EPA-450/2-88-003C
October 1989
Addendum To The
Air Emissions Species Manual
By:
Radian Corporation
3200 Progress Center
P.O.Box 13000
Research Triangle Park, North Carolina 27709
Contract No. 68-02-4286
Work Assignment No. 91
William B. Kuykendal, Project Officer
Office Of Air Quality Planning And Standards
Office Of Air And Radation
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
Charles C. Masser, Project Officer
Air And Energy Engineering Research Laboratory
Office Of Research And Development
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
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This report has been reviewed by the Office of Air Quality Planning
and Standards, U.S. Environmental Protection Agency, and approved
for publication as received from the contractor. Approval does not
signify that the contents necessairly reflect the views and
policies of the Agency, neither does mention of trade names or
commercial products constitute endorsement or recommendation for
use.
EPA-450/2-88-003c
n
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FOREWORD
This report is the result of a cooperative effort between the Office of
Air Quality Planning and Standards' Air Quality Management Division (AQMD) and
the Office of Research and Development's Air and Energy Engineering Research
Laboratory (AEERL). The overall management of the program was the
responsibility of AQMD.
iii
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ABSTRACT
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated volatile organic compound (VOC) or
particulate matter (PM) profiles from several source categories. In 1980, EPA
published the "Volatile Organic Compound (VOC) Species Data Manual, Second
Edition" (EPA-450/4-80-015) which provided VOC species profiles for some
emission source categories. In 1985, EPA published the "Receptor Model Source
Composition Library" (EPA-450/4-85-002) which contained particulate matter
(PM) species profiles for several source categories. More recently, EPA
published the "Air Emissions Species Manual - Volume I, Volatile Organic
Compound (VOC) Species Profiles" (EPA-450/2-88-033a) and the "Air Emissions
Species Manual - Volume II, Particulate Matter Species Profiles" (EPA-450/2-
88-033b). These documents represent expansions of the 1980 and 1985 VOC and
PM species profile documents. As part of an effort to update the VOC and PM
profile data bases, EPA has initiated several studies. The objective of the
current study was to update the VOC and PM Species Manuals by adding in new
profiles and making necessary revisions to existing profiles.
The PM update was performed by contacting researchers working in the
areas of PM species profile development and source receptor modeling. These
researchers were questioned regarding the availability of PM species profile
data that were not already contained in the Source Composition Library or the
Air Emissions Species Manual. New species profiles were developed from data
submitted by the researchers for a variety of source categories. The new
profiles were developed according to the protocols and procedures specified in
the PM Air Emissions Species Manual (EPA-450/2-88-003b).
The VOC update primarily reflects information on oil wells and oil field
operations that EPA obtained from the Tulsa City-County Health Department.
Tulsa recently conducted a sampling and analysis program to quantify emissions
of 30 organic compounds from six different types of oil field operations. The
Tulsa data were submitted to EPA and profiles were developed according to the
protocols and procedures specified in the VOC Air Emissions Species Manual
(EPA-450/2-88-033a).
Minor revisions were made to existing VOC profiles for light-duty
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gasoline vehicles to reflect corrections necessary for compounds that coelute
on the gas chromatography analyses. The specific VOC profiles affected by the
revisions are 1101, 1203, and 1204. The primary revisions were to the
benzene/cyclohexane and propane/propene splits.
This Addendum also has the purpose providing the VOC Species Manual user
with the notification that the printed version of the existing manual, "Air
Emissions Species Manual - Volume I, Volatile Organic Compound Species
Profiles" (EPA-450/2-88-003a), contains erroneous CAS numbers for several
chemicals. The computerized version of the speciation data base system
contains correct CAS numbers. The hard copy report, however, is in error due
to a bug in the programming used to print the data. The programming bug
caused the last digit in the first field of the CAS number to be duplicated
automatically as the first digit of the second field of the number after the
dash. The user should verify any CAS number in the printed data from other
sources. This problem will be corrected in the second edition of the manual
to be published in the near future.
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CONTENTS
Page
Foreword i i i
Abstract v
Tab!es ix
Executive Summary xi
1. Introduction 1
2. PM Species Profile Format and Application 5
2.1 PM Species Profile Format 5
2.2 Limitations of Data 13
2.3 PM Species Profile Application 15
2.3.1 Document Guide 15
2.3.2 Example of Use of a Profile 15
2.4 References For Section 2 18
3. PM Species Profiles - Point and Area Sources 19
3.1 • External Combustion Boilers 25
3.2 Chemical Manufacturing 69
3.3 Primary Metal Production 83
3.4 Secondary Metal Production 101
3.5 Mineral Products 113
3.6 Petroleum Industry 121
3.7 Solid Waste Disposal 135
3.8 Metal Fabrication : 141
3.9 Unpaved Roads 147
3.10 Paved Roads 151
3.11 Natural Sources 181
3.12 Wood Combusti on 195
3.13 Mobi 1 e Sources 213
3.14 Heavy Construction 253
3.15 References for PM Prof i 1 es 259
vii
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CONTENTS (Continued)
Page
4. VOC Species Profile Format and Application 263
4.1 VOC Speci es Profi1e Format 263
4.2 Limitations of Data 266
4.3 VOC Species Profile Application 267
4.4 References for Section 4 269
5. VOC Species Profiles - Point and Area Sources 271
5.1 Crude Oil Production 272
5.2 Mobile Sources 281
5.3 References for VOC Profiles 291
Appendices
A. PM Profile Calculations A-l
B. Particle Size Distribution Data B-l
C. Assignment of Source Classification and Area Source Codes by
Profile Number C-l
D. PM Profile Compositing Procedure D-l
E. Documentation of the Mobile Sources Profile Development
Procedures E-l
viii
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TABLES
Table Page
2-1 Sample Profile 6
4-1 VOC Sample Profile 264
B-l Sources of Mass Fraction Data B-4
C-l Source Classification Code Assignments C-3
C-2 Area Source Code Assignments C-10
IX
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EXECUTIVE SUMMARY
The U. S. Environmental Protection Agency (EPA) has several activities
that require speciated participate matter (PM) or volatile organic compound
(VOC) profiles from several source categories. Some of these activities are
preparation of air toxics and acid precipitation emission inventories, acid
precipitation modeling studies, receptor modeling, and ozone strategy
development. In an effort to update the available speciated PM profile data
base, EPA has initiated studies to update the "Receptor Model Source
Composition Library" (EPA-450/4-85-002) and produce a revision entitled "Air
Emissions Species Manual - Volume II, Particulate Matter Species Profiles"
(EPA-450/2-88-003b). Similarly for VOC emissions, EPA has performed studies
to revise the "Volatile Organic Compound Species Data Manual - Second Edition"
(EPA-450/4-80-015) and provide an updated version in the "Air Emissions
Species Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-
450/2-88-003a).
The primary objective of the current study was to update the PM profiles
in the Air Emissions Species Manual, Volume II with new information obtained
from contacts with principal researchers in the field of PM species profiles
and source receptor modeling. .The new profiles were developed using the
procedures and protocols specified in the Air Emissions Species Manual,
Volume II. The profiles are based on data voluntarily submitted by the
researchers.
Each PM profile in this document contains the following information:
Profile name
Profile number
Profile data quality
Control device identification
Reference(s)
Data source
Source Classification Code (SCC)
Mass fraction data
xi
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Species identification: species identified by Chemical Abstract
System (CAS) number, species number, and species name
Composition data in weight percent for four size ranges: 0-2.5 urn,
2.5-10 urn, 0-10 urn, and total particulate measured
Uncertainty associated with composition data for four size ranges:
0-2.5 urn, 2.5-10 urn, 0-10 urn, and total particulate measured
Date
This update includes 158 new PM profiles representing 14 source categories.
Profiles were developed for two new source categories, metal fabrication and
construction, which were not covered in the Air Emissions Species Manual,
Volume II.
Each profile in this update was assigned the SCC or area source code
considered appropriate for the specific profile, based on engineering
judgement. Profile assignments in this report were not made for all SCC's nor
were industry specific average profiles developed. This approach differs from
that followed in the Air Emissions Species Manual, Volume II.
The current study also contains new VOC profiles for a small number of
source types related to the oil production industry, principally oil wells and
oil field storage tanks. These data were produced from recent testing
performed by the Tulsa City-County Health Department. The oil production
profiles were developed using the same format and procedures outlined in the
Air Emissions Species Manual - Volume I (EPA-450/2-38-003a). Each VOC profile
contains the following information:
Profile name
Profile number
Profile data quality
Control device identification
References
Data source
Source Classification Code (SCC)
xn
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Chemical species identified by: Storage and Retrieval of Aerometric
Data (SAROAD) code, Chemical Abstract System (CAS) number, species
name, molecular weight, weight percent
Date
Minor revisions were made to three existing VOC profiles and these
revised profiles are included in this addendum. The affected profiles, 1101,
1203, and 1204, are for light-duty gasoline vehicles. The revisions were
necessary to correct a problem caused by compounds that coelute during gas
chromatography analyses. Revisions were made to the relative weight
percentages assigned to each coeluting compound.
This Addendum also has the purpose providing the VOC Species Manual user
with the notification that the printed version of the existing manual, "Air
Emission Species Manual - Volume I, Volatile Organic Compound Species
Profiles" (EPA-450/2-88-003a), contains erroneous CAS numbers for several
chemicals. The computerized version of the speciation data base system
contains correct CAS numbers. The hard copy report,, however, is in error due
to a bug in the programming used to print the data. The programming bug
caused the last digit in the first field of the CAS number to be duplicated
automatically as the first digit of the second field of the number after the
dash. The user should verify any CAS number in the printed data from other
sources. This problem will be corrected in the second edition of the manual
to be published in the near future.
xiii
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XIV
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SECTION 1
INTRODUCTION
The U. S. Environmental Protection Agency (EPA) has several ongoing
activities that require speciated participate matter (PM) and volatile organic
compound (VOC) profiles from several source categories. Some of these
activities include receptor modeling, preparation of acid precipitation and
air toxics emission inventories, acid precipitation modeling studies, and
ozone strategy development.
As part of an effort to update the available speciated VOC and PM
profile data bases, EPA has conducted studies to update the "Volatile Organic
Compound Species Data Manual - Second Edition" (EPA-450/4-30-015) and the
"Receptor Model Source Composition Library" (EPA-450/4-35-002). These updates
produced two new species profile documents entitled "Air Emissions Species •
Manual - Volume I, Volatile Organic Compound Species Profiles" (EPA-450/2-88-
003a) and "Air Emissions Species Manual - Volume II, Particulate Matter
Species Profiles" (EPA-450/2-88-003b).
The principal objective of the current study was to update the profiles
in the Air Emissions Species Manual, Volume II with new information obtained
from contacts with principal researchers in the fields of PM speciation and
source receptor modeling. The new profiles were developed using the
procedures and protocols specified in the Air Emission Species Manual, Volume
II. These profiles are based on data voluntarily submitted by the
researchers.
Composition data are reported for four size ranges: 0-2.5 urn, 2.5-
10 urn, 0-10 urn, and total particulate measured. In addition, uncertainties
associated with composition data of each size interval are reported when
available. The size interval 0-10 urn is of particular interest in PM10 source
apportionment studies and in modeling efforts under the National Acid
Precipitation Assessment Program (NAPAP). When data for the 0-10 urn interval
were not reported by the sources listed, they were calculated from data for
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the 0-2.5 urn and 2.5-10 urn intervals according to procedures outlined in the
Air Emissions Species Manual, Volume II (refer to Appendix A). Uncertainty
values for the 0-10 urn size range were also calculated, when sufficient data
were available, based on the methodology discussed in the Air Emissions
Species Manual, Volume II (see Appendix A). Appendix A also contains a
procedure that may be used to estimate composition data for the 2.5-6 urn and
6-10 urn size intervals from data for the 2.5-10 urn size interval.
In addition to the composition data, mass fraction data (i.e., fraction
of mass of particulate emissions within a given size range) are also presented
in the profiles. These data are provided for the following size intervals:
0-2.5 urn, 0-6 urn, and 0-10 urn.. About 60 percent of the mass fraction data
were obtained from AP-42 (see Appendix B).
This update includes 158 new PM profiles representing 14 source
categories. Profiles were developed for two new source categories, metal
fabrication and construction, which were not covered in the Air Emissions
Species Manual, Volume II.
Each profile in this update was assigned the SCC or area source code
considered appropriate for the specific profile, based on engineering
judgement. Profile assignments were not made for all SCC's. This approach
differs from that followed in the Air Emissions Species Manual, Volume II,
which assigned profiles to all SCC's. Also, the Air Emissions Species Manual,
Volume II developed industry-specific average profiles from the profiles
available for each source category. This update does not develop average
profiles but reports only the composite profiles developed by the references
listed.
To provide the user/reader with guidance on the overall quality of data
contained in a given profile, each profile is ranked A, B, C, 0, or E, similar
to the ranking scheme used in AP-42. The overall quality ratings reflect the
uncertainties associated with composition data, mass fraction data,
calculational procedures (associated with the 0-10 urn range), and assumptions
about the composition of size fractions to fill data gaps. A more detailed
discussion on profile data quality is contained in Section 2.
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A secondary objective of the current study was to add eight new VOC
profiles to the VOC species data base. These eight new profiles were
developed based on recent testing of oil production operations by the Tulsa
City-County Health Department in Oklahoma. The Tulsa Health Department
provided the data to BPA for use in the VOC species profile data base. The
oil production operations testing program evaluated emissions of 30 light-ends
organics emitted from oil well heads and oil field crude oil storage tanks.
The procedures and formats for VOC profiles specified in the "Air Emissions
Species Manual - Volume I, VOC Species Profiles" were used to develop profiles
from the Tulsa test data. A detailed description of all data fields reported
for each profile is given in Section 4.
A third objective of this document is to present revisions that have
been made to three existing VOC profiles (EPA-450/2-88-003a). Revisions were
necessary to correct compound assignment errors caused by coelution of
compounds during gas chromatography analyses. The affected profiles are for
light-duty gasoline vehicles and are numbered 1101, 1203, and 1204.
Additional documentation on the derivation of mobile source profiles is
provided in Appendix E.
This Addendum also has the purpose providing the VOC Species Manual user
with the notification that the printed version of the existing manual, "Air
Emissions Species Manual - Volume I, Volatile Organic Compound Species
Profiles" (EPA-450/2-88-003a), contains erroneous CAS numbers for several
chemicals. The computerized version of the speciation data base system
contains correct CAS numbers. The hard copy report, however, is in error due
to a bug in the programming used to print the data. The programming bug
caused the last digit in the first field of the CAS number to be duplicated
automatically as the first digit of the second field of the number after the
dash. Examples are shown below:
624-46-6
109-96-0
760-02-3
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The user should verify any CAS number in the printed VOC speciation manual
(EPA-450/2-88-003a) with data- from other sources. This problem will be
corrected in the second edition of the manual to be published in the near
future.
This document is divided into five sections. Section 1 contains this
introduction. Section 2 describes the PM species profile format and discusses
the applicability of PM profiles. Section 3 contains the PM profiles for both
point and area sources. Section 4 contains a description of the VOC species
profile format and a discussion of the applicability of VOC profiles. The new
and revised VOC profiles are presented in Section 5.
There are five appendices that provide additional information.
Appendix A - PM Profile Calculations
Appendix 8 - Particle Size Distribution Data
Appendix C - Assignment of Source Classification and Area Source
Codes by Profile Number
Appendix D - PM Profile Compositing Procedure
Appendix E - Documentation of the Mobile Sources Profile Development
Procedures
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SECTION 2
SPECIES PROFILE FORMAT AND APPLICATION
2.1 PM'SPECIES PROFILE FORMAT
Table 2-1 is an example of the format used in presenting the PM profiles
in this document. Composition data and uncertainty information are reported
for size intervals 0-2.5 urn, 2.5-10 urn, 0-10 urn, and total particulate
measured. The size interval 0-10 urn is of particular interest in PM10 source
apportionment studies and in modeling and emission inventory preparation
efforts under NAPAP.
Particle size distribution data (i.e., fraction of mass in a given size
interval) are also included in the profiles in this document. The particle
size distribution data can be used in estimating size-specific particulate
emission rates in preparation of emission inventories. When combined with the
composition data from the profiles, these data can be used to estimate size-
specific and speciated particulate emission rates.
The profile ratings used in the Air Emissions Species Manual, Volume II
are adopted as data quality indicators. These ratings take into account the
uncertainties associated with mass fraction data, calculational procedures
used for the 0-10 urn size interval, and assumptions used in filling data gaps.
Each entry in Table 2-1 is described below:
Profile Name: The profile name is the descriptor used for the
applicable source category.
Profile Number; This is a unique number assigned to each profile.
The same numbering scheme used in the Air Emissions Species Manual,
Volume II is followed in this update. Profiles are coded into four
groups as follows: combustion sources (10000 series), industrial
processes (20000 series), mobile sources (30000 series), and area
sources (40000 series). Composite profiles developed during this
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TABLE 2-1. SAMPLE PROFILE
PM Profile Spec i an on Report
Profit* Name Di ammonium Phoshate Plant
Profile Number 25411
Data Quality D
Control Device Uneontrolled(a)
Reference(s) 1.17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30103001, 30103002, 30103003, 30103004
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) • (0-10)
Mass Fraction : 0.300 0.620 0.930
Total
Species
CAS Number
7440-41-7
7440 -42 -8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
~-0-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
No
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
Sym
Be
B
F
Na
"g
Al
Si
p
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co •
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
Mo
Pd
Ag
Cd
0-2.5
Xut
0.000
0.092
0.000
0.270
0.023
1.103
25.306
0.725
4.687
5.368
0.602
0.617
0.020
0.042
0.006
0.024
0.925
0.000
0.013
0.023
0.096
0.001
0.019
0.000
0.022
0.000
0.015
0.000
0.011
0.028
0.011
0.000
0.000
urn
unc
0.023
0.092
0.092
0.900
0.012
0.221
5.161
0.145
0.937
1.174
0.120
0.123
0.004
0.008
0.003
0.005
0.185
0.210
0.004
0.005
0.019
0.002
0.009
0.003
0.004
0.003
0.004
0.005
0.021
0.015
0.011
0.020
0.027
2.5-10 urn
Xut
MR
NR
NR
NR
NR
3.561
39.441
4.541
5.327
4.271
2.105
6.520
0.199
0.035
0.000
0.151
3.551
NR
0.000
0.251
0.091
0.000
0.000
0.000
0.000
0.000
0.229
0.000
0.000
0.334
0.340
0.077
0.439
unc
0.000
0.000
0.000
0.000
0.000
0.890
9.860
1.337
1.332
1.068
0.526
1.630
0.056
0.026
0.025
0.042
0.388
0.000
0.028
0.066
0.041
0.018
0.064
0.027
0.029
0.034
0.062
0.049
0.212
0.172
0.150
0.220
0.320
0-10
Xwt
NE
NE
NE
NE
NE
2.693
34.629
3.194
5.101
4.335
1.575
4.437
0.136
0.037
0.002
0.106
2.624
NE
0.005
0.171
0.093
0.000
0.007
0.000
0.008
0.000
0.153
0.000
0.004
0.226
0.224
0.050
0.284
urn
unc
0.000
0.000
0.000
0.000
0.000
0.555
6.424
0.316
0.912
0.329
0.329
' 1.000
0.037
0.017
0.015
0.029
0.551
0.074
0.017
0.043
0.028
0.011
0.038
0.016
0.017
0.020
0.041
0.029
0.126
0.105
0.092
0.131
0.192
Measured
Xut
NR
NR
NR
NR
MR
1.330
27.063
1.077
4.746
5.721
0.741
1.162
0.037
0.041
0.006
0.036
1.168
NR
0.011
0.044
0.096
0.001
0.018
0.000
0.020
0.000
0.003
0.000
0.010
0.056
0.041
0.007
0.041
unc
0.000
0.000
0.000
0.000
0.000
0.332
6.766
0.269
1.187
1.430
0.185
0.290
0.009
0.010
0.005
0.009
0.292
0.000
0.006
0.011
0.024
0.004
0.014
0.005
0.006
0.006
0.008
0.009
0.038
0.029
0.023
0.038
0.053
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TABLE 2-1. SAMPLE PROFILE (Continued)
PM Profile Speciation Report
continued (profile 25411)
Total
Spec i es
CAS Number
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
No
49
50
51
56
57
30
82
203
204
Sym
In
Sn
Sb
Ba
La
Hg
Pb
S04
N03
0-2.5 urn
Xut
0.012
0.000
0.000
0.000
0.000
0.005
0.081
3.220
3.780
unc
0.030
0.037
0.064
0.172
0.239
0.005
0.016
0.310
0.950
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
4.411
0.000
0.194
NR
NR
unc
0.302
0.390
0.675
1.810
2.769
0.037
0.105
0.000
0.000
0-10
Xwt
0.004
0.000
0.000
0.000
2.854
0.002
0.154
NE
NE
urn
unc
0.180
0.232
0.402
1.077
1.656
0.022
0.065
0.000
0.000
Measured
%ut
0.011
0.000
0.000
0.000
0.407
0.047
0.091
NR
NR
unc
0.055
0.070
0.120
0.323
0.462
0.076
0.023
0.000
0.000
TOTALS:
48.147
76.068
63.608
44.032
(a) Mo control. specified; thus, assumed uncontrolled.
(b) Calculated baaed on methodology described In the Air Emissions Species Manual, Volume II.
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study from individual profiles are assigned profile numbers in the same
series. For example, the profile Paved Road Dust - SCAB Composite is
developed from Profiles 41123, 41124, and 41131-41135 and assigned the
number 41136.
Profile Data Quality: The data quality ratings include the data quality
associated with size distribution data and any assumptions associated
with developing the composition data for the 0-10 urn size interval and
filling data gaps. The guidelines used in assigning data quality
indicators are somewhat subjective.
It was assumed that the procedures for calculating composition data for
the 0-10 urn size interval using mass fraction data would lower the
overall profile data quality by one level. Additional assumptions about
missing data (e.g., no data reported for the 0-2.5 urn size interval)
would also lower the data quality by one or two levels. For example,
.for Profile 11210 (Coal-Fired Power Plant), composition data for the 0-
2.5 urn and 2.5-10 urn size intervals were not reported. To fill these
two data gaps, it was assumed that the composition data for these two
intervals are the same as that for the total particulate measured.
Thus, the data quality assigned to Profile 11210 in this document was
"E." Specifically, each data quality indicator represents the
following:
Data Quality A: Composition and mass fraction data obtained for the
size intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from several sources using
sound sampling and analytical methodology.
. Profiles are considered representative and
recommended for use.
Data Quality B: Composition and mass fraction data obtained for the
size intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from a few sources using a
generally sound methodology.
8
-------
Data Quality C: Composition data obtained for the size intervals
0-2.5 urn, 2.5-10 urn, and total particulate
measured from a few sources using a generally
. sound methodology and mass fraction data of
below average quality; or composition data
obtained for two of the three size intervals 0-
2.5 urn, 2.5-10 urn, and total particulate
measured from a large number of sources using a
sound methodology coupled with mass fraction
data of below average quality.
Data Quality D: Composition data obtained for size intervals
0-2.5 urn, 2.5-10 urn, and total particulate
measured obtained from a limited number of
sources using uncertain or undocumented
methodology coupled with mass fraction data of
average or below average quality; or composition
data obtained for two of the three size
intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from a few sources using a
generally sound methodology coupled with mass
fraction data of poor quality.
Data Quality E: Composition data obtained for the size intervals
0-2.5 urn, 2.5-10 urn, and total particulate
measured from a single source using poorly
documented methodology coupled with mass
fraction data of poor quality; or composition
data obtained for two of the three size
intervals 0-2.5 urn, 2.5-10 urn, and total
particulate measured from a limited number of
sources using poorly documented methodology
coupled with mass fraction data of poor quality;
or composition data obtained for one of the
three size intervals 0-2.5 urn, 2.5-10 urn, and
total particulate measured coupled with mass
fraction data of poor quality; or industry-
9
-------
specific average profiles; profiles with "E"
rating are recommended for use only if there is
no other information available.
Control Device: This entry is used to indicate if the profile data
represent emissions downstream or upstream of a control device (if
present). The downstream composition and size distribution of
particulate emissions would be affected by the presence of a control
device.
Reference(s): This entry identifies the primary reference(s) used in
development of the profiles. If more detailed information is required
about the data contained in the profile, the user/reader should consult
these reference(s).
Data Source: This entry briefly describes the basis of the composition
data used'in the profile (e.g., number of tests, sources and samples,
sampling and analytical methods, how data were composited, etc.). More
detailed information about the data used can be obtained from the
references indicated in the profile.
SCC: This entry is the code for the source category for which the
profile was originally developed. These codes are obtained from NEDS
for point sources (1-01-001-01 through 5-03-900-10) and area sources (01
through 64). Area source codes from 65 through 115 developed under
NAPAP are also considered.
Mass Fraction Data: Size distribution data (i.e., the fraction of mass
[particulate emissions] contained within a specific size range) are
reported in this entry. Three size ranges are considered: 0-2.5 urn, 0-
6 urn, and 0-10 urn. When composition data for the 0-10 urn interval were
not reported, mass fraction data for 0-2.5 urn and 0-6 urn size ranges
were used to estimate composition data for the 0-10 urn size range.
10
-------
Mass fraction data for the 0-6 urn interval are presented as additional
information. A large portion of the mass fraction data was obtained
from AP-42. A detailed description of the mass fraction data (how data
were compiled, data quality, references, etc.) used \n this document is
included in Appendix B.
One area of concern is that the mass distribution data and the source
profiles used to estimate the composition of the 0-10 urn size range are
not from the same data set and represent data collected from different
emission sources. This introduces an additional source of uncertainty
when composition data for the 0-10 urn size interval are not reported and
must be calculated.
Species Identification: Each specie in the profile data is identified
by a species number, species name, and CAS number. In general., the
species number is the atomic number for the element. Other species are
arbitrarily assigned the numbers starting with 200 (e.g., total carbon -
200; organic carbon - 201; elemental carbon - 202; sulfate ion - 203,
etc.). The CAS numbers for the species were obtained from the Registry
of Toxic Effects of Chemical Substances (1983 Supplement to the 1981-82
edition).
The format for the species listed in the profiles in this update varies
somewhat from the format used in the Air Emission Species Manual,
Volume II. The profiles in this document include only those species for
which data are reported in the references given. .
Composition Data: In a typical profile, composition data expressed as
weight percent are presented for four size ranges: 0-2.5 urn, 2.5-10 urn,
0-10 urn, and total particulate measured. These data were extracted
directly from the reference(s) listed when available. For many
profiles, data for the 0-10 urn size interval were derived from
calculations based on the methodology described in the Air Emissions
Species Manual, Volume II (refer to Appendix A). In these profiles, a
footnote indicates that the data are based on calculations described in
Appendix A.
11
-------
In some cases, profile data were not complete (i.e., data were only
reported for one or two size intervals). In these cases, engineering
judgement was used to fill the data gaps. For example, in Profile 11210
(Coal-Fired Power Plants), composition data are reported only for the
total particulate measured. In absence of other information, it was
assumed that the composition data for the 0-2.5 urn, 2.5-10 urn, and 0-
10 urn size intervals were the same as that for the total particulate
measured. This assumption is indicated by footnote (a) for these three
size intervals. The following symbols are used in the composition data:
NR (not reported) and NE (not estimated). The NE symbol is used in
cases where a specific calculation could not be carried out due to
missing data.
Following the data tabulation, the percent of mass accounted for by the
composition data under each size interval is presented. This value is
based on the summation of weight percentages of the species in a given
column. The sum does not include oxygen, hydrogen, nitrogen, water, or
other components that were not included in the analysis. In some
profiles, the summation of weight percentages may be greater than 100
due to double counting (e.g., sulfur/sulfate, total carbon/elemental
carbon/organic carbon, etc.). Failure to include the carbonaceous,
oxygen, and hydrogen components in the aerosol characterization is often
the largest source of unexplained mass.
Since the composition data in weight percentages are associated with a
specific size interval, it is not possible to add the percentages for a
particular species across size intervals. For example, in Table 2-1,
the percentages for Al in the 0-2.5 urn, 2.5-10 urn, and 0-10 urn size
intervals are 0.230, 5.200, and 1.799; and 0.230 + 5.200 t 1.799.
Uncertainty; The uncertainty associated with composition data for the
size ranges 0-2.5 urn, 2.5-10 urn, and the total particulate measured are
based on either the estimated analytical precision of the measurement
(single sample) or the standard deviation of the data sets. For some
profiles, the uncertainty associated with the 0-10 urn size range is
calculated according to the procedure outlined in the Air Emissions
Species Manual, Volume II (refer to Appendix A). As Table 2-1 shows,
12
-------
footnotes indicate whether they are based on actual data
(i.e., extracted from the listed reference) or calculated. In many
cases, uncertainties were either not reported or not known by the
authors. The abbreviations used for uncertainty values include NR and
NE.
Date: This entry will be used to indicate the date the profile was last
reviewed/updated by EPA.
2.2 LIMITATIONS OF DATA
As indicated in the Air Emissions Species Manual, Volume II, the
reader/user should be aware of the limitations of each data set, specifically
with respect to measurements of carbonaceous emissions and volatile elements
(e.g., Pb, As, Hg, etc.) that partially exist in the gaseous phase at high
stack temperatures. Unless special precautions such as dilution source
sampling, aircraft, or balloon methods are exercised, these components will
not be accurately represented in the data. In addition, many of the studies
from literature do not report a sufficiently broad range of- particulate matter
components to account for the majority of the mass, typically due to the
specific sampling and analytical protocols employed. Therefore, studies that
use these source profiles (e.g., receptor modeling) may be unable to apportion
all of the ambient aerosol mass accurately. Thus, the user/reader is
cautioned to use these profiles with discretion. The profile data should be
carefully reviewed to ensure that they represent the sources being studied
reasonably well.
When composition data for the 0-10 urn size interval were calculated,
size distribution data were combined with composition data reported for the 0-
2.5 urn and 2.5-10 urn size intervals. The size distribution data and the
composition data from the source profiles represent data collected from
different emission sources. Therefore, this introduces an additional source
of uncertainty in calculating composition data for the 0-6 urn size interval.
13
-------
In several profiles, composition data information for one or two size
intervals were not reported. To increase the usefulness of the profiles,
certain assumptions were employed to fill these data gaps.
If data were reported for a single size interval, it was assumed
that data for the other two intervals were the same. Values for
the 0-10 urn size interval were also assumed to be the same.
If data for the 0-2.5 urn size interval were missing, it was
assumed the data for the 2.5-10 urn size interval could be
substituted and vice versa. Values for the 0-10 urn size interval
were also assumed to be the same.
If data for the total particulate measured were not reported,
assume the estimated data for the 0-10 urn size fraction can be
substituted.
Since the chemical composition of particulate emissions of many sources
is a function of particle size, application of data based on total particulate
measured to particulate mass in the fine particle fraction (0-2.5 urn) or
coarse particle fraction (2.5-10 urn) may affect the validity of the analysis.
Where such an assumption is made, it is indicated with a footnote in the
profile.
As pointed out in the Air Emission Species Manual, Volume II, the
user/reader should be aware of the potential variability in the chemical
composition of emissions, both within a source group and between similar
sources. Due to limited availability of high-quality, size-resolved profile
data sets, an indepth evaluation of the magnitude of profile variability is
not possible. However, comparisons of profiles in the literature based on the
total particulate measured indicate that profile variability is dependent on
the chemical composition of fuels or process materials, volatility, and
sampling and analytical procedures.
Profiles for individual sources may vary considerably from the values
provided in this document. Therefore, source-specific data from local sources
are preferable to the use of literature data and are recommended, particularly
14
-------
for regulatory applications. Nevertheless, preliminary analyses based on
source profiles in this document may be adequate to meet a number of
objectives. The reader/user must ultimately assess whether the data in the
document are appropriate for use in any particular application.
2.3 PM SPECIES PROFILE APPLICATION
There are several ongoing EPA activities that require speciated PM data
as an input parameter. These activities include preparation of air toxics
emission inventories, receptor modeling, preparation of acid precipitation
inventories, and acid precipitation modeling studies. This section provides a
specific example to illustrate how to use PM species profiles in preparation
of an air toxics emission inventory.
2.3.1 Document Guide
Appendix C provides a list of the point and area sources covered by the
profiles in Section 3. To identify the applicable profile for a given source
category, the user/reader should refer to Appendix C. The location of the
profile can then be determined using the profile number and the profile list
presented in Section 3.
2.3.2 Example of Use of a Profile
A hypothetical example will be used to describe how profiles might be
applied: a State air pollution control agency is developing-an air toxics
emission inventory for the State. An earlier study conducted for the State
has identified a list of potentially toxic species from several emission
sources. The emission rates of these individual species will be used as an
input to the proposed air toxics regulatory program for the State. The
proposed program advocates regulating particulate species in the fine fraction
(i.e., <2.5 urn).
The PM profiles can identify the relative amounts of individual
particulate species within specified size intervals in a given emission
15
-------
stream. In most cases, emission factors are available for total particulate
matter where the elemental breakdown is not specified (e.g., AP-42, Criteria
Pollutant Emission Factor Document).1'2 The information contained in this
document supplements the general emissions data in AP-42 or the Criteria
Pollutant Emission Factor Document. For a given source category, the
appropriate PM species profile should be identified using Appendix C and the
total particulate emission factor should be multiplied by the weight fractions
for each species in a given size interval, as given in the profile, to
determine size-specific individual emission factors.
In this example, arsenic is one of the species on a State's list and
emissions from a municipal waste incinertor are of concern. The incinerator
burns routine residential and commercial refuse and is uncontrolled. Since
the species profiles are keyed off of SCC, the first task is to determine the
SCC for the municipal waste incinerator. The SCC and PM emission factor for a
specific category can be obtained from the National Emissions Data System
(NEDS) or the Criteria Pollutant Emission Factor Document. These materials
would indicate that the appropriate SCC for municipal incinerators is 5-01-
001-01. The reader/user can then refer to the SCC/profile list in Appendix C
to identify which profiles correspond to the subject SCC. For 5-01-001-01,
two profiles, 17107 and 17108, are listed in Appendix C and the document page
numbers of each are given. At this point, the reader/user should review both
of the candidate profiles to see which corresponds to the particular source in
question. A review of the "Control Device" field shows that there is only one
profile for uncontrolled incincerators. This would be Profile 17108. A
review of the "Species" field indicates that arsenic is contained in the
profile. If there had been more than one profile applicable to this
situation, the reader/user could have consulted the "Data Source" field for
more refined information on which to make a profile selection, or the original
references(s) on which the profiles were based could be consulted. In cases
with multiple potentially applicable profiles, the "Data Quality" field may
also be useful in selecting the most preferred profile.
In Profile 17108, the weight percentage of cadmium (Cd) under the "0-
2.5 urn" column is 0.110 and the fraction of mass associated with this size
interval is 0.26. Applying the weight fraction of cadmium to the total
particulate emissions of 1,500,000 Ib/yr for the incinerator, cadmium
16
-------
emissions in the fine fraction are estimated as 1,500,000 x 0.0011 x 0.26 =
429 Ib/yr. The uncertainty associated with the cadmium weight percentage is
reported as 0.060 percent in the profile. From this information, a range for
cadmium emissions can be specified as follows:
1,500,000 x 0.26 x (0.0011 - 0.0006) = 195 Ib/yr
1,500,000 x 0.26 x (0.0011 + 0.0006) = 663 Ib/yr
Thus, the annual cadmium emissions in the 0-2.5 urn size range may be expected
to range from 195 to 663 Ib/yr, with a mean of 429 Ib/yr.
17
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2.4 REFERENCES FOR SECTION 2
1. U. S. Environmental Protection Agency. Compilation of Air
Pollutant Emission Factors, AP-42. Fourth Edition. Office of Air
Quality Planning and Standards, Research Triangle Park, North
Carolina. September 1985; Supplement A, October 1986; Supplement
B, September 1988.
2. U. S. Environmental Protection Agency. Criteria Pollutant Emission
Factors for the 1985 NAPAP Emissions Inventory. EPA-600/7-87-015.
Office of Research and Development, Air and Energy Engineering
Research Laboratory, Research Triangle Park, North Carolina. May
1987.
18
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SECTION 3
PM SPECIES PROFILES - POINT AND AREA SOURCES
This section contains the 158 PM profiles grouped in 14 separate
subsections according to source categories. The profiles representing point
sources are presented first, followed by those representing area sources. The
following list can be used to identify and locate the profiles for each source
category group. Individual profiles within each source category group are
presented in numerical order.
POINT SOURCES
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.1
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11212
11213
11214
11215
11301
11502
11503
11504
11505
11506
11507
11508
11509
11510
12301
12705
13502
13503
13504
EXTERNAL COMBUSTION BOILERS
Coal-Fired Power Plant
Power
Power
Power
Power
Power
Power
Power
Power
Power
Power
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Coal-Fired
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
External Combustion - Coal-Fired Composite
Uncontrolled Coal-Fired Power Plant Composite
Coal-Fired Power Plant/ESP Composite
Coal and RDF-Fired Power Plant
Oil-Fired Power Plant
Oil-Fired
Oil-Fired
Oil-Fired
Oil-Fired
Oil-Fired
Oil-Fired
Oil-Fired
Oil-Fired
Power
Power
Power
Power
Power
Power
Power
Power
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Plant
Composite
Kerosene-Fired Boiler Composite
Wood-Fired Boiler Composite
Heavy Oil-Fired Boiler Composite
Indonesian Oil-Fired Boiler Composite
Oil-Fired Boiler
Page Number
25
27
29
30
32
33
34
35
36
37
38
39
40
41
42
43
45
47
49
51
53
55
57
58
60
61
62
63
64
65
19
-------
POINT SOURCES (Continued)
Page Number
SECTION 3.1
Profile 14101
Profile 14102
Profile 15101
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
3.2 -
25408
25409
25410
25411
25412
25413
25414
25415
3.3
28304
28306
28307
29203
Profile 29204 -
Profile
Profile
Profile
29205
29206
29207
Profile 29208 -
Profile 29209 -
Profile 29210 -
Profile 29211 -
Profi1e
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
29310
29311
3.4
20103
20402
20403
20404
20405
20406
20503
29501
29502
- EXTERNAL COMBUSTION BOILERS (Continued)
- External Combustion - Waste Oil-Fired Boiler
- External Combustion - Liquid Waste-Fired Boiler
- External Combustion - Solid Waste-Fired Boiler
CHEMICAL MANUFACTURING
- Fertilizer Production - Phosphate Rock Dust
- Ammonium Nitrate - Prill Tower
- Ammonium Sulfate Production
- Diammonium Phosphate Plant
- Superphosphate Plant
- Superphosphate Granulation
- Sodium Tripolyphosphate - Cyclone Dust
- NPK Fertilizer
PRIMARY METAL PRODUCTION
Iron Ore Dust - Sinter
Steel Desulfurization Baghouse Dust
Steel Production - Basic Oxygen Furnace
Primary Copper Reverberatory Furnace -
Slag Tap
Primary Copper Reverberatory Furnace -
Slag Skim and Pour
Primary Copper Converter - Secondary Hood
Primary Copper converter - Secondary Hood
Primary Copper Flash furnace - Matte and
Slag Tap
Primary Copper - Process Stack
Primary Copper - Roaster
Primary Copper Reverberatory Furnace
Fugitives Composite
Primary Copper Converter - Secondary Hood
Composite
Primary Lead - Dross Building
Primary Lead - Slag Pour
SECONDARY METAL PRODUCTION
Secondary Aluminum - Dross Recovery Furnace
Secondary Lead - Sanitary Baghouse
Secondary Lead - Reverberatory Furnace
Secondary Lead - Melting Pot Fugitives
Secondary Lead - Melting Pot Stack
Secondary Lead - Yard Dust
Antimony Oxide Plant - Antimony Roasting
Secondary Copper Pyrometal - Cathode Charge
Secondary Copper Pyrometal - Regular Charge
66
67
68
69
71
72
73
74
76
78
80
82
83
85
86
87
89
90
91
92
93
94
95
96
97
98
99
101
103
104
105
106
107
108
109
110
111
20
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POINT SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
3.5
27204
27205
27502
27503
27601
27602
3.6
26203
26204
26205
26206
26207
26208
26209
SECTION 3.7
Profile 17107
Profile 17108
Profile 17109
SECTION 3.8
Profile 25701
Profile 25702
Profile 25703
AREA SOURCES
SECTION 3.9
Profile 41205
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
Profile
3.10
41111
41112
41113
41114
41115
41116
41117
41118
41119
Profile 41120
Profile 41121
Profile 41122
Profile 41123
- MINERAL PRODUCTS
- Portland Cement Dust
- Cement Ball Mill
- Gypsum Handling
- Gypsum Kiln
- Lime Handling
- Lime Kiln
- PETROLEUM INDUSTRY
- Petroleum Refinery Catalytic Cracker
- Petroleum Refinery Catalytic Cracker
- Petroleum Refinery Catalytic Cracker
- Coke Calciner
- Green Coke Dust
- Coke Cooler
- Catalytic Cracker Composite
- SOLID WASTE DISPOSAL
- Municipal Incinerator (East Chicago, IN)
- Municipal Incinerator (Philadelphia)
- Car Shredder
METAL FABRICATION
Metal Fabrication
Metal Fabrication
Metal Fabrication
Galvanizing (ZnO)
Sandblasting
Welding
UNPAVED ROADS
Unpaved Road Dust-Riverside, CA
PAVED ROADS
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
Paved Road Dust -
(Los Angeles, CA)
Paved Road Dust -
Paved Road Dust -
(Anaheim, CA)
Paved Road Dust -
Paved Road Dust -
Pasadena Freeway (CA)
Artesia Freeway (CA)
Long Beach Boulevard (CA)
Long Beach, CA
La Cienega Boulevard (CA)
Hawthorne, CA
Victory Boulevard (CA)
Burbank, CA
North Main Street
Los Angeles, CA
South Harbor Boulevard
Anaheim, CA
Riverside, CA
113
115
116
117
118
119
120
121
123
125
126
128
129
131
133
135
137
138
140
141
143
144
145
147
149
151
153
155
156
157
159
160
161
162
164
166
167
168
169
21
-------
AREA SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
Profile
3.10
41124
41131
41132
41133
41134
41135
41136
41137
3.11
41321
41322
41323
41324
41351
43304
•43305
43306
43307
43308
43309
3.12
42305
42306
42307
42308
42309
- PAVED ROADS (Continued)
- Paved Road Dust - Sepulveda Tunnel
(Los Angeles, CA)
- Paved Road Oust
- Paved Road Dust -
- Paved Road Oust -
- Paved Road Dust -
- Paved Road Dust -
- Paved Road Dust -
- Paved Road Dust -
- NATURAL SOURCES
Profile
Profile
Profile
Profile
Profile
Profile
Profile
42313
42314
42315
42316
42317
42318
42319
SECTION 3.13
Profile 31103
Profile 31104
Profile 31105
Composite
Long Beach.Composite
Hawthorne Composite
Burbank Composite
Los Angeles Composite
Anaheim Composite
SCAB Composite
Soil Dust
Soil Dust
Soil Dust
Soil Dust
Soil Dust
Limestone,
Shale, Crustal
Sandstone, Crustal
Sediment, Crustal
Igneous, Rock
Earth's Crust
Laurel, MD
Washington, DC
Riverside, CA
Hawthorne, CA
SCAB Composite
Crustal
Area
WOOD COMBUSTION
Slash Burning (Conifer -
Burning (Conifer -
Burning (Hardwood
Burning (Hardwood
Burning (Ponderosa
Profile 42310 -
Profile 42311 -
Profile 42312 -
Slash
Slash
Slash
Slash
Phase)
Slash Burning
Phase)
Slash Burning
Slash Burning
Phase)
Slash Burning
Slash Burning
Slash Burning
Slash Burning
Flaming Phase)
Smoldering Phase)
• Flaming Phase)
• Smoldering Phase)
Pine - Flaming
(Ponderosa Pine - Smoldering
(Tractor
(Tractor
Piled -
Piled -
Flaming Phase)
Smoldering
(Crane Piled
(Crane Piled
(Chaparral -
(Chaparral -
- Flaming Phase)
- Smoldering Phase)
Flaming Phase)
Smoldering Phase)
Wood Combustion - Las Vegas Valley (1987)
Residential Wood Combustion
Residential Wood Combustion Composite
MOBILE SOURCES
Light-Duty Vehicles
Light-Duty Vehicles
Light-Duty Vehicles
Leaded
Leaded
Leaded Composite
171
173
174
175
176
177
178
179
181
183
184
185
186
187
188
189
190
191
192
193
195
197
198
199
200
201
202
203
204
205
206
207
208
209
210
211
213
215
217
219
22
-------
AREA SOURCES (Continued)
Page Number
SECTION
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profile
Profi1e
Profile
Profile
Profile
Profile
SECTION
Profile
Profile
Profile
Profile
3.13
31202
31203
32102
32103
32104
32203
32204
32205
32206
33004
33005
33006
33007
33008
33009
33010
33011
34003
34004
34005
34006
3.14
44101
44102
44103
44104
Valley (1987)
Composite
MOBILE SOURCES (Continued)
Light-Duty.Vehicles - Unleaded
Light-Duty Vehicles - Unleaded
Light-Duty Vehicles - Diesel
Light-Duty Vehicles - Diesel
Light-Duty Vehicles - Diesel Composite
Heavy-Duty Vehicles - Diesel
Heavy-Duty Vehicles - Diesel
Diesel Vehicles - Las Vegas
Heavy-Duty Vehicles - Diesel
Transportation Composite
Transportation Composite
Transportation Composite
Composite
Composite
Composite
Gasoline Vehicles - Las Vegas Valley (1987)
Highway Vehicles Composite
Tire Wear
Brake Lining, Asbestos
Motor Oil
Semi-metal Disk Brake Pads
HEAVY CONSTRUCTION
Excavation - El Segundo, CA
Excavation - Haul Road
Rock Crushing
Sandblasting and Plastering
t
Transportation
Transportation
Transportation
220
222
224
226
228
229
231
232
233
234
236
238
240
242
244
246
247
249
250
251
252
253
255
256
257
258
23
-------
24
-------
3.1 EXTERNAL COMBUSTION BOILERS
External combustion sources include utility, industrial, commercial
and institutional boilers; commercial and domestic combustion units; process
heaters, furnaces, and kilns. Coal, oil, and natural gas are the major fossil
fuels used by these sources.
25
-------
26
-------
PM Profile Sped at ion Report
Profile Name
Profile Number
Data Quality
Coal-Fired Power Plant
11202
D
Control Device
Reference(s)
Data Source
Uncontrolled^!}
1,2
Data taken from Reference 1.
2.
For details, consult Reference
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
74AO-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
Nun
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
40
42
55
56
57
58
60
62
63
64
65
Sym
Na
Al
Si
P
S
ct
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Zr
Mo
Cs
Ba
La
Ce
Nd
Sm
Eu
Gd
Tb
0-2.5 urn
Xwt
0.
13.
21.
0.
3.
0.
1.
1.
0.
1.
0.
0.
0.
7.
0.
300
400
800
620
400
020
200
400
004
100
051
036
028
200
009
0.038
0.
0.
.0.
d.
0.
0.
0.
0.
029
039
NR
061
024
003
018
129
063
0.017
0.
0.
0.
0.
0.
0.
0.
001
300
011
017
007
002
001
NR
0.000
unc
0.020
1.500
1.600
0.060
0.600
0.011
0.090
0.500
0.000
0.1QO
0.014
0.012
0.001
0.400
0.001
0.005
0.002
0.005
0.000
0.308
0.002
0.001
0.008
0.006
0.014
0.006
0.000
0.190
0.001
0.001
0.002
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.060
2.5-10 urn
Xwt
0.410
18.400
18.500
0.220
0.540
0.103
1.330
2.300
0.004
1.300
0.043
0.019
0.022
8.100
0.008
0.032
0.024
0.028
0.016
0.020
0.002
0.001
0.012
0.123
0.042
0.007
0.001
0.094
0.013
0.019
0.007
0.003
0.001
0.004
0.000
unc
0.020
2.700
2.800
0.040
0.070
0.005
0.080
0.300
0.000
0.200
0.009
0.001
0.001
0.400
0.000
0.002
0.001
0.002
0.006
0.007
0.000
0.001
0.001
0.025
0.014
0.001
0.000
0.016
0.001
0.001
0.001
0.000
0.000
0.002
0.000
<0-6)
0.170
0-10
Xwt
0.381
17.096
19.361
0.324
1.286
0.081
1.296
2.065
0.004
1.248
0.045
0.023
0.024
7.865
0.008
0.034
0.025
0.031
NE
0.031
0.008
0.001
0.013
0.125
0.047
0.010
0.001
0.148
0.013
0.018
0.007
0.002
0.001
NE
0.000
unK2}
unc
0.021
1.591
1.761
0.035
0.204
0.006
0.075
0.217
0.001
0.119
0.007
0.004
0.002
0.411
0.001
0.003
0.002
0.003
0.000
0.005
0.001
0.000
0.003
0.015
0.009
0.002
0.000
0.052
0.002
0.002
0.001
0.001
0.000
0.000
0.000
(0-10)
0.230
Total
Measured
Xut
0.382
17.104
19.356
0.324
1.282
0.082
1.296
2.067
0.004
1.248
0.045
0.023
0.024
7.867
0.008
0.034
0.025
0.031
0.012
0.031
0.008
0.001
0.013
0.125
0.047
0.010
0.001
0.147
0.013
0.018
0.007
0.002
0.001
0.003
0.000
unc
0.020
2.114
2.246
0.038
0.189
0.005
0.078
0.265
0.000
0.157
0.008
0.003
0.001
0.418
0.001
0.002
0.001
0.002
0.005
0.006
0.001
0.001
0.002
0.019
0.011
0.002
0.000
0.051
0.001
0.001
0.001
0.000
0.000
0.001
0.000
27
-------
PM Profile Speciation Report - continued (profile 11202)
Total Paniculate Hatter -
CAS Number
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-33-7
7439-92-1
7440-29-1
spec i es
Num Sym
70
71
72
73
74
82
90
201
203
Yb
Lu
Hf
Ta
W
Pb
Th
OC
S04
0-2
%wt
0
0
0
0
0
0
11
.001
NR
.001
NR
.002
.041
.002
.890
.900
.5 urn
unc
0.000
0.000
0.000.
0.000
0.001
0.004
0.000
0.120
0.600
2.5-10 urn
Xut
0.001
0.000
0.001
0.000
0.001
0.026
0.003
2.000
2.400
unc
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.100
0.200
0-10
Xwt
0.001
NE
0.001
NE
0.002
0.030
0.003
1.710
4.878
unK2>
unc
0.000
0.000
0.000
0.000
0.001
0.003
0.001
0.088
0.482
Total
Measured
Xut
0.001
0.000
0.001
0.000
0.002
0.030
0.003
1.712
4.863
unc
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.095
0.397
TOTALS:
64.165
56.180
58.247
58.253
O> No control specified; thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
28
-------
PM Profile Speciat ion Report
Profile Name Coal-Fired Power Plant
Profile Number 11203
Data Quality C
Control Device Cyclonic Precipitator
Reference(s) 3,4
Data Source Sampled with an Andersen
AES, X-ray spectrometry,
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
Spec i es
CAS Number
7440-41-7
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-43-9
7440-31-5
7440-36-0
7440-28-0
7439-92-1
TOTALS:
Nun
4
12
13
14
16
19
20
22
23
24
25
26
27
28
29
30
33
34
48
50
51
81
82
200
Sym
Be
Mg
At
Si
S
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Cd
Sn
Sb
Tl
Pb
TC
0-2
Xwt
0.006
0.463
13.600
27.000
40.933
3.400
3.400
1.247
0.050
0.353
0.050
15.667
0.013
0.173
0.030
1.300
0.180
0.007
0.004
0.002
0.006
0.008
0.163
0.640
108.695
.5 um
unc
0.000
0.093
2.720
5.400
2.047
0.170
0.170
0.062
0.008
0.071
0.002
3.133
0.004
0.035
0.006
0.390
0.036
0.001
0.001
0.000
0.002
0.002
0.033
0.128
impact or. Analyzed using AAS, dc
and spark-source MS.
: (0-2.5) (0-6)
: 0.610 0.840
2.5-10 um
Xwt
0.004
1.064
18.948
31.714
11.096
4.653
4.653
1.182
0.026
0.069
0.020
13.741
0.008
0.054
0.034
0.838
0.089
0.002
0.002
0.001
0.003
0.005
0.135
0.669
89.010
unc
0.000
0.213
3.790
6.394
0.555
0.233
0.233
0.059
0.004
0.014
0.001
2.748
0.002
0.011
0,007
0.251
0.018
0.000
0.000
0.000
0.001
0.002
0.027
0.134
0-10
Xwt
0.005
0.804
16.633
29.674
24.011
4.111
4.111
1.210
0.036
0.192
0.033
14.575
0.010
0.106
0.032
1.038
0.128
0.004
0.003
0.001
0.004
0.006
0.147
0.656
97.530
unKO
unc
0.005
0.157
2.998
5.273
2.735
0.342
0.342
0.111
0.010
0.044
0.009
2.530
0.005
0.025
0.008
0.255
0.027
0.003
0.002
0.002
0.003
0.004
0.029
0.118
(0-10)
0.930
Total
Measured
0
0
18
30
16
4
4
1
0
0
0
14
0
0
0
0
0
0
0
0
0
0
0
0
92
:===
r.wt
.005
.958
.004
.382
.362
.432
.432
.193
.030
.119
.025
.081
.009
.075
.033
.919
.106
.003
.002
.001
.003
.006
.140
.664
.484
ss==
unc
0.000
0.192
3.601
6.176
0.818
0.222
0.222
0.060
0.005
0.024
0.001
2.816
0.003
0.015
0.007
0.276
.0.021
0.001
0.000
0.000
O.OOT
0.002
0.028
0.133
O> Calculated based on methodology in the Air Emissions Species Manual, Volume II.
29
-------
PM Profile Speciat ion Report
Profile Name Coal-Fired Power
Profile Number 11204
Data Quality C
Plant
Control Device ESP
Reference(s) 3,5
Data Source Sanpled with a SASS train. Analyzed using XRF, INAA, and
FAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) <0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matter
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-56-4
7440 -38- 3
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-27-9
7440-64-4
7440-58-6
7440-25-7
^yvi* i ca
Hum Sym
11
13
14
16
19
20
21
22
24
25
26
27
28
29
30
31
32
33
34
35
37
38
48
50
51
55
56
57
58
62
63
65
70
72
73
Na
Al
Si
S
K
Ca
Sc
Ti
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Cd
Sn
Sb
Cs
Ba
La
Ce
Sin
Eu
Tb
Yb
Hf
Ta
0-2
Xut
0.996
11.567
17.795
3.959
1.954
6.495
0.002
0.906
0.027
0.097
10.445
0.004
0.017
0.014
0.225
0.013
0.018
MR
0.001
NR
0.014
0.148
NR
0.002
0.002
0.001
0.722
0.010
0.015
0.002
0.000
0.000
0.001
0.000
0.000
.5 urn
unc
0.286
6.345
9.090
1.521
0.442
1.191
0.000
.0.227
0.009
0.027
1.393
0.001
0.003
0.004
0.029
0.004
0.005
0.000
0.000
0.000
0.002
0.021
0.000
0.000
0.001
0.000
0.095
0.003
0.005
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 um
Xut
0.853
11.597
22.000
1.126
1.740
8.418
0.002
0.702
0.018
0.077
10.754
0.003
0.011
0.009
0.136
0.006
0.012
0.005
0.000
0.000
0.010
0.135
0.001
0.002
0.002
0.001
0.410
0.008
0.013
0.001
0.000
0.000
0.000
0.001
0.000
unc
0.200
4.237
7.996
0.420
0.311
1.100
0.000
0.157
0.003
0.017
0.995
0.001
0.001
0.002
0.013
0.002
0.003
0.001
0.000
0.000
0.001
0.019
0.000
0.001
0.001
0.000
0.039
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.915
11.584
20.180
2.352
1.833
7.586
0.002
0.790
0.022
0.086
10.620
0.003
0.014
0.011
0.175
0.009
0.015
ME
0.000
NE
0.012
0.141
NE
0.002
0.002
0.001
0.545
0.009
0.014
0.001
0.000
0.000
0.000
0.001
0.000
um<1>
unc
0.197
4.010
6.728
0.759
0.318
1.043
0.002
0.160
0.008
0.021
1.196
0.002
0.005
0.005
0.027
0.005
0.006
0.000
0.001
0.000
0.004
0.023
0.000
0.002
0.002
0.001
0.074
0.004
0.005
0.002
0.000
0.000
0.001
0.000
0.000
(0-10)
0.670
Total
Measured
Xwt
0.
11.
21.
1.
1.
8.
0.
0.
0.
0.
'10.
0.
0.
0.
0.
0.
0.
- 0.
'o.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
864
579
683
339
756
273
002
717
019
078
731
003
012
009
143
007
013
NR
000
NR
010
136
NR
002
002
001
434
008
013
001
000
000
000
001
000
unc
0.186
3.947
7.426
0.405
0.289
1.022
0.000
0.146
0.003
0.016
0.926
0.001
0.001
0.002
0.013
0.001
0.003
0.000
0.000
0.000
0.001
0.018
0.000
0.001
0.001
0.000
0.036
0.002
0.003
0.000
0.000
0.000
0.000
0.000
0.000
30
-------
PM Profile Speciation Report - continued (profile 11204)
Total Participate Matter -
Total
CAS Number
7440-33-7
7439-92-1
7440-29-1
7440-61-1
opec i es
Num Sym
74
82
90
92
U
Pb
Th
U
0
0
0
0
0-2
Xut
.001
.114
.002
.001
.5 urn
unc
0.000
0.016
0.001
0.000
2.5-10 urn
Xut
0.001
0.075
0.002
0.001
unc
0.000
0.007
0.001
0.000
0-10
Xut
0.001
0.092
0.002
0.001
um<1> Measured
unc
0.001
0.016
0.002
0.001
Xut
0.001
0.078
0.002
0.001
unc
0.000
0.007
0.000
0.000
TOTALS:
O>
55.570
58.132
57.021
Calculated based on methodology described in the Air Emission
Volume II.
57.918
Species Manual,
31
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Coal -Fired Power Plant
11205
C
Control Device ESP
Reference(s) 3,6
Data Source Plant A sampled with EPA Method 5 and Andersen impact or.
