relation is more consistent with observed nitrate  loss  patterns  than  is
Gossett1s.

     Because of the less efficient furrow irrigation  systems in  general  usage
throughout much of the Pacific Northwest, compared  to the more efficient
irrigation sytems (often sprinkler systems)  at many of  the University of
California study sites, direct use either of Gossett's  or or Pfeiffer1s
equation in this report generally resulted in over-estimation of nitrogen
leaching losses.  McNeal and Pratt (1978), for example, found nitrate leaching
predictions from these equations to be two-  to three-fold too high  for the
Twin Falls (Carter et al.,  1973) and Wapato  (Nelson and Weaver,  1971) irriga-
tion projects.  It was, therefore, deemed advisable to  make  field subunit
adjustments before applying Pfeiffer1s equation,  and  to provide  an  upper limit
for the amount of nitrogen  that could be leached  from each  subunit  no matter
how much water passed through that portion of the field.

     Deep percolation estimates for individual  one-tenth field  subunits  were
used fn our studTes7~aTong  wTth a modified Pfeiffer equatfon, to obtain
nvtrogen Teaching estimates for each subunit rather than for the field as  a
whole.  These values were~then summed to obtain field-wide values.  The
equation used to oFtafTPsubunHTeachfng values had the form:

     NL = 0.038 (Nf)1'05 (Qd)0'7

The first two columns of data in Table B-13  present the individual  subunit deep
percolation values required to obtain a total field-wide deep percolation
value of 20.54 percent (corresponding to a 75 percent adequacy  level  and an
80 percent uniformity coefficient) at a total water application  rate  of  127 cm
(50 inches).  The next column presents the fertilizer application rate per
tenth-field subunit if the  fertilizer were uniformly  applied, and the
following column provides corresponding nitrogen  leaching estimates.   Each of
the latter values was obtained through use of the adjusted Pfeiffer equation.
The net result of the subunit approach was only a 10  percent reduction in  the
nitrate leaching estimate (39.9 kg N/ha or 35.6 Ibs N/acre)  when compared  to
the value obtained from fieldwide use of the Pfeiffer equation  (43.9  kg  N/ha
or 39.2 Ibs N/acre).

     When furrow irrigation is simulated, leaching  of nitrogen  can  be more
accurarbeTy described by assuming that the most heavily  leached  subunits  of
each field are associated with the irrigation furrows.For  illustrative
purposes it might be assumed that only one-tenth  as much of  any  band-applied
fertilizer nitrogen ends up in the most heavily leached subunit (e.g., within
the irrigation furrow) and  that only one-half as much fertilizer nitrogen
ends up in the next most heavily leached subunit.  For  the  remainder  of  the
field, the fertilizer application would then be 1.175 times  the  average
fertilization rate, so that the total quantity of nitrogen  applied per acre
remained unchanged.  The final columns of Table  B-13 shows  these subunit
fertilization rates and resultant nitrate leaching  values.   The  leaching
values are reduced approximately 20 percent  further,  to approximately two
thirds of the original field-wide Pfeiffer estimates.  The  leaching estimates
for the most heavily leached and next most heavily  leached  subunits are
substantially reduced by this "simulated furrow"  technique.   Hence, additional


                                      354

-------
e/
z.
i—i
1C


UJ UJ

   
                •a i—
                 
       CDT3
     -^ 3
    (O -^ O
    $-00.

   ••-   3
O r—  
                   .j
                to
             CDT3
          cu c c
          •P -^ 3
          to J= O
          S- O O-
          •i-   O T3
 C  N ••- C
 CO •!- -l-> 3
 CDt—  (O O
 O i-  O Q.
 $_ +J .1- ^-.
+J  $- I—
•i-  0)  CX CD
z u_  ex.*
      ja w
          O)
       >)-C
      •!-> O
      •r- C
      •»-> •!-
       c ~-^
       
                                                                                 U.  to
c
a>
o

ai
Q.

o
CO
                                                                                                 +J
                                                                                                 c
                                                                                                 (U

                                                                                                 u
                                                                                    a>
                                                                                    S-
                                                                                    o
                                                                                    <0

                                                                                    $-
                                                                                    0)
                                                                                    CX
(U
o
o

>>
+J
E"*~

• o
•r-
c
3


a>
r—

>,
O
to
3
cr
(U
-o
l
10
(U
JC
o
c
•r—
O
LO
"* —
O

I--
CM
^"1
O
+J
c
(U


i-
•1—
3
cr
cu
s_

c
0
jp
(0
o
•t—
^~.
ex
CX
(O

s_
0)
+J
(O
S

CO
I/)
(U
E
3
CO
CO
<
>,
00
•o
c
3
o
CX
o
o
I— 1
CD
j*:

*!•
LO
ll
^^
0

(U


•i—
C


-------
water which might pass through the soil  beneath the  furrows  would  have  little
effect on nitrate leaching,  despite its  considerable influence  on  Pfeiffer's
field-wide estimates.  The difference between nitrate leaching  estimates from
the field-wide and "simulated furrow" estimation techniques  would  be  even
larger for larger nitrogen fertilizer application rates or water application
requirements.

     Leaching estimates obtained from the "simulated furrow"  leaching
technique are probably more  representative of nitrogeWleached'from'Turrow-
irrigated fields of the Pacific Northwest than are the directly applied field-
wide values.  For sprinkler  irrigation, "estimates~from the  subunft leaching
technique are also probably  more useful  than directly-applied field-wide
values.  Though the sprinkler irrigation estimates could be  improved  somewhat
further by adjusting the amount of fertilizer nitrogen in each  subunit  to
correspond with either band  or broadcast application of fertilizer,  the only
reasonable approximation at  present is to assume a uniform  distribution of
fertilizer nitrogen throughout each field subunit.

Denitrification Corrections

     Water-saturated surface soils provide the best  conditions  for gaseous
loss of nitrogen via denitrification, for they have  both the microbes and  the
energy source (soluble or solid-phase carbon) required for  the  process.
Relatively high soil temperatures also speed the conversion.

     Estimates of nitrogen leaching using the techniques described above all
assume an amount of denitrification roughly equivalent to that  from a uniform
sandy loam under ~southern~Cal ifornTa'conditions.  For other  soil  types, Pratt
D.979T has shown that adjustments can be made^ in the form of multipl iersT¥P
based on saturated soil hydraulic conductivity (h) values using the equation":
     m
= 0.8(h)0.5
Multipliers for specific surface-soil  textures are listed in Table B-14.   It
appears that approximate multipliers may also be attainable from the  relation
m = (0.015)(percent sand) for additional soil types.

     As an example, assume that the value of nitrate  leaching under simulated
furrow leaching (31.3 kg/ha or 27.9 Ib/acre) in Table  B-13 was  for a  uniform
sandy loam.  Using the appropriate denitrification multiplier for silt loams
(0.4), we obtain

     27.9(0.4) = 12.5 kg/ha (11.2 Ibs/acre)

The estimate of nitrate leaching is now only approximately 30 percent of the
value obtained using the unmodified Pfeiffer equation (43.9 kg/ha or  39.2
Ibs/acre).  Approximately 30 percent of the decrease  is due to adoption of the
"simulated furrow" leaching technique, and another 40 percent is due  to use of
the denitrification multiplier.  The net effect is values which are much more
in agreement with nitrate leaching values for Pacific Northwest irrigated
tracts (Nelson and Weaver 1971; Carter et al. 1973; McNeal and Pratt  1978)
than were the unmodified Pfeiffer estimates.


                                      356

-------
TABLE B-14.   NITRATE LEACHING DENITRIFICATION MULTIPLIERS  FOR  SELECTED  SATURATED
             HYDRAULIC CONDUCTIVITY VALUES  AND CORRESPONDING SOIL  TEXTURES
       Soil                   Saturated hydraulic
      texture                    conductivity                 Multiplier
                              cm/hr  (inches/hr)

     Coarse  sand                    10 (4.0)                      1.6

     Sandy loam                    4.1 (1.6)                      1.0

     Silt loam                     0.5 (0.2)                      0.4

     Silty clay loam              0.08 (0.03)                     0.15
 NOTE:   These multipliers are to be applied to the nitrate leaching values for
        sandy loam  soils in order to obtain estimates for other soil textures.


 Sample  Predictions

     Sample nitrate leaching predictions for the Magic Valley (Idaho) and
 Umatilla  (Oregon) areas are presented in Tables  B-15 and B-16.These values are
 used for  the case studies reported in the planning manual, Section V.


 IV.  GEOGRAPHICAL DIFFERENCES IN THE IRRIGATED AGRICULTURE PREDICTIONS

     The  preceding estimates of sediment and phosphorus loss from irrigated
 fields  were derived mainly from sediment-loss measurements in Idaho,
 Washington, and Utah, coupled with irrigation efficiency measurements in
 California, Washington, and Idaho.  Nitrate leaching estimates were based
 primarily on data from extensive studies in central  and southern California,
 as modified to more accurately describe irrigated settings in Washington and
 southern  Idaho.  The major case study areas used for economic evaluations of
 sediment  and nutrient loss control measures are located in south central
 Washington, south central Idaho, and north central Idaho.

     The  techniques described can be applied as well  to center-pivot irrigated
 fields  in the Sand Hills of Nebraska, to furrow-irrigated fields in eastern
 Colorado, or to basin-irrigated fields in central Arizona.  The  authors are
 currently assembling published information from throughout the irrigated West
 for model verification and/or refinement purposes.  The models of sediment and
 phosphorus runoff losses, and of nitrate leaching losses, at least provide a
 basis for comparison so that situations which are inadequately described can
 be recognized and dealt with subsequently.


                                     357

-------



2
oc
<
^
^ S
o n:
o ^
o uj
U 	 1
_i
GO 
00
GO CJ
O 1-1
_I CD
<
CD s:
z
i— I LlJ
or in
0 I—
<
LU Z
— 1 i— I
Q OO
uj s:
h- LU
-
1— 00
oo
LU z:
o
Q i— i
i£
CD
OO i — i
LU Q£
1— C£

O h-H
>-. |—
1— — 1<— lOOCOCTirOVO
i— 1 O O O • — •• — 'LO — • ,— 1 f— 1 r-H 	 -i— 1 i— 1 • — OO
i T— i .— i t— i i— i en oo «3-ooro«cMLo«cvi
i t— i evj CNJ o t— i «-i
^-1 rH r-l CVJ CM ^~
1 1
OOOCMCMOOOOr-OOLO O>— l^'d-^tOOOOOlO


— . ooooocTi<^3oor~- iocn ^~ rH
1- Locrioo s^OrHi»~-r^cMix>oo«d-CT)
CO' — •• — •• — •• — •,— I.-H- — • i— i "Oor-i — ^r-CMCMoocM'ja
3 kD i-D U3 CO — .^-CM^ C ^ — ^. — • ,_( ^H *^ CM
O OOOOOOOLOCOCM 3 O«3tOLO — >—r-.^—
a. ^-)i-ii-i ooo CM o •••«<-icyt«i-i
^— CM^-I CM C3.000OCOCM»«CM«
— ^ ^i- o
i- .-< ^H OO
O S-
o
 *— tt-H^H OJO^i ^- •» r-*OO»LOt— i«CTt
(TJ  OO Lf) LO i— II — VO
S- Oi-Ht-lr-IOOCMLO
^-l
c
O D1
+JOlO<^3l£>ir)OCT>CnOO 'i-OVOt-Ht-ltOCMi-HOO^O

••- OOOOOOON— .^-CM^-- _-^-- 	 ^-,_,,_I_PO
i — ooooooocjioor^- cu LOCMCVJCD — •• — •!-< — •
Q. i— 1 i— 1 .— 1 i— ICO CVJ r— ••••t_iCM««a-
Q. CVJt-HCM COOOCM««OO«
 LO
+J ^-t ,_( OO
c «a
CO J-
01 4J
S-OCT>O1cnLOCVJ.— IOCM ZO«l-^)-«d-CMr~-OLOl£>
•r-O- — • — • • — •• — • CM i— 1 	 CVI OO»-»t— lOOOOOOO'-H
'Si ^H i— 1 i— 1 CTl • — •• 	 -«d- 	 • 1 t-H f— 1 r-H • 	 • t— 1 CM — **•
^-I^HT-I ^HCTi OO 1 lOCOOO«CTi^i-«vO
1 CM i— 1 CM ...OO««OO«
1 ^H CM CM O CM V£>
1 .— 1 i— 1 ^-1 CM CM *J-
1
O«-<«-t'-<^OCM^O^^^t OCM«*^l-r--.!-
OO LO LO '-t t~~ ^O
i— 1 f— 1 T-I OO CM LO
c c c c
•1- -I- «/) •!-•!- «/>
(O
s- t. ucuto s- S- s- cu oo
a>o> ocuctn CJICD ocucfi
(O cu o .a rc> a>  u^S~S- cu o i+- en s_ s_ aio
r— C O> 3 -Oi_jD-l-> i— C CU 3 •OS-J3+->
dj .,- +J 4-> CO r— fO f)i — (T3 >4-> It- S- C f> 03 Q) CD >,•!->
r— O.'"- OOQ. <003QLQ-U.OOQQ-

































^.
CU E E
W 4J 4->
>> to to
«" >> >>
to to
cu
CX-(-> S-
Q. to ,—
•o -^ c
 i— S-
(O 3 CL
CD E ">
to o o •—
CO -r- •,- r-
Q. +•> -P O
O ra  3 3 -1-

0 III
a> LU i— _i
Q. CL. oo a:
KH |_ Q
CM Q 	 1 OO
o 05:
-l->
4->
c:
cu
o
s-
cu
o.
LO
•

+•> • CD
•i- d) -*-* E
ro E 35 >>4->
oo +J cD +-> to 
r— O -P «rt >,
•r- CU "> >, C tO
O .C >> to O
to ^ to ••- 5
CD S •!-> 0
fO O S- CD S-
^ ,-1 $- 3 S- <4-

^ -oo
NOTE: Assumes s1
a/ 1 pound/acre =
* PFRW - Preseni
IFRW - Improve
CTBK - Cutback
PMPBK - Pump-be
358

-------
TABLE B-16.  NITROGEN APPLICATION RATES AND ESTIMATED NITRATE LEACHING LOSSES
             FOR MAJOR  CROPS UNDER THE CENTER-PIVOT  IRRIGATION SYSTEMS  IN THE
             UMATILLA (OREGON)  AREA
Crop
Alfalfa hay

Winter grain

Field corn

Dry beans

Early potatoes

Late potatoes
                         Nitrogen
                      Application Rate
                                     Nitrate
                                   Leaching Loss
PCP*
ICP**
PCP
ICP
0(0)
180(161)
226(202)
169(151)
338(302)
451(403)
- - Ny/ ii
0(0)
157(140)
194(173)
151(135)
290(259)
368(329)
                                     kg/ha (pounds/acre) a/
0(0)
46.5(41.5)
64.5(57.6)
38.1(34.0)
97.1(86.7)
159.9(142.8)
0(0)
23.7(21.2)
32.5(29.0)
19.8(17.7)
49.3(44.0)
76.2(68.0)
NOTE:  Assumes sandy soils.
a/ 1 pound/acre = 1.12 kg/ha.

 * PCP - Present center-pivot.
** ICP - Improved center-pivot.
     The models have been kept simple intentionally, while still incorporating
the most importanf physical parameters and processes conceptualized tolfate,
so that they may_be used with minimum difficulty by planning groups and by
research wo'rkers from outside the physical and biological sciences.  The
far-western bias of the data base used foT model development and initial
verification is acknowledged.It is ncTmore provincial, however, than the
strong mid-western bias of initial sediment loss estimates for nonirrigated
regions (i.e., development of the Universal Soil Loss Equation).  In each
case, only a few locations have undertaken the extremely expensive and time
consuming research needed for model  verification and refinement, so climatic
and physiographic settings near or similar to those where the most research
has been conducted enjoy greatest initial emphasis as the new models emerge.
                                      359

-------
                                  REFERENCES

Adn'ano, D.C., P.P.  Pratt,  and  F.H.  Takatori.  1972a.  Nitrate in Unsaturated
     Zone of an Alluvial  Soil in  Relation  to Fertilizer Nitrogen Rate and
     Irrigation Level.  J.  Environ.  Qua!.  1:418-422.

Adriano, D.C., F.H.  Takatori, P.F. Pratt,  and O.A. Lorenz.   1972b.  Soil
     Nitrogen Balance in  Selected Row-Crop Sites  in  Southern California.
     J. Environ. Qual.  1:279-283.

Ayers, R.S. and R.C. Branson.   1973.  Nitrates in the Upper  Santa Ana Basin
     in Relation to  Groundwater Pollution.  California Agricultural Experiment
     Station Bull. 861, University of California.

Bingham, F.T., S. Davis,  and E. Shade.   1971.  Water Relations, Salt Balance,
     and Nitrate Leaching Losses  of  a 960-Citrus  Watershed.  Soil Sci.  112:
     410-418.

Brown, M.J., D.L. Carter, and J.A. Bondurant.  1974.  Sediment in Irrigation
     and Drainage Waters  and Sediment Inputs and  Outputs  for Two Large  Tracts
     in Southern Idaho.  J. Environ. Qual. 3:347-351.

Busch, J.R.  1978.   Unpublished data.   Dept. of Agricultural Engineering,
     University of Idaho.

Carter, D.L. and J.A. Bondurant.   1977.  Control  of  Sediments, Nutrients,  and
     Adsorbed Biocides in Surface Irrigation Return  Flows.   U.S. Environmental
     Protection Agency, EPA Technology Series, No. 600/2-76-237.

Carter, D.L., J.A. Bondurant, and C.W. Robbins.   1971.  Water-Soluble N03-
     Nitrogen, P04-Phosphorus,  and Total Salt  Balances on a  Large  Irrigation
     Tract.  Soil Sci.  Soc. Amer. Proc. 35:331-335.

Carter, D.L., M.J. Brown, and J.A. Bondurant.  1976.  Sediment-Phosphorus
     Relations in Surface Runoff  from Irrigated Lands.  Proc. Third Federal
     Inter-agency Sedimentation Conf., pp. 3-41 to 3-52.

Carter, D.L., M.J. Brown, C.W.  Robbins, and J.A.  Bondurant.  1974.  Phosphorus
     Associated with Sediments  in Irrigation and  Drainage Waters  for Two Large
     Tracts  in Southeastern Idaho.  J. Environ. Qual. 3:287-291.

Carter, D.L., C.W. Robbins, J.A.  Bondurant. 1973.   Total Salt, Specific Ion
     and Fertilizer Element Concentrations and Balances  in the  Irrigation  and
     Drainage Waters of the Twin  Falls Tracts  of  Souther  Idaho.   USDA Bulletin
     ARS-W-4, Snake River Conservation Research Center, Kimberly,  Idaho.


                                      360

-------
Devitt, D., J. Letey, L.J.  Lund,  and J.W.  Blair.   1976.   Nitrate-Nitrogen
     Movement through Soils as Affected by Soil  Profile  Characteristics.  J.
     Environ. Qual.  5:283-288.

Evans, N.A. and M.E. Jensen.   1952.   Erosion  under Furrow Irrigation.  North
     Dakota Agricultural  Experiment Station Bi-monthly Bull., Vol. XV,
     No. 1, pp. 7-13.

Fitzsimmons, D.W.,  C.E.  Brockway, J.R.  Busch,  L.R. Conklin,  R.B.  Long,
     G.C. Lewis, K.H. Lindeberg,  C.W. Berg, G.M.  McMaster, and  E.L. Michalson.
     1978.  Evaluation of Measures for Controlling Sediment  and Nutrient
     Losses from Irrigated Areas.  U.S. Environmental Protection  Agency, EPA
     Technology Series,  No. EPA-600/2-78-138.

Gardner, W. and C.W. Lauritzen.   1946.   Erosion  as a  Function of  the Size of
     the Irrigation Stream and the Slope of the  Eroding  Surface.   Soil Sci.
     62:233-242.

Gossett, D.L.  1975.  The Economics of Changing  the Water Quality of Irri-
     gation Return  Flow from Farms in Central  Washington.  M.S. thesis,
     Washington State University.

Hagan, R.M.  1978.   Energy in Western Agriculture—Requirements,  Adjustments
     and Alternatives.  California Contributing  Project  Report, Western
     Regional Research Project,  Department of Land, Air  and  Water Resources,
     Water Science  and Engineering Section, Davis, Calif.

Israel son, O.W., G.D. Clyde,  and C.W. Lauritzen.   1946.   Soil Erosion  in Small
     Irrigation Furrows.   Utah Agricultural Experiment Sta.  Bull.  No.  320.

Kloster, L.D. and N.K. Whittlesey.  1971.   Production Function  Analysis of
     Irrigation Water and Nitrogen Fertilizer in  Wheat Production.  Washington
     State Agricultural  Experiment Station Bull.  746, Washington  State
     University.

Kraft, D.F.  1975.   Economics of Agricultural  Adjustments to Water Quality
     Standards in an Irrigated River Basin.  Ph.D. thesis, Washington  State
     University.

Lund, L.J., D.C. Adriano, and P.F. Pratt.   1974.   Nitrate Concentrations in
     Deep Soil Cores as Related  to Soil  Profile  Characteristics.   J. Environ.
     Qual. 3:78-82.

Lund, L.J. and R.A.  Elliott.   1976.   Nitrate  and  Chloride Leaching as  Related
     to Soil Profile Characteristics.  In  Nitrate in  Effluents  from Irrigated
     Lands.  P.F. Pratt,  ed.   University of California,  Annual  Report  to
     National Science Foundation.

McNeal, B.L., N.K.  Whittlesey, and V.F. Obersinner.  1980.   Control of
     Fertilizer Nutrient Losses  in Irrigated  Portions of the Pacific
     Northwest.  U.S. Environmental  Protection Agency, EPA Technology  Series,
     unpublished.


                                     361

-------
 McNeal,  B.L.,  N.K. Whittlesey, and L.G. King.  1979.  Factors Influencing
      Sediment  Loss from  Some  Pacific Northwest Irrigated Croplands.  Agron.
      Abstracts,  American Society  of Agronomy, Ft. Collins, Colorado.

 McNeal,  B.L. and P.F.  Pratt.  1978.  Leaching of Nitrate from Soils.  In
      Proceedings of  the  National  Conference on Management of Nitrogen in
      Irrigated Agriculture, U.S.  Environmental Protection Agency, National
      Science Foundation, and  University of California.

 Mech, S.J.  1959.  Soil  Erosion and Its Control under Furrow Irrigation in
      the Arid  West.   USDA, ARS, Agr. Inf. Bull. No. 184.

 Mech, S.J.  and D.D.  Smith.  1967.  Water Erosion under  Irrigation.  In
      Irrigation  of Agricultural Lands.  R.M. Hagan, H.R. Haise, and T.W.
      Edminster,  eds.   Agronomoy 11, pp. 951-963.

 Middleton,  J.E.  and  S. Roberts.   1972.  Irrigation and  Fertility Management
      on  Sandy  Soils.   Proceedings of the llth Annual Washington Potato
      Conference, Moses Lake.

 Nelson,  C.E. and W.H.  Weaver.  1971.   Salt Balance for  the Wapato Project for
      1970-71 Compared with the Salt Balance for 1941-42.  Washington Agri-
      cultural  Experiment Station  Bull. 743, Washington  State University.

 Obersinner, V.F. 1979.   The  Economics of Reducing Pollution from Irrigation
      Return Flows in Selected Areas of the Pacific Northwest.  M.S. thesis,
      Washington  State University.

 Pfeiffer, G.H.   1976.  Economic Impacts of Controlling  Water Quality in an
      Irrigated River Basin.   Ph.D. thesis, Washington State University.

 Pratt, P.F. 1979.   Estimated Leaching and Denitrification Losses of
      Nitrogen  in a Four-Year  Trial with Manures.  In Nitrate in Effluents
      from Irrigated  Lands.  Final report to the National Science Foundation
      from the  University of California.

 Pratt, P.F., S.  Davis, and R.G. Sharpless.  1976.  A Four-Year Field Trial
      with Animal Manures.  I.  Nitrogen Balances and Yields.  Hilgardia 44:
      99-112.

 Pratt, P.F., W.W. Jones, and  V.E. Hunsaker.  1972.  Nitrate in Deep Soil
      Profiles  in Relation to  Fertilizer Rates and Leaching Volume.  J.
      Environ.  Qual.  1:97-102.

 Regional and Technical Committee  W-lll.  1973.  Nitrogen and the Environment.

 Shearer, M.N.   1978.   Comparative Efficiency of Irrigation Systems.  Irri-
      gation Association  Technical Conference, Cincinnati, Ohio.

Stewart,  B.A.,  D.A. Woolhiser, W.H. Wischmeier, J.H. Caro, and M.H. Frere.
     1975.  Control of Water Pollution  from Cropland.  Report No. ARS-H-5-1
     or EPA-60012-75-026  a, b; U.S. Department of Agriculture, Agriculture


                                      362

-------
    Research Service and U.S.  Environmental  Protection Agency, Office of
    Research and Development,  Washington,  D.C.

Sutter, R.J., and G.L.  Corey.   1970.   Consumptive  Irrigation Requirements for
     Crops in Idaho.  Agricultural  Experiment  Station Bull. 516, University
     of Idaho.

U.S. Department of Agriculture,  Soil  Conservation  Service.  1973.   Irrigation
     Guide for Columbia Basin.   Spokane, Washington.

Vomocil, J.A.  1976.  Estimated Irrigation and Water Application Requirements:
     Northern Morrow County and Northwest  Umatilla County, Oregon.  Project
     Working Paper No.  1, Northern  Columbia River  Basin  Irrigation  System
     Development Project, Pacific Northwest Regional Commission, Oregon State
     University.

Watts, D.G., C.R. Dehlinger, J.W. Wolfe, and M.N.  Shearer.  1968.   Consumptive
     Use and Net Irrigation Requirements for Oregon.  Oregon Agricultural
     Experiment Station Circ.  628,  Oregon  State  University.

Whittlesey, N.K. and T.H. Allison,  Jr.  1971.  The Value of Water Used in
     Washington's Irrigated Agriculture.   Washington Agriculture Experiment
     Station Bull. 745, Washington  State University.

Worstell, R.V.  1976.  Costs and Benefits  of a High Efficiency, Automatic
     Gravity Irrigation System.  Pacific Northwest Regional ASEA Meeting,
     Penticton, B.C., Canada.
                                     363

-------
                                 APPENDIX C

                    ESTIMATING THE COST-EFFECTIVENESS OF
                           SALINITY CONTROL MEASURES
                        W.  R.  Walker and T. E.  Waddell

                                  SECTION 1

                                INTRODUCTION
BACKGROUND
     Salinity is among the most serious water quality problems associated
with irrigated agriculture.  As water is diverted from rivers,  streams
reservoirs, and groundwater basins for agricultural needs,  the salts in
the water are concentrated by evapotranspiration.  If they are not leached
from the crop root zone, the productive capacity of the land will be
eliminated.  On the other hand, if the flow of water through the root zone
greatly exceeds the natural drainage capacity of underlying soils and
aquifers, the water table level may rise until salts are transported into
the root zone by the upward movements of water caused by evapotranspiration.
Thus, salinity is a potentially significant problem in every agricultural
area being irrigated.

     Salinity problems also have a regional scope.   A downstream user is
generally supplied a more saline water than an upstream neighbor because the
concentrating effect, as well as the increased mass of salts acquired
through physical and chemical weathering of soil and acquifer materials.
Salinity levels in the lower elevations of a watershed reach their highest
levels as the total water resource approaches full  development.  Such
conditions of full development are occurring in important areas where the
costs of dealing with salinity have become a major  factor in agricultural
productivity and municipal-industrial treatment designs.

     The salinity problem in the western U.S. is a  classical case of an
economic externality--the problem is created at one location and felt at
another.  The free market system does not include an adequate mechanism
for returning the costs of salinity to the origin of the problem, and
the government must ameliorate the damages through  its power of regulation and
its own financial resources.  Provisions have been  made in several legislative
enactments to provide funds and guidelines to remedy individual salinity
problems.  However, few, if any, presently conceived salinity control
programs have considered a complete array of alternatives, selected those
of most cost-effectiveness, or evaluated the resulting instream impacts
of the program.  This report is a salinity related  appendix supporting the
basic planning manual entitled, "A Planning Guide for the Evaluation of


                                     364

-------
Agricultural Nonpoint Source Water Quality Controls," which is intended
to provide the planning methodologies needed to develop more effective
water quality strategies.

SCOPE OF REPORT

    The information needed to evaluate alternative salinity control programs
is generally available in a large body of technical literature.  However,
unless a planning group includes personnel from a number of disciplines
familiar with the literature, it is extremely difficult to integrate control
options into an effective and efficient framework for implementation.  It
is important for administrative personnel responsible for coordinating the
planning exercise to be capable of judging the adequacy of the planning
methodologies.  To assist this individual or group, this report gives a
generalized overview of important aspects of the planning problem associated
with the control of salinity in irrigation return flows.

    The scope of the appendix report has been restricted by three further
considerations.  First, the economic basis for comparing salinity control
alternatives has been limited to a relatively simple minimum cost criterion.
Minimum annual and annualized capital costs are accurate indicators of the
relative merits of most salinity control measures and are therefore,
adequate at the planning level.  The other technical appendicies for this
project outline the more comprehensive net benefit economic analyses that
could be applied to salinity control planning.  There are probably more
useful towards the implementation stage when such questions as cost-sharing
levels arise.  In general, salinity planning must recognize the large
spatial separation between source areas and impacted areas which complicate
economic analyses designed for "edge of field" evaluations, particularly
if the problem involves finding solutions restricted by pre-existing water
quality standards.

    The second limitation to the scope of this report is actually a result
of the first limitation, but one with a practical basis.  The array of
salinity control alternatives described herein are basically structural
in nature although improved management practices are implied in some cases.
These are grouped into treatments of the irrigation system to improve
efficiency and collecting, treating, and/or disposing of brackish irrigation
return flows.  Control of point sources such as saline springs, seeps, wells,
etc., can be examined along with agricultural salinity control alternatives,
but their control is usually straight forward.

    Examining only structural alternatives is based on the fact that
minimum cost criteria are usually limited to these measures.  However, they
also happen to be the measures most accepted, and therefore the most
feasible, by land owners and irrigation districts.  Land retirement,
pollution taxes, subsidies and regulatory changes in irrigation practices
and cropping patterns, etc., require comprehensive economic evaluation of
the sort discussed in companion reports.
                                    365

-------
    The third limitation is that the salinity control project is primarily
concerned with the mass emission of salts.  Most control measures will have
only minor impacts on the concentrating effect unless irrigated acreage is
reduced and phreatophyte consumption and evaporation are minimized.   Thus,
the primary impact of salinity control programs is generally to reduce
salt pickup from water-soil weathering.

USE OF REPORT

    The content and methodologies contained herein are considered by the
writer to be the minimum levels of analysis that should be considered
adequate in a planning document.  The use of this report, therefore, should
be a comparative one as well as a means to generate an assessment of the
costs and associated impacts that can be expected from the implementation
of selected measures.  It is intended to be supplemental to the main report
by addressing salinity specifically and alerting the reader to other sources
of information.

    The report is divided into five parts.  The first given as Section 2
outlines the methodology for delineating the elements and potential
solution to the irrigation-return flow salinity problem.  This almost
universally requires some mathematical simulation or modeling to be  effective.
The second part, Section 3, deals with improving irrigation conveyance
efficiencies by lining to reduce seepage.  This is followed by Section 4
describing methods to increase on-farm irrigation efficiency and finally
by Section 5 which discusses desalting as an alternative.  The report
concludes with a discussion of the Grand Valley salinity control project
in Colorado and demonstrates the planning methodologies described earlier.
                                    366

-------
                                  SECTION 2

                     MODELING THE HYDRO-SALINITY SYSTEM
     An irrigated area contributing to the salinity problems in a river
or groundwater basin must be initially studied by large scale and long-
term monitoring of water quality.  If the problem is acute and decisions
need to be made concerning the solution of the problem, the next questions
are the following:

     1.  Which segments of the irrigation system are responsible
         for the salinity loadings and to what extent?

     2.  What would be the in-stream impacts of control measures
         if implemented?

The hydro-salinity system in irrigated areas is far too complex to evaluate
without the assistance of computer models of these systems.  The purpose
of models is to systematically coordinate data input and computations which
simulate the real system in order to quantify the answers to the two
questions raised above.  The purpose of this section is to review the model-
ing procedures and indicate models already available which can be utilized
in the planning framework.
CONCEPTUAL HYDRO-SALINITY MODELING

     Simulation of the irrigated system generally occurs at two levels.
First, a mass budgeting of the local hydrology is undertaken to trace the
individual impacts of various irrigation system components on the aggregate
in-stream water quality.  The second level is a detailed simulation of the
soil and aquifer system to evaluate the chemical response of the system to
changes in the various water and salt flows.  Together these modeling
procedures detail the causes of salinity and the effectiveness of potential
solutions.

Developing Water and Salt Budgets

     The process involved in formulating general water and salt budgets
for an irrigated area is often referred to as hydro-salinity modeling.  A
schematic diagram of a general hydro-salinity model proposed by Skogerboe
et al. (1979) and shown in Figure C-l,  illustrates  a three level  subdivision
of the general system used to delineate respective water and salt flows.
First, as shown in Figure  C-2,  the irrigated system is  generally a  small part
                                     367

-------
                  Irrigation  System
  Water Supply
(Reservoir and/or
  River System)
                Main Delivery Subsystem
                          	 Water  Flows
                          	Salt Flows
                          	 System Boundary
                          	 Subsystem  Boundary
Figure C-l.   Schematic  of a generalized hydro-salinity  model
               (Skogerboe, et al.,  1979).
                                  368

-------
                                  00
                                                                       M
                                                                       d)
                                                                       CO
                                                                       5-1
                                                                       (1)
                                                                       •U
                                                                       n)
                                                                       o
                                                                      •H
                                                                       C
                                                                      •H
                                                                       0)
                                                                       M
                                                                       tfl
                                                                       bO
                                                                      •H
                                                                       S-i
                                                                       S-i
                                                                      •H

                                                                       a
                                                                       cS
                                                                      00
                                                                      p!
                                                                      CU
                                                                      CO
                                                                      
-------
of the overall hydrology in a region and must be segregated from other types
of water use within the hydrologic system in which it exists.  At the second
level, the main conveyance, secondary or lateral conveyance, on-farm and
groundwater subsystems are evaluated.  And finally, within each subsystem,
various hydrologic processes such as illustrated in Figure C-3, are simulated.

     The most common water supply for irrigation is the surface diversion
from streams, rivers and reservoirs.  If the water supply to the farm is
from groundwater, most if not all of the main and secondary conveyance
subsystems are by-passed and the groundwater subsystem has an input loop
into the on-farm subsystem.  However, a discussion of the surface supply
case will adequately illustrate the essential modeling functions.

Main Delivery Subsystem—
     Figure 1 shows two linkages with the surface hydrology and an irrigated
system.  The first is the diversion of water from the water supply and the
second is the return flow network comprised of surface wastes and subsurface
drainage.  The surface diversions, derived from data recorded by public
institutions charged with administering the water supply, are divided within
the main delivery subsystem into evaporative losses, seepage, diversions
into the secondary conveyance network, and surface return flows (spillage).
Evaporation can be estimated from climatological information whereas seepage
must be based on actual measurements that will be discussed later.  In some
cases, diversions into the secondary conveyance networks are also based on
administrative records inasmuch as this information is needed to properly
allocate water among the interests of the main conveyance subsystem.
Spillage is calculated by mass balance or as the difference in inflows and
outflows.

Secondary Conveyance Subsystem—
     The lateral subsystems convey water from the main delivery subsystem to
the farms.  As above, these flows may be either diminished by seepage
(measurement based flow), farm deliveries (occasionally measured, generally
estimated), and spillage (estimated, but often small in comparison to other
flows).  Evaporation is generally negligible.

Farm Subsystem—
     Water and salt reaching the farm system are initially divided into
field runoff (tailwater) and water entering the root zone,  Tailwater is
usually estimated from information describing the behavior of the irrigation
method.  In many cases, these flows are determined indirectly by subtracting
the root zone supply from the inflows.

     The important water movements within the root zone are evapotranspira-
tion and deep percolation, with water storage changes also occurring.
Separation of these flows by taking measurements on a large scale is
impractical and empirical computational methods must be employed.  The
operation of most budgeting models assume that irrigations are applied
uniformly over the cropland.  Phreatophyte vegetation in the area is assumed
to use water from other groundwater flows or natural precipitation which
falls on the area occupied by this vegetation.


                                     370

-------
  o
 N
  o
  CO
  c
  S  ;:
  s
  o
 V)  \
Upward  Flow  by Capillarity

 *   J	1	i
                                                                  Deep
                                                                  Percolation
                                                                    Water Table
            apillary Fringe
           of Water Table
Figure  C-3.  An illustration  of hydrologic processes comprising part  of  the
              on-farm subsystem (Walker,  1978b).
                                      371

-------
     Salts in the water applied to the crops move into the root zone where
they become concentrated by evapotranspiration.  The behavior of specific
ions is complex and not often considered at this particular level of
modeling.

Groundwater Subsystem—
     Most of the water in the soils and shallow groundwater aquifers originate
as seepage from canals and laterals, deep percolation from the irrigation
of croplands, and tributary subsurface inflows.  Groundwater discharges
eventually reach a local river or stream as drainage or subsurface return
flows.  The flows in the drainage system can be measured by installing flow
measuring devices at the outflow points.  Subsurface return flows are
estimated from water table elevation data, the hydraulic gradients and the
estimated hydraulic conductivities of the aquifer.  It should be noted that
in any hydro-salinity model, these estimated hydraulic conductivities
contain the largest potential for error.  Therefore, considerable effort
must be made to properly evaluate the necessary parameters in the groundwater
computations.

Detailed Simulations

     Detailed simulations are used to provide refinement to the hydro-
salinity models primarily in the temporal prediction of root zone and deep
percolation salinities.  These models can locally predict the quantity and
quality of the leachate with respect to time.  They can also quantify the
effects of reducing irrigation return flows and the corresponding reductions
in salinity.  Their most valuable purpose is to establish the functions
relating groundwater or deep percolation quantities and salt loading.  In
effect, such models are microscale hydro-salinity models that consider
individual chemical reactions, the ionic constituents and the water flow
system.

     The hydro-salinity models generally describe the existing water and
salt flow conditions in an agricultural area.  Many methods for predicting
the reduction in salts returning via the groundwater to the river as an
outcome of salinity control measures assume a one-to-one relationship
between water and salt flows.  For example, when subsurface return flows
are reduced by 50 percent, it is assumed that salt loading is also reduced
by 50 percent.  This may be a poor assumption.  It is usually necessary
to perform a detailed simulation to arrive at the correct relationships
between the volume of return flows and the mass emission of salt.

     One of the most popular detailed simulation models is the program
initially developed by Dutt et al.  (1972) and later updated by Shaffer
et al.  (1977).  The model consists of three separate programs.  The first
program describes soil-moisture movement and distribution with time.  The
second program interfaces the soil-moisture movements with a chemical-
biological model to reconcile differences in the soil layers used in the
calculations of soil moisture and chemistry.  The third program computes
the chemical and biological activity occurring in the soil profile.
Figure C-4 shows a block diagram of the overall model and illustrates the
conceptual approach.

                                     372

-------
                                            CM
     Q CO
     Z U)
     <
Q.
Z
                                      o

                                      UJ
                                      o
   \-
    Q
(L CO

-------
EVALUATION OF AVAILABLE MODELS

     The use of computers in the study of the complex irrigation system
processes has provided a means for their rapid and intensive evaluation.  The
basis for the computer codes (or models) is the expression of the real system
as concise mathematical relationships with the major thrust of most models
being associated with the excess water being applied to croplands.  The volume
of irrigation water needed to promote high crop yields is almost universally
less than the volumes diverted for these purposes.

     The principal interest here is the models which deal with the environ-
mental impact of irrigation return flows (IRF).  These are the models which
simulate the occurrence and magnitude of the flows, their quality character-
istics, and their effects on receiving waters.  Recognizing that the IRF
system is an aggregate of several complex hydrologic, chemical, and biological
processes, this group of models also includes simulations of the basic
processes.  A more detailed evaluation intended to summarize modeling state-
of-the-art, including a brief description of the model scope, input
requirements, characteristics of the computer code, expected time and spatial
resolutions, basic mathematical approach, and where possible a note concerning
previous applications, calibration, or verification is given by Walker
(1978b).

Scope and Resolution of Existing Models

     It is convenient to classify the available IRF models into three levels
of simulation:  (1) simulation of the basic hydrologic, biological, and
chemical processes; (2) simulation of particular subsystems of the irrigated
system, and (3) simulations of large scale irrigated systems.  In many cases,
level 3 models consist of several integrated level 1 and 2 models.

Process Level Models—
     The principal hydrologic processes in an irrigation system include
transpiration, evaporation, infiltration-redistribution, and root extraction
(Figure C-3).  Associated with each of these processes are a number of chemical
and biological transformations affecting the dissolved and adsorbed
constituents in the soil.  The programs classed as process level models
include for the most part simulation of infiltration-redistribution,
unsaturated soil solute chemistry and transport, and irrigation uniformity.
Other contributions to irrigation return flows which might be categorized
as process level topics, namely conveyance seepage and field tailwater, are
generally not modeled independently.  Root extraction, transpiration, and
evaporation do not appear separately in most modeling efforts, and are
therefore included in the second level of modeling.

     Process level models by themselves have only marginal utility in
evaluating irrigated systems unless the modeler proposes to fabricate new
subsystem or system models.  Two important exceptions are to be noted.
First, deep percolation represents a major component of return flow.  Analysis
of deep percolation or leaching depends on either determining a root zone
mass balance or simulating the infiltration-redistribution process.  The
first alternative requires more data, and is more applicable to large

                                     374

-------
scale situations.  Evaluating infiltration-redistribution involves shorter
time intervals, less data (although more sophisticated), and yields a closer
approximation to the actual event.  The second exception is the analysis of
the chemical-biological aspects of soils and soil solutes.  Moisture flow is
often better approximated by assuming steady-state conditions or that the
transient nature may be represented by a series of steady-state conditions.
In these cases, the quality aspects of modeling are somewhat independent of
the moisture flux and can be accurately simulated by limiting the scope
of the analyses.  These types of models are also of benefit when computer
time and core capacities are limited.

Subsystem Level Models—
     The subsystem level of modeling is defined as the combination of two
or more process level simulations.  The main subsystem for IRF studies is
the field hydrology within the irrigated system itself.  In a major water-
shed or river basin, there are other logical subsystems describing
precipitation-runoff relations, reservoir operations, instream processes like
dissolved oxygen behavior, groundwater interflows, etc.  Within the irriga-
tion system itself there may be a number of similar subsystems reflecting
different soils, crops, and irrigation management practices.

     As with any modeling classification, subsystem models vary in the scope
and dimension of their mathematics.  Some models are detailed treatments of
a small part of the irrigated agriculture subsystem while others are more
macroscopic, large scale and time resolved treatments.  The more detailed
models involved basic physics and chemistry principles whereas the macroscopic
approaches are generally mass continuity descriptions.

System Level Models—
     As the scope and scale of IRF models increase, the variety of models
also become wider.  At the system level, there are two broad classes of
models.  The first is the models of the agricultural watershed in which one
or more unsaturated zone subsystems are linked with a groundwater or drainage
subsystem simulation to predict total IRF volumes and their time distribu-
tions (Figure  C-5) .  The  second  set  of  system models  are  those  simulating
river basin or subbasin hydrology (Figure C-2).  In these models, irrigated
agriculture represents a small fraction of the actual land area and the
emphasis is on evaluating the impact of irrigation on the system rather than
quantifying its magnitude.
ASSESSMENT OF IRF MODELING CAPABILITY

     If irrigation return flows are to be minimized in an area, the excess
diversions and applications should approximate the water just necessary
to maintain a favorable salt balance in the root zone.  The capacity of
conveyance and drainage systems should be reduced to the peak seven to ten
day average consumptive use rates.  Obviously in most situations, large
capital investments for remodeling the irrigation and drainage facilities
would have to be made in advance and each irrigator would require substantial
retraining.  It can also be argued that the agricultural scientists and


                                     375

-------
INFLOW
   \

 r
                   ^^'
               (
\
                STREAM GAGING
                   STATION A
   V
     ^N
      \
       i

       \
        V
          i- o  s As
         where
            I   = Inflow
            0  = Outflow
            AS = Change in Storage
          \
                                     STREAM
                                  GAGING STATION
                \
                                                           OUTFLOW
Figure  C-5.  An illustration of a largely  agricultural watershed evaluated at
            the system modeling level.
                                  376

-------
engineers would need significantly better practical or "hands-on" training in
order to assist the irrigator.  To achieve these conditions, years of investi-
gations must also precede the decision for implementation.  The dimension of
the problem needs to be defined and the effectiveness of the alternative
improvements predicted.  The simulation model is one of the most important
tools available to planners and researchers as they seek to remedy the
irrigation problem.

     After evaluating these irrigated system models it becomes apparent that
the existing models are almost entirely research oriented and are not easily
or cheaply utilized.  Planners are generally not using models to arrive
at their decisions and risk the likelihood of these plans not being cost-
effective.  The existing models need to be thoroughly reevaluated, their
parameter sensitivities quantified, and alternative simplifying assumptions
assessed.  A new modeling technology is needed for planning and large scale
evaluations.
                                     377

-------
                                  SECTION 3

                      CONVEYANCE SYSTEM SEEPAGE CONTROL
EVALUATING SEEPAGE LOSSES

     There have been numerous methods developed for measuring seepage from
canals and laterals involving both field and laboratory investigations.
Each has its own unique characteristics that make it useful under certain
conditions.  The objectives of this discussion are to describe several methods
that could be used as a part of salinity investigations.

     The factors influencing seepage rates include:  the soil characteristics
of the channel bed; time of year the tests are made; length of time water has
been in the channel; depth to the water table; sediment load in the water;
depth of water in the channel; temperature of both the water and soil;
barometric pressure; biological factors; and salts contained in both the
water and soil (Robinson and Rohwer, 1959; U.S. Bureau of Reclamation, 1952
and 1963; Rohwer and Stout, 1948; Brockway and Worstell, 1968).  Although
the literature contains much information about the relationship between
these parameters and seepage rates, the conditions found in most conveyance
systems are so variable that individual field tests are generally required.

     The most common methods of measuring seepage can be categorized as those
that yield results indicating an average seepage from a length of channel
and those in which information simply gives the permeability of a sample of
the channel bed.  If the latter type of measurement is employed, additional
information on hydraulic gradients is necessary in order for the actual
seepage to be computed.  In most investigations, those methods that indicate
actual seepage rates prove to be most valuable.  Three of the most employed
methods include the inflow-outflow method, ponding method, and seepage-meter
method.

Inflow-Outflow Measurements

     When the seepage rates from relatively long lengths are to be measured,
the inflow-outflow method is a reliable and commonly used technique.  The
method consists of measuring all inflows and outflows to the canal or lateral
section under investigation.  By computing the net discharge loss in the
channel, the actual seepage rate can be determined.  Since the usual units of
seepage rate are m^/m /day, the conversion from the total loss in the section
also requires measurements of the length and wetted perimeter (average) of
the channel.  The seepage rate can thus be expressed as:
                                     378

-------
                    „„ _ (Inflow - Outflow) x 8.64 x 1Q4                  ,.,
                    SR -£(1)
                               o  2               4
in which SR = seepage rate in mj/m /day, 8.64 x 10  = number of seconds per
day, A = average wetted area of the channel in m , and the difference between
the inflow and outflow is expressed in m^/sec.  The canal reach must be
of sufficient length so that the total seepage loss is much greater than the
expected measurement error.

     Although this method does give an indication of seepage rates under
actual operating conditions, there are several factors that should be care-
fully observed or large errors will be introduced into the results.  The
maintenance of constant flow depths in the canal during the tests is essential
to eliminate the effects of bank and channel storage changes.  Also, an
accounting must be made of all return flows from uplands and diversions or
leaks from the canal.  Occasionally, if the seepage rates are small, it may
be useful to note rainfalls and evaporation, although these latter factors
are generally inconsequential.  Finally, flow measuring devices to be
employed should be considered.  In the absence of measuring structures in the
system, flows generally can be measured by flumes, weirs, and current meters
to accuracies of about 5 percent if operated correctly.  Specialized methods
such as the dye-dilution technique discussed by Liang and Richardson (1971)
can be used in large channels.

Ponding Method

     Although an objection is often raised that still water may seep at a
different rate than flowing water, the difference is probably small in
comparison to errors associated with discharge measurement.  Basically,
the ponding method involves measuring the rate of fall of the water surface
in the pool created in the canal section (Figure C-6) .  Then, by measuring
length and cross-sections, it is possible to compute the seepage rate
according to the following formula:

                                  AE x SW  x 24
                             SR =    WP  xT                              (2)
                                       a

where AE = drop in water surface elevation in meters, SW  = average surface
width in meters, WP  = average wetted perimeter in meters, and T = time of
the run in hours.   a

     The ponding method usually provides the basis for comparison with other
methods because it can be expected to yield the best results (Robinson and
Rohwer, 1959; U.S. Bureau of Reclamation, 1968).  It does have certain
disadvantages that should be noted.  Construction of the dikes is often
expensive and must be completed during peiords when the canal is not in use,
or during periods  of interrupted canal operation.  Providing water to fill
the ponds may represent a significant problem.  If the canal discharges are
very large in relation to the seepage rates, then the ponding method is the
best method by which the seepage rates can be determined.  Under such
conditions, errors expected in other methods, may prevent any seepage losses
from being observed.


                                     379

-------
           /•Dam  /Headgate
   Spillage |v
Water Level
Measurement
Stations
                                        Water Supply
                                                                               Wasteway for
                                                                               Excess Water
                                                                               Control
                                                                               (Optional)
                                     Plan View
               'Headgate

       Dam    (   j- Meas. Station
                                                                      /Vf
                                                                     I/   \ I
                                  Section View
                                  ( Not to Scale )
                                                              Water Stage Recorder
                                   Steel Headgate

                  Temporary Earthen Dam
                                  Water Level.
           Downstream
           Water Level
             Temporary  Dam and Water Measurement Station Detail
Figure C-6.   Schematic  representation  of the ponding  test  method for seepage
                measurement (Skogerboe et^ a±. ,  1979).
                                           380

-------
Seepage Meters

     Seepage meters determine seepage rates under normal operating conditions,
but only for a small fraction of the total area.  Nevertheless, by taking
readings at several points along the canal section, a realistic average
value can be determined.  One type of seepage meter uses a cylindrical bell
that is pressed into the channel bed.  Attached to the bell via plastic hose
is a plastic bag filled with water that is submerged in the channel.  Water
that seeps into the channel bed is replaced by water in the bag which is
under the same pressure as the channel flows. Seepage from the bell is
determined by weighing the plastic bag before and after the test, and the
elapsed time of the test.  The seepage rate then may be determined by:


                                 SR =
                                      Ar
                                                                        o
in which Q = the amount of water that seeped through the canal bank in m ,
A = the area of the bell in m , and T = elapsed time in days.

     The seepage meter may be expected to work well unless the bed material
is badly disturbed during meter installation.  The seepage meter method is
difficult to apply under conditions in which the flow depths are too great
or the channel velocities are too fast.  Gravel, moss, or heavily vegetated
channels present difficulties in properly evaluating seepage rates.
ESTIMATING LINING COSTS

     The direct contribution to local or regional salinity problems from
water conveyance networks is generally the result of seepage.  Seepage from
canals, laterals, and ditches can be reduced or eliminated by lining with an
impervious material such as concrete, plastic, or asphalt.  Concrete is
probably the most common lining material because of combined advantages
relating to cost, ease of construction, availability, maintenance, and low
permeability.  For small channels, it is often advantageous to convert the
conveyance to small (usually plastic) pipelines.  Lining costs vary from
site to site and should be estimated for each individual case.

Canal Linings

     A review of concrete linings costs in the western United States by
Walker (1978a) indicated a reasonably high correlation between capacity
and cost.  Data presented by the U.S. Bureau of Reclamation (1963, and
personal communciation) and Evans  et al. (1978) indicate the following
general form:

                                        K2
                               Cc = Kx Q   + K3                           (4)

                                                                     3
in which C  = unit lining cost, in $/m; Q = conveyance capacity, in m /sec;
Kp K2 = empirical site specific coefficients; and Ko = fixed costs, in $/m.
The slope of the canal would affect values of Kj and K^ since a given


                                     381

-------
discharge can be conveyed in a smaller channel if the slope is increased.
Many large canals have fairly flat slopes and can be estimated with Eq. 4.
If the channel slope is greater than 0.001, the coefficients should be
reevaluated.

     For typical July 1979 conditions, the value of K, was found to be 94.61,
K  was 0.56,  and K, ranged from $24-$90/m.  The costs included in the first
term on the right-hand side of Eq. 4 are earthwork, relocation, lining costs,
service facilities, engineering and investigative and administrative
expenses.  Fencing, diversion, and safety structures are included in the
coefficient,  K».  In an irrigation system, the discharge of the network
declines along its length due to continuous withdrawal for irrigation and
less acreage serviced per unit length.  If it is assumed that the discharge
can be linearly distributed, an expression for this distribution can be
combined with Eq. 4, and then integrated over length.  The resulting
expression gives the total cost of lining a specific length, L (Walker et
al., 1979):
C  — K, Q   -T-.	;———r—-
 c    1m  (1  + K2)b
                                    1 -  I 1 -
                                                   1+K,
                                              bL
(5)
where Q  = inlet channel capacity, m^/sec; Lfc = total channel length, m; and
b = empirical constant associated with the distribution of channel capacity.

     The effect of lining a length of a particular channel on salt loadings
can be based on the difference between the equilibrium salinity in return
flow and the salinity in the seepage water.  Walker et al. (1979) developed
the following expression for estimating the impacts of channel lining:
                              Q~ - Q,
              Sl =
in which S, = annual salt loading reduction in megagrams per year  (Mgm/yr)
associated with lining L meters of a canal or lateral; AS  = difference
between the equilibrium salinity concentration in the return flows resulting
from seepage and the concentration of the initial seepage flow, mg/1;
N  = number of days per year water flows in the channel, ASR = change in
seepage rate due to the lining, rn^/m /day; Q  = total volume of irrigation
return flows, m-Vyr; Qp = consumption of return flows by phreatophytes,
m3/yr; and WP^ = wetted perimeter of the canal or lateral and its inlet
capacity,  m.

     Equations 5 and 6 indicate the cost-effectiveness of a lining program
and can be combined if necessary for a single mathematical expression.

Small Ditch and Lateral Linings

     Small ditches and laterals have basically the same cost-effectiveness
characteristics as larger scale linings.  However, three differences should
                                     382

-------
be noted.  First, the small capacities generally do not warrant expensive
fencing, diversion, and safety structures and therefore K,. in Equation 4
can be considered negligible.  The second difference is that the operation
of smaller conveyance channels is distinctly different from larger systems.
Ownership is often private and sharing of flow is often rotated.  Consequently,
the discharge capacity generally does not diminish significantly along the
channel length and Equation 5 can be simplified by letting b = 0.

     It may be worth noting here that using the large canal values of K, and
K~ coefficients for small ditches may introduce significant errors.  Small
ditches often have larger slopes and thereby carry a given flow rate in a
smaller cross-section.  In addition, the construction specifications are
often less stringent, thereby reducing the costs.  Pipelines can be used to
replace open ditches where feasible.

     It is possible to provide the user of this report with some information
useful in defining the coefficients in Equation 4.  Typical values of slip-
form concrete lining costs in the western U.S. using the sulfate resistant
specifications of the U.S. Department of Agriculture, Soil Conservation
Service can be approximated by


                           y - exp - ( y9;3°-65 )                          (7)

                                                   2
where y is the cost per square meter of lining ($/m ) and x is the perimeter
of the lining in meters.  Costs for ditches carrying up to 0.4 m /sec range
from $9/m to $12/m.

     The costs of converting a small ditch or lateral to a pipeline convey-
ance involves two cost estimates.  The salinity or effectiveness functions
are the same as given above.  Irrigation pipeline materials range from
plastic to concrete and metal.  A typical pipeline cost using low head PVC
pipe is  0.72 $/cm of diameter/m of length and includes flow measurement,
trash removal, and inlet structures.

     As a general rule, slip-form concrete and low head PVC pipelines have
about the same salinity control cost-effectiveness.  The use of other
materials in these small capacity systems represent much higher cost and are
therefore not generally cost-effective in comparison.


OPTIMIZING CANAL AND LATERAL SALINITY CONTROL

     Each canal or lateral network is characterized by unique values of cost
coefficients, seepage rates, discharge distributions, salinity conditions,
and return flow paths.  As a result, there are substantial differences in
the cost-effectiveness of lining various systems.  Simple operation research
techniques for evaluating the optimal lining program in an area have been
reported by Walker et al.  (1979)  and Evans et al. (1981).  These will not
be given here, but they should be reviewed for actual planning exercises
since they are simple and effective.


                                     383

-------
                                  SECTION 4

               ON-FARM CONTROL OF SEEPAGE AND DEEP PERCOLATION
EVALUATION OF IRRIGATION EFFICIENCIES

     Farm investigations for nonpoint pollution control constitute the
largest proportion of work involved in the evaluation of an irrigated area.
Of the water applied as irrigation to croplands, some returns to the
atmosphere and some returns to the groundwater and stream systems from which
it was diverted.  Segments of this complex system are often characterized
by a chemical constituent derived from the earth materials contacted by the
water.

     Salinity is primarily associated with two segments of the field of
hydrology:  (1) on-farm conveyance seepage, and (2) deep percolation.  In
order to provide a direct measure of effectiveness in managing seepage and
deep percolation, a modified version of application efficiency is suggested.
Application efficiency, E , as used herein is defined as the percentage
of irrigation water actually applied to the soil reservoir that is stored
and then utilized from the root zone.  Another on-farm return flow, field
tailwater, is not included in this definition because it has a very minor
effect upon salinity.  Precipitation entering the soil profile should be
included.  Thus,

                       AS  + E' - P          E  - P
                  E  = —	=±	 x 100 = -i	— x 100                 (8)
                   d         .L               r , — 1
                                              d    W

in which AS   = change in soil moisture storage before and after an irriga-
tion, cm; I = infiltrated irrigation depth, cm; P = precipitation during
irrigation, cm; E' = evapotranspiration during irrigation, cm; Et = evapo-
transpiration between irrigations, cm; F, = field deliveries, cm; and T  =
field tailwater, cm.

     The variety of structural improvements that might be effective in
increasing application efficiency includes lining or piping head and tail-
water ditches to eliminate seepage, conversion to alternative irrigation
systems to apply water more uniformly and with better control of the
application depth, and modification of existing systems such as by added
flow measurement devices, land leveling, and automation.

     The improvement of irrigation efficiencies through on-farm seepage
control can be evaluated with the methods outlined in Section 3 except
that on these small systems, the parameter, K~, would normally be zero and


                                     384

-------
K. should be reduced to a value of about one-third since construction
specifications are less rigid and the ditch contains fewer control structures.
The use of pipe rather than concrete linings, particularly gated pipe, can
also be included in this manner.

     The effectiveness of amending existing systems or converting to other
methods of irrigation depends on the difference in application efficiency
that can be achieved.  Specifically, the change in deep percolation can be
written as:

                             AD  = (1 - AE ) D                            (9)
                               P          33.

in which AD  = reduced depth of deep percolation, cm; and D  = average depth
of applied water, cm.

     By assuming that the soil chemical reactions can be considered in
equilibrium, the prediction in salt pickup associated with a change in deep
percolation is developed into the following form:


                       AS  = AS AD  (  -Brr	E)x 10~4                     (10)
                         E     c  p \   Qg    /


in which AS  = reduction in salt loading due to improved application
efficiencies, Mgm/ha/yr.

     Evaluation of the term, AE , is a difficult task.  It requires that
existing efficiencies be characterized and that expected efficiencies for
potential improvements be predicted.  Both tasks are compounded by the highly
variable and diffuse nature of irrigated systems.  About 70% of the irrigated
lands in the United States are served by surface irrigation methods, in
particular furrow, border, and basin systems.

Furrow Irrigation

     Furrow irrigation is a method of water application accomplished by
diverting flows into small channels which traverse the field slope.  In
irrigated fields, these closely spaced channels are referred to as furrows,
rills, creases, or corrugations.  As the irrigation water flows in the
furrows, the infiltration into the bottom and sides of the furrow is
redistributed in the crop root zone.

     Efficient furrow irrigation requires that the inlet discharge and the
duration of the irrigation be carefully coordinated with the field slope,
furrow geometry, infiltration capacity of the soil, and the soil moisture
holding characteristics.  Crops which are subject to crown or stem injury
if covered with water are often irrigated by furrows.  This method is also
well suited for crops which are planted and harvested in rows.  The two-
dimensional soil moisture movement condition is advantageous in not only
minimizing the wetted surface area but also in the movement of fertilizers
and pesticides toward the central root zone.  The furrows are often used by


                                     385

-------
irrigators in controlling the distribution of water over a field that is not
uniformly graded.

     The driving force for furrow irrigation is gravity, but the subsequent
redistribution of soil moisture and evapotranspiration are functions of many
soil-plant-atmospheric parameters.  The water application itself, however,
can be divided into three phases:  (a) advance; (b) wetting; and
(c) recession.  For the normal practice of irrigating when the soil moisture
reservoir has been depleted 50-75 percent, the recession phase is compar-
atively insignificant (Fok and Bishop, 1965).  Infiltration at a specific
point along the furrow begins at the moment the advancing water front
reaches the point (advance phase) and continues as long as water remains
in the furrow (wetting phase).  When the discharge at the head of the furrow
is terminated, the flow recedes down the field until reaching the end
(recession phase).

     The evaluation of a furrow irrigation system involves a number of
alternative approaches.  Detailed descriptions of the procedures are given
by Griddle et al.  (1956), Merriam and Keller (1978) and Walker et al. (1981).
The problem is two-fold.  In the initial stages of design or evaluation, the
first investigative efforts are oriented toward definition of the intake
relationships.  Later, with a knowledge of intake characteristics, the
advance and uniformities are predicted.

Field Evaluation and Infiltration—
     Infiltration of water into the bottom and sides of a furrow is a two-
dimensional process, the magnitude of which depends on depth of flow,
furrow shape, and type of soil.  Therefore, accurate information regarding
infiltration characteristics may be obtained under actual flowing conditions
or using a number of available on-site measurement techniques (blocked-
furrow infiltrometers, inflow-outflow measurements, and cylinder
infiltrometers).  There are limitations associated with each procedure.

     The only technique using flowing conditions for the infiltration
determination is based on rate-of-advance data.  This approach is based on
the principle of kinematics or volume-balance and requires accurate knowledge
of the water introduced at the head of the furrow  (V ) and the volume of
storage in the furrow at any time (V,,).
                                    s

     The primary element in surface irrigation evaluations is definition of
soil intake or infiltration rates.  Many empirical equations have been
proposed, but the most commonly employed is the relationship introduced by
Kostiakov (1932):

                                   i = atb                                 (11)

where i = infiltration rate, cm/min; t = interval since infiltration began,
min; and a,b = empirical regression coefficients.  Equation 11 can be
integrated over the irrigation interval to yield cumulative depth of
infiltration.
                                     386

-------
     Because the intake opportunity time varies in a field due to the time
required for water to reach a point, the infiltrated depth over a field's
length will also vary.  A commonly employed function expressing the relation-
ship between the advance rate and time is:

                                   x = pt*                                (12)
                                         -X

where x = the distance along the flow path, m; t  = time to advance x meters,
min; and p,r = empirical regression coefficients.  Actually, the parameter r
is closely related to the infiltration exponent, b, as shown by Fok and
Bishop (1965):

                              r = exp ( - 0.6B)                           (13)

where B = b+1.  Generally, r is determined by field data and then used to
estimate B.  Because Equation 12 is an exponential function, the slope r can
be determined by knowing two points on the curve, say the time required
to reach the end of the field, t, , and the time necessary to advance one-half
the field length, t_ „,
                   (J • -)J-i
                                r = 0.69/ln T                             (14)

in which

                                T = 'lAo.SL

     The parameter, p, however, depends on the inflow, slope, roughness,
and furrow geometry.  Data have been reported which tend to substantiate
these conclusions, but a well verified general predictive capability for
p has not been published so far as the writer now knows.  Consequently,
values for p must be determined for each irrigation test.

     By conducting field tests to evaluate p and r in Equation 12 and then
allowing B to be defined by Equation 13, only the parameter, a, remains
unknown.  It is however, easily defined by volume balance at the end of
the advance phase.  A detailed mathematical approach for this process is
found in Walker et al. (1981).

     The volume balance analysis has at least two important advantages for
field scale evaluations.  First, the approach determines an average furrow
infiltration rate expression rather than the point measurements derived from
other techniques.  Thus, the problem of spatial variability at least along
the furrow is appropriately addressed and the variability across the field
can be determined by investigating a number of furrows.  And secondly, the
data necessary to calculate infiltration are easily determined.  The
investigator diverts a known and constant discharge into the furrow, notes
the times until the flow has advanced one-half the field length and the
field length, and measures the cross-sectional area.  These data along with
the field slope and length allow evaluation of the soil intake character-
istics.
                                     387

-------
Predicting Application Efficiencies —
     Once the infiltration coefficients have been evaluated, the application
efficiency for any soil moisture deficit can be predicted.  Three cases for
the furrow irrigation regime may be detailed:  (a) the under-irrigated case
where some of the lower reaches are not completely refilled (Figure C-7a);
(b) the case where the minimum irrigated area is just refilled (Figure C-7b) ;
and (c) the general over-irrigated case (Figure C-7c) .

     Gerards (1978) and Walker et al. (1979) derive equations for calculating
application efficiency for the three furrow irrigation regimes using three
simple time ratios:  (1) M = ratio of time required to infiltrated desired
depth (soil moisture depletion) to total time of irrigation; (2) K = ratio
of the field advance time to the time for advance flow to reach the point
(X ) where the soil moisture depletion is exactly replaced; and (3) P =
ratio of field advance time to total irrigation time. Using these ratios,
the application efficiency for furrow irrigations can be represented by:


                Ea
E (CI) = E (01) =  7        M      x 100                 (17)
 a        a
                                                   1
                                                   j
in which UI, CI, and 01 are the irrigation regimes on Figure  C-7  and  P.J  (P) =
"incomplete subsurface shape factor":

                                 (3±(P) = n Pm                              (18)

                         n = 0.9598 exp (-0.3383 B)                        (19)

                         m = 1.0171 exp (-0.9763 B)                        (20)

Border and Basin Irrigation

     The oldest and most widely practiced methods of irrigation are border
and basin irrigation.  Border irrigation uses earthen dikes or "borders"
to contain the water within specified boundaries.  When the border has a
very small slope and the end is also diked to prevent runoff, they are
referred to as basins.  Thus, basin irrigation and border irrigation  are
similar water application methods and can be considered together.

     On very steep areas where land leveling costs would be prohibitive and
the soils are usually not deep enough for leveling, a variation of flood
irrigation using dikes is used.  This method is often called  guide border
irrigation.  Generally speaking, these "borders" are spaced fairly close
together, the runs are short, and uniformities and efficiencies are low.

     Graded border irrigation requires that the field be divided  into strips
varying from 10 to 20 meters or more in width and extending 100 to 800
meters in length.  The slope of these "bordered strips" should not exceed
                                     388

-------
                                   X0     L       f        x
                                        (a) under-irrigation
                                                      f    X
                                        (b) complete-irrigation
                                                        !  x
                                        (c) over-irrigation
Figure C-7.   Definition sketch of surface irrigation application uniformity
             for a)  the case where part of the field is underirrigated,
             b)  the case of zero underirrigation, and c) conditions of
             significant overirrigation.
                                    389

-------
2 percent for row crops.  Slopes can be as high as 6 percent for small grains
and pastures or hay.

     Irrigation efficiency of graded borders is usually about 65 percent,
and the application efficiency ranges from 70 to 80 percent with proper
amangement.  Bos and Nugteren (1974) in a worldwide survey of irrigation
efficiencies reported that the average application efficiency for graded
borders was about 53 percent.  The average for the United States was 57
percent.  A limitation of graded border irrigation is that it generally
requires considerable skill and a higher degree of management than does
furrow irrigation.

     The level border or basin irrigation method consists of turning
relatively large streams of water into the plots surrounded by dikes or
levees.  This method is especially adaptable to soils with moderate to low
permeability rates where other irrigation methods do not provide an adequate
infiltration opportunity time.  In the study cited earlier by Bos and
Nugteren (1974), application efficiency on a worldwide basis for level
borders and basins averaged about 58 percent.  In the United States, the
average value was 59 percent.

Predicting Border Application Efficiencies—
     The evaluation of the infiltration coefficients for both the border and
basin irrigation system can be accomplished with the water advance procedure
discussed under the heading of furrow irrigation.  The only analytical
differences are that instead of furrow inflow, the discharge per unit width
is used and the corresponding flow area is simply the depth times a unit
width.

     Unlike furrow irrigation where water movements after the inlet flow
shut-off were neglected, these movements must be considered for the border
irrigated system.  There are two components of the post shut-off period.
The first is called the depletion phase in which the water at the head of
the border just drains off and infiltrates.  The second is the recession
phase where the remainder of the surface water flows from the field and
infiltrates.  A schematic illustration of these phases is shown in Figure C-8
The analysis of border irrigation efficiencies is more detailed than can be
given here and the interested reader is referred to Strelkoff (1977).

Predicting Basin Irrigation Efficiencies—
     The estimation of basin application efficiencies is somewhat simplified
by the small field slope and the prevention of runoff.  Water first entering
the basin would advance to the end dike and then pond on the surface as
illustrated in Figure C-9.  As the water surface rises, it will approach a
horizontal orientation.  Once the inflow is shut-off, the surface profile
also assures the horizontal condition.  Thus, it can be seen that during the
depletion and recession phases, the surface water has little or no movement,
and the subsurface profile can be determined by adding the surface depths to
the profile which developed during the advance phase.

     The application efficiency computation for basins requires an estimate
of the water depth at the head of the field  (Y ) and at the end (Y^) as well

                                     390   -

-------
Figure C-8.  Schematic surface profiles for border irrigation indicating
             the depletion and recession phases of the post shut-off period.
                                    391

-------
       Supply  Ditch
                       Completely Ponded Condition  at Shut-off
                        Partially  Ponded  Condition at-Shut-off
Field Inlet
Figure C-9.   Schematic  representation of a typical basin irrigation system
             showing two  conditions of the surface water profile following
             shut-off.
                                        , t .  At Jhe
the infiltrated  depth  at  the basin inlet is I  - At CQ and
 = A(tco - t)B.   At the  end of the irrigation, these
 as the  time required for the water to advance over the  basin,
 cut-off time,  t
 at the  end ±t  i     = A(tco - tL)
 depths  will be increased to:
                                o
                                  = AtB  +
                                      CO
                                                      (21)
                                     392

-------
and
in which A = a/b+1 and B = b+1.   Then assuming a near linear subsurface
profile, the application efficiency for the basin case is:
                                      21
                                Ea - T-T-I7                              (23>
                                      o    1

where I  is the average depth of moisture required to refill the root zone
reservoir.

Sprinkler Irrigation

     Sprinkler irrigation systems are recommended and used on pratically all
types of soils and on almost all types of crops.  This type of irrigation,
with its flexibility and efficient water control, has permitted a wider
range of soils to be irrigated than have surface water application methods.
It has thus allowed more land to be classed as irrigable.  As a direct
result, many thousands of hectares, which were previously considered suitable
only for dryland farming or as wasteland, are being irrigated today and
producing high yields.  This phenomenon is particularly evident in eastern
Colorado, western Nebraska, and Kansas.

     Sprinklers, like most physical systems, do have disadvantages.  Damage
to some crops has been observed when poor quality irrigation water has been
applied to the foliage by sprinklers.  Also, poor quality water can leave
undesirable deposits or coloring on the leaves or fruit of the crop.
Sprinklers are also capable of increasing the incidence of certain crop
diseases such as fire blight in pears, fungi or foliar bacteria.

Evaluating Sprinkler Irrigation Efficiency—
     Because the depths of water applied over a surface irrigated by a
sprinkler system are largely independent of soil properties, the efficiency
analysis is based on a cumulative frequency function of the pattern
uniformities.  The procedure for testing sprinkler systems is outlined by
the American Society of Agricultural Engineers in standard A330, and will
not be repeated here.  The information of interest derived from the testing
is the spatial distribution of water under the wetted pattern.  These data
are usually collected by arranging catch-cans in a grid pattern over the
area and then measuring the collected depths in each can.

     The catch-can data can be used to develop a statistical measure of
uniformity that can be related directly to application efficiency.  Walker
(1979) developed empirical equations for the relationship between the
fraction of the area not receiving adequate depths,  A ,  and the coefficient
of variation Of the pattern,  v,  required to refill the root zone.
The resultant expression for application efficiency, is described as follows:


             Efl = 1 - v [ 3.634 - 1.123 A^'3 + 0.003 A^'2325  ]           (24)

                                    393

-------
Trickle Irrigation

     Trickle irrigation is a system whereby water and possibly fertilizer
are applied directly to individual plants, as opposed to irrigating the
entire field area as with surface or sprinkler irrigation.  For orchard crops
and other widely spaced crops, this is accomplished with small diameter
"laterals" running along each crop row.  "Emitters" attached to the lateral
supply each plant with its water needs.  In the case of row crops or truck
crops, products are available with small diameter orifices spaced along
a thin-wall hose, or porous walls through which water is allowed to escape
to the soil.

     With trickle irrigation, water may be provided to the crop on a low-
tension, high-frequency basis, thereby creating a near optimal soil moisture
environment.  Because only the plants' root zone is supplied with water
(Figure c-10),  under proper  system management little water is  lost  to  deep
percolation, consumption by nonbeneficial plants, or soil surface evaporation.

     In addition to reduced water requirements and minimization of return
flows, trickle irrigation has other positive advantages.  These include:
(a) relatively saline water may be used under proper management; (b) sloping
or irregularly shaped land areas may be more easily irrigated; (c) sandy
soils may be more efficiently irrigated; (d) increased production with most
crops is documented; (e) irrigation labor requirements are reduced;
(f) insect, weed, and disease problems are often reduced; (g) soluble
fertilizers and possibly pesticides may be applied through the
system; (h) harvesting and tillage operations may occur simultaneously with
irrigation; (i) systems may be easily automated; and (j) the practicality
of using low-yielding wells is increased.  Also, there is potential for
using sewage or processing effluent water as a water source.

     Good system management on the part of the irrigator is very important
in achieving high efficiencies with trickle irrigation systems.  Some excess
water is required for leaching and providing a small safety margin.  Keller
and Karmeli (1975) suggest E  = 0.90 as a reasonable design value for most
situations.  Although trickle irrigation E  values may be this high, it has
proved to be somewhat less for commercially installed and operated
enterprises.  This is .due to many factors including:  (a) contractor
inexperience with trickle irrigation; (b) cases where agriculturalists have
underdesigned and built their own systems; and (c) irrigator inexperience
with trickle system operation and maintenance.

IMPROVEMENT COSTS

     A general model describing irrigation system costs for various farming
conditions is not readily available.  It is not a difficult task to estimate
these costs if the conditions at the farm are known, but in the absence of
this information, irrigation improvement costs are usually given as
representative values.  The objective of this section is to provide typical
costs for several irrigation system improvements that are effective in
reducing salinity impacts.  The costs estimates will be presented in annual
                                     394

-------
        ORCHARD
           CROP
                     ff.v?.£CM^kr^v'*i^;.£"••/#
                     l"'-Yl' -rvvOf»HK'Xl.k.-^i*^
                                            EMITTER
       WETTED
       PROFILE
                                               ROOT  ZONE
       Figure C-10.   Illustration of the trickle irrigation concept.
costs per  hectare and will include capital and construction costs, operation
and maintenance costs, and energy costs.  The cost  estimates are current  as
of February  1979.

     Not all irrigating costs  are included in this  analysis because many  are
incident to  the farming enterprise and do not affect  the choice of system
improvements for salinity control.  A farmer is committed by his own choice
to irrigated agriculture and is, therefore obligated  in any situation to  the
contribution of a certain level of labor, energy, capital, and water
resources.   Seed, fertilizer,  pesticides, taxes,  and  insurance are costs
only minimally affected by system improvements and  are not considered.
Actually,  many of these costs  would be compensated  for by higher yields and
greater land value.  It is obvious, then, that the  costs on which a specific
on-farm salinity control measure is compared with others are the differences
between the  total annual cost  of the improved system  minus the pre-
implementation total annual costs and minus increases in net farm profit
incurred as  the result of better irrigation practices.
                                   395

-------
     The pre-implementation or "base" conditions in the salinity affected
regions of the United States are most likely to be the furrow irrigated
field having slopes less than 1.5 percent and relatively low intake soils.
The water supply is delivered to the field in unlined ditches from rivers
diversions or at the farm from wells.  Water supply costs are already being
paid and therefore would not affect the choice of the on-farm improvement.
The exception to this would be the case of the water supply being a well.
If the system improvement was to be a sprinkler or trickle system, the pumping
plant and energy costs must be included in the evaluation because these
facilities would require substantial modification.

     The base condition one might expect would also be relatively well
graded, thereby eliminating leveling costs for most improved systems except
for possibly border and basin irrigation.  Water distribution on the farm
itself would typically be with unlined ditches and application to the fields
would be accomplished with cuts in the ditch bank, siphon tubes, spiles, or
small check structures.  New systems would replace all of these facilities
except siphon tubes as well as added new structures for flow measurement
and regulation.

     In order to present representative estimates of irrigation system
improvement costs, actual designs were prepared for fields ranging in size
from 4 to 90 hectares.  Quantity take-offs for materials, construction,
operation-maintenance (including labor), and energy were priced and used
to estimate annual costs.  Typical values of crop water demands and growing
seasons were used to establish system capacities and operating hours.  For
capital cost items, an interest rate of 7.5 percent and an expected system
life of 20 years was used to annualize the cost estimates.  No salvage value
was given to any irrigation system component.  Replacement costs for short-
lived components were included in the operation and maintenance cost
estimates.

     All irrigation systems were analyzed under the same soil conditions
(loamy soil with a moderate infiltration rate) and field slope (0.1 percent
cross slope and 0.5 percent average slope in the direction of irrigation).
All the systems were analyzed obtaining water from two sources:  surface
and groundwater supplies.  A surface source is a gravity canal or a small
lake or pond.  No annual cost of water was assessed for surface water.
Groundwater supplies were standardized as pumping electrically from 100
feet of depth, the well cased and screened with a column pipe to 150 feet.
Pumps over 10 HP were all turbines.  It was also assumed that one well
was always capable of providing the water required.  Pumps were located
at the highest corner in the field, except for center pivots where the pump
was located at the pivot.

     The results indicate some economies of scale in the cost estimates,
but given the wider variety of conditions actually existing in the field,
it is probably only justified to give average figures.  Consequently, the
costs for the various field sizes were averaged.  The results, presented
in Table 1, includes capital, 0 & M, and energy costs for several of the
most common irrigation system improvements.
                                     396

-------
TABLE C-l.  TOTAL ANNUAL COSTS OF SELECTED IRRIGATION SYSTEMS AND IMPROVEMENTS
            FOR SELECTED ALTERNATIVES
 Description  of  System or  Improvement
Annual Costs, $/ha
 Concrete  Ditch Linings

 Gated-pipe  Replacement  of  Head  Ditches  and
      Pipes  Connecting  Systems

 Automated Cutback System

 Gated-pipe  Tailwater Recovery and  Reuse
      System

 Big  Gun Traveler  Sprinkler System

 Solid-set Sprinkler System with Above
      Ground Aluminum Piping

 Solid-set Sprinkler System with Below
      Ground PVC Piping

 Hand Move Sprinkler System with
      Aluminum Piping

 Sideroll  Sprinkler System

 Center  Pivot  Sprinkler  System

 Trickle Irrigation Systems for  Orchards
      and  Widely Spaced  Row Crops
40


35

100


147

480 to 644-/
667 to 800^
947 to 1065^
327 to
218 to 295-^
146 to
458
              1
— Range  of  costs  for  surface water  supplies  (small  values)  and  groundwater
   supplies  (large values)
 2/
— For  center  pivot  systems  covering more  than  32 ha.
      One  can  see  that  annual  costs  cover  a wide  range  in the  irrigation
 industry.   Simple head ditch  linings  are  more  than  an  order of  magnitude,
 cheaper than  most of the pressurized  conversions.   However, the improvement
 in application  efficiency  is  also a factor in  the cost-effectiveness  of the
 measure as  a  salinity  control alternative.  Head ditch linings  would
 improve the irrigation efficiency by  the  amount  of  seepage prevented  whereas
 the remaining improvements also  create  increases due to better  water  control
 and uniformity.
                                     397

-------
DEVELOPING ON-FARM COST-EFFECTIVENESS FUNCTIONS

     The development of cost-effectiveness functions for the on-farm segment
of a salinity control program follows the same two step procedure outlined
earlier for the canal lining alternatives.  A detailed procedure is given by
Walker et al. (1979).  The application efficiency of the existing system and
that expected from the improvement are determined from the evaluation of the
irrigated system using previously described methodologies.  The net increase
in application efficiency is utilized along with the average annual depth of
applied water to determine the changes in deep percolation.  This value is
then used to define the annual salt reduction achieved by the increased
application efficiency.  Thus, the elements of the cost-effectiveness
function are defined:

                              Cf = (Cf/ASE) Sf                          (25)
where C  = annual cost of reducing salinity by S,., Mgm/yr; C^ = annual per
hectare cost of the irrigation system improvement; and ASp = reduction in
salt loading due to improved application efficiencies, Mgm/ha/yr.
                                    398

-------
                                  SECTION 5

                                DESALINATION
INTRODUCTION

     The traditional scope of saline water conversion programs has been to
reclaim otherwise unsuitable waters for specific needs.  However, this scope
has dealt almost exclusively with utilization of product water directly
rather than returning it to receiving waters to improve water quality.  With
mounting concerns for managing salinity on a regional or basin-wide scale,
the potential for applying desalination within the framework of an overall
salinity control strategy might be feasible.  For instance, the use of
desalting systems to resolve critical salinity problems is planned as part
of the Colorado River International Salinity Control Project agreement
between the United States and the Republic of Mexico (U.S. Department of the
Interior, 1973).

     For regional salinity control evaluations, desalting costs are expressed
in dollars per unit volume of salt extracted in the brine discharge rather
than the conventional index of costs per unit volume of reclaimed product
water.  In this manner the respective feasibility of desalination and other
alternatives for salinity management can be systematically compared during
the processes of developing strategies for actual implementation of salinity
controls.  A desalting system as used herein consists of facilities for
supplying raw water (water to be desalted) to the plant, the desalting plant
itself, and facilities to convey and dispose of the brine (Figure C-11) .
Transportation of product water beyond the confines of this system is not
considered.

     The cost simulations described in this section are based on two major
references.  Prehn  et al. (1970) summarized a desalting cost calculation
procedure for several desalting methods and related facilities.  This work
was subsequently improved and expanded by the Bureau of Reclamation (U.S.
Department of the Interior, 1972).  These costing procedures were
mathematically simulated and then programmed for a digital computer by
Walker (1978a).

     For most agriculturally oriented uses of desalination, electro-dialysis
and reverse osmosis are likely to be the major processes.  Since reverse
osmosis (RO) can treat a wider range of brackish waters, it is used in this
report (Figure C-12).
                                     399

-------
                                           0)

                                          .£  £
                                           1_  
                                          00 -D
                                         0)
                                         O


                                         I    -
                                         o>     o
                                         m
                                                        o


                                                        t»
                                                        3

                                                        1
                                                        ex
          0»
              (A
•—  
 a) "S
^CL
•-   «

I  I
—   (A
O  A
«>   3
«D  (/)
Q
                                                                    £  §
                                T3
                                 0)
                                 4)
                                            S



                                            1
                                            O
                                            O
                                                      d>
                                                          o
                                                    a>
                                                    o
                                                    c
                                                    o
                                                    >«

                                                    I
                                                    o
                                                    o
                                                                                           OJ
                                                                                           4J
                                                                                           CO
                                                                                                    o
                                                                                                   •H
                                                                                                   4-1
                                                                                                    cfl
                                                                                                    c
                                                                                                   •H
                                                                                                   iH
                                                                                                    n)
                                                                                                    CO
                                                                                                    C1J
                                                                                                    o
                                                                                                   •H
                                                                                                    P.
                                                                                           cfl


                                                                                           O
                                                                                                    60
                                                                                                    O
                                                                                                    •r-t
                                                                                           6
                                                                                           CU

                                                                                           o
                                                                                          CO
                                                                                  CD
                                                                                  M
                                            400

-------
 Feedwater
Pretreatment
               Reverse  Osmosis Pressure Cells
                             T
  Brine
'Discharge
                                                 Brine
                                                           Product Water
        Figure  C-12.   Flow diagram of typical RO desalting system.
     The reverse osmosis process uses hydraulic pressure to separate water
and salts via a semi-permeable membrane.  Energy consumption is proportional
to the quantity of salts to be removed.  Consequently, the most economic
application of RO plants should be to soft, warm feedwaters having 1000 to
10,000 mg/£ IDS and producing water of 100-500 mg/£.

     Two vessels of water having different salt concentrations and separated
by a semi-permeable membrane (permeable to water but exclusive of salts)
will produce a flow of relatively pure water from the dilute solution to
the more concentrated until either they are both the same concentration or
a buildup of pressure in the latter stops the process.  This phenomenon is
called osmosis.  It should also be noted that the more substantial the
initial concentration differential, the greater the pressure (osmotic
pressure) necessary to stop the flow.  If a pressure greater than the osmotic
pressure is applied to the solution of higher salinity, the flow of water
can be reversed.

     The variety of waters that might be desalted by any system includes
sea water, brackish and saline groundwater, and brackish surface waters
including irrigation return flows.  Many of these waters contain substances
deleterious to desalting plant operation.  Dissolved gases and organic
materials are usually controlled by deaeration and ultrafiltration.  However,
                                    401

-------
one of the principle problems in desalination systems is the potential for
scaling due to high concentrations of calcium.  As a general rule, waters
having calcium concentrations above 600 mg/£ should be pretreated (such as
the injection of a polyphosphate).  In this study, it is assumed that sodium
hexametaphosphate is utilized in all cases and that by so doing, the allowable
calcium concentration in the feedwater is 900 mg/£.  The total dissolved
solids concentration is also limited to 10,000 mg/£.

     In a typical desalting complex, a significant fraction of the annual
expenditures is associated with facilities to collect and convey feedwater,
and to convey and dispose of brines.  Feedwater facilities in this study are
limited in several respects.  First, the water supply to be desalted is
assumed to be either groundwater which can be collected with well fields or
surface flow capable of simple diversion.  (No costs have been attributed to
surface diversions.)  After collection, feedwater is conveyed by concrete
pipeline which may require pumping stations to satisfy both the transmission
and desalting plant head requirements.  Pipeline capacity for cost estimating
purposes is considered to be the capacity of the desalting complex.   The
length of the pipeline is assumed to be the weighted average connector
serving the individual wells or surface diversions.  The relatively high
cost incurred by these assumptions should insure a conservative estimate
of desalting costs.
DESALTING COST-EFFECTIVENESS

     While recognizing the site-specific nature of desalting technology
as applied to regional water quality management, some generalization of the
cost-effectiveness relationships can be made.  A detailed evaluation of input
parameters to a desalting cost analysis was presented by Walker (1978a).
All systems are most sensitive to the capacity of the desalting plant.  When
the costs are expressed in terms of salt removal, the unit costs stabilize
to nearly constant values when the capacities are greater than about 10,000
to 15,000 m /day.  Since desalting would be most competitive with the salinity
control alternatives when the unit costs are minimal, only systems with
capacities greater than 15,000 nP/day can be considered.  The result of
this consideration is that the desalting cost-effectiveness functions become
linear.

     For the purpose of formulating a desalting cost-effectiveness function
which can be evaluated along with other salinity control measures, the model
by Walker (1978a) was updated to April 1979 conditions.  Then the model
was used to generate cost-effectiveness curves for feedwater salinities
ranging from 1,000 to 11,000 mg/£.  These functions shown in Figure C-13 were
then condensed into the following mathematical form:


                               C", = 0.5 + M'S,                         (26)
                                d            1
         _                                                        3
in which C, = annual cost in $/million of removing S,, Mgm/yr x 10 ; and

                            M' = 1404 TDS^1'18                        (27)


                                     402

-------
           100
       200     300     400    500
    Annual  Salt  Removal,  Mg X I0~8
600
700
Figure C-13.
Annual  costs of salt removed by reverse osmosis desalination
process at various  feedwater concentrations.
                                403

-------
where IDS. = feedwater salinity, mg/£.  The input data used to generate
Equation Z6 should be fairly typical of those generally encountered in or
near agricultural areas, and therefore, the cost estimates should be
representat ive.
                                     404

-------
                                  SECTION 6

                 CASE STUDY:  GRAND VALLEY SALINITY CONTROL
INTRODUCTION

     Several irrigated areas in the Western U.S. would qualify as salinity
control case studies, but only the Grand Valley in western Colorado has
experiences the broad spectrum NFS planning procedure.  A large body of
technical literature has been generated by local research and demonstration
studies.  The purpose of reiterating some of it here is purely to
illustrate the NFS procedures.

     This manual is premised somewhat on the assumption that the primary
pollution problem in most areas would be identified before the NFS planning
techniques would be instituted.  Consequently, this case study will begin
by giving a brief summary of the problem identification phase of the Grand
Valley study.  References will be presented for the reader interested in
more detail concerning the studies conducted to delineate the basic elements
of the hydro-salinity system.  After describing the physical system, the
case study will concentrate on evaluation of alternative BMP's and the
optimization of the candidate measures to arrive at the best set of salinity
control practices for the Grand Valley.
IDENTIFICATION OF SALINITY PROBLEM

Colorado River Salinity Problem

     Salinity is the most serious water quality problem in the Colorado River
Basin (Figure C-14).  The impact, felt largely in the Lower Basin, is acute
because the Basin is approaching conditions of full development.  Increasing
salinity concentrations are threatening the utility of water resources in
the downstream areas of Arizona, California, and the Republic of Mexico.
Detriments to agricultural water users are primarily being encountered in
Imperial and Mexicali Valleys, while the primary urban detriments are
occurring in Los Angeles and San Diego.  The U.S. Environmental Protection
Agency (1971) reported that existing damages to Lower Basin users would
increase from $16 million annually in 1970 to $51 million annually by the
turn of the century if planned developments do not include appropriate
salinity control measures.  More recent estimates by the U.S. Bureau of
Reclamation show present damages at $53 million annually, with projections
to $124 million annually by the year 2000 (Bessler and Maletic, 1975).
Annual costs of salinity increases have been estimated to be from $10 to


                                      405

-------
/Coiora3o
 Basin
\J\7~upper    )
 ^x^~~lower    (
                  5UJiah__
            Lake  2,' Arizona
            MeadVl
           Figure C-14.  The Colorado River basin.
                             406

-------
$18 per megagram (Mgm) increase per year (Bressler and Maletic, 1975;
Valentine, 1974; Walker  et al., 1978).

     Approximately 9.7 million Mgm of salts are delivered each year in the
water supply serving the Lower Colorado River Basin.  These salts reach
Hoover Dam in about 1.59 x 10   cubic meters of water.  Studies have indi-
cated that roughly 37 percent of this salt load is contributed by irrigated
agriculture in the Upper Colorado River Basin.

     As the result of the mounting problem, a concerted effort to identify
the sources of salinity in the Colorado River Basin indicated that the
Grand Valley in western Colorado (Figure  C-15) was  one  of the  largest  per
hectare agricultural sources of salinity (about 18 percent of the total Upper
Basins' agriculturally related contribution) (U.S. Environmental Protection
Agency, 1971).  This area subsequently became the site for the first studies
to evaluate field-scale salinity control measures.

General Description of the Grand Valley
Location and Setting—
     The Grand Valley is located in west central Colorado near the western
edge of Mesa County.  Grand Junction, the largest city in Colorado west of
the Continental Divide, is the population center of the valley.  The valley
is a crescent shaped area which encompasses about 49,800 hectares of which
about 25,000 hectares are irrigated.  Urban and industrial expansion,
service roads and farmsteads, idle and abandoned lands account for most of
the land not farmed.  The valley was carved in the Mancos Shale formation
(a high salt bearing marine shale) by the Colorado River and its tributaries.
The Colorado River enters the valley from the east, is joined by the Gunnison
River at Grand Junction and then exits to the west.

     An economic survey by Leathers (1975), along with the land use inventory
by Walker and Skogerboe (1971), indicates that local farming is primarily
a small unit operation.  The population engaged in agricultural activities
is widely dispersed throughout the valley with most living on their property.
Leathers (1975) determined from sampling about 100 random selections that
most farm units were less than 40 hectares in size.  Of the total 7,870 fields
in the valley, 50 percent are less than 2 hectares in size [United States
Department of Agriculture—Soil Conservation Service (USDA-SCS), 1976].

     The Grand Valley recieves an average annual precipitation of only 211 mm
and practically all irrigation and potable water supplies come from the
nearby high mountain snowpacks.  The climate is marked by a wide seasonal
range, but sudden or severe weather changes are infrequent due to the high
mountains surrounding the valley.  The usual occurrence of precipitation
in the winter is snow and during the growing season is in the form of light
showers from thunderstorms.  Severe cloudbursts occur infrequently during
the late  summer months and hail storms are rare.  Although temperatures
have ranged to as high as 40.6 °C, the usual summer temperatures range to
the middle and low 30's in the daytime and around 15°C at night.  Relative


                                     407

-------
                                                    o
                                                    T3
                                                    cfl
                                                    h
                                                    O
                                                    iH
                                                    O
                                                    c
                                                    cd

                                                    O

                                                    01

                                                    H



                                                    LO

                                                    I
                                                    u
                                                    60
408

-------
humidity is usually low during the growing season, which is common in all
of the semi-arid Colorado River Basin.  The average annual relative
humidity is 58.8 percent.  The prevailing wind direction is east-southeast
with an average velocity of about 13.4 kilometers per hour.


Irrigation—
     Two main irrigation entities divert water from the Colorado River.
These are the Grand Valley Water Users Association and the Grand Valley
Irrigation Company.  A third irrigation company, the Redlands Power and
Water Company, diverts water from the Gunnison River.  A number of smaller
companies have carriage agreements with the two major canals for delivery
of Colorado River water.  The irrigation system of the valley currently
consists of about 287 kilometers of canals and ditches.

     Discharge capacities at the head of the irrigation canals range from
20 cm /sec in the Government Highline Canal to 0.8 m /sec in the Stub Ditch
and diminish along the length of each canal or ditch.  The lengths of the
respective canal systems are approximately 74 kilometers for the Government
Highline Canal, 35 kilometers for the Price, Stub, and Redlands Ditches,
125 kilometers for the Grand Valley system, and 53 kilometers for the
Orchard Mesa Canals.

     Laterals are small conveyance channels which deliver water from the
company canals to the farmer's fields.  These small channels usually carry
flows less than 0.14 nrvsec and range in size up to 1.2 or 1.5 meters of
wetted perimeter.  There are about 600 kilometers of laterals in the Grand
Valley as determined by the U.S. Bureau of Reclamation (USER) (1976).  Not
counting the Redlands area of the valley, there are 1,553 laterals in the
valley (USER, 1976).

     Single users served by an individual turnout are not uncommon, but most
laterals serve several irrigators who decide among themselves how the
lateral will be operated.  Most of the multiple-user laterals, which may
serve as many as 100 users, run continuously throughout the irrigation season
with the unused water being diverted into the drainage channels.  USER
(1976) figures show that the average irrigated acreage served by a lateral
is between 10 and 15 hectares.  The prevalent method of applying water to
croplands in the valley is furrow irrigation.


Geology—
     The geologic formations throughout the Colorado River Basin were laid
by an inland sea.  After the retreat of the sea, the land masses were
uplifted and subsequent erosion has created the mountains and plateaus as
they are today.  The upper formations are sandstones and marine shales which
are underlain by the marine Mancos Shale and the Mesa Verde formations
Mancos Shale is a very thick formation that lies between the underlying
Dakota sandstones and the overlying Mesa Verde formations.  The thickness
of the Mancos Shale usually varies from between 900 to 1,500 meters.  Due
to its great thickness and its ability to be easily eroded, this shale forms
most of the large valleys of western Colorado and eastern Utah.

                                     409

-------
     The Grand Valley was created by erosion cutting through the upper
formations creating the valley in the Mancos Shale.  The shale contains
lenses of salt which are easily dissolved as water moves over the shale
beds.  Water moving over and through the shale originates from overirrigation
and leakage from the canals and laterals.  Since the overlying soil is
derived from the shale, it is also high in salts and contributes significantly
to the salinity of return flows.

