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                               United States
                               Environmental Protection
                               Agency
                               S/TE  Technology  Capsule
                               MatCon™ Modified Asphalt for
                               Waste  Containment
  Abstract

  As part of the Superfund  Innovative Technology
  Evaluation (SITE) Program, the U.S. Environmental
  Protection Agency (EPA) evaluated the use of a
  proprietary asphalt mixture as a cover for hazardous
  waste landfills or other land disposal sites. Wilder
  Construction Company  (WCC),  the  firm  that
  developed the  asphalt mixture called MatCon™,
  claims that its asphalt has a permeability of about
  1x10* centimeters  per second (cm/sec) and is
  flexible enough that it does not crack under the
  small amounts of differential settlement typically
  encountered in hazardous waste landfills. Potential
  sites  for application  of this technology include
  hazardous waste sites that are relatively level and
  have a firm base. The use of MatCon™ asphalt as a
  site  cover allows reuse  of  the  site  for  public
  recreation or light industrial purposes.

  Two MatCon™1 asphalt covers have recently been
  installed for evaluation at two sites. The primary
  evaluation site is the Lindane Source Area (ISA) in
  the west management unit of Dover Air Force Base
  (DAFB) in Dover, Delaware. The second evaluation
  site is the Tri-County Landfill (TCL), located in Elgin,
  Illinois.
A  pilot-scale  MatCon™ cover (0.35  acre)  was
installed at the DAFB site in April 1999 together with
an  adjacent  conventional  asphalt  cover for
comparative testing. Samples of both the MatCon™
and conventional asphalt covers were obtained in
August 1999 for extensive laboratory testing. A 3.6-
acre MatCon™ cover was installed at the TCL site in
November  1999,  and  samples  were obtained
immediately following installation for laboratory
permeability testing.

Preliminary laboratory testing results indicate that
the permeability of the MatCon™ cover at the DAFB
site is less  than  1.0x10* cm/sec, whereas the
permeability of the adjacent conventional asphalt
cover is between 2.7X10-4 cm/sec and 1.0x1Q-5 cm/
sec. Flexural tests of samples of the MatCon™ and
the conventional asphalt covers indicate that the
MatCon™  cover  tolerates  three times  more
deflection  without cracking  compared  to the
conventional asphalt cover. Field hydrologic data
obtained to date at the DAFB and TCL sites indicate
average field permeabilities of about 2.3x108 cm/
sec and 5.0x10 •" cm/sec,  respectively. Complete
data from  the field permeability testing are
available in the Technology Evaluation Report.
                                 SUPERFUND INNOVATIVE
                                 TECHNOLOGY EVALUATION
                             U.S. Environmental Protection Agency
                             Region 5, Library (PL-12J)
                             77 West Jackson Boulevard, 12tft Floor
                             Chicago, IL  60604-3590
                          Recycled/Recyclable
                          Printed with vegetable-based ink on
                          paper that contains a minimum of
                          50% post-consumer fiber content
                          processed chlorine free

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Introduction

The  SITE Program  was established  in 1986 to
accelerate the development, evaluation, and use of
innovative technologies  that offer  permanent
cleanup alternatives for hazardous waste sites. One
component of the SITE Program is the Demonstration
Program,  under which engineering, performance,
and  cost data  are  developed  for  innovative
technologies.  Data  developed under  the  SITE
Demonstration Program enable potential users to
evaluate each technology's applicability to specific
waste sites.

MatCon™ is an asphalt mixture produced by using a
proprietary  binder  and  a  specified  aggregate
gradation in  a  conventional hot-mix asphalt plant.
WCC claims that MatCon™ asphalt is much less
permeable and possesses superior flexural strength
compared to conventional asphalt. WCC specifically
claims that MatCon™ asphalt has a permeability of
1.0x10^  cm/sec  or  less, which exceeds the
requirement   of  less  than  1.0x1Q-7 cm/sec
established for Resource Conservation and Recovery
Act (RCRA)  Subtitle C hazardous waste landfill
covers (Title 40 of the Code of Federal Regulations,
Section 264.301).