Analyzed using XRF and INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7439-92-1
TOTALS:
aycv tvs
Nun Sym
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
82
{1> Calculated
Na
Mg
Al
Si
S
<
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zr\
As
Se
Pb
based on
0-2
Xwt
0.168
1.656
10.018
17.120
0.501
1.136
0.575
0.614
0.051
0.064
0.023
2.330
0.028
0.023
0.039
0.062
0.014
0.016
34.438
.5 urn
unc
0.025
0.331
1.503
2.568
0.050
0.170
0.058
0.092
0.005
0.013
0.003
0.350
0.007
0.003
0.006
0.009
0.004
0.009
2.5-10
Xwt
0.384
3.770
23.103
40.031
0.405
2.180
0.750
1.435
0.067
0.065
0.030
3.523
0.017
0.030
0.086
0.030
0.005
0.024
75.935
methodology described in
0
0
3
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.059
.479
.535
.1.08
.135
.573
.215
.261
.009
.021
.010
.708
.007
.008
.026
.010
.002
.008
0-10
Xwt
0.291
2.855
17.439
30.114
0.447
1.728
0.674
1.080
0.060
0.065
0.027
3.007
0.022
0.027
0.066
0.044
0.009
0.021
57.976
umO}
unc
0.047
0.399
2.687
4.637
0.101
0.403
0.154
0.193
0.011
0.018
0.009
0.535
0.008
0.008
0.019
0.012
0.005
0.008
(0-10)
0.670
Total
Measured
Xwt
0.316
3.103
18.971
32.796
0.435
1.850
0.146
1.176
0.062
0.065
0.040
3.146
0.020
0.028
0.071
0.040
0.008
0.022
62.295
unc
0.039
0.310
2.371
4.100
0.091
0.389
1.022
0.176
0.006
0.014
0.006
0.472
0.004
0.006
0.018
0.006
0.001
0.004
the Air Emission Species Manual,
Volume II.
32
-------
PM Profile Speciation Report
Profile Name Coal-Fired Power
Profile Number 11206
Data Quality C
Plant
Control Device ESP
Reference(s) 3,6
Data Source Plant 8 sampled with EPA Method 5 and Andersen impactor.
Analyzed using XRF and INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7439-92-1
TOTALS:
^^KTV 1 C3
Nun Sym
11
12
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
82
Na
Mg
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Pb
0-2
Xwt
0
0
4
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
13
.076
.673
.093
.550
.199
.051
.393
.234
.260
.020
.015
.015
.953
.010
.015
.015
.015
.010
.000
.597
.5 urn
unc
0.009
0.336
1.023
2.129
0.066
0.006
0.099
0.070
0.105
0.014
0.017
0.014
0.238
0.008
0.014
0.014
0.011
0.007
0.000
2.5-10 urn
Xwt
0.146
1.649
10.730
17.729
0.402
0.023
0.927
0.373
0.589
0.023
0.041
0.017
2.390
0.023
0.017
0.029
0.017
0.000
0.000
35.125
unc
0.025
0.716
9.702
15.948
0.634
0.022
0.235
0.179
0.292
0.029
0.035
0.030
0.911
0.028
0.030
0.028
0.029
0.014
0.000
0-10
Xwt
0.116
1.227
7.857
12.890
0.314
0.035
0.696
0.313
0.447
0.022
0.030
0.016
1.768
0.017
0.016
0.023
0.016
0.004
0.000
25.807
unKO
unc
0.021
0.501
6.420
10.569
0.419
0.017
0.169
0.125
0.201
0.021
0.025
0.021
0.621
0.019
0.021
0.020
0.020
0.010
0.000
(0-10)
0.670
Total
Measured
Xwt
0.109
1.128
7.189
11.765
0.294
0.038
0.642
0.299
0.413
0.022
0.027
0.016
1.623
0.016
0.016
0.022
0.016
0.005
0.011
23.651
unc
0.011
0.282
4.493
7.353
0.033
0.009
0.096
0.075
0.124
0.011
0.014
0.012
0.406
0.012
0.012
0.011
0.012
0.005
0.005
Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
33
-------
PM Profile Speciat ion Report
Profile Name Coal-Fired Power Plant
Profile Number 11207
Data Quality C
Control Device ESP
Reference(s) 3,6
Data Source Plant C sampled with EPA Method 5 and Andersen impactor.
Analyzed using XRF and INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Participate Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7439-92-1
TOTALS:
S3SSSSS3S3X
a^jcv i ca
Mum Sym
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
32
Ma
Mg
Al
Si
S
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
As
Se
Pb
0-2
Xwt
0.231
2.027
12.030
21.689
0.362
1.420
0.636
0.808
0.036
0.041
0.028
2.690
0.021
0.027
0.028
0.034
0.006
0.009
42.123
.5 urn
unc
0.058
0.507
3.308
5.422
0.109
0.403
0.184
0.173
0.008
0.014
0.008
1.009
0.004
0.008
0.008
0.009
0.002
0.008
2.5-
Xwt
0.366
3.021
15.144
25.945
0.327
1.512
0.562
1.173
0.036
0.026
0.006
3.192
0.021
0.018
0.028
0.002
0.003
0.036
51.418
SS32S3S—
10 urn
unc
0.115
0.354
4.078
6.975
0.126
0.437
0.186
0.274
0.010
0.013
0.013
1.118
0.016
0.010
0.011
0.007
0.002
0.012
0-10
Xwt
0.308
2.591
13.796
24.103
0.342
1.472
0.594
1.015
0.036
0.032
0.016
2.975
0.021
0.022
0.028
0.016
0.004
0.024
47.395
um<1>
unc
0.084
0.632
3.199
5.442
0.101
0.356
0.156
0.210
0.010
0.013
0.011
0.884
0.012
0.010
0.010
0.009
0.003
0.009
(0-10)
0.670
Total
Measured
%wt
0.
310
2.607
13.
24.
0.
1.
0.
1.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
47.
347
172
342
473
593
021
036
033
015
983
021
022
028
015
004
025
547
unc
0.063
0.451
1.939
3.379
0.058
0.191
0.077
0.143
0.004
0.005
0.007
0.498
0.009
0.005
0.006
0.002
0.001
0.006
O> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
34
-------
PM Profile Special ion Report
Profile Name Coal-Fired Power
Profile Number 11208
Data Quality E
Plant
Control Device ESP
Reference(s) 3,7
Data Source Samples collected isokinetically
by AAS and XRF.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0
Mass Fraction : 0
Total Particulate Matter -
CAS Number
7429-90-5
7439-89-6
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-36-0
7439-92-1
Num Sym
13
26
29
30
33
34
37
38
39
40
41
42
51
82
Al
Fe
Cu
Zn
As
Se
Rb
Sr
Y
Zr
Nb
Mo
Sb
Pb
0-2.5
Xwt
9
.200
7.400
0
0
0
0
0
0
0
0
0
0
0
0
.032
.037
.015
.006
.006
.247
.006
.019
.002
.006
.002
.013
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
using bag filters. Analyzed
-2.5) (0-6)
.290 0.500
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.670
Total
Measured
Xwt
9.200
7.400
0.032
0.037
0.015
0.006
0.006
0.247
0.006
0.019
0.002
0.006
0.002
0.013
unc
0.497
0.400
0.005
0.001
0.000
0.001
0.000
0.008
0.000
0.001
0.001
0.001
0.000
0.002
TOTALS:
16.991
16.991
16.991
16.991
C1> Estimated / extrapolated.
35
-------
PM Profile Special ion Report
Profile Name Coal-Fired Power Plant
Profile Number 11209
Data Quality E
Control Device Wet Scrubber
Reference(s) 3,7
Data Source Samples collected isokinetically using
backed up with wet impingers. Anlyzed
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.510
Total Particulate Matte
Species
CAS Number
7429-90-5
7439-39-6
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-36-0
7439-92-1
TOTALS:
Num
13
26
29
30
33
34
37
38
39
40
41
42
51
82
Sym
Al
Fe
Cu
Zn
As
Se
Rb
Sr
Y
Zr
Nb
Mo
Sb
Pb
r •
0-2.5
Xwt
7
4
0
0
0
0
0
0
0
0
0
0
0
0
.400
.900
.029
.060
.028
.044
.003
.247
.003
.008
.002
.011
.002
.034
unKO
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.771
2.5-10
Xwt
7.400
4.900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
alundum thimbles
by AAS and XRF.
(0-6)
0.620
0-10
Xwt
7.400
4.900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xwt
7.400
4.900
0.029
0.060
0.028
0.044
0.003
0.247
0.003
0.008
0.002
0.011
0.002
0.034
12.771
unc
0.999
0.300
0.010
0.012
0.008
0.011
0.001
0.004
0.002
0.001
0.001
0.002
0.001
0.008
O) Estimated / extrapolated.
36
-------
PM Profile Special ion Report
Profile Name Coal -Fired Power
Profile Number 11210
Data Quality E
Plant
Control Device ESP
Reference(s) 3,8
Data Source Samples collected isokinetically using EPA train with
12-minute runs. Analyzed by AAS and INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5.
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-3
7440-38-2
7782-49-2
7440-24-6
7440-74-6
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7429-91-6
7439-92-1
7440-29-1
Nun
11
12
13
19
20
21
22
23
24
25
26
27
28
29
33
34
38
49
51
56
57
58
62
63
66
82
90
Sym
Na
Mg
Al
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
As
Se
Sr
In
Sb
Sa
La
Ce
Sm
Eu
oy
Pb
Th
TOTALS:
0-2.5
Xwt
0
3
19
1
2
0
1
.280
.300
.700
.200
.600
.015
.800
0.062
0
0
11
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
41
.061
.074
.700
.013
.017
.021
.048
.031
.180
.001
.007
.160
.013
.035
.004
.001
.003
.011
.005
.342
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.280
3.300
19.700
1.200
2.600
0.015
1.300
0.062
0.061
0.074
11.700
0..013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 unK1>
Xwt
0.280
3.300
19.700
1.200
2.600
0.015
1.300
0.062
0.061
0.074
11.700
0.013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
41.342 41.342
(0-10)
0.670
Total
Measured
Xwt
0.280
3.300
19.700
1.200
2.600
0.015
1.800
0.062
0.061
0.074
11.700
0.013
0.017
0.021
0.048
0.031
0.180
0.001
0.007
0.160
0.013
0.035
0.004
0.001
0.003
0.011
0.005
41.342
unc
0.130
o.aoo
6.500
0.500
0.600
0.007
0.700
0.021
0.016
0.064
7.300
0.008
0.005
0.002
0.019
0.014
0.040
0.001
0.005
0.020
0.004
0.006
0.001
0.000
0.000
0.002
0.002
{1> Estimated / extrapolated.
37
-------
PM Profile Special ion Report
Profile Name
Profile Nunber
Data Quality
Coal-Fired Power Plant
11211
E
Control Device
Reference(s)
Data Source
Uncontrolled
3,9
Samples collected with a University of Washington Mark 10
impactor and an MR I Model 1502 impactor. Analyzed by INAA
and XRF.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Matter
CAS Number
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7439-96-5
7439-89-6
7440-55-3
7440-38-2
7782-49-2
7440-24-6
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-27-9
7440-58-6
7440-25-7
7440-29-1
TOTALS:
^yW 1 79
Num Sym
13
19
20
21
22
23
25
26
31
33
34
38
51
55
56
57
58
62
65
72
73
90
Al
K
Ca
Sc
Ti
V
Mn
Fe
Ga
As
Se
Sr
Sb
Cs
Sa
la
Ce
Sm
Tb
Hf
Ta
Th
0-2.5
Xut
9
0
2
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.325
.423
.883
.001
.429
.009
.023
.761
.004
.003
.001
.135
.000
.000
.190
.005
.009
.001
.000
.001
.000
.002
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
16.205
: (0-2.5)
0.060
2.5-10
%wt
9.325
0.423
2.383
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
unK1>
unc
0.000
0.000
O.QOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.170
0-10
Xwt
9.325
0.423
2.883
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.230
Total
Measured
%ut
9.325
0.423
2.883
0.001
0.429
0.009
0.023
2.761
0.004
0.003
0.001
0.135
0.000
0.000
0.190
0.005
0.009
0.001
0.000
0.001
0.000
0.002
16.205
unc
1.119
0.051
0.346
0.000
0.052
0.001
0.003
0.331
0.000
0.000
0.000
0.135
0.000
0.000
0.023
0.001
0.001
0.000
0.000
0.000
0.000
0.000
<1> Estimated / extrapolated.
38
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Coal-Fired Power Plant
11212
E
Control Device ESP
Reference(s) 3,10
Data Source Samples collected using ASTM sampling train; two data sets
consisting of three 4 to 5-hr runs per set. Analyzed by XRF,
GC. flame Iess AAS, and INAA.
SCC Assignments: 10100203
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Number
7440-23-5
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7782-49-2
7440-17-7
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-58-6
7440-25-7
7439-92-1
7440-29-1
TOTALS:
apci* i ca
Hum Sym
11
13
19
20
21
22
23
24
25
26
27
30
33
34
37
48
51
55
56
57
58
62
63
72
73
82
90
Na
Al
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Zn
As
Se
Rb
Cd
sb
Cs
Ba
La
Ce
Sm
Eu
Hf
Ta
Pb
Th
0-2.5
Xwt
1.
7.
2.
3.
0.
0.
0.
0.
0.
15.
0.
129
576
424
182
004
985
121
089
043
152
007
0.591
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
31.
044
009
019
005
005
003
075
004
012
001
000
000
000
065
003
548
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.360
2.5-10
Xwt
1.129
7.576
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
0.044
0.009
0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
31.548
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.560
0-10
Xut
1.129
7.576
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
• 0.044
0.009
0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
31.548
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.680
Total
Measured
%wt
1.129
7.576
2.424
3.182
0.004
0.985
0.121
0.089
0.043
15.152
0.007
0.591
0.044
0.009
0.019
0.005
0.005
0.003
0.075
0.004
0.012
0.001
0.000
0.000
0.000
0.065
0.003
31.548
unc
0.068
0.379
0.152
0.152
0.001
0.152
0.015
0.005
0.006
0.758
0.000
0.045
0.003
0.000
0.001
0.003
0.001
0.000
0.011-.
0.000
0.001"
0.000
0.000
0.000
0.000
0.003
0.000
C1> Estimated / extrapolated.
39
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
External Combustion - Coal-Fired Composite
11213
E
Control Device
Reference(s)
Data Source
Two bag filters, one ESP, and two uncontrolled.
3,11
Composite of five coal fired plants in Japan. Samples
collected on on PTFE filters and analyzed using XRF and
INAA.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Hatter
CAS Number
7440-23-5
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
TOTALS:
^pcw i ?a
Hum Sym
11
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
51
55
56
57
82
Ma
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
Sb
Cs
Ba
La
Pb
0-2.5
Xut
0.970
2
1
1
.600
.500
.100
1.000
2
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
.300
.001
.260
.013
.040
.031
.800
.010
.018
.130
.300
.026
.016
.005
.004
.008
.001
.110
.001
.200
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
12.444
: (0-2.5)
: 0.290
2.5-10
Xwt
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.800
0.010
0.018
0.130
0.300
0.026
0.016
0.005
0.004
0.008
0.001
0.110
0.001
0.200
12.444
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.500
0-10 unO)
Xwt
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.800
0.010
0.018
0.130
0.300
0.026
0.016
0.005
0.004
0.008
0.001
0.110
0.001
0.200
12.444
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.200
(0-10)
0.670
Total
Measured
%ut
0.970
2.600
1.500
1.100
1.000
2.300
0.001
0.260
0.013
0.040
0.031
1.300
0.010
0.018
0.130
0.300
0.026
0.016
-.0.005
0.004
' 0.008
0.001
0.110
0.001
0.000
12.244
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Estimated / extrapolated.
40
-------
PH Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Uncontrolled Coal-fired Power Plant Composite
11214
E
Control Device
Reference(s)
Data Source
Uncontrolled
Profile represents a composite of Profiles 11202 and 11211
uncontrolled utility boiler, wet bottom design, firing
pulverized bituminous coal.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7439-96-5
7439-89-6
7440-38-2
7782-49-2
7440-24-6
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-27-9
7440-58-6
7440-29-1
apw I ca
Nun Sym
13
19
20
21
22
23
25
26
33
34
38
55
56
57
58
62
65
72
90
Al
1C
Ca
Sc
Ti
V
Hn
Fe
As
Se
Sr
Cs
Ba
La
Ce
Sm
Tb
Hf
Th
11
0-2
Xwt
.363
0.812
2
0
0
0
0
4
0
0
0
.142
.003
.765
.030
.026
.981
.032
.013
.132
0.001
0
0
0
0
0
0
0
.245
.008
.013
.002
.000
.001
.002
.5 urn
uncCD
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.060
2.5-10 un
Xwt
13.863
0.877
2.592
0.003
0.865
0.026
0.023
5.431
0.012
0.002
0.129
0.001
0.142
0.009
0.014
0.002
0.000
0.001
0.003
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000 .
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.170
0-10 urn
Xwt
13.211
0.860
2.474
0.003
0.839
0.027
0.024
5.313
0.017
0.005
0.130
0.001
0.169
0.009
0.014
0.002
0.000
0.001
0.003
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.465
Total
Measured
Xwt
13.215
0.860
2.475
0.003
0.839
0.000
0.024
5.314
0.017
0.005
0.130
0.001
0.169
0.009
0.014
0.002
0.000
0.001
0.003
unc{1>
0.000
0.000
0.000
0.000
0.000
0.300
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 20.571
==2==s=2==ss======ssac=3=s===sssss=
<1> Uncertainty not evaluated.
23.995
23.102
23.081
41
-------
PM Profile Speciat ion Report
Profile Name Coal -fired Power
Profile Nutter 11215
Data Quality D
Plant/ESP Composite
Control Device ESP
Reference(s)
Data Source Profile represents a composite of Profiles 11204, 11205,
11206, 11207, 11208, 11210, and 11212.
SCC Assignments: 10100201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7440-36-0
7439-92-1
TOTALS:
z==s3sssass=
ape*, i ca
Hum Sym
11
12
13
14
16
19
20
22
23
24
25
26
28
29
30
33
34
51
82
=====3
Na
Mg
Al
Si
s
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
AS
Se
Sb
Pb
0-2.5 urn
Xut
0.480
1.914
10.598
15.789
1.255
1.421
2.287
0.896
0.058
0.050
0.047
7.239
0.019
0.022
0.156
0.036
0.011
0.004
0.033
42.315
unc£1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
0.526
2.935
13.864
26.426
0.565
1.665
2.648
1.114
0.062
0.050
. 0.041
7.730
0.018
0.021
0.151
0.023
0.008
0.004
0.032
57.883
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
•
0-10 urn
Xut
0.507
2.493
12.450
21.322
2.364
1.559
2.492
1.020
0.060
0.050
0.044
6.089
0.018
0.022
0.153
0.031
0.009
0.004
0.032
51.719
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
2
12
22
0
1
2
1
0
0
0
7
0
0
0
0
0
0
0
(0-10)
0.670
Total
Measured
r.wt
.501
.555
.580
.604
.603
.558
.516
.019
.061
.049
.044
.534
.017
.021
.149
.030
.009
.004
.032
uncO}
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
51.886
O> Uncertainty not evaluated.
42
-------
PM Profile Speciation Report
Profile Name Coal- and Refuse
Profile Number 11301
Data Quality 0
Derived
Fuel (RDF)-Fired Power Plant
Control Device ESP
Reference(s) 3,5
Data Source Sampled with a SASS train. Analyzed using XRF, INAA, and
FAA.
SCC Assignments: 10100201, 10101201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.290 0.500
Total Particulate
Matter
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-3
7440-66-6
7440-55-3
7440-56-4
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-27-9
7440-64-4
7440-58-6
7440-25-7
Qtjefc. ' e*
Num Sym
11
13
14
16
19
20
21
22
24
25
26
27
28
29
30
31
32
33
34
35
37
38
48
50
51
55
56
57
58
62
63
65
70
72
73
Na
A I
Si
S
K
Ca
Sc
Ti
Cr
Hn
Fe
Co
Ni
Cu
Zn
Ga
Ge
As
Se
Br
Rb
Sr
Cd
Sn
Sb
Cs
Ba
La
Ce
Sm
Eu
Tb
Yb
Hf
Ta
(0-10)
0.670
Total
0-2.5 urn
%ut
0.809
9.701
17.639
4.687
2.165
6.570
0.002
0.830
0.036
0.122
13.323
0.004
0.018
0.018
0.496
0.015
0.022
0.008
0.001
0.001
0.010
0.115
0.010
0.008
0.007
0.001
0.344
0.009
0.015
0.002
0.000
0.000
0.001
0.000
0.000
unc
0.317
5.609
10.198
2.129
0.648
2.148
0.001
0.292
0.013
0.045
3.728
0.002
0.005
0.006
0.134
0.007
0.008
0.003
0.000
0.000
0.003
0.042
0.003
0.002
0.002
0.001
0.092
0.004
0.006
0.001
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.736
11.202
20.550
1.480
1.753
7.971
0.002
0.683
0.021
0.088
12.899
0.003
0.011
0.009
0.201
0.006
0.011
0.005
0.001
0.001
0.009
0.083
0.002
0.003
0.004
0.001
0.201
0.007
0.011
0.001
0.000
0.000
0.001
0.000
0.000
unc
0.165
4.135
7.367
0.527
0.265
1.166
0.000
0.148
0.003
0.019
1.047
0.001
0.001
0.002
0.018
0.002
0.003
0.001
0.000
0.001
0.002
0.016
0.000
0.001
0.001
0.000
0.019
0.002
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.768
11.021
20.200
1.866
1.803
7.802
0.002
0.701
0.023
0.092
12.950
0.003
0.012
0.010
0.236
0.007
0.012
0.005
0.001
0.001
0.009
0.087
0.003
0.004
0.004
0.001
0.218
0.007
0.011
0.001
0.000
0.000
0.001
0.000
0.000
umO>
unc
0.187
3.728
6.705
1.030
0.368
1.320
0.002
0.173
0.009
0.028
2.018
0.003
0.005
0.006
0.072
0.006
0.007
0.004
0.001
0.001
0.004
0.025
0.004
0.003
0.003
0.001
0.052
0.004
0.005
0.002
0.000
0.000
0.001
0.000
0.000
Measured
0
11
"20
1
1
%ut
.741
.100
.352
.706
.782
7.875
0
0
0
0
12
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.002
.694
.022
.090
.933
.003
.012
.010
.222
.007
.012
.006
.001
.001
.009
.085
.003
.004
.004
.001
.211
.007
.011
.001
.000
.000
.001
.000
.000
unc
0.155
3.366
6.889
0.512
0.251
1.095
0.000
0.139
0.003
0.018
1.008
0.001
0.001
0.002
0.019
0.001
0.003
0.001
0.000
0.001
0.002
0.015
0.000
0.001
0.001
0.000
0.019
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
43
-------
PM Profile Speciation Report - continued (profile 11301)
Total Participate
Hatter
CAS Number
7440-33-7
7439-92-1
7440-29-1
7440-61-1
Hum Sym
74
82
90
92
U
Pb
Th
U
Total
0-2
Xwt
0.001
0.253
0.002
0.001
.5 urn
unc
0.000
0.068
0.001
0.000
2.5-10 urn
%wt
0.000
0.112
0.002
0.001
unc
0.000
0.010
0.000
0.000
0-10
Xwt
0.000
0.129
0.002
0.001
umO>
0
0
0
0
unc
.001
.039
.002
.001
Measured
Xwt
0.000
0.122
0.002
0.001
unc
0.000
0.011
0.000
0.000
TOTALS: 57.246 58.071 57.993 58.033
O) Calculated based on methodology in the Air Emissions Species Manual, Volume II.
44
-------
PM Profile Special ion Report
Profile Name Oi I -Fired Power Plant
Profile Number 11502
Data Quality E
Control Device Uncontrolled{1>
Reference(s) 3,12
Data Source Samples collected using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate Matter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
• 7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
.apci. i ca
Hum Sym
4
5'
9
11
12
13
14
15
16
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
56
Be
8
f
Na
Mg
Al
Si
P
S
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Mo
Cd
Sn
Sb
Ba
0
0
0
3
18
1
0
0
12
0
0
0
0
2
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-2.5 unK2>
Xwt
.000
.003
.000
.906
.380
.249
.310
.008
.317
.130
.999
.000
.050
.268
.010
.020
.609
.050
.658
.050
.004
.000
.003
.001
.001
.000
.050
.005
.005
.001
.010
.000
.002
.000
.100
one
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.300
0.000
0.000
0.000
0.000
-0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.000
0.003
0.000
3.906
18.380
1.249
0.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
o.'ooo
0.003
0.000
3.906
18.380
1.249
0'.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xwt
0.000
0.003
0.000
3.906
18.380
1.249
0.310
0.008
12.317
0.130
0.999
0.000
0.050
2.268
0.010
0.020
0.609
0.050
1.658
0.050
0.004
0.000
0.003
0.001
0.001
0.000
0.050
0.005
0.005
0.001
0.010
0.000
0.002
0.000
0.100
unc
0.000
0.000
0.000
0.200
0.919
0.060
0.020
0.001
0.609
0.006
0.050
0.000
0.005
0.110
0.001
0.002
0.031
0.005
0.080
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.005
45
-------
PH Profile Speciation Report - continued (profile 11502)
Total Partfculate
Matter
CAS Number
7439-91-0
7440-45-1
7440-28-0
7439-92-1
7440-29-1
7440-61-1
apec i es
Nun Sym
57
58
81
82
90
92
200
203
204
La
Ce
Tl
Pb
Th
U
TC
S04
N03
Total
0-2.5
Xut
0.004
0.005
0.001
0.300
0.001
0.001
12.387
36.861
0.005
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.004
0.005
0.001
0.300
0.001
0.001
12.387
36.861
0.005
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.004
0.005
0.001
0.300
0.001
0.001
12.387
36.861
0.005
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
0
0
0
0
0
0
12
36
0
Xwt
.004
.005
.001
.300
.001
.001
.387
.861
.005
unc
0.000
0.000
0.000
0.015
0.000
0.000
0.619
1.838
0.000
TOTALS:
91.764
91.764
91.764
91.764
CD No control specified; thus, assumed uncontrolled.
C2> Estimated / extrapolated.
46
-------
PM Profile
ReP°rt
p^Tile Name Oil -Fired Power Plant
Profile Murber 11505
Data Quality E
Control Device Uncontrolled^!}
Refer ence(s) 3,12
Data Source Samples collected using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate Matter
CAS Number
7440-41-7
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
&}JG\* i ca
Mum Sym
4
5
11
12
13
14
15
16
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
56
57
58
Be
8
Na
Mg
Al
Si
P
s
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Mo
Cd
Sn
Sb
Ba
La
Ce
0-2.5
Xut
0.
0.
0.
3.
0.
0.
0.
4.
0.
0.
0.
6.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
299
403
050
200
002
000
100
309
030
667
050
020
399
005
348
010
004
000
002
000
000
000
010
000
000
000
005
000
000
000
020
001
000
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Swt
0.000
0.000
0.299
3.403
0.050
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.848
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
umC2>
unc
0.000
0.000
JO. 000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
0.299
3.403
0.050
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.348
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Swt
0.000
0.000
0.299
3.403
0.050
0.200
0.002
4.000
0.100
0.309
0.030
6.667
0.050
0.020
0.399
0.005
0.848
0.010
0.004
0.000
0.002
0.000
0.000
0.000
0.010
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.020
0.001
0.000
unc
0.000
0.000
0.015
0.170
0.005
0.010
0.000
0.200
0.005
0.016
0.003
0.333
0.005
0.002
0.020
0.000
0.043
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
47
-------
PM Profile Speciation Report - continueo (orofile 11503)
Total Partfculate Hatter -
Tot'l
0-2.5 uiK2> 2.5-10 un<2> 0-10 um{2> Measured
Species
CAS Number Nun Sym Xut unc Xut unc Xwt unc Xwt unc
7439-92-1
7440-29-1
7440-61-1
82
90
92
200
203
204
Pb
Th
U
TC
S04
M03
0
0
0
68
11
0
.020
.000
.000
.862
.976
.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
68.862
11.976
0.013
0.002
0.000
0.000
3.443
0.599
0.001
TOTALS: 97.305 97.305 97.305 97.305
O> No control specified; thus, assumed uncontrolled.
C2> Estimated / extrapolated.
48
-------
PM Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Number 11504
Data Quality E
Control Device Uncontrolled^}
Reference(s) 3,12
Data Source Samples collected using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Particulate
Matter
(0-10)
0.710
Total
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30- 1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-39-3
•apw J ca
Mum Sytn
4
5
9
11
12
13
14
15
16
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
56
Be
a
f
Na
wg
Al
Si
P
s
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mb
Mo
Cd
Sn
Sb
Ba
0-2.5
Xwt
0
0
0
0
5
0
0
0
13
0
0
0
0
10
0
0
0
0
1
0
0
-0
0
0
0
0
0
.000
.001
.000
.500
.942
.400
.200
.004
.766
.100
.100
.001
.040
.204
.100
.020
.410
.020
.291
.020
.020
.005
.003
.001
.003
.001
.030
0.001
0
0
0
0
0
0
0
.002
.000
.010
.000
.001
.001
.020
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
um<2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.000
0.001
0.000
0.500
5.942
0.400
0.200
0.004
13.766
0.100
0.100
0.001
0.040
10.204
0.100
0.020
0.410
0.020
1.291
0.020
0.020
0.005
0.003
0.001
0.003
0.001
0.030
0.001
0.002
0.000
0.010
0.000
0.001
0.001
0.020
unc
0.000
0.000
0.000
0.025
0.297
0.020
0.010
0.000
0.688
0.005
0.005
0.000
0.004
0.510
0.005
0.002
0.021
0.002
0.065
0.002
0.002
0.001
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.002
49
-------
PM Profile Speciation Report - continued (profile 11504)
Total Participate
Matter
CAS Number
7439-91-0
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
spec i es
Hum Sym
57
58
74
81
82
90
92
200
203
204
La
Ce
U
Tl
Pb
Th
U
TC
S04
N03
Total
0-2.5
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
41.216
0.020
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2
0
0
0
0
0
0
0
21
41
0
.5-10
Xwt
.005
.003
.000
.000
.040
.001
.000.
.509
.216
.020
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
41.216
0.020
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.005
0.003
0.000
0.000
0.040
0.001
0.000
21.509
41.216
0.020
unc
0.001
0.000
0.000
0.000
0.004
0.000
0.000
1.080
2.061
0.002
TOTALS:
96.011
96.011
96.011
96.011
{1} No control specified; thus, assumed uncontrolled.
(2} Estimated / extrapolated.
50
-------
PM Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Number 11505
Data Quality E
Control Device Uncontrolled^}
Reference(s) 3,12
Data Source Samples collected using. EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Particulate Matter
Species
CAS Number
7440-.41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
Num
4
5
9
11
12
13
14
15
16
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
55
Sym
Be
3
F
Na
Mg
Al
Si
P
S
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Mo
Cd
Sn
Sb
Cs
0-2.5
Swt
0.000
0.000
0.000
1.995
2.494
0.010
0.050
0.001
19.196
0.100
0.200
0.000
0.040
12.821
0.050
0.050
0.479
0.030
2.275
0.040
0.040
0.006
0.003
0.000
0.002
0.000
0.030
0.001
0.002
0.000
0.010
0.000
0.000
0.001
0.000
unK2>
one
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2
.5-10 unK2>
%wt
0
0
.000
.000
0.000
1
2
0
0
0
19
0
0
0
0
12
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.995
.494
.010
.050
.001
.196
.100
.200
.000
.040
.821
.050
.050
.479
.030
.275
.040
.040
.006
.003
.000
.002
.000
.030
.001
.002
.000
.010
.000
.000
.001
.000
unc
0.000
0.000
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
0.000
1.995
2.494
0.010
0.050
0.001
19.196
0.100
0.200
0.000
0.040
12.821
0.050
0.050
0.479
0.030
2.275
0.040
0.040
0.006
0.003
0.000
0.002
0.000
0.030
0.001
0.002
0.000
0.010
0.000
0.000
0.001
0.000
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xut
0.000
0.000
0.000
1.995
2.494
0.010
0.050
0.001
19.196
0.100
0.200
0.000
0.040
12.821
0.050
0.050
0.479
0.030
2.275
0.040
0.040
0.006
0.003
0.000
0.002
0.000
0.030
0.001
0.002
0.000
0.010
0.000
0.000
0.001
0.000
unc
0.000
0.000
0.000
0.100
0.130
0.001
0.005
0.000
0.960
0.005
0.010
0.000
0.004
0.639
0.005
0.005
0.024
0.003
0.110
0.004
0.004
0.001
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
51
-------
PM Profile Speciation Report - continued (profile 11505)
Total Participate Matter
CAS Number
7440-39-3
7439-91-0
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
apec i es
Hum Sym
56
57
58
74
81
82
90
92
200
203
204
Ba
La
Ce
U
Tl
Pb
Th
U
TC
S04
N03
0-2.5
Xwt
' 0
0
0
0
0
0
0
0
1
57
0
.100
.005
.003
.000
.000
.040
.000
.001
.497
.468
.020
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
unK2)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xwt
0.100
0.005
0.003
0.000
0.000
0.040
0.000
0.001
1.497
57.468
0.020
unc
0.005
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.075
2.873
0.002
TOTALS:
99.060
99.060
99.060
{1} No control specified; thus, assumed uncontrolled.
(2> Estimated / extrapolated.
99.060
52
-------
PM Profile Speciation Report
Profile Name Oil -Fired Power Plant
Profile Number 11506
Data Quality E
Control Device UncontrolledC1>
Reference(s) 3,12
Data Source Samples collected using EPA Method 5 probe and PTFE bag.
Method of elemental analysis not given.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate
Matter
CAS Number
7440-41-7
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-43-9
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
opci. i «r»
Num Sym
4
5
11
12
13
14
15
16
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
48
50
51
55
56
57
Be
8
Na
Mg
Al
Si
P
S
K
Ca
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Nb
Mo
Cd
Sn
Sb
Cs
Ba
La
(0-10)
0.710
Total
0-2.5
%ut
0.
0.
0.
2.
1.
0.
0.
16.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
200
400
420
220
050
432
120
320
070
100
045
030
400
030
350
040
020
004
002
001
000
001
020
001
001
000
015
000
000
015
000
100
015
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0.000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%ut
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
. 0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0.000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
%wt
0.000
0.000
0.200
2.400
1.420
0.220
0.050
16.432
0.120
0.320
0.070
1.100
0.045
0.030
0.400
0.030
0.350
0.040
0.020
0.004
0.002
0.001
0.000
0.001
0.020
0.001
0.001
0.000
0.015
0.000
0.000
0.015
0.000
0.100
0.015
unc
0.000
0.000
0.001
0.120
0.071
0.011
0.005
0.822
0.006
0.016
0.007
0.055
0.005
0.003
0.020
0.003
0.018
0.004
0.002
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.000
0.000
0.002
0.000
0.000
0.002
0.000
0.005
0.002
53
-------
PM Profile Speciat ion Report - continued (profile 11506)
Total Paniculate Matter -
Total
0-2.5 unK2} 2.5-10 unK2> 0-10 um<2> Measured
Species - - —
CAS Number Mum Sym Xwt unc Xut unc Xwt unc Xwt unc
7440-45-1
7440-33-7
7440-28-0
7439-92-1
7440-29-1
7440-61-1
58
74
81
82
90
92
200
203
Ce
W
Tl
Pb
Th
U
TC
S04
0.
0.
0.
0.
0.
0.
14.
49.
010
000
000
030
000
000
501
205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.030
0.000
0.000
14.501
49.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.030
0.000
0.000
14.501
49.205
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.000
0.030
0.000
0.000
14.501
49.205
0.005
0.000
0.000
0.003
0.000
0.000
0.730
2.460
TOTALS: 87.168 87.168 87.168 87.168
{1> No control specified; thus, assumed uncontrolled.
C2> Estimated / extrapolated.
54
-------
PH Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Munber 11507
Data Quality C
Control Device Uncontrolled^}
Reference(s) 1
Data Source Twenty five samples from four boilers collected over a
period.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Participate Matter -
Spec i es
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
201
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
.Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
H9
Pb
OC
0
0
0
11
0
0
0
0
0
0
0
1
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
5
0-2
Xwt
.097
.263
.026
.858
.144
.149
.609
.045
.519
.050
.017
.267
.115
.007
.100
.005
.025
.002
.001
.000
.001
.000
.006
.000
.001
.005
.002
.003
.000
.002
.000
.000
.000
.032
.000
.5 urn
unc
0.139
0.152
0.032
1.071
0.122
0.068
0.172
0.016
0.146
0.024
0.007
0.675
0.425
0.007
0.030
0.004
0.008
0.002
0.002
0.003
0.002
0.005
0.013
0.001
0.005
0.007
0.003
0.005
0.001
0.007
0.134
0.244
0.000
0.014
2.500
2.5-10 urn
Xwt
1.063
1.448
0.087
10.758
1.056
0.165
0.978
0.128
0.381
0.164
0.107
1.254
0.728
0.021
0.050
0.007
0.019
0.034
0.053
0.028
0.021
0.029
0.006
0.000
0.096
0.218
0.227
0.293
0.218
0.598
0.996
1.728
0.019
0.136
44.000
unc
0.594
0.467
0.091
3.227
0.629
0.127
0.268
0.065
0.105
0.061
0.063
0.600
0.111
0.034
0.039
0.011
0.029
0.031
0.058
0.050
0.041
0.057
0.021
0.180
0.145
0.247
0.193
0.263
0.326
0.770
1.449
2.660
0.018
0.164
16.500
0-10 urn
Xwt
0.155
0.334
0.029
11.792
0.199
0.150
0.631
0.050
0.511
0.057
0.023
1.266
1.092
0.008
0.097
0.005
0.025
0.004
0.004
0.002
0.002
0.002
0.006
0.000
0.007
0.018
0.015
0.020
0.013
0.038
0.060
0.104
0.001
0.038
7.300
unc
0.528
0.435
0.083
3.227
0.555
0.124
0.285
0.062
0.157
0.062
0.059
0.734
0.353
0.031
0.044
0.011
0.027
0.029
0.052
0.044
0.036
0.050
0.021
0.154
0.125
0.214
0.169
0.228
0.281
0.662
1.247
2.288
0.017
0.143
14.614
6 -day
(0-10)
0.710
Total
Measured<2>
%wt
0.155
0.334
0.029
11.792
0.199
0.150
0.631
0.050
0.511
0;057
0.023
1.266
1.092
0.008
0.097
0.005
0.025
0.004
0.004
0.002
0.002
0.002
0.006
0.000
0.007
0.018
0.015
0.020
0.013
0.038
0.060
0.104
0.001
0.038
7.300
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
'o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
55
-------
PM Profile Speciation Report - continued (profile 11507)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured{2>
Species ......................... - ............. - ........
CAS Number Hum Sym %wt unc Xut unc Xut unc Xut unc
202 EC 12.800 9.300 18.700 15.000 13.200 14.659 13.200 0.000
TOTALS: 34.151 85.814 37.258 37.258
{1} No control specified: thus, assumed uncontrolled.
{2} Estamated / extrapolated.
56
-------
PM Profile Speciation Report
Profile Name Oil-Fired Power Plant
Profile Number 11508
Data Quality D
Control Device UncontrolledO}
Reference(s) 1
Data Source Unspecified methodology.
SCC Assignments 10100401
Mass Fraction Data - Size Interval Cum)
Mass Fraction
Total Particulate
Hatter
: (0-2.5)
: 0.520
(0-6)
0.580
(0-10)
0.710
Total
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7439-92-1
apec i e»
Nun Sym
11
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
38
40
42
50
51
56
57
58
60
62
82
201
202
203
Ma
Al
Si
P
S
Ct
<
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
8r
Sr
Zr
Mo
Sn
Sb
Ba
La
Ce
Md
Sm
Pb
OC
EC
S04
0-2
Xwt
2.
0.
1.
1.
11.
0.
0.
3.
0.
1.
0.
0.
1.
0.
1.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
600
420
900
500
000
018
160
400
050
100
022
035
500
075
500
098
200
003
002
011
016
021
087
034
035
186
012
008
003
000
1.800
3.
7.
40.
200
700
000
.5 urn
unc
0.600
0.080
0.600
0.400
2.000
0.008
0.050
0.900
0.050
0.300
0.001
0.004
0.200
0.014
0.500
0.032
0.300
0.001
0.001
0.006
0.005
0.021
0.018
0.022
0.038
0.009
0.002
0.002
0.000
0.000
0.600
0.500
1.500
3.000
2.5-10 urn
Xut
2.500
3.700
3.200
2.300
9.000
0.160
0.350
7.600
0.690
1.500
0.065
0.057
2.900
0.100
2.100
0.140
1.600
0.004
0.003
0.002
0.100
0.200
0.077
NR
0.012
0.550
0.170
0.058
0.050
0.004
3.000
12.000
21.000
47.000
unc
1.100
0.300
1.500
0.200
1.000
0.090
0.050
3.800
0.140
0.800
0.016
0.018
0.400
0.020
0.200
0.020
0.500
0.003
0.001
0.001
0.013
0.110
0.022
0.000
0.013
0.260
0.020
0.007
0.021
0.001
0.400
8.000
1.000
4.000
0-10 urn
Xut
2.594
0.602
2.250
1.544
10.889
0.026
0.171
3.633
0.086
1.122
0.024
0.036
1.578
0.076
1.533
0.100
1.222
0.003
0.002
0.011
0.021
0.031
0.086
0.032
0.034
0.206
0.021
0.011
0.005
0.001
1.867
3.689
8.439
40.389
unc
1.093
0.398
1.507
0.420
2.155
0.082
0.074
3.387
0.145
0.740
0.022
0.022
0.468
0.030
0.468
0.040
0.516
0.005
0.003
0.006
0.024
0.100
0.031
0.016
0.031
0.232
0.033
0.017
0.023
0.004
0.636
6.924
2.241
6.763
Measured{2>
Xut
2.594
0.602
2.250
1.544
10.889
0.026
0.171
3.633
0.086
1.122
0.024
0.036
1.578
0.076
1.533
0.100
1.222
0.003
0.002
0.011
Oi021
0.031
0.086
0.032
0.034
0.206
0.021
0.011
0.005
o.oor
1.867
3.689
8.439
40.389
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
79.696
127.192
82.334
82.334
{1} No control specified: thus, assumed uncontrolled.
{2> Estamated / extrapolated.
57
-------
PM Profile Special ion Report
Profile Name Oil-Fired Power Plant
Profile Munber 11509
Data Quality 0
Control Device Uncontrol led{1>
Reference(s) 1
Data Source Unspecified methodology.
SCC Assignments 10100401
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-22-4
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-27-9
7439-92-1
7440-29-1
^f^^V 1 CO
Mum Sym
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
38
40
42
47
50
51
56
57
58
60
62
63
65
32
90
Na
Al
Si
P
S
Cl
<
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
AS
Se
Sr
Sr
Zr
Mo
*g
Sn
Sb
3a
La
Ce
Nd
Sm
Eu
Tb
Pb
Th
0-2
Xwt
3
0
2
1
13
0
2
0
1
Q
0
1
0
1
0
.100
.390
.600
.000
.000
NR
.210
.100
NR
.120
.900
.022
.023
.600
.110
.900
.110
0.730
0.005
0
0
0
0
0
0
0
0
0
0
0
0
1
.002
.004
.028
.016
.160
NR
.021
.097
.130
.042
.034
.022
.002
NR
NR
.000
NR
.5 urn
unc
0.900
0.070
0.400
0.100
1.000
0.000
0.030
0.900
0.000
0.020
0.300
0.007
0.008
0.400
0.010
0.200
0.050
0.290
0.001
0.001
0.000
0.007
0.013
0.020
0.000
0.008
0.008
0.005
0.003
0.002
0.002
0.000
0.000
0.000
0.200
0.000
: <0-2.5)
: 0.520
2.5-
Xut
4.400
9.700
22.000
1.700
9.200
0.430
0.340
16.000
0.001
1.000
1.000
0.041
0.062
3.200
0.120
1.800
0.800
0.340
0.008
0.001
0.007
0.150
0.190
0.240
0.010
0.330
0.064
0.940
0.590
0.350
0.270
0.028
0.001
0.001
0.650
0.002
10 urn
unc
4.300
1.400
6.000
0.600
4.000
0.260
0.110
2.000
0.000
0.200
1.800
0.013
0.017
0.500
0:030
0.500
0.300
0.110
0.007
0.001
0.004
0.040
0.050
0.160
0.004
0.310
0.034
0.060
0.140
0.020
0.030
0.007
0.000
0.000
0.340
0.000
(0-6)
0.580
0-10 urn
Xwt
3.152
1.242
3.376
1.028
12.348
0.017
0.215
2.656
0.000
0.155
1.864
0.023
0.025
1.664
0.110
1.896
0.138
0.734
0.006
0.002
0.005
0.033
0.023
0.163
0.000
0.033
0.096
0.162
0.064
0.047
0.032
0.003
0.000
0.000
0.986
0.000
unc
3.768
1.410
5.404
0.549
3.815
0.228
0.108
2.201
0.001
0.197
1.571
0.018
0.023
0.603
0.037
0.517
0.690
0.258
0.008
0.002
0.006
0.044
0.053
0.143
0.007
0.269
0.035
0.106
0.136
0.048
0.046
0.012
0.002
0.002
0.349
0.003
(0-10)
0.710
Total
Measured<2>
Xwt
3.152
1.242
3.376
1.028
12.348
0.017
0.215
2.656
0.000
0.155
1.864
0.023
0.025
1.664
0.110
1.896
0.138
0.734
0.006
0.002
0.005
0.033
0.023
0.163
0.000
0.033
0.096
0.162
0.064
0.047
0.032
0.003
0.000
0.000
0.986
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
58
-------
PM Profile Speciation Report - continued (profile 11509)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured{2>
Species
CAS Number Nun Sym Xwt unc ' %ut unc Xwt unc %wt unc
201 OC 1.000 0.500 26.000 16.000 2.000 13.833 2.000 0.000
202 EC 0.220 0.170 1.100 1.100 0.255 0.955 0.255 0.000
203 S04 45.000 7.000 40.000 30.000 44.800 26.756 44.800 0.000
TOTALS: 77.198 143.566 79.853 79.853
O> No control specified: thus, assorted uncontrolled.
{2} Estamated / extrapolated.
59
-------
PH Profile Speciat ion Report
Profile Name Oil-fired Power Plant Composite
Profile Number 11510
Data Quality E
Control Device Uncontrolled
Reference(s)
Data Source Profile represents a composite of Profiles 11502, 11503,
11504, 11505, 11506. 11507. 11508, and 11509.
SCC Assignments: 10100401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.520 0.580
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-24-6
7440-67-7
7439-98-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-92-1
TOTALS:
^pw i ca
Nun Sym
13
14
15
16
19
20
22
23
24
25
26
28
29
30
33
34
35
38
40
42
50
51
56
57
82
Al
Si
P
S
0
0
0
12
0-2
.5 urn
X«t uncO>
.567
.718
.324
.696
< 0.134
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
8r
Sr
Zr
Mo
Sn
Sb
Ba
La
Pb
1
.005
0.056
4
0
0
0
.572
.044
.027
.833
1.367
0
0
0
0
0
0
0
0
0
0
0
0
0
23
.047
.265
.006
.001
.003
.023
.007
.037
.007
.019
.082
.011
.408
.259
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt uncC1>
2.199
4.079
0.519
11.834
0.176
3.313
0.256
4.493
0.066
0.046
1.206
1.381
0.140
0.322
0.006
0.005
0.009
0.051
0.051
0.046
0.079
0.086
0.353
0.315
0.527
31.558
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt unc{1>
0.641
0.863
0.333
12.655
0.136
1.106
0.065
4.570
0.045
0.028
0.351
1.368
0.051
0.268
0.006
0.001
0.003
0.025
0.009
0.037
0.010
0.023
0.096
0.027
0.415
23.637
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.710
Total
Measured
Xut
0.641
0.868
0.333
12.655
0.136
1.106
0.065
4.570
0.045
0.028
0.851
1.368
0.051
0.268
0.006
0.001
0.003
0.025
0.009
0.037
0.010
-0.023
0.096
0.027
0.415
23.637
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Uncertainty not evaluated.
60
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
External Combustion - Kerosene- F i red Boiler Composite
12301
E
Control Device Uncontrolled
Reference(s) 3,11
Data Source Composite of three kerosene- fired boilers in Japan. Samples
collected on PTFE filters and analyzed using XRF and INAA.
SCC Assignments: 10200500
Mass Fraction Data - Size Interval (urn) : (0-2.5X1} <0-6><1> (0-10X1}
Mass Fraction : 0.120 0.300 0.500
Total Particulate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
TOTALS:
Hum
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Sym
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
• Cd
Sb
Cs
Ba
La
Pb
0-2.5
Xut
0.380
0
0
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
4
0
0
.000
.600
.400
.260
.000
.360
.000
.045
.015
.024
.026
.500
.002
.120
.000
.140
.003
.005
.000
.000
.000
.002
.000
.700
.000
.000
unK2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
9.582
{1} Mass fraction data
(2} Estimated /
for uncontrolled
2.5-10
%ut
0.380
0.000
0.600
1.400
0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
un*2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
distillate oil
0-10
Xut
0.380
0.000
0.600
1.400
0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
firing.
umC2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
%wt
0.380
0.000
0.600
1.400
0.260
0.000
0.360
0.000
0.045
0.015
0.024
0.026
1.500
0.002
0.120
0.000
0.140
0.003
0.005
0.000
0.000
0.000
0.002
0.000
4.700
0.000
0.000
9.582
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
extrapolated.
61
-------
PM Profile Spcciation Report
Profile Name External Combustion - Wood- Fired
Profile Number 12705
Data Quality E
Boiler
Composite
Control Device Three multicyclone and bag filter, one multicyclon
Reference(s) 3,11
Data Source Six wood-fired boilers in Japan. Samples collected on
filters and analyzed using XRF and INAA.
SCC Assignments: 10200903
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.540 0.800
Total Particulate Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-92-1
TOTALS:
SXXaaaaStSaSS
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
15.000
0.000
0.100
0.000
23.000
5.200
4.000
0.000
0.010
0.000
0.004
0.100
0.230
0.000
0.027
0.024
0.067
0.008
0.180
0.009
0.001
0.000
0.000
0.000
0.066
0.035
48.061
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 unK1>
Xwt
15.000
0.000
0.100
0.000
23.000
5.200
4.000
0.000
0.010
0.000
0.004
0.100
0.230
0.000
0.027
0.024
0.067
0.008
0.180
0.009
0.001
0.000
0.000
0.000
0.066
0.035
48.061
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
PTFE
(0-10)
0.910
Total
Measured
Xut
15.000
0.000
0.100
0.000
23.000
5.200
4.000
0.000
0.010
0.000
0.004
0.100
0.230
0.000
0.027
0.024
0.067
0.008
0.180
0.009
0.001
0.000
0.000
0.000
0.066
0.035
48.061
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
62
-------
PM Profile Speciation Report
Profile Name External Combustion - Heavy Oil-Fired Boiler Composite
Profile Number 13502
Data Quality E
Control Device Seven uncontrolled and five FGD.
Reference(s) 3,11
Data Source Composite of 13 heavy oil-fired boilers
collected on PTFE filters and analyzed
SCC Assignments: 10200401
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.560
Total Particulate
Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
TOTALS:
SS3S33SSSSS9
OfJd. i ea
Nun Sym
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Sa
La
Pb
in Japan. Samples
using XRF and INAA.
(0-6) (0-10)
0.770 0.860
Total
0-2.5
Xwt
1.
0.
9.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
NR
210
600
092
085
085
000
074
920
021
012
460
003
490
000
040
002
001
000
000
000
001
000
092
000
0.033
13.
221
SSS3
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
BSSSSSS
2.5-10
Xwt
1.000
NR
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000
0.000
0.000
0.001
0.000
0.092
0.000
0.033
13.221
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um<1>
Xwt
1.000
NR
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000 .
0.000
0.000
0.001
0.000
0.092
0.000
0.033
13.221
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
1.000
0.000
0.210
9.600
0.092
0.085
0.085
0.000
0.074
0.920
0.021
0.012
0.460
0.003
0.490
0.000
0.040
0.002
0.001
0.000
0.000
0.000
0.001
0.000
0.092
0.000
0.033
13.221
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Estimated / extrapolated.
63
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data QuaIity
External Combustion - Indonesian Oil-Fired Boiler Composite
13503
E
Control Device
Reference(s)
Data Source
ESP or multicyclone plus ESP
3,11
Composite of three Indonesian oil-fired boilers in Japan.
Samples collected on PTFE filters and anal/zed using XRF and
INAA.
SCC Assignments: 10200401
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91 -0
7439-92-1
TOTALS:
Num
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Sym
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
Zn
AS
Br
Rb
Ag
Cd
Sb
Cs
Ba
La
Pb
i
B-2.5
%wt
2
0
0
11
1
0
0
0
0
.200
.000
.540
.000
.200
.140
.860
.000
.110
0.067
0
0
1
0
2
0
0
0
0
0
0
0
0
0
0
0
0
20
.042
.014
.300
.070
.400
.000
.130
.025
.039
.000
.000
.000
.003
.000
.000
.000
.380
.520
urnO)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.410
2.5-10
Xut
2.200
0.000
0.540
11.000
1.200
0.140
0.860
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
'0.025
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
20.520
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0; o.ao
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.520
0-10
Xut
2.200
0.000
.0.540
1 1 . 000
1.200
0.140
0.860
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
0.025
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
20.520
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.630
Total
Measured
%wt
2.200
0.000
0.540
11.000
1.200
0.140
0.360
0.000
0.110
0.067
0.042
0.014
1.300
0.070
2.400
0.000
0.130
0.025
0.039
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.380
20.520
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(1> Estimated / extrapolated.
64
-------
PM Profile Speciat ion Report
Profile Name Oil-Fired Boiler
Profile Number 13504
Data Quality 0
Control Device Uncontrolled^!}
Reference(s) 1
Data Source Unspecified methodology.
SCC Assignments 10200401
Mass Fraction Data • Size Interval (urn)
Mass Fraction
Total Participate
Matter
: (0-2.5)
: 0.560
(0-6)
0.770
(0-10)
0.860
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
3t»U ' ca
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
201
202
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
1
2
0
13
0
0
0
0
1
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
8
0-2
Xwt
.203
.077
.398
.074
.000
.056
.208
.079
.004
.003
.011
.357
.595
.051
.052
.008
.034
.004
.005
.003
.011
.003
.018
.024
.017
.001
.000
.001
.003
.019
.020
.094
.001
.032
.960
.690
.5 urn
unc
0.120
0.208
0.073
1.307
0.056
0.006
0.021
0.009
0.100
0.012
0.002
0.036
0.160
0.008
0.005
0.002
0.005
0.001
0.002
0.002
0.002
0.004
0.015
0.008
0.017
0.011
0.015
0.014
0.018
0.031
0.085
0.124
0.002
0.006
0.396
0.369
2.5-10 urn
Xwt
2.217
4.505
0.151
1.761
0.000
0.046
0.571
0.168
0.689
0.028
0.018
0.696
1.508
0.120
0.017
0.002
0.002
0.002
0.005
0.002
0.030
0.004
0.006
0.008
0.019
0.001
0.000
0.053
0.003
0.014
0.010
0.177
0.002
0.012
5.630
80.200
unc
0.222
0.451
0.050
0.280
0.028
0.008
0.057
0.017
0.069
0.013
0.004
0.070
0.151
0.013
0.004
0.002
0.006
0.002
0.003
0.003
0.005
0.006
0.020
0.015
0.012
0.020
0.026
0.028
0.034
0.056
0.155
0.230
0.004
0.009
0.563
3.020
0-10
Xut
1.557
2.924
0.312
9.127
0.000
0.053
0.334
0.110
0.894
0.011
0.013
0'.475
1.565
0.075
0.040
0.006
0.023
0.003
0.005
0.003
0.018
0.004
0.014
0.019
0.017
0.001
0.000
0.019
0.003
0.017
0.017
0.123
0.002
0.025
7.798
33.635
untf2>
unc
0.282
0.538
0.077
1.498
0.043
0.016
0.078
0.032
0.143
0.017
0.009
0.097
0.250
0.026
0.010
0.003
0.007
0.003
0.005
0.004
0.011
0.007
0.019
0.014
0.017
0.017
0.023
0.028
0.030
0.050
0.137
0.204
0.004
0.011
1.176
3.391
Measured
Xut
1.541
2.879
0.316
9.321
0.000
0.053
0.329
0.108
0.898
0.011
0.013
0.470
1.564
0.074
0.041
0.006
0.023
0.003
0.005
0.003
0.017
0.004
0.014
0.019
0.017
0.001
0.000
0.019
0.003
0.018
0.018
0.117
0.002
0.026
7.850
32.500
unc
0.154
0.288
0.065
0.932
0.047
0.006
0.043
0.011
0.090
0.012
0.003
0.047
0.156
0.010
0.004
0.002
0.005
0.002
0.002
0.002
0.003
0.005
0.014
0.011
0.010
0.014
0.018
0.019
0.023
0.039
0.108
0.159
0.003
0.007
0.785
3.250
TOTALS: 38.116 98.677 59.242 58.283
===33:5=========3:==:s3:ssr=s=====s=====zs=s:::5====s=======s===s========r=================
(1) No control specified: thus, assumed uncontrolled.
<2> Calculation based on methodology described in the Air Emissions Species Manual,
Volume II.
65
-------
PH Profile Special ion Report
Profile Name External Combustion - Waste Oil-
Profile Number 14101
Data Quality E
Fired Boiler
Control Device Uncontrolled*!!}
Reference(s) 3,11
Data Source Boiler firing waste oil in Japan. Samples collected on
filters and analyzed using XRF and INAA.
SCC Assignments: 10201302
Mass Fraction Data - Size Interval (urn) : (0-2.5X2} (0-6X2}
Mass Fraction : 0.520 0.580
Total Particulate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
.7440-70-2
7440-22-2
7440-32-6
. 7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7439-92-1
Nun
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
57
82
Sym
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Hi
Cu
Zn
As
8r
Rb
Ag
Cd
Sb
Cs
Ba
La
Pb
0-2.5
Xut
1
0
0
15
3
4
4
0
0
0
0
0
1
.500
.710
.330
.000
.600
.200
.000
.000
.013
.002
.021
.074
.000
0.001
0
.007
0.150
0
0
0
0
0
0
0
0
0
0
1
.850
.000
.220
.017
.001
.012
.003
.000
.710
.000
.900
unK3}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.350
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
unK3}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.350
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
unK3}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
PTFE
(0-10X2}
0.710
Total
Measured
Xut
1.500
0.710
0.330
15.000
3.600
4.200
4.000
0.000
0.013
0.002
0.021
0.074
1.000
0.001
0.007
0.150
0.350
0.000
0.220
0.017
0.001
0.012
0.003
0.000
0.710
0.000
1.900
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
34.321
34.321
34.321
34.321
SSS3353333333SS333333333SSS3:S35333Sa
S333S3SSS3E3533333333333333S
{1} No control specified: thus, assumed uncontrolled.