Defining the Hydro-Salinity Systems


The Impact of Irrigation on Salt Loading—
     The Grand Valley was identified as an important agricultural source
of salinity in the Colorado River Basin through a water and salt mass
balance.  lorns et al. (1965) evaluated stream gaging records for the 1914
to 1957 period, concluding that the net salt loading (salt pickup) from
irrigation ranged from about 450,000 to 800,000 Mgm annually.  Similar
analyses by Hyatt et al. (1970), Skogerboe and Walker (1972), and the U.S.
Geological Survey (1976) substantiated this range of salt loadings.  Most
studies indicate an average, long-term salt pickup rate of between 600,000
to 700,000 Mgm/year.  This mass of salts is added primarily by irrigation
return flows, thereby necessitating a delineation of the components and
practices.

     The irrigation return flow system in the valley may be divided according
to whether or not the return flows are surface or subsurface flows.
Surface flows occur as either field tailwater or canal, ditch, and lateral
spillage.  Subsurface flows include canal and ditch seepage, lateral seepage,
and deep percolation from on-farm applications (deep percolation in this
sense to include head ditch and tailwater ditch seepage).

     Canal and ditch seepage—Since the early 1950's, five major seepage
investigations of the major canals and ditches have been conducted (Skogerboe
and Walker, 1972, and Duke et al., 1976).  Although seepage rates have been
noted over a wide range, a representative rate is 0.061 m-Vm^/day.
In the Grand Valley, the total canal seepage is estimated to be approximately
3,700 ha-m per year.

     Lateral seepage—Tests reported by Skogerboe and Walker (1972) and Duke
et al.  (1976) indicate seepage losses from the small ditches comprising
the lateral systems probably average about 8 to 9 ha-m/km/year.  Thus, for
the 600 km of small laterals, the total seepage losses are approximately
15,300 ha-m annually.  Combined lateral and canal seepage is, therefore,
approximately 9,000 ha-m annually.

     On-farm deep percolation—Numerous studies in recent years have
attempted to quantify deep percolation from on-farm water use.  Skogerboe
et al. (1974a, 1974b) estimated these losses (including head ditch and
tailwater ditch seepage) to be about 0.30 ha-m/ha.  Duke et al. (1976)
estimated these losses, independent of on-farm ditch seepage, to be 0.15
ha-m/ha.  Kruse (1977) presents information showing on-farm ditch seepage
to be 0.12 ha-m/ha.  Combining the figures given by Duke et al.  (1976) with

                                     410

-------
Kruse (1977) gives a total on-farm subsurface loss of 0.27 ha-m/ha.  Total
on-farm seepage and deep percolation losses are therefore, about 7,500
ha-m per year.

     Canal spillage and field tailwater—The operational wastes and field
tailwater are difficult to define because, first, they do not generally
create problems associated with salinity degradation, and second, data
regarding these flows are sparse.  Skogerboe et al. (1974a) listed field
tailwater as 43 percent of field applications, whereas Duke et al. (1976)
reported estimates of field tailwater and canal spillage or administrative
wastes which were 18 percent and 35 percent, respectively.  Estimates of
spillage and tailwater by the Bureau of Reclamation were slightly smaller
than the first estimate.  Using the 43 percent figure for field tailwater
and the 18 percent figure for canal spillage yields about 37,000 ha-m per
year for field tailwater and spillage.

     Aggregating the data presented previously with inflow-outflow records
in the vicinity of Grand Valley gives a clear picture of how the irrigation
system relates to the overall hydrology (Figure C-16).  The flow diagram is
particularly helpful in visualizing the relative magnitude of the irrigation
return flows from the agricultural area in comparison with the flow in the
Colorado River.  A more detailed summary of an annual Grand Valley water
and salt flow is given in Table C-2.

     Adding up the individual contributions to the groundwater and dividing
the figure into the mass of salts contributed annually to the river gives
an estimated salt loading ratio of 3.82 by 10~3 Mgm/m^.  This figure assumes
an annual salt contribution, from the agricultural portion of the watershed,
of 630,000 Mgm/year.  Thus, the contributions from canal seepage, lateral
seepage, and on-farm deep percolation are respectively, 140,000 Mgm/yr.,
205,000 Mgm/yr., and 285,000 Mgm/yr.
DEVELOPMENT OF BMP'S

     The first steps in the salinity control planning framework after the
problem identification phase are to delineate the array of alternatives for
controlling salinity.  Those that appear acceptable can then be evaluated
and demonstrated under field conditions to identify the practicable
solutions.  These field data describing not only the effectiveness of the
solution but their associated costs as well are then combined in an
optimizational context to determine BMP's.

Identifying Potential and Appropriate Solutions

     The description of the hydro-salinity system in the valley pointed out
the likelihood of the salinity system being in a saturated condition.  As
a result, any salinity control alternative that would diminish the flow of
subsurface return flows would be effective.  In fact, the relationship
between groundwater control and salinity control is approximately linear.
Therefore, the potential solutions that might be applied would include most
if not all of the measures described earlier.  In many other areas, the

                                     411

-------
                                                              00
                                                              o
                                                              01
                                                             tH
                                                             ,H
                                                              CO
                                                              n)
                                                              S-4
                                                             o
                                                              ni
                                                              CO
                                                             •H
                                                             T3


                                                              g
                                                              CO

                                                              fi
                                                              G
                                                              CO
                                                              I
                                                             U
412

-------
TABLE C-3.  MEAN ANNUAL GRAND VALLEY WATER AND SALT BUDGETS (WATER UNITS
            IN HECTARE-METERS, SALT UNITS IN Mgm).
                                                   Water
               Salt
River Inflows
   Plateau Creek
   Colorado River near Cameo
   Gunnison River near Grand Junction
Evaporation and Phreatophyte
   Use (net)
Canal Diversions
   Lateral Diversions
   Seepage
   Operational Wastes
Lateral Diversions
   Seepage
   Field Tailwater
   Cropland Consumptive Use
   Cropland Precipitation
   Deep Percolation
Irrigation Return Flows
   (Subsurface)*
   Canal Seepage
   Lateral Seepage
   Deep Percolation
   Phreatophyte Withdrawals
      (net)
Irrigation Return Flows (surface)
   Operational Wastes
   Field Tailwater
River Outflows
   Colorado River at
     Colorado-Utah State Line
 13,800
297,650
178,000
489,450
  3,450

 52,900
  3,700
 12,400
 69,000
  5,300
 24,600
 18,600
 -3,100
  7,500
 52,900
  3,700
  5,300
  7,500

 -8,100
  8,100
 12,400
 24,600
 37,000
462,100
   62,600
1,352,600
1,371,700
2,786,900
  301,100
   21,100
   70,600
  392,800
   30,200
  140,000
  130,900
  301,100
  163,200
  232,200
  416,800
                                                                812,200
   70,600
  140,000
  210,600
3,445,900
      This segment of the budget includes all salt pickup and mass balance
for salts will not be achieved.

      Includes 30,000 Mgm of naturally contributed salts.
Note:  1 ha-m = 8.108 acre-ft; 1 megagram = 1.102 English short tons.
                                     413

-------
list would not be so extensive.  For instance, in areas where individual
irrigators pump groundwater, the measures which impact conveyance systems
could be omitted directly.

     If the problem associated with this case study demands remedy in the
near future, then many of the potential solutions of an institutional nature
are not appropriate because their implementation is currently restricted
by the existing legal system.  For example, influent standards, water markets,
taxation, etc., require basic changes in both the administrative framework
now in place as well as laws governing water resource use.  A salinity
control planner would likewise need to evaluate each of the other alterna-
tives and develop a list of appropriate solutions.  For the purpose of this
case study it will be assumed that the list of appropriate solutions includes
only the following technological measures:  the conveyance system can be
lined or piped, the irrigation system improved or modified, and the brackish
return flows collected and desalted.  It should be noted in passing to the
next step in the procedure, that the process of selecting appropriate
solutions from the array of potential solutions, has essentially arrived
at this simplifying assumption.  As a general rule, salinity control programs
will nearly always emphasize the "structural" components among the available
options.

Field Demonstration and Evaluation

     As a means of developing basic information concerning the multitude
of salinity control alternatives, the Grand Valley Salinity Control
Demonstration Project was set up in 1968.  The demonstration project area.
shown in Figure C-15, was located a few miles east of Grand Junction and
comprised about 1,300 irrigated hectares.  The area was initially selected
because it was representative of the Grand Valley and had five canals
traversing the area, thereby allowing greater participation by the irriga-
tion companies in the valley.  The demonstration and evaluation was divided
into three phases all of which involved detailed hydro-salinity investiga-
tion to define the effectiveness and costs of the salinity control practices.
Details of the studies are reported by Skogerboe and Walker (1972),
Skogerboe et al.  (1974a, 1974b) and Evans et al. (1978).

     The first phase of the demonstration project was an evaluation of
canal and lateral linings as salinity control measures.  More than 12
kilometers of canals and seven kilometers laterals were lined with slip-
form concrete and gunite.  Seepage measurements before and after the linings
along with a detailed hydro-salinity budgeting effort indicated that salt
loading had been reduced by approximately 4,300 Mgm/yr.  The total cost
was $420,000.  It became apparent during this first phase that the conveyance
system was not the major salinity contribution in the valley.  As a result,
a second phase was launched to investigate the benefits of irrigation
scheduling and drainage.

     The evaluation of irrigation scheduling, indicated that irrigation
scheduling would have a small effect on improving on-farm water management
because the existing irrigation systems did not allow irrigators to evaluate
how much water they were applying.  The scheduling could be expected,

                                     414

-------
however, to be more effective if farmer confidence could be gained and
certain structural improvements such as flow measurement devices were made.
The evaluation of drainage centered on the feasibility of field drainage
as a salinity control alternative.  Waters percolating below the crop root
zone can be intercepted by the field drainage system before the salts in
the lower subsoils and aquifers can be dissolved.  One field drainage
system was built as part of this project and was successful in intercepting
the flow as intended.  It was found, however, that the cost per Mgm of
control was approximately two orders of magnitude greater than any of the
other alternatives.

     The canal lining, irrigation scheduling, and drainage studies were
evaluated individually.  In order to extend these research results to the
formulation of comprehensive plans for salinity control on a valley-wide
scale, it was necessary to evaluate the interrelationships which existed
among these and other alternatives.  To do this, a two part effort was
initiated in 1973, as the third phase of the project.  The first part
involved a highly refined research investigation into the physical and
chemical processes of salt pickup from local soils.  The second part was
a large demonstration of the combined effects of several irrigation improve-
ments.

     The results of the first part have been published (Skogerboe  et  al.,
1979) and are only of interest here because they show the salt pickup rates
per unit of groundwater flow.

     The primary objective of the second part of this phase of the demonstra-
tion project was to show the advantages of implementing a "package" of
technological improvements within the lateral subsystems in reducing the
salt load entering the Colorado River.  As defined by this project, the
lateral subsystem began at the canal turnout and included all of the water
conveyance channels below the turnout and the farmlands served by the
lateral subsystem.  Although major emphasis was upon on-farm improvements,
considerable improvements in the water delivery conveyances and some improve-
ments in lowering high water tables (drainage) were also required.  This
phase of the project utilized each of the salinity control measures
previously evaluated with the additional use of various irrigation methods.

     In order to facilitate the continued participation by the irrigation
interests in the Grand Valley, the laterals were selected to cover as many
canals as possible.  The final selection had two laterals under the Highline
Canal, one under the Price Ditch, three under the Grand Valley Canal, and
three under the Mesa County Ditch.  The laterals were selected to capitalize
on previous work regarding canal and lateral lining, irrigation scheduling,
and drainage studies.

     The experimental design for the preevaluation was primarily aimed at
providing specific information for the 330.7 hectares undergoing treatment.
The field data collection program allowed the design of irrigation and
drainage facilities and provided sufficient data to allow predictions of
salinity benefits which resulted from each specific salinity control measure.
Although the postevaluation included the monitoring of water and salts

                                    415

-------
entering and leaving the demonstration area, the primary emphasis was the
on-site evaluation of each specific salinity control measure.

     The types of planned treatments included sprinkler irrigation, drip
irrigation, concrete lateral linings, concrete head ditches, gated pipe,
automated cut-back furrow irrigation, land shaping and clearing, flow
measurement, tailwater removal systems, buried PVC plastic irrigation
pipelines, agricultural field drainage, irrigation scheduling, and various
improved water management practices for each subsystem.  In some cases,
only increased labor spent on irrigation, in conjunction with one other
type of treatment, was incorporated into the experimental design.

     The total improvements completed in the project area since 1969 as
part of the demonstration of salinity control include:  12.2 km of large
canal linings, 16,432 meters of perforated field drainage tile, construction
of a wide variety of on-farm improvements, and an irrigation scheduling
program.  The costs of the various improvements totaled almost $750,000.
The total combined improvements remove almost 12,300 Mgm of salt per year.
The resulting "average" cost-effectiveness is $5.98 per Mgm assuming 7.5%
interest rate and a 20 year facility life.  The resulting benefit-cost ratio
based on downstream damages of $14.71 per Mgm/yr was 2.50 to 1.

Optimizing BMP's

     Optimization procedures can be used to determine the best overall
selection of projects based on some criterion such as minimum cost.  For
the purpose of this case study, four groupings of salinity control alterna-
tives will be considered:  (1) canal and ditch lining; (2) lateral linings;
(3) on-farm improvements; and (4) desalination of return flows.  The first
and third groupings will involve the use of optimization to identify the
best project selections.


Canal and Ditch Lining—
     The Grand Valley irrigation system involves fourteen canals and ditches
ranging in size and operating characteristics.  The first step in the
optimization of a canal lining strategy is to formulate the cost-
effectiveness function for each canal or ditch system.  Utilizing the
equations outlined by Walker et al.  (1979) the costs of lining various
fractions of each canal were determined.  These data and the resulting
salinity reductions were fit with the simple cost-effectiveness fraction:

                               c~c = As^Vr                        (28)

in which C  is the cost in dollars of lining sufficient meters of a
particular canal to achieve a salinity reduction of S,, Mgm/yr.  The
coefficients A and B, are regression constants, a summary of which for
each of the fourteen canals is given by Evans et al.  (1981).

     The next step was to determine  the optimal canal  lining strategy given
the alternatives represented by the  fourteen canal system cost-effectiveness


                                     416

-------
functions.  The results of the optimization process are shown in Figure  C-
17.  These data can also be fitted with a function like Eq. 28 to yield
a second level or general canal lining cost-effectiveness function as
indicated in the figure.

     In order to illustrate the use of Figure  C-17,  consider the consequences
of a decision made as the result of subsequent or higher level optimization
to reduce seepage related salinity in the Grand Valley by 50%.  Figure C-17
indicates that the total controllable salinity achieved by linings is
approximately 110,000 Mg/yr.  Fifty percent of this salt reduction is
therefore 55,000 Mg/yr and from Figure C-17 can be achieved at a minimum cost
of $26 million or about $2.5 million annually.

Lateral Linings—
     The Grand Valley lateral system generally runs in the north-south
direction.  The average land slope in this direction is a little more than
1% which is sufficient gradient to handle most flows in the smaller sizes
of slip-form concrete ditch or pipelines with diameters from 30 to 38 mm.
Thus, it can be expected that lateral lining cost-effectiveness is
essentially a linear function and basically the same for each lateral
subsystem.  Utilizing an average discharge of 0.1 m-^/sec, the per meter
lateral lining cost was found to be $26.  Thus, the total cost of lining
the 600,000 meters of lateral would be about $15.6 million.

     The salinity contribution from lateral seepage was discussed previously
as 205,000 Mgm/yr.  If the lateral linings can be assumed to be effective
for 20 years and the project interest rate is 7.5%, then the cost-
effectiveness of lateral linings on an annual cost basis is $7.46/Mgm.

On-Farm Improvements—
     The various on-farm salinity control measures which are adaptable to
the Grand Valley can be grouped into three general classes:

     (1)  Lining farm ditches to prevent seepage;

     (2)  Improve water application uniformity and efficiency by modifying
          existing systems or converting to more effective irrigation
          methods; and

     (3)  Irrigation scheduling and irrigator training.

     The existing application efficiencies in the Grand Valley can be
evaluated from Table C-2.  Walker et al. (1979) shows that 52,900 ha-m of
water are delivered annaully to the head of the lateral system, of which,
47,600 ha-m are diverted at the farm turnout.  The average application
efficiency as defined earlier was about 67%.  As noted previously, this
part of the agricultural system contributes an estimated 285,000 Mg of
salt per year to the Colorado River.   The cost-effectiveness of various
measures to reduce this salt loading and their optimal integration is
discussed below.
                                     417

-------
jo
to
  in
                             uj  isoo jonuuv   10401
                                 to      cvj      —
           o
           CO
   O
   IO
                        O
                        IO
O
CO
                                            O  w
                                            0>  E
                                               o
                                               o»

                                            O  S
                                            GO  «
                                               XJ
                                               c
                                               o

                                            O  S
                                            CO  O
                                            0-E
                                            •O  c
                                               O
                                            ^  "°
                                            ^  «
                                               or

                                               x>
                                            O  o
                                            ro  o
                                                                          o
                                                                         U-l
                                                                          a
                                                                          o
                                                                          o
                                                                          a
                                                                          3
                                                                         M-l
                                                                         Q)
                                                                         C
                                                                         a)

                                                                         •H
                                                                         4J
                                                                         O
                                                                         Q)
                                                                         M-l
                                                                         m
                                                                         CD
                                                                         I
                                                                         4J  •
                                                                         cn  o
                                                                         O T3
                                                                         o  nj
                                                                            M
                                                                         60  O
                                                                         C iH
                                                                         •H  O
                                                                         a o
                                                                         •H
                                                                         r-l  QJ
                                                                         n) M
                                                                         C iH
                                                                         n3  R)
                                                                         o >
                                                                         a)  c
                                                                         N  nj
                                                                         •H  f-t
                                                                         e o
                                                                         •H
                                                                         •u  ai
                                                                         ex ^
                                                                         O 4J
                                                                          I
                                                                         u
                                                                         00
                                                                         •H
sjo||OQ  jo suojiijw  u;  isoo   Bumn   JDUDQ  10401
                                 418

-------
     Lining farm ditches—Many farmers have lined their farm conveyance
networks to reduce seepage, maintenance and labor.  The most common lining
methods include a concrete slip form lining, a buried plastic membrane,
compacted earth, or converting the ditches to plastic or aluminum pipelines.
Each of these alternatives are relatively inexpensive, and have become
accepted methods for improving on-farm water management.

     In the Grand Valley, head ditch requirements are generally less than
the capacity of the smallest standard ditch available through local
contractors (12 inch bottom width, 1:1 side slope, slip form concrete).
Assuming an average head ditch capactiy of 0.05 m^/sec, the estimated unit
cost of head ditch linings is $7.50/m.  There are approximately 1.3 million
meters of head ditches in the Grand Valley contributing an estimated 95,000
Mgm of salt to the river annually.  If the head ditch linings are assumed
to be 90 percent effective in controlling seepage over a 20 year period
and the interest rate is 7.5 percent, the cost-effectiveness of head ditch
linings is $11 Mgm and the limit of the measures effectiveness is 86,000
Mg/yr.

     It is worth noting that head ditch linings are incorporated either
directly or indirectly into nearly every other on-farm salinity control
measures.  If the surface irrigation system is automated, the head ditch
is lined as part of the automation.  In addition, a conversion to sprinkler
or trickle irrigation would essentially eliminate head ditch seepage by
replacing the conveyance network with pipe.

     Automation of existing systems—There are two "operational" wastes which
occur under furrow irrigation.  The first, is the water percolating below
the root zone and the second, is the runoff from the lower end of the field.
Efforts to reduce each one is competitive; i.e., measures to minimize
runoff will tend to increase deep percolation and vice versa.  Since
salinity is directly associated with deep percolation, local improvement
programs will cause high runoff if not coupled with some system modification.
In the Grand Valley, furrow irrigation uniformity and consequently efficiency
can be substantially improved by three alternatives.  First, irrigation
scheduling should always be based on sampling at the lower end of the field
so that the minimal intake opportunity (or irrigation set) can be determined.
The flow in the furrow should be adjusted so that the time required for the
flow to advance to the end of the field is about 25 percent of the minimal
intake opportunity time.  If these practices were implemented and strictly
adhered to, local deep percolation volumes would be cut by more than 50
percent.

     The second method for improving furrow irrigation uniformities and
efficiencies is called cutback furrow irrigation.  Under this method, the
head ditch is sufficiently automated so that a large "wetting" furrow
stream is introduced to advance the flow down the furrow and then the flow
is "cutback" to a "soaking" flow rate to finish the irrigation.  Cutback
irrigation has one notable advantage over simply controlling the existing
system—the field tailwater is greatly reduced.  A system built in the
Grand Valley and described by Evans (1977) achieved an application
                                    419

-------
efficiency of 75%.  The salt load reduction achieved by this system was
86,000 Mgm/yr due to seepage control in the field ditch and 46,000 Mgm/yr
due to an 8% increase in efficiency.  Using these figures as a guideline
for efficiencies, and an annual cost of cutback furrow irrigation of
$100/ha, the cost effectiveness was $18.94 Mgm/yr with an effectiveness
limit of 132,000 Mgm/yr.

     The final alternative for improving furrow irrigation is to utilize
large furrow streams, collecting the excessive tailwater in a small
reservoir, and then pumping this water back to the head of the field.  This
technology has also been demonstrated on one field in the Grand Valley.
Because of the low value of water in Grand Valley, there are some
difficulties in gaining farmer acceptance for this tailwater reuse system.
However, this technology represents the most efficient furrow irrigation
system when operated in terms of a known soil moisture deficit.  A
reasonable expectation of reuse system application efficiencies is 80%.
Salinity control should be 86,000 Mgm/yr due to seepage control and 74,800
Mgm/yr due to a 13% increase in application efficiency.  Using an annual
cost for reuse systems of $147/ha, the cost-effectiveness of reuse systems
is expressed as $22.85 Mgm/yr and limited in effectiveness to 160,800 Mgm/yr.

     Sprinkler irrigation—A conversion from surface methods of irrigation
to sprinkle irrigation systems by farmers in the Grand Valley would be
highly beneficial in terms of efficient water use.  Sprinkle irrigation
systems, properly designed, installed and operated, have advantages both
in terms of water quantity and quality.  More uniform water application
is generally possible on local types of soils, thereby minimizing deep
percolation losses, and, of course, such a system should result in no
tailwater runoff.  The division of lands in the Valley are such that the
most effective sprinkler system would be a sideroll or other portable
system.

     Sprinkler irrigation systems should be expected to be about 85%
efficient when designed properly and operated in conjunction with an
irrigation scheduling service.  Consequently, the salinity control
potential is comparable to well operated reuse systems described above.
The annual costs of sprinkler irrigation systems are higher than those for
furrow systems due to increased energy and maintenance costs.  An annual
figure of $250/ha is representative for the Grand Valley, indicating a
cost-effectiveness of $32.89 Mgm/yr.  The upper limit of salinity control
for the sprinkle system is 168,000 Mgm/yr.

     Trickle irrigation—Trickle irrigation is an irrigation method and
would appear to have potential for orchard crops in the Grand Valley area.
This method of irrigation has gained attention during recent years because
of the potential for increasing yields, while decreasing water require-
ments and labor input.

     For irrigating widely spaced crops, the cost of a correctly designed
trickle irrigation system is relatively low in comparison to that for other
solid-set or permanent irrigation systems.  In orchards, the unit salinity
control cost of a trickle irrigation system is comparable to that for a

                                    420

-------
solid-set or permanent sprinkle system having the same level of automation.
In addition, where clogging is not a problem and emitter line maintenance
is minimal, operation and maintenance costs of the trickle irrigation system
are usually quite low.  However, in plantings of row crops or vines, where
the average distance between emitter lines must be less than 3 meters, the
cost of trickle irrigation is relatively high.  When a trickle irrigation
system is installed, there is usually a substantial need for technical
assistance to insure that the plants are not being stressed and that a
nutrient balance is being maintained.

     The application efficiency for trickle irrigation systems, well
designed and operated in conjunction with an irrigation scheduling program,
can be 90-95%.  The higher figure represents about a 9.9 Mgm/ha/yr reduction
in salinity.  Using an annual cost of $458/ha, the salinity cost-effectiveness
is $46.32/Mgm/yr.  The upper limit on trickle irrigation effectiveness,
assuming it is applicable only to the orchard acreage in the valley is
28,500 Mg.

     Optimizing the on-farm strategy—The cost-effectiveness of each on-
farm salinity control practice along with its limits leads next to the
evaluation of the optimal on-farm strategy.  The cost-effectiveness relations
detailed above are all linear as are the constraints which allows direct
use of the linear programming algorithm.  However, a subtle problem must be
handled.  The on-farm salinity control measures are not mutually exclusive
as was the case for the canal linings.  Thus, one other constraint must
be imposed to insure that some measures are not implemented on the same
fields.  This is accomplished by dividing the total salt loading allocated
to each measure by the per hectare effectiveness and then constraining the
sum to be less than the total irrigated acreage.

     The results of the Grand Valley optimization of on-farm salinity
control measures are shown in Figure C-18.  The figure shows the least cost
on-farm cost-effectiveness curve fitted to data points corresponding to
the individual solutions over the range of potential on-farm salinity
control.  For an example, suppose it was decided to reduce the farm related
salinity contribution by 100,000 Mgm/yr.  Figure  C-18 indicates that  this
can be accomplished by an annual investment for improvements of $1.3 million.

Desalting—
     In the previous section, the cost-effectiveness of the desalting
alternative was expressed as a linear function of feedwater salinity.   If
the average feedwater salinity is assumed to be 5000 Mg/1 for the Grand
Valley, thereby allowing some mixing of surface and subsurface flows,  the
cost-effectiveness function for desalination alternative becomes:

                          C~d = 5.0 x 105 + 60.62 S                     (29)
where C  = annual cost of reducing S.  Mgm/yr.
                                     421

-------
    8r
  OT
  o
  o
  c
  O
  o
_  Annual Cost = A*exp (B*Salt Load.Mg)

               A= 2.184628711 *I09

               B  1.786064228*IO~5

               *\ = Interest Rate of 7.5%,
                  Life = 20 yrs
  •? 4
  o
  CO
  I3
  c
  o

  I2
      0
            50           100           150

             Salt Load  Removal, MgXiO"3
200
Figure C-18.  Optimal on-farm salinity control cost-effectiveness curve.
                             422

-------
AGGREGATING INDIVIDUAL BMP 's

     Once the most cost-effective strategies have been developed for the
major salinity options for an area like the Grand Valley, the subsequent
question is what is the most cost-effective valley-wide program.  Obviously,
this is an optimization of the optimal functions for canal and lateral
lining, on-farm irrigation system improvement, and desalting of surface
and subsurface return flows.  The information to organize the optimization
procedure is already available at this stage and the procedure can be under-
taken with a standard operation research procedure.

     The results of this final step are shown in Figure C-19.   For  instance,
consider the consequences of a decision to reduce Grand Valley salinity
by 400,000 Mgm/yr.  Figure C-19  shows  the  annual  cost  of level  of salinity
reduction in Grand Valley to be $8.9 million/yr.  Directly under the point
at a cost of $6.0 million/yr is the boundary between the canal linings
and the on-farm improvements.  In other words, $2.19 million/yr is invested
in canal linings under the optimal policy.

     An examination of Figure  C-19  shows  that lateral linings  are  the first
salinity control measure to be implemented and are a part of all other
levels of control.  As can be seen, the lateral lining cost for total
reduction greater than 205,000 Mgm/yr is $1.5 million/yr.  Consequently,
it is now possible to determine from the graphs that the annual investment
in on-farm improvements at the 400,000 Mgm/yr control level is $6.0
million minus $1.5 million or $4.5 million/yr.
SUMMARY

     This case study on salinity control has been presented to illustrate
the procedure for beginning with a salinity problem and finishing with an
array of optimal practices for alleviating the problem.  The Grand Valley
in western Colorado is one of the most publicized salt problem areas because
of its relationship to the problem in the Colorado River Basin.

     The first step illustrated was the identification of specific causes
of salt loading from an agricultural area.  Field data collection and
investigative studies are necessary programs in nearly any irrigated region
because so little hydro-salinity data are reported.  Once the various
irrigation system components are identified as to their salinity impact,
the potential solutions must be evaluated and demonstrated.  Since not all
will be found workable or acceptable to local irrigators, the list of
potential measures will be generally reduced when implementation efforts
are planned.  Computer simulation along with experience in establishing
the cost of each applicable salinity control allows the planner to
formulate cost-effectiveness functions which can be used to compose
alternatives to define the best strategy.  A system of successive aggregation
is demonstrated for taking individual project design alternatives and
                                    423

-------
                                     0S9
                                     009
                                     0SS
                                               CO
                                                I
                                                E
                                                01
                                               21
                                                L
                                                0
                                               •H
                                               +>
                                                0
                                                D
                                               -o
                                                9
                                               (X.

                                               "0
                                                0
                                                0
                                                0
                                               to
 03
 cn
 a)
 fi
                                                           •H
                                                           4-)
                                                           O
                                                           OJ
 0)
 I
J-l
 cn
 o
 o
 C
 O
 O
+J
•H
C
•H
iH
rt
03   •

>i  60
OJ  0)
rH  4-J
^H  cfl
cti  >-i
>  4J
    CD
13
C T3
n)  C
M  cti
CD

H  §
cfl -H
e  jj
•H  n)
4-1 rH
ex  
-------
organizing them into large scale plans for salinity control using operations
research techniques to insure the resulting policy is one of least cost.

     Those who deal with water and air quality improvement must be warned
that the best solutions are rarely obvious.  The array of alternatives
should, therefore, be kept broad and evaluated regardless of how inefficient
one might appear.  A program of periodic reassessment is generally necessary
to make the most effective communication links with each other, the research
community, consulting organizations, administrative and legislative
personnel, and the irrigation interests.
                                    425

-------
                                REFERENCES

Bessler, M. B. and J. T. Maletic.   1975.   Salinity Control and the Federal
     Water Quality Act.  Journal of the Hydraulics Division, ASAE.  Vol.
     101, No. HY5.  May.  pp. 581-594.

Bos, M. G. and J. Nugteren.   1974.   On Irrigation Efficiencies.   Publication
     19 of the International Institute for Land Reclamation and
     Improvement/1LR1.   P.O. Box 45, Wageningen, The Netherlands.  89 pp.

Griddle, W. D.,  S. Davis, C. H. Pair, and D. G. Shockley.   1956.   Methods
     for Evaluating Irrigation Systems.  Soil Conservation Service, United
     States Department  of Agriculture, USDA Handbook No.  82.  24  pp.

Duke, H. R., E.  G. Kruse, S. R. Olsen, D. F. Champion,  and D. C.  Kincaid.
     1976.  Irrigation  Return Flow Quality as Affected by Irrigation Water
     Management  in the  Grand Valley of Colorado.  Agricultural Research
     Service, U.S. Department of Agriculture, Fort Collins, Colorado.
     October.

Dutt, S. R., M.  S. Shaffer and W.  S. Moore.  1972.  Computer Simulation
     Model of Dynamic Bio-physiochemical Processes in Soils.  Technical
     Bulletin 196, Agricultural Experiment Station, University of Arizona,
     Tucson, Arizona.  October.  101 pp.

Evans, R. G., W. R. Walker,  G. V.  Skogerboe, and S. W.  Smith.  1978.
     Evaluation  of Irrigation Methods for Salinity Control in Grand Valley.
     EPA-600/2 78/160.   Robert S.  Kerr Environmental Research Laboratory,
     U.S. Environmental Protection Agency, Ada, Oklahoma.   172 p.

Evans, R. G., W. R. Walker,  and G.  V. Skoverboe.  1981.  Optimizing
     Salinity Control Strategies for the Upper Colorado River Basin.
     Report AER  80-81 RGE-WRW-GVS1.  Agricultural and Chemical Engineering,
     Colorado State University, Fort Collins, Colorado.  January.  295 p.

Fok, Y. S. and A. A. Bishop.  1965.  Analysis of Water Advance in Surface
     Irrigation.  Journal of Irrigation and Drainage Division, ASCE, Vol.
     91, No. IR1, Proc. Paper 4251.  March,  pp. 99-116.

Gerards, J. L. M. H.  1978.   Predicting and Improving Furrow Irrigation
     Efficiency.  Unpublished Ph.D. Dissertation, Colorado State
     University, Fort Collins, Colorado.   135 p.
                                    426

-------
Hyatt, M. L., J. P. Riley, M. L. McKee and E.  K. Israelsen.  1970.    Computer
     Simulation of the Hydrologic Salinity Flow System Within the Upper
     Colorado River Basin.  Utah Water Research Laboratory, Report PRWG54-1,
     Utah State University, Logan, Utah.  July.

lorns, W. V., C. H. Hembree and G. L. Oakland.  1965.  Water Resources of
     The Upper Colorado River Basin.  Geological Survey Professional Paper
     441.  U.S. Government Printing Office, Washington, D.C.

Kostiakov, A. N.  1932.  On the Dynamics of the Coefficient of Water
     Percolation in Soils and on the Necessity for Studying it From a
     Dynamic Point of View for Purposes of Amelioration.  Trans. 6th Com.
     Int. Soc. Soil Sci., Part A.  pp. 17-21.

Kruse, E. G.  1977.  Minutes of the Grand Valley Salinity Coordinating
     Committee, Grand Junction, Colorado.  February.

Leathers, K. L.  1975.  The Economics of Managing Saline Irrigation Return
     Flows in the Upper Colorado River Basin:   A Case Study of Grand Valley,
     Colorado.  Ph.D. Dissertation, Department of Economics, Colorado State
     University, Fort Collins, Colorado.

Liang, W. S. and E. V. Richardson.  1971.  Dye Dilution Method of Discharge
     Measurement.  Water Management Technical  Report No. 3.  (CER 70-71WSL-
     EVR47), Engineering Research Center, Colorado State University, Fort
     Collins, Colorado.  29 p.

Prehn, W. L., L. L. McGaugh, C. Wong, J. J. Strobel, and E. F. Miller. 1970.
     Desalting Cost Calculating Procedures.  Research and Development
     Progress Report No. 555.  Office of Saline Water, U.S. Department of
     The Interior, Washington, D.C.  May.

Robinson, A. R. and C. Rohwer.  1959.  Measuring Seepage from Irrigation
     Channels.  U.S. Department of Agriculture, Agricultural Research
     Service.  Technical Bulletin No. 1203.  Washington, D.C.  September.
     82 p.

Skogerboe, G. V., D. M. McWhorter and J. E. Ayars.  1979.  Irrigation
     Practices and Return Flow Salinity.  Report EPA 600/2-79-148.   U.S.
     Environmental Protection Agency, Ada, Oklahoma.  August.

Skogerboe, G. V.  and W. R. Walker.  1972.  Evaluation of Canal Lining for
     Salinity Control in Grand Valley.  Report EPA-R2-72-047, Environmental
     Protection Agency, Washington, D.C.  October.

Skogerboe, G. V., W. R. Walker, J. H. Taylor,  and R. S. Bennett.  1974a.
     Evaluation of Irrigation Scheduling for Salinity Control in Grand
     Valley.  Report EPA-660/2-74-052, Environmental Protection Agency,
     Washington, D.C.  June.
                                    427

-------
Skogerboe, G. V., W.  R.  Walker,  R.  S.  Bennett,  J E.  Ayers,  and J.  H.  Taylor.
     1974b.  Evaluation of Drainage for Salinity Control in Grand  Valley.
     Report EPA-660/2-74-084,  Environmental Protection Agency, Washington,
     D.C.  August.

Skogerboe, G. V., W.  R.  Walker,  and R. G.  Evans.  1979.   Environmental
     Planning Manual for Salinity Management in Irrigated Agriculture.
     Report EPA-600/2-79-062.   Office  of Research and Development, U.S.
     Environmental Protection Agency,  Robert S. Kerr Environmental Research
     Laboratory, Ada, Oklahoma.   March.  237 p.

Shaffer, M. S., R. W. Ribbens, and C.  W. Huntley.  1977.  Prediction of
     Mineral Quality of Irrigation Return Flow, Volume V.  Detailed Return
     Flow Salinity and Nutrient  Simulation Model.  EPA-600/2-77-179e.
     Robert S. Kerr Environmental Research Laboratory, Office of Research
     and Development, U.S. Environmental Protection Agency, Ada, Oklahoma.
     August.  228 p.

Strelkoff, T.  1977.   Algebraic  Computation of  Flow in Border Irrigation.
     J. Irr. and Drain.  Div.,  ASCE, Vol. 103, No. IR3, September.

U.S. Department of Agriculture,  Soil Conservation Service.   1976.   Inventory
     of Conservation Plan Needs  for the Grand Valley.  Open File Data,
     Grand Junction,  Colorado.

U.S. Bureau of Reclamation.  1963.   Linings for Irrigation Canals.  U.S.
     Government Printing Office, Washington, D.C.  149 p.

U.S. Bureau of Reclamation.  1968.   Measuring Seepage in Irrigation Canals
     by the Ponding Method.  Irrigation O&M Bulletin No. 65, Denver,
     Colorado.  September.  21 p.

U.S. Bureau of Reclamation.  1976.   Initial Cost Estimates for Grand Valley
     Canal and Lateral Linings.   Personal Communication with USER  Personnel
     in Grand Junction, Colorado.

U.S. Bureau of Reclamation and Office of Saline Water.  1973.  Colorado
     River International Salinity Control Project, Executive Summary.
     September.

U.S. Environmental Protection Agency.   1971.  The Mineral Quality  Problem
     in the Colorado River Basin.  Summary Report and Appendices A, B, C,
     and D.  Region 8, Denver, Colorado.

U.S. Geological Survey.  1976.  Salt-Load Computations—Colorado River:
     Cameo, Colorado to Cisco, Utah.  Parts 1 and 2.  Open File Report,
     Denver, Colorado.

U.S. Department of the Interior.  Bureau of Reclamation and Office of
     Saline Water.  1972.  Desalting Handbook for Planners.  Denver,
     Colorado.  May.  274 p.
                                    428

-------
Valentine, V. E.  Impacts of Colorado River Salinity.  1974.  Journal of
     the Irrigation and Drainage Division, American Society of Civil
     Engineers.  Vol. 100, No. IR4.   December,  pp. 495-510.

Walker, W. R.  1978a.  Integrating Desalination and Agricultural Salinity
     Control Alternatives.  EPA-600/2-78-074.  U.S. Environmental
     Protection Agency, Ada, Oklahoma.  182 p.

Walker, W. R.  1978b.  Identification and Initial Evaluation of Irrigation
     Return Flow Models, EPA-600/2-78-144.  U.S. Environmental Protection
     Agency, Ada, Oklahoma.

Walker, W. R.  1979.  Explicit Sprinkler Irrigation Uniformity-Efficiency
     Model, Journal Irrigation and Drainage Division, ASCE, Vop. 105,
     No. IR2, pp. 129-136.

Walker, W. R. and G. V. Skogerboe.  1971.  Agricultural Land Use in the
     Grand Valley.  Agricultural Engineering Department, Colorado State
     University, Fort Collins, Colorado.

Walker, W. R., G. V. Skogerboe and R. G. Evans.  1979.  Reducing Salt Pickup
     From Irrigated Lands.  Journal Irrigation and Drainage Division,
     Vol. 105, No. IR2, pp. 1-14.

Walker, W. R. and G. V. Skogerboe.  1981.  Evaluating Furrow Irrigation
     Systems for Regional Water Quality Planning.  Report AER 80-81,
     WRW-GVS1,  Agricultural and Chemical Engineering, Colorado State
     University, Fort Collins, Colorado.  March.  150 p.

Walker, W. R., G. V. Skogerboe, and R. G. Evans.  1978.  Best Management
     Practices for Salinity Control in Grand Valley.  EPA-600/2-78-162.
     U.S. Environmental Protection Agency, Ada, Oklahoma.
                                     429

-------
                                 APPENDIX  D

                   NONPOINT SOURCE  WATER QUALITY  PROBLEMS
                        RELATED  TO  ANIMAL  AGRICULTURE
                       J.H. Martin, Jr. and  R.C.  Loehr
                                   SECTION  1

                                 INTRODUCTION
     The potential of animal  production  activities  to impair the quality of
adjacent surface waters is well documented.   Water  quality problems
including fish kills due to depressed  dissolved  oxygen  levels and ammonia
toxicity, accelerated rates of eutrophication, microbial  contamination, and
visual impairment have been directly  linked  to manures  and other wastes
associated with animal agriculture.  Although  not  unrecognized, the impacts
of animal production activities on  water quality have,  until recently,
received little attention  in  water  pollution  control  programs,  being
obscured by the magnitude  of  problems  related  to other  sources, particularly
point sources.  Where identifiable, water quality  problems associated with
animal as well as other agricultural  production  activities were generally
viewed as natural and uncontrollable.  Over  the  past  decade, however, a
change in this traditional philosophy  has occurred.  Results of a number of
studies have shown that pollutant discharges  related  to animal  production
activities can be substantial  and that the resultant  water quality impacts
can be significant.

     While the potential of animal  agriculture to  contribute to nonpoint
source related water quality  problems  is clear,  the magnitude and
significance of pollutant  discharges  from individual  production units can
vary substantially.  Difference in  management  practices which vary widely in
animal agriculture can be  a major factor contributing to this variability.
Thus, it is not possible to rely solely  on analyses of  physical factors such
as location, topography, precipitation,  etc.  to  identify individual
production units which require remedial  measures such as implementation of
best management practices  to  reduce or abate  nonpoint pollutant discharges.

     The purpose of this technical  report is  to  provide guidance to those
individuals responsible for the development  and  implementation  of programs
for the control of pollutants  from  agricultural  nonpoint sources in addres-
sing water quality problems associated with  animal  production activities.
                                     430

-------
This task appears to  be  best  accomplished  by providing an understanding of:
(1) the nature and characteristics  of  water  quality problems related to
animal  production activities;  (2) the  relative significance of the various
physical  sites from which  pollutant  discharges may occur; and (3) applicable
control strategies.
                                     431

-------
                                  SECTION  2
                      SCOPE OF NONPOINT  SOURCE  CONTROL
                      ACTIVITIES  FOR  ANIMAL  AGRICULTURE
     Water pollutant discharges  associated  with  animal  production activities
can occur from a variety of  sources.   Included  are  land used for manure
disposal, pasture and rangeland, open  confinement  facilities,  manure
storages, milk houses and milking  centers,  and  silos.   With the exception of
lands used for grazing and manure  disposal,  these  potential  sources of water
pollutants could be considered to  be  point  sources  in  that discrete,
identifiable facilities, and in  some  situations  conveyances, are involved.
However, only concentrated animal  feeding  operations  (feedlots) are
designated point sources of  water  pollutants  (U.S.  Congress, 1972).

     To assess needs, identify priorities,  and  develop  implementation
strategies for the control of nonpoint  source  discharges of pollutants from
animal production units, the delineation of program scope is critical.  If
water quality problems associated  with  animal  production activities are to
be addressed successfully, point and  nonpoint  source  control programs must
interface but not overlap.   This section has  the following objectives:

     I)  To briefly review and discuss  the  established  definitions of point
         and nonpoint sources of water  pollutants,

     2)  To outline the nature and  scope of the  present point  source control
         program for concentrated  animal feeding operations (feedlots), and

     3)  To discuss the logic for  including all  other  sources  of water
         pollutants associated with  animal  agriculture  in a nonpoint source
         control program.

POINT AND NONPOINT SOURCE DEFINITIONS

     The terms point and nonpoint  are formally used for the first time as
descriptors of sources of water  pollutants  in  the  Federal Water Pollution
Control Act Amendments of 1972  (the  Act),  (U.S.  Congress, 1972).  The term
point source was defined as:  ".  .  ,any discernible,  confined  and discrete
conveyance, including but not limited to any pipe,  ditch, channel, tunnel,
conduit, well, discrete fissure,  container, rolling stock, concentrated
animal  feeding operation, or vessel  or other floating  craft, from which
pollutants are or may be discharged"  (U.S.  Congress,  1972).
                                     432

-------
     Although the term nonpoint  source  was  used  extensively in the Act, it
was never defined.  Subsequently,  it  was  defined  by  the  U.S.  Environmental
Protection Agency as follows,  "Nonpoint sources  tend to  be characterized by
three elements.  First, the pollutants  are  conveyed  by water  the source of
which is uncontrolled by any  person;  that is,  the water  pollution results
from precipitation, natural flooding  or snowmelt.   Second, the pollution
itself is not traceable to a  discrete,  identifiable  source such as a
facility or industrial  process.   The  fact that this  runoff may be channelled
into a ditch or drain before  entering navigable  waters does not, in and of
itself, make natural surface  runoff a  discharge  from a point  source.  Third,
the control of nonpoint source water  pollution  is generally best achieved by
planning and management techniques rather than by end-of-pipe treatment to
remove pollutants.  End-of-pipe  treatment,  designed  to meet specified
effluent limitations, is often inappropriate for  pollution control  for
nonpoint sources.   Instead, planning  and  management  techniques control and
abate the nonpoint  pollution  before it  is created and thus effectively limit
and prevent pollutants from reaching  navigable waters."(Federal Register,
1976a).  These planning and management  techniques are approaches which have
come to be known as best management practices  (BMPs).

CONCENTRATED ANIMAL FEEDING OPERATIONS

     Although concentrated animal  feeding operations (feedlots) are desig-
nated to be point sources of  water pollutants  (U.S.  Congress, 1972), all
feedlots which generate water  pollutant discharges are  not subject to regu-
lation under the National  Pollutant Discharge  Elimination  System (NPDES)
permit program.  Under the present NPDES  permit  program  (Federal Register,
1976b), pollutant discharges  from  feedlots  with  less than  1000 animal  units
may be either not identified  or  not considered to be point source
discharges.  Thus,  concentrated  animal  feeding operations  cannot be
completely excluded from the  scope of a nonpoint  source  control program
designed to address water quality  problems  associated with animal
agriculture.

     In the development of the NPDES  permit  program  for  concentrated animal
feeding operations, the term  "animal  feeding operation"  was introduced and
defined as, ". . .a lot or facility (other  than  an aquatic animal production
facility) where the following conditions  are met:

     (i) Animals have been, are  or will be  stabled or confined and fed or
         maintained for a total  of 45 days  or  more in any  12-month period,
         and

    (ii) Crops, vegetation, forage growth or post-harvest  residues are not
         sustained  in the normal  growing  season  over any portion of the lot
         or facility."   (Federal  Register,  1976b).

However, not all  animal  feeding  operations  as defined above are considered
to be potential point sources of water  pollutants.   The  criteria for desig-
nating an animal  feeding operation to  be  a  concentrated  animal  feedng opera-
tion, and therefore a point source, are outlined  in  Table  D-l.
                                     433

-------













£
i
O
P-i

£-t
3
a
w
H
(X
O
a
£2
H
O
3
PS
H
C/3

U
W

<1
CP

1

JE

H
C/3
J*^
C/l

§
H

13
M
S
t-J
M
W
O
3 ~
II
Q tH

I-* j-T
< 01
H  CO
O 4-1
rH E
73 cd
CU 4J
U 3

iH
m o
•H O.

73 rH
CU CO
rl CU
•H 00
3 rl
cr co
U X
rl CJ
CO
4J -H
r
4> •
PL, rH





CO
4-1
CO E
4J CO
0 4J
H 3
4) iH
41 o
"4H CX
O O
MH
rH
•O CO
41 41
rl 00
•H M
3 cd
cr x
41 CJ
rl tO
•H
4J -O
•H
B X
C 4J
41 -H
PM »










^
g
iH
U

1>
•0
•H
O

O.
CO
cd







o
4J
rl B
O ft

- CO
41 4J
O E
E td
CO 4J
>s 3
CU rH
> rH
B 0
O CX
CJ
rH
1) CO
73 41
CO 00
II
cd u
B co
•H
cd O

CM

























x
rH
B
0

B
O
•H
4J
CO
B
00
vH
CO
CU
•a
41
0) 1
CO 4J
0 0
1 rH
X 4<
1 O
CU *4H
CO
CO <4H
U -H








4J
rl CJ
O CO
4J
X B
00 O
3 O
0
rl 4J
X O
4J 41
rl
00 IH

•H
CO O
CO 4J
cd E
O.-H
CO 00
0 -H
4J B
cd o
* CJ






























CO
4J
E
CO
4J
3
iH
tH
0
a
H
to

1
CJ
CO
TH
O

iH






•a
41
B
•H
I4H
B
o
CJ

41

4J

E
•H

CO
rH
cd
B
•H
§
X
4J
•H
3


































eg
T3


i

CO
P-
oo
3
O
tH
X
4J






























CO
41

cd






























CO
4J
E
CO
4J
3

IH O
o a
••rH
U CO
CJ CU
E 00
ll
> o
B CO
O iH
0 0

CN






cu
CO
CO
CJ
1

X
1
41
CO
CO
CJ

o
4J

4J
CJ
41

x1
3
CO
CO
4H
O
rH
•a
u
4)
Px

























oo
3
o
IH
X
4J 4J
U
oo u
C rl
iH  U
•H (X
T3 CO
B E
•H -H

e u
S 4J
•H
00 CO
E B
•H O

iH ^
3 U
cr 4J
41 14H
IH CO

E >,
O rH
•H C
4J O
cd
B 4-1
00 'H
•S E
1) U
•a tx

























0
4J
CO
B rl
•H T3 41
B CX
CO cd - 1 O
rH BO)
CO ••> O B rl
B CO -H CO O
•H I* 4J rl
B rl O 4J !-l
CO CO U U
O. CO B
X 73 CO -rl S
4J 41 B O
•H B -H U
S -H O 41
MH 4> -H X
CJ 0 tH 0
cd u co E o
4J E 4-1
E U O E
ox u -a
CJ 4J V4 4J 11
CU 4J 4J
4J *H 4H
<4H U *H
< 5 B







^J
o
4J
Cd

11
CX
o

rl
O

rl
41

5


0
4J
4>
U
•H

O
B
B
cd

























E
0



l-i
JC,
1

CN

£
*n
CN
It-
O
w
E
41
41
CU
X
•rl
>,
rH
B
O

CO

3
U
U
O

u
oc


f-
o
CO
•H
•o

ii |
•H

4J
•rH
H

a
c
•H
CO

X
0
o
4-1
B
B
41

3
cr

-------
     The term "animal unit"  is  a  standard  unit  of measurement based upon a
feeder cow or steer representing  one  animal  unit.   The  following numbers of
various species of animals are  equal  to  1000 animal  units:

     1)  1000 slaughter and  feeder  cattle,
     2)  700 mature dairy cattle  including  dry  cows,
     3)  2500 swine weighing  over 25  kg  (55 Ib),
     4)  500 horses,
     5)  10,000 sheep or  lambs,
     6)  55,000 turkeys
     7)  100,000 laying hens  or broilers  (if the  facility has continuous
         overflow watering)
     8)  30,000 laying hens  or  broilers  (if the facility has a liquid manure
         handling system)
     9)  5000 ducks (Federal  Register, 1976b).

     Those animal feeding operations  designated to be point sources of
pollutants are required to comply with the  effluent  guidelines and standards
for feedlots point source category  established  by the U.S.  Environmental
Protection Agency (Federal Register,  1974).   These guidelines and standards,
which specify that no discharge of  process  wastewater pollutants is
permitted with the exception  of a 10-year,  24-hour rainfall  event, are
determined to be the best practicable control technology currently
available.  For best available  technology  economically  achievable determined
to be applicable to all new  sources as of  1974  and is applicable to all
sources by 1983, the exception  to the no discharge requirement is a 25-year
24-hour rainfall event.

     The no discharge effluent  standard  for animal  feeding  operations desig-
nated to be point sources of  pollutants  has resulted  in the use of planning
and management techniques, BMPs,  such as  runoff diversions  and collection
ponds rather than end-of-pipe treatment  for control  of  discharges from these
point sources.  End-of-pipe  treatment to meet specific  stream standards has
been shown in a number of studies to  be  neither practical nor economically
feasible.  The use of BMPs in these situations  represents an extension of
the basic philosophy that land-based  disposal of  wastes associated with
animal agricultural activities  represents  the most suitable alternative.

SCOPE OF ANIMAL NONPOINT  CONTROL  ACTIVITIES

     The foregoing discussion provides the  underlying logic for including
other sources of pollutants  associated with animal  production activities in
the scope of a nonpoint source  control program.  Although pollutant dis-
charges from manure storages, milk  houses  and milking centers, and silos may
occur via pipes or other  man-made conveyances,  end-of-pipe  treatment techni-
ques are clearly inappropriate.   Thus, the  question of whether or not these
potential sources are point  or  nonpoint  sources of pollutants is a moot
issue.  From a practical  standpoint,  inclusion  of these potential sources as
well as small animal feeding operations,  less than 1000 animal units, in
point source control programs is  questionable due to limitation of resources
for identification, monitoring, and enforcement.
                                     435

-------
                                   SECTION  3
                    POLLUTIONAL  CHARACTERISTICS  OF  WASTE
                     ASSOCIATED  WITH  ANIMAL  AGRICULTURE
     Typically, animal production  activities  occur  in  areas that include
other land-based activities  such as  crop  production,  silviculture, etc.
which also can generate nonpoint discharges  of  water  pollutants.  The
determination of the  effectiveness  of  best  management  practices (BMPs) in
controlling specific  water quality  problems  is  dependent on the ability to
distinguish between problems  related to  animal  agriculture and other
nonpoint sources.  Knowledge  of the  characteristics  and resultant water
quality impacts of pollutants  associated  with animal  production provides a
basis to make this distinction.

     The three principal  sources of  water pollutants  associated with animal
production are (1) manures,  (2) milk house  and  milking center wastewaters,
and (3) silage liquors.   Although  animal  manures  are  the most visible of
these sources, milk house and  milking  center wastewaters and silage liquors
also can impair water quality.  This section  has  the  following objectives:

     1)  To provide an understanding of  the  origins  and characteristics of
         these potential  sources of  water pollutants,

     2)  To discuss the nature  of  the  water  quality  impacts of specific
         pollutant constituents, and

     3)  To outline a methodology  which  can  be  used  to determine if an
         observed water quality problem  is  related  to  animal agriculture.

POLLUTIONAL CHARACTERISTICS

Animal Manures

     Manures are significant  potential  sources  of water pollutants due to
the quantities produced.   It  has been  estimated (Van  Dyne and Gilbertson,
1978) that the dry matter content  of manures voided  annually by livestock
and poultry in the United States exceeds  100 million  tonnes annually.
Manure produced by beef cattle  on  range  and  in  feedlots accounts for over  50
percent of this amount  (Table  D-2).  Although only  a  small fraction of the
total quantity of animal  manures produced enter surface waters, the impact
on water quality can  be substantial.  Manures are concentrated sources of
pollutants such as oxygen demanding  compounds,  nutrients, and
microorganisms.

                                     436

-------
TABLE D-2.  ESTIMATED U.S.  MANURE PRODUCTION BY LIVESTOCK AND POULTRY,  1974
            (Van  Dyne and  Gilbertson,  1978)


                                   Manure,  Dry
                                     Weight
Specie                            1000  Tonnes/yr                   % of  Total
Beef cattle on range
Dairy cattle in feedlots
Dairy cattle
Swine
Sheep
Laying hens
Broilers
Turkeys
47,268
9,469
22,891
12,131
3,447
3,064
1,894
1,136
46.7
9.3
22.6
12.0
3.4
3.0
1.9
1.1
                                    101,300                          100
     It is difficult to quantitatively  describe  typical  characteristics of
nonpoint source discharges  containing  manurial  constituents due to the many
variables which affect the  concentrations  of  specific pollutants.  Runoff
and seepage from  animal manures  will,  however,  contain many constituents
the manures.  Thus, knowledge  of  the  pollutional  characteristics of animal
manures provides  a  sound  basis  for  assessing  the possible relationship
between manures and an observed  water  quality problem.
     Manures are  the combined  urinary  and  fecal  excretions of livestock and
poultry and are waste products  of digestive  processes.  The principal
constituents of manures are water,  undigested and indigestible feedstuffs,
end products of various metabolic processes,  digestive fluids, and
micro-organisms indigenous  to  the gastrointestinal  tract.  Varying
quantities of wasted feed,  bedding,  and other materials  such as soil may be
mixed with the manure.  Typical  characteristics  of  livestock and poultry
manures as excreted are summarized  in  Tables  D-3 and D-4.  In that manures
are semi-solids,  these characteristics  are presented on  a weight rather than
a volume basis.
     Manure runoff  and seepage  normally result  in decreased and possibly
zero dissolved oxygen levels,  nutrient  enhancement,  microbial contamination,
and possible ammonia toxicity  to  aquatic organisms  in surface waters.
Visual  impairment due to  manurial solids and  pigments as well as noxious
odors also can occur.
                                      437

-------
 TABLE  D-3.   PHYSICAL  AND  CHEMICAL CHARACTERISTICS  OF  ANIMAL  MANURES  (American
             Society of Agricultural  Engineers,  1979)

Parameter
Raw Manure* (RM) ....
Total Solids (TS) . . .
Volatile Solids (VS) .
BOD- 	
COD 	
BOD : COD 	
J
Total Kjeldahl Nitrogen
Total Phosphorus, as P
Potassium, as K ....



wt/day t
%RM
%TS
%TS
%TS
Ratio
%TS
%TS
%TS


Dairy
Cow
82
12.7
82.5
16 5
88
0.19
3.9
0.7
2.6


Beef
Feeder
60
11.6
85
23
95
0.24
4.9
1.6
3.6


Swine
Feeder
65
9.2
80
33
95
0.35
7.5
2.5
4.9


Laying
Hen
53
25.2
70
27
90
0.29
5.4
2.1
2.3


Broiler
71
25.2
70


6.8
1.5
2.1

*Feces and urine only
tKg per 1000 kg liveweight
TABLE D-4.  AVERAGE DENSITY OF INDICATOR ORGANISMS IN HUMAN AND DOMESTIC ANIMAL
            FECES



Animal
Man
Chicken
Cow
Pig
Average Indicator
Fecal
Coliforms*
1.3 x 107
1.3 x 106
2.3 x 105
3.3 x 106
Density, Per Gm.
Fecal
Streptococcit
3.0 x 106
3.4 x 106
1.3 x 106
8.4 x 107
Ratio^
Coliform/
Streptococci
4.3
0.4
0.2
0.4

*Geldreich, 1966
tKenner et al., 1960
                                      438

-------
     Depressed dissolved  oxygen  levels  can  be  the  result of both carbona-
ceous and nitrogenous compounds.   The  five-day biochemical  oxygen demand
(BOD5) values reported  for manures and  runoff  and  seepage are not truly
indicative of potential impact on  dissolved  oxygen  levels in  that the nitro-
genous oxygen demand normally  is  not measured  in  the BOD5 analysis.  In
addition, the BODs determination  is not  an  estimate of total  carbonaceous
oxygen demand but rather  oxygen  demand  exerted by  carbonaceous compounds
which are readily available as microbial  substances in five days.  The
chemical oxygen demand  (COD) test  includes  carbonaceous compounds which
cannot be utilized microbially as  substrates and  is,  therefore,  an over-
estimate of carbonaceous  oxygen  demand.   The actual carbonaceous oxygen
demand of animal  manures  liesbetween reported  BOD5  and COD  values.  Both
parameters are, however,  useful  in indicating  potential impact on the
dissolved oxygen status of surface waters  receiving nonpoint  discharges
related to animal manures.  The  carbonaceous oxygen-demanding materials in
animal manures are present in  both soluble  and particulate  forms.  Thus,
reduction or abatement  of only the particulate fraction of  manurial runoff
and seepage may not totally alleviate water  quality problems  involving
reduced dissolved oxygen  concentrations.

     As indicated (Table  D-3), animal manures  also  can contribute nitrogen
and phosphorus to surface waters  resulting  in  the development of eutrophic
conditions.  Manurial nitrogen as  excreted  is  in  the form of proteinaceous
compounds and urea or uric acid.   Urea  is  excreted  by mammals and uric acid
by poultry.  If ammonia,  nitrite  or nitrate  compounds are present in fresh
manures, their quantities are  insignificant.   These nitrogen  compounds can
be present in manure that has  been partially degraded or oxidized.

     The organic nitrogen compounds present  in manures, particularly urea
and uric acid, are readily available as  substrates  to a wide  variety of
aerobic and anaerobic,  heterotrophic microorganisms.   When  manurial organic
nitrogen compounds are  degraded  microbially, the  nitrogen not utilized as a
microbial nutrient is transformed  into  ammonia nitrogen.  This process is
termed ammonification and can  occur under a  wide  variety  of environmental
conditions.  Thus, ammonia nitrogen is  a common constituent of manurial
runoff and seepage and  is a possible indicator of animal  manure  caused water
quality problems.

     Under aerobic conditions, ammonia  nitrogen can be microbially oxidized
to nitrate and nitrite  nitrogen.   The microorganisms  primarily responsible
for these transformations are  the  autotrophic  species Nitrosomonas and
Nitrobacter.   The oxidation of ammonia to  nitrate nitrogen  is a  two-step
process termed nitrification which can  be  described as follows:
  +
NH^ + 3/2 02  Nitrosomonas>N02 +  2H+ + H20           (1)

N02  + 1/2 02 Nitrobacters N03                      (2)
                                     439

-------
The nitrification process is an oxygen  demanding  process.   Stoichiometri-
cally, 4.57 grams of oxygen are required for  each  gram  of  ammonia nitrogen
oxidized to nitrate nitrogen.  Thus,  the nitrogenous  oxygen demand exerted
by organic and ammonia nitrogen in manurial nonpoint  source discharges can
be substantial (Table D-5).

     The nitrification process can occur in terrestrial  as well  as aquatic
environments.  Thus, nitrate nitrogen also can  be  a constituent  of manurial
nonpoint pollutant discharges  (Table  D-6).  Since  nitrite  and nitrate nitro-
gen are not exchangeable ions, they can be transported  independently of
particulate matter.  Ammonia nitrogen is water  soluble  but also  is an
exchangeable cation.  Thus, ammonia nitrogen  transport  can occur in associa-
tion with or independently of  soil and  organic  particles.   Elevated concen-
trations of ammonia and nitrate nitrogen in surface waters are a potential
indicator of nonpoint or point sources  containing  manure.   Phosphorus in
animal manures is present in both soluble and particulate  forms.  Available
data  (Table D-7) indicate that a  substantial  fraction of manurial phosphorus
can be in the soluble form.  In addition, the particulate  phosphorus which
is organically bound will be solubilized as organic matter degradation
occurs.  In the soluble form,  phosphorus is readily available for transport
via runoff.  Elevated concentrations  of both  soluble  and particulate phos-
phorus in surface streams can  be  indicative of  runoff" containing manure.

     A wide variety of microorganisms are indigenous  to the gastrointestinal
tract of livestock and poultry and are  excreted in fecal material.  Nonpath-
ogenic species, many of which  are important to  the digestive process,
predominate.  Although pathogenic species also  may be present in manures,
transmission of zoonotic diseases through contact  with  contaminated natural
waters is rare.  The presence  of  fecal  coliforms  and  fecal streptococci in
natural waters is, however, commonly  used as  an indicator  of fecal contamin-
ation.  Both of these groups of microorganisms  are common  inhabitants of the
gastrointestinal tract of warm-blooded  animals  including man (Table D-4).
Thus, they are utilized as organisms  indicative of human or animal pollu-
tion.  Geldreich (1966) suggested that  the differences  in  the ratios of
coliforms to streptococci for  human and animal  feces  (Table D-4) may repre-
sent a method to distinguish between  farm animal  and  human sources of water
pollutants such as septic systems for human wastes.   Thus, high  ratio of
fecal coliforms to fecal streptococci  (greater  than  4)  in  surface waters
suggest contamination by human rather than animal  sources.  The  use of  fecal
coliform to fecal streptococci ratios to distinguish  between human and
animal sources of fecal contamination should  be used  with  caution, however,
since differences in die-off rates can  significantly  alter this  ratio.

Milk House and Milking Center  Wastewaters

      Following each milking of dairy  cattle,  milking  equipment and
facilities must be thoroughly  cleaned to maintain  milk  quality.   This
results in the generation of a waste  stream described as either  milk house
or milking center wastewater.  On farms where cows are milked in the housing
unit, the cleaning operation is limited to the  milking equipment, the milk
storage tank, and the milk house  floor. The  term milk house wastewater
                                     440

-------
o
S5
L_j
g


*^
§
£_}

CO
W
P§
<

CO
^
«
£_l
^;
f-*
»_4
Q
PH
§
Z
z
M
P
W
Q

2
w
o
SH
S
o
CO
a
5
z
w
o
o
pj
E-l
1— 1
g;

Q

3

,-1

I— I
X w
W H
a z
c_> w
o t>
M H
M M
£H
fn co
O Z
O
0 "
CO t-4
M 3
33
P i i~~i
o <2
u s



IO
i
Q
W
^4
M
 Q
•rH
z
/ — v
z
1
^°
2
cb ^-^
• H
C G
O <1)
J&o
P
H
4J
•H
Z



c
0)
bO.— ^
X LO
X Q
O O
CO
i-H v_^
03
O TJ
•H Pi
6 rt
| 0)|
4-11 CD X
0)  rt in
i— ( (Nl > LO rt i— 1
,-H t-- C r- U t^
(D Ol O C71 O O>
S i-l U i-H 2 '-<




LO LO
r-~- CN
to 1-1 LO
LO t~~- CTi
IO 1 1
1 tt OC
i-H i-H
LO i-H CJl
•-H LO tO



C7* CTi
LO
10 0
Tt i-H CM
r-- i i
f> CT^ r~-
i r-i
to i— 1 °0
tO r-i










LO
o
LO O>
r~ oo o
" C7* i — i
(N tO 1
i— i cr> CM
i i
LO VO ,-!
O^ ^* t^O
tO i-H
CM C7>






/^ — %
o<
U)
e
v — ;
/-> fl) /^
<^ bO °<
•^ rt ~^
W) P, M
4-> S CD £
P; v_^ 0) r-H ^
(U CD w a]
€ <4-l fn U) <-H
dl <4-l 3 TJ O <4-(
CO C P! PL, O
•HP; rt rt  4)
0) rX C M 4->
P! ^H O3 3 -H
(D rt rt fn Pi  rt
CD CO S






















































t^
LO
•*fr

X

-------
TABLE D-6.  COMPARISON OF AMMONIA AND NITRATE NITROGEN CONCENTRATIONS  IN

            NONPOINT DISCHARGES CONTAINING MANORIAL CONSTITUENTS
Source
Ammonia Nitrogen  Nitrate Nitrogen

 (NH -N), mg/£     (NO--N), mg/H     Reference
    T-                 J
Open confinement area
runoff





Manure disposal site runoff



151-780

--

33-774

25
0.4-1.3
8.7-20.9

10-17.5

2.1

0-1270

3-5
2-8
2.8-7.6

Gilbertson
et_ al_. , 1975
Edwards et al . ,
1972
Wells et al . ,
1972 ~
Muck, 1975
Long, 1979
McCaskey et al . ,
1971

  TABLE  D-7.   AVERAGE  VALUES  FOR TOTAL  AND  SOLUBLE  PHOSPHORUS  IN  LIQUID ANIMAL

              MANURES  (Townshend et  al.,  1969)

Species
Swine
Poultry
Beef
Dairy
Total Phosphorus,
%. of Total Solids
3.6
2.3
1.4
0.8
Soluble Phosphorus,
% of Total Phosphorus
43
18
54
46
                                      442

-------
describes these wastewaters.  These  farms,  typically,  have  herds  of 50 cows
or less.  On larger farms, cows are  more commonly  milked  in  a  specialized
facility called a milking parlor which  is  adjacent to  the milk house.   This
milk house-milking parlor combination is collectively  described  as a  milking
center.  Since the milking parlor  also  is  cleaned  with water after each
milking, milking center wastewater can  contain a significant quantity  of
manure in addition to the constituents  of  milk house wastes.

     Typical pollutional characteristics of milk house and  milking center
wastewaters are outlined in Table  D-8 through D-ll.  Similar characteristics
for the wastewaters have been reported  by  others (Loehr and  Ruf,  1968  and
Zall, 1972).  These data show that the  quantities  of milk house  and milking
center wastewaters generated on dairy farms are  not  insignificant and  can be
sources of oxygen-demanding materials and  nutrients  if permitted  to enter
natural waters.  The densities of  fecal  indicator  organisms  (Table D-ll) in
milking center wastewaters also should  be  noted.   Although  no  data concern-
ing indicator organism concentrations in milk house  wastewaters  is avail-
able, such concentrations should be  less than those  listed  in  Table D-ll
since manure is not included in milking center wastewaters.

Silage Liquors

     Ensiling is a fermentation process used extensively  to  preserve  forage
materials for use as feedstuffs for  dairy  and beef cattle.   Although  a
variety of plant materials can be  ensiled,  most  silages are  made  from
grasses, legumes, corn, or sorghum.  Silages made  from grasses and legumes
are often referred to as hay crop  silages.

     The preservation of ensiled materials  results from the  microbial  pro-
duction of lactic acid produced from plant  carbohydrates  in  quantities that
will reduce the pH of the ensiled  mass  to  levels of  4.5 or  less.   At  these
pH levels, microbial activity of proteolytic and putrefactive  organisms is
inhibited.  Although other acids including  acetic, formic,  andsuccinic as
well as alcohols also are produced during  the ensuing  process, only lactic
acid is produced in quantities sufficient  to achieve the  required low  pH
levels.  This is due to the ability  of  species of  the  genus  Lactobacillus to
tolerate acidic conditions.

     A common characteristic of the  ensiling process is the  generation of a
liquid waste stream which is described  by  a variety  of names including silo
effluent, silo seepage, and silage liquor.   The  potential  water  quality
impact of this waste stream is not widely  recognized particularly in the
United States.  Thus, little information exists  about  the pollutional  char-
acteristics of silage liquors.  The  information  which  is  available
is summarized in Table D-12.  The  extremely high BOD5  concentrations  of
silage liquors are noteworthy.  A  large fraction of this  BOD5  is  attribut-
able to the soluble organic compounds such  as the  organic acids  and alcohols
produced during the ensiling process.   The  forms in which nitrogen and phos-
phorus are present in silage liquors are unreported.   Although the micorbial
characteristics of silage liquors  also  are  unreported,  it is not  likely that
fecal indicator organisms would be present.
                                     443

-------

















0)
rH
C
•H
+-1
1
en
u
HH
H
en
t—t
c£
H
U

cx
<
*\
bC
E








•f-
CQ

E
rt







*
<£

E
H
rt
P-,




















?H
 CM
*\ •%
O ^D
i— I












C
0
M
W X
T3 X
•H O
W F-H
T3 O --H
•H to rt
rH O
O CD -H
C/) i-H E
•H 0
rH +J X
rt rt O
4-> rH O
O O -H
H > OQ

O^
•
T^J-









00
•
rH
to


to
to
•*








LO
to
01
*
rj-

















X

Q

LO

f\
rO
C
rt
0
Q

O
•
\D
rH








T^(-
•
T^J-



^>
t^..
^
rH







0
r^
00
•\
^j-
rH








T3
C

B
0
Q

C
0
Ml
X
X
0

rH
rt
o
•H
6
0
C_J
CTl t~^
LO LO 1 1
1 1
O rH








to oo
CM CM 1 1
1 1
CM rH


^
00 ^t" rH O
LO I~^ O rH
rH CTl







CM
oo 01 ** f-
VO ^O t~~* rH
tO CM t^










C
0
bo
0
rH

•H X
2 w rt
3 Q
rH rH 1
rC O X S
rt X rt O
T3 O. Q U
rH t/) "^--x. *^v^
 X
S*5 Cu •> •>
0 0
rH i-H 6 B
rt rt 3 3
•P 4-> rH rH
O O 0 0
H H > >


























































W t/)
IS "£
o o
u u
LO LO
^t 00
•X -f-
444

-------
TABLE D-9.   MILKING CENTER WASTEWATER CHARACTERISTICS (Bland, 1980)

Parameter, mg/&
Total Solids
Volatile Solids
Suspended Solids
Biochemical Oxygen Demand,
5 -Day
Chemical Oxygen Demand
Total Kjeldahl Nitrogen
Ammonia Nitrogen
Total Phosphorus
Filterable Orthophosphate
Number of Cows, Av.
Volume, A/Day

A
3830
2030
1160
2290
4060
280
189
135
101
58
1020
Farm
B
6460
4522
3870
2270
6100
560
250
79
36
125
1250

C
1200
588
290
370
880
60
29
44
35
64
2010

TABLE D-10. QUANTITIES OF
POLLUTANTS IN MILKING
CENTER WASTE WATERS
(Bland, 1980)

Parameter, Gm/Cow-Day
Total Solids
Volatile Solids
Suspended Solids
Biochemical Oxygen Demand,
5 -Day
Chemical Oxygen Demand
Total Kjeldahl Nitrogen
Total Phosphorus
Volume, £/Cow-Day

A
67
36
20
41
70
4.9
2.5
18
Farm
B
65
45
38
22
61
5.6
0.8
10

C
38
18
9
11
30
1.8
1.3
32
                                     445

-------
 TABLE D-ll.   AVERAGE DENSITY OF INDICATOR ORGANISMS  IN  MILKING CENTER
              WASTEWATERS (Bland, 1980)

Farm
A
B
C
Average Indicator
Fecal
Coliform
2.2 x 106
1.9 x 107
2.3 x 107
Density, Per 100 mg/£
Fecal
Streptococci
5,9 x 105
3.0 x 107
2.0 x 107
Ratio
Coliform
Streptococci
3.7
0.6
1.2

TABLE D-12.  POLLUTIONAL  CHARACTERISTICS OF SILAGE LIQUORS (mg/1)
                      Bioche'i'.i cal  Oxygen      Nitrogen      Phosphorus
Source               Demand,  5 Day (BOD )    (Total as N)       (as P)



Anon.,  1963            12,550 -  66,400       1000-5000        61-613

Little, 1966            30,000 -  60,000

Berryman, 1970                 -                 2300           44-1311
     The volume of silage liquors generated  during  the  ensiling process is
highly variable, with reported values  ranging  from  virtually  nil  to
quantities in excess of 400 £ per tonne  of material  ensiled  for conventional
tower silos.   Thus, volume of silage  liquor  discharges  may  be substantial.
For example,  the volume of silage liquor  discharged from a  6.1 m x 18.3 m
tower silo can exceed 151,000 &.  A silo  having  the dimensions noted above
has a capacity of approximately  360 tonnes.

     Due to greater internal pressures,  the  quantity of silage liquor
discharged from a tower silo normally  exceeds  that  from a  horizontal  or
bunker silo.   An exception is an uncovered horizontal  silo  where
precipitation infiltration can result  in  a substantial  silage liquor
discharge.  Silage liquor discharges  from controlled atmosphere silos is nil
when these structures are operated properly.

     Normally, silage liquor discharges  are  limited to  a six-week period
following silo filling with maximum flow  occurring  during  the first two
weeks.  These discharges are seasonal  in  nature  being  limited to summer and
early fall months.  Typically, no effort  is  made to contain  or collect


                                     446

-------
silage liquors with disposal  occurring in an uncontrolled manner.  Water
quality impacts caused by  silage  liquors  occur in the summer and early fall
and primarily  result  in  decreased dissolved oxygen levels.

WATER QUALITY  IMPACTS

     From the  previous discussion it  can  be seen that the pollutional char-
acteristics and therefore  the  potential water quality impacts of the princi-
pal sources of water  pollutants  associated with animal  agriculture are simi-
lar.  A number of these  pollutional  characteristics can be used to distin-
guish between  water quality  problems  associated with animal  production
activities and those  related  to  other nonpoint sources  such  as cropland
runoff.  The relative water  quality  impacts of animal agriculture and crop-
land nonpoint  sources (Table  D-13)  indicate a number of differences.

     One probable Impact common  to all potential sources of water pollutants
associated with animal production Is  decreased dissolved oxygen concen-
trations.  These discharges  also  will be  reflected by Increases In BOD5 and
COD concentrations In a  stream.   Although nitrogen enrichment can result
from nonpoint  source  discharges  from  a variety of land-based activities,
Increases in ammonia  nitrogen  concentrations are most likely to be
associated with animal production activities.  Conversely, nitrate nitrogen
is less useful  as a parameter  for source  identification in that nitrate
nitrogen is a  common  constituent  of  cropland runoff.  The presence of fecal
col 1 form and fecal streptococci  indicator organisms in  increased
concentrations also suggests  that animals or manures could be a source of
the problem.   These organisms, however, may not be present in increased con-
centrations in situations  where milk  house wastewaters  or silage liquors are
the principal   nonpoint pollutant  sources.

     In the analysis  of  available water quality data to determine if an
observed water quality problem is related to animal agriculture, placing
total emphasis on one water  quality characteristic should be avoided.
Rather, a combination of water quality characteristics  should be examined.
Results of a study by Dornbush £t a\_., 1974 provide an  excellent example of
the need to consider more  than one water  quality characteristic.  Although
the use of fecal indicator organisms  to indicate manurial  contamination is
fundamentally  sound,  these organisms  may  be present in  runoff from sites not
recently used  for animal confinement  or manure disposal  (Table D-14).
Although the observed fecal  indicator organism concentrations suggest the
presence of animal manures,  neither BOD5, COD, or ammonia nitrogen
concentrations  would  support this  conclusion.  The combination of parameters
in this example indicate that  the source  is more likely to be runoff from
land on which manure might have been  added at one time.   This demonstrates
the need for comprehensive water  quality  characterization in problem areas
to provide a sound basis for  source determination analyses.
                                     447

-------
H
2
i — i
O
OH

O
2
PH
PH
O
2
§

Q

O-
O
oi

Q

j

PJ
DS

2
B

S

^

] i
^
H- 1


o

co
H
^
OH

1 !

>.
H
t— H


&
^
LU
F-H
5
S co
OJ
PJ U
OQ <£
< ffi
CO CJ
O CO
Oi rH
0, Q

to
I— 1
1
Q
PJ
CQ

H
rH f| |
Cti 4-(
rH O
P< Pi
O 3
rH 0-
U



CD ,
bO «
rH 3
•H ^
co ^


f_l
fj to
c ^
CD ^
f j 4-*
o3
bO ^
CH
•H ^
Lj W
• H ^





0 ^
to jl

1 |
^ CD
rH ^
• pH _j
^




r-H ^
\~j 0
Cu (

• H ^
C ^
<3 s










h
CD
g
rt
03
OH








OOO + O + + + O +








I + + + + O + + OO










I + + + + O + + +O













I + + + + O + + OO










1 + + + + * + + +o








n^
f-H
n3

CD C
Q cd _
g 13
C3 CD to pi
CD Q 3 rt
pi bO pi pi to f-i
CDXC CDCDSOto
box CD C bObOf-iX 6-H
X O bOCD O O O Pnf-iu
X XbOrHrHrCWOO
03 O fn -H -H to ^C -H U
T3O +-» 2 2 O OH >— i O
CD -H rH -H X O 4-> 4J
> S 032 rt CDO, CDUPnp;
1—10)0 -H4-> rH CDCD
Ord'HrH Pi CTjrH,£lrHrH g
tOOgnJO^H033rt+-»-H
t/1 O CD-P g-P4J'-H OCOH3
•H -H rC O c -H O O CD CD
Qoac_3E-c<2E-cOOUH CO











c/}
fn
O
O
O
£
o
Pi
rn

0)
rH
to t/1 O
PC ^H
O O CD
• H -H ,O
• H -H tO
T3 T3 CD
P! C rH
O O 3
oo p:
a3
T3 T3 g
P C
^ J3 *+H
o o o
rH rH
bo bo C
rM Ai O
O O -H
ai cd +->
t3
O O -H
+-> -P X
o
*"O '"O
CD CD fH
fn rn O
CT3 Cd *H
PH PH rH
g g PH
0 0
O O C
O
C C PH
CD 4) 3
rC rP
S IS W)
C C -H
O O *T3
•H -H p
P +-> CD
cti rt 4-> pt«

4-> P CTJ 13
C P PH
CD CD g CD
o o -H tn
P P rt
O O 4-> CD
0 0 p rn
ctf O
P P 0 P
• H -H -H -H
CD CD -H CD

-------

Q
W

O
OH
PJ

Q
r-H

Q


OS •
P-l ' — 1
H rt

<£ -P
OS CD
<£
U 10
3
j r>
< G

O O
HH Q

|~1
—J Q
-i <-~
t~~* r-t
O <
OH Hj
.
•*
1
Q

OJ

CQ
<^
H


























































































co o
H, -H
\ +->
u rt
UH OS






i — 1
e

0
o
r-H
~ — ,
in
•P
C
3
O
U






•H
U
o
0
i-H O
rt 0
CJ +->
CD p i
UH CD
J_j
•p
co



t/1
G
rH M
rt 0
O 4H
0) -H
UH r-H
0









C
o
•H
rt
£-1
4->
C
CD
O
G
O
U














G
CD CD
•P M
rt O
+-> -P
z z

fH
rt CD
•H bo
C 0
O ,H

S -H
< Z


i-H
rt G T3
0 CD C

's x B
CD X 0)
X! 0 Q
C_}



i — i
rt
0
•H G "U
6 co C
CD M rt
X X B
O X 0)
0 O Q
•H
CQ



C|_j
<4H CD
O OH
G X
3 H
OS




CD
in
|-"i

T3
G
rt

r-H O MD LO
K) ^ CN OO
.-H O .-H K)
• • • •
O O O O



r-H r-H OO t~-
r^ en ^r CM
\O o LO r^
*\ «x »\ n
MD LO O^J MD
o to r~
r-H








r-H i-H 00 CM
t^ r-H VD CTl
CTl -^ r-H LO
n •* n n
bO i-H CTl CM
r-H




K) to O ^f
00 OO CTl v£>
O O O O




CTl O to
CM LO rH
1
O O O







v£5 \O CTl O
\£> LO tO \O
T^










00 i-H II
i — l




r-H +J r-H 4J
r— 1 r-H i-H i-H
rt CD rt CD
^4H £~ ^4H B
G S G 1
•HO -HO
rt C rt G
OS CO OS CO

irt
rt -d
O 0)
*xj o
G rH
rt OH

G CD T3
rH r-H C
O 13 rt
U r-H J
449

-------
                                   SECTION 4
                  PHYSICAL  SOURCES  OF  POLLUTANTS ASSOCIATED
                      WITH  ANIMAL  PRODUCTION ACTIVITIES
     Once it has been decided  that  an  observed  water quality problem is
related to animal production activities,  it  is  then necessary to identify
the physical  source or sources  of the  responsible pollutant discharges
before appropriate candidate best management practices (BMPs) can be
selected and evaluated.  These  physical  sources are the sites from which
nonpoint pollutant discharges  can occur.   This  represents one of the most
challenging steps in  reducing  nonpoint  water quality problems associated
with animal agriculture  due to  the  number of possible sources:

     1)  Confinement  facilities,
     2)  Land used for manure  disposal,
     3)  Manure  storage  facilities,
     4)  Pasture and  rangeland,
     5)  Silos,  and
     6)  Milk houses  and milking  centers.

This section will provide  direction  in  identifying the most potentially
significant nonpoint  sources associated with individual animal production
units.

CONFINEMENT FACILITIES

     Confined production facilities  are used extensively in animal
agriculture with the  exception  of the  cow-calf  and stocker segments of the
beef cattle industry  where  unconfined  production systems utilizing pasture
and range predominate.   An  animal confinement facility is one in which an
insignificant fraction,  commonly  none,  of the confined animal's nutrient
requirements are satisfied  by  grazing.   An important difference between
confined and unconfined  animal  production systems is that manure produced in
confinement facilities requires  collection and  disposal.  Estimates of the
distribution of  confined and unconfined production systems in the dairy,
beef, swine, and poultry industries  are outlined in Table D-15.

     Confinement facilities used  in  animal agriculture are of three general
types:  (1) totally enclosed,  (2) partially  enclosed, and (3) open.  In
partially enclosed facilities,  animals  have  access to uncovered areas.  Both
partially enclosed and open confinement facilities are potential nonpoint
pollutant sources due to opportunities  for manurial contaminated runoff to
enter surface waters.  Totally  enclosed facilities themselves are not

                                     450

-------






en
I***
O*l
*""*
*
,__
(O

"S
c
o


(_
01
1
C3
* — *
y
UJ
^~
GO

CO
H-
z:
LU

UJ
US


I

z:
o
i—
§*
a
o
^

i—
35
g

g
^£

O
O

I/)
UJ


i


u->
1— 1
1
o

01
ja
IO
i —
























VI
01
4->
IO
tfl

•O
Ol
4->
C
~3 **
0)
JZ
4-
O

VI
IO
Ol

"*
























VI
§
4->
Vt
t^^
^
C

Ol

10

*

c
IO
C •!-
L. JZ
Ol U
4-> < —
C- 10
o a.
•x. a.
et

4-> 13
i— C
0) IO
CO
C VI
<- c
O •!-
O IO
51





cvj ^- 1— ) ro
PJ n «!•










JZ t-
4J Ol
O
C £
IO U
4-> IO
c a.
3
O T3
IO
CO -C VI
en c 4J 01
10 o 4-> o in o in
rHCO^- O*r*- OO ^O i-H CO p— 4->
L. en i— i incOr-ti — ^
t!*
(O
iii




C
IO •»-
4-1 IO

'ai a.
a
c
« t-
4-> ai
VI JZ
10 4->
ai 3
JZ 0
3
o -o
(/> C
10
£ 01 »/>
+^ +^ c
CO  •*-
ro to 0)
^-•o t. aioooo
O**™ OO to  C CM r—t ^ ^-* •— »


ro CM co i> 3 
IO f>
Ol
JZ Ol
t- IO
O —1
z?




ro vcno m
U3 CM
i
^_>
to
tn

en
en c
C T-
•r- "O
VI r— I. i.
3 O 01 01
o j: *-> »->
JZ 4-> 4-> t- 1 (/I 4J +->
o o 01 ai 4-> ••-••-
-TJ I— I— 4-> 4-> U ••- t— r—
Ol Or— 3 C5.
4-1 T3 "O •— Ol CfJZ
•r- OIL.OIJZ  Ol > -e> vi en E ••-•!-•,-
•r- IO4->IOOI C 3XX
r- it Q.I— o. i. > 4-> ••- >, cr
en o coicoiloa vi i. -r- en en
C« O 3JZ34->O.O 3 -O i— C C
•r- 4-» 4J VI i — JZ 4-» O -I-T-
VI) — O  M«ol«4-> OJZ jzJZVtt/l
C 3 r— r- Ol t-4Jl_JZl-T- 4->-— 4->4->33
ooio cns_ O3Ovio2 o-a T-T-OO

o ai > -ovij:ai4->4->4->4->4->4J 3 -o > ••- uo-tg-ooiuJoi
O£IOOO>CL u.aia.oaioxoxojl zvi>cxc LU en en o •— » o
*«t4JOt-C; UJUI1OII 1 1 •— IIOIOCO >-IO!OOOO
a co i^ _i co
451

-------
potential nonpoint sources due  to  the  absence of opportunities for contact
between manures and elements of  the  hydro!ogic cycle.   However, the manure
disposal sites associated with  totally enclosed confinement facilities can
be sources of nonpoint pollutant discharges.

Poultry

     Totally enclosed production facilities  are used almost exclusively in
the production of eggs and meat-type chickens such as  broilers.  Cage
systems are used extensively for egg production with only a small fraction
of U.S. egg production occurring in  loose  housing-litter systems.  In con-
trast, loose housing-litter systems  predominate in the broiler industry and
are used for breeder flocks of  both  egg and  meat-type  birds.

Dairy

     All three types of  confinement  facilities are used in the dairy
industry.  Stanchions, free stall, and loose  housing systems can be operated
as either totally or partially  enclosed confinement units at the option of
the producer.  When operated as  partially  enclosed units, animals have
controlled or uncontrolled access  to a paved  or unpaved barnyard or exercise
lot which can be a potential nonpoint  pollutant source.  Where pastures are
utilized, barnyards and  exercise lots  may  be  used as milking parlor holding
areas with some resultant manure accumulation.  In situations where
barnyards and exercise lots are  located immediately adjacent to streams, the
stream may be used directly as  a source of drinking water providing a second
mechanism for water quality degradation.  Although open confinement systems
can be considered to be  potential  nonpoint sources of  pollutants, systems
with  flushing systems for manure removal are  an exception.  Containment of
the flush water also should prevent  runoff discharges  resulting from
precipitation and snowmelt.

Beef

      Most beef cattle are finished in  confinement facilities.  However,
unconfined animal production systems are used almost exclusively in the cow-
calf  and stocker segments of the beef cattle industry.  Typically, young
cattle from cow-calf and stocker operations  are fattened (finished) on high
energy  rations in confinement  facilities known as feedlots.  The large
commercial feedlots located primarily  in the  west-central and  south-western
states have been the cause  of  significant  surface water pollution  in  the
past  decade.  Commercial  feedlots  which typically have capacities exceeding
1000  animal units are considered to  be point rather than nonpoint  sources  of
pollutants.   In contrast, farmer-feeder finishing operations commonly
involve  feedlots with less  than 1000 and often less than 300 animal units.
These  smaller beef cattle feedlots are common in both  the midwest and upper
midwest  and also may be  encountered  in other geographical areas.  Although
totally  enclosed feedlots are  increasing in  number particularly  in the upper
midwest  due to improved  feed efficiency, open and partially enclosed
feedlots are  more common.   Even though these small concentrated  feeding
operations can be designated as point sources in specific situations, these
facilities are not likely to be considered as point sources in state

                                     452

-------
regulatory programs.
control programs.

Swine
They, therefore, should be  included  in  nonpoint source
     All three of the  general  types  of  animal  confinement facilities are
used in the swine industry.   Unpaved open  lots are the most common followed
by partially enclosed  paved  lots  and totally  enclosed facilities.  Although
totally enclosed facilities  are  used for  fattening feeder pigs, their use
for farrowing operations  is  more  common.   Both paved and unpaved lots
constitute potential nonpoint  sources due  to  the presence of manure
accumulations.  Location  of  unpaved  lots  for  swine adjacent to streams to
provide a source of drinking  water  and  relief from heat has not been
uncommon.  This provides  an  additional  mechanism for water quality
degradation.

Runoff Characteristics

     The pollutional characteristics of runoff from open areas of partially
enclosed animal confinement  facilities  are  highly variable due to factors
such as the type of surface  (paved  or unpaved),  stocking density, quantity
of accumulated manure, antecedent moisture  conditions, amount and intensity
of precipitation, and  temperature.   Data  for  commercial  beef feedlots
summarized by Clark et_ £l_.   (1975)  (Table  D-16)  and observations from the
study of a small beef  feeding  operation (barnlot) reported by Edwards et al.
(1972) (Table D-17) are indicative  of the  variability in runoff char-
acteristics which can  be  expected.   Gilbertson et_ a]_. (1975) have shown that
the type of runoff, precipitation vs snowmelt, also significantly affects
runoff characteristics (Table  D-18).  Thus,  it cannot be realistically
assumed that all open  confinement facilities  are equivalent in terms of
nonpoint pollution potential.

TABLE D-16.  CHARACTERISTICS OF  BEEF CATTLE FEEDLOT* RUNOFF, AVERAGE VALUES
              (Clark et al.,  1975)


Location
Bellville, TX.
Bushland, TX.
Ft. Collins, CO.
McKinney, TX.
Mead, NE.
Pratt, KS.
Sioux Falls, S.D.

Chemical
Total Electrical Oxygen
Solids, Conductivity Demand
mg/& ymho/cm mg/£
9,000
15,000 8.4
17,500 8.6
11,429 6.7
15,200 3.2
7,500 5.4
2,986
4,000
15,700
17,800
7,210
3,100
5,000
2,160

Total
Nitrogen
9,000
15,300
17,500
11,400
15,200
7,500
3,000

Total
Phosphorus
mg/Jl
85
205
93
69
300
50
47

  Unpaved except around  feedbunks  and water troughs

                                     453

-------
TABLE D-17.  SEASONAL VARIATION IN NUTRIENT CONCENTRATION OF BARNLOT RUNOFF
             (Edwards et_ al. , 1972)



Month
January
February
March
April
May
June
July
August
September
October
November
December
Yearly Average

Total
Nitrogen
68.2
60.8
47.8
32.9
30.9
14.9
14.7
8.6
30.4
37.3
29.6
40.7
34.7
Mean Concentration,
Nitrate
Nitrogen
1.7
1.9
1.3
1.2
0.5
1.1
4.4
5.8
1.6
2.6
2.0
0.9
2.1
mg/SL
Total
Phcsphrri's
8.6
6.7
5.0
4.0
4.7
3.5
3.1
1.4
13.9
10.8
7.2
5.8
6.2


Potr.ssinn
326
326
350
195
290
172
131
122
201
189
191
158
221

TABLE D-18.  DIFFERENCES  IN  PHYSICAL  AND  CHEMICAL  CHARACTERISTICS BETWEEN
             RAINFALL AND SNOWMELT  RUNOFF FROM  BEEF  CATTLE  FEEDLOTS*
              (Gilbertson  et  al.,  1975)

Parameter
Total Solids (TS) , %
Volatile Solids, % of TS
Fixed Solids, % of TS
Chemical Oxygen Demand, mg/£
Total Kjeldahl Nitrogen, mg/£
Ammonia Nitrogen, mg/Jl
Nitrate Nitrogen, mg/£
Total Phosphorus, as P, rag/A
pH
Snowmelt
Runoff
6.3
50.6
49.4
41,000
2,105
780
17.5
292
6.3
Rainfall
Runoff
7.0
42.1
57.9
3,100
854
151
10
300
7.0

 * Unpaved;  18.6  m2/animal
                                     454

-------
LAND USED FOR MANURE DISPOSAL

     Manure collection and  disposal  is  a requirement common to all confined
animal  production facilities.   Sites  used  for  manure disposal  can be sources
of nonpoint pollutant discharges  resulting in  water quality impacts such as
those (Table D-19) observed  by  Janzen et^ a]_.  (1974).  The actual  signifi-
cance of specific sites  is  , however, dependent on a number of variables.
In addition to the general  factors  affecting  runoff quality such as slope,
degree of vegtative cover,  etc.,  timing and rate of manure application also
are important.

     Frequency of manure  disposal  is  highly variable, ranging from daily to
once per year depending  on  the  availability and capacity of manure storage
facilities.  Daily manure spreading is  most commonly practiced in the dairy
industry, particularly where confinement and  free stall  stystems are used.
Although it is not typical,  some  poultry producers also  spread manure daily
as an odor control measure.  In nothern areas,  daily spreading results in
applications of manure to frozen  and  snow-covered fields.  Results of
studies such as that by  Minshall  et jal_. (1970)  have shown that winter appli-
cations of manures can significanTTy  increase  nutrient losses (Table D-20).
Studies by Converse _et ^1_.  (1975b)  and  Klausner et_ ^1_. (1976) have shown
that nutrient losses from sites receiving  winter manure  applications are
highly variable depending on the  amount of winter precipitation producing
runoff and the timing of  manure applications with respect to runoff events.

     When manure is stored,  six months  is  a common system design value
resulting in two intensified periods  of manure  disposal, commonly early
spring and late fall.  When  12-month  storage  is available, manure disposal
normally occurs in the fall.  Thus,  there  may  or may not be a seasonal
pattern of nonpoint pollutant discharges from  manure disposal  sites.

     Normally, pastures  and  cropland  are utilized for manure disposal  with
the objective of plant nutrient recovery.   Although escalating chemical
fertilizer prices have resulted in  the  more careful, use  of manures as
sources of plant nutrients,  application rates  are not always matched to
agronomic need.  Nonproductive  land  also may be used for manure disposal,
particularly where all feedstuffs are purchased or when  productive land is
not available.  Many large  poultry  farms and commercial  feedlots purchase
all feedstuffs resulting  in  the use of  nonproductive land for manure
disposal.  Under these conditions,  application  rates which are significantly
higher than those used for  productive land are  not uncommon.  Thus, the
potential for adverse water  quality  impact is  substantially increased when
nonproductive land is used  for  manure disposal.

MANURE STORAGE FACILITIES

     Manure storage facilities  are  not, in general, potential  sources of
water pollutant discharges.  Manure  stacking systems are the one notable
exception.  Open facilities  for storage of liquid manures such as earthen
lagoons are totally confined and  are  potential  sources of water pollutants
only if management practices do not  provide for containment of incident pre-
                                     455

-------









_J
<£
co
O
OH
co
i — i
Q
PU
OS
3
p?l
§
•^
PJ

H
U
>H
OS
h- 1
Q

OS
O
PL,

Q
UJ
co


Q

<^
i-J
s
o
OS
PL,

PL,
PL,
0
2
OS

PL,
0
r — \
CO •*
< ^
OH
S
1— 1 "

> i-H
H rt
i — i
i-J -P
< CD

o- c
CD
OS N
tu C
H 3

^ \ 	 /


,
CTI
I — 1
1
Q

PJ

pa

H






*
CD CD
3 -H
C CO
rt
S o
•p
"d

3 CD
CT-H
'•J "Pn
P!
<]^






un
U








-H-
CQ








•}—
<












*
CD
CD «P
H -H
3 CO
C
OJ O
-t-"
"^ "^
•H CD
r-H -H
O i-i
co p.
PH
<£






ten
U








4f
CQ








4-
<£

















o^
"\^
bO
B

*\
J_(
o
-p
CD
e
c«

rt
OH
to
o
1 — (
LO I-H i— i cn o X
• • • . •
O \D CN i— 1 O LO tO
i-H i-H i-H CN •— 1


to
o
i-H

Ol OO CNI LO tO X
• • • • •
tO 00 CNI CNI O) O tO
CNI CN LO i-H




to
o
rf O CNI O t^
X
O> CNI CN CN O> tO





to
o
rH

00 00 OO CTl r-4 X
k • • . •
TJ- I-H CNI CNI r-^ o •*
i — t CNI CN t^-



to
0
1 — 1
v0 O^ CTl vO CN X
• • • • •
\o r^ to to t^ o I-H
CN tO tO \O



to
o
1-1
CN [^ to rf LO X
• • k . •
\o ^ CNI CNI r^- LO 'd-
I-H CNI i— i r-.