The two  primary objectives of the SITE Program
evaluation of  the MatCon™ technology were to
compare   (1)  the  in-field permeability  of the
MatCon™ cover to the RCRA requirement of less than
1.0x1fr7 cm/sec,  and  (2) the permeability and
flexural properties of MatCon™ asphalt to those of
conventional hot-mix asphalt. Secondary objectives
of the evaluation were to (1) compare various
laboratory-measured   physical   characteristics
(including load capaa'ty/deformation, shear strength,
joint  permeability,  and  aging and  degradation
characteristics) of MatCon™ asphalt  to those of
conventional asphalt covers; (2)  assess the field
performance of the MatCon™ cover under extreme
weather conditions and vehicle loads; (3) estimate a
cumulative hydrologic balance for the MatCon™
cover at the DAFB site; and (4) estimate the costs of
MatCon™ cover installation.

Dover Air Force Base Site

WCC installed a pilot-scale cover system at the DAFB
site in April 1999 for purposes of evaluating the
MatCon™   technology.  The  evaluation   cover
measures  approximately 124  by 220 feet and
consists  of  three sections:  (1)  12-inch-thick
MatCon™ asphalt with a drainage layer (Section I),
(2) 4-inch-thick MatCon™ asphalt (Section II), and
(3) 4-inch-thick conventional asphalt (Section III).
The drainage layer in Section I was constructed as a
4-inch-thick  channel   of   open-graded  asphalt
between two 4-inch-thick MatCon™ layers, as shown
in Figures 1 and 2. The purpose of this drainage layer
was to collect and allow measurement of the water
that infiltrated through the top 4 inches of the
cover.    The  purpose  of  constructing  both
conventional asphalt and MatCon™ sections was to
allow a direct comparison of the physical properties
of each type of asphalt based on laboratory testing
of cover samples.

To monitor infiltration,  the four 3-inch-diameter
polyvinyl chloride pipes leading from the drainage
layer in Section I were connected  to a 10-inch-
diameter sump, as shown in Figure 1.  During the
field evaluation, the volume of infiltration water
collected in the sump was monitored during rainfall
events, and Darcy's Law was used to estimate the in-
field permeability of the MatCon™ cover.

To  monitor surface runoff,  a lined  ditch was
constructed downgradient from  the cover, and
berms were constructed to direct the runoff from
Section I of the cover  into the drainage ditch.
Surface runoff was measured continuously with a
flow meter, which recorded both instantaneous and
cumulative flow.

Tri-County Landfill Site

WCC installed a 3.6-acre MatCon™ cover at the TCL
site in Elgin, Illinois during November 1999. A plan
view of the test section of the cover is  shown in
Figure 3. The drainage system underneath the test
section incorporates an intermediate gravel layer
underlain  by an impermeable geomembrane,  as
shown in Figure 4. This configuration was requested
by the U.S. Army Corps of Engineers,  the agency
providing oversight of the TCL closure.

A sump was installed at the edge of the  MatCon™
cover at this site to collect the drainage from the
gravel layer. The surnp is similar in construction to
that installed at the Dover site and was used  to

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               ' 3" HOPE
     10-Inch Diameter Sump
                                                                                                     A1
3" HOPE
fc,  ) Open Graded Asphalt (Below Surface)
[ '  | Dense MatCon" Asphalt
Figure 1.  Plan view of Section 1 of the evaluation cover system at Dover Air Force Base.
                                                                    V.  ^-'  •'.• .i-i.vV^
                                             .(lf/v-.' .
                              3" HOPE
                                                                                        LEGEND
                                                                                        Open Graded Asphalt
                                                                                        Dense MatCon™ Asphalt
Figure 2. Section A - A' (from Figure 1) showing infiltration collection system at Dover Air Force Base.