{2} Mass fraction data for uncontrolled residual oil firing.
(3} Estimated / extrapolated.
66
-------
PM Profile Speciation Report
Profile Name External
Profile Number 14102
Data Quality E
Combustion - Liquid Waste-Fired Boiler
Control Device Uncontrol led{1>
Reference(s) 3,11
Data Source Boiler firing pitch in Japan. Samples collected on PTFE
filters and analyzed using XRF and INAA.
SCC Assignments: 10201301
Mass Fraction Data - Size Interval (urn) : (0-2.5X2} (0-6X2} (0-10X2}
Mass Fraction : 0.560 0.770 0.360
Total Particulate Matter -
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
-7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-92-1
TOTALS:
Mum
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
82
Sym
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Ba
Pb
15
0
0
25
0
0
1
0
0
1
0
0-2.5
Xwt
.000
.000
.450
.000
.000
.000
.300
.000
.000
.200
.015
0.030
1
0
1
0
0
0
0
0
0
0
0
0
0
0
46
.700
.013
.500
.000
.066
.003
.000
.000
.003
.000
.002
.000
.000
.100
.382
unK3}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 umC3}
Xwt
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
46.382
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
46.382
um<3}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xut
15.000
0.000
0.450
25.000
0.000
0.000
1.300
0.000
0.000
1.200
0.015
0.030
1.700
0.013
1.500
0.000
0.066
0.003
0.000
0.000
0.003
0.000
0.002
0.000
0.000
0.100
46.382
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<1> No control specified: thus, assumed uncontrolled.
{2} Mass fraction data for uncontrolled residual oil-fired boiler.
<3> Estimated / extrapolated.
67
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
External Combustion - Solid Waste-Fired Boiler
15101
E
Control Device
Reference(s)
Data Source
Uncontrolled{1>
3,11
Boiler firing miscellaneous fuel (primarily wood and
building materials) in Japan. Samples collected on PTFE
filters and analyzed using XRF and INAA.
SCC Assignments: 10201201
Mass Fraction Data • Size Interval (urn)
. Mass Fraction
Total Participate Matter
CAS Number
7440-23-3
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7440-17-7
7440-22-4
7440-43-9
7440-36-0
7440-46-2
7440-39-3
7439-92-1
3f*=W 1 ca
Num Sym
11
12
13
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
35
37
47
48
51
55
56
82
Na
Mg
Al
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
Zn
As
Br
Rb
Ag
Cd
Sb
Cs
Ba
Pb
0-2.5
Sut
0
2
0
9
6
0
18
0
0
0
0
0
0
.840
.100
.220
.100
.800
.000
.000
.000
.000
.001
.063
.016
.980
0.001
0
0
3
0
0
0
0
0
0
.014
.190
.400
.000
.310
.000
.002
.003
.007
0.000
2
2
.000
.000
unK3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: <0-2.5><2>
: 0.760
2.5-10
Xwt
0.840
2.100
0.220
9.100
6.800
0.000
18.000
0.000
0.000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
0.000
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
unK3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-6X2>
0.860
0-10
Xwt
0.340
2.100
0.220
9.100
6.800
0.000
18.000
0.000
0.000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
0.000
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
unK3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10X2>
0.900
Total
Measured
Xwt
0.340
2.100
0.220
9.100
6.300
0.000
18.000
0.000
0..000
0.001
0.063
0.016
0.980
0.001
0.014
0.190
8.400
o.'ooo
0.310
0.000
0.002
0.003
0.007
0.000
2.000
2.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
51.047
51.047
51.047
51.047
<1> No control specified: thus, assumed uncontrolled.
C2> Mass fraction data for uncontrolled residual wood/bark-fired boiler.
(3> Estimated / extrapolated.
68
-------
3.2 CHEMICAL MANUFACTURING
The manufacture of organic and inorganic chemicals involves the
production of a wide variety of end-product and intermediate chemicals.
Emissions from the chemical manufacturing industry can be high but are usually
recovered for economic reasons. The particulate emissions are usually very
finely sized and difficult to remove. Emission sources can include storage
and handling operations, reactor processes, separation processes, and fugitive
and secondary sources.
69
-------
PM Profile Special ion Report
Profile Name Fertilizer Production -
Profile Number 25408
Data Quality 0
Phosphate Rock
Dust
Control Device UncontrolledO}
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30102803, 30102804, 30102923, 30102924
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Particulate
Matter
(0-10)
0.510
Total
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-3
7440-66-6
7440-55-3
7440-38-2'
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
7440-69-9
TOTALS:
apec i es
Nun Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
83
Ma
Mg
Al
Si
P
S
Cl
1C
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
8a
La
Hg
Pb
Bi
0-2.5 urn
Xwt
NR
NR
2.543
3
11
1
0
0
19
1
0
0
0
7
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.349
.152
.285
.364
.368
.872
.057
.138
.108
.332
.579
.032
.032
.086
.000
.000
.001
.025
.003
.551
.029
.127
.002
.004
.000
0.000
0
0
0
1
0
0
0
51
.049
.038
.131
.531
.491
.005
.143
NR
.427
unc
0.000
0.000
0.254
0.335
2.231
0.129
0.040
0.042
1.987
0.106
0.034
0.011
0.033
0.758
0.005
0.006
0.009
0.003
0.013
0.003
0.004
0.004
0.055
0.006
0.039
0.018
0.019
0.023
0.032
0.036
0.044
0.077
0.263
0.324
0.004
0.017
0.000
2.5-10 urn
Xwt
0.340
0.130
2.099
2.482
9.547
0.882
0.411
0.203
22.922
0.342
0.099
0.087
0.188
4.162
0.014
0.011
0.049
0.003
0.000
0.000
0.003
0.004
0.706
0.034
0.088
0.009
0.011
0.000
0.011
0.000
0.025
0.000
1.873
0.000
0.004
0.035
0.000
47.274
unc
0.020
0.010
0.210
0.248
1.910
0.088
0.041
0.034
2.292
0.084
0.026
0.009
0.019
0.416
0.003
0.003
0.005
0.001
0.004
0.001
0.002
0.002
0.071
0.004
0.036
0.009
0.009
0.012
0.016
0.018
0.023
0.036
0.187
0.172
0.003
0.001
0.020
0-10
Xut
NE
NE
2.230
2.737
10.019
1.000
0.397
0.251
22.025
0.905
0.110
0.093
0.230
5.167
0.020
0.017
0.060
0.002
0.000
0.000
0.009
0.004
0.660
0.033
0.100
0.007
0.009
0.000
0.007
0.014
0.029
0.038
1.772
0.144
0.004
0.066
NE
48.159
unK2>
unc
0.000
0.000
0.186
0.232
1.342
0.087
0.035
0.029
1.742
0.077
0.020
0.010
0.022
0.466
0.004
0.003
0.007
0.002
0.004
0.001
0.002
0.002
0.055
0.005
0.024
0.008
0.008
0.009
0.013
0.015
0.018
0.031
0.156
0.135
0.002
0.009
0.000
Measured
r.ut
0.306
0.117
2.143
2.568
9.706
0.922
0.407
0.219
22.620
0.863
0.103
0.089
0.202
4.501
0.016
0.013
0.052
0.003
0.000
0.000
0.005
0.004
0.690
0.033
0.092
0.009
0.011
0.000
0.010
0.005
0.026
0.013
1.839
0.049
0.004
0.045
0.000
47.685
unc
0.018
0.009
0.194
0.230
1.741
0.082
0.038
0.031
2.096
0.078
0.024
0.008
0.018
0.392
0.003
0.003
0.005
0.001
0.004
0.001
0.002
0.002
0.064
0.003
0.033
0.008
0.008
0.011
0.015
0.016
0.021
0.034
0.172
0.159
0.003
0.002
0.018
(1> No control specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
71
-------
PM Profile Special ion Report
Profile Name
Profile Nunber
Data Quality
Ammonium Nitrate - Prill Tower
25409
Control Device
Reference(s)
Data Source
Uncontrolled^!}
1,17
Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30102712
Mass Fraction Data - Size
Mass
Total Particulate Matter -
CAS Number Num Syra
Interval (urn) :
Fraction :
0-2.5 umC2>
Xut one
(0-2.5)
0.560
2.5-10 um<2}
Xut unc
(0-6)
0.730
0-10 um<2}
Xut unc
(0-10)
0.830
Total
Measured
Xwt unc
204 N03 77.500 0.000 77.500 0.000 77.500 0.000 77.500 7.750
TOTALS: 77.500 77.500 77.500 77.500
<1> No control specified: thus, assumed uncontrolled.
{2} Estimated / extrapolated.
72
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Ammonium Sulfate Production
25410
Control Device
Reference(s)
Data Source
Uncontrolleda>
1.17
Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30113004, 30113005
Mass
Total
CAS
Fraction Data
- S i ze
Mass
Particulate Matter -
Spec i es
Number Hum Sym
Interval (urn)
Fraction
0-2.5
Xwt
um<2>
unc
: (0
: 0
2.5-10
Xwt
-2.5)
.110
unK2>
unc
(0-6)
0.490
0-10 unK2>
Xwt unc
(0-10)
0.990
Total
Measured
Xut
unc
7704-34-9 16 S NE 24.200 NE 26.155 NE 24.200 2.420 7.750
203 S04 72.700 0.000 72.700 0.000 72.700 0.000 72.700 7.270
TOTALS: 72.700 72.700 72.700 75.120
===SSSSS5SSS=== = SSSSSSS5S = 5ZS=3= = = 2SS3SS5 = SS====SS:=S=S = 5==X=SSSS ==E5SS = = =:=SSS = = = = = SS=
<1> No control specified: thus, assumed uncontrolled.
(2> Estimated / extrapolated.
73
-------
PM Profile Special ion Report
Profile Maine Di ammonium Phoshate Plant
Profile Number 25411
Data Quality D
Control Device Uncontrol ledO)
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30103001, 30103002, 30103003, 30103004
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.300 0.620
Total Participate Hatter -
CAS Number
7440-41-7
7440-42-8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
J^ICV 1 C9
Nun Sym
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
Be
&
f
Ma
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
0-2
Xut
0.
0.
0.
0.
0.
1.
25.
0.
4.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
092
000
270
023
103
806
725
687
868
602
617
020
042
006
024
925
000
013
023
096
0.001
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
019
000
022
000
015
000
011
028
011
000
0.000
0.012
0.000
.5 urn
one
0.023
0.092
0.092
0.900
0.012
0.221
5.161
0.145
0.937
1.174
0.120
0.123
0.004
0.008
0.003
0.005
0.185
0.210
0.004
0.005
0.019
0.002
0.009
0.003
0.004
0.003
0.004
0.005
0.021
0.015
0.011
0.020
0.027
0.030
0.037
2.5-10 urn
Xwt
NR
NR
NR
MR
NR
3.561
39.441
4.541
5.327
4.271
2.105
6.520
0.199
0.035
0.000
0.151
3.551
NR
0.000
• -.9.251
0.091
"0.000
0.000
0.000
0.000
0.000
0.229
0.000
0.000
0.334
0.340
0.077
0.439
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.890
9.860
1.337
1.332
1.068
0.526
1.630
0.056
0.026
0.025
0.042
0.888
0.000
0.028
0.066
0.041
0.018
0.064
0.027
0.029
0.034
0.062
0.049
0.212
0.172
0.150
0.220
0.320
0.302
0.390
0-10
Xut
NE
NE
NE
NE
NE
2.693
34.629
3.194
5.101
4.835
1.575
4.437
0.136
0.037
0.002
0.106
2.624
NE
0.005
0.171
.0.093
0.000
0.007
0.000
0.008
0.000
0.153
0.000
0.004
0.226
0.224
0.050
0.284
0.004
0.000
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.555
6.424
0.816
0.912
0.829
0.329
1.000
0.037
0.017
0.015
0.029
0.551
0.074
0.017
0.043
0.028
0.011
0.038
0.016
0.017
0.020
0.041
0.029
0.126
0.105
0.092
0.131
0.192
0.180
0.232
(0-10)
0.850
Total
Measured
%wt
NR
NR
NR
NR
NR
1.330
27.063
1.077
4.746
5.721
0.741
1.162
0.037
0.041
0.006
0.036
1.168
NR
0.011
0.044
0.096
0.001
0.018
0.000
0.020
0.000
0.003
0.000
0.010
0.056
0.041
0.007
0.041
0.011
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.332
6.766
0.269
1.187
1.430
0.185
0.290
0.009
0.010
0.005
0.009
0.292
0.000
0.006
0.011
0.024
0.004
0.014
0.005
0.006
0.006
0.008
0.009
0.038
0.029
0.023
0.038
0.053
0.055
0.070
74
-------
PM Profile Speciation Report • continued (profile 25411)
Total Participate Matter -
Total
CAS Number
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
species
Num Sym
51
56
57
80
82
203
204
Sb
Ba
La
Hg
Pb
S04
N03
0-2
Xwt
0.
0.
0.
0.
0.
3.
3.
000
000
000
005
081
220
780
.5 un
unc
0.064
0.172
0.239
0.005
0.016
0.810
0.950
2.5-
Xwt
0.000
0.000
4.411
0.000
0.194
NR
NR
10 urn
unc
0.675
1.810
2.769
0.037
0.105
0.000
0.000
0-10
Xwt
0.000
0.000
2.854
0.002
0.154
NE
NE
unK2>
unc
0.402
1.077
1.656
0.022
0.065
0.000
0.000
Measured
Xwt
0.000
0.000
0.407
0.047
0.091
NR
NR
unc
0.120
0.323
0.462
0.076
0.023
0.000
0.000
TOTALS:
48.147
76.068
63.608
44.032
O> No controlled specified: thus, assumed uncontrolled.
(2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
75
-------
PH Profile Speciat ion Report
Profile Name Superphosphate Plant
Profile Number 25412
Data Quality D
Control Device UncontrolledO>
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30102823, 30102824, 3010282S
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Participate Hatter
CAS Number
7782-41-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
afjcv ica
Hum Syro
9
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
F
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb .
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
52.900
0.572
26.606
0.070
0.136
1.309
0.003
0.079
0.003
0.004
0.000
0.001
0.025
0.001
0.000
0.001
0.000
0.059
0.000
0.005
0.000
0.007
0.000
0.000
0.018
0.011
0.000
0.010
0.000
0.000
0.000
0.000
0.111
0.001
0.009
.5 urn
unc
5.290
0.114
2.661
0.014
0.027
0.262
0.002
0.016
0.001
0.001
0.001
0.001
0.005
0.001
0.001
0.001
0.001
0.012
0.001
0.001
0.001
0.002
0.002
0.009
0.007
0.005
0.009
0.013
0.013
0.016
0.028
0.073
0.109
0.002
0.004
2.5-10 urn
Xut
NR
1.541
64.783
0.350
0.518
3.727
0.012
0.322
0.021
0.003
0.010
0.001
0.041
0.009
0.000
0.004
0.000
0.000
0.000
0.022
0.000
0.025
0.014
0.114
0.031
0.058
0.024
0.024
0.089
0.020
0.000
0.000
0.601
0.000
0.009
unc
0.000
0.308
6.478
0.087
0.114
0.745
0.016
0.064
0.010
0.006
0.007
0.007
0.023
0.009
0.009
0.007
0.005
0.017
0.007
0.009
0.010
0.012-
0.014
0.062
0.044
0.037
0.062
0.083
0.091
0.111
0.190
0.499
0.732
0.012
0.026
0-10 umC2>
Xut
1.
53.
0.
NE
256
554
268
0.406
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
016
009
251
016
003
007
001
036
007
000
003
000
017
000
017
000
020
010
080
027
044
017
020
0.063
0.
0.
0.
0.
0.
0.
014
000
000
457
000
009
unc
0.000
0.180
4.224
0.050
0.066
0.431
0.009
0.039
0.006
0.003
0.004
0.004
0.013
0.005
0.005
0.004
0.003
0.010
0.004
0.006
0.005
0.007
0.008
0.035
0.024
0.021
0.034
0.045
0.050
0.060
0.103
0.271
0.399
0.007
0.014
(0-10)
0.510
Total
Measured
Xut
NR
0.679
30.313
0.101
0.178
1.576
0.004
0.106
0.005
0.004
0.001
0.001
0.027
0.002
0.000
0.002
0.000
O.OS2
0.000
0.007
0.000
0.009
0.002
0.013
0.020
0.017
0.003
0.012
0.010
0.002
0.000
0.000
0.165
0.001
0.009
unc
0.000
0.136
3.081
0.021
0.036
0.315
0.004
0.021
0.002
0.002
0.002
0.002
0.006
"0.002
0.002
0.002
0.001
0.010
0.002
0.002
0.002
0.003
0.003
0.015
0.011
0.009
0.015
0.020
0.021
0.027
0.046
0.120
0.178
0.003
0.006
76
-------
PM Profile Speciation Report - continued (profile 25412)
Total Participate Matter
Spec i es
CAS Number Nun Sym
203 S04
204 N03
TOTALS:
0-2
Xut
0.060
0.000
82.001
Total
.5 cm 2.5-10 urn 0-10 uiK2> Measured
unc Xwt unc Xwt unc Xut
0.034 NR 0.000 NE 0.000 NR
0.166 NR 0.000 NE 0.000 NR
72.373 59.628 33.821
unc
0.000
0.000
O> No controlled specified: thus, assumed uncontrolled.
(2) Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
77
-------
PM Profile Speciation Report
Profile Name Superphosphate Granulation
Profile Number 25413
Data Quality D
Control Device UncontrolledO}
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30102823
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Particulate Matter
Species
CAS Number
7440-41-7
7440 -42 -8
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-39-6
7440-48-4
7440-02-0
7440-50-3
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
Hum
4
5
9
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
Sym
Be
3
F
Na
Mg
Al
Si
p
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
CO
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
0-2
Xwt
0.000
0.067
0.051
0.000
0.000
0.973
5.791
3.016
6.112
14.676
0.051
0.486
0.019
0.268
0.000
0.004
0.052
0.000
0.127
0.002
0.006
0.001
0.043
0.000
0.033
0.000
0.021
0.000
0.000
0.016
0.020
0.005
0.000
0.002
0.005
.5 urn
unc
0.011
0.045
0.045
0.440
0.006
0.097
1.453
1.806
0.813
6.014
0.006
0.204
0.003
0.105
0.004
0.002
0.008
0.091
0.037
0.002
0.003
0.001
0.028
0.002
0.007
0.002
0.003
0.003
0.012
0.009
0.007
0.012
0.016
0.017
0.021
2.5-
Xut
NR
MR
NR
NR
NR
3.137
10.562
7.098
11.579
8.479
0.131
4.382
0.049
0.132
0.008
0.033
0.302
NR
0.041
0.023
0.014
0.005
0.000
0.000
0.002
0.000
0.211
0.000
0.000
0.367
0.229
0.002
0.137
0.173
0.000
10 urn
unc
0.000
0.000
0.000
0.000
0.000
0.784
3.675
3.924
2.895
7.313
0.102
3.163
0.048
0.094
0.044
0.037
0.224
0.000
0.072
0.051
0.032
0.025
0.086
0.038
0.045
0.049
0.064
0.069
0.305
0.230
0.223
0.306
0.422
0.446
0.547
0-10 unrf2>
Xut
NE
NE
NE
NE
NE
2.501
9.159
5.898
9.971
10.301
0.108
3.589
0.040
0.172
0.005
0.024
0.228
NE
0.066
0.017
0.012
0.004
0.013
0.000
0.011
0.000
0.155
0.000
0.000
0.264
0.167
0.003
0.097
0.123
0.002
unc
0.000
0.000
0.000
0.000
0.000
0.440
2.077
2.208
1.646
4.393
0.056
1.723
0.027
0.061
0.024
0.020
0.122
0.000
0.041
0.028
0.018
0.014
0.047
0.021
0.025
0.027
0.037
0.038
0.165
0.126
0.122
0.166
0.229
0.242
0.296
(0-10)
0.510
Total
Measured
Xut
1
5
3
6
14
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
NR
NR
NR
NR
NR
.046
.950
.157
.295
.465
.054
.638
.020
.264
.000
.005
.061
NR
.124
.002
.006
.001
.042
.000
.032
.000
.027
.000
.000
.028
.027
.005
.005
.007
.005
unc
0.000
0.000
0.000
0.000
0.000
0.105
1.515
1.888
0.841
6.075
0.009
0.316
0.005
0.099
0.005
0.003
0.010
0.000
0.038
0.004
0.003
0.002
0.027
0.003
0.006
0.004
0.005
0.005
0.021
0.016
0.013
0.022
0.029
0.031
0.039
78
-------
PM Profile Speciation Report
continued (profile 25413)
Total Paniculate
Matter
Total
CAS Number
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun Sym
51
56
57
80
82
201
202
203
204
Sb
Ba
La
Hg
Pb
OC
EC
S04
N03
0
0-2.5 urn
Xwt
.000
0.000
0
0
0
21
3
3
3
.000
.062
.016
.000
.230
.430
.140
unc
0.037
0.095
0.136
0.007
0.005
2.100
0.323
0.343
0.314
2.5-10 urn
Xwt
0.000
0.000
1.764
0.000
0.126
NR
NR
NR
NR
unc
0.978
2.595
3.655
0.072
0.134
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
1.245
0.018
0.094
NE
NE
NE
NE
unK2> Measured
unc
0.530
1.408
1.983
0.039
0.073
0.000
0.000
0.000
0.000
Xwt
0.000
0.000
0.056
0.059
0.020
NR
NR
NR
NR
unc
0.069
0.179
0.255
0.009
0.010
0.000
0.000
0.000
0.000
TOTALS: 62.725 49.486 44.287 32.401
{1} No controlled specified: thus, assumed uncontrolled.
(2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
79
-------
PM Profile Speciation Report
Profile Name Sodium Tripolyphosphate
Profile Number 25414
Data Quality 0
- Cyclone Dust
Control Device Mot ApplicableO}
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30104501
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.300 0.620
Total Paniculate Hatter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
apw 1 73
Nun Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Mi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
r
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
0-2
%wt
2
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
MR
MR
.537
.875
.086
.370
.380
.479
.131
.006
.044
.023
.000
.052
.002
.043
.122
.157
.000
.000
.000
.060
0.000
0
0
0
0
0
0
0
0
0
0
.004
.000
.000
.050
.000
.007
.000
.544
.063
.390
1.696
0.000
.5 urn
unc
0.000
0.000
0.357
0.141
0.486
0.289
0.118
0.091
0.039
0.018
0.016
0.017
0.017
0.053
0.001
0.018
0.032
0.031
0.014
0.063
0.015
0.022
0.023
0.028
0.033
0.143
0.111
0.104
0.152
0.188
0.234
0.259
0.440
1.338
1.836
2.5-10 urn
r.wt
13.400
0.023
1.732
1.947
11.733
0.270
0.048
0.036
0.075
0.006
0.004
0.001
0.014
0.097
MR
0.000
0.132
0.046
0.000
0.005
0.001
0.003
0.005
0.003
0.003
0.000
0.000
0.000
0.003
0.000
0.006
0.025
0.016
0.150
0.051
unc
2.680
0.006
0.173
0.195
2.350
0.033
0.013
0.006
0.008
0.002
0.002
0.001
0.002
0.010
0.000
0.002
0.013
0.005
0.002
0.006
0.001.
0.002
0.002
0.002
0.003
0.013
0.010
0.010
0.013
0.018
0.021
0.027
0.045
0.128
0.182
0-10 unK2>
Xwt
ME
ME
2.016
1.569
8.328
0.482
0.165
0.192
0.095
0.006
0.018
0.009
0.009
0.081
ME
0.015
0.128
0.085
0.000
0.003
0.001
0.023
0.003
0.003
0.002
0.000
0.018
0.000
0.004
0.000
0.196
0.038
0.148
0.696
0.033
unc
0.000
0.000
0.219
0.157
1.474
0.114
0.047
0.041
0.018
0.007
0.007
0.006
0.007
0.022
0.000
0.007
0.020
0.015
0.005
0.023
0.005
0.009
0.009
0.010
0.012
0.051
0.040
0.037
0.054
0.067
0.088
0.093
0.159
0.486
0.657
(0-10)
0.850
Total
Measured
%ut
13.400
0.023
1.732
1.947
11.733
0.270
0.048
0.036
0.075
0.006
0.004
0.001
0.014
0.097
ME
0.000
0.132
0.046
0.000
0.005
0.001
0.003
0.005
0.003
0.003
0.000
0.000
0.000
0.003
0.000
0.006
0.025
0.016
0.150
0.051
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
80
-------
PM Profile Speciation Report - continued (profile 25414)
Total Partfculate Matter -
Total
0-2.5 urn 2.5-10 un 0-10 um(2> Measured
Species ................................................
CAS Number Nun Sym Xwt unc Xut unc Xwt unc Xut unc
7439-97-6 80 Hg 0.020 0.023 0.001 0.003 .0.008 0.008 0.001 0.000
7439-92-1 82 Pb 0.615 0.112 0.072 0.008 0.264 0.051 0.072 0.000
7440-69-9 83 Bi NR 0.000 0.000 0.005 NE 0.000 0.000 0.000
TOTALS: 11.256 29.908 14.638 29.908
O> No controlled specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
81
-------
PM Profile Spcciation Report
Profile Name
Profile Number
Data Quality
NPK Fertilizer
25415
Control Device Uncontrolled^}
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30104501
Mass Fraction Data - Size
Mass
Total Participate Hatter -
Species
CAS Number Nun Sym
Interval (urn) :
Fraction :
0-2.5 urn
%ut unc
(0-2.5)
0.150
2.5-10 urn
Xwt unc
(0-6)
0.340
0-tO urn
%wt unc
CO-10)
0.510
Total
Measured
Xwt unc
7723-14-0 15 P
7440-09-7 19 <
20.000 0.000 20.000 0.000 20.000 0.000 20.000 10.000
18.000 O.OOQ 18.000 0.000 18.000 0.000 18.000 10.000
TOTALS: 38.000
O> Estimated / extrapolated.
38.000
38.000
38.000
82
-------
3.3 PRIMARY METAL PRODUCTION
Primary metal production is the production of metals from unprocessed
ore. Processes involved depend on the element of concern. Processes
generating particulate emissions in this industry include smelting operations,
grinding, sintering, electrolytic processes, refining, and leaching.
83
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Iron Ore Dust
28304
D
Sinter
Control Device
Reference(s)
Data Source
UncontroltedO>
1,17
Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30300813, 30400701
Mass Fraction Data - Size Interval (urn) :
Hass Fraction :
Total Participate Matter
Spec i es
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
In
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
2.634
6.447
0.145
1.050
0.319
0.300
12.655
0.290
0.055
0.094
0.652
27.491
0.018
0.053
0.058
0.000
0.000
0.001
0.014
0.005
0.023
0.009
0.000
0.039
0.000
0.000
0.082
0.029
0.030
0.037
0.000
0.000
0.011
0.060
.5 urn
unc
0.263
0.645
0.033
0.105
0.037
0.032
1.266
0.029
0.007
0.009
0.065
2.749
0.004
0.007
0.006
0.003
0.009
0.003
0.004
0.004
0.006
0.006
0.027
0.021
0.019
0.026
0.040
0.039
0.049
0.080
0.234
0.337
0.005
0.014
(0-2.5)
0.270
2.5-10 urn
%ut
1.
3.
0.
0.
0.
0.
14.
0.
0.
0.
0.
32.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
139
308
051
000
206
186
174
280
049
103
536
511
012
015
008
000
000
002
003
008
015
007
009
021
007
012
0.039
0.
0.
0.
0.
0.
0.
0.
011
000
000
000
000
013
051
unc
0.114
0.331
0.017
0.101
0.026
0.022
1.417
0.028
0.005
0.010
0.054
3.251
0.001
0.002
0.001
0.001
0.003
0.001
0.001
0.001
0.002
0.001
0.005
0.004
0.004
0.005
0.009
0.008
0.010
0.017
0.046
0.067
0.002
0.005
(0-6)
0.600
0-10 unK2>
Xut
1.724
4.537
0.088
0.411
0.250
0.231
13.580
0.283
0.052
0.099
0.581
30.547
0.014
0.030
0.027
0.000
0.000
0.002
0.007
0.007
0.018
0.008
0.006-
0.028
0.004
0.007
0.055
0,018
0.012
0.014
0.000
0.000
0.012
0.054
unc
0.200
0.504
0.020
0.095
0.032
0.029
1.358
0.033
0.009
0.014
0.064
3.043
0.004
0.006
0.005
0.001
0.004
0.002
0.003
0.003
O.OOS
0.004
0.012
0.010
o.ooa
0.011
0.018
0.016
0.020
0.033
0.096
0.138
0.004
0.010
(0-10)
0.690
Total
Measured
Xwt
2.244
5.628
0.120
0.776
0.289
0.270
13.052
0.287
0.054
0.096
0.622
28.302
0.017
0.043
0.045
0.000
0.000
0.001
0.011
0.006
0.021
0.009
0.002
0.034
0.002
0.003
0.070
0.024
0.022
0.027
0.000
0.000
0.011
0.058
unc
0.323
0.796
0.029
0.127
0.042
0.039
1.678
0.038
0.008
0.012
0.083
3.675
0.004
0.007
0.007
0.002
0.007
0.002
0.003
0.003
0.005
0.005
0.020
0.016
0.014
0.019
0.031
0.029
0.036
0.059
0.173
0.250
0.004
0.012
TOTALS:
52.601
52.776
52.706
52.646
(1> No controlled specified: thus, assumed uncontrolled.
(2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
85
-------
PM Profile Speciation Report
Profile Name Steel Desulfurization Baghouse Dust
Profile Number 28306
Data Quality D
Control Device Not Applicable
Reference(s) 1,17
Data Source Sample of baghouse dust
unit.
SCC Assignments: 30300999
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7UO-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
CnAtf"
Spec
Nun
13
• 14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
Matter
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
from steel plant desulfurization
: (0-2.5) (0-6)
: 0.420 0.650
(0-10)
0.850
Total
0-2
Xwt
0.878
1.628
0.226
2.739
0.458
2.539
25.445
0.165
0.041
0.064
0.277
20.537
0.016
0.016
0.091
0.002
0.000
0.004
0.006
0.019
0.116
0.003
0.000
0.013
0.000
0.015
0.033
0.007
0.008
0.063
0.000
0.000
0.010
0.059
55.478
.5 urn
unc
0.088
0.163
0.053
0.274
0.046
0.254
2.545
0.017
0.005
0.006
0.028
2.054
0.004
0.005
0.009
0.003
0.008
0.003
0.003
0.005
0.012
0.006
0.025
0.019
0.018
0.026
0.034
0.034
0.043
0.073
0.213
0.301
0.005
0.013
2.5-10 urn
Xwt
0.561
0.967
0.081
0.437
0.265
1.020
2T.313
0.227
0.047
0.079
0.221
29.277
0.014
0.010
0.034
0.001
0.000
0.002
0.004
0.015
0.095
0.004
0.015
0.018
0.008
0.015
0.025
0.021
0.009
0.000
0.000
0.030
0.022
0.069
54.906
unc
0.056
0.097
0.025
0.115
0.029
0.102
2.131
0.023
0.005
0.008
0.022
2.928
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.010
0.001
0*.006
0.003
0.004
0.004
0.007
0.007
0.008
0.013
0.036
0.055
0.002
0.007
0-10 um€1>
Xwt
0.732
1.323
0.159
1.676
0.369
1.338
23.538
0.193
0.043
0.071
0.251
24.571
0.015
0.013
0.065
0.001
0.000
0.003
0.005
0.017
0.106
0.003
0.007
0.015
0.004
0.015
0.030
0.013
0.008
0.034
0.000
0.014
0.016
0.063
55.211
unc
0.
0.
0.
0.
0.
0.
2.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
103
124
028
183
038
174
147
024
008
011
027
387
004
004
009
001
004
002
002
005
014
003
011
008
007
010
014
014
016
027
078
111
005
0.011
Measured
Xwt
0.598
1.043
0.098
0.702
0.287
1.195
21.788
0.219
0.046'
0.077
0.228
28.271
0.014
0.011
0.041
0.001
0.000
0.002
0.004
0.016'
0.097
0.004
0.014
0.017
0.007
0.015
0.026
0.019
0.009
0.007
0.000
0.027
0.020
0.068
54.971
unc
0.052
0.090
0.023
0.111
0.027
0.100
1.947
0.020
0.004
0.007
0.020
2.633
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.009
0.001
0.006
0.004
0.004
0.005
0.007
0.007
0.009
0.014
0.040
0.059
0.002
0.006
<1> Calculated based on methodology in the Air Emissions Species Manual, Volume II.
86
-------
PH Profile Speciat ion Report
Profile Name Steel Production
Profile Number 28307
Data Quality 0
- Basic
Oxygen
Furnace
Control Device UncontroUed{1>
Referenced) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30300913
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.650 0.660
Total Particulate Matter -
Spec i es
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Mum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
201
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
MO
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0
1
0
1
1
2
0
0
0
0
2
50
0
0
0
0-2.5 urn
%wt
.383
.500
.223
.525
.819
.803
.981
.375
.093
.189
.073
.131
.017
.020
.057
0.007
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.002
.003
.016
.022
.013
.002
.017
.024
.020
.040
.039
.004
.028
.018
.059
0.021
0
0
.014
.081
NR
unc
0.055
0.648
0.045
1.126
0.825
0.554
0.612
0.102
0.014
0.019
1.138
15.178
0.005
0.009
0.024
0.006
0.007
0.001
0.009
0.004
0.003
0.003
0.012
0.009
0.008
0.012
0.054
0.017
0.020
0.033
0.090
0.138
0.003
0.009
0.000
2.5-10 urn
Xut
0.285
1.060
0'. 1 1 1
0.019
0.398
1.421
0.944
0.421
0.097
0.191
1.250
60.592
0.018
0.013
0.034
0.003
0.000
0.003
0.006
0.020
0.011
0.000
0.007
0.018
0.017
0.023
0.035
0.017
0.029
0.005
0.019
0.010
0.011
0.102
NR
unc
0.092
0.637
0.051
0.198
0.394
0.536
0.851
0.046
0.014
0.021
0.622
6.059
0.003
0.003
0.023
0.003
0.008
0.001
0.002
0.008
0.004
0.003
0.010
0.008
0.009
0.010
0.016
0.016
0.018
0.030
0.078
0.120
0.004
0.045
0.000
0-10
Xut
0.383
1.500
0.223
1.525
1.819
2.803
0.981
0.375
0.093
0.189
2.073
50.131
0.017
0.020
0.057
0.007
0.002
0.003
0.016
0.022
0.013
0.002
0.017
0.024
0.020
0.040
0.039
0.004
0.028
0.018
0.059
0.021
0.014
0.081
NE
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.670
Total
Measured
Xut
0.465
1.229
0.149
1.129
0.654
3.636
1.545
0.369
0.085
0.167
• 1.470
50.199
0.016
0.014
0.047
0.005
0.003
0.002
0.009
0.027
0.016
0.002
0.005
0.013
0.030
0.035
0.020
0.012
0.035
0.017
0.083
0.000
0.012
0.076
0.440
unc
0.162
0.545
0.056
1.261
0.504
2.303
0.758
0.160
0.033
0.046
0.338
20.979
0.005
0.005
0.033
0.003
0.007
0.002
0.003
0.011
0.003
0.004
0.014
0.012
0.017
0.015
0.020
0.021
0.025
0.042
0.112
0.168
0.007
0.069
0.044
87
-------
PM Profile Speciation Report - continued (profile 28307)
Total Parttculate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 um(2> Measured
Species -- - --
CAS Number Nun Sym Xut unc Xwt unc Xut unc Xut unc
202 EC NR 0.000 NR 0.000 NE 0.000 0.000 0.030
TOTALS: 62.619 67.190 62.619 62.016
{1} No controlled specified: thus, assumed uncontrolled.
{2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
88
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Primary
29203
D
Copper Reverberatory Furnace -
Slag Tap
Control Device UncontrolledO>
Reference(s) 1,18
Data Source Data taken from Reference 1. For details, consult Reference
18.
SCC Assignments: 30300514, 30499999
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.210 0.230
Total Particulate Matter -
Species
CAS Number Mum
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
744a-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
33
Sym
Al
Si
S
Cl
K.
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
As
Se
Br
Kb
Sr
Y
Mo
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
• Bi
0-2.
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
1
60
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.190
.000
.150
.700
.000
.000
.000
.000
.000
.000
.092
.011
0.630
0
0
1
0
0
6
0
70
.012
.130
.100
.090
.000
.000
.370
.475
5 urn
unc
0.200
0.200
1.000
0.200
0.500
0.500
0.300
0.010
0.010
0.010
0.016
0.030
0.005
0.050
3.600
0.200
0.200
0.100
0.100
0.100
0.005
0.002
0.220
0.001
0.021
0.029
0.022
0.030
0.790
0.100
2.5-
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.380
0.000
0.167
0.320
71.000
0.000
0.000
0.000
0.000
0.000
0.110
0.000
0.530
0.000
0.210
0.980
0.130
0.000
8.000
NR
82.327
10 urn
unc
1.000
1.000
5.000
0.500
2.000
0.800
0.060
0.020
0.010
0.030
0.060
0.050
0.010
0.090
2.000
0.300
0.900
0.300
0.050
0.200
0.010
0.030
0.460
0.020
0.020
0.080
0.010
0.500
0.400
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.215
0.000
0.152
1.586
61.423
0.000
0.000
0.000
0.000
0.000
0.094
0.010
0.617
0.010
0.140
1.085
0.095
0.000
6.259
0.322
72.008
unc
0.896
0.896
4.478
0.468
1.806
0.806
0.239
0.019
0.012
0.028
0.070
0.050
0.028
0.220
9.226
0.307
0.809
0.276
0.089
0.193
-9. 021
0.027
0.449
0.018
0.037
0.166
0.028
0.442
1.157
0.088
(0-10)
0.270
Total
Measured<2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.215
0.000
0.152
1.586
61.423
0.000
0.000
0.000
0.000
0.000
0.094
0.010
0.617
0.010
0.140
1.085
0.095
0.000
6.259
0.322
72.008
533S55===3=33535555SE======3535SS5S=5S======3=533355SSS5SSS5=3==353SS3S5======:
O> No controlled specified:
C2> Estimated /
thus.
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
:======
assumed uncontrolled.
extrapolated.
89
-------
PM Profile Speciation Report
Profile Name Primary
Profile Number 29204
Data Quality D
Copper Reverberatory Furnace •
Control Device Uncontrolled{1>
Reference(s) 1,19
Data Source Data taken from Reference 1
19.
SCC Assignments: 30300514
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate
C*K_A.d
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
a^icv
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
Matter
*ies
Sym
Al
Si
P
s
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2
Xut
0.000
0.000
0.000
0.050
0.000
0.361
0.000
0.010
0.003
0.000
0.010
0.663
0.000
0.194
24.455
0.000
15.725
0.000
0.000
0.000
0.004
0.021
0.001
0.368
0.000
0.000
1.840
0.061
0.721
1.648
0.000
0.000
0.000
21.951
68.086
.5 urn
unc
0.081
0.296
0.097
1.351
0.209
0.049
0.338
0.009
0.003
0.013
0.004
0.066
0.049
0.019
2.446
0.075
1.573
0.071
0.855
0.012
0.004
0.054
0.016
0.037
0.001
0.004
0.184
0.007
0.072
0.165
0.008
0.014
0.077
2.195
Slag Skim i Pour
. For details, consult Reference
(0-2.5) (0-6)
0.210 0.230
2.5-10 urn
Xut
0
3
0
0
0
0
0
0
0
0
0
6
0
6
13
0
11
0
0
0
0
.030
.593
.000
.000
.000
.435
.123
.059
.175
.085
.020
.401
.115
.795
.279
.009
.732
.000
.000
.000
.001
0.007
0
0
0
0
1
0
0
1
0
0
0
13
59
.000
.377
.000
.003
.045
.083
.405
.086
.000
.000
.000
.763
.621
unc
0.733
0.359
0.291
2.596
0.345
0.086
1.151
0.055
0.021
0.019
0.005
0.640
0.057
0.680
1.375
0.116
1.601
0.146
1.461
0.020
0.008
0.080
0.082
0.038
0.003
0.017
0.231
0.025
0.077
0.215
0.042
0.078
0.145
1.376
0-10 urn
Xwt
0.002
0.233
0.000
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
1.035
0.008
0.622
23.730
0.001
15.466
0.000
0.000
0.000
0.004
0.020
0.001
0.369
0.000
0.000
1.789
0.062
0.701
1.612
0.000
0.000
0.000
21.420
67.539
unc
0.649
0.487
0.267
2.519
0.345
0.103
1.048
0.050
0.028
0.024
0.008
0.765
0.065
0.306
3.662
0.118
2.708
0.140
1.450
0.020
0.008
0.082
0.073
0.071
0.002
0.016
0.334
0.027
0.125
0.307
0.038
0.070
0.141
3.374
(0-10)
0.270
Total
Measured(2>
Xut
0.002
0.233
0.000
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
1.035
0.008
0.622
23.730
0.001
15.466
0.000
0.000
0.000
0.004
0.020
0.001
0.369
0.000
0.000
1.789
0.062
0.701
1.612
0.000
0.000
0.000
21.420
67.539
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> No controlled specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
90
-------
PH Profile Speciat ion Report
Profile Name Primary
Profile Number 29205
Data Quality 0
Copper Converter
- Secondary Hood
Control Device UncontrolledO>
Reference(s) 1,18
Data Source Data taken from Reference 1. For details, consult Reference
18.
SCC Assignments: 30300515
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.120 0.320
Total Paniculate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
Hum
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
83
Sym
Al
Si
S
Cl
K
Ca
•Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Y
Mo
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5 urn
Xwt
0
0
.000
.000
0.000
0
0
0
0
0
0
0
0
0
1
.000
.000
.000
.000
.000
.000
.000
.260
.000
.100
2.600
26
0
0
0
0
0
0
0
0
0
0
3
0
0
28
1
63
.000
.000
.000
.000
.000
.000
.000
.260
.600
.140
.530
.100
.072
.000
.000
.000
.662
unc
0.200
0.200
2.000
0.200
0.400
0.100
0.020
0.020
0.020
0.020
0.190
0.030
1.100
2.600
11.000
0.200
0.200
0.060
0.050
0.090
0.100
0.360
0.870
0.120
0.320
2.200
0.038
0.200
13.000
0.920
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
NR
7.100
NR
9.400
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.160
0.260
0.000
0.420
1.730
0.000
NR
0.000
NR
19.070
unc
3.000
10.000
30.000
5.000
5.000
2.000
0.200
0.050
0.050
0.000
1.200
0.000
T.500
2.000
22.000
0.400
1.000
0.300
0.200
2.000
0.200
0.040
0.050
0.050
0.080
0.300
0.020
0.000
20.000
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.113
0.000
2.135
2.276
22.758
0.000
0.000
0.000
0.000
0.000
0.000
0.248
- 0.558
0.123
0.516
2.929
0.063
0.000
24.509
0.875
58.103
unc
1.354
4.510
13.536
2.255
2.256
0.902
0.090
0.023
0.023
0.004
0.563
0.006
0.740
1.048
10.198
0.185
0.453
0.136
0.091
0.902
0.092
0.076
0.179
0.033
0.077
0.478
0.012
0.041
9.434
0.189
(0-10)
0.590
Total
Measured{2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.113
0.000
2.135
2.276
22.758
0.000
0.000
0.000
0.000
0.000
0.000
0.248
0.558
0.123
0.516
2.929
0.063
0.000
24.509
0.875
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
' 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
58.103
C1> No controlled specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated.
91
-------
PH Profile Special ion Report
Profile Name Primary
Profile Number 29206
Data Quality D
Copper Converter •
Control Device Uncontrolled{1>
Reference(s) 1,19
Data Source Data taken from Reference 1
19.
SCC Assignments: 30300515
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Hatter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92- 1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
Svm
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe'
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0.000
0.000
0.000
0.000
0.000
0.133
0.000
0.000
0.000
0.000
0.000
0.039
0.007
0.499
7.250
0.024
7.229
0.000
0.000
0.000
0.000
0.037
0.014
0.050
0.000
0.050
0.631
0.036
0.305
1.107
0.000
0.000
0.000
23.558
40.969
.5 urn
unc
0.039
0.231
0.087
1.393
0.215
0.017
0.145
0.003
0.001
0.005
0.004
0.004
0.002
0.050
0.725
0.035
0.831
0.059
0.359
0.006
0.004
0.046
0.014
0.005
0.000
0.005
0.063
0.004
0.031
0.111
0.004
0.008
0.025
2.356
Secondary Hood
. For details, consult Reference
(0-2.5) (0-6)
0.120 0.320
2.5-10 urn
0
0
0
0
0
0
0
0
0
0
0
0
0
1
8
Xwt
.000
.000
.000
.000
.000
.310
.000
.000
.000
.000
.000
.283
.009
.323
.546
0.000
10
0
0
0
0
0
"o
0
0
0
0
0
0
1
0
0
0
28
.534
.000
.000
.000
.001
.064
.015
.095
.000
.033
.825
.048
.445
.577
.000
.000
.000
.996
unc
0.503
1.999
0.496
4.031
0.678
0.043
0.755
0.020
0.008
0.018
0.017
0.028
0.005
0.132
0.855
0.091
2.608
0.196
1.175
0.020
0.013
0.142
0.056
0.010
0.002
0.016
0.146
0.018
0.068
0.254
0.030
0.055
0.094
2.900
53.104
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.145
0.000
0.000
0.000
0.000
0.000
0.055
0.007
0.552
7.333
0.023
7.440
0.000
0.000
0.000
0.000
0.039
0.014
0.053
0.000
0.049
0.643
0.037
0.314
1.137
0.000
0.000
0.000
23.904
41.745
unc
0.227
0.903
0.224
1.840
0.309
0.023
0.342
0.009
0.004
0.008
0.008
0.016
0.003
0.070
0.496
0.041
1.226
0.089
0.535
0.009
0.006
0.065
0.026
0.007
0.001
0.008
0.073
0.009
0.035
0.127
0.013
0.025
0.043
1.659
(0-10)
0.590
Total
Measured(2>
Xwt
0.000
0.000
0.000
0.000
0.000
0.145
0.000
0.000
0.000
0.000
0.000
0.055
0.007
0.552
7.333
0.023
7.440
0.000
0.000
0.000
0.000
0.039
0.014
0.053
0.000
0.049
0.643
0.037
0.314
1.137
0.000
0.000
0.000
23.904
41.745
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0:000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> No controlled specified: thus, assumed uncontrolled.
(2> Estimated / extrapolated.
92
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
Primary
29207
D
Copper Flash Furnace - Matte, & Slag Tap
Control Device Uncontrolled{1>
Reference(s) 1,19
Data Source Data taken from Reference 1. For details, consult Reference
19.
SCC Assignments: 30300512
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.840 0.890
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
8a
La
Hg
Pb
0
0
0
0
0
0
0
0
0
0
0
2
0-2.
Xwt
.000
.000
.000
.000
.000
.331
.000
.000
.000
.018
.013
.688
0.000
3
9
0
32
0
2
0
0
0
0
0
0
0
1
0
0
1
0
0
0
12
68
<1> No controlled specified:
{2> Estimated /
.354
.767
.000
.785
.000
.532
.000
.000
.000
.000
.161
.000
.024
.679
.031
.423
.991
.000
.000
.000
.464
.261
thus,
5 urn
unc
0.228
0.204
0.088
1.195
0.185
0.033
0.508
0.020
0.007
0.002
0.002
0.269
0.004
0.335
0.977
0.087
3.279
0.098
0.253
0.032
0.004
0.107
0.069
0.016
0.001
0.004
0.169
0.006
0.043
0.229
0.008
0.014
0.196
1.246
2.5-10 urn
Xwt
0.000
2.188
0.000
0.467
0.000
0.583
0.000
0.000
0.000
0.123
0.042
7.085
0.023
3.420
7.812
0.000
31.323
0.000
0.000
0.000
0.000
0.000
0.000
0.154
0.000
0.086
1.257
0.000
0.427
2.014
0.000
0.000
0.000
11.596
74.100
unc
0.691
0.361
0.167
3.455
0.536
0.119
2.104
0.222
0.046
0.012
0.009
0.709
0.015
0.842
1.403
0.265
5.174
0.343
5.961
0.090
0.014
0.274
0.221
0.031
0.004
0.029
0.465
0.037
0.136
0.658
0.067
0.124
0.592
1.791
0-10 urn
Xwt
0.000
0.137
0.000
0.029
0.000
0.347
0.000
0.000
0.000
0.025
0.015
2.962
0.002
3.670
9.645
0.000
32.725
0.000
2.374
0.000
0.000
0.000
0.000
0.160
0.000
0.028
1.652
0.029
0.424
1.992
0.000
0.000
0.000
12.410
68.626
unc
0.692
0.459
0.178
3.478
0.539
0.151
2.063
0.213
0.044
0.035
0.020
1.054
0.020
1.259
2.180
0.265
7.746
0.339
5.710
0.090
0.014
0.279
0.220
0.054
0.004
0.039
0.539
0.036
0.162
0.745
0.064
0.119
0.594
2.833
(0-10)
0.920
Total
Measured(2}
%wt
0.000
0.137
0.000
0.029
0.000
0.347
0.000
0.000
0.000
0.025
0.015
2.962
0.002
3.670
9.645
0.000
32.725
0.000
2.374
0.000
0.000
0.000
0.000
0.160
0.000
0.028
1.652
0.029
0.424
1.992
0.000
0.000
0.000
12.410
68.626
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
assumed uncontrolled.
extrapolated.
93
-------
PM Profile Speciation Report
Profile Name Primary
Profile Number 29208
Data Quality D
Copper -
Process
Stack
Control Device Uncontrolled{1>
Referenced) 1,18
Data Source Data taken from Reference 1. For details, consult Reference
18.
SCC Assignments: 30300524
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.970 1.000
Total Paniculate Matter
Species
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
TOTALS:
Nun
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
83
Sym
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Y
Mo
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
Bi
0-2.5 urn
%ut
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0,
0.
3.
4.
24.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
016
014
009
290
040
000
200
000
000
000
000
000
000
100
120
510
0.023
0.400
6.
0.
0.
18.
0.
57.
000
170
000
000
400
292
unc
0.200
0.200
2.900
0.300
0.500
0.800
0.100
0.001
0.001
0.004
0.020
0.008
0.260
1.400
2.600
0.100
0.300
0.100
0.100
0.100
0.012
0.015
0.150
0.005
0.063
0.580
0.025
0.200
0.930
0.082
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.017
0.015
0.400
0.070
2.400
4.000
38.000
0.000
0.000
0.000
0.000
0.000
0.134
0.120
0.460
0.000
0.390
5.600
0.180
0.000
16.000
NR
67.801
unc
2.000
1.000
2.000
0.500
0.500
2.000
0.200
0.003
0.005
0.003
0.060
0.020
0.200
1.400
9.000
0.200
1.000
0.100
0.100
0.100
0.035
0.050
0.080
0.020
0.070
0.400
0.030
0.500
2.000
0.000
0-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.015
0.010
0.313
0.046
2.876
4.159
26.393
0.000
0.000
0.000
0.000
0.000
0.107
0.120
0.500
0.018
0.398
5.917
0.172
0.000
17.587
0.317
59.464
unc
1.979
1.004
2.765
0.572
0.691
2.117
0.220
0.013
O'.OU
0.013
0.104
0.034
0.590
2.065
10.474
0.220
1.027
0.138
0.138
0.138
0.054
0.065
0.196
0.021
0.129
1.223
0.063
0.529
3.654
0.097
(0-10)
1.000
Total
Measured{2)
%ut
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.015
0.010
0.313
0.046
2.876
4.159
26.893
0.000
0.000
0.000
0.000
0.000
0.107
0.120
0.500
0.018
0.398
5.917
0.172
0.000
17.587
0.317
59.464
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> No controlled specified: thus, assumed uncontrolled.
(2> Estimated / extrapolated.
94
-------
PN Profile Special ton Report
Profile Name Primary
Profile Number 29209
Data Quality D
Copper Roaster
Control Device Uncontrolledd}
Reference(s) 1,18
Data Source Data taken from Reference 1. For details, consult Reference
18.
SCC Assignments: 30300502, 30300509
Mass' Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.970 1.000
Total Particulate
Matter
(0-10)
1.000
Total
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
13494-80-9
7439-97-6
7439-92-1
7440-69-9
a^i i ea
Num Sym
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
52
80
82
83
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
8r
Rb
Sr
Y
MO
Ag
Cd
In
Sn
Sb
Te
Hg
Pb
3i
6
13
9
0
1
0-2.5 urn
Xwt
.300
.500
.800
.000
.010
2.000
0
0
0
0
18
0
18
1
4
0
.260
.000
.066
.137
.600
.110
.600
.090
.200
.000
0.000
0.000
0
0
0
0
0
0
0
0
0
0
2
0
.050
.000
.160
.000
.000
.000
.000
.340
.000
.000
.130
.300
unc
0.600
1.200
0.900
0.100
0.100
0.170
0.050
0.050
0.015
0.015
1.500
0.050
1.500
0.120
0.400
0.050
0.300
0.040
0.020
0.030
0.050
.0.200
0.200
0.200
0.200
0.160
0.200
0.100
0.180
0.100
2.5-10 urn
Xwt
2.400
4.300
8.100
0.000
0.420
1.520
0.160
0.000
0.040
0.081
13.000
0.000
18.400
1.020
3.700
0.000
0.000
0.000
0.000
0.000
0.120
0.042
0.000
0.000
0.000
0.076
0.000
0.000
1.750
0.060
unc
0.200
0.500
0.300
0.100
0.080
0.110
0.040
0.040
0.020
0.018
0.600
0.080
1.900
0.080
0.600
0.030
0.200
0.050
0.040
0.040
0.040
0.010
0.020
0.020
0.020
0.021
0.100
0.040
0.100
0.030
0-10 um
Xwt
2.621
5.293
8.196
0.000
0.453
1.642
0.166
0.000
0.042
0.084
13.317
0.006
18.411
1.024
3.728
0.000
0.000
0.000
0.003
0.000
0.122
0.040
0.000
0.000
0.000
0.091
0.000
0.000
1.772
0.074
unc
1.096
2.300
1.830
0.138
0.201
0.393
0.083
0.062
0.033
0.041
3.269
0.094
3.935
0.248
0.998
0.057
0.351
0.063
0.044
0.049
0.075
0.195
0.195
0.195
0.195
0.166
0.218
0.105
0.413
0.112
MeasuredC2>
Xwt
2.621
5.293
8.196
0.000
0.453
1.642
0.166
0.000
0.042
0.084
13.317
0.006
18.411
1.024
3.728
0.000
0.000
0.000
0.003
0.000
0.122
0.040
0.000
0.000
0.000
0.091
0.000
0.000
1.772
0.074
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
78.653
55.789
57.085
57.085
<1> No controlled specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
95
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Primary Copper Reverberatory Furnace Fugitives Composite
29210
0
Control Device
Reference(s)
Data Source
Uncontrolled
Profile represents a composite of Profiles 29203 and 29204,
fugitive emissions from reverb furnace slag tapping and
slag skimming.
SCC Assignments: 30300514
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Hatter
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7439-97-6
7439-92-1
3yd. 1 C9
Num Sym
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
80
82
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
3r
Rb
Sr
Y .
HO
Ag
Cd
In
Sn
Sb
Hg
Pb
0-2
Xwt
0.000
0.000
0.050
0.000
0.361
0.000
0.010
0.003
0.000
0.010
0.427
0.000
0.172
13.078
37.863
0.000
0.000
0.000
0.004
0.021
0.230
0.006
1.235
0.037
0.426
1.374
0.000
13.976
.5 urn
uncd>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5)
: 0.210
2.5-10 urn
Xut uncO}
0.003
3.593
0.000
0.000
0.435
0.123
0.059
0.175
0.085
0.020
3.391
0.115
3.481
7.050
41.366
0.000
0.000
0.000
0.001
0.007
0.244
0.002
0.788
0.042
0.308
1.033
0.000
10.882
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.230
0-10 urn
Xwt uncC1>
0.002
0.233
0.047
0.000
0.366
0.008
0.013
0.014
0.006
0.010
0.625
0.008
0.387
12.658
38.445
0.000
0.000
0.000
0.004
0.020
0.232
0.005
1.203
0.036
0.421
1.349
0.000
13.840
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.270
Total
Measured
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
12
38
0
0
0
0
0
0
0
1
0
0
1
0
13
.002
.233
.047
.000
.366
.008
.013
.014
.006
.010
.625
.008
.387
.658
.445
.000
.000
.000
.004
.020
.232
.005
.203
.036
.421
.349
.000
.840
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
69.283
73.203
69.932
69.932
Uncertainty not evaluated.
96
-------
PM Profile Speciation Report
Profile Name Primary
Profile Nunber 29211
Data Quality 0
Copper Converter
- Secondary Hood Composite
Control Device Uncontrolled
Reference(s)
Data Source Profile represents a composite of Profiles 29205 and 29206.
SCC Assignments 30300515
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.120 0.320
Total Participate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7439-97-6
7439-92-1
TOTALS:
Num
13
14
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
39
42
47
48
49
50
51
80
82
Sym
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Y
Mo
Ag
Cd
In
Sn
Sb
Hg
Pb
0-2.5 urn
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.067
.000
.000
.000
.000
.000
.150
.004
.800
4.925
16
0
0
0
0
0
0
0
0
0
0
2
0
25
51
.615
.000
.000
.000
.000
.019
.030
.155
.616
.088
.418
.104
.000
.779
.770
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.boo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xut
0.000
0.000
0.000
0.000
0.155
0.000
0.000
0.000
0.000
0.000
3.692
0.005
5.362
4.273
5.267
0.000
0.000
0.000
0.000
0.032
0.048
0.097
0.543
0.024
0.433
1.654
0.000
14.498
36.083
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.000
0.000
0.000
0.000
0.073
0.000
0.000
0.000
0.000
0.000
0.584
0.004
1.344
4.805
15.099
0.000
0.000
0.000
0.000
0.020
0.027
0.149
0.601
0.080
0.415
2.033
0.000
24.207
49.441
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.590
Total
Measured
Xut
0.000
0.000
0.000
0.000
0.073
0.000
0.000
0.000
0.000
0.000
0.584
0.004
1.344
4.805
15.099
0.000
0.000
0.000
0.000
0.020
0.027
0.149
0.601
0.080
0.415
2.033
0.000
24.207
49.441
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Uncertainty not evaluated.