*
rO
C
cfl
G to
CD • C
Q I-H O
e -H
C +J
0 O cti
bO C C 0 >
X C CD i~^ CD ^H M
X CD W) ^ bO ~-^ CD
O bO O O X W co
X H Cu X -P ,£>
I~H X "M *" — ' O CH O
OS O -H 0
o Z CD -a MH
•H i-H 4-> CD "• O
6 rt CD rt > -H
CD O ^O 4-* r^ I-H f-H ^|
XX -H c rt P,O O CD
Ort Srt fn t/) co OrCi
OQCDS-POCO g
•H| rd CD 'H rC 'H • P
MLO UQ 2 0, Q PU 2


























































CD CD
•p -p
JH -H
O W
P,
CD .-H
?H rt
tn
•P O
O PH
C to E
•H nJ
CO E T3 CD
CD rt ?H
•P CD CD -P
rt !H X w
JH -p 4-> C
CO |S
C P, O 0
O 3 -P "^
•H
•P 6 -P E
rt C
O O CD O
•H O O O
I-H *o rt ^o
P, 1 T1 1
P,0 T3 0
<; LO rt LO

* 4- -H- ton
456

-------
.-H
,— j
Oj
^
CO
s
•H
S
v — •*

P4
05
Z
5

P4
£_,
H
g

05
1— 1
Q
HH
O
C3
Z
I-H
Q

05
P4
H
Z
rH
i
UH

CO
HJ ^
CO O
CO I--
O en
.— ] i — i
H
Z •>
PJ •
i — i i — i
05 o3|
E— '
HD -P
Z 0
O
fM
1
Q
P4
CQ
H
































































rH
03
uT §
tn C
0 <


4J
C
0 rH
•H 0

3 "rt 3
Z 4S CO
0 M

rH rH
0 0
> -P

rH Oj
0 O5
•§




•P
C
0
•H
P
Z



*
e
o
•H

O cd
O
0 -H
•HP,
H P*






0
rH 0
G X
Clj E— '
vojoS ;^2S SSS ^SS
rHOCN LOrHtO rHOCN i— 1 O CM
i— t






CM O LO ^ *^l" OO ^O CTl CM tO ^1" CM
O^t-* I^CNVO r-^rHOO h-CMrH
rHOrH OOO OOO OOrH




^J" tO rH LO LO 00 ^ *sf CM CM LO f~-^
l^rHCM tOOl-5t OOrHt^ I^rH\O
OOrH ^OCM OOrH OOrH









rHCM.0 LOCMCJi WvOfO
1 1 1 CM *^" T— H p—H ^" O"> O"> tO r-4
1 1 1 rH rH <-H rH








(*0 t/J C/) t/1
3S 36 36 36
CrH3 GrH3 CrH3 CrH3
0 O -H 0 O -H 0 O -H 0 O -H
bO,Ct/} boxlw bOrCW bo ^5> 1/5
rHW^cS rH^tS rHt/^cS rH^tS
•H & o -H x; o -H x o -H ,c; o
ZQ-.O-, ZCXO, ZO.P-, ZCuO,






^
0
i P-. X X
i i nj cti
e 2 s
^




T3 T3
0 0
X 0 0
0 i/i e e
C 0 rH rH
O rH 0 0
Z P-, Pu [x.



























































































rt

Ul
0
C
G
O

\o

to
to

o

0
P
rt
rH
0
rt
J_J
nj
0
X
.
0

0 t/i
O 0
0 nj
T3 0
0 >
•H 03
rH
PL, rt
o3 0
X
0
rH 0
3 0
C fH
* 4-
457

-------
clpitation and runoff or  if  lagoon  sides  and  bottoms  are  not  properly
sealed.  Pollutant discharges from  liquid  or  slurry manure  storage facili-
ties are not common.

     The use of stacking  systems  for manure storage is  limited  to  the dairy
industry and generally to manure  produced  in  confinement  stall  housing units
where high amounts of bedding are used.   Where  stacking  sites  are  not
enclosed, both runoff and seepage can  be  significant  sources  of water
pollutants (Table D-5).   Although runoff  discharges do  not  occur from
enclosed stacking facilities, seepage  losses  may  be greater during summer
months due to reduced evaporation (Tenpas  et  aj_.,  1972).

PASTURE AND RANGELAND

     Pastures and rangeland  are used extensively  in the  cow-calf and  stocker
segments of the beef cattle  industry.  Pastures also  are  used  in combination
w/jth confinement facilities  for dairy  cattle  and  for  swine.  Although the
£erms pasture and range have different meanings,  the  distinction between the
two terms is not always clear-cut.   In general, the term  range  refers to
naturally vegetated areas of relatively low productivity  whereas plant
species in pastures are usually introduced and  maintained.  Due to higher
levels of plant productivity, animal stocking rates for  pastures are  usually
higher than those for rangeland.

     The principal areas  of  concern  relative  to water quality  impacts of
pastures and rangeland are where  animals  congregate,  where  they have  access
to streams, and wintering sites where  supplemental feed  is  provided
(Rabbins, 1978).  Grazing livestock  have  the  tendency to  congregate in
shaded and protected areas and adjacent to watering troughs,  salt  sources,
e,tc.  In addition to increased manure  accumulation, soil  compaction and
destruction of vegetative cover occurs in  these areas.   This  results  in
increases in both runoff  quantity and  pollutant concentrations  as  compared
to pther areas of pasture and range.   Soil erosion rates  also  can  be
increased.  Characteristics  of rainfall and snowmelt  runoff from grasslands
used as grazing sites and from cropland not used  for  manure disposal  (Table
D-21) show comparable pollutant concentrations.   Results  of a  study by
Sewall and Alphin, 1972 (Table D-22) illustrate the potential  water quality
impacts which can result  from heavily  grazed  pastures when  compared to
forested watersheds.

     Livestock on pasture and range  frequently  have access  to  streams
traversing these areas.   In  many  instances, the stream  is the  only source of
water for the grazing animals.  This access results in  the  direct  deposition
of feces and urine into surface waters and can  destabilize  streambanks,
increasing soil erosion.  Although  the potential  for  water  quality
impairment is clear, the  actual impact of  grazing  animals entering streams
is unclear.  In studies that have attempted to  look at  pollution from
pasture and range, (Robbins  elt £l_.,  1971  and  Milne, 1976),  the  impacts of
livestock entering streams and runoff  discharges  of pollutants  from adjacent
land have not been separated.
                                   458

-------






Q
J
CM
O
OS
(—2
Q
<;
CO
1
H
co

CX

S
OS
PL,
P-,
B-,
O
2
Pi
E-
w
O
CO
Q
<
n4
nJ
**•
PH
2
*~2
*5
os
0

co
u
hH
CO ^-s
os r^-
£2
«
K r
< r-H
Z cti
V«J
^s
§^
ell ^
c"~* ^Q
j S
^ o
^ Q
CX v_,

"
*~^
CN
1
Q

T
i — 4
?3
H















































































CM
O
rH
X

.
6

o
o
, — 1
+J
c
o
u







•> o
CO -H
P-, 4->
">x-% cd
U OS
[T ,

• H
o

o
o
rH O
rt +J
O ft
G G
CO

W
E
rH fH
Cfl O
O "HH
G -H
P-, rH
O



(/I


°<
bo
„
c
o
• H
nl
fn
C
G
0
C
O
U








3
rH O
cS JZ
4-> ft
o w
H 0
tx

1
O
2

^
I
^>
^C
2

v;
^__,


Q
O
U

Q
O
OQ




%4 G
O P1 1
C X
OS
















i— 1 LO CM Ol OO
to o o r^ rH CM
rH ^± O CM LO CT)
......
O O O O rH O






[•-- rH rH CM LO CM
o LO ^o o°> ^j~ CM
i — 1 tO rH LO





CT>
.
o ^ t~- LO oo o
rj- •— 1 CM CM CM
rH 00





o to o n- LO r--
r-- LO to r-- to \o
rH O O O O O


to to o •rf LO o>
oo oo to r~- to oo
o o o o o o


en o o o> o
CM LO CM Tj- tO
... 1
O O O rH O 1


<3- o oo CM r-^ '3-
CM CM O tO rH tO


rH \O CM 1 — 1 O^ CT^
i— i LO CM r~- ^t vo

OO rH 1 VO 1 1
rH 1 i— 1 1 1


•«• *
rH 4-) t— 1 +J rH 4-J
rH I — 1 rH rH i — 1 i— 1
rt G ctj G cfl G
c i c i c i
•H O 'H O -H O
nj C 03 C oj C
OS CO OS CO OS CO


•X fH
rrj ^ ^)
e ss i
O 3 -P 3
U T3 c/> CO
C w rt i
•> nj i/i CL, 13
t3 w ctf C +-
C 4-> Oj rH rH rt G
03 CTJ 4-1 WlrH rH fn
rH O ' — * G rt co 3
ft ctf g PL, co 4->
O T3 4-1 o rt t/)
h C rH J-( t/) r-l CS
u cs < oa ca u o-
















































































































4_>
c
G
(/)
G
ft
G

G
u
in
ctf
•H
(S
nj
C
G
r^
0
•H t/>
r-l T)
G O
ft -H
rH
G G
6 ft
•H
•(-> G
T3 -H
G 4->
•H I/)
4-i ,^ to
•H G G
O G T3
G 3 3
ft rH
 **• o
C i C
3 tO rH
* +- -H-
459

-------




, — ,
CM
t~~-
CT>
•-t
„
q
•H
t(~l
PH
i — 1
<3^

*~O
c
o3
rH
0)
CO
* — '

CO
U3
i — t
H
\ — i
i — i
H
U
H
f — i
1 — 1
, 1
w
bfl
6

»*
G
O
• H
rt
^H
P
C
0)
o

o
C_J













0
03
1 rG
O CL,
X m
P O
rH i^^
O D-t



i C
0) (D
P 50
03 O
^ fH
P P
•rH *rH
z z





X
rt
Ci
LO
03 -
O 13
•H C
e 03
£>


to to to to
o o o o
i-H i-H i-H T— 1

X X X X

LO r-~ o oo
to LO
i-H i-H tO i— I




LO OO
O O i— 1 CM
• • • •
O O I-- r-H







LO "3-
O O LO rH
• • . .
o o <3- LO














LO \O OO t^
• • . .
CM CM tO ^O
rH i— 1




* *
  >
rH !H 03 03
O O O ID
tL, PL, a: x




































































CJ
i — i
p
P
03
^J

X
^_i
•H
n3
Q
*
460

-------
     In areas where dormant  vegetation  is  not  adequate  for animal  main-
tenance, winter pasture or range with supplemental  feeding of hay  and
forages is used in cow-calf  and stocker  operations.   Animal  densities in
wintering areas are significantly higher than  those  typical  of grazing
operations resulting in more concentrated  accumulations  of manure  and
increased concentrations of  pollutants  in  rainfall  and  snowmelt runoff
(Table D-23).  Results of a  study of the water quality  impacts of  a live-
stock wintering operation by Milne  (1976)  showed  no  significant impact on
chemical water quality parameters.  Counts  of  fecal  coliforms and  fecal
streptococci, however, increased significantly at  the location of  greater
livestock activity as compared to upstream  counts.   The  contradictory
results of these two studies are indicative  of the  site-specific  nature of
pasture and  rangeland runoff water  quality  impacts.

SILOS, MILK  HOUSES, AND MILKING CENTERS

     Silages are widely used as feedstuffs  for dairy cattle and also may be
used as roughage for feeder  steers.  Therefore, the  use  of silos  is limited
to dairy and beef cattle production.  Silage liquor  discharges (Table D-12)
are normally limited to the  first six to eight weeks of  the ensiling
process.  In that silages are made  only  in  the summer and early fall, water
quality problems associated  with silage  liquors are  limited to this period
of the year.

     Both milk houses and milking center wastewaters (Tables D 8-11) are
generated daily through the  year.   These wastewaters can  be discharges
directly to  streams, to roadside ditches,  or to unmanaged land disposal
sites.  When the land disposal sites are not managed properly, surface
runoff and seepage can transport the pollutional  constituents of  the applied
wastewaters to adjacent surface waters.

SUMMARY

     The potential significance of  the  six  sources  of nonpoint pollutant
discharges associated with animal production activities  are summarized in
Table D-24.  Manure disposal sites  are  potential  sources  of water  pollutants
common to all segments of animal agriculture.   The dairy  farms have the
greatest number of potential pollutant  sources and  poultry farms  have the
least.

     The actual significance of the possible nonpoint sources of  water pol-
lutants discussed in this section is dependent on  more  than the presence of
animals or manure.  Factors  such as proximity  to  surface  waters and manage-
ment practices also can have a significant  influence on  the potential water
quality impacts and the need to implement  BMPs.
                                     461

-------




*
^>_J
H
i — i
i-J
2j
c/

OS
UJ
H

3=
PH
PH
0
z

ai

•z.
o
UJ
pj
H

CJ

[-j^
UJ
UJ
CQ
P-,
O

CD
•z.
h— 1
Q
UJ
UJ
PH

UJ
H

h- 1
S
Q
^ ^
CD 01
2 r^
I-H O1
N] r— 1

S CD
CO f-i
CD
PH 4->
O w
CD
H -C
G 0
< -H
OH 4T,

CN
1
Q

UJ

O3
^
f_






















































































t/1
^3
^-|
O
c~j
PH
U)
O °^
a to
e
r-H
cd
4^
O
H
DO
f-i C
CD -H
4-} *^
C CD
•H CD
S PH



f-i 13
CD CD
E N
g cd
3 f-i
CO CD



4-
C
CD
bO
O
fn
4->
2 \
^-i E
cd
^H:
CD
C
•H
2
bO
f-i C
CD -H
4-> 13
C 0)
•H CD
IS tL,


fn 13
CD CD
E M
E cd
3 f-i
CO CD




DO
s
CD
DO
O
f-l
4->
•H
2 °*
O bO
•H E
s
cd
DO
0
f-i C
CD -H
+-> 13
C CD
•H 0)
^ PH



f-i 13
CD CD
E ^
E cd
CO CD






*.
pj
0
rQ
f-l
cd
U
O ^
• H bO
pi e
cd
DO
H
o

bo
fn C
CD -H
4-> T3
C CD
•H CD
S tL,



f-l T)
CD CD
e N
E cd
3 f-i
CO CD






13
O
•H
fa
CD
a,



OO i— 1 vO ^±
• • • .
r— 1 i— 1 O i— 1






to \D to to
• • • •
r— 1 O I — 1 O







00 CM t^ LO
• • • *
i— 1 CN CN O1





O> LO r~- o
• • • •
CN .—1 O rH








\O CN rf \O
• • • •
O "3- CN CN
i— 1




tO CN vD <3"
. • • •
tO i— 1 O r— 1







CN ^t rH O
• • • •
I-H LO CM r~
CN OO -"d" vO





OO 00 CN \O
• • • •
OO LO CN OO
tO to CN




4-) fH 4-. fH
CJ CO, CJ PH
O < O <

1 1 1 1
^t LO LO VD
X I — • r> t — X r — £* ^
cdoi oc7> cdo^ 001
Si— i 2:1—1 Si— i 2 i— i



CM

i — I






CTl
.
O







O

^3-





LO
•
r-H








O

LO





\o
•
i— i







01
•
to
LO





"3-
•
vD
T^






CD
bO
cd
fH
CD
^>
<;










































































































































C
CD
bO
O

4_)
•H
2

CD

TO
fH
•H
2

+

CD
4->
•H
f-l
4->
• H
2
cd
• H
C
O 0
•H E
43 E
0 <

* +-
462

-------
TABLE D-24.  SIGNIFICANCE OF POTENTIAL NONPOINT SOURCES OF WATER POLLUTANTS
             ASSOCIATED WITH ANIMAL AGRICULTURE
Source Category
Poultry    Dairy
Swine
Beef
Production Facilities
Land Used for Manure Disposal
Manure Storage Facilities
Pasture and Rangeland
Silos
Milk Houses and Milking
Centers
+ A potential nonpoint source
0 System dependent
- Not a potential nonpoint source
* Not applicable
                                    463

-------
                                  SECTION  5
              COMPARISON OF THE POLLUTION  POTENTIAL  OF  NONPOINT
                 SOURCES ASSOCIATED WITH ANIMAL AGRICULTURE
     The financial and technical  resources  available  to  address  nonpoint
source water quality problems resulting  from  agricultural  activities  are not
limited.  Thus, there is the need to  focus  attention  on  those potential
sources of pollutants which have the  greatest  impact  on  water quality.   In
allocating program resources, the first  step  is  to  determine which agricul-
tural  activities - irrigated crop production,  nonirrigated crop  production,
or animal production - are most critical  with  respect to an identified water
quality problem.  If, for example, animal agriculture is identified as  the
most significant contributor of pollutants, the  next  step is to  locate and
address those sources which are of the greatest  significance.

     The purpose of this section  is to compare the  concentrations  of  con-
stituents in typical discharges from  the various  animal  agriculture nonpoint
source categories.  The objective is  the identification  of those pollutant
source categories which should  receive priority  in  animal  agriculture best
management practice (BMP) implementation programs.

METHODOLOGY

     The comparisons which follow were developed  using data from several
studies.  Ranges of values from selected studies  rather  than averages of all
reported values were used for two reasons.  First,  the intent was  to  reflect
typical situations with respect to management  practices.  Analysis of avail-
able data showed that for certain source categories,  average values were not
typical values due to the somewhat limited  data  base.

     Second, data from a single study in each  source  category were compiled
to eliminate the effects of possible  differences  between separate  studies.
Thus, it was necessary to identify studies  for each source category in which
all pollutant parameters of interest  were measured  and reported.  Although
chemical oxygen demand  (COD) data are more  commonly reported, five-day
biochemical  oxygen demand (BOD5)  was  used in  place  of COD for the  comparison
due to the lack of COD data for silage liquors.   This factor limited the
number of studies which could be  used as data  sources, and necessitated the
use of two data sources for open  confinement  areas  due to the absence of
total  phosphorus (TP) data in the study  used  as  the source of BOD5 values.

     Initially, the intent was to compare the  nonpoint source potential  of

                                      464

-------
open confinement facilities for dairy  cattle,  beef  cattle,  and swine in
order to characterize the relative significance  of  such  sources  as a func-
tion of animal species.  However,  little  information  exists on the charac-
teristics of runoff from open confinement  facilities  for dairy cattle and
swine.  Therefore, this comparison was  not  possible,  and it was  necessary to
use data from beef cattle feedlot  studies  as  generally  indicative of runoff
characteristics for all open confinement  facilities.

     The comparisons were developed  using  pollutant concentrations, even
though there are limitations to this approach.   Quantities  rather than
concentrations of pollutants are discharged  and  are more indicative of
potential water quality impacts.   The  use  of  areal  pollutant  yields,
quantity per unit land area per unit time,  is  inappropriate however, for
nonpoint sources such as milk houses,  milking  centers,  manure storage
facilities and silos; pollutant discharges  in  these cases are not the result
of land-based activities.  In order  to  include these  potential  nonpoint
sources, the comparisons were based  on  pollutant concentrations.

SOURCE CATEGORY COMPARISONS

     The results of the selected studies  are  summarized  in  Table D-25.  The
comparisons of significance using  BOD5, total  nitrogen  (TN),  and  TP concen-
trations as parameters are presented in Figures  D-l,  D-2, and D-3.  Data for
fecal  coliform and fecal  streptococci  concentrations  and ratios  are
summarized in Table D-26.

     When BOD5, TN, and TP concentration  ranges  are compared, animal agri-
culture pollutant source categories  appear to  be divisible  into  two distinct
groups, "concentrated" and "diffuse" nonpoint  sources.   Those nonpoint
sources producing high BOD concentrations,  generally  greater  than 300 mg/£,
are often confinement facilities,  milk  houses, milking  centers,  silos, and
manure stacking facilities.  Manure  disposal  sites  and  pastures  and
rangeland produce lower BOD concentrations  and form the  diffuse  nonpoint
group.  Total  nitrogen and total phosphorus concentrations  in runoff from
manure disposal  sites and pastures and  rangeland also are substantially less
than those associated with the concentrated nonpoint  sources  (Figures D-2
and D-3).  These general  groupings also appear applicable to  the potential
for microbial  contamination based  on indicator organism  concentrations
(Table D-6).

     Although pollutant concentrations  in  runoff from diffuse nonpoint
sources are substantially lower than concentrated nonpoint  sources, total
quantities of pollutants discharged  from  these diffuse  sources are likely to
be greater.  This is due to the greater number and  larger area of discharge
of these potential diffuse nonpoint  sites  in  comparison  to  open  confinement
facilities, milk houses,  etc.  The immediate  water  quality  impacts of
discharges from concentrated nonpoint  sources  can,  however, be greater due
to the higher concentrations of pollutants.   Even if  a  dissolved  oxygen sag
is not observed, the water quality impacts  of  discharges from concentrated
nonpoint sources are more likely to  be  reflected in  increased receiving
stream concentrations of BOD5, TN, TP,  etc. than those  from the  diffuse
nonpoint sources.

                                     465

-------
-H  O
flj  JZ. ^
<->  ao.
     /«
   O 'Jr.
   I- H
     •
eo  0)
U O /-^
                                   466

-------
Figure D-l.   Comparison of 5-day biochemical oxygen demand concentrations in
             discharges from in discharges from various animal agriculture
             nonpoint sources.
70POO




iopoo

__
\
1
«
i
o

2
g
XYGEN
O
_i
o
^
BIOCHEi

100

K
UJ
UJ
n 5
*
OL
UJ
z
8
o
5

U *
CO f~"
&
_J
o
UJ
UJ
u.
UJ
a.
o

tc. l_
UJ
UJ
5
UJ
i
_i
Z
















—














—





1000
UJ
(9
a.
u
UJ
CO
UJ
K
Z
^
Z
o
8
a: * 100
O CO
o
j
UJ
<
^ j
CO

10

s

CO
1
CO
5
u
a:
z
Z





0
uj 5
1 ^
i o
DD
                                    467

-------
Figure D-2.   Comparison of nitrogen concentrations in discharges from
             various animal agriculture nonpoint sources.
0000




>^
o»
6 1000

-------
Figure D-3   Comparison of phosphorus concentrations  in discharges  from

             various animal agriculture nonpoint  sources.
600


400






200




5C
O»
in
§ '00
i

0.
j
»-

90








D
V)
t-
o
*J
0
UJ
UJ
u.
z
UJ
0.
o


















"™





.^
a:

^
UJ
1
UJ
en
i
^
_i
i







c

UJ
I
or

h-
UJ
U

(9
z
^
_l
z









—














—




















o:

















D
UJ
(9
a.
UJ
UJ
en
UJ
a:
z
^j ^^
O ^
O z
-1 IJ °
5 1
en
                                             60
                                             40
                                             20
                                             1.0
                                            0.7
                                            0.9
                                            0.3
                                                    uj
TF'


2
(A

O


UJ
K.
                                                        V)
                                                        UJ

                                                        a:
                                                        (O


                                                        0?
                                                             O
          _
          a

          S
          u
           20
                                    469

-------
CJ
0 I
U I-H
O OS
H U
OH <
P-1
OS -J

co s
rH
{ "] p?»
*H* !
0 0
PH OS
I-H PH
,-J
O CO
U W

,-4 OS
33
w u
BH CO
h-H
« Q
CO
2 Z
CO i-H
Z co
<2 o
U I-H
OS H

c2
OS
O M
H U
< U
U O
HH U
Q O
Z H
1— 1 OH
PnOH
O E—*
CO
CO
2 >-J
0 <
i-H U CO
C_H ff] m
< BH C_)
OS OS
H O 3
Z H O
pq CO
U S
Z 2 H
O O 2
U PH I-H

PH 1-3 OH
O O Z
U O
Z Z
O "J
CO < J
I-H U <
OS H OS
OH H
2 a J
0 Z 3
u < u


.
^o
CM
i
Q

UJ

CO

[_





a>
o
c

ft
0
rH
+->
CO
""•^
g
,0
4H
•H
1— 1
o
u












•
l—t
6

0
o
rH

rH
0)
ft

•
O
Z













•H
0
0
o
0
o
•p
p 1
CO
r4
4_)
CO
rH
rt
o
0
p-



g
^
o
*4H
•H
i— 1
0

rH
rt
o
co
PH




X
f-t
o

(U
^_)
rt
o

(U
o

rj
O
co
rH 1 • rH
rt| rH «
rt
O -P -P
OO   CO
rH X XI
co to t/)
r^ C 3
13 t/j -H Xi
C rt •— i XI rH C ^J-
rt u r-~ Xi r-- r-i i^»
rH o a> o en o en
CQ 2 rH OS rH Q rH










rH
to
t^ rH
« •
to i
1 1 1 rf
\O 1 1 O
0 0










r^-
t^ o
O rH
rH X
X r-
o
o
tO rH
1 III
LO 1 I rt
0 0
l—t rH
X X
a> u~>
• •
LO tO





l^ tO LO
o o o to
1— 1 rH rH O
X X X rH
to 00 LO X
• * • «3"
CM tO tO rH
1 III
\D to rt to
O O O O
i-H rH rH rH
X XXX
CM rH O rt
• • • •
CM l—t tO rH




i-H
t-t rt
co to
•P O
C ft
CO r-l tO
CJ CO -H
4-> Q TJ
oo rt co c
C S d> rH rt
•H CO fH t/1 3 rH
r^ -P 3 CO P ft
i— 1 to C 4-1 t" O
•H rt .rt *H rt r-l
2 S: S co O- u
470

-------
     While water quality  data  should  be  useful  in identifying pollutant
discharges from concentrated  nonpoint  sources,  distinguishing between water
quality impacts of  runoff  discharges  from manure disposal  sites, pastures
and rangeland, and  cropland using  water  quality data will  be more difficult.
This is particularly true  for  pastures  and rangeland versus cropland.  As
shown in Figures D-l, D-2, and  D-3,  concentrations  of BOD5, TN, and TP in
pasture and rangeland runoff  and cropland runoff will be similar.  Sediment
losses from pasture and range  areas  should,  however, be lower than those
from cropland, particularly in  situations involving row crops.

SUMMARY

     These comparisons suggest  that  the  concentrated animal agriculture non-
point source categories should  receive  priority in  the allocation of
available financial and technical  resources  for BMP implementation with the
next priority given to land used for  manure  disposal.  As  possible sources
of nonpoint pollutant discharge, pastures and rangeland could have still
lower priority until Mater quality problems  associated with land used for
irrigated and nonirragated crop production are  effectively addressed.

     The objective  in developing these  comparisons  was to  establish which
source caregories were likely  to have  the greatest  water quality impact  and
what the priorities might  be  for allocating  resources for  addressing
nonpoint water quality problems.   Care  should be taken in  applying these
generalizations to  specific situations.   A number of site  specific factors
such as location relative  to  surface  waters  of  concern, management practices
employed, etc. must be considered  before the relationship  of any potential
pollutant source to an identified  water  quality problem and the need to
implement BMPs can  be determined.
                                     471

-------
                                  SECTION 6
                             ANIMAL AGRICULTURE
                       POLLUTION CONTROL ALTERNATIVES
     Once it has been determined that an observed water quality  problem  is
related to animal agriculture, and the physical source or  sources  of  the
responsible pollutant discharges have been identified, it  is  then  possible
to select a practice or combination of practices that will effectively
address the problem.  Due to variables such as established water quality
goals, availability of capital, management capabilities, physical
constraints, etc., the selection of effective  practices is a  site  specific
process.  There  is no pollution control practice or combination  of practices
that can be designated as most suitable for each of the animal agriculture
nonpoint pollutant source categories previously identified.   The purpose of
this section is to identify and discuss available pollution control
alternatives for each pollutant source category.

OPEN CONFINEMENT FACILITIES

     There are several available options for addressing nonpoint water
quality problems associated with open confinement facilities.  Runoff
collection systems have been used extensively  and effectively  for  commercial
feedlots to control polluted runoff.  The level of pollution  control
provided by runoff collection systems is dependent on the  storm  frequency
used for design  of the storage pond.  If, for  example, the design  objective
is to provide total containment up to a 25-year, 24-hour storm event, pol-
lutant discharges and resultant water quality  impacts will be  minimal.   This
level of runoff control has been designated as best available  technology
economically achievable for feedlots which are point sources  or  pollutant
discharges.

     Although runoff collection systems can be highly effective  in reducing
pollutant discharges, the land area for ponds  and associated  collection
channels and settling basins can be significant and may not be available
when confinement facilities are located immediately adjacent  to  streams  or
major drainage channels.  In addition to the possible loss of  productive
land, runoff collection systems impose a continuing labor  requirement for
maintenance and dewatering.  Normally, dewatering is accomplished  by  surface
or spray irrigation of accumulated runoff on adjacent pasture  or cropland.
Periodic removal of settled solids from settling basins or collection ponds
also is necessary.  Detailed information concerning runoff collection
systems for open confinement facilities, including design  parameters, is


                                   472

-------
available from sources such  as  Shuyler  et  al.  (1973), Miner and Smith
(1975), and Midwest Plan Service  (1975).

     Commonly, a substantial  fraction of  the  surface runoff from an open
confinement facility originates  from  sources  outside the facility such as
upland areas and from  roofs  of  adjacent  buildings.   Thus, practices such as
constructing diversion terraces  to  intercept  surface runoff from upland
areas and installing gutters  and  leaders  to  collect and divert roof runoff
can significantly  reduce the  volume of  contaminated runoff and the
quantities of pollutants that must  be controlled  or that are discharged.
Practices to reduce runoff volume  should  be  used  in combination with runoff
collection systems to  reduce  storage  capacity  and dewatering requirements.

     Diverting upland  runoff  and  installing  gutters may, in many instances,
reduce pollutant discharges  from  open confinement facilities to levels that
will permit attainment or maintenance of  desired  water quality goals.  When
this does not occur, additional  reductions in  pollutant discharges, particu-
larly particulates, may be obtained by  combining  practices to control runoff
volume with grassed outlets  or  vegetated  buffer strips.

     In situations where runoff  reduction  is  not  sufficient to decrease
pollutant discharges to a level  compatible with established water quality
goals, and physical constraints  preclude  construction of a runoff collection
system, conversion of  open confinement  facilities into totally enclosed
production units may be an appropriate  pollution  control alternative.  This
approach may be at least partially  justified  in certain climatic regions by
improvements in feed efficiency,  reduced  labor requirements, and improved
working conditions.  Another  option is  to  relocate  an open confinement
facility to an area hydrologically  remote  from streams and major drainage
channels, assuming that a suitable  site  is available.

LAND USED FOR MANURE DISPOSAL

     Land used for manure disposal  is a  potential nonpoint pollutant source
common to all confined animal production  activities.  Water quality problems
related to manure  disposal sites  can  be  most  effectively addressed by
management practices that reduce  the  probability  of pollutant transport
during runoff events,  such as:

     1)  Elimination of excessive  application  rates,
     2)  Timing of manure applications,
     3)  Soil incorporation  of  manure,  and
     4)  Other practices.

Application Rate

     Application rates of manures  to  pasture  and  cropland should be based on
plant nutrient content and agronomic  need  using soil test results and
estimates of crop  residue nutrient  content and uncontrollable nutrient
losses.  Both nitrogen and phosphorus requirements  should be considered in
determining appropriate application rates.  Applying manures to satisfy crop
nitrogen requirements  may result  in overapplication of phosphorus.  A

                                      473

-------
detailed methodology for  determining  manurial  application rates that will
minimize pollutant losses  has  been  outlined  by Gilbertson et al. (1979).

     Disposal of manure on  unproductive  land should be avoided particularly
due to underutilization of  plant  nutrients  which remain available for trans-
port via surface runoff.   Where daily manure spreading is practiced and
cropping patterns preclude  the use  of productive land for manure disposal
during the growing season,  plant  nutrient  conservation may justify manure
storage as a production as  well as  a  pollution control practice.  When all
animal feedstuffs are  purchased,  use  of  productive land on adjacent farms
appears to be the only feasible pollution  control  alternative available.

Timing of Manure Disposal

     Ideally, applications  of  manures as well  as manufactured fertilizers
should coincide with crop  needs to  maximize  plant  nutrient utilization and
reduce the potential for  runoff losses.   Thus, utilizing manures as side-
dressing for row crops and  top-dressing  for  hay crops and pastures to the
greatest extent possible  can be highly desirable with respect to both
nutrient utilization and  pollution  control.   Although top-dressing of hay
crops and pastures with manures is  common,  equipment to apply manures as
side-dressing for row  crops  is not, at present, commercially available.
When it is necessary to apply  manure  before  planting, application should be
scheduled to coincide  as  closely  as possible with  the commencement of
tillage operations recognizing possible  labor and  equipment conflicts.

     Spreading of manure  on  frozen  and/or  snow-covered soil is generally
recognized as a practice  that  should  be  avoided particularly due to pollu-
tant losses associated with  critical  runoff  events.  Thus, manure storage is
commonly cited as a pollution  control  practice because winter manure-
spreading can be avoided.   Disposal of stored manure particularly in the
spring can, however, create  labor and equipment conflicts and produces
intense periods of manure-spreading which  can negate possible water quality
benefits if a significant  runoff  event occurs.

     The timing of manure  applications should be based on local weather
patterns as delineated by  temperature and  precipitation records.  This will
permit identification  of  time  periods in which the probability of runoff
events, particularly critical  events  such  as rapid snowmelt, is high.
Months generally suitable  for  manure  disposal  for  various climatic regions
are outlined in Table  D-27.

     The establishment of  field priorities  for manure disposal  (Walter et
al., 1978) is a possible  alternative  to  construction of storage facilities
to  reduce water quality impacts related  to  winter  manure spreading.  The
basis of this approach is  the  ranking of available manure disposal sites
with respect to pollutant  discharge potential  using criteria such as
location relative to streams and  major drainage channels, slope, nature of
vegetative cover, etc.  Then a manure-spreading schedule can be developed to
avoid critical areas during  periods of high  rainfall or snowmelt runoff
event probability.
                                     474

-------
c
o
P
to
0

•H
CJ

CO
2
O
i — i
O
a
u
t— H
H

S
i— i
i— 3
u

co

o
h- 1
OS

^>

OS
o

T
1— ^
co
o
OH
co
1 — 1
Q
1

*Zi

c
o
•H *^
bo T-t
0 f-t
os <:
O rH
•H O
P O
OJ CJ
G PO
•H -H
rH S
U 3




•H
^_f

f-i G
3 to
c! O
03 PH
S


i "c
oS 3
0 O
>- rH



i 13


0 O
>- rH




1 T3
rH C
03 3
0 O
>* rH




X rH
O -H
rH to
nS QH
S <





rH
•H
to X
PH 03



rH
•H
to X
PH 03
< S



X C
OS 3
S 1-5



0
II









""rH,
•H
rH
O
co



























.
• -p •
bO PH P
300
< CO O






. •
+•* r-*
0 0
0 2




. .
P >
0 0
0 2


•
PH

co


•
• P
W) PH
3 0
< co















rH C
oS 3
0 O
>H rH



1 T3
rH C
oJ 3
0 O
>- rH




I 'O
rH C
o3 3
0 O
>- rH




I 13
rH C
os 3
0 O
>- rH





rH
• rH • +J • •
^H X bO PH 4-> >
PH OS 30 O O
< S < CO 0 2

<-]
bO
X 3
O O •
to to 0
03 rC 0
S P Q



•H 0 X • +J •
to X C --i bo PH P
PH 03 3 3 3 0 O
<: 2: *-s 1-5 < to o

•
0 X • -P
X fi rH bO PH
oi 3 3 3 0
S 1-5 1-5 < co








X

rH
3
rH
co


rH C
03 3
0 O
>- rH



i ""O
rH C
OS 3
0 O
>- rH




1 13
to C
oS 3
0 O
>- rH




1 T3
rH PI
oi 3
0 O
>- r,



rC
bo
X 3
0 O •
to to 0
03 X 0
S 4-> a

X
bO
rC 3
0 O •
!H to o

2 -P Q



0 4-)
^^ rH pH
oS 3 0
S 1-5 co


0 X
X C rH
oS 3 3






/ — \
4-1
13 'H
•H 0
3 C
cr 3
•H rH
J ^— '

























































•
• P
3 0
<; co













475

-------
Soil Incorporation of Surface Applied Manure

     Runoff losses of pollutants  from manure  disposal  sites  also can be
reduced by subsurface application  (injection)  or  immediate  incorporation by
plowing or discing.  In addition  to water  quality benefits,  these practices
can reduce ammonia volatilization  losses 
-------
vegetation, grazing systems,  and  geographic  regions is available from a
number of sources such as Ensminger  (1970).

     Winter pastures and areas  of  animal  congregation, such as shaded and
protected areas, and around watering  troughs,  salt sources, etc. should be
relocated to areas hydrologically  remote  from  streams  and major drainage
channels whenever possible to minimize  water quality impacts associated with
resultant manure accumulations.   Manure accumulations  around watering
throughs and salt sources can be  reduced  by  periodic relocation.  At sites
where significant manure accumulations  are  present, tillage, particularly
discing, can be used to break up,  distribute,  and incorporate manure into
the soil.  Accumulations of manure  also can  be removed periodically and
applied to cropland or more evenly  on pastures.

     Although animal access to  surface  waters  should be minimized, the
necessity of total stream fencing  as  a  pollution  control  practice is
unclear.  It may be possible  to  achieve desired  water  quality goals by
restricting animal access to  streambank areas  where destabilization can
occur and by reducing the need  for  animal  congregation in streams to obtain
relief from heat and insects.   The  latter  can  be  encouraged by providing
shade and using insecticides.   These  alternatives should receive careful
consideration, particularly for  range areas, when it is necessary to develop
alternative sources of drinking  water as  a  consequence of stream fencing.

SILAGE LIQUORS

     Studies examining the impact  of  silage  liquor losses on feedstuff value
have shown that moisture content  control  can effectively reduce both the
volume and duration of silage liquor  seepage.   At moisture contents of 70
percent or less, silage liquor  seepage  is  essentially  nil (Wittwer et al.,
1958 and Moore, 1962).  Due to  losses of  feedstuff value via seepage, rec-
ommended moisture content values  for  crops  to  be  ensiled range from 60 to 70
percent (Moore, 1962 and Ensminger  and  Olentine,  1978).  Thus, water quality
problems associated with silage  liquors can  be simply  and effectively
addressed by employing sound  ensiling practices.

     It should, however, be recognized  that  precise control of silage crop
moisture content is not always  possible.   Thus,  provisions for silage liquor
collection and disposal may be  warranted.   Most  silos  are constructed with
drainage systems which will facilitate  collection of silage liquors.  When
seepage occurs through silo walls,  diking  to collect silage liquors and
divert surface runoff will be necessary.   Due  to  the plant nutrient content
of silage liquors (Table D-12),  productive  land  should be used for
disposal.  Where available, liquid  manure  storage facilitates and collection
ponds for manure stacking facilities  can  be  used  to store collected silage
liquor.

MILK HOUSE AND MILKING CENTER WASTEWATERS

     Water quality problems related  to  milk  house and  milking center waste-
waters differ from typical nonpoint  water  quality problems in that pollutant
discharges can be independent of  runoff events.   Water quality problems


                                     477

-------
associated with these waste  streams  are  best  addressed by collection,
storage, and/or treatment prior to disposal.   One  alternative is combined
storage and disposal of these wastewaters  with liquid  manure.  Although this
approach has the advantage of simplicity,  manure  disposal  requirements are
increased and manure storage capacity  is  reduced  due to increased volume.

     A second alternative is to use  facultative lagoons or ponds for treat-
ment and storage.  Lagoons and ponds have  been demonstrated to be an effec-
tive and practical approach  for milking  center wastewater management and
also appear applicable for milk house  wastewaters.   When designed and
managed properly, these structures provide nuisance-free storage as well as
waste stabilization.  Labor  and management requirements are minimal, and a
source of water for fire protection  is available  possibly reducing fire
insurance costs.  Design parameters  for  milking center wastewater lagoons
have been established and are available  (U.S.  Department of Agriculture,
1977).

     Other options for management of milk  house and milking center waste-
waters include direct controlled  land  application,  use of vegetative
filters, and controlled stream discharge.   In  climatic regions where freez-
ing problems will not be encountered,  controlled  land  application of these
wastewaters by either spray  or surface irrigation  on a daily basis is
another possibility.  If application rates are based on soil infiltration
capacity, runoff during irrigation and associated  pollutant transport can be
avoided.

     For situations where total abatement  of  pollutant discharges is not
necessary to attain desired  water quality  goals,  or implementation of the
previously discussed control practices is  not  possible, use of vegetative
filters to reduce quantities of pollutants discharged  should be considered.
The effectiveness of vegetative filters,  particularly  with respect to
removal of organic solids, nitrogen, phosphorus,  and microorganisms, has
been demonstrated in a number of  studies  involving  municipal and other
agriculturally related wastewaters.  Results  of these  studies suggest that
this pollution control approach also should be applicable to milk house and
milking center wastewaters.  Data to characterize  performance and to
establish design and operating parameters  is,  however, presently
unavailable.

     A final alternative for addressing  water quality  impacts related to
milk house and milking center wastewaters  is  controlled stream discharge.
Although quantities of pollutants discharged  will  not  be reduced, the
impacts of slug loads associated  with  milking events can be eliminated  by
uniform discharge throughout the  day.   This approach is recommended only
when all other alternatives  are not  feasible.

SUMMARY

     The selection of pollution control  practices  to address water quality
problems related to animal production  activities  is a  relatively simple
task due to the limited number of available options (Table D-28).   In
considering available options, effectiveness  with  respect to desired water

                                     478

-------
  quality goals,  costs,  particularly  private  capital  costs,  and  labor  and
  management  requirements  should  receive  careful  consideration.
TABLE D-28.  SUMMARY OF SUGGESTED PRACTICES TO ADDRESS WATER QUALITY PROBLEMS
             ASSOCIATED WITH ANIMAL PRODUCTION ACTIVITIES
Open Confinement
Facilities
Land Used For
Manure Disposal
Manure Stacking
Facilities

Pasture and Rangeland
Silage Liquors
Milk House and Milking
Center Wastewaters
Runoff collection, runoff diversion, vegetative
practices - grassed outlets and buffer strips,
enclosing open facilities, relocation.

Use of application rates based on agronomic
need; timing of manure application - side-
dressing and top-dressing, avoidances of time
periods with high runoff probability, storage,
and establishment of field priorities; injection
or immediate soil incorporation; and vegetative
practices - field borders and buffer strips.

Retention ponds
Use of recommended stocking rates; discourage
animal congregation in critical areas includ-
ing streams; breakup, distribution, and incor-
poration or removal of manure accumulations;
and restriction of animal access to highly
credible areas.

Use of recommended ensiling practices and col-
lection of seepage from silos.

Combined storage and disposal with liquid manures,
lagoons and ponds, controlled land application,
vegetative filters, and controlled stream dis-
charge .
                                     479

-------
                                 REFERENCES

American Society of Agricultural Engineers.  1979.   Manure  Production  and
     Characteristics.  ASAE Data:  D384.   In:  Agricultural  Engineers  Year-
     book.  American Society of Agricultural Engineers,  St.  Joseph,
     Michigan,  p. 446.

Anonymous.  1963.  Waste Waters from  Farms,  Notes  on Water  Pollution,  No.
     17.  J. Inst. of Sewage Purification  62:182-185.

Berryman, C.  1970.  Composition of Organic  Manures  and  Waste  Products Used
     in Agriculture.  N.A.A.S. Advisory  Paper  No.  2.   Ministry of Agricul-
     ture,  Fisheries, and Food.  London.

Bland, R.R.  1980.  Facultative Treatment  Ponds  for  Milking  Center Waste-
     water.  Unpublished M.S. Thesis,  Cornell  University,  Ithaca, N.Y.
      230p.

Chichester, F.W., R.W. Van Keuren, and J.L.  McGuiness.   1979.   Hydrology and
     Chemical Quality of Flow from Small  Pastured  Watersheds:  II. Chemical
     Quality.  J. Environmental Quality  8(2):167-171.

Clark, R.N., C.B. Gilbertson, and H.R. Duke.   1975.   Quantity  and Quality  of
     Beef Feedyard Runoff in the Great Plains.   In:   Managing  Livestock
     Wastes.  American Society of Agricultural Engineers.   St. Joseph
     Michigan,  p. 43-436

Converse, J.C., C.O. Cramer, G.H. Tenpas,  and  D.A.  Schlough.   1975a.
     Properties of Solids and Liquids  from Stacked  Manures.   In:   Managing
     Livestock Wastes.  American Society of Agricultural  Engineers.   St.
     Joseph, Michigan,  p. 432-436.

Converse, J.C., G.D. Bubenzer, and W.H.  Paulson.   1975b.   Nutrient Losses  in
     Surface Runoff  from Winter  Spread Manure.   Paper No.  75-2035.  American
     Society of Agricultural Engineers,  St.  Joseph,  Michigan.   10 p.

Dornbush, J.N., J.R. Anderson, and L.L.  Harms.   1974.   Quantification  of
     Pollutants in Agricultural  Runoff.   Environmental  Protection Technology
     Series Report No. EPA-660/2-74-005.   U.S. Environmental  Protection
     Agency, Washington, D.C.   149 p.
                                      480

-------
Edwards, W.M., E.G. Simpson, and M.H.  Frere.   1972.   Nutrient  Content of
     Barnlot Runoff Water.  J. Environmental Quality  1(4):401-405.

Ensminger, M.E.  1970.  The Stocksman's Handbook, 4th  Ed.   The  Interstate
     Printers and Publishers,  Inc., Danville,  Illinois.

Ensminger, M.E. and C.G. Olentine, Jr.  1978.   Feeds  and  Nutrition  -
     Complete, 1st Ed.  The Engminger  Publishing Co.   Clovis,  California.

Federal  Register.  1974.  Effulent Guidelines  and Standards,  Feedlots Point
     Source Category.  Vol. 39, No. 32.  U.S.  Government  Printing  Office,
     Washington, D.C.  p. 5706-5710.

Federal  Register.  1976a.  Proposed Rules, Agricultural Activities,  National
     Pollutant Discharge Elimination System.   Vol.  41,  No.  36.   U.S.  Govern-
     ment Printing Office, Washington, D.C.  p. 7963-7966.

Federal  Register.  1976b.  State Program Elements Necessary for Participa-
     tion in the National Pollutant Discharge  Elimination  System,  Concen-
     trated Animal  Feeding Operations.  Vol. 41, No.  54.   U.S.  Government
     Printing Office, Washington,  D.C.  p.  11458-11461.

Geldreich, E.E.  1976.  Sanitary Significance  of Fecal  Coliforms  in  the
     Environment.  U.S. Department of  Interior, Federal Water  Pollution
     Control Administration.   Water Pollution  Control  Research  Series
     WP-20-3.

Gilbertson, C.B., J.R. Ellis,  J.A. Nienaber, T.M. McCalla,  and  T.J.  Klopfen-
     stein.  1975.  Physical and Chemical  Properties  of Outdoor Beef Cattle
     Runoff.  University of Nebraska,  Agricultural  Experiment  Station
     Research Bulletin No. 271.  Lincoln,  Nebraska.   16 p.

Gilbertson, C.B., F.A. Norstat, A.C. Mathers,  R.F.  Holt,  A.P.  Barnett,  T.M.
     McCalla, C.A. Onstad, and R.A. Young.   1979.   Animal  Waste Utilization
     on Cropland and  Pastureland.  USDA Utilization  Research  Report  No. 6.
     U.S. Department of Agriculture, Science and Education  Administration
     and EPA-600/2-79-059.  U.S. Environmental  Protection  Agency,  Office of
     Research and Development.  Washington,  D.C.  135  p.

Janzen,  J.J., A.B. Bodine, and L.J. Luszcz.  1974.  A  Survey of Effects of
     Animal Wastes on Stream Pollution from  Selected  Dairy  Farms.   J. Dairy
     Science 57(2) :260-263.

Kenner,  B.A., H.F. Clark, and  P.W. Kabler.   1960.   Fecal  Streptococci II.
     Quantification of Streptococci in Feces.   American Jour.   Public Health
     50:1553-1559.

Klausner, S.D., P.J. Zwerman,  and  D.F. Ellis.   1976.   Nitrogen  and  Phos-
     phorus Losses from Winter Disposal of Dairy Manure.   J.  Environmental
     Quality 5(l):47-49.
                                     481

-------
Lauer, D.A.  1975.  Limitations of Animal Waste  Replacement  for  Inorganic
     Fertilizers.  In:  Energy, Agriculture and  Waste  Management.   W.J.
     Jewell (ed).  Ann Arbor Science Publishers, Ann Arbor,  Michigan,   p.
     409-432.

Little, F.J.  1966.  Agriculture and the Prevention of  River  Pollution  as
     Experienced in the Wast of Scotland.  J.  Inst. of  Sewage Purification
     65:452-454.

Loehr, R.C. and J.A. Ruf.  1968.  Anaerobic Lagoon Treatment  of  Milking
     Parlor Wastes.  J. Water  Poll. Cont. Fed. 40. 40:83.

Long, F.L.  1979.  Runoff Water Quality as Affected by  Surfce Applied
     Dairy Cattle Manure.  J.  Environmental Quality 8(2):215-218.

Martin, J.H.,  Jr.  1979.  Unpublished Data.  Agricultural  Waste  Management
     Program,  Department of Agricultural Engineering,  Cornell  University,
     Ithaca, New York.

McCalla, T.M., J.R. Ellis, C.B. Gilbertson, and  W.R. Woods.   1972.   Chemical
     Studies of Solids, Runoff, Soil Profile and Groundwater  from  Beef
     Cattle Feedlots at Mead,  Nebraska.  In:   Waste Management Research.
     Cornell University, Ithaca, New York.  p. 211-223.

McCaskey, T.A., G.H. Rollins,  and J.A.  Little.   1971.   Water  Quality of
     Runoff from Grassland Applied with Liquid,  Semi-Liquid,  and "Dry"  Dairy
     Waste.  In:  Livestock Waste Management and Pollution Abatement.
     American  Society of Agricultural Engineers.   St.  Joseph,  Michigan,  p.
     239-242.

Midwest Plan Service.   1975.   Livestock Waste  Facilities  Handbook.   MWPS-18.
     Iowa State University, Ames, Iowa.  94 p.

Milne, C.M.  1976.  Effect of  a Livestock Wintering Operation on a  Western
     Mountain Stream.  Transactions of  the American Society  of Agricultural
     Engineers 19(4):749-752.

Miner, J.R. and R.J. Smith.  1975.  Livestock  Waste Management with
     Pollution Control.  Midwest Plan Service  Handbook,  MWPS-19.   Iowa  State
     University, Ames, Iowa.   89 p.

Minshall, N.E., S.A. Witzel, and M.S. Nichols.   1970.   Stream Enrichment
     from Farm Operations.  J. San. Engr. Div.,  American  Society of Civil
     Engineers 96(SA2):513-524.

Moore, L.A.  1962.  Grass-legume Silage.  J_n:  Forages.   H.D.  Hughes, M.E.
     Heath, and D.S. Metcalfe  (eds.).   Iowa State  University  Press, Ames,
     Iowa.  p. 535-546.

Muck, R.E.  1975.  Unpublished Data.  Agricultural Waste  Management Program,
     Department of Agricultural Engineering, Cornell University,  Ithaca,  New
     York.

                                     482

-------
Robbins, J.W.D.   1978.   Environmental  Impact  Resulting from Unconfined
     Animal Production.   Environmental  Protection  Technology Series Report
     No. EPA-600/2-78-046.   U.S.  Environmental  Protection Agency,  Ada,
     Oklahoma.  34 p.

Robbins, J.W.D.,  D.H. Howells,  and  G.J.  Kriz.   1971.   Role of Animal  Wastes
     in Agricultural  Land Runoff.   Water Pollution Control Research Series
     Report No. 13020 D6X 08171.  U.S.  Environmental  Protection Agency,
     Washington,  D.C.   114 p.

Sewell, J.I. and  J.M. Alphin.   1972.   Effects  of Agricultural Land Use on
     the Quality  of Surface  Runoff.   Tennessee  Farm and  Home Science
     Progress Report  No.  82.   University of Tennessee, Knoxville.   p.  4-7.

Shuyler, L.R., D.M. Farmer,  R.D.  Kreis,  and M.E.  Hula.  1973.  Environmental
     Protecting Concepts  of  Beef  Cattle  Feedlot  Wastes Management.  U.S.
     Environmental Protection  Agency,  Corvallis,  Oregon.

Stewart, B.A., D.A. Woolhiser,  W.H.  Wischmeier,  J.H.  Card, and M.H. Frere.
     1975.  Control of  Water Pollution  from Cropland,  Vol. I.  U.S. Depart-
     ment  of Agriculture,  Agricultural  Research  Service  and U.S.  Environ-
     mental Protection  Agency,  Office  of Research  and  Development.
     Washington,  D.C.   Ill p.

Tenpas, G.H., D.A. Schlough, G.O. Cramer,  and  J.C. Converse.  1972.  Roofed
     vs. Unroofed  Solid  Manure  Storages  for Dairy  Cattle.  Paper  No.  72-949.
     American Society of Agricultural  Engineers,  St.  Joseph, Michigan.

Townshend, A.R.,  K.A. Reichert, and J.W.  Nodwell.   1969.   Status  Report  on
     Water Pollution  Control Facilities  for Farm Animal  Wastes in  the
     Province of  Ontario.   In:  Animal  Waste  Management.   Cornell
     University,  Ithaca,  New York.   p.  131-149.

U.S. Congress.  1972.   Federal  Water  Pollution  Control  Act Amendments  of
     1972, Public  Law 92-500.   Washington, D.C.

U.S. Department of Agriculture.   1977.   Soil  Conservation Service  National
     Handbook of  Conservation  Practices,  Practice  Standard 359 -  Waste
     Treatment Lagoons.   Washington,  D.C.

Van Dyne,  D.L. and C.B.  Gilbertson.   1978.  Estimating U.S. Livestock  and
     Poultry Manure and  Nutrient  Production.   U.S.  Department of  Agriculture
     ESCS-12.  Washington,  D.C.   148  p.

Walter, D.L., P.O. Robillard,  R.  Gilmour,  and  R.W. Hexem.  1978.   BMP
     Development  for Manure  in  New  York  State.   Paper  No. 78-2033. American
     Society of Agricultural Engineers,  St. Joseph, Michigan, 31  p.

Wells, D.M., G.F.  Meenaghan, R.C. Albin,  E.A.  Coleman, and W. Grub.  1972.
     Characteristics of  Wastes  from Southwest  Beef Cattle Feedlots.  In:
     Waste Management Research.   Cornell  University,  Ithaca, NY.   p.385-404.
                                     483

-------
Wittwer, L.S., W.K. Kennedy, G.W.  Trimberger,  and  K.L.  Turk.   1958.  Effects
     of Storage Methods Upon Nutrient  Losses and  Feeding Value of Ensiled
     Legumes and Grass Forage.   Agricultural  Experiment Station Research
     Bulletin 931, Cornell University,  Ithaca,  New York.  58  p.

Zall, R.R.  1972.  Characterisitics  of  Milking  Center Effluent from New York
     State Dairy Farms.   J. Milk  and Food  Technology 35:43.
                                      484

-------
                                  APPENDIX  E

                WATER QUALITY  IMPACT  AND  CONTROL ALTERNATIVES
                   ASSOCIATED  WITH  THE  USE  OF  INSECTICIDES
                      C. A.  Shoemaker and  M.  D.  Harris
                                   SECTION  1

                                 INTRODUCTION

     There are a wide  range  of  practices which  can  be used to reduce the
movement of pesticides  into  the environment.   Unfortunately, because of the
diversity of cropping  systems and  the  large  number  of chemically dissimilar
pesticides in use, it  is  difficult  to  make general  statements about which of
these practices are feasible  and most  effective for a given situation.  The
purpose of this report  is  to  describe  some of the practices which are avail-
able and to discuss the factors which  may  influence their success in
reducing pesticide transport.   The  bulk  of the  report consists of a
tabulation of the information available  on chemical characteristics,
toxicity, transport and effectiveness  of control  procedures for a large
number of commonly used insecticides.

     Management practices  for reducing pesticide  transport include the
following:

     1.  Procedures which  reduce the amount  of  pesticide applied.  Example:
         integrated pest  management.

     2.  Changes in application procedures to reduce the amount of pesticide
         transported away  from  target  areas.   Example:  replacing aerial
         applications  by  ground applications  which  have made lower drift
         losses.

     3.  Improved control  of  disposal  of surplus  pesticide and pesticide
         containers.   Example:   requiring  a  substantial  deposit on pesticide
         containers.

     4.  Changes in timing of application  to reduce the amount of pesticide
         transported.  Example:  avoiding  applications which are followed
         shortly by rain.

     5.  Implementation of soil  and water  conservation practices to reduce
         the transport of  water-born pesticides.   Example:  use of strip-
         cropping.


                                    485

-------
                                  SECTION  2


                                 CONCLUSIONS
     There are a large number of practices which  can  be  developed  to reduce
the transport of pesticides  into non-target  areas.  The  effectiveness and
costs of each of these practices will  vary among  crops,  pests  and
geographical regions.  In deciding which  practices  to implement,  we should
consider the impact of a practice on all  pathways of  pesticide transport,
including transport by air,  water, improper  disposal  or  accidental  spills.
Practices which reduce the amount of pesticide  used are  the  only  methods
which reduce transport via all pathways  simultaneously.   For this  reason, a
high priority should be  given to the implementation of practices  like pest
management, which  reduce the amount of pesticide  applied.   If a
comprehensive integrated pest management  program  is not  available for a
particular pest and crop, sometimes pesticide use can be reduced  by
implementation of  relatively simple programs involving the use of scouting
or cultural control methods  like crop  rotation.   Other important  methods
which are likely to be available in the  short term  are replacement of aerial
applications of pesticides with ground applications,  improvements  in timing
of pesticide applications, additional  controls  on disposal,  soil  and water
conservation practices, and  substitution  of  the current  pesticide  with
another which is less mobile.  In the  longer term,  we would  hope  to see the
development of more selective chemical and microbial  pesticides,  additional
resistant plant varieties and comprehensive  integrated pest  management
programs for an even wider range of crops.
                                     486

-------
                                   SECTION 3


                        PATHWAYS  OF PESTICIDE TRANSPORT
     Pesticides move  into  the  environment by several pathways.  The major
pathway for most pesticides  appears to be air-borne transport resulting  from
drift during application or  volatilization during or after application.
Gerakis and Sficas  (1974)  have estimated that about one-half of the
pesticide applied to  field crops  enters  the atmosphere through evaporation
from soil and plant surfaces.   Drift is  usually defined as the percentage of
pesticide applied which does not  reach the targeted field.  Drift losses can
be quite substantial,  especially  with  aerial  applications.  For example  Ware
et al (1970) found that 45%  of the  methoxychlor applied did not reach the
foliage or ground in  their five acre target plot.  In this experiment the
applicator plane was  only  5-6  feet  above the alfalfa crop and the wind speed
was only 3.6 mph.  Garston et  al  (1968)  reported that 30 minutes after
Amitrole spray was applied aerially to 100 acres in a watershed it appeared
in stream waters at concentrations  of  155 ppb.   Drift losses are usually
lower for ground applications, especially for granular formulations.

     Pesticides can also be  transported  into the environment by water.
Pesticides carried in  runoff may  either  be dissolved in solution or sorbed
onto soil particles.   The  fraction  of  pesticide sorbed onto soil particles
will influence the amount  of material  which is  transported and the
effectiveness of procedures  to control  this transport.

     The amount of pesticide which  is  transported by surface runoff is
usually smaller than  air-borne losses.  In an extensive review of the
literature on pesticide losses in  runoff, Wauchope (1978) estimates that the
highest average losses will  be about five percent of the applied material
for wettable powder herbicides whose application is followed by rains.
Wauchope estimated losses  from organochlorine insecticides currently in
use to be about one percent  or less of the applied material.  He estimated
that losses of most other  pesticides would average .5 percent or less of the
material applied.

     Leaching losses  of strongly  or moderately  absorbed pesticides tend  to
be quite small.  However,  highly  soluble pesticides like Aldicarb can pose
serious problems to groundwater quality  when applied to well drained or
sandy soils.  Recently about a fourth  of over 500 wells tested in Suffolk
County, New York had  concentrations of Aldicarb in excess of 7 ppb, a
standard suggested by  a National  Academy of Sciences report (1977) and by
the New York State Department  of  Environmental  Conservation (Severe, 1980).


                                     487

-------
     Improper disposal can  also  be  significant in the transport of
pesticides to non-target areas.   As  a  result,  it is recommended that
containers be rinsed  and punctured  before disposal.  In a study at Southern
Illinois University,  600 five  gallon  used pesticide containers were sampled
at one farm disposal  site.   It was  found  that  less than forty percent of  the
containers had been rinsed.  Several  cans had  between one quart and 4.25
gallons of undiluted  pesticide in the  discarded container.  Another study at
Oregon State University has  shown that  on the  average, nearly six ounces  of
pesticide is left  in  unrinsed  five-gallon containers (Luckman _e_t ^1_,  1978).

     Each of the management  practices  for controlling pesticide transport
affects the movement  of pesticide in  different ways.  In most cases,  a
practice obstructs movement  along a single pathway.  For example, soil  and
water conservation practices may reduce the amount of pesticide carried  in
runoff, but they do not decrease drift  losses.  The only practices which
diminish the movement of pesticides along all  pathways are those practices
which reduce the amounts of pesticide used.  For this reason  such practices
should be given first consideration in  areas where they are feasible  and
effective.
                                      488

-------
                                   SECTION 4


  REDUCTION IN PESTICIDE  USAGE  THROUGH  INCREASED EFFICIENCY OF PEST CONTROL
     New developments  in  pest  control  technology have resulted in dramatic
decreases in the use of pesticides  for some serious insect pests.  Much of
this reduction in pesticide  use  has been  the result of the utilization of
non-chemical methods of pest control  in conjunction with improvements in
timing of pesticide applications.

SCOUTING

     Pest management is a  term which  is used to describe the effective co-
ordination of a variety of pest  control techniques to contain a pest popula-
tion.  Several principles  are  involved in  the development of pest management
programs.  Control procedures  should  be implemented only when they are
economically justified.   This  principle has resulted in the concept of an
"economic threshold",  which  is the  minimum pest density that justifies a
pesticide application.  Below  this  density, no pesticide should be applied.
This policy represents a  marked  departure  from earlier programs in which
pesticide was applied  on  a fixed schedule  regardless of pest density.

     In order to implement an  "economic threshold" policy for timing pesti-
cide applications, it  is  necessary  to  sample the pest population to
determine its density.  Such a sampling program is called "scouting".  Based
on a survey of cotton  entomologists in 1972-74 the reduction in insecticide
use for control of cotton  insects has  been estimated to be around twenty-
three percent as a result  of scouting  (Pimentel _et__al_., 1979).

RESISTANT PLANT VARIETIES

     Nonchemical means of  suppressing  pest populations include cultural and
biological control methods as  well  as  the  use of resistant plant varieties.
Resistant varieties have  been  widely  used  for many years and will continue
to be a very important means of  pest  control in the future.  Unfortunately
in some situations, high yielding resistant plant varieties are not
available.  It may take years  or even  decades to develop a commercially
available resistant variety.   The investment in time has been well rewarded.
For example, wheat varieties resistant to  Hessian fly have been available
for years and have been tremendously  important in reducing the need for
insecticides in wheat  production.   Cotton  varieties such as frego bract
cotton with resistance to  boll weevils are currently being developed for
commercial use in the  South.


                                     489

-------
CULTURAL METHODS OF  PEST  CONTROL

     Cultural pest control  methods  involve  the physical  alteration of the
crop ecosystem.  Common examples  of cultural  control  procedures are changes
in planting dates or harvest  dates.   Such  changes  affect the synchrony of
the pest with the host crop and can  thereby  reduce the amount of crop
damage.  For example, in  New  York a  computerized pest  management system
using  regional scouting information  and  weather data  advises farmers when
densities of alfalfa weevils  are  sufficiently  high to  justify an early
cutting.  Changes in planting or  harvest dates are often done in conjunction
with the use of special plant  varieties  or  alterations in irrigation
schedules so that the crop  matures  in a  shorter period of time.  This
procedure has been widely used in cotton production in Texas and has
significantly reduced insecticide use.

     Another very important cultural  means  of controlling pests is crop
rotation.  Many pests, like the southern corn  rootworm,  require continuous
presence of the host crop to  complete its  life cycle.   By rotating corn with
a nonhost crop like  soybeans,  corn  rootworm can be suppressed to
non-damaging levels.  Although crop  rotation  was widely  used before the
development of modern pesticides, many farmers are reluctant to use the crop
rotations because they are  sometimes  less  profitable  than continuous growing
of a high-value crop.

BIOLOGICAL CONTROL

     Biological control refers to the use  of  biological  organisms to
suppress pest populations.  Insect  parasites  and predators, for example, can
significantly decrease the  size of  pest  populations,  sometimes to the point
where  pesticide applications  are  no longer necessary.   One of the most
successful examples  of this type  of control  is the establishment of two
insect parasite populations which have successfully controlled the olive
parlatoria scale.  This insect was  the most  serious pest of olives in
California before the parasites were  introduced (Huffaker and Kennett,
1966).  These parasites have  been so effective that currently pesticide
control is almost never used  for  control of olive  paralatoria scale.  One of
the greatest advantages of  this type of  biological control is that once it
is established, it continues  at no  cost  to  the farmer.

     Another form of biological control  is  the enhancement of the
effectiveness of natural  enemies  of the  pest  which are already present in
the crop field.  This enhancement usually  involves measures which increase
survivorship of the  natural enemies.   A  major cause for mortality of insect
parasites and predators is  the presence  of  pesticide  applied to suppress
pest populations.  Reduction  or elimination  of pesticide applications during
periods when natural enemies  are  susceptible  can  greatly enhance the
effectiveness of natural  control.

     Another form of biological control  is the use of pathogens which attack
pest populations.  Commercial  mixtures of such pathogens used for short-term
pest control are called microbial pesticides.   The most commonly used micro-
bial pesticide is Bacillus  thuringiensis which is  applied for the control of

                                     490

-------
lepidopterous insects.  The  advantage  of a  microbial  pesticide is that is
usually only attacks a specific  range  of lower  organsims  and is not expected
to harm natural enemies or to  persist  in the environment  in the absence of
host species.  Microbial pesticides  have several  disadvantages.  The first
is that they are sometimes not  as  toxic  to  the  target species nor as
economical as competing chemical pesticides.   Secondly,  microbial pesticides
must be extensively tested before  registration  to prove  that the organisms
or its mutants will not be harmful to  man or nature.   Because of the expense
of such testing and because  of  the small  market for materials which are
toxic to only a narrow range of  pests,  relatively few micorbial pesticides
are available.

OTHER PEST CONTROL METHODS

     Attractants are also used  to  monitor pest  populations and as a direct
control method.  For example,  Mediterranean fruit fly populations have been
suppressed by the  distribution  of  a  protein hydrolysate  bait containing
malathion.  The attractiveness of  the  bait  provides pest  control with much
less insecticide than would  have otherwise  been necessary.  Attractants in
traps can also be  useful in  estimating  pest population densities and thereby
ascertaining the best time to  apply  pesticides  in order  to maximize
effectiveness.  In citrus orchards,  traps containing female California red
scale may catch thousands of males.   From the trap data,  the damage
potential from the pest and the  need  for a  pesticide treatment can be
estimated.

     The traps containing live  females  are  effective in  attracting males
from a long distance because the female  releases  a chemical  called a sex
pheromone which males can detect even  in extremely low concentrations.  For
some insects the chemical structure  of  the  pheromone has  been discovered.
Commercially synthesized pheromones  are  also used in traps.   As a direct
control measure, pheromones  have been  applied to  crop fields in order to
disrupt insect mating and thereby  reduce the size of subsequent generations
of the pest.

     Crops themselves are sometimes  used as traps.  In cotton, for example,
a trap crop for cotton boll  weevil is  developed by planting about 5% of the
cotton two or three weeks before the  rest of the  crop is  planted.  The
emerging boll weevils are attracted  to the  early  cotton  which is then
heavily sprayed with insecticide.  This  reduces the amount of insecticide
necessary to control the pest  over the  entire cotton acreage.  An economic
analysis of the costs and benefits associated with early  trap crops in
cotton indicate that trap crops  reduce  production costs  (including pesticide
costs) by about $6.80/acre.  (Pimentel  et_^l_.,  1979).

     The environmental advantages  of  pheromones and microbial pesticides are
associated with the relatively narrow  spectrum  of organisms  which are sus-
ceptible to their  harmful effects.   It  is also  possible to develop chemical
pesticides which are toxic to  only a  few closely  related  species.  If their
selectivity makes  them less toxic  to  insect parasite and  predators,
selective pesticides are very  useful  in  programs  to enhance the
effectiveness of natural  enemies for a  pest population.   However, because of

                                    491

-------
the multi-million dollar cost  of  developing and testing a pesticide, the
pesticide, industry is  reluctant  to  make  such  an investment in a product
which will have a small market.   As  a  result,  selective pesticides are not
as available as one might wish.

     There are many other practices  being  developed for improving the
effectiveness of pest  control  programs.   Among these other practices are the
application of juvenile hormones  and the  release of sterile males.  In the
later procedure, males  which  have been  sterilized by chemicals or radiation
are released into the  natural  population  to mate with mature females.  The
method is most effective if the  sterile  males  greatly outnumber the fertile
males and if the female mates  only once.

INTEGRATED PEST MANAGEMENT

     Since a range of  pest  control methods Is  available, plant protection
research  In recent years has  put  an  Increasing emphasis on a more effective
means of  integrating these  techniques.   In most cases the development of
such programs has reduced the  need for  pesticides.  For example, based on  a
survey of cotton entomologists  in 1972-1974, Pimentel et_jil_., (1979)
computed  that implementation  of  the  most  economical integrated pest
management practice in  each cotton growing region would reduce insecticide
use by an average of 40%.

     Effective integrated pest management usually involves a detailed bio-
logical study of the population  dynamics  of the pest, its host crop and  its
natural enemies.  From such studies, an  understanding can be gained of the
impact of management practices  on the  interactions among populations.
Armbrust et_^l_., (1980) illustrate the  approach to such a comprehensive
analysis  of alfalfa weevil  control.   Because of the complexity of the crop
ecosystem, techniques  of systems  analysis  have been found to be increasingly
useful in developing integrated  pest management programs (Shoemaker, 1979,
1980; Norton and Rolling, 1979;  Shoemaker et^ £]_., 1978).

     An excellent example of  an  integrated pest management program has been
developed in Texas for control  of cotton  pests.  The program utilizes
scouting, a short season cotton  variety,  and protection of natural enemy
populations through use of  a  selective  insecticide.  The insecticide
Azinphosmethyl is effective in  controlling boll weevil, but in not harmful
to natural biological  control  agents.   Pesticide applications are made only
when field scouting indicates  they are  necessary.  The amount of pesticide
used is subsequently less than in conventional pest control programs.
Because of the short-season cotton variety, these few pesticide applications
were sufficient to control  the boll  weevil before it caused significant  crop
damage.   No pesticide  is used  against  the other major insect pests, the
Heliothis species.  When they  are not  threatened by the use of wide spectrum
insecticides, the natural enemies of the Heliothis are more effective that
any of the insecticides currently registered in cotton  (Phillips et al.,
1980).

     The  economic and  environmental  benefits of this program are
substantial.   In the pilot  program with normally spaced short season cotton

                                     492

-------
in Frio County, Texas, production  required  80%  less  fertilizer,  50% less
water and 75% less insecticide.  The net  profit  of the  integrated pest
management program was more than double that  of  the  typical  producer
(Phillips et_£l_., 1980).  Hence, it is possible  through  improved technology
to simultaneously decrease pesticide use  and  to  improve  farmer income.
                                    493

-------
                                   SECTION  5


       CHANGES IN APPLICATION  PROCEDURES TO REDUCE  PESTICIDE TRANSPORT
REDUCTION IN DRIFT LOSSES:   IMPACT  OF  GROUND  APPLICATION,  DROPLET SIZE, AND
PESTICIDE FORMULATION.

     Warej?t jiK,  (1970,  1975)  have shown  that nuch more drift occurs during
aerial application of pesticides  than  with the use of ground sprayers.  For
example, Adair_et al.,  (1971) found that  following an aerial application of
methyl parathion, Tess  than  50% of  the applied pesticides  was recovered on
the ground in an area which  included the  target field plus the area 800
meters downwind from the  field.   In an extensive  review of drift losses by
von Rumker _ejt jj_.   (1975), drift  losses from  ground applications are
estimated to be between 0% and  40%  of  the  pesticide applied.  Byass and Lake
(1977) have shown that  even  small  drift losses can be hazardous.  They
observed that drift  losses of less  than 1% of the applied  picloram caused
significant damage to sensitive plant  species located downwind.

     Although ground applications  are  more effective at reducing drift
losses, aerial applications  are often  preferred for a variety of reasons.
First they may be  somewhat less expensive.  In Texas for example, ground
application costs between $3.25 and 3.50/acre.  Aerial  application costs are
between  $2.25 and $2.75  per acre,  depending  on the volume of material
applied (LeClair,  1977  personal communication).  Another advantage of an
aerial application is that planes  can  cover a large area much more quickly
than is possible with ground equipment.  In some  areas, the use of ground
application equipment may be limited by wet fields or irrigation pipes which
obstruct the movement of  ground equipment.

     Besides being more desirable  from an  environmental point of view,
ground applications  have  some advantages  over aerial applications.  The most
obvious advantage is that without  such substantial drift losses, more of the
pesticide remains  in the  target area where it is  more effective in killing
target pests.  Some  entomologists  also argue  that because  the nozzle is
closer to the plant, a  ground application  results in a more thorough
coverage of the crop, and hence its pest  control  effectiveness is enhanced.

     Droplet size  is extremely  important  to drift losses.   Droplets ranging
from 10 to 50 urn in  diameter are  likely to drift  up to several kilometers
whereas droplets greater  than 100  urn in diameter  rarely drift except in
windy conditions (Gerakis and Sficas,  1974).   This is one of the reasons why
drift is a less serious problem for herbicides which are applied with larger


                                     494

-------
droplets than for  insecticides.   Brazzel  et al., (1968) have suggested that
more progress in the control  of  drift  could be made by the control of the
droplet spectrum than  by  any  other means.

     The formulation of pesticide also has a large impact on drift losses.
For example, in the case  of DDT,  it was found that dust applications placed
fourteen times more material  downwind  than was found with spray applications
(Gerakis and Sficas, 1974).   As  a result,  dust has been largely replaced by
spray and granular formulations.   Drift is generally lower with granular
formulations than  with spray  applications.

REDUCTION IN VOLATILIZATION LOSSES:  SOIL  INCORPORATION AND CHOICE OF
PESTICIDE

     Volatilization is a  major factor in the transport of many pesticides.
The rate at which  this volatilization  occurs depends upon environmental
factors such as temperature,  air  flow  rate, type of cover crop, soil
composition and penetration of pesticide into the plant tissue (Harns and
Lichtenstein, 1961; Farmer et_ £]_.,  1973;  Lichtenstein et_ a]_., 1970; Spencer
and Cliath, 1977;  Kearney _et jil_., 1964; Swoboda _et _al_., 1971).  The rate of
volatilization also depends upon  characteristics of the pesticide itself,
especially  its vapor pressure,  but also its water solubility and the
strength of its absorbtion to soil  particles.  Since the volatilization  rate
depends upon the type  of  pesticide, one obvious way to reduce pesticide
volatilization is  to replace  a pesticide with a less volatile alternative
pesticide.

     Another management practice  which can be used to reduce volatilization
is incorporation of a  pesticide  into the soil during application.  The rate
of volatilization  of pesticides  buried in  the soil  is much slower than for
pesticides on the  surface.  For  pesticides mixed into the soil, the
volatilization losses  depend  upon the  rate of pesticide desorption from
soil, the rate of  diffusion to the soil  surface, and the mass flow of water
to the soil surface (Spencer  and  Cliath,  1973; Fa rme r _ejt ^1_., 1973).  Farmer
and Letez (1974) have  further  discussed the effects of soil  incorporation on
volatility and have developed  several  models for the prediction of
volatilization losses.
                                     495

-------
                                   SECTION  6
                 REDUCING TRANSPORT  OF  PESTICIDES  BY RUNOFF:
     SOIL AND WATER CONSERVATION  PRACTICES  AND  NON-PERSISTENT PESTICIDES
     Pesticides can be transported  from  crop fields either dissolved in run-
off water or sorbed onto soil  particles  suspended in runoff water.  The par-
titioning of the pesticide  between  the dissolved and sorbed state varies
considerably among pesticides.   Most  pesticides used in agriculture are
transported primarily in the dissolved phase.  As mentioned earlier,
Wauchope (1978) estimates that  for  most  pesticides less than 1% of the
material applied is transported  in  runoff.

     Soil and water conservation practices  (SWCPS) tend to be more effective
in reducing the movement of sediment  than  in reducing the quantity of runoff
water.  Since most agricultural  pesticides  are  transported partially in the
dissolved phase, SWCPS generally are  not  as  effective in reducing the
movement of a pesticide as  they  are in reducing the movement of sediment.
An exception is for very strongly adsorbed  pesticides like Paraquat, which
is usually entirely adsorbed.   The  effectiveness of SWCPS in reducing
pesticide transport is discussed in detail  in an earlier report of this
project (Shoemaker and Harris,  1979;  Steinhuis, 1979; and Beyerlein and
Donigian, 1979).

     Another way to reduce  runoff losses is  to use a less persistent
pesticide.  Pesticides which are persistent  are subject to runoff and
volatilization for a  longer period  of time,  and thus the quantities of
pesticide transported in this  fashion tend  to be higher.
                                     496

-------
                                  SECTION  7


    CONTROL OF LEACHING LOSSES:  WATER MANAGEMENT  AND  CHOICE  OF PESTICIDE
     Many pesticides are moderately  or  strongly  adsorbed  to soil  particles.
For such pesticides, transport into  groundwater  tends  to  be small  because
most of the pesticide is filtered  by  the  soil  from  the leachate as it moves
down through the soil column  into  groundwater.   For this  reason,  in the
past, runoff transport has been  considered  to  be a  more important source of
pesticide pollution than leaching.   However, some of the  carbamate
pesticides which have come into  use  more  recently are more soluble and more
prone toward transport in leachate.   For  example, Toxaphene,  an
organochlorine which has been  in use  for  many  years,  has  a solubility of 3
ppm whereas the solubility of  the  newer carbamate insecticides, Aldicarb and
Carbofuran, are 6000 ppm and  700 ppm, respectively  (Finlayson and MacCarthy,
1973).  As mentioned earlier,  over one-fourth  of  the  wells sampled in a
potato-growing region in Long  Island  had  Aldiarb  concentrations in excess of
the recommended maximum level.   The  soils on Long Island  are  sandy and so
soil adsorbtion of the Aldicarb  is probably  less  than  in  many other areas.
Carbofuran was also found in  some  of  the  wells on Long Island (Severe,
1980).  One obvious way to reduce  leaching  losses is  to replace a weakly
adsorbed, soluble pesticide with one  which  is  more  strongly adsorbed to
soil.  However, if the alternate pesticide  is  more  persistent or volatile,
such substitutions may increase  runoff  or volatilization  losses.

     In irrigated crops water  management  can also reduce  leaching losses.
Keeping a soluble pesticide in the root zone where  it is  subject to
microbial degradation and to  plant uptake for  as long as  possible usually
decreases leaching losses.  In the period following application of a
soluble, weakly adsorbed pesticide,  irrigation should  be  controlled to
minimize the movement of water out of the root zone.   Similarily, applying a
soluble pesticide during a period  of low  probability of rainfall  can
substantially reduce leaching losses.
                                     497

-------
                                   SECTION  8


             IMPACT OF APPLICATION  TIMING  ON  PESTICIDE TRANSPORT
     Weather can have a  significant  impact  on  the transport of pesticides.
Pesticide applications should  be  timed  to  avoid  the  likelihood of
unfavorable weather conditions.   For example,  windy  conditions can greatly
increase drift losses.   Baker  and  Johnson  (1977) found drift losses of 50%
in winds of 20 km/hr, from  ground  applications of a  granular insecticide
(Fonofos) and of a large droplet  spray  herbicide (Atrazine).  Although such
losses are frequently observed  for aerial  applications, these losses are
much higher than would be expected for  ground  applications in non-windy
conditions, especially for  granular  or  large  droplet applications.  Ware et
al., (1972) found that early morning (1.8  mph  wind speed)  aerial
applications of methoxychlor had  only 25%  drift  losses whereas evening
applications (3.2 mph wind  speed)  had 45%  drift  losses.  Since a midafter-
noon application that occurred  under windier  conditions (3.6 mph) had less
drift (37%) than the evening application,  other  factors in addition to wind
conditions appear to contribute  to drift  losses.

     For nonpersistent pesticides, the  amount  of material  carried by runoff
or leaching is very sensitive  to  the time  interval between application and
the first significant rainfall.   By  changing  application timing so that it
occurs during a period of low  probability  of  rainfall  the expected amount of
pesticide transported in runoff  can  be  substantially reduced.  The impact of
precipitation can also be reduced  by applying  pesticides later in the season
when the presence of a crop canopy can  reduce  the impact of precipitation on
runoff transport.

     Although changes in timing  of a pesticide application may be a simple
and very effective way to reduce  pesticide  transport,  significant changes in
timing may not be feasible.  The  effectiveness of a  pesticide application is
greatly diminished if it is blown  away  by  wind or washed away by rain.
Hence most farmers try to avoid  application during weather that is likely to
contribute to the movement  of  a  pesticide.  However, the farmer's choice of
timing may be constrained by other factors.  He  must avoid applications
which are sufficiently close to  harvest to  cause unacceptable residue levels
in the crop.  He also may find  it  difficult to apply pesticides during
periods when labor is in short  supply.   Most  importantly,  altering the
timing may reduce the effectiveness  of  the  pesticide as a  pest control
agent.  For example, runoff losses of a herbicide can  often be reduced by
replacing pre-emergence  treatments with postemergence  applications of the
herbicide.  Unfortunately,  this  practice  is not  practical  in many cases
                                     498

-------
because the postemergence  treatments  allow early competition of weeds with
the crop and because they  require  labor  at a  time which is critical on many
farms.  Development of  production  schedules which are both feasible and
economical for the farmer  and  which  result in timings of pesticide
applications during dry, nonwindy  periods  can substantially reduce pesticide
transport.
                                    499

-------
                                   SECTION  9


                         REDUCING  IMPROPER  DISPOSAL
     Although extension  personnel  have for many years distributed
Information on the proper  techniques  for disposing of pesticides, the advise
is not as widely followed  as  might be desired.   A study by Southern Illinois
University discovered that  fewer  than 20% of the pesticides containers
sampled had been properly  rinsed  and  punctured  as recommended.  One
suggestion to remedy this  problem  is  to expand  farmer education programs to
futher acquaint farmers  with  proper disposal  techniques and with hazards
resulting from improper  disposal.   A  more effective measure would be to
require a substantial deposit on  each pesticide container which would be
refunded only when a rinsed,  punctured container was brought to a disposal
site.

     Changes in application equipment may also  help to minimize the amount
of pesticide entering the  environment due to improper disposal.  Some spray
equipment is designed so that an  unopened pesticide container is inserted
into an attachment which automatically punctures the can and mixes the
pesticide with water.  The  container  is then rinsed.  This system insures
proper disposal of containers while  reducing poisoning risks to the
applicator.
                                      500

-------
                                  REFERENCES

Adair, H. M., F. A. Harris,  M.  V.  Kennedy,  M.  L.  Laster,  and E. D.
     Threadgill.  1971.  Drift  of  Methyl  Parathion  Aerially Applied Low
     Volume and Ultra  Low  Volume.

Arbrust, E. J., B. C.  Pass,  D.  W.  Davis,  R. 6.  Helgesen,  G. R. Manglitz, R.
     L. Pienkowski, and C.  G.  Summers.   1980.   General  Accomplishments
     Toward Better Insect  Control  in  Alfalfa,  in  New Technology of Pest
     Control, C. B. Huffaker  (ed.).   John  Wiley & Sons,  New York.

Baker, J. L. and H. P. Johnson.   1977.   Tillage System  Effects on Runoff
     Water Quality:   Pesticides.   ASAE  Paper No.  77-2504B.   American Society
     of Agricultural   Engineers,  St. Joseph, Michigan.

Beyerlein, D. C. and  A. S.  Donigian.  1979.  Effects of  Soil  and Water
     Conservtion Practices  on  Runoff  and  Pollutant  Losses From Small
     Agricultural  Watersheds:   A  Simulation Approach, pp. 385-427 in
     Effectiveness of Soil  and  Water  Conservation Practices for Pollution
     Control.  D. A.  Haith  and  R.  C.  Loehr, Environmental Protection Agency,
     EPA-600/3-79-106.

Brazzel, J. R., W. W.  Watson,  J.  S. Hursh  and  M.  H.  Adair.   1968.  The
     Relative Efficiency of  Aerial  Application  of Ultra-Low-Volume and
     Emulsifiable Concentrate  Formulations  of  Insecticides.  Journal of
     Economic Entomology 61(2):408-413.

Byass, J. B. and J. R. Lake.   1977.   Spray  Drift  From a  Tractor-Powered
     Field Sprayer.   Pesticide  Science  8:117-126.

Farmer, W. J. and J.  Letey.   1974.  Volatilization  Losses of Pesticides From
     Soils.  EPA-670/2-74-054,  U.  S.  Environmental  Protection Agency,
     Washington, D. C.

Farmer, W. J., K. Igue and  W.  F.  Spencer.   1973.   Effect  of Bulk Density on
     the Diffusion and Volatilization of  Dieldrin From  Soil.   Jornal of
     Environmental Quality  2(1):107:109.

Finlayson, D. G. and  H. R.  MacCarthy.   1973.  Pesticide  Residues in Plants,
     in C. A. Edwards  (ed.)  Environmental  Pollution  by  Pesticides, Plenum
     Press, London, pp. 57-86.

Gerakis, P. A. and A.  G. Sficas.   1974.   The Presence and Cycling of
     Pesticides in the Ecosphere.   Residue  Reviews  52:69-88.
                                     501

-------
Harris, C. R. and E. P.  Lichtenstein.   1961.   Factors  Effecting the
     Volatilization of  Insecticidal  Residues  From  Soil.   Journal  of Economic
     Entomology 54:1038-1045.

Huffaker, C. B. and C.  E.  Kennett.   1966.   Studies of Two Parasites of Olive
     Scale Parlatoria oleae  (Colvee)  IV  Biological  Control  of Parlatoria
     oleae "(Colvee) Through  the  Compensatory  Action of Two  Introduced
     Parasites.  Hilgardia 37:283-335.

Huffaker, C. B. (ed.).  1980.  New Technology of  Pest Control, John Wiley &
     Sons, New York.

Kearney, P. C., T. J. Sheets,  and  J.  W.  Smith.   1964.  Volatility of Seven
     s-Triazines.  Weeds 12:83-86.

Lichtenstein, E. P. and K. R.  Schulz.   1970.   Volatilization  of Insecticides
     From Various  Substrates.  Journal  of  Agricultural  and  Food Chemistry
     18:814-818.

Luckmann, W. H., R. Barganz, A.  Brigham, PI Challand, M.  Conlin,  H. Dodd, C.
     Erb, W. Hadley, M. Shurtleff, P.  Hermsen,  J.  Hogancamp,  G. Kapusta, E.
     King, J. Kirk, M.  Levin,  G. Meadows,  J.  C.  Cole  and  H.  Seymour.  1978.
     Final Report  of the Subcommittee on Pesticides of the  State of Illinois
     Task Force on Agriculture Nonpoint  Sources  of Pollution.  Urbana,
     Illinois.

Metcalf, R. L. and W. H. Luckman.  1975.   Introduction to Pest Management.
     John Wiley &  Sons, New  York.

Norton, G. A. and  C. S. Holling  (eds.).  1979.   Pest  Management,  Pergamon
     Press, Oxford.

Phillips, J. R., A. P.  Gutierrez,  P.  L.  Adkisson.   1980.   General Accom-
     plishments Toward  Better  Insect  Control  in  Cotton,  in  New Technology of
     Pest Control , C. B. Huffaker  (ed.), John Wiley & Sons,  New York.

Pimentel, D. and E. H.  Smith (eds.).   1978.   Strategies  of  Pest Control  ,
     Academic Press, New York.

Pimental, D., C. A. Shoemaker, Eddy  L.  La  Due,  R.  B.  Rovinsky, N. P.
     Russell.  1979.  Alternatives for Reducing Insecticides  on Cotton  and
     Corn:  Economic and Environmental  Impact.   Envrionmental Protection
     Agency EPA-600/5-79-007a.

Severo, Richard.   1980.   "Story  of a Safe  Pesticide Ends  as Classic Case of
     Misuse".  New York times, March  4.

Shoemaker, C. A.,  C. B. Huffaker,  and C. E. Kennett.   1978.   A Systems
     Approach  to the  Integrated  Management of a Complex of Olive Pests.
     Environmental Entomology  8:182-189.
                                     502

-------
Shoemaker, C. A.   1979.   Optimal  Timing  of Multiple  Applications of
     Pesticides with Residual Toxicity.   Biometrics  35:803-812.

Shoemaker, C.A. and M.O.  Harris.   1979.   The  Effectiveness  of Soil  and Water
     Conservation  Practices  in  Comparison with  Other Methods for Reducing
     Pesticide Pollution, in  Effectiveness  of Soil and  Water Conservation
     Practices for Pollution  Control,  pp.  206-287. D.A.  Haith and R.C. Loehr
     (eds.), Environmental Protection  Agency  EPA-600/3-79-106.

Shoemaker, C. A.   1980.   The  Role  of  Systems  Analysis  in Integrated Pest
     Management, in New Technology of  Pest  Control ,  C.  B.  Huffaker (ed.).
     John Wiley &  Sons, New  York.

Spencer, W. F. and M. M.  Claith.   1973.   Pesticide Volatilization as  Related
     to Water Loss From Soil.   Journal of Environmental  Quality  2(2):284-289

Spencer, W.  .F and M. M.  Claith.   1977.   The  Solid-Air  Interface:  Transfer
     of Organic Pollutants Between the Solid-Air  Interface.   In:  I.  H.
     Suffet,  (ed.) Fate of Pollutants  in  the  Air  and Water  Environments.
     John Wiley &  Sons, Inc., New  York.   pp.  107-126.

Sprott, J. M., R.  D. Lacewell,  G.  A.  Niles, J.  K.  Walker,  and J. R. Gannaway
     1976.  Agronomic, Economic  and  Environmental  Implications  of Short
     Season, Narrow-Row Cotton  Production.  Texas Agricultural Experiment
     Station, MP-1250c.

Steenhuis, T. S.   1979.   Simulation  of the  Action  of Soil  and Water Conser-
     vation Practices in  Controlling  Pesticides,  pp.  106-146.  In:
     Effectiveness of Soil and  Water  Conservation Practices  for  Pollution
     Control, D. A. Haith and R.
     Agency, EPA-600/3-79-106.
C. Loehr (eds.), Envrionmental Protection
Swoboda, A., G. W. Thomas,  F.  B.  Cady,  R.  W.  Baird  and  W.  G.  Knisel.   1971.
     Distribution of DDT and Toxaphene  in  Houston Black  Clay  on  Three Water-
     sheds.  Environmental  Science  and  Technology 5(2):141-145.

Von Rumker, R., G. K. Kelso, F. Horay and  K.  A.  Lawrence.   1975.   A Study of
     the Efficiency of the  Use of Pesticides  in  Agriculture.   EPA-9/75-025.
     U. S. Environmental Protection  Agency,  Washington,  D.  C.

Ware, G. W., W. P. Cahill,  P.  D.  Gerhardt  and K.  R.  Frost.   1970.   Pesticide
     Drift IV:  On-Target Deposits  From Aerial Application  of Insecticides.
     Journal of Economic Entomology  63(4):1982-1985.

Wauchope, R. D.   1978.  The  Pesticide Content of Surface Water Draining From
     Agricultural  Fields - A Review, Journal  of  Environmental  Quality 7(4):
     459-472.
                                     503

-------
                                 APPENDIX  1


                      CHARACTERIZATION OF  INSECTICIDES


GUIDE TO USE OF INSECTICIDE TABLES
     The tables listed in this appendix are designed to  aid  in  the  indenti-
fication of practices which might be most  effective  for  reducing a  specific
insecticide pollution problem.  Available  information  on volatilization,
solubility, runoff, drift losses and toxicity  is  reported for a number of
commonly used pesticides.  This information is  useful  in determining which
modes of transport are most important  to control.  The adsorbtion,
solubility, volatilization and toxicity data are  also  useful  in assessing
the environmental advantages  of substituting an alternative  insecticide for
the one currently in use.  These  tables catalogue only  insecticides.
Unfortunately in the time available for this project  it  was  not possible to
also develop tables for the most widely used herbicides  and  fungicides.

     The development of integrated pest management practices  which  reduce
insecticide use depend more upon the crop  and  its major  pest  than upon the
pesticide being used.  As a result, pest management  alternatives are not
discussed in the tables.  Usually the  best source of information on
available pest management techniques can be provided  by  extension or
research personnel involved in developing  pest  management programs  in the
area of concern.  Reviews of  some of the pest  management programs which have
been developed in the United  States are discussed in the books  edited by
Huffaker (1980), Metcalf and  Luckman  (1975) and Pimentel  and  Smith  (1978).

     The same format is used  for presenting information  for  each of the
pesticides.  The outline below briefly summarizes the significance of each
of the factors discussed and  its possible  impact  on  the  effectiveness of a
given alternative for control of pesticide transport.

     A.  Nomenclature, Chemical and Physical Properties
         1.  Product Name:  A single  chemical  compound may be marketed under
             several names.

         2.  Vapor Pressure:  All other factors being equal,  volatilization
             will be higher for pesticides with a higher vapor pressure.
             For comparison,  Toxaphene has a vapor pressure  of .2 or .4 mm
             Hg at 25 C. Nash jjt^l_.,  (1977) measured volatilization losses
             of toxaphene in  an agroecosystem  chamber to be  24% of the
             toxaphene applied to cotton  plants at weekly intervals for six


                                     504

-------
        weeks.  The rate of application  was  2.0  - 2.7 kg/hr per week
        which is within the range  used during  cotton  pest  infestations.

    3.  Solubility:  The propensity of a  pesticide  to leach and the
        effectiveness of soil and  water  conservation  practices in part
        depend upon the partitioning of  the  pesticide between soil  and
        water.  A pesticide's affinity to be absorbed by soil is
        measured by the adsorption and desorption partition
        coefficients.  Unfortunately the  partition  coefficients are not
        published for most pesticides.   Solubility  values,  however, are
        widely available and are  reported here.   In most cases,
        solubility and adsorption  are inversely  related.  Hence,
        transport by leaching may  be a concern for  a  highly soluble
        pesticide.  Similarily, soil and  water conservation practices
        which reduce the transport of sediment but  not the  transport of
        water are in general much  more effective  in controlling
        insoluble pesticides than  in controlling  the  transport of
        soluble pesticides.  For  example,  Aldicarb  (solubility:  6000
        ppm) has been detected  in  a large number  of wells  in Long
        Island.  This has not been true  of Toxaphene  (solubility:  3
        ppm)

B.  Use

    1.  Type:  A non-systemic insecticide is designed to make direct
        contact with the pest.  A  systemic insecticide is  taken up  by
        the plant and has a toxic  impact  on  pests as  they  feed upon the
        crop.

    2.  Primary Crop:  Methods  like integrated pest management for
        reducing pesticide use  are developed for  a  particular crop  and
        pest rather than for a  particular pesticide.   Hence, in order
        to determine the feasibility of  reducing  the  use of a
        particular pesticide, it  is necessary  to  know the  crops and
        pest for which it is used.

    3.  Rates commonly used:  The  amount  of  pesticide transported
        depends in large part on  the amount  applied.

    4.  Formulation:  Drift losses are highest for  dust formulations
        and lowest for granules.   Runoff  losses  are higher  for wettable
        powders.

C.  Behavior in Treated Fields

    1.  Adsorption and Leaching Characteristics:   This section reports
        the results of investigations studying the  adsorption of the
        pesticide and its impact  on transport  of  the  pesticide by
        leaching.

    2.  Persistence:  The likelihood of  transport by  runoff, leaching
        or volatilization is higher for a  more persistent  pesticide.

                                505

-------
    3.  Runoff Losses:  This section is a summary of  studies  of  runoff
        losses of the pesticide.

D.   Behavior in Aquatic Systems

    1.  Persistence in Water:  Pesticides which are persistent in  water
        are more likely to have toxic effects  on aquatic  organisms  than
        less persistent pesticides of equal toxicity.  A  higher
        fraction of the pesticide transported  by runoff water is  likely
        to reach a water body for a pesticide  which is persistent  in
        water than for a less persistent pesticide with the  same
        adsorption characteristics.