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                                                -100'-
/
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3-Inch Diameter
Perforated PE Pipe
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3.3% ^

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MatCon™ Asphalt with
Drainage Channel Below
/
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L- 3-Inch
Non-P
PEPip
              MatCon™ Asphalt
Figure 3. Plan view of the test section of the cover system at Tri-County Landfill.
                                                      -30f-
                                                            MatConn Asphalt
              NOT TO SCALE
3-inch Diameter Perforated PE Pipe
       T ronsttiofiirtQ to
     Non-Perforated PE Pipe


Coarse Aggregate Backfill
     (IxKHcmfe)

16 oz. Geotextile

40 Mil LLDPE Geomembrane

 MatCon« Asphalt

Prepared Coarse Aggregate
      Base Course
 Figure 4.  Section B - B' (from Figure 3) showing infiltration collection system at Tri-County Landfill.

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assess the volume of infiltration water. However, a
system for collection and measurement of surface
runoff was not installed at this site.

Evaluation Results

Both MatCon™ and conventional asphalt cover core
samples were obtained from the DAFB site in August
1999; these samples were subjected to extensive
laboratory  testing of physical  properties.   On
November  8,  1999,  eight core  samples were
obtained from the MatCon™ cover at the TCL site in
areas adjacent to the test section; these samples
were subjected to permeability testing for purposes
of comparison to the testing results for the DAFB site
samples.

This section  summarizes  the results  of the
laboratory testing of the cover samples and of in-
field observations as they relate to the primary and
secondary objectives. Field permeability data and
the hydrologic balance for the MatCon™ cover at the
Dover site will be available in July 2000.

Comparison With RCRA Requirements

Field permeability tests  on  the 12-inch-thick
MatCon™ cover at DAFB site and the MatCon™cover
at the  TCL  site show that the permeability is
between 1.28x107 and 5.15x1010  cm/sec.   This
permeability is up to three orders of magnitude
better than the RCRA requirement for Subtitle C
landfill covers of 1.0x10'7 cm/sec.

Comparison  with  Conventional Asphalt  -
Permeability and Flexure

Laboratory  test results  for  the  MatCon™ and
conventional asphalt covers are presented in Table
1.  The permeability of the conventional asphalt
cover samples ranged from 2.7x10"* cm/sec  to
1 .Oxlfr5 cm/sec, whereas all the MatCon™ samples
showed permeabilities of less than 1.0x1 fr8 cm/sec.

The flexural properties of the conventional asphalt
and the MatCon™ covers were measured using a
special test developed for this evaluation.  The test
measures the flexural properties under simulated
differential settlement using a 40-inch-long by 4-
inch-square slab sample. The sample sags under its
own weight when  it  is subjected  to differential
settlement by removing the sand supporting the slab
through an aperture about mid-point along the
sample length. The sand is removed over a 30-day
period in incremental, predetermined quantities.
The flexural tests of the MatCon™ cover samples
indicate that a 36-inch beam showed 20.41 mm of
deflection without cracking, whereas conventional
asphalt cracked with 7.2 mm of deflection. Further,
the MatCon™ cover sample did not show any cracks
after  30 days, whereas the conventional asphalt
sample had cracks up to 3 mm wide and 2.5 cm long
at 31.25 mm of deflection.

Comparison  with  Conventional  Asphalt
Performance

Other physical properties that were measured to
compare conventional and MatCon™ asphalt covers
included the following:

    •  Joint integrity
    •  Load capacity and deformation
    •  Tensile strength
    •  Thermal crack resistance
    •  Aging and degradation
    •  Void space

Table 1 summarizes the properties obtained for
MatCon™ and conventional asphalt.
Field  Performance  of  MatCon™
Extreme Weather Conditions
Under
The field performance of MatCon™ under freeze-
thaw and vehicle loads was evaluated at the TCL
site. Since installation in November 1999, several
snow storms occurred at the TCL site.  In early
March, a thawing period of about 1 week was
followed by cold weather and a snow storm.