97
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Primary Lead - Dross Building
29310
D
Control Device
Reference(s)
Data Source
Uncontrolled<:i>
1,14
Data taken from Reference 1. For details, consult Reference
14.
SCC Assignments: 30301009
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
at*=u i ess
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
0.003
0.
0.
0.
0.
0.
0.
58.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
482
023
179
745
027
289
000
000
000
007
026
018
051
000
081
0.548
0.
028
0.233
5.871
0.065
0.122
0.000
13.256
.5 urn
unc
0.078
0.024
0.016
0.416
0.147
0.040
0.080
0.008
0.002
0.008
0.003
0.634
0.042
0.052
0.200
0.092
9.331
0.016
0.194
0.042
0.012
0.088
0.009
0.026
0.002
0.075
0.297
0.084
0.400
4.088
0.060
0.141
0.024
9.693
80.054
: (0-2.5)
: 0.830
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ood
0.005
0.000
0.000
1.431
0.073
1.889
0.672
0.035
6.755
0.000
0.000
0.000
0.016
0.000
0.039
0.033
0.017
0.290
0.133
0.047
0.842
1.077
0.000
0.000
0.040
15.791
29. 185
unc
0.111
0.056.
0.023
0.635
0.130
0.045
0.113
0.011
0.021
0.003
0.006
0.820
0.102
0.457
0.235
0.146
5.152
0.028
0.065
0.016
0.055
0.039
0.128
0.089
0.056
0.155
0.235
0.190
0.320
0.855
0.028
0.028
0.155
5.347
(0-6)
0.930
0-10 umC2>
Xut
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.003
0.000
0.627
0.031
0.441
0.734
0.028
50.401
0.000
0.000
0.000
0.008
0.022
0.021
0.048
0.003
0.113
0.484
0.031
0.326
5.137
0.055
0.103
0.006
13.644
72.267
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.980
Total
Measured
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.000
0.770
0.038
0.697
0.723
0.030
42.673
0.000
0.000
0.000
0.010
0.018
0.024
0.046
0.005
0.144
0.422
0.034
0.418
4.418
0.045
0.085
0.012
14.024
64.640
unc
0.064
0.024
0.013
0.348
0.110
0.031
0.065
0.007
0.007
0.006
0.003
0.511
0.043
0.152
0.172
0.078
8.645
0.014
0.137
0.030
0.019
0.063
0.039
0.033
0.017
0.071
0.224
0.082
0.297
2.906
0.043
0.099
0.050
7.113
<1> No controlled specified: thus, assumed uncontrolled.
C2> Calculated based on methodology described in the Air Emissions Species Hanual,
Volume II.
98
-------
PH Profile Speciat ion Report
Profile Name Primary Lead - Slag
Profile Number 29311
Data Quality E
Pour
Control Device Uncontrol ted<1>
Reference(s) 1,14
Data Source Data taken from Reference 1. For details, consult Reference
14.
SCC Assignments: 30301021
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.730 0.830
Total Participate
Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apw i ca
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr .
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2.5
Xut
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
um<2}
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
77.671
2.5-10 unK2J
Xut
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.890
Total
Measured
Xut
0.000
0.000
0.000
0.000
0.000
0.959
0.091
0.000
0.000
0.043
0.044
0.319
0.000
0.084
48.556
0.034
0.060
0.000
0.000
0.021
0.000
0.000
0.015
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.000
0.015
27.417
77.671
unc
0.023
0.011
0.011
1.506
0.311
0.557
0.104
0.002
0.001
0.082
0.081
0.039
0.010
0.181
11.856
0.123
1.626
0.011
0.016
0.125
0.010
0.079
0.034
0.007
0.023
0.011
0.023
0.062
0.045
0.023
0.045
0.045
0.042
2.821
{1} No control specified: thus, assumed uncontrolled.
{2} Estimated / extrapolated.
99
-------
3.4 SECONDARY METAL PRODUCTION
Secondary metal production is the production of metals from scrap
material. Processes generating particulate emissions can include smelting,
pouring into molds, cleaning, refining, alloying, and storage and handling.
101
-------
PM Profile Special ion Report
Secondary Aluminum - Dross Recovery Furnace
Profile Name
Profile Number
Data Quality
20103
0
Control Device UncontrolledO}
Reference(s) 1,2
Data Source Data taken from Reference 1. For details, consult Reference
2.
SCC Assignments: 30400107
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Matter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-22-4
7440-31-5
7440-36-0
7439-91-0
7440-45-1
7439-92-1
7440-29-1
ayci. i «r»
Nun Sym
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
37
47
50
51
57
58
82
90
201
202
203
204
Na
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Ag
Sn
Sb
La
Ce
Pb
Th
OC
EC
S04
N03
0-2
Xwt
15.
1.
3.
0.
3.
20.
10.
0.
0.
0.
0.
500
700
100
450
000
000
900
120
NR
024
004
039
0.012
0.
0.
0.
290
001
033
0.045
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
075
002
006
063
009
NR
055
570
002
NR
081
NR
500
190
400
2.200
.5. urn
unc
1.600
0.200
2.200
0.270
4.000
4.000
1.500
0.090
0.000
0.003
0.001
0.004
0.001
0.090
0.000
0.003
0.020
0.008
0.001
0.001
0.007
0.004
0.000
0.054
0.060
0.001
0.000
0.014
0.000
1.400
0.070
0.360
0.900
: (0-2.5)
: 0.820
2.5-10 urn
Xwt
18.000
4.700
7.600
0.370
2.000
21.000
6.300
0.870
0.000
0.120
0.006
0.061
0.029
1.200
0.006
0.056
0.110
0.190
0.002
0.009
0.039
NR
0.008
NR
NR
NR
0.002
0.098
0.000
43.000
4.000
NR
NR
unc
4.400
0.800
3.700
0.110
0.200
5.000
4.500
0.260
0.000
0.040
0.004
0.007
0.011
0.200
0.001
0.029
0.030
0.020
0.001
0.001
0.008
0.000
0.001
0.000
0.000
0.000
0.001
0.031
0.000
33.000
1.400
0.000
0.000
(0-6)
0.890
0-10
Xwt
15.772
2.026
3.589
0.441
2.891
20.109
10.400
0.202
NE
0.034
0.004
0.041
0.014
0.389
0.002
0.036
0.052
0.088
0.002
0.007
0.060
NE
NE
NE
NE
NE
NE
0.083
NE
6.011
0.604
NE
NE
(0-10)
0.920
Total
um(2} Measured
unc
5.081
0.926
4.088
0.275
3.597
6.709
4.700
0.282
0.000
0.049
0.008
0.024
0.018
0.252
0.006
0.035
0.045
0.047
0.004
0.008
0.021
0.000
0.000
0.000
0.000
0.000
0.000
0.044
0.000
31.420
1.381
0.000
0.000
Xwt
15.972
2.266
3.949
0.435
2.811
20.189
10.032
0.262
0.000
0.042
0.004
0.043
0.015
0.462
0.002
0.037
0.057
0.097
0.002
0.007
0.059
0.008
0.002
0.045
0.463
0.001
0.000
0.084
0.000
9.330
0.909
0.325
1.785
unc
2.374
0.319
1.959
0.226
3.263
4.091
1.910
0.091
0.000
0.009
0.001
0.006
0.003
0.093
0.000
0.007
0.018
0.012
0.001
0.001
0.009
0.003
0.000
0.044
0.077
0.000
0.000
0.016
0.000
6.375
0.281
0.295
0.766
TOTALS:
60.371
109.776
62.857
69.695
{1} No control specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
103
-------
PM Profile Speciat ion Report
Profile Name Seconary Lead
Profile Number 20402
Data Quality E
• Sanitary
Baghouse
Control Device Not Applicable
Reference(s) 1,15
Data Source Data taken from Reference 1. For details, consult Reference
15.
SCC Assignments: 30400499
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.650 0.780 0.840
Total Particulate
Hatter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
ap^w i ca
Nun Sym
11
12
13
14
15
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
80
82
Na
Mg
Al
Si
P
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
8r
Rb-
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
Total
0-2.5
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
120
015
150
072
010
380
390
039
011
000
015
031
320
002
021
120
032
035
005
004
001
004
014
000
010
001
106
0.840
0.035
0.003
11.500
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 18.286 18.286
0-10
Xut
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
18.286
um<1> Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.120
0.015
0.150
0.072
0.010
0.380
0.390
0.039
0.011
0.000
0.015
0.031
4.320
0.002
0.021
0.120
0.032
0.035
0.005
0.004
0.001
0.004
0.014
0.000
0.010
0.001
0.106
0.840
0.035
0.003
11.500
18.286
unc
0.024
0.015
0.030
0.014
0.010
0.076
0.120
0.020
0.008
0.000
0.003
0.006
0.364
0.001
0.004
0.024
0.013
0.012
0.002
0.001
0.001
0.003
0.014
0.001
0.010
0.000
0.106
0.168
0.035
0.005
1.200
O> Estimated / extrapolated.
104
-------
PM Profile Speciation Report
Profile Name Seconary Lead - Reverberatory Furnace
Profile Number 20403
Data Quality E
Control Device Uncontrolled{1>
Reference(s) 1,15
Data Source Data taken from Reference 1. For details, consult Reference
15.
SCC Assignments: 30400402
Mass Fraction Data - Size Interval
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
um€3>
unc
0.000
0.000
0.000
0.000
0.000
0.000
o.ootf
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
I=3SSZSS
Measured
Xut
1.043
0.054
0.323
0.398
0.215
2.118
1.312
0.301
0.688
0.005
0.005
0.118
0.033
0.946
0.002
0.022
0.269
0.172
0.355
0.050
0.290
0.022
0.027
0.280
0.022
0.645
0.000
0.065
1.893
0.807
0.108
11.400
23.988
========
unc<3>
0.209
0.054
0.065
0.080
0.215
0.422
0.262
0.065
0.138
0.005
0.001
0.032
0.007
0.189
0.002
0.022
0.054
0.034
0.071
0.013
0.058
0.043
0.027
0.151
0.022
0.430
0.000
0.409
0.379
0.807
0.043
1.183
{1} No control specified: thus, assumed uncontrolled.
{2} Estamated / extrapolated.
{3} Estimated / extrapolated.
105
-------
PM Profile Speciat ion Report
Profile Name
Profile Member
Data Quality
Seconary Lead
20404
E
Melting Pot Fugitives
Control Device
Reference(s)
Data Source
UncontrolledO)
1.15
Data taken from Reference 1. For details, consult Reference
15.
SCC Assignments: 30400413
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Participate Matter -
0-2.5
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
"7440-36-0
7440-39-3
7439-97-6
7439-92- 1
TOTALS:
S3SSSSSSSSSSS
a|JW 1 V9
Num Sym
11
-12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
30
82
Na
Mg
Al
Si
P
S
Cl
1C
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
8a
Kg
Pb
Xut
0.
0.
1.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
559
353
529
412
112
230
506
065
218
039
002
006
010
329
001
018
129
055
212
003
007
012
012
088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
18.021
: (0
: 0
2.5-10
Xwt
0.559
0.353
1.529
1.412
0.112
0.230
0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
18.021
-2.5)
.650
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-6)
0.780
0-10 unK3>
Xut
0.559
0.353
1.529
1.4.12
0.112
0.230
• 0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
18.021
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.840
Total
Measured
Xwt
0.559
0.353
1.529
1.412
0.112
0.230
0.506
0.065
0.218
0.039
0.002
0.006
0.010
0.329
0.001
0.018
0.129
0.055
0.212
0.003
0.007
0.012
0.012
0.088
0.001
0.035
0.001
0.171
1.294
0.588
0.024
10.000
18.021
unc<3}
0.112
0.077
0.306
0.282
0.112
0.230
0.101
0.029
0.047
0.014
0.001
0.012
0.002
0.066
0.001
0.012
0.026
0.011
0.042
'0.003
0.001
0.0'12
0.012
0.071
0.001
0.029
0.001
0.171
0.259
0.588
0.024
1.177
O> No control specified: thus, assumed uncontrolled.
{2} Estamated / extrapolated.
<3> Estimated / extrapolated.
106
-------
PM Profile Speciat ion Report
Profile Name Seconary Lead - Melting
Profile Number 20405
Data Quality E
Pot Stack
Control Device Baghouse
Reference(s) 1,15
Data Source Data taken from Reference 1. For details, consult Reference
15.
SCC Assignments: 30400401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.710 0.840
Total Particulate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-97-6
7439-92-1
TOTALS:
Mum
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
46
47
48
49
50
51
56
80
82
= SSS3S
Syra
Na
Mg
Al
Si
p
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Pd
Ag
Cd
In
Sn
Sb
Ba
Hg
Pb
0-2.5
Xwt
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
umC1>
0
0
0
0
0
0
0
0
0
0
0
0
0
0
unc
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
0
.000
.000
.000
.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
2.5-10
Xut
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0,175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
unKD
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
(0-10)
0.890
Total
unK1> Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xut
0.205
0.063
0.243
0.234
0.097
0.167
0.365
0.083
0.039
0.017
0.000
0.007
0.002
0.175
0.000
0.019
0.020
0.034
0.036
0.001
0.032
0.005
0.005
0.010
0.001
0.004
0.000
0.073
0.080
0.122
0.020
11.100
13.259
unc
0.041
0.027
0.049
0.047
0.097
0.167
0.073
0.017
0.020
0.006
0.000
0.005
0.000
0.035
0.000
0.006
0.005
0.007
0.007
0.001
0.006
0.005
0.005
0.034
0.001
0.004
0.000
0.097
0.016
0.122
0.015
1.120
<1> Estimated / extrapolated.
107
-------
PM Profile Speciation Report
Profile Name Seconary Leao
Profile Number 20406
Data Quality E
- Yard Dust
Control Device Not Applicable
Reference(s) 1,16
Data Source Data taken from Reference 1. For
16.
SCC Assignments: 30400499
Mass Fraction Data - Size Interval (urn) : (0
Mass Fraction : 0
Total Particulate Matter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apw i cst
Num Sym
11
13
14
15
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Na
Al
Si
P
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Sr
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0.
1.
2.
0.
b.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
t.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
420
866
971
909
610
406
122
041
017
021
020
458
090
t51
150
042
000
052
014
008
020
041
063
097
044
064
650
000
186
2.600
0.020
0.088
0.016
66.630
.5 urn
unc
0.084
0.373
0.549
0.183
0.120
0.018
0.054
0.008
0.003
0.004
0.004
0.092
0.018
0.030
0.030
0.042
0.200
0.052
0.003
0.008
0.020
0.041
0.063
0.019
0.044
0.016
0.620
0.000
0.186
0.520
0.010
0.088
0.016
6.663
79.887
2.5-10
Xut
0.533
1.466
2.367
0.681
0.872
0.500
0.124
0.009
0.005
0.023
0.020
0.408
0.090
0.156
0.156
0.041
0.397
0.053
0.010
0.008
0.014
0.041
0.063
0.121
0.163
0.039
0.527
0.000
0.347
1.055
0.015
0.046
0.014
68.091
78.455
details, consult Reference
-2.5) (0-6)
.350 0.390
umO}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 UnK2>
Xut
0.434
1.816
2.896
0.880
0.643
0.418
0.122
0.037
0.016
0.021
a. 020
0.452
0.090
0.152
0.151
0.041
0.925
0.052
0.013
0.008
0.019
0.041
0.063
0.100
0.059
0.061
0.635
0.000
0.206
2.407
0.019
0.083
0.015
66.813
79.708
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.400
Total
Measured
Sut
0.533
1.466
2.367
0.681
0.872
0.500
0.124
0.009
0.005
0.023
0.020
0.408
0.090
0.156
0.156
0.041
0.397
0.053
0.010
0.008
0.014
0.041
0.063
0.121
0.163
0.039
0.527
0.000
0.347
1.055
0.015
0.046
0.014
68.091
78.455
unc
0.091
0.229
0.370
0.105
0.151
0.085
0.037
0.002
0.002
0.004
0.003
0.065
0.015
0.026
0.026
0.034
0.056
0.044
.0.002
0.006
0.016
0.034
0.052
0.021
0.154
0.026
0.411
0.000
0.311
0.149
0.005
0.033
0.012
6.809
O> Estimated / extrapolated.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
108
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Antimony Oxide Plant
20503
E
Antimony Roasting
Control Device
Reference(s)
Data Source
Uncontrolled^}
1.2
Data taken from Reference 1. For details, consult Reference
2.
SCC Assignments: 30400299
Mass Fraction Data -
Size Interval (urn) :
Mass Fraction :
(0-2.5)
0.180
(0-6)
0.370
(0-10)
0.530
Total Particulate Hatter -
Total
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-32-6
7440-62-2
7439-96-5
7440-02-0
7726-95-6
7440-31-5
7440-36-0
7439-92-1
Spec i es
Num Sym
13
14
16
17
22
23
25
28
35
50
51
82
201
202
203
Al
Si
S
Cl
Ti
V
Mn
Ni
Br
Sn
Sb
Pb.
OC
EC
S04
0
1
0
0
0
0
,0
0
74
0
1
0
0
0-2
Xwt
.030
NR
.280
.011
NR
.001
.001
.014
.022
.530
.000
.170
.000
.099
.052
.5 urn
unc
0.053
0.000
0.070
0.018
0.000
0.000
0.000
0.001
0.001
0.030
4.000
0.040
0.600
0.014
0.012
2.5-10 um
%ut
0.330
0.750
1.300
0.990
1.000
0.002
0.001
0.012
0.028
NR
76.000
0.110
4.300
0.230
NR
unc
0.500
0.810
0.100
0.130
0.600
0.003
0.001
0.003
0.001
0.000
13.000
0.020
1.600
0.280
0.000
0-10
Xut
0.228
NE
1.293
0.658
NE
0.001
0.001
0.013
0.026
NE
75.321
0.130
3.509
0.186
NE
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0,000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured{3}
%wt
0.228
NE
1.293
0.658
NE
0.001
0.001
0.013
0.026
NE
75.321
0.130
3.509
0.186
NE
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
77.210
35.553
81.366
81.366
{1} No control specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
<3> Estimated / extrapolated.
109
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Secondary
29501
E
Copper Pyrometal - Cathode Charge
Control Device Uncontrolled^!}
Reference(s) 1,14
Data Source Data taken from Reference 1. For details, consult Reference
H.
SCC Assignments: 30400215
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.820 0.890
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-3
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
ap«v i «%
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
C1> No control
(2> Estimated /
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
specified:
0-2.5
Sut
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
0.000
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
0.000
2.521
21.248
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
thus, assumed
2.5-10
Xut
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
0.000
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
0.000
2.521
21 .248
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.-ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.000
0.000
0.000
0.187
0.373
0.152
0.273
0.000
0.000
0.000
0.007
0.176
0.000
15.435
1.672
0.000
0.015
0.000
0.037
0.001
0.000
0.000
0.004
0.046
0.000
0.000
0.000
0.000
0.349
0.000
0.000
0.000
0.000
2.521
21.248
um<2}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.920
Total
Measured
0
0
0
0
0
0
0
0
0
0
0
0
0
15
1
0
0
0
0
0
0
0
0
0
0
0
0
0
Xwt
.000
.000
.000
.187
.373
.152
.273
.000
.000
.000
.007
.176
.000
.435
.672
.000
.015
.000
.037
.001
.000
.000
.004
.046
.000
.000
.000
.000
0.349
0
0
0
0
2
21
.000
.000
.000
.000
.521
.248
unc
0.076
0.152
0.030
0.182
0.075
0.061
0.076
0.008
0.005
0.003
0.002
0.035
0.015
3.087
0.334
0.015
0.142
0.008
0.007
0.002
0.003
0.010
0.008
0.015
0.008
0.012
0.030
0.015
0.070
0.015
0.076
0.122
0.008
0.504
uncontrolled.
extrapolated.
110
-------
PH Profile Speciat ion Report
Profile Name Secondary Copper
Profile Number 29502
Data Quality E
Pyrometal - Regular Charge
Control Device UncontrolledO}
Reference(s) 1,14
Data Source Data taken from Reference 1. For details, consult Reference
14.
SCC Assignments: 30400214
Mass Fraction Data - Siie Interval (urn) : <0-2.5) (0-6)
Mass Fraction : 0.820 0.890
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
ape& i es
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
As
Se
Sr
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0
0
0
0
2
0
0
0
0
0
0
0
0
18
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
7
33
0-2.5
%wt
.000
.000
.000
.348
.004
.320
.594
.000
.000
.000
.000
.312
.093
.755
.745
.027
.135
.157
.017
.000
.000
.000
.000
.000
.000
.000
.000
.000
.532
.000
.000
.000
.000
.159
.198
uiK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%wt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.755
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000'
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.755
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
um(2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.920
Total
Measured
%wt
0.000
0.000
0.000
0.348
2.004
0.320
0.594
0.000
0.000
0.000
0.000
0.312
0.093
18.755
2.745
0.027
0.135
0.157
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.532
0.000
0.000
0.000
0.000
7.159
33.198
unc
0.191
0.511
0.064
0.579
0.401
0.064
0.119
0.006
0.006
0.006
0.006
0.062
0.019
3.751
0.549
0.035
0.410
0.031
0.011
0.008
0.009
0.030
0.039
0.032
0.032
0.032
0.057
0.063
0.115
0.097
0.319
0.638
0.010
1.432
{1} No control specified: thus, assumed uncontrolled.
(2> Estimated / extrapolated.
Ill
-------
3.5 MINERAL PRODUCTS INDUSTRY
Production and processing of minerals produces particulate emissions
frequently of the same composition as the finished product. This is because
most of the processes involved generate dust. These processes include
quarrying, crushing, screening, drying, and storage and handling.
113
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Portland Cement Oust
27204
E
Control Device
Reference(s)
Data Source
SCC Assignments
Uncontrolledd}
1
Unspecified methodology.
30500618, 30500619
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7440-47-3
7439-96-5
7439-89-6
7440-66-6
7440-24-6
Qfjeu i cs
Nun Sym
13
14
15
16
19
20
22
24
25
26
30
38
Al
Si
P
S
K
Ca
Ti
Cr
Mn
Fe
Zn
Sr
0-2.5
Xut
2.000
10.200
0.100
0.880
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
um<2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.
5-10
Xut
2.
10.
0.
0.
0.
46.
0.
0.
0.
2.
0.
0.
000
200
100
380
140
100
140
007
030
940
008
260
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
2.000
10.200
0.100
0.380
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
umC2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Total
Measured
Xut
2.000
10.200
0.100
0.880
0.140
46.100
0.140
0.007
0.030
2.940
0.008
0.260
unc
0.400
2.000
0.020.
0.170
0.028
4.610
0.028
0.001
0.006
0.580
0.002
0.052
TOTALS:
62.805
62.805
62.305
O> No control specified: thus, assumed uncontrolled.
C2> Estimated / extrapolated.
62.805
115
-------
PM Profile Speciation Report
Profile Name Cement Ball Hill
Profile Number 27205
Data Quality 0
Control Device UncontrolledCI}
Referenced) 1,17
Data Source Data taken from Reference 1. For
17.
SCC Assignments: 30500609, 30500610
Mass Fraction Data - Size Interval (urn) : (0
Mass Fraction : 0
Total Participate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-3
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
In
Ga
As
Se
Br
ftb
Sr
Y
Zr
Mo-
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2.5
Xwt
2.
3.
0.
2.
0.
0.
24.
0.
0.
0.
0.
1.
0.
0.
0.
0.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
542
363
105
357
328
873
175
186
016
016
273
221
004
000
013
001
002
001
002
010
091
010
015
015
005
008
013
000
005
000
063
001
002
0.011
um<:2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
40.727
2.5-10
Xwt
2.542
3.363
0.105
2.357
0.328
0.373
24.175
0.186
0.016
0.016
0.273
1.221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0.010
0.091
0.010
• 0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
40.727
details, consult Reference
-2.5) (0-6)
.300 0.620
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um<2>
Xwt
2.542
8.363
0.105
2.357
0.328
0.373
24.175
0.186
0.016
0.016
0.273
1.221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0.010
0.091
0.010
0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
40.727
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.850
Total
Measured
Xwt
2.542
8.363
0.105
2.357
0.328
0.373
24.175
0.186
0.016
0.016
0.273
1.221
0.004
0.000
0.013
0.001
0.002
0.001
0.002
0.010
0.091
0.010
0.015
0.015
0.005
0.008
0.013
0.000
0.005
0.000
0.063
0.001
0.002
0.011
40.727
unc
0.639
2.332
0.029
0.480
0.049
0.131
3.626
0.029
0.004
0.002
0.041
0.183
0.001
0.001
0.002
0.000
0.001
0.000
0.001
0.002
0.014
0.001
0.005
0.003
0.002
0.003
0.005
0.005
0.005
0.009
0.024
0.034
0.001
0.002
O> No control specified: thus, assumed uncontrolled.
(2) Estimated / extrapolated.
116
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
SCC Assignments
Gypsum Handling
27502
E
Uncontrolled*!}
1
Unspecified methodology.
30501504, 30501508
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.300 0.620
Total Participate Matter -
0-2.5 um<2} 2.5-10 unK2> 0-10 unK2>
CAS Number Nun Sym Xwt unc Xwt unc Xwt unc
(0-10)
0.850
Total
Measured
Xut unc
7704-34-9 16 S 18.600 0.000 18.600 0.000 18.600 0.000 18.600 1.860
7440-70-2 20 Ca 23.300 0.000 23.300 0.000 23.300 0.000 23.300 2.330
203 S04 55.800 0.000 55.800 0.000 55.800 0.000 55.800 5.580
TOTALS:
97.700
97.700
97.700
97.700
{1} No control specified: thus, assumed uncontrolled.
(2> Estimated / extrapolated.
117
-------
PM Profile Speciation Report
Profile Name Gypsum Kiln
Profile Number 27503
Data Quality E
Control Device ESP
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30501520
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.180 0.370
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apci. i cs»
Mum Sym
13
14
. 15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
0-2
%ut
2
1
1
11
0
0
23
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
.044
.036
.733
.783
.000
.148
.792
.530
.334
.123
.068
.928
.010
.019
.017
.003
.000
.002
.015
.007
.768
.058
.178
.015
.032
.000
.000
.000
.000
.000
0.260
0.077
Hg 0.009
Pb
0
.083
.5 urn
unc
0.204
0.283
0.348
1.178
0.063
0.037
2.379
0.053
0.033
0.012
0.007
0.093
0.004
0.004
0.003
0.002
0.009
0.003
0.004
0.004
0.177
0.007
0.085
0.016
0.015
0.020
0.029
0.032
0.035
0.066
0.189
0.270
0.005
0.012
2.5-10 urn
Xwt
1.200
0.728
0.736
15.456
0.000
0.058
20.938
0.179
0.089
0.032
0.022
0.327
0.002
0.018
0.007
0.001
0.000
0.001
0.004
0.007
0.697
0.017
0.073
0.005
0.000
0.009
0.014
0.000
Q.OOO
0.000
0.114
0.098
0.004
0.036
unc
0.120
0.127
0.149
1.546
0.073
0.028
2.094
0.018
0.009
0.003
0.002
0.033
0.001
0.002
0.001
0.001
0.003
0.001
0.001
0.001
0.070
0.002
0.033
0.006
0.006
0.008
0.011
0.011
0.015
0.024
0.072
0.103
0.002
0.005
0-10
Xut
1.487
0.832
1.074
14.208
0.000
0.088
21.907
0.298
0.172
0.063
0.038
0.531
0.005
0.018
0.010
0.002
0.000
0.001
0.008
0.007
1.061
0.031
0.108
0.008
0.011
0.006
0.010
0.000
0.000
0.000
0.164
0.091
0.005
0.052
umO>
unc
0.147
0.135
0.172
1.256
0.048
0.023
1.991
0.035
0.022
0.009
0.006
0.061
0.002
0.004
0.003
0.001
0.003
0.001
0.002
0.002
0.116
0.005
0.037
0.007
0.006
0.009
0.012
0.013
0.015
0.026
0.078
0.110
0.002
0.008
(0-10)
0.850
Total
Measured{2>
Xut
1.487
0.832
1.074
14.208
0.000
0.088
21.907
0.298
0.172
0.063
0.038
0.531
0.005
0.018
0.010
0.002
0.000
0.001
0.008
0.007
1.061
0.031
0.108
0.008
0.011
0.006
0.010
0.000
0.000
0.000
0.164
0.091
0.005
0.052
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 45.072 40.872 42.296 42.296
=====================================================================================
(1> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
<2> Estimated / extrapolated.
118
-------
PM Profile Speciat ion Report
Profile Name Lime Handling
Profile Hunter 27601
Data Quality E
Control Device UncontrolledO)
Reference(s) 1
Data Source Unspecified methodology.
•
SCC Assignments 30501607, 30501608, 30501615
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.300 0.620 0.350
Total Participate Matter -
Total
0-2.5 um<2> 2.5-10 um{2> 0-10 um<2> Measured
Species - -
CAS Number Num Sym Xut unc Xut unc Xut unc Xut unc
7440-70-2 20 Ca 71.000 0.000 71.000 0.000 71.000 0.000 71.000 7.100
TOTALS: 71.000 71.000 71.000 71.000-
~~—S2S = SSSS3 = ~=S = S = ~ = = 5 = ===S = 5 = SS — S£=S S3 ==S —S3SS —SS —SS~SS3SSSS=S = S=a = = = S = SSSSSS = S = = = =
C1> No controt specified: thus, assumed uncontrolled.
{2} Estimated / extrapolated.
119
-------
PM Profile Speciation Report
Profile Name Lime Kiln
Profile Number 27602
Data Quality 0
Control Device Uncontrolled^!}
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30700106
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.180 0.370
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
• 7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3 ,
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
4fjw ica
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Swt
1
1
0
7
0
1
22
0
0
0
0
1
0
0
0
0
0
0
.138
.812
.231
.531
.439
.825
.580
.030
.006
.008
.240
.870
.004
.007
.007
.001
.017
.002
0.012
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.013
.011
.002
.006
.016
.012
.010
.001
.006
.017
.003
.035
.000
.006
.044
.5 urn
unc
0.114
0.222
0.047
0.753
0.218
1.322
2.258
0.007
0.001
0.003
0.045
0.405
0.001
0.003
0.001
0.001
0.003
0.002
0.002
0.007
0.003
0.002
0.008
0.004
0.004
0.005
0.008
0.008
0.009
0.016
0.048
0.064
0.001
0.010
37.942
2.5-10 urn
Xut
0.765
1.300
0.088
3.819
0.287
0.166
26.651
0.037-
0.005
0.008
0.198
1.590
0.005
0.007
0.005
0.001
0.004
0.001
0.003
0.003
0.014
0.003
0.005
0.012
0.009
0.005
0.001
0.007
0.004
0.000
0.000
0.000
0.003
0.015
35.021
unc
0.077
0.130
0.031
0.382
0.034
0.037
2.665
0.004
0.001
0.001
0.020
0.159
0.001
0.001
0.001
0.000
0.001
0.000
0.000
0.001
0.001
0.001
0.003
0.002
0.002
0.003
0.004
0.004
0.004
0.008
0.020
0.030
0.001
0.002
0-10 unK2>
Xut
0.392
1.474 '
0.136
5.080
0.338
0.729
25.268
0.035
0.005
0.008
0.212
1.685
0.005
0.007
0.006
0.001
0.009
0.001
0.006
0.006
0.013
0.003
0.005
0.013
0.010
0.006
0.001
0.007
0.008
0.001
0.012
0.000
0.004
0.025
unc
0.087
0.147
0.028
0.515
0.081
0.458
2.239
0.006
0.002
0.002
0.026
0.199
0.002
0.002
0.002
0.001
0.002
0.001
0.002
0.003
0.003
0.002
0.004
0.003
0.003
0.003
0.003
0.004
0.004
0.007
0.020
0.028
0.002
0.005
36.011
(0-10)
0.530
Total
Measured
Xwt
0.368
1.440
0.128
4.351
0.330
0.633
25.510
0.035
0.005
0.008
0.209
1.666
0.005
0.007
0.006
0.001
0.008
0.001
0.005
0.005
0.013
0.003
0.005
0.013
0.010
0.006
0.001
0.007
0.008
0.001
0.009
0.000
0.004
0.023
35.824
unc
0.087
0.144
0.035
0.485
0.086
0.390
2.551
0.005
0.001
0.001
0.021
0.167
0.001
0.001
0.001
0.000
0.002
0.001
0.001
0.002
0.001
0.001
0.004
0.003
0.002
0.003
0.005
0.005
0.006
0.010
0.026
0.040
0.001
0.004
<1> No control specified: thus, assumed uncontrolled.
<2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
120
-------
3.6 PETROLEUM INDUSTRY
The petroleum industry includes petroleum refining and natural gas
processing. Petroleum refining involves the production of several fuels,
oils, and feeds for the petrochemical industry from crude oil. Refining
processes include distillation, conversion, treatment, and storage and
handling processes. The most significant sources of emissions include vacuum
distillation, catalytic cracking, thermal cracking, boilers, and heaters.
Particulate emissions are also generated from the burning and processing of
petroleum coke.
121
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Petroleum Refinery Catalytic Cracker
26203
C
Control Device
Reference(s)
Data Source
Uncontrolled^!}
1
Size-selective dilution samplers used to collect three
samples with two dichotomous virtual impactors.
Spectrographic analysis used.
SCC Assignments: 30600201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate
Matter
: (0-2.5)
: 0.450
(0-6)
0.700
(0-10)
0.790
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
afjvt; i es
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
58
60
Al
Si
. P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
8a
La
Ce
Nd
18
17
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0-2
Xwt
.377
.345
.042
.647
.246
.179
.156
.799
.000
.000
.000
.688
.017
.001
.012
.003
.010
.006
.003
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.431
.357
.404
.5 urn
unc
2.426
2.479
0.024
0.380
0.069
0.016
0.024
0.093
0.199
0.078
0.030
0.113
0.010
0.002
0.007
0.002
0.007
0.002
0.004
OiOQ2
0-.003
0.004
0.015
0.010
0.010
0.013
0.017
0.021
0.025
0.057
0.105
0.318
0.122
0.060
2.5-10 um
Xwt
18.761
17.395
0.055
0.504
0.253
0.119
0.177
0.325
0.000
0.000
0.000
0.322
0.033
0.001
0.014
0.003
0.000
0.006
0.009
0.000
0.012
0.013
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.594
1.285
0.361
unc
3.154
2.808
0.009
0.092
0.061
0.017
0.033
0.163
0.239
0.096
0.039
0.094
0.004
0.002
0.003
0.001
0.001
0.001
0.001
0,001
0.004
0.003
0.004
0.002
0.002
0.003
0.004
0.005
0.006
0.013
0.025
0.266
0.280
0.075
0-10 urn
Xwt
18.481
17.628
0.048
1.189
0.252
0.154
0.165
0.306
0.000
0.000
0.000
0.744
0.024
0.001
0.013
0.003
0.006
0.006
0.005
0.000
0.005
O.OOS
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.512
1.316
0.382
unc
3.310
3.668
0.023
0.329
0.082
0.033
0.044
0.188
0.246
0.098
0.039
0.152
0.012
0.003
0.008
0.003
0.005
0.004
0.006
0.002
0.007
0.007
0.011
0.007
0.007
0.010
0.012
0.016
0.019
0.042
0.077
0.326
0.306
0.095
Measured
Xwt
18.481
17.628
0.048
1.189
0.252
0.154
0.165
0.806
0.000
0.000
0.000
0.744
0.024
0.001
0.013
0.003
0.006
0.006
0.005
0.000
0.005
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.512
1.316
0.382
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
123
-------
PH Profile Speciat ion Report - continued (profile 26203)
Total Partfculate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn MeasuredC2}
Species
CAS Number Num Sym Xut unc Xwt unc Xwt unc Swt unc
7439-97-6 80 Hg 0.001 0.002 0.001 0.000 0.001 0.002 0.001 0.000
7439-92-1 82 Pb 0.000 0.006 0.031 0.006 0.013 0.012 0.013 0.000
TOTALS: 42.224 41.274 41.759 41.759
(1> No control specified: thus, assumed uncontrolled.
<2> Estimated / extrapolated.
124
-------
PM Profile Special ion Report
Profile Name Petroleum Refinery Catalytic Cracker
Profile Number 26204
Data Quality C
Control Device Uncontrot led{1>
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30600201
Mass Fraction Data - Size Interval (um) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.700
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440 -.62 -2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
aptrc i ITS
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
21
43
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
69
.412
.462
.249
.324
.059
.148
.247
.998
.441
.113
.065
.956
.251
.047
.040
.000
.000
.000
.015
.000
.017
.003
.000
.000
.000
.000
.011
.098
.072
.174
.000
.196
.017
.150
.565
.5 um
unc
2.141
4.346
0.052
0.077
0.028
0.022
0.025
0.100
0.044
0.013
0.008
0.096
0.025
0.009
0.007
0.005
0.017
0.004
0.006
0.006
0.008
0.009
0.040
0.030
0.028
0.042
0.055
0.061
0.074
0.126
0.352
0.526
0.008
0.024
2.5-10 um
Xut
16.911
32.652
0.125
0.192
0.012
0.115
0.319
1.065
0.447
0.118
0.065
0.829
0.171
0.068
0.027
0.004
0.000
0.001
0.003
0.007
0.019
0.018.
0.023
0.000
0.000
0.017
0.006
0.001
0.008
0.009
0.000
0.995
0.002
0.066
unc
1.691
3.265
0.025
0.026
0.010
0.012
0.032
0.107
0.045
0.019
0.007
0.083
0.017
0.007
0.003
0.002
0.006
0.001
0.001
0.002
0.003
0.003
0.011
0.008
0.008
0.011
0.015
0.017
0.022
0.036
0.097
0.270
0.002
0.007
54.295
0-10
Xut
19.475
38.809
0.196
0.267
0.038
0.134
0.278
1.027
0.444
0.115
0.065
0.901
0.217
0.056
0.034
0.002
0.000
0.000
0.010
0.003
0.018
0.009
0.010
0.000
0.000
0.007
0.009
0.056
0.045
0.103
0.000
0.540
0.010
0.114
62.992
unK2>
unc
2.658
6.442
0.053
0.073
0.023
0.031
0.055
0.178
0.081
0.029
0.018
0.156
0.042
0.018
0.011
0.005
0.013
0.003
0.005
0.006
0.010
0.010
0.031
0.022
0.021
0.032
0.041
0.047
0.057
0.096
0.262
0.446
0.006
0.027
(0-10)
0.790
Total
MeasuredO
%wt
19.475
38.809
0.196
0.267
0.038
0.134
0.278
1.027
0.444
0.115
0.065
0.901
0.217
0.056
0.034
0.002
0.000
0.000
0.010
0.003
0.018
0.009
0.010
0.000
0.000
0.007
0.009
0.056
0.045
0.103
0.000
0.540
0.010
0.114
62.992
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
d.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> No control specified: thus, assumed uncontrolled.
(2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
{3} Estimated / extrapolated.
125
-------
PM Profile Speciation Report
Profile Name Petroleum Refinery Catalytic Cracker
Profile Number 26205
Data Quality D
Control Device Uncontrolled{1>
Reference(s) 1,2
Data Source Four samples analyzed using XRF and neutron activation.
SCC Assignments 30600201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction ' : 0.450 0.700
Total Paniculate Hatter -
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-53-1
7440-54-2
7440-27-9
7440-64-4
7440-58-6
jyci. i ca
Num Sym
11
13
14
15
16
17
19
20
21
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
50
51
56
57
58
60
62
63
64
65
70
72
Na
Al
Si
P
S
Cl
K
Ca
Sc
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Sn
Sb
Ba
La
Ce
Nd
Sm
Eu
Gd
Tb
Yb
Hf
0-2
Xwt
0
6
9
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.360
.500
.800
.160
.200
NR
.031
.030
.000
.350
.023
.006
.001
.200
.001
.022
.001
.002
NR
.001
.001
NR
.004
.012
.005
.001
.032
.310
.250
.170
.016
.001
.007
.001
.000
NR
.5 urn
unc
0.040
1.100
1.300
0.030
0.500
0.000
0.005
0.004
0.000
0.090
0.007
0.001
0.000
0.030
0.000
0.003
0.001
0.001
0.000
0.000
0.000
0.000
0.001
0.004
0.002
0.000
0.004
0.040
0.040
0.020
0.002
0.000
0.001
0.000
0.000
0.000
2.5-10 urn
Xwt
0.944
16.520
49.560
NR
4.012
0.384
0.118
0.159
0.001
0.708
0.049
0.015
0.005
0.590
0.004
0.058
0.008
0.012
0.004
0.001
0.004
0.007
0.012
0.094
NR
0.002
NR
0.873
0.684
0.454
0.045
0.001
0.017
0.002
0.001
0.000
unc
0.118
2.360
2.950
0.000
1.829
0.153
0.018
0.035
0.000
0.708
0.027
0.002
0.001
0.030
0.001
0.010
0.007
0.001
0.001
0.000
0.001
0.003
0.001
0.030
0.000
0.003
0.000
0.041
0.041
0.035
0.002
0.000
0.003
0.000
0.000
0.000
0-10 um<2>
Xwt
0.611
10.812
26.912
NE
4.119
NE
0.068
0.086
0.000
0.504
0.034
0.010
0.003
0.368
0.003
0.037
0.004
0.006
NE
0.001
0.002
NE
0.007
0.047
NE
0.001
NE
0.552
0.437
0.292
0.028
0.001
0.011
0.001
0.001
NE
unc
0.121
2.530
4.525
0.000
1.663
0.000
0.025
0.038
0.001
0.604
0.026
0.007
0.004
0.070
0.003
0.016
0.007
0.006
0.000
0.002
0.003
0.000
0.006
0.031
0.000
0.003
0.000
0.096
0.083
0.061
0.012
0.002
0.007
0.003
0.002
0.000
(0-10)
0.790
Total
Measured
Xut
0.384
6.911
11.430
0.153
4.192
0.016
0.035
0.035
0.000
0.365
0.024
0.006
0.001
0.216
0.002
0.024
0.002
O.Q03
0.000
0.001
0.001
0.000
0.004
0.015
0.005
0.001
0.031
0.333
0.268
0.182
0.017
0.001
0.007
0.001
0.000
0.000
unc
0.064
1.396
1.912
0.036
0.748
0.007
0.007
0.006
0.000
0.103
0.008
0.001
0.000
0.040
0.000
0.004
0.001
0.001
0.000
0.000
0.000
0.000
0.001
0.004
0.002
0.000
0.006
0.058
0.052
0.031
0.003
0.000
0.001
0.000
0.000
0.000
126
-------
PM Profile Speciation Report - continued (profile 26205)
Total Parttculate Matter -
Total
CAS Number
7440-25-7
7439-92-1
7440-29-1
apci. i ed
Hum Sym
73
82
90
201
202
203
204
Ta
Pb
Th
OC
EC
S04
N03
0-2
Xut
0
0
0
0
38
0
NR
.009
.001
.280
.160
.000
.051
.5 urn
unc
0.000
0.002
0,000
0.990
0.050
4.000
0.220
2.5-10 urn
Xut
0.000
0.033
0.002
NR
0.277
NR
NR
unc
0.000
0.013
0.000
0.000
0.071
0.000
0.000
0-10
Xut
NE
0.019
0.001
NE
0.210
NE
NE
unK2>
unc
0.000
0.015
0.002
0.000
0.079
0.000
0.000
Measured
Xwt
0.000
0.010
0.001
0.269
0.165
36.443
0.049
unc
0.000
0.003
0.000
0.950
0.053
6.341
0.022
TOTALS:
60.999
75.660
45.188
61.603
O> No control specified: thus, assumed uncontrolled.
{2> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
127
-------
PM Profile Speciat ion Report
Profile Name Coke Calciner
Profile Number 26206
Data Quality D
Control Device Baghouse
Reference(s) 1
Data Source Baghouse catch dust sampled by operating personnel.
SCC Assignments 30601401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.180 0.370
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
- 7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
^|JW 1 CS
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0.
0.
0.
16.
0.
0.
25.
0.
0.
0.
054
000
000
184
000
037
778
009
105
000
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
059
028
000
005
000
000
000
002
000
018
000
000
000
000
000
000
000
000
000
0.000
0.000
0.000
0.005
.5 urn
unc
0.054
0.047
0.060
0.824
0.039
0.037
1.293
0.002
0.007
0.002
0.002
0.005
0.003
0.001
0.001
0.001
0.003
0.001
0.001
0.002
0.003
0.003
0.011
0.007
0.008
0.009
0.012
0.015
0.018
0.041
0.073
0.136
0.001
0.005
42.284
2.5-10 urn
Xut
0.150
0.105
0.000
15.272
0.000
0.061
28.154
0.006
0.122
0.002
0.006
0.096
0.035
0.002
0.006
0.000
0.000
0.000
0.004
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.022
0.000
0.000
0.018
44.084
unc
0.051
0.047
0.052
0.816
0.033
0.039
1.410
0.001
0.007
0.002
0.001
0.006
0.002
0.001
0.001
0.000
0.001
0.000
0.001
0.001
0.001
0.001
0.004
0.003
0.003
0.003
0.004
0.005
0.006
0.013
0.024
0.044
0.001
0.002
0-10 urn
Xwt
0.141
0.095
0.000
15.355
0.000
0.058
27.937
0.007
0.120
0.002
0.005
0.093
0.035
0.002
0.006
0.000
0.000
0.000
0.003
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.016
43.918
unc
0.037
0.033
0.037
1.089
0.023
0.027
1.826
0.002
0.012
0.002
0.002
0.010
0.005
0.001
0.002
0.000
0.001
0.000
0.002
0.001
0.004
0.001
0.004
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.029
0.053
0.001
0.004
(0-10)
0.530
Total
MeasuredO)
Xwt
0.141
0.095
0.000
15.355
0.000
0.058
27.937
0.007
0.120
0.002
0.005
0.093
0.035
0.002
0.006
0.000
0.000
0.000
0.003
0.001
0.022
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.016
43.918
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
-0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Estimated / extrapolated.
128
-------
PM Profile Speciation Report
Profile Name Green Coke Dust
Profile Number 26207
Data Quality D
Control Device Uncontrolled{1>
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30601401
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Participate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Mum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.101
.123
.080
.723
.001
.000
.019
.000
.017
.000
.001
.022
.022
.004
.006
.000
.000
.002
.000
.000
.000
.000
.000
.016
.000
.000
.000
.014
.071
.000
.000
.000
.003
.002
NR
.5 urn
unc
0.015
0.012
0.017
0.072
0.011
0.004
0.004
0.002
0.003
0.002
0.002
0.007
0.003
0.003
0.002
0.002
0.004
0.002
0.002
0.003
0.003
0.004
0.016
0.013
0.012
0.017
0.021
0.023
0.031
0.047
0.142
0.202
0.003
0.007
0.000
2.5-10 urn
Xwt
0.119
0.122
0.059
0.687
0.000
0.000
0.036
0.000
0.011
0.000
o.odo
0.014
0.016
0.010
0.002
0.000
0.000
o.ooo
0.001
0.001
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.000
0.000
0.000
0.000
0.009
24.600
unc
0.012
0.012
0.012
0.069
0.007
0.003
0.004
0.001
0.001
0.001
0.001
0.003
0.002
0.002
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.008
0.006
0.005
0.007
0.011
0.012
0.016
0.026
0.072
0.105
0.001
0.004
4.920
0-10
Xut
0.114
0.122
0.065
0.698
0.000
0.000
0.031
0.000
0.013
0.000
0.000
0.016
0.018
0.008
0.003
0.000
0.000
0.001
0.001
0.001
0.001
0.000
0.000
0.005
0.000
0.000
0.000
0.004
0.024
0.000
0.000
0.000
0.001
0.007
NE
um<2>
unc
0.012
0.012
0.010
0.059
0.005
0.002
0.005
0.001
0.003
0.001
0.001
0.004
0.003
0.003
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.006
0.005
0.004
0.006
0.009
0.009
0.013
0.020
0.057
0.082
0.001
0.004
0.000
(0-10)
0.510
Total
Measured
Xut
0.113
0.122
0.066
0.698
0.000
0.000
0.031
0.000
0.013
0.000
0.000
0.017
0.018
0.008
0.003
0.000
0.000
0.001
0.001
0.001
0.001
0.000
0.000
0.005
0.000
0.000
0.000
0.004
0.025
0.000
0.000
0.000
0.001
0.010
16.966
unc
0.011
0.011
0.010
0.061
0.006
0.002
0.003
0.001
0.001
0.001
0.001
0.003
0.002
0.002
0.001
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.007
0.006
0.005
0.007
0.010
0.011
0.015
0.023
0.066
0.096
0.001
0.003
3.434
129
-------
PM Profile Speciation Report - continued (profile 26207)
Total Parttculate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 umC2} Measured
Species --
CAS Number Num Sym Xwt unc Xwt unc Xwt unc Xwt unc
202 EC NR 0.000 80.500 16.100 NE 0.000 55.517 11.236
TOTALS: 1.227 106.192 1.133 73.621
O> No control specified: thus, assumed uncontrolled.
{2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
130
-------
PH Profile Special ion Report
Profile Name Coke Cooler
Profile Number 26208
Data Quality D
Control Device UncontrolledO)
Reference(s) 1,17
Data Source Data taken from Reference 1. For details, consult Reference
17.
SCC Assignments: 30601201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.340
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
As
Se
3r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3
0-2.5 urn
Xut
.211
.304
.142
.485
.071
.056
.161
.010
.100
.011
.007
.329
.038
.003
.007
.001
.345
.004
.023
.000
.004
.000
.006
.006
.014
.000
.000
.007
.011
.018
.000
.051
.005
.007
.280
unc
0.021
0.056
0.026
0.149
0.101
0.007
0.016
0.002
0.012
0.002
•0.007
0.065
0.004
0.001
0.003
0.001
0.219
0.001
0.010
0.001
0.002
0.002
0.009
0.007
0.008
0.009
0.012
0.012
0.015
0.025
0.069
0.102
0.002
0.004
0.328
2.5-10 urn
Xut
0.166
0.169
0.080
0.702
0.000
0.014
0.052
0.004
0.047
0.010
0.003
0.213
0.038
0.000
0.001
0.000
0.051
0.001
0.004
0.000
0.001
0.000
0.000
0.004
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
1.300
unc
0.042
0.017
0.018
0.070
0.005
0.002
0.005
0.001
0.005
0.001
0.005
0.057
0.004
0.001
0.001
0.000
0.031
0.001
0.002
0.001
0.001
0.001
0.005
0.004
0.006
0.005
0.006
0.007
0.008
0.013
0.038
0.055
0.001
0.002
0.130
0-10
Xwt
0.179
0.209
0.098
0.932
0.021
0.026
0.084
0.006
0.063
0.010
0.004
0.247
0.038
0.001
0.003
0.000
0.138
0.002
0.009
0.000
0.001
0.000
0.002
0.005
0.007
0.000
0.000
0.002
0.003
0.005
0.000
0.015
0.002
0.003
1.882
(0-10)
0.510
Total
LnK2} Measured
unc
0.017
0.021
0.011
0.089
0.004
0.004
0.010
0.001
0.007
0.002
0.001
0.023
0.005
0.000
0.001
0.000
0.018
0.001
0.002
0.000
0.001
0.000
0.000
0.001
0.002
0.000
0.000
0.000
0.001
0.001
0.000
0.003
0.001
0.001
0.187
Xut
0.180
0.211
0.099
0.949
0.023
0.027
0.087
0.006
0.064
0.010
0.004
0.250
0.038
0.001
0.003
0.000
0.144
0.002
0.010
0.000
0.002
0.000
0.002
0.005
0.008
0.000
0.000
0.002
0.003
0.005
0.000
0.016
0.002
0.003
1.920
unc
0.030
0.026
0.020
0.095
0.032
0.003
0.009
0.001
0.006
0.002
0.006
0.060
0.004
0.001
0.001
0.001
0.092
0.001
0.004
0.001
0.001
0.001
0.006
0.005
0.007
0.006
0.008
0.008
0.010
0.017
0.048
0.070
0.001
0.003
0.192
131
-------
PM Profile Speciation Report - continued (profile 26208)
Total Particulate Matter *
Total
0-2.5 urn 2.5-10 urn 0-10 inK2> Measured
Species -
CAS Number Nun Sym Xwt unc Xwt unc Xut unc Xwt unc
202 EC 73.900 7.390 94.700 9.470 88.582 6.953 88.100 8.810
TOTALS: 80.617 97.567 92.579 92.176
S3552333Z332S—3333333333Z3Z S5333333332S3 533333335—555533—33355S335333S53533 3—33—33333
O> No control specified: thus, assumed uncontrolled.
{2} Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
132
-------
PM Profile Special ion Report
Profile Name Catalytic Cracker Composite
Profile Number 26209
Data Quality 0
Control Device Uncontrolled
Reference(s)
Data Source Profile represents a composite of Profiles 26203, 26204,
and 26205.
SCC Assignments: 30600201
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.700
Total Participate
Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-92-1
TOTALS:
3fjei* ] ea
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
33
34
35
37
38
40
50
51
56
57
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Sn
Sb
Ba
La
Pb
(0-10)
0.790
Total
0-2.5 urn
Xwt
15.430
23.702
0.150
2.057
0.153
0.119
0.144
0.716
0.155
0.040
0.022
0.615
0.100
0.016
0.018
0.005
0.002
0.006
0.000
0.007
0.004
0.026
0.058
0.011
0.312
0.053
43.921
uncO?
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ESSESSSSS
2.5-10 urn
Xwt
17.397
33.202
0.090
1.569
0.216
0.117
0.218
0.866
0.165
0.044
0.023
0.747
0.087
0.026
0.018
0.001
0.003
0.005
0.005
0.014
0.039
0.004
0.004
0.000
0.821
0.043
55.724
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
16.256
27.783
0.122
1.858
0.145
0.119
0.176
0.779
0.159
0.042
0.023
0.671
0.093
0.020
0.018
0.003
0.002
0.057
0.002
0.010
0.019
0.023
0.035
0.000
0.535
0.049
48.999
unc(1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
14
22
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Measured
Xwt
.956
.622
.132
.883
.102
.108
.159
.733
.156
.040
.022
.620
.088
.020
.017
.002
.002
.005
.001
.009
.008
.017
.035
.010
.462
.046
uncO)
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
42.255
C1> Uncertainty not evaluated.
133
-------
3.7 SOLID WASTE DISPOSAL
Solid waste sources can be industrial, urban, agricultural, or
construction. Solid waste may be disposed of in landfills or land appli-
cation units or incinerated. A large percentage of urban and industrial waste
is burned. Waste burning processes include open burning and controlled and
uncontrolled incineration where significant particulate emissions may be
generated.
135
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Municipal Incinerator (East Chicago,IN)
17107
E
Control Device
Reference(s)
Data Source
Spray chamber and 3-stage scrubbing touer.
3,13
Samples collected according to EPA incinerator method (HN03
impingers) and with Andersen impactors. Analyzed by INAA and
AA.
SCC Assignments: 50100101
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Number
7440-23-5
7439-95-4
7782-50-5
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-19-9
7440-57-5
7439-92-1
7440-29-1
TOTALS:
afjcu i ca
Nun Sym
11
12
17
24
25
26
27
28
29
30
33
34
35
47
48
49
50
51
55
56
57
62
79
82
90
Na
Mg
Cl
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Ag
Cd
In
Sn
Sb
CS
Ba
La
Sm
Au
Pb
Th
0-2.5
Xut
8
2
27
0
0
0
0
0
0
11
0
0
0
0
0
0
1
0
0
0
0
0
0
6
0
58
.200
.800
.000
.010
.027
.330
.000
.008
.170
.400
.020
.005
.088
.011
.150
.001
.290
.160
.001
.022
.000
.000
.000
.900
.000
.593
urnO)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
: (0-2.5) .
: 0.260
2.5-10
%ut
8.200
2.800
27.000
0.010
0.027
0.330
0.000
0.008
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1.290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
58.593
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.310
0-10
Xwt
8.200
2.800
27.000
0.010
0.027
0.330
0.000
0.008
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1.290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
58.593
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.380
Total
Measured
%wt
8.200
2.300
27.000
0.010
0.027
0.330
0.000
0.008
0.170
11.400
0.020
0.005
0.088
0.011
0.150
0.001
1.290
0.160
0.001
0.022
0.000
0.000
0.000
6.900
0.000
58.593
unc
1.300
0.800
3.000
0.002
0.008
0.150
0.000
0.003
0.030
2.800
0.009
0.004
0.039
0.008
0.040
0.000
0.160
0.080
0.000
0.013
0.000
0.000
0.000
1.000
0.000
O> Estimated / extrapolated.
137
-------
PH Profile Speciat ion Report
Profile Name Municipal Incinerator (Philadelphia)
Profile Number 17108
Data Quality E
Control Device UncontrolledO}
Reference(s) 1,2
Data Source Data taken from Reference 1
2.