    2.  Persistance in Submerged Sediments:  Submerged sediment can
        provide a long-term source of the pesticide in the  aquatic
        system.

E.   Impact of Aquatic Organisms and

F.   Impact on Terristrail Organisms

    Toxcity data are very useful in determining the seriousness
    associated with the transport of a pesticide through  a  given
    pathway such as runoff losses.  They are also helpful in  assessing
    the advisability of switching to an alternative insecticide.   The
    following abbreviations are used in reporting toxicity  results:

    LD50,  median lethal dose, is the milligrams of toxicant  per
    kilogram of body weight lethal to 50 percent of the test  animals  to
    which  it is administered under the conditions of  the  experiment.

    LC5Q,  median lethal concentration, is the  concentration  (ppm  or
    ppb) of toxicant in the environment (usually water) which kills 50
    percent of the test organisms exposed.

    EC5p,  median effective concentration, is the concentration  (ppm or
    ppb) of toxicant in the environment (usually water) which produces
    a designated effect to 50 percent of the test organisms  exposed.

    TLm, median tolerance limit, the concentration of chemical  in
    dilution water that kills 50 percent of the test  organisms  in  a
    given  time.
                                506

-------
                                  SECTION 1

                                  ALDICARB


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

         1.  Product Name:  Temik, Ambush.

         2.  Vapor Pressure at 25°C:  1 x 10~4 mm Hg (USEPA 1975).

         3.  Solubility in Water at 25 C:  6000 ppm (Finlayson and MacCarthy,
             1973) .

B.    USE

         1.  Type:  Systemic pesticide for use against insects, mites and
             nematodes.

         2.  Primary Crops Used on:  Cotton, sugar beets, alfalfa, Irish
             potatoes, corn, peanuts (Eichers et^ al_.,  1978; USEPA, 1975).

         3.  Rates Commonly Used: 0.56 to 5.6 kg/ha.

         4.  Formulations Available:  Granules.

C.    BEHAVIOR IN TREATED FIELDS

         1.  Adsorption and Leaching Characteristics:   Aldicarb is moderately
             adsorbed to soil particles.   A recent study on the adsorption of
             several organophosphorus and carbamate insecticides determined
             relative adsorption capacities (in order of most strongly ad-
             sorbed to most weakly adsorbed) to be chlorpyrifos > parathion >
             terbufos >  phorate > aldicarb.  Sorption of the pesticides
             reached equilibrium between solution and soil within 2 hours
             after application and was positively correlated with organic
             matter content (Felsot and Dahm, 1979).  When aldicarb was in-
             corporated in a sandy loam soil at a rate of 6 kg Al/ha and
             watered with furrow and sprinkler irrigation in separate plots
             to simulate both normal and wet growing seasons, residues did
             leach beyond the 1.3 meter level; however, the researcher noted
             that concentrations of the total toxic residues were no higher
             than 100 ppb below the 1.3 meter level (Moorefield, 1974,
             reported in USEPA, 1975).
                                     507

-------
         2.   Persistence:   When three soils were treated with 20 ppm of
             the material,  percentages of aldicarb and aldicarb sulfoxide
             were as follows 12 weeks after application:  0.7% and 95% in
             clay soil,  42% and 25% in a silty clay loam and 28% and 50% in a
             fine sand (Coppedge et_ al., 1967) .

         3.   Runoff Losses:  When a bare Norfolk sandy loam field (slope ~
             1%) was treated with an exaggerated rate of 10 Ib Al/acre of
             of aldicarb and disced to a depth of 6 inches immediately after
             treatment,  8.3 acre-inches  of water from sprinkler irrigation
             and rainfall  resulted in only one "analytically significant
             residue", 140 ppb, which was found in a sample of runoff water
             taken 8 days  after application.  No other "analytically signifi-
             cant concentration" was found in runoff water, eroded sediment
             or pond water taken from the area:   the highest concentration
             of aldicarb found in these  samples was 90 ppb (Moorefield, 1974
             reported in USEPA, 1975).  Although these concentrations may be
             termed "analytically insignificant", a suggested no-adverse
             effect level  from drinking water of 7 ppb or 0.35 ppb (depending
             on how much aldicarb is assumed to come from the human diet -
             NAS, 1977)  suggests that these residue levels cannot be dismis-
             sed as environmentally insignificant.

D.    BEHAVIOR IN AQUATIC  SYSTEMS

         1.   Persistence in Water:  Moorefield (1974 reported in USEPA, 1975)
             found that  aldicarb degraded very little in distilled water or
             pond and lake water when no bottom material was present.  In
             pond water  with 5% mud and lake water with bottom silt half-
             lives were  5  days and 6 days, respectively.  When a farm pond
             was treated at 3 ppm aldicarb, concentrations declined to 1.1
             ppm after 2 weeks, 0.26 ppm after 4 weeks, and 0.06 ppm (the
             limit of sensitivity for the method) after 6 weeks.  When
             tested in a terrestrial-aquatic model ecosystem aldicarb had
             high persistence and low biodegradability when compared to other
             carbamates; oxidation products (sulfoxide and sulfone) were
             found in the water phase of the system at concentrations of
             7.4 ppb (Sangha, 1972).

         2.   Persistence in Submerged Sediment:  When a farm pond was
             treated at  3 ppm, concentrations in bottom mud peaked at 0.09
             ppm 4 weeks after application; the author reported that residues
             did not build up in sediment and that dissipation of aldicarb
             residues was rapid and complete  (Moorefield, 1974 reported in
             USEPA, 1975).
                                     508

-------






















































CO
2
co
i— i
^
^
CJ
OS
O

U
1 — 1
H

j 1
cy


z
o

£_l
£_J
<3^
CL,
2
n


•
U










c/5
4-1
i— 1
^
t/1
CD
OS














t — s
CD CD
C B fH
O -r-l 3
• H C 4-1 4-1
4-J -H rt
rt X 0 f-i
fn O fn 0
4-1 4-1 3 P-
C w B
0 t+H O 0
O O PH 4-1
i—1 k^
V-H »*1
O CD --O
U ^ C
rt


















13
0
4J
1/5
0
H

B

•H
p;
rt
bo
f-i
O

















i— i
o
LO
U





















pQ
PH
PH

O
LO
to










co
OS
PJ
u
* i
Q
O
OS
a,

>H
OS
«3^
*=i!
1— 1
Ctf
a,

Q
^r

0O -H
rt -H
fn O +->
0 P o\° O
4-1 o rt
C/J ^O OO
0 ,-H
C » fn rt
CN CN K) -H o\° O B
O O O i— 1 O <4-l f-l
LO LO LO O CTl O
U U U X 1 T3 C
_J ,-J ,-J O O 0
00 fH <4H
C -HO
rt 0 a" X
fn P 0 f-i
f> -H fn 0
rP >
C -H w O
0 ,C X O
X C rt 0
5 -H 13 fn







^"^ ^~%
/• — N fn |H
fn X X

vO Ti-
00 CTi CN
^J" ^ — ' ^ — ' tfi
^ G
B 6 0
6 PH PH -tH
PH PH PH 4-1
PH r-H rt
LO rt f-l
\Q CN \O i~| 4_)
• • • 4-i PJ
i— 1 i— 1 •— 1 00
II .— 1 O
00 CN rP P!
t**^ \O 3 O
w o
















r~*t
t/1
4-J -H

O 4-1
fn rt
4_) CJ

12 i— 1
O 0
rO C
C C
•H rt
rt X
OS U





»o
4-1
•H bO
IS CH
•H
t/) bO
•H rt
t/) t"1
0 fH
C fH
•H O
-H S
O 0
U X

n3 0
0 N
O -H
3 *~H
T3 rt
0 0
fH 0














(/)
o
•H
4_)
i — i rt
rt fn
X 4J
4-> PJ
0 0
i-H O
^1 PJ
3 O
w o












































•^t LO LO LO
o o o o
LO LO LO LO
U U U U
ij 1-J ij 1-J










fH
0
o
1 0 1
C/5 4-1 "^ t/1 4-1
- O -H -O0
,0 3 X £> 3 C
^ — s / — \ fn 13 O fn T3 O
fn fn rtOHn nJO<4H
X X OfHi-H OfHi-H
• H PH 3 -H PH 3
00 ^O HJ tSt *T3 t/)
^1- C7l i-H C i-H P,
* 	 ' v 	 ' rt O ^P rt O rP
•H fH -H fH
B B <4H4-lrt t+H^rt
PH PH OrtO OrtO
PH PH 13 -H 13 -H
B -H 13 6 -H 13
PH X r-l PH X i-H
LO PH O rt PH O rt
f-
i— 1 t— 1 O
• • • ^j"
O *3" vD

















c~|
t/1
•H
^H
c
^3
t/5

i — i
t-H
•H
bO
0
^
I-H
03


509

-------



























I — •
13
CD
3
C
•H
e
o
u
V 	 '
CO
2
CO
1— 1
§3
C3
OS
o

^J
1— t
H

1 — 1
O"


t~pfl
o

H
U

a.
^
I-H



[13


t/1
I— 1
3
t/1
0)
OS










CD CD
C 6 ?H
O -H 3
4-> -H rt
rt X 0 ?H
^ 0 ^  4-> 3 P.
C tn S
0 <4H O 0
0 0 PL, 4->
C X
O CD 13
U ^ C
rt













13
CD
4-1
t/1
0
£—1

e
10
•H
f^
rt
bo
^H
O




C
r-H 0
o s
i-H f-l
0 -H 4->
3 .-H O
O -H
rC JD O
10 rt 4-> t/1
13 0
w rt 13 4->
0 fH 0 rt
3 M ^ g
T3 0 rt rt
•H T3 PH ^
t/> 0 6 f-i
0 -H o rt
^H ,Q O O





1
1
1
1












3 CD
•> o rt
(/) 4_) J>
i— 1 C ^H
•H 0 rt
rt E 1-1
o p; rt
C -H W i-H O
*"O 'H 4-> *H 4-J
C rt • HH -H
rt w 3 1-1 3
E cr O C a*
,c; w rt C 0 w
(/J -H 1 -i-l 0 O
•H C ^H >— • ^ 6
<4H rt rt bo
bO-H 6 13
O !H fn 0 « C
4J O 4-> 4-* rt rt
•H ts> (/> -H
3 !H 0 X C 0
cr 0 fn w X rt
t/) ,d fn O p. bo
O 4-> 0 O rt I-H
2 o 4-» 0 a rt







































^
vO
• v^
/— N Ol
\O i-H
\^ \ 	 s
CT)
•-H I/)
>— ' 0
t-H / — x
•H (30
/ — i i-H / — v i-H \O
CN rt i-H 0 CTl
f*-> F*^ (*f} i— H
CTl 4-> CTl ' — '
i-H 0 i-H 13
^_^ V^ _J ^ £^
w rt O
rt 0 ^ t/)
x I-H 0 4-> A;
bO -H 4-J 4-> fH
C I-H H O rt
rt 0 rt C .-i
CO CQ U Ni U

i-H CM K) r^ LO
510

-------














c
o
•H
4J
cd
fn
•P
(S
CD
(J
c
O





















CD
O
c
CD
CD
CD
OS
10
10
CD
OS






c
•H
X
o
•p

t4_{
0







*"O
CD
•P
(/)
CD
•P

to
6

•H
C
cd
bO
0
,_,
cn
i— t
"— '
i— i
i-H
•H
ac







_





















_





















_







0
j
u




6

P,

^j-
o^
LO


T?
i-H
O

X
cd
13

LO
* — /

to
13

cd

00 i-H
Q cd
OS 2
OQ
i
"




6
PH
PH

O
0
0
I — 1
v
2
o

X
cd
















•P
c
cd
to
cd
CD


""




e
PH
PH

O
O
to

A




f — ^
13




















i— 1

=




e
PH
PH

i— 1
CO
to






f — ^
13
PH i-H •!-! i-H
o
rH
v — /

to
TJ
^
cd

^-f
cd
S


13

^
CJ
CD
e
i
bO

•H
OS

0

X
cd
*d

o
i-H
v 	 /




cd
3
a-

CD
l/l
CD
r^
cd
PH
cd


O

X
cd
13

^>
rH
\^j




00   CO

CTi   C7i
CD
H
cd
      rt
                 C7i
                 C/D
58
z   z
co
z





0
LO
Q
!_3

i — i
cd

o






o
LO
Q
i_3

r-H
cd
£3
£_l
CD
13



CD
cd
C
•H
X
1-H
•H
cd
13

0
i— i
43
cd
-p
PH
CD
0
O
cd
X
cd
TJ
adverse
i
o
c

T3
CD
•P
to
CD
bo
i
O
c
X
O
<4H

i-H
CD
£>
CD
i— I

•P
U
CD
•g

i — i

C
O
•H
•p
PH
e

adverse
i
o
c

13
CD
•P
t/1
CD
bO
1
O
CN
K
O

i-H
CD
£>
CD
r-H

-P
O
CD
bOMH i/) bfl 4-1
£3
to



4n

-------
                            SECTION 2

                         AZINPHOSMETHYL


NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

1. Product Names:  Guthion, Carfene, DBD, Gusathion, Gusathion M, Methyl
   Guthion.

2. Vapor Pressure at 20°C:  2.2 x 10"  mm Hg (Spencer, 1976).

3. Solubility in Water at 25°C:  33 ppm (Martin and Worthing, 1977).

USE

1. Type:  Non-systemic insecticide and acaricide.

2. Primary Crops Used on:  Apples, other fruits and nuts, cotton, Irish
   potatoes, other vegetables, soybeans, alfalfa (Andrilenas, 1974;
   Eichers et_ al.  1978) .

3. Rates Commonly Used:  In 1971 application rates in crops using
   azinphosmethyl averaged 0.67 kg/ha  (Carey e_^ a^., 1978).

4. Formulations Available:  Emulsifiable concentrates, wettable
   powders, dusts.

BEHAVIOR IN TREATED FIELDS

1. Adsorption and Leaching Characteristics:  Azinphosmethyl is moder-
   ately to strongly adsorbed to soil particles.  No residues were
   detected below 38 cm  in a sandy loam soil 8 years after its appli-
   cation  (Staiff e_t al. , 1975) .

2. Persistence and Vapor Losses:  Fifty percent of the azinphosmethyl
   applied to Florida muck-sand and Louisiana clay degraded within  one
   month and 3 months, respectively (Anderson et_ al_., 1974); when
   applied to a  silt loam, 90% of the material had disappeared after
   5 months  (Schulz et^ al., 1970).  Spencer  (1976) reviewed the
   limited data  on azinphosmethyl's potential for vapor  losses and  con-
   cluded that volatilization will occur at a slow rate.
                               512

-------
D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water:  The degradation of azinphosmethyl follows
         first-order kinetics and is fairly slow in acid waters.  Half-lives
         at pH 8.6, pH 9.0 and pH 9.5 are 28 days, 30 days and 7 days,
         respectively; half-life at 45°C and pH 9.5 was less than one day
         (Heuer et_ aK, 1974).  Residues had disappeared from water 2 weeks
         after treatment when the material was tested as a piscicide at
         1 ppm (Meyer,  1965).  When azinphosmethyl in water was exposed to
         UV light (2537 $) photolytic degradation occurred at pH 10 and
         pH 11 but not at pH 6 and pH 9; none of the photolytic degradation
         products that were formed at the higher pH's were insecticidal
         (Liang and Lichtenstein, 1972) .
                                     513

-------

















































CO
S
CO
rH
^
<£
CJ
OS
o

U
rH
H

*""1
cx

^
0

H

a,
S
rH
PJ

















































































I/)
•P
1— 1
3

0
Qi












, — <
0 0
C B rH
O -H 3
• H C +J 4->
P -H 03
Oi X 0 rH
rH O rH 0
•P -P 3 ft
C WE
0 4-1 O 0
O O ft -P
C X
O 0 T3
U ^ C
03














*"O
0
-P

0
£—1

E

•H
oj
too
^
O






0
U to
3 C
""cj o 0
0 -H -P
rH -P 03
03 rH X
•P JH 0 -P
0 +-> rH -H
C C O rH

X 0 .p
•P C -O rH
•H CM CM O rH O
> 0 0 0 3 B
• H -H -H O
•P X X E 0 .p
u O o 33
3 +-> H-> B 10 O
"O 1 1 -H E rC
O C C X rH -P
rH O O 03 O -H
ft C C S S S








f 	 1 / 	 \
t/) ?H

^f]
(N
•sj" t^
\^__/ \^_^1

r*) FO o ^f)
ft ft ft ft
ft ft ft ft
o o o o
o o o o
o o o o
rH rH i— 1 rH
OJ
U
a
o
Oi
a,
x ^
>-, q 0
OS 0 4-1
<£ -P CO -H
S ^ OJ rO r1
n C H 3
OS nS  0 X
Oi O Z oS 0
OJ 0 03 E rH ,£5 4-1
CO C rH o O -H
O'H'— IT3CJ O,P H
OH rH 0 X rH fcO 3
S 3 rH E X -H 4->
O oj O o3 H rH
U +-> rH rH 2 O C
oj w rC ^: oj
Q PJ U U PQ








•* ^f •* LO LO LO
O O O O O O vD
LO LO LO LO LO LO E
U U U U U CJ J
*-J I-J l-J I-J I-J k-J t~*











^-v 0
u u
/ 	 v / 	 1 / 	 s O O
U U U LO LO
o o o •
rH r— 1 rH LO LO
CM CM CM rH rH
t 	 ^ t — ^
" " " ""XX
rH rH rH rH rH Oj 03
rC XI rC ^C ,C T3 T3

^f 00 ^O ^H/ OO O O
CM ^ C7} CM ^ tO tO
\ 	 / \ 	 J \ — / \ — / \ 	 / \ 	 / V 	 '

^ O f*> O ^ O ^ O O ^ O
ft ft ft ft ft ft ft
ft ft ft ft ft ft ft
\D LO LO LO
LO CM rH CM O LO tO
• • • • « »
O O O OO rH rH



1 03
1 t/) O
f> 13 -H
3 0) C
O -H rH
ft i/l nj O
H -H C 4-1
C rH -H
ft -P Xf-i
S t/) rH 03
Tj 3 4-10
O 0
oj CW
• rH OX
I/) +-> O
Cl/) t/) rH
T) 3 03
U rH "Pi
J Oj 03 O
13 E +•> rH
LJ E 00
f> 03 0 -P
3 u w a.
H C
J HH



514

-------





































t — \
T)
3
c
•H
(3
O
U
en
HH
§
Bi
O

u
h- 1
E-

£3
O'
<^

z
0

H
^J
^
0.
2
1— 1
w










































































w
^J
1— 1
3
in
O
CK










/ — s

CJ O PH -P
O O *"O
u ^ e
rt










id
•P
in
Q)
£-H

10
S

•H
C
rt
bO
fn
O














IS 0. 0 O 0 C 0
xO O60600O Or— 1 i— 1 i— it— 1 i— I
E LO B E S LO £3 B € S S
1—3 CH) I— 3 H-3 t— i] ^J H- 3 I-J 1— 3 h-H1 I-J
H I-JHHE-I-JHHHHH










C? G1 o /-^
o o t~~ u
\o CM o
CM tO
i-H f^ i-H i— 1
'to X4343434343434343X
^J
^y- ^~ ^ '^ 00 \O ^O vO ^O \O
\O (NJ C*J CN CN ^" CTl O^ O^ O^ O^
Q
Essesesese
o o . o. o . o . o . o . f^ . f*^ . o . p .
P, PHPHPHpHPHPHPHPnPHPH
PH
CJiLOLOtOtO^j'^J'^tOCM
^f CM i— 1 i— t • CM t— 1 O i— I i-H LO
LO OOOOOOOOOO
OO OOOOOOOOOO



rt
u
• pH
•pH
u
rt
PH

rt 43
•H in
fn -P -H
33 43 MH
(DO .p (3 O C
C h 3 0 to 3
O -P O B  in
M ^H T-H PH
OS 4J rt to
< o in S rt
t o C O O
C 3 O t-n
33 -H O 43 I-H T3
co rt to o o 0
I-H aj po cj >< ctf

,-H 0
(D 42
3 rt
•H in
t/1 *rH
(D S
!H ^
ID
*T3 PH
o o (D m
r— 1 i-H .p (DrH
B e rt >
H H -P 430)

rt
43 i-HO)
in I-H
•H OO






to to
43 43

vO ^O
CT) CTl

B S 6
PH PH PH
PH PH PH

LO
0 O
O to O
O to I-H











-------
                               LO








































-o
CD
3
C
• H
C
O
u
I-H
fvj
O

cj
rH
H
^
O
O^
<£

2
O

E~"
CJ
^
D-i
s
1— t
w















































































i/)
+-*
i-H
3
t/)
CD
oi










/— \
CD 0)
C 6 rH
O -H 3
•H C 4-> 4->
4-> -H Cd
Cd X CD rH
rH O rH CD
4-» 4-> 3 P-
(3 to 6
CD (4-1 o CD
0 O PH 4->
O CD T3
C 3 '*— * C^
cd









TJ
CD
4J
(/)
CD
L_^

e
t/i
•H
C
cd
bO
^i
O







CM
^-1
C
•H

f^
O CD
•H t/1
4-» Cd
U rH ^
O 3 rHi — 1 i— ) OOOOO
B -H
C rH
cd O
o f~l
•H O
•H C
Pi -H
oo cd
•H £n

CJ CJ
O O
f^« to
• .
CN 00
i— 1 i — I

/— ^ ^"-"\ /— -\ /^^i /-— \ ** •*
rH ?H rH ?H JH ?H pH
X 45 45 X 45 X 45
*-JD ^O vO \O vO ^ ^3"
CFt C7i CTi CA CT> CM  r-H r— 1
to o CM co ^ CNJ CD o
• • •.*...
rt-o oooooo







r^
tn
S -H
O <4-l
C C
C 3
•H tO
6
45 X I-H
W I/) 13 "—I
•H -H Cd -H
4H 4H CD bO
T3 t3 c1, p , CD
i-H i-H 4J fH 3
O O Cd Cd rH
u cj PH c_j ea

0)
to
cd

0
•P
t/j
0)
C
• H
r-l
c to o
OO OO •— 1 i— 1 X
t ~] , "] t ~] l •]
H H H H C
•H
cd

^.r^

rH
cd
^
f_|
O
C
U t/i
o /-s p;
00 CJ O
O -H
to ^ 4->
CM CM Cd

^ ^ / — ^ / 	 ^ 1 1
rH M !H fn PI
X X X 45 CD
CJ

CM 'Sr Oi Ol O
U
S S E B rH
PH PH PH PH X
VO CM CM LO CD
rH O CM O rH
C) O C^ CO r*i
3
O O O O (fl




f-]
V)
• H

f- '
3


T?
0)
(D

C
• H
^L
PH

r^
&H


1
X
CD

fH
CD
X
4->
O

cd
• »v
^
0
i-H


X

>
o
o
CD
rH













































cd

n3
cd
X

^_,
CD
4->
cd
i-H
t/)
v^
CD
CD
3

CM

rH
3

O
PH






















































4->
O
<4H

CD

CD
>
•H
4->
rH
3

^
O












































516

-------
nd
 0

 G
•H
P

 O
u
co
oo
o
u
o
H
OH
PJ
                  p
                  t/)
                 as
                  0
           c  -P P
          •H      CTi
              0
       rH  O  rH  0
       •P  -P  P  PH
       C     Wg
       0  <4_|  O  0
       O  O  PH P
              X
              0 13

                  rt
                  0
                 H-)
                  to
                  0
                 H


                  CO
                 •H

                  §
                  M
                  rH
                 O
                        00
                                      U
                          01
                          PH
                          LO

                          to
                                 en    O
0 CO S v—/ CT>
(3jQ ""^ '^ ^ y_^/
G G G 0
•H rt rt p co
rH CO rH
0 > 0 CT3 0
,X OJ AS rO t3
0 ,G C cr) C
•H Cd 0 rH Oj
a, i-j 03 < co
to TJ- LO vO t^
i — 1 I— 1 i — 1 I — t rH


• 00 • ^-N
/• — \ vO / — s ^D
^^ Cn OO ^O
LO rH SO C^
CT> v — ' O rH •
I— 1 rH * 	 ' / 	 v
V 	 ' C V 	 ' CTl
O C ^3
co 0 -H en
rH p • PL, UH rH
oj bO ^^ o P ^
/-v rH Oi CJ Ctf
to p 0 \O u . .
\o 0 P-, en T3 / — v I-H
Cn rH f^ ""O LO Cti
rH *4H *"O ^-^ CJ G ^O
v— ' <4H G nJ O) -P
O ai co co rH 0
rH C rH rH C ^
0 Cfl -H 0 0 0 ^
rHtO>'OT3tO00
•POcrcGGPHO
POcSrtrt0ort
oSi-JZcocoi-juS

i—irMtO^t-l-OvDt^OO

























CD ^3"
en en
rH rH
v — J \ — '

rH rH
0 0
•P +-*
tO H-)
•H CTJ
rH +-)
rH CO
< • ^
o ^-\ rt
^-> S LO u
vO \O
^o ro en T3
Cn G rH C
rH Oj ^-^ CTJ

^4 rH CO
0 0 0 CO
PH 0 X -H
O CTJ 0 0
U S 2 2=
O rH CM
CT> rH rH i— 1
                                                             517

-------
t/1
I— 1
J3
(/)
CD
OS








/ — s
C CD
0 B
•H C -H
.p -H -P
cd x
rH O CD
•P -P rH
S 3
Q) M-l -]_]

/— N /— \ /""N



V ^ K



» — r



^ fc ^

x*-/ v— / x— /

B B B
o. o . o .
Pi Pn PC

o
o o o
o o o
CN in i^
i i i
o o o
000
00 •fl- VD
rH









rH rH
•H -H
cd ctf
3 3
o* o*
to
•P CD X
C -P -H
Ctf -H C
W X rH
ctf S 3
CD XI -P
rC 0 0
O. CQ U










CN
O
in
Q
r—3

rH
rt
j_(
o
1





CN
O
in
Q


i— H
ctf
g
M
CD
13
1O
X
rH
• H
Ctf
13
1— (
rD
Ctf

PH
CD
O
O
Ctf

g~
3 CD
S ^
•H rt
r*^ 4— J
ctf C
B -H
4
intake

X
i — i
•H
Ctf
T3

CD
rH
ft
Ctf
•4_)
PH
0)
o
o
ctf
O
<£
CD
CD
rH
CD
>
13
ctf
1
O
C

13
CD

{/)
CD
bO
W)
3



i

O
CN
X rH

B C
0 0

<4H 4_>
p t
1—1 B
CD 3
> w
CD I/I
rH Ctf
CJ
CD
CD
CD
rH
CD
>
13
ctf
i
O
C

TJ
CD

to
CD
W)
bO
^
to


i

O
CN
X r

B
0
rH •


rH
0
>
CD







— <

r^
O
H
P
PH
B
3

(/}
ctf
          S     3


          bO    bO
                      txO
          B°
                bfl
                      O
                      O
                o
                CN
                CN    O
                                X
                                cd
                               13
bo



LO
CN
rH

O


O
                                      bO
                                      3.
                                      UO
                                     00
                                                   bO
                       10
                       C
518

-------







































, — ^
T3
0
3
C
•H
^_j
c
0
u
v— '
CO
s
n
§>
CD
OS
O

»_3
<£
1 — 1
o£
f— *
co
w
o2
OJ
H

*^'
0

&
^
OH
hH
p/












































































i— i
0 at
0 t/i I-H
rO 3 4-*
M •> O
0 o S rt
> X rt t-t
rt Pi .*"! -t-1
X w co
o — i
(/) x; T3 rt
0 PH d C
o o rt -H
C C +J
rt rt C w
o bo O 0
3 5n ,C +->
h O t/> C
J_J t i ,_J
4^ r* M
w o 0 o
•H +J U M
13 W
(J 0 (/) rt
•H (/) H too
fn O rt
rt X X,C
•H 0 4-)
JS 0
0 X--H 6
X"-H O
t/1 T3 O f-i
P^ 0 4-> M-l
-p
• ^ rt CM 'Q
^1 0 -^ 0
O Q i i~~l ^0
4-> 0 1 1-1
•H f-l rH O
,£> t/1
• H 0 <4-l £>
X h o rt
C 0
• H S t/> X
T3 i— 1
UJ O O -H
rC .'"I "H T3
U S h rt
0 0
rt W PH ^1 •
?H /~~N
t/i 0 fn t/) vO
•H ^ 0 -H r~-
>— I O O i— I i— I
X S X
4-1 (3 0 4.) -H
6 ' -H g N
 JS 0
PH ^ 0 &,4->
(H O 0 C 4->
• H PH I/) -H 0
N 0 C N >
<; f-i -H <; ^— '


• •
4J
C
0
&
2
o
CJ
^
0
0

































































































































.
/— \
rt
o

o^ •
>— 1 ' — .

^
• Oi
I—) / — \ 1— )
rt oo ^-^

•P Oi
0 ^H
^ i u
C3 • »» •
f »H / s
SI t~»
OS • si r^
U rt o>
rC " O ' 	 '
4-* 0 4-*
rt in 4J CO
0 rt 0 •<
t-l CM tO ^t
519

-------
                                  SECTION 3

                                  CARBARYL


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Sevin, Hexavin, Karbespray, Ravyon,  Septine,
         Tricarnam.

      2. Vapor Pressure at 26 C:  < 0.005 mm Hg (Stansburg and Miskus, 1964).

      3. Solubility in Water at 30°C:   40 ppm (von Rumker et^ al_.,  1974).

B.    USE

      1. Type:  Broad spectrum contact insecticide with slight systemic
         properties.

      2. Primary Crops Used on:  Soybeans (the use of carbaryl accounted for
         46.8% of the 7.9 million pounds of insecticides used in soybeans in
         1976), corn (use accounted for 6.6% of the 32.0 million pounds of
         insecticides used in corn in 1976), tobacco (use acounted for 15.6%
         of the 3.2 million pounds of insecticides used in tobacco in 1976),
         peanuts (use accounted for 12.5% of the 2.4 million pounds of insec-
         ticides used in peanuts in 1976).  Other grains, hay and forage,
         cotton, alfalfa, vegetables,  fruits and nuts (Andrilenas, 1974;
         Eichers et^ al., 1978) .

      3. Rates Commonly Used:  1.12 to 2.9 kg/ha, one to ten applications per
         season; in 1971 application rates in soybeans ranged from 0.90 to
         4.30 kg/ha (Carey e£ al_., 1978).

      4. Formulations Available:  Wettable powders, granules, dusts, pellets,
         sprayables,  flowable suspension in non-phytotoxic oil and molasses.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Carbaryl is moderately to
         strongly adsorbed to soil particles.  Haque and Freed (1974) have
         estimated that leaching will move carbaryl less than 20 cm through
         loam soil under an annual rainfall of 150 cm; however, when 1000
         liters of 3% Sevin were applied to the soil, residues were detected
         50 to 60 cm down in the soil profile for 5 to 20 days after the
                                      520

-------
         application (Nalbandyan,  1974).

      2. Persistence and Vapor Loss:   Insecticidal effectiveness persists for
         3 to 10 days on treated plants  (von Rumker et_ al.,  1974) .   The
         persistence of carbaryl in soil  depends on the organic matter con-
         tent of the soil and pesticide  application methods.  When carbaryl
         was applied to soils high in organic matter,  half-lives ranged from
         2 to 3 days (Alt and Heady,  1977) .   When carbaryl  was banded into
         corn furrows and incorporated to a 5 cm depth, 135  days were required
         for a 95% disappearance of residues; broadcast applications resulted
         in a more rapid degradation of  carbaryl (Alt  and Heady, 1977) .  There
         are indications that volatilization may transport significant amounts
         of the carbaryl away from treated fields (Lyon and  Davidson, 1965) .
         Haque and Freed (1974)  have used the best available information to
         form a vaporization index; according to their estimates, carbaryl
         may have vapor losses which amount to 3.5 to  14 kg/ha/year or more
         from a loam soil at 25°C under  an annual rainfall  of 150 cm.

      3. Runoff Losses:  When corn grown  on a silty loam soil (slope 9.6%)
         was treated with 5.03 kg/ha of carbaryl, 0.15% of the pesticide was
         transported away from the field  during the 3  months following treat-
         ment,. (Caro ej^ al.,  1974) .
             *•-«
D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water:  In raw river water (pH 7.3 to 8.0)  held at
         room temperature,  95% of the material disappeared one week after
         application and no residues were detected after 2  weeks; the
         suspected degradation product 1-napthol was not detected after the
         original carbaryl  had decomposed (Eichelburger and Lichtenberg,
         1971).   When the rate of degradation by chemical hydrolysis was
         tested in a solution having pH's of 7.0 and 9.0, the half-lives
         were 10.5 days and 2.5 hours, respectively; the degradation product
         was 1-napthol (Faust and Gomaa,  1972).  Aquatic bacteria degrade the
         1-napthol while using it as a source of carbon (Paris and Lewis,
         1973).   The exposure of carbaryl in ETOH or hexane  solutions to
         mercury lamps (2537 ft)  or natural light caused the  formation of
         1-naphthol and several cholinesterase-inhibiting materials (Crosby
         et_ al_. , 1965).

      2. Persistence in Submerged Sediment:   In sea water,  decomposition of
         carbaryl was slower in the presence of mud than it  was in the
         absence of it (Korinen et al.,  1967) .
                                     521

-------













































CO

CO
H- 1
^
5
(_3
Pi
O

fj
I-H

^
^
O'
*£
,_,
o

H

^
D-.
2
i — i

tu









(/)
P
i — i
3

O
oi










0 CD
c e f-i
O -H 3
•H C P P
P -H Cd
cd X 0 5n
H O H CD
P p 3 p.
PI «E
CD <4H O CD
0 O PL, -P
O CD 13

cd












2

i/i
CD
H

e

•H
cd
bo
fn
o









to
^o c
i-H 0
PI «N H
O 1 PL, P
•Hi pi CJ
•PC -H -P CD
•H CD cd MH
Xi u 13 •« MH
•H c CD x fn 0
XI O W P CD
C 0 cd 5 +-> p>


w
H
(/)
0

^J
E^

o
p ^d"
O 13
•H CD O cd CX CD
w f-i H CD en cd
PI cd O bo H O
•H C bOH -H
X -H 13 PL, «4H
CD P CD C -H
t/) 3 PI POP PI
cd O O -H -H cd bo
CD fH -H XI P -H
(H bO 4.) -H -H C t/>
CJ cd X X> cd
P; m SH c -H x o
•HOP -H X P PI

6
PL,


LO
(N

o e

Pn '
i-H 1
O i-H 1
1
O O 1
A
to
on
m
u
Q
o
a
a,

^4
C£
^ cd cd
,g t 	 v W t/)
r-H W O O
Oi CD 13 13
CL, 4-> -H -H
CD cd O O
Q cd I-H PI C
Z bO O CD CD
 CD CD
2 X CD H f-l
O f) (/) O O
CJ 0 > — ' i-H i-H
PJ fH X X
a u, u u

pt , fXj
QH ^"
13 O 13
C P 0
cd tn P
cd
X X PI
P P -H
.2 s e
O O -H
H fn I-H
bO bO 0








E E
PL, PM
PH PH
i— t i-H
•
O








B
3

3
t-t
O -H
0 H
•H 0
fH X
4-> 4->
3
S I-H
3
•-H W
X -H
P W
0 X
cd ^H
13 X
0 0
0 O
cd C
X O
a. s

1
•H ! PI 13 i
g i o -H cd t/i 0 i— i
•H 3 -H 0 e o t-H
l/)6*OW|-HOtMCd
tn -H 0 c o o
CdPfnOl3i-Ht+H4-> v£)
t/) PH *H i^ O e Cd 0
C P 3 -H 31
Q (/) t/1 Cd O i-H 0 PI 13
xi to f-t ^H ^ cd fa o *H
FH CB O -P bO -H (/)
Cd E XI CH m i-H P -fJ / — ^ 0
OOP0EcdC«Ot/l JH
•H 3 CJ 0 0 3 i-H
* X1 cd C p 13 3 13 0 13
(H Ot/)0CTO> 0
0 *O 0 U X t/1 0 JH 0 4-*
X) C X w cd Pn O
,-H4->p133 PCO C
0cdcd0cro-H0H o


**
E ** — ^
PH W
PL, X
cd
,-H 13

T3 to
Pi to
cd ^
i-H 1
. 1
0 1










cd
13
3 6
0 3
•H O
!H Cd
13 -H
cd "O
3 IH
cj4 cd
o
i/)
3 E
B .H

0 'c
13 0
0 bO
« £
0 13
CJ 0
CO O

522

-------








































t — s
TJ
3
C
•H
c
0
u
\ — '
HH
o;
o

u
n
<
cx
^

^
0

H
U
<£
5s
hH
W









































































(/)
•M
r— (
3
C/l
0)
Di










0) 0)
C S H
0 -H 3
•H C 4-> 4J
4J -H rt
rt X <1> f-i
^H O ^ O
4-J 4-> 3 P.
C to g
0) 4-1 O CD
0 O PH 4-1
C X
o a) -a
u ^ c
rt







0)
4-1
to
(U
H
S
•H
C
rt
60
fn
0






rt i f-i
O rt 
t^~ g 4-> rt
o a> c 5
•H x; cu
4J O O C
rt c -H
fn 4-1 O
O O •-!
C rt
O C O 0
•H O 4-> -H
4J -H e
rt 4-> B (U
i— i rt i/) xl
3 f-l -H O
i 4-> c
3 C rt 4-i o
O (1) 60 O O
O U M O
rt C 0 C rf
O 0 O
•H O C -H 1/5
,O v_^ .,_| +J .H






1
1
1
1
1
























o
rt
60
rt

o
u
         oo     oo
            o     o
            LO     LO
           u     u
           UJ     PJ
                       vO
                        4-1
                         O


                         O
         rt  f-i
        rH  0)
         3
                            rt
                         3
                         O
                         O  rH
                         rt  rt
                         o  C
                        •H  -H
                        ,0  t>0
                            •H
                         O  M
                         C  O
          u
         o
          LO
           00
           £>
           PH
           PH
 U
O
 LO

 LO
x:

00

^_y


 PH
       U
                                        CT)
                  z
                  w
                  CQ
                          o  a>
                         •H  4->
                         4->  rt
                          rt  ^
                          ^  a>
                                                 X
                                                 -p
                          C  O ^H
                          O

                          O
                          O



                          I
                         •H
                          X
                          rt
                            -p  rt
                            1-1  O
                            3  6
                            O
                            O  4->

                            t/)  O
                            6  x:
x:

CM



 e'

 PH

LO























I/)
a:
HJ
^
5





i
i/)
c
rt
f-i
0)
o
o
ro
rt
i — i
U

• •
to
c
rt
0)
O
rt

to
3





(/)
3

rt
i — t
3
f-i

0)

X
0)
1 — 1
3
PH

rt
•H
C

PH
rt
a

t/)
3
i— i
rt

PH
0)
u
o
6
• H
to






to
OJ
£_ 1

rt
c
60
rt
S

rt
•H
G

PH
rt
Q
a;
OQ
w
H

U4

^*i
i— i

o^
h- 1
S
X
(U
4-1
•H
Xi
3
4-1

X
CD
4H
•H
f*i
3



. .
l/l
(U
^J



                        O

                        o
                                                                                    rt

                                                                                 i   o
                                                                                    c

                                                                                TJ  PH

                                                                                §J
                                                                                rt  
-------





































CD
3
C
,_J
P
C
o
u
V — /
CO
1— I
1
o
u

H

p3
^y
^

2^
o

E-
O
PL,
IS
h- 1





C/)
^_>
i-H
3
to
CD
OS










/ — -\
CD CD
C 6 H
O -H 3
• H C -P -P
p -H rt
rt X CD h
f-i O *H CD
•P +-> 3 ft
C w g
CD 4-1 O CD
U O ft -P
C X
O CD 13
U ^ C
rt








CD
•P
CD
H

E
i/i
•H
C
rt
bo
!H
O




i— i
O rt
•P O
h-. -H
O W g
•H 6 CD
P  C -H -H
i-t rt -H 4->
3 M rt ^
g .p ^H ^ ^
3 C rt +-> CD
U CD 0 G -P
U O -H CD rt
rt C g 0 5
O O CD C
•H o x; o c
^3 > — ' O O -H





1
1
1
1
1















_£-
C/)
.H
4-4
^^
rt
fc
u







  M     CM
  -*     i—I
     O     O
     LO     LO
   u     u
   pj     1-J
  o
  LO
u
J
                           o
                           LO
                         u
  o
  LO
u
                                         o
                                        U
M     CM
H     i—I
   O     C
   LO     LC
 u     u
  o
  LO
u
o      •«*•    LO
H      !—I    I—I
   o     o  o
   LO     LO  LO
 u     u   u
 >J     hJ   J
u
0
LO
LO
1 — 1
£
Tj-
u
o
LO
LO
i — 1
fH
00
u
o
LO
LO
rH
fn
X
vO
u"
O
LO
i— I
X
^f
u
o
LO
1— 1
fl
X
00
U
o
LO
LO
1— 1
£
vO
u
o
LO
LO
I— t
£
rt
u
0
LO
LO
« — 1
?H
OO
u
o
LO
LO
i — t
•\
X
\D
                  C7>
    O


    LO
                                 ft


                                00

                                VO
                              ft
                              ft
                      XI
                       ft
                                                                             I
                                                                             PH
                                        LO
                                                                                   u
                                                                                  o
                                                                                   OO
                                      ft
                                      ft

                                     O


                                     CM
 I/)
TJ
 rt
• H
 rt  rt
 C  -H

 X rt
CD  rt
C I-H
O <-t
•P  CD
t/1  O
    rt

rt  O
•p  ^
O  CD
CD +->
I/) CL,
                              X
                              o

                              rt

                              O
                                                                     in
                                                                     i—i
                                                                     U,
                                                                             3
                                                                             o
                                                                             O
                                                                            XI

                                                                            •H
                   524

-------







































f — N
*"O
CD
3
C
C
O
U
\ — '
co
CO
2
U
Di
0

U
H

|~~i
Cf


*^T
0

H
U
^
0,
2
>— 1
w

























































































in
P
i— i

in
CD
oi
CD CD
C 6 fn
0 -H 3
• H C P P
P -H 03
03 X CD fn
fn O fH CD
P P 3 P-
C w 6
CD <4H o CD
CJ O PH P
C ?S
O CD T3
U ^ C












CD
4_l
in
CD
H
in
s
w
•H
C
o3

fH
O















vO
i-H t^ C^~ I~^ 1^ t^-~
O 1— 1 I— 1 1— 1 rH f— 1
LO s s s B B

J H H H H H
















/""•N (*""•%
— ^_^ ^_^ t . t i
A^^ fi r^ ri rH
f-i fn fn 5n rC ^2
,C X X rC
vD ^O
OO ^O vO ^O O*i O^
•^t o^ 0.1 o> ^^ ^-^
v — ' v — / \»_/ v — '
B B B B H PH
o. rv o . o t QJ o .
PH PH PH PH
CN •*
LO o oo r^
i— I \o
r-H CN] ^-1











rC W

•H o3
r^ (4^ o
P CCJC

o B CD in P
fn I-H PH 3
P 03 hO
in S 01 S
C O CD CD
S 0 rH W)
O ,C .-H T3 ^i
fH O CD CD oj
CQ t_) >H OS J

OO
r-l C
CD O
4J -H
03 P
rH CD
3 P h
SCO
<* 3  in 3
T3 in -H T3
•H CD i— 1 -H
r3 3 o m
T3 XI CD
X -H 03 SH
in in P
•H CD CD 4-1
MH ?-i S 0
G"
0
^~

T3
oS

OJO
C
•rH
c
S

PH
in

*"C3
C
03

i-H
03
^
•H
£>
J^
3
in
i
•H
X
0
p
CD
. — i
r*i
03
P

CD
CJ
o
03

B
3
B
•H
X
03
B



C
0
•H
p
OS
fH
p
C
CD
O
C
O
CJ

p
C
03
CJ

f — ^
fH


\Q
CTl
V — /

S
PH
PH

CM
CO*

r — N
fH


vQ
a\
V — J

B
PH
PH

VD
^
P- ^~~.
fH CD
CD fH
P 3
i in
bo O
C PH
0 X
iH CD
^ — '

E
PH
PH

00
VO
o



e
PH
PH

00
^O
•
0
1
, — 1
Csl
o
                               in
                               •H
T3
03
CD
.C
P
03
525

-------



































^
*^
0
3
C
•H
C
O
u
CO
c/3
h- 1
§
OS
0
u
£_
 0)
C 6 h
O -H 3
• H C 4-> 4->
4-» -H rt
rt K tt) (H
JH O f-i 0)
4J 4-> 3 ft
C w g
0 <4H O 0)
0 0 ft 4-1

fj v^^y f-<
rt











13
4-1
W
H
w
6
t/)
• H
C
cS
W)
^
o








^O
f~^
(/) O
•H
<4-l II

•H 01
TT 00 4-1
t^ i— i r- r^ i— i a; ca
I-H O i— i i— i o 3 5
6 LO 6 6 LO T)
,-j u J ,-J u -H c
H nJ H H .-J in -H
0)
fH (1)
3
<4-l 13
O -H
(/)
O 0)
4-1

/• — \
u
o
^
CM
s~~*\
f — % " f — S t 	 \ / — N V)
rH W rH r4 r~t ^**
ff^ TC^ |C*^ tf^ r^ ft
T3
^O OO *>O ^O ^^
CTi ^f O O CM to

g 6 6 6 6
ft ft ft ft ft
ft ft ft ft ft
i
tO LO 00 ^t 1
1
LO CN vO O tO 1
(N 1









w
•H T3 rC
*4H rt 1/5 4H
C O -H W
3 4= ^-l -H
U1 ^H 4-1
-H C
.-H 3 -H O
i-t 43 3 4J
•H CT -H
bo ^O3
ft a* o I-H cr
fn 3 (4 £H V)
03 i— 1 rH rt O
U CQ PQ X 2

C
rt
t/1 -H
0) 3 T3
CT> 1 > O -H
i—4 ^ *H ^ ^H
(n T3 O fl fn O
42 rt C w
•— I •" g O
rH T) X 0) f-(
0) C 4-1 (U 42 0
£ rt -H *H 4-1 -H
i— 1 <1> g
W 42 rt S 4-1
rt (/i 4-» o rt
•H J-l 0)
S 4-1 o fn w X

f-l rH 42 O 4-1
&0 O 0> 4-1 -H g -H
£-1 rH C/) 0) I/)
W C 4-> 0 > W ^
4-1 U i— 1 0 -H W ft




/ — *
l/l
o
g

LO

o
^
,_!
^-*
1
1

1
1




















r^
W
•H
PU

526

-------
73
 CD
 3
                                                                      t^
                                                                      \O
                                                                      o>
 o
u
to

to
I-H
u
OS
o

u
t—I
H

3
cx
<:


§

H
U

OH
S
                 cd
                LO
                CTl
                                      C7i
co
UJ

g
       o
       PL,
                •-i   a.
                 cd   -H
 CD|   CD
     •H
 f-t   +J
 CD    t/1
i—I   -H
 I)    t.^

 3   ^
pa   u
                           •M
                           rs
                            nJ
                           O
                           U
                         01
                         vD
                                 CD
                                i—i
                                 CD
                                      -a
                                      cd
 O
,£>
 C
                                                 t-
                                                 r-
                                                 en
cdl

+J|
CD|

CD

cr
cd
                                                       CD
                                                       PH
                                                       O
                                                      U
 cd

 (/i
 H
 CD
13

 cd
to
                                                            oo
                 c
                 o
                 w
                 3
                 W)
                                                            T3
                                                            C
                                                            n}
                                                            cd
                                                           2
                                                       CD
                                                       I/)
                                                       CD
                                                       CD
                                                       !H
                                                      pa

                                                      T3
                                                       C
                                                       cd


                                                       s
                                                       ^
                                                 r-^   
-------































w
S
to
rH
OS
O
I-J
<
OS
H
w
OS
OS
w
E— 1

r^
o

£_|
Qj
 CJ U U
I— 3 i-J t— •} i-J

rrj *"rj
0 0
0 0 - r :
TJ C
0 03
03 rH
0 CJ
£_(
P to
X - - -
to o3
X '"d
oi

"~ •" •-
to X
^ — ^ rQ \ — -* >. 	 s v — *
g -o eg s
p , CD ftj ft( ft)
ft £ ft ft ft
O
O rH O O O
O rH O O O
O O O O O
LO MH LO LO LO
A A A A









f~H i~H
•H -H
03 03
3 3
Cr O"
t/)
to p 0 X
T3 C P -H
rH OJ -H C
03 I/) ,C rH
rH 03 £ 3
C/D rH 0 J3 P
Q 03 ,£ O O
os s cx, ca u
rH
CQ

               to
CM
o
LO
Q



rH
03
f-l
o




CM
o
LO
Q
I-J


i-H
03
B
^4
0
T3


X
rH
•H
03
0
rH
,0
03
p
ft
0
CJ
CJ
rt

£2
3
g
•H
X
03
g









0
i— (

^J
CJ
0
<4H
^H
0

t-H

C
0
•H
•P
ft
g
3

t/J
oj
adverse
i
0
c

13
0
P
to
0
bO
bfl
3
t/)
i
O
CM
ffi
O

rH
0
J>
0
rH

P
CJ
0
m
(4.4
0

CM

C
o
•H
P
ft
g
3

(/)
nJ
    s


    bo
           W)
    biQ     t*0
    g      e

    t^-*     O
    o     o
    to     O
          CM
f>

 bo
 bO
 g
                            X
                            03
 bo



CM
oo
O
                                  bO
                                                bO
                                               OO

                                               CM
    i/)
                  3
528

-------













































/ — s
13
0
3
C
•H
•P
c
0
u
V 	 /

co
^
co
HH
z

U
a;
o

j
<£
I-H
Oi
H
co
OS
OS
UJ
H

JgJ
o

H
^
i— I
C
rt
i
e JH 5
rt 0
C -H
w 0 >
000
•H ,0 fH
O
0 0 OS
p, > <
i/i rt D-.
J3 OS
erf c/1 O
e c f-i
•H rt Pn
c s
rt 3 h
rH 13
rt C C •
!H -H 3 X
0 P
> O X-H
0 -H i-H O
10 4.) 4J -H
rt C !«!
C ^H 0 O
•H W P
0 0 O
X G fc -P
bO-H p, 0
0 C 4H
i— 1 -H t/)
O P -H 13
•H Cfl C
X 0 I-H rt
t/) fH X
,C o fn X
PH rt rt P
0 O fn O
> p rt -H
•H U (S
4J 13 0
O -H M
30 • o
13 rt ^-^ -P
O \O CtJ
f-i o r- h
PH C 0> 0
0 .H i— 1 -P
?H £
cd •% 0
C -H i-H
O X N XI
fn N -H
t/> ni a) i/)
P C ^H W
O -H O O
0 fn -P P*
-H 3 P
<4H 0 <4H
0 13 > O
0 v — '
0 W 0
to rt 13 w
H 0 0 3
0 ^H •P Cti
> U £H U
13 C O 0
<^ -H PH X>


t/1
•P
c
0
s
6
O
u

0
o


















































































































































•
f — ^
rt
o
f^ f — ^
O^ \D
I-H r^
^— * 01
i-H
i-H 1 r—\
ns| oo -H ^-N
f^. w 1*^
p| a> N r^
01 r-H Ctf CT>
> — ' fH i-H
JC 0 ^
•P 0 4->
rt f-i +J w
0 rt 0 <
DC S > Z
i— 1 CM f) •*
529

-------
                                  SECTION 4

                                 CARBOFURAN


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Name:  Furadan, Curaterr.

      2. Vapor Pressure at 33°C:  2 x 10~  mm Hg (Cook, 1973).

      3. Solubility in Water at 25°C:  700 ppm (USEPA, 1976).

B.    USE

      1. Type:  Broad spectrum systemic insecticide, acaricide and miticide.

      2. Primary Crops Used on:  Corn (the use of carbofuran accounted for
         30.9% of the 32 million pounds used in corn in 1976), peanuts (use
         accounted for 20.8% of the 2.4 million pounds used in peanuts in
         1976), alfalfa, rice, sorghum, soybeans, tobacco, wheat (Andrilenas,
         1974; Eichers et^ a^., 1978).

      3. Rates Commonly Used:  1.0 to 5.6 kg/ha, one application per season
         for soil treatments, one to two applications per season for foliar
         treatment; in 1971 application rates in field corn ranged from 0.28
         to 2.58 kg/ha (Carey et_ a^., 1978).

      4. Formulations Available:  Granules, flowable paste, wettable powder.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Carbofuran is moderately
         adsorbed to soil particles.  Field studies in a Nebraska fallow
         field and a Georgia tobacco field indicated that residues generally
         remain in the upper 30 cm (USEPA, 1976).

      2. Persistence and Vapor Losses:  Carbofuran?s persistence in soils
         varies greatly depending on manner of application, soil pH and
         microbial populations.  The half-life of the material was 117 days
         when furrow applications were made on an acidic heavy textured soil;
         broadcast applications on a more neutral soil resulted in a half-
         life of 46 davs (Caro et^ al., 1973).  High microbial activity in a
         soil can reduce the nersistence and insecticidal effectiveness of
                                      530

-------
         carbofuran (Williams e^ al_., 1976) while in other areas degradation
         can be so slow as to cause a build-up of residues after 2 successive
         years of treatment (Williams and Brown, 1976).   Studies have shown
         that 50% of the carbofuran hydrolyzes to its phenol in 30 days; the
         phenol then becomes an unextractable residue with a half-life for
         extractability of about 7 days (Knaak, 1971).  No data was available
         on vapor losses (Spencer, 1976).

      3. Runoff Losses:  Caro et^ al_. (1973) studied carbofuran in runoff from
         a silty loam soil with soil treatments by broadcast and in-furrow
         applications and reported losses of 0.5 to 2.0 percent of the
         original material.  Although the carbofuran applied as an in-furrow
         treatment persisted for a longer period of time (117 days versus
         46 days for the broadcast material), runoff losses were less for a
         given volume of runoff when in-furrow applications were used.  Run-
         off losses were transported primarily in the dissolved phase of the
         runoff and were higher after the granules had dissolved and released
         the active ingredient.  Smith et_ al_. (1974) have studied loss of
         carbofuran from conventionally tilled corn grown on claypan soils
         and found larger runoff losses than those reported from silty loam
         soils.  Carbofuran was applied at a rate of 1.12 kg Al/ha, and
         suffered single event runoff losses which ranged from zero to 10.73
         g/ha in 1971, 32.4 to 56.6 g/ha in 1972, and zero to 161.5 g/ha in
         1973.  Maximum single event losses in each year in terms of a per-
         centage of the material applied consisted of .96 percent in 1971,
         5.05 percent in 1972, and 14.42 percent in 1973; maximum concentra-
         tions in water ranged from 298 to 600 ppb in the three years of the
         study.  Lysimeter studies have indicated that 20 to 30 times more
         carbofuran is transported in the dissolved phase than in the sediment
         phase of the runoff (von Rumker et^ al., 1974).   It has been shown by
         Smith et_ al. (1974) that on claypan soils the runoff losses of
         carbofuran from corn grown under conventional tillage will be equal
         to, or smaller than the runoff losses from corn grown under conser-
         vation and no tillage production systems.  Conservation tillage
         methods which reduce water runoff may be more successful in reducing
         runoff losses of carbofuran from soils lacking claypans.

         The FMC Corporation has conducted runoff studies (reported in USEPA,
         1976), and found carbofuran residues of 1 ppm in a neighboring pond
         when heavy rainfall followed four days after corn treatment with
         4.48 kg Al/ha.  This contamination was reduced to "negligible"
         concentrations by the time the next sample was taken sixteen days
         later.  As the 96 hour LC_0 for ten fish species range 0.08 to 1.18
         ppm, (Pimentel, 1971), these runoff losses constitute a serious
         threat to non-target species.

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water:  Studies in model ecosystems have shown that
         carbofuran hydrolyzes rapidly in aquatic systems (Yu et al., 1974)
                                     531

-------
and degrades to water soluble materials which do not persist or
remain at high levels (Sanborn, 1974).   Applications to flooded rice
fields showed maximum concentrations 14 hours after application
whereupon residues quickly dissipated,  having a half-life of one
day or less (USEPA, 1976).
                             532

-------






































C/D
IS
CO
1— I
SH
«3,
^D
OS
o

1— 1
1
ex
**•
2
0

P-H
tj
<£
ex
h-H
W






























































to
4-1
i— 1
3

0)
OS











(U 0)
c e *
O -H 3
4-> -H rt
rt X 
4-> 4-> 3 P.
C 
G X
O 013
U v_/ c
rt









ro
(U
4_)
to
0)
H

to
E
to
•H
rt
bo
£_|
O





0 0
U i~H 1 i
T3 "O 13 T3 G C
0000 O f-1 Or-(
4->4->4->4-J CN-Hrt rJ-^t-Hrt
•H -H -H -H O 4-> -H O O 4-i -H
43434343 LOrtfn LOLOrtfn
• H -H -H -H U <-H 
CCGC grt | rt
•H -H -H -H 36 36
o o
0 —1 O --H
rt rt rt rt
O G O C
• H -H -H -H
fi (3^ o GO
•H -H
O £•! O ?H
co co
4: 4:
rf OO
CM '*
^ *-j
6 6 S 6 43 43 43
O . O . fS | O t O | Q. f^ .
O . O j O . O . O . O <~1 ,
1 1
O O O O O 1 OO vd 1
o o o o CM i i
i— 1 i— 1 i— 1 t— I \D ^J"




CO
U
D
Q
O i
OS 1
ex 10 p. a)
c e rt
>- rt -H >
OS fH f-H ?H
^ toi3 6
«: 3 (!) p< C 2 c
W6rti3tocortrtrt H- i rt to
cot/ir-io aSa>-H-H a>3
Of-if-irtuJocc c_>oCSrt434: i-nrtrt +->

OGO-HrHCOtortrt Fto
-------



































1 — >
-d
0)
3
(3
•H
•P
Pi
o
u
V 	 '
C/5
M
J2
<£
CJ
OS
o

u
1— 1
£-H
^
j^3
0


z
o

£_t
r_}
^
OH
s
I-H
w










w
rH
3

OS







a> CD
C S rH
O -H 3
• H C 4-> 4->
4-> -H Ctf
crj X CD rH
^H O 1-t CD
i\ 4_> H rv
^"* *~ r-* >-**
C w 6
O (f-l O (U
CJ O PH +->
C X
O 0) TJ
U*v r^
^^ C
rt












*T3
0)
4->

0)
H

t/1
6

•H
C
rt
bo
^
(^







C
CD
LO 4->
T3 4->
O -H
w 6
rt f-i
CD O


C TH -r-l
•rH ^H
T3 ,0
LO " C -H
X X fS rH
J_l J \ -_J
+J ^^ *nl
•H -H C 3
> > o cr
•H -H -H CD
O O rt <4-l
Ctf OS fn O
CD CD PH W
P< PH W W
X X CD O
X rC f-l r-t




e €
QH PH
OH OH

00 CM
• •
i-H tO





















•4-*
3
O

^j

^
o
FQ
C
•H
X cd
CO OS
1— 1
tu












vO \O \O
LO LO O O O
E S LO LO LO
E— » f— < hJ i-3 >— 3







/ — s
/ — s fn
rH rC

vO
^O CJ>
o^ ^— ^
V_l
i— i

CD O J-l rH rH
rH .H 43 42 X
3 C
P5 _f^ Tj" ^" \o
rt o CM CN en
bO 4J
e e e
6 6 PH ft, PH
PH PH PH PH PH
O. O .
LO CM
Tt OO LO ^t 00
CN tO 00 CM
• • • •
O O O


f — \ f~\ f — ^
rH rH rH
CD CD CD
P 4-> P
crj rt rt
S 5 S

X -O X
P rH 4-*
•H rt -H
O T3 O
V 	 ' C \ 	 /
0)
1 i 1 t
^ IT
o ^

+J

c
^
o
rH
CO














O \D \£) vO \D
O O O O O

j j j j j















SH SH fn ^ SH
JS X X X X

Ol CM CTl CM CT)

S 6 6 S E
PH PH PH PH PH
OH PH PH PH PH

^~ r*^
\O tO CM LO ^t
LO LO LO rH i— 1
i • • • •
O O O O O


f — s
0)
4->
rt


r^
^
ctf
'O
p^
rt ^n
4-> C 0
to O fn
^— ^ £ fl)
rH ft
rt
(/) S
o
O r-H
X rH
O CD
U >-



534

-------






































t — \
*"O
0
•H
•P
C
o
u
en
u
C£
O
c_>
hH
L_4
^
3

^

2
O

f— 1
U

CL,
2
hH








































































W
rH
£3
t/1
0
Pi











f — ^
0 0
£ S fH
0 -H 3
• H C 4-> -P
•P -H rt
rt X 0 fn
fH O fH 0
.p 4-> 3 P-
C w g
0 4-1 O 0
O O ft -P
C rS
O (D TJ
rj ^_^ f^
S









0
•p

H

t/1
g
w
•H
C
rt
bO
fH
O






t3
0 i
-J i-J ** rt
rJ E- H X W
•PCW
•H O O
> -H rH
-p rt 4-> 6
O fH C 3
rt -H 0 -H
O ft -P fH
ft i/> -P XI
X 0 -H TH
X! fH g rH
1 — s
r~~ fH
fH Xi
Xi
\o
vO O^
O^ v — '
N 	 1
rH
w rt
/ — v 0 O
fH rH -H
Xi 3 C
rt rt O
CM rH 0
*•— J CO 4-)

g g g
ft ft, ft g
ft, ft, ft ft.
ft
tO rH
O rH CM OO
CM rt rH







,£
(/)
'O "H
0 4H
-P -P
t/> rt
0 O
H
rH
g 0
w C
•H C
C rt
rt xl
M U
fH
O










vO vO
O O LO I
LO LO S
U U rJ
rJ iJ H












LO
13
0
I/)
pj
0
fn
O
e
LO -H
JB

H X
•p
•H
£>
•H
^j
O
rt
o
X
XI

•p
C
0
4_>
•P
•H
g
fH
0
.p
C
• H

n
C
0
•H
•P
rt
fH
•H
ft
0
fH
1
fH
0
•P
C


•N
€
^
• H
r-l
o
•H
rH
•H
£3
cr
0

4-1
o


C
0
U

+J
C
0
•p
1)
T^
•H
e
00
r^
tn
•H
4-t

C
•H

I/)
O
^
TJ
• H
{/)
0
^

4H
O

O
•H
rt



o

u

^
0
4-)
rt
|5

C
•H

t/1
CU
^
'"O
•H
t/j
0
fH
O
•p


/ — N
fH
X

t
CM
v — /
e
ft
ft
CM
to
rH


i — \
fH
rC

vD
C7>
v — '
e
ft
ft
00
rH
i— 1
/ — \
fH
rC
VD
CTl
(/)
0
rH
3
C
rt
fH
bo
S
ft
ft

to
CM
rH
rC
\0
CT)
i-H
rt
0
•H
C
rC
O
0
•P
e
ft
ft
rt
CM










e
ft
ft

00
I — 1
                                                    X
                                                    rt
                                                   to
 C
•H
 g
          rt
          0

          4->
          rt
          B-,
                      §
            •H
            bo
            0

            i—i
            CO
                                                   •H
                                                   4H
O*
535

-------




















13
V
3
C
• H
P
c
o
en
i— i
1
o
U
H

<

*j£t
O
HH
UJ






































t/)
p
i— 1
3
t/)
0)
OS
0) CD
§ .ss
•H C +-> -P
P -H rt
rt X 
O
•&1
rt
+j

tO 60
^ Q
CQ ^H
HH ^H
DC 3
&. CO

                                       to

                                       Ol
01
 0)
          (^-    •   Ol  /—\  rH
          01   /—s   t—i     t~~       Ol  i-H
               Ol   60  i—I  ^—'
                              ^   rH
                                  r-
                                  01
"rt   u

 »l  "e
     PS
     ^
              536

-------












































2
rH
z
^
CJD
OS
o
_,
<^
t— 1
OS
H
en
«
OS
B
§
H
U
<£
2
rH
B,







































































(/)
•P
i-H
3

CD
OS











C
O
•H C
•P -H
rt X
rH 0
•P -P
f5
CD MH
0 0
c
o
U














"B
•P
V)
CD

6
V)
•H
§
bo
rH
0





f — \ t — \ t — \ f — \
CD 0 CD 0
"3 3 Is "p
to to to to
PH PH PH PH CM
rt rt rt rt CM o
O O O O O LO
LO Q
rH £,_,£_,£,_<£ QrJ
O -H O -H O -H O -H <-}
LO LO LO LO rH
Q0Q0Q0Q0 i-Hrt t — *
,_!(/) _)!/>,-J(/) .—It/) rt6  — ^_/ cfl
CD
3
0
P
•rH
43
•H
G
•rH
•3. ••£. -a •$
43 43 43 43 S S 0
(i**l _f*i (/)
bO bO bO bo oS
^J ,X Ai r^ bO bO rH

bO W) bO bO --~. -~^ 4->
6 S 6 S bo bo w
^ £ CD
0 Tt C
n- CM o CM oo o -H
O rH
O t LO O CM O
0 45
rH O
"x
0
U
rt
rt
t/i
'
c
rt
£H
g

rH O
•H l/l Q
rt ^ >H
3O cfl
cr 3 U
T3
t/1 4-> 0
"2 S ^ s?
H rt 'H 3 l/l
at (/) 45 O -P
rH «S S > C
t-i 0 43 i— i 0
rt 45 O 3 S
6 PH 43 4H 1
O
bO bO bO bO C/3 U
C5 C f5 f5 rJ to
t03 3 3 3<4-> rH
QO O O Ogrt 0
OS>H >H >H >H SOi 45
rH < -P
co SO













































•
o

cr>
t-H
V 	 ^

0
J^
4-*
•§
!H
U
T3 OC?
rt ai
£_, \ 	 /
0
^ 0
O fn
3 rt
H S

rH CM

537

-------
                                  SECTION 5

                                  DIAZINON


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Spectracide, G-24480, Dasudin, Diazajet, Diazide,
         Diazol, Dazzel, Gardentox.
                             o            -4
      2. Vapor Pressure at 20 C:  1.4 x 10   mm Hg (Sanborn et_ aj_., 1977).

      3. Solubility in Water at Room Temperature:  40 ppm (Sanborn et al.,
         1977).

B.    USE

      1. Type:  Broad spectrum, non-systemic insecticide with some acaricidal
         action.

      2. Primary Crops Used on:  Alfalfa (the use of diazinon accounted for
         11.1% of the 5.4 million pounds of insecticides used in alfalfa in
         1976); corn, wheat, sorghum, soybeans, cotton, tobacco, vegetables,
         and other field crops (Andrilenas, 1974; Eichers et^ a]_., 1978).

      3. Rates Commonly Used:  In 1971 application rates in crops using
         diazinon averaged 0.84 kg/ha; rates in field corn 0.01 to 2.80
         kg/ha (Carey et_ a^., 1978).

      4. Formulations Available:  Wettable powder, dust, emulsifiable con-
         centrate, granules.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Diazinon is moderately to
         strongly adsorbed to soil particles.  Haque and Freed (1974) have
         estimated that leaching will move diazinon less than 20 cm through
         a loam soil under an annual rainfall of 150 cm; however, in 17.8 cm
         soil columns diazinon was more mobile than phorate, disulfoton, the
         triazine herbicides and the chlorinated hydrocarbon insecticides
         (Harris, 1969).

      2. Persistence and Vapor Losses:  Insecticidal effectiveness persists
         for 7 to 10 days on treated foliage (von Rumker et al., 1974).  The
                                      538

-------
         half-lives of diazinon in peaty loam and in a loam soil were 35
         days and 20 to 40 days, respectively (Suett, 1971; Bro-Rasmussen
         et_ al_.,  1968); 85% of the diazinon applied to a silt loam had dis-
         appeared after 140 days (Getzin, 1967).   Spencer (1976) has re-
         viewed the limited data on diazinon's vapor losses and has concluded
         that diazinon will volatilize slowly from various substrates; how-
         ever, Haque and Freed (1974) have estimated that diazinon may have
         vapor losses amounting to 3.5 to 6.5 kg/ha/year or more from a loam
         soil at  25 C under an annual rainfall of 150 cm.

      3. Runoff Losses:  In the Bradfield Marsh in Ontario, where the use of
         diazinon has replaced the use of DDT for carrot fly control, runoff
         water in ditches draining the black soils contained diazinon residues
         in every sample taken from April to October of 1972; maximum concen-
         trations of 1070 ppb, 680 ppb and 2040 ppb were seen in early July,
         late August and the middle of October,  respectively (Harris and
         Miles ,  1975).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water:  Paris and Lewis (1973) considered hydrolysis
         to be diazinon's major degradation mechanism; diazinon's rate con-
         stant of hydrolysis (and half-life?)  at 20°C and pH 7.4 is 4435.8
         hours (~ 184 days) whereas the rate constant of hydrolysis of the
         major metabolite, diazoxon, is 693.5 hours (~ 29 days) (Faust and
         Gomaa, 1972).   Water from rice fields which had been repeatedly
         treated  with diazinon did mineralize residues within 4 days
         (Sethunathan and Pathak, 1971, 1972).  The component of the system
         responsible for this degradation was inactivated by streptomycin;
         strains  of Flavobacterium and Arthrobacter were isolated from the
         water.  Diazinon applied to a cranberry bog at initial concentra-
         tions of 0.32  ppm disappeared completely within 144 hours (Miller
         et^ al^.,  1966).  When diazinon was exposed to UV light hydroxydiazinon
         was formed (Paris and Lewis, 1973).

      2. Persistence in Submerged Sediment:   When diazinon was applied to
         rice fields in the Phillipines, concentrations of the pyrimidine
         hydrolysis product exceeded concentrations of diazinon 12 days after
         application (Sethunathan and Yoshida, 1969); the pyrimidine ring
         was further degraded to C0? (Sethunathan and MacCrae, 1969).
                                     539

-------


















































C/3
S
H- 1
^
^
u
PS
0

u
1— 1
H

J~l
cx


J2^
o

H
y

ex
S
1— 1








en
4J
i— i
3
t/)
0
OS








0 0
c e to
0 -H 3
•H C 4-> 4J
4-> -H 0!
03 X 0 f-l
^1 O to 0
4-1 4-> 3 ft
c we
0 <4-l O 0
O O ft 4->
C X
O 0 T3
U ^ C
oj
















T3
0
^_)
t/1
0)
£— i

(/)
6

•H
r^
rt
W
fa
O

















































CO
cs
w
u
Q
O
OS
ex
^
OS
^
Is
hH
p^
Cu

Q
px
<£

CO
OS
U)
CO
o







f — ^
W
$-1
r~|

^>
v. — s

r\
ftt
ft

O
0
O
i— 1








C
0

1-^
pj
oj
t— i
fti
O
4-1
X

pi l

0
C
•H
£_l
3
03
4J

UJ
CM
(/)
C
o
• H
4-1
0)
$-1
•M
C
0
u
C
o
0

0
^_>
03
fn
i— i
O














e
ft
ft

o
o
^J*










0
oi
W)
1— 1
03

C
0
0
^t
bO
1
0
3
i-H
f*i


M
J!~}
H








to
t~l
4-1

O

bO

0
4-1
•H
43
•iH
P^
•H







S
ft
ft

LO
CM

O


1— 1
o
•
o












f^
o
4-1

C
03
i— i
ft

£_i
0
4J
03

A

0
to
PH

C
0

4-1
U
03
ft
e
•H

4-1
C
oS
U
•H
•H
C
bO
•H
C/)
O
C














1
1
1
1
1










OS

3
oS
O
•H
(^
rO
03
3
cr

(/)
3
6
w
0
-0
0
C
0
o
CO
•H
0

^_J
C
X

o
4-1
o
r~]
ft

^
to
0 ui
6 oi

C 0
•H
t-H _ f*i
i— 1
0 to
0 O




















































                 LO     tO    LO     LO
                     O    O     O    O
                     LO    LO     LO    LO
                   u     u     u     u
                   m     uj     HJ     LU
U
O
\o
r
LO
t— 1
•s
to


00
•>*
v-^
43
ft
ft

O
CD
O

f 	 s,
BH
O
00
\D
•\
to


O
LO
>. — *
43
ft
ft


to
^j-'


/^-4
UH
O
00
^
f-l
4=

CM
to

43
ft
ft

00
O
, — ,
U
o
\D
•
LO
r-H
•S
fn


00
n-

43
ft
ft

00
1 — 1
O     \0
   O    O
   L/i    LO
 U     U
 hJ     1-4
                                                      O
                                                       r—I
                                                       CM
                                                       to
                                                       CM
                                                       O
                                                       o
                                                       oo
       o
        i-H
        CM
                                                              to


                                                             oo
        ft
        ft


        O
        O
        LO















LO
rrj
5
^5
CO
o
u
w
C
03
to
0
U
O
t3
ci
i— i
O


• •
W
C
0)
0
0
03

W
s
u
w
3
4-1
03
i— 1
to
03
4-1
03

0
rH
3
ft

0)
•H
c^
4i
ft
03
0
oi
£
bO
oS
S

oi
•H
C

ft
oS
Q
£
• H
^
03
O

03
• H
f^
45
ft
Oi
Q
!H
0
W

W
3
i — t
oS
r"j
ft
0
o
o
6
•H
co




co
w
^
pr,
PQ
w
f~*
p^
w

£^
1— 1
u
hH
pC
p
U4
CQ


1

'O
0
ft
•H
<-^
ft

Co

• •
w
C
03
0
O
oj
4_)
C/)
3
U





•H
£_4
4-1

3
O
OS
i— i

I/)
to
oS

g
oS


540

-------


























f~~^
rrj
0
3
fi
•rH
4->
c
o
u
V 	 '
CO
S

rH
p^|
<3^
CJ
OS
o

u
rH
H

^
^y
^

2
O

£-H
U
^J
OH
s
rH































































4_>
rH
3

0
OS


f 	 N
0 0
G B H
0 -H 3
• H C 4-> 4->
+J -H rt
nS > 4-> 3 ft
C 
O 0 TJ
U ^ C
rt
















13
0

y}
0
£— t

t/1
B

• H
e
rt
bO

O






O rH O CM
VO t^ t^ l^ OO O} O} i — 1 CJ> rH rH rH
O OOO O OOOOOOO
LO LOLOLO LO LOLOLOLOLOLOLO
U U U U U UUUUUUU
1—3 h-^ h-J I-J H-J I-J t-4 I-J K-J t-J t-J H-3

G" G" /— N
s~\ f-** O O ^— v tU
U U LT3 LO tin O
O O O LO
I-H i— ( LO LO LO r^-
CN CN rH rH LO
*» *^^
•» *» * •» ^--^ ^ »\ ^ — ^ ^-^ J_) ^ — ^ J_( ^— N
J_) J«|^^ f_| ^^H^_4 i~] J_( J^ f^
_i~| r^ ^ir^ rc^ rc^ _r^ ij^j ^grj ,irj rt~]
^" vD
*O OO OO "O ^^ ^J 00 "O C*^ CO CTt ^S*
Gl ^"^0^ CN Csl^O^ ^^ ' ^f s*- ' CN
v-^ ^^v^-/^^ ^^ ^-/ >«/ ^^ N— / \— /
(O ^,0,0 rQ SSSPnSPnS
f*l . O . O . O . O. p , p . p . p . p j p . p .
p . p. p . p t p . p^ p . p^ p j p^
CM CM
o LOOLO to oor^ LOMCMLO
O LO^DCM 00 ^r-HdOOO'd'
CM rH .......
O O O O O O i-H






1
(f) rt i
I 13 U
rt -H 0
13 -H fi rt
o rt h >
ft W C O r<
•H -H <4H rt
^3 r< X-H rH X
ft 4-> rH rH t/1
BtnUnctt ow -H ^5
rt30u 4->C 4-> ^H tn
0 C -H rt 3 C -H
rtow 3WIO 3 MH
•• rH 4-» X CJ'-H rH t/)
t/) t/) O I/) 4.) 4J C
PI !/) fn O rt i-H -H
rt3rt S4HS rn 3
0 H •• C O -H CT
OrtrtO X^3 bO 0
rtg4->fH 0C 0 rH
4->B<->0 rH-H 3 fH
wrt04J 3Xrt i-t rt
3Utna, UcooS 03 3G
h C rH
U rH p.

541

-------








































f — \
13
3
C
•H
•M
C
o
u
co
»— <
^
<£
rn
c£
O

u
t-H
£— <
^^
^3
o-


^
o
E-H
U

i— i
m








t/)
4->
i— i
j3
1/3
(D
OS











C 6 h
O -H 3
• H U -P •(->
4-> -H rt
rt X 0 ?H
fn O fc OJ
4-> 4-> 3 PL
c we

C X
O 0> T3
U v_/ c
rt









•O
0)
4_>
t/)
(D
H

i/)
6

•H
C
OJ
bfl
O





w
tO 0)
C "T3
•rt -H (/)
>O f~H i-H (-H
0) O ,X O
+-> UH t/i a)
C^J (L) (D C"1
fn O 3 S -H
•M i-H (/J
C W i-H T3
(U FH -H 0)
0 0 4J C 0
C 4-> rt rt
O nj C ,C I-H
(J S -H 4-> PL,




B

O-1

to
•
0














/ — N
5
O
c
c
•H
E
V 	 '

bO
O

O
•H
3
2
s
















































•
• vO OO
/ — \ / — \ ^O ^O
rt <-H O) O">
LO t^- <"H i-H
t^ O} *• — ' ^^ — '
O i-H
^H ^ 0) 0)
^^ PL, • OH
0^,0
r^ • • I-H U O U /-^
to / — v i— i nj vD oo •
^o to rt *"O o^ 'O ^o /* ^
O^ ts^ 4-* P! rH C O} LO
i — 1 G) 4-) (U Oj * — ' rt i — 1 \D
1 — ' i-H D > — ' CT>
<— ' ,^ I/I (/) t/) i-H
O f— | ^ >^ ^ Q) Q} c _ 1
f— H bO *-H T3 'O *"C) FO " Q^
I > r^ i * Q^ r^ r^ r^ *T~* o .
fV^ y^ fV^ y^ y^ £/} y^ ^g" C_^
i-H C^l tO ^^ LO vO ^^ 00 O^

















































•
^ — V
\Q
VO
• CTi
/-> «-H
O^ ^— ^
\D
• CT> •
,— > i-H i-H
/-^ oo >-^ rt
LO vD

O> >-l O O
i— 1 "• — ' 4->
< rt 0)
HH CJ 43 t-H
Q O, rt i-H
CO S i—l -H
3 U, < S
O •— 1 
-------






