Because the cover could not be completed in 1 day,
it was necessary to complete "cold joints" after the
edges of the daily applications cooled overnight. It
is often difficult to bond and compact the asphalt
properly at a cold joint. Poor workmanship at these
cold joints caused  raveling,  or separation  of
aggregate particles, from the edge and surface of
the compacted  asphalt during  cold weather.  A
surficial crack was found at one location on  the
MatCon™ cover. WCC repaired the crack by routing
the joint, cleaning the joint using a hot air lance,

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Table 1.  Comparison of Average Physical Properties of MatCon™ and Conventional Asphalt Covers
             Property
             Test Method
     MatCon™
Conventional Asphalt
       Hydraulic Permeability   ASTM D-5084
       (cm/sec)

       Flexural Properties at   New Method1
       Center of Beam
       Joint Integrity
       Load Capacity and
       Deformation at-20°C
       (MegaPascals)

       Tensile Strength at
       -20°C
       (MegaPascals)

       Thermal Crack
       Resistance at-30°C
       (MegaPascals)
       Accelerated
       Weathering (60 days)
       (cm/sec)

       Fuel Resistance
       (Depth of Penetration,
       cm)
       Void Space (%)

       Hydraulic
       Transmissivity
       (drainage layer only)
       (cm/sec)
          ASTM D-5084

          ASTM D-4123



          AASHTO TP-9



          AASHTO TP-10



          ASTM D-5084



          ASTM 1856



          ASTM D-3203

          ASTM D-5084
< 1.0x 10-8


20.41
No cracking


5.47x10-5

2048
3.55



3.60



2.2x10-6



1.5



1.53

8. 94x1 0-3
2.7x10-* to 1.0x10-5


31.252
(3-mm-wide, 2.5-cm-
long cracks)

1.04x10-4

3200
2.58
2.70
3.15x10-*
5.5
10.53
      Notes:
      AASHTO
      ASTM
Method developed by Ronald Terrel of WCC
Cracking was initiated at 7.2 mm of deflection
American Association of State Highway and Transportation Officials
American Society for Testing and Materials
and extruding it full of hot modified asphalt mastic
joint  sealer.  Permeability measured from  the
sample obtained from the location containing the
crack was 3.56x105 cm/sec,  demonstrating  the
critical importance of quality assurance and quality
control (QA/QC) in installing the MatCon™ cover.
The  QA/QC  requirements  for  MatCon™  cover
installation  will be detailed  in  the  Innovative
Technology Evaluation Report (ITER).

The other areas of the 3.6-acre  MatCon™ cover
appear to be performing well under  the  heavy
vehicle   loads.     Heavy  trucks  from  Waste
Management's recycling fleet have been operating
on the MatCon™ cover since it was installed.  The
                              trucks are parked on the MatCon™ cover, and the
                              cover is performing well under oil leaks from the
                              trucks.

                              Cost Estimate for MatCon™ Covers

                              The MatCon™ cover installation involves the mixing
                              of the proprietary binder along with aggregates in an
                              asphalt plant, placing the asphalt mixture on the
                              prepared surface,  and compacting it.  The costs
                              provided by WCC per acre of  MatCon™ cover are
                              summarized below.
                                               6

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   Aggregates
   MatCon™ Binder
   Mix Preparation
   Transport to Site
   Lay and
   Compact Mixture
   Permitting
   Site Preparation


   Total
$10,000
$77,000
$9,000
$8,000


$16,000
$2,000
$10.000


$120,000
This cost compares favorably with the cost per acre
for RCRA Subtitle C  covers, which  range from
$150,000 to $300,000 per acre, depending on local
availability of appropriate soil cover materials.