SCC Assignments: 50100101
Mass Fraction Data - Size Interval (urn) :
Mass Fraction •:
Total Particulate Matter
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-67-7
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-58-6
Mum
11
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
33
34
35
37
38
40
42
47
48
49
50
51
55
56
57
58
62
72
Sym
Na
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Co
Ni
Cu
Zn
As
Se
Br
Rb
Sr
Zr
Mo
Ag
Cd
In
Sn
Sb
Cs
8a
La
Ce
Sm
Hf
0-2
Xut
6.200
0.230
1.700
0.630
2.900
27.000
7.600
0.230
0.030
0.001
0.009
0.016
0.220
0.000
0.029
0.120
9.300
0.007
0.004
0.230
0.022
0.009
0.029
0.038
0.007
0.110
0.001
0.670
0.140
0.001
0.083
0.000
NR
NR
NR
.5 urn
unc
3.200
0.100
0.300
0.120
0.800
4.000
2.300
0.100
0.015
0.001
0.003
0.003
0.050
0.000
0.004
0.004
0.500
0.003
0.001
0.080
0.004
0.001
0.002
0.004
0.001
0.060
0.000
0.190
0.080
0.000
0.042
0.000
0.000
0.000
0.000
. For
(0
0
details, consult Reference
-2.5) (0-6)
.260 0.310
2.5-10 urn
Xwt
5
5
8
0
3
15
4
11
1
0
0
0
1
0
0
0
4
0
0
0
0
0
0
0
0
0
1
0
0
0
0
0
.700
.200
.600
.900
.200
.000
.500
.200
.500
.010
.110
.095
.600
.003
.110
.073
.200
.006
.007
.120
.009
.036
NR
.011
.008
.079
.001
.460
.049
.000
NR
.002
.001
.000
0.000
unc
0.800
0.600
2.000
0.140
0.700
3.000
0.600
0.600
0.300
0.004
0.040
0.005
0.200
0.001
0.050
0.021
3.300
0.006
0.002
0.050
0.004
0.009
0.000
0.005
0.001
0.023
0.000
0.080
0.049
0.000
0.000
0.000
0.001
0.000
0.000
0-10 um<2>
Xwt
6.042
1.799
3.879
0.715
2.995
23.211
6.621
3.694
0.494
0.004
0.041
0.041
0.656
0.001
0.055
0.105
8.032
0.006
0.005
0.195
0.018
0.017
NE
0.029
0.007
0.100
0.001
0.919
0.111
0.000
NE
0.001
NE
NE
NE
unc
0.961
0.567
0.953
0.128
0.492
3.586
1.026
1.211
0.169
0.004
0.018
0.017
0.182
0.002
0.019
0.020
1.249
0.003
0.004
0.034
0.005
0.009
0.000
0.006
0.004
0.020
0.001
0.183
0.020
0.001
0.000
0.002
0.000
0.000
0.000
(0-10)
0.380
Total
Measured
XHt
6.148
0.748
2.419
0.658
2.931
25.750
7.277
1.373
0.183
0.002
0.019
0.024
0.364
0.001
0.037
0.115
9.217
0.007
0.004
0;219
'0.021
0.012
0.026
0.035
0.007
0.107
0.001
0.752
0.131
0.001
0.074
0.000
0.000
0.000
0.000
unc
2.973
0.130
0.431
0.136
0.310
4.910
2.267
0.166
0.038
0.001
0.005
0.004
0.062
0.000
0.008
0.016
1.331
0.003
0.001
0.077
0.005
0.002
0.004
0.006
0.002
0.056
0.000
0.193
0.074
0.000
0.039
Q.OOO
0.000
0.000
0.000
138
-------
PM Profile Speciation Report - continued (profile 17108)
Total Participate Matter •
Total
CAS Number
7439-92-1
7440-29-1
Nun Sym
82
90
201
202
203
Pb
Th
OC
EC
S04
0-2
Xwt
5
0
3
6
.800
NR
.570
.500
.800
.5 urn
unc
1.200
0.000
0.230
0.200
2.300
2.5-
Xut
1.700
0.000
0.570
2.300
12.000
10 urn
unc
0.500
0.000
0.230
0.500
3.000
0-10
Xwt
4.505
NE
0.570
3.121
8.442
unK2>
unc
0.713
0.000
0.097
0.487
1.526
Measured
Xut
5.373
0.000
0.570
3.375
7.342
unc
1.288
0.000
0.220
0.474
2.269
TOTALS: 74.736 80.360 76.432 75.323
{1} No control specified: thus, assumed uncontrolled.
C2> Calculated based'on methodology described in the Air Emissions Species Manual,
Volume II.
139
-------
PM Profile Special ion Report
Profile Name Car Shredder
Profile Number 17109
Data Quality E
Control Device Uncontrolled{1}
Reference(s) 1,32
Data Source Data taken from Reference 1. For details, consult Refrence
32.
SCC Assignments: 31401101, 31401102
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.390 0.480
Total Particulate Matter -
CAS Number
7782-41-4
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6-
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
TOTALS:
?|Jd» i ca
Nun Sym
9
11
12
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
203
204
F
Ma
Mg
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
8r
Pb
OC
EC
S04
N03
0-2
Xwt
"o.
0.
0.
0.
0.
0.
' 0.
0.
0.
0.
0.
0.
0.
5.
0.
0.
2.
0.
0.
7.
0.
050
180
100
470
870
470
680
270
480
025
001
040
088
760
031
100
100
490
490
700
600
0.290
0.
21.
150
435
.5 urn
unc
0.050
0.240
0.100
0.064
0.190
0.085
0.460
0.180
0.057
0.025
0.001
0.004
0.045
0.980
0.007
0.014
0.210
0.350
0.049
3.300
0.060
0.030
0.150
2.5-10 urn
Xwt
0.000
NR
NR
1.900
NR
NR
8.700
NR
5.500
NR
NR
0.000
0.078
3.700
0.000
0.990
0.870
3.400
0.000
31.000
4.000
0.000
0.000
65.138
unc
5.000
0.000
0.000
0.350
0.000
0.000
0.790
0.000
0.710
0.000
0.000
2.000
0.100
1.100
0.001
0.300
0.120
1.100
0.005
2.800
4.200
6.000
15.000
• 0-10 urn
Xwt
0.035
NE
NE
0.886
NE
NE
3.0T3
NE
1.940
NE
NE
0.028
0.085
5.161
0.022
0.359
1.742
2.791
0.347
14.478
1.589
0.206
0.106
32.788
unc
4.211
0.000
0.000
0.338
0.000
0.000
0.979
0.000
0.727
0.000
0.000
1.684
0.092
1.324
0.006
0.268
0.288
1.140
0.060
4.068
3.550
5.053
12.632
(0-10)
0.550
Total
Measured
Xwt
0.197
NR
NR
0.556
NR
NR
1.161
NR
0.781
NR
NR
0.098
0.087
5.636
0.029
0.153
2.026
0.965
0.461
9.098
0.804
0.453
0.591
23.096
unc
0.157
0.000
0.000
0.064
0.000
0.000
0.436
0.000
0.078
0.000
0.000
0.060
0.043
0.924
0.007
0.022
0.203
0.336
0.046
3.108
0.258
0.182
0.472
C1> No control specified: thus, assumed uncontrolled.
140
-------
3.8 METAL FABRICATION
Metal fabrication includes establishments engaged in fabricating ferrous
and nonferrous metal products, such as metal cans, tinware, handtools,
cutlery, general hardware, nonelectric heating apparatus, fabricated
structural metal products, metal forgings, metal stampings, and a variety of
metal and wire products. Emission sources include, but are not limited to,
casting, rolling, forging, welding, and sandblasting of metals.
141
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Metal Fabrication - Galvanizing (ZnO)
25701
E
Control Device
Reference(s)
Data Source
Uncontrolled^
1,15
Data taken from Reference 1. For details, consult Reference
15.
SCC Assignments: 034
Mass Fraction Data - Size Interval (urn) : <0-2.5) (0-6) <0-10)
Mass Fraction : 0.820 0.890 0.920
Total Particulate Matter -
Total
0-2.5 um<2> 2.5-10 umC2> 0-10 unK2> Measured
Species -- -
CAS Number Hum Sym Xut unc Xut unc Xut unc Xut unc
7440-66-6 30 Zn 30.000 0.000 80.000 0.000 80.000 0.000 80.000 8.000
TOTALS: 80.000 80.000 80.000 80.000
{1> No control specified: thus assumed uncontrolled.
(2> Estimated / extrapolated.
143
-------
PM Profile Speciat ion Report
Profile Name Metal Fabrication
Profile Number 25702
Data Qua I ity E
- Sandblasting
Control Device Uncontrolled{1>
Reference(s) 1,15
Data Source Data taken from Reference 1
15.
SCC Assignments: 30900202
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Hatter
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-38-2
7726-95-6
7439-92-1
TOTALS:
SSSSSSSSSSS3
Hum
11
13
14
16
17
19
20
22
23
24
25
26
23
29
30
33
35
82
200
Sym
Na
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
As
8r
Pb
TC
0-2.5
Xwt
0.800
0.750
40.000
0.880
2.300
0.700
0.820
0.400
0.003
0.580
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0.580
0.500
56.748
SS333S3SSX
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2
. For details, consult Reference
(0-2.5) (0-6)
0.300 0.620
.5-10
Xut
0
0
40
0
2
0
0
0
0
0
0
6
0
0
0
0
0
0
0
56
.800
.750
.000
.380
.300
.700
.320
.400
.003
.580
.140
.300
.320
.690
.470
.010
.005
.580
.500
.748
unK2>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 umC2>
Xwt
0.800
0.750
40.000
0.880
2.800
0.700
0.820
0.400
0.003
0.580"
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0.580
0.500
56.748
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.850
Total
Measured
Xut
0.800
0.750
40.000
0.380
2.800
0.700
0.320
0.400
0.003
0.580
0.140
6.300
0.320
0.690
0.470
0.010
0.005
0.580
0.500
56.748
unc
0.080
0.075
4.000
0.088
0.230
0.070
0.032
0.040
0.000
0.058
0.014
0.630
0.032
0.069
0.047
0.001
0.001
0.058
0.050
O> No control specified: thus, assumed uncontrolled.'
{2} Estimated / extrapolated.
144
-------
PM Profile Spcciation Report
Fabrication - Welding
Profile Name
Profile Number
Data Quality
Metal
25703
E
Control Device
Reference(s)
Data Source
UncontrolledO>
1,32
Data taken from Reference 1. For details, consult Reference
32.
SCC Assignments: 034
Mass Fraction Data - Size
Mass
Total Paniculate Matter -
Species
CAS Number
7440-09-7
7440-70-2
7439-96-5
7439-89-6
TOTALS:
Hum
19
20
25
26
{1} No control
(2> Estimated /
Sym
K
Ca
Mn
Fe
specified:
Interval (urn)
Fraction
0-2.5 urn
Xut
20.900
19.400
6.280
24.600
71.180
thus.
unc
2.090
1.940
0.628
2.460
assumed
: (0-2.5)
: 0.820
2.5-10
Xut
20.900
19.400
6.280
24.600
71.180
um€2>
unc
0.000
0.000
0.000
0.000
(0-6)
0.890
0-10
Xut
20.900
19.400
6.280
24.600
71.180
(0-10)
0.920
Total
unK2> Measured{2>
unc
4.234
3.931
1.285
4.980
Xut
20.900
19.400
6.280
24.600
71.180
0
0
0
0
unc
.000
.000
.000
.000
uncontrolled.
extrapolated.
145
-------
146
-------
3.9 UNPAVED ROADS
Dust particles can become airborne on unpaved roads by vehicular traffic
and wind action dan increase the activity. Particulate emissions on unpaved
roads can be controlled to some degree by chemical stabilizers.
147
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Unpaved Road Dust - Riverside, CA
41205
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 055
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-15
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
32
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
9.890
20.360
0.212
0.406
0.157
1.981
2.831
0.529
0.038
0.024
0.159
5.671
0.009
0.011
0.028
0.003
0.008
0.000
0.002
0.007
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.013
.5 urn
unc
1.484
3.054
0.043
0.020
0.008
0.099
0.142
0.027
0.006
0.002
0.008
0.286
0.001
0.002
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.002
0.011
0.007
0.007
0.009
0.012
0.014
0.017
0.038
0.071
0.128
0.001
0.004
: (0-2.5)
: 0.300
2.5-10 urn
Xwt
9.231
19.190
0.175
0.332
0.179
2.227
2.900
0.556
0.025
0.029
0.150
5.955
0.007
0.007
0.026
0.000
0.000
0.000
0.003
0.016
0.028
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.030
unc
1.385
2.878
0.035
0.017
0.009
0.111
0.145
0.029
0.006
0.002
0.008
0.299
0.001
0.001
0.001
0.003
0.002
0.000
0.000
0.001
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.022
0.000
0.002
(0-6)
0.590
0-10
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
1
.2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
urn
unc
.283
.651
.035
.037
.020
.176
.238
.051
.008
.006
;019
.476
.003
.003
.006
.002
.002
.000
.002
.005
.006
.003
.005
.003
.003
.004
.005
.006
.007
.016
.031
.055
.001
.007
(0-10)
0.730
Total
HeasuredC1>
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
42.352
41.122
41.189
41.189
{1} Estimated / extrapolated.
149
-------
152
-------
PM Profile Speciation Report - continued (profile 41111)
Total Partfculate Matter -
Total
0-2.5 UB 2.5-10 urn 0-10 um Measured<1>
Species -- —
CAS Member Nun Sym Xwt unc Xwt unc Xut unc Xwt unc
201 OC 17.574 1.597 14.502 71.384 14.854 53.840 14.854 0.000
202 EC 0.451 0.130 0.401 0.074 0.407 0.105 0.407 0.000
TOTALS: 58.815 59.269 59.222 59.222
£333338233323223833333353333!523333333S333333353S3352333Z2339E9B333SS3333533S3352S255:S33
O> Estimated / extrapolated.
154
-------
PM Profile Special ion Report
Profile Name
Profile Umber
Data Quality
Paved Road Oust
41112
C
Artesia Freeway (CA)
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440- T7- 7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
a^jvc i es*
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
6
17
0
0
0
1
4
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.371
.995
.039
.874
.190
.242
.081
.544
.029
.020
.094
.530
.018
.044
.253
.000
.002
.000
.008
.006
.072
.000
.005
.000
.000
.000
.000
.000
.000
0.000
0
0
.052
.000
0.002
0
36
.288
.759
.5 urn
unc
0.956
2.699
0.008
0.044
0.010
0.062
.0.204
0.028
0.006
0.002
0.005
0.229
0.002
0.003
0.013
0.001
0.016
0.001
0.001
0.001
0.004
0.002
0.009
0.005
0.005
0.007
0.008
0.010
0.013
0.027
0.052
0.093
0.001
0.015
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
6.460
17.486
0.035
0.718
0.200
1.691
4.512
0.593
0.002
0.020
0.122
5.534
0.019
0.034
0.195
0.001
0.000
0.000
0.011
0.012
0.112
0.001
0.000
0.000
0.000
0.000
0.013
0.000
0.000
0.000
0.145
0.000
0.000
0.278
38.194
unc
-0.969
2.623
0.007
0.036
0.010
0.085
0.226
0.033
0.007
0.002
0.006
0.278
0.001
0.002
0.010
0.001
0.015
0.000
0.001
0.001
0.006
0.001
0.007
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.020
0.033
0.000
0.014
(0-6)
0.370
0-10 urn
Xwt
6.454
17.524
0.035
0.730
0.199
1.658
4.480
0.589
0.004
0.020
0.120
5.460
0.019
0.034
0.199
0.001
0.000
0.000
0.011
0.012
0.109
0.001
0.000
0.000
0.000
0.000
.0.012
0.000
0.000
0.000
0.139
0.000
0.001
0.279
38.090
2222222S
unc
1.111
3.060
0.011
0.095
0.027
0.164
0.471
0.069
0.007
0.006
0.018
0.548
0.006
0.008
0.030
0.002
0.015
0.001
0.004
0.004
0.016
0.002
0.007
0.003
0.003
0.004
0.007
0.006
0.008
0.017
0.037
0.058
0.001
0.037
sasssas
(0-10)
0.440
Total
Measured{1}
Xwt
6.454
17.524
0.035
0.730
0.199
1.658
4.480
0.589
0.004
0.020
0.120
5.460
0.019
0.034
0.199
0.001
0.000
0.000
0.011
0.012
0.109
0.001
0.000
0.000
0.000
0.000
0.012
0.000
0.000
0.000
0.139
0.000
0.001
0.279
38.090
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======
<1> Estimated / extrapolated.
155
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - Long Beach Blvd.
41113
C
(CA)
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
^fJ^w 1 V9
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd "
In
Sn
Sb
3a
La
Hg
Pb
0-2
Xut
5.611
17.174
0.250
0.576
0.268
1.260
3.836
0.347
0.028
0.024
0.091
3.967
0.014
0.025
0.306
0.000
0.004
0.000
0.005
0.002
0.028
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.302
.5 urn
unc
0.842
2.576
0.050
0.029
0.013
0.063
0.192
0.018
0.004
0.002
0.005
0.200
0.002
0.002
0.016
0.002
0.017
0.001
0.002
0.002
0.003
0.003
0.012
0.008
0.008
0.010
0.013
0.016
0.020
0.043
0.081
0.147
0.001
0.017
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
5.681
16.088
0.210
0.531
0.258
1.633
3.747
0.415
0.020
0.030
0.104
4.779
0.014
0.025
0.273
0.000
0.000
0.000
0.009
0.011
0.053
0.000
0.014
0.000
0.000
.0.000
0.000
0.000
0.007
0.000
0.072
0.000
0.000
0.284
unc
0.852
"2.413
0.042
0.027
0.013
0.082
0.187
0.023
0.006
0.002
0.005
0.240
0.001
0.001
0.014
0.002
0.016
0.000
0.001
0.001
0.003
0.001
0.004
0.002
0.002
0.002
0.003
0.004
0.005
0.011
0.020
0.035
0.000
0.014
(0-6)
0.370
0-10 urn
Xwt
5.676
16.165
0.213
0.535
0.258
1.606
3.753
0.410
0.021
0.029
0.103
4.721
0.014
0.025
0.275
0.000
0.000
0.000
0.009
0.010
0.051
0.000
0.013
0.000
0.000
0.000
0.000
0.000
0.006
0.000
0.067
0.000
0.000
0.285
unc
0.978
2.366
0.052
0.067
0.035
0.162
0.421
0.048
0.008
0.007
0.016
0.477
0.005
0.007
0.038
0.001
0.015
0.001
0.004
0.004
0.010
0.002
0.009
0.005
0.005
0.006
0.008
0.010
0.012
0.026
0.050
0.088
0.001
0.038
(0-10)
0.440
Total
Measured(1>
Xut '
5
16
0
0
0
1
3
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.676
.165
.213
.535
.258'
.606
.753
.410
.021
.029
.103
.721
.014
.025
.275
.000
.000
.000
.009
.010
.051
.000
.013
.000
.000
.000
.000
.000
.006
.000
.067
.000
.000
.285
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.opo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 34.118
SS33S3322S333S333£SS32S3S35:3335S33=
<1> Estimated / extrapolated.
34.258
34.245
34.245
156
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Oust
41114
C
Long Beach, CA
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval
-------
PM Profile Speciat ion Report - continued (profile 41114)
Total Particulate Hatter -
Total
0-2.5 un 2.5-10 in 0-10 un Measured^}
Species -- -- —
CAS Number Nun Sym Xut unc Xwt unc Xwt unc Xwt unc
201 OC 19.626 3.184 18.959 1.465 19.002 2.858 19.002 0.000
202 EC 2.213 0.407 1.188 0.100 1.254 0.311 1.254 0.000
TOTALS: 52.184 52.212 52.211 52.211
=33S3S=333S333=33333=3333S33333
{1} Estimated / extrapolated.
158
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Paved Road Oust - La Cienega Blvd. (CA)
41115
C
Control Device Not Applicable
Reference(s) 1
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
a^jei. i e&
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
5
14
0
0
0
0
1
0
0
0
0
3
0
0
0
0
0
Q
0
0-2
Xwt
.837
.851
.023
.220
.067
.915
.622
.308
.017
.009
.063
.268
.007
.010
.046
.000
.003
.000
.002
0.003
0
0
0
0
0
0
0
0
0
0
0
0
0
.014
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.026
27
.311
.5 urn
unc
0.876
2.228
0.005
0.011
0.003
0.046
0.081
0.016
0.004
0.001
0.004
0.165
0.001
0.001
0.003
0.001
0.002
0.001
0.001
0.001
0.002
0.002
0.007
0.005
0.004
0.006
0.008
0.010
0.011
0.025
0.048
0.087
0.001
0.003
: (0-2.5)
: 0.250
2.5-10 urn
Xut
8.096
20.769
0.028
0.184
0.059
1.698
2.336
0.517
0.011
0.018
0.111
5.302
0.011
0.013
0.062
0.000
0.000
0.000
0.004
0.014
0.040
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
0.005
0.099
0.000
0.000
0.049
39.436
unc
1.214
3.115
0.006
0.009
0.003
0.085
0.117
0.028
0.006
0.002
0.006
0.267
0.001
0.001
0.003
0.000
0.003
0.000
0.000
0.001
0.002
0.001
0.004
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.018
0.029
0.000
0.003
(0-6)
0.370
0-10 urn
Xwt
7.957
20.406
0.028
0.186
0.059
1.650
2.292
0.504
0.011
0.018
0.108
5.177
0.011
0.013
0.061
0.000
0.000
0.000
&004
0.013
0.038
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
0.005
0.093
0.000
0.000
0.048
38.692
unc
1.236
3.156
0.008
0.028
0.012
0.148
0.219
0.052
0.007
0.005
0.016
0.465
0.004
0.005
0.011
0.000
0.003
0.000
0.003
0.005
0.008
0.001
0.006
0.003
0.003
0.004
0.005
0.006
0.008
0.016
0.033
0.054
0.001
0.009
(0-10)
0.440
Total
MeasuredO}
Xwt
7.957
20.406
0.028
0.186
0.059
1.650
2.292
0.504
0.011
0.018
0.108
5.177
0.011
0.013
0.061
0.000
0.000
0.000
0.004
0.013
0.038
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.004
0.005
0.093
0.000
0.000
0.048
38.692
==3====
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
======
O> Estimated / extrapolated.
159
-------
PM Profile Special ion Report
Profile Name
Profile Nunber
Data Quality
Paved Road Dust - Hawthorne, CA
41116
C
Control Device Not Applicable
Reference(s) 1
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-U-O
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
jyw i ca
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
6.
17.
0.
0.
0.
1.
2.
0.
146
411
040
648
130
080
864
326
0.024
0.
0.
3.
0.
0.
018
076
530
016
031
0.164
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
32.
000
004
000
008
004
044
000
000
000
000
000
000
000
000
000
000
000
000
180
744
.5 urn
unc
0.922
2.612
0.008
0.032
0.007
0.054
0.143
0.017
0.004
0.002
0.004
0.178
0.002
0.002
0.009
0.001
0.011
0.001
0.001
0.001
0.003
0.002
0.009
0.006
0.005
0.007
0.009
0.011
0.014
0.030
0.056
0.102
0.001
0.010
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
5.810
15.633
0.031
0.398
0.134
1.414
2.618
0.408
0.009
0.017
0.101
4.245
0.013
0.020
0.162
0.000
o.qoo
o.ooo
0,008
0.012
0.076
0.001
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.085
0.004
0.000
0.132
31.339
unc
0.872
2.345
0.006
0.020
0.007
0.071
0.131
0.023
0.005
0.002
0.005
0.214
0.001
0.001
0.008
0.001
0.007
0.000
0.001
0.001
0.004
0.001
0.005
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.019
0.032
0.000
0.007
(0-6)
0.370
0-10 urn
Xwt
5.830
15.739
0.032
0.413
0.134
1.394
2.633
0.403
0.010
0.017
0.100
4.202
0.013
0.021
0.162
0.000
0.000
0.000
0.008
0.011
0.074
0.001
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
0.003
0.000
0.135
31.422
unc
1.033
2.845
0.010
0.066
0.020
0.141
0.308
0.047
0.006
0.005
0.015
0.425
0.005
0.006
0.023
0.001
0.008
0.000
0.004
0.004
0.012
0.002
0.007
0.004
0.003
0.004
0.006
0.007
0.008
0.018
0.037
0.063
0.001
0.023
(0-10)
0.440
Total
Measuredd)
Xut
5.330
15.739
0.032
0.413
0.134
1.394
2.633
0.403
0.010
0.017
0.100
4.202
0.013
0.021
0.162
0.000
0.000
0.000
0.008
0.011
0.074
0.001
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.080
0.003
0.000
0.135
31.422
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
160
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Oust - Victory Blvd. (CA)
41117
C
Control Device Not Applicable
Reference(s) 1
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate
Matter
: (0-2.5)
: 0.250
<0-6)
0.370
(0-10)
0.440
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
*}*si- i e»
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
At
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
4
12
0
0
0
0
3
0
0
0
0
3
0
0
0
0-2
Xut
.062
.435
.325
.864
.368
.836
.941
.331
.022
.023
.067
.538
.011
.041
.267
0.001
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
27
.009
.000
.008
.000
.019
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.281
.449
.5 urn
unc
0.609
1.865
0.065
0.043
0.018
0.042
0.197
0.017
0.004
0.002
0.004
0.179
0.001
0.003
0.014
0.002
0.016
0.001
0.001
0.002
0.002
0.003
0.011
0.006
0.006
0.009
0.011
0.014
0.017
0.037
0.070
0.125
0.001
0.015
2.5-10 urn
Xut
4.913
13.602
0.283
0.700
0.389
1.332
4.986
0.441
0.020
0.031
0.092
4.618
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.054
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.081
0.000
0.000
0.334
32.238
unc
0.737
2.040
0.057"
0.035
0.019
0.067
0.249
0.023
0.005
0.002
0.005
0.232
0.001
0.002
0.014
0.001
0.018
0.000
0.001
0.001
0.003
0.001
0.004
0.002
0.001
0.002
0.002
0.003
0.004
0.008
0.015
0.026
0.000
0.017
0-10 urn
Xut
4. 880
13.557
0.284
0.707
0.388
1.312
4.946
0.437
0.020
0.031
0.091
4.576
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.052
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.078
0.000
0.000
0.332
32.053
unc
0.787
2.259
0.067
0.093
0.047
0.123
0.485
0.049
0.007
0.007
0.014
0.444
0.005
0.009
0.036
0.001
0.017
0.001
0.004
0.004
0.010
0.002
0.008
0.004
0.004
0.005
0.007
0.008
0.010
0.022
0.043
0.074
0.001
0.040
MeasuredCI}
Xwt
4.380
13.557
0.284
0.707
0.388
1.312
4.946
0.437
0.020
0.031
0.091
4.576
0.013
0.040
0.275
0.000
0.000
0.000
0.012
0.010
0.052
0.000
0.009
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.078
0.000
0.000
0.332
32.053
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Estimated / extrapolated.
161
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Paved Road Oust - Burbank, CA
41118
C
Control Device Not Applicable
Reference(s) 1
Data Source Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
•afjd. 1 1S9
Mum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
4
12
0
0
0
0
5
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.511
.666
.223
.872
.348
.918
.542
.334
.021
.020
.076
.319
.009
.025
.217
.001
.005
.000
.004
.000
.028
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.181
.5 urn
unc
0.677
1.900
0.045
0.044
0.017
0.046
0.277
0.018
0.004
0.002
0.005
0.168
0.002
0.002
0.012
0.001
0.011
0.001
0.002
0.002
0.003
0.003
0.012
0.007
0.008
0.010
0.013
0.016
0.019
0.043
0.080
0.145
0.001
0.011
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
5.034
.14.087
0.213
0.703
0.355
1.352
5.732
0.432
0.020
0.027
0.095
4.280
0.013
0.026
0.215
0.000
0.000
0.000
0.009
0.010
0.051
0.000
0.000
0.000
0.000
0.000
0.011
0.000
0.013
0.000
0.067
0.000
0.000
0.225
unc
0.755
2.113
0.043
0.035
0.018
0.068
0.287
0.023
0.006
0.002
0.005
0.215
0.001
0.002
0.011
0.002
0.013
0.000
0.001
0.001
0.003
0.001
0.004
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.019
0.032
0.000
0.012
(0-6)
0.370
0-10 urn
Xwt
5.002
14.000
0.214
0.713
0.355
1.326
5.721
0.426
0.020
0.026
0.094
4.221
0.013
0.026
0.216
0.000
0.000
0.000
0.008
0.010
0.049
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.012
0.000
0.062
0.000
0.000
0.223
unc
0.832
2.324
0.049
0.094
0.044
0.129
0.620
0.048
0.007
0.007
0.015
0.414
0.005
0.007
0.029
0.002
0.011
0.001
0.004
0.004
0.010
0.002
0.008
0.004
0.004
0.006
0.009
0.010
0.012
0.025
0.048
0.086
0.001
0.028
(0-10)
0.440
Total
MeasuredO}
%wt
5.002
14.000
0.214
0.713
0.355
1.326
5.721
0.426
0.020
0.026
0.094
4.221
0.013
0.026
0.216
0.000
0.000
0.000
0.008
0.010
0.049
0.000
0.000
0.000
0.000
0.000
0.010
0.000
0.012
0.000
0.062
0.000
0.000
0.223
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
162
-------
PM Profile Speciation Report - continued (profile 41118)
Total Participate Hatter -
Total
0-2.5 urn 2.S-10 urn 0-10 urn Measuredt1>
Species
CAS Number Num Sym Xwt unc Xwt unc Xut unc Xwt unc
201 OC 10.647 1.669 15.978 2.162 15.651 2.266 15.651 0.000
202 ec 0.999 0.207 1.778 0.225 1.730 0.248 1.730 0.000
TOTALS: 40.966 50.726 50.128 50.128
O> Estimated / extrapolated.
163
-------
PM Profile Spec tat ion Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - North Main St., Los Angeles, CA
41119
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
2
9
0
0
0
0
3
0
0
0
0
7
0
0
.893
.439
.524
.352
.352
.663
.609
.258
.025
.031
.078
.120
.011
.050
0.398
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.001
.006
.000
.002
.000
.030
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.137
.5 urn
unc
0.434
1.416
0.105
0.043
0.018
0.033
0.180
0.014
0.004
0.002
0.005
0.359
0.002
0.003
0.021
0.001
o.ooa
0.001
0.001
0.002
0.003
0.002
0.012
0.007
0.007
0.009
0.012
0.014
0.017
0.039
0.073
0.130
0.001
0.009
: <0-2.5)
: 0.250
2.5-10 urn
Xwt
3.734
10.987
0.496
0.782
0.428
1.107
4.405
0.354
0.019
0.039
0.089
6.131
0.013
0.059
0.437
0.000
0.000
0.000
0.006
0.009
0.084
0.000
0.013
0.004
0.000
0.000
0.000
0.000
0.012
0.000
0.091
0.000
0.000
0.175
unc
0.560
1.648
0.099
0.039
0.021
0.055
0.220
0.020
0.005
0.002
0.005
0.308
0.001
0.003
0.022
0.001
0.010
0.000
0.001
0.001
0.004
0.001
0.005
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.018
0.030
0.000
0.009
(0-6)
0.370
0-10 urn
Xwt
3.689
10.905
0.498
0.785
0.424
1.084
4.363
0.349
0.019
0.039
0.088
6.184
0.012
0.059
0.435
0.000
0.000
0.000
0.006
0.008
0.081
0.000
0.012
0.003
0.000
0.000
0.000
0.000
0.012
0.000
0.086
0.000
0.000
0.173
unc
0.586
1.781
0.111
0.096
0.049
0.102
0.437
0.040
0.007
0.008
0.014
0.744
0.004
0.011
0.052
0.001
0.009
0.001
0.003
0.004
0.013
0.002
0.009
0.005
0.004
0.005
0.007
0.009
0.011
0.023
0.045
0.077
0.001
0.023
(0-10)
0.440
Total
MeasuredO>
Xwt
3.689
10.905
0.498
0.785
0.424
1.084
4.363
0.349
0.019
0.039
0.088
6.184
0.012
0.059
0.435
0.000
0.000
0.000
0.006
0.008
0.081
0.000
0.012
0.003
0.000
0.000
0.000
0.000
0.012
0.000
0.086
0.000
0.000
0.173
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
164
-------
PM Profile Speciatfon Report - continued (profile 41119)
Total Particulate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn MeasuredO}
Species --
CAS Number Hum Sym Xwt unc Xwt unc Xwt unc Xwt unc
201 OC 19.267 5.454 21.522 1.630 21.403 3.877 21.403 0.000
202 EC 0.858 0.429 1.718 0.137 1.672 0.295 1.672 0.000
TOTALS: 46.604 52.714 52.389 52.389
saasassaaaaaasasaaaaaassaaaaaaaaaaaaaaaaasasaaaas3saasaaaaaaaasaasaaasa=s3saaaa=a=aa=
{1} Estimated /. extrapolated.
165
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - Los Angeles, CA
41120
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Hass Fraction
Data - Size Interval (urn)
Hass Fraction
Total Participate Hatter -
Spec i es
CAS Number Nun Sym
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
4.456
10.398
0.223
0.943
0.270
0.641
2.877
0.352
0.031
0.066
0.077
3.301
0.048
0.056
0.458
0.000
0.014
0.000
0.002
0.000
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.282
24.507
.5 urn
unc
0.669
1.560
0.045
0.047
0.014
0.032
0.144
0.019
0.005
0.004
0.005
0.167
0.003
0.004
0.024
0.002
0.016
0.001
6. "002
0:002
0.003
0.003
0.014
0.008
0.008
0.010
0.014
0.017
0.021
0.046
0.085
0.157
0.002
0.016
: (0-2.5)
: 0.250
2.5-10 urn
Xut
4.859
11.389
0.224
0.338
0.300
1.059
3.715
0.560
0.033
0.103
0.080
4.621
0.070
0.061
0.426
0.000
0.000
0.000
0.006
0.009
0.066
0.000
0.005
0.016
0.000
0.000
0.000
0.000
0.007
0.000
0.050
0.000
0.000
0.307
29.304
unc
0.729
1.783
0.045
0.042
0.015
0.053
0.186
0.029
0.007
0.005
0.004
0.232
0.004
0.003
0.021
0.002
0.017
0.000
0.001
0.001
0.003
0.001
0.005
0.003
0.002
0.002
0.003
0.004
0.004
0.009
0.019
0.032
0.000
0.016
(0-6)
0.370
0-10 urn
Xwt
4.
11.
0.
0.
0.
1.
3.
0.
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
843
827
224
343
299
041
680
552
033
101
080
566
069
061
427
000
001
000
006
008
064
000
005
015
000
000
000
000
007
000
048
000
000
0.306
unc
0.811
1.940
0.051
0.104
0.037
0.098
0.360
0.057
0.009
0.015
0.014
0.431
0.012
0.011
0.055
0.002
0.016
0.001
0.003
0.004
0.011
0.002
0.009
0.007
0.005
0.006
0.008
0.010
0.013
0.027
0.051
0.092
0.001
0.038
29.106
(0-10)
0.440
Total
Measured
Xwt
4.343
11.827
0.224
0.343
0.299
1.041
3.680
0.552
0.033
0.101
0.080
4.566
0.069
0.061
0.427
0.000
0.001
0.000
0.006
o.ooa
0.064
0.000
0.005
0.015
0.000
0.000
0.000
0.000
0.007
0.000
0.043
0.000
0.000
0.306
29.106
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=====================================================================================
O> Estimated / extrapolated.
166
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - South Harbor Blvd., Anaheim, CA
41121
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (un)
Mass Fraction
Total Paniculate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
a^eu i c»
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
3.
10.
0.
1.
0.
0.
3.
0.
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
821
645
191
209
818
847
108
188
017
023
050
268
008
041
220
000
002
000
007
000
0.081
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
000
000
000
126
.5 urn
unc
0.573
1.597
0.038
0.060
0.041
0.042
0.155
0.011
0.003
0.002
0.004
0.115
0.002
0.003
0.012
0.001
0.008
0.001
0.002
0.002
0.005
0.003
0.015
0.009
0.009
0.012
0.015
0.019
0.023
0.050
0.094
0.171
0.002
0.009
: (0-2.5)
: 0.250
2.5-10 un
Swt
3.720
11.378
0.185
1.237
0.797
1.320
3.864
0.288
0..015.
0.036
0.073
3.416
0.012
0.017
0.178
0.000
0.000
0.000
0.011
0.011
0.132
0.000
0.015
0.000
0.004
0.005
0.005
0.000
0.008
0.000
0.108
0.000
0.000
0.169
unc
0.558
1.707
0.037
0.062
0.040
0.066
0.193
0.017
0.005
0.002
0.004
0.172
0.001
0.001
0.009
0.001
0.009
0.000
0.001
0.001
0.007
0.001
0.008
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.020
0.033
0.000
0.009
(0-6)
0.370
0-10 urn
Xut
3.726
11.337
0.186
1.235
0.798
1.293
3.822
0.283
0.015
0.035
0.072
3.353
0.011
0.018
0.181
0.000
0.000
0.000
0.011
0.011
0.129
0.000
0.014
0.000
0.003
0.004
0.005
0.000
0.008
0.000
0.102
0.000
0.000
0.167
unc
0.654
1.909
0.043
0.140
0.095
0.123
0.381
0.033
0.006
0.008
0.012
0.311
0.004
0.006
0.028
0.001
0.008
0.001
0.004
0.004
0.018
0.002
0.011
0.005
0.006
0.007
0.009
0.011
0.014
0.030
0.057
0.100
0.001
0.022
(0-10)
0.440
Total
Measuredd}
Xwt
3.726
11.337
0.186
1.235
0.798
1.293
3.822
0.283
0.015
0.035
0.072
3.353
0.011
0.018
0.181
0.000
0.000
0.000
0.011
0.011
0.129
0.000
0.014
0.000
0.003
0.004
0.005
0.000
0.008
0.000
0.102
0.000
0.000
0.167
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 23.670
O) Estimated / extrapolated.
27.004
26.319
26.819
167
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - Anaheim, CA
41122
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-3S-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2
Xut
4
14
0
0
0
1
4
0
.994
.029
.290
.941
.412
.073
.890
.338
0.024
0
0
3
0
0
0
.022
.098
.550
.015
.023
.202
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.005
.000
.005
.001
.035
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.167
.5 urn
unc
0.749
2.104
0.058
0.047
0.021
0.054
0.244
0.018
0.004
0.002
0.005
0.179
0.001
0.002
0.010
0.001
0.010
0.001
0.001
0.001
0.002
0.002
0.007
0.004
0.004
0.005
0.007
0.008
0.010
0.023
0.042
0.076
0.001
0.009
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
5.259
14.421
0.237
0.899
0.414
1.461
5.325
0.424
0.020
0.026
0.107
4.306
0.015
0.021
0.196
0.000
0.000
0.000
0.007
0.011
0.058
0.000
0.010
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.017
0.000
0.001
0.174
unc
0.789
2.163
0.047
0.045
0.021
0.073
0.266
0.022
0.005
0.002
0.005
0.217
0.001
0.001
0.010
0.002
0.010
0.000
0.001
0.001
0.003
0.001
0.004
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.014
0.023
0.000
0.009
(0-6)
0.370
0-10 urn
Xwt
5.243
14.397
0.240
0.902
0.414
1.438
5.299
0.419
0.021
0.026
0.107
4.261
0.015
0.021
0.196
0.300
0.000
0.000
0.007
0.011
0.056
0.000
0.009
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.016
0.000
0.001
0.174
unc
0.390
2.460
0.059
0.107
0.051
0.143
0.560
0.048
0.007
0.007
0.017
0.429
0.005
0.006
0.027
0.002
0.009
0.000
0.003
0.004
0.010
0.001
0.006
0.003
0.003
0.003
0.005
0.005
0.007
0.014
0.027
0.047
0.001
0.024
(0-10)
0.440
Total
MeasuredO}
Xwt
5.243
14.397
0.240
0.902
0.414
1.438
5.299
0.419
0.021
0.026
0.107
4.261
0.015
0.021
0.196
0.000
0.000
0.000
0.007
0.011
0.056
0.000
0.009
0.003
0.000
0.000
0.004
0.000
0.006
0.000
0.016
0.000
0.001
0.174
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 31.114
=S==SS==S3!S==SS===S==SSSS==S3SS=SS
CO Estimated / extrapolated.
33.422
33.286
33.286
168
-------
PN Profile Specfat ion Report
Profile Name
Profile Number
Data Quality
Paved Road Dust - Riverside, CA
41123
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ioniration.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-.90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
^fjd. 1 C3
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2.5 urn
Xwt
8.
18.
0.
0.
0.
1.
3.
0.
0.
0.
0.
4.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
320
597
228
739
241
667
793
458
028
025
117
789
008
010
087
000
012
000
003
005
028
000
000
000
000
000
000
000
000
000
000
000
000
101
unc
1.248
2..790
0.046
0.037
0.012
0.083
0.190
0.024
0.005
0.002
0.006
0.241
0.001
0.001
0.005
0.003
0.007
0.001
0.001
0.001
0.002
0.002
0.009
0.005
0.005
0.007
0.009
0.011
0.014
0.031
0.058
0.105
0.001
0.007
: (0-2.5)
: 0.250
2.5-10 um
Xut
7.123
16.470
0.187
0.555
0.232
1.913
3.590
0.496
0.022
0.027
0.119
5.117
0.008
0.010
0.086
0.000
0.000
0.000
0.007
0.014
0.044
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.055
0.000
0.000
0.114
unc
1.068
2.471
0.037
0.028
0.012
0.096
0.180
0.026
0.006
0.002
0.006
0.257
0.001
0.001
0.004
0.002
0.006
0.000
0.001
0.001
0.002
0.001
0.004
0.002
0.002
0.002
0.003
0.003
0.004
0.009
0.017
0.029
0.000
0.006
(0-6)
0.370
0-10 urn
Xwt
7.213
16.630
0.190
0.569
0.233
1.894
3.605
0.493
0.023
0.027
0.119
5.093
0.008
0.010
0.086
0.000
0.001
0.000
0.006
0.014
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
0.000
0.000
0.113
unc
1.331
3.019
0.047
0.079
0.032
0.200
0.412
0.058
0.008
0.007
0.018
0.544
0.004
0.004
0.015
0.002
0.006
0.000
0.003
0.005
0.009
0.001
0.006
0.003
0.003
0.004
0.006
0.007
0.008
0.019
0.036
0.063
0.001
0.017
(0-10)
0.440
Total
Measured^}
Xut
7.213
16.630
0.190
0.569
0.233
1.894
3.605
0.493
.0.023
0.027
0.119
5.093
0.008
0.010
0.086
0.000
0.001
"0.000 .
0.006
0.014
0.043
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.051
0.000
0.000
0.113
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
169
-------
PM Profile Speciat ion Report - continued (profile 41123)
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 um 0-10 urn Measured^}
Species -
CAS Number Num Sym Xwt unc Xwt unc Xwt unc Xwt unc
201 OC 7.478 1.527 11.801 0.948 11.475 1.446 11.475 0.000
202 EC 0.419 0.174 0.174 0.051 0.192 0.113 0.192 0.000
TOTALS: 47.153 48.164 48.088 48.088
{1} Estimated / extrapolated.
170
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Paved Road Dust
41124
C
Sepulveda Tunnel, Los Angeles,CA
Control Device
Referenced)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-S
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
7
17
0
2
0
0
3
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0-2
Xut
.087
.853
.250
.066
.317
.917
.338
.517
.026
.027
.072
.673
.013
.077
.263
.001
.003
.000
.020
.000
.231
.000
.083
.000
.011
.009
.012
.004
.003
.000
.091
.000
.001
.368
.5 urn
unc
0.357
0.894
0.050
0.116
0.022
0.048
0.168
0.027
0.006
0.002
0.004
0.186
0.001
0.004
0.014
0.002
0.021
0.001
0.002
0.001
0.012
0.002
0.016
0.005
0.006
0.007
0.009
0.012
0.014
0.031
0.059
0.105
0.001
0.019
: (0-2.5)
: 0.250
2.5-10 urn
Xut
7.353
20.843
0.174
1.145
0.312
1.532
3.058
0.620
0.021
0.039
0.104
5.530
0.009
0.095
0.269
0.003
0.000
0.001
0.025
0.013
0.443
0.000
0.012
0.000
0.000
0.000
0.006
0.000
0.000
0.018
0.162
0.042
0.002
0.429
unc
0.368
1.045
0.035
0.072
0.018
0.077
0.154
0.033
0.007
0.002
0.005
0.278
0.001
0.005
0.014
0.002
0.024
0.000
0.001
0.001
0.022
0.002
0.024
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.021
0.033
0.000
0.022
(0-6)
0.370
0-10 urn
Xut
7.336
20.653
0.179
1.204
0.312
1.493
3.076
0.614
0.021
0.039
0.102
5.413
0.009
0.094
0.268
0.002
0.000
0.001
0.025
0.012
0.429
0.000
0.016
0.000
0.001
0.001
0.007
0.000
0.000
0.016
0.158
0.039
0.002
0.425
unc
0.792
2.090
0.048
0.202
0.042
0.139
0.359
0.069
0.009
0.008
0.015
0.499
0.004
0.015
0.035
0.002
0.021
0.002
0.007
0.004
0.044
0.002
0.022
0.003
0.004
0.005
0.007
0.007
0.009
0.020
0.042
0.065
0.002
0.050
(0-10)
0.440
Total
MeasuredO}
Sut
7.336
20.653
0.179
1.204
0.312
1.493
3.076
0.614
0.021
0.039
0.102
5.413
0.009
0.094
0.268
0.002
0.000
0.001
0.025
0.012
0.429
0.000
0.016
0.000
0.001
0.001
0.007
0.000
0.000
0.016
0.158
0.039
0.002
0.425
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
171
-------
PM Profile Speciation Report - continued (profile 41124)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measuredtn
Species 7-
CAS Number Nun Sym Xwt unc Xwt unc Xwt unc Xwt unc
201 OC 13.780 2.758 12.805 0.916 12.867 2.169 12.867 0.000
202 EC 1.753 0.581 0.579 0.050 0.653 0.363 0.653 0.000
TOTALS: 52.866 55.644 55.467 55.467
=333Saa33333a33S3=a33aaaa3S333333
{1} Estimated / extrapolated.
172
-------
PM Profile Special ion Report
Profile Name Paved Road Oust -
Profile Number 41131
Data Quality C
Freeway Composite
Control Device Not Applicable
Reference(s) 1
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
S«
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
6
20
0
0
0
0
3
0
0
0
0
4
0-2
Xwt
.471
.849
.049
.615
.107
.943
.615
.468
.027
.020
.076
.117
0.018
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
17
0
56
.038
.412
.000
.004
.000
.006
.005
.083
.002
.007
.000
.000
.000
.000
.000
.000
.000
.026
.000
.001
.816
.574
.451
.800
.5 urn
unc
0.710
2.854
0.010
0.259
0.083
0.300
0.466
0.076
0.004
0.001
.0.018
0.413
0.001
0.006
0.159
0.002
0.038
0.001
0.002
0.001
0.011
0.002
0.006
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.030
0.054
0.001
0.528
1.666
0.131
41111 and 41112.
: (0-2.5) (0-6)
: 0.250 0.370
2.5-10 urn
Xwt
6.690
19.901
0.046
0.359
0.100
1.354
4.748
0.543
0.004
0.021
0.115
5.765
0.019
0.035
0.388
0.001
0.000
0.000
0.006
0.011
0.130
0.003
0.000
0.000
0.000
0.001
0.008
0.000
0.000
0.000
0.131
0.000
0.000
0.902
14.502
0.401
56.184
unc
0.710
2.415
0.011
0.359
0.100
0.337
0.236
0.050
0.005
0.001
0.007
0.232
0.001
0.001
0.193
0.003
0.043
0.000
0.005
0.002
0.018
0.003
0.006
0.001
0.001
0.002
0.005
0.003
0.003
0.007
0.014
0.022
0.000
0.624
1.289
0.074
0-10 urn
Xwt
6.667
19.999
0.046
0.385
0.101
1.316
4.627
0.535
0.006
0.021
0.111
5.597
0.019
0.035
0.389
0.001
0.000
0.000
0.006
0.010
0/T26
0.003
0.001
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.121
0.000
0.000
0.892
14.854
0.407
56.282
unc
0.935
3.171
0.014
0.313
0.090
0.327
0.515
0.080
0.005
0.006
0.019
0.557
0.006
0.009
0.177
0.003
0.039
0.001
0.005
0.004
0.022
0.003
0.005
0.002
0.002
0.003
0.006
0.004
0.005
0.010
0.026
0.035
0.001
0.565
2.129
0.105
(0-10)
0.440
Total
Measured^}
Xwt
6.667
19.999
0.046
0.385
0.101
1.316
4.627
0.535
0.006
0.021
0.111
5.597
0.019
0.035
0.389
0.001
0.000
0.000
0.006
0.010
0.126
01003
0.001
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.121
0.000
0.000
0.892
14.854
0.407
56.282
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O) Estimated / extrapolated.
173
-------
PM Profile Speciation Report
Profile Name Paved Road Oust -
Profile Number 41132
Data Quality C
Composite- Long
Beach, CA
Control Device Not Applicable
Reference(s) 1
Data Source Developed from profiles 41113 and 41114
SCC Assignments 113
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.250
Total Participate Matter
Spec i es
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Mum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
-
0-2
Xut
5.
15.
0.
0.
0.
1.
4.
0.
0.
0.
0.
3.
0.
0.
0.
0.
a.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
398
316
252
789
337
241
014
337
027
023
087
830
013
025
264
001
006
000
006
002
033
000
000
000
000
000
000
000
000
000
000
000
0.000
0.229
19.
626
2.213
.5 urn
unc
0.611
1.857
0.037
0.213
0.069
0.066
0.213
0.018
0.003
0.002
0.005
0.204
0.001
0.002
0.041
0.001
0.010
0.001
0.001
0.001
0.005
0.002
0.009
0.006
0.006
0.007
0.010
0.012
0.014
0.031
0.059
0.108
0.001
0.073
3.370
0.425
2.5-10 urn
Xwt
5.431
15.197
0.219
0.717
0.359
1.592
3.838
0.410
0.018
0.029
0.098
4.546
0.014
0.025
0.249
0.000
0.000
0.000
0.009
0.011
0:068
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.088
0.000
0.000
0.218
18.959
1.188
unc
0.577
1.615
0.031
0.186
0.101
0.057
0.136
0.016
0.004
0.001
0.006
0.232
0.001
0.001
0.024
0.001
0.009
0.001
0.000
0.001
0.015
0.001
0.003
0.001
0.001
0.002
0.004
0.003
0.003
0.007
0.016
0.023
0.000
0.066
1.467
0.100
(0-6)
0.370
0-10 urn
Xut
5.429
15.208
0.221
0.722
0.357
1.568
3.849
0.405
0.019
0.028
0.097
4.497
0.014
0.025
0.250
0.000
0.000
0.000
0.009
0.010
0.066
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.082
0.000
0.000
0.219
19.002
1.254
unc
0.775
2.209
0.043
0.202
0.095
0.154
0.427
0.046
0.007
0.007
0.016
0.460
0.005
0.007
0.043
0.001
0.009
0.001
0.004
0.004
0.016
0.001
0.007
0.003
0.003
0.004
0.007
0.007
0.009
0.019
0.038
0.063
0.001
0.071
2.926
0.319
(0-10)
0.440
Total
MeasuredO)
Xwt
5.429
15.208
0.221
0.722
0.357
1.568
3.849
0.405
0.019
0.028
0.097
4.497
0.014
0.025
0.250
0.000
0.000
0.000
0.009
0.010
0.066
0.000
0.014
0.000
0.000
0.000
0.004
0.000
0.007
0.000
0.082
0.000
0.000
0.219
19.002
1.254
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 54.069
533333SS333=333333S3333323S333332 =
O> Estimated / extrapolated.
53.308
53.356
53.356
174
-------
PM Profile Speciat ion Report
Profile Name Paved Road Oust -
Profile Number 41133
Data Quality C
Hawthorne Composite
Control Device Not Applicable
Reference(s) 1
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
==S=3S2S3===
Hum
.13
14
15
16
17
19
. 20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
-
0-2
Xwt
5.
16.
0.
0.
0.
0.
2.
0.
0.
0.
0.
3:
0.
992
131
031
434
099
998
243
317
020
014
070
399
012
0.021
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
105
000
003
000
005
004
029
000
000
000
000
000
000
000
000
000
000
000
000
103
.5 urn
unc
0.676
1.826
0.008
0.214
0.031
0.083
0.621
0.017
0.003
0.004
0.007
0.178
0.005
0.010
0.059
0.001
0.005
0.001
0.003
0.001
0.015
0.001
0.006
0.004
0.004
0.005
0.006
0.007
0.009
0.019
0.037
0.067
0.001
0.077
30.030
41115 and 41116
: (0-2.5)
: 0.250
2.5-10 urn
Xwt
6.953
18.201
0.030
0.291
0.096
1.556
2.477
0.463
0.010
0.018
0.106
4.773
0.012
0.017
0.112
0.000
0.000
0.000
0.006
0.013
0.058
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.003
0.092
0.002
0.000
0.091
35.389
unc
1.143
2.568
0.004
0.107
0.038
0.142
0.141
0.055
0.004
0.001
0.005
0.529
0.001
0.004
0.050
0.000
0.004
0.000
0.002
0.001
0.018
0.001
0.003
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.022
0.000
0.042
(0-6)
0.370
0-10 urn
Xwt
6.894
18.072
0.030
0.299
0.097
1.522
2.462
0.454
0.010
0.017
0.104
4.690
0.012
0.017
0.111
0.000
0.000
0.000
0.006
0.012
0.056
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.086
0.002
0.000
0.092
35.056
unc
1.134
2.756
0.009
0.152
0.037
0.173
0.438
0.062
0.005
0.006
0.016
0.569
0.005
0.008
0.053
0.000
0.004
0.000
0.004
0.004
0.019
0.001
0.005
0.002
0.002
0.003
0.004
0.005
0.006
0.012
0.026
0.041
0.001
0.056
ss=s===
(0-10)
0.440
Total
MeasuredO)
Xwt
6.394
18.072
0.030
0.299
0.097
1.522
2.462
0.454
0.010
0.017
0.104
4.690
0.012
0.017
0.111
0.000
0.000
0.000
0.006
0.012
0.056
0.001
'0.006
0.000
0.000
0.000
0.000
0.000
0.002
0.002
0.086
0.002
0.000
0.092
35.056
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Estimated / extrapolated.
175
-------
PM Profile Speciat ion Report
Profile Name Paved Road Dust -
Profile Number 41134
Data Quality C
Burbank Composite
Control Device Not Applicable
Reference(s) 1
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
S=2SSSS3SS==:
apci. i cs
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
201
202
Al
Si
P
S
Cl
1C
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
0-2
Xut
4
12
0
0
0
0
4
0
0
0
0
3
0
0
0
.286
.550
.274
.868
.358
.877
.742
.332
.022
.021
.071
.428
.010
.033
.242
0.001
0
0
0
0
0
• o
0
0
0
0
0
0
0
0
.007
.000
.006
.000
.023
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
0
10
0
40
.000
.000
.231
.647
.999
.028
.5 urn
unc
0.492
1.439
0.051
0.049
0.020
0.049
0.801
0.019
0.003
0.002
0.005
0.193
0.001
0.008
0.025
0.001
0.010
0.001
0.002
0,001
0.004
0.002
0.008
0.005
0.005
0.007
0.009
0.011
0.013
0.028
0.053
0.096
0.001
0.050
1.789
0.216
41117 amd 41118.
: (0-2.5) (0-6)
: 0.250 0.370
2.5-10 urn
Xwt
4.974
13.845
0.248
0.702
0.372
1.342
5.359
0.436
0.020
0.029
0.093
4.449
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0.010
0.052
0.000
0.005
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.074
0.000
0.000
0.280
15.978
1.778
50.360
unc
0.528
1.469
0.035
0.025
0.017
0.048
0.373
0.017
0.004
0.002
0.003
0.169
0.001
0.007
0.030
0.001
0.011
0.000
0.002
0.001
0.002
0.001
0.005
0.002
0.001
0.001
0.005
0.002
0.006
0.006
0.012
0.020
0.000
0.054
2.163
0.225
0-10 urn
Xwt
4.941
13.779
0.249
0.710
0.371
1.319
5.333
0.431
0.020
0.028
0.092
4.399
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0.010
0.051
0. 000
0.004
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.070
0.000
0.000
0.277
15.651
1.730
49.779
unc
0.665
1.884
0.051
0.093
0.046
0.121
0.729
0.047
0.007
0.007
0.014
0.418
0.004
0.010
0.040
0.001
0.010
0.000
0.004
0.004
0.010
0.001
0.006
0.003
0.003
0.004
0.007
0.006
0.009
0.017
0.033
0.057
0.001
0.059
2.296
0.251
sssssss:
(0-10)
0.440
Total
MeasuredO)
Xwt
4.941
13.779
0.249
0.710
0.371
1.319
5.333
0.431
0.020
0.028
0.092
4.399
0.013
0.033
0.245
0.000
0.000
0.000
0.010
0.010
0.051
0.000
0.004
0.002
0.000
0.000
0.005
0.000
0.006
0.000
0.070
0.000
0.000
0.277
15.651
1.730
49.779
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
176
-------
PM Profile Speciation Report
Profile Name Paved Road Oust -
Profile Number 41135
Data Quality C
Los Angeles Composite
Control Device Not Applicable
.Reference(s) 1
Data Source Developed from profiles
SCC Assignments 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apec i es
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
201
202
Al
Si
p
S
Cl
0-2
Xut
3.
9.
0.
0.
0.
675
919
373
898
311
< 0.652
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
3.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
243
305
028
048
078
210
029
053
428
000
010
000
002
000
021
000
000
000
000
0.000
0.
0.
0.
0.
0.
000
000
000
000
000
0.000
0.
0.
19.
0.
45.
000
209
267
858
617
.5 urn
unc
0.782
1.170
0.150
0.056
0.041
0.040
0.366
0.047
0.003
0.018
0.005
1.910
0.019
0.004
0.030
0.001
0.009
0.001
0.001
0.001
0.009
0.002
0.009
0.005
0.005
0.007
0.009
0.011
0.014
0.030
0.056
0.102
0.001
0.073
5.579
0.432
41119 amd 41120
: (0-2.5)
: 0.250
2.5-
Xwt
4.297
11.438
0.360
0.810
0.364
1.083
4.060
0.457
0.026
0.071
0.084
5.376
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.009
0.075
0.000
0.009
0.010
0.000
0.000
0.000
0.000
0.010
0.000
0.070
0.000
0.000
0.241
21.522
1.718
52.628
10 urn
unc
0.563
1.215
0.136
0.029
0.064
0.038
0.345
0.103
0.007
0.032
0.004
0.755
0.029
0.002
0.015
0.001
0.010
0.000
0.000
0.000
0.009
0.001
0.004
0.006
0.001
0.002
0.002
0.003
0.003
0.007
0.021
0.022
0.000
0.066
1.631
0.137
(0-6)
0.370
0-10 urn
Xwt
4.266
11.366
0.361
0.814
0.361
1.062
4.022
0.450
0.026
0.070
0.084
5.375
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.008
0.072
0.000
0.008
0.009
0.000
0.000
0.000
0.000
0.009
0.000
0.067
0.000
0.000
0.240
21.403
1.672
52.283
unc
0.728
1.534
0.140
0.100
0.067
0.097
0.488
0.093
0.009
0.028
0.014
1.333
0.026
0.011
0.053
0.001
0.009
0.000
0.003
0.004
0.014
0.001
0.007
0.007
0.003
0.004
0.005
0.007
0.009
0.018
0.037
0.060
0.001
0.071
3.935
0.296
(0-10)
0.440
Total
Measuredd}
Xwt
4.266
11.366
0.361
0.814
0.361
1.062
4.022
0.450
0.026
0.070
0.084
5.375
0.041
0.060
0.431
0.000
0.000
0.000
0.006
0.008
0.072
0.000
0.008
0.009
0.000
0.000
0.000
0.000
0.009
0.000
0.067
0.000
0.000
0.240
21.403
1.672
52.283
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
CO Estimated / extrapolated.