co
rH
Pi
O
,J
i >-
1 1
CO










CM CM
0 0
LO LO
Q Q



rH rH
rt rt
rH B
O rH

T3
















|2
r)
U
"^ r^")
bO
AS bO
~~~. AS
60 \
6 bO
B


\Q Q}
^O 1^
to































4_>
rt
05



to
0 i i
AS
rt to o to O
•P 0 CM 0 CM
C in OC in X
•H fn (H
0 B 0 B
X > 0 > 0
rH -T3 rH Tj rH
•H rt MH rt MH
rt i i
T3 O rH rH O rH CM
C 0 C 
0> > C > C
rH 13 fl) Q 'O 0 O
X3 0 1— 1 -H 0 rH .H
rt P p -p P
p in p ft in p ft
ft 0 u g 0 o S
0 bo 0 3 bo 0 3
o bo ^4H in bo ^HH in
o 3 4-i in 3 4-i in
rt in 0 rt in 0 rt












X
rt
*o
•^^
bO
AS

bO rH rH
bo bo
CM 3. 3.
O
oo r-
• • •
O rf O
rH






























C
rt

£3
EC


i
pj ""O E
•H  O
rH 0 X rH
O 0O
ft W
0 0 in p
rH T3 -H in
•H -H
C O C in
0 -H O rH
0 P C 0
,0 O -H ft
0 N
0 in rt p
> C -H o
rt -H Q c

in in
in 3 -0
0 rH r-N 0
O O rH t3
rt ft O) t3
,O I/) rH p]
rH O rt
3 rC •>
P ft 15 0 <*~i
in o rt P ^O
•H C X rt t~~
T3 rt CO rH <7l
bO rH
O rH 'O T3
•H O C -H -
f-i rt ft-H
P O rt N
C1J P C rH N
•H _. O rt
r£ J2 X f-t
o X in rH o
^ in t. t, ii
r*^ « rH f— ( T-*
ft ^U rt 0
• n ^ \*— ^
M X w rt
O rH f-l in
•P T3 rt P C
•H 0 0 rt rtl
J3 4-> X W)
•H rt tn fn
X 0 o 0 o
P! ft--< 0
•H 0 0 rH
rH O M-l O
W P
rd 0 T3 in
U rH CM C 0
0 \ rt 3
rt S I-H in
i 0 in
in O rH C -H
•H £ -HP
S M-l rH
c o 3 e:
o m 'H
C rH T3 0
•H 0 O ,C 0
SI AS -H P +J
rt rH rH «
•H O 0 P! rH
0 S ft-H 3


• •
in
p
C
0
g
o
u

f-f

_r^
P
O


























•
/r— ^
f^.
K
0*v
rH
N— '

C/3
<3^
z


to



0?
(•<
0^
r-H
V— '

o
£-1
03
SE



-------
                                  SECTION 6

                                 DIMETHOATE


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Cygon, Dimetate, De-Fend, Perfekthion, Roger

      2. Vapor Pressure at 25 C:  8.5 x 10   mm Hg (Martin and Worthing,
         1977).

      3. Solubility in Water at 21°C:  25000 ppm (Martin and Worthing, 1977).

B.    USE

      1. Type:  Broad spectrum contact and systemic insecticide and acaricide,

      2. Primary Crops Used on:  Sorghum, corn, cotton, wheat, alfalfa, soy-
         beans, tobacco (Eichers e_£ aJ_.,  1978).

      3. Formulations Available:  Emulsifiable concentrates, ultralow volume,
         wettable powders, granules.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Dimethoate is moderately
         adsorbed to soil particles, Haque and Freed (1974) have estimated
         that leaching will move dimethoate more than 35 cm through a loam
         soil under an annual rainfall of 150 cm.

      2. Persistence and Vapor Losses:  When applied to a loam soil at the
         rate of 1.8 Ib/A, dimethoate's half-life in soil was 11 days
         (Bro-Rasmussen et^ al_., 1970); applications to a sandy  loam soil
         resulted in a half-life of 4 days when no rain fell after appli-
         cation and a half-life of 2.5 days when application was followed by
         moderate rainfall (Bohn, 1964).   In a Coachella fine sand, dimetho-
         ate persisted for less than  2 months as tested by Hippelates
         collusor larvae  (Mulla et al., 1961; Mulla, 1966).  It has been
         reported that dimethoate is metabolized to dimethoxon in soil
         (Bache and Lisk, 1966; Duff  and Menzer, 1973).  Haque and Freed
         (1974) have used the best available information to form a vapor-
         ization index; according to  their estimates, dimethoate may have
         vapor losses which amount to 0.2 to 3.0 kg/ha/year or more from a
                                     544

-------
   loam soil at 25 C under an annual rainfall of 150 cm.

BEHAVIOR IN AQUATIC SYSTEMS

1. Persistence in Water:  When dimethoate was added to raw river water
   (pH 7.3 to 8.0) held at room temperature, 50% of the residues dis-
   appeared in eight weeks (Eichelberger and Lichtenberg, 1971).
                               545

-------















































C/3
S
C/}
S
5,
C3
(A
a

u
r-H
H

*~~i
9-


2
O

E""1
U
^^
CL,
^
t— i
W



















































































to
4_J
r— 1
J3
t/)
0
OS










C 6 S
O -H 3
•H G 4-1 4-1
4J -H OS
ri X 0 5n
rH O 5n 0
4-1 4-1 3 PH
C to 6
0 <4H O 0
O O ft 4-1
C X
o 0 13
u ^ c
re












rr3
0
1 1
to
0
H

to
6
to
• H
C
ri
bO

O







13 i
0) -H
4-1 4-1
•HO 10
,P 0 0
•H tO 1 "O
f, C O -H
C -H C 0

0) bo 4-1
0 C ?H O
!-i -H O <1)
OH to
e o x c
i— 1 JO -H
^ f~^ (-^
o o c to
3 O cfl 3
6 G JS fn
aj 4-1 O
r^ CiO r<~j
4-1 J-l IO ft
3 O co to
O T3 O
H X-H ^
bO ,O H
o^
^r
s c
n 0
OS 4-1
DM .y
c
Q aS
Z i— i
< ft
O

OS X
tu ,c
CO ft
o
(X a;
S c
O -H
U f-i
tq aj
Q 2





CM
4-1 tO
O 1 O
O 'O
C C -H
o rt o
•H bO-H
4-1 f-l 4-1
•H O 0
,O (U
•H CM tO
X ^ C
C -H
•H J-l
O 0)
0) 4-1 C
bo -H
rt o\° fn
f-l K) O
 LO ,C





^--^
f-l
f_f^

^>
V^-'

O
ft
ft
o
0
0
1— 1







c
o
H^J
^
c
n3
i— i
ft
0
•4_>
X
f.
ft

0)
c
•H
^
3
rt
4^
to
tu

p
1 -H
IO -H
r-H 4-1 tO
o c H 0)
C 4-1 5n ^^
4-1 -H O 0 o\=
3 3 > LO
O to 'T3 CTi •
30> — ' LO
LO 5H rH CM
O o\°
X.C T3 O II
i — 1 ft 0 r-H
C W 10 C
O O 3 MH o
X cti o -H
••> ft O 4->
*"O O to *H
0 C tO tO rQ
4-1 aj 0 0 -H
to bOTJ O ^3
0 fH -H X C
4-1 O U 0 -H
















































 O
 LO
u
   00
   LO    LO
 u    u
 _J    _l
                                                           0
                                                           LO
                                                         u
                            o
                             I
                            00
                             ft

                            O
                            O
                            LO
                            CM
 u
o

 CM
                                             !H
                                            JS
  ft
  ft
 o
 o
                                                   u
                                                  o
        f.

        00
                                                   ft
                                                   ft
                                                        o

                                                         CM
                                                          fH
                              ft
                              ft
                       o    o
                       o    o
                       ^J-    CM








to
OS

^
P"S
in
z
o
u
adoceran
r-H
O


• •
to
C

0
o
cd
4J
to
*3
rH
U
C/}
PJ
03
cfl
C
bO
re
E

re
•H
c

ft
re
Q
PJ
H
OS
W
^>
2
r— 1

U
1 — 1
K

Z
w
CQ
to
-a
o
ft
•H
g~
aj


* •
to
C
rt
0
o
re
4-1
to
3
$_|
U
•H
tf\
3
o
re
r-H

to
3

re
£3
g
aj
CJ


546

-------




























TJ
0)
3
C
•H
P
c
0
v — /
CO
^
O)
h- 1
^
<^
C3
OS
o

u
rH
H

£3
Cf


*z.
5
E-
U

i:

w






























































t/i
^j
i-H
^
0)
Oi







^— ^
0  *H rt
TO X 0
J^
O






LO \D
0 C
LO LJ
a a



/-^\
u
o
LO

LO
rH

rH H
i^ ^f-^

OO -=t
•^t CM

o o
o . f*i t
1^ 1 f"l
rH O
rH
O LO
•P
to
•
O





1
ft
B 1 TO
•H O
fH -O -H
rC TO fi
 o
C  fH
ro C rt
 TO O
TO C -P rH
+J rt O (D
W fH 0> 4-)
3 ^-J V) DH
fH C
U rH


0
vo r*~* oo o*) to ^^
3 O O O O O O
1 LO LO LO LO LO LO
U U U U U U
_! J J i-J i-J iJ



G" u"
o o
LO LO

LO LO
rH rH

fH fH fH fH fH fH fH
^r~| r* t~\ ir^ r^ f^ (~|

OO v«O ^" vO vO OO xO
^t 01 CM 01 01 ^ o>

rP Ct S S S S S
p | o p^ r> pi pi | o |
OH 0, OH 0, PH fX 0,
o to cj» LO oo \o o
^ ^ i-H • CN1 • •
fH 00 Cft ^O




















fi2
(/)
•H
<4_> t^-j
3 C
o 3
fH tf)
+J
rH
S rH
O -r-l
& W)
C  rH
fn r~-
0) Ol
f*t rH
rH " — '
fH
3 C
X • 0
, — v !/)
C 00 rH
•H \O -H
01 ^ S

CM tO ^—^ 'O "T3
\jQ V.Q Q^ f^
O^ O> rH 03
^H rH < ^-S
\— ^ V— •* • (^
U W C
I/) H • H TO
(D 0) Q-, 0) 6
rH rH • T) -P

-------

































































CO
»S
CO
i— i
p?*
*?
C3
Di
o

J
^^
H- (
05
H
CO
UJ
OH
OS

H

Z
O
H
QJ
^
(X
S
I-H
tu










(/)
•P
t— 1
3

CD
05























/ — s
C CD
0 S
•H C -H
P -H +->
re x
r-H O CD
P -P (H
C 3
CD 4-1 t/1
0 O O
C ft
0 X
U CD
V — '


















TJ
CD
P
t/1
CD
f— i

-H 0 +->
§rt x o
2 D-i U
i— i
03

to
X
•H
rt
13

CD
rH
43
re
CM CM 4->
^D f|"!i O . ^
LO LO CD AS
Q Q O rt
i-J J O +J
rt C
i-l i-t -H
rt re B
^ R 3
o h B
CD -H
T3 X
rt
B






















> 3 3
43 43 43

bo bo bo
Ai AS AS
"^^ ^^ *^^
bO bO bO
B B B

O O CM
LO LO C
CM rH
O





























W
CO C
i-J i/i rt
^ 4_) S
2E! rt 3
S OS 33

^



C -H +J
•H re
CD 4-1
13 P
CD H rt C
P CD O -H
fn > 42
O O P f-i ^— x
ft CD 3 vO
CD ft B <-> 1^-
fn CD -H U Oi
T) *"O O i-H
C -H
CD O 42 P •>
CD -H bO O -H
43 -P 3 C M
O O N
CD CD 42 W rt
> (/) -P CD !H
re C iH O O
42 -H < 13 +->
^_)
(/It/) (2 CD
CD 3 - O >
O i-, ,-v -H W-
C O •-! -P
rt 42 \D rt t/)
43 ftOl rH pj
H t/1 rH 3 rt
30 SB

t/1 fti 3 O 42
•H o rt O
T3 C 42 rt 13
rt co c
O bo •> rt
•H ^ 13 4->
^i O C O W)
•p re rt -P
rt o fn rt
• H P Pi -P f-l
42 O

X CD (/> > -H
W 10 fn -H
ft O CD 4-> 13
ft) CD (/) «H
•» X ^-^ CD ft
JH CD bO rt
O W -H ^
•P X fn T3
•H rH rt (/)
43 13 CD CD *H
•H CD X42
42 -P PC
C rt o o
•H CD i-t 6 -H
ft 0 -P
HJ CD O fn rt
42 ft -P MH C
U -H
CD CM T3 B
rt r-l ">^^ CD 'H
CD rH 43 rH
(/) 3 ' r^ CD
•H rH O
O W T3
CD 42 MH 43 (2
•P 3 O rt rt
rt
O t/) t/i X t/i
42 f-l 13 rH CU
•P CD O T3 3
CD AS -H -H (/)
S f-i fn ft in
•H O CD rt T-I
Q 3 ft rH -P


• •
t/1
p
c

€
§
o
u
FH
CD
Ff~l
^_)
o
































t
t — ^
\D

O^
rH
V — /

•H
M
N
rt

o
-p

CD
£>

to






^-^
oo
r^.
o^
rH
V 	 /

CD
^H
rt
S


CM






•
/ — \
o
^
Ol
rH
v_^

•
rH
re

p
0>

42

rt
(1)
1—t
548

-------
                                  SECTION 7

                                 DISULFOTON


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Di-Syston, Bay 19639, Dithiodemeton, Dithiosytox,
         Frumin AL, Solvirex, Thiodemeton.

      2. Vapor Pressure at 20°C:  1.8 mm Hg (Sanborn et^ al_., 1977).

      3. Solubility in Water at 20°C:  25 ppm (Sanborn et_ al_., 1977).

B.    USE

      1. Type:  Systemic insecticide and acaricide.

      2. Primary Crops Used on:  Wheat (the use of disulfoton accounted for
         25.0% of the 7.2 million pounds of insecticides used in wheat in
         1976); sorghum, (use accounted for 23.9% of the 4.6 million pounds
         used in sorghum in 1976); cotton, soybeans, tobacco, corn, alfalfa,
         peanuts, Irish potatoes (Andrilenas, 1974; Eichers et_ al^., 1978).

      3. Rates Commonly Used:  0.33 to 5.6 kg/ha, one to three applications
         each season; in 1971 rates in cotton ranged from 0.01 to  7.85 kg/ha
         (Carey et_ al_., 1978) .

      4. Formulations Available:  Water soluble powder, wettable powders,
         water soluble liquid,  dust, granules.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Disulfoton is strongly
         adsorbed to soil particles.  Studies in a 17.8 cm  soil column have
         indicated that disulfoton is only slightly mobile  within  soil
         (Harris, 1969).

      2. Persistence:  Disulfoton's half-life in soil ran from 40  to 100 days
         (von Rumker et_ al., 1974) .

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Submerged Sediments:  Disulfoton is degraded more
                                     549

-------
rapidly in flooded or anaerobic soils than in upland or aerobic
soils; the major metabolite resulting from the oxidation is
disulfoton sulfoxide (Takase et al.,  1972).
                             550

-------














































CO
0S
CO
1— 1
•^
5,
U
OS
o
U
rH
H

1 1
o^
^

2
0

H
U
<^
Cu
rH
UJ















































































en
•P
rH
to
O
OS







t 	 N
0 0
C B rH
O -H 3
• H C -P -P
P -H rt
rt X 0 rH
rH O rH 0
P P 3 ft
G W g
0 4H O 0
O O ft -P
C X
O 0 T3
U ^ G
rt














TJ
0

t/>
H

t/)
g

• H
C
rt
W>
^
0














































3
UJ
U
Q
O
OS
DM

S-l
OS
<^
^
rH
OS
O-.
Q
^

rH P -H
rt P
coo
LO 3
C*TJ 0
O 0 rH
•P rt G
0 O -H






^ 	 \
rH
r^

^>
\— s

to
p t
ft
0
o
0








G
0
p

PJ
rt
ft
0
•p
X
A
ft

0
G
•H
rH
3
rt
4^
10
UJ

co
UJ
H
CO
UJ

£
UJ
U
CQ
         CM     CN     CM
            000
            LO    LO    LO
           U     U     U
           I-J     ij     1-J
o
o
I-— I
CM
rn"
CM
ft
ft
O
rH
U
O
CM
£
f.
00
^ — /
43
ft
ft
O
U
O
CM
rn"
\o
Oi
ft
ft
CM
LO
        10
  O
  LO
U
         O
         LO
       U
                                                                 O  to
                                                                 Lrt
                                                               U
                                   U
                                rt  rt
                                C  O
                                i— I -H
                                <+4  O
                                a)  rt
                                    rt
                                   TH
                                    rH
                                    3
                                    0)
                                    C
                                    O
                                O  rH
                                rt
                                a>  o
                                          U
                                         o
                                          o
                                                 U
                                                o
                                                 LO
       U
      o
       LO
              U
             o
              LO
 CJI
o
 oo
 U
o
 oo
„
X
rt
T3

LO
J-J
ft
ft
^t
•
01
X
rt
*"O

0
to
^
ft
ft
•st
•
rH
n
rH
t~]

^>
CM
^
ft
ft
O
^~

n
rH
(~{

OO
2^
43

ft
00
rH

n
rH


VO
O^
) o
ft
ft
o
•
LO
n
X
rt


LO
v — '
^
ft
ft
^J-
CM

X
rt
rO

O
to
^
ft
ft
01
•
rH
 X
 O
 rH
 rt

 O
 rH
 
•P
B.
              551

-------







tinued)
c
o
u
V — >
co
S
CO
I-H
§
tj
OS
o

u
H- 1
E-

O'
^^

§

b
 ui
^B ^6 irt ^6 ^S

H H vJ H H

vD vO 00 vD ^O
CTl G1* ^" CTi O"i
6 B 6 S 6
O . O . O . O . f^ .
*d" \D LO
LD r-- o o CN
vO tO O O O










x .e
in tn
S -H -H
o CLJ ii j
1 i i

'E
43 i-H i-l
tn "O IH i— t tn
•H 0} -H -H <»
M-4 0 bO 00 -H
rO .'"! 0 0 fti
rH -P 3 3 ft
3C O Ctf ^-1 rH 3
C/3 u LL, CQ CQ U
I— I
U-















.
\? /—*
\D OO
m v£>
i-l CTi
' — ' i-H
v — '
c
•H 0
• 4-t ft
•^30
f-^ CTi rt U
to VD U
\O O^ *^
2 ci "c §
V~>^ (Tj
tn to
?H fH C fH
0000
I-H Tj (/) *^
•P C C C
3 rt 0 rt
CQ to "-5 co
rH CM tO "t














( 	 >
CM
^O
Cft

^— ^ •
^— ^
• 00
r-H \O
rt o
rH
i \ \*~S
0
bO <
C
•H U
M
0 CL,
r^ •
u 3:
•H
p | J"T |
Lf) VO
552

-------















tf>
H- 1
U
OS
o
J
<
1— 1
OS
H
WD
PJ
Pi
OS
PJ
H

§

H
S
a.
S
i— i
a.






































w
4->
fH
3
0>
/ — \
c o
0 6
•H C -H
cd X
f-i O  +-> f-l
C 3
0) 4-1 t/>
CJ O O
a a.
0 X1
u CD
V 	 /




o
4_)
t/)
CD
H

l/l
g

•H
c
cd
bo
f-i
O







































W
Q
as
03

                                                       to
         00     O
         LO   LO     LO
       u   u     u
       J   J     HJ
                              o
                              LO
                            u
                                         CN     (NI
                                            o     o
                                            LO     LO
                                           Q     Q
                                           fj     I-J
                                                   etf
                                                   O
                                                          0)
                                      cd
                                     4-»
                                      ft
                                      0)  0)
                                      o  .y
                                      O  cd
                                      cd  4->
                                                          S  X
                                                         •H i—I
                                                          X -H
                                                          cd  cd
                                                          & T3
                                                                     cd
                                                                    T3
                                                                     (U
                                                                     nS
                                                                     O
                                                                     O
                                                                     cd
t O
0> (Nl
fn

> 0
T3 M
cd 4-1
i
O «— I i— I
C 1)
> C
tJ  0
TJ fn
cd 4-1
1
O rH
C 
T3 0)
(D t-H
 4J
(1) o
bo 






(N

p;
O
•H
ft

^
W
(/)
rt
T3
 0)
 CD  ifl
4-1  X
    cd

 CD
4->  tO
 cd


 f-i  & '
 1/1  CD
 X S
 cd  O
T3
    •-i  o   r
LO  O
o
o
\o
 1
o
o
             o
             o

              I
             o
             o
 a
 ft
o
o
oo
 I
o
o
 ft
 ft

o
o

 I
o
o
                                           bfl
                                           bO
                                           e
                                          (N
                                                  W)
                                                  bO
                                                  6
                                                          bo
                                                         rX
                                                         0
                                                         o
                                                                    JQ

                                                                     bO
                                         bO

                                         r—I
                                         o
                                         8
                                                                                bO
                                                                                               bo
                                                                                              uo
                                                                                              to
                                                                                              0
 f-l
 cd
             I
             cd
             cu
             a.
                     cd

                     cr
                    I
                     o
                    M
                       cd
                      a:
                              c
                              cd


                             I
                                  553

-------
a














































^™ "\
CD
3
C
•H
P
C
o
u
N 	 '

CO
^
co
rH
J2J
*?
rn
OS
O

^J
^^
I-H
P^
H


OS
w
H
2
0

£-4
rj
^£
a,
S
n

UH
13 rH
CD rt
+J O
fn in -H in
O CD bO CD
ftT3 O O
CD *H rH t3
rH O O
•H O T3
C P -H C
CD 0 X rt •
CD CD O /-^
f~\ tfl f— < f^ \O
C O f-
CD -H -H (7i
> . 4-> rH

,£33^3 -
r-l \D T3 -H
in o 01 o N
CD rC rH rH M
u ft ft rt
g V> " CD f-i
(ti O S rH O
rQ rC rt P
f-i ftx; c P
3 O CO O CD
+J C >
in rt TJ P v — '
•H M C O
T3 r-i rt CD in
O <4-l CD
CJ C 4-1 -H
•H O O CD 4->
4-> in o CD
rt 13 rH C ft
• H CD CD O
pd in cj in fn
o o ^ rt ft
X ft rC
tn x in o
ft CD rH C -H
rt o C
• - X CD P CD
f-i i— 1 X O M
O T3 4-1 rt
P CD O rH 4->
P^ -1 > «^ ^ *™^
•r^ ^^ ^^ ^ ^
,0 rt in 6
• H CD O -H
rC ft 4-* T3 rH
C CD O
•H rH CN 4->
~^ rt o
PJ CD rH X -H
rC rH 1 4-> C
U CD rH CD
IS CD M
rt 4-1 4-> O
O O rt P
in rC o rt
•H S in -H fn
T3 13 CD
C in o C P
O fH -H -i-l
P CD JH CD
O M 
4H rH ft CD rt
rH O T-l 42
3 S rH T3
in CD 3 4->
• H C > P O
Q -H o in C

. .
in
p
pi
CD
i
0
u

fH
CD
rC-
4->
O








































































•
t — N
O
O"! \O
rH r^
^^ a^
rH
. ^
rt oo -H <-^
t**^ M ^*
+-> O^ N t^
 CD P
rt rH 4-> CO
CD rt CD  Z
rH (N tO ^-
554

-------
                            SECTION 8

                           ENDOSULFAN


NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

1. Product Names:  Thiodan, Chlorthiepin, Cyclodan, Insectophene, Kop-
   Thion, Malic, Malix, Thifor, Thimal.

2. Vapor Pressure at 25°C:  1 x 10"5 mm Hg (Martin and Worthing, 1977).

3. Solubility in Water:  < 1 ppm (Sanborn et^ al_., 1977).

USE

1. Type:  Non-systemic contact and stomach insecticide.

2. Primary Crops Used on:  Cotton, alfalfa, Irish potatoes, other
   vegetables, tobacco, apples, other fruits and nuts, other field
   crops (Andrilenas, 1974; Eichers et_ al_., 1978).

3. Rates Commonly Used:  In 1971 application rates in crops using endo-
   sulfan averaged 1.6 kg/ha; rates in Michigan ranged up to 6.72 kg/ha
   (Carey et_ al^., 1978) .

4. Formulations Available:  Emulsifiable concentrates, wettable powders,
   dusts, granules, ultralow volume.

BEHAVIOR IN TREATED FIELDS

1. Adsorption and Leaching Characteristics:  Endosulfan is very strongly
   adsorbed to soil particles.  When applied to soil at 6.7 kg/ha, 90%
   of the material leached no further than the top 15 cm; 9% was re-
   covered from the zone of 15 to 30 cm (Stewart and Cairns, 1974).

2. Persistence:  Half-life on plants is three to seven days for most
   fruits and vegetables (Martin and Worthing, 1977).  When endosulfan
   was applied to soil at a rate of 6.7 kg/ha, the alpha and beta
   isomers took 60 and 800 days, respectively for 50% conversion to
   endosulfan sulfate (Stewart and Cairns, 1974).  Studies on the
   persistence of endosulfan sulfate were not carried out; however, the
   authors defined it as "relatively stable" and equally toxic to
   insects.
                                555

-------
      3.  Runoff Losses:   When potatoes grown on a gravelly loam (slope 8%)
         were treated with 1.05 kg/ha of endosulfan,  0.3% of the pesticide
         was transported away from the field during the 3 months following
         treatment (Epstein and Grant, 1968).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1.  Persistence in Water:  When endosulfan was added to raw river water
         (pH 7.3 to 8.0) containing colloidal  material but kept aerobic, con-
         centrations of the two active isomers were reduced by 70% within one
         week; 8 weeks after application complete degradation of both isomers
         had occurred (Eichelburger and Lichtenberg, 1971) .   It has been
         estimated that endosulfan will have a half-life of 5 weeks in water
         at pH 7 and a half-life of 5 months at pH 5 (Greve and Witt, 1971).

      2.  Persistence in Submerged Sediment:  The ratio of adsorbed to free
         insecticide is 4:1 when endosulfan is added to a turbid aqueous
         suspension (Richardson and Epstein, 1971).
                                     556

-------













































C/3
S
CO
1 — 1
2
<
C3
OS
0

U
rH
E-
<
CS
<:

2
o
H
U
<
OH
1 	 1
w




tn
p
i— i
3
in
0>
OS









CD 
C 6 rH
0 -H 3
• H Pi 4-> P
+-> -H rt
rt X 0> rH
rH O rH 0)
P P 3 P-
C W S
0) t+H O 0)
O O PH P
C X
O 0 T3
U ^ C
rt















t3
<1>
P
in
(D
H

in
6
in
•H
C
rt
bo
rH
o












































co
OS
u
3
Q
O
OS
(X

>-
OS
^
^
rH
OS
Cu

Q

co
OS
w
co
o
PH
i
u
w
Q

rH
X
f~\
rtJ
T3

•rH
p
o
3
T3
O
rH
&





/ — \
w
rH
X

Th
V 	 /

,p
PH
PH
O
0
O
1— 1









P!
O
4->
^
C
rt
rH
PH
O
P
x
PH

(D
Pi
•H
rH
rt
P
in
tu

CM
|
0
rH
PH
(1)
rH

<4H
O

o
p
ai
rH
-o c
0) O
O -H
3 P
o\° T3 O
t^ 0 3
OO rH T3













€
PH
&
CN

O















I/)
•H
f-l
rt
bo
i — i
3

rt co
rH OS
i— 1 LU
® e&
O CO
-^ 25
x: o
u u







•s±
t^i O
6 LO
nj U
H HJ














/ — \ r — \
rH rH
rC rC

00 v£>
•^J- Ol
* — f *• — >

-Q £1
PH PH
PH PH
O CT>
^t
CM CM
LO





1

W
C
rt
fH

C Z
rt rt rt n

Tf


v£>
00


LO
 8"
 p-1

o

vO
                                           rt
            o
            LO
           u
  o   o
  LO   LO
u   u
                 u
                o
                 LO

                 LO
                                                     CN
                                                   i   rt
                                                      u
                                                  *O -H
                                                  rt  Pi
                                                  •H  rH
                                                  rt  O
                                                  C   rH
                                rt

                            rt  o
                            P  rH
                            o  o>
                            0)  4-1
                            W CL,
                            p:
                                                            u
                                                           D
                                                            LO
                                                            LC
                        CJ
                       o
                        LO

                        LO
                                                            LO
557

-------

























t — \
0)
3
c
p
c
0
V — i
C/}
rH
g;
f~D
OS
O
U
rH
H

3
o-


§
H
U
&.

rH

U4
t/)
P
rH
rj
t/1
a>
OS


,_—- 4
O  e

C X
O 0) 13
U ^ C
cd









T)

•P
a>
H

s

•H
c

bo
O







00 00
r**- ["*•» !"*•-• ^^ r*^. t**^ r**^- c^
seeLoeegLo
H4r4H4UrJJJU
HHHnJHHHJ

/-, ^ G r-s ^ G"
U U O CJ U O
O O f- O O t~»
\O CM • \& CM •
CM CM
i— 1 C~^ rH rH t^» rH

*v *\ *\ ^-^^ ft f* r* f — ^
^Hr^HfHrlrHrlr^
f.AAf.f^f^Af.

^•^j-^J-OOvO^OvO^"
rMCNCMTfcnaiCTirM
V 	 1 ^=J V^^ \^.J v_^* ^.^ \^J \ 	 /

O <"*> O (^ O O ;O Pi
ftftftftftftftft
ftftftftftftftft
rH (Nl CM \O *~~ LO O
• >.••••
tO\OtOi — IfNJi — IrHO
rH









_<~^
P I/I
3 -H
O MH
fH
P C
• H
S 3
o a"
43 a)
C r-H
•H rH
rc cd cd
CO OS X
rH
P-.










\O
O^
rH
» — '

!H
O
•P
t/)
03
rO
cfl
i— i
<^


OO








/ — \ •
to ^
1^ 00
O} ^O
d/ 2
1 — ' CTl
0) ^— v i— ^ vD
N 00 O  O^ i — v O ' — '
,— V f. rH rH Ol U
to O ^— ' ^— ' v£)
\O CO Cn T3 rH
Ol • rH rH C Cd
i— i 13 <;  — ' <&
^ c • w> P
rt cj -p w ui a>

-------


















co
rH
UJ
OS
O

•J
1 — 1
Di
H
OJ
Qi
PJ
H

2
O

<
2
rH
P<
P
rH
w
0
Pi
c 'o?
0 S
• H C -H
P -H P
rt X
rH O 0
P P rH
C 3
0 4-i w
O O O
C ft
O X
U 0




13
0
if)
0
H
t/i
6
•H
c
rt
bo
rH
O







































Q
p— I
CO

        O
        LO
       u
  o
  LO
u
  o
  LO
u
o
LO
13
 0
 0  (/)
4H  X
    rt
13 "O
 0
 P to
 rt
 0  X^
 rH rd  13
 P     0
   13  0
 !/)  0  4H


 rt  O  P!
13 rH  rt
   rH  0
LO  O  rH
^—-^ f I I  U



 ft
o
o
o
o
                    ft
o
LO     O
to     o
rH     01
              1
                     1
o     o
o     o
CM     OO
       o
       LO
                          CM

                           I
      o
      o
             rt
             rt
             CD
       rt
       3


       0

      •H

       S

       o
      pa
                           rt

                           cr

                           x
                          •H
                           P!
                           O
                          u







••1 CM
0 0
LO LO
Q Q
iJ >-J
rH rH
rt rt
fn £
o S
0
13












3 ^
O t"*l

bO bO
^ ^
*^^ \^
bo bo
6 £

OO "St
rH r^«





























(/)
rt
Pi



to i
0 O
rH 13
ft rH C
rt O 0
P 4-1
ft
0 0 <
O .X
o rt C
rt P rt
C 4-1
E "rH i-H
S X w
•H rH O
X -H T3
rt rt C
6 T3 0












s
rQ

bO
F^
•^^s^
bO
6

to
^
o
o
•
0























V)
p[
rt
§
02




i
0
13

0 0
p
Tj rt
C 4H
rt ^
3
OQ ^
C C
rt rt
4H 4H
rH rH
3 3
v> w

w
0
•rH
p
rH
0 0
P ft
rt O
0 rH
•H ft
13
C 0
•H >
•rH
w p
rH rt
rt i— i
6 3

'c 3
rt O

4n 0
O >
rt
f> rC
0
•H 4->
U O
0 C
in w
i — t O / — *
rt t3 LO
rH r~-
0 C CT)
> rt rH
0 4H
t/) r~H *v
3 -H
C W N
DON
13 rt
W C rH
0 0 O
•H P
13 P P
3 rt 0
•P ^ >
CO P v-^

t/1
Pi
0
i
o
u

0
rC
P
O


















,
LO
O)
rH

•H
N
N
rt
rH
O
P
0

to










•
^-^
oo
CTl
v — /

0
rH
rt


CM







•
/— -^
o
rH

•
rt

•p
0
j~
P
rt
0
X
rH
                              559

-------
                            SECTION 9

                               EPN


NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

1. Product Names:  EPN
                        o          -4
2. Vapor Pressure at 100 C:  3 x 10   nun Hg (Martin and Worthing, 1977)

3. Solubility in Water:   Insoluble (Gunther et_ a^., 1968).

USE

1. Type:  Non-systemic insecticide and acaricide with contact and
   stomach action with a broad range of activity.

2. Primary Crops Used on:  Cotton (the use of EPN accounted for 9.5%
   of the 64.1 million pounds of insecticides used on cotton in 1976);
   corn, soybeans (Eichers et_ al_., 1978).

3. Formulations Available:  Emulsifiable concentrates, granules.

BEHAVIOR IN TREATED FIELDS

1. Adsorption and Leaching Characteristics:  EPN's small degree of
   solubility in water would lead one to expect very little movement
   of residues by leaching.

2. Persistence:  When EPN was applied to the soil, residues persisted
   for less than 3 years (Terriere and Ingalsbe, 1953).  When EPN was
   applied at 11.2 kg/ha and incorporated to a depth of 6 inches,
   concentrations of 0.2 ppm were detected by bioassay one year later.
   This rate of degradation works out to a half-life of approximately
   10 weeks  (Alt and Heady, 1977).

BEHAVIOR IN AQUATIC SYSTEMS

1. Persistence:  No information was available on the degradation of
   EPN in water and submerged sediments  (see FONOFOS for general
   information on the persistence of organophosphates in aquatic
   systems).
                                560

-------
                    to
                    0
                    OS
       0  0
 PS     6  fn
 O     -H  3
• H  C  P P
 P -H      rt
 cd  X  0  fn
 fn  O  f-t  0
 P P
 C
       3  ft]

0  M-l  O  0
O  O  ft P
           O
          U
       X
       0 T3
       ^  13
           Cd
g
CO
OS
o

CJ
I—I
H


cx
§

H
U
W
 W
 B
 to
•H
 f3
 cd
 bo
 fn
O
                                      I
                           CO
                           o
                           PL,

                           O
                           U
                           w
                           Q
                                         1
                                  0
                                  P  P  W Z
                                 •H  O  O PL,
                                 43  0 f, W

                                 43  C  o"^
                                  P  -H  f3  W
                                 • H      Cd  0
                                     O  &0 PO
                                  0  C  fn -H
                                  '   H  O  O
                                            H
                                      I
                                     h
                                     O
                                                          I   C
                                                         •H -H
              io
                                         x +->
                                 43  43     0  r—v
                                  O  O  C  to  T3
                                  3  O  cd  C  0
                                  g  C 43 -H  P
                                     cd p     t/i
                                 X  bo     to  0
                                 P  fn  w  3  P
                                  S  O  0  fn
                                  O     T3  O  P
                                  f-<  X-H 43  O
                                  0043  O  ft C
                        g
                        P
                        ft
                        o
                                     o
                                     o
                                     PS
                                           to
                                         0  O
                                               o

                                                 LO
 cd   •
>—' LO
      fn
 rt  O
                                                                                               to
                                                                                                 O
                                                                                                 U
                                                                                                o
                                                                                                 vD

                                                                                                 LO
                                                                                                 1-t



                                                                                                 CO
                                                                                                 43
                                                                                                 ft
                                                                                                 ft

                                                                                                 00
                               C
                            I   O
                              •P
                           t/) ,X
                           c  es
                           cd  cd

                           0  ft
                           O  O
                           o  o

                           rt ^

                           "o  x
                               0


                           w  p.

                           cd  cd
                           0 -H
                           O  C
                           cd 43
                           P  ft
                           t/i  cd
                           3 Q

                           U
                                                                                                   13

                                                                                                    o 'd'
                                                                                                    ft 0
                                                                                                    I*?
       to
    O 0
       P
 ?H  (/)
 O  3 P
M-l  fn O
    O PS

  LOftZ
U  to PL,
mow

    ft
                                                                                                 0
                                                                                                 bO  O
                                                                                                 cd  f3
                                                                                                 H  cd
                                                                                                 0
                                                                                                           rt
       0
       P
    bO to
    H 0
    O P
                                                                                      O
                                                                                       \O
                                                                                                           LO
                                                                                       fn
                                                                                       45
                                                                                                           00
                                                                                       43
                                                                                        ft
                                                                                        ft
                                                            561

-------







































/— \
•"Q
0
3
C
•H
C
O
u
en
S
en
§
C_2
oi
0
u
n
H
|


j2»
o

f— i
CJ
^
D-*
^
HH

UJ














































































w
4_)
rH
3
(-0
o
c*












/ — -V
0 0
C B rH
O -H 3
• H C -P 4->
+->-r-i cd
Cd X 0 rH
rH O rH 0
H-> 4-> 3 ft
C « 6
0 <4H O 0
O O ft +J
o 0 -d
u ^ c
cd












-a
0
4_>
V)
H

to
to
• H
C
cd

rH
O








00
C
•H 0
X cd
rH 0
cd +•>
o to
**t Ln \o -H 0
oo o r- r*> t>» i~- 4->f5
LOLO LO BBEEw-H
U U U -J iJ rJ MJ -H rH
Ji-J iJ EH H H H M O
rH JS •
0 0 C
to o H->
•H
T3 IO X>
0 6 -H
4-> rH rC
O 0 C
cd •(-> -H

0
w
C
o
•H
f— ^ | ^
u cd
O rH

CN c a,
^-^ ^^ /— > /-^ 0 uj
^-> /— . rH rH M rH 0
rHrH rH rCrCrCrCC-O

vO ^O vO ^C O cd
\Q \O ^J C7^ CTl O^ CTl
CT) CT> CM > — ' * — ' ^— ' > — ' rH C
v— ' ^ v-' cd O
B B B B X T-l
O O O £K fS . fS . o . ^ _j r^
o j p^ p j o . o^ o^ o . ^ ^ _>
ft ft ft rH Cd
LO LO tO ,Q rH
LOI^- ^ ^CNlrHO3cd
rH • IO B
•
en o !H
UJ ft< m m cd
H -H -H 3 rH
< rC rH +J rC
oi ft •»-> cd o (/> tn
OQBlO'H4-)W 3-H tO
UJCd3O'HC OM-I rH
H oto3cd RC 0
oi cdcdcTbO C3 C
UJ •• rH MH W -H -H tO -H
> to o +J S X
ZGwwBcd 43 -H to
HHcd33 'n tonarHW
0 rH H 'H Cd TH 0 C
UOcdcdcdX <+H0bO'H0
HH aj g S +-> 0 "OrCUfttS
X-MEBOrH rH+J3ftrH
F-H tncd cd 03D3 o cdrH 3 o
55 3ua touenupueoucj
UJ rH (3 rH
03 U rH tt,




























































































/ — \
CM
rH
.
rH
cd
• f — N
<— N 00 +->
IT) VD 0
t^^ CTi
G> ' — I bC
-H ^^ C

rH
< C 0
D-l • A^
en • -H
D S a.


LO **o r —





.
^ — ^
LO
rH
v^ — J
^
0 ^^
XI vO
i — 1 ^O
rH C7l
3 rH

C 0
•H ft
O
CM tO
vO ^O 'O
O Ol C
rH rH Cd
N 	 / V 	 ^
to
10 rH rH
000
rH rH T3
0 -P C
& 3 cd
5 CQ en
rH CM tO

























.
f — s
CT>
LO

rH
^^f

I/)
to
•H
0



OO


















t — \
CT>
VO
O^
rH
**~J

IO
rH
0
'O
C
cd
en
*d"
562

-------






































CO
•s,
co
rH
OS
O

HH
OS

CO
tq
OS
OS
PJ
E-
py
O
^_H
£_J
^^
DH
S
rH
tu

to
1 >
(H
3
to
0
OS











/,— ^
C O
o 6
•H C -H
4-> -H 4->
rt X
rH O 0
4-> 4-> rH
C , 3
0 4-1 to
0 O O

o ^
CJ CD
v_ /











•a
to
0
H

to
to
•H
rt
bo
O







C
•H
CN
0 O
tO LO
0 U


rt
O 0
^"3
OtO
Q rt
nJ 0
0 tO
rt >>f-^
0 Xi 'O
rH 0
+-> T3 0
0 (4-1
to S
X 0 C
rt rH rt
^O rH 0
O rH
LO tH O
v — '
5 S 0 X
rf*} p . ^ J^
OH ^M "^
W)
F^ o
\ LO
bO rH
6 rH
1
rH O
LO
tO CTl









to
T3
rt
rH
t-l IO
rt 4-»
6 C
rt
oo to
C rt
co 3 0
Q O XI
OS >- CL,
rH
PQ



(N
O
LO
u
,_J







/— N
"

^



£



£

\*-/
6
ft
PH

0
LO
to
1
0
o
to









rH
•H
rt
CT"
0
4-1
•H
rC
S
Xi
0
D3





CM
C
Lf
U
J







t 	 N
"

*;



^



^

X 	 /
S
p<


0
o
to
1
0
LO
CM









rH
•H
rt
cr
^
•H
e
3

O
U











to
o
LO
Q



rH
rt
rH
O





















5


oo
*>
^^
00
S

[•*»

























to
rt
OS



to
rH
0 tO
f^ ^
rH O 1
O -H rH
S rH 0
0 "t>
to C p, C
O -H 3
LO rH
Q T3 0 X
*J 0 > rH
4-J O 4-»
0 C
rH C tO 0
rt 0 
6 C t3 0
rH 0 -rl rH
0 0 CJ p | •
*O X> 'H X
0 O -H -H
> 0 U
rt i/i 2 -H
rC C D- X
•H PJ O
0 tO O
0 3 • rH
C rH /-N 3
rt O rH 0
XI -£ ^ C
3 tO rH 0
4-> O rH
to X »X>
• H P, S -H
T3 o rt to
C X! tO
o rt co o
•H OO fl.
rH rH 'O
5 4J O C ^
X> rt rt O
•H O
bO X! +-> C 0
A! O O to
\ XtS rC 3
oo to 0 to rt
S rH W rH 0
O 0 0
CM • ** C^ CJ Q
(N rH X -_,
00 S
4-1 tO 0
•H X rH -H
Xi i— i rt >
•H t3 0 0
rC 0> X rH
C 4->
•H rt o oS
0 rH <;
OJ PL, OH
x;  1
0
rt 0 CM rH
rH ^ OH
• H S 1 00
rH fi
CL, fi 4-1 O
EJJ 5 O OO

is
C
0
g
o
u

0

^J
0















































































































































•
/~-^
o
CT>
rH
.
0 /-^
0 O
rt ^
rH
U
T3 rt 0?
C r-
rt 4-> CTl
0 rH
0 rC

O rt rH
3 0 rt
rH CM tO
563

-------
                                 SECTION 10

                                   FONOFOS


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1.  Product Names:   Dyfonate

                             o            -4
      2.  Vapor Pressure at 25 C:  2.1 x 10   mm Hg (Martin and Worthing, 1977).

      3.  Solubility in Water at 25°C:  13 ppm (Wauchope, 1978).

B.    USE

      1.  Type:  Insecticide particularly effective for control soil insects.

      2.  Primary Crops Used on:  Corn (the use of Fonofos accounted for 15.6%
         of the 320 million pounds of insecticides used in corn in 1976);
         peanuts (Eichers et_ al., 1970).

      3.  Rates Commonly Used:  In 1971 application rates on corn averaged
         1.01 kg/ha (Carey et^ al_., 1978).

      4.  Formulations Available:  Granules.

C.    BEHAVIOR IN TREATED FIELDS

      1.  Adsorption and Leaching Characteristics:  When fonofos granules were
         band applied and incorporated to a maximum depth of 5 cm, residues
         remained primarily in the top 10 cm of the soil profile (Baker and
         Johnson, 1979) .

      2.  Persistance and Vapor Losses:  Fonofos had a half-life of 22 weeks
         in a peaty loam high in organic matter and cation exchange capacity;
         in a sandy loam low in both organic matter and cation exchange
         capacity, the half-life of fonofos was more than 50% shorter
         (Suett, 1971).   When fonofos was applied as an emulsion at a rate of
         11.2 kg/ha and incorporated ot a depth of 5 to 6 inches, residues
         had a half-life of 20 days (Schulz and Lichtenstein, 1971) .  How-
         ever non-extractable bound residues have been found and indicate
         that fonofos may be more persistent than was previously thought.
         Lichtenstein e£ al. (1977) tested an agricultural loam soil for
         fonofos residues and found that after 28 days, 47% of the applied
         fonofos existed as extractable residues and an additional 35%
                                     564

-------
         existed as extractable residues.   Lichtenstein and Schulz (1970)
         studied the relative volatilities of various pesticides and found
         that approximately 0.96% of the parathion,  0.63% of the diazinon,
         16.3% of the fonofos and less than 0.01% of the azinphosmethyl
         volatilized from soil incubated at 30°C whereas 26.1%,  11.5%, 1.32%
         and 0.78% of the aldrin, lindane, dieldrin and DDT volatilized in
         the same period of time.

      3.  Runoff Losses:   When continuous corn grown on a silt loam soil
         (slope 12 to 18%)  with conventional tillage systems was treated
         with 1.12 kg/ha active ingredient of fonofos, an average of 0.21
         and 0.15% of the pesticide was lost with sediment and water,
         respectively.   The conservation tillage method of ridge-plant reduced
         runoff losses  relative to conventional tillage by 77% whereas the
         conservation tillage method of till-plant resulted in average run-
         off losses of 107% of those seen with conventional tillage (Baker
         and Johnson, 1979).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1.  Persistence:  No data was available on the persistence of fonofos
         in aquatic systems.   There is some disagreement about the degra-
         dation of organophosphates in water and sediment.  While some have
         asserted that  this group of insecticides generally hydrolyze within
         8 to 12 days in water and sediments having pH's ranging from 6.0 to
         8.5 (Muirhead-Tnomson, 1971; Pionke and Chesters, 1973), others have
         predicted that in temperature conditions (zero to 25 C)  and pH values
         (pH 5.5 to 8.5) of natural waters, organophosphates are quite
         persistent (Faust and Gomaa, 1972).
                                     565

-------














































CO
IS
CO
H-t
J2
«^
^j3
OS
o

u

H

J"i
CO'
^J

z
0

y

D-«
•S
hH


•
tU




















































































in
p
rH
3
in
0)
OS










'c?
13 0) 5n
0 63
•H C -H P
4-> -H P rt
rt X 5-i
$H O 4) G)
4-* 4*^ £n Q-i
C 36
0> 4-i in 0>
0 O O P
C p i
0 X T3
U d)C
'-' rt











TJ
-l
OS
^
^
rH
OS
o.

Q
^
^

CO
OS
co
o
OH
5?
o
u
tu
Q
rH
tJ 1
 OOT3 P
W C rH -H W
5-1 -H O 0 0)
O 5n -HP
6 0 X P
rH 43 O P
43 43 
rt






S~\
^
43

^>
V — t

r\
ft
ft
0
O
O
1— 1










c
o
p

£
rt

ft
O
p
X
43
ft

13
•H
j^
3
rt
P
in

n>
P!
•H
^
O
rH
fj
O
o
c
rt

f_j
0

(N
!-^

rH
O
4-1

o\°
i*O
•
LO








































to
o
•H
•P
•H


s
§
o
o




X

c
o

* *
13
0)
P
in
W
p

in
w
*d
•H
O
•H
P
O
o
in
C
•H






















































in
Z
0


1
0
3
T3
(U
^

ftT?
in v
o
43
ft
0
C
rt
00
J^
o

to
rH

IP.
O





















































in
3
rt
o

in
w
*rj
•H
O
•H
P
O
0>
in
C
•H























































c\°
0 II
rH
"4-1 O
O -H
P
in -H
W 43
(U -H
0 43
X C

•H rt
•p *~>





















































13
(U
P
in
0)
p
p
o
c

CO
o
tb
o

o
u,

f — \
0\°

•
LO
CM



















































to
1
o
c
rt
00
5-i
o
(N
1— 1

rH rX3
O 0>
til 1J
in
OO)
l-OP
u
W tn
 43
rt O
to
1 *"O
o  o o
> 43 UH
rt ft v< — '
                             U
                            o
                             JH

                             43
                             00
                             I
                             OO















g
[Xj
^^
^5
CO
z
o
u
c
o
1 p
in C
C rt
rt rH
rH ft
HI O
O O
O M
"rt V~'
rH X
O 0)
.. *3
in ft
rt rt
0> -H
0 C
rt 43
P ft
in rt
3 Q
5H
U
 U

O

 vO


 LO
  5-1

 43
                                     00
 ft
 ft
 ft
566

-------























TJ
0)
3
G
•H
•P
O
u
CD
S
C/3
OH
O

U
H

ID
o1


§

£_l
^J
^J
OH
S
1— 1


UH





















































t/i
-P
rH
^3
t/1
 0)
C 6 rH
O -H 3
• H C -P -P
4-> -H rt
rt X (U rH
rH O ^H 0)
•P -P 3 P-
C 14-1 W 6

O O PH +->
C X
O 0) T3
U ^ C
rt











•P

0
H
i/>
e

•H
G
rt
rH°
O









^J" ^*
0 0
in LO
u u
rJ i-J


^— ^
/**^ f-l
fn .H
f^
^>
Tj- CM
(N ^— '
1^_-'
€
S PH
o | o |
f* !
un
rH ^t
rH O
O O














.C

•H
ij til
3 C
0 3
rH W
4^>
i— 1
S rH
O -H

G 4)
•H 3
X rt rH
 OS CO
UH
















































































,
/— N
to
1— 1
\— *
ti
CD /•" %
i-H \O
(H G^
3 t-(
32 v— '
C <1>
•H p-t •
O f~^
s-*. s-^ cj r^
CM to r-»
vO ^D *T3 ^^
0> 0» fi rH
rH i— ( rt * — '
v — ' ' — <
(/) W
t/1 JH rH *O
0 
-------
           c
           o
          •H  C
           •P  -H
           ct)  X
           fn  O
           4J  •!->

           0)  >4H
           O  O
           c
           o
to

CO
OS
co
§
OS
PJ
2
O
Q.
 (1)
+J
 W
      in
                            Q     Q
                            Oj

                            ^
                            O
                                   rt
              Xi

              00
              ^S

              M


              DO
txo
00
                             rt
                            oi
                                      00
                                                     0)
                                                     !H
                                                     rt
                                                               568

-------
                                 SECTION 11

                                  MALATHION


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Cythion, Emmatos, Emmatos Extra, Fyfanon, Karbofos,
         Kop-thion, Kypfos, Malaspray, Malamar, MLT, Zithiol.

      2. Vapor Pressure at 30°C:  4 x 10~  mm Hg (Sanborn et_ al_., 1977).

      3. Solubility in Water at Room Temperature:  145 ppm (Sanborn et al.,
         1977) .

B.    USE

      1. Type:  Broad spectrum nonsystemic insecticide and acaricide.

      2. Primary Crops Used on:  Alfalfa (the use of malathion accounted for
         14.8% of the 5.4 million pounds of insecticides used in alfalfa in
         1976);  sorghum, tobacco, wheat, rice, peanuts, cotton, fruits and
         nuts, vegetables  (Andrilenas, 1974; Eichers et_ al_., 1974).

      3. Rates Commonly Used:  0.6 to 4.48 kg/ha, one to ten applications
         each season; in 1971 rates in cotton 0.78 to 2.69 kg/ha (Carey et_
         aj_., 1978) .

      4. Formulations Available:  Ultralow volume,emulsifiable concentrate,
         wettable powder.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Malathion is moderately
         adsorbed to soil particles- adsorption is positively correlated with
         organic matter content, humic acid content and cation exchange
         capacity  (MacNamara and Toth, 1970).  Haque and Freed (1974) have
         estimated that leaching will move malathion more than 35 cm through
         a loam soil under an annual rainfall of 150 cm; however the likeli-
         hood of groundwater contamination is small because malathion
         residues reaching the soil surface (the material is not applied to
         the soil) degrade very rapidly (von Rumker et al., 1974).
                                     569

-------
      2.  Persistence and Vapor Losses:   Insecticidal effectiveness persists
         for 1 to 3 days on most treated crops (von Rumker e£ al., 1974).
         When malathion was sprayed on  ladino clover and exposed to UV light
         at 37°C, 66% of the residues disappeared in 16 hours (Archer, 1971).
         Fifty percent of the raalathion applied to clay soil and silty clay
         loam and 90% of the malathion  applied to loamy sand degraded within
         24 hours (Konrad et_ al.,  1969).   Spencer (1976) reviewed the limi-
         ted data on malathion's vapor  losses and concluded that accurate
         predictions about potential volatility in field conditions could  not
         be made because of the lack of data.  Haque and Freed (1974) have
         used the best available information to form a vaporization index;
         according to their estimates,  malathion may have vapor losses which
         amount to 0.2 to 3.0 kg/ha/year or more from a loam soil at 25°C
         under an annual rainfall  of 150 cm.

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1.  Persistence in Water:  The persistence of malathion in water depends
         to a large extent on the  pH of the solution.  Residues resist
         degradation by chemical hydrolysis in neutral and acid waters but
         are readily degraded by aquatic bacteria (such as Pseudomones,
         Xanthomonas, Comanonas and Flavobacterium) which hydrolyze off one
         of the ethyl groups of the succinyl-ester side chain (Paris et al.,
         1975) creating malathion  3-monoacid along with some diethyl maleate
         (Zepp et_ al^. , 1975).  In  raw river water (pH 7.3 to 8.0)  held at
         room temperature malathion was degraded within 4 weeks (the metabol-
         ites of this degradation  were  not identified); when this same test
         was run in distilled water no  hydrolysis occurred (Eichelburger and
         Lichtenberg, 1971; USEPA, 1973).  Chemical hydrolysis occurs fairly
         rapidly in waters having  a pH  above 7.0; malathion had a half-life
         of one week in a solution of pH 8 (Weiss and Gakstatter,  1965) and
         hydrolyzed almost immediately  at pH 12 (Spiller, 1961).  Diethyl
         fumarate is a product of  chemical hydrolysis (Weiss and Gakstatter,
         1965) and is twice as toxic as malathion for fathead minnows
         (Bender, 1969).  In Sawannee River water containing large amounts of
         colored material the photolytic half-life (wavelengths > 290 nm)  of
         malathion was 16 hours;  photolytic half-life was 990 hours in clear
         water at pH 6 (Wolfe et al., 1975).
                                     570

-------



















































CO
^
CO
Z
0
D«
O

U
t— i
£— <
o
•^
z
o

H
U

^
rH
PJ


















































































 3 P.
C 0 B
0 4-1 O 0
O O PH -P
C X
O 0 T3
U ^ C
rt















•8
+j
1/1
0
6-

to
B
•H
§
bO
rH
0






(N 3 T3
BO -H -O
rH PH O 1 O «* 1C
X PnO orttJOrt
X ^ X w O C 0
O C C1 — I'HC rt PH 0 LO LO
13 LOO-HCO t/1 N XX
0 -H O4->BX0'H -P -P
O *"O H-* C 1 O t H-J rH (/} 12 i£
3 C'HO-P30Q-3rH OO
T3 rt X 'H X *X3 O*HB rH rH
0 *HXbOOCrH 3 bobo
rH BX H->-HrHO bOCrH
PnC rtrHpn-H O30 4H  C C
> CN.P .HrH+->X-H OO
•H S 13 0 +J rt O -H bO -H -H
•p -PO 0ortB 0<4-iM-ic -P -P

13 X rHWrH0 0O0P-I'H -H
O rHi3 b00b04-> CJ>6 X X
rH o\° C -H 0 $-1 0 rt O •* -H rt C C


c
C 0
O -H
•H X

t/) | i c^
rH rt rH
X i— i rt
rt B
2. 6 | ^ o

PH 1 1 o\° (71
J3 1 1 v£> CM
PH 0 1 1 -^ \
PH LO 1 1 PJ U
Q E
o o H pa
0 4->
O 0\° 0\°
rH rH \O O
rH
CO
PJ
u
Q
O
OS
OH
>- C

*tEi r^ V) (/)
rH C O O
OS rt 13 13
Cu i-H -H -H
PH 0 O O
Q 0 rt C C
Z 4_> bO 00
<2 X rH . rH rH
X rt PH XX
CO PH  •> -H X
X O S bO
bO • -H
•H Oi T3 X
rH 0
(/] «^ (/) ^_J
C rt rt
X rt 0
•P rH X
S LO O i— 1 l/l
0-0 C C
rH VO T3 O O
bO -H
EC C -P
13 PH O O rt
0 -H -H rH
•P X -P P -P
X O X X 0
•H X -H 0 -HO
X X B X C
c -P c -H co
•H rt -H 4-> -HO






E
PH
PH

LO
1 CNI
1
1 t~-
1
1 O
4-)

LO
rH
•
0







t/1
rH
rt rH
I/I 0
O O
13 *—*
•H
O t/1
C -H
0 rH
rH -H
X 0
PJ rt
rH
rt bo
rH
rH rt
0 C
rH 0
O rH
rH bO
X 3
U PJ

571

-------
































, — N
13

P
C
• H
P
C
O
U

C/3
^
CO
I-H
^
^
CJ
oi
O

CJ
1 — 1
E-i

|— i
cx


2
O

H
<3*
OH
2
l—t
tu




C/)
P
r-H
3
to
0
Pi





0
C 0 fH
0 E 3
• H C -H 4-1
•P -H P 03
03 X fH
fn O 0 0
P P fn p.
C 36
0 <4H 1/5 0
0 O 0 -P
C PH
O X 'C
U 0 C
^ 03

















*"O
0
p
t/1
0
H

l/i
6

• H
C
03
bO
fH
0






oo
X
p
0
fH




O O O I-H




r-H




i-H
bO Oi Oi O> (J> i — i i— i i — i i — i I-H i— i
O O O
<4H LO LO LO
O O O O C
> C
> O
LO LO LO LO LO LO LO
0 U U U U U U U U
tu w oj
c
o
•H
p
03
e
• H
to
JJ J _J J J






u
I-J






U







OG _ .
\O til [T ,
O O
LO OO 00
^0 UUUU
o o o o
LO r-H r-H i— 1 O
r—1 v£> t^ r-H CMCMCM CM

«\ «\ «\
fH fH fH
e xxx
PH

». »v * •% ^
fn fn fn fn fn
X i t rC _<~^

u
o
o
CM

*\
^i
i-^

U
o
o
CM

*
fH
X

PH OOO^OO ^tOO^O \D^O\O
*^f LO vO
[~) V. V \- J \. J
o
^" CM *vj" O^ C7^
* 	 ' V 	 1 \ 	 / V. — / \^/

CTi
X 	 /

01
^ — /

r—< rQ rQ ,f*i ,Q ^O rQ ^d ,^ pQ r^
PH PH PH
0 PH PH PH
P
00 C7> CM
O ...
r— 1 i— 1 O O






1

to
C
03

0
O
O
-a o3
03 P
c/> .— i o3
•H o X 03 C
.-H 0 C -H
•H r-H bO fn
0 •• 3 rt 03
o3 (/> p. S 0
fH C
bO CO oj o! 03 03
Oi 0 -H -H -H
03 UJ O C C C
CS 03 X X X
0 5 4-> P< PH PH
i-H CO t/1 03 O) Oj
bO 2 3 Q Q Q
3 O fn
W U U

PH PH PH OH PH
PH OH OH PH PH

LO 00 OO O
• ...
to to I-H i — I to
to



i
i/)
*t3
o
V) PH
3 03
4-11 O Oj
03 0 tfl
rH CO *"C) ""O O
3 W 0 W C
fH H PH-H 0 -H
fH < -H fH C P.
0 Oi X P -H W
tO CO PH W fH 6
OJ e 3 03 0

3 Di rt p.
i— 1 ILJ •• t— 1 "0
rt J> i/i w
X 2 C to
p. I-H o3 3 C
0 0 fn O
Q U  6 «
•H E-H ft Oj fH
CO 2 3 U U
PJ fH
oa u

PH
PH



CM
OO









t/)
•H
fH
o3
M
i— i
3
^

W
d)
•4->
0
c
0
e

oi
r-H
cti
OH



PH
PH



to
00











t/1
3
P.
fH
rt
O
•rH
bC
C
o
r-H

t/1
3

3
o3
CL.



572

-------






















/ 	 N
13
CD
3
Pi
•H
P
Pi
O
U
w
w
I-H
^
u
OS
o

C_)
I-H
H

*^
ex
<£

^
o

H
U

p
i-H
3
t/i
CD
OS







C CD H
0 63
•H C -H P
cd X t-t
!H O CD CD
P P M p.
C 36
CD 4-1 I/) CD
0 O O P
Pi o ,
O X 13
CJ CD C
>-' cd















13
0
P

CD
£—4

t/1
£3
t/)
•H
C
cd
M
?H
O







CN
O
C
o to to to to to to
P 13 O O O O O
Cd PI LO LO LO LO LO
.-H 3 U U U U U C
3O i-J >-3 i-J i-J i— ) >
6 PH
3 6
0 O
o o
O P
•rH ("^
XI 0)
O cd
f~j f**l ,
/-^ U CJ U U t
U 0 O O O O
O LO LO LO LO I
LO
LO LO LO LO I
I— 1
!H t-t fn fn
fH X X: rC X!
OO \D 'S; 00 *
^3" ^1" O) c\l rj- c
r-^ ^— / ^-^ v— '
rO f^t f-l f"*i F
Xi PL, P, PL, PL,
PL, p, pu Pn PL,
PM
0 i-H O <
O
rH vD I-H to \O (
i— (




1
1/5
13
cd
•H
t cd cd cd
(H -H 1/1
(/) 13 O
i-H X Cd rH
•H i— 1 ,C 3
cd ^^ »Q
C CD cd cd
tn pi I-H w
O i-t
P CD cd
Ifl (/) O -H
C !H p;
cd cd CD
CD •• C 
O cd O t/1
cd p fn cd
P O CD cd
(/) CD P i-H
3 W OH U
fH Pi
U I-H




rt to to
O O O O r-t ^H
LO LO LO LO E E
J U U U hJ J
J J nJ nJ E-H H








_3 U U U O U
O O O 00 O
f) LO LO LO -OO
(M
O LO LO LO r-H CM
^ r, A * X •>
N M fn fn cd X
C rC X X T3 cd
13
J3 TT OO v£> O
TI CM «a- o\ to LO

Q rP f^ ,O ,O ,P
a, PL, PL, Pu, PL, PL,
PL, p, PL, Pi, PL, PL,

XD oo r-
. . .
N LO o o oo r^
tO CM .-H





cd
o
•H
^H cd
0 0

•H UH
^H -H
cd O
o cd
PL,
t/5
X cd
O -H
!H M
cd 3
C CD
0 P!
fH O
CD fH
+-> U
0, <







^vj"
, — 1
3 6

E-








O
00
CN4
rH
»i
X
cd
T3
o
to

rP
PH
Pu

po
•
o































                                                            LO

                                                           U
                                                           PL,

                                                           PL,
                                                           O
                                                           00
                                                        CD
                                                        cd
                                                        cd
                                                        3  C
                                                        cr cd
                                                        in  bo
                                                        o  -H

                                                        ^
                                                           X
                                                           CD


                                                           *3
                                                           U
573

-------






















1 — \
'S
^
C
•H
4->
O
u
^ — /
s
C/3
1— t
^
3
U
Di
o

u
1 — 1
H

£D
cy
^

2
o

E-
u

0,
2
h- 1
OJ























































1/5
4-1
i— t
^
1/1
0
Oi

f — s
0 0
C S ^
O -H 3
•H (S 4-> 4->
4-> -H 03
03 X 0 ^
h O M 0
4-> 4-> 3 ft
(2 WE
0 O ft 4->
C X
O 0 T)
C_3 x — ' C3
o3












*"O
0
4^
t/1
0
H

t/)
B

•H
C
cU
M
^H
O







0 0
LO LO
u u
I-J ,-J




r~H r~i
O O C
LO LO LT
U U
1-4 nJ

' — \ <• — ^
U U.
U
i-J


o o o
^~
T± O
LO LO LO
1
^H
l-~* LO
^
43 **
-* 43
^ — ' vO
O^
43 v-*
ft
1 1
i-H OO
LO Tf

* *\
f-t H
rC 43
\O \D
3} O>
>^^f i^^i

ft 43 43 43
ft
ft
O CM
CM t~O
to







1
t/) t/)
3 W -H
CH O T3
03 -H fi
B -H o3
•H <4-l ^l
43 (/) bO
i-H -H
o3 "T3 0
T3 43
M 03 O
0 OX
i-H I/)
0 •• ft
43 0
ft 4->
O 0
G !H
< <


p , Q^
ft ft
LO 0
o
CM i-H
CM



03
O
H
C
f-i in
0 -H
4-1 1 T3
H C
r— 1 M Oj
03 M-H
O 03 ^H
X B 0
 fn
ft •• 0
0 B
!H 0
T3 43
X ft
X W


r — ^
U
o
1— 1
CM

A
^
00
,-j.
v«_^

43
ft
ft
vO



















.
ft


w
•H
4->
0
o!
oa


              o
              LO
o
LO
o
LO
o
LO
o
LO
    o     o
O  CM     CM
LO      B
                                                                 o
                                                                 CM
            [ii     P-.     H-.     PU     UH     PL,
           O      O      0      O      O      O
            LOLOLOLOLOLO
            43434=42434=434=43
                   LO            CTl                    O     O     i-H

            i—lOi—HOOi—(i—ICMi—I

            ooooooooo
     CO
            4->

            o

            4->
             o
            43

            •H
             03
            &.
                                         4->
                                         §
                                         I
                                         f-t
                                         CQ
                                         1
                                         rH
                                         03
                                         O

                                         O
574

-------














































r — \
T3
CD
3
(5
•H
P
C
o
u
co
co
1— 1
§>
cj
oS
o

u
|— I
£-H
<•£
1 1
ex


^
o

E-
U
OH
rH
PJ


























































































t/1
P
f— 1
3
t/)
CD
Di















, 	 N
CD CD
C 6 rH
O -H 3
•H C P 4->
4-> -H Oi
03 X CD rH
fH O rH CD
•P 4-1 3 P-
C5 W g
CD <4-l O CD
O O PH 4->
C X
O CD 13
V~/ ol













13
CD

l/l
CD
H

V)
g

•H
C
oi
W)
^H
0








CN
CN (5
C X-H
•H fH
CD 13
C > CD
O O 0
•H O 03
4-> 0 rH
OOOOO-H O rH PH
CN CN CN CN CN CN 3
g g g g e e ts ••> c
H H H H H H rH i/) 45
oi S
4-> rH rH
C CD rH CD
03 4-> CD 4-1
O W 4-> OS
•H CD 03 3
<4H f5 rH
•H -H C
C rH O Ol
OO O g CD
•H X rH
W O rH O










F-l rH rH rH rH rH rH
45 45 45 45 45 45 45

^D ^O ^O ^«O ^O ^O vO
CTi CT> CTi CTi Ol CTi CTi

g g g g g g g
QH p t Q4 Q, p t Q^ p ,
pi , pH p , Q_| p-, p, p_,

tO LO >-H
vD r^- oo i***> LO c>
CM I-H CN CTi r^* ^ O
• ••••••
O O O 00 O O O
f-H











45 W 45 x
t/1 Ul (/)(/)
• H 03 -H -H
45 ^H o 4-( t| |
O C 4-> 4->
rH 3 45 03 cS
CD (/) 4-> O (j
PH 3 45 45
rH O rH rH W (/)
S 03 g CD CD -H -H
O CD CD C C "4H 4-1
rH 00 C C 13 13
rH 13 r4 Oi Cd 1— 1 i— 1
CD CD oS 45 45 O O
>H OS i-J U U U CJ







K)
CN
(5
0
• H
4J
O
0 3
CN 13
g 0
»-J rH
f-H p ,

rH
PL,

rH
03

^
O
c
•§









/ — s
/ — \ t/1
rH O
45 g

^O ^^
O^ rH

g g
PH Pn
PH PH

CN
LD O
vO O
• *
00 O

A |










C/) (/I
^5 |5
0 0
C (5
C (5
•H -H
g g

13 13
OS 03
CD CD
45 45
P P
OS 03
U, PH


C
O
•H
CM rH 5
" O cd
CM g ,H
CN nj
CD ••> e
0 C
•H O <4-|
S -H o
4-i 45

CD 03 u
4-> i — ' pj
OS Oi (U
^ E !^
OS CD
g W £*j •
3 oS o. (u
Ml '^ ,5
PH
u f5 O

X X cfi
45 O u
4-» 4-> .H C
 C
O o!
rH rH t/)
T3 03 -H
X g
45 3 rH
4H CD
rH 4_>
Ctf rH Ol
U X 5
• H -C
g 4-> C
CD CD CD
45 -H 45
CJ 13 S













-------











































/ — ^
13
0
3
e
•rH
P
e
o
u
i— i
OS
0

LJ
1— 1
H

^
O'
^

2
O

f— (
£_J
^
0,
2
hH
w








1/5
P
r— 1
3
t/5
0
OS












, — ^
0 0
C E rH
0 -H 3
•H R +->+->
P -H Cd
Cd X 0 rH
rH O !H 0
4-> 4-> 3 P.
e 
•H
e
cd
bo
j_i
O








LO C
CM C -H
C -H
•H C 
•H t/5 0
E X 3
PH E Cd TJ
PH PH 'O *H
PH l/>
00 "vT 0
CM LO rH
• rH E
^ CM 0 rH PH
0 4-> 0 PH
•P T3 4H P
cd C cd cd I-H
•-H cd 5
3 * " v
E X! C C
3 w -H cd X
O 0 Cd 0 TJ
O rH rH i-H O
cd 4H Xi O XI






f — ^
t/5
X
cd
13

^t

E
PH
PH

LO
O
o

o



















PH
rH
cd
u


^
CM
bo
C
•H
C
^
cd
OO PH
^O VO ^O rH O t/)
CM CM CM O CM
E e e LO B o
rJ nJ rJ U rJ P
H H H J H
t/5
3
O
•H
^
0
^_>
0
i— I
0
13
t — \ t — -\ t — \
U U U
O O 0 r-^
t^ to oo u
o
CM 00 tO rt
i-H i-H CM CM

^ ^ n •, , 	 ,

X X! X Xi XI

<3- ^- ^t oo \O
CM CM CM Tt O

E E E E E E
j~l j O ^ p 1 p. ( p^ p .
PH P, PH PH P, PH

O O O \O to O
CM T)- i-H OO O CM
CM r— 1 i-H O i-H O
• •••••
O O O O O O
A






XI XI
in in
•H -H
CHH 4H
£ C
3 3
t/5 t/5

i-H rH
rH rH
•H -H
bo bO
0 0
3 3
i— i i— i
CO CQ


0 tn
PH 3
O Xi
rH P
0
J> •»
0 tfl

0
bO-H
C -P
•H cd
rH E
PH rH
t/5 O
4H -^
EBB
PH PH PH
f^ ^ O ! O t


^J-
Oi 00

CM O O
i-H i-H








*"O r?r^
oj w
(D -H
r^ (^_(
,—H
T~H f,J
3 -H
Xi w 3
0 a"
M -H 0
0 PH rH
Cd PH rH
rH 3 Cd
CO CJ K


576

-------


•

















































/~-\
'"O
CD
^
P:
•H
C
O
u

CO
S
CO
I-H
§
U
D£
o

u
rH
H

| 1
cy


p?^
o

f— i
^
DH
2
HH
,
w





























































































in
p
rH
rj
in
0
oi















f — s
0 0
C B rH
O -H 3
•H G P P
P -H 03
03 X 0 rH
rH O rH 0
P P 3 P-
C m 6
0 m o 0
O O PH P

O 0 13
U *•_, £
03















13
0

t/)
0
H

C/)
E

•H
G
03
bfl

O









CTi
CN 0 O
G m to
•H 03
rH II
X 0
rH 4-> ,C
rH in tO rH r-H
OS 0 0 to to
O G rH 00
• H -H IHH LO LO
P rH U U
in o G i-J iJ
•H X -H
bO CJ G
fH O 0
0 <4H -H 
vO
CTl
r-H
v — /

JH
0>
1— 1
w
•H
W


i-H
i-H
















•
/ — \
bO
\Q
CTl
i-H
V 	 f

TH
(D
.— i
4-*
oa
rH







r-l
0
4_1
P
03
p
in
rM
03
U

T3
C
03

in
in
•H
0
"3.

CN
CN
•
LO
l\
CTl
i — l
* — '

Pi
rH
O
i-O
P!
03
co

TJ
C
nj

IHH
rH
03
O
P
0
2


CN
rH








.
f — ^
, f~1
LO
t^*
CTi
rH
V — J

•
1 — I
03

^_i
0

rH
0
rH
4_J
3
eQ
CN




















•
f — ^
T^J-
vO
CTl
i— 1
"— '

K

•
, — x
1 — .
vO
CTl
rH
*• — ' r — \
CTl
P: vo
03 CTl
rG rH
PH • V— '
CD r-~,
P CTi ,—N
CO VO rH rH
CTl \O OS
13 rH Ol
Pi v_, rH 4->
03 *— ' CD
rH
P 0 C r*:
C T3 IS 0
3 Pi 0 0
O CD rH Ctf
2 ea CQ 2

5 ^f LO "O t"-
in •
rH ^~N
CD O
T3 I~^
C CTl
03 i-H
CO v-/
,_^
to

/ 	 N
CTi
vO
• CTi • •
t — ^ rH f — \ t — \
O * — ' CTi O
^^ LO t^
CTl rH Ol CTl
rH CD rH rH
^ — / 4J \ — / ^ — J
in
C o3 in ^
O ,0 m 0
P 03 -H CJ
03 rH 0 03
m < 3s 2

CO O^ O
CNCNCNCNCNCNCNIO


•
, — ^
00
vO
CTi
rH
V — /

0
PH
0
CJ

13
Pi
03

in
rH
0
*"O
G
o!
CO


to
1 — 1








.
, — ^
vO
f-^
CTl
rH
^ — '

•
i — 1
oS

P
0

0
be
•H
fH
13
r-H
to


.
^ — ^
^O
vO
CTi
rH f — ^
v_/ LO
VO
Pi • 01
•H / — x rH
<4-l CN -^
3 • r-
03 / — , CTl
U OO rH rH
VO v — ' 03
13 CTl
Pi -H 3 P
oj v_/ o CD
•H
C • rG C
CD O bo -H
in • rH 
CJ rH O
13 ^ — ' ^
13 G CTi
Pi 03 CD rH
03 -H v_,
03 P
in pi in CD
•H X -H rH
i-H O rH 0
rH rH XI O
w u u 2
*sj* LO vo r^

/— "»
o
r^
0*1
i— i
v — ^

rH
0
P
in
•H
rH
rH
«3^
O
e — ^ t — s 2
VO LO
vO vO T3
CTI CTI p:
rH r-H 03
v. — i *• — '
^
000
PH PH 0
O O 03
u u 2


OO CTi O
rH rH CN







•
vO
vO
CTi
rH
* 	 '

0
PH

tO U CTl

CTl T3 CTl
i — 1 (± rH
-—< a ^

C w in
03 rH rH
600
£H '^ Pr5
o P; pi
O n3 03
On CO CO
OO Ol O
rH
577

-------


















CO
OS
o
rJ
rH
OS
H
CO
tu
OS
w
H

2
o

H
U

rH
U,
•p
1 — (
10
0
OS
t — N
0 0
C B rH
O -H 3
• H O -P P
•P -H Cd
Cd X 0 rH
rH O fH CD
•P .P 3 ft
C to B
CD 4-1 O 0
U O ft +->
C X
O 0 T)
U ^ C
cd



0
0
H

t/1
t/)
•H
c
cd
bo
J_(
O







































co
Q
rH
CQ

         O

         LO

       U
  o

  LO

U     U
rJ     rJ
  o
  LO
  o
  LO
to
cd
•H
CM CM X
0
LO
Q


rH
cd
f-|
O






o
LO
o
_J

rH
cd
B

0
•a




1— 1
•H
cd
-d

0
rH
O
cd
•P
ft
0
0
o
cd
verse effect
""O
cd
i
o
c

TJ
0
4->
t/)
0
bO
W)
3
OT
1

O
r
X

B
0

4n

rH
0
>
0
rH



si
rH

c
o
•H
•P
pi.
3
3
to
t/i
cd
verse effect
*o
cd
i
O
c

13
0
P
to
0
bO
bO
3

i

O
r
X

B
o
£_i
4-4

rH
0
>
0
rH



-4
CM

c
o
•H
•P
ft
B
3
t/i
to
cd
 0  

 0  X
4-i  cd


T)
 0  tO


 Cd  r*"* *"~^
 0  C^ 'd

 rH      0

 P  *O  0
    0 4-1


 X O  C

 Cd  r-H  Cd
        o
 ft
 ft


O
o
o
LO
O
o
LO
               o
               o
               LO
               CM
o
o
r--

 i
o
o
to
to
 ft
 ft

o
o
to
CM
 I
o
o
o
CM
                             rQ


                              bO

                             AS
LO

00

00
                             5



                             bO
o
o
o
                             X
                             rt
                             13

                             bO
 bO



CM
o
                                                   bO



                                                   o
                                                           p.

                                                          o
 fH

 ed
 cd

 cd
                      cd      cd
                      3      3
                      cr     cr

                      0      X
                      o
                      CQ
               o
               U
                      cd
                      OS
                             cd

                             I
                             X
                             578

-------

















































,, — ,,
13
XI \
(L>
c
• H
•P
C
o
u
V 	 t

co
2
CO
h- 1
^
<£
CJ
«:
o

j
H- 1
OS
H
to
w
OS
os
w
H
z
0

H
u
<
a.
2
H- i

B,



























































































1
C -H
0 1 

I/) -H cd C X X -H o X H C t/)t/> rt (ii •-$ r^ C fc cs rt CT> •H 0 -^ J-l rH S i-H O P 1 4-* " O O rH t/) -H 0 X N fn S <+-i n3 N •H O C nS T3 W rt fn C ^ W O •H 0 TJ 3 P X O O -P C ^ -H r-H 0 rt o fn > |3 0 t/) v_^ t/) fli-H •H C 0 •H f-l (/> 0 C 0 i-H f-l O T3 > n} U) •H 0 O S 0 X -P 6 tJ P fn i/) rt rt O 0 6 -p I (^j n— \ r- » *^ »-AH Tj K. rt 0 -H o rt 2 fn O p O • • (/) p c 0 g o u f-l 0 X p o ^ ^ rt o t-~ CT> 1— 1 V ' •, T~1 1 /*~\ rtl oo . I~- +-> CTl 0| r-l X p 0 03 5-i 0 rt K S i— t CN tO 579


-------
                           SECTION 12

                            METHOMYL


NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

1. Product Names:  Lannate.

2. Vapor Pressure at 38°C:  4.0 x 10~  mm Hg (Spencer, 1976).

3. Solubility in Water at 25°C:  58000 ppm (Martin and Worthing, 1977).

USE

1. Type:  Foliar treatment and systemic when mixed in soil.

2. Primary Crops Used on:  Tobacco (the use of methomyl accounted for
   21.9% of the 3.2 million pounds of insecticides used in tobacco in
   1976); peanuts (use accounted for 25.0% of the 2.4 million pounds
   used in peanuts in 1976); cotton, soybeans, alfalfa, Irish potatoes,
   other vegetables (Andrilenas, 1974; Eichers et_ aj_. , 1978),

3. Rates Commonly Used:  In 1971 application rates in crops using
   methomyl averaged 1.27 kg/ha (Carey e^ a_l_., 1978).

4. Formulations Available:  Water soluble powder, wettable powder, water
   soluble liquid, dusts, granules.

BEHAVIOR IN TREATED FIELDS

1. Adsorption and Leaching Characteristics:  No leaching data, distri-
   bution coefficients or Freundlich adsorption coefficients were found
   for methomyl.

2. Persistence:  Laboratory and field studies show that methomyl has a
   half-life of less than 30 to 42 days; some of the disappearance may
   be due to incorporation into soil organic matter  (Kaufman, 1976).

BEHAVIOR IN AQUATIC SYSTEMS

1. Persistence in Water:  No data was found specifically on the persis-
   tence of methomyl in water; however the carbamate insecticides,
   though less persistent than the organophosphates, do not degrade
                               580

-------
rapidly by chemical hydrolysis in conditions of temperature (zero
to 25°C) and pH values (5.5 to 8.5) found in aquatic environments
(Faust and Gomaa, 1972) .   When five carbamate insecticides were
added to raw river water (pH 7.3 to 8.0) and held at room temper-
ature, degradation was fairly rapid; carbaryl and Zectran and their
suspected degradation products disappeared from the water in two
weeks time whereas Matacil, Mesurol and Mesurol's decomposition
product 4-methyl-thio-3,5-dimethyl phenol disappeared in four weeks
time.  Ninety-five percent of the Baygon degraded in eight weeks;
Baygon's phenol was not detected after eight weeks (Eichelberger and
Lichtenberg, 1971) .
                            581

-------
                  3
                  tr>
                  O
                  04
       C
       O
                 0)
               6  fc
              •H  3
       •P -H     Cti
       ri  X    4->  3  Oj
       C      W
       0) <4-l  O
        O
       U
               O T3
              ^  C
                   rt
a
i
                  •a
                  0)
w
                                01
                                V	/


                                 6
 £
                                              O)
                                               OH
                                               CX
r-t     00


O     O


A
                                 0
                                 I
                                x>
                                 c
                                •H
                                 rt
                                        t/1
                                        •H
                                               X
                                               I/)
        

       rH
       i—H
       •H
        txfl
        (U
        3
       rH
       CO
                                                                 CJ)
 M
 c
•H
X
 •P
 (-1

i
                                                                 §
                                                                 •P

                                                                 I
                                                                 582

-------







I/)
p
"3
t/>

OS






c
o
•H C
•P -H
rt X
h 0
p -p
fll (It
Vi/ NH
0 O
c
0
u

13
0>
P
(/>

•H
c
rt
bfl
f-i
O





i— i
/-~N
(U
r~H
3
(/)
OH
rt
O CM
(N O
C o m
•H Lft Q
Q .-J
*1 J
 r-H
o ^^ rt
T3 Clj £

^H O 
cu
^ (U
0 M
5 £
r-l (N
583

-------
                                 SECTION 13

                                METHOXYCHLOR


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Marlate, Dianisyltrichloroethane, Dimethoxy-DT, DMDT,
         Methoxy-DDT.

      2. Vapor Pressure:  No data found (Spencer, 1976).

      3. Solubility in Water at 25°C:  0.10 ppm (Freed, 1976).

B.    USE

      1. Type:  Non-systemic contact and stomach insecticide with little
         aphicidal or acaricidal activity.

      2. Primary Crops Used on:  Alfalfa (the use of methoxychlor accounted
         for 25.9% of the 5.4 million pounds of insecticides used on alfalfa
         in 1976); other hay and pasture, tobacco, corn,  peanuts, other field
         crops, fruits, nuts, potatoes and other vegetables (Andrilenas, 1974;
         Eichers et_ al_., 1978).

      3. Rates Commonly Used:  In 1971 application rates  in crops using
         methoxychlor averaged 0.19 kg/ha; rates ranged from 0.01 to 0.02
         kg/ha in field corn (Carey et^ a 1. , 1978) .

      4. Formulations Available:  Wettable powders, emulsifiable concen-
         trates, dusts, aerosols.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Methoxychlor is very
         strongly adsorbed to soil particles.  When applied to soil surface,
         95 to 97% of the residues leached no further than the top 10 cm;
         the remaining percentage migrated as much as 100 cm through the soil
         profile  (Obuchowska, 1972).

      2. Persistence:  Methoxychlor applied to soil at a rate of 2 mg/100 gm
         soil persisted for 20 to 38 weeks; persistence was inversely related
         to soil moisture levels (Obuchowska, 1969).
                                     584

-------
      3. Runoff Losses:   When grass grown on a silty clay loam (slope 0.2%)
         was treated with 22.5 kg/ha of methoxychlor, 0.0047% of the pesti-
         cide was transported away from the field during the 14 months follow-
         ing treatment (Edwards and Glass, 1971).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water: In water, methoxychlor declined from appli-
         cation concentrations of 1.5 mg/liter to 0.5 mg/liter after 155 to
         169 days; a further decline in concentration was not observed be-
         tween 169 and 460 days (Luczak, 1969).   Bender and Eisele (1971)
         predicted that methoxychlor would persist for 2 to 7 days if bio-
         logical degradation was the major mode of degradation and 200 days
         if hydrolysis was the major mode.  Further studies have shown that
         if chemical hydrolysis is the only mode of degradation, methoxy-
         chlor 's half-life in water is one year; the degradation products of
         hydrolysis are anisoin (the major product) which hydrolyzes faster
         than methoxychlor and DMDE which hydrolyzes slower than methoxy-
         chlor (Wolfe et^ al_., 1977).  When concentrations of 0.1 to 0.2 ppm
         methoxychlor in water were exposed to ultraviolet light approxi-
         mately 50% of the methoxychlor decomposed to form 2 metabolites in
         one week; 90% of the methoxychlor decomposed in one month (Paris and
         Lewis, 1973) .

      2. Persistence in Submerged Sediment:  The ratio of adsorbed to free in-
         secticide was 10:1 when methoxychlor was added to a turbid aqueous
         suspension (Richardson and Epstein, 1971); however, when methoxychlor
         was added to pond water at a concentration of 0.04 ppm, residues
         were not found in the bottom sediments (Kennedy et_ al., 1970).
         Methoxychlor persisted for one to more than three months in four
         different flooded Phillipine soils (Castro and Yoshida, 1971).
                                     585

-------
LO
















































X
co
ss
<^
rn
2
o

u

1
01


z
o

frH
£_J
*-C
a,
•S
H- f















































































(/)
•M
r-H
j3
t/)
CD
05










o CD
C g rH
P .H 3
• H C -P P
•P -H TO
TO X CD rH
rH O rH CD
P -P 3 P-
{3 i/i 6
CD (HH O CD
O O PH -P
O CD 13
U ^ C
TO












*rj
CD
P

CD
H

6
•H
C
TO
bO
rH
O






to"
rH -
X CN
43 43
40
13 12 E
CD O O
0 rH rH
3 bo LJ-H
13 CD
CD P 13 03
rH -H CD bO
43 > rH
X -H O TO
•P X E
•H f3 CD X
> -H JH 43
•H o\°
•P O Hj-J t/1 CD
CJ 00 O TO rH
3 C 5 3
13 4->
P 13 +-* rH
rH -H 3 3
PH TJ 43 0





, — ^
CO
f_4
C~|

s

43
PH
PH
O
0
O
rH
05
PJ
U
Q
O
OH
>- C
05 O

Us .M
rH C
05 TO
OH rH
PH
Q P
§ X

CO PH
05
tU CD
CO C
O -H

23 CD
O TO TO
CJ HP bo
PJ (/) i-H
Q PJ <





\D
t/l
X
TO


CD

•H
t4_|

C
•H

T3
CD
rH
rH
•H













S
P.
PH
0
CN
















P3
CD

TO
rH
•H
<4H

rH
TO
bO
rH

I/)
CD
3

•H
t/1
CD
rH

13
CD
4_)
TO
rH
rj
r4
3
O
U
TO

r^
+-»
P





























I/I
CD
C
CD
bO
P
CD
TO

fa
(U
^J
0
TO
O
P
£H
CD







1

O
r
X

e
p

^i-i

X
i-H
4-*
CJ
CD
^1
•H
13














P
j 1
+^
LO
•
O




























-a
CD
X
CJ
TO
CD
£_|

JW
rH
CD

0)
rH

i-H
TO
•H
J_j
CD
P
O
TO
43









rH
CD
p
•H
rH
"^
bO

O
•
LO












I/}
•H
""^
43
3
t/1

to
3
rH
rH
•H
U
TO
CQ
to
rH
CD

CD
rH

to
_
X

0
o
t~O
>\
^-

p
p

o
o
Tt-

i-H

























































CH
CD
p
TO
3

C
•H

•o
C
3
p















































                                             CD
                                             P
                                             TO
                                             CD
                                             CD
                                             i-H
                                             rH

                                             •H
                                             O
                                             CN
oo    oo     oo
   000
   LO    LO     LO
  u     u    u
  BJ     OJ    PJ
U
p

•
LO
rH
rT
X
00
\ — i
43

PH
00
t~^
O

f — ^
p-
0
00
vO
•s
X
^j-
CN
V 	 '
43
PH
P.

t--
to
CJ
p

>
LO
i — 1
f-T
X
00
s
43

PH


LO















co
05
PJ
^
p^
CO

o
CJ
















TO
P
N
P
P
0
rH
cx

t/!
C
TO
rH
CD
CJ
O
TO
rH
O

* *
to
C
TO
CD
O
TO
•P
t/)
3
rH
CJ
to
3
H->
TO
i — I
3

rH
W
X
CD
rH
3
P.

TO
• H
C
X
p.
TO
Q
TO
C
bO
TO
e

TO
• H
C
X
p.
03
Q

(/)
3
rH
TO
X
P.
CD
CJ
p
6
•rH
CO


                   586

-------




























t 	 N
CD
3
•H
4->
C
o
CJ
^^
(/>
S
en
1 — 1
§
o
OS
o
CJ
rH
H

113
o^
^
§
H
CJ

a.
S
KH
W


























































to
4->
rH
3
to

OS




/•— \
0) CD
C 6 rH
O -H 3
•H C -M +->
4-> -H rt
CTJ X CD rH
rH O rH CD
•P 4-> 3 P-
C  4-> J rJ J ,J rj rJ


f~\ f~~\ /~""\ /""*\ »"— 1 /— "\
U U U U U CJ
OOO OOO
rH rH rH OOO
CM CM CN  \ 	 J \^J V— rf* ^^ V_^*

E E rQ FQ jr\ lr*i rf^t ro
P^PH CL, QH & QH QH P^
o . o t o . r^ . o j o j o j ^ .

rH
O *3"
O ^ C71 tO OO
OO CMrHO ^CMrH
rH

to
3 '
O
•H t/)
rt o
J3 tO Q^
0-3" ed
rt +J O
rt to 0 cri to
tO 60 Tj Tj t/) »H to
CO 3 CD O O fn 3
WrH-HpntO CDCCtiPn
H rH > -H -H C -H 00 rH
<;CD-HXrH -HP-rHrt
OSlO>P,-P rHl030
CQ<; 6to rtB>-H
ji] tO ctf 3 S CD 60
H 3O +J to c
OS •• rH cS P. CD O
UJt03"rH  CD O to to CD
2 4-> -H C 10 C
rHCDrHClJ3 COlO
rt rP CD rH O g 3
CJXEOrt MCDrH
rHO3rtE CctJ3
:CO(J4->E rtrHC'
t-i 60 tO Pj rH Pj CTJ
Z -H •• 3 u cj a. a,
UJ rH H
OQ O CJ

CM CM CM tO
rH rH rH rH
000 C
in to LO L/
CJ CJ CJ CJ
rJ J rJ rJ

/ 	 \ 1 	 \ / — \
CJ CJ CJ
OOO
in m if)
...
in in in
rH rH rH

•» ^ »\ /-— \
rH rH rH rH
,C rC J3 rC

^f 00 xO ^H/
CM ^ Ol CM
^^/ ^~~J ^~S ^^>

O O f*i f^
PH pi , pi r pi t
PH PH PL, P^



o n-
O 00 rH I--
tO vO





1
1
cS CD
TJ 0 rt
rt -H >
•HP! rH

CO rH
X'H O
rH rH +J
'n rt -H to
CD 0 3 C
C cr ed
O tO to 60
•MX O -H
tO O S 4->
fn ct)
rt M-i
rt O X
4-> rH CD
O CD rH
CD 4-> 3
to O- CJ
c
rH

587

-------






































/ 	 1
0
3
C
•H
P
C
o
s
(7}
^
*?
CJ
Q-
0

U
I— I
£— i
<3^
3
C/


z
o

H
U
^
a,
S
h- 1
UJ














































































(/)
P
rH
^
(/)
0
o;









/ — •*
0 0
C 6 ^
O -H 3
•H C P P
p -H rt
Oj X 0 ^H
H O fn 0
P P 3 PH
G WE
0 4-1 O 0
U O PH P
C X
O 0 13
U ^ C
rt











*"O
0
.p

0
H

l/l
e

•H
C
a)
W>
^
O






1— 1
o
4-4

13
0
W
I/)
0

PH
0
13

C
o w
•H A;
p 0
rt 0
•—i S
3
PH 0
O S
PH P




S
PH
PH

"*3"
O
•
0

*"O
!3
rt
i— <
O
•
o




tSl
13
•H 'o?
rt rt
pj ^O
•H
X C
rH O

rH ?H
0 W>

6 C
rt 0
13 o
u
V — /
« •
rt
p
O
0
to
C
1 — 1

1 — 1
"3- O
I— 1 ^H
O ••> 1 P
S P 0 G
P (3 ^ O
0 O
fn 6 X
O P i— I <4-l
u-i rt c o
0 O
P ^H 0\°
C P W 0
0 X^J-
to f-i rt
43 0 T3 O C
nj P P O
4-1 ^t -H
to rt oo T3 p
P 0 Oj
O (/) fn f-i i— I
0^003
(0 0 -P > PH
G 0 4-1 O O
•H S 0} O PH













e

PH
O
•
0








f — ^
13
•H
•H
C
X 0
i~H bfi
m nj
XP
rt PH
6 0

\ — '










^J-
r— 1
X
1 — 1
p

w>
•H
1— 1
(/)

to
C
O 13
•H 0
P W
oj to
r-H 0
3 ^
PH PH
O 0














6
PH
PH
O
•
0






/•""**
13
• H
^_)
0
CTJ
CO


X
1— 1
4-1
X
rt
€









                LO    LO     LO    LO
                                               LO
                  U
                        U
                       O
                        
-------







































/ — ^
•0
CD
3
C
•H
c
o
u
n
^3
OS
0

u
H

3

«3j

0

H
U
^
h- 1
PJ












































































tO
P
i— 1
3
to
CD
OS










CD CD
C B h
O -H 3
• H C P -P
P 'H rt
rt X CD !H
fn O fn (D
fi *"" W i"
CD 4-4 O CD
O O ft P
C X
O CD 13
rt










13
CD

to
(D
H
w
B

• H
C
rt
£f
0









































































to
C 0 CD
<0 r-H fi
45 O
\Q U f_|
•H CD C

O IO CTJ
+J X 3 t/> t-~-
pj CD i— 1 OO
'O FO .'"I 3 ^3 pH
CD to 13 CD B
P 1*^ CD *H T3 i-J
rt fn (O t-~ fn H
^-i C MH CD i— 1 03
P -H fn 13 P
C C V CD
CD 43 -H  CT) CT>

O O ^Q f*l
ft ft ft ft
ft ft ft ft

LO O LO vO
r-4 CN LO
vO
0









r"]
P O
3 ^
O CD
H ft 4!
S -H
^ 0 M-l
O r-l 13
O i— 4 I— 1
fn CD O
ca >- u

r-l X
CD CD
4-* P
•H CD
43 •— i
•H ft
45 B
C 0
•H CJ
[•^
OO >— I to to 13
i— I O bO bO CD
B LO bO bO P
J J CD CD -H
HE- 43
4-1 4-1 -H
O O 45
C
bO bO -T-I
C C5
• H -H
f^ t-|
O O
•P -p
rt rt








fn fn (H f_i
45 45 45 45
vO vO vO vO
C7i OT CT) CT>

4^ 4^ 43 4^
ft ft ft ft
ft ft ft ft

Tt i— 1 CN
VO tO
vO
00








O
C
c
•H
B

cj
CD

•P
rt
tu











LO LO LO LO
t— t i— 1 i— 1 i— 1
B B B B
j _l _l j
H H E- E-












O O 0
t^ to oo
• • •
CN 00 tO
i— 1 t-l CN

^H f-i fn f-i
X 45 45 45

CN CN CN Ol

43 43 43 43
ft ft ft ft
ft ft ft ft


00 t^ to to
LO VO OO LO







4:

•H


(/)

1— 1
rH
• H

CD
3
^H
CO

589

-------











































f — *
-0
o
3
C
P
C
o
u
co
rH
§
OS
o

u
H

P
cy
^£

z
o

H
u
i^
CX
S
rH


















































































to
•P
rH
3
to
O
O£










o o
C 6 rH
O -H 3
• H C 4-> +->
P -H 03
03 X O rH
rH O rH 0
4-1 P 3 P-
0 4_| W §

0 O PH +J
(3 X
O 0 TS
U v— ' C
03











13
•P
to
O
E-
to
E

•H
C
OS
bO
rH
O











r^
rH (0
to o
0 6
3
(/} CM
to
•H C
P -H

C ""^3
• H 0
J_j
V) 03
0> 0
^ OH
13 PH
•H 03
to to
O -H









I
1
|
1
1
















("•*
to
•rH
c
3


rH
rH
•H
too
O
3
i— i
QQ

O rH
030 X
CM 13 4-> rH
CT> 43 O -H OS rH O
rH U -H t/1 S CM P
1 -H -HOT3 43pu
rH -H t/l -P O 03 -H -H tO PL,
64-lOrHH-> -H+Jt/1 -HOJ
•J PnOfH rHOSO 4H
H OX6O 4->rHrH 4-1
X 0 43 to CO
•P S oi O •> O -H
CO rH S -P O
4-l03rH^ MO rH «4-IX
O o\° O 4-> 43 •• O -H O
toO'd O •PtOt/lO 3rHO
o\° C O •* bO X-H LO T3 i S
LO-HWIC 031O4-ILO •H4-H
rH>3Ol3 O rH tOrHO
•HoSi-HO COC Oo3C
i > 0 v-' X -H 0 -H II rH 43 O






/ — \

43 *• — ^
10
vD X
CTi OS
^^ -a

O f^)
PH ^-^
PH
1 1
O 1 1
CM 1 1
rH 1 1










43 43
to 10
•H -H
t4H 4H

O 0

O -H -H
•H 3 3
PH cr a- 43
PH tO 10 tO
3O 0 -H
US S tt,





CM
CM
1
10
•H 10
13 X
OS
43 13

•H r^
4-4 rH

C C
•H -H

t/l 13
O O
3 rH
13 oi
•H O
t« P-,
o p*
rH 03

















1
1
|
1



















43
to
•H
[I*

                                      to    to
                                      CM    CM
                                         O    O
                                         LO    LO
                                        U     U
                                        LO


                                        LO
                                        PH
                                        PH

                                        O
                                        VO
 U
O
 LO

 LO
                                             CN
 PH
 PH
                                              O













co
^
<2
HH
CO
rH
X
tx



^ — ^
o
0
PH
13
03
^ — /
13
ctt
O
-P
to
••
rH
O
rH
3
O
UH
O
PH
13
03
P

bO
O
rH
to
e
o
43
U

C
rH
O
4^J
t/)
O
S
590

-------
TJ
 O


•r-t

 C
 O
u
                                    LO
                                    \o
co
                                         to
g
o
o
H
§
E-
U
O,
S
              <—v   LO


              LO   CTl
         tO
         r-t    +J
               |  rH
                    (DC
                    PJrt
LO   -H   X



r-H   fJ   S
                                               C   0>
                                                               O^
00

CT>





 PH



     OO


"8   CT>
                                                                                                     LO
 0)|  -H
      N   C    W
                                                 «J|

                                                 4->|
                                                 
                            (Dl  CTl
                                 r-H
LO


CTl
                                                                                                                rt
                                                                                                                o
                                                                                       y    o
                                                                                           G    
                                                                                  (U    Cd    rH
                                                                                 2    2   u.
                                           o
                                           r-
                                           CT>
                                                            0>

                                                            C

                                                            t/>
                                                                                                        CTl   O   r-H   r«J   tO
                                                                                                        r-t   CM   CM   CM   
-------


























































C/D
s
CO
h- 1
p?;
^£
U
OS
o

>J


rt X 0
fH O fH
•P -P 3
e 
I/)
0
H

i/)
B
t/>
•H
C
rt
tu
fH
O















rH rH rH 1— 1
O O O O
LO LO LO LO
U U U U
J J -4 J










/• 	 •* t 	 -i f 	 N
-o
0
0 (/) - Z Z
M-H r^S
rt
0
•P to
rt
0 X-— N - - -
fH rP 13
+-> 0
13 0
 4-> 0 X
T3 C -P -H
fn rt -H c
rt  0
•H rt HH
Cf) 1
CM T) O rH rH
0 C 0
 C
O O rH 13 0 O
LO 1-4 JD 0 1-H -H
rt PH 0 o E

rt fH O bo MH t/)
fn 0 U 3 HH: W
O rO cij t/) D rt



















X
3 3 rt
rO ^Q T3

M DO bO
^ r^H pM rH
^v^. **x^ "^ ^^^
bO 00 bO M
E B B ^>

O O rH O
O CN O
O 00 O 1^
LO O-l




























{/)
co C
i-j i/) rt
< -P 6
S rt 3
S OS X
=


i
to o C
0 CM 3 rt
i/) x o
fH X rH 0
0 B O -P
> 0 -H •- 0
rt <4H 3 0 "PH
1 0 E
O rH CN 0 0 O
C 0 4-> HH O
r-* P "H
T3 0 O rH 0 (/)
0 rH -H O A -H
0 o B -P C
(DjQ 030 'H B
t>0 ^H t/1 B O
J3 t^H ty) J^ fH
t/) 0 rt rt *T3 ^H
0
in ,Q -P
rH 0 3
0 X! «
•H 4-) 0
X fH
E
fH O 0
0 fH 00
> <4H rt
rH 13 O
0 4->
0 > I/I
X O
•P B 0
0 3
C fH t/) •
• H t/) ,— •>
13 -H LO
PI C -P r-
O rt CT>
•H 3 rH
4-^ 0 O
rt G rH •*
rH O -H -H
^ — . 'H -p 'O M
bO X I/) (S N
^i o 0 rt rt
4-> +-> fH
0 0 C X O
13 -H 4-> 4->
LO -H 4-i
to 13 0 O 0
•H ^ -H >
PH 4-1 X ^^
rt O
fH 0 4-> E
4-i t/)
(/> C 1— 1 TH
- -H rt rH
fH fH 0
O -U O ,Q
i— i 0 rt
fi 4-> (S 4->
O 0 rt 0
X fn -H B
X 0 rH
0 X rt -O
rC 0 g -H
4-> g PH
0 (/) rt rt
s -H e fn


• •
t/>
•P
C
0
g
g
o
U

fH
0

o

592

-------
13
 0>


 C
•H
4->


 O
co
OS

CO
tu
O
t^
Oi
g
 nJ|  oo
   I  ^
•p   o>
a.
S
4->   0)
rt   ^i   co
a;   as   <;
X   S   2
                                                           593

-------
                                 SECTION 14

                              METHYL PARATHION


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Dalf, Folidal M, Metron, Metacide, Nitrox 80, Panton
         M, Bladan M, Tekwaisa, E 601, Metaphor, Folidol 80, Wofatox.

      2. Vapor Pressure at 20°C:  0.97 x 10~  mm Hg (Martin and Worthing,
         1977) .

         Solubi:
         1977).
3. Solubility in Water at 25°C:   55 to 60 ppm (Martin and Worthing,
B.    USE

      1. Type:  Broad-spectrum, non-systemic insecticide.

      2. Primary Crops Used on:  Cotton (the use of methyl parathion accounted
         for 31.2% of the 6.41 million pounds of insecticides used in cotton
         in 1976); wheat (use accounted for 16.7% of the 7.2 million pounds
         of insecticides used in wheat in 1976); soybeans, corn, sorghum,
         other grains, alfalfa (Andrilenas, 1974; Eichers et^ al_., 1978).

      3. Rates Commonly Used:  In 1971 application rates in crops using methyl
         parathion averaged 3.15 kg/ha; rates in cotton ranged from 0.06 to
         11.21 kg/ha (Carey et_ al_.,  1978).

      4. Formulations Available:  Emulsifiable concentrate,  wettable powders,
         dust.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Methyl parathion is strong-
         ly adsorbed to soil particles.  Li and Fleck (1972) have reported
         presence of small amounts (in parts per trillion range) of the
         material in surface and subsurface rain effluents.  Haque and Freed
         (1974) have estimated that leaching will move methyl parathion less
         than 20 cm through a loam soil udner an annual rainfall of 150 cm.

      2. Persistence and Vapor Losses:  Methyl parathion has a short residual
         life on treated plants; in midsummer, applied concentrations of
                                     594

-------
         106 ppm may fall to 3.9 ppm 96 hours after application (Ware et al.
         1972).   When the material was applied to a Carrington silt loam
         only 8% of the residues remained 15 days after treatment (Lichten-
         stein and Schulz, 1964).  Later studies by Lichtenstein et^ al^. (1977)
         have shown, however, that while only 7% of the applied methyl para-
         thion was extractable 28 days after soil treatment, 43% of the
         applied material persisted in the form of nonextractable bound
         residues.  These bound residues are apparently not excluded from
         environmental interactions (Fuhremann and Lichtenstein, 1978).
         Spencer (1976) has reviewed the data on methyl parathion's vapor
         losses  and has concluded that vaporization is an important pathway
         of dissipation from treated fields.  Haque and Freed (1974) have used
         the best available information to form a vaporization index; accord-
         ing to  their estimates, methyl parathion may have vapor losses amount-
         ing 7 to 14 kg/ha/year from a loam soil at 25 C under an annual rain-
         fall of 150 cm.  Methyl parathion has been detected in air samples
         from Alabama, Florida and Mississippi (Stanley et^ al_., 1971); the
         maximum residue level of methyl parathion found in the air above the
         Mississippi Delta was 2060 ng/m , a level which was 313 and 1315
         ng/nr higher than the detected maximum residue levels of toxaphene
         and DDT, respectively (Arthur, 1976).  Methyl parathion has also
         been found in indoor and outdoor air samples taken from pesticide
         formulators' homes (Tessari and Spencer, 1971).

      3. Runoff Losses:  When four different plots of cotton grown on loamy
         sand and sandy loam soils (slopes of 4% and 2%, respectively) were
         treated with 13.4 kg/ha of methyl parathion, 0.008 to 0.25% of the
         pesticide was transported away from the field during the 4 to 6
         months  following treatment (Sheets et^ al_., 1972).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1. Persistence in Water:  Eichelberger and Lichtenberg (1971) found
         that methyl parathion degraded completely in bottled raw river water
         (pH 7.3 to 8.0) within 8 weeks and USEPA (1975) reported that per-
         sistence of less than 4 months in lake water.  Apperson et_ al. (1976)
         in a study on Clear Lake found a carry over of methyl parathion
         residues from treatment-to-treatment when the material was applied
         at intervals of 20 days.

      2. Persistence in Submerged Sediments:  When Clear Lake was treated with
         methyl  parathion in the absence of residues in sediment samples
         suggested that degradation took place before or upon penetration of
         the bottom mud (Apperson et al., 1976).
                                     595

-------
















































CO
^
CO
I-H
2

OS
o

CJ
HH
H

O^
^

2
O

rj
^
OH
l-H
w








t/)
^_>
1— 1
2
(/)
 4-»
4-> -H Cd
Cd X 0 ?H
h 0 fH O
4-> 4-> 3 P
c we
0 t4-l O 0
0 0 P, 4->
C X
O 0 *O
U ^ Pi
cd














0
(/)
0
t_l

s

•H
c
cd
1
















































OS
w
U
Q
O
OS
OH

>H
OS
t — 1
OS


Q


co
OS
UJ
CO
o
Cu

Q
CJ
Q

T3 I
0 -H 1
4-> 4-> IO
•H O O
•H t/) Pi
42 C 0
C -H Pi 10
•H cd 0
0 bO *"O
0 C *H -H
^ -H O U
O ^ -H
6 O X 4->
rH 43 CJ
4n 4n 0
o o pi to
3 0 cd pi
6 C 4: -H

43 W>  $H W 3
S O 0 ^
O T3 O
SH X-H 43









I
1
I
I


















O

^
c
cd
i-H
P.
O
4_)
X

0
C
•H
cd

(0 C CM
1 0 O pi 1
fn •- I O •<-! O 0
O "O O t/) X 4J -H 43
t4H434->Cdl3 434-1 13 -H
O O t/) GO "H PJ *H Cd 0 *T3
O 0 JH CJ «rH 4^ !-i 4-1 I/} P;
p;p;4-io-H ccd r-iccd
OCd 4-IW-HP, 3O
• HtJOt/ltOOp! l/l «H l/l
4-1 ^H 0 i-H 0 O 0 i-H 0 4-* P
•HOT) tO-HOOX VlOO

•HCMOO'HOfH4-> WT3CJ
f*^ I-H >rH 300 S ^ X
C 4^ 4-* W Ti r* S TJ O ?H O
•H ^nO330cd 0 O
O0Of-if-:> — ' / — v4-i r-t tt-l
0 C4H t/1 O ^^ (/) 43 O Cti
W) PI LO f, T3 o\° LO 0 -H
Cd o\° -H P, 0 O -4-1 X 0 Pi
fntO XWW--HLO >W43
0 • 0 r~H O 3 CM 4-* Cd 3 P
>uop;p;rc;cdt4-i o 0cdcd
Cdl^-'HOPnOOM Pi 4SOQ
i
•H 43

Pi PH
P> ,
cd tn

^~. 0 MH
^ > 0
4; -H
to to
^" t/) pi
^— / 0 O
O -H
43 04-"
Pi 3 cd
Pi tO CJ
O fO
o
o
i-H





0 1
cd i 
C i-H X •!-
o rt o i-










to
6

H
t

to
J3
S
o
p
H CS
•H
Q






/ — v
^_|
43

00
^f*
V — J

43
Pi
Pi
00
•
^





1

t/)
C C
O cd
tj
£t pi C bO 0 0
C 0 -H p; ^H o
cd 0 *r-
i-H fH H 1-
PH bo O t—
O i MH -i-
+j 0 ^
X 30
43 I-H --H T;
Qj _Q -O f
•H O
•H T3
TJ cd
i— i i— i cd
•H 0 Pi
5 ,-*. bo
to •• cd
T) T) to S
^•H cd pi G fl
0 W
C cS C b
•H GOP
?H 0 P.M-
3 cd to 4-
cd 43 0 c;
4-> cd fn C
to pj
UJ <

cd O co cd cd
Q P, OS 0 -H
! rX W O Pi
< 0 6 g cd 43
> O fH 5 4-1 P
i 4-> cd co to cd
) to <4H 2 3 Q
0 H
U U

596

-------



































/— s

'S
to
0
OS










0 0
c a JH
0 -H 3
•H C -P +J

hH 0 rt U X! I-H O 2 -H W --H CQ O 1 •H S 0 rt ^ 0 o •P X •p 13 -H i-H i— 1 3 rt o +-> O !H O w a g H -P 0 3 S 0 LO LT) LO O O O u u u u o o CM LO vO PH PH 3 O LO U hJ o PH 6 •H fH x: to t4-l O x -p •H i— 1 •H XI rt ^_i • H rt PH a •H 4-1 i— l 3 W> X XI c o •H •p rt 13 0 fn PH 0 c*> J rt 0 t/l 0 l/l •H 13 C rt bO to ^ 1— 1 3 C 3 P-, 00 x; t/l •H 4-1 •H 1— 1 I-l • H ^ 4-H I-H 3 f~*t to fn •H O *-H -4-* •H rt i-H Hj l— I 0 • H £n r^H PH i O fn PH fn 0 ,|_J rt 0 bo rt 13 0 a 3 to C o 0 c 0 x; PH a •H f_4 x; to to t/l rt bfi 4-4 O c o •H •P fn O PH 0 0 13 I-H C -H rt C 0 PH > S _3 £_l X! 0 10 i-H ^Xl •H to p 0 PH •H 0 0 O 0 t/l PH 3 l/l t/l X to 0 i/> M 0 OH--H (D rH CD |2 ,. — N t/) ^2 0 c c •H a *"O rt _fH to PH O 0 <"] l/l 1 0 0 c o o 1 — t rt x; 0 ,_ i r*i 3 O -o 0 to o PH X 0 4-1 1 0 t/l 0 bO bO 3 in ^_i o r~] ^_> 3 rt • *\ t/i C O •H •P rt ^_f +-> 3 O0 •H!H •Hn3 t/>-H 03 Es CJ o OX 1/>H 010 •HfH O0 0 r* Pw-l T3 t/l 00 M-H 00 P0 rH PH CtfW CJ O o CM vO CTi XI PH PH U O O CM 01 PH PH U o CM I CM to CM I LO to c o •H •P rt fn •P 0 O § O rt x: 0 i-H •§ 10 1 t/l 13 O PH rt o 0 13 0 c • H fH rt • • t/l C rt 0 o rt P t/i P i PH a •H £_| x: fn rt o C •H Q_ I/I g« 0 •P PH 0 l/l c o bfl C rt u to •H £_l rt bC i— i 3 > to 0 P 0 C 0 a 0 rt rt a. 0 P 1/1 3 £_| rt O • H bO C O I— 1 10 g rt bo rt a, rt X! to 0 £_| UH • • 1 to •H l/l c 0 ^ rt •H "T3 rt ^i 1/1 0 p 0 £ O 0 rt i— i rt a, PH a • H £_l X! l/l l/l l/l rt £_4 CJ3 • • O 1 •1— 1 tiO 3 f*l J t/l 0> f^ 0 0 rt i-H rt a, t/l o rt !H +-> C CD O g O rt P CD i—I X> 3 t/i t/l O t/) -H to bO rt 3 ^H PH o to CD •• -p 0 § CD rt rH rt a. u 597


-------



































/•— \
rx3
(D
3
c
•H
•P
C
O
U

CO
CO
5
^£
§
o
U
r— 1
£—1
^£
3
•^
2
o

H
U
<
r— 1
PJ






in
^>
rH
3
tn
0)
o£









/— -V
d) 0
C 6 M
0 -H 3

•P -H nJ
OJ X <
O (D-d
rt














•8
tn
o
H

V)
s
•H
C
rt
00

^^




rH O
•» c
in
•H -H
?H X
(i O
rH (N O
OOOO i— 1 i— I tOtO ^HtOtOtOtO
Or— Ir— (•— 1 O O rH i— ( CO r— 1 r— 1 r— 1 i— 1
oo ^6 ^6 6 LO LO 6 6 -H B ^E 6 6

*JHHE- nJj HHT3O E-HHH
C -H
3 -P
O erj
+J
rQ C
ft 
CT> O -H
LO O bO
u1 u1 u1
O O O
CM CM (N
to to to
1 1 1
vO vD ^O
r-H r-H rH
/— ^
V) ** * * / — \ t — \ f — \ / — \ f — \ t — \ t — \ t — ^
^^ rHrHM r-
•rH CTj
^ij ^
X fH
rt .H .H -H -H rt in
rH -H -H -H -H rH 3
O M X ^ AS C P
rH rH rH rH O CTJ 3
'^ rt rt rt rt 4^ B O _^ in
(UrHrHrHrH-Hin-H rH WW
JHOOUO3CX5 -P -P -HCd
CT rt rH 3 ,£ ^ r£>
intninininbOrt o-Prt coc
CrtnJrtc5ertJ T3 CTJ f-l O
o £ 6 S G ** 1) O O t/)Srt6
O rt cd c3 rt rt X <"] o p ^_> o 0 O
rt O O O O 4-* QJ O- C 5 ^-* O <~H ^0
4->OOOOOrHO -HOO XrHTJrH
30,0,0,0, inu
-------








I/)
p
I— t
3
c/)
/i\
U?

















t — \
0 0
C 6 !H
O -H 3
•HUPP
P -H rt
rt X 0 rH
rH O rH O
P -P 3 ft
C we
0^00
O O ft P
c x
u ^ c
rt











13
0
P
t/)

f-H

l/l
€
(/)
•H
(3
rt
bo
^i
O









\o
'""'l/l
0
(3
to to to rt
tOtOtOtOtOrHrHi — 1 43
i-H rH i-H rH O O O O O
6 B E S LO m in in
,-J1-JhJlJUUUUrH
O
• H
bO
O
rH
O
•H
(/)
X

ft





V)
C
0
•H
•P
rt
f_|
^_>
C
rHrHrHrHrHrHrHrHO
4343434343434343 C
O
vOvOvDvOOOvOvOvO CJ
OlOlOlOl^J-OlOlOl
rt
seGeee6643
ftftftftftftftft-p
ftftftftftftftp«0
rH
r~ O Ol rH l-~ vD OO 43
3
inoioor~-ooin\or-- w








43
43 W
(/) JB «H *O
•H O 4-1 rt
 f3 3 43
rt -H W rH
06 rH
43 rH 3
rH  -H rt -H 0) H
C tP. 0 bO A! -H -H +J. H 3 rtftUn
43OrtrtrH rH33
UUUnCJOQ oauix











rH 00
X rH

•H O
0 -H
•H P
^ t i
?S H
o o
p 42
rt
2
o w
rH 0)
0
X 3
rH -0
0 £
> -H





in
C
0

+->
rt
£_l
4->
0
O
g
o
o

rH
i rt

i P
1 (U
rH
O
3














43

• H
*-H

0

•H X
^g?| P^




0)
w
rt
0)
P

0 C

0 43





















43
fc






















• •