Comparison to Superfund Feasibility Study
Evaluation Criteria

Table 2 summarizes the MatCon™ cover performance
compared  to  the  Superfund  feasibility study
evaluation criteria. This table is provided to assist
Superfund  decision-makers  in  considering  the
MatCon™ cover for remediation at hazardous waste
sites.

Technology Status

The MatCon™ technology is commercially available,
and WCC has been discussing with  several site
owners the potential application of the technology.
The MatCon™  technology is being specifically
considered for several other landfill closures.  In
2003, MatCon™ covers over landfills in Beaumont,
Texas  and Albuquerque,  New  Mexico  may  be
evaluated under the SITE program.

Technology Applicability

The MatCon™ technology is applicable as a final
cover at many hazardous waste sites.  A MatCon™
cover can be constructed within a few days using
conventional asphalt paving equipment. Maintenance
of the cover is relatively easy, using conventional
asphalt paving repair equipment and materials. The
potential for hazardous waste site reuse is a major
advantage of this technology.  Uses being planned
for the MatCon™ cover include  the following:
staging area for heavy equipment and vehicles; light
industrial manufacturing; and sports facilities, such
as tennis courts and tracks.

Limitations

The technology is difficult to implement at waste
sites that are steep and have an unstable surface
because  the  MatCon™ cover requires  a firm
subgrade for placement of the cover.  Waste sites
must have slopes less then 3:1 for the safe  use of
compacting and paving equipment.

Sources of Further Information

Future field data from the hydrologic monitoring at
the DAFB and TCL sites will be used to continue the
evaluation of in-field permeability of the  cover.
Observations at the TCL site will continue to provide
data on field performance of the MatCon™ cover
under  extreme weather conditions  and  heavy
vehicle loads.

Further details  regarding  the  technology  are
available from the following sources:

David Carson
U.S. Environmental Protection Agency
ORD/NRMRL
5995 Center Hill Avenue
Cincinnati, OH 45224
Phone: 513-569-7527
Fax: 513-569-7879
carson. david@epamaH. epa.gov

Karl Yost
Wilder Construction Company
1525 E. Marine View Drive
Everett, WA 98201
Phone: 425-551-3100
Fax:425-551-3116
karlyost@wilderconstruction.com

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Table 2. Superf und Feasibility Evaluation Criteria for the MatCon™ Technology
               Criterion
                       Discussion
       Overall protection of
       human health and the
       environment
       Compliance with           2
       applicable or relevant and
       appropriate requirements
       (ARAR)

       Long4erm effectiveness     3.
       and permanence
       Reduction of toxicity,
       mobility, or volume
       through treatment

       Short-term effectiveness
       Implementability
4.
       Cost
       State acceptance
7.
8.
       Community acceptance     9.
The MatCon™ technology is expected to protect human
health by containing the hazardous waste. It affords
environmental protection by preventing the formation of
leachate at hazardous waste landfills.

The MatCon™ technology complies with the  EPA
permeability requirement of 10* cm/sec for landfill
covers that do not have bottom geomembrane layers.  It
also complies with the state and local ARARs.

According to WCC, the MatCon™ cover can  be a
permanent containment system requiring limited routine
maintenance.

The technology reduces the mobility of contaminants by
minimizing the entry of water into the waste.


The technology can be implemented expeditiously and
is effective in  reducing water infiltration into the waste.

The technology is readily implementable since hot-mix
plants are available in all parts of the country. Standard,
readily available paving equipment can be used to
construct the  MatCon™ cover.

The technology uses natural materials (aggregates and
petroleum products) that are used extensively in the
construction industry.

The cost is comparable to RCRA Subtitle C day and
geosynthetic covers.

State acceptance of the technology is likely because of
the redevelopment possibilities with a MatCon™ cover.
Illinois, Texas, California, and Florida have accepted this
cover.

Community acceptance of the technology is  likely
because of the redevelopment possibilities with a
MatCon™ cover.
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