177
-------
PM Profile Speciation Report
Profile Name Paved Road Dust -
Profile Number 41136
Data Quality C
Anaheim Composite
Control Device Not Applicable
Reference(s) 1
Data Source Developed from profiles 41121 amd 41122
SCC Assignments 113
Mass Fraction Data - Size Interval (urn) : (0-2.5)
Mass Fraction : 0.250
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
ap^i. i ca
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
4.
12.
0.
1.
0.
0.
3.
407
337
241
075
615
960
999
0.263
0.
0.
0.
2.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
021
023
074
909
011
032
211
000
003
000
006
001
058
000
000
000
000
000
000
000
000
000
000
0.000
0.000
0.147
.5 urn
unc
0.586
1.692
0.049
0.134
0.203
0.113
0.891
0.075
0.003
0.002
0.024
0.641
0.003
0.009
0.012
0.001
0.006
0.001
0.001
0.001
0.023
0.002
0.008
0.005
0.005
0.006
0.008
0.010
0.013
0.028
0.052
0.094
0.001
0.020
2.5-10 urn
Xut
4.490
12.899
0.211
1.068
0.606
1.390
4.595
0.356
0.018
0.031
0.090
3.861
0.013
0.019
0.187
0.000
0.000
0.000
0.009
0.011
0.095
0.000
0.012
0.001
0.002
0.002
0.005
0.000
0.007
0.000
0.062
0.000
0.001
0.172
unc
0.769
1.521
0.030
0.169
0.192
0.071
0.731
0.068
0.003
0.005
0.017
0.445
0.002
0.002
0.009
0.001
0.007
0.000
0.002
0.001
0.037
0.001
0.004
0.001
0.002
0.002
0.002
0.002
0.003
0.006
0.046
0.020
0.001
0.006
(0-6)
0.370
0-10 urn
Xut
4.484
12.867
0.213
1.069
0.606
1.366
4.561
0.351
0.018
0.031
0.089
3.807
0.013
0.020
0.189
0.000
0.000
0.000
0.009
0.011
0.093
0.000
0.012
0.001
0.002
0.002
0.004
0.000
0.007
0.000
0.059
0.000
0.001
0.170
unc
0.803
1.944
0.046
0.186
0.197
0.145
0.859
0.076
0.006
0.008
0.023
0.594
0.005
0.008
0.027
0.001
0.006
0.000
0.004
0.004
0.034
0.001
0.007
0.003
0.003
0.004
0.006
0.006
0.008
0.016
0.046
0.055
0.001
0.025
(0-10)
0.440
Total
MeasuredO}
Xut
4.484
12.367
0.213
1.069
0.606
1.366
4.561
0.351
0.018
0.031
0.089
3.807
0.013
0.020
0.189
0.000
0.000
0.000
0.009
0.011
0.093
0.000
0.012
0.001
0.002
0.002
0.004
0.000
0.007
0.000
0.059
0.000
0.001
0.170
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 27.393
ss3a=ssass==5==ss=55as===s=====sss=
{1} Estimated / extrapolated.
30.213
30.055 30.055
====• a: sssr====s================
178
-------
PM Profile Special ion Report
Profile Name Paved Road Dust -
Profile Number 41137
Data Quality C
SCAB Composite
Control Device Not Applicable
Reference(s) SOCA8
Data Source Developed from profiles
41123, and 41124.
SCC Assignments: 113
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
3r
Rb
SP
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
0-2
Xut
5.704
15.444
0.212
0.935
0.298
1.032
3.623
0.375
0.025
0.025
0.081
3.920
0.014
0.036
0.251
0.000
0.006
0.000
0.007
0.002
0.063
0.000
0.011
0.000
0.001
0.001
0.001
0.001
0.000
0.000
0.015
0.000
0.000
0.275
14.729
.5 urn
unc
0.556
1.296
0.041
0.175
0.058
0.107
0.257
0.033
0.001
0.004
0.006
0.269
0.002
0.007
0.044
0.001
0.006
0.000
0.002
0.001
0.025
0.001
0.010
0.002
0.002
0.002
0.003
0.004
0.004
0.010
0.018
0.033
0.000
0.083
2.023
41131, 41132. 41133, 41134, 41135,
: (0-2.5) (0-6)
: 0.250 0.370
2.5-10 urn
5
16
0
0
0
1
3
0
0
0
0
4
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Xut
.914
.099
.184
.706
.305
.470
.966
.473
.017
.033
.101
.927
.016
.037
.246
.000
.000
.000
.010
.012
.121
.001
.007
.002
.000
.000
.004
.000
.004
.003
.092
.006
0.000
0
15
.306
.928
unc
0.443
1.191
0.038
0.108
0.059
0.085
0.332
0.029
0.003
0.006
0.004
0.225
0.004
0.010
0.043
0.001
0.007
0.000
0.002
0.001
0.047
0.000
0.003
0.001
0.001
0.001
0.001
0.001
0.001
0.003
0.013
0.009
0.000
0.093
1.520
0-10 urn
Xwt
5.904
16.072
0.186
0.721
0.305
1.443
3.942
0.467
0.018
0.033
0.100
4.859
0.016
0.037
0.246
0.000
0.000
0.000
0.010
0.011
0.117
0.000
0.008
0.002
0.000
0.000
0.003
0.000
0.004
0.002
0.087
0.005
0.000
0.303
15.875
unc
0.737
1.936
0.045
0.157
0.066
0.154
0.474
0.056
0.006
0.009
0.015
0.487
0.006
0.012
0.051
0.001
0.006
0.001
0.004
0.004
0.041
0.001
0.007
0.002
0.001
0.001
0.003
0.002
0.004
0.006
0.019
0.020
0.001
0.091
2.208
(0-10)
0.440
Total
Measured{1>
Xwt
5.904
16.072
0.186
0.721
0.305
1.443
3.942
0.467
0.018
0.033
0.100
4.859
0.016
0.037
0.246
0.000
0.000
0.000
0.010
0.011
0.117
0.000
0.008
0.002
0.000
0.000
0.003
0.000
0.004
0.002
0.087
0.005
0.000
0.303
15.875
unc
0.000
0.000
0.000
0. 000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
179
-------
PM Profile Speciation Report - continued (profile 41137)
Total Paniculate Matter -
Total
0-2.5 tin 2.5-10 um 0-10 urn MeasuredO}
Species -- -
CAS Number Nun Sym Xwt unc Xwt unc Xut unc Xwt unc
202 EC 1.116 0.295 0'.973 0.281 0.985 0.292 0.985 0.000
TOTALS: 48.203 51.963 51.761 51.761
(1> Estimated / extrapolated.
180
-------
3.11 NATURAL SOURCES
Natural sources of particulate emissions include sources such as marine
aerosols, volcanic ash, crustal sources, and soil dust. Marine aerosol
particulates would be most significant in coastal areas. Volcanic ash,
crustal sources, and soil dust would be more significant in rural areas than
urban areas.
181
-------
PM Profile Speciation Report
Profile Name Soil Oust -
Profile Number 41321
Data Quality C
Laurel HO
Control Device Not Applicable
Reference(s) 3,24
Data Source Sieved and resuspended; analyzed by PGAA and INAA.
SCC Assignments 058
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter -
CAS Number
7440-42-8
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7782-50-5
7440-09-7
7440-22-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5 .
7439-89-6
7440-48-4
7440-66-6
7440-55-3
7440-38-2
7726-95-6
7440-17-7
7440-67-7
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-00-8
7440-19-9
7440-54-2
7440-58-6
7440-29-1
apct- i cs
Num Sym
5
11
12
13
14
17
19
21
22
23
24
25
26
27
30
31
33
35
37
40
51
55
56
57
58
60
62
64
72
90
B
Na
Mg
Al
Si
Cl
K
Sc
Ti-
V
Cr
Mn
Fe
Co
Zn
Ga
As
3r
Rb
Zr
Sb
Cs
3a
La
Ce
Nd
Sm
Gd
Hf
Th
0-2
Xut
0
0
0
11
0
0
2
0
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.316
.000
.862
.000
.608
.472
.002
.666
.022
.000
.103
.991
.003
.009
.003
.003
.000
.000
.000
.000
.001
.000
.007
.009
.000
.001
.001
.001
.002
.5 urn
unc
0.000
0.029
O.'OOO
0.142
0.000
0.045
0.106
0.000
0.183
0.002
0.000
0.005
0.359
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.275
0.000
11.614
0.000
0.541
2.851
0.002
1.115
0.023
0.000
0.101
5.624
0.002
0.013
0.003
0.002
0.000
0.000
0.000
0.000
0.001
0.000
0.006
0.009
0.000
0.001
0.001
0.001
0.002
unc
0.000
0.026
0.000
0.163
0.000
0.018
0.145
0.000
0.145
0.002
0.000
0.005
0.281
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.000
0.285
0.000
11.676
0.000
0.558
2.756
0.002
1.003
0.023
0.000
0.101
5.716
0.002
0.012
0.003
0.002
0.000
0.000
0.000
0.000
0.001
0.000
0.006
0.009
0.000
0.001
0.001
0.001
0.002
unK1>
unc
0.000
0.020
0.000
0.518
0.000
0.030
0.137
0.000
0.093
0.002
•0.000
0.006
0.304
0.000
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.001
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
0.007
0.190
3.500
7.892
34.201
0.019
1.799
0.001
0.886
0.009
0.006
0.067
3.798
0.002
0.011
0.002
0.001
0.000
0.012
0.068
0.000
0.000
0.034
0.005
0.007
0.002
0.001
0.001
0.002
0.001
unc
0.000
6.010
0.350
0.087
1.700
0.001
0.284
0.000
0.115
0.001
0.002
0.002
0.190
0.000
0.001
0.000
0.000
0.000
0.001
0.008
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
22.082
22.187
22.160
52.524
C1> Calculated based on methodology described in the Air Emissions Species Manual.
Volume II.
183
-------
PH Profile Special ion Report
Profile Name Soil Dust - Washington, D
Profile Number 41322
Data Quality E
.c.
area
Control Device Not Applicable
Reference(s) 3,25
Data Source Fifty-gram, surface sample and one-kg subsurface sample
collected at each of four sites. Analyzed by INAA and IPAA.
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Participate Matter
SpGCI 6S
CAS Number Num Sym
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7440-70-2
7440-22-2
7440-62-2
7440-4-7-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7782-49-2
7726-95-6
7440-36-0
7440-46-2
7440-39-3
7439-91-0
7440-45-1
7440-19-9
7440-53-1
7440-64-4
7439-94-3
7440-58-6
7440-25-7
7440-29-1
TOTALS:
11
12
13
14
20
21
23
24
25
26
27
30
33
34
35
51
55
56
57
58
62
63
70
71
72
73
90
Na
Mg
Al
Si
Ca
Sc
V
Cr
Mn
Fe
Co
Zn
As
Se
Br
Sb
Cs
Ba
La
Ce
Sm
Eu
Yb
Lu
Hf
Ta
Th
0-2.5
Xut
0.320
0.560
5.990
35.001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
3.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
46.340
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2
.5-10
Xut
0.320
0
5
35
0
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
46
.560
.990
.001
.490
.001
.014
.006
.099
.780
.002
.008
.000
.000
.001
.000
.000
.052
.006
.007
.001
.000
.000
.000
.001
.000
.001
.340
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.320
0.560
5.990
35.001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
0.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
46.340
3S333S3
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
oiooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
33SS333
(0-10)
0.080
Total
Measured
Xwt
0.320
0.560
5.990
35:001
0.490
0.001
0.014
0.006
0.099
3.780
0.002
0.008
0.000
0.000
0.001
0.000
0.000
0.052
0.006
0.007
0.001
0.000
0.000
0.000
0.001
0.000
0.001
46.340
=========
unc
0.026
0.120
1.080
7.000
0.150
0.000
0.003
0.001
0.009
0.600
0.000
0.002
0.000
0.000
0.000
0.000
0.000
0.013
0.001
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1> Estimated / extrapolated.
184
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Soil Oust - Riverside, CA
41323
C
Control Device Not Applicable
Reference(s) 1
Data Source . Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 053
Mass Fraction Data - Size Interval (urn)
Mass Fraction
: (0-2.5)
: 0.020
(0-6)
0.040
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apvu i ea
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
In
Ga
As
Se
9r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
8a
La
Hg
Pb
0-2.5 urn
Xwt
9.
20.
0.
0.
0.
1.
2.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
42.
890
360
212
406
157
981
831
529
038
024
159
671
009
011
028
003
008
000
002
007
012
000
000
000
000
000
000
000
000
000
000
000
001
013
352
unc
1.484
3.054
0.043
0.020
0.008
0.099
0.142
0.027
0.006
0.002
0.008
0.286
0.001
0.002
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.002
0.011
0.007
0.007
0.009
0.012
0.014
0.017
0.038
0.071
0.128
0.001
0.004
rs=s====
2.5-10 urn
Xwt
9.231
19.190
0.175
0.332
0.179
2.227
2.900
0.556
0.025
0.029
0.150
5.955
0.007
0.007
0.026
0.000
0.000
0.000
0.003
0.016
0.028
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.050
0.000
0.000
0.030
41.122
unc
1.385
2.878
0.035
0.017
0.009
0.111
0.145
0.029
0.006
0.002
0.008
0.299
0.001
0.001
0.001
0.003
0.002
0.000
0.000
0.001
0.002
0.001
0.003
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.013
0.022
0.000
0.002
:======='
0-10 urn
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
0.390
1.345
0.022
0.020
0.009
0.109
0.148
0.029
0.004
0.002
0.008
0.300
0.001
0.001
0.002
0.001
0.001
0.000
0.001
0.001
0.002
0.001
0.003
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.019
0.034
0.000
0.002
(0-10)
0.080
Total
Measured^}
Xwt
9.267
19.253
0.177
0.336
0.177
2.213
2.897
0.554
0.026
0.029
0.150
5.940
0.007
0.007
0.027
0.000
0.000
0.000
0.003
0.016
0.027
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.048
0.000
0.000
0.029
41.189
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
185
-------
PH Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Soil Oust
41324
C
Hawthorne, CA
Control Device
Reference(s)
Data Source
Not Applicable
1
Surface dust sampled, aerosolized, and recollected with a
Sierra dichotomous virtual impactor. Analyzed using XRF and
flame ionization.
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Participate Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
^p^l. 1 C9
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
11.277
23.575
0.033
0.300
0.061
1.470
1.278
0.541
0.025
0.019
0.107
5.178
0.007
0.013
0.051
0.001
0.015
0.000
0.000
0.001
0.019
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.000
0.006
.5 urn
unc
1.299
2.717
0.005
0.050
0.026
0.084
0.092
0.038
0.006
0.004
0.007
0.298
0.003
0.005
0.028
0.001
0.007
0.001
0.001
0.002
0.003
0.003
0.012
0.007
0.008
0.009
0.012
0.016
0.018
0.039
0.075
0.136
0.001
0.006
(0
0
-2.5)
.020
2.5-10 urn
Xwt
10
21
0
0
0
1
1
.021
.218
.012
.095
.020
.683
.319
0.581
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.023
.021
.129
.593
.008
.005
.016
.000
.000
.000
.002
.013
.034
.001
.000
.000
.000
.000
.000
.000
.000
.008
.023
.013
.000
0.024
unc
1.064
2.251
0.012
0.013
0.001
0.060
0.047
0.031
0.005
0.002
0.005
0.200
0.001
0.001
0.002
0.002
0.001
0.000
0.002
0.001
0.003
0.001
0.003
0.002
0.002
0.002
0.003
0.004
0.005
0.010
0.023
0.034
0.000
0.002
(0-6)
0.040
0-10 urn
Xwt
9.890
20.802
0.011
0.101
0.022
1.622
1.275
0.558
0.023
0.021
0.124
5.417
0.008
0.006
0.018
0.000
0.001
0.000
0.001
0.012
0.032
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.026
0.014
0.000
0.023
unc
0.781
1.645
0.006
0.018
0.007
0.077
0.065
0.030
0.003
0.002
0.006
0.262
0.001
0.002
0.007
0.001
0.002
0.000
0.001
0.001
0.002
0.001
0.003
0.002
0.002
0.003
0.003
0.004
0.005
0.011
0.022
0.038
0.000
0.002
<0-10)
0.080
Total
MeasuredO}
Xwt
9.890
20.802
0.011
0.101
0.022
1.622
1.275
0.558
0.023
0.021
0.124
5.417
0.008
0.006
0.018
0.000
0.001
0.000
0.001
0.012
0.032
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.007
0.026
0.014
0.000
0.023
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
43.997
40.862
40.015
40.015
C1) Estimated / extrapolated.
186
-------
PH Profile Sped at ion Report
Profile Name
Profile Number
Data Quality
Soil
41351
C
Dust - SCAB
Composite
Control Device Not Applicable
Reference(s) 1
Data Source Composite of surface dust samples collected to develop
profile #41323 and #41324.
SCC Assignments: 058
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
0-2
Num Sym %wt
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
8r
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
10.
21.
0.
0.
0.
1.
2.
0.
0.
0.
0.
5.
0.
0.
0.
0.
0.
0.
0.
0-.
0.
583
968
123
353
109
726
054
535
031
021
133
424
008
012
040
002
012
000
001
004
015
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
43,
000
000
000
000
000
000
000
010
000
000
000
009
173
.5 urn
unc
1.011
2.095
0.090
0.053
0.048
0.255
0.776
0.026
0.006
0.002
0.026
0.247
0.002
0.003
0.014
0.001
0.004
0.001
0.001
0.003
0.003
0.002
0.008
0.005
0.005
0.006
0.008
0.011
0.012
0.027
0.052
0.094
0.001
0.004
2.5-10 urn
Xwt
9.626
20.204
0.094
0.213
0.099
1.955
2.109
0.568
0.024
0.025
0.139
5.774
0.008
0.006
0.021
0.000
0.000
0.000
0.003
0.015
0.031
0.003.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.037
0.006
0.000
0.027
40.991
unc
0.873
1.827
0.082
0.118
0.079
0.272
0.791
0.021
0.004
0.004
0.010
0.181
0.001
0.001
0.005
0.002
0.001
0.000
0.001
0.002
0.003
0.003
0.002
0.001
0.001
0.001
0.002
0.002
0.003
0.006
0.014
0.020
0.000
0.003
0-10 urn
Xwt
9.683
20.310
0.095
0.221
0.100
1.942
2.105
0.566
0.025
0.025
0.139
5.755
0.008
0.006
0.022
0.000
0.001
0.000
0.003
0.014
0.030
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.035
0.006
0.000
0.026
41.125
unc
0.673
1.403
0.047
0.062
0.042
0.170
0.450
0.027
0.003
0.002
0.011
0.264
0.001
0.001
0.005
0.001
0.001
0.000
0.001
0.001
0.002
0.002
0.002
0.001
0.001
0.002
0.002
0.003
0.003
0.007
0.01S
0.026
0.000
0.002
(0-10)
0.080
Total
Measured<1}
%wt
9.683
20.310
0.095
0.221
0.100
1.942
2.105
0.566
0.025
0.025
0.139
5.755
0.008
0.006
0.022
0.000
0.001
0.000
0.003
0.014
0.030
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.035
0.006
0.000
0.026
41.125
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
sssssssssssasssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssssxsss
(1> Estimated / extrapolated.
187
-------
PM Profile Speciation Report
Profile Name Limestone, Crustal
Profile Number 43304
Data Quality E
Control Device Not Applicable
Reference(s) 1,29
Data Source Data taken from Reference 1. For details, consult Reference
29.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 Oi040
Total Participate Matter
Species
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-66-6
7726-95-6-
7440-24-6
7440-39-3
7439-92-1
TOTALS:
Nun
11
12
13
14
15
16
17
19
20
22
23
24
25
26
28
30
35
38
56
82
202
Sym
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Zn
Br.
sr
Ba
Pb
EC
0-2.5
Xwt
0
4
0
2
0
0
0
0
30
0
0
0
0
0
0
.040
.700
.420
.400
.040
.120
.015
.270
.200
.040
.002
.001
.110
.380
.002
0.002
0
0
0
0
11
50
.001
.061
.001
.001
.400
.206
um<1}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.040
4.700
0.420
2.400
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.040
4.700
0.420
2.400
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
0.040
4.700
0.420
2.400
0.040
0.120
0.015
0.270
30.200
0.040
0.002
0.001
0.110
0.380
0.002
0.002
0.001
0.061
0.001
0.001
11.400
50.206
unc
0.004
0.470
0.042
0.240
0.004
0.012
0.002
0.027
3.020
0.004
o.ooo-
0.000
0.011
0.038
0.000
0.000
0.000
0.006
0.000
0.000
1.140
{1} Estimated / extrapolated.
188
-------
PM Profile Speciation Report
Profile Name Shale,
Profile Number 43305
Data Quality E
Crustal
Control Device Not Applicable
Reference(s) 1,29
Data Source Data taken from Reference 1. For details, consult Reference
29.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Particulate Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-17-7
7440-24-6
7440-31-5
7440-39-3
7439-92-1
TOTALS:
?t^U 1 C3
Nun Sym
11
12
13
14
15
16
17
-19
20
22
23
24
25
26
28
29
30
37
38
50
56
82
202
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Rb
Sr
Sn
Ba
Pb
EC
0-2.5
Xut
0
.960
T.500
8
27
.000
.300
0.070
0
0
2
2
0
0
0
0
4
0
0
0
0
0
0
0
0
1
49
.240
.018
.660
.210
.460
.013
.009
.085
.720
.007
.005
.010
.014
.030
.001
.058
.002
.500
.872
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
%ut
0.960
1.500
8.000
27.300
0.070
0.240
0.018
2.660
2.210
0.460-
0.013
0.009
0.085
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.960
1.500
8.000
27.300
0.070
0.240
0.018
2.660
2.210
• 0.460
0.013
0.009
0.085
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
' 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ISSSSSSS
(0-10)
0.080
Total
Measured
Xut
"0.960
1.500
8.000
27.300
0.070
0.240
'0.018
2.660
2.210
0.460
0.013
0.009
0.085
4.720
0.007
0.005
0.010
0.014
0.030
0.001
0.058
0.002
1.500
49.872
unc
0.096
0.150
0.800
2.730
0.007
0.024
0.002
0.266
0.221
0.046
0.001
0.001
0.009
0.472
0.001
0.001
0.001
0.001
0.003
0.000
0.006
0.000
0.150
{1} Estimated / extrapolated.
189
-------
PM Profile Speciation Report
Profile Name Sandstone, Crustal
Profile Number 43306
Data Quality E
Control Device Not Applicable
Reference(s) 1,30
Data Source. Data taken from Reference 1. For
30.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0
Mass Fraction : 0
Total Particulars Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
. 7440-09-7
7440-70-2
7440-32-6
7439-89-6
7440-39-3
Mum Sym
n
12
13
14
15
16
19
20
22
26
56
202
Na
Mg
Al
Si
P
S
K
Ca
Ti
Fe
Ba
EC
0-2.5
Xwt
Q
Q
2
36
0
0
1
3
0
0
0
1
.334
.700
.523
.580
.035
.028
.087
.933
.150
.981
.045
.373
un»O>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
JO. 150
0.981
0.045
1.373
details, consult Reference
-2.5) (0-6)
.020 0.040
um<1>
unc
0.000
0.000
0.000
0.000
0.000
g.ooo
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
0.150
0.981
0.045
1.373
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.080
Total
Measured
Xwt
0.334
0.700
2.523
36.580
0.035
0.028
1.087
3.933
0.150
0.981
0.045
1.373
unc
0.067
0.140
0.505
7.316
0.007
0.006
0.218
0.787
0.030
0.196
0.009
0.275
TOTALS:
47.769
47.769
47.769
47.769
C1> Estimated / extrapolated.
190
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Sediment, Crustal
43307
E
Control Device
Reference(s)
Data Source
Not Applicable
1,30
Data taken from Reference 1. For details, consult Reference
30.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Part icul ate
Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7440-09-7
7440-70-2
7440-32-6
7439-89-6
3fJVl. 1 C9
Mum Sym
11
12
13
14
15
16
19
20
22
26
202
Ha
Mg
Al
Si
P
S
K
Ca
Ti
Fe
EC
: (0-2.5)
: 0.020
(0-6)
0.040
(0-10)
0.080
Total
0-2.5 unK1>
Xut
0
1
7
27
0
0
2
4
0
4
2
.839
.598
.083
.063
.057
.216
.374
.211
.341
.042
.129
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
unK1}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
0.839
1.598
7.083
27.063
0.057
0.216
2.374
4.211
0.341
4.042
2.129
unc
0.168
0.320
1.417
5.413
0.011
0.043
0.475
0.842
0.068
0.808
0.426
TOTALS: 49.953
{1} Estimated / extrapolated.
49.953
49.953
49.953
191
-------
PM Profile Special ion Report
Profile Name Igneous
Profile Number 43308
Data Quality E
Rock
Control Device Not Applicable .
Reference(s) 1,30
Data Source Data taken from Reference 1. For details, consult Reference
30.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Participate Matter -
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7440-09-7
7440-70-2
7440-32-6
7439-89-6
7440-39-3
TOTALS:
Num Sym
11
12
13
14
15
19
20
22
26
56
202
Na
Mg
Al
Si
P
K
Ca
Ti
Fe
Sa.
EC
0-2.5
Xnt
2
2
8
27
0
2
z
0
5
0
0
52
.849
.105
.115
.618
.131
.598
.632
.629
.106
.054
.027
.864
un*1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
52.864
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
52.864
(0-10)
0.080
Total
um{1} Measured
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
2.849
2.105
8.115
27.618
0.131
2.598
3.632
0.629
5.106
0.054
0.027
52.864
unc
0.570
0.421
1.623
5.524
0.026
0.520
0.726
0.126
1.021
0.011
0.006
{1> Estimated / extrapolated.
192
-------
PM Profile Speciation Report
Profile Name Earth's
Profile Number 43309
Data Quality E
Crust
Control Device Not Applicable
Referenced) 1,30
Data Source Data taken from Reference 1. For details, consult Reference
30.
SCC Assignments: 115
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.020 0.040
Total Participate
Hatter
(0-10)
0.080
Total
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
74400-30-1
7439-98-7
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
3(JCT. i era
Nun Sym
11
12
13
14
15
16
17
19
20
22
23
24
25
26
27
28
29
30
31
33
34
35
37
38
39
40
41
42
47
48
49
50
51
56
57
Na
Mg
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Co
Hi
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Nb
Mo
Ag
Cd
In
Sn
Sb
Ba
La
2
2
8
28
0
0
0
2
4
0
0
0
0-2.5
Xwt
.360
.330
.320
.200
.105
.026
.013
.090
.150
.570
.014
.010
0.095
5
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.630
.003
.008
.006
.007
.002
.000
.000
.000
.009
.038
.003
.017
.002
.000
.000
.000
.000
.000
.000
.043
.003
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.OOQ
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
2.360
2.330
8.320
28.200
0.105
0.026
0.013
2.090
4.150
0.570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0.003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
2.360
2.330
8.320
28.200
0.105
0.026
0.013
2.090
4.150
0.570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0.003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
2.360
2.330
8.320
28.200
0.105
0.026
0.013
2.090
4.150
0.570
0.014
0.010
0.095
5.630
0.003
0.008
0.006
0.007
0.002
0.000
0.000
0.000
0.009
0.038
0.003
0.017
0.002
0.000
0.000
0.000
0.000
0.000
0.000
0.043
0.003
unc
0.708
0.699
2.496
8.460
0.032
0.008
0.004
0.627
1.245
0.171
0.004
0.003
0.029
1.689
0.001
0.002
0.002
0.002
0.001
0.000
0.000
0.000
0.003
0.011
0.001
0.005
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.013
0.001
193
-------
PM Profile Speciation Report - continued (profile 43309)
Total Participate Matter -
Total
0-2.5 unK1> 2.5-10 un{1} 0-13 umC1> Measured
Species -- — -
CAS Number Hum Sym Xwt unc Xwt unc Xwt unc Xwt unc
7440-45-1
7440-00-8
7439-97-6
7439-92-1
7440-69-9
58
60
80
82
83
202
Ce
Nd
Hg
Pb
Si
EC
0
0
0
0
0
0
.006
.003
.000
.001
.000
.020
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.003
0.000
0.001
0.000
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.003
0.000
0.001
0.000
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.003
0.000
0.001
0.000
0.020
0.002
0.001
0.000
0.000
0.000
0.006
TOTALS: 54.084 54.084 54.084 54.084
33S333333=33S3SSSSSS33S3S333S=33S3333333333333SSS3
C1> Estimated / extrapolated.
194
-------
3.12 WOOD COMBUSTION
Forest fires, wood slash burning, and residential wood burning are
area sources of particulate emissions in the category of wood combustion.
Residential wood burning is commonly used to supplement conventional heating
systems. Residential woodstoves are usually radiating or circulatory designs
constructed from cast iron, heavy gauge sheet metal, or stainless steel.
Emissions from wood combustion are affected by furnace design and operating
conditions, and fuel characteristics such as fuel composition, moisture
content, and effective burning surface area.
195
-------
PM Profile Speciation Report
Profile Name Slash Burning (Conifer-flaming phase)
Profile Number 42305
Data Quality E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over three
ten-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate
Matter
(0-10)
0.990
Total
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
TOTALS:
O^VU 1 C5
Nun Sym
11
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
Na
Al
Si
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Pb
OC
EC
2
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
36
18
0-2.5 urn
Xut
.734
.120
.091
.341
.556
.419
.182
.218
.069
.113
.038
.057
.009
.009
.118
.048
.154
.400
.600
unc
3.664
0.083
0.064
0.147
0.317
0.809
0.231
0.220
0.122
0.194
0.033
0.102
0.006
0.006
0.094
0.021
0.097
11.284
12.462
61.276
2.5-10
Xwt
2.734
0.120
0.091
0.341
0.556
1.419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
61.276
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
2.734
0.120
0.091
0.341
0.556
1.419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
61 .276
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
MeasuredO}
Xut
2.734
0.120
0.091
0.341
0.556
1.419
0.182
0.218
0.069
0.113
0.038
0.057
0.009
0.009
0.118
0.048
0.154
36.400
18.600
61.276
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
197
-------
PM Profile Special ion Report
Profile Name Slash Burning
Profile Number 42306
Data Quality E
(Conifer-smoldering phase)
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 10 meters above slash fire over three
180-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate Matter
Species
CAS Number
7440-23-5
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7439-92-1
TOTALS:
Nun
11
13
14
16
17
19
20
22
23
24
25
26
28
29
30
35
82
201
202
Sym
Na
Al
Si
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
In
Br
Pb
OC
EC
"
0-2
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
51.
3.
57.
732
101
167
114
118
126
127
124
031
024
020
061
010
010
016
025
078
900
400
184
.5 urn
unc
0.483
0.097
0.197
0.066
0.063
0.063
0.103
0.089
0.025
0.016
0.017
0.040
0.006
0.006
0.010
0.013
0.055
3.304
0.782
2.5-10
Xut
0.732
0.101
0.167
0.114
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51.900
3.400
57.184
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.732
0.101
0.167
0.114
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51.900
3.400
57.184
(0-10)
0.990
Total
unK1> MeasuredO)
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
%ut
0.732
0.101
0.167.
0.114"
0.118
0.126
0.127
0.124
0.031
0.024
0.020
0.061
0.010
0.010
0.016
0.025
0.078
51.900
3.400
57.184
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
198
-------
PM Profile Speciation Report
Profile Name Slash Burning (Hardwood- ft anting
Profile Number 42307
Data Quality E
phase)
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over. three
10-minute periods. Analyzed by gas chroma tography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulate
Matter
(0-10)
0.990
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
a|jw i c»
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0
0
0
1
2
5
0
0
0
0
0
0
0
0
0
0
0
0
0-2
Xut
.280
.427
.237
.118
.703
.014
.181
.019
.006
.018
.023
.107
.024
.021
.154
.124
.077
.169
0.086
0
60
8
.211
.300
.300
.5 urn
unc
0.434
0.521
0.254
1.219
3.163
6.217
0.398
0.029
0.009
0.043
0.030
0.227
0.054
0.037
0.186
0.104
0.156
0.397
0.169
0.371
1.809
4.731
79.599
2.5-10
Xut
0.280
0.427
0.237
1.118
2.703
5.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
79.599
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.280
0.427
0.237
1.118
2.703
5.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
79.599
umO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
0.280
0.427
0.237
1.118
2.703
5.014
0.181
0.019
0.006
0.018
0.023
0.107
0.024
0.021
0.154
0.124
0.077
0.169
0.086
0.211
60.300
8.300
79.599
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(1) Estimated / extrapolated.
199
-------
PM Profile Special ion Report
Profile Name Slash Burning (Hardwood-smoldering phase)
Profile Number 42308
Data Quality E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 10 meters above slash fire over three
1 So-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulate Matter •
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
4yc\. i va
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
S33333
Al
Si
p
s
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
Zn
8r
Ag
Cd
Sn
Pb
OC
EC
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
61
.181
.336
.093
.503
.468
.577
.183
.013
.004
.003
.011
.062
.003
.001
.014
.019
.030
.066
.043
.031
.700
2.700
67
.041
.5 urn
unc
0.161
0.407-
0.079
0.483
0.225
0.565
0.344
0.013
0.006
0.004
0.013
0.087
0.004
0.001
0.018
0.010
0.034
0.115
0.066
0.041
2.468
0.999
2.5-10 umO>
Xut
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
67.041
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
533333333
0-10
Xut
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
67.041
S3333333
unO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
MeasuredCO
Xut
0.181
0.336
0.093
0.503
0.468
0.577
0.183
0.013
0.004
0.003
0.011
0.062
0.003
0.001
0.014
0.019
0.030
0.066
0.043
0.031
61.700
2.700
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
67.041
3S33333333333=33333S3
{1} Estimated / extrapolated.
200
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Slash Burning (Ponderosa Pine-flaming phase)
42309
E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 . 0.960
Total Participate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
3S333335S333
aym. i «»
Hum Svm
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
33333
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
•3333533
0
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
55
10
69
assess
0-2
Xwt
.081
.152
.088
.556
.554
.103
.112
.010
.003
.003
.016
.010
.005
.000
.115
.033
.028
.045
.013
.068
.100
.900
.995
.5 urn
unc
0.038
0.082
0.034
0.295
0.332
1.157
0.052
0.010
0.003
0.005
0.007
0.008
0.005
0.000
0.069
0.025
0.018
0.048
0.015
0.068
3.857
5.559
2.5-10
Xwt
0.081
0.152
0.088
0.556
0.554
2.103
0.112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
un»C1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.081
0.152
0.088
0.556
0.554
2.103
0.112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
(0-10)
0.990
Total
um(1} MeasuredCI}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.081
0.152
0.088
0.556
0.554
2.103
0.112
0.010
0.003
0.003
0.016
0.010
0.005
0.000
0.115
0.033
0.028
0.045
0.013
0.068
55.100
10.900
69.995
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
33===3
{1} Estimated / extrapolated.
201
-------
PM Profile Speciat ion Report
Profile Name Slash Burning (Ponderosa
Profile Number 42310
Data Quality E
Pine-smoldering phase)
Control Device Not Applicable
Referenced) 26
Data Source Samples collected 10 meters above slash fire over three
180-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulars Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726:95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
SSSZ3SS3SSS3S
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
sssssa
Sym
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
3r
Ag
Cd
Sn
Pb
OC
EC
ESa=333
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.105
.148
.048
.162
.226
.501
.073
.005
.002
.000
.008
.057
.002
.000
.025
.308
.018
.014
.018
0.019
61
4
66
.000
.100
.539
.5 urn
unc
0.069
0.170
0.023
0.110
0.167
0.396
0.094
0.008
0.002
0.000
0.008
0.094
0.001
0.000
0.019
0.005
0.013
0.010
0.014
0.013
3.050
1.107
2.5-10
Xut
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
0.019
61.000
4.100
66.539
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
0.019
61.000
4.100
66.539
urnCD
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
MeasuredCO
Xwt
0.105
0.148
0.048
0.162
0.226
0.501
0.073
0.005
0.002
0.000
0.008
0.057
0.002
0.000
0.025
0.008
0.018
0.014
0.018
-X>.019
61.000
4.100
66.539
3323SS33:
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
5SS==S
{1} Estimated / extrapolated.
202
-------
PM Profile Speciat ion Report
Slash Burning (Tractor-piled;flaming phase)
Profile Name
Profile Number
Data Quality
42311
E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Paniculate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
at*£b i «a
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0-2
Xwt
0
0
0
0
0
3
0
0
0
0
. 0
0
0
0
0
0
0
0
0
0
49
8
.181
.348
.128
.950
.921
.895
.619
.018
.007
.000
.045
.030
.011
.007
.389
.146
.172
.066
.196
.234
.000
.200
.5 urn
unc
0.083
0.115
0.040
0.504
0.341
2.298
0.142
0.017
0.006
0.000
0.030
0.020
0.013
0.009
0.222
0.105
0.127
0.104
0.182
0.201
5.390
3.690
: (0-2.5)
: 0.900
2.5-10
Xut
0.181
0.348
0.128
0.950
0.921
3.895
0.619
0.018
0.007
0.000
0.045
0.030
0.011
0.007
0.389
0.146
0.172
0.066
0.196
0.234
49.000
8.200
unKU
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.960
0-10
Xwt
0.181
0.348
0.128
0.950
0.921
3.895
0.619
"0.018
0.007
0.000
0.045
0.030
0.011
0.007
0.389
0.146
0.172
0.066
0.196
0.234
49.000
8.200
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
Measuredd)
Xwt
0.181
0.348
0.128
0.950
0.921
3.895
0.619
0.018
0.007
0.000
0.045
0.030
0.011
0.007
0.389
0.146
0.172
0.066
0.196
0.234
49.000
8.200
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
65.563
65.563
65.563
65.563
C1> Estimated / extrapolated.
203
-------
PH Profile Speciat ion Report
Profile Name Slash Burning (Tractor-pi led;smoldering
Profile Number 42312
Data Quality E
phase)
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 10 meters above slash fire over three
180 -minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-H-O
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
3r
Ag
Cd
Sn
Pb
OC
EC
0-2
Xwt
0.056
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.052
.039
.228
.227
.606
.071
.002
.001
.000
.005
.003
.027
.000
.012
.012
.008
.015
.000
.010
53.100
2
57
.900
.374
.5 urn
unc
0.007
0.024
0.007
0.043
0.018
0.188
0.011
0.002
0.001
0.000
0.003
0.005
0.045
0.000
0.005
0.003
0.010
0.022
0.000
0.004
2.124
1.421
2.5-10
Xut
0.056
0.052
0.039
0.228
0.227
0.606
.0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
0.008
0.015
0.000
0.010
53.100
2.900
57.374
unC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.056
0.052
0.039
0.228
0.227
0.606
0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
0.008
0.015
0.000
0.010
53.100
2.900
57.374
(0-10)
0.990
Total
umCD MeasuredO}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xut
0.056
0.052
0.039
0.228
0.227
0.606
0.071
0.002
0.001
0.000
0.005
0.003
0.027
0.000
0.012
0.012
0.008
0.015
0.000
0.010
53.100
2.900
57.374
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{1} Estimated / extrapolated.
204
-------
PH Profile Speciat ion Report
Profile Name Slash Burning (Crane-pi led;f laming phase)
Profile Number 42313
Data Quality E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate
Matter
(0-10)
0.990
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
==5SSSS=5SS3
apei; i es
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0-2
Xut
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
59
2
63
.025
.016
.011
.229
.196
.195
.074
.001
.001
.000
.019
.006
.000
.001
.054
.004
.005
.001
.005
.007
.800
.300
.950
.5 urn
unc
0.009
0.032
0.004
0.034
0.025
0.215
0.019
0.001
0.001
0.000
0.005
0.004
0.000
0.001
0.020
0.003
0.004
0.002
0.010
0.008
4.186
0.345
2.5-10
Xwt
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
umCO
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
%ut
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
MeasuredO}
Xwt
0.025
0.016
0.011
0.229
0.196
1.195
0.074
0.001
0.001
0.000
0.019
0.006
0.000
0.001
0.054
0.004
0.005
0.001
0.005
0.007
59.800
2.300
63.950
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Estimated / extrapolated.
205
-------
PM Profile Specialion Report
Profile Name Slash Burning (Crane-pi led.-smoldering phase)
Profile Number 42314
Data Quality E
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 10 meters above slash fire over three
180-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Particulars Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
.7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
• 7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
dfJCT. lea
Han Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
0-2
Xut
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0.007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
62.714
.5 urn
unc
0.008
0.012
0.004
0.051
0.046
0.335
0.018
0.001
0.000
0.001
0.006
0.002
0.000
0.001
0.004
0.002
0.005
0.003
0.000
0.002
2.416
0.363
2.5-10
Xut
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0.007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
62.714
um{1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.013
0.013
0.007
0.125
0.107
0.818
0.077
0.002
0.000
0.001
0.018
0.007
0.000
0.001
0.012
0.002
0.004
0.004
0.000
0.003
60.400
1.100
62.714
umC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
ESSS2XS3
(0-10)
0.990
Total
MeasuredC1>
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
60
1
62
Xut
.013
.013
.007
.125
.107
.818
.077
.002
.000
.001
.018
.007
.000
.001
.012
.002
.004
.004
.000
.003
.400
.100
.714
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
SSS33SS
O> Estimated / extrapolated.
206
-------
PM Profile Speciation Report
Profile Name Slash Burning (Chaparral
Profile Number 42315
Data Quality E
; flaming
phase)
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 20 meters above slash fire over three
10-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.900 0.960
Total Participate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
SSSS3SSSS3S
af^ri; i es
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
sssssss
Al
Si
p
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Br
Ag
Cd
Sn
Pb
OC
EC
ssasss:
0
0
0
2
4
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
48
9
76
0-2
Xut
.261
.699
.209
.297
.323
.896
.581
.015
.004
.000
,010
.121
.002
.003
.181
.110
.097
.055
.031
.425
.000
.200
.520
.5 urn
unc
0.227
0.377
0.056
0.350
1.686
3.563
0.308
0.013
0.005
0.000
0.006
0.071
0.001
0.001
0.056
0.057
0.082
0.043
0.024
0.157
3.360
4.784
2.5-10
Xwt
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0.121
0.002
0.003
0.181
0.110
0.097
0.055
0.031
0.425
48.000
9.200
76.520
um<1}
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0.121
0.002
0.003
0.181
0.110
0.097
0.055
0.031
0.425
48.000
9.200
76.520
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.990
Total
MeasuredO}
Sut
0.261
0.699
0.209
2.297
4.323
9.896
0.581
0.015
0.004
0.000
0.010
0.121
0.002
0.003
0.181
0.110
0.097
0.055
0.031
0.425
48.000
9.200
76.520
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<1> Estimated / extrapolated. .
207
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Slash Burning
42316
E
(Chaparral
.•smoldering phase)
Control Device Not Applicable
Reference(s) 26
Data Source Samples collected 10 meters above slash fire over three
ISO-minute periods. Analyzed by gas chromatography.
SCC Assignments: 062, 50300201
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6) (0-10)
Mass Fraction : 0.900 0.960 0.990
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7726-95-6
7440-22-4
7440-43-9
7440-31-5
7439-92-1
TOTALS:
ape
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
35
47
48
50
82
201
202
•V IC3
Sym
Al
Si
p
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
8r
Ag
Cd
Sn
"• Pb
- OC
EC
0-2
Xut
0.077
0.238
0.
0.
1.
3.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
63.
7.
78.
096
838
549
988
268
010
002
000
014
020
001
000
040
035
026
015
000
082
900
800
999
.5 urn
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.077
0.238
0.096
0.838
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63.900
7.800
78.999
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
3.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.077
0.238
0.096
0.838
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63.900
7.800
78.999
un»O>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
sssssss
Total
MeasuredO>
Xwt
0.077
0.238
0.096
0.338
1.549
3.988
0.268
0.010
0.002
0.000
0.014
0.020
0.001
0.000
0.040
0.035
0.026
0.015
0.000
0.082
63.900
7.800
78.999
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.oog
0.000
0.000
0.000
0.000
0.000
O) Estimated / extrapolated.
208
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
Uood Combustion - Las Vegas Valley (1987)
42317
C
Control Device
Reference(s)
Data Source
Not Applicable
20.27
Samples collected with two dichotomous samplers. Analyzed
using sequential thermal oxidation and XRF.
SCC Assignments: 006
Mass Fraction Data - Size Interval Cum) :
Mass Fraction :
: (0-2.5)
: 1.000
(0-6)
1.000
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
Nun Sym
13
14
16
17
19
82
200
Al
Si
S
Cl
K
Pb
TC
TOtALS:
0
0
1
0
0
0
61
64
0-2.5 urn
Xwt
.300
.300
.010
.250
.870
.250
.000
.480
unc
0.030
0.080
0.100
0.025
0.100
0.025
10.000
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.300
0.300
1.010
0.250
0.870
0.250
61.000
64.480
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
MeasuredO}
Xwt
0.300
0.800
1.010
0.250
0.870
0.250
61.000
64.480
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Only data in the 0 - 2.5 on range were measured.
209
-------
PM Profile Speciation Report
Profile Name Residential Wood
Profile Number 42318
Data Quality C
Combustion
Control Device Uncontrolled
Reference(s) 1,28
Data Source Data taken from Reference 1. For details, consult Reference
28.
SCC Assignments: 006
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 1.000 1.000
Total Particulate Matter •
CAS Number
7440-23-5
7439-95-4
7429-90-5
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-66-6
Nun Sym
11
12
13
16
17
19
20
30
201
202
203
Na
Mg
Al
S
Cl
K
Ca
Zn
OC
EC
S04
0-2.5 urn
Xut
0.
0.
0.
0.
0.
0.
a.
0.
47.
12.
0.
083
073
021
182
509
860
067
037
500
800
289
unc
0.012
0.017
0.010
0.019
0.031
0.096
0.006
0.002
13.800
8.400
0.021
2.5-10 un
Xut
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.083
0.073
0.021
0.182
0.509
0.860
0.067
0.037
47.500
12.800
0.289
unc
0.017
0.020
0.010
0.032
0.078
0.155
0.011
0.006
15.348
8.593
0.046
(0-10)
1.000
Total
Measured(1>
Xut
0.083
0.073
0.021
0.182
0.509
0.860
0.067
0.037
47.500
12.800
0.289
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
62.421
0.000
62.421
62.421
O> Only data in the 0 - 2.5 -jn range were measured.
210
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Residential Wood Combustion Composite
42319
Control Device
Reference(s)
Data Source
Uncontrolled
Profile represents a composite of Profiles 42317 and 42318
for the elements AL, S, CL, and K.
SCC Assignments: 006
Mass Fraction Data
- Size Interval (urn) :
Mass Fraction :
: (0-2.5)
: 1.000
(0-6)
1.000
Total Participate Matter •
CAS Number
7429-90-5
7704-34-9
7782-50-5
7440-09-7
TOTALS:
Nun Sym
13
16 .
17
19
Al
S
Cl
<
0
0
0
0
2
0-2.5 urn
Xwt
.161
.596
.380
.865
.002
uncCU
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.000
0.000
0.000
0.000
0.000
unc<1>
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.161
0.596
0.380
0.865
2.002
uncCO
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured<2>
Xwt
0.161
0.596
0.380
0.865
2.002
unc{1>
0.000
0.000
0.000
0.000
<1> Uncertainty not evaluated.
C2> Only data in the 0 - 2.5 urn range was measured.
211
-------
3.13 MOBILE SOURCES
Because of their widespread use, the internal combustion gasoline and
diesel powered engines in mobile applications are major sources of PM
emissions. Automotive PM emissions typically consist of exhaust emissions
that occur from the tailpipe. Particulate emissions, however, can also be
generated from brake and tire wear.
213
-------
PM Profile Special ion Report
Profile Name Light Duty Vehicles - Leaded
Profile Number 31103
Data Quality C
Control Device Mot Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 035, 036, 037, 038
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.580
Total Particulate Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
. 7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apec i c»
Nun Sym
13
14
15
16
17
19
20
22
25
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
y
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb .
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2
Xwt
0
0
0
0
0
•o
0
0
0
0
0
0
0
0
0
.642
.786
.167
.000
.262
.051
.092
.004
.002
.001
.987
.111
.012
.026
.148
0.031
0
0
6
0
0
0
0
0
0
0
0
0
0
0
0
0
0
21
.009
.000
.183
.005
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.002
.649
.5 urn
unc
0.642
0.460
0.180
1.208
0.262
0.025
0.029
0.002
0.002
0.002
0.612
0.045
0.005
0.006
0.040
0.041
0.698
0.006
2.113
0.046
0.005
0.041
0.022
0.011
0.012
0.015
0.020
0.024
0.029
0.064
0.120
0.220
0.005
7.650
2.5-10 urn
Xwt
0.342
0.282
0.122
0.000
0.000
0.013
0.295
0.017
0.004
0.033
1.205
0.849
0.026
0.039
0.392
0.005
0.000
0.007
6.147
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
30.631
unc
0.699
0.201
0.122
2.164
0.336
0.024
0.151
0.021
0.008
0.011
0.304
0.230
0.007
0.008
0.085
0.075
1.262
0.011
2.212
0.087
0.008
0.083
0.028
0.010
0.023
0.014
0.046
0.022
0.040
0.055
0.103
0.190
0.008
6.884
0-10 urn
Xwt
0.599
0.720
0.168
0.000
0.238
0.045
0.107
0.004
0.002
0.006
0.956
0.198
0.013
0.028
0.181
0.024
0.009
0.003
6.021
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
23.122
unc
0.744
0.375
0.165
2.004
0.338
0.028
0.134
0.019
0.008
0.014
0.520
0.211
0.012
0.014
0.090
0.069
1.166
0.011
2.496
0.080
0.007
0.076
0.028
0.011
0.021
0.015
0.041
0.025
0.039
0.065
0.120
0.222
0.010
3.463
(0-10)
0.640
Total
Measured^}
Xwt
0.599
0.720
0.168
0.000
0.238
0.045
0.107
0.004
0.002
0.006
0.956
0.198
0.013
0.028
0.181
0.024
0.009
0.003
6.021
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
23.122
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
215
-------
PM Profile Speciat ion Report - continued (profile 31103)
Total Particulate Matter -
Total
0-2.5 urn 2.S-10 urn 0-10 urn MeasuredO}
Species -- -
CAS Number Hunt Sym Xut unc Xwt unc Xwt unc Xwt unc
201 OC 31.374 19.838 3.768 3.309 28.900 14.563 28.900 0.000
202 EC 15.053 2.434 7.220 5.538 12.736 5.198 12.736 0.000
TOTALS: 77.597 51.411 74.088 74.088
S3S3S533333333333333385S33233333333333333S333333335S8333S3333333333Z33333333233S::Z23S!
O> Estimated / extrapolated.
216
-------
PM Profile Spec fat ion Report
Profile Name Light Duty Vehicles - Leaded
Profile Number 31104
Data Quality C
Control Device Not Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 035, 036, 037, 038
Mass Fraction Data - Size Interval (un) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.580
Total Participate
Matter
<0-10)
0.640
Total
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apec i ea
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
p
s
Cl
1C
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
9a
La
Hg
Pb
0
1
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0-2
Xut
.670
.588
.435
.022
.051
.133
.102
.003
.004
.001
.345
.020
.014
.031
.109
.038
0.182
0
10
0
0
0
0
0
0
0
0
0
.000
.365
.000
.000
.001
.000
.000
.000
.000
.000
.000
0.000
0
0
0
0
17
.000
.000
.000
.001
.992
.5 um
unc
1.146
0.641
0.135
0.908
0.155
0.057
0.058
0.009
0.007
0.007
0.878
0.025
0.007
0.009
0.015
0.032
0.505
0.008
1.186
0.068
0.013
0.035
0.072
0.042
0.044
0.058
0.076
O.OV4
0.115
0.253
0.476
0.368
0.010
1.386
2.5-10 um
Xwt
0.693
0.199
0.070
0.000
0.058
0.028
0.149
0.008
0.007
0.034
0.303
0.065
0.020
0.011
0.084
0.005
0.000
0.005
1.429
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
3.706
unc
1.172
0.191
0.165
1.439
0.234
0.023
0.175
0.061
0.025
0.020
0.189
0.064
0.018
0.011
0.078
0.050
0.329
0.009
1.187
0.088
0.010
0.051
0.048
0.028
0.028
0.037
0.048
0.060
0.073
0.160
0.302
0.548
0.017
2.979
0-10 um
%ut
0.492
1.335
0.374
0.016
0.062
0.112
0.103
0.003
0.004
0.007
1.169
0.023
0.014
0.027
0.098
0.031
0.133
0.001
8.445
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
15.056
unc
1.274
0.504
0.174
1.365
0.225
0.047
0.154
0.052
0.022
0.020
0.653
0.059
0.018
0.013
0.070
0.048
0.780
0.010
1.663
0.087
0.012
0.050
0.065
0.038
0.039
0.051
0.067
0.083
0.101
0.223
0.420
0.764
0.017
3.358
Measured^!}
Xut
0.492
1.335
0.374
0.016
0.062
0.112
0.103
0.003
0.004
0.007
1.169
0.023
0.014
0.027
0.098
0.031
0.133
0.001
8.445
0.000
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
15.056
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
217
-------
PM Profile Speciation Report • continued (profile 31104)
Total Paniculate Matter -
Total
0-2.5 um 2.5-10 urn 0-10 un MeasuredO)
Species
CAS Number Hum Sym Xwt unc Xut unc Xwt unc Xwt unc
201 OC 51.847 4.424 13.791 12.363 48.988 12.029 48.988 0.000
202 EC 1.322 1.030 1.429 2.259 1.297 2.036 1.297 0.000
TOTALS: 86.276 22.110 77.794 77.794
C1> Estimated / extrapolated.
218
-------
PM Profile Speciat ion Report
Profile Name Light Duty Vehicles - leaded Composite
Profile Number 31105
Data Quality C
Control Device Not Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 31103 and 31104.
SCC Assignments 035, 036, 037, 038
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.450 0.580
Total Participate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
201
202
Svm
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Hi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
0
t
0
0
0
0
0
0
0
0
1
0
0
0
0
0
0
0
8
0
0
0
0
0
0
0
0
0
0
0
0
0
0
19
41
8
81
0-2.5 urn
Xut
.656
.187
.301
.011
.157
.092
.097
.004
.003
.001
.166
.066
.013
.029
.129
.035
.096
.000
.274
.003
.000
.001
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.002
.321
.611
.188
.943
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
Xwt
0.518
0.241
0.096
0.000
0.029
0.021
0.222
0.013
0.006
0.034
0.754
0.457
0.023
0.025
0.238
0.005
0.000
0.006
3.788
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
17.169
8.780
4.325
36.765
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xut
0.546
1.028
0.271
0.008
0.150
0.079
0.105
0.004
0.003
0.007
1.063
0.111
0.014
0.028
0.140
0.028
0.071
0.002
7.233
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
19.089
38.944
7.017
75.948
unc<1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O.QOO
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.640
Total
Measured
Xwt
0.546
1.028
0.271
0.008
0.150
0.079
0.105
0.004
0.003
0.007
1.063
0.111
0.014
0.028
0.140
0.028
0.071
0.002
7.233
0.003
0.000
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.003
19.089
38.944
7.017
75.948
unc{1 >
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
{13 Uncertainty not evaluated.
219
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
Light Duty Vehicles - Unleaded
31202
Control Device Mot Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCO Assignments: 027, 028, 029, 030
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Participate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Qpci» 1 C9
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
AS
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2.5 urn
Xut
0
3
0
3
0
Q
0
0
0
0
0
.699
.427
.441
.255
.066
.011
.526
.004
.022
.005
.004
0.421
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.031
.592
.001
.000
.000
.249
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.364
unc
0.281
1.755
0.164
2.025
0.034
0.008
0.141
0.002
0.011
0.004
0.003
0.124
0.000
0.024
0.263
0.001
0.000
0.000
0.114
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.138
<0-2.5)
0.890
2.5-10 urn
Xwt
1.129
0.856
0.305
0.534
0.068
0.037
0.44.8
0.019
0.006
0.037
0.053
1.178
0.020
0.028
0.485
0.002
0.000
0.007
0.109
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
1.139
unc
0.375
0.350
0.088
0.223
0.031
0.011
0.137
0.006
0.003
0.009
0.013
0.309
0.005
0.007
0.149
0.003
0.035
0.003
0.040
0.004
0.004
0.005
0.021
0.013
0.013
0.017
0.022
6.029
0.035
0.077
0.143
0.262
0.003
0.354
(0-6)
0.930
0-10 urn
Xwt
0.815
2.793
0.373
2.830
0.071
0.020
0.479
0.007
0.017
0.013
0.016
0.583
0.005
0.026
0.509
0.001
0.000
0.002
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
'0.000
0.000
0.000
0.000
0.000
0.002
0.558
unc
0.473
1.708
0.191
1.919
0.050
0.022
0.210
0.014
0.013
0.020
0.025
0.353
0.014
0.028
0.300
0.005
0.033
0.008
0.120
0.003
0.004
0.005
0.020
0.012
0.013
0.017
0.021
0.027
0.033
0.073
0.136
0.251
0.007
0.391
(0-10)
0.970
Total
Measuredd}
Xut
0.315
2.793
0.373
2.830
0.071
0.020
0.479
0.007
0.017
0.013
0.016
0.583
0.005
0.026
0.509
0.001
O.QOO
0.002
0.200
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.558
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
220
-------
PM Profile Speciat ion Report - continued (profile 31202)
Total Particulate Hatter -
Total
0-2.5 cm 2.5-10 urn 0-10 urn Measured^}
Species - - -
CAS Number Num Sym Xwt unc Xwt unc Xwt unc %wt unc
201 OC 49.202 9.893 22.208 8.891 41.331 14.143 41.331 0.000
202 EC 38.630 8.106 4.993 3.133 30.076 9.471 30.076 0.000
TOTALS: 97.951 33.666 80.727 80.727
O> Estimated / extrapolated.
221
-------
PM Profile Special ion Report
Profile Name Light Duty Vehicles - Unleaded
Profile Number 31203
Data Quality C
Control Device Not Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 027, 028, 029, 030
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.890 0.930
Total Particulate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P.
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Sa
La
-
0-2
%wt
0.
154
6.237
0.
5.
0.
0.
0.
0.
0.
0.
041
393
050
024
348
005
003
000
0.000
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
006
115
007
000
000
409
000
000
000
000
000
000
000
0.000
0.
0.
0.
0.
000
000
000
000
0.000
Hg 0.000
Pb
0.