/ — \ i — \
t-^ oo
t^ r^
O> Ol
i-H rH
N 	 ' > 	 >
rH rH
rH rH
rt rt
tU UH
h- oo


•
/ — \
00
vD
01
i-H
'—'

r^
8
3
rH / — \

PL. \O
01
^3 ^^
^ \^ _t
rt

•H 0
cr w
rt -H
2: tu
•*t m
•
to
vD
O)

y j

(/)
^i
O
f — \ f3



^>
o
TJ
(3
0
DC
01


•
/ 	 s
o
f-.
01
rH
"-^
PJ
O
•H
t/>
s>
D*J
rH

b

''Q
C
rt

•H
bo
rt
•z
VO





,
j^— ^
oo
\D
Oi
rH
\^j

•
<
u
a.
^
•
tu
to
599

-------
T3
 0)

 C
• H


 O
u
co
OS
O

U
p—i

%


I


§
a,
S
               00
          C7>
 ^
 a>

•H
r—I
O


1
 rt
           X  O
           (J
           c   a:
                                    vO
                    CN
                    r^
                    CTl
                     o
                     t>0
                     o
                     
00

CTi



 c

 O

OQ
 Q)
13
!—I
 O
PJ
                   CM   to
                                                 oo
                                                             600

-------













rH
Z
Di
0
I-J
rH
Oi
H
Oi
Oi
UJ
H
§
u
O,
S
rH
rH
t/5
Di
o 6
•H C -H
•P -H P
cd X
!H O 
O
13
rH
cd
^_l
O
v — /
O
LO
U

13
0)
MH
C
•H

o
o
cd

£«
rj
g
•H
X
cd
B




-P

0
rC
e>0
•H
r]

C
o

13

(/)
cd
^Q
\»^ '


cd
rC

CD
t/)
o
ro

£>^
£_i
cd
•P
(D
•H
t3


/— ^
to
c
cd
B
3
rC

C
• H

X
•p
• H
^>
•H
•P
O
cd

tu
rC
U

C
o




^f
(D

cd

fi
•H

X
rH
•H
03
T3

CD
rH
O
cd
4->
p> |
0>
o
0
cd
•*fr
•P
o
0)
<4H
MH
o>

0)
w
fH
0)
>
13
cd
1
o
C

•"C3
CD
•P
t/)
0
bO
bO

t/)














0
c


B
o
rH


rH
(D

(D
rH
















13
cd
i
O
c

T3
(U
•P
t/1
0
bo
bo

w














O
CM
X CM

B C
0 0
rH -H
f 1 1 I \
ft

 w

rH Cd
^—^
 w
 X
 cd
        X
        cd
       13

       CO
 e      e
 ft     ft
 ft     ft

CM     "tf-
Oi     to
CO     rH
 I       I
LO
 w
 X
 cd
13

CO
              ft
 £
13

oo
       LO

       LO
                     00
                     to
                                  I
                                   W)
                                          W)
                            bO


                            to
                                                O
                                                O
                                                           X
                                                           cd
                                                          13

                                                           bo
                                                           B

                                                          to
                                                          «*
                                                          o
                                                          o
                                                                         3.
                                                                 O

                                                                 o
                                                                                       00
 rt
-p
c
03

cd
(D
f,
a.
              cd     03
              3     3
              cr    cr

              (D     a)

              • tH     
-------









































/ — \
TJ
0
3
C
• H
P
C
o
0
^^

SQ
2S
W
1— H
125
^
t3
QCl
O

J
<
rH
«
H
to
UJ
ai
Cd
OJ
H
Z
0

H
U
<

HH

•
PH
T3
0
P
rH
O 0) -H
ft rH > N
CD 0) oi to
rH > X 03
0 rH
C W 0
Q} {/) 4-J +-J
CD 0 OS p
X T3 r-l CD
•H >
0 0 C ^— '
> -H O
03 P X
X o in &o
0 CD O
in tn -H i— i
0 C -O O
O -H 3 -H
C p in
oj in oo X
X 3 X
( (, f-i
M " i-H
3 O •
P X ^ 0
in OH rH £>
•H in ^o -H
T3 o a> p
X rH 0
o ft 3
•HO - TJ
rH C 3 O
P 03 OS rH
n) MX ft
•H rH CO 0
X 0 !H
CJ 13
X O C in
in p 03 X
f-\ t.
H c =
.- 0 0 P
rH "* X I/I
o 2 in -H
P & rH T3
i ?S, /|\
•r-i ..J1 vJ
X ^ U C
•H X^ 0
X rH -H
C T3 in X
•H 0 rH P
P OS 03
UJ Oi 0 rH
X 0 X 03
U ft ft
0 O
Cd rH rH rH
X
in 0 o X
• H rH P P
0 0
C 3 CM S
O \
•H O rH p
X X 1 03
P 3 rH X
OS P
rH in 4-1
03 rH O t3
ft 0 0
^ in P
rH rH T3 03 •
X O O CJ /— s
X 3 -H -H VO
P rH *O r-»
0 C 0 C CTi
S -H ft-H rH

••
to
p

0

fc
o
u
rH
0
iX
p
o

































































.
f — ^
CM
t~- i-~>
O> \D
rH t~^
'•«—•' C7}
rH
• • v — /
i — 1 f — \ •
03 00 -H /— ,
,i^ N r->
p \ a\ N r-
01 rH 03 Ol
^-^ rH rH
X O ^
P 0 P
03 fH P CO
0 03 0 •<
X 3£ > Z

rH CM tO TJ-
602

-------
                                 SECTION 15

                                  PARATHION


A.    NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

      1. Product Names:  Alkron, Aileron, Bladan, Corothion, E-605, Ethyl
         Parathion, Ethlon, Folidol E-605, Niran, Orthophos, Panthion, Paramar,
         Parathene, Parawet, Phoskil, Rhodiatrox, Soprathion, Stathion,
         Thiophos.

      2. Vapor Pressure at 20°C:  3.78 x 10"  mm Hg (Martin and Worthing,
         1977).

      3. Solubility in Water at 25°C:  24 ppm (Martin and Worthing, 1977).

B.    USE

      1. Type:  Broad-spectrum, non-systemic contact and stomach insecticide
         and acaricide with some fumigant action.

      2. Primary Crops Used on:  Wheat (the use of parathion accounted for
         43.1% of the 7.2 million pounds of insecticides used on wheat in
         1976); sorghum (use accounted for 26.1% of the 5.4 million pounds of
         insecticides used in sorghum in 1976); cotton, corn, other grains,
         alfalfa, soybeans, vegetables, fruits and nuts (Andrilenas, 1974;
         Eichers, et^ al_., 1978).

      3. Rates Commonly Used:  In 1971 application rates in crops using
         parathion averaged 3.72 kg/ha; rates in cotton ranged from 0.84 to
         21.02 kg/ha (Carey et^ al_., 1978).

      4. Formulations Available:  Emulsifiable concentrates, dusts, granules,
         wettable powders.

C.    BEHAVIOR IN TREATED FIELDS

      1. Adsorption and Leaching Characteristics:  Parathion is strongly
         adsorbed to soil particles.  Fifteen years after parathion was
         applied to a light sandy soil, residues were not found below 20 cm in
         the soil profile (Voerman and Besemer, 1970).   A recent study on
         adsorption and desorption of several organophosphorus and carbamate
         insecticides determined the relative adsorption capacities (in order
                                     603

-------
         of most strongly adsorbed to most weakly adsorbed)  to be chlorpyri-
         fos > parathion > terbufos > phorate > aldicarb.   Sorption of the
         pesticides reached equilibrium between solution and soil within two
         hours after application and was positively correlated with organic
         matter content (Felsot and Dahm, 1979) .

      2.  Persistence and Vapor Losses:  Insecticidal activity persists for
         3 or more days on exposed plant surfaces (von Rumker et_ al.,  1974).
         When parathion was applied to a silt loam at the  rate of 5.6  kg/ha,
         95% of the residues had disappeared after two and one half months.
         The two major metabolites aminoparathion and p-nitrophenol persisted
         for 2 and 16 days, respectively, while the minor  metabolite,  para-
         oxan, hydrolyzed in 12 months (Lichtenstein and Schulz,  1964).   The
         recent discovery of nonextractable bound residues of parathion in
         soil (Katan et al., 1976) may bring about a redefinition of para-
         thion 's supposed "non-persistence".  Parathion is also more persis-
         tent when applied at high rates: after applications of 33.6 kg/ha
         for four consecutive years, residues were found in soil  for 16 years
         after treatment had ceased (Stewart et_ al., 1971).   Spencer (1976)
         has reviewed the limited data on parathion's vapor losses and has
         concluded that vaporization may be an important route of dissipation
         from treated fields.  Haque and Freed (1974) have used the best
         available information to form a vaporization index: according to
         their estimates, parathion may have vapor losses  amounting to 3.5 to
         6.5 kg/ha/year or more from a loam soil  at 25°C under an annual rain-
         fall of 150 cm.  Parathion residues have been detected in air
         samples taken over Florida (Stanley et^ al., 1971) and were found in
         samples of air taken from inside and outside farmers' and pesticide
         formulators' homes (Tessari and Spencer, 1971).

      3.  Runoff Losses:  In the Bradfield Marsh in Ontario,  where parathion
         may be applied as many as 19 times in a single season for the con-
         trol of onion maggot adult control, runoff water in ditches draining
         the black soils contained parathion residues in every sample  taken
         from April to October of 1972; maximum concentrations of 50 ppt or
         more were observed in April, early July and late  October (Harris and
         Miles, 1974).

D.    BEHAVIOR IN AQUATIC SYSTEMS

      1.  Persistence in Water:  Parathion does not hydrolyze as rapidly as
         other organophosphates but undergoes microbial degradation in both
         anaerobic and aerobic aquatic environments (Graetz et_ al., 1970).
         Yu and Sanborn (1975) estimated parathion's half-life in water to
         be 15 to 16 days.  When parathion was added to lake water and held
         in the dark, all but 0.2% of the original material had degraded in
         one year (Yasuno et al., 1965); however, when parathion was applied
         to ponds at 1.12 kg/ha, initial concentrations of 450 ppb declined
         to 3 ppb in two weeks (Mulla et_ al., 1966).  If hydrolysis is the
         major mode of degradation, the prolonged persistence of parathion
                                     604

-------
   residues will increase toxic hazards to aquatic flora and fauna; the
   hydrolysis half-life at 20°C and pH 7.4 is 108 days for parathion
   and 144 days for parathion?s more toxic metabolite paraoxon (Faust
   and Gomaa, 1972) .   Chemical hydrolysis in alkaline water produces
   diethylphosphorothioic acid and p-nitrophenol (Paris and Lewis,
   1973).   When exposed to UV light, parathion oxidizes to several
   oxidation and degradation products among which is paraoxon, a power-
   ful cholinesterase inhibitor (Frawley et al., 1958).

2.  Persistence in Submerged Sediment:  When parathion was applied to
   ponds  at 1.12 kg/ha and initial concentrations of 450 ppb in the
   water,  average concentrations in the hydrosoil were 30 ppb three
   weeks  after application; when .11 kg/ha were applied, residues were
   not found in the hydrosoil 4 days after the application took place
   (Mulla et_ &\_., 1966).   Sediments from a eutrophic alkaline (pH 7.2)
   lake degraded parathion by 28% to 39% in 54 days (averages at 0.74%
   of the material per day) whereas sediment from a oligotrophic acid
   (pH 4.7) lake degraded only 26% of the material in 92 days (averages
   at .28% of the material per day).  The primary degradation product
   was aminoparathion (Graetz et al., 1970).
                               605

-------


























•























CO
2
co
•^
<£
O
OS
o

u

E""*
^l
*3
cs


z
0

E-H
u

OH
2
hH
PJ










tn
p
rH
3
t/l
0)
OS










/ — \
C 6 %
O -H 3
•H C -P -P
4-> -H 03
oS X 0> !H
fH O fH 
p
w
0)
H

C/)
E
to
•H
c
rt

fH
O






to w
• H fH 4H  o C
XO'O'P W l/> 'H; +J (1)
tOT3OC 0) 0) (DCD-H 13
O D C rC oj >P 33 ^ fn o (-^
PWOOrCoJ t3 'O •H3-HP+-)
OCSOOSP -H -H rH4->XSC
XOOJP in w OrHCOO)
PHfHi-HOC O 0) JD3'HfHfH
OrH.p-H(D fn (H o3O lbOC OE4H
rH EPrtCD D >-l E-HCfn-H
l3CrCbO+->0)OP -P 13 0)13
C> O 4-> C n) OWfnO rt P 4-> O C-H rHbO rt
0) -HrHrt-PBOrH CW CW 0 X OJC
4-1 jQbOH.^ rH3 D"  1 1 P,
in in PH
X X
rt cS (N
T) -d
i-H
i*^ r^*
V J > J Q
P B
E E OH
PH PH rH PH
PH PH 0
O
rH rH O rH
PJ
U ^
D C
Q H 0) bO
OS 3 ^
^ 03 rH
S w ,Q tn
I I f^ v_ J ^
OS 13 3
OH -H W CT
O C -H PH HrH -HIDTJ rtOj
&,  XT3XECC
2fnfH PO)E30<1)
OOO OCCJ-HrHrH
U-HrH niCUrHCbObO
UJrCrC COXOSS
QUU 
-------









































t — x
13
CD
3
PS
•H
•P
PS
o
u
^- -J

CO
35
CO
HH
•2^
^*
§
o

^J
1— 1
f— i
^^
£D
^
z
o
H
U
^
0.
rH
W





in
4->
rH
3
in
CD
OS












t — ^
CD CD
PS 6 rH
O -H 3
•H PS P P
P -H Oj
oj x o> H
rH O rH 
to
CD
H

m
6

•H
o3
bO
rH
O






in in in
LO 0) (U (U
rO 333
CD LO T3 13 13
P 13 -H -H -H
o cu in in in
CD 4-1 CD  PS w ps -
+j 4J 0 - CD - CD
S S OX OX 0
0 0 PS PS PS '
rH rH OCN O'* O'
bO bO O\D O CT> Or
X
oj
•U

t^^
f — s
rH rH
X CD
P
^- 14^
csi nj /— \

"uT 'in" X
e e x x oj

ft ft 13 T3 ^
co o r^ r^^ to
o o ^~> ^ ^~>
rH i— 1
B B i
O O ft ft 1
+-) p ft ft 1
1
i — t rH rH rH 1



r — \ t~~^
CD CD
P -P
Oj oj
rH -H
rH rH
 in
CD PS -O PS
4-> O PS O
f~H 'H Cd "H
3 -P -P
in o in oj oo oo
CD 3 ft rH O O CJl
M 13 O 3 LO LO S
CD rH PH U U J
W rH O O OJ PJ H
B X ft
O 4-1 U
o o in
rH •> Oj
/) ,Q 
> oj X ft
t Oj O ft Oj
a- 0 CD oj -H
H rC 43 Q Q
in r-^
PS ^ PH
o u o
•H O 00 /-^
4-* V^ \Q ^T ,
oj • 0
O LO - OO
•H rH rH r-
rH 45
ft -
ft rH O rH
03 X LO 4S
1
CD OO OO Tt
r* ^* ^J1 ^O
w ft
in ft, rP Pi O
CD p*i . o . o
O to ft ft ft
o
3 «H 0
in o vo oo LO
* • •
to o o o






 1 1
Oj 1 CD
bO-H > W
rH X -H PS PS
Oj O rH O Oj

PS C bO CD CD
CD -H pS ^H O
CD -H -H O oj
rH rH rH rH 13 P
bO O rH 13 Cd Oj
1 l(H .H rH rH X "3 PS
CD ^4 -H O CD PS -H
3 CD IS /*~i rH bO rH
rHrHTJ W "3 OJ OJ
4343P31313 inftl S O
^— ' -H oj PS PS C
in oJOCO ojoj oj oj
oj PS bo ft OS CD -H -H -H
PSOPS^ Pj OPS PS PS
CDft-HOS S oj^S 4S 4S
OJin4-»OrH 5 -PPi ft ft
43CDOJ-POJ c/3 tnoj oj oj
oJrnOin^-i z 3O Q Q
PS O rH
< U U







00
c
3 u
u












f 	 N
u
0

•
LO
rH

n
rH


00
"fr

o
ft
ft

l^v.
to
•
0







t/1
3
•P
oj
rH
S
rH
CD
in

in
3
rH
OJ
ft
CD
O
0
e
•H
CO




O
rH
C
0
•H
3 -P
T oj
rH
JJ
£5
3
O
o
Oj
o
•rt

O
PS








/"•"-I
(/)
X
oj


t--

rO
ft
ft,


LO
•
o





















rj
•H
_g
ft
OJ
Q


607

-------


































T?
3
S3
•H
4-*
e
o
u
w
(—1
§
C3
BS
0

u
1— 1
E-

|""1
cx


^
o

H
U
^
OH
I— 1
w



t/)
•P
r-H
3
to
(D
OH










/• — ^
O CD
c e rn
O -H 3
•H f3 -P -P
4-> •!-( rt
rt X CD rH
fn O rH CD
•P 4-> 3 P-
C WB
CD M-l O CD
0 O ft -P
CH rS
O CD T3
U ^ C
rt









13
(U

i/i
CD
£— 1

to
e

• H
(3
rt
M
rH
O






r— 1
rH
C
O
•rH
4->
rt
^
4J
C
CD
O
C
O
o

£3
£3
g~
•H
^
rt
e








^
i~|

CM
[^
^-^
e
ft
CM



X
tn
3
X
en CD
w ^n
E-i -H
^ 43
OH 3
CO H
UH
H
OH
PJ W
^> (1)
^y Ij
1— t d)
rt
U 43
I-H O
|T^ o
H M
W rH
oa o


CD
rt
FH X
CD 4->
i— 1 -H
O rH
•P rt
•p

rH O
3 e
o
O 4->
3
(/) O
B 43
^H -P
0 -H
s a













































(N
              CM
  O    O    O
  LO    LO    LO
u     u     u
_J     _-]     J
                           o
                           LO
                          u
  u
 o
   ft
   ft
 u
o
         f-t


         oo
 43
  ft
  ft
                u
              o
43
 ft
 ft

LO


t-O
                          (N
                   ft
                   ft

                  00
                              o
                              LO
                            u
                             o
                             LO
                           u
                           _J
               o
               LO
             u
               o
               LO
              u
               o
               LO
             u
               o     o
               LO     LO
             u     <_>
                    u
                   o
                    LO

                    LO
       u
      o
       LO

       LO
                                   00
       u
      o
       LO

       LO
       u
      o
       LO

       LO
                                  43     X



                                  CTl     CM
                                                              o
                                                               LO
                                                               LO
                                                        00
              u
             o
              LO

              LO
                                                                    o
                                                                     LO
                                                                             LO
                                  43     43



                                  CJl     CM
 ft
 ft


O


00
43
 ft
 ft
                                           LO
43
 ft
 ft

CM
43
 ft
 ft

oo

oo
                                                             43
                                                              ft
                                                              ft

                                                             LO

                                                             to
43
 ft
 ft

LO
                                                                             43
                                                                              ft
                                                                              ft
                                                                             oo
                                                                             CM
&
•H
43
!/)
M
CD
4->
rt
^5
43
to
0

t4_j

• •










1
t/)
•H
c
CD

rt
•H
T3
rt
^1

t/)
CD
4J
CD
c
O
g
0)
rt
i— i
rt
DH

t/)
rt
•H
rt


X
i — t
*4H
0)
(3
O
4.)
(/)


• •
rt
+->
O
CD
t/1
c





rt
•H
13
rt
43

rt
i-H
i-H
o
o
^_t
rt
e
o

CD
4J
OH

                                                         rt
                                                         
                                                         O
                                                         1— I
                                                         3
                                                         43
                                                         rt
                                                         t/1

                                                         rt
                                                         •H
                                                         rt
                                                         rt
                                                         i— i
                                                         u
                                                                      rt
                                                                      O

                                                                      to
                                                                      X
                                                                      o

                                                                      rt

                                                                      §

                                                                      CD
                                                                      4->
                                                                      OH
              608

-------

























, — (
13
CD
3
PS
•H
PS
o
CJ
v~_^/

CO
s
co
I-H
^
<£
CJ
04
O

U
I — i
H

ID
O'
^

2
O

H
U
^
0,
S
i— i





























































to
1 1
r-H
3
1/5
0
04


t — \
 4-»
4-> -H 03
03 !*? 0 fH
M O ?H CD
4-> 4-> 3 P.
PS to S
0 4n O 0
U 0 PH 4-J
f-« rS
O CD 13
U ^ PS
03















T3
0

to
0
H

to
6

•H
C
rt
W)
£_i
O






i— 1 i-H
O O
LO LO
U U
*— 3 i-4


/ 	 N / 	 \
CJ U
O O
LO LO
• •
LO LO
r- 1 .-H

* f\
?H ?H
l-C f-C*

00 vO
^j" Ql
v. — i \ — /

x- ^
PH PH

^J-
i— H
i— 1 LO




1

IO
13 03
03 U
•H -H
03 C
PS f-i
O

t— 1 -H
4-4 i — (
0 03
PS U
O
4-> to
to X
CJ
f-l
•• 03
C
03 O
<4-* ?H
CJ CD
0 4->

PS
1— 1

LO
i-H
F
nJ
^— «


/ 	 \
U
o
00
•
CM
!-H

r,
^
03
•U

LO
^ — '

rP
ft


vO
to
































LO LO
rH i-H
B E
_J nJ
f— 1 f-H


LJ CJ
O 0
00 00
* •
CN CN
rH r- i

*\ *\
^ ^
rt rt
*T3 "^

O LO
t^> ^-^
v — /
rQ
rd P^
& ^
to
CN CTl
. .
CN O











03
O
•H
4H
•H
O
03
Pn

08
•H
fH
3
0
C
0
h
o
<


LO
i-H
3 £
J
f— H

G"
o
00

CN
r- H

r,
^
cti
'O

O
bO
*- — '

t-Q
&H
&H
"vf
^
•
O































             o
            U
                   U
                          0
                          4->
                          03
                          i—i
                          3
                          O

                          o
                          •H
                          X
                          o
                          C
                         •H
                         13
3O    OO
-H    i-H
   O     O
   LO     LO
 U     U
 ,-J     _4
                                                   00
   O
   LO
                                                     U
 o
 LO
                   CM      1
                   &,
                   to'
 U
o
 •st-
 LO
  I
 r-H
 LO
                                    fn
                                    X
                                    Xi
                                    PH
                                    PH

                                    r-^
                                           LO
                                            I
                                           LO
        \D
        CTl
         PH

        to
o
 o
 LO
  1
 00
 VD
 CTl
  PH

 to
00
•=t
                                                                 PH
                                                                 PH
1
0
o3
>
fn
03
i — i

0

•H
3
0"
to
o
S

• •







CD
T^
• H
4->
(^
0
to
3
C
o3

to
PS
03
M

4->
03
M-H

X
0
i-H
3
O
•H
f-)
r-H
03

to
0
i-H
0

P.
O
^
13
•H

4J
O

V 	 /

to
0
4->
03
JH
X
0
4->
fn
0
>
PS




1

to
0
• H
t-H
<4H
to
• H
13
13
03
CJ










03
O
•H

to
•H
T3
C
03
fH
bO

0
X
CJ
X
to
p.
O
4->
O
!H
<
h
0

•H
!-H
03
O

0
X
CJ
X
to
p.
O
fH
13
X



i

to
0
•rH
i-H
<4H
X
03
B

. .













to
•H
*"O
C
03

bo

03
r-H
i-H
0
^
0
E
0
X
PH
W






4->
3
o

4-i

^
0

PS
•H
35 rt
oo 04
I-H
609

-------








































t — s
T3
0
3
C
• H
C
o
u
V 	 /
to
I-H
1
0

u
I-H
H

3
o-


z
o

E-
u

s
I-H
W















































































to
4_>
i— 1
to
0
OS










, — .,
0 0
C E fc
O.c^ 1
*n ,-J
• H C -P 4->
4-> -H rt
rt X 0 ^H
^H O !H 0
-P -P 3 P-
C to E
0 4H O 0
0 O PH 4->
O 0 T3
U ^ C
rt










0
I/)
0
E-

to
E
to
•H
C
rt
bo
£_|
o






o

C C 0 C
•H O -H 4-> rt
C i-H 4H 0
to O rt I-H
C -"X U
O 0 O O
•H to BO
•P rt i-H 4-> CM
o M rt I-H CM to
Ot 3 0 E T3 r-H O CM O> Ot
,— 1 T3 4-> ?H tO 0 CM O Oi-H i— 1
E 0 t/i O i— i fn BI-HLO E E
i-J ^ 0 G 0 ^ i-J u U i-J nJ
H C>0 E-Ji-JE-H
•P -H 4H 0 4H
C i-H O i-H t/)
rt O C
O X X 0 rt
•H U t-t 10 ?H
4H 0 rt 4->
•H C > f-i fn
C -H O 0 X 0
bo rt O +-> to 4->
• H fH 0 t/5 -H rt
tO ^3 fH 0 4H S




fn f-i h f-i M
iX <~* H r- r^

/— ^ vO
M O^ O\ 'sf O1 O\
r^ V— ^ v— ^ ^-* x_/ ^^

^o E B E E B
O) PH PH PH PH PH
^ E PH PH PH PH PH
PH
E o . f*^
PH *
PH i-H CM h-
O 1 i— 1 "Sf LO
t^ O ^ O I-H O
• • • • • •
CM O i-H O O O






r^ .*"*
i/) tn
< — > S -H -H
13 O 4H 4H
0 C C C
3 C 3 3
C -H tO t/>
•H E
4-> X X i-H i-H
C t/) W *d rH •— 1 tO
O -H -H rt -H -H 0
Cj 4n 4n 0 bo W) -H
v — ' T3 T3 X PH 0 0 PH
rH i-H 4-> J-l 3 3 PH
XOO rtrti-Hi-n3
couu PuucQoao
UH

i rt -H
O -P
X O C
PH -P O

^^ 'O 4-*
•-H R O
rt 3

•H 
C -H -H
O X o\° ^1
•H PnO O
4-> O CM O
O fn -P
3 0 •- rt

0000
5n X -P rt

o\p - cj
O to O 13
\O 0 U O
1 4-> 3 0
O X 0 i-H
LO O i-H ,Q
C
o
•H
4->

4->
C
0
0
C
0
0
1— 1
rt / — \
r^3 tO
•P X
0 rt
^H r^
fj^
3 CM
to ^^








to

0
C
•H
r*
to

C
0
'O
i-H
O
o














LO
CM
X
•H
i-H
rt
4->

O
B
0\°
o
LO






i — \
fn


vD

V 	 ^
B
PH
PH

at
i— i
•
o









X

•H
4H

O
4->
•H
3
cr
to
0
2




vO
CN
O
4->

0
3
T3
•H to
to 0
0 3
fH I/)
T3 -H
0 4-*
4J
« c
fH -H

C E
0 PH
0 PH
O LO
O i-H







e — \
fH
X

^j-
V 	 /
E
PH
PH

CM
0

o









X

• H
4H

O
•P
•H
3
cr
(/)
o
2


610

-------














































f — ^
•v

3
C
•P
pi
0
u
CO
rH
^
CD
c*
o

o
E-1
^
•ID
O^
^

»2«
o

H
U

ex,
S
i— i

























































































to
p
i— i
3
to
0
Di










,— j
o> a;
C B h
O -H 3
•H C P -P
+J -H rt
rt X 0 ?H
rH O rH 0
P -P 3 PL
C to 6
0) 4-1 O 0)
0 O PL, P
Ck>
r^i
O 0 13
U ^ Pi
rt











13
0
P
(O
0
H
to
6
to
•H
C
rt
00
f-i
O










vO
O i-H
•P ••
LO
A M
to to
• H
4-1 II

C (H
• H 0
•P
(D rt
3 3

•H c
tO -H

rH  to
rt  O
C -P
0 -H
3 3

to
X O
c/5 2
rH
UH







[ —
(N
to
ID

C
O
PL,
to
0
JH

i-H
rt

o
• H
rt

0)

Pi
o
•H
•P
rt
f_|
4_i
c
(U
o
p]
o
o

i-H
rt
f*
•p
(U
i-H
r\
3
to




















t*l
to
•H












00
CM
C
•H


4-1
O
C
C 0
0 -H
•H +->
+-> rt
rt ^
n3 0
rt 


to
to
0
i-H

0
3
to
to
•H
^j

r"J
to
•H
4-1

Pi
•H









































































^
0
0
3




















































































CO
£7
HH
CQ
rH
K

2?
<^


i-H
to
o
LO
CJ








(^->
u
o
LO
•
LO
i-H

*,
^
r*

^f
CN
v — f
e
PL,
PL,
i-H
O

to
fH 't/T
o 0
rC ^-1
U 0
PL,
pj ro
in rt
0 -P
4_) N 	 /
to
0
^E






















































00
• LO
/ — \ t — \ Ol
tO \O rH
Ol Ol
rH i-H .rl
rt
to 0 to
• !H PL, rt
<~^ O O 3
^f P! U rt

Ol O T3
rH U C T3
^ rt pi
^O rt
C C to
rH rt rH rt
O Q) 'O
rQ rX TJ -H
C 0 Pi -P
rt o rt rt
co cj co 2

\D 1^ 00 Ol

LO i — \ i — <
01 0 01
^n r^1^ ^D
v^-^ CTi O^
rH t-H
r^l ^ ^
rt| +j
. P i-H
*-> rt rt /-N
0| rH O
cu -p r-
4H 0 Ol
4H T3 i-H
o PJ x '-'
C rt rH
rt 00
tO 0 OO rH
O rH 0 O
O O rH O
J U U 2











•
/ 	 N
LO
01
rH
V_^

rH

+->
to
0
•H
!H
0,

O
rH



.
^ — \
to
Ol
i-H
v — f
P!
rt
g
rH
O
0
OH
rH CM tO ^T LO
611

-------
t — \
0)
c
•H
o
V 	 /
CO
1— 1
Z
^
L3
C*
0
u
1— 1
f— 1
^
1 — i
ex
^

§

£— i
u
a.
i— i
.
U4




• / 	 N
r-~, O
oo r^ • , — ,
^O O^ f~~^ vD
O^ rH OO \O
I-H < — ' \O C7l
V 	 / Q^ ,_)
i-H > — '
C C ^
0 O C
W 1/1 0 r-\ M O 3
fn O1 LH cj rt /->
CD \O 0 CJ3 OO
PH CD P-l "^ V«O
I-H c *d o>
C C nS ^^
rt t/i cC t/)
?H ?H f^ •
•H CD -H 0) CU O
a- c w> c e DC
Z CO Z CO 1-3 S
i-H CM tO 'H; LO ^D
i— 1 i-H i — 1 i — 1 i-H i-H
                                       CN1
                                       vO
          CM
          \o
LO

at
C^l

CT>
                    LO  CTl

                    •-H  O)
                    i-H   (30
                                  VO
                                  i— 1   T3
                                            CT1
 rtl   cu|  CTI   



 h

 Pu


 0)

 0)
 w
•H
 0)
                                                       rt

                                                       OT
                                                            rt
o

CTl
                                                                (D
                    612

-------


































s
H- 1
0
j
<
HH
OS
H
CO
OJ

a:
PJ

2
O

H
a.
H- 1
•P
i— 1
3

 ^H O
O - -
W <4H W
X X
rt 13 rt
13 CD 13 - =
0
LO 4H tO
^—s *> _ j *~^>

B BE
PH PH PH
PH PH PH

LO O O
r~ oo o
CN tO CN
1 1 1
o o o
LO LO 00
CN tO .-H






i-H
•H
rt

cr
(/) 4-> 0
13 C +J
fn rt -H
rt i/) X!
t— i rt 12
Q rt x: O
a; 2 ex ca
n
03

O
LO
U


/ — \

^



~



^



~


\ — /

E
PH
PH


O
LO
1
O
^J-







,-H
•H
rt
3
cr
X
• H
PJ
fH CO
3 iJ
u s

J
0
LO
D


t-H
rt
f-i
O






to
X
i-H
•H
rt
0
i — i
CN XI
O rt
LO -P
Q
,_j

rH
rt
E

0
13




PH 0
0 ,*
o rt
O -P
rt C
• H
£S
3
6
•H
X
rt
g
0
rt
•P
•H
X
•H
rt
13

0
i-H
O
rt
•P
PH
0
O
u
rt
4
adverse
i
o
C

*"O
0
•p
(/)
0
bO
bO
3
w
i
O
CN
O

i-H
0
^
0
i-H

•P
O
0
4H
4H
0

i-H

C
O
• H
P
PH

^
t/1
t/)
rt
adverse effec
i
o
c

13
0
P
tf)
0
bO
bO
3

i
O

CM
2C

E
O

4-t

i-H
0
£>
0
i — 1
CN

C
o
•H
•4_J
PH
6
3

i/)
rt
          bO



         tO
bO
E
                     X>

                      bo
                      bO
LO
O
O
               X
               rt
               -a

               bO
 bO


to

o
o
                                     bO
                                     O
                                     to
                                                  bO
         (/)
         •p
         rt
                      rt
613

-------































T3
 a;
• j *...
•*-* r*
^ o
o
p 
ft\ fl\
^y vu
?H ^3
•rH
C 0
 c
rt -H
x:
t/J
 3 •
0 ^ r->
U O rH
G X vD
a! p a>
f^ W j
^H O
3 ,£ «
•P P 3
to O a)
•H C X
T3 ai CO
bj(
CJ ^H 13
•HOC
^ at
•(-> O
rt P C
•H O
t-H rrt r^
r*-H W r*-l
O CD V)
S. m LJ
r*" «J PH
WOO)
p p u
<<* \_J
rS ^^
.. 0)
H i/i
0 ^ rH
4-> rH Rj
•H 13 <1>
X> 0 X
•H -4-*
X at o
C 0 rH
•H P
0) O
W fH P
rC
CJ  v£)
rH 1^
s— J O^
rH
. . v_/
• 1 ,
rH 1 ^— > •
Oil 00 -H r-^
. t~~ N t^-
4-> o^ N r-~
01 rH OS CTl
*— ' f-l rH
X O ^
+J 0) +J
OJ r< 4J CO
0) aJ 0) •<
K * > Z
rH (Nl tO Tj-
614

-------
                                 SECTION 16

                                   PHORATE


A.     NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

       1.     Product Names:  Thimet, Timet

       2.     Vapor Pressure at 20°C:  8.4 x 10   mm Hg (Sanborn et^ al_., 1977).

       3.     Solubility in Water at 26°C:  19 ppm (Freed, 1976).

B.     USE

       1.     Type:  Systemic and contact insecticide and acaricide.

       2.     Primary Crops Used on:  Corn (the use of phorate accounted for
              18.1% of the 32.0 million pounds of insecticides used in corn
              in 1976); cotton, sorghum, other grains, peanuts, alfalfa,
              soybeans, Irish potatoes (Andrilenas, 1974; Eichers, et al.,
              1978) .

       3.     Rates Commonly Used:  In 1971 application rates in crops using
              phorate averaged at 1.91 kg/ha; rates in field corn ranged
              from 0.19 to 16.81 kg/ha (Carey et^ al_. , 1978).

       4.     Formulation Available:  Emulsifiable concentrates, granules.

C.     BEHAVIOR IN TREATED FIELDS

       1.     Adsorption and Leaching Characteristics:  Phorate is strongly
              adsorbed to soil particles.  Studies in 17.8 cm soil columns
              have indicated that phorate is only slightly mobile within soil
              (Harris, 1969).   A recent study on adsorption and desorption of
              several organophosphorus and carbamate insecticides determined
              the relative adsorption capacities (in order of most strongly
              adsorbed to most weakly adsorbed) to be chlorpyrifos > parathion
              > terbufos > phorate > aldicarb.  Sorption of the pesticides
              reached equilibrium between solution and soil within two hours
              after application and was positively correlated with organic
              matter content (Felsot and Dahm, 1979).

       2.     Persistence and Vapor Losses:  One hour after application to
                                     615

-------
              the soil,  more than 50% of the phorate had been converted to
              the insecticidal  phorate sulfoxide;  phorate sulfoxide is then
              converted  to phorate sulfone (Ahmed  and Casida, 1958) which
              persists for up to one year (Harris  et_ al., 1972) .   Fifty per-
              cent of the phorate applied to sandy soil and peaty loam de-
              graded within 68  days and 35 days, respectively (Way and Scopes,
              1968; Suett, 1971); in a Coachella fine sand, residues persis-
              ted for more than 2 months but disappeared less than 6 months
              after application (Mulla, 1964; Mulla et_ al_., 1961).  Burns
              (1971) observed a rapid disappearance of phorate from a sandy
              soil (41%  loss in first 3 days after application)  and largely
              attributed it to  volatilization losses; Spencer (1976) reviewed
              the limited data  on phorate's vapor  pressure and concluded that
              there is a strong potential for high volatility in field con-
              ditions.

D.     BEHAVIOR IN AQUATIC SYSTEMS

       1.     Persistence in Water:  When the rate of degradation by chemical
              hydrolysis was tested in a buffer solution (20:80)  having a
              pH of 6.9, the half-life of phorate  was 450 hours (~ 19 days)
              (Faust and Gomaa, 1972) .
                                      616

-------
CD















































CO
s
CO
HH
p?>|
^
CJ
OS
0

o
rH
H

r"">
ex
^

z
0

H
CJ
^
DH
S
hH
PJ




















































































to
P
rH
3
I/}
CD
OS










CD CD
C 6 rH
O -H 3
• H C P P
P -H OS
OS X 0 rH
rH O rH CD
P P 3 Pi
c we
0 
0
H

(/)
e
t/i
•H
r^
oS
M
rH
0






CN +J
-O 1 OS
0 -H 1 fH
P P I/) O
•H o o .c
rO 0 X PH

rH rC PH O
0 fi -H C ITl
P -H OS 0
o3 0 bo T3
rH 0 C rH -H
O rH -H O O
X O rH -H
PH S O X P
rH r^ (J
r^ r-^ r"] 0 ^ — ^
0 CJ O C W T3
tsi 3 O OS C 0
•1-4 E C rC -H P
rH OS P V)
O rC bO t/) 0
,d P rH W 3 P
OS S O 0 rH
P O T3 O P
0 rH X-H rC O
6 boja u PH C

e
P,
PH

1
O 1
O 1
o
rH





CO
OJ
u
Q
O
OS
OH

^-(
OH
^ OS
»^! ^ PH
rH O O
OS T3 P
OH -H ^
O C
O C OS
Z 0 rH
< rH PH
X O
co pj p
OS X
U4 OS X
CO rH PH
O rH
OH 0 0
S fH C
O O -H
U rH rH
PJ rC OS
Q U 2

to
0\°
to
•
LO
f^

<+H
0

c
o
•H
p
• H
o
•rH
f-^
C
•H

0
P
O
0
(/)
C
•H

0
C
• H
rH
O
rH
r^
O
0
c
OS
M
rH
0


4-1
O

P
3
O

LO

X
i — i
C
o

• *\
^3
0
P
{/)
0
P
bOCN
oS
rH
0
>
OS
/^ — ^

Tj-
^ — '

rQ
P,
PH

o
O
O
rH










C
O
p
**/
c
cti
i — (
PH
0
P

rC


0
C
•H
rH
3
OS
P

0

rH

^
O
















































(/}
0
*t3
• H
O















































1
•H
P
U
0
c/)
C
•H

  rC
                                             oj  U
                                            rH
                                            X

                                            oo
                                            r
                                             PH
                                             PH

                                            00
 i   *d
 o  0
 C  P
 oS  
 bo 0
 rH  P
 O

c^  'Q rd
rH  C  0
    3 P
 rH  O  W
 O  PH 0
<4H  6 P
    O
  OU P
  LO    O
U  tf>  C
P4  3
    fH  0
 0  O P
 bO rC  oS
 OS  PH rH
 rH  W  O
 0  O X
 >  -C  PH
 03  CH^^
 rH


00
r
 PH
 PH
617

-------






















/~*\
-o
o
3
•H
•P
C
0
u
1
*2T
^C
tD
oi
P
rj-
rH
£"•*
«^
^3
o*

z
o

C-4
fj

02

 ^ C
rt












13

^—4

V)
g
W
• H
C
nj
J-*
O








LO LO LO \D r^ oo
OOQ O O O
LO LO LO LO LO. LO
U U U U U Q




C? G" u" /-x
O O O rH
rH i-H rH /-^\ /— \ ^Cj
CN (N (N JH fn
rC J[^ ^~
*\ », »* f\J
fH JH rH 00 -^ ^^
IX X r& ^t CM
\«^ v^-« bO
«?!• 00 VO r^
CM ^ en s e ^^
V— ' V_-/ v^-^ Q^ Q_j tuQ
PH PH g

PH PH PH LO LO
PH PH PH LO G)
O
*3- rt O O O
CM rH •
CTl O rH
V




1

CO 13
tu o w
f— « PJ *H
< -H rH X
ce X P w
en PH  -IH x
W g 3 4-i w
H c3 o c -H
oi cs 3 in
PJ •• rH 0)
> w C
IS C ") rH -H CO bO
rH C7J 3 rH 3 Z O
CD rH -H CT < rH
U O rt bfl 0) i-i MH
t— 1 CTi g 1) rH P3 rH
eP g 3 rH rH rH
w nj X rH nj a: 3
3 u to oa x cu oa
OJ rH ^H S
pa c_> tu 
13 -H PH CTl
• H • O / — x \O
if} / — s /•— -x C_J C7^ • CT»
C8 CM tO VO /— ^ rH
CJ ^O ^O ^O O^ CO x — '
CTl CTl f*1 rH \O
13 rH rH CO X — / (J^ f_.
f^ x — / x — / f—4 Q)
Oj I/I (/) ( — ' P
t/) rH rH rH t/1
13 0) 0) 0) 0) 
-------





































in
2
C/}
1— H
U
e:
o

nJ
<
1— (
ofi
E-
CO
w
0£
DH
W
H

§
H
U
<
0.
h- 1
P-,
tn
4->
, — 1
3
W
(U
on










f — ^
C V
0 B
•H C -H
p -H P
rt X
f-i O <1)
-p p f-l
C 3
(D 4-i en
0 O 0
§ &
U 0)
^ — '












*O
 o > o
i-t 13 f-t T3 !-(
•H nS M-i rt 4-i
rt i i
13 O t-H i-l O r-H CM
£H 0 f-* 0
CD > C > C
rH *^  0) i-H -H (U ft .H
rt ^ p P P p
PCS t/lPPn t/l-PpL,
p> , p cu o B 0 o B
COC bO(I>3 bOQ>3
O-H bOMnw b04-it/)
O 3 4-1 to 3 4-1 tfl
rt w 
i— i
w
z
to



.
f — \
OO
t^
1— (
\ — /

0)
F-l
ni
CM
/ 	 s
rt
o
f-
i—i
V — J
1— 1
rt

0)

jf]
rH
               619

-------
                                 SECTION 17

                                  TERBUFOS


A.     NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

       1.      Product Names:   Counter

                                  o            -4
       2.      Vapor Pressure at 25 C:  2.6 x 10   mm Hg (Martin and Worthing,
              1977).

       3.      Solubility in Water at Room Temperature:   10 to 15 ppm (Martin
              and Worthing, 1977).

B.     USE

       1.      Type:  Insecticide particularly effective against soil insects.

       2.      Primary Crops Used on:  Corn (Eichers et_ a_K,  1978).

       3.      Formulations Available:  Granules.

C.     BEHAVIOR IN TREATED FIELDS

       1.      Adsorption and Leaching Characteristics:   A recent study on the
              adsorption and desorption of several organophosphorus and car-
              bamate insecticides determined the  relative adsorption capaci-
              ties (in order of most strongly adsorbed to most weakly adsorbed)
              to be chlorpyrifos > parathion > terbufos > phorate > aldicarb.
              Sorption of the pesticides reached  equilibrium between solution
              and soil within two hours after application and was positively
              correlated with organic matter content (Felsot and Dahm, 1979) .
              Given the results of this study, leaching would not be expected
              to move terbufos more than 20 cm through the soil.

       2.      Persistence:  When terbufos was added to soil, the original
              material oxidized rapidly to its sulfoxide and had a half-life
              of only 4 to 5 days.   The sulfoxide reached maximum concen-
              trations 2 weeks after the experiment began and in turn oxidized
              to terbufos sulfone.  Since the metabolites demonstrate insecti-
              cidal toxicity equal to that of terbufos, the researchers sug-
              gested a half-life of 6 weeks for terbufos and its metabolites
              in soil (LaVeglia and Dahm, 1977).
                                     620

-------
D.     BEHAVIOR IN AQUATIC SYSTEMS

       1.     Persistence:  No information was available on the degradation
              of terbufos in water and submerged sediments (see FONOFOS for
              general information on the persistence of organophosphates in
              aquatic systems).
                                     621

-------


















































C/3
w
h-H
^£
C3
Pi
o

u
h—i
f-H
<]^
J~^
ex


^
o

^— t
QJ
^
p ,
s
rH
UJ











to

rH
3
to
0
OS










0 CD
C S !H
O T-i 3
•H £ -P -P
P -H Cd
Cd X CD rH
in O rH 0
p -P 3 P
C to S

O O PH P
C X
O 0 T3
U *-> fi
cd









*O
0
P
to
0
H

10
6
to
•H
C
cd

rH
0

















































to
OS
w
u
Q
O
oi
0,
OS
«^
Jg
rH
OS
OH

Q
^
«3^

to
OS
UJ
to
o
OH
»s
Q
u

Q



rH
id
0
-P
•H
r*i
•H
43
C
•H

0
rH
O
3

43
O

£~

f-|
^_>
3
O
rH
bo






i
i
i
















G
O
P
*^
c;
cd
rH
PH
O
p
X

PH

0
r^
•H
rH

^




I
•H
•P
O
0
to
C
•H

0>

•H
rH
O
rH
f]
O
0
c
cd

£_j
o

X
43


















































1
to
O
43

O
(3
cd
bO
rH
O

X


C
cd
tj~^
4.)

to
0
13
•H
O














































to
o
tp,
3
pd
?H
0
^_)
^_/

t/1
0
td
•H
O
•H
P
0
0 ^
10 13
c CD
•H .p
to
to 0
3 -P
rH
O 4->
43 O
PH C















































(Nl
o\°

• 1
LO C
t^- -H

IHH 0
O G
•H
G rH
0 0
• H rH
P 43
•H O
o O
•H G
43 cd
C W)
•H rH
o
0
bOCM
Cd rH
^
0 rH
> O
cd m
/ 	 v
f-H
43

^t"
^— /

pO
PH
PH

0
o
o
rH








O
p
_^
c
cd
rH
PH
O
4_>
X to
43 0
Pn-H
+->
0 -H
G C
•H 3
rH §
3 S
cd o
P 0
to
tu


4-1
0

LO

X
i-H
C
o

• »l
*^
0
•p
to
0
4J

to
0
13
•H
o
•H
p
o
0
to















































1
•H
P G
U 'H
0
to to
C G
•H O
•H
tO 4->
3 0
rH 3
O T3
43 O
PH rH
to
O Td
43  43 > 43 -P
Cd 0 Cd PH*— '

/•"""* *"~^
U U
O O
vD **O
LO LO
t-H r— 1

•\ »\
rH rH
43 43

00 00
43 43
PH PH
PH PH

OO t~-

'c
0
•P
to C
C cd
Cd rH
rH PH
0 O
0 0
O N

cd
rH X
O 0
• • "Es
c
to cd cd
OS 0 -H
UJ 0 (3
S cd 43
to to cd
Z 3 Q
0 rH
U U




























VO
CTi
rH
v — >
0
PH
0
u

*"O
(3
cd
0
13
C
cd
to
LO
f-~-
cn
i — i
* i

+->
M
(U
pQ
t-H
JH
3
X

•rH

(Nl tO
\O vO
CTi CTi
rH rH
^ ^
t/1 rH
0 0
rH rH
0 P
1-^ £3
D 03
rH (Nl
622

-------
          C
          o
          •H  C
          •P -H
          rt  X
          Vi  O
          P P

          (D 
-------
                                 SECTION 18

                                  TOXAPHENE


A.     NOMENCLATURE, CHEMICAL AND PHYSICAL PROPERTIES

       1.     Product Names:   Camphechlor, Alltox, Phenacide, Phenatox,
              Strobane-T, Toxakil.

       2.     Vapor Pressure  at 25 C:   0.2 to 0.4 mm Hg (Finlayson and Mac-
              Carthy, 1973).

       3.     Solubility in Water at Room Temperature:   3 ppm (Martin and
              Worthing, 1977).

B.     USE:

       1.     Type:  Non-systemic contact and stomach insecticide with some
              acaricidal action.

       2.     Primary Crops Used on:  Cotton (the use of toxaphene accounted
              for 41% of the  64.1 million pounds of insecticides used in
              cotton in 1974);  soybeans (the use accounted for 27.9% of 7.9
              million pounds  of insecticides used in soybeans in 1976);
              sorghum (use accounted for 21.7% of 4.6 million pounds of insec-
              ticides used in sorghum in 1976);  peanuts (use accounted for
              16.7% of 2.4 million pounds of insecticides used in peanuts in
              1976); wheat (Andrilenas, 1974; Eichers et_ aj_., 1978).

       3.     Rates Commonly  Used:  In 1971 application rates in crops using
              toxaphene averaged 7.84 kg/ha; rates in cotton ranged from
              0.10 to 40.35 kg/ha (Carey et_ a^., 1978).

       4.     Formulations Available:   Emulsifiable concentrates, wettable
              powders, dust,  granular.

C.     BEHAVIOR IN TREATED FIELDS

       1.     Adsorption and  Leaching Characteristics:   Toxaphene is very
              strongly adsorbed to soil particles.  Ten years after applica-
              tion, 95% of the residues remaining in a Houston black clay were
              found in the top 30 cm of the soil profile (Swoboda et al.,1971).
              When 100 kg/ha were applied to study "sterilant concentrations",
                                     624

-------
       toxaphene residues leached through approximately 300 cm of
       soil and entered and contaminated groundwater for the entire
       year of observation (LaFleur et al.,  1973).

2.      Persistence and Vapor Losses:   Vaporization  plays a very major
       role in the disappearance of toxaphene from  soil surfaces and
       treated foliage.  Studies on cotton grown in the San Joaquin
       Valley have shown that the residues remaining on leaves 50 days
       after treatment (135 ppm) "showed a regular  trend toward great-
       er loss of components of higher volatility when compared with
       the 0-day sample (661 ppm) (Seiber et al., 1979).  Nash et al.
       (1977) found that twenty-four percent of the applied toxaphene
       volatilized from soil and cotton plant surfaces in a model
       ecosystem.  The authors suggested that volatilization losses in
       the field might be larger because cotton plants are more widely
       spaced and thus allow more of the volatilization losses from the
       soil to escape to the atmosphere.  Swoboda et_ al_ (1971) observed
       the rapid disappearance of toxaphene from a  heavy clay soil and
       attributed it to large volatilization losses encouraged by
       daily soil temperatures of 60°C.  Haque and  Freed (1974) used
       available information to quantify annual vaporization losses of
       pesticides from soil and estimated that 7-14 kg/ha of toxaphene
       would vaporize from a loam soil at 25 C.  Toxaphene has been
       detected in air samples taken over the Southern U.S. (Stanley
       et_ al_., 1971; Arthur, 1976)  and Bermuda (Bidleman and Olney,
       1975); atmospheric residue levels over the southern states were
       as high as 2500 ng/m3 while mean residue levels in Bermuda were
       0.63 ng/m3.  Residue levels of 280, 170, 44, 86 and 220 ppt in
       five out of eight rainwater samples collected in Maryland indi-
       cate that some of the air-borne toxaphene is redeposited on the
       earth's surface (Munson, 1976).  Toxaphene residues which
       escape volatilization will persist for prolonged periods in the
       soil; Nash and Harris (1973)  studied the persistence of toxa-
       phene in a Congaree sandy loam and found 49% of the material
       remaining 16 years after application.

3.      Runoff Losses:  When eight different plots of cotton grown on
       loamy sand and sandy loam soils (slopes of 2% and 4%, respec-
       tively) were treated with 26.9 kg/ha of toxaphene, 0.078 to
       0.72% of the pesticide was transported away  from the field
       during the 3 to 6 months following treatment; approximately
       75% of the toxaphene leaving the field in runoff was associated
       with the sediment phase with the remainder of the residues being
       transported in the dissolved phase (Bradley  et_ al., 1972).
       While these losses appear to be small when seen as a percentage
       of the material applied, they take on greater significance when
       it is observed that 0.078 to 0.72 percent of the 26.9 kg/ha
       applied results in losses of 21 to 200 gm/ha of toxaphene.
       Given large tracts of cotton acreage, these  losses could result
       in serious contamination problems in surface waters located in
                              625

-------
              cotton growing areas.  Bradley et_ aJ_. (1972) did find that
              significant concentrations of toxaphene appeared in a 0.2
              hectare pond located in the experimental watershed.  Concen-
              trations increased from levels of less than 1 ppb before the
              cotton was treated to 65 ppb at midseason and equaled or
              exceeded the ninety-six hour median tolerance for bluegill on
              all but one occasion during the growing season.  The authors
              attributed this toxaphene pollution to runoff but did not study
              possible residue inputs from drift losses and contaminated rain-
              fall.

D.     BEHAVIOR IN AQUATIC SYSTEMS

       1.     Persistence in Water:  The task of determining toxaphene's
              persistence in aquatic systems is difficult because of the
              insecticide's chemical complexity [although the technical
              material has been shown to contain nearly 200 polychlorinated
              camphenes, its chemical composition remains largely undeter-
              mined - Holmstead et_ al., 1974) and reversible sorption to
              aquatic flora and fauna (Pollack and Kilgore, 1978).  High
              evaporation rates (MacKay and Wolkoff, 1973) and sorption onto
              suspended sediments (Hughes and Lee, 1968; Veith and Lee, 1971;
              Terriere et_ atl_., 1966; Stringer and McMynn, 1958) have both
              been identified as mechanisms for the removal of toxaphene
              from solution.  Concentrations of toxaphene in a shallow
              eutrophic lake declined by 99% one year after application,
              whereas concentrations in a deep oligotrophic lake were still
              toxic to fish 5 years later (Terriere et_ al_., 1966).  Initial
              treatment concentrations of 50 ppb declined to 1 ppb one month
              after application in a shallow New Mexico Lake; however, con-
              centrations did not further decline for the next 9 months
              (Kallman et_ al_., 1962) .

       2.     Persistence in Submerged Sediment:  When a shallow New Mexico
              Lake was treated at 50 ppb, concentrations of toxaphene in
              the lake sediment reached levels of 150 ppb (Kallman et al.,
              1962).   When eight Wisconsin lakes were treated at 100 ppb,
              residue concentrations in submerged sediments ranged from 0.2
              to 1 ppm for 3 to 9 years after treatment (Johnson et al., 1966).
              Williams and Bidleman (1978) studied the degradation of toxa-
              phene in an anaerobic salt marsh and found that residues were
              quickly degraded in sterile and non-sterile sediment to com-
              pounds having gas chromatograph retention times shorter than
              those of standard toxaphene components.  Lee £t_ a.l_. (1977)
              found "weathered" toxaphene components to be less toxic to
              bluegills and concluded that some of the more toxic components
              had indeed degraded.

       3.     Persistence in Aquatic Vegetation:  When a shallow New Mexico
              Lake was treated at 50 ppb, concentrations in aquatic plants
                                     626

-------
peaked at 18 ppm one week  after application and remained above
2 ppm for 3 years  (Kallman et^ al_.,  1962).
                        627

-------







































CO
S
co
Z
<;
u
a;
o

u
hH
H
<
3
cy
<

z
o

H
U
<
CL,
S
rH


W













































































i/i
P
1— 1
3
in
CD
Pi









CD CD
C 6 JH
O -H 3
• H C p p
P TH. cd
Cd X CD rH
rH O rH ID
P P 3 P-
c we
CD 4-1 O CD
0 0 PH P
C X
O CD 13
U *— ' C
cd







13
ID
P
(/)
CD
H

w
6
w
•H
C
cd
bo
f-i
O









\£5 O
* -H
"* 6 l/> 43
*-* C C PH rH
X -H -H PH CD T3
43 tO 43 C
i/> T3 t/) to S cd
13 CN CD pi CD t^ 3
ID T) 33 3 LO LO LO c Pi
O CD T3OT34-I UOO O
3 P CNJ -iH 4-1 -HO -H -H -H r-l .H
13 O13W W LOXXXrHP
CD CDCDCDI/) CDl/> OOOOCDCd
M 4-IPrHi-H f-|rH -HpPPOrH
4-1 -H CD CD XCCC-H
X cd43T3> 13> OOOOCg
P -HCDCD DID PCCC-H-H
•H 0\° P 45 P r- 1 P rH U)
>'-|Op!cd cd XXXXcw
•HCTl C'H ^Hl/1 !-lO rHrHrHr-H OCd
^^ 4^ "" ^••J 4^ *~^ r^ t~ H i~\ »i-~\
O X4SCX C LO cdcdcdcdPC
3 PPCD^CDfHO-HHf-i^OO
13 S IS OCMCD OCD-H P CD 0 CD 343W
O O O COP CP X fH C C Cl3^W
t-( SH fn ocncd ocd o cd CD CD CD cDcdcd
PH bfl bO O\O3 US P PH txO bo bfi ^nO6
? i. i
H MH HM
45 PH PH B
PH
"* --1 S
v_^ 0 ^

43 0 rH 1 rH
PH 1
PH T3 TJ 1
Pi P! I
o ctfcd e 66666T3
0 PHPHPHPHPnPHPi
OrH PHPHPHPnPHPHCd
rH O
OrH CM CNCNCNCNCNrH

o o o o
CO
OS
PJ

Q (U
0 S
rv* »
tX H
(X O
Pi "P
>" C O -H cd
Q~ 0 P cd pi 13
«< P ^ tn a> 3
2 r* C O 45 w cd
i-< c ctfcu3cd o
oi cd i-i -H -H 3 p .H
CXrH PHbQrHCTCd fH
PnCDCD O3 -HbO "d
QO cdcd p ^6rHCD,cd
ZP bObo x CD343-r-(cd3
cdw
Oi rHfH M-Hp.3 PJ3
WCDCDCD (DpWEcd 6
COC pP +J WOWrHCdl/)
O-H cdcd cd X^CDrH-HtD
CX^H 3S S GT3T3CD4513
23 X45CD Xi OCCD5-HOCD
Ocd WWCd 10 r-l-HpiONpl
OP CDCDbO CD O rH CD i— 1 +J CD
OJW rHfHrH f^ -HXOrC'HO
QCD 4-l4-tcd 4-1 2UCOUZCO

628

-------






































f — ^
ro
(1)
3
C
•rH
P
c
o
N — '
co
S
co
h- 1
Z
cS
oi
o

C_}
h- 1
H

^3
ex
^

z
o

H
U
^
OH
S
1— 1
UJ










































































w
•P
rH
3

CD
oi










0> U
C S ?H
0 -H 3
•H C P 4->
p -H rt
rt X 
P P 3 P.
C i/) 6
 6
0) -H 0
f-l i-t
PH ^

t~| r^
P +J
S S
0 0
fH fH
(X) bo


6 S
PH PH
PH PH

LO
rH rH
• •
0 0














£
o
-p
^^
c
rt
rH
PH
0
P -H
£*•> r-(
X (I)

,J_J
« 3

• H
rH (/)
rt -H
6  c z
 o o
 S U











o
U
•H
X
o
•p
0)
O O i-H
U
U
UJ



o
T3
0)
^j
• H
o
•H
<•*
C
•H
u"
o
6 vo
PH
PH LO
rH

rH "
. £_(
O X

00
^»
v — '

,0
PH
PH

LO
rH



C
rt

rH t/) *O
O -H O W

•H fn
(U
/ 	 v / 	 > , 	 > O
o

PH "rt
W rH X
O 0)
.... ,-H
rt PH PH "3
o tn tn w p.
rt c
rH •• •• rt rt
P rt rt  N rt X
6  PH
o -H P tn rt
•P P O 3 Q
C O rH rH
UJ OS OH U

1 U
U
UJ













/ — ^
U
O
vD
.
LO
rH

A
^
f^

oo
^~
^— ^

o
PH
PH

CTi
rH






t/1
3

rt
rH
g

0)
01

t/)
3
rH
rt

P.
CD
O
O
S
•H
CO



•)
o
p

*&
a)
p
rt
£H
•P X
C W
0} -H
O <4-l
C
o o
U P





1
1
1
1
1































rt
•H
f5
X
PH
rt
Q



                             o

                             I/I  -p

                             §§
                             •H  X
                             p  p
                             rt  -H
0) P
O rt

O 0)
o
  o
                                rH  X
                             6 T3  rt
                             •H i—I  -P
                             X  3  h
                             rt  o  o
                             e  o  B
                             CM
                             PH
                             PH
                           w 3
                           0) P
                          +J
                           0) X
                           rt 0
                          JS «+-)
                           O -H
                           O J3
                           bO 3
              O
              LO
             U
                                                 O
                                                 LO
                                          U
                                         o
             PH
             PH


             O
             00
                  U
                 o
oo

V	'


JO


PH


O
629

-------
















































t — \
13
3
C
•H
C
0
CJ
co

to
I-H
u
OS
O

U

£— i
^*
J^
C/


py
o

H
^
5s
rH
W









t/)
-P
r— 1
3
w
0)
OS















/ 	 S
cj a>
c s M
O -H 3
• H C .p P
•P -H rt
tf X 0 rH
f-H O rH 0
•P -P 3 P
C w S
0 
C X
O (D *O
CJ ^^ CH
ctf











"8
p

0)
H

w

w
•H
C
rt
bO

0





0
f-l rH W
O rt 0
S M T3
C rH -H
T3 3 0 0
C U-l !-H -H
03 P p
tN rH C W
rH 4J Cj O 0
o x -H o p,
LO bO rH
U -H 0 C 0
i-J 0 O CTJ rH
S XXi bO +J
6 4-> C 0
W -H 0
in O  tn  H O

C •!— ^ 0 4-*
•H X> <4H W T3
rt 3 C X rt
bO i/l >H OX!
•V
0
C
P.
rt
X
o
p
t — \
U
O H
rH Q
(N| Q

" (4H
M O
X C
Xi 0
VO 0 -rl
CTI ni x:
*— ' 0 P
a
x> e H
Pl Pn 0}
P, P, P,
\D rH
Cxi

^ — ^
I?
P
C
o
u
V 	 i
TJ
o w
Pi-H
•H M
-C P
p, w
c 3
03 O
rt
•• rH
W
C W
oj 3 w
0 rH rH
On! 0
rt S .p
w S x
3 U 0
u

     o
     LO
   o
   LO
 u
 ,-J
   o
   LO
 u
                     o
                     LO
   o
   LO
 u
   o
   LO
 a
O
LO
         O
         LO
        u
        iJ
   o
   LO
                                                        u
  o
   LO
   LO
 u
o
 LO
   •

 LO
           rH

          rC


          OO
 u
o
 LO

 LO
                    u
                   o
                    LO

                    LO
                        f-l
 u
o
 LO

 LO
                              oo
 u
o
 LO
   •
 LO
 u
o
 LO

 LO
 p.
 Pl

(N

CTi
 I

 I/I

 
                 •a
                 P.
                        PI
          LO
  Pl
  p,

 CM

 to
 Xi
  p,
  Pl

 to
               nJ
               in
               o
              rH
               3

              •8
               rt
              •H

               0

               w
               rt
                                  Xi
                                   Pi
                                   Pi
                                           00
                                   rt
                                   o
                                  •H
                                   C
                            rt
                            o
                            rt

                            I
                            d)
                            •p
                            Cu
     u
    o
     LO

     LO
                                         x;

                                         00
                                  Xi

                                   &
 u
o
 LO

 LO
              Xi
               &
              to
              (N
    630

-------



































3
C
•H
•P
c
0
u
v — '

in
S
c/}
i— i
jz
^
C.D
OS
o
u
rH
H

N^
O^
^

z
o

H
u
<
OH
S
1 — 1
m







t/i
•p
rH
3
i/)

£_|
0
^
c
n

O X
•rH
42 O
O LO
rH rH
4-»
3 0
0 4->
S T3
O 0
rH 4->
rH Gj fn
Oi rH 0
42 -P -P
t/) C 03
C 0
•H C (2
O -H
... o
6 rH
P, 0 0
PH r^H r*
rt 0
LO rH rH













































                                  LO
                                    t/)
                                    0
                                    3
D     h-     00
H     rH     rH
   O     O     O
   LO     LO     LO
 U     U     U
 J     rJ     rJ
                                        0
                                        3
                                    X -H
                                    O -P
                                   T3
                                    0)
                                   •P
                                    CIS
                                    C
                                    0)  o>
                                    U  CM
                                    C  oo
                                    O  00
                                    O  rH
                                            CTl

O
CM
(2
• H

l/>
t/>
0
(2
^
03
0
12

-0
0



C
0
bO
03
rH
rH
O
0

o
-p

0
3
0
rH
o
0
T3

•P
42
bO
•H
rH
trt

T3

cd

PiTJ i—\
O
rH
0
>
0
TJ

X
rH

rH rH
6
nJ nJ
0 H H
+J
cd
rH

42
+->
3
O
rH
50

C











CTi
rH
6 I

H













        PL,
        PH

       o
       LO
                     U
                    O
42     42

00     00





 Q.     O .
 p j     Pi


00     '*

CM
                            VD
                       PH
                       P,
                                              rH
                                              C71
43
 PH
 PH
        o
        !H
        O
       •H
        rt
       OS
                                   •P


                                   g
                             o
                             43

                             •H
                             rt
                                O
                                rH
                               00
Pu
43
 PH
 P,

O
LO
O
                                                                      CTi
                                                                      43
                                                                       PL.
                                                                00
                                                                              rH
                                                                             X
                                                                             CTl
                                                                                   01
43    43
 PL.    P,
 PH    PH

CM    tO
+J     -P
3     3
O     O
rH     rH
       O
       o
       rH
       QQ
                                                                       i
                                                                      r— I
                                                                       rt
                  O

                  o
                 u
                                                               42
                                                               O
                                                               rH
                                                               
                                                               PH


                                                               O
                                                                             42
                                                                             t/l
                                                                             •H
                                                                             4-1


                                                                             t/)

                                                                             rH
                                                                             cS
                                                                             (U
                                                                             OS
                 631

-------
           O
           •H  R
           4J -H
           cd  x
           fH  O
                   0
                  4-i  oi
                      fH
                  0  0
                  fH  P.
           R     3  fc
           0 4n  w  0
           O  O  O  4-J
           R     PH
           O     X  13
           LJ     0  R
                  1—> oj
13
 0
 3
 R
 O
U
LO
2
erf
o
u
i—i
H

cx
o
H
u
Oj
UJ
                     13
                      0

                      (/)
                      
                                    J
                                    H
                                           nJ
                                           H
                                    43
                                     PH
                                                  Ol
                                                   PH
13
 0

 R
•H
4-1

 O
U
                             [i,
 t/1
 c/1
 oS
pa
 o
 0
 bO
                                            03
                                            O
               03
               X
               U
H
J
1
0
PH
X
0
e
o
u
0


o
4_J

<~^
If]
•H
4-1

13
0
to
^
03
O
stimuli
r— 1
03
R

0

X
0

o


CD

•H
1 i
• H
C/}
R
0
to
render,,,,

X
i — i
o
•H
to
to
o
PH

13
r— (
3
O


t/i
•H
(~^
4_>
v — '
1
]
X
bO
3
03
U

X
1 — 1
•H
(/)
03
0

0

O
6

<~|
t/)
•H
4-1
O
LO -H
OI (/I
i—{

r\
4-> Ol
fH i-l
0 e
43 i-J
r-H H

3


U)
f_|
0
4-1
cd
13
0

PH
tn
0
pj
^
03
0
^

13
0
PH
0

0
>
0
13

X

4H
collagen

o
4-1

0
3

v 	 1

0
R
O
n
y
O
03
43

0
r~]
4->
decrease
4-J
X
bO
•H
i— 1
tO

13
R
03

/)>^
O
R
0
•H
O
•H
4H
0
13








0
4_>
03
£_|

(^
4-J
U
O
^_l
bO

R
•H
                                                                                                       Ol     to"
                                                                                                       i-t     CN
                                                                                                                                    oo
                                                                                                                            CN
                                                                                                                         s      e
                                                                                                                                       O
                                                                                                                                       LO
                                                                                                                                      u
                                                          o
                                                          03
                                                          fH

                                                          R
                                                          0
                                                          U

                                                          O
                                                          0
                                                         43
                                                          3
                                                                               Oi
                                                                                PH
                                                                                PH
                                                                                       PH
                                                                                       PH

                                                                                       O
                                                                                       LO
                                                                                       O






^^
^
01
*— '
J-,
PH
PH

U
o

•
(NJ
r-H
-
^
CNI
x — '
43
PH
PH

U
O
to
*
00
I — 1
-
^
CN
v — /
43
PH
PH

, — ,
U
o
00
•
to
CM
£
^t
CM

43
PH
PH


f — *
U
o
T^
CM
X
00
**

43
PH
PH
                                                                                                                       00
                                                                                                                               \0
 O
 R
 R
•H
 e

13
 03
 0
                      O
                      CJ
o
R
                                                                                       03
                                                                                       0
        03
       UH
                                                                                                          PH
                                                                                                          H
                                                                                                          OJ
                                                                                                         U
                                                                                                                 10
                                                                                                                •H
                                                                                                                <4-l


                                                                                                                 I/)
                                                                                                                 W)
                                                                                                                 0

                                                                                                                i-H
                                                                                                                CQ
                                                                 632

-------













































f — *«
f£)
0
3
C
•H
4->
0
u
IS
CO
hH
1
P-
O

CJ
H

£D
O^
^

z
o

E~"*
u

ex

w
VD










C/J
4->
i— 1
3
1/5
co












r— ^
0)
C CD JH
0 63
•H C -H 4->
4J -H 4-> TO
03 i"! (H
fn O CD CD
4J 4-> fn p
C 36
CD tH W CD
0 O O 4-J
C OH
O X 13
u 
6

•H
pj
CQ
tx
fn
O






CM
bO
C
3
O


^o
TJ- 0
C3% CM C7i IT) 4->
i— 1 O i— 1 CM ^H
6 to 6 6 0
J (_) nJ >J 43
H J H H rt

^_)
3
^

3
M
i— 1
O
CD
f-l

/ — v <-S / — v / — , 4->
M ^H F-H fn
45 45 45 45 CD
J>
vO ^ OO \O O
G^ CM ^± CTi 43
> — ' ^_/ v_^ v-^ rt X
4_)
43 43 43 43 V) 'H
PH P, PH PH C 0
PH PH PH PH O -H
•H X
00 CM LO O 4-> O
i— 1 CM CTJ 4->
F~- ^H
4J
C
CD
U
C
0
O








r"|
t/>
T3 <+-i n5 45
CO C CD (/)
3 3 45 -H
C W rH 14-|
• H i— 1
4-> i— I 3 O
fn F"H 43 l/l 4-*
O -H CD -H
U M ^ -H 3
* — ' CO O PH CJ"
3 rt PH w
OC r-H ^H 30
co ca OQ cj s
HH
PH




1--
CM
(/)
CO
o
Pi
ctf
^0
f_l
3
+J
w
•H
•^

03
o
• H
J>
rt
co
43


t/1
C
o
• H
4~>
rt
?H
+J
C
co
o
C
o
0

i-H
rt
f^
+J
 — '
0
3=
633

-------
               LO
               Ol
 CD

 §
 O
u
         Q
         cn
               O   O)
               W5   rH
 CD
13
 §
 X
 o
CQ
                          to

                          Ol
                          CD
                         T3
CD
O

I
                      O

                      Oi
                                     t/1
                                     Clj
             LO   v£>   r-~
             CM   CM   CM
              OO   O)
              CS|   CM
to
&.
o

0
rH
H

O"
g
tu
         tO
LO   1--

Ol
                     rt
     rH   IT)
         ^   CD)


          CD    CD
               CQ


             CM   tO
      cS
      O

     1
                               LO
                               Oi
                 CD

                 o
                          
                           CD         rH    O
                           >    CD    O    t/I

                           rH    O    T3    W)
                                                                                OO
                                                            CTl    Pn    • i
                                                            rH    O   rH
                                                                           (D-O
                                                                                                      0)
                                                                                                           O
                                                                                                           l~~
                                                                                                           Ol
                                                                                                           <
                                                                                                           o
                                                                                                  t~~
                                                                                                  O)
                                                                                  ^
                                                                                  CD
                                                                                                                 co
                                                                                                 vD
                                                                                                 Ol
                                                                                                 Ol
                                                                                                 vO
                                                                                                 Ol
                                                                                                                           vO
d
o3

*^
CD
O
rt
S
i
H
Ctf

CD
r— 1
rH

CD
2
o
CM
CD

J_|
CD
C
rH
rt

rH
CM
I
i — I
CD

O
• H
+->

CM
CM
4->


^
CD
O
rt
2
to
CM
                                                                 634

-------




























CO
S
CO
rH
0
OS
o
_J
•<
1— H
OS
H
co
w
OS
OS
to
H

2
0

H
U
^
CU
S



LL,
t/1
4_>
rH
3
I/)
0
OS






C 0
0 B
• H C -H

rt 'x
rH O 0
IJ 4^J t^
0 M-i in
o o o
C P.
o >s
C_) 0









0
4J
0
H

to
B
to
• H
e
rt
bO
rH
O









rH
O
LO
U




13
0 t/1
0 X
4n rt
13
0 tO
to X^-N
fn n T-<
rH 0
4J T3 0
0 4-1
to S
x o c
rt rH rt
13 rH 0
O rH
LO 4-1 O
i — '

ft
to
LO











t/1

c
•H
rH
rV,
U
3
T3

13
JH
rt
rH
CO rH
Q rt

CO
                                                             •<*
S)     rH     CN
   000
   LO     LO     LO
 u     u     u
 •J     J     I-J
 o
 LO
 LO
  1
 o
 o
 LO
        ft
        ft
to
00
 ft
 ft

o
LO
vD
 I
o
o
 t/1
 4->

 g
 t/1
 rt
 0
 o
•H

 o

1—I
•H
 rt

 cr

 0
        o
        CQ
              • H
               rt
 X
• H
 c

 3
 4->
 o
u









T 1
O
LO
Q
,j

rH
rt
rH
O





























|2
FQ

bo
*^
"•^_
bO
B

0 <
^f



































to
o
LO
o
,J

rH
rt
B
rH
0
13



























S


bO
^
^-^
bo
B

0
O
vD




























^-
0
\^
rt
+-*
C
•H

X
rH
•H
rt
*"O

0
(-H
pO
rt

ft
0
o
o
rt




















X
rt
13
•^-s^
b£
r^
•^s^
bO
B

LO
(N
i— 1
O
0
•
o



















t/1
c
4J
u
0
(4H
t4_j
0

0

rH
0
> 1
13
rt O
1 CM
O I rH
P]
S C
13 O O
0 rH -H

W ft
0 rH B
bfl 0 3
bo > i/i
3 0 i/)
I/) rH rt

























rH
^•^
bO
3.




LO
f^
•
oo





















±J
0
0

M-4
0

0

rH
0
> 1
13
rt O
1 CN
o ac CN

B C
13 0 0
0 rH -H
4-> 4-1 4->
W ft
0 rH B
bO 0 3
bO > t/i
3 0 t/>
t/) rH rt

























rH
•*^
t>0
P-




^J*
*sf
•
0





















1 0 N
O C N
•H 0 rt
ja JS rH
ft 0
<4H rt 4->
OX4->
O 0 •
01 4-> > W
0 >— ' 4->
rH •- O
bO rH 13 0
0304-1
13 O 3 4n
U C 0
rC 0 -H
bO 4-> O
•H 4-» C -H
x; o o c
C 0 0
0 t/i bO
,C tO -H O
4-> 0 13 C
O -H
t/1 13 to O
rH -H rH
rt t/i rt
B 0 0 o
•H 13 rH
C -H 3 0
rt O 10 rH
•H O JO
4-1 4-> ft-H
O 0 X to
001/1
to to o
0 C C ft
3 -H 0
to 0 s o
•H C
4-> -H 13 0
rH 0 10
4-> O 4-» 3
rt rH rt rt
4-i X C O
0 -H 0
0 O B ja
J2 C -H
+_> rt rH T3
bO 0 0
C rH OS
•H O X <
rH D-,
T3 rH 13 OS
0 0 -H
rH XI ft C
O 4J rt 0
4-> O rH 0
to ja
JS 0
tO 4-> fH tO
•H -H O CO
S B X
0
C C O 0
0 0 to C
X 0 rH 0
ft to rt x!
rt ft
X C 0 rt
O O rH X
4-> -H rt O
4_) [—1
JS rt to
bO rH 0
333-

x: 3 -H LO
4-) CJ tfl t-~
rH O 0 O^
< rt fH rH
4->
0
O
u
                     rt
                     OS
 0


o
                  635

-------
 0)
 3

•H
•M

 O
en
oi
o
Di
H
cn
OS
PJ
H


O
            (D
           rX
            O
     Ctf I   OO  i—•,
T3     .   f-  r--
 C   +J   en  r-
d.
            •P   4J    
-------
                                 REFERENCES

Ahmed, M. K. and J. E. Casida.  1958.  Metabolism of Some Organophosphorus
       Insecticides by Microorganisms.  J. Econ. Entomol. 51:59.

Albaster, J. S.  1969.  Survival of Fish in 164 Herbicides, Insecticides,
       Fungicides, Wetting Agents and Miscellaneous Substances.  Internat.
       Pest Control 11(2):29-35.

Aldridge, E. F., G. L. Blume, J. C. O'Kelley and T. R. Deason.  1976.  Degra-
       dation of Malathion by Planktonic Algae  (in Butler 1977).

Alt, K. F. and E. 0. Heady.  1977.  Economics and the Environment: Impacts of
       Erosion Restraints on Crop Production in the Iowa River Basin.  Center
       for Agricultural and Rural Development, Report No. 75, Iowa State
       University, Ames, Iowa.

Anderson, C. A. et_ al_.  1974.  Guthion (azinphosmethyl:Organophosphorus Insec-
       ticide). "Residue Reviews 51:123-180.

Andrilenas, P. A.  1974.  Farmers' Use of Pesticides in 1971 - Quantitites.
       U. S. Department of Agriculture, Agricultural Economic Report No. 252.
       Washington, D. C.

Apperson, C. S., R. Elston and W. Castle.  1976.  Biological Effects and Per-
       sistence of Methyl Parathion in Clear Lake, California.  Environmental
       Entomology 5(6) :1116-1120.

Archer, T. E.  1971.  Malathion  [0-0-dimethyl S-l,2-di(ethoxy-carbamyl)-ethyl
       phosphorodithioate] Residues on Ladino Clover Seed Screenings Exposed
       to Ultraviolet Irradiation.  Bull. Environ. Contam. Toxicol. 6:142-143.

Arthur, R. D., J. D. Cain and B. F. Barrentine.  1976.  Atmosphere Levels of
       Pesticides in the Mississippi Delta.  Bulletin of Environmental Con-
       tamination and Toxicology 15(2):129-134.

Baker, J. L. and H. P. Johnson.  1979.  The Effect of Tillage Systems on
       Pesticides in Runoff From Small Watersheds.  Transactions of the
       American Society of Agricultural Engineers 22(3):554-559.

Beliles, £t_ al_. 1966.  Report on Aldicarb, EPA Pesticide Petition No. 9F0798,
       Section C, Book III (reported in the U.S. Environmental Protection
       Agency, 1975).

Bender, M. E.  1969.  The Toxicity of the Hydrolysis and Breakdown Products


                                      637

-------
      of Malathion to the Fathead Minnow.   Water Res.  3:571-582.

Bender, M. E. and P.  Eisele.   1971.   Long Term Effects of Pesticides on
      Stream Invertebrates.   National Tech. Inf. Serv. PB-206,  692.

Benke, G. M. and S. D. Murphy.   1974.  Anticholinesterase Action of Methyl
      Parathion, Parathion and Azinphosmethyl on Mice  and Fish.   Bull.  Env.
      Contain. Toxicol. 12:117-122.

Bidleman, T. F. and C. E. Olney.   1975.  Long Range Transport of Toxaphene
      Insecticide in the Atmosphere  of the Western North Atlantic.   Nature
      257:475-477.

Bohn, W. R.  1964.  The Disappearance of Dimethoate From Soil.   J.  Econ.
      Entomol. 57:798-799.

Boyd, C. E.  1964.  Insecticides  Cause Mosquito Fish to Abort.   Progr.  Fish-
      Cult. 26:138.

Bradley, J. R., T. J. Sheets  and  M.  D. Jackson.  1972.  DDT and Toxaphene
      Movement in Surface Water From Cotton Plots.  Journal of Environmental
      Quality 1(1) :102-105.

Bro-Rasmussen, F., E. Noeddegaard and K. Voldum-Clausen.  1968.   Degradation
      of Diazinon in Soil.  J.  Sci.  Food Agric. 19:278-282.

Bro-Rasmussen, F., K. Orboek, K.  Voldum-Clausen and E. Noeddegaard.   1969.
      Residues of Five Organophosphate Insecticides in Carrots,  Rutabagas,
      Cabbage, Cauliflower,  and Onions.  Tidsskr. Planteaul. 73:382-393.
       (Chem. Abstr. 72:77562d,  1970).

Brown, A. W. A.  1978.  Ecology of Pesticides.  Wiley-Interscience,  New York,
      525 pp.

Brown, W. L.  1961.  Mass Insect  Control Programs, Psyche 68:75-109.

Burdick, G. E., H. J. Dean,  E.  J. Harris, J. Skea, C.  Frisa and C.  Sweeny.
      1968.  Methoxychlor as  a Blackfly Larvicide, Persistence of its
      Residues in Fish and its Effect on Stream Arthropods.  N.  Y.  Fish. Game
      Journal 15:121-142.

Burns, R. G.  1971.  Loss of Phosdrin and Phorate Insecticides from a Range
      of Soil Types.  Bull.  Environ. Contam. Toxicol.  6:316-321.

Butler, P. A.  1963.  Commercial  Fisheries Investigations.  In:  Pesticide-
      Wildlife Studies: A Review of Fish and Wildlife Service Investigations
      During 1961 and 1962.   Fish Wildl. Serv. Circ. 167:11-25.

Butler, P. A.  1969.  The Sub-lethal Effects of Pesticide Pollution.  In:
      The Biological Impact of Pesticides in the Environment.  Environmental
                                     638

-------
      Health Series 1.  Oregon State University, pp. 87-89.

Butler, G. L., T. R. Deason, and J. C. O'Kelley.  1975a.  The Effect of
      Atrazine, 2,4-D, Methoxychlor, Carbaryl and Diazinon on the Growth of
      Planktonic Algae.  British Phycol. J. (in Butler, 1977).

Butler, G. L., T. R. Deason, and J. C. O'Kelley.  1975b.  The Effect of
      Endrin, Heptachlor, Aldrin, Dieldrin, Captan, Toxaphene and Malathion
      on the Growth of Planktonic Algae (in Butler 1977).

Butler, G. L., T. R. Deason and J. C. O'Kelley.  1975.  Loss of Five Pesti-
      cides from Cultures of Twenty-one Planktonic Algae.   Bull. Environ.
      Contain. Toxicol. 13:149.

Butler, G. W., D. E. Ferguson and C. R. Sadler.  1969.  Effects of Sublethal
      Parathion Exposure on the Blood of Golden Shiners.  J. Miss. Acad. Sci.
      15:33-36.

Cabejszek, I. and J. Stanislawska.  1965.   Effects of Methoxychlor (1,1,1-
      trichlor-2-,2-bis(p_-methoxyphenol) ethane) on Water Organisms.
      Roczniki Panstwowego Zakladu Hig. 16:261-268.  (Chem. Abstr. 63:12259b,
      1965) .

Carey, Ann E., Jeanne A. Gowen and G. Bruce Wiersraa.  1978.  Pesticide
      Application and Cropping Data from 37 States, 1971 - National Soils
      Monitoring Program.  Pesticide Monitoring Journal 12(3):137-148.

Carlson, A. R.  1972.  Effects of Long-term Exposure to Carbaryl (Sevin) on
      Survival, Growth and Reproduction of the Fathead Minnow (Pimephales
      promelas).   J. Fish Res. Board Can.  29:583.

Caro, J. H., H. P. Freeman, D. E. Glotfelty, N. C. Turner and W. M. Edwards.
      1973.  Dissipation of Soil-Incorporated Carbofuran in the Field.
      Journal of Agricultural Food Chemistry 21:1010-1015.

Caro, J. H., H. P. Freeman and B. C. Turner.  1974.  Persistence in Soil and
      Losses in Runoff of Soil-Incorporated Carbaryl in a Small Watershed.
      Journal Agriculture and Food Chemistry 22(5):860-863.

Carter, F. L., Jr.  1971.  In vivo Studies of Brain Acetylcholinesterase
      Inhibition by Organophosphate and Carbamate Insecticides in Fish.
      Diss. Abstr. Int. 32(5):2772-2773.

Carter, F. L., Jr. and J. B. Graves.  1973.  Measuring Effects of Insecti-
      cides on Aquatic Animals.   Louisana Agr. 16(2):14-15.

Castro, T. F. and T. Yoshida.  1971.  Degradation of Organochlorine Insecti-
      cides in Flooded Soils in the Phillipines.  J. Agr.  Food Chem. 19:
      1168-1170.
                                     639

-------
Christie, A.  E.   1969.   Effects of Insecticides on Algae.   Water Sewage
      Works 116:172.

Clarkson,        1968.   Summary with Respect to Guidelines PR 70-15 Project
      No, 113B32, EPA Pesticide Petition File (reported in U.S.  Environmental
      Protection Agency 1975).

Cole, D. R. and F. W. Platt.   1974.  Inhibition of Growth and Photosynthesis
      in Chlorella pyrenoidosa by a Polychlorinated Biphenyl and Seven
      Insecticides.  Environ.  Entomology 3:217.

Cook, S. F. and J. D. Connors.   1963.  The Short-term Side Effects of the
      Insecticidal Treatment of Clear Lake, California in 1962.   Ann. Entomol.
      Soc. Am. 56:819-824.

Cope, 0. B.  1965.  Sport Fishery Investigation.  In: The Effect of Pesti-
      cides on Fish and Wildlife.  U.S. Fish § Wildlife Serv. Circ. 226:51-64.

Cope, 0. B.  1966.   Contamination of the Freshwater Ecosystem by Pesticides.
      J. Appl. Ecol.  3 (Supplement on Pesticides in the Environment and
      their Effects on Wildlife):33-44.

Coppedge, J.  R., D. A.  Lindquist, D. L. Bull and H. W. Dorough.   1967.  Fate
      of Temik in Cotton Plants and Soil.  J. Agric. Food Chem.  15:902-910.

Crosby, D. G.  1976.   Photochemistry of Benchmark Pesticides.  In: A Liter-
      ature Survey of Benchmark Pesticides.  George Washington University
      Medical Center, Science Communication Division, Washington, D. C.
      pp. 166-184.

Crosby, D. G., E. Leitis and W. L. Winterlin.  1965.  Photodecomposition of
      Carbamate  Insecticides.   J. Agr. Food Chem. 13:204-207.

Eaton, J. G.   1970.  Chronic Malathion Toxicity to the Bluegill (Lepomis
      macrochirus).  Water Res. 4:673-684.

Edwards, C. A.   1977.  Nature and Origins of Pollution of Aquatic Systems by
      Pesticides.  In: Mohammed A. W. Kahn, ed. Pesticides in Aquatic
      Environments.  Plenum Press, New York, pp. 11-38.

Edwards, W. M. and B. L. Glass.  1971.  Methoxychlor and 2,4,5-T in Lysimeter
      Percolation and Runoff Water.  Bull. Environ. Contam. Toxicol. 6:81-84.

Eichelburger, J. W.  and J. J. Lichtenberg.  1971.  Persistence of Pesticide
      in River Water.  Envir. Sci. and Techn.  5:541-544.

Eichers, Theodore R., Paul A. Andrilenas and Thelma W. Anderson.   1978.
      Farmers' Use of Pesticides in  1976.  U.  S. Dept. of Agri., Agricultural
      Economic Report No. 418, Washington, D.  C.,58 pp.
                                     640

-------
Eisler, R.   1967.   Tissue Changes in Puffers Exposed to Methoxychlor and
      Methyl Parathion.  U.S. Bur. Sport Fish. Wildlife Tech. Paper 17:1.

Eisler, R.   1969.   Acute Toxicities of Insecticides to Marine Decapod Crusta-
      ceans.  Crustaceana 16:302.

Ellis, S. W. and K. H. Goulding.  1973.   The Effects of Pesticides on
      Chlorella. Br. Phycol. J.  8:208.

Epstein, E. and W. J. Grant.  1968.  Chlorinated Insecticides in Runoff Water
      as Affected by Crop Rotation.  Soil Sci. Soc. Am. Proc. 32:423-426.

Farmer, W.  J.   1976.  Leaching,  Diffusion and Sorption.  In: A Literature
      Survey of Benchmark Pesticides.   George Washington University Medical
      Center,  Science Communication Division, Washington, D. C. pp. 185-245.

Faust, Samuel  D. and Hassan M. Gomaa.   1972.  Chemical Hydrolysis of Some
      Organic  Phosphorus and Carbamate Pesticides in Aquatic Environments.
      Environmental Letters 3(3):171-201.

Felsot, Allan  and Paul A. Dahm.   1979.  Sorption of Organophosphorus and
      Carbamate Insecticides by Soil.   Journal of Agricultural and Food
      Chemistry 27(3):557-563.

Finlayson,  D.  G. and H. R. MacCarthy.   1973.  Pesticide Residues in Plants.
      In: C. A. Edwards, ed., Environmental Pollution by Pesticides, Plenum
      Press, London, pp. 57-86.

Frawley, J. P., J. W. Cook, J. R. Blake and 0. G. Fitzhugh.   1958.  Effect  of
      Light on Chemical and Biological Properties of Parathion.  Journal of
      Agricultural and Food Chemistry 6:28.

Fredeen, F. J. H., J. G. Saha and M. H.  Balba.  1975.  Residues of Methoxy-
      chlor and Other Chlorinated Hydrocarbons in Water, Sand, and Selected
      Fauna Following Injections of Methoxychlor Black Fly Larvicide into
      the Saskatchewan River, 1972.  Pestic. Monit. J. 8:241-246.

Freed, V. H.  1976.  Solubility, Hydrolysis Dissociation Constants and Other
      Constants.  In: A Literature Survey of Benchmark Pesticides.  George
      Washington University Medical Center, Science Communication Division,
      Washington,  D. C. pp. 1-18.

Fuhremann,  T.  W. and E. P. Lichtenstein.  1978.  Release of Soil-Bound Methyl
      [!4c] Parathion Residues and Their Uptake by Earthworms and Oat Plants.
      Journal  of Agricultural and Food Chemistry 26(3):605-610.

FWPCA.  1968.   Water Quality Criteria.  Report of the National Tech. Adm.
      Comm. to Seer, of the Interior.   Fed. Water Pollution Contr. Adm.
      U.S.D.I.,234  pp.
                                     641

-------
Gaufin, A. R.,  L. D.  Jensen, A.  V.  Nebeker, T.  Nelson, and R.  W.  Teel.  1965.
      The Toxicity of Ten Organic Insecticides  to Various Aquatic Inverte-
      brates.  Water Sewage Works 12:276-279 (In: U.S. Environmental Protec-
      tion Agency, 1975).

Georghiou, G. P.   1972.  Studies on Resistance  to Carbamate and Organophos-
      phorus Insecticides in Anopheles  albimanus.  Amer. J. Trop. Med. Hyg.
      21:797.

Gershon, S. and F. W. Shaw.  1961.   Psychiatric Sequelae of Chronic Exposure
      to Organophosphorus Insecticides.  Lancet 1-2:1371-1374.

Getzin, L. W.  1967.   Metabolism of Diazinon and Zinophos in Soils.  J. Econ.
      Entomol.  60:505-508.

Gloyna, E. F. and D.  Thirumurth.  1967.  Suppression of Photosynthetic
      Oxygenation.  Water Sewage Works 114:83.

Graetz, D. A.,  G. Chesters, T. C. Daniel, L. W. Newland and G. B. Lee.  1970.
      Parathion Degradation in Lake Sediments.   Journal of the Water Pollution
      Control Federation 42:R76.

Gregory, W. W., Jr.,  J. K.  Reed and L. E. Priester, Jr.  1969.  Accumulation
      of Parathion and DDT by Some Algae and Protozoa.  J. Protozool. 16:69.

Greve, P. A. and S. L. Wit.  1971.   Endosulfan  in the Rhine River.  J. Water
      Pollut. Contr.  Fed.  43:2338-2348.  (Chem. Abstr. 76:37157b, 1972).

Haque, R. and V.  H. Freed.   1974.  Behavior of  Pesticides in the Environment:
      Environmental Chemodynamics.   Residue Reviews 52:89-116.

Harris, C. I.  1969.   Movement of Pesticides in Soil.  J. Agr. Food Chem.
      17:80-82.

Harris, C. R.,  A. R.  Thompson and C. M. Tu.  1972.  Insecticides and the
      Soil Environment.  Proc. Entomol. Soc. Ont. 102:156-168.

Harris, C. R. and J.  R. W.  Miles.  1975.  Pesticide Residues in the Great
      Lakes Region of Canada.  Residue Reviews  57:27-80.

Heath, R. G. et al.  1970.   Comparative Dietary Toxicities of Pesticides to
      Birds iiTsHort-term Tests.  U.S. Bur. Sport Fish § Wildlife, Patuxent
      Wildlife Research Center.   Unpublished data.

Heath, R. G., J.  W. Spann,  E. F. Hill and J. F. Kreitzer.  1972.  Comparative
      Dietary Toxicities of Pesticides to Birds.  U.S. Fish Wildl. Serv.,
      Bur. Sport Fish § Wildlife, Special Scientific Report - Wildlife No.
      152, 57 pp.
                                     642

-------
Heath, R. G. and L. F. Stickel.  1965.  Protocol for Testing the Acute and
      Relative Toxicity of Pesticides to Penned Birds. In: The Effects of
      Pesticides on Fish and Wildlife.  U.S. Fish § Wildl. Serv. Circ. 226:
      18-24.

Henderson, C., Q. H. Pickering and C. M. Tarwell.  1959.  Relative Toxicity
      of Ten Chlorinated Hydrocarbon Insecticides to Four Species of Fish.
      Trans. Am. Fish. Soc. 88:23-32.

Henderson, C., Q. H. Pickering and C. M. Tarzwell.  1959.  Toxicity of Organic
      Phosphorus and Chlorinated Hydrocarbon Insecticides to Fish.  Biol.
      Probl. Water Poll., Trans. 1959 Seminar, Robert A. Taft San. Eng.
      Center, Tech. Rep. W60-3:76-92.

Hendrick, R. D., T. R. Everett and H. R. Caffey.  1966.  Effects of Some
      Insecticides on the Survival, Reproduction and Growth of the Louisiana
      Red Crawfish.  J. Econ. Entomol. 59:188-192.

Heuer, B., B. Yaron and Y. Birk.  1974.  Guthion Half-life in Aqueous Solutions
      and on Glass Surfaces.  Bull. Environ. Contain. Toxicol. 11:532-537.

Hill, Elwood F.  1974.  (U.S. Department of Interior, Patuxent Wildlife
      Research Station).  Toxicity of Aldicarb to Wildlife, personal communi-
      cation to Criteria and Evaluation Division, Office of Pesticide Programs,
      Environmental Protection Agency (Reported in U.S. Environmental Protec-
      tion Agency 1975).

Hoffman, D. A. and J. R. Olive.  1961.  The Effects of Rotenone and Toxaphene
      Upon Plankton of Two Colorado Reservoir.  Limnol. Oceanogr. 6:219-222.

Holden, A. V.  1973.  Effects of Pesticides on Fish.  In:  C. A. Edwards, ed.
      Environmental Pollution by Pesticides.  Plenum Press, London,
      pp. 213-253.

Holmstead, R. L., S. Khalifa and J. E. Casida.  1974.  Toxaphene Composition
      Analyzed by Combined Gas Chromatography-Chemical lonization Mass Spec-
      trometry.  Journal of Agricultural and Food Chemistry 22(6):939-944.

Hughes, R. A. and G. F. Lee.  1968.  Report to the Wisconsin Conservation
      Division, Department of Natural Resources.  Mimeo , Wisconsin.

Huntj E. G. and J. 0. Keith.  1963.  Pesticide-Wildlife Investigations in
      California 1962.  Proc. 2nd Ann. Conf. on the Use of Agr. Chem. in
      Calif., University of California at Davis.  29 pp.

Hurlbert, S.  1975.  Secondary Effects of Pesticides on Aquatic Ecosystems.
      Residue Reviews 57:81-148.

Jensen, L. D. and A. R. Gaufin.  1966.  Acute and Long-term Effects of
      Organic Insecticides on Two Species of Stonefly Naiads.  J. Water Poll.
      Contr. Fed. 38:1273-1286.


                                     643

-------
Johnson, B. T. and J. 0.  Kennedy.   1973.   Biomagnification of p,p'-DDT and
      Methoxychlor by Bacteria.   Appl.  Microbiol.  26:66-71.

Johnson, W. D., G. F. Lee and D.  Spyrioakis.   1966.   Persistence of Toxaphene
      in Treated Lakes.  Air Water Pollution 10:555-560.

Kallman, B. J., 0. B. Cope and R.  J.  Navarre.   1962.   Distribution and
      Detoxication of Toxaphene  in Clayton Lake, New Mexico.   Trans.  Am.  Fish
      Soc.  91:14-22.

Katan, J.,  T. W. Fuhremann and E.  P.  Lichtenstein.  1976.   Binding of [l C]
      Parathion in Soil:  A Reassessment of Pesticide Persistence.  Science
      193:891-894.

Kaufman, D. D.  1976.  Soil Degradation and Persistence.   In: A Literature
      Survey of Benchmark Pesticides.  George Washington University Medical
      Center, Science Communication Division,  Washington,  D.  C., pp 19-71.

Kennedy, H. D., L. F. Eller, and D. F.  Walsh.   1970.   Chronic Effects of
      Methoxychlor on Bluegills  and Aquatic Invertebrates.  U.S. Dept. of
      Interior, Bur.  Sport Fish  § Wildl.  Tech. Paper 53,  18 pp.

Kleerekoper, H.  1974.  Effects  of Exposure to a Subacute  Concentration of
      Parathion on the Interaction Between Chemoreception  and Water Flow in
      Fish.  In: F. J. Verneberg and W.  B. Verneberg,  eds.   Pollution and
      Physiology of Marine Organisms, Academic Press, New  York, pp. 237.

Knaak, J. B.  1971.  Biological  and Nonbiological Modifications of Carbamates.
      Bulletin of the World Health Organization 44:121-131.

Knauf, W. and E. F. Schulze.  1973.  Toxicity of Endosulfan and its Metabo-
      lites to Aquatic Organisms.   Meded. Fac. Landbouwwetensch., Rijksuniv.
      Gent 38:717-732.  (Chem. Abstr. 81:34185e, 1974).

Knott,       and Beliles,       .   1966.   Report on Aldicarb, EPA Pesticide
      Petition No. 9F0798, Section C, Book III (reported in U.S. Environ-
      mental Protection Agency,  1975) .

Konrad, J.  G., G. Chesters and D.  E.  Armstrong.  1969.  Soil Degradation of
      Malathion, a Phosphoradithioate Insecticide.  Soil Sci. Soc. Amer.
      Proc. 33:259-262.

Kricher, J. C., J. C. Urey and M.  L.  Hawes.  1975.  The Effects of Mirex and
      Methoxychlor on the Growth and Productivity of Chlorella pyrenoidosa.
      Bull. Environ.  Contam. Toxicol. 14:617.

Lahav, M. and S. Sarig.  1969.  Sensitivity of Pond Fish to Cotnion (azinphos-
      methyl) and Parathion.  Bamidgeh. 21(3):67-74.

Lakota, S.   1974.  Toxic Action of Methoxychlor on Certain Water Animals.
                                     644

-------
      Tagungsber., Akad. Landwirtschaftswiss. D.D.R. 126:111-115.  (Chem.
      Abstr. 83:73043q, 1975).

Laveglia, J. and P. A. Dahm.  1975.  Oxidation of Terbufos (Counter^ in
      Three Iowa Surface Soils.  Environmental Entomology 4:715-718.

Lee, G. F., R. A. Hughes and G. D. Veith.  1977.  Evidence for Partial Deg-
      radation of Toxaphene in the Aquatic Environment.  Water, Air and Soil
      Pollution 8:479-484.

Lewallen, L. L. and W. H. Wilder.  1962.  Toxicity of Certain Organophosphorus
      and Carbamate Insecticides to Rainbow Trout.  Mosquito News 22(4):369-
      372 (In: U.S. Environmental Protection Agency, 1975).

Li, M. and R. A. Fleck.  1972.   The Effects of Agricultural Pesticides in
      the Aquatic Environment, Irrigated Croplands, San Joaquin Valley.
      Pesticide Studies Series No. 6.  Environmental Protection Agency,
      Office of Water Programs, Applied Technology Division, Rural Waste
      Research TS-00-72-05.  268 pp.

Lichtenstein, E. P., J. Katan and B. N. Anderegg.  1977.  Binding of "Persis-
      tent" and Nonpersistent" -^C-Labeled Insecticides in an Agricultural
      Soil.  Journal of Agricultural and Food Chemistry 25(l):43-47.

Lichtenstein, E. P. and K. R. Schulz.  1964.  The Effect of Moisture and
      Microorganisms on the Persistence and Metabolism of Some Organophos-
      phorus Insecticides in Soils With Special Emphasis on Parathion.
      Journal of Economic Entomology 57:618-627.

Loosanoff, V. L., J. E. Hanks and A. E. Ganaros.  1957.  Control of Certain
      Forms of Zooplankton in Mass Algae Cultures.  Science 125:1092.

Lowe, J. I.   1970.  Bio-Assay Screening Test--Carbofuran.  Gulf Breeze
      Environmental Laboratory, U. S. Environmental Protection Agency, Gulf
      Breeze, Florida (In: U.S. Environmental Protection Agency, 1976).

Lowe, J. I., P. D. Wilson, A. J. Rick, A. J. Wilson and J. Alfred, Jr.  1970.
      Chronic Exposure of Oysters to DDT, Toxaphene and Parathion.  Proc.
      Nat. Shellfish Assoc. 61:71-79.  (Chem. Abstr. 75:128793b, 1971).

Luczak, J.  1969.  Stability of Methoxychlor in Natural Waters.  Rocz.
      Panstw. Hig. 20:147-154.  (Chem. Abstr. 71:53307c, 1969).

Lyon, W. F. and R. H. Davidson.  1965.  The Effect of Humidity on the
      Volatilization of Insecticides.  J. Econ. Entomol. 58:1037.

MacKay, D. and A. W. Wolkoff.  1973.  Rate of Evaporation of Low Solubility
      Contaminants From Water Bodies to the Atmosphere.  Environmental Science
      and Technology 7(7):611-614.
                                     645

-------
MacNamara, G. M. and S. J. Toth.   1970.  Adsorption of Linuron and Malathion
      by Soils and Clay Minerals.  Soil Sci.  109:234-240.

Macek, K. J.  1970.  Biological Magnification of Pesticide Residues in Food
      Chains.  In:  J. W. Gillett, ed.  The Biological Impact of Pesticides
      in the Environment, Series No. 1, Oregon State University, pp. 17-21.

Macek, K. J., C. Hutchinson and 0. B. Cope.  1969.   Effects of Temperature
      on the Susceptibility of Bluegills and Rainbow Trout to Selected
      Pesticides.  Bull. Environ. Contam. Toxicol.  4:174-183.

Macek, K. J. and W. A. McAllister.  1970.  Insecticide Susceptibility of Some
      Common Fish Family Representatives.  Trans. Am. Fish Soc. 99:20-27.

Martin, Hubert and Charles R. Worthing.  1977.  Pesticide Manual, British
      Crop Protection Council, England.  593 pp.

Matida, Y. and N. Kawasaki.  1958.  Study on the Toxicity of Agricultural
      Control Chemicals in Relation to Freshwater Fisheries Management,  No. 2
      Toxicity of Agricultural Insecticides to Daphnia carinata.  Bulletin
      of the Freshwater Fisheries Research Lab., Tokyo 8:1-6 (In: U.S.
      Environmental Protection Agency, 1975).

Mauck, B.  1972.  Annual Progress Report: 1972, U.S. Department of the
      Interior, Bureau of Sport Fisheries § Wildlife, Fish Pesticide Research
      Unit, LaCrosse, Wisconsin.

Mayhew, T.  1955.  Toxicity of Seven Different Insecticides to Rainbow Trout,
      Salmo gairdnerii Richardson.  Proc. Iowa Acad. Sci. 62:599-606.

Mehrle, P. M. and F. L. Mayer.  1977.  Bone Development and Growth of Fish as
      Affected by Toxaphene.  In:  I. H. Suffet, ed.  Fate of Pollutants in
      the Air and Water Environments, Volume 2.  John Wiley and Sons,  New
      York. pp. 301-316.

Merna, J. W. and P. J. Eisele.  1973.  Effects of Methoxychlor on Aquatic
      Biota.  U.S. Nat. Tech. Inform. Serv.,  PB Rep. #228643/3GA, 66 pp.
      GPO  80.95.

Metcalf, R. L.  1976.  Bioaccumulation.  In:   A Literature Survey of Bench-
      mark Pesticides.  George Washington University Medical Center, Science
      Communication Division, Washington, D.  C.  pp. 246-252.

Metcalf, R. L., G. K. Sangha and I. P. Kapoor.  1971.  Model Ecosystem for
      the Evaluation of Pesticide Biodegradability and Ecological Magnifi-
      cation.  Environ. Sci. Technol. 5:709-713.

Metcalf, R. L. and J. R. Sanborn.  1975.  Pesticides and Environmental Quality
      in Illinois.  111. Nat. His. Survey Bull.
                                     646

-------
Meyer, F. P.  1965.  The Experimental Use of Guthion as a Selective Fish
      Eradicator.  Trans. Am. Fish. Soc. 94:203-209.

Miles, J. R. W. and C. R. Harris.  1971.  Insecticide Residues in a Stream
      and Controlled Drainage System in Agricultural Areas of Southwestern
      Ontario, 1970.  Pesticides Monitoring Journal 5:289.

Miller, C. W., B. M. Zuckerman and A. J. Charig.  1966.  Water Translocation
      of Diazinon-C^ and Parathion-S-^ Off a Model Cranberry Bog and Subse-
      quent Occurrence in Fish and Mussels.  Trans. Am. Fish. Soc. 95:345-349.

Minnesota Pollution Control Agency.  1979.  Pesticides Package 1.  Water
      Quality Management Planning Division of Water Quality, Planning
      Section, 63 pp.

Moore, R. B.  1970.  Effects of Pesticides on Growth and Survival of Euglena
      gracilis Z.  Bulletin Environ. Contam. Toxicol. 5:226.

Moorefield, H. H.  1974.  Data on Temik Aldicarb Pesticide Environmental
      Impact.  (Personal communication reported in U.S. Environmental Protec-
      tion Agency, 1975).

Mount, D. I. and C. E. Stephan.  1967.  A Method for Establishing Acceptable
      Toxicant Limits of Fish: Malathion and the BE Ester of 2,4-D.  Trans.
      Am. Fish. Soc. 96:185-195.

Muirhead-Thomson, R. C.  1971.  Pesticides and Fresh Water Fauna.  Academic
      Press, London.

Mulla, M. S., G. P. Georghiou, and H. W. Cramer.  1961.  Residual Activity
      of Organophosphorus Insecticides in Soil as Tested Against the Eye
      Gnat.  J. Econ. Entomol. 54:865-870.

Mulla, M. S., J. 0. Keith and F. A. Gunther.  1966.  Persistence and Biological
      Effects of Parathion Residues in Waterfoul Habitats.  Journal of
      Economic Entomology 59:1085-1090.

Muncy, R. J. and A. D. Oliver, Jr.  1963.  Toxicity of 10 Insecticides to
      the Red Crayfish Procambarus clarki (Girard).  Transactions of the
      American Fisheries Society 92:428-431.

Munson,  T.  0.   1976.  A Note on Toxaphene in Environmental Samples From the
      Chesapeake Bay Region.  Bulletin of Environmental Contamination and
      Toxicology 16:491.

Nalbandyan, R. A.  1974.  Persistence of Sevin and Phosalone in the Soil.
      Zashch. Rast. (Moscow) 26.  (Chem. Abstr. 81:73331r, 1974).

Naqvi, S. M. and D. E. Ferguson.  1968.  Pesticide Tolerances of Selected
      Freshwater Invertebrates.  J. Miss. Acad. Sci. 14:121-127.
                                     647

-------
Naqvi, S. M. and D. E.  Ferguson.   1970.   Levels of Insecticide Resistance in
      Fresh-water Shrimp,  Palaemonetes  kadakiensis.   Trans.  Am.  Fish.  Soc.
      99:696-699.

Nash, R. G., M. L.  Beall, Jr.  and W.  G.  Harris.  1977.   Toxaphene and 1,1,1,
      -trichloro-2,2-bis(p-chlorophenyl)ethane (DDT)  Losses From Cotton in an
      Agroecosystem Chamber.   Journal Agricultural and Food Chemistry 25(2):
      336-341.

Nash, R. G. and W.  G. Harris.   1973.   Chlorinated Hydrocarbon Insecticide
      Residues in Crops and Soils.  Journal of Environmental  Quality 2:269-
      273.

National Academy of Sciences.   1977.   Summary Report: Drinking Water and
      Health - A Report of the Safe Drinking Water Committee, Advisory Center
      on Toxicology, Assembly of Life Sciences, National Research Council,
      Washington, D. C. 62 pp.

Obuchowska, I.  1969.  Stability of Methoxychlor in the Soil.  Roca Panstw.
      Zakl. Hig. 20:489-493.   (Chem.  Abstr. 72:89234m,  1972).

Obuchowska, I.  1972.  Behavior of Tritox-30 in Soil.  Roca.  Panstw. Zakl.
      Hig. 23:147-154.   (Chem. Abstr. 77:57592p, 1972).

Palmer, C. M. and T. E. Maloney.   1955.   Preliminary Screening for Algiicides.
      Ohio J. Science 55:1.

Paris, D. F. and D. L.  Lewis.   1973.   Chemical and Microbial  Degradation of
      Ten Selected Pesticides in Aquatic Systems.  Residue Reviews 45:95-124.

Paris, D. F., D. L. Lewis and N.  L. Wolfe.  1975.  Rates of Degradation of
      Malathion by Bacteria Isolated From Aquatic Culture.  Environ. Sci.
      Technol. 135-138.

Pickering, Q. H., C. Henderson and E. A. Lemke.  1962.   The Toxicity of
      Organic Phosphorus Insecticides to Different Species of Warmwater
      Fishes.  Trans. Am. Fish. Soc.  91:175-184.

Pimentel, D.  1971.  Ecological Effects  of Pesticides on Non-Target Species.
      Executive Office of the President, Office of Science and Technology,
      U.S. Government Printing Office, Washington, D. C.

Pionke, H. B. and G. Chesters.  1973.  Pesticide-Sediment-Water Interactions.
      Journal of Environmental Quality 2(l):29-45.

Pollack, G. A. and W. W. Kilgore.  1978.  Toxaphene.  Residue Reviews 69:
      87-140.

Poorman, A. E.  1973.  Effects of Pesticides on Euglena gracilis.  I.  Growth
      Studies.  Bulletin Environ. Contam. Toxicol. 10:25.
                                     648

-------
Portmann, J.  E.  and K.  W.  Wilson.   1971.   The Toxicity of 140 Substances to
      the Brown Shrimp  and Other Marine Animals.   Min. Agric. Fish. Food,
      U.K., Shellfish Information Leaflet No. 22, 11 pp.

Priester, L.  E.   1965.   The Accumulation in Metabolism of DDT, Parathion and
      Endrin by Aquatic Food-Chain Organisms.  Ph.D. Thesis, Clemson Univer-
      sity, 74 pp.

Richardson, E. M.  and E. Epstein.   1971.   Retention of Three Insecticides on
      Different Size Soil  Particles Suspended in  Water.  Soil Sci. Soc. Amer.
      Proc. 35:884-887.

Sanborn, J. R.  1974.  The Fate of Select Pesticides in the Aquatic Environ-
      ment.  Ecological Research Series.   EPA-660/3-74-025.  U. S. Environ-
      mental Protection Agency, Corvallis, Oregon.

Sanborn, J. R.,  B.  Magnus  Francis and R.  L. Metcalf.  1977.  The Degradation
      of Selected Pesticides in Soil:  A Review of the Published Literature.
      EPA-9-77-022.  U.S.  Environmental Protection Agency, Washington, D. C.

Sanders, H. 0.  1969.  Toxicity of Pesticides to  the Crustacean Gammarus
      lacustris.  Tech. Paper 25, Bur. Sport Fish. Wildl., U. S. Department
      of Interior.   18  pp.

Sanders, H. 0.  1970.  Pesticide Toxicities to Tadpoles of the Western Chorus
      Frog, Pseudacris  triseriata, and Fowler's Toad, Bufo woodhousii fowleri.
      Copeia 2:246-251.

Sanders, H. 0. and 0. B. Cope.  1966.  Toxicities of Several Pesticides to
      Two Species of Cladocerans.   Trans. Am. Fish. Soc.  95:165-169.

Sanders, H. 0. and 0. B. Cope.  1968.  The Relative Toxicities of Several
      Pesticides to Naiads of Three Species of Stoneflies.  Limnol. Oceanogr.
      13:112-117.

Sangha, G. K.  1972.  Environmental Effects of Carbamate Insecticides as
      Assayed in the Model Ecosystem, A Comparison with DDT.  Dissertation
      Abstracts International 32(8):4650.
                                                       <§)
Schoenig, G.   1967.  Fish and Bird Toxicology, Furadan ^ 10G: Four-Day Fish
      Toxicity.   FMC Corporation, Middleport, New York (in U.S. Environ-
      mental Protection Agency, 1976).

Schoettger, R. A.   1970.  Toxicology of Thiodan in Several Fish and Aquatic
      Invertebrates.  Invest. Fish Contr. No. 35, 31 pp.   (Chem. Abstr.
      73:119606z,  1970).

Schoettger, R. A.  and J. R. Olive.  1961.  Accumulation of Toxaphene by Fish-
      Food Organisms.  Limnol.  Oceanogr. 6:216-219.
                                     649

-------
Schulz, K. R., E. P. Lichtenstein, T. T. Liang and T. W. Fuhremann.  1970.
      Persistence and Degradation of Azinphosmethyl in Soils.   J. Econ.
      Entomol. 63:432-438.

Schulz, K. R. and E. P.  Lichtenstein.  1971.  Field Studies on the Persis-
      tence and Movement of Dyfonate in Soil.  Journal of Economic Entomology
      64:283-287.

Seiber, James N., Steven C. Madden, Michael M. McChesney and Wray L. Winterlin.
      1979.  Journal of Agriculture and Food Chemistry 27(2) : 284-291.

Sethunathan, N. and I.  C. MacCrae.  1969.  Persistence and Biodegradation of
      Diazinon in Submerged Soils.  J.  Agric. Chem. 17:221-225.

Sethunathan, N. and M.  D. Pathak.  1971.  Development of A Diazinon-Degrading
      Bacterium in Paddy Water After Repeated Application of Diazinon.
      Can. J. Microbiol. 17:699-702.

Sethunathan, N. and M.  D. Pathak.  1972.  Increased Biological Hydrolysis of
      Diazinon After Repeated Application to Rice Fields.  J.  Agric. Food
      Chem. 20:586-589.

Sethunathan, N. and T.  Yoshida.  1969.   Fate of Diazinon in Submerged Soil:
      Accumulation of Hydrolysis Product.  J. Agric. Food Chem. 17:1192-1195.

Sheets, T. J., J. R. Bradley, Jr. and M. D. Jackson.  1972.  Contamination
      of Surface and Ground Water With Pesticides Applied to Cotton.
      University of North Carolina Water Resource Research Institute Report
      No. 60.  Chapel Hill, North Carolina.

Singh, P. K.  1973.  Effect of Pesticides on Blue-Green Algae.  Arch.  Mikro-
      biol. 89:317.

Smith, E. G., F. D. Whitaker and H. G.  Heineman.  1974.  Losses of Fertil-
      izers and Pesticides From Clay Pan Soils.  EPA 660/2-74-068.  U.S.
      Environmental Protection Agency,  Athens, Georgia.

Spencer, William.  1976.  Vapor Pressure and Vapor Losses.  In: A Literature
      Survey of Benchmark Pesticides.  George Washington University Medical
      Center, Science Communication Division, Washington, D. C. pp.72-165.

Spiller, D.  1961.  A Digest of Available Information in the Insecticide
      Malathion.  Adv.  Pest Control Research 4:249.

Stadnyk, L., R. S. Campbell and B. T. Johnson.  1971.  Pesticide Effect on
      Growth and l^C Assimilation in a Freshwater Alga.  Bull. Environ.
      Contam. Toxicol.  6:1-8.

Staiff, D. C., S. W. Comer, J. F. Armstrong and H. R. Wolfe.  1975.  Persis-
      tence of Azinphosmethyl in Soil.   Bull Environ. Contam.  Toxicol.  13:
      362-368.


                                     650

-------
Stanley, C. W., J. E. Barney, M. R. Helton and A. R. Yobs.  1971.  Measure-
      ment of Atmospheric Levels of Pesticides.  Environmental Science and
      Technology 5:430-435.

Stewart, D. K. R. and K. G. Cairns.  1974.  Endosulfan Persistence in Soil
      and Uptake by Potato Tubers.  J. Agr. Food Chem. 22:984-986.

Stewart, D. K. R., D. Chisolm and M. T. H. Ragab.  1971.  Long-Term Persis-
      tence of Parathion in Soil.  Nature 229:47.

Stewart, N. E., R. E. Milleran, and W. P. Breese.  1967.  Acute Toxicity of
      the Insecticide Sevin and its Hydrolytic Product 1-Naphthol to Some
      Marine Organisms.  Trans. Am. Fish. Soc. 96:25-30.

Stickel, W. H.  1967.  Wildlife, Pesticides and Mosquito Control.  Mass.
      Audubon 51:110.

Stringer, G. E. and R. C. McMynn.  1958.  Experiments with Toxaphene as a
      Fish Poison.  The Canadian Fish Culturist 23:39-48.

Suett, D. L.  1971.  Persistence and Degradation of Chlorfenvinphos, Diazinon,
      Fonophos, and Phorate in Soils and Their Uptake by Carrots.  Pesticide
      Science 2:105-12.

Swoboda, A., G. W. Thomas, F. B. Cady, R. W. Baird and W. G. Knisel.  1971.
      Distribution of DDT and Toxaphene in Houston Black Clay on Three Water-
      sheds.   Environmental Science and Technology 5(2):141-145.

Takase, I., H. Tsuda and Y. Yoshimoto.  1972.  Fate of Disyston Active
      Ingredient in Soil.  Pflanzenschutz-Nachr. (Amer. Ed.) 25:43-63.
      (Chem. Abstr. 80:67395c, 1974).

Terriere, L. C., U. Kiigemagi, A. R. Gerlach and R. L. Borovicka.  1966,  The
      Persistence of Toxaphene in Lake Water and its Uptake by Aquatic Plants
      and Animals.  Journal Agricultural and Food Chemistry 14:66-69.

Tessari, J. D. and D. L. Spencer.  1971.  Air Sampling for Pesticides in the
      Human Environment.  Association of Official Analytical Chemists
      54(6):1376-1382.

Trichell,   D. W., H. L. Morton and M. G. Merkle.  1968.  Loss of Herbicides
      in Runoff Water.  Weed Sci. 16:447-449.

Tucker, R. K. and D. G. Crabtree.  1970.  Handbook of Toxicity of Pesticides
      to Wildlife.  U.S. Fish. Wildl. Serv., Bur. Sport Fish. $ Wildl.,
      Resource Publ. No. 84, 131 pp.

Ukeles, R.  1962.  Growth of Pure Cultures of Marine Phytoplankton in the
      Presence of Toxicants.  Applied Microbiol. 10:532.
                                     651

-------
Union Carbide Corporation.          Technical Information Temik   Aldicarb
      Pesticide.

U.S. Department of Interior.   1965.  Wildlife Research, Problems, Programs
      and Progress.  Pesticide-Wildlife Relations.   Fish Wildl.  Serv.  Bur.
      Sport Fish & Wildl. Circ.  23, 103 pp.

U.S. Environmental Protection Agency.  1975.  Initial Scientific and Mini-
      economic Review of Aldicarb.  Office of Pesticide Programs, Substitute
      Chemical Program Report No. EPA-540/1-75-013, U.S.  Environmental
      Protection Agency, Washington, D. C., 122 pp.

U.S. Environmental Protection Agency.  1975a.  Initial Scientific and Mini-
      economic Review of Malathion.  Office of Pesticide Programs, Sub-
      stitute Chemical Program Report No. EPA-540/1-75-005.  U.S. Environ-
      mental Protection Agency,  Washington, D. C.

U.S. Environmental Protection Agency.  1975b.  Initial Scientific and Mini-
      economic Review of Methyl  Parathion, Office of Presticide Programs, Sub-
      stitute Chemical Program Report No. EPA-540/1-75-004, U.S. Environ-
      mental Protection Agency,  Washington, D. C.

U.S. Environmental Protection Agency.  1975c.  Initial Scientific and Mini-
      economic Review of Parathion.  Office of Pesticide Programs, Substi-
      tute Chemical Program Report No. EPA-540/1-75-001.  U.S. Environmental
      Protection Agency, Washington, D. C.

U.S. Environmental Protection Agency.  1976.  Initial Scientific and Mini-
      economic Review of Carbofuran.  Office of Pesticide Programs, Substitute
      Chemical Program Report No. EPA-540/1-76-009.  U.S. Environmental
      Protection Agency, Washington, D. C., 187 pp.

U.S. Environmental Protection Agency.  1973.  Effects of Pesticides in Water-
      A Report to the States, Washington, D. C.

Veith, G. D. and G. F. Lee.  1971.  Water Chemistry of Toxaphene-Role of Lake
      Sediments.  Environmental Science and Technology 5(3):230-234.

Vettorazzi, G.  1975.  State-of-the-Art of the Toxicological  Evaluation
      Carried Out by the Joint FAO/WHO Expert Committee on Pesticide Residues.
      I.  Organohalogenated Pesticides Used in Public Health and Agriculture.
      Residue Reviews    :107-134.

Vettorazzi, G.  1976.  State-of-the-Art of the Toxicological  Evaluation
      Carried Out by the Joint FAO/WHO Expert Committee on Pesticide Residues.
      II.  Carbamate and Organophosphorus Pesticides Used in Agriculture and
      Public Health.  Residue Reviews 63:1-44.

Vettorzaai, G.  1977.  State-of-the-Art of the Toxicological Evaluation
      Carried Out by the Joint FAO/WHO Expert Committee on Pesticide Residues.
      III.  Miscellaneous Pesticides Used in Agriculture and Public Health.


                                     652

-------
      Residue Reviews 66:137-184.

Voerman, S. and A. F. H. Besemer.  1970.  Residues of Dieldrin, Lindane,
      DDT and Parathion in a Light Sandy Soil After Repeated Application
      Throughout a Period of 15 Years.  J. Agr. Food Chem. 18:717-719.

Von Rumker, R. , G. K. Kelso, F. Horay and K. A. Lawrence.  1975.  A Study of
      the Efficiency of the Use of Pesticides in Agriculture.  EPA-9/75-025.
      U.S. Environmental Protection Agency, Washington, D. C.

Von Rumker, R., E. W. Lawless, A. F. Meiners.  1974.  Production, Distri-
      bution, Use and Environmental Impact Potential of Selected Pesticides.
      EPA-1/74-001.   U.S. Environmental Protection Agency, Washington, D. C.

Ware, George W.  1978.  The Pesticide Book.  W. H. Freeman and Company, San
      Francisco, 197 pp.

Ware, G. W., B. Estesen and W. P. Cahill.  1972.  Organophosphate Residue
      Cotton in Arizona.  Bulletin of Environmental Contamination and Toxi-
      cology 8(6) :361-362.

Warner, R. E., K. K. Peterson and L. Borgman.  1966.  Behavioral Pathology
      in Fish: A Quantitative Study of Sublethal Pesticide Toxication. J.
      Applied Ecol.  3 (Suppl.) 223.

Wauchope, R. D.  1978.  The Pesticide Content of Surface Water Draining From
      Agricultural Fields - A Review.  Journal of Environmental Quality
      7(4) :459-472.

Way, M. J. and N. E. A.  Scopes.  1968.  Studies on the Persistance And
      Effects on Soil and Fauna of Some Soil-Applied Systemic Insecticides.
      Ann. Appl. Biol. 62:199-214.

Weis, J. S. and P. Weis.  1975.  Retardation of Fin Regeneration in Fundulus
      by Several Insecticides.  Transactions of the American Fisheries
      Society 104:135.

Weiss, C. M. and J.  H. Gakstatter.  1964.  Detection of Pesticides in Water
      by Biochemical Assay.  J. Water Pollut. Contr. Fed. 36:240-253.

Weiss, C. M.  1959.   Response of Fish to Sub-lethal Exposures of Organic
      Phosphorus Insecticides.  Sewage Indust. Wastes (J. Water Pollut.
      Contr. Fed.) 31:580-593.

Weiss, C. M. and J.  H. Gakstatter.  1965.  The Decay of Anticholinesterase
      Activity of Organic Phosphorus Insecticides on Storage in Water of
      Different pH.   Proc. 2nd Internat. Water Poll. Res. Conf., Tokyo,
      pp. 83-95.

Williams, R. R. and  T. F. Bidleman.  1978.  Toxaphene Degradation in Sediments.
      Journal Agricultural and Food Chemistry 26(1):280-282.


                                     653

-------
Williams, I. H. and M. J. Brown. 1976.   Persistence of Carbofuran Residues
      in Some British Columbia Soils.  Bulletin of Environmental Contami-
      nation and Toxicology 15(2):242-243.

Williams, I  H., H  S. "ep~n ard M. J.  Brown.  1976.  Degradation of Carbo-
      furan by Soil Microorganisms.  Bulletin of Environmental Contamination
      and Toxicology 15(2)':244-249.

Wolfe, N. L., R. G. Zepp, G. L.  Baughman and J. A. Gordon.   1975.  Kinetic
      Investigation of Malathion Degradation in Water.  Bull.  Environ.
      Contam. Toxicol. 13:707-713.

Wolfe, N. L., R. G. Zepp, D. F.  Paris,  G. Baughman and R. C. Hollis.  1977.
      Methoxychlor and DDT Degradation in Water:  Rates and Products.
      Environmental Science and Technology 11(12) : 1077-1081.

World Health Organization.  1968.   Evaluation of Insecticides for Vector
      Control.  Part I.  WHO/VBC/66.66.

Yasuno, M., S. Hirakoso, M. Sasa and M. Uchida.  1965.  Inactivation of Some
      Organophosphorus Insecticides by Bacteria in Polluted Water.  Jap. J.
      Exp. Med. 35:545-563.

Yu, C. C., G. M. Booth, D. J.  Hansen and J. R.  Larsen.  1974.   Fate of Carbo-
      furan in a Model Ecosystem.   Journal of Agricultural and Food Chemistry
      22(3) :431^33.

Yu, C. C., R. Metcalf and G. M.  Booth.   1972.  Inhibition of Acetylcholin-
      esterase From Mammals and Insects by Carbofuran and Its Related
      Compounds and The Toxicities Toward These Animals.  Journal of Agri-
      cultural and Food Chemistry 20(5) :923-926.

Yu, C. C. and J. R. Sanborn.  1975.  Fate of Parathion in a Model Ecosystem.
      Bull. Environ. Contam. Toxicol. 13:543-550.

Zepp, R. G., N. L. Wolfe, J. A.  Gordon, R. C. Finche and G. L. Baughman.
      1975.  Chemical and Photochemical Transformations of Selected Pesti-
      cides in Aquatic Systems.  U.S. Environmental Protection Agency, Ecol.
      Res. Ser. EPA-600/3-76-067.
                                     654

-------
                                  APPENDIX F

               ECONOMIC  PERSPECTIVE AND  EVALUATION  METHODS  FOR
            AGRICULTURAL NONPOINT SOURCE WATER QUALITY  MANAGEMENT

                 N.K. Whittlesey, S.C. Matulich, W.  Pietsch,
                    P.O. Robillard, G.L. Casler, E.A. Lang
                                   SECTION  1

            AN ECONOMIC PERSPECTIVE OF NONPOINT  POLLUTION  CONTROL
THE PROBLEM DEFINED

     Economic activity  is  the  process whereby  natural  resources  are converted
into products that satisfy  human  needs and wants.  The conversion  may  be
relatively direct, for  example, when wind is  harnessed to  pump water for an
isolated farmstead.  More  commonly, the conversion involves  many  steps,  as in
the case of automobile  production; ore is mined, melted, and cast into pigs,
which are then shipped, melted, stamped, rolled, shaped, and eventually
transformed into an automobile.

     When natural resources  are converted via  economic activity,  the change
in the resources is often  irreversible.  Until  recently, resources such  as
air, sunlight, and water have  appeared plentiful.  Because  they  have been
treated as free, they have been subject to abuse; smoke has  been  emitted into
'free' air, sewage has  been  dumped into 'free'  river water,  and  cans have
been thrown on 'free' grass  along public roadways.

     The relationship between  economic growth  and environmental  quality  is
generalized in Figure F-l.   The line AC represents possible  combinations of
environmental  quality and  consumer goods.  In  some cases, we might actually
increase production while  improving environmental quality. However,  more
typically, there is a tradeoff between the two.  To gain one requires  giving
up some of the other.   Goods exchanged in the  marketplace  are given  a  value.
The value placed on environmental quality, however, may not  always be  clear.
To the extent that the  relative values placed  on consumer  goods  and
environmental  quality can  be compared, such a  comparison allows  us to
determine the slope of  the maximum revenue (total utility) line DO as  an
indicator of the relative  preference between the two alternatives.   It can be
shown, for example, that complete abatement of  pollution from irrigation
return flows would be very costly, and would probably  include a  significant
reduction in food production.  The public might prefer to operate  at point B,
where we have a moderate supply of goods and a  tolerable environment.  Those

                                    655

-------
with a preference for a more pristine environment, however, might prefer  to
operate at point C, and the producer might prefer to operate at point A,
where production is maximized, but at a greater cost to the environment.
A major problem in arriving at a socially desirable mix of commercial goods
and environmental quality is that the preference for these alternatives are
indicated in different ways.  Market prices serve to indicate our desire  for
consumer goods, but there is generally no such convenient method for
measuring preferences for an improved environment.
       Figure F-l.  Generalized relationship between economic production
                    and environmental quality.
               <
               o
               LJ
               2
               z
               o
                            ECONOMIC PRODUCTION
                                     656

-------
PROPERTY RIGHTS

     Property rights are the  rules of  resource  ownership  and  use.
'Resources'  include minerals, soil, air, water, etc.,  commonly  referred  to as
'natural' resources, and in addition,  such  items  as  automobiles,  furniture,
and wages.   In this context,  resources  refer to natural resources  only.

Private Property

     Private property rights  conferred  upon the owner  of  an object provide
him/her with the privilege of exclusive  use and the  right to  transfer its use
to anyone else whenever that  becomes advantageous.   Society may impose  rules
that restrict the use of the  item, but  the  individual  who holds title to the
item is the only one who can  use the item within  the bounds of  the law.
Private land is owned by individuals or  groups, but  restrictions  on land use
may be imposed through zoning or building codes.   If all  activities of
people were carried out exclusively through the use  of private  property, the
market would measure the positive value  or utility,  and the negative value,
or disutility, derived by people from  the use of  a good.   A great  deal  of
disutility or loss of value is created  by the use of private  property items
such as automobiles which emit exhaust  fumes or by residues from  fertilizers
which are carried onto other  properties.

Common Property

     Our markets are well equipped to  guide resources  into productive uses
and to distribute economic rewards among members  of  the community  as long as
we are dealing only with the  class of  goods or  resources  known  as  private
property.  There is, however, a large  class of  resources  that are  not
susceptible to restrictive property rules.  These are  known as  common
property resources or simply  as "community  property".

     Common property rights are not possessed exclusively by  one  individual,
and thus are nontransferrable.  Truly  common rights  are vested  equally  in
each citizen, and allocation  of common  property resources among individiuals
becomes problematic.  Some common property  is subject  to  limited  individual
choice, such as the sailing,  water skiing,  or fishing  services  available from
a publicly owned lake; individuals may  choose to  utilize  the  wind  for sailing
or the water for fishing or skiing.  The use of other  common  property is
intensive, and characterized  by competition and conflict.  Water  used for
irrigation is an example of this type  of common property.

     There is no marketplace  where users of common property  resources can
interact and negotiate.  If one person's use of a common  property  resource
serves to damage the incentive or reduce the profits of a second  person, the
second person has absorbed a  cost that will be  reflected  in the value of his
other  resources.  Pollution commonly yields this  effect.   Mutual  benefits can
occur, on the other hand; one farmer's drain system, for  example,  may lower
the water table on his neighbor's land.

     Problems arise because we cannot  assign property  rights  to resources
such as water and air.  These public resources  become  the sinks for many of

                                     657

-------
the discharges  or  unwanted by-products of production processes  in  our
economy.  Some  of  the  costs  of  producing a particular good are  imposed  on
people outside  the market regime of those actually producing  or consuming the
goods.  This phenomenon  is illustrated in Figure F-2.  The curve SS  indicates
a supply of consumer  goods being provided in a market economy.   A  quantity
Q! can be provided at  a  price Px.   The demand curve for these consumer  goods
is indicated by curve  DD.   The production of goods, such  as the food which
comes from agriculture,  can result in environmental degradation with costs
falling upon others outside of agriculture.  There is a social  cost  which the
producers of food  and  pollution do not incorporate in their decision-making.
If the costs of environmental  degradation were assigned to the  polluter or to
the goods causing  such pollution,  it would raise the costs of those  consumer
goods to the level  of  curve  SSi.  After recognition of these  additional
costs, there would result a new equilibrium with fewer consumer goods
produced at higher costs;  the quantity produced would be  reduced to  Q£  and
the price raised to P2.
        Figure  F-2.   Adjustment in output which might  result  from an
                      incorporation of environmental costs.
                                       Supply Curve-pollution
                                        cost incorporated
            o
            rr
            a.
            a
            o
            O
            O
                                                   Supply Curve - pollution
                                                    cost not incorporated
                                Q2 Q,

                              QUANTITY  PRODUCED
                                      658

-------
     Such "internalizatlon"  of  pollution costs  via  the marketplace would
solve many of our  environmental  problems, but this  is usually impractical.
Public  intervention into  the private market  is  the  most  common means of
internalizing pollution costs.

ECONOMIC CONCEPTS

     Market prices  generally  serve  to guide  resources into  their  most
productive uses.   The  prices  of  production factors  and goods  are  assumed to
represent the contribution of each  to social welfare.  If knowledge is
perfect, even the  level of pollution will not exceed society's desires.
Under such circumstances, the homemaker who  buys beef in New  York is assumed
to be paying for the damage  caused  by odors  near the meat packing plant or
for damages due to  stream pollution near the point  of production.  Obviously,
these conditions do not hold  in  fact.  Pollution costs are  not completely
absorbed or internalized, and homemakers near the pollution source are  not
fully compensated.

Externalities

     An economist  describes  the  incompleteness  of the production  system
as "externalities".  For example, a farmer will strive to maximize profits by
combining land, water, fertilizer,  labor, and sunshine to produce crops in an
efficient way.  In  the process,  he may create externalities such  as air
pollution (dust or  odors) or water  pollution (sediment or nutrients)  which
can harm or reduce  the welfare of others.

Opportunity Costs

     Externalities  generally can not be easily  measured.  To  determine  the
impacts of externalities, the economist relies  heavily on the concept of
opportunity cost.   Briefly defined, the opportunity cost of a resource  is the
value of its best  alternative use.  Water used  for  irrigation may yield a
profit of $15 per  acre foot.  If the same water were used to  generate power,
it might have a value of $20 per acre foot.  This $20 becomes the opportunity
cost of water used  for agricultural production.

     The concept of opportunity  costs can be used to assess the impact  of
pollution that reduces the recreational  value of a  lake.  The value of  lost
recreation is measured by the costs required  to develop alternative means of
recreation.  Construction and maintenance of swimming pools,  and  travel  to
more distant lakes, may all  be  involved.

     The opportunity costs of resource use can  be used to measure pollution
costs and to help determine whether or not pollution abatement programs
should be undertaken.  Although  the opportunity cost is  the key to  damage
assessment, the distribution of  damages among members of society  is also
useful  in rendering opinions about allocating the costs  of pollution
abatement.   The magnitude of opportunity costs  and  their distribution among
members of society  become an index of the pollution costs; they become  a
standard against which the benefits of pollution abatement can be judged.


                                     659

-------
     The distribution of opportunity costs is often difficult to  determine.
When responsibility for damage is widely distributed, for example when  return
flows from irrigation in the Upper Colorado River cause damage  throughout  the
Southwest desert, enforcing payment for this damage is extremely  complicated.

Abatement Costs and Benefits

     The ideal criteria for setting pollution abatement standards would  be to
have a perfect knowledge of the costs and benefits of pollution abatement.
Generally, the costs of pollution abatement can be identified because they
are determined in the marketplace.  The measure of abatement costs  used  in
this report is the decrease in net farm income  (uncompensated)  for
alternative management practices.  There is no  standard measure of  abatement
benefits, however.  Health, recreation, or aesthetic effects are  nearly
impossible to quantify in a manner that allows  them to be compared  with
other, largely economic costs.  Even factors that can be measured in economic
terms, such as land values or production costs, are often difficult to
quantify as a function of pollution abatement.

     Despite  the  problems of measuring pollution abatement  benefits, such
measurement should remain a goal.  To the extent that this  goal is  reached,
we can be more confident that imposed environmental standards are optimally
designed to meet  social goals.  Since the identification and measurement of
benefits will identify those who  receive the benefits, a more valid basis  for
distribution  of abatement costs will result.

METHODS OF ABATEMENT

     There are three  broad classes of solutions to environmental  quality
problems:  (1) market  solutions, following the establishment of  liability
rules to serve as a starting point for negotiations,  (2) systems  of per-unit
taxes, charges, fines or subsidies designed to  alter  pollution  levels  by
influencing production methods, and  (3) systems of standards, enforced  by  the
threat of fines or jail sentences.

Market Solutions

     Market negotiations concerning externality problems are  based  upon laws
of liability.  Under  full liability  rules, a polluter is responsible for the
cost of abating pollution or compensating those affected by pollution.   Under
zero liability, on the other hand, the polluter has no responsibilities.

     Under partial liability, compensation for  pollution is required only
after a specified degree of pollution has occurred.   Partial  liability  rules
may prevent either the affected or affecting parties  from extorting
unreasonable  compensation from  the liable party by claiming excessively large
damages or abatement  costs.  Partial  liability  rules  can be devised to
recognize the environment's ability  to assimilate  a certain amount  of  waste
without significant external effects.

     Costs of making  and enforcing decisions  regarding pollution  control,  or
'transaction  costs',  can have a significant effect on the decision-making


                                     660

-------
process itself.  For example, with the  full  liability  rule  in  effect,
transaction costs could result in the polluter  being unable  to compensate  the
receptors, and the polluter may decide  for complete abatement.   A  dairy, for
example, might be polluting a river and faced with the  full  responsibility
for abating all such pollution or paying all affected citizens  an  amount
sufficient te allow some  level of pollution  to  continue.  The  firm would most
likely find it very costly to seek out  all affected parties  and to arrive  at
an acceptable level of payment.   It would be cheaper to quit polluting  or,  in
this case, to cease production.

     The amount of production and pollution  can be influenced  markedly  by  the
type of imposed liability rule.  Under  a zero liability rule,  the  acting
party which receives the  payment will have more capital  to  work with,  and  may
produce even more (with the subsequent  ability  to pollute more  as  well).
Under a full liability rule, the acting party will have its  working capital
reduced because of the need to pay compensation  or invest in pollution
control devices.  Hence,  this party will produce and pollute less.

     Transaction costs are likely to be larger  when negotiations must  be
initiated by large and diffuse groups of individuals rather  than by a  few
individuals having common  interests.  Thus,  it  follows  that  the full
liability rule is more likely to have smaller transaction costs than the zero
liability rule, and more  of a chance for abatement.  The full  liability rule
has generally been followed in solving  point source pollution  problems.

     With the zero liability rule, little incentive exists  for  an  emitter  to
develop or use pollution  control devices.  Farmers polluting through
irrigation return flows generally fall  in this  category.  Farmers  may  adopt
pollution reduction technologies, but only if compensated for  additional
costs in some manner.  The alternative  is to shift the  liability onto  the
farmer through threats of fines or jail  sentences.

     Full liability rules  carry an incentive to adopt  environmentally
sensitive technologies.   Such rules also promote the location  of polluting
businesses in areas where  external costs to  society are small.   An additional
argument for the full liability rule can be  made on the grounds of equity.
If polluters are more prosperous than affected  parties,  the  full liability
rule helps to "redistribute the wealth", and once again is  more equitable
than a zero liability rule.

Nonmarket Solutions

     Market bargaining can solve some pollution problems, but  in other  cases,
nonmarket policies must be implemented.  Such policies  include  effluent
standards, effluent taxes, subsidies, output taxes, input taxes, and  input
limits.  Though generally  resembling full liability policies,  these solutions
are controlled by government or regulatory groups, rather than by  market
negotiations.  The case studies in Section 5 of the planning manual  present
examples of control alternatives based  on effluent, output  and input  taxes.
                                     661

-------
Effluent Standards --

     Effluent standards or emission  rights  are  in  effect  a  means  of  assigning
liability limits to polluters.  An effluent standard,  for example, could
state the amount of sediment, nitrates, or  irrigation  return  flow  allowed  to
leave the farm.  Such standards result in the polluter  being  foeced  to  abate
some or all of his pollution.  There may  or may  not  be  financial  assistance
for the polluter for meeting the costs of pollution  abatement.

     A policy of issuing  rights to farms  allowing  a  specific  amount  of
pollution is conceivable, but unlikely.   The amount  of the  emission  rights
issued would be determined by the environmental  standard  to be  achieved.   It
would be desirable to allow trading  (buying and  selling)  of the rights  among
farms within a river basin or watershed,  in order  to allow  all  farms to
equate their marginal costs of abatement.   Farms relying  on old irrigation
systems or located on soils which are difficult  to control  could  buy rights
from others in order to increase their level of  emission  rights.

     An effluent standard is the same as  a fixed resource to  the  farm.   It
can be used up to its limits, but not exceeded.  The value  of the  standard
shows the farm's value to the environment for waste  disposal  services,  just
as the price for land shows its value for crop  production.  Disadvantages  of
effluent standards are: (1) the allocation of resources may be  unfair,  unless
trading is allowed or the initial level of  allocation  is  based  on  ability  to
meet the standard, and (2) firms benefit  from overstating their abatement
costs, resulting in levels of emissions which are  higher  than necessary.   In
general, it does a relatively poor job of inducing pollution  abatement
technology.

     The use of an emission rights (effluent standard)  policy is probably  not
well adapted to nonpoint  source pollution problems in  agriculture because  it
requires that the level of pollution coming from the farm be  identifiable  and
measurable.  This type of policy could be useful in  determining optimal
abatement policies for a  river basin.  To meet  a given environmental goal  in
a  river basin, it might be desirable to force some farms  to meet higher
standards than others, while having  all farms share  in the  associated costs.

Effluent Taxes --

     Rather than issue permits or standards for  pollution,  it is  possible  to
impose a tax on emissions to be paid by the polluter.   Firms  will  react by
abating pollution as long as the abatement costs are less than  the tax;
beyond that point they will pollute  and pay the  tax  on emissions.   Tax  rates
can then be adjusted to achieve the desired level  of pollution  abatement.

     If sufficient information exists to  measure the benefits of abatement,
it is possible to set the effluent tax so that  abatement  benefits  equal
abatement costs.  The taxes collected can be used  to compensate the  lost
benefits of those affected by the resulting pollution.   The actual economic
value of abatement benefits, however is usually  not  easily  determined.   In
this case, a desirable environmental quality standard  is  selected, then the
effluent tax is adjusted  to meet the standard at minimum  cost.   The  approach

                                     662

-------
presumes a full or partial  liability  rule  to  be  in  effect,  with appropriate
governmental enforcement.

     For any given effluent  standard,  there is a  tax  that  will  result in the
same degree of abatement.   That  tax  rate  is equal  to  the marginal  abatement
cost at the given standard  of  pollution.   Abatement is  achieved by reducing
production, or altering  the  combination of inputs.

     To achieve a given  level  of abatement a  uniform  effluent standard may be
more costly than a uniform  effluent tax.   A uniform effluent  standard will
cause each firm to meet  the  same level of  emissions regardless  of the firm's
ability to do so.  Some  firms  may, therefore, be  forced out of  business.  A
uniform effluent tax, on  the other hand,  may  allow  those firms  unable to meet
a specified standard to  at  least remain in operation  by paying  the tax and
continuing to pollute.   The  aggregate  income  loss  to  the industry should be
about the same in each case, however.

     A disadvantage of the  emission tax is the possibility of suboptimal
investment decisions made on the basis of  suboptimal  tax rates.  Unless the
initially imposed tax is  at  exactly the right level,  firms  will incorrectly
respond by making investment decisions on  the basis of  improper tax rates.
There is the additional  problem  of setting up a  government  tax  program
without knowing the proper  tax rate or the amount  to  be collected.  Standards
also cannot be indiscriminately  changed or adjusted without imposing serious
and unnecessary hardships on most  industries.

     Both the emission standard  and the effluent  tax  require  that a firm's
effluent be readily identified and measured.  This  requirement  is virtually
impossible to meet for most  nonpoint  source pollution.

Subsidies --

     Subsidies to reduce  emissions are similar to taxes in  several respects.
Using subsidies, the payment is  from  the  public  to  the  polluting firm, rather
than in the opposite direction.  A level of subsidy can be  devised to achieve
the same level of abatement  as with a  tax.  Firms will  theoretically adjust
production or use of inputs  that are  contributing to  pollution  until  the
level of foregone income  exactly equals the level  of  the subsidy.   This
approach is obviously subject  to cheating  if the  polluter  overstates his
abatement cost or accepts the  subsidy  and  then continues to pollute.   It
requires careful identification  of polluters and  continual  monitoring of
their abatement programs.   However, this  is one  approach which  is commonly
advocated for influencing farmers to adopt abatement  control  practices.

     In the long run, effluent taxes  and  subsidies  may  have opposite effects
on an industry.  Taxes will  reduce the amount of effluent from an industry as
a whole.  If it is known  that  the public will pay  the costs of  solving
environmental problems via  subsidies,  an  industry will  grow unimpeded.  Thus
although subsidies will  cause  a  reduction  in  the  effluent discharged per
firm, they may cause an  increase in the discharge from  the industry as a
whole.
                                     663

-------
Output Taxes —

     It is also possible to impose a tax on the product or good  (for  example,
potatoes) whose production is causing the pollution.  Again, a tax level  is
devised that will result in the desired level  of pollution abatement.  A  tax
on the product may be partially passed on to consumers in the form of a price
increase if the entire industry faces the same output tax.  Whenever  the  tax
is imposed on only a small portion of the industry, however, that portion  of
the industry will probably have to adsorb the additional cost or switch to
another product.

     An output tax does not effectively alter the prices of inputs used in
production.  Thus, the combination of inputs remains unaffected.  For any
level of abatement, an effluent (pollutant) tax will generally be less costly
than an output tax except when the output and pollutant are directly
proportional to each other.  This is a rare circumstance.

     An output tax generally has only limited use in agriculture, since most
pollution is a function of only a few inputs (such as water, fertilizer,  or
chemicals).  Effluents would be reduced only in relation to output
reductions, and input substitution would not be encouraged (e.g., increasing
management or labor to reduce the amount of water and fertilizer used).   A
policy encouraging resource substitution would be more efficient in  improving
agricultural water quality; a policy to reduce pollution of irrigation
return flows, for example, would be more efficient if focused on such inputs
as water and nitrogen than if guided by a tax on crop production.

Input Taxes and Limits —

     Taxing or rationing those inputs which are responsible for  pollution,
rather than taxing the effluent directly, is a policy better suited  to
agricultural pollution abatement.  The need for identifying and  measuring
levels of emission by individual firms is eliminated.  If taxing or  limiting
input resources could bring the price of input resources in line with their
true social costs, then pollution would be reduced to the socially desirable
1evel.

     This policy alternative is practical only if the effluent results from a
limited number of inputs.  If there is only one input contributing to an
effluent, taxing it or rationing its use can be as efficient as  an effluent
standard.   If two inputs contribute to effluents (e.g., water and
fertilizer), then taxing or limiting only one input will be less efficient
than an effluent tax or standard.  Only by taxing or limiting both inputs in
direct proportion to their contribution to effluents will maximum efficiency
be reached.

     Uniform input limits or taxes applied across regions will not be
equitable if regional pollution problems and production methods  are  not
uniform.  Unless a variable input limit or tax system is used, trading of
input use rights should be allowed to equalize costs among regions or among
farms within each region.  In an irrigated river basin, for example,  the
responsible agency would  have to estimate ,the total amount of water  to be

                                    664

-------
used within the basin and then appropriately  reduce  the  amount  of  water to
each farmer.

     Throughout this discussion, efficiency and cost have been  described  only
in terms of total impact on the economy.  The  net  economic  cost of any
program is the sum of both its public and private  costs.  An  effluent
standard that reduces the income of  farmers but imposes  no  other costs  on the
public sector would have its costs measured in terms of  lost  farm  income
only.  A subsidy to farmers to affect pollution abatement would have  its  cost
measured as the level of the subsidy, since farm income  would not  be
decreased.  These two programs could achieve  similar results  at simialar
expenses, but with a completely different distribution of costs.

Zero Pollution

     Zero pollution is not a means,  but  an end.  It  is questionable whether
zero pollution can even be met in  nature, let  alone  under the conditions
imposed by an industrial society.  All human  activity alters  the environment
in some way.  Rules insisting on zero pollution are  not  generally  taken
seriously, because most people realize that there  is  little room for  economic
activity in such cases.

The Economic Optimum

     In a perfect world where all  effects and  all  costs  are measurable, the
optimum would be defined by extending pollution control  activities to  the
point where added expenditures for control are just  offset  by added
benefits.  This is a familiar rule in all of  economics and  it has  a common
sense interpretation:  keep doing  something as long  as it pays.

     In cases of nonpoint source pollution, the physical and  economic  data
for estimating the degree of optimal control  are generally  not  available.
It is not known whether one of the hundreds of polluting farmers could solve
the entire problem if he were to discontinue  all activities contributing  to
the problem.  Nor is it known whether a  10 percent reduction  in all polluting
activities would necessarily reduce  pollution  by 10  percent.  The  economic
optimum cannot be precisely determined.   Policy makers can  recommend  that all
farmers use best management practices in  order to  achieve an  acceptable level
of pollution control, or they can  set arbitrary standards and attempt  to
enforce these by laws, taxes, susidies,  or combinations  of  the  three.

SUMMARY

     U.S. agriculture is a highly  intensive industry  that uses  complex sets
of inputs to produce huge volumes  of foodstuffs.   The industry  has been held
up as a model of efficiency in other parts of  the  world.  Only  recently have
environmentalists begun to point to agriculture and  indicate  that  some
environmental problems may arise in  that  sector of the economy.  Nonpoint
source pollution from agriculture  could  be abated  by stopping agricultural
production or by reducing output to  extremely  small  levels.   It could  also  be
abated by generating a new class of  inputs that leave fewer pollutants  or
that are less amenable to transport  into  other areas or  into  common property

                                     665

-------
resources.  In any event, the structure of the industry would change  in
response to the change in rules about input use.  The new  rules would also
change the output mix of agriculture, the size and distribution of  income
within the industry, and the relationship between agriculture and local or
national economics.
                                     666

-------
                                  SECTION  2

                EVALUATING THE  INCOME  EFFECTS  OF AGRICULTURAL
                           NONPOINT SOURCE CONTROLS
     Many results of pollution controls,  for example  uncertainty  associated
with changes in production technology or  reduced  recreational  opportunities,
are difficult to measure.  In this  section, analytical  methods are presented
for the evaluation of those aspects of  nonpoint source  controls which  can be
quantified.  Detailed examples of some  analytical techniques  are  provided to
assist 208 planners in collecting data  and developing computational  methods
for evaluating alternative abatement policies.  The methodology described
herein is only one of the many that could be useful for policy analysis.   The
reader interested in alternative methodologies or a more detailed  description
of the planning methodologies presented  in this report  should  refer to the
main report which describes case study watersheds.  The original  reports  for
these and other case studies cited  may  be of assistance to water  quality
planners.

     This section focuses on the anticipated income effects of nonpoint
source controls on farm operators.  Generally, cost comparisons are made  at
the farm level, while recognizing that the final distribution  of costs  will
be determined by the cost-sharing policies implemented.  In addition,
abatement choices are based on short-term maximization  of profits,  constant
prices and do not account for the influence of non-economic objectives.
In sections 4 and 5 of this report, alternative evaluation criteria  are
discussed.

BUDGETING PROCEDURES FOR FARM MANAGEMENT  SYSTEMS

     The goal of the farm manager is to  allocate  farm resources among
production alternatives to achieve  an objective.  Typically the objective
used in economic analyses is the maximization of  short-term profits.   Other
objectives include maximization of  equity, or maximization of  the  present
value of future cash flows.

     The farm manager can measure his success in  maximizing short-term
profits using a number of farm budgeting  techniques.  Total farm  budgeting or
partial farm budgeting can be used  to determine the profitability  of existing
farm enterprises and, in addition,  the  net income effects of  any  planned
changes in farm activities.
                                     667

-------
Partial  Farm Budgets

     When determining the profitability of adding to an existing  farm  enter-
prise or purchasing new equipment, it is not always necessary to  do a  total
farm budget.  It is often adequate to look only at the farm practices  or
resource requirements which will change as a result of the change in
activity,  this type of budgeting is commonly called partial  farm budgeting.

     The following information must be collected to determine relative
profitability using partial budgeting methods:

     1)   additional receipts as a result of the change in activity,
     2)   reduced costs,
     3)   additional costs as a result of the change,
     4)   reduced receipts, and
     5)   the change in net profitability which is simply additional receipts
         and reduced costs less additional costs and reduced  receipts.

     In  the case of both total and partial farm budgeting the availability  of
time and labor to collect records and information will  limit the  precision
and detail  of the estimates.  The reader is referred to Castle  et al.  (1972),
and Osburn  and Schneeberger (1978), for a complete discussion oT~aTfernative
budgeting procedures.

LINEAR PROGRAMMING APPLICATIONS

     Comparing the cost of control practices for all crops on different  soils
and fields  can be a very time-consuming and tedious process.  A commonly  used
method for assisting in these types of computations is linear programming
(LP).  Linear programming is helpful in determining and comparing the
profitability of farm activities, and also in estimating aggregate  farm  costs
for different levels of environmental controls.  It is merely an  efficient
means of carrying out budgeting calculations described above.

     A base LP solution maximizes net farm income subject to  certain
restrictions on the amount of land, labor and capital available to  the farm
operator.  The resources available to the farmer should be realistically
represented by these constraints.  Much of this information may have to  be
collected in farm visits.  The information needs are exactly  the  same  as  for
farm budgeting.

     To estimate the cost of nonpoint source controls, constraints  are
normally added to limit edge-of-field losses or the amount of pollutant
delivered to water courses.  Since nitrogen and phosphorus as well  as  soil
erosion occur naturally  (see Section 2, Planning Manual) all  losses cannot  be
eliminated.  In addition, most conventional farming operations  require
fertilizer  inputs and cropping  rotations which will appreciably accelerate
erosion and the loss of nutrients.  Linear programming methods  are
particularly useful  in establishing the relationship between  loss levels  and
the income effects of associated  pollutant control measures.
                                     668

-------
     Activities included in the  LP model  should  be  chosen  to  reflect
realistic alternatives available to farms in the area.   The number  of  options
considered, however, must be  limited to prevent  an  unweildly  amount of
output.

     Most cropping activities will have a certain amount of sediment  loss  and
nitrogen and phosphorus losses associated with them.   In addition,  they  will
each generate a certain amount of income.  The linear  programming solution
will select the combination of activities which  maximizes  net farm revenues
subject to constraints on the amount of these losses which can be discharged
from the farm.

     In choosing resource constraints it  is  important  to define  what  is  meant
by sediment and nutrient loss and the cost of control.   Pollutant losses can
be estimated at the edge of field, edge of stream,  instream at point  of
discharge,, or downstream below the point  of  discharge.   Where specific data
are available to correlate edge  of stream losses to instream  loading  or
directly to water quality parameters, this approach is preferable.  Relating
instream pollutant load to corresponding  instream water quality parameters,
however, is very difficult; usually only  edge of field and edge of stream
losses can be considered in practice.

     As also discussed in Section 3 of the Planning Manual, the  control  cost
can be defined as simple installation and maintenance  costs of abatement
practices, changes in farm income, the public costs of technical  assistance
and administration or the regional costs  of  changes in the agricultural
product mix as a result of the nonpoint source controls. In this section all
control costs are defined as  estimated changes in farm income including  the
costs associated with installation and maintenance  of  the  practices.   Again,
this is an incomplete assessment of total abatement costs.

NON-UNIFORM NPS TREATMENT

     Brill _e_t al. (1976) and  Downey et _al_. (1976) have shown  that using
different leveTs" of treatment in different areas can decrease pollution
costs.  Although they observe that uniform treatment levels within  a  given
zone may have some advantages from both an equity and  an administrative
perspective, the zone designation would not  have to be geographic.

     Much of the methodological  development  of pollution control  strategies
has been associated with point source controls.  Nonpoint  source  controls  are
not as easily included in optimization methods.  This  is due  primarily to the
lack of estimates of existing pollutant discharges  and the associated  cost of
treatment.   Although such data  are generally not available,  some work has
been accomplished in studying the variable cost  of  erosion controls.
Schneider and Day (1976) and  White and Partenheimer (1978) have shown  that
the marginal costs of adjusting  to erosion controls vary appreciably  between
farms and between regions.  Using linear  programming techniques,  White and
Partenheimer (1978) imposed erosion controls on  twelve Pennsylvania farms.
The flexibility of the farms  to  change tillage and  cropping practices  to meet
the erosion controls strongly influenced  control cost.  Schneider and  Day
(1976) also pointed out similar  differences  between a  number  of Wisconsin

                                     669

-------
farms.  They also demonstrated that the marginal  cost  of  erosion  control  in
the eastern part of the state was much higher than marginal  control  costs  in
the western half of the state.  Miller and  Gill  (1976)  have  found such
differences between farms in different counties and  farms  of different  sizes
in Indiana.

SUMMARY

     The evaluation of nonpoint source controls  involves  effectiveness  and
cost calculations for one set of average conditions.   As  these  conditions
change, so do cost estimates, often with a  different variance.   For  example,
practice A may control more sediment than practice B for  a given  field  and
precipitation intensity.  However, a more intense rainstorm  may show practice
B more effective than A.  It may be that the greatest  pollutant losses  are
associated with  intense rainstorms and high  runoff events.  Thus  some
preference should be  given to practice A.   Similarly,  the  variance of cost
estimates will often  determine the cost-effectiveness  ranking of  practices,
particularly with those practices which have an effect  on  yield and
crop/livestock production.
                                     670

-------
                                  SECTION  3

               EXAMPLES OF DATA COLLECTION AND ANALYSIS METHODS

     This section demonstrates data compilation procedures  and evaluation
methods outlined in Section  2.  Many of the examples are drawn from  the
Honeycreek Case Study presented in the planning manual.

WATERSHED DESCRIPTION

     Information concerning  land use, slope, soils and crop/livestock
activities can be collected  from secondary sources such as  the U.S.
Geological Survey; aerial photographs, county soils data, experiment
stations, and census data.   However, some of the information may have to be
collected as direct field observations or  in farm surveys.

Sub-watersheds

     As mentioned in Section 2, it may be more cost-efficient to apply NFS
controls non-uniformly in a  watershed.  The criteria to sub-divide a water-
shed should be based on factors which are expected to change crop production
costs or soil/siope/topography factors which would influence pollutant
losses, the effectiveness of controls, or the extent to which fanners can
adjust to controls.  For example, the Honeycreek watershed  was divided into
four sub-watershed areas A,B,C,D as shown in Figure F-3.  Based on data
collected by the U.S. Army Corps of Engineers (Honeycreek Co-occurrence
Tables, 1978), the physiographic characteristics of each of the four sub-
watersheds are similar, thus it was expected that control costs would differ
less within sub-areas than between sub-areas.  Other sub-areas could have
been identified if additional data had been collected.  Characteristics which
might have been used to identify sub-areas include:

     11  The concentrations  of certain crop or livestock activities,
     2)  soil series,
     3)  drainage density, and
     4)  farm management systems.

Topography

     Slope and slope length  can be determined by a number of methods
including:

     1)  published inventories by the Soil Conservation Service,
     2)  sampling by soil  type or area using topographic maps, and
     3)  field sampling.
                                     671

-------
                                        \   ~
                                         l-;\
                                                   SCALE OF MILES

                                                 2034
                 Figure F-3.  Honeycreek Basin.
     Each of these methods has advantages and drawbacks.  Use  of  Soil
Conservation Service  (SCS) Conservation Needs Inventories  (CNI) and  similar
surveys provides estimates of slope and slope length using a  relatively  small
national sample (see, for example, CNI, 1975).  Although there is no
assurance that the soils sampled are in or near the study watershed,  these
estimates are based on field data which is the only accurate  way  of  measuring
slope length.

     Use of topographic maps (see Appendix A) (U.S.G.S., 1979) is another
method of deriving slope and slope length for the watershed  in question.
However, it has been  demostrated that this technique greatly  overestimates
field-checked slope length.  This is primarily due  to  the  fact that  the  scale
of U..S.G.S. quadrangles  (1:24,000) is too small to  indicate  natural  breaks  or
divisions in slope.

     Field  sampling is the most  accurate method of  determining slope and
slope length.   If the study watershed is nearby this can be  accomplished
quite easily with an  abney level and tape measure.  The  total  number of
fields sampled will depend on the number of  soil types or  soil management
groups,  and the desired  level of statistical  confidence  in  the estimates.
Samples of as little  as  2% were  used to generate CNI estimates.

                                     672

-------
Soli  Type

     One of the most  Important decisions  to make  In  evaluating practices In a
watershed is the grouping of soils  for  analysis.   Ideally  each individual
soil  type in the watershed  should be  treated  separately.   These soil  types
and their descriptions can  be found in  County  Soil Surveys.   The  detail  and
accuracy of these surveys varies considerably  between  counties.   For  example,
the Honeycreek watershed is included  in four counties  (Crawford,  Seneca,
Huron and Wyandote).  Crawford and  Seneca Counties have  up to date  soil
surveys with maps (Crawford, 1975 and Seneca,  1979)  while  Huron and Wyandote
do not (Huron, 1942).  From these surveys 44 different soil  types were
identified.  As will  be demonstrated  in the analyses which follow,  this
number of soil types  is too unwiedly  to work with  using  linear programming
methods.   Examples of criteria which  may  be used to  group  soils are:

     1)  Cropping practices and yield,
     2)  Soil drainage,
     3)  Soil erodability (k factor), and
     4)  Organic matter and soil nutrient levels  (Appendix A lists  the
         results of a survey indicating which  states supply  this
         information).

     A practical limit to the number  of soil  groups  which  can be  included in
the analyses is the anticipated number  of control  measures which  can  be
evaluated given time  and expense limitations.   Cropping  rotation, tillage
practices and structural control options  can  result  in hundreds  and even
thousands of possible control activities.  The  number  of man-hours  in data
preparation and the computational expense alone will greatly limit  the  number
of alternatives to be considered.

Livestock Numbers/Crop Area

     Often both state and federal agencies collect data  on livestock  numbers
by county.   In the  case of  Honeycreek,  two sources of  data were available:

     1)  U.S.D.A. census data indicating  livestock numbers by county  (Census,
         1978), and
     2)  A survey conducted by Ohio State University researchers  in the
         Honeycreek area (Venice Township, 1978).

     Such information must  then be  used to derive  livestock  numbers for  the
watershed in question.  For the Honeycreek case study,  the ratio  of livestock
to cropland area was  determined for the three  principal  counties  in the
watershed.  Total livestock numbers (Table F-l) were then  estimated as  the
county livestock density multiplied by the amount  of cropland from  each
county in the watershed.  Table F-2 indicates  the  breakdown  of livestock by
subwatershed areas.
                                     673

-------
TABLE F-l.   LIVESTOCK NUMBERS  FOR THE  HONEYCREEK WATERSHED
County
Crawford (Total #)
#/HA
Total # in
Watershed
Huron (Total #)
#/HA
Total # in
Watershed
Seneca
#/HA
Total # in
TOTAL/WATERSHED
Beef Cattle2
(#)
19,100
.193
2,672
10,700
.044
347
15,000
.112
2,759
5,778 .
(6,000r
Milk Cows
& Heifers
(#)
3,300
.033
457
4,600
.041
149
4,200
.031
773
1,379
(1,500)
Hogs3
(#)
57,448
.579
8,017
45,236
.399
1,466
50,740
.379
9,334
18,817
(20,000)
Area
Cropped
(HA)
99,190
113,360
134,000

1
 Approximately 93% of the watershed is in Crawford,  Huron and  Seneca  Counties
2,
  All cattle calves' - 'milk cows and heifers
 Number of hogs marketed per year (14% breeding stock, 2 litters/year)




 Limits used in linear programming model.
                                    674

-------
    TABLE  F-2.   NUMBER OF LIVESTOCK BY SUBWATERSHED,  HONEYCREEK


       Livestock1                        A         ^watershed        ^

                        (% of Area)   (14.5)    (25.8)    (41.6)    (18.2)
Dairy Cows
Beef Cattle
Hogs
217
870
2000
387
1548
2400
623
2490
5160
273
1092
3640
     Number  used  as  constraints for linear programming model
     Crop areas were estimated  as a  function of  relative  prices  and  the
extent of livestock activities.  For Honeycreek  approximate  areas  of wheat
and meadow were derived from census  data  (17% and 6%,  respectively).   Most  of
these crops were  fed to livestock.   The  remaining area  of cropland was plant-
ed to corn and soybean during the past few years.   Estimates were based  on
the assumption that the areas planted to  relatively  low valued crops such as
wheat and hay do  not vary greatly in the  short term, whereas the areas plant-
ed to relatively  high-valued row crops such as corn  and soybean  change yearly
according to price.

Irrigation Systems

     If the project area includes irrigation systems and  no  improvements or
demonstration programs have been constructed prior to  practice implementa-
tion, materials and installation costs must be obtained from other sources.
Reliable cost information for larger sizes of various  types  of canal  lining,
closed conduits and water control structures can be obtained from the United
States Water and  Power Resources Service  (formerly the Bureau of Reclama-
tion).   Fairly accurate and representative costs for smaller delivery system
components, as well as various  on-farm and drainage  improvements, can be
obtained from local irrigation equipment suppliers and manufacturers.

     To extend the costs to the entire irrigated area, it  is necessary to
collect information for the area concerning farm sizes, field areas,  lengths,
and widths,  field slopes,  lateral lengths and the area served by each
lateral, and canal and lateral  capacities and cross-sections at several
points  in the delivery systems.   To determine the types of on-farm improve-
ments that could be implemented, it is necessary to collect  information  on
infiltration rates, cropping patterns,  depth of top soil,   and localized


                                     675

-------
problems such as high water tables or soil fertility  levels.   Some  of  this
information can be taken from aerial photographs or detailed farm maps;  much
of the information, however, must be collected  in the  field  via  actual
measurements and personal interviews with farmers and  local  irrigation
company officials.

DEVELOPING CROP BUDGETS  IN THE STUDY AREA

     The basis of all farming enterprises is the cost  and  relative
profitability of crop/livestock activities.  As discussed  in Section 2  of
this appendix, each budget consists of the variable and  fixed  costs  of
producing a specific commodity.  In estimating  the cost  of NPS controls  a
partial budgeting framework is usually adopted.  Using this  approach,  only
those budget components which are influenced by NPS controls were evaluated.
The following budgets for the Honeycreek watershed provide examples  of  this
method.

Yield Estimates

     Total crop production and farm income are  directly  linked to crop  yield,
thus the estimation of existing crop yields and changes  which  may occur  with
implementation of NPS controls is very important.  Sources of  yield
information include:

     1)  actual field measurements in the watershed,
     2)  county soil surveys,
     3)  research data from experiment stations, and
     4)  farmer estimates in watershed.

In the Honeycreek example, yield estimates were based  on experiment  station
data.

Crop Expenses

     The principal source of information for the Honeycreek  budgets  were
estimates made by Ohio State University.  Tables F-3  and F-4 outline these
estimates for corn and soybeans for three different tillage  systems.

Livestock Budgets

     Crops can be either sold or fed to  livestock.  Thus a livestock budget
must include the  value of crops grown and  fed  on the  farm.   It also must
include estimates other  livestock expenses, such as housing,  manure  disposal
and  veterinary expenses.  Tables F-5 to  F-7 give examples  of the livestock
budgets used in the Honeycreek example.

ESTIMATING NPS CONTROL COSTS USING LINEAR  PROGRAMMING

     There are numerous  ways in which linear programming can be  used to esti-
mate the costs of environmental controls.   To  provide an example of one
approach, details of the Honeycreek LP solutions are  presented.
                                     676

-------
TABLE F-3.  CORN BUDGETS,  HONEYCREEK WATERSHED
                                        Corn
                                    Conventional
                  Corn
                Minimum
               Corn
            No-Tillage
Variable Cost

     Seed

     Chemicals
     Fuel, Oil, Grease
                     2
     Repair and Misc.

     Labor2


Sub-Total of Operating Cap.

Interest on Operating  Cap.

     Drying3
             4
     Trucking

     Fertilizer

Fixed Cost

     Management costs

     Machinery Deprec.


Total
 13.33



 11.00

 23.00

 20.00


 67.33

  3.73
 30.00
101.06
13.33



10.12

21.15

18.40


63.00

 3.49
27.60
94.09
13.33



 9.90

20.70

18.00


54.93

 3.04
27.00
84.97
Chemicals
     Atrazine

     Lasso
  4.00             4.00

  7.50             7.50

        Paraquat   2.38
                4.00

                7.50

                2.38

      Furaden   7.00
 Cost added in LP
 Source:  N.  Rask and D.L.  Forester,  "Corn  Tillage  Systems  -  Will  Energy  Cost
         Determine the Choice,"  Agriculture  and  Energy.  Academic Press,  Inc.,
         1977.   (Base Price =  Conventional Till, Base  price  x  .92 = minimum
2        till,  Base price  x .90  =  no-till.
.Drying Cost =  $.06 per bu.  Cost  added  in LP
 Trucking Cost  = $.01 per  bu.  Cost  added  in LP

 Fertilizer  function of yield  cost,added in  LP.  Nitrogen  (Ibs.)  = -110  + 1.876
 (yield).  P?0c (Ibs.) = 18.838  +  .333 (yield)  -  .335  (P Test)  K,0 (Ibs.) = 84.844
 + .25 (Yiel3)D+ 1.618 (CEC) - .33 (K Test)                     i

 Interest on Operating Capital.  9.5% for  7  m. = 0.554169
 Management  = $.10 per bu.   Cost added in  LP
                                     677

-------
            TABLE F-4.  SOYBEAN BUDGETS. HONEYCREEK WATERSHED

Soybean
Conventional
Soybean
Mi n i mum
Soybean
No -Till
Variable Costs
  Seeds
  Chemicals1
  Fuel, Oil, Grease2
  Repair and Misc.2
  Labor2
Sub-Total  Operating Cap.3
Interest on Operating Cap.3
  Trucking4
  Fertilizer5
Fixed Cost
  Management Costs6
  Machinery Deprec.
Total
13.00
30.00
89.71
13.00
27.60
83.08
13.00

 7.20
18.90
13.50
52.60
 2.50
27.00
82.10
Chemicals
  Lor ox
  Lasso
 7.50
 7.50
 7.50
 7.50
 7.50
 7.50
LChemical  - cost  added  in  LP  and  interest
2Source:   N. Rask and D. L. Forester  Corn  Tillage  Systems  -  Will  Energy  Cost
           Determine  the  Choice  in  Agriculture  and  Energy.   1977.   Academic
           Press,  Inc.   (Base  price =  Conventional  till,  Base  price x  .92
           minimum till,  Base  price x  .90 = no-till).
3Interest  on Operating  Capital  -  9.5% for  6 mo. =  .0475
^Trucking  cost  =  $.01 per  bu.   Cost added  in  LP
fertilizer function of  yield.  Cost  added in  LP
   P205  (Ibs) =  26.06 +  .555  (yield) - .355 (P  Test)
   K20   (Ibs) =  80.556 +  1.333 (yield) +  .75 (CEC)  -  .33  (K Test)
Management - 29.5 cents per  bu.   Cost taken  out  in  LP
                                     678

-------
            TABLE F-5.  DAIRY BUDGETS, HONEYCREEK WATERSHED
                                         Dairy1                Dairy2
                                          Cows               Replacement
Variable Costs
  Cone. Protein  (SB)                     41.00                 138.00
  Minerals                               14.00                   6.00
  Salt and Dicol                          4.00                   2.00
  Milk and Starter                      	                  36.00
Sub-Total Feed Cost3                     59.00                 182.00
  Vet. and Med.                          24.00                  15.00
  Breeding (DHI)                         27.00                  25.00
  Utilities                              26.00)
  Bedding                                20.00)                 15.00
  Misc. and Supplies                     20.00)
  Market Costs                           72.00)
Interest on Operating Capital            22.00                  47.00
Total Variable Costs                    270.00                 284.00
Fixed Cost
  Labor                                 270.00                 135.00
  Interest                               69.00                  95.00
  Cow/Calf Replacement                  215.00                 100.00
                                        554.00                 330.00

Total Costs                             824.00                 614.00

Production 13,000 #/cow, receipts $1683/yr
Replacement period birth to freshening, 36 mo.
3Corn/hay feed requirements accounted for separately as part of  farm crop
  production
kCow replacement = 0.35 x $614
                                     679

-------
TABLE F-6.   CATTLE BUDGETS, HONEYCREEK

Variable Costs
Feeder Steer
Purchased Supply
Vet. and Med.
Marketing
Utilities and Misc.
Sub-Total Feed Costs3
Interest on Operating Costs
Total Variable Costs
Fixed Costs
Labor
Replacements
Bull
Interest on Breeding Stock
Total Fixed Costs
Total Costs
Feeder1
Steers

315.00
37.00
4.00
5.00
3.00
364.00
26.00
390.00

16.00



16.00
406.00
Cow/Calf2


3.00
7.00
8.00
10.00
28.00
7.00
35.00

27.00
88.00
7.00
46.00
168.00
203.00
^050 Ib.  steer, receipts $577/steer

2
 Feeder calf and cull  cow, receipts $313


 Corn/hay feed requirements accounted for separately
                                  680

-------
TABLE F-7.   HOG BUDGETS,  HONEYCREEK

Variable Costs
Feed Supplement
Purchased Feeders
Marketing
Vet. and Med.
Utilities
Misc.
Interest on Feeders
Interest on Operating Capital
Total Variable Costs
Fixed Costs
Labor
Interest of Sows
Total Fixed Cost
Total Costs
Feeder
Pigs

12.84
45.00
2.13
1.50
0.75
1.20
1.43
0.60
65.45

4.50

4.50
69.95
Sow/2 litters2

288.00

22.00
20.00
30.00
45.00

19.00
424.00

198.00
18.00
216.00
640.00
 Finish purchased feeder pigs, receipts $96/hog

o
 Farrow-finish, receipts $1440/2 litters (includes partial  receipts from sale
 of sow, non-breeders and boars)
                                     681

-------






























_l
LU
o
i

Q.
_J
^f
LU


>•
LU
|
UJ
£
^™
s

CO
LU
5*
5
o
O
f~
IS)
UJ

f _f
_J

Q_
O
OC




CO
t
u.

UJ


H-






































£
C


i — 4->
O> •«-
Q. >

U
^
J_ C
o> o
£1-
0
a. «t













4_>


>P_
4-1
u




















o
o

CO



-o

JZ
CO
s~
01
fO
5
.a
3
CO
1

•X



=*==»=!*!=*:





_l —1 -1 — 1



<_3 CO O O
0 U- 0 Z
CO CO LU






in
i.
Ol



36 XJ O
O 0) 3 -c
u 01 o
t- O i.

S- 1- H- XJ
• r— Ol QJ OJ
ro Ol Ol Ol
O CO CO LU

o
c
r—
S-

4->
01
ce •
c.
• o
!- 4->
o> u
||
c
01
O "-
O -I-1
4-> O
in 01
>!a
•r- 0

*"" C
l|- -r-
O
-a
i. o>
o xj
•r— 1—
C O
S •--
1
_
	 1



3
=«= O

t/v







CM _l
UJ










in
i.
OJ



f^ , 	 .
fO
csj in

2 r-

CO S

ai
>
4J
U
01

JD
0

C


XI
r~

.^
4->
O
.=
0
S-
Q.

•*s •
U C
0 0
+-> -f-
ai u
> c
I] it-
i
OJ
_)

J_
ai M-
01 r—
in u

*<» V*


CNJ CM




UJ UJ













CO


ra i —
i/> ro

s_
OJ r-
4-) ro
CO t_>
i-
4J O
oi -a
az i — a>
OI T3
> 3
• C 01 .—
in o i — u

a>-M s_ .,-
> u o
0) C 4->
i— 3 -0 O
<4- 0 C

O OI 4-> C
•r- > Ol 5-
+J-1- E 3
U -U 4->

O ••-> -i-
0.0 0 •
3 OI
O ••- O -i-
S- S- 4->
U T3 Q. U
0> ro

o 3 o a.

S-13 S- r—
°.^ ° °
•r~ 'r— 4-i
C +J C C
£ ° s 8
1 1
r— CM
O O

Vi
S-
Dl OI
J= ±J J=

•to"* i—
^

OJ OJ ^~




LU LU 3







GJ

(0

O


T3 O> OJ


CO (/I
••- c
•r- 'i— o
U. O. O














•

.2
0
c
g

01
>

4->
O

•"-^
0

•r^







S





t3



X












ro




C


_O
Q
OO
>
'43
8

2
0

c


^
-a
3
u
•^

^
«r—
>
•^3
u
ro


O •
•i- C

3+3
XI 0
O C
0. <*-
1
ro





5 5





G G



1— Q
3 x
















i. ro



>,
^ ro
3£ 1C









in
CL
o

01
c

Ol
(O

i


>,_
o
(/>


•—
>


•
n

C\J



JS





<-)



X








X)
Ol
3
o

r~\


^_
ro


ro
^,
^













l/l
in Oi
Ol O
•i- in 'F-
S. C 4-»
O O O
en T- ro
Ol 4-> S-
4-> ro O.

U O Ol
Ol ra
a, a. r—
o o •—
r— S- -r-
M U 4->

ro ^~ ^1*


.

• ' '
II II II





5 J= J= S fe fe

vt v* «y»


[M CM CM CO CO CO




•K * * * * *
0. i— 0 0 _J 3
XXX 	 1 CO LU




XJ

X? XJ 4->
Ol O> C
3 3 ro
0 0 f-
r- i— Q.
Q. CL CO

Ol t~~ r— r— in
c 01 '"~ *n ro 01

S- ••- 1 i — ro
CL f~ o t3 c in

Ol 4J
ro ra ro C -Q ro
i, i- S— O O f
~ C£ 31 >- *—
ID J— Q- TD CO
CQ »— i CO CO O
2: o _i
>- ac o
o ex. co
CQ 5-

CQ

OJ
a> '—

-o c s- i. w
•i- OJ O 3 O
O O> -C Q. i—
•r- 0 Q.
-l-> S- CO C •—
Ul +J O S- -i-
O» 'r- JJ O O
Q_ ZZ Q_ O CO






































(O





0



or
••-3

CO










^^^



„

•t

•r—
• 	
682

-------























J

o

§
Q.
i

^j
UJ
UJ
o:

UJ
0
CO
t—
s
^f
at
\—
o
z:

y-
^£

0

Q_


^£

^r
^

cn



UJ

CQ
t—
£
C
ro
cu re
0. S-
>>+J
1— VI
0
CJ
II
CJl O
0 S.
S- U
0- =t



c


^

V)
c
o
CJ






l/l
4->

c
ro

^
cu re
o. s-
1— V>
c
o
o

11,
!- C
cno
0 S-
i- 0








c:
re
s-

V)
C3
o
o


1—
s:





02


o









c

o
CJ
cu
U


Q_



I—
s:






2




oo
00
o
	 1
— 1

o
00



c
o

VI
o
s_
QJ

• r-
O
V)


re
o
1—
£ SE
•^ \




c£ c±:


z h-
•^ <:
UJ UJ
CO 31
oo 3




c
fO
OJ +->
JD ro
>> <1J
0 J=
v) 3
cu 01
u o

s- £
0_ 0-
j_

U V)
^^ ^^





02 02




v^ 1 1
_l UJ
>-, UJ
S CO










3
p
.*: Ol
i— CU

E V)

c c
S- S_

cu cu
02 02
£
\ JZ




ce 02


>- 2:
•4 02
or o
o
1








>, re
re cu
JT S-
cu
o c
•r- S-
S- 0
Q- O
S-
cu
3 4->
O 4->
O T-
*-^ r—

CM
"


or: 02




CJ CD
cj o
CQ 3T
CO



l/l
Ol
O
jr

n-
o

It- S-
i— Q)
re 4->
O 4J

o
(J CM

C C
S- S-

cu cu
OL 02
re re
JZ -t~



CM CM
02 02


CQ (-;
O LJ
oo or
or 3





re
cu
s. re
re cu

c re
re
CU 4->
jo re
>-, cu
O JZ
00 3


Ol
o

*^





rv rv




CD >-
O ce

0
X
s:


V)
01 3
0 0
JZ 0

TO ^>
QJ ^_
,
re





4=






ce




u.
UJ
UJ
CO
X
s:


cu

4-)

re


it-
CU
S

lt-
o

S-


u c

t- <*-
O O

re 4->
s- o
<£ CJ
re 01
JZ ^^



CM on
02 02


02 H-
ro oo
O UJ
1— 0-
•Zi
o



V)
cu
cu o
S- -r-
3 4->
O VI
4-> CU
C 0.
8 n-
0
re
cu cu
s- v>




en en

••»*. ^s^





02 02




00 1—
O 0
3r a.
0.







l/l
3 E
i- 3
O ••-
JZ l/l
O- V)
v> re
o +-*
JZ O
o. o.

If- M-
o o

4-> 4->
o o
CJ CJ
1- 1—
z: £:



CM CM
02 02

41 ^c
~-~ Q
•1-5 UJ
•t- 00
oo ro
oo oo
o

00
JO JO
c c
o o
•r- O. T-
VI 3 VI
O O O
S- S- S- T3
CU Ol 01 CU

r— r— r— V)
•1- -r- -I- JO
O O O 3
OO l/l OO VI




en 01 en
^£ 3£. ^3£.





02 O2 O2




1- 00 \-
•— 0 O
2: or o.
OO 0- OO
ro oo ro







VI
3 E
C S- 3
CU O ••-
en jz i/i
O O_ V)
s- vi re
4-* O 4-*
•i- JZ O
C 0. O-

M- »*- H-
O O O

CU CU CU
V) l/l VI
ro ro ro














































CO
*
CJ
CO



VI
TO
cu

VI
s-

re
3

JO

oo


•»
s-
0
E
re
cu
s-
VI
1
o
1
ai
en
T3
cu
TO
"cu
1
o
1
cu
Ol
T3
CU
O
4J
O
0)
S-
TO
l/l
CU
re
cu
4J
c
re
s-

VI
c:
0
o


0
S-

c
o
CJ

c:
o

3

"o
a.


s-

F


0.
1
, 	
02

















01
C
TO
re
o


e.
re
cu
S-

V)



t - relates directly to availability of land, labor, and cap
p~
•r-
ro
s-

c/l
C
0
o

OJ
o

zt
o

0)
s-

E
re
lt-


s-

^


0_
1
CO
02
straint - relates to farm use of potential pollutants
c
0
o


o
S-

c
o
u

c
o

3


o
O-


S-
re
TO
c
o
o
cu
00
1
CO
02

o
i-
CL
01
S-
re
E
VI
re
JZ
o
3
VI
V)
S-
o
u
re
o
0
u
cu
0
l/l
Ol
re
Ol
S-
c
re
i.

1/1
c
0
o

cu
CJ
S-
3
O
l/l
01
s-
E
s-
re


s_
re
TO

o
o
o>
00
1
^j-
02

VI
o.
3
O
i-
01

4_>
C


O)
01
re
c



o
l/l

0






1 —
II
.,_








VI
cu

s_
o
Ol
Ol
4J
re

Ol
Q.
0
VI

CO






I —
II
••-J










VI

o


re

2

Q.
O
O




i —
II
_^;







(/I
CU
u

_!_>
(J
ro

O.

OJ
0>
rtS

^


^>



•


f—
II
,_

683

-------
     The evaluation of control costs in Honeycreek had three principal
objectives:

     1)  the estimation of changes in net farm income with the  imposition  of
         control practices,

     2)  the demonstration of methods for evaluating combinations of
         practices or control strategies, and
     3)  the linkage of each LP solution to a pollutant pathway control.

     The objective function used to estimate control costs for  the Honeycreek
case study maximized net farm income from all crop and livestock activities
for the entire watershed.

     Livestock and crop activities used in the Honeycreek LP runs are listed
in Table F-8.  As noted, some types of activities (L2 and C3) are associated
with a direct dollar return to the farm operator in the form of livestock  or
crop sales.  Other types of activities (LI and Cl) simply indicate total
livestock or crop production levels.  Of particular interest are the C2
activities which indicate the level of environmental variables  for different
LP solutions.  These variables include soil loss, nitrogen, phosphorus and
pesticide use in the Honeycreek runs.


Limits on Resource Use

     Constraints acting on the objective function limit the area available
for planting, livestock feed  requirements, and capital available (Table
F-9).  Generally, these constraints should be realistic estimates of avail-
able farm  resources.  From a water quality viewpoint, soil loss, nutrient
export and pesticide use are of interest.  Constraints determine the combina-
tion of activities included in the objective function.  The types and levels
of activities which produce LP solutions are the basis for estimating control
costs.
     Constraints on resource availability used in the Honeycreek  case  study
included typical farm  resources such  as  land  area,  livestock  numbers  and  the
area devoted to particular crops  (R2  constraints).  Soil  erosion  (Rl)  was the
primary constraint  in  terms of pollutant pathway control.   Use  of fertilizer
and pesticides as well as limitations on tillage practices  (R3) were  included
as secondary environmental constraints.

Parameter Estimates

     Income is generated from each L2 and C3  type activity  listed in  Table
F-8.  This estimated  income is derived from  the crop/livestock  budgets cited
in Tables F-3 to F-7.  Other LI,  Cl,  and C2  activities  are  simply production
or environmental variables of interest.  The  level  at which these activities
enter LP solutions  is  governed by the constraints listed  in Table F-9.
                                     684

-------
      For nonpoint source controls which do not influence yield, the relative
 changes in production costs are an accurate indicator of income penalties.
 Table F-10 lists differences in production costs for selected crop rotations
 and nonpoint source controls in the Honeycreek watershed.
TABLE F-10.   CHANGES IN COST ASSOCIATED WITH SPECIFIC CROPS OR CROP ROTATIONS
             GIVEN THE METHODS OF PRODUCTION
                          Up & Down
                           Plowing
             Contour
             Plowing
           30.5 M Spaced'
             Diversions
          61 M Spaced
           Diversions
Continuous Corn
                .1
     Spring plow
     Fall pi owl
     Minimum tillage
     No-tillage
 Corn/Soybean
     Spring plow
     Fall plow
     Minimum tillage
     No-tillage
Corn/Wheat
      Spring plow
      Fall plow
      Minimum tillage
      No-tillage
1
187.25
187.25
175.96
173.17
173.19
173.19
162.98
160.45
170.26
170.26
160.56
158.16
191.59
191.59
180.04
177.19
177.21
177.21
166.78
164.17
174.21
174.21
164.28
161.83
 Conventional tillage

 Diversions amortized at 9.5% for 20 years
284.78
284.78
274.96
272.54
272.56
272.56
263.69
261.47
270.01
270.01
261.57
259.49
238.18
238.18
227.50
224.86
224.88
224.88
215.23
212.82
222.10
222.10
212.92
210.65
Corn/Wheat/Meadow
Spring plow
Fall plow
Minimum tillage
No-tillage

175.17
175.17
165.01
162.79

179.23
179.23
168.84
166.57

274.28
274.28
265.44
263.51

226.75
226.75
217.14
215.04
      Rl and R2 constraints relate directly to available farm resources and
 pollutant losses.  The area of cropland available for each soil/slope com-
 bination was reported in Table 12 of the Planning Manual.   A statistical
 summary of the grid cell sampling procedure used to estiamte these figures is
 included in Appendex A.
                                      685

-------
     An important element of the return figures were yield  estimates.   Table
F-ll gives yield estimates used in the Honeycreek runs for  different soils,
management groups, and crop rotations.  These estimates were  based  on  county
soil surveys and experiment farm data.

     Estimates of soil erosion were made using the Universal  Soil Loss
Equation  (USLE) described in Appendix A (Equation 10).  For each  practice
evaluated pollutant loading estimates were made for combinations  of soil
group, slope category, crop rotation, and tillage practices.   Table F-12
provides an example of these calculations for the Honeycreek  watershed.
Comparable tables were generated for contour farming and  the  two  different
diversion spacings (30.5 m and 61.0 m).  In each case, a  total of 10 soil
groups were considered.

Localized Constraints

     Excessive slopes, poorly drained soils and shallow soils  limit certain
farming and conservation practices.  In Honeycreek, contouring, minimum
tillage and no-tillage were not recommended for soil group  8  because these
soils exhibit poor intrinsic drainage characteristics even  with subsurface
drainage  systems.  Terrace systems were not common to the watershed and
generally were not recommended for poorly drained or shallow  soils.  They
also did  not appear to be acceptable to cash crop farmers in  the  watershed
using wide equipment on the typically complex slopes found  in  this  study
area.

     Parametric LP runs are simply a series of solutions  with changing
constraint levels.  The Honeycreek solutions were generated from  an
unrestricted soil erosion level to increasingly stringent erosion limits.   A
typical run is shown  in Figure F-4.  Management controls  used included
tillage and contouring practices,  vegetative practices  included crop
rotations, and structural Controls included diversion ditches.

     Point A in Figure F-4 represents the base solution where  short run
profits are maximized while pollutant loss is not constrained.  As  losses  are
limited from 16 to 8  Mt/ha income decreases for vegetative  and structural
controls, while small increases in income are realized  for  the management
controls.  The small  income increase in this case is attributed to  changes  in
tillage systems which reduce production costs and have  a  favorable  tillage
response.  As soil loss is limited below 8 Mt/ha, income  effects  become more
severe for vegetative and structural controls.

     The  Honeycreek model has the  capability of constraining  the  use of
nitrogen, phosphorus  and pesticides as well as soil erosion.   Direct control
of  other  pollutant pathways such as overland flow and leaching were not
included  in the model but externally linked to the CNS model  described  in
Appendix  A.
                                     686

-------










^
LU
LU
cx
o
£j
z
o
^
Q
o
3;
1—
LU


S
_J
— 1
P
o

z
o
I—
«c
r—
o
ce

Q_
o
o:


"

g
ce
o

— i
o
CO

00
LU
)
g
t— |
GO
UJ
Q
	 1
LU
t-H
*"
O

CO
UJ
Q_
i
X
UJ

r-^

U.
LU
_J
CQ
c£
r—
•z.
g
-o
rC
«D
s: z:
^j
(O
cu
.c
3 LL.
C
o
CJ
CO




t-
z



+J
rO ^
,
0
CO


S-
 o^^*c\j CT» Ch^j"«$
oj ourN.,— ogtJOi — ojoOi — ogr-r— ojr*.
•ifc,* .^ *t "H—** X—^- >^-»
oj ojcn o Lor^. r— ^-ro co CMOJ co  inr-x o «a-co co OJCM co tocn
ro o^^j" o co CM oj CT»CJ^ co cr^^- co o^^f
CM OJOJ CMOJ OJr— CMr- CM

r— CMCh CO LOf^. O ^-CO CO OJCM 00 UOOS
CO CT>^- O COCM CM CftCn CO C?>«3- CO CT)^-

CM CMCM OJCSJ OJr- CMr- OJ


r— 00 COCO |--.r— COCO COLO
O fO COCM CO1^ COfO CO^"
COf— CMr— CMr— OJ< — OJr—


CM CO LOCO VOr- CMCO OJLO
COCO COCM r- ^J- COCO C0«tf-

COr— OJr- COi — OJr— CMr—
^OCO COCO Or- CMCO CMLO
nj-co ooj co** coco co«a-

COr— COi — COi — CMr- CMr—
^OCO COCO Or— CMCO CMLO
«3-CO OCM CO*3- COCO CO1*^
COi — COr- rOr- CMr— CMr—


OO CO^- COr- COO COr—
COr- CMr— CMr- CMr- CMr-


CMCM UOCM >JOr- CMr- CMCO
COr- CO»— r-CM COO COr-

COr— CMr— COi — OJ> — CMr-


*O,CO CO'* OCO CMr- CMCO
«tf-i — Oi — COCM COO COi —
COi — COr— COr- OJi — CMi —

"43CO CO^J- OOO CMr— CMCO
«^-r— Oi — rooj coo COi —
COi — COf— COi — OJr— CMr-
CM LO CO IJD >JO


^O LO LO LO LO
LO CO LO LO
 LO (JO LO LO

CM LO o% LO LO
Ol r— LO IO ^D
kO ^D *iO LO LO

CM LO CT^ LO LO

C -Q >> S. >) 0) >) f. >) 0 >« fc->^> S->,0)>,
O O -C ro O O ^— ro O O ^» ro O O ^^ ro O O r^ rO

-------
t—

s
o
rO

z: s
+J
fO
O)
.C
3 U.

C
0




H-



+J

et 01
:c -c:
1— -^
2: c

o
1 1 i t_}
1—
[


a
—J I—

£^_
c

.a *•
>)
o
-C.
c u-
o
U


OO


I—


c
c
o
•x.
in

c

• i- U.

c
0
C_J

CM
c/)




a.
0
S-
O

5-
3
i.
CJ3
r~
C
OO
CM
CM

CM

<^
CM
CM


CO

CM

2

CM

ro
ro

ro

vo


00
0
CM

CO

0
CM
ro


ro
ro
ro

vo
'"J
ro

O
CM
ro


C
CM
ro

'•O
v£>

t^>

CM




O






o

<*o










c
L-
*— >

VC
*o CM in i — in ^j- co
CTi ^- CM CO CO CO O

CM r- r— CMI--

VO CM CO in *j-
CT\ «a* r- co co
CM r— CM


cn ^^ r— . co co

CM r— CM

vo CM co m *j-
O"t ^~ I— . CO CO
• • • • •
CM r— CM

in CM co

• — CM r—

in (— v co
«3-  CM

r— CM r—

in r^ co
i — CM r—



co r— cy>
r— CM

cr> r*^ ^f
co 10 en
r— CM

in r-. <&
co vo cn
,— CM


in i— t ^~
co «p en
r— CM

"9"


ur>

^J-
co

in

^.
CO

in



^.
CO
in








c c
CU 4^ OJ ^^
^3 fD C -^ *O
O -C fU O C -C ra
CO 3 — (_J ^ 3 Z

r-
CD
CO

r—

fx^
*^
,_!


2

•—

CO

*~

CO
o

CM

c^
CM

CM
in
<^>

CM

in
CM



O
CM

O
CM
CM

in
«a-
CM


m
•^
CM

IO


•a-

r—




O






0

^










c
0
o

oo
o r-~c\?
r^ ro i —

VO CM

O CM
*"". "~I
CM


O CM
h^ i —

CM

O CM
, •
CM

S

1 —

^>
O

•—
^.
CO

r—

S
r-^



1^*


CM
CO


, 	
Ol
'


r—
Ol






























c
CD •*->
-O (O
O -c ie
t/^3 —


ur>
IN^

•—

CM
f^
,_!


CM
r^

i—

CM

•—

ro

CM

r^

,
CM
r-.
in

CM

r^
in
CM



10
CM

J>^
in
CM

r^-
m
CM


f^_
in
CM

U")
CM

LO

in

.


in


in



in

m










c
o


Ol
incM'iC i^ o-a-^
CO r— CO r- C7> VO CD

CM VD CM CM 1^

in CM CD o ^°
CO i — i — CD VD
CM CM CM


00 i— .O Ol VD

CM CM CM

in CM CO O «d-
co i— o crv vo

CM CM CM

co m in
CM CM CO

i — ro i —

co co in
CM CM CO

i— ro i—
co ro in
CM r— ro

i — ro i —

00 ro in
CM i— ro
r— ro i—



CD CM . —
ro i —

^f CO ^°
CD CM •—
CO i —

«!• ro r-
CD i — i —
ro i —


«sj- ro i —
CD r— !—
CO . —

O


VO

1*^
in

vo

in
CM





in
CM
VD








C C
CU •*-> CU -4->
J3 ro C -O ro
>) CU >> S- >j CU >>
O £ ro O O -C ro


O
z:
in

o

it-
CD

c
o

s-
cu
.^
-a
i-
o

4_1 (_)

£= v»-
•1-" in
(/) CM
CU CD

CU
si "o.
0> CL
•a ro

o































1
T3

CU


to

O
c
•p~
c
o
U

t-
o
<4-

, 	
CU
>-
" — •
	
CO
688

-------












LU
0
i— i
i


UJ

^C
_J
h-
Q
^

A
0
p-
ce
a.
s
4-5
.J1
a:
o
o
LU
1—

LU
0.
0
CO

o_
g
cc
CD


O
>-
CO
1 1 1
a.
o
	 i
CO
IT
|
a.
a:
o
U_
CO
UJ
t—
 co
O c-





vo o
i—


P**« ^3
00 CO
•—
VO 00
oo r^
i— CM



r- 0
VO «3-
i — CM

i— CM
CM 00
CO «3-
O vo
«• vo

in p^
CM 00
in px


Sin
cn
*!- VO

i— CO
o o
«3- VO

i— CM
oo P^
LO OO

CO CO
LO CO
CO O
r— CVJ

LO «3-
co in
CM CO


i — CO
0 O
«3- VO

i — CM
co r-.
LO CO

CO VO
cn ^~
CM cn


LO O
Px VO
, 	 r^
' '

r— CM




CM

VO
CO





-
CM


cn
vo
CM
Tl-
LO



CO
en
•a-

LO
cn
*
OO
CM
IF—
^
CVJ
VO
^~

in
CO
^

vo
i —
CO
r~
in
o
cn

LO
CM
<3-
•sf

CO
in
0
*

vo
CO
"~
LO
O
cn

LO
in
CM
•3-

en
el-
oo
CO

CO






cn co
O i—





vo o
i—


px co
00 CO
<-
VO 00
oo P^.
r— CM



1— O
vo «3-
i — CM

r- CM
CM 00
CO «3-
O VO
«3- VD

in p-x
CM CO
LO px


«!• in
vo cn
*j- vo

i — CO
o o
*t vo

i— CM
co PX
m oo

oo co
LO CO
CO O
i— CvJ

LO ^3-
CO LO
CM CO


r— CO
O O
«J- VO

• — CM
CO 1 —
LO CO

CO VO
cn ^~
CM cn


in o
px VO
i— P-


i — CM




CO

o
CM





CM
LO
•—


CO
cn
<-
CM
^f



VO
in
CO

CO
i —
i —
CM
cn

oo
vc,
^
1

CO
o

CM
cn
CO

cn
CM

CvJ
CM
0
CO

oo
(X,
CM

CM
cn
co

cn
CM

LO
co
CO
CM

£1
vo
CM

CO






i— VO





co r-»
r-


cn co
cn «t
<~
<— 00
CM CO



^- VO
CO Px
i— CM

CO r-
VO LO
CO LO
CO «!-
vo o
•* Px

,_ __
0 O
vo cn


CM cn
LO p-x

0 00
LO OO
0- VO

CO LO
o en
vo cn

co en
LO CM
LO CO
i — CM

CM CO
•3- i—
i — CM

o co
VO 00
*3- VO

CO LO
o cn
VD Ol

CM «3-
CO CM
"3- CM
r-r CM

O CO
CO O
i — CM

1 — CVJ




,-J.

CO





VO
LO
CM


LO
CM
CO
cn
cn
VO



in
o
vo

0

CM
cn
in
r~
cn

cn
1

VO
£

CO
f—
LO
1
g
, —
CM
CM
i
LO

S
vo


CO
LO
"~
CD
CM

CO
cn
CO


p-
CM
^.
•3-

CO






i— VO





co P~
1-


cn co
cn «3-
<-
t— oo
CM CO



§VO
p-
i— CM

oo i—
VO LO
CO LO
CO «3-
VO O
•* r-

__ ^_
0 0
vo cn


cn «3-
CM cn
LO Px

O CO
VO CO
«- vo

CO LO
o en
vo cn

co cn
LO CM
LO CO
r- CM

CM CO
«*• i—
i— CM

O CO
VO CO
"3" VO

cn LO
o cn
vo cn

CM *d-
00 CM
*3- CM
t— CM

O CO
CO O
i — CM

i— CM




LO

CM
CM





VO
VO
r-


r__
i—
CM
CO
LO
^f.



0
cn
CO

o
co
r-
CO
en

LO
r-.
CM
*~~

LO
CM
|

in
px
cn

o
^3-

CM
o
CO
CO

CM
o
CD
CO

LO
cn

CD
2:

CM
LO
r--
CO

LO
CO
CM

CO

•o
01
•j3
0
i_i
689

-------
          o-o

          iS
o
•o
re
OJ
        -p
        s
        c
        s-
        o
        o
        +J

        (O
        c
        J-
        o
        o
n
 o
oo
 i.
 o
o
         c
         s-
         o
J->
 c
 o
o
z
o
o
          o re
          i— O
          GO
         _ O-
                      i—  i—  csj    i—  i—   ro    '—  i—   c\j    i—   cvj^j-    i—  csjro
                               c\j
                               co
                                                     o^rooo    OLDO    omvo


                                                          1—   I—    r—   i—  CO    I—  r-  C\J
                      OtOOr-     ^-OCVJ
                      CT>^-CO     i—  r-.  i—
                                                     i—  r*»ro
                                                             CSJO^O
                                                             roooo
c\j   o  oo
n   o  n
                      i—  co  co
                      r—r—C^
                              5  S  3    5  3  S

                              CSI  CO  ^3    CM  CO  LO
                                                             to  ^o   r-..    to   r**  ^o
                                                             CO  CM   CM    CO   ^D  CM
                      *^voro     rococo    cococn
                      corN.ro     i—  r—  r-*    •—  i—   ro
                                                                       r->    P-.   o  o
                                                                       •—    «3-   r^  co
                                      CM<^OLO    CMPOtt
                      COi—  f—     <3-r*»r-*    •<*•  P--   VO    COOLO    COOO

                                                     *a-  vo   co    ^j-r-^t    ^tp^CM
                      CO  «d-  CO    CM  **•  CM    CM^-LO    O   <£>  VO    O^OCM
                               i—    LOCO^t
              •—   •—   o
              OOr—
                                                               r-    VD   CTt   CO    ^O   Cf»  VD
                                                      CTt-ctCO    Or--5t    Or—  VD
                                                                     OOCMCO

                                                                          r-CM
                                                                                     I—   P-  CO

                                                                                     r-   VD  i—
                                               CO
                                               ^-
                                                                     r^   O   o    r^s   O  co
                                                                          r-CM         r-  r—
                                                      COCT>O    r-CMCTl    r-CMP^
                      cotno    r^oo
                      OCTAVO    lOUOCft
                      ^£)   Ol  IT)
                               ,_



                      COCDO1
                                   r—  O

                                   r-CM
                                                  f*«.  r—    10  CJ^   P*»    ^O   CT>  LO