000
.5 urn
unc
0.131
3.971
0.036
2.732
0.105
0.045
0.232
0.017
0.013
0.013
0.017
0.037
0.014
0.016
0.049
0.013
0.036
0.013
0.313
0.021
0.026
0.032
0.143
0.087
0.089
0.117
0.153
0.192
0.233
0.517
0.968
1.763
0.016
0.056
2.5-10 urn
Xut
0.129
1.555
0.074
0.694
0.068
0.018
0.132
0.007
0.007
0.017
0.014
0.057
0.004
0.003
0.125
0.001
0.000
0.007
0.032
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.004
0.130
unc
0.071
0.804
0.052
0.554
0.041
0.012
0.056
0.027
0.011
0.008
0.007
0.024
0.003
0.004
0.059
0.002
0.009
0.004
0.014
0.005
0.006
0.007
0.034
0.020
0.021
0.027
0.036
0.045
0.054
0.134
0.225
0.408
0.005
0.049
0-10 urn
Xut
0.158
4.618
0.053
4.346
0.057
0.022
0.245
0.006
0.004
0.006
0.005
0.017
0.001
0.005
0.113
0.004
0.000
0.002
0.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.041
unc
0.144
3.815
0.065
2.658
0.107
0.045
0.227
0.031
0.018
0.018
0.020
0.046
0.015
0.016
0.082
0.012
0.034
0.015
0.293
0.020
0.024
0.030
0.135
0.082
0.084
0.110
0.144
0.182
0.220
0.492
0.914
1.664
0.017
0.077
(0-10)
0.970
Total
Measured<;i>
Xwt
0.158
4.618
0.053
4.346
0.057
0.022
0.245
0.006
0.004
0.006
0.005
0.017
0.001
0.005
0.113
0.004
0.000
0.002
0.285
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.041
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
222
-------
PM Profile Speciation Report - continued (profile 31203)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 un 0-10 urn MeasuredOJ
Species — --
CAS Number Num Sym Xut unc Xwt unc Xwt unc Xwt unc
201 OC 92.907 51.738 29.259 25.589 66.193 54.837 66.193 0.000
202 EC 4.833 6.801 0.000 6.483 2.762 8.826 2.762 0.000
TOTALS: 110.532 32.337 78.945 78.945
C1> Estimated / extrapolated.
223
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Light Duty Vehicles - Diesel
32102
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 111
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xut
0.007
0.202
0.026
0.589
0.025
0.005
0.021
0.000
0.000
0.000
0.000
0.016
0.000
0.001
0.047
0.000
0.002
0.000
. -.'0.005
0.000
' 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
.5
urn
unc
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
004
177
015
168
014
002
014
000
000
000
000
006
000
000
027
000
001
000
001
000
0.000
0.
0.
0.
0.
000
002
001
001
0.002
0.
0.
0.
0.
0.
0.
0.
0.
002
003
003
007
013
025
000
013
(0-2.5)
0.920
2.5-10 un
Swt
0.224
0.444
0.191
1.002
0.176
0.037
0.071
0.014
0.006
0.015
0.021
0.381
0.008
0.008
0.118
0.000
0.000
0.008
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.143
unc
0.101
0.106
0.064
0.270
0.018
0.016
0.023
0.023
0.009
0.007
0.005
0.130
0.003
0.002
0.068
0.001
0.006
0.003
0.008
0.003
0.003
0.004
0.018
0.012
0.011
0.014
0.019
0.024
0.029
0.064
0.121
0.222
0.002
0.041
(0-6)
0.960
0-10 un
Xwt
0.023
0.217
0.038
0.617
0.034
0.007
0.025
0.001
0.001
0.001
0.002
0.035
0.001
0.002
0.053
0.000
0.001
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
unc
0.109
0.207
0.077
0.337
0.047
0.024
0.036
0.025
0.011
0.013
0.014
0.142
0.009
0.009
0.078
0.002
0.006
0.009
0.014
0.003
0.003
0.004
0.017
0.011
0.011
0.014
0.018
0.023
0.028
0.061
0.116
0.214
0.005
0.055
(0-10)
1.000
Total
MeasuredCl}
Xwt
0.023
0.217
0.038
0.617
0.034
0.007
0.025
0.001
0.001
0.001
0.002
0.035
0.001
0.002
0.053
0.000
0.001
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
224
-------
PM Profile Speciation Report • continued (profile 32102)
Total Participate
Matter
CAS Number
spec i es
Nun Sym
201
202
OC
EC
Total
0-2.5 urn
Xwt
23.635
65.862
unc
5.490
12.971
2.5-10 urn
Xwt
38.903
74.030
unc
3.484
6.857
0-10 urn
Xwt
24.994
67.384
unc
7.
17.
699
496
MeasuredO)
Xwt
.24.994
67.384
unc
0.000
0.000
TOTALS: 90.459 115.819 93.468 93.468
3asss==s=ss======s==5==s=asssas=============s=sssss3:s
<1> Estimated / extrapolated.
225
-------
PH Profile Speciation Report
Profile Name
Profile Number
Data Quality
Light Duty Vehicles
32103
C
Diesel
Control Device
Reference(s)
Data Source
Hot Applicable
1
Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 111
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter •
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440:17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
a^Jd. 1 C»
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2.5 urn
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.009
.053
.026
.620
.035
.013
.023
.000
.000
.000
.000
.002
.000
.002
.037
.000
.002
.000
.002
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.025
unc
0.007
0.028
0.008
0.239
0.012
0.008
0.014
0.001
0.001
0.001
0.001
0.002
0.001
0.001
0.011
0.001
0.002
0.001
0.001
0.001
0.001
0.002
0.008
0.005
0.005
0.006
0.008
0.010
0.012
0.027
0.051
0.094
0.001
0.017
: (0-2.5)
: 0.920
2.5-10 urn
Xut
0.474
0.780
0.229
0.484
0.427
0.099
0.103
0.034
0.015
0.037
0.051
0.181
0.016
0.028
0.061
0.005
0.000
0.026
0.059
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.010
0.311
unc
0.248
0.236
0.122
0.187
0.166
0.040
0.037
0.069
0.028
0.009
0.019
0.079
0.008
0.012
0.019
0.006
0.019
0.008
0.019
0.010
0.013
0.016
0.071
0.045
0.045
0.058
0.078
0.097
0.116
0.260
0.489
0.906
0.008
0.092
(0-6)
0.960
0-10 urn
Xwt
0.040
0.099
0.040
0.612
0.060
0.018
0.028
0.003
0.001
0.002
0.003
0.011
0.001
0.004
0.039
0.001
0.002
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.042
unc
0.250
0.253
0.127
0.305
0.175
0.049
0.049
0.068
0.029
0.020
0.028
0.087
0.014
0.019
0.031
0.008
0.019
0.017
0.029
0.010
0.013
0.015,
0.069
0.044
0.043
0.056
0.075
0.093
0.112
0.250
0.471
0.873
0.012
0.107
(0-10)
1.000
Total
MeasuredC1>
Xut
0.040
0.099
0.040
0.612
0.060
0.018
0.028
0.003
0.001
0.002
0.003
0.011
0.001
0.004
0.039
0.001
0.002
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.042
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0..000
0.000
0.000
0.000
0.000
0.000
0.000
o.coo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
226
-------
PM Profile Speciation Report - continued (profile 32103)
Total Paniculate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured^}
Species -
CAS Number Nun Sym Xwt unc Xut unc Xut unc Xwt unc
201 OC 43.358 2.103 102.175 36.083 47.468 36.367 47.468 0.000
202 EC 62.746 7.051 26.851 8.747 60.160 13.617 60.160 0.000
TOTALS: 106.953 132.456 108.642 108.642
O> Estimated / extrapolated.
227
-------
PM Profile Speciation Report
Profile Name Light Duty Vehicles - Diesel Composite
Profile Number 32104
Data Quality C
Control Device Not Applicable
Refer ence(s)
Data Source Profile represents a composite of Profiles 32102 and 32103.
SCC Assignments 111
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.920 0.960
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
^pcv tea
Nun Sytn
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
32
201
202
Al
Si
P
s
ct
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
0-2
.5 urn
Xwt unc{1>
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.008
.128
.026
.605
.030
.009
.022
.000
.000
.000
.000
.009
.000
.002
.042
.000
.002
.000
0.004
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.021
33
64
.497
.304
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 um
%wt
0.349
0.612
0.210
0.743
0.302
0.068
0.087
0.024
0.011
0.026
0.036
0.281
0.012
0.018
0.090
0.003
0.000
0.017
0.038
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.006
0.227
70.539
50.441
unct1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 um
Xwt
0.032
0.158
0.039
0.615
0.047
0.013
0.027
0.002
0.006
0.002
0.003
0.023
0.001
0.003
0.046
0.001
0.002
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.034
36.231
63.772
uncd>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured
Xut
0.032
0.158
0.039
0.615
0.047
0.013
0.027
0.002
0.006
0.002
0.003
0.023
0.001
0.003
0.046
0.001
0.002
0.002
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.034
36.231
63.772
uncCI}
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
. 0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
98.709
124.140
101.066
101.066
<1> Uncertainty not evaluated.
228
-------
PH Profile Special ion Report
Profile Name
Profile Number
Data Quality
Heavy Duty Vehicles - Diesel
32203
C
Control Device Not Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Paniculate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
spec i es
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
AS
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
in
Sn
Sb
8a
La
Hg
Pb
0-2
Xut
0.
0.
0.
0.
0.
0.
0.
0.
0'.
0.
0.
0.
0.
0.
003
018
042
343
016
000
048
002
002
000
000
000
002
001
0.053
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000
000
000
000
000
000
000
000
000
000
009
000
000
000
000
0.000
0.
0.
0.
000
000
000
.5 urn
unc
0.026
0.018
0.009
0.055
0.022
0.010
0.008
0.004
0.003
0.003
0.003
0.008
0.003
0.003
0.017
0.002
0.008
0.003
0.003
0.004
0.005
0.007
0.030
0.018
0.018
0.025
0.032
0.040
0.048
0.109
0.202
0.368
0.003
0.011
: (0-2.5)
: 0.920
2.5-10 urn
Xut
1.909
1.417
0.464
0.650
0.622
0.251
0.322
0.061
0.017
0.152
0.112
0.274
0.030
0.059
0.112
0.000
0.000
0.066
0.135
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.023
0.883
unc
1.598
1.253
0.394
0.782
0.632
0.217
0.246
0.630
0.248
0.129
0.086
0.282
0.032
0.065
0.109
0.017
0.066
0.051
0.100
0.037
0.048
0.136
0.254
0.166
0.157
0.209
0.278
0.342
0.416
0.933
1.760
3.205
0.033
0.632
(0-6)
0.960
0-10 urn
Xut
0.137
0.110
0.071
0.347
0.051
0.018
0.069
0.009
0.004
0.011
0.011
0.015
0.004
0.004
0.055
0.000
0.000
0.006
0.012
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.081
unc
1.548
1.214
0.386
0.759
0.614
0.214
0.243
0.605
0.238
0.130
0.089
0.276
0.035
0.067
0.111
0.016
.0.064
0.055
0.103
0.035
0.046
0.131
0.245
0.160
0.151
0.201
0.269
0.330
0.401
0.900
1.698
3.093
0.035
0.617
(0-10)
1.000
Total
MeasuredO}
Xut
0.137
0.110
0.071
0.347
0.051
0.018
0.069
0.009
0.004
0.011
0.011
0.015
0.004
0.004
0.055
0.000
0.000
0.006
0.012
0.000
0.000
0.000"
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.081
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
229
-------
PM Profile Speciation Report - continued (profile 32203)
Total Paniculate Matter -
Total
0-2.5 urn 2.S-10 urn 0-10 urn Measured^}
Species --
CAS Number Hum Sym Xwt unc Xwt unc Xwt unc %wt unc
201 OC 36.046 3.406 67.980 71.384 37.330 68.989 37.830 0.000
202 EC 52.058 4.644 15.840 20.203 50.035 21.021 50.035 0.000
TOTALS: 88.643 91.379 88.890 88.890
33333333333333355Z233S3333Z33S33333322332333
O> Estimated / extrapolated.
230
-------
PM Profile Speciation Report
Heavy Duty Vehicles - Diesel
Profile Name
Profile Number
Data Quality
32204
C
Control Device Not Applicable
Reference(s) 1
Data Source Vehicle exhaust gases sampled with a dilution sampler and
constant volume sampling system. Analyzed using XRF and
flame ionization.
SCC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apc:w I tss
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
s
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
A9
Cd
In
Sn
Sb
3a
La
Hg
Pb
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.065
.191
.059
.349
.022
.000
.033
.000
.000
.000
.000
.001
.000
.005
0.045
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.5 urn
unc
0.033
0.031
0.009
0.027
0.009
O.D03
0.006
0.001
0.001
0.001
0.001
0.002
0.001
0.002
0.002
0.001
0.002
0.001
0.001
0.001
0.002
0.002
0.009
0.006
0.006
0.007
0.010
0.012
0.015
0.032
0.060
0.111
0.001
0.004
i (0-2.5)
: 0.920
2.5-
Xut
1.653
1.840
0.467
0.167
0.585
0.243
0.307
0.106
0.060
0.052
0.094
0.378
0.026
0.049
0.151
0.002
0.000
0.060
0.146
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.053
0.361
10 urn
unc
0.897
1.013
0.329
0.365
0.429
0.178
0.155
0.061
0.039
0.044
0.051
0.254
0.023
0.041
0.088
0.012
0.053
0.038
0.093
0.027
0.032
0.041
0.183
0.119
0.115
0.152
0.193
0.256
0.297
0.659
1.237
2.313
0.032
0.474
(0-6)
0.960
0-10 urn
Xut
0.117
0.245
0.071
0.342
0.039
0.007
0.042
0.004
0.002
0.002
0.003
0.012
0.001
0.006
0.048
0.000
0.000
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.028
unc
0.882
0.995
0.325
0.356
0.421
0.178
0.160
0.066
0.044
0.047
0.057
0.253
0.027
0.045
0.093
0.012
0.051
0.043
0.097
0.026
0.031
0.039
0.176
0.114
0.110
0.146
0.185
0.246
0.285
0.633
1.188
2.221
0.038
0.469
(0-10)
1.000
Total
MeasuredO}
%wt
0.117
0.245
0.071
0.342
0.039
0.007
0.042
0.004
0.002
0.002
0.003
0.012
0.001
0.006
0.048
0.000
0.000
0.002
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.028
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.coo
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 0.770
=s=s==ss=s=sss=sss=ss3ssssss==sss==
<1> Estimated / extrapolated.
7.300
0.978
0.978
231
-------
PM Profile Speeiation Report
Profile Name
Profile Number
Data Quality
Diesel Vehicles - Las Vegas Valley (1987)
32205
E
Control Device Not Applicable
Reference(s) 20
Data Source Samples collected with two dichotomous samplers. Analyzed
using Sequential thermal oxidation and XRF.
SCC Assignments: 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
(0-2.5)
0.920
(0-6)
0.960
(0-10)
1.000
Total Paniculate Hatter -
Total
0-2.5 un 2.5-10 umO) 0-10 unK1> Measured(1>
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
spet
Num
13
14
16
17
19
82
200
:ies
Sym
Al
Si
S
Cl
K
Pb
TC .
0
1
0
0
0
0
44
Xwt
.370
.030
.620
.000
.160
.210
.000
unc
0.040
0.100
0.060
0.000
0.030
0.020
4.400
Xut
0.370
1.030
0.620
0.000
0.160
0.210
44.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.370
1.030
0.620
0.000
0.160
0.210
44.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Xwt
0.370
1.030
0.620
0.000
0.160
0.210
44.000
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 46.390
<1> Estimated / extrapolated.
46.390
46.390
46.390
232
-------
PM Profile Sped at ion Report
Profile Name Heavy Duty Vehicles - Diesel Composite
Profile Number 32206
Data Quality
Control Device Not Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 32203 and 32204.
SCC Assignments 040, 041, 042, 043
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.920 0.960
Total Particulars Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
202
Sym
Al
Si
P
S
Cl
<
Ca
Ti
V
Cr
Mn
Fe'
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
OC
EC
0-2
Xwt
0.034
0.105
0.051
0.346
0.019
0.000
0.041
0.001
0.001
0.000
0.000
0.001
0.001
0.003
0.049
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
36.046
52.058
88.761
.5 urn
uncO)
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 un
Xwt
1.781
1.629
0.466
0.409
0.604
0.247
0.315
0.084
0.039
0.102
0.103
0.326
0.028
0.054
0.132
0.001
0.000
0.063
0.141
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.038
0.872
67.980
15.840
91.254
uncO>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.127
0.178
0.071
0.345
0.045
0.013
0.056
0.007
0.003
0.007
0.007
0.014
0.003
0.005
0.052
0.000
0.000
0.004
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.055
37.830
50.035
88.868
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
o.obo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
1.000
Total
Measured
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
37.
50.
88.
127
178
071
345
045
013
056
007
003
007
007
014
003
005
052
000
000
004
009
000
000
000
000
000
000
004
000
000
000
000
000
000
002
055
330
035
872
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
C1> Uncertainty not evaluated.
233
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33004
C
Control Device Not Applicable
Reference(s) 1
Data Source Developed using steady state vehicle exhaust profiles and
AP-42 tire wear factors, relative to vehicle miles traveled
in the Sepulveda Tunnel (Los Angeles).
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Particulate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92- 1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0
0
0
1
0
0
0
0
0
0
.076
.645
.124
.364
.535
.005
.056
.006
.001
.000
0.018
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.001
.000
.003
.385
.001
.003
.000
.174
.000
.003
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.000
.000
.245
.5 urn
unc
0.039
0.924
0.103
0.926
0.473
0.006
0.053
0.004
0.001
0.001
0.016
0.003
0.001
0.002
0.221
3.002
0.008
0.001
0.106
0.002
0.004
0.003
0.013
0.008
0.008
0.010
0.013
0.017
0.020
0.045
0.085
0.155
0.001
0.149
(0-2.5)
0.690
2.5-10 urn
Xwt
0.179
0.219
0.255
1.796
1.367
0.017
0.046
0.021
0.004
0.005
0.009
0.027
0.002
0.004
0.913
0.000
0.000
0.004
0.022
0.000
0.009
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.000
0.004
0.088
unc
0.123
0.166
0.315 '
1.875
1.601
0.017
0.030
0.017
0.004
0.004
0.007
0.025
0.002
0.004
0.908
0.001
0.007
0.004
0.017
0.002
0.012
0.003
0.011
0.007
0.007
0.009
0.011
0.015
0.017
0.038
0.072
O.t34
0.004
0.065
(0-6)
0.770
0-10
Xwt
0.092
0.577
0.145
1.432
0.667
0,007
0.054
0.008
0.001
0.001
0.017
0.005
0.000
0.003
0.469
0.001
0.003
0.001
0.150
0.000
0.004
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.220
(0-10)
0.820
Total
untO} Measured
unc
0.123
0.797
0.305
1.904
1.530
0.019
0.055
0.019
0.006
0.007
0.017
0.026
0.004
0.006
0.361
0.002
0.009
0.006
0.094
0.002
0.014
0.004
0.015
0.009
0.009
0.012
0.015
0.020
0.023
0.051
0.097
0.179
0.006
0.144
Xwt
0.095
0.451
0.159
1.459
0.765
0.007
0.047
0.010
0.001
0.001
0.016
0.007
0.001
0.003
0.532
0.001
0.002
0.001
0.122
0.000
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.001
0.000
0.001
0.195
unc
0.043
0.585
0.153
0.956
0.724
0.004
0.032
0.006
0.001
0.001
0.014
0.004
0.001
0.002
0.360
0.001
0.005
0.001
0.080
0.001
0.005
0.002
0.007
0.004
0.004
0.005
0.007
0.009
0.011
0.024
0.045
0.082
0.001
0.128
234
-------
PM Profile Speciation Report - continued (profile 33004)
Total Parti cut ate
Matter
CAS Number Nun Sym
201
202
OC
EC
Total
0-2.5 urn
Xut
52.728
45.404
unc
21.578
16.481
2.5-10 urn
Xwt
60.260
27.351
unc
53.967
27.084
0-10
Xut
53.922
42.542
umC1>
unc
53.346
29.056
Measured
Xwt
54.147
39.907
unc
25.247
17.021
TOTALS: 101.778 92.604 100.323 97.936
O> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
235
-------
PM Profile Special ion Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33005
C
Control Device Not Applicable
Referenced) 1
Data Source Developed using steady state vehicle exhaust profiles and no
tire wear factors included, relative to vehicle miles
traveled in the Seoulveda Tunnel (Los Angeles).
SCC Assignments: 110
Mass Fraction Data - Size Interval (un) :
Mass Fraction :
Total Paniculate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Num
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
Sym
Al
Si
p
s
ct
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
8a
La
Hg
Pb
0-2
Xwt
0
0
0
1
0
0
0
.077
.957
.057
.037
.029
.008
.072
0.001
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.001
.000
.028
.001
.000
.005
.053
.002
.004
.000
.264
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
0.000
0
0
.000
.373
.5 urn
unc
0.051
1.391
0.020
1.182
0.020
0.008
0.079
0.003
0.002
0.002
0.024
0.005
0.002
0.003
0.028
0.002
0.012
0.002
0.152
0.003
0.003
0.004
0.019
0.012
0.012
0.016
0.020
0.026
0.031
0.069
0.129
0.236
0.002
0.207
(0-2.5)
0.690
2.5-10 urn
Xut
0.959
1.484
0.288
0.360
0.374
0.140
0.213
0.059
0.034
0.038
0.078
0.233
0.017
0.030
0.125
0.002
0.000
0.036
0.184
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.030
0.749
unc
0.636
1.075
0.211
0.440
0.272
0.110
0.132
0.044
0.026
0.028
0.041
0.165
0.014
0.024
0.088
0.007
0.061
0.025
0.120
0.014
0.016
0.020
0.090
0.058
0.057
0.075
0.095
0.126
0.146
0.325
0.609
1.138
0.022
0.425
(0-6)
0.770
0-10 um{1}
Xut
0.217
1.041
0.094
0.930
0.084
0.029
0.094
0.010
0.006
0.006
0.036
0.038
0.003
0.009
0.064
0.002
0.003
0.006
0.251
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.005
0.433
unc
0.595
1.543
0.200
1.082
0.256
0.106
0.144
0.045
0.028
0.030
0.048
0.157
0.016
0.026
0.089
0.007
0.057
0.027
0.175
0.013
0.015
0.019
0.084
0.054
0.053
0.070
0.089
0.118
0.136
0.304
0.569
1.063
0.024
0.439
(0-10)
0.820
Total
Measured
Xwt
0.116
0.343
0.069
0.940
0.046
0.014
0.069
0.004
0.002
0.002
0.031
0.013
0.001
0.006
0.056
0.001
0.004
0.002
0.242
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.002
0.385
unc
0.054
1.122
0.024
1.058
0.022
0.008
0.058
0.003
0.002
0.002
0.024
0.006
0.001
0.003
0.030
0.002
0.011
0.001
0.134
0.002
0.002
0.003
0.013
0.008
0.008
0.011
0.014
0.018
0.021
0.048
0.089
0.162
0.002
0.206
236
-------
PM Profile Speciation Report - continued (profile 33005)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 utK1> Measured
Species — ...... — ------------ ------------ ............
CAS Number Nun Sym Xyt unc Xut unc Xwt unc Xwt unc
201 OC 49.809 24.151 74.890 39.591 53.785 42.511 50.081 20.949
202 EC 54.153 19.783 17.275 9.531 48.306 19.932 50.878 18.906
TOTALS: 106.931 97.598 105.452 103.807
O) Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
237
-------
PH Profile Speciation Report
Profile Name
Profile Munber
Data Quality
Transportation Composite
33006
C
Control Device Not Applicable
Reference(s) 1
Data Source Developed using Federal test procedure vehicle emission
profiles and California Air Resources Board emission
factors. Tire wear factors are not included.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
2r
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
~
0-2
Xwt
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
6.
332
908
155
799
102
018
150
003
005
001
306
115
004
014
184
010
003
000
958
002
000
000
000
000
000
004
000
000
000
000
000
000
001
760
.5 urn
unc
0.216
0.407
0.069
0.562
0.085
0.010
0.040
0.002
0.003
0.002
0.207
0.036
0.002
0.006
0.062
0.013
0.216
0.002
0.839
0.014
0.003
0.013
0.015
0.009
0.009
0.012
0.016
0.020
0.024
0.053
0.099
0.180
0.002
2.998
: (0-2.5)
: 0.690
2.5-10 urn
Xwt
0.712
0.554
0.207
0.214
0.096
0.049
0.329
0.023
0.006
0.048
0.796
0.842
0.025
0.038
0.373
0.004
0.000
0.014
3.970
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.013
19.942
unc
0.513
0.239
0.101
1.388
0.230
0.033
0.126
0.081
0.032
0.020
0.309
0.251
0.008
0.013
0.107
0.048
0.807
0.010
1.870
0.056
0.008
0.056
0.037
0.022
0.025
0.028
0.046
0.046
0.059
0.125
0.235
0.428
0.007
7.523
(0-6)
0.770
0-10
Xut
0.392
0.852
0.163
0.706
0.101
0.023
0.178
0.006
0.005
0.008
0.384
0.230
0.007
0.018
0.214
0.009
0.003
0.002
2.277
0.002
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.003
8.850
um€1>
unc
0.514
0.427
0.117
1.362
0.224
0.036
0.132
0.075
0.030
0.025
0.348
0.253
0.014
0.020
0.126
0.046
0.762
0.013
1.905
0.053
0.008
0.053
0.036
0.022
0.024
0.028
0.044
0.045
0.058
0.123
0.231
0.421
0.011
7.587
(0-10)
0.820
Total
Measured
Xwt
0.430
0.355
0.163
0.714
0.122
0.028
0.160
0.007
0.005
0.009
0.353
0.192
0.008
0.017
0.188
0.009
0.003
0.004
2.219;-
0.002
0.000
0.000
0.000
0.000
0.000
0.003
0.000
0.000
0.000
0.000
0.000
0.000
0.002
8.495
unc
0.229
0.346
0.054
0.539
0.091
0.010
0.040
0.014
0.006
0.002
0.216
0.051
0.003
0.005
0.052
0.013
0.210
0.002
0.983
0.015
0.003
0.013
0.017
0.010
0.010
0.013
0.019
0.022
0.027
0.060
0.111
0.203
0.002
3.765
238
-------
PH Profile Speciation Report - continued (profile 33006)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 uiK1> Measured
Species
CAS Number Num Sym Xut unc Xwt unc Xut unc Xwt unc
"-•----.--------------------------------*---•-•---•-•---•-------•------•-------••"••-•
201 OC 36.474 8.684 16.456 9.962 33.300 12.560 34.722 9.320
202 EC 38.767 7.216 8.743 4.710 34.007 8.798 33.449 6.554
TOTALS: 87.075 53.454 81.743 82.159
S3S333S3S3S333:33333333S3333333333333X3SS333S3333333S3332333333333S33333333333333S==S3
(1> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
239
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33007
C
Control Device
Referenced)
Data Source
Not Applicable
1
Developed using Federal test procedure vehicle emission
profiles with no tire wear factors included.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Hum
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
201
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
oc
0-2.5 urn
Xwt
0.032
0.093
0.049
0.379
0.026
0.002
0.051
0.002
0.002
0.000
0.035
0.009
0.002
0.002
0.060
0.001
0.000
0.000
0.224
0.000
0.000
0.000
0.000
0.000
0.000
0.008
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.779
34.831
unc
0.045
0.067
0.050
0.400
0.030
0.009
0.055
0.004
0.003
0.003
0.052
0.010
0.003
0.003
0.062
0.003
0.026
0.002
0.305
0.004
0.005
0.006
0.025
0.016
0.016
0.024
0.028
0.035
0.042
0.094
0.174
0.317
0.003
1.069
40.857
: (0-2.5)
: 0.690
2.5-10 urn
Xut
1.431
1.090
0.367
0.536
0.442
0.179
0.301
0.047
0.013
0.113
0.333
0.429
0.027
0.050
0.182
0.001
0.000
0.047
1.390
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.019
7.092
50.978
unc
1.945
1.467
0.475
0.894
0.681
0.257
0.329
0.435
0.171
0.155
0.342
0.380
0.034
0.068
0.160
0.019
0.269
0.065
1.689
0.031
0.033
0.095
0.174
0.114
0.107
0.143
0.191
0.235
0.285
0.640
1.208
2.200
0.030
8.239
75.139
(0-6)
0.770
0-10
Xut
0.254
0.251
0.099
• 0.404
0.092
0.030
0.091
0.009
0.004
0.018
0.082
0.076
0.006
0.010
0.079
0.001
0.000
0.007
0.409
0.000
.0.000
0.000
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.003
1.780
37.391
um<1>
unc
1.791
1.352
0.441
0.891
0.628
0.239
0.309
0.399
0.157
0.145
0.321
0.354
0.034
0.065
0.160
0.018
0.248
0.062
1.578
0.029
0.031
0.087
0.161
0.105
0.099
0.133
0.177
0.218
0.264
0.592
1.118
2.036
0.030
7.638
77.257
(0-10)
0.820
Total
Measured
Xut
0.
0.
0.
155
175
075
0.381
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
058
018
071
008
003
010
054
031
004
005
066
001
001
005
0.293
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
1.
36.
000
000
000
000
000
000
007
000
000
000
000
000
000
002
154
262
unc
0.161
0.142
0.080
0.400
0.068
0.022
0.078
0.032
0.013
0.012
0.066
0.026
0.005
0.006
0.066
0.003
0.028
0.007
0.386
0.005
0.005
0.009
0.029
0.019
0.018
0.026
0.032
0.040
0.048
0.108
0.200
0.367
0.004
1.484
42.168
240
-------
PM Profile Special ion Report - continued (profile 33007)
Total Participate Hatter -
Total
0-2.5 urn 2.5-10 urn 0-10 um<1> Measured
Species ...... — .............. - ----- ...................
CAS Number Hum Sym Xwt unc Xut unc Xwt unc Xwt unc
202 EC 51.911 59.353 18.052 20.450 46.543 53.729 49.703 56.151
TOTALS: 88.498 83.119 87.646 88.542
O> Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
241
-------
PM Profile Special ion Report
Profile Maine
Profile Munber
Data Quality
Transportation Composite
33008
C
Control Device
Reference(s)
Data Source
Not Applicable
1
Developed using Federal test procedure vehicle emission
profiles, AP-42 tire wear factors, and asbestos brake wear
data.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) :
Mass Fraction :
Total Paniculate Matter -
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.035
.192
.053
.417
.065
.002
.068
.002
.002
.001
.035
.046
.002
.002
.087
.001
.000
.000
.216
.000
.001
0.000
0
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.008
.000
.000
.000
.000
.009
.000
.000
0.752
.5 urn
unc
0.043
0.114
0.048
0.384
0.053
0.008
0.057
0.004
0.003
0.003
0.050
0.037
0.003
0.003
0.064
0.003
0.025
0.002
0.290
0.004
0.004
0.006
0.025
0.015
0.015
0.023
0.027
0.033
0.040
0.090
0.168
0.306
0.003
1.018
: (0-2.5)
: 0.690
2.5-10 urn
Xwt
0.949
1.927
0.296
0.844
0.677
0.113
0.411
0.034
0.008
0.083
0.216
0.725
0.017
0.032
0.409
0.001
0.000
0.030
0.880
0.000
0.007
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.105
0.000
0.012
4.488
unc
1.165
1.217
0.295
0.669
0.547
0.154
0.309
0.275
0.108
0.093
0.201
.0.394
0.020
0.041
0.200
0.012
0.170
0.039
0.994
0.020
0.021
0.060
0.110
0.072
0.068
0.091
0.121
0.149
0.180
0.405
0.769
1.392
0.018
4.831
(0-6)
0.770
0-10
Xwt
0.180.
0.467
0.092
0.485
0.162
0.020
0.122
0.007
0.003
0.014
0.064
0.154
0.004
0.007
0.138
0.001
0.000
0.005
0.321
0.000
0.002
0.000
0.000
0.000
0.000
0.007
0.000
0.000
0.000
0.000
0.024
0.000
0.002
1.344
(0-10)
0.820
Total
uiK1> Measured
unc
1.075
1.137
0.278
0.702
0.511
0.144
0.294
0.253
0.099
0.088
0.193
0.374
0.021
0.040
0.201
0.012
0.157
0.038
0.950
0.019
0.021
0.055
0.103
0.067
0.064
0.086
0.113
0.139
0.169
0.379
0.720
1.303
0.019
4.533
Xwt
0.152
0.370
0.082
0.448
0.127
0.017
0.103
0.009
0.003
0.011
0.052
0.105
0.004
0.005
0.114
0.001
0.001
0.005
0.274
0.000
0.001
0.000
0.000
0.000
0.000
0.006
0.000
0.000
0.000
0.000
0.017
0.000
0.002
1.078
unc
0.147
0.225
0.075
0.375
0.100
0.020
0.084
0.030
0.012
0.011
0.060
0.074
0.005
0.005
0.074
0.003
0.026
0.007
0.352
0.004
0.005
0.008
0.028
0.018
0.017
0.024
0.030
0.037
0.045
0.101
0.188
0.343
0.004
1.354
242
-------
PM Profile Speciation Report - continued (profile 33008)
Total Participate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 unC1> Measured
Species
CAS Number Nun Sym Xut unc Xut unc Xwt unc Xut unc
201 OC 35.106 38.883 47.056 46.624 37.001 54.158 36.601 38.463
202 EC 50.83156.450 18.70713.564 45.73849.500 47.78851.121
TOTALS: 87.933 78.027 86.364 87.376
33«3S3333S5333333533S3S535383t383335S:533S3S3S333333SS8333333333333333333SS3!S33333333335
{1} Calculated based on methodology described in the Air Emission Species Manual,
Volume II.
243
-------
PM Profile Spec tat ion Report
Profile Name
Profile Number
Data Quality
Transportation Composite
33009
C
Control Device Not Applicable
Reference(s) 1
Data Source Samples collected through a vent eight feet above roadway in
Seputveda Tunnel (Los Angeles) using Sierra Model 244 manual
dichotomous samplers. Analyzed using XRF and flame
ionization.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
^^Cl. 1 73
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
0-2
Xut
0
0
0
0
0
0
0
0
0
0
0
2
0
0
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.338
.383
.293
.731
.363
.019
.125
.004
.000
.004
.134
.218
.010
.112
.247
.003
.039
.000
.355
.000
.000
.000
.000
.020
.000
.000
.000
.000
.000
.000
.328
.000
.000
.5 urn
unc
0.131
0.225
0.054
0.304
0.324
0.021
0.048
0.011
0.004
0.004
0.017
0.277
0.003
0.014
0.031
0.005
0.082
0.002
0.164
0.011
0.005
0.008
0.026
0.018
0.016
0.021
0.028
0.035
0.042
0.092
0.056
0.318
0.003
: (0-2.5)
: 0.690
2.5-10 urn
Xut
0.816
6.053
0.241
0.092
0.000
0.000
1.327
0.008
0.000
0.018
0.201
11.338
0.056
0.291
0.606
0.003
0.000
0.002
0.269
0.018
0.000
0.000
0.000
0.039
0.000
0.000
0.000
0.000
0.000
0.000
1.077
0.000
0.002
unc
2.154
14.086
0.522
1.643
20.748
0.784
2.719
0.132
0.069
0.047
0.426
23.081
0.111
0.611
1.150
0.012
0.108
0.007
0.634
0.050
0.480
0.015
0.065
0.062
0.037
0.048
0.064
0.080
0.096
0.216
1.905
0.722
0.007
(0-6)
0.770
0-10
Xwt
0.414
1.282
0.285
0.630
0.306
0.016
0.316
0.005
0.000
0.007
0.145
3.664
0.017
0.140
0.304
0.003
0.033
0.000
1.183
0.003
0.000
0.000
0.000
0.023
0.000
0.000
0.000
0.000
0.000
0.000
0.447
0.000
0.000
(0-10)
0.820
Total
um<1> Measured(2)
unc
1.982
12.934
0.484
1.531
19.035
0.720
2.498
0.122
0.063
0.045
0.393
21.198
0.103
0.563
1.058
0.012
0.121
0.008
0.620
0.048
0.441
0.015
0.064
0.061
0.036
0.047
0.063
0.079
0.095
0.212
1.753
0.714
0.008
Xut
0.338
0.383
0.293
0.731
0.363
0.019
0.125
0.004
0.000
0.004
0.134
2.218
0.010
0.112
0.247
0.003
0.039
0.000
1.355
0.000
0.000
0.000
0.000
0.020
0.000
0.000
0.000
0.000
0.000
0.000
0.328
0.000
0.000
unc
0.131
0.225
0.054
0.304
0.324
0.021
0.048
0.011
0.004
0.004
0.017
0.277
0.003
0.014
0.031
0.005
0.082
0.002
0.164
0.011
0.005
0.008
0.026
0.018
0.016
0.021
0.028
0.035
0.042
0.092
0.056
0.318
0.003
244
-------
PM Profile Speciation Report - continued (profile 33009)
Total Participate Hatter -
Total
CAS Number
Spec i es
Nun Sym
0-2.5 un 2.5-10 urn 0-10 um<1> Measured{2>
Xwt unc Xut unc Xut unc Xwt
unc
7439-92-1 82 Pb 2.437 0.298 2.049 3.952 2.375 3.651 2.437 0.298
201 OC 38.586 5.550 39.164 61.704 38.677 57.077 38.586 5.550
202 EC 38.119 4.909 12.656 24.275 34.082 23.124 38.119 4.909
TOTALS: 85.868 76.326 84.357 85.868
333333333333S::333333333S3S3333SS3333333333333333333333S3SSS333:333333333333S33::3=:S=S==
C1> Calculated based on methodology described in the Air Emissions Species Manual,
Volume II.
{2} Estimated / extrapolated.
245
-------
PM Profile Speciation Report
Profile Name
Profile Number
Data Quality
Gasoline Vehicles - Las Vegas Valley (1987)
33010
E
Control Device
Reference(s)
Data Source
Not Applicable
20
Samples collected with two dichotomous samplers. Analyzed
using Sequential thermal oxidation and XRF.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Particulate Matter -
CAS Number
7429-90-5
7440-21-3
7704-34-9
7782-50-5
7440-09-7
7439-92-1
Nun Sym
13
14
16
17
19
32
200
Al
Si
S
-Cl
<
Pb
TC
0-2.5 urn
Xwt
0
0
0
0
0
2
57
.046
.092
.092
.830
.320
.500
.600
unc
0.005
0.009
0.009
0.083
0.032
0.250
10.000
: (0-2.5)
: 0.670
2.5-10
Xwt
0.046
0.092
0.092
0.830
0.320
2.500
57.600
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-6)
0.750
0-10
Xwt
0.046
0.092
0.092
0.830
0.320
2.500
57.600
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
<0-10)
0.800
Total
MeasuredO)
Xwt
0.046
0.092
0.092
0.830
0.320
2.500
57.600
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS: 61.480
{1} Estimated / extrapolated.
61.480
61.480
61.480
246
-------
PM Profile Speciation Report
Profile Name Highway
Profile Number 33011
Data Quality C
Vehicles
Composite
Control Device Not Applicable
Reference(s)
Data Source Profile represents a composite of Profiles 33004, 33005,
33006, 33007, 33008, and 33009.
SCC Assignments: 110
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.690 0.770
Total Participate
Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apec i ca
Mum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
30
82
201
Al
Si
P .
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
8r
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
DC
(0-10)
0.820
Total
0-2.5 urn
Xwt
0.148
0.530
0.122
0.789
0.187
0.009
0.087
0.003
0.002
0.001
0.093
0.398
0.003
0.023
0.169
0.003
0.008
0.000
0.700
0.000
0.001
0.000
0.000
0.003
0.000
0.003
0.000
0.000
0.000
0.000
0.056
0.000
0.002
1.891
41.256
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10 urn
%Mt
0.341
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
.888
.276
.507
.493
.083
.438
.032
.011
.051
.272
.266
.024
.074
.435
.002
.000
.022
.119
.003
.003
.000
.000
0.007
0
0
0
0
0
0
0
0
0
5
48
.000
.000
.000
.000
.000
.000
.197
.000
.013
.721
.134
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10 urn
Xwt
0.258
0.745
0.146
0.765
0.235
0.021
0.143
0.008
0.003
0.009
0.121
0.695
0.006
0.031
0.211
0.003
0.007
0.004
0.765
0.008
0.001
0.000
0.000
0.004
0.000
0.003
0.000
0.000
0.000
0.000
0.079
0.000
0.002
2.500
42.346
unc{1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xwt
0.214
0.513
0.140
0.779
0.247
0.017
0.096
0.007
0.002
0.006
0.107
0.428
0.005
0.025
0.201
0.003
0.008
0.003
0.751
0.001
0.001
0.000
0.000
0.003
0.000
0.003
0.000
0.000
0.000
0.000
0.058
0.000
0.002
2.291
41.733
uncC1>
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
247
-------
PM Profile Speciation Report - continued (profile 33011)
Total Paniculate Matter -
Total
0-2.5 urn 2.5-10 urn 0-10 urn Measured
Species
CAS Number Mum Syra Xwt uncCD Xwt unc{1> Xwt uncC1> Xwt uncd>
202 EC 46.531 0.000 17.131 0.000 41.870 0.000 43.307 0.000
TOTALS: 93.018 78.043 90.989 90.951
=33333333333333SS:3S33S33333S333:E2:SSS3C3353333333333333S3833333333S333333333S333333=3=3
O> Uncertainty not evaluated.
248
-------
PM Profile Speciat ion Report
Profile Name Tire Wear
Profile Number 34003
Data Quality E
Control Device Not Applicable
Reference(s) 1,21,22
Data Source Data taken from Reference 1. For details, consult References
21 and 22.
SCC Assignments: 112
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
.Mass Fraction : 0.390 0.430
Total Particulate
Matter
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-70-2
7440-32-6
7440-62-2
7439-96-5
7440-50-3
7440-66-6
7726-95-6
7440-24-6
7440-39-3
7439-91-0
TOTALS:
ajjm. ics
Num Sym
11
12
13
14
15
16
17
20
22
23
25
29
30
35
38
56
57
201
202
Na
Mg
Al
Si
P
s
Cl
Ca
Ti
V
Mn
Cu
Zn
8r
Sr
Ba
La
OC
EC
(0-10)
0.550
Total
0-2.5
Xut
0
0
0
0
0
1
1
0
0
0
0
0
.054
.039
.074
.050
.250
.989
.500
.024
.016
.000
.000
.000
1.018
0
0
0
0
58
28
92
.001
.010
.002
.000
.300
.700
.027
unKD
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xut
0.054
0.039
0.074
0.050
0.250
1.989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
92.027
um€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
'. '-."
0-10
Xut
0.054
0.039
0.074
0.050
0.250
1.989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
92.027
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
0.054
0.039
0.074
0.050
0.250
1.989
1.500
0.024
0.016
0.000
0.000
0.000
1.018
0.001
0.010
0.002
0.000
58.300
28.700
92.027
unc
0.013
0.008
0.022
0.050
0.250
0.694
1.000
0.008
0.005
0.000
0.000
0.000
0.047
0.000
0.008
0.002
0.000
15.000
10.000
O> Estimated / extrapolated.
249
-------
PM Profile Speciation Report
Profile Name Brake Lining
Profile Number 34004
Data Quality E
, Asbestos
Control Device Not Applicable
Reference(s) 1,21
Data Source Composition of asbestos brake pads analyzed using neutron
activation.
SCC Assignments: 112
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.390 0.480
Total Part icul ate
»_....
CAS Number
7440-23-5
7439-95-4
7429-90-5
7440-21-3
7782-50-5
7440-70-2
7440-22-2
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-48-4
7440-66-6
7440-38-2
7726-95-6
7440-24-6
7440-36-0
7440-39-3
7439-91-0
7440-45-1
TOTALS:
apei
Nun
11
12
13
14
17
20
21
23
24
25
26
27
30
33
35
38
51
56
57
58
Matter
»« ma
;ies
Sym
Ma
Hg
Al
Si
Cl
Ca
Sc
V
Cr
Mn
Fe
Co
Zn
As
Br
Sr
Sb
3a
La
Ce
0-2.5
Xwt
0
13
0
.032
.300
.215
10.800
0
1
0
0
0
0
4
0
0
0
0
0
0
0
0
0
32
.145
.895
.001
.001
.098
.043
.000
.007
.310
.001
.000
.041
.000
.922
.000
.001
.312
unO>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.5-10
Xwt
0.032
13.800
0.215
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
um<1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xwt
0.032
13.800
0.215
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
um€1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
(0-10)
0.550
Total
Measured
Xwt
0.032
13.800
0.215
10.800
0.145
1.895
0.001
0.001
0.098
0.043
4.000
0.007
0.310
0.001
0.000
0.041
0.000
0.922
0.000
0.001
32.312
unc
0.008
0.200
0.055
2.160
0.015
1.705
0.000
0.000
0.022
0.003
1.095
0.002
0.074
0.000
0.000
0.004
0.000
0.474
0.000
0.000
SSSS3SS
<1> Estimated / extrapolated.
250
-------
PM Profile Speciation Report
Profile Name
Profile Hunter
Data Quality
Motor Oil
34005
E
Control Device
Reference(s)
Data Source
Not Applicable
1,23
Data taken from Reference 1. For details, consult Reference
23.
SCC Assignments: 112
Mass Fraction Data - Size
Total Paniculate
Mass
Matter -
Interval (urn) :
Fraction :
(0-2.5X2}
0.
000
<0-6K2>
0.000
(0-10K2J
0
.000
Total
Species
CAS Number
7439-95-4
7704-34-9
7782-50-5
7440-70-2
7439-89-6
7440-66-6
7782-49-2
7726795-6
7440-36-0
7440-39-3
Nun
12
16
17
20
26
30
34
35
51
56
Sym
Mg
S
Cl
Ca
Fe
Zn
Se
Br
Sb
Ba
0-2.5
Xut
0.023
0.430
0.017
0.103
0.000
0.082
0.003
0.000
0.021
0.099
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2
0
0
0
0
0
0
0
0
0
0
.5-10
Xut
.023
.430
.017
.103
.000
.003
.000
.021
.099
.099
uraC1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0-10
Xut
0.023
0.430
0.017
0.103
0.000
0.082
0.003
0.000
0.021
0.099
unK1>
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Measured
Xut
0.023
0.430
0.017
0.103
0.000
0.082
0.003
0.000
0.021
0.099
unc
0.040
0.230
0.024
0.109
0.000
0.073
0.001
0.000
0.021
0.156
TOTALS:
0.778
0.795
0.778
{1> Estimated / extrapolated.
{2} 0.000 indicates the unavailability of mass fraction data for this
0.778
profile.
251
-------
PH Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Semimetal Disk Brake Pads
34006
Control Device Not Applicable
Reference(s) 1
Data Source Sample collected from deposition on wheel of 1986 Acura.
Analyzed using XRF.
SCC Assignments: 112
Mass Fraction Data - Size Interval
Xut unc
Total
2.5-10 unKD 0-10 umd) Measured
Xwt unc Xwt unc Xut unc
7439-89-6
7440-50-8
7439-98-7
7440-31-5
7440-39-3
26
29
42
50
56
Fe
Cu
MO
Sn
Ba
45
2
0
0
3
.900
.260
.370
.660
.450
0.000
0.000
0.000
0.000
0.000
45.900
0.370
0.660
0.660
3.450
0.000
0.000
0.000
0.000
0.000
45.900
2.260
0.370
0.660
3.450
0.000
0.000
0.000
0.000
0.000
45.900
2.260
0.370
0.660
3.450
3.900
0.180
0.050
0.050
0.190
TOTALS: 52.640
333333333333333333333X333333333:333
<1> Estimated / extrapolated.
51.040
52.640
52.640
252
-------
3.14 HEAVY CONSTRUCTION
Heavy construction is a source of dust emissions that may have
substantial temporary impact on local air quality. Building and road
construction are the prevalent construction categories with the highest
emissions potential. Emissions during the construction of a building or road
are associated with land clearing, blasting, ground excavation, cut and fill
operations, and the construction of the particular facility itself. Dust
emissions vary substantially from day to day depending on the level of
activity, the specific operations, and the prevailing weather. A large
portion of the emissions result from equipment traffic over temporary roads at
the construction site.
253
-------
PH Profile Speciation Report
Profile Name Excavation -
Profile Number 44101
Data Quality C
El Segundo.CA
Control Device Not Applicable
Reference(s) 1
Data Source Soil sample from excavation site. Analyzed using XRF.
SCC Assignments 015
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Hass Fraction : 0.020 0.040
Total Participate
Hatter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
apci. i c»
Nun Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Hn
Fe
Ni
Cu
. Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Ho
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
11
24
0
0
.0
1
1
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0-2.5 urn
Xwt
.513
.710
.033
.390
.035
.548
.186
.578
.025
.023
.112
.243
.009
.008
.023
.001
.008
.000
.000
.000
.020
0.000
0
0
0
0
0
0
0
0
0
0
0
0
45
SSS5S3
.000
.000
.000
.000
.000
.000
.000
.040
.000
.000
.000
.011
.476
=====
unc
1.727
3.707
0.007
0.018
0.002
0.077
0.059
0.032
0.008
0.004
0.008
0.267
0.002
0.002
0.003
0.001
0.004
0.001
0.002
0.002
0.003
0.003
0.016
0.009
0.010
0.012
0.017
0.020
0.024
0.055
0.099
0.183
0.002
0.006
========
2.5-10 urn
Xwt
9.749
21.239
0.025
0.108
0.019
1.721
1.359
0.612
0.021
0.020
0.133
5.655
0.008
0.004
0.014
0.000
0.000
0.000
0.004
0.014
0.037
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.016
0.000
0.000
0.000
0.024
40.782
unc
1.462
3.186
0.005
0.005
0.001
0.086
0.068
0.032
0.007
0.002
0.007
0.285
0.001
0.001
0.001
0.002
0.002
0.000
0.001
0.001
0.002
0.001
0.005
0.003
0.003
0.004
0.005
0.006
0.008
0.017
0.032
0.055
0.001
0.002
0-10 urn
Xwt
9.873
21.483
0.025
0.125
0.020
1.709
1.347
0.609
0.022
0.020
0.131
5.626
0.008
0.004
0.015
0.000
0.001
0.000
0.004
0.013
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.024
41.113
unc
0.973
2.108
0.003
0.014
0.002
0.085
0.066
0.032
0.004
0.002
. 0.007
0.282
0.001
0.001
0.002
0.001
0.001
0.000
0.001
0.001
0.002
O.J001
0.005
0.003
0.003
0.004
0.005
0.006
0.007
0.016
0.029
0.053
0.001
0.002
(0-10)
0.080
Total
Measured
Xwt
9.873
21.483
0.025
0.125
0.020
1.709
1.347
0.609
0.022
0.020
0.131
5.626
0.008
0.004
0.015
0.000
0.001
0.000
0.004
0.013
0.036
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.018
0.000
0.000
0.000
0.024
41.113
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
a. ooo
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
O> Estimated / extrapolated.
255
-------
PM Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Excavation - Haul Road
44102
C
Control Device Not Applicable
Reference(s) 1
Data Source Soil sample from haul road at highway construction site.
Analyzed using XRF.
SCC Assignments: 30100103
Mass Fraction Data - Size Interval (urn)
Mass Fraction
Total Participate Matter
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
apve i C9
Num Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
11.041
22.441
0.033
0.250
0.087
1.393
1.371
0.503
0.025
0.015
0.101
5.112
0.004
0.018
0.079
0.000
0.021
0.000
0.000
0.002
0.017
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
.5 urn
unc
1.656
3.366
0.007
0.013
0.004
0.070
0.069
0.029
0.007
0.003
0.007
0.261
0.002
0.003
0.006
0.001
0.004
0.002
0.002
0.003
0.004
0.004
0.018
0.011
0.012
0.014
0.018
0.023
0.027
0.056
0.113
0.202
0.002
0.007
: (0-2.5)
: 0.020
2.5-10 urn
Xwt
10.292
21.196
0.000
0.082
0.021
1.645
1.278
0.551
0.024
0.023
0.126
5.532
0.008
0.006
0.018
0.000
0.000
0.000
0.000
0.013
0.032
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.046
0.025
0.000
0.024
unc
1.544
3.179
0.000
0.004
0.001
0.082
0.064
0.030
0.006
0.002
0.007
0.279
0.001
0.001
0.001
0.003
0.002
0.000
0.000
0.001
0.002
0.001
0.004
0.003
0.002
0.003
0.004
0.005
0.006
0.012
0.024
0.040
0.000
0.002
(0-6)
0.040
0-10 urn
Xwt
10
21
0
0
0
1
1
0
0
0
0
5
0
0
0
0
0
0
0
0
0
0
0
.325
.250
.002
.090
.024
.634
.282
.549
.024
.022
.125
.513
.008
.007
.021
.000
.001
.000
.000
.013
.031
.001
.000
0.000
0
0
0
0
0
0
0
0
0
0
.000
.000
.000
.000
.000
.000
.044
.024
.000
.023
unc
0.993
2.036
0.002
0.010
0.004
0.079
0.069
0.028
0.004
0.002
0.007
0.275
0.001
0.001
0.003
0.002
0.002
0.000
0.001
0.001
0.002
0.001
0.005
0.003
0.003
0.004
0.005
0.006
0.007
0.015
0.031
0.054
0.000
0.002
(0-10)
0.080
Total
Measured<1>
Xwt
10.325
21.250
0.002
0.090
0.024
1.634
1.282
0.549
0.024
0.022
0.125
5.513
0.008
0.007
0.021
0.000
0.001
0.000
0.000
0.013
0.031
0.001
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.044
0.024
0.000
0.023
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
42.513
40.943
41.013
41.013
(1> Estimated / extrapolated.
256
-------
PH Profile Special ion Report
Profile Name Excavation -
Profile Number 44103
Data Quality C
Rock
Crushing
Control Device Not Applicable
Reference(s) 1
Data Source Oust sample collected from rock crushing site. Analyzed
using XRF.
SCC Assignments: 30502001
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.150 0.300
Total Particulate Hatter
Species
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
Nun
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
39
40
42
46
47
48
49
50
51
56
57
80
82
Sym
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Ni
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
*g
Cd
In
Sn
Sb
Ba
La
Hg
Pb
11
34
0
0
0
2
1
0
0
0
0
0-2
Xwt
.539
.003
.000
.028
.014
.715
.509
.359
.032
.004
.119
2.958
0
0
0
0
0
0
0
0
0
- 0
0
0
0
0
0
0
0
0
0
0
0
0
.003
.007
.023
.000
.003
.000
.000
.006
.043
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.003
.5 urn
unc
1.731
5.100
0.000
0.001
0.001
0.136
0.075
0.020
0.005
0.002
0.007
0.151
0.001
0.001
0.002
0.001
0.002
0.001
0.001
0.002
0.003
0.002
0.010
0.006
0.006
0.008
0.012
0.012
0.015
0.034
0.063
0.117
0.001
0.004
2.5-10 urn
%ut
9.681
29.414
0.000
0.000
0.000
2.721
1.732
0.339
0.008
0.007
0.117
2.908
0.003
0.005
0.010
0.000
0.000
0.000
0.000
0.012
0.057
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.027
0.000
0.000
0.014
unc
1.452
4.412
0.000
0.000
0.000
0.136
•0.087
0.022
0.006
0.001
0.006
0.147
0.001
0.001
0.001
0.002
0.001
0.000
0.000
0.001
0.003
0.001
0.005
0.002
0.002
0.003
0.004
0.005
0.006
0.013
0.027
0.043
0.000
0.002
0-10 urn
Xwt
9.357
29.849
0.000
0.003
0.001
2.720
1.711
0.341
0.011
0.006
0.117
2.912
0.003
0.005
0.011
0.000
0.000
0.000
0.000
0.012
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.013
unc
1.093
3.277
0.000
0.001
0.001
0.165
0.100
0.025
0.004
0.002
0.010
0.179
0.001
0.002
0.002
0.001
0.001
0.000
0.000
0.002
0.006
0.001
0.004
0.002
0.002
0.003
0.004
0.005
0.005
0.012
0.024
0.041
0.000
0.003
(0-10)
0.810
Total
Measured {1>
Xwt
9.857
29.849
0.000
0.003
0.001
2.720
1.711
0.341
0.011
0.006
0.117
2.912
0.003
0.005
0.011
0.000
0.000
0.000
0.000
0.012
0.056
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.025
0.000
0.000
0.013
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
TOTALS:
53.368
47.055
47.653
47.653
{1} Estimated / extrapolated.
257
-------
PM Profile Specialion Report
Profile Name Soil Oust - Sandblasting
Profile Number 44104
Data Quality C
& Plastering
Control Device Not Applicable
Reference(s) 1
Data Source Dust sample collected from concrete structure sandblasting,
plastering, and uallboarding site. Analyzed using XRF.