                                                                       ^r    CM   o  r**.


                                                  Lf>  CT»    CTt  ^3-    •      ...

                                                         •      •    •   LO    CO   CO  CM

                                                  r—  If)    CO  CO   CM         i—  CM
                                                          ^j-

                                                          CTt
                      LOCOUD
                      r-CMCO
                                              P**   VO  P"*    CD  r—  CD    CD  r~-   CO

                                              r-   CM  CO    CMCOt£>    CMCOLO
                      CMCOCO    CMCO^"     CMCOl^
                                                                            .

                                                                     Ol<3-CM
                                          ^-^-     ^o^-^j-    cocoto    cococo
                                          CM^t-     r-CMCO    r—CMLO    r-   CM**
                                               CO

                                               ^-
                      crimes
                        en   o
                                                                             r—  CM   UO
                      OCOCM    i—   r*N.^j-    i—  f*xcn    CMCOIO    CMCO^-
                      ^f   r—  IO    LOCMCO    LOCMi—    OOi*    OOO
                      COOi —    LOCOCM

                      r-CMCO    r—   CM  ^f
                                              LOCOCM    COf^-CM    COr^-

                                              r-CMCO    r—  CM   Lf)    r—   CM
                                                          CMCO    r—  CM   CO
                                                 690

-------
Figure  F-4.   Change in gross farm income for various  soil  loss  constraints
              Subwatershed A.
    320
    280
    240
 (T
 (E  200
    160
    120
                                 	-o-
EROSION CONTROL  TECHNIQUE

    A  Vegetotive
    •  Structural
    o  Managerial
                                I
                                        I
                                                I
       18        16       14       12       10       8

                                SOIL LOSS, MT/ha
Nutrient Loss Estimates

     Solutions to the  parameteric  LP runs provided input data for the  CNS
model to estimate solid  phase  and  dissolved nutrient losses.  Thus  soil
group, slope, crop, tillage  practice and conservation practices were used to
predict gross edge-of-field  losses of nitrogen and phosphorus.  Figure F-5
illustrates LP solutions  for limiting dissolved phosphorus in overland flow.
Again point A represents  dissolved phosphorus losses in the  unconstrained
case.  Although change in  crop rotations decrease runoff potential
appreciably, the cost  reflected by reduced areas in row crops causes
vegetative controls to be  less cost effective than contouring and changes in
tillage practice (management controls).
                                     691

-------
  Figure F-5.   Dissolved phosphorus loss in runoff from Subwatershed A for
               varying levels of return.
   z
   (E
   LU
   cr
340


320


300


280


260


240


220

200
                                                         Management
                                • Vegetative
           1100           1000            900           800

                    DISSOLVED  PHOSPHORUS IN RUNOFF,  kg/yr
                                                            700
SUMMARY

     Budgeting and linear programming are powerful and effective analytical
tools for cost-effectiveness calculations.  Pathway controls of various
pollutants can be directly related to farm income effects allowing  for the
ranking of practices.

     Because of the large array of practices which could be evaluated,
methods for grouping practices are desirable.  The categories  used  for the
Honeycreek case study, management, vegetative and structural,  are examples of
this approach.  By focusing on control mechanisms and crop production
impacts, indications of the cost-effectiveness of practices can be  gained at
this level of planning without the costly and tedious process  of individual
practice evaluation for each farm or area.
                                     692

-------
                                  SECTION 4

             CRITERIA FOR PROGRAM DEVELOPMENT AND  IMPLEMENTATION
GOALS OF FARM OPERATORS

     A common assumption of economics and the basis of the linear programming
calculations in the previous section is that each  farmer will  always  be
striving to maximize the net income potential from his resource base  which
includes land, labor, capital, and management.  The objective  of  income
maximization may, however, be constrained by other goals,  for  example the
desire for leisure, recreation, family vacations,  education, travel,  asset
accumulation, or a better tractor than his neighbor's.  Family needs,
windfall gains or losses, age, education, nonfarm  income,  equity  position,
risk aversion, and managerial abilities are some factors which influence
financial decisions on the farm.  Normal variations in yields, crop prices,
and factor costs will markedly influence the outcome of a  management  plan.
Thus, each farmer may respond in a different manner to pollution  abatement
incentives.

CLASSICAL STUDY APPROACH

     Classical applications of the profit-maximizing approach  to  agricultural
pollution control are usually constructed around single period models  of
"typical" or "representative" farms.  The applications generally  proceed in
two stages.  First, attention is devoted to the firm's production choices and
its rate of resource use per unit of production activity.  Production
activities that maximize net returns to land, overhead, and management are
selected subject to various combinations of inputs such as labor, fertilizer,
energy, and equipment.  A profit-maximizing plan is developed  without regard
to resulting environmental damage.  Third party environmental  spillovers,
e.g., sediment and/or nutrient losses from runoff  and deep percolation, are
considered only in a bookkeeping sense.  Estimates of gross outflows  of such
pollutants are made for the current profit-maximizing plan.  This first stage
analysis yields a baseline or benchmark solution for comparison with  later
(stage two) solutions in which alternative pollution abatement practices are
implemented.  Differences in net farm income compared to the benchmark
solution provide a measure of costs incurred to implement  such practices.

     The two-stage, profit-maximizing approach offers several  advantages
in the study of environmental quality control.  The approach is analytically
tractable since the tools and data required are generally  available,  and the
findings are readily understandable by policy makers and farm  managers.
In addition, the approach not only traces the impacts of alternative  control
measures upon farm income, but also identifies the source  of such impacts.

                                     693

-------
     The conventional approach may give inadequate recognition  to  factors
that contribute to the broad spectrum of farm types and sizes observed  to
exist side-by-side in a given setting.  All farms do not adjust to
constraints similarly.  Such economic considerations as financial  structure
of the farm, managerial objectives and capacity, farm size, legal
organization of the firm, tax treatment, and ability to bear risk may figure
prominently in the ultimate direction and  speed of adopting control
practices.  The role of these factors in decision-making and policy  analysis
is difficult to capture in static profit-maximizing models.  Many  of the
long-run goals and abilities of a farm may be overlooked when devising  a plan
that maximizes net income for a single production period.  The  potential
importance of some of these factors perhaps can be illustrated  by  an example.
Suppose a farmer is confronted with only two pollution control  options:  one
nonstructural  (e.g. different crop rotation), the other structural (e.g. new
irrigation system).  The static profit-maximizing model can evaluate, with
little difficulty, the nonstructural variable-cost practice.  It is  treated
much like any other variable factor of production whose effects do not  extend
beyond a single production period.  But the durable structural  practice
generates a flow of services throughout its useful life.  Moreover,  it
involves a substantial fixed cost or capital commitment.  Insufficient
consideration may be given to the farmer's ability to finance a large capital
outlay in providing a down payment or in carrying the additional debt
service.  Failure to incorporate tax considerations which are cost-reducing
only for capital expenditure items might underestimate the real  cost-effec-
tiveness of the structural practice.  Even if the structural practice is more
cost-effective as shown by the static profit-maximizing model,  financial
restraints may prohibit its adoption.  A faulty policy prescription  might
result.

     It may be that the modeling process does not adequately capture the
complexity of a farmer's goal structure, including nonfinancial  as well as
financial considerations.  Hence, the model may incorrectly measure  his costs
of pollution abatement.  At the worst, the ranking of control practices
recommended for the "representative farm" may differ from the order  in  which
practices would actually be adopted.  A less serious problem might be over-
or under-estimation of the financial costs of implementing a given practice,
with relative ranking of practices remaining unchanged.

     A substantial body of research exists on the adjustment and adoption
process of firms.  In most of the firm growth literature, greater  attention
is given to time-dependent resource allocation problems.  Firm  growth
research achieves this resource allocation objective by blending short-run
production theory with long-run theory of  investment and disinvestment.
Resources held fixed in the single period  setting, such as land or machinery,
are allowed to vary in the long-run dynamic models.  More attention  can also
be given to alternative goals, such as farm size, growth, and wealth
accumulation.

     A more dynamic analysis of control practices need not be concerned per
se_with growth strategies and the resource accumulation process, though such
concerns are not totally separable from the question of abatement  practice
adoption.  Rather, the objective may be merely to incorporate  into profit-

                                     694

-------
maximizing models that ability  and  intent  to  adopt  control  practices.   Of
course, every firm faces a unique set of circumstances that  impact  its
ultimate decisions.  On the surface, such  uniqueness  seems  to  leave policy
oriented research in a hopeless predicament.   Representative firm analyses
have definite limitations, but  the  suggestion  of  a  need  for  more dynamic
analyses is not an indictment of the representative firm  approach.   Such
analysis must be expanded, however,  to  encompass  a  "representative  cross-
section" of firms.   If the analysis  is  to  be  useful for  policy prescriptions
as well as for improved firm-level  decision making, an adequate measure of
response to pollution abatement incentives must be  developed for groups of
firms.

ALTERNATIVE FIRM OBJECTIVES

     There is a rather diverse  assortment  of  managerial objectives  throughout
commercial agriculture.  Such objectives differ not only  in  content and
ranking, but also in desired level  of attainment.   Four managerial  objectives
apart  from simple profit-maximization have been investigated by economists:
(1) maximization of  net worth,  (2)  maximization of the discounted present
value  of disposable  income,  (3) maximization  of utility,  with  net worth and
disposable income being rigorously  quantified, and  (4) maximization of
utility, including intangibles  related  to  the  quality of  life  and/or
community recognition.  Simple  profit-maximization models may  or may not
adequately capture these alternative managerial objectives.  However, these
alternative objectives are much more difficult to model than the single
objective of short-run profit maximization, which explains  the general
tendency toward usage of the latter approach.

Maximization of Net  Worth

     Perhaps the most common of the four managerial objectives  listed above
is maximization of net worth.   This  is  essentially  a  broadened concept  of
profit-maximization  over time,  in which the firm's equity is allowed to
expand.  Unlike the  simple profit-maximizing  approach, the  net worth
objective permits accumulation  both of  net income and of  wealth in  the  form
of durables like land and equipment.  This explicit treatment  of investment
generally renders the net worth objective  more appropriate  than short-run
profit maximization  in modeling the adoption of structural  pollution
abatement practices.

     Accumulation of investment and equity over time  raises  the important
question of an appropriate length (horizon) for the planning process.   In the
context of 208 planning programs, a relatively short  horizon seems  most
appropriate.  Policy makers are rarely  interested in  the  continuum  of
adjustments and growth throughout a firm's life.  Instead,  their concern is
with immediate adjustment prospects and impacts.  Likewise,  farmers
confronted with a decision as to control practice adoption  are  more
interested in the immediate issues of opportunity cost and financial
Accordingly, a five  to ten year planning horizon seems most  appropriate.
This time framework  coincides with most finance periods,  thereby enabling
linkage of annual production decisions with longer  run investment decisions.
Proper consideration must be given to the  time value  of money,  and  the

                                     695

-------
present value of net worth must be maximized through time.

Identifying Farm Management Goals

     Incorporation of goal structure into an analysis of pollution control
practice adoption (i.e., multi-dimensional utility analysis) is by far the
most conceptually appealing approach.  Both tangible and intangible goals
unquestionably strike at  the heart of individual firm behavior.  Policy
makers, however, need broad guidelines to analyze the question of control
practice adoption, not firm-specific analyses for individual farmers.  The
infinite variation in goals and goal ranking associated with individual
management decisions is completely impractical  from a policy-adoption
standpoint.

     Of the two more tractable objectives, maximizing net worth and
maximizing disposable income, maximizing net worth appears  to be the best
cumulative objective.  The importance of disposable income must not be
ignored though.  Its influence on asset accumulation can be profound.  It
must be treated realistically within the framework of maximizing net worth.

     Many behavioral  differences among producers can be incorporated in  a
model.  Differences in resource requirements, capital structure, etc.
interface with the postulated objective to collectively influence adoption
patterns.  Operator age,  for example, can play an important role even within
a common objective of maximal net worth.  A young operator  trying to acquire
initial resources most likely will exhibit a preference toward different
control practices than an older operator approaching retirement and concerned
with disinvestment of his holdings.  Similarly, the operator's reaction  to
risk may differ with age.  Incorporation of a suitable time horizon, and
consideration of financial liquidity, can capture many of these differences.

     When economic models are used to rank and choose between pollution
abatement alternatives, the decision must be made whether to use an
analytically simple profit-maximizing objective or more complex objectives.
Certainly the answers provided by a carefully designed, single period,
profit-maximizing model will be superior to those derived without a
quantitative method of evaluation.  Cost estimates associated with
alternative abatement programs are also generally adequate  for aggregate
planning purposes.  The recognition of the more complex managerial objectives
of most farmers is instead an appeal for flexibility in adoption of pollution
abatement programs.

MAJOR FARM CHARACTERISTICS

Financial Structure

     Implementation of  specific control practices, particularly structural
ones, depends not only upon  their impact on net revenues and net worth,  but
also on the magnitude,  structure, and liquidity of a farmer's assets and
liabilities.  Thus, the financial structure of  the farm is  a critical
consideration in determining the ability  to adopt a particular technology.
Control practices can be  adopted via retained cash earnings, credit, lease,

                                     696

-------
or even reduction of debt.  The extent to which these sources of  finance  are
available to a firm effectively limits the number of relevant pollution
abatement practices.  Cash flow becomes an overwhelming consideration.  Such
flow is not normally incorporated into traditional, single-period profit-
maximizing approaches, but is essential to short-run net worth  studies.

     The long run aspects of investment decisions may significantly  impact
analyses of environmental technology adoption.  Of specific  interest is the
internal and external flow of funds.  The ability to secure  necessary  down
payments for the purchase of structural control devices, the ability to meet
annual  obligations including household expenses and repayment of  loans, the
ability to purchase annual operating inputs, and the maintenance  of  liquidity
of assets all influence a manager's decisions to adopt pollution  abatement
practices.

     An additional financial consideration of potential importance to  the 208
planning process is the length of repayment period for debt  capital.   Short
and long term debt capital availability may reflect different loan limits and
interest rates.  Nonstructural/labor intensive practices, which can  be
financed out of short-term operating capital loans, may also receive
perferential interest rates, thus creating a bias toward such practices.
This preference might be further accentuated by greater ease in obtaining
short-term credit, or thwarted by modifying the capital costs of  structural
investments.

Tax Structure, Legal Organization, and Farm Size

     Effective tax management is an increasingly important consideration  in
the adoption of agricultural technologies, including pollution  abatement
practices.  Decisions to incur large capital expenditures on abatement, in
contrast with nonstructural  short term methods of control, cannot be divorced
from tax implications.  Significant tax savings can be realized on long-term
capital outlays, such as structural control practices.  Resultant after-tax
profits may differ significantly from before-tax  profits, thereby influenc-
ing the cost-effectiveness of alternative control measures.

Tax Management Strategies —

     Three tax management objectives which should be considered in an
evaluation of the cost-effectiveness of environmental quality control
options are:  (1) reduction in actual out-of-pocket costs, (2)  deferment  of
income taxes, and (3) conversion of ordinary income to capital  gains.  The
conventional economic approach often fails to address the impact  of  tax
management strategies on the adoption of control practices; expenses are
treated in a uniform manner, simply as offsetting revenues.  Little  or no
consideration is given to reductions in tax burden which reduce the  real  cost
of a particular practice.  Unlike control practices involving only variable
costs,  capital  expenditures may be subject to preferential tax  treatment  in
terms of deductible expenses, and/or special credits.

     The conventional profit-maximizing approach also fails  to  capture the
benefit from managing income flow between years; potential benefits  from  tax

                                     697

-------
deferral and conversion of ordinary  income  to capital  gains  income  are  over-
looked.  By deferring Income tax from one tax period to  another  through
accelerated depreciation methods,  for example, short term cash availability
is increased.  Thus, tax deferral  can contribute  to liquidity in  early  (and
often critical) cash-flow periods.   The currently available  20 percent  first-
year depreciation that may be applied to new or used business assets with  six
or more years useful life may also ease potential cash-flow  difficulties  and
reduce the actual cost of structural practices.  A maximum bonus  deduction  of
$4,000 may be claimed in a given year for joint (husband and wife)  returns,
or $2,000 for single returns, corporations, or partnerships.

     Investment in most depreciable  property with a useful life  of  three  or
more years, which includes most structural  control devices,  is also eligible
for an investment credit.  In contrast with depreciation expense  deductions,
an investment credit reduces tax liability  directly.   In other words, a one
dollar investment credit offsets one dollar of taxes.  Currently, the maximum
investment credit rate is 10 percent of the qualifying amount.

     The following example illustrates the  combined tax  advantages  that can
be realized from a structural control practice.   Suppose a farmer purchases
a $70,000 center pivot irrigation  system.   The combined  tax  savings from
investment credit, double-declining  balance depreciation, and bonus first-
year depreciation are computed in  Table F-13 assuming  a  $10,000  salvage
value, a 10-year useful life, and a  40 percent marginal  tax  bracket.  The
present value of the tax savings totals $26,020,  based on a  12 percent  dis-
count rate.  This figure represents  over 37 percent of the $70,000  cash cost,
or 43 percent of the cash cost less  salvage value.  Tax  implications thus  can
be extremely important to adoption or nonadoption decisions.  A  farmer  paying
little or no taxes, on the other hand, would derive no incentives from  tax
considerations.

     Pollution control practices that enhance the value  of the farm over
time, whether structural or nonstructural,  further benefit from  special tax
treatment.  Conversion of ordinary income to capital gains income realizes
a greatly diminished tax liability,  for the capital gains tax rate  is rarely
more than 40 percent of the ordinary income tax rate.  This  special  treat-
ment, however, is rarely considered  in aggregate  policy  models.   Planners
should observe this additional tax benefit when computing farmers'  costs  of
adopting various pollution control practices.

Farm Size--

     The benefit derived from alternative tax management strategies (exclud-
ing investment credit) is dependent  upon the level of  farm income.   One
factor associated with greater income is farm size.  Resource availability,
often varies directly with farm size.  Given our  progressive income tax
structure and regressive treatment of expenses, larger farms typically
benefit more from available tax advantages  than do smaller farms with less
income.  Consider,  for example, the  after-tax cost of  one dollar of expense
on high and low  income tax brackets.  The after-tax cost in  a 70 percent  tax
bracket is only 30 cents, whereas  it is 70  cents  in a  30 percent bracket,  and
one dollar if no taxes are being paid.  The impact is  clear; costs  of control

                                     698

-------
practices may differ by farm  size.  Because of  tax  structure, more  costly
(before-tax) practices may  in fact be more cost-effective on an  after-tax
basis for large farms.

     Capital-intensive control practices may be more attractive  to  larger
farms for other reasons.  Large, capital-intensive  farms may view labor-
intensive control practices as unacceptable because of  tight labor
constraints or managerial difficulties.

     Incorporating these size dimensions into analytical models, 208  planners
will be in a better position  to evaluate alternative policies.   However 208
planners must also recognize  that weak equity positions  (large debts) may
discourage additional capital investment, and that  income prospects may be
uncertain; both condition the extent to which tax advantages may be
realized.  A large debt/equity ratio may prevent additional capital
expenditures for want of a  down payment.  Tax deduction  benefits are  also
greater to the high equity  farmer than to the low equity farmer, other things
being equal.  Regardless of the tax advantages, the potential after-tax
income remains of fundamental concern, not the minimization of taxes!

Legal Organization--

     A final consideration  in assessing the role of income  taxes on the
adoption of environmental control practices is  the  legal organization of the
firm.  Though single proprietorship remains the dominant legal organization
in commercial agriculture,  incorporation is becoming increasingly more
prevalent.  Apart from the  legal benefits, like sheltering  personal assets
from extensive liability, corporations also enjoy special tax treatment
unavailable to single proprietorships.  This differential tax treatment comes
in a variety of forms; most important are different statutory tax rate limits
and the ability to shelter  income.  Corporate tax rates  are relatively
constant in contrast to the progressive individual  rates.   Corporations face
a maximum tax rate of 46 percent at present, whereas single proprietorships
are taxed at a maximum rate of 70 percent.  Corporations also can shelter
income from taxation by retaining earnings.  Each of these  factors  can
influence the adoption of pollution abatement practices.

RISK AND UNCERTAINTY

     Regardless of the type of control practices under consideration, an
important factor affecting  adoption is the uncertainty which producers
perceive as being associated with the practice.  Planners should recognize
that individual producers are likely to exhibit widely varying perceptions of
the risk associated with different control practices, as well as varying
abilities and desires to bear perceived risks.

     Four main sources of risk and uncertainly Influence managerial decision-
making In agriculture:  (1) changes In technology,  (2) changes In the legal
and Institutional setting,  (3) yield variability, and (4) price  variability.
Changes in technology contribute to a farmer's uncertainty  in that  the
ultimate impact of new technology upon the entire farm production system is
unknown.  Lack of familiarity with some pollution control practices may be a

                                     699

-------
problem.  Thus, until control practices have been widely applied  in
commercial agriculture, farmers can be expected to favor those practices with
which they have greater familiarity or which they preceive to have little
potential for adverse impact on the production system.

     Institutional and legal risks are becoming increasingly important
considerations to agricultural producers.  Decision-makers face considerable
uncertainty regarding the nature and extent of future environmental  improve-
ment requirements.  The only certainty in this regard is the inevitability  of
more stringent environmental controls, but the degree of improvement and the
method(s) implemented remain uncertain.  The 208 planning process should
strive to minimize risk associated with institutional instability by adoption
of widespread, relatively uniform and stable standards and/or approaches to
pollution abatement.

     Yield variability in irrigated agriculture typically poses less risk
than for dryland agriculture.  The perceived risk of control practices  on
irrigated crop yields may be heightened, however, because of the  generally
higher yields from irrigated fields.  This source of perceived risk  is
closely linked to the risk of technology changes.

     Price variability perhaps poses the greatest source of risk  to  farmers.
Its impact on the adoption of control practices may be profound;  the degree
of impact will depend upon crop types and the individual-grower financial
situation.  Cash flow problems, for example, can become severely  aggravated
by price fluctuations.  Managers possessing limited liquid assets may tend  to
associate a high risk with capital intensive practices as opposed to
nonstructural  practices.  The latter may be favored from a standpoint of
reduced financial risk.

     The role of risk in the adoption of pollution control practices needs  to
be incorporated directly into analyses of cost-effectiveness.  Incorporation
of risk management behavior  in the evaluation of controls could strengthen
the 208 planning process.  Such efforts would better portray control practice
cost-effectiveness.

SOCIOLOGICAL DIMENSIONS

     The adoption of control practices is not exclusively an economic
problem; a variety of sociolgoical factors also contribute to the ultimate
behavior of decision-makers.  Ethnic, educational, and communication
factors are involved in the  transfer and adoption of new technologies.
However, incorporating sociological dimensions into economic models  is
difficult at best.  Perhaps  the best that can be hoped for is to  have policy-
makers, e.g., SCS and ASCS personnel, which are sensitive to some of these
factors.  Formal negotiations with individual farmers might be enhanced by
such knowledge.

CONCLUSIONS AND IMPLICATIONS

     The maximum-profit approach  to evaluating cost-effectiveness of pollu-
tion control practices focusses attention on tradeoffs between pollution

                                     700

-------



,
UJ
_l
co
=3
O
o z:
UJ
Q 1-
Z. OO
00
<\
•z. •z.
o o
t— 1 (—1
1— t—

^C |~~|
LU Q.
>- 1
OL
h- LU
OO h-
CtC Z
Lu C_>

oo o
r> o
•z. o
o «
03 O
r^.
« ^j-
I—
i— < ^c
Q
LU Z
a; o
O
~^
h- 0
Z i-t
LU 1—
SI <
U— I-H
00 O
LU LU
> C£
Z 0-
l— l LU
O
2:
O —1
i-V c£
Lu ^)
Z
00 Z
CJO ^t
z
i— I LU
=> 0
«-C z
co <;
— i
X =C
•^ CO
h-
CO
Q Z
1 1 1 i— i
t— < i— i
CO —1
2Z C_)
O LU
C_> Q


•
OO
1—
1
LU

LU
	 1
CO

c re
w CU CO
to 3
0) i— X
s_ re re
a. > H-






•a

O>
•r—
X >
rO fO
h- 00



O
C
o

•4-*
fO
,r_
r— O
ft} QJ
3 S-
C Q.
C CD
=1 Q


fi
C
0
S- -r-
re 4-^
O) re
>- -r-
o
to +-> o>
3 co S-
C S- CL
O -i- O)
CQ Lu Q





4^
c~
CD
E re

tO *r—
CD T3
> 0)
C S-
l—i O







r— CU
re +->
c re
•i- o;
01
t- X
re re
2: h-












S-
ci)
>-

o o o  CM CM
co r»» 10 en
CO CO CM i—


•be-






o o en co
co CM r^ o
co CM co r-
co ^- oo CM
f—

•^o-








O O CO CO
O V£5 •* LO
CM LO *fr r~-
co o co vo
^— r~

•bO-








O
CD
CD

^j-

^/^.








O
O
o

f^

-t/^










0000
















O i— CM CO


LO o co en CM co
»a- vo •— t*» LO en
tt r— i— o co en
pv. co o o r*- r—
co en r*^ LO i — o
i— UD
CM

oo






co o ^~ r^» o vo
vo co co o co en
r— r^ co i — ^~ en
CM i— i— i— O
CO

•feO-







14^
r^* LO CD co ^j~ CD
CD CSJ co co r^« CD
^- co ^~ r^* o o
LO «* CO CM i — CO
LO

•(/}








O
o
CD

^f-

co








O
o
o

r>^

•t/>










O O CD O O O O














	 1
di
1—
<^- LO CO l~^ CO CTt O O
•— h-


























.
CO
c
s-
3

O)
i_
CD
+J
re
S-
o
CL
S-
o
u

^
o

o
o
o
WS
CO


*v
c:
s_

4_)
O)
i-

^_)
£=
CD •!-
O 0
o ••->
v^
r^^- re
^^
sz
II O

CD "O
O CD
O 3
O
CD i —
r-. i —
*/> re
X CO

o """

•i—
E
CO -i—
re i —

*O CD
CD O
+-> 0

CL ^-
E •co
o
CJ et
re -O

















.
- — »
o
o
o

^^J-
•t^>

1

o
o
o

o

I/O
s"~'
co

CO
re
-Q

"O
CD
+J
CO
^

•^3
re

O)
-EI


O


-Q
CD

, —
CL
CL
re

Ol
0
£Z
re

re
-CD

o>

•, —
c:

, 	
u
CD
1
CD

JD
^3
O
•^

C
o

"O
CD
CO
re
CQ
o



co
CD
E
'43

CD
+J
re
s-
X
re
4_)

r-~
re
c
'D-.
s-
re
F^

CD

.u>

C)_
0

4_>
(_>
Z3
O
o
c_
CL

CD

4_)

CO
3

CL

, —
>,
i —
C
o

S-
re
O)


1 1
CO

., —
^ —
^ 	

^_)
>, —
T3
CD
l_
U

4_>
C
CD
E

CO
O)
>
.^

CD
c~
4->

CO
re

ID
CD
+->
^J
CL
E
0
CJ
-a







































•
c;
o

-tJ
re

u
CD

CL
Ol
-a

	 ^
>,

j—
o

S-
re
CD


^_)
CO
S-
•i —
^_
^ 	 .

CO
^3
^
O
-Q

TD
C
re
l 	
re
=3
f—
C
re

<4-
o

E
Z5
CO

CD
£





•
i-
01
>^

II

C
T3
C
re

CNJ
r—
•
II

• r—

Ol
1-
ai

3

n
c
i
^ — .
•i—
-4-
«. —

X

CO
O-i
c
•r—
>
re
co

X
re
4_j

CO
re

~C3
CD

^3
O
E
O
o

. r*
Ol

re


^ 	 >
c:

o
CJ
CO
•r^
T3

^_>
C
CD
O
s^
01
CL

CM
i — .

re

CO
O)
d.

CO
CO
0>



































































01
=5
( 	
(O


Ol
O)
re
;>
, —
re
CO
o
o
o

CD
( —
C/")

fO

(/I
O)
f-
^3
CO
CO
M-
701

-------
abatement and economic efficiency.   Insufficient attention may  be  given
to the complexity of economic incentives influencing adoption of various
control practices.  The static maximum-profit model does  not  address  dynamic
factors that contribute to adoption or nonadoption decisions.   Such static
models provide only a partial guide to the technological  adjustment process.
Relative efficiencies of structural and nonstructural control practices may
be inaccurately assessed, and policy options may be overlooked  or  even
misdirected.

     Reformulation of the maximum-profit model to address time-dependent
resource allocation problems appears fruitful In the future.  Such
redirection Including variations  in  interest rates and  value  of the dollar,
liquidity of assets, debt/equity  ratios, etc., may better reflect  the
practice adoption process.

     Managerial objectives,  financial situation, tax structure, and risk  and
uncertainty can each impact  a firm's adoption motives.  Although firms will
differ in response, even in  comparable production settings practicality
limits the extent to which such differences can be investigated.   A limited
set of scenarios can be developed  to characterize different  groups of
adoption motives.  Firm size and  financial situation seem most  important  in
this regard, for they condition the  firm's treatment of risk  and uncertainty,
and its tax situation.  Policy-makers should recognize  that  the age of the
farmer can play an overwhelming role in adoption or nonadoption of practices,
depending upon the current stage  of  the individual's investment/disinvestment
career cycle.  Preoccupation with  the myriad of alternative  managerial
objectives seems less rewarding,  however.  Maximizing the discounted  net
worth of a firm is a promising alternative evaluation model,  though it may be
difficult to accurately obtain.
                                      702

-------
                                  SECTION  5

                          IMPLEMENTATION  INCENTIVES
     Pollution abatement activities must generally be  accompanied  by  some
incentive for their adoption.   It  is theoretically possible  to  legislate
standards that must be met under threat of fine or imprisonment.   This
procedure has been followed with respect to most  industrial  pollution
problems.  Most people agree, however, that similar incentives  would  be
difficult to legislate and to implement with  respect to  the  nonpoint  source
pollution problems of agriculture.  As an alternative, it  has generally been
decided that "voluntary" agricultural pollution abatement  will  be  achieved
only if accompanied by sufficient  subsidies to offset  farmer costs.

THE FEDERAL WATER POLLUTION CONTROL ACT

     The Federal  Water Pollution Control Act  Amendment of  1972  (PL  92-500)
and the Clean Water Act of 1977 suggest that  water resource  development,  land
use planning, and environmental policies be coordinated, integrated,  and
updated in a continuing planning process.  This process  is  required by each
state, both for "designated" and "nondesignated"  areas.  Designated areas are
discrete urban-industrial communities, where  the  principle  focus of the
planning process is to coordinate  nonpoint and point source  waste  disposal
controls.

     Section 303 of PL 92-500 requires that each  state adopt a  continuing
planning process that is consistent with all  provisions  of the  Act.   This
process is designed to insure that the initial plan formulated  under  Section
208 remains effective under changing environmental conditions.  Section 304
(k) (1977 Clean Water Act) further authorizes the Administrator of EPA to
enter into agreements with other federal agencies to utilize their
authorities and programs to support the development and  implementation of
state and local  water quality management plans.   This  section recognizes that
implementation of many state and local programs is dependent upon  the
expertise and support of other federal agencies.  Traditionally, most
agricultural programs have been either production or conservation  oriented,
but rarely both.  The extent to which past production  and  conservation
practices will become "best management practices" is a subject  of
considerable current debate.

THE PRESENT (ACP) INCENTIVE SYSTEM

     The Agricultural  Conservation Program is authorized in  the Soil
Conservation and Domestic Allotment Act approved  February  29, 1936.   The
original Act has been amended and  supplemented by the  Rural  Development Act

                                     703

-------
of 1972 and by title 10 of the Agricultural and Consumer  Protection  Act  of
1973.  Funds for the program are authorized annually by the Congress.
Originally, the ACP offered payments for  land use and/or  production
adjustments in addition to conservation measures.  Since  1944, however,  its
assistance has been limited to conservation measures which  farmers  generally
would not be likely to carry out without  cost-sharing aid.

     The 1979 Agricultural Conservation Program, as designed  by the  ASCS and
submitted to the Secretary of Agriculture, emphasizes enduring practices for
soil  and water conservation and/or environmental problem-solving on  privately
owned agricultural land.  The national program will authorize only  those
practices that meet Congressionally mandated objectives.  They include wind
and water erosion control, water conservation, nonpoint source pollution
control, forestry and wildlife enhancement, and rural clean water goals.

     Initially, emphasis  of the national  program will be  on water quality
goals.  A substantial national reserve will be established  to fund  specific
project areas for water quality improvement, and for special  purposes,
including small fanner demonstrations.  The President and Congress  have
generally agreed that the ACP should:  (a) solve nonpoint pollution  problems
for agricultural lands, (b) help achieve  rural clean water  goals as  expressed
in environmental protection legislation,  (c) help conserve  scarce water
resources, (d) control pollution from animal wastes, (e)  control erosion and
sedimentation on agricultural lands, and  (f) help assure  a  continuous  supply
of food and fiber.  Only  practices that primarily contribute  to these
objectives will be offered for cost-sharing.  In accordance with past
Presidential directives,  the emphasis upon using the ACP  primarily  for soil
and water conservation and pollution abatement programs will  likely  be
continued.

     State and county committees in conjunction with development groups  will
determine individual practice cost-share  percentage  levels.   National  guide-
lines provide that percentage levels may  mot exceed  80  percent of actual
cost.  A higher level may be approved, however,  for  practices in special
project areas or for other practices which would not be followed without
increased cost-sharing.   Cost-sharing rules change slightly over time,  and
are  subject to some state and county modification.   In  general,  however,  they
are  for limited periods of time to indiviual operators.   In no case  are
allowances to be made to  offset yield or  output  reductions  that  may be
associated with the application of practices.  This  latter  constraint  may
substantially change  farmer program choices from those  suggested by economic
models and/or criteria described earlier.

     Two factors are obvious deterrents to  the  achieving  of substantial
improvements  in water quality by means of present  cost-sharing  programs.  The
first and overriding  factor is simply the low level  of  financial commitment
to the problem.  The  Environmental Protection Agency has  estimated  capital
costs as high as  $10 billion to deal effectively with agricultural  nonpoint
source pollution.   In  1977, however, the  ACP was funded at  a  level  of about
$175 million.  At that  rate, little progress  toward  achieving water quality
goals can be  expected to  occur through farmer inducements—even  if  all  funds
are  directed  at water  quality measures.   The  second  factor  relates  closely

                                      704

-------
to the first.  To distribute the  limited number of dollars  in  a  politically
tolerable manner, at state, regional, and county  levels, stringent  rules  for
cost-sharing must be used.  These rules generally have  the  objective  of
spreading the dollars out,  rather than inducing changes in  the most critical
water quality areas.  The  restriction of sharing  only costs of pollution
control practices, rather  than total variable  costs  (including revenue
reductions), and sharing costs only of conservation, not production-oriented
costs hampers the adoption  of control practices.

CLASSIFICATION OF PRACTICES

    There are many ways that abatement control practices may be  classified.
For this discussion, only  a distinction between temporary and  permanent
practices will be used.  On one extreme of  such a classification are
practices such as changes  in crop  rotation, tillage  practices, or fertilizer
management which have no assured  impact beyond a single growing  season.   At
the other extreme are practices such as capital investments in diversion
ditches,  terraces, land leveling  or concrete ditch lining that may  be
expected to last a lifetime.  A host of practices fill  the  gap between these
extremes.

     As discussed earlier,  there  is a bias  in  current programs toward  the
subsidization of capital investments having a  long expected life.   However,
case studies of pollution  abatement alternatives, similar to those  presented
in Section 5 of the general manual, frequently show  that temporary  pollution
abatement measures are also the most efficient, i.e. least  expensive  per  unit
of pollution abatement.  Thus, we  may find  ourselves implementing practices
inferior to those suggested by current economic evaluation  procedures  such  as
reviewed in this report.

Temporary Practices

     Cropping pattern changes, filter strips,  adjustments in fertilizer or
water use, and use of hired management services are  examples of  temporary
practices.  Temporary measures can often abate pollution up to 50 percent of
current levels with lower  costs than alternative means. Their nonpermanent
nature may also be an advantage in that rigidities are  not  built into
production processes that  may affect the long  run ability of agriculture  to
adjust to new technologies  or changing resource supplies.   For example,
adoption of a sprinkler irrigation system to abate pollution not only
increases the energy intensity of  that segment of agriculture, but  also makes
it more vulnerable to problems created by future  shortages  of  energy  supply.
In an economy where funds to support pollution abatement are limited,  such
characteristics are not to  be taken lightly.

     Temporary measures are not without disadvantage, however.   Current
regulations prohibit cost-sharing of any single practice on a  farm  more
frequently than once every  five years.  Temporary practices are  difficult to
implement on a continuing  basis,  particularly  if the allowable level  of
cost-sharing is based upon  their  net farm income effect, a  feature  not
encompassed by current programs.   Changes in crop yield, input costs,  or  crop
practices markedly influence net  income impacts of pollution abatement

                                     705

-------
practices.  The uncertainty of these factors over time make  it  difficult  to
administer programs relying upon temporary measures for abatement.   Moreover,
a cost-sharing program not sensitive to such factors could lead to wild
fluctuations in the amount of abatement adhieved from year to year.   To
obtain a specified level of pollution abatement with temporary  measures would
require continual  adjustment of program costs.  In many cases,  interrupting
the abatement process even for a single year could reduce or eliminate
potential  benefits achieved during periods when the practices were in
effect.  If temporary practices are to be employed on a continuing basis,
there will  have to be program incentives tailored to meet this  end.

     Despite some rather serious implementation problems, temporary  practices
should not be rejected during pollution abatement planning.  Their cost per
unit of pollution abatement may be so low in some cases that implementation
can be achieved for little more than the cost of educating farmers about
them, appealing to their civic duty regarding environmental  protection.   In
fact, there may be limited situations in which these procedures alone would
create an adequate program of continual pollution abatement.

Permanent Practices

     Permanent practices of pollution abatement are generally structural  in
nature.  Such practices, once implemented, usually have abatement effects
ranging over several years.  They are an investment in the future and will
normally add to the total value of a farm.  Examples of practices in  this
category range from well-designed sediment ponds, whose lifetimes may still
be relatively short, to some types of terrace or irrigation  systems  with  life
expectancies of 30 years or more.

     Many of the advantages and disadvantages of permanent practices  were
alluded to in the previous section.  The primary advantage is the relative
simplicity of administration.

INCENTIVE PROGRAMS

     Voluntary adoption of pollution abatement practices in  agriculture is
generally assumed to require some form of subsidy.  The individual goals  of
farmers will influence their response to incentive programs.  No single
incentive program can be equally attractive to all farmers.  Current ACP
programs are relatively rigid in defining the types of practices which can be
subsidized and the manner of cost-sharing to be followed.  A broader  range of
program incentives might be considered for the future.  The  use of a
combination of several  types of incentives is perhaps appropriate to  achieve
environmental standards.

Fixed Rate Cost Sharing

     Cost-sharing programs have traditionally been based on  the principal
that a fixed rate be paid to farmers for a particular practice  (e.g., a fixed
number of dollars per acre for terracing, or fixed number of dollars  per  foot
of irrigation mainline).  The rates are adjusted to fit costs in different
parts of the country.  The approach has the advantage of being  relatively

                                     706

-------
easy to administer, but it has the disadvantage of  not  being  equally
attractive to all farmers in any given area.  Under a voluntary  program,  it
elicits adoption patterns not commensurate with the problems  to  be  solved.

     Farmers with different debt/equity  ratios, ages, tax  brackets,  cash
positions, etc. will each respond differently to  such a cost-sharing
program.   In some cases, a farmer is paid to install an irrigation  system
that he would have installed even without a subsidy, whereas  a neighbor may
not be able to afford the investment even with a  subsidy.   The fixed  rate
program provides no assurance that it will achieve  desired levels of
abatement.  It will not necessarily attract the right farmers or the  right
number of  participants, and will provide either too much or too  little
pollution  abatement for the dollars expended.

Variable Rate Cost Sharing

     It is conceivable that cost-sharing programs could be designed with  more
flexibility than the fixed rate approach described  above.   Case  studies for
alternative pollution abatement practices have typically developed
information for a representative farm in a given  area and  then measured costs
of practices in terms of how they will impact net farm  income.   By
recognizing the relevant characteristics of individual  farms, it should be
possible to vary the subsidy payments for a practice to more  nearly  reflect
the needs  of each farmer.  Such flexibility would provide  more assurance  of
obtaining  the right amount of pollution abatement per dollar  of  program
cost.  Of  course, the administrative costs of such  a program  could be
prohibitively high.  By focusing only on predominant differential
characteristics among farmers, however, greater program flexibility could be
achieved without the inordinate expense of tailoring detailed individual
programs for each farm.

Tax Credit

     Rather than providing direct subsidies to farmers  for adopting  certain
practices, it is possible instead to provide tax  credits against the  cost of
an investment.  This approach is available now in a limited form to  farmers
who invest in new machinery or irrigation equipment.  The  program could be
expanded to specifically attract investment to pollution abatement practices,
much as homeowners are being enticed to  invest in energy-saving  items.

     This  approach has the advantage of encouraging investment of private
capital in such programs, thus decreasing the need  for  federal expenditures.
A portion  of the capital invested would be offset by a  reduction in the tax
obligation of the farmer.  This type of program would not  be  equally
attractive to all farmers.  Hence, it would not necessarily elicit  investment
of desirable amounts in the optimal  places for pollution abatement.   Low
income farmers or those with large debts that already reduce  their tax
burdens might find little incentive through a tax credit program.
                                     707

-------
Cost of Capital

     Rather than directly subsidizing farmers for investments,  it  is  also
possible to reduce the cost of capital required for such investments.  This
can be accomplished in several ways.  Interest-free or low-interest loans
provided by the action agency constitute an obvious approach.   It  should also
be possible to guarantee loans for small or low equity farmers.  Repayment
periods could be adjusted to accomodate the ability of farmers  to  repay the
incurred debt.  All of these approaches have the advantage of encouraging the
use of private capital to solve environmental problems.

OTHER CONSIDERATIONS

     In the above discussion of program incentives, the implied costs were
for long-term capital investments.  There may, however, be valid reasons,
including cost effectiveness, to encourage adoption of temporary practices.
It should be possible to develop a contractual arrangement between a  farmer
and the action agency that would ensure the long-term use for temporary
practices.  Perhaps this could take the form of commitment to a series of
annual payments for a given practice.  It should also be possible  to  purchase
the rights of a farmer to grow certain crops or to engage in specific
practices that result in environmental damage.  Such programs would have to
be carefully tailored to the need of a particular area.  They might provide
considerably higher returns in terms of environmental improvement, however,
than programs encouraging only capital investment.

     Education of farmers regarding managerial adjustments that could abate
pollution may provide high payoff at low cost In many cases.  Frequently, a
change In fertilizer management, water management, or tillage practice can
provide significant environmental Improvement at little or no cost to the
farmer.  In fact, the reduction In soil loss, fertilizer savings,  or  Improved
yields may actually Increase returns to the farmer once the  practice  has been
adopted.

     There may also be situations where an environmental standard  can be set
for a watershed or a river basin while leaving the choice of specific abate-
ment practices up to the farmers of the area.  In most situations  of  this
kind, some farmers will find it less costly to abate pollution  than others
(keeping in mind the broader definition of "costs" which was introduced  in
Section 1).  Hence, some farmers might choose to continue polluting while
giving their share of the subsidy to neighbors willing to abate a
proportionately larger amount of pollution.  The environmental  standard could
be met with greater efficiency in this manner than through a program
requiring equal amounts of abatement from all farmers.

Benefits Versus Costs

     It must be recognized that all environmental  improvement is expected  to
benefit someone.  It is implicity assumed, though certainly  not assured, that
total social benefits will equal or exceed the cost of pollution abatement.
It may be possible to identify beneficiaries of environmental improvement  in
some areas who are willing to share the costs of  improvement directly rather

                                     708

-------
than through increased commodity prices  in the marketplace.   Under  these
circumstances, a mechanism would have to be arranged  to accomplish  the
transfer of funds from one citizen's group to another.

Administrative Costs

     Implementing control strategies usually requires  additional  accounting,
monitoring, reporting, supervision, enforcement, and management.  These
additional costs vary substantially, according to the  type of control method
selected.  They are usually borne both by farmers and  public  agencies.
Administrative costs are usually not considered  in deciding on a  course of
public action.  In some cases, however,  the public and private administrative
costs of a program may exceed the public benefits derived from the  program.

     Section 208 plans require approval  from a diverse set of interest
groups.  This approval process suggests  that compromise control practices
will result.  The politics of local governmental bodies will,  therefore, be
important.  Current institutional arrangements and legal frameworks may not
allow some control strategies to operate, which would  require the
establishment of new institutional  structures.
                                    709

-------
                               REFERENCES
Ahmad, S.,  June 1966.  On The Theory of Induced Invention.   Econ.  J.
     344-357.

Alexander, R. M.,  1971.  Social  Aspects of Environmental  Pollution.
     Ag. Sci. Rev.  Vol.  9.

Alt, K. F. and E. 0. Heady.,  1977.   Economics and the Environment.
     Impacts of Erosion  Restraints on Crop Production in the Iowa
     River Basin.  Center for Agricultural  and Rural  Development.
     Report no.75.,  Iowa State University,  Ames, Iowa.

Baker, C. B.,  1977.  Introduction to the Growth of the Agricultural
     Firm in Economic Growth of the  Economic Firm.,  Tech.  Bull.  86.,
     College of Agriculture Research Center, Washington State Univer-
     sity.,  1-6.

Barry, P. J.,  May 1972.  Asset Indivisibility and Investment Plan-
     ning.  An Application of Linear Programming.  Amer. J.  Agr.
     Econ.  255-260.

     1977.  Theory and Method in  Firm Growth Research, in  Economic
     Growth of the Agricultural Firm.  Tech. Bull. 86.,  College
     of Agriculture Research Center,  Washington State University
     7-14.
                                  710

-------
Barton, D. G., and C. P. Francis.,  1976.   A User's  Guide  to  MRS,
     A Linear Programming System from IBM,   A.  E.  Ext.   76-26.,
     Department of Agricultural  Economics,  Cornell  University,  Ithaca,
     New York.

Baumol, W. J.,  1972.  On Taxation and  Control  of  Externalities.
     Amer. Econ.  Rev.  62:307-322.

Bamol,  W.  J.  and  W.  E.  Oats.,   1971.  The Use of Standards and Prices
     for Protection  of  the Environment.,  Swedish  J.  Econ.  73:42-54.

Beedles, W. L., Sept.  1977.   A  Micro-Econometric  Investigation of
     Multi-Objective  Firms,   J-  Finance.  1217-1233.

Beneke, R. R. and R.  Winterborg.,   1973.  Linear Programming, Appli-
     cations  to Agriculture.   The  Iowa  State University  Press.,  Ames,
     Iowa.

Boehlje, M. D. and T. K. White.,   Aug.  1969.  A Production Invest-
     ment Decision Model of  Farm  Firm Growth.   Amer.  J.  Agr.  Econ.
     546-563.

Boussard,  J.  M. V.,   Aug. 1971.   Time Horizon,  Objective  Function, and
     Uncertainty  in  a Multiperiod  Model of  Firm Growth.  Amer. J. Agr.
     Econ.  467-477.

Bower,  B.  T., C.  N.  Ehler, and A.  V.  Kneese.,   1977.  Incentives for
     Managing the Environment.   Environ. Sci. & Tech. 11 (3)  : 250-254.

Brill,  E.  D., J.  C.  Liebman  and  C. S. Revelle.  1976.  Equity Measures
     for Exploring Water Quality  Management Alternatives.  Water Re-
     sources  Research.  12 (5)  :  845-851.

Bundgaaco-Nielson, M. and C.  L.  Hwang.  A Review on  Decision Models In
     Economics of Regional Water  Ouality Management.

                                  711

-------
Butcher, W. R. and N. K.  Whittlesey.,   Dec.   1966.   Trends  and  Problems
     in Growth of Farm Size.   J.  Farm.  Econ.   1513-1519.

Cahill, T. H., R. W. Pierson  Jr., and  B.  Cohen.   1979.   The Evaluation
     of Best Management Practices for  the Reduction  of  Diffuse  Pollutants
     in an Agricultural Watershed.   In Best  Management  Practices  for
     Agriculture and Silviculture.   R.  C. Loehr,  D.  A.  Haith, M.  F.  Walter,
     C. S. Martin (Eds.)   Ann Arbor Science  Publisher Inc.,  Ann  Arbor,
     Mich.  465-490.

Cahill, T. H., and R. W.  Pierson.,   March 1979.   Honeycreek Water-
     shed Report.  Lake Erie  Waste  Management Study.  Technical Re-
     port Series.  U. S.  Army Engineer District.   Buffalo,  N. Y.

Carter, H. 0. and K. D. Cocks.   Micro  Goal  Functions  and Economic
     Planning.  Amer. J.  Agr.  Econ.  400-411.

Castle, E. N., M. H. Becker,  and F. J.  Smith.   1972.   Farm  Business
     Management.  Mormillan Publishing Co.

Coarse, R. H.,  1960.  The Problem  of  Social  Cost. J. Law & Econ.
     3:1-44.

Conservation Needs Inventory.   1967.   506 Counties iRandom selection
     9 Plots/county and 9 points/plot), Soil  Conservation Service,
     USDA, Washington D.  C.

C.osper. H. R., July 1978.  The Influences of Tillage Systems on Corn
     Yields and Soil Loss in  Ohio,  Indiana,  Illinois, and Iowa.  Work-
     ing Paper.  NRE/USDA.

Crocker, T. D. and A. J.  Roberts 111.,  1971   Environmental Economics.
     The Dryden  Press, Inc.  Hinsdale, 111.
                                  712

-------
 Crosson,  P.  R.,   Jan-Feb.  1975.   Environmental Considerations in Ex-
      panding Agricultural  Production,  J. Soil & Water Cons. 23-28.

Dick, D. T.,  1976.  The Voluntary Approach  to Externality Problems:
     A Survey of The Critico.  J. Environ. Econ.  & Mgmt.   2:185-195.

Downey, J. C., C. S. Liebman, and C. S. Revelle.   1976.   Equity Meas-
     ures For Exploring Water Quality Management  Alternatives.   Water
     Resources.  12 (5): 845-851.

Eisgruber, L. M. and G. F. Patrick.,  Aug. 1968.   The Inpact of
     Managerial Ability and Capital  Structure on  Growth  of the  Farm
     Firm.  Amer. J. Econ.  491-506.

Feds Budgets.  1979.  Firm Enterprises Data  System.  CED-ERS/USDA.
     Oklahoma State University,  Stillwater, Oklahoma.

Forster, D.  L., Aug. 1978.   Economic Impacts  of Changing  Tillage
     Practices  in the  Lake Erie Basin.  Technical  Report  Series.  U.  S.
     Army Engineer District.   Buffalo,  N.  Y.

Forster, D.  L.  and G.  S. Becker., 1977.   Economic  and Land  Manage-
     ment Analysis.   Honeycreek Watershed.   Ohio  Agricultural Research
     and Development Center.   Ohio State  University,  Columbus,  Ohio.

Freeman, A.  M., R. H.  Haveman, and A.  V.  Kneese.,   1973.   The Economics
     of Environmental  Policy.   John  Wiley  &  Sons.   New York.

Gold, B., Spring 1977.   Research, Technological Change, and  Economic
     Analysis:   A Critical  Evaluation  of  Prevailing Approaches.   Quart.
     Rev. Econ. & Bus.   7-30.

Goldman, M.  I.  (Ed.).,   1967.   Controlling Pollution,  The  Economics of
     a Cleaner  America.   Prentice-Hall, Inc.
                                  713

-------
Gossett, D. L.,  1975.  The Economics of Changing the Water Quality of
     Irrigation Return Flow from Farms in Central Washington.   Unpublished
     Master's Thesis.   Dept.  of Agr. Econ.,  Washington State  University.

Hadley, J.  C., and J.  N. Lewis.,  1967.  The Pesticide Problem:   An
     Economic Approach to Public Policy.   Resources for the Future,
     Inc.,   distributed by the John Hopkins Press.

Heidhues,  T.,  Aug. 1966.  A Recursive Programming Model  of Farm
     Growth in Northern Germany.  J. Farm Econ.   668-684.

Hochman, E., and G. S. Rausser.,  1977.  Firm Growth Policies  under
     different Pollution Abatement, Production,  and Financial  Structures
     in Economic Growth of the Agricultural Firm.  Tech.   Bull.  86,
     College of Agriculture Research Center, Washington State  University.
     38-53.

Homer, G. L., and D. J. Dudek.,  1979.  An Economic Methodology for Eval-
     uating "Best Management  Practices" in the San  Joaquin Valley of
     California.  Paper presented at USDA-EPA Monitoring and Modeling
     Workshop, Airlie  House,  Va.

Honeycreek  Co-Occurrence Tables.,  1978.   U. S.  Army Corps of  Engineers.
     Buffalo District.

Horner, G.  L.,  1975.   Internalizing Agriculture Nitrogen  Pollution Ex-
     ternalities:  A Case Study.  Amer. J. Agr.  Econ.  57:33-39.

Irwin, G. D.,  July 1968.  A Comparative Review of Some Firm Growth
     Models.  Agr. Econ. Res.  82-100.

Jacobs, J.  J., and G.  L. Casler.,  May 1979.  Internalizing Externalities
     of Phosphorus Discharges from Crop Production  to Surface  Water:
     Effluent Taxes versus Uniform Reductions.  Amer. J.  Agr.  Econ. (note).
     309-312.
                                   714

-------
Jarrett, H.,  (ed.).,  1966.  Environmental Quality in a Growing Economy.
     Resources for the Future, Inc.  Johns Hopkins Press.

Johnson, S. R., D. S. Moore, and  K. R.  Tefertiller.,   Nov.  1967.  Stochastic
     Linear Programming and Feasibility Problems  in  Farm Growth Analysis.
     908-919.

Kneese, A.  V., R.  V.  Ayers, and R.  C.  D'Arge.,  1970.  Economics  and the
     Environment:   A Materials  Balance  Approach.  John Hopkins  Press,
     Baltimore.

Kraft,  D. F.,  1975. Economics of  Agricultural  Adjustments to Water Quality
     Standards in  an  Irrigated  River Basin.   Unpublished Ph. D. Thesis.
     Dept.  of Ag.  Econ.,  Washington State University.

Langhan, M. R.. 1972.  Theory of  the Firm and the Management of Residuals.
     Amer.  J.  Agr. Econ.   54:315-322.

Lins, D. A.  Jan.  1969.   An Empircal  Comparison  of   Simulation and Recur-
     sive Linear Programming Firm Growth Models.   Agr.  Econ. Res.  7-12.

Logan,  T. J.,  Dec. 1977.   Levels  of Plant Available  Phosphorus  in  Agri-
     cultural  Soils in the Lake Erie Drainage Basin.   Lake  Erie Waste
     Management Study.  Technical  Report Series.  U.S.  Army Engineer
     District.  Buffalo,  N. Y.

Logan,  T. J.,  Jan. 1978.   Chemical  Extraction as  an  Index of Bioavail-
     ability of Phosphate in Lake Erie  Suspended  Sediments.   Lake  Erie
     Waste  Management Study. Technical  Report  Series.   U.S. Army Engi-
     neer District.  Buffalo, N.  Y.

Logan,  T. J.,  F.  H. Verhoff, and  J. V.  Depinto.,  Jan. 1979.   Biological
     Availability  of  Total  Phosphorus.   Lake  Erie Waste  Management Study.
     Technical Report Series.  U.  S. Army Engineer District.  Buffalo, N.  Y
                                  715

-------
MacMillan, J. A., and R.  M.  A.  Lyons.,   July 1969.   A Cross-section
     Analysis of Farm Household Expenditures. Canadian J.  Agr.  Econ.  92-105.

Martin, J. R., and 0. L.  Walker., Dec.  1966.  Firm  Growth  Research Oppor-
     tunities and Techniques.  J. Farm Econ.  1521-1531.

Mayfield, R. C., and L. Yapa.,   Jan. 1978.   Non-Adoption  of Innovations:
     Evidence from Discriminant Analysis.  Econ.   Geog.  145-156.

McGrann, J. M. and J. Meyer.,  1978.  Farm-Level  Economic  Evaluation
     of Erosion Control and Reduced Chemical Use  in Iowa.   Cornell Waste
     Management Conference, Rochester, N. Y.

Miller, W. L., and J. H.  Gill.,  1976.  Equity Considerations in Con-
     trolling Nonpoint Pollution from Agricultural  Sources.  Water
     Resources Bulletin #12  253-261.

Neeley, W. P., R. M. North, and J. C. Forston.   1975.  Planning and
     Selecting Multiobjective Projects by Goal Programming. Water
     Resources Bulletin  12  (1).

O'Byrne, J. C.,  1977.  Doanes Tax Guide for Farmers, Doane Agricul-
     tural Service,  Inc.  St. Louis, Mo.

Ohio Agricultural Statistics.,  1977.  Ohio Crop Reporting Service,
     Columbus, Ohio.

Ohio Ag.,  1973.  An Evaluation of Ohio Soils in Relation  to No-Tillage
     Corn Production.  Research-Bull.  1068.  Ohio Agricultural Research
     and Development Center,  Wooster, Ohio.

Osburn, D. D., and  K. C. Scheeberger.,  1978.  Modern Agriculture
     Management. Reston Publishing Co. Reston, Va.
                                   716

-------
Perrin, R., and D.  Winklemann.,  Dec.   1976.   Impediments  to  Technical
     Progress on Small  versus Large Farms.   Amer.  J.  Agr.  Econ.   888-894.

Pfeiffer, G.  H.,  1976.  Economic Impacts of Controlling  Water Quality
     in an Irrigated River Basin.  Unpublished Ph.  D.  Thesis.  Dept.
     of Agricultural  Economics,    Washington State  University.


Rae, A. N.,  June 1970.  Capital  Budgeting,  Intertemporal  Programming
     Models with Particular Reference to Agriculture.   Australian J.
     Agr. Econ.  39-52.

Rafeld, F. J., and E. T. Shaudys.,  Dec. 1970.  Empires!   Testing of a
     Farm Firm Growth Theory.  S. J.  Agr. Econ.  175-181.

Randall, A.,   1972.  Market Solutions to Externality  Problems:   Theory
    and Practice.  Amer. J. Agr.   Econ.   54:175-183.

Rose, M.,  1973.  Market Problems in  the Distribution  of  Emission Rights.
     Water Resources Res.   9:1132-1144.

Schneider, R. R., and R. H. Day.,  1976.  Diffuse  Agricultural  Pollution:
     The Economic Analysis of Alternative Controls, Department of Agri-
     cultural Economics,  University  of  Wisconsin,  Madison,   Wisconsin.

Seckler, D.,  1965.   Theoretical  and Practical  Issues  in Quality Manage-
     ment of Water and  Land, (Discussion of  Paper  by  W. Chryst).  Con-
     ference  Proceedings Committee on the Economics of Water Resource
     Development of the Western  Agricultural  Economics Research Council,
     San Francisco.,  Dec. 15-16.

Soil Survey.,  April  1969.  Supplement to the  Soil  Survey of Huron County
     Ohio USDA/SCS.
                                  717

-------
Stanton, B. F.,   1977.   Notes  on  The  Use  of The  IBM  MPSX Linear  Program-
     ming Package.   A.  E.  Res.   11-14.   Dept.  of Agr.  Econ.  Cornell  Univ.
     Ithaca, New York.

Tillage Research in Ohio.,  Bull.  620.  Cooperative Extension Service,
     Ohio State  University, Columbus, Ohio.

Trippi, R. R., and  D.  R. Wilson.,   Fall  1974.   Technology Transfer and
     the Innovative Process in Small  Entreprenurial  Organizations.
     J. Econ. & Bus.  64-68.

U. S. Department of Agriculture, Economic Research Service.,  Sept. 1976.
     U. S. Land and Water:  Assessment through 2000 A. D. Farm Index.  4-7,

U. S. Internal Revenue Service.,  1978.   Farmers Tax Guide.   Pub!.  225,
     Dept. of Treasury.
 Venice  Township  Survey,  Seneca  County, Ohio., Nov. 1976.  A Summary of
      Economic  Data  From  the Agricultural  Practices Survey by G. Becker
      and  D.  L.  Forster.   Dept of Agricultrual Economics, Ohio State
      University.

 Voon, P.  K.,   Oct.  1977.  The Adoption of Technological  Innovations in
      Rubber  Processing:   The Case of Malaysian Smallholders.  Malayan
      Econ. Rev.  33-51.

 Walker, W. R.,  G. V.  Skogerboe, and T. L. Huntzinger.,   1979.  Optimal
      Allocation  of  Water Quality Controls and Urbanizing River Basins.
      Water Resources  Bulletin,  10 (5).

 Water Quality  Data, Sandusky River.  Material Transport. Lake Erie Waste
      Management  Study.   Technical Report  Series.  U. S.  Army Engineer
      District.   Buffalo,  N. Y.
                                   718

-------
Wenders, J. T.,  1975.  Methods of Pollution Control and The Rate of
     Change in Pollution Abatement Technology.  Water Resources. Res.
     11: 393-396.

White, G. G., and E. J. Partenheimer.,  1978.  The Economic Implications
     of Erosion Control Plans for Selected Pennsylvania Dairy Farms.
     Cornell Waste Management Conference, Rochester, N. Y.

Whittlesey, N.  K., and P.  W. Barkley.,  May 1978.   The Economic Concepts
     and Policies  Related to Controlling Nonpoint Pollution Stemming
     from Agriculture. Proceedings:   Conference on Management in
     Irrigated Agriculture, Sacramento, Calif.

Whittlesey, N.  K.,  Oct. 1971. Economics and  Nitrogen in The Environ-
     ment.   Paper W-lll Technical  Committee Meeting, Reno, Nev.

Willett, G. S., and M. H.  Becker.,  1979.   Federal Income  Tax Manage-
     ment Principles for Farmers.   EM 4505.  Cooperative Extension
     Service,  Washington State University.

Wischmeier, W.  H.,  1978.   Predicting Rainfall  Erosion  Losses,  A Guide
     to Conservation Planning. Handbook 537.   SEA/USDA,   Washington,
     D. C.

Young,  D.  L.,  et.  al.  Dec.  1979.   Risk  Preferences of Agricultural
     Producers:   Their Measurement and  Use.   Proceedings issue,   Amer.
     J. Agr.  Econ.
                                  719

-------
                                   GLOSSARY
adequacy of irrigation:  The percentage of the field in which the root  zone
     is restored to field capacity during an irrigation.

adsorption:  Attraction of ions or compounds to the surface of a solid.

aerobic:  Having or occurring in the presence of oxygen.

aggregate  (soil):  Mass or cluster of soil particles, often having  a  charac-
     teristic shape.

ammonification:  The release of ammoniacal nitrogen from an organic nitrogen
     source, by biochemical processes.

ammonia volatilization:  The reduction of ammonium to free nitrogen.

anaerobic:  Having no  oxygen, or occurring in oxygen-free conditions.

anion:  Negatively charged ion; can adsorb to a soil particle.

antecedent moisture condition:  Index of  soil water content determined  by
     the quantity of rainfall during a specified period preceding the time
     of the storm.

available  nitrogen:  Form of nitrogen which  is  immediately available  for
     plant growth (N03-or NH^+J.

available  nutrient:  A soil molecule which can be adsorbed and assimilated
     by growing plants.

available  phosphorus:  Forms of phosphorus which can be immediately used for
     plant growth.

available  water capacity:  The difference between moisture content  at  -1/3
     bars  and  at -15 bars atmospheric pressure; used as an index  of moisture
     available to plants.

average cost:  Total cost divided by total quantity of  goods.

base solution:  That combination of farm  practices which maximizes  profit
     when  no constraints are  in effect.

Best Management Practice  (BMP):  A practice  or  combination of  practices
     found to  be the most effective, practicable  (including technological,


                                    720

-------
     economic and institutional considerations) means of preventing  or
     reducing the amount of pollution generated by non-point sources to  a
     level compatible with water quality goals.

biological oxygen demand (BOD):  An indirect measure of the concentration  of

     biodegradable substances present in an aqueous solution.  Determined  by
     the amount of dissolved oxygen required for the aerobic degradation of
     the organic matter at 20°C.  BOD5 refers to that oxygen demand  for  the
     initial  five days of the degradation process.

biomagnification:  The process by which toxic substances become concentrated
     in animal and plant tissues.

buffer strips:  Grass or other erosion-resisting vegetation between  or below
     cultivated fields.

bulk density:  The mass of dry soil per unit bulk volume including the air
     space.

call period:   Minimum length of time  in which an irrigator is expected to
     place an order with the canal operator for a specified quantity of
     water prior to the next irrigation.

candidate measure (CM):  A practice which has the potential to reduce pol-
     lutant loading, and thereby, the potential to improve water quality.

capital:  The amount of property  (including funds) owned by an individual  or
     business at a specified time.

capital intensive:  Requiring large amounts of capital relative to labor.

cash flow:  Money which is involved in payment of debts or receipt for goods
     and services.

cation:  Positively charged ion; can adsorb to soil  particle.

center pivot  sprinkler:  Rotating sprinkler device;  set time equals  one
     revolution.

clay:  Soil particles less than 0.002 mm in equivalent diameter.

clay soil:  Soil material containing more than 40 percent clay, less than  45
     percent  sand and less than 40 percent silt.

cohesion:   Attractive force which holds two molecules together.

common property:  That which is not owned by the private sector, and is,
     therefore, nontransferable between individuals, e.g., air, water, etc.

conservative  pollutants:  Those pollutants which are not altered as  they are
     transported from their source to the receiving water.


                                    721

-------
constraints:  Limitations imposed on the  farm  system;  usually  results  in
     different optimal combination of farm land, labor and capital when
     maximizing farm  income.

contour farming:  Plowing, planting, cultivating, harvesting and  other field
     operations conducted on the contour.
contour ridge planting:  Row crops are planted on semi-permanent  ridges
     which follow the contour.  Tillage usually occurs only on top of the
     ridges.

contour strip cropping:  Crops which  require different tillage practices are
     grown in alternate strips along the contours.

conventional tillage:  Those primary and secondary tillage operations which
     are considered  standard for the  specific location and crop.

cost-benefit:  A term used to denote  the comparison  of the decreases  in
     social welfare  to increases in welfare as a result of the allocation  of
     a public good.

cost-effectiveness:  A term used to compare agricultural  nonpoint  source
     control alternatives.  It is generally expressed as  dollars  per  unit
     pollutant load  reduction.

cost-sharing:  The practice whereby a public organization pays part of the
     cost  incurred by an individual upon implementation of, for example, a
     pollution control measure.

cover crop:  A close-growing crop whose main purpose is to protect and
     improve the soil during the absence of the regular crop or in the non-
     vegetated areas of orchards and  vineyards.

crop consumptive use:  The amount of  water  used for  and transpired during
     plant growth  plus that evaporated from the soil  surface and  foliage of
     the area occupied by the growing plant.

crop root  zone:  That depth of soil which is penetrated by crop  roots.

crop rotation:  The  growing of different crops  in a  specified  sequence on  a
     given parcel  of land.

cultural eutrophication:  The process of nutrient enrichment artificially
     accelerated by  some action(s) of human society  (see  "eutrophication").

curve number:  An  index of potential  runoff developed and used by the Soil
     Conservation  Service.

cut-back irrigation:  An irrigation method wherein the head ditch  is  suffi-
     ciently automated so a large  "wetting" furrow stream quickly advances
     the flow down the furrow and then the  flow is reduced to  a  "soaking"

                                     722

-------
     rate to finish the irrigation.

dead level furrows:   Irrigation  furrows, having  no  slope,  that  are  diked  at
     the end of the furrow to prevent runoff.

deep percolation:  The downward  movement of water through  the soil  to  below
     the crop root zone.

denitrification:  The biochemical  change of nitrogen  from  an  ionic  to  a
     gaseous form.
depletable soil moisture:  The quantity of moisture which  can be  withdrawn
     from the root zone without  resultant crop moisture stress.

depreciation:  A decrease in the value of an asset  due to  causes  such  as
     wear or obsolescence.

debt/equity  ratio:  The ratio of money borrowed  to  monetary  value of the
     assets above that which is  financed by another party.

desalination:  The removal of salts from saline  water or soil.

desorption:  The release of sorbed ions or compounds  from  solid surfaces.

diminishing returns:   Where the  marginal gain decreases for each  additional
     unit.

direct runoff:  Both  surface flow  and the interflow component of  subsurface
     flow.

disposable income:  Income remaining after fixed costs have been  subtracted.

dissolved oxygen (DO):  Oxygen in  lakes and streams which  is  readily avail-
     able to the aquatic organisms.

disutility:  Undesirable effects of specified action.

diversion:  A channel or channels  which protect  a field from  erosion by
     intercepting and diverting  surface flow from croplands uphill  of  the
     given field.

drainage:  Readiness with which  soil water is removed from the  soil  profile.

drift:   The unintentional transport of a substance  out of  the area  in  which
     it was applied.

economic risks:  Monetary investments for which  the benefits  or returns are
     not guaranteed nor can the  outcome be associated with a  certain prob-
     ability.

efficiency frontier:   Locus of points indicating lowest control costs  ($/kg)
     for a particular range of NPS load reduction.
                                    723

-------
effluent:  The discharge of a pollutant, or pollutants, and the medium  in
     which they are transported.

effluent standard:  Designated limit of pollutant discharge, usually  given
     in quantity of pollutant per unit time.

electrodialysis:   Process which removes salt ions from a solution  by  running
     an electrical current through the solution; anions are attracted to the
     cathode and cations move toward the anode.

enrichment ratio:  The ratio of pollutant concentration in the soil or  soil
     water to its concentration in the runoff or the sediment, respectively.
EPA:  Environmental Protection Agency

erosion:  Detachment and movement of rocks and  soil particles by water  and
     gravity.

erosion potential index:  Average annual soil loss that would occur in  the
     absence of any vegetation or erosion-reducing practices.

eutrophication:  A natural or artificial process of nutrient enrichment
     whereby a water body becomes abundant in aquatic plants and low  in
     oxygen content.

evaporation pond:  Basin in which wastes are retained for the purpose of
     reducing water and ammonia content.

evapotranspiration:  The loss of water from an  area by evaporation from the
     soil or snow cover and transpiration by plants.

evapotranspiration rate:  The rate at which water is lost via plant tran-
     spiration and surface evaporation.

exchange capacity:  The abundance of sites  (within the soil sample) which
     have the  potential for being actively  engaged in ion adsorption.

externality:   Cost associated with an activity  which is not borne  by  the
     producers.

farm subsystem:   That which lies within the boundary of the farm.

Federal  Water  Pollution Control Act  (FWPCA) Amendments  (PL 92-500):
     Legislation  governing the discharge of point and nonpoint  source pol-
     lutants to attain water quality goals.  (Ammended in 1977,  PL 95-217.)

fertility:  The availability of those nutrients necessary for plant growth.

field borders:  Grass strips placed  at  field edges where pollutants,
     originating  from the field, can be  filtered.

field capacity:   The percentage of water which  still remains  after a
     recently  saturated soil has drained freely for 2 or 3 days.

                                    724

-------
fixed costs:  Those costs which  remain constant  even  when  the  production
     level varies.

fragipan:  Dense soil layer through which water  and roots  have  difficulty
     permeating.

fungicide:  Chemical used to destroy  fungi.

furrow advance  rate:  The velocity at which  the  initial  water  stream moves
     down a previously dry furrow.

furrow irrigation:  Irrigation method whereby water travels  through  the
     field by means of ditches between each  row.

furrow length:  Distance between entry point of  water and  end  of furrow;
     affects efficiency of irrigation.

furrow slope:   Change in elevation from head to  end of  furrow  divided  by
     distance,  given as a percentage.

gated pipe irrigation:  Irrigation method which  incorporates the improved
     furrow and cut-back irrigation systems; length of  set can  be  automat-
     ically controlled and varied to meet seasonal needs.

graded rows:  Rows which only approximately  follow the  contour.   This
     prevents row breakage by allowing excess water to  leave the field.

grassed waterway:  A channel  covered with erosion-resisting  vegetation  which
     is used for the transport of surface water  from  cropland.

gravitational water:  Water which moves through  a soil  solely  by gravita-
     tional forces.

gross income:   Money received for goods or services.

gross soil erosion:  Soil  erosion as defined by  the Universal  Soil  Loss
     Equation.

groundwater:  Subsurface water supply directly below  the water  table;  zone
     is saturated.

groundwater runoff:  Water that having infiltrated the  soil  surface,
     percolates to the groundwater table and moves laterally to reappear  in
     surface runoff.

growing degree days:  The number of consecutive  days  without a  frost during
     the growing season, for a specified location.

gully erosion:  Soil erosion occurring from  large channels which normal
     tillage operations will  not remove.

half-life:  The time required for one half of a  specified  substance  to
     disappear.
                                    725

-------
herbicides:  Chemicals used to kill undesirable vegetation.

heterotrophic:  Deriving energy from organic matter.

holding pond:  Basin in which wastes are retained prior to disposal.

hydraulic conductivity:  The readiness of a liquid to flow given  a  certain
     pressure gradient.

hydrologic condition:  Description of the moisture present in a soil by
     amount, location, configuration, etc.

hydrologic soil group:  A classification system used by the Soil
     Conservation Service to group soils according to drainage characteris-
     tics.

immobilization:  The process by which an element becomes  unavailable to
     other plants and organisms because of a change in form from  inorganic
     to organic.

improved furrow irrigation:  Standard furrow irrigation techniques  are
     utilized but, by comparison to the early 1970's the  scheduling of
     irrigation events is more closely correlated to crop needs.

infiltration:  The downward entry of water into soil.

infiltration rate:  A measure of the maximum rate at which water  can
     permeate the soil under specific conditions.

inorganic:  Not derived from or pertaining to an organism.

insecticides:  Chemicals used to control insect population.

intake opportunity time:  Quantity of time soil surface is exposed  to
     irrigation water.

interception drainage:  A type of tile drainage which collects  the  ground-
     water flows at the edge of the field and diverts them downstream,
     thereby removing their potential to aggregate high water table
     conditions.

interflow:  Water that enters the soil surface and moves  laterally  through
     the upper soil  layers to reappear as surface flow.   Flow is  above
     groundwater level.

irrigation delivery schedules:  Plans for the timing and  quantity of future
     irrigations based on soil moisture levels and climatic data.

irrigation efficiency  (E):  The fraction or percentage of water  applied  to
     an irrigated field that is stored in the crop root zone.

irrigation frequency:  Number of irrigations in one season.

                                     726

-------
irrigation return flow:  Surface and subsurface water which  leaves  the  field
     after irrigation.

kinetic energy:  Energy resulting from motion; it cannot be  stored  in this
     form.

labile:  Readily coming into equilibrium.

labor  intensive:  That which requires a large labor  input  relative  to
     capital.

land forming:  Altering the characteristics of the slope and slope  length.

leaching:  The removal from the soil of materials which are  in solution.

length of set:  Amount of time irrigation water is diverted  to a particular
     field(s).

LC50 Lethal Concentration:  Lethal concentration of  50 percent of the
     species tested.

LC50-Lethal Dose:  Lethal  dose for 50% of the organisms tested.

liability (full, partial,  zero):  Refers to the obligation of a producer of
     an externality to cover the cost of that externality.

linear programming (LP):  Computational technique used to  find optimal
     solutions for multivariable problems.

loading:   Quantity of substance entering the receiving body.

macronutrient:  A chemical element required, in relatively large amounts,
     for proper plant growth.

managerial controls:  Candidate measures which involve changes in timing,
     chemical applicaton rates or tillage systems and usually do not involve
     separate field activities.

marginal  cost:  Cost of producing an additional unit of output.  In the
     context of NPS control, cost of decreasing pollutant  loading by an
     additional unit.

marginal  return:  Additional gain or benefit of producing  an additional unit
     of output or decreasing pollutant loading by an additional unit.

marginal  propensity to consume:  That fraction of each additional dollar
     received that will be spent rather than saved.

market demand:  That quantity of goods desired by consumers  at the  given
     price.
                                    727

-------
market supply:  That quantity of goods producers are willing  to  supply  at
     the given price.

meadowless rotation:  A crop rotational sequence which does not  include  the
     growing of sod crops.

micronutrient:  A chemical element  required,  in  relatively  small  amounts,
     for proper plant growth.

mineralization:  The microbial conversion of  an  element from  an  organic  to
     an inorganic state.

mulch:  Any substance which  is spread  on the  soil  surface to  decrease  the
     effects of raindrop  impact, runoff and other  adverse conditions.

multiset irrigation:  Irrigation method which combines the  improved  furrow
     system with a shorter length of run; irrigations may be  automatically
     controlled by a master  control panel.

net cost:   Cost of specified action after value  of benefits has  been
     deducted.

net income:  Money  received  for goods  and services after production  costs
     have been subtracted.

net irrigation requirement:  Crop consumptive use  less seasonal  precipita-
     tion.

nitrification:  The biochemical transformation  of  ammoniacal  nitrogen  to
     nitrate.

nitrogen cycle:  The succession of  biochemical  reactions that nitrogen
     undergoes.

nitrogen fixation:  The biological  process  by which  elemental nitrogen is
     converted to organic or available nitrogen.

nonpoint source (NPS):  Entry of effluent into  a water body in a diffuse
     manner so there is no definite point of  entry.

no-tillage:  Management practice where seeding  involves  only  opening the
     soil for seed  placement at the desired depth  and where weed control is
     effected with  the  use of herbicides.

objective  function:  A  mathematical statement of the program  objectives,
     usually profit maximization or cost minimization.

opportunity costs:  That  which is  sacrificed  in  taking a given course  of
     action.

organic:   Composed  of carbon compounds.


                                     728

-------
osmotic pressure:  The force due to water moving from an area of low concen-
     tration of a dissolved substance to that of a higher concentration of
     the substance.

overland flow:  Water which moves across the surface of a field.  Contribu-
     tions to overland flow are from both direct runoff and the interflow
     component of subsurface flow.

pathogens:  Disease-causing organisms.

percolation:  The downward movement of water through soil.

permanent wilting point:   (see wilting point).

permeability:  The degree  of penetration of gases, liquids, or  plant roots
     through a bulk mass or layer of soil.

persistence:  That period of time required for a complete degradation of a
     material into harmless products.

pH:  Scale of acidity and  alkalinity where the numbers below seven signify
     acidic conditions and those above, basic.

plow layer:  That layer of soil disturbed by tillage.

point source:  The release of an effluent from a conveyance form into a
     water body.

pollutant:  A substance which changes our environment in an undesirable way.

pollutant delivery ratio  (PDR):  The fraction of a pollutant leaving an area
     that actually enters a water body.

porosity:  Percent of soil sample not consisting of solid particles.

precipitation:  Amount and intensity of rainfall that provides  the transport
     energy for pollutant  loss from cropland.

productivity:  The ability of a soil to produce certain yields.

pumpback irrigation:   Irrigation system in which the runoff is  collected in
     ponds and pumped back to the top of the same or adjacent field.

pump drainage:  The pumping of groundwater for the purposes of  lowering the
     water table to alleviate waterlogging and providing additional irriga-
     tion water supplies.

rainfall erositivity:   A measure of the degree to which rainfall contributes
     to the soil erosion  process; depends on precipitation patterns and
     intensity.
                                     729

-------
reduced tillage:  A management practice whereby the use of secondary  tillage
     operations is significantly reduced.

relief drainage:  A type of tile drainage which controls the water table
     elevation by intercepting and removing deep percolation from the  over-
     lying root zone.

retention ponds:  Collection ponds for agricultural runoff where pollutants
     may settle out of solution, be assimilated by plants and organisms or
     degrade biochemically, depending on the nature of the pollutant.

reverse osmosis:  A desalination process in which salts are forced, by an
     induced pressure gradient, out of the original saline solution to one
     of a higher concentration.

ridge planting:  The practice of growing a row crop on the ridges between
     the furrows.

rill erosion:  Soil erosion occurring from small well-defined channels which
     are removed during normal  tillage operations.

runoff:  That portion of the precipitation and/or irrigation water which
     appears in surface streams or water bodies.

sand:  Soil whose particle size is between .05 and 2 mm in diameter.

sediment:  Any eroded material which has been moved from its point of  origin
     to be deposited on other land or in water.

sediment delivery:  Sediment arriving at a specific location.

sediment delivery ratio (SDR):  Fraction of eroded soil that actually
     reaches a water body.

sediment yield:  Quantity of sediment leaving a specified land area.

seepage:  Percolation losses from unlined canals, ditches, laterals,  and
     water courses running between the point of diversion and the farm.

set time:  (see length of set).

sheet erosion:   Soil erosion occurring from a thin, relatively uniform layer
     of soil particles on the soil surface.  Also called intern'!! erosion.

sideroll sprinkler:  Mobile sprinkler device.

silt:  Soil  particles between  .05 and .002 mm in equivalent diameter.

slope:  Change  in elevation over change  in distance, given as a percentage.

slope .length:   Length of land area for which slope is  measured; usually both
     measurements are taken along the direction of flow.

                                    730

-------
sod-based rotations:  Rotational crop sequence which  includes  the  growing  of
     hay.

Soil and Water Conservation Practices (SWCPs):   The manipulation of  such
     variables as crops,  rotation, tillage  and structures  to  reduce  the  loss
     of soil and water.

soil credibility:  An indicator of a soil's susceptibility to  raindrop
     impact, runoff and other erosional  processes.

soil organic matter:  That part of the  soil originating  from  animal  and
     plant material.

soil salinity:   A measure of the soluble salts present in  the  soil.

soil solution:   Water present in the soil and its solutes.

soil structure:  Characteristics of the  arrangements  of  the primary  soil
     particles into aggregates, throughout  the soil profile.

soil texture:  The proportions of soil  particles  (sand,  silt  and clay)  in  a
     soil.

soil type:  Lowest soil classification  unit.

soil water holding capacity:  Same as field capacity  (inches/ft).

splash erosion:  Soil erosion occurring  from raindrop  impact.

sprinkler irrigation:  A  highly efficient irrigation  technique whereby water
     is applied to the field by spraying.

stream size:   Size of irrigation water  stream delivered  to the  head  of
     irrigation furrows.

strip cropping:  Crops which require different types  of  tillage are  grown  in
     alternate strips to  reduce the field's potential  for  soil, water and
     pollutant losses.

structural controls:  Candidate measures which require capital  investment,
     construction activities and, consequently,  certain  economic risks.

subsidies:  Financial aid from the government for the support  of practices
     which are desirable to the public.

subsurface runoff:  Water which infiltrates the  soil  and then moves
     laterally below the  surface; includes  both  base  flow  and  interflow.

tailwater:  Runoff from the lower end of an irrigated field.
                                     731

-------
terrace:  A relatively level raised strip of earth  (usually built along the
     contour)  used for growing crops; designed to reduce soil, water and
     pollutant losses.

tile drain:  Subsurface pipes used to remove excess water.

tillage:  Plowing and seed preparation practices.

till plant:  Tillage practice where rows are scored in preparation  for
     seeding and residues are left in and on the soil  between these rows.

timing of field operations:  Scheduling primary and secondary tillage
     practices to minimize the overall impact on the environment.

toxicity:  Degree to which a chemical deleteriously affects an organism.

transaction costs (administrative costs):  Cost of  initiating or carrying
     out a specified program; involves extension, organizational and
     monitoring costs.

trickle  irrigation:   Irrigation method where the water drips  from perforated
     tubes situated on the soil  surface and running along each row.

uniformity coefficient:  Indicates the relative distribution of an  irriga-
     tion application; the higher the coefficient,  the more uniform the
     application and, for the same adequacy level, the greater the  irriga-
     tion efficiency.

Universal Soil Loss Equation (USLE):  A method of estimating  gross  soil
     erosion by adjusting a set soil loss to the conditions present in a new
     situation.

utility:  Degree of usefulness of a certain program or action.

variable  costs:  Those costs which change relative  to the production  level.

vegetative controls:  Candidate measures which usually involve changes  in
     the  cropping system and/or land use patterns and must be renewed
     annually.

volatilization:  Loss of a substance through evaporation.

water application requirement:  Quantity of water that must be applied  to
     the  field in order to meet crop needs.

water delivery subsystem:  The irrigation system component which includes
     the  transport  of the water from the headwaters of the watershed  to  the
     individual farm.

water removal subsystem:   The irrigation system component which  includes
     surface  runoff from the lower end of the  farm  and water  moving below
     the  root  zone.

                                    732

-------
watershed:   The area drained  by  a specified stream  and  its tributaries.

water  table:   The level below which the soil or other material present  is
     saturated.

wilting  point:   Soil moisture  content below which plants  irreversibly wilt,

zoonotic  disease:  Disease which  is transferred from animal  to man.
                                      733
                                                     U S GOVERNMENT PRINTING OFFICE 1982-559-092/0491

-------