SCC Assignments: 015
Mass Fraction Data - Size Interval (urn) : (0-2.5) (0-6)
Mass Fraction : 0.300 0.620
Total Participate Matter -
CAS Number
7429-90-5
7440-21-3
7723-14-0
7704-34-9
7782-50-5
7440-09-7
7440-70-2
7440-32-6
7440-62-2
7440-47-3
7439-96-5
7439-89-6
7440-02-0
7440-50-8
7440-66-6
7440-55-3
7440-38-2
7782-49-2
7726-95-6
7440-17-7
7440-24-6
7440-65-5
7440-67-7
7439-98-7
7440-05-3
7440-22-4
7440-43-9
7440-74-6
7440-31-5
7440-36-0
7440-39-3
7439-91-0
7439-97-6
7439-92-1
TOTALS:
9\xsi~ i es
Hum Sym
13
14
15
16
17
19
20
22
23
24
25
26
28
29
30
31
33
34
35
37
38
" 39
40
42
46
47
48
49
50
51
56
57
80
82
Al
Si
P
S
Cl
K
Ca
Ti
V
Cr
Mn
Fe
Mi
Cu
Zn
Ga
As
Se
Br
Rb
Sr
Y
Zr
Mo
Pd
Ag
Cd
In
Sn
Sb
Ba
La
Hg
Pb
0-2
Xwt
5
16
0
1
0
1
14
0
0
0
0
2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
42
.553
.443
.031
.982
.022
.288
.350
.245
.013
.022
.051
.325
.004
.007
.181
.000
.006
.000
.000
.000
.028
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.000
.001
.005
.557
.5 un
unc
0.333
2.466
0.006
0.099
0.001
0.064
0-.718
0.014
0.003
0.002
0.004
0.118
0.001
0.001
0.010
0.001
3.002
0.001
0.001
0.001
0.002
0.002
0.008
0.005
0.005
0.007
0.008
0.011
0.013
0.028
0.052
0.092
0.001
0.003
2.5-10 un
Xwt
4.944
14.210
0.000
1.524
0.016
1.353
14.212
0.223
0.005
0.011
0.062
2.377
0.005
0.008
0.131
0.000
0.000
0.000
0.003
0.009
0.043
0.001
0.006
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.015
0.000
0.000
0.015
39.173
unc
0.742
2.132
0.000
0.076
0.001
0.068
0.711
0.013
0.404
0.001
0.003
0.120
0.000
0.001
0.007
0.002
0.001
0.000
0.000
0.001
0.002
0.001
0.003
0.002
0.002
0.002
0.002
0.003
0.004
0.008
0.015
0.025
0.000
0.001
0-10 urn
Xwt
4.984
14.355
0.002
1.554
0.016
1.349
14.221
0.224
0.005
0.012
0.061
2.374
0.004
0.008
0.134
0.000
0.000
0.000
0.003
0.009
0.042
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.000
0.000
0.015
39.392
unc
0.627
1.817
0.003
0.133
0.004
0.100
1.011
0.023
0.003
0.004
0.009
0.173
0.002
0.003
0.016
0.001
0.001
0.000
0.002
0.003
0.007
0.001
0.004
0.002
0.002
0.003
0.003
0.004
0.005
0.011
0.021
0.036
0.000
0.004
(0-10)
0.850
Total
Measuredd)
Xwt
4.984
14.355
0.002
1.554
0.016
1.349
14.221
0.224
0.005
0.012
0.061
2.374
0.004
0.008
0.134
0.000
0.000
0.000
0.003
0.009
0.042
0.001
0.005
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.014
0.000
0.000
0.015
39.392
unc
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
=======
{1} Estimated / extrapolated.
258
-------
3.15 REFERENCES FOR PM PROFILES
1. Cooper, J. A., et. al., NEA, Inc. PM10 Source Composition Library
for the South Coast Air Basin, Volume I and II. Prepared for the
South Coast Air Quality Management District, El Monte, CA.
July 15, 1987.
2. Olmez, I., et. al. Composition of Particles from Selected Sources
in Philadelphia for Receptor Modeling Applications. Journal of
Air Pollution Control Assoc. 38(11):1392-1402 (1988).
3. Gordon, G. E. and A. E. Sheffield, University of Maryland.
University of Maryland Source Library. College Park, MD.
April 27, 1987.
4. Davison, R. L., et. al., Environ. Sc1. Techno!. 13:1107-1113
(1974).
5. Norton, G. A., E. L. Dekalb, and K. L. Malaby,
Environ. Sci. Technol. 20:604-609 (1986)
6. Baker, G., fii. aj.. Emission Characterization of Major Fossil Fuel
Power Plants in the Ohio River Valley. Prepared for the U. S.
Environmental Protection Agency, Office of Research and
Development, Research Triangle Park, NC. 1983.
7. Kaakinen, J. W. Trace Element Study in a Pulverized Coal-Fired
Power Plant. Ph.D Thesis, University of Colorado, Boulder, CO.
8. Kowalczyk, G. S. Emission and Atmospheric Impact of Trace
Elements from a Reconverted Coal-Fired Power Plant. Presented at
the 77th Annual Meeting of the Air Pollution Control Association,
San Francisco, CA. June 24-19, 1984.
9. Markowski, G. R., and R. Filby, Environ. Sci. Technol. 19:796-804
(1985).
10. Klein, D. H., et. al. Environ. Sci. Technol. 9:973-979 (1975).
11. Mamuro, T., A. Mizohata, and T. Kubota. Elemental Compositions of
Suspended Particles Released from Various Boilers. Annual Report
of the Radiation Center of Osaka Prefecture 20. Shinke-cho,
Sakai, Osaka, Japan. 1979.
12. Henry, W. M., and K. T. Knapp, Environ. Sci. Technol. 14:450-456
(1980).
13. Greenberg, R. R., et. al., Environ. Sci. Technol. 12:1329-1332
(1978).
259
-------
14. Houck, J. E., J. A. Cooper, L. C. Pritchett, and T. R. Wasierski.
Revised Participate Source Profiles, East Helena, Montana. Final
Report to ASARCO, Inc. from NEA, Inc., Beaverton, OR.
November 26, 1984.
15. Cooper, J. A., C. A. Frazier, and J. F. Mohan. Harbor Island Lead
Source Apportionment. Final Report to Puget Sound Air Pollution
Control Agency from NEA, Inc., Beaverton, OR. December 28, 1982.
16. Cooper, J. A., fit. aj.. Quantitative Source Apportionment of South
Bay's Particulate Air Quality Using Receptor Modeling Methods.
Final Report to San Diego County Air Pollution Control District
from NEA, Inc., Beaverton, OR. January 30, 1987.
17. Miller, E. A., J. A. Cooper, C. A. Frazier, and L. C. Pritchett.
Cubatao Aerosol Source Apportionment Study. Final Report to
CETESB, Sao Paulo, Brazil, from NEA, Inc., Beaverton, OR.
March 1985.
18. Cooper, J. A., J. E. Houck, L. C. Pritchett, and C. A. Frazier.
Applications of Receptor Modeling Methods to Source Apportionment
of Arsenic in the Ruston-Tacoma, Washington Airshed: A
Feasibility Study. Final Report to Puget Sound Air Pollution
Control Agency from NEA, Inc., Beaverton, OR. June 15, 1985.
19. Cooper, J. A., et. a1_. Receptor Modeling Apportionment of PM10
and Toxic Species in Hayden, Arizona. Final Report to Region IX,
U. S. Environmental Protection Agency, by NEA, Inc.,
Beaverton, OR. March 1987.
20. Benedict, R. and M. Naylor, Clark County, NV, Health District.
Fine Particulate Receptor Modeling in Las Vegas Using Combined
Gaseous and Particulate Source Profiles. Presented at the 81st
Annual Meeting of the Air Pollution Control Association, Dallas,
TX, June 20-24, 1988.
21. Ondov, J. M., W. H. Zoller, and G. E. Gordon,
Environ. Sci. Techno!. 16:318-328 (1981).
22. Cass, G. R., P. M. Boone, and E. S. Macias. Emissions and Air
Quality Relationships for Atmospheric Carbon Particles in Los
Angeles. Particulate Carbon, Atmospheric Life Cycle, edited by
G. T. Wolff and R. K. Klimisch, Plenum Press, NY, 1982.
23. Ondov, J. M. A Study of Trace Elements on Particulations from
Motor Vehicles. Ph.D. Thesis, University of Maryland, 1974.
24. Thompson, C. M. Elemental Composition and Particle Size
Distribution of Mineral Dust: Field and Laboratory Studies.
Ph.D. Thesis, University of Maryland, College Park, MD. 1985.
260
-------
25. Thomas, S. C., Size and Composition of Atmospheric Particles in
Rural Areas Near Washington, DC. Ph.D. Thesis, University of
Maryland, College Park, MD. 1977.
26. Ward, D. E. and C. C. Hardy-, USDA Forest Services. Organic and
Elemental Profiles for Smoke from Prescribed Fires. Presented at
APCA Specialty Conference, San Francisco, CA. February 1988.
27. Rau, J. A. and J. J. Huntzicker, Oregon Graduate Center. Size
Distribution and Chemical Composition of Residential Wood Smoke.
Presented at the 78th Annual Meeting of the Air Pollution Control
Association. Detroit, MI. June 16-21, 1985.
28. DeCesar, R. T. and J. A. Cooper. Medford Aerosol Characterization
Study (MACS). Final Report to Oregon Department of Environmental
Quality from Oregon Graduate Center, Beaverton, OR,
February 3, 1981.
29. Mason, B., Principles of Geochemistry, 3rd Edition. John Wiley
and Sons, Inc., New York, NY, 1966.
30. West, R. C., CRC Handbook of Chemistry and Physics, CRC Press,
Boca Raton, FL, p. F146, 65th Edition, 1984.
31. Cooper, J. A., et. al. Characteristics of Attached Radon-222
Daughters Under Both Laboratory and Field Conditions with
Particular Emphasis Upon Underground Uranium Mine Environments.
Battelle Northwest Laboratories Report BN-SA-299, Richland, WA,
December 1973.
32. Cooper, J. A., C. A. Frazier, and J. E. Houck. Seattle-Tecoma
Aerosol Characterization Study (STAGS). Final Report to Puget
Sound Air Pollution Control Agency from NEA, Inc., Beaverton, OR.
March 1, 1985.
261
-------
SECTION 4
VOC SPECIES PROFILE FORMAT AND APPLICATION
4.1 VOC SPECIES PROFILE FORMAT
Table 4-1 is an example of the format used in presenting the VOC
profiles for this document; it is basically the same as that used in the Air
Emissions Species Manual - Volume I, VOC Species Profiles. Each of the
entries in Table 4-1 is described below:
Profile name: In a majority of the cases, the profile name is the
descriptor used for the applicable source category. In cases where a
particular profile is applicable to more than one source category, a more
general term is used to identify a given profile.
Profile number: This is a unique number assigned arbitrarily to a
profile.
Profile data quality: A ranking scheme is employed to assign data
quality indicators to each profile. The following criteria were used in
assigning data quality indicators:
Data Quality A: Data set based on a composite of several tests
using analytical techniques such as GC/MS and
can be considered representative of the total
population.
Data Quality B: Data set based on a composite of several tests
using analytical techniques such as GC/MS and
can be considered representative of a large
percentage of the total population. Profiles
from the VOC field sampling program are assigned
data quality "B".
263
-------
TABLE 4-1. VOC SAMPLE PROFILE
VOC Profile Speciation Report
Profile Name Oilfield Pipeline Tanks
Profile Number 1209
Data Quality C
Control Device Internal Floating Roofs with Seals
Referenced)
Data Source
33, 34
Four samples
sweet" crude
and analyzed
concentration
'
of emissions from tanks storing
"Oklahoma
oil were taken in stainless steel canisters
using a GC with cryogenic sample pre-
and flame ionization detection.
SCC Assignments: 40400302, 40400305
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296 '
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PEMTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-OIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYL CYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 OIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-OIHETHYLBUTANE
3-HETHYLHEXANE
2-METHYLHEPTANE
3-HETHYLHEPTANE
2-ME-PROPANE
2-ME-BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_MW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT
3.95
22.66
13.62
19.21
2.58
1.30
2.74
0.56
0.18
0.61
0.07
0.93
0.78
1.13
0.29
0.09
O.SO
0.08
0.31
0.32
0.16
0.08
2.47
22.50
0.24
0.08
0.12
0.02
0.03
0.12
TOTAL
97.73
264
-------
Data Quality C: Data set based on a small number of tests using
analytical techniques such as GC/MS and can be
considered reasonably representative of the
total population.
Data Quality D: Data set based on a single source using analytical
techniques such as GC/MS; or data set from a
number of sources where data are based on
engineering calculations.
Data Quality E: Data set based on engineering calculations from one
. source; data set(s) based on engineering
judgement; data set(s) with no documentation
provided; may not be considered representative
of the total population.
Control device: This entry is used to indicate if the profile data
represent an emission stream downstream, or upstream of a control device (if
present) since the composition of the uncontrolled and controlled streams may
be significantly different.
Reference(s): This entry identifies the primary reference(s) used in
developing the profiles. If more detailed information is required, the
user/reader should consult these references.
Data source: This entry briefly describes the basis of the composition
data used in the profile (e.g., number of tests, number of sources, analytical
methods, how data were composited, etc.). More detailed information about the
data used can be obtained from the references indicated.
SCC: This entry is the code for the source category for which the
profile was originally developed. These codes are obtained from the current
265
-------
National Emission Data System (NEDS) for point sources (1-01-001-01 through 5-
03-900-10) and area sources (01 through 64). Area source codes from 65
through 115 developed under NAPAP are also considered.
Composition data: Each species in the profile data is identified by a
SAROAD code, CAS number, species name, molecular weight, and weight
percentage. SAROAD codes were obtained from Volume V of the Aeros Manual
Series (third edition, September 1986). For species not contained in this
manual, new SAROAD codes have been assigned following the methodology employed
in the Aeros Manual.
Most of the CAS numbers were obtained from the National Air Toxics
Information Clearinghouse Data Base (1985) and the Registry of Toxic Effects
of Chemical Substances (1983 supplement to the 1981-82 edition). For some
species/group of species, CAS numbers were not identified.
Date: This entry will be used to indicate the date the profile was last
reviewed/updated by EPA.
4.2 LIMITATIONS OF DATA
The data for the eight new profiles supplied in this addendum are
presented as received from the Tulsa City-County Health Department. The data
were provided with sufficient documentation and no attempt was made to verify
the completeness/accuracy of the data. In some case-s, the profiles may not be
a full characterization of the emission source. Therefore, -the user/reader is
cautioned to use these profiles with discretion. Nevertheless, the profile
data quality indicator provides a qualitative measure of confidence in a
particular profile.
Profiles for individual sources may vary considerably from the values
provided in this document. Therefore, profiles in this document should not be
used to characterize specific sources; rather, they should be used for
screening purposes. Source-specific data should always be preferred to the
use of literature data presented in this document.
266
-------
4.3 VOC SPECIES PROFILE APPLICATION
There are several ongoing EPA activities that require speciated VOC data
as an input parameter. These activities include preparation of air toxics
emission inventories, ozone strategy development, and preparation of acid
precipitation inventories. This section briefly discusses how to use the
profiles and provides a specific example to illustrate how to use VOC species
profiles in preparation of air toxics emission inventories.
Example of Use of Profile
The easiest way to describe how profiles might be applied is to present
a hypothetical example: A State air pollution control agency is interested in
developing an air toxics emission inventory for the State. An earlier study
conducted for the State has identified a list of toxic/potentially toxic
compounds from several emission sources. The emission rates of these
individual compounds will be used as an input to the proposed air toxics
regulatory program for the State.
The profiles can identify the relative amounts of individual compounds
in a given emission stream. In most cases, emission factors are available for
total VOC's where the compound breakdown is not specified (e.g., AP-42 or the
Criteria Pollutant Emission Factor Document).1'2 The information contained in
the Air Emissions Species Manual supplements these general emissions data.
For a given source category, the appropriate VOC species profile should be
identified and the total VOC emission factor should be multiplied by the
weight fractions for each compound in the profile to determine compound-
specific emission factors.
. In this example, cyclohexane is one of the toxic compounds on a State's
list and crude oil production-well heads (gas driven) are a major emissions
source. The reader/user can identify the appropriate profile for oil
production well heads using Appendix C. However, since all profiles are keyed
off of the SCC for the operation, the proper SCC must first be determined.
267
-------
This can be done by consulting NEDS or the Criteria Pollutant Emission Factor
Document. The appropriate SCC for crude oil production well heads is 3-10-
001-01. A review of Appendix C indicates that there are four profiles with
this SCC, 1205, 1206, 1207, and 1212. Of the four, only Profile 1212 is
applicable because it is the only one for gas driven well heads. The weight
percentage of cyclohexane in Profile 1212 is 0.68. Applying the weight
fraction of cyclohexane to the total VOC emissions for the well head operation
of 50,000 Ibs/yr, cyclohexane emissions are estimated as 50,000 x 0.0068 = 340
Ibs/yr. The reader/user should review the "Data Source" description for the
profile to ensure that the data apply to the specific situation on hand. If
there are questions, the reader may wish to review the original document on
which the profile is based.
268
-------
4.4 REFERENCES FOR SECTION 4
1. U.S. Environmental Protection Agency. Compilation of Air Pollutant
Emission Factors, AP-42. Fourth Edition. Office of Air Quality
Planning and Standards, Research Triangle Park, North Carolina.
September 1985; Supplement A, October 1986; Supplement B,
September 1988.
2. U.S. Environmental Protection Agency. Criteria Pollutant Emission
Factors for the 1985 NAPAP Emissions Inventory. EPA-600/7-87-015.
Office of Research and Development, Air and Energy Engineering
Research Laboratory, Research Triangle Park, North Carolina.
May 1987.
269
-------
SECTION 5
VOC SPECIES PROFILES - POINT AND AREA SOURCES
This section contains eight new VOC profiles for the crude oil
production industry. These profiles were developed based on source testing
information recently gathered by the Tulsa City-County Health Department.1
Testing was performed on several parts of the crude oil production process
including water flood well heads (17 total samples), gas drive well heads
(4 total samples), gathering tanks (7 total samples), pipeline storage tanks
(4 total samples), tank farm storage tanks (4 total samples), and refinery
storage tanks (4 total samples). Thirty specific organic compounds were
analyzed for in each sample in addition to total nonmethane hydrocarbons.
An index of the eight oil production profiles is given below.
Page Number
Profile 1205 - Crude Oil Production - Well Heads
(Water Flood) 273
Profile 1206 - Crude Oil Production - Well Heads
(Water Flood) 274
Profile 1207 - Well Heads (Water Flood) Composite 275
Profile 1208 - Crude Oil Production - Gathering
Tanks 276
Profile 1209 - Oilfield Pipeline Tanks 277
Profile 1210 - Pipeline Terminal Tanks 278
Profile 1211 - Refinery Crude Oil Storage Tanks 279
Profile 1212 - Crude Oil Production - Well Heads
(Gas Drive) - 280
Revisions to three existing VOC profiles are also included in this
section. The affected profiles, 1101, 1203, and 1204, are all for light-duty
gasoline vehicles. Modifications were made to the profiles to correct weight
percentage assignment problems caused by compounds that coelute during gas
chromatography analyses. The coelution cases that were revised in this
Addendum relate to the benzene/cyclohexane split and the pentane/pentene
split.2 The revised profiles given in Section 5.2 should replace the
271
-------
similarly numbered profiles currently contained in "Air Emissions Species
Manual - Volume I, Volatile Organic Compound (VOC) Species Profiles" (EPA-
450/2-88-003a).
5.1 CRUDE OIL PRODUCTION
The oil and gas production industry includes the following processes:
exploration and site preparation, drilling, crude processing, natural gas
processing, and secondary or tertiary recovery. The principal products of
this industry are natural gas and crude oil. Sources of VOC emissions from
the crude oil production process include blowouts during drilling operations,
storage tank working, standing, breathing, and filling losses, wastewater
treatment processes, and fugitive leaks in gauges, fittings, valves, pumps,
pipes, and vessels.
272
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Well Heads (Water Flood)
1205
C
Control Device Uncontrolled
Reference(s) 96
Data Source Crude comes from the Oklahoma Glen Sand formation which
at a depth of 1500 feet. Nine samples were taken in
stainless steel canisters and analyzed using a GC with
cryogenic sample pre-concentrat ion and flame ionization
detection.
is
SCC Assignments: 31000101
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
. 287-92-3
108-08-7
110-82-7
108-87-2 .
96-37-7
.591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
HETHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-OIMETHYLBUTANE
3-METHYUHEXANE
2-HETHYLHEPTANE
3-METHYLHEPTANE
2 -HE -PROPANE
2-HE-BUTANE
2,2,4-TRIHE-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_MU
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT
6.27
18.42
14.74
5.68
1.49
0.89
1.95
1.32
1.02
0.49
0.22
0.77
1.27
1.45
0.39
0.16
0.16
0.47
0.05
0.53
0.66
a. 35
5.36
4.62
0.75
0.38
0.62
0.95
1.35
3.62
TOTAL
76.40
273
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Well Heads (Water Flood)
1206
C
Control Device Uncontrolled
Reference(s) 96
Data Source Crude comes from the Oklahoma Redfork formation which is at
a depth of 1,300 feet. Eight samples were taken in
stainless steel canisters and analyzed using a GC with
cryogenic sample pre-concentration and flame ionization
detection.
SCC Assignments: 31000101
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298'
43910
43911
43912
45201
45202
45203
45204
90010
TOTAL
SSSSSSSSS3
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-OIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-OIMETHYLSUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-HE-PROPANE
2 -ME -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
SpecJIW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_W7
6.74
16.55
18.78
10.97
3.29
1.94
4.78
2.27
1.06
0.91
0.13
1.43
1.97
3.04
0.74
0.32
0.32
0.26
0.09
1.04
0.79
0.34
5.48
8.08
1.37
0.16
0.13
0.12
0.04
0.34
93.48
274
-------
VOC Profile Speciat ion Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Well Heads
1207
C
(Water Flood) Composite
Uncontrolled
96
Composite
profile developed from Profiles
1205 and 1206.
SCC Assignments 31000101
Saroad CAS Number
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-HETHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-OIMETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 OIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2 -ME -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
SpecJtW
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT
6.51
17.48
16.77
8.33
2.40
1.42
3.37
1.80
1.04
0.70
0.18
1.11
1.63
2.44
0.57
0.25
0.24
0.37
0.08
o.ao
0.73
0.35
5.42
6.36
1.07
0.28
0.38
0.54
0.70
1.98
TOTAL
85.30
275
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Crude Oil Production - Gathering Tanks
1208
C
Control Device Uncontrolled
Reference(s) 96
Data Source Seven samples from Oklahoma G,len Sand and Dutcher
formations were taken in stainless steel canisters and
analyzed using a GC with cryogenic sample pre-concentration
and flame ionization detection.
SCC Assignments: 40400302
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-HETHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2.4-OIMETHYLPENTANE
CYCLOHEXANE
HETNYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 D1METHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2 -ME -PROPANE
2-HE-BUTANE
2.2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spee_MU
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spee_UT
9.28
25.84
20.03
7.30
1.30
1.03
2.20
1.21
0.70
0.51
0.06
0.90
1.23
1.48
0.37
0.16
0.20
0.28
0.08
0.51
0.52
0.24
7.14
6.29
0.56
0.12
0.23
0.09
0.11
0.46
TOTAL
90.93
276
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Oilfield Pipeline Tanks
1209
C
Control Device Internal Floating Roofs with Seals
Referenced) 96
Data Source Four samples of emissions from tanks storing "Oklahoma
sweet" crude oil were taken in stainless steel canisters
and analyzed using a GC with cryogenic sample pre-
concentration and flame ionization detection.
SCC Assignments: 40400302, 40400305
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-34-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2.4-OIMETHYLPENTANE
CYCLOHEXANE
HETHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-OIHETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2 -HE -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE AND P-XYLENE
Spec_MU
30.07
44.09
58.12
72.15
36.17
86.17
86.17
100.20
114.23
70.14
100.20
34.16
98.21
34.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT
3.95
22.66
13.62
19.21
2.58
1.30
2.74
0.56
0.18
0.61
0.07
0.93
0.78
1.13
0.29
0.09
0.50
0.08
0.31
0.32
0.16
0.08
2.47
22.50
0.24
0.08
0.12
0.02
0.03
0.12
TOTAL
97.73
277
-------
VOC Profile Special ion Report
Profile Name Pipeline Terminal Tanks
Profile Number 1210
Data Quality C
Control Device Internal Floating Roof with Seal
Reference(s)
Data Source
96
Four samples
sweet" crude
and analyzed
from Sinclair Terminal storing "Oklahoma
oil were taken in stainless steel
using a GC with cryogenic sample
canisters
pre-
concentration and flame ionization detection.
SCC Assignments: 40400303, 40400304, 40400305
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43243
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2.4-OIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-METHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIMETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2 -ME -PROPANE
2 -ME -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
Spec_MW
30.07
44.09
58.12
72.15
86.17
36.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
.72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_UT
0.35
3.31
9.57
9.41
5.26
3.13
4.69
2.11
0.67
2.02
0.38
4.57
5.91
7.22
0.98
0.80
1.07
0.61
0.30
1.50
1.07
0.50
4.51
9.76
3.03
0.54
0.90
0.22
0.16
0.73
TOTAL
85.28
278
-------
VOC Profile Special ion Report
Profile Name
Profile Number
Data Quality
Refinery Crude Oil Storage Tanks
1211
C
Control Device Internal Floating Roof with Seal
Reference(s) 96
Data Source Four samples from Sinclair and Sun Refinery crude oil
storage tanks were taken in stainless steel canisters and
analyzed using a GC with cryogenic sample pre-concentrat ion
and flame ionization detection.
SCC Assignments: 40400303, 40400304, 40400305
Saroad
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
CAS Number
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-83-2
589-34-4
592-27-8
75-28-5
78-78-4. .
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
Name
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-OIMETHYLPENTANE
CYCLOHEXANE
METHYLCYCLOHEXANE
METHYLCYCUOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIMETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-DIHETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2 -ME -BUTANE
2,2,4-TRIME-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
H-XYLENE AND P-XYLENE
Spec_HU
30.07
44.09
58.12
72.15
86.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
84.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
Spec_WT
4.51
18.97
22.71
13.29
3.12
1.79
3.39
1.31
0.34
0.37
0.11
1.24
1.21
2.15
0.50
0.22
0.38
0.11
0.16
0.77
0.30
0.15
6.06
11.22
0.70
0.32
0.35
0.05
0.04
0.14
TOTAL
96.98
279
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Crude Oil Production • Well Heads (Gas Drive)
1212
C
Control Device Uncontrolled
Reference(s) 96
Data Source Crude comes from the Oklahoma Dutcher formation which is at
a depth of 1,400 feet. Four samples were taken in stainless
steel canisters and analyzed using a GC with cryogenic
sample pre-concentration and flame ionization detection.
SCC Assignments: 31000101
Saroad
CAS Number
Name
Spec_MU Spec_WT
43202
43204
43212
43220
43229
43230
43231
43232
43233
43242
43247
43248
43261
43262
43263
43274
43276
43288
43291
43295
43296
43298
43910
43911
43912
45201
45202
45203
45204
90010
74-84-0
74-98-6
106-97-8
109-66-0
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
287-92-3
108-08-7
110-82-7
108-87-2
96-37-7
591-76-4
565-59-3
79-29-8
1678-91-7
75-33-2
589-34-4
592-27-8
75-28-5
78-78-4
540-84-1
71-43-2
108-88-3
100-41-4
95-47-6
ETHANE
PROPANE
N- BUTANE
N-PENTANE
2-METHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
CYCLOPENTANE
2,4-OIMETHYLPENTANE
CYCLOHEX'ANE
METHYLCYCLOHEXANE
METHYLCYCLOPENTANE
2-HETHYL HEXANE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
ETHYLCYCLOHEXANE
2,2-OIMETHYLBUTANE
3-METHYLHEXANE
2-METHYLHEPTANE
3-METHYLHEPTANE
2-ME-PROPANE
2 -HE -BUTANE
2,2,4-TRIHE-PENTANE
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE AND P-XYLENE
30.07
44.09
58.12
72.15
36.17
86.17
86.17
100.20
114.23
70.14
100.20
84.16
98.21
34.16
100.20
100.20
86.17
112.23
86.17
100.20
114.23
114.23
58.10
72.20
114.20
78.11
92.13
106.16
106.16
106.16
17.52
32.63
21.33
6.46
1.48
0.83
1.68
0.68
0.25
0.38
0.05
0.68
0.74
1.04
0.24
0.11
0.17
0.09
0.05
0.32
0.23
0.10
6.44
5.56
0.32
0.05
0.09
0.02
0.03
0.12
TOTAL
99.69
280
-------
5.2 MOBILE SOURCES
Because of its widespread use, the internal combustion gasoline powered
engine in mobile applications is a major source of VOC emissions. Gasoline
fueled light-duty vehicles account for about 75 percent of VOC emissions from
mobile sources (1983). Automotive VOC emissions consist of exhaust emissions
that occur from the tailpipe, evaporative emissions that occur from (1) the
gas tank as the temperature rises during the day, (2) the carburetor after the
engine has been shut off (hot soak emissions), and (3) emissions from vehicle
refueling.
This section contains revised profiles for light-duty gasoline vehicles-
exhaust emissions, light-duty gasoline vehicles-evaporative emissions, and for
the light-duty gasoline vehicle composite.
281
-------
VOC Profile Speciat ion Report
Profile Name Light Duty Gasoline Vehicles
Profile Number 1101
Data Quality 8
Control Device Catalyst
Reference(s)
Data Source
56
Composition
methods for
data collected using GC/FID
exhaust and evaporative (hot
emissions from 45 cars were composited.
and DNPH
soak)
Based on AP-42
(4th. edition), data were weighted according to travel
fractions.
(See Appendix A for details)
•
SCC Assignments:
Saroad
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
CAS Number
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N- BUTANE
SUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-9UTENE
CIS-2-BUTENE
1,3-SUTADIENE
N-PENTANE
ISO PENTANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BU7ENE
2-METHYLPENTANE
3-HETHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL-1-BUTENE
NONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
Spec_MU
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
34.16
58.12
56.10 .
58.12
56.10
56. 1t
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
34.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
Spec_WT Peak*
0.16
0.00 (20)
10.07
1.41
3.92
0.56 ( 1}
1.06 ( 1)
0.75
0.08
0.06
0.00 ( 7)
9.48 ( 3)
0.85 ( 2)
1.70
0.00 ( 2)
0.55 < 4)
0.50 ( 5)
1.68 ( 3)
2.88
6.54
0.15
0.32 ( 6)
0.68
0.38
0.98
1.76 ( 8)
1.09
0.87 (10)
0.65
0.31
0.00 ( 3)
0.19
0.16
0.53
0.35 ( 7)
0.07
0.31 ( 9)
0.58
282
-------
VOC Profile Special ion Report - continued (profile 1101)
Saroad
43248
43250
43252
43261
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
CAS Number
110-82-7
540-84-1
565-75-3
108-87-2
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6 ..
107-02-8
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
Name
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
METHYLCYCI.OPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 OIMETHYLBUTANE
2,4-OIMETHYLHEXANE
2,5-OIMETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TR1METHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
OIMETHYLHEXEME
2,2 DIMETHYLHEXANE
2,3 DIMETHYLHEXANE
2,2-OIHETHYLBUTANE
CYCLOPENTENE
3-HETHYLHEXANE
2-METHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCLQHEXENE
FORMALDEHYDE
ACETALDEHYOE
PROPIONALOEHYDE
' ACROLE1N
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3,5-TRIMETHYLBENZENE
1 , 2 ,4-TR IMETHYLBENZENE
N-PROPYL3ENZENE
S-BUTYLBENZENE
1,2 01 ETHYLBENZENE
M-0 I ETHYLBENZENE
1 ,2,3-TRIMETHYLBENZENE
BENZALDEHYDE
2,3,5-TRIMETHYLHEXANE
2,4 DIMETHYLHEPTANE
Spec_MU
84.16
114.22
114.22
98.21
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
. 54.09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
Spec_WT
1.40
1.97
0.12
0.50
0.78
0.00
0.00
0.01
0.00
1.40
0.69
0.63
0.00
0.00
1.09
0.00
0.00
0.00
0.42
0.16
0.12
0.05
0.00
0.21
0.37
1.06
0.19
0.45
0.36
0.00
0.74
0.28
0.02
0.06
0.02
2.02
1.39
5.14
0.77
1.56
0.00
2.56
1.87
2.30
0.48
0.11
0.59
0.59
0.66
0.08
0.09
0.11
Peak
(12)
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
283
-------
VOC Profile Speciation Report - continued (profile 1101)
Saroad
90004
90005
90006
90007
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
CAS Number Name
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
691-37-2 4-METHYL-1-PENTENE
2-METHYLOCTANE
2,4,5-TRIMETHYLHEPTANE
13269-52-8 T-3-HEXENE
2,2,5-TRIMETHYLHEXANE
496-11-7 INDANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
1-METHYL-3-ETHYLBENZENE
1 -METHYL - 2- ETHYLBENZENE
538-93-2 ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1 -METHYL-3- ISOPROPYLBENZENE
2-METHYLDECANE
UNIDENTIFIED
Spec_MW
128.26
128.26
128.26
84.16
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
Spec_WT
0.00
0.73
0.00
0.00
0.01
0.26
0.29
0.46
0.52
0.07
0.74
1.06
0.21
0.55
0.17
0.38
1.08
3.46
Peak
(17)
(17)
(18)
( 7)
TOTAL
100.04
*The numbers in the parentheses indicate groups of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent. It uas assuMd that 85 percent of peak (3) is
due to n-Butane and 15 percent is due to 1,3-Butadiene.
284
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data Quality
Control Device
Reference(s)
Data Source
Light-Duty Gasoline Vehicles - Exhaust
1203
B
Catalyst
56, 86
Composition
methods for
data collected using GC/FID and
exhaust emissions (see Appendix
DNPH
A for
details; see also Profile 1101).
Saroad CAS Number
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227.
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
HETHYLACETYLENE (PROPYNE)
3-METHYL-1-PENTENE
N- BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE
T-2-BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PEMTANE
3-METHYL-1-BUTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-BUTENE
2-HETHYLPENTANE
3-METHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL- 1 -BUTENE
NONANE
N-DECANE
N-UNOECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-OIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
Spec_MW
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
98.21
Spec_WT
0.19
0.00
10.97
1.79
8.41
0.00
2.88
2.25
0.13
0.17
0.00
3.81
0.00
0.62
1.41
0.00
0.46
0.67
1.60
3.51
0.18
0.19
0.34
0.20
0.51
1.27
0.86
0.67
0.53
0.30
0.00
0.25
0.20
0.60
0.00
0.17
0.22
0.53
1.62
1.95
0.11
0.47
Peak*
(20)
( 1)
( 1)
( 7)
( 3)
( 2)
( 2)
( 4)
( 5)
( 3)
( 6)
( 8)
(10)
( 8)
( 7)
( 9)
(12)
285
-------
VOC Profile Special ion Report - continued (profile 1203)
Saroad
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
43285
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
90004
90005
90006
90007
CAS Number
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6
107-02-3
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
691-37-2
Name
HETHYLCYCLOPENTANE
2-METHYL HEXANE
3-METHYL-T-2-PENTENE
METHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 OIMETHYLBUTANE
2,4-DIMETHYlHEXANE
2,5-DIHETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 DIMETHYIHEXANE
2,3 DIMETHYLHEXANE
2,2-OIMETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-HETHYLHEPTANE
4-METHYLHEPTANE
3-METHYLHEPTANE
1-METHYLCYCIOHEXENE
FORMALDEHYDE
ACETALOEHYDE
PROPIONALDEHYDE
ACROLEIN
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1,3,5-TRIMETHYLBENZENE
1,2,4-TRIMETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 DIETHYLBENZENE
M-DIETHYLBENZENE
1,2,3-TRIMETHYLBENZENE
BENZALDEHYDE
2,3,5-TRIMETHYLHEXANE
2.4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
4-METHYL-1-PENTENE
Spec_MU
84.16
100.20
% 84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
34.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
128.26
128.26
128.26
84.16
Spec_WT
0.61
0.00
0.00
0.02
0.00
1.25
0.53
0.00
0.63
0.00
1.10
0.00
0.00
0.00
0.23
0.08
0.13
0.07
0.00
0.71
0.27
0.92
0.22
0.52
0.36
0.00
1.42
0.49
0.05
0.15
0.07
2.65
1.62
5.72
0.88
1.76
0.00
2.87
2.21
2.90
0.56
0.17
0.67
0.57
0.81
0.24
0.11
0.13
0.00
0.00
0.00
0.25
Peak
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
( 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
(17)
(17)
(18)
( 7)
286
-------
VOC Profile Special ion Report - continued (profile 1203)
Saroad CAS Number Name
Spec_MW Spec_WT Peak*
90008
90009
90042 13269-52-8
98033
98044 496-11-7
99910
99911
99912
99913
99915 538-93-2
99916
99917
99918
99999
TOTAL
2-HETHYLOCTANE
2,4,5-TRIMETHYLHEPTANE
T-3-HEXENE
2,2,5-TRIMETHYLHEXANE
INDANE
2,4 DIMETHYLOCTANE
3,4 DIMETHYLOCTANE
1-METHYL-3-ETHYLBENZENE
1 -METHYL-2-ETHYLBENZENE
ISOBUTYLBENZENE
1-METHYL-3N-PROPYLBENZENE
1-METHYL-3-ISOPROPYLBENZENE
2-METHYLOECANE
UNIDENTIFIED
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
0.02
0.45
0.20
0.48
0.54
0.10
0.96
1.25
0.26
0.49
0.39
0.51
1.32
9.08
100.04
*The number In the parentheses indicate group* of two or three species
identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent. It was assumed that 35 percent of peak (3) is
due to n-Butane and 15 percent is due to 1,3-Butadiene.
287
-------
VOC Profile Speciation Report
Profile Name
Profile Number
Data duality
Control Device
Reference(s)
Data Source
Light-Duty
1204
B
56, 86
Compos i t i on
Gasoline Vehicles - Evaporative
data collected using GC/FID for
emissions (see Appendix A for details; see
1101).
Saroad CAS Number
43135
43136
43201
43202
43203
43204
43205
43206
43208
43209
43211
43212
43213
43214
43215
43216
43217
43218
43220
43221
43223
43224
43226
43227
43228
43229
43230
43231
43232
43233
43234
43235
43238
43241
43242
43243
43245
43247
43248
43250
43252
43261
74-82-8
74-84-0
74-85-1
74-98-6
115-07-1
74-86-2
463-49-0
74-99-7
760-20-3
106-97-8
106-98-9
75-28-5
115-11-7
624-64-6
590-18-1
106-99-0
109-66-0
78-78-4
563-45-1
109-67-1
646-04-8
627-20-3
513-35-9
107-83-5
96-14-0
110-54-3
142-82-5
111-65-9
563-78-0
111-84-2
124-18-5
1120-21-4
287-92-3
78-79-5
592-41-6
108-08-7
110-82-7
540-84-1
565-75-3
108-87-2
Name
C10 PARAFFINS
C9 PARAFFIN
METHANE
ETHANE
ETHYLENE
PROPANE
PROPENE
ACETYLENE
PROPADIENE
METHYLACETYLENE (PROPYNE)
3:M£THYL-1-PENTENE
N- BUTANE
BUTENE
I SO- BUTANE
ISOBUTYLENE-
T- 2- BUTENE
CIS-2-BUTENE
1,3-BUTADIENE
N-PENTANE
ISO PENTAME
3-METHYL-1-3UTENE
1-PENTENE
TRANS-2-PENTENE
CIS-2-PENTENE
2-METHYL-2-8UTENE
2-METHYLPENTANE
3 -METHYL PENTANE
HEXANE
HEPTANE
OCTANE
2,3 DIMETHYL- 1 -BUTENE
MONANE
N-DECANE
N-UNDECANE
CYCLOPENTANE
ISOPRENE
1-HEXENE
2,4-DIMETHYLPENTANE
CYCLOHEXANE
2,2,4-TRIMETHYLPENTANE
2,3,4-TRIMETHYLPENTANE
METHYLCYCLOHEXANE
evaporative
also Profile
Spec_MW
142.28
128.25
16.04
30.07
28.05
44.09
42.08
26.04
40.06
40.06
84.16
58.12
56.10
58.12
56.10
56.11
56.11
54.09
72.15
72.15
70.13
70.13
70.13
70.13
70.13
86.17
86.17
86.17
100.20
114.23
84.16
128.25
142.28
156.31
70.14
68.12
84.16
100.20
84.16
114.22
114.22
98.21
Spec_WT
0.09
0.00
0.04
0.03
0.03
1.54
0.00
0.01
0.02
0.00
0.00
28.34
0.00
.6.56
0.86
0.00
0.81
0.00
4.67
13.60
0.18
0.62
1.11
1.13
0.74
2.28
1.17
0.72
0.52
0.24
0.00
0.12
0.20
0.09
0.00
0.00
0.39
0.59
0.67
0.59
0.59
0.33
Peak*
(20)
( 13
( 1)
( 7)
( 3)
( 2)
( 2)
( 4)
( 5)
( 3)
( 6)
( 8)
(10)
( 8)
( 7)
( 9)
(12)
288
-------
VOC Profile Speciation Report • continued (profile 1204)
Saroad
43262
43263
43270
43272
43273
43274
43276
43277
43278
43279
43280
43281
43282
43283
43284
4328S
43286
43287
43290
43291
43292
43295
43296
43297
43298
43299
43502
43503
43504
43505
43515
45110
45201
45202
45203
45204
45205
45206
45207
45208
45209
45216
45217
45218
45225
45501
90002
90003
90004
90005
90006
90007
CAS Nuifcer
96-37-7
591-76-4
922-61-2
693-89-0
110-83-8
565-59-3
79-29-8
592-13-2
760-21-4
107-00-6
503-17-3
625-27-4
590-73-8
75-83-2
142-29-0
589-34-4
592-27-8
589-53-7
50-00-0
75-07-0
123-38-6
107-02-8
123-73-9
71-43-2
108-88-3
100-41-4
95-47-6
108-38-3
106-42-3
108-67-8
95-63-6
103-65-1
135-98-8
135-01-3
141-93-5
526-73-8
100-52-7
691-37-2
Name
METHYLCYCLOPENTANE
2-METHYL HEXANE
3-HETHYL-T-2-PENTENE
HETHYLCYCLOPENTENE
CYCLOHEXENE
2,3 DIMETHYL PENTANE
2,3 DIHETHYLBUTANE
. 2.4-D1METHYLHEXANE
2,5-DIHETHYLHEXANE
2-ETHYL-1-BUTENE
2,3,3 TRIMETHYLPENTANE
1-BUTYNE
2-BUTYNE
C-3-HEXENE
2-METHYL-2-PENTENE
2-HEXENE
DIMETHYLHEXENE
2,2 OIHETHYIHEXANE
2,3 D1HETHYLHEXANE
2,2-DIMETHYLBUTANE
CYCLOPENTENE
3-METHYLHEXANE
2-METHYLHEPTANE
4-HETHYLHEPTANE
. 3-METHYLHEPTANE
1-METHYLCYCLOHEXENE
FORMALDEHYDE
ACETALDEHYDE
PROPIONALDEHYDE
ACROLEIN
CROTONALDEHYDE
C10 AROMATIC
BENZENE
TOLUENE
ETHYLBENZENE
0-XYLENE
M-XYLENE
P-XYLENE
1 ,3,5-TRIMETHYLBENZENE
1,2,4-TRlMETHYLBENZENE
N-PROPYLBENZENE
S-BUTYLBENZENE
1,2 01 ETHYLBENZENE
M-DIETHYLBENZENE
1 ,2,3-TRIMETHYLBENZENE
BENZALDEHYDE
2, 3, 5 -TR I METHYL HEXANE
2,4 DIMETHYLHEPTANE
3,5 DIMETHYLHEPTANE
2,5 DIMETHYLHEPTANE
2,3 DIMETHYLHEPTANE
4-METHYL-1-PENTENE
Spec_MW
84.16
100.20
84.16
82.14
82.14
100.20
86.17
114.22
114.22
84.16
114.22
54.09
54.09
84.16
84.16
84.16
112.20
114.22
114.22
86.17
68.11
100.20
114.23
114.23
114.23
96.17
30.03
44.05
58.08
56.07
70.09
134.22
78.11
92.13
106.16
106.16
106.16
106.16
120.19
120.19
120.19
134.21
134.22
134.22
120.19
106.13
128.25
128.26
128.26
128.26
128.26
84.16
Spec_WT
0.84
0.00
0.00
0.07
0.00
1.03
1.04
0.00
0.48
0.00
0.41
0.00
0.00
0.00
0.64
0.08
0.05
0.05
0.00
1.68
0.20
0.77
0.22
0.10 .
0.35
0.00
0.00
0.00
0.00
0.00
0.00
0.63
0.66
8.51
0.53
0.87
0.00
2.11
0.71
1.21
0.36
0.16
0.13
0.13
0.17
0.00
0.07
0.05
0.00
0.00
0.00
1.49
Peak
(11)
(13)
(11)
(13)
(13)
(14)
(14)
( 9)
( 5)
< 6)
(10)
(15)
( 4)
(16)
(16)
(12)
(15)
(18)
(20)
(19)
(19)
(17)
(17)
(18)
( 7)
289
-------
VOC Profile Speciation Report - continued (profile 1204)
Saro«d
CAS Nuaber
Spec_MW Spec_WT Peak*
90008
90009
90042
98033
98044
99910
99911
99912
99913
99915
99916
99917
99918
99999
2-METHYLOCTANE
2,4,5-TRIMETHYLHEPTANE
13269-52-8 T-3-HEXEME
2,2,5-TRIMETHYLHEXANE
496-11-7 INDANE
2,4 OIMETHYLOCTANE
3,4 OIMETHYLOCTANE
1 -METHYL -3-ETHYLBENZENE
1-NETHYL-2-ETHYLBENZENE
538-93-2 ISOBUTYLBENZENE
1 -NETHYL-3N-PROPYLBENZENE
1 -METHYL-3- ISOPROPYLBENZENE
2-METHYLOECANE
UNIDENTIFIED
128.26
142.29
84.16
128.26
118.18
142.29
142.29
120.19
120.19
134.22
134.22
134.22
156.32
86.00
0.00
0.15
0.13
0.38
0.13
0.20
0.40
0.95
0.04
0.03
0.02
0.13
0.21
2.61
TOTAL
100.06
*The nunbers in the parentheses indicate grot** of two or three species
• identified as a single peak in GC analysis. Only one of the species is
assigned the weight percent.
290
-------
5.3 REFERENCES FOR VOC PROFILES
1. Viswanath, R.S. and J.H. Van Sandt. Oil Field Emissions of
Volatile Organic Compounds. EPA-450/2-89-007. Office of Air
Quality Planning and Standards, U.S. Environmental Protection
Agency, Research Triangle Park, North Carolina. April 1989.
2. Memorandum from Gray, C. I., U. S. Environmental Protection Agency
to J. Calcagni, U. S. Environmental Protection Agency and W.
Laxton, U. S. Environmental Protection Agency. March 23, 1989.
Motor Vehicle VOC Speciation for SIP Development.
291
-------
APPENDIX A
PM PROFILE CALCULATIONS
A-l
-------
APPENDIX A
PM PROFILE CALCULATIONS
This appendix provides details of the procedures used for calculating
composition data for the 0-10 urn size interval and uncertainty associated with
composition data for the 0-10 urn size range. The calculational procedures are
based on the methodologies outlined in the Air Emissions Species Manual,
Volume II. The assumptions used in filling profile data gaps are also
discussed. The calculations discussed in this appendix involve combining
composition data reported by a number of different sources with size
distribution data compiled primarily from AP-42. An additional uncertainty is
introduced into the, calculations since the composition data and size
distribution data were developed for different sources.
In addition to procedures for calculating composition data for the 0-
10 urn size range, a methodology that can be used to estimate composition data
for the 2.5-6 urn and 6-10 urn size intervals is also presented. However, as
discussed below, the application of this methodology is limited.
A.I CALCULATION OF COMPOSITION DATA FOR PM10 (0-10 urn)
According to the Air Emissions Species Manual, Volume II, page B-l, PM10
composition is calculated as:
"lJ.O-10 * (?2 .iJ/'lOj) "-lJ,0-2.5 "*"[!" (F2.3J/ FIOJ) J "lJ.2.5-10
Where:
AU.O-IO * PMi0 composition data (weight percent) for species i
in emissions from source J
FZ.SJ * fraction of mass in the 0-2.5 urn size interval in
source J emissions
A-3
-------
F10J - fraction of mass in the 0-10 urn size interval in
source J emissions
Au,o-2.5 * composition data (weight percent) for fine fraction
. ' (<2.5 urn) for species i in emissions from source J
Aij,2.3-io = composition data (weight percent) for coarse
fraction (2.5-10 urn) for species i in source J
This equation is derived from the following basic relationship:
NEMU.0_10 - NEMUi0.a.3 + NEM1Jj2.5_10 (2)
where NEM is defined as the normalized elemental mass (mass fraction x weight
percent). .For example,
NEMIJ>0_10 » F10J x A1J(0_10 (3)
As shown schematically in Figure 1, a plot of NEM versus particle size would
lead to a curve increasing with particle size. Equation (1) is illustrated
below for Profile 17108:
Let:
J - Municipal Incinerator (MI) - Profile 17108
i » Al (aluminum)
F2.5fia" - 0.26 (see Profile 17108)
F10rMI « 0.38 (see Profile 17108)
AAI.M,0-2.5 - 0-230 (see Profile 17108)
AAI.MI.Z.S-IO - 5-200 (see Profile 17108)
Then:
AAI.M.O-IO " (0.26/0.38) (0.230) + [1 - (0.26/0.38)] 5.200
AAI.MI.O-IO * 0.157 + 1.642 = 1.799 percent
A-4
-------
IU
z
Particle Size
Figure 1. Normalized Elemental Size versus Particle Size
A-5
-------
A. 2 CALCULATION OF COMPOSITION DATA FOR THE 2.5-6 urn AND 6-10 urn INTERVALS
As indicated above, the application of the following methodology for
estimating composition data for the 2.5-6 urn and 6-10 urn size intervals from
data for the 2.5-10 urn size interval is limited. This limitation is largely
due to the fact that the mass fraction data and composition data used in these
calculations are from different sets of data and represent different emission
sources.
Having estimated the PM10 composition and NEM1J(0.10, a simple linear
relationship can be assumed to exist between NEMU 0_2 5 and NEM^ 0.10 over the
size interval 2.5-10 urn. The equation for this relationship can be
represented by the following:
(NEMUf0.10 - NEM1J>0_2.3)
NEMIJ>0.X -- (X - 2.5) + NEM1Ji0.2.5 (4)
(10 - 2.5)
Where X is the particle size of interest.
Substituting X » 6 urn will yield NEM^ 0_6 which can be used in the
following equation to solve for Au 2 5.6.
NEMU(0_6 - NEM1J>0_2.5 + NEMU>2.5_6 (5)
Similarly, the value for A1J>6_10 can be estimated from Equation (6):
NEM1J>0.10 > NEMIJ>0_6 + NEM1J>6.10 (6)
Using the same example data set,
,MI ,0-10 ' NEMAl.MI.O-2.5)
(6 - 2.5) + NEMA1(MI;0.2.5
(10 - 2.5)
- [(0.38 x 1.799) - (0.26 x 0.230)]
7.5
0.291 + 0.060 - 0.351
A-6
(3.5) + (0.26 x 0.230)
-------
From Equation (5),
>MI( 0-2.5 + NEMAlfMl>2.5_6
0.351 - (0.26 x 0.230) + (F2.3_6>M1 x A^^.j.J
^2. 5-6, MI = '6, MI " r2.s,MI
F6>MI - 0.31 (see Profile 17108)
F2.5.MI - 0-26 (see Profile 17108)
F2.5-6,MI ' °'05
Therefore,
AAi,Mi,2.5-6 " (0.351 - 0.060) / 0.05 - 5.824 percent
Using Equation (6),
NEMA1,MI.O-10 " NEMAl,MI,0-6 + NEMA1,MI,6-10
(0.38 x 1.799) - 0.351 + F6.10
-------
for the 0-2.5 urn and 0-10 urn size intervals and a 2A1Jj0-2.3 and a 2AiJ/2.5-io
represent the variances associated with the composition data for the fine and
coarse size fractions. This equation is illustrated below for Profile 17108:
Let:
i
J - Municipal Incinerator (MI) - Profile 17108
i - K (potassium)
F2.3)M1 - 0.26 (see Profile 17108)
F10(MI - 0.38 (see Profile 17108)
bi.ia.o-z.i - 7.600 (see Profile 17108)
\,Mi,2.5-io - 4.500 (see Profile 17108)
,MI,0-2.5 - 2.300 (see Profile 17108)
,MI,2.5-10 - 0.600 (see Profile 17108)
Since aF2.5,MI andaF10,MI are not available, assume the following:
(7F2.5,MI - 0.1 F2.5.MI - 0.026
aF10,MI - 0.1 F10,MI - 0.038
Then:
aK,MI,10 = [(7.60/0.38)2 (0.026)2 + (0.26/0.382)2 (7.60)2 (0.038)2
+ (0.26/0.38)2 (2.30)2 + (4.50/0.38) (0.026)2
+ (0.26/0.382)2 (4.50)2 (0.038)2 + (0.26/0.38) (0.600)2]1'2
- [0.2704 + 0.2704 + 2.4765 + 0.0080 + 0.0948 + 0.2463]1'2
- (3.3664)1'2 - 1.835
A-8
-------
A.4 ASSUMPTIONS USED IN FILLING DATA GAPS
In several profiles, composition data information for one or two size
intervals were not reported. To increase the usefulness of the profiles,
certain assumptions were employed to fill these data gaps.
If data are reported for a single size interval, assume data for
the other two intervals are the same. Values for the 0-10 urn size
interval are also assumed to be the same.
If data for the 0-2.5 urn size interval are missing, assume the
data for the 2.5-10 urn size interval can be substituted and vice
versa. Values for the 0-10 urn size interval are also assumed to
be the same.
If data for the total particulate measured are not reported,
assume the estimated data for the 0-10 urn size fraction can be
substituted.
These assumptions are indicated on each profile with appropriate footnotes.
A-9
-------
APPENDIX B
PARTICLE SIZE DISTRIBUTION DATA
B-l
-------
B-2
-------
APPENDIX B
PARTICLE SIZE DISTRIBUTION DATA
This appendix discusses how the particle size'distribution data
(i.e., fraction of mass in a given size interval) presented in the PM profiles
in Section 3.0 are compiled. The mass fraction data can be coupled with the
size-specific composition data in a given profile to estimate size-specific
and speciated particulate emissions.
A large portion of the particle size, distribution data were obtained
from Supplement A of AP-42. Mass fraction data for about 60 percent of the PM
profiles in this update were extracted from AP-42. For several profiles, only
generic particle size distribution data were identified in Supplement A of AP-
42.
Data from other sources were used to characterize those profiles for
which mass fraction data did not exist in Supplement A of AP-42. Table B-l
presents a listing of profile numbers, information sources for the mass
fraction data, and data quality indicators. The quality indicators are
primarily based on the ratings used in Supplement A of AP-42 for cumulative
size-specific emission factors. The ratings designated for the size-specific
emission factors are assumed to represent the quality associated with the
particle size distribution data.
Data based on generic size distributions in AP-42 are assigned a rating
of "D" whereas the default value is assigned a rating of "E." The default
value is the same distribution used in the Air Emissions Species Manual,
Volume II and represents the overall average of the size distribution data
based on all the profiles in that report. It is used for profiles where no
size distribution data were identified.
B-3
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA
Profile Number
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11212
11213
11214
11215
11301
11502
11503
11504
11505
Mass Fraction
Data Quality
C
E
D
D
D
D
D
D
D
C
E
D
C
D
D
C
C
C
C
Information Source
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from Profiles 11202
and 11211
Based on data from Profiles 11204-
11208, 11210, and 11212
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
B-4
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
11506
11507
11508
11509
11510
12301
12705
13502
13503
13504
14101
14102
15101
17107
17108
17109
20103
Mass Fraction
Data Quality
C
C
C
C
C
E
E
E
E
D
E
•: E
E
0
D
E
D
Information Source
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from Profiles
11502-11509
Based on AP-42 (Reference 1)
distillate oil firing
AP-42 (Reference 1)
Based on AP-42 (Reference 1)
residual oil firing
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on AP-42 (Reference 1)
residual oil firing
Based on AP-42 (Reference 1)
residual oil firing
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Default value
AP-42 (Reference 1) - generic
data for
data for
.data for
data for
: size
distribution
B-5
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
20402
20403
20404
20405
20406
20503
25408
25409
25410
25411
25412
25413
25414
25415
25701
25702
Mass Fraction
Data Quality
D
D
D
D
E
D
D
E
C
D
D
D
D
D
D
D
Information
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
Based on data from
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
Source
Profile 20403
- generic
- generic
- generic
- generic
- generic
- generic
- generic
- generic
- generic
size
size
size
size
size
size
size
size
size
distribution
B-6
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
25703
26203
26204
26205
26206
26207
26208
26209
27204
27205
27502
27503
27601
27602
Mass Fraction
Data Quality
D
D
D
D
D
D
0
D
D
D
D
D
D
D
Information
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
Source
generic size
generic size
generic size
generic size
generic size
generic size
generic size
Based on data from Profiles
26203-26205
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
distribution
AP-42 (Reference 1) -
generic size
generic size
generic size
generic size
generic size
generic size
distribution
B-7
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
28304
28306
28307
29203
29204
29205
29206
29207
29208
29209
29210
29211
29310
29311
29501
29502
31103
Mass Fraction
Data Quality
C
D
C
D
E
E
E
D
D
D
0
E
D
D
D
D
C
Information Source
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
distribution
AP-42 (Reference 1}
AP-42 (Reference 1)
Based on data from
and 29204
Based on data from
and 29206
AP-42 (Reference 1)
AP-42 (Reference 1)
AP-42 (Reference 1)
distribution
AP-42 (Reference 1)
distribution
AP-42 (Reference 2)
- generic size
Profiles 29203
Profiles 29205
- generic size
- generic size
B-8
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
31104
31105
31202
31203
32102
32103
32104
32203
32204
32205
32206
33004
33005
33006
33007
33008
33009
33010
Mass Fraction
Data Quality
C
C
C
C
C
C
C
C
C
C
C
D
D
D
D
D
0
D
Information Source
AP-42 (Reference 2)
Based on data from Profiles 31103
and 31104
AP-42 (Reference 2)
AP-42 (Reference 2)
AP-42 (Reference 2)
AP-42 (Reference 2)
Based on data from Profiles 32102
and 32103
AP-42 (Reference 2)
AP-42 (Reference 2)
AP-42 (Reference 2)
Based on data from Profiles 32204
and 32205
Based on data from Reference 3
Based on data from Reference 3
Based on data from Reference 3
Based on data from Reference 3
Based on data from Reference 3
Based on data from Reference 3
Based on data from Reference 3
B-9
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
33011
34003
34004
34005
34006
41111
41112
41.113
41114
41115
41116
41117
41118
41119
41120
41121
41122
41123
41124
41131
Mass Fraction
Data Quality
D
E
E
E
E
D
D
D
D
D
D
D
D
D
D
D
D
D
0
D
Information Source
Based on data from Profiles
33004-33009
Default value
Default value
Default value
Default value
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
B-10
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
41132
41133
41134
41135
41136
41137
41205
41321
41322
41323
41324
41351
42305
42306
42307
42308
42309
42310
42311
42312
Mass Fraction
Data Quality
D
D
0
D
0
0
D
D
D
D
D
D
D
D
D
D
D
D
D
D
Information Source
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 4
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
B-ll
-------
TABLE B-l. SOURCES OF MASS FRACTION DATA (Continued)
Profile Number
42313
42314
42315
42316
42317
42318
42319
43304
43305
43306
43307
43308
43309
44101
44102
44103
Mass Fraction
Data Quality
D
D
D
D
C
C
C
E
E
E
E
E
E
E .
E
D
Information Source
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Extrapolated from data in Reference 5
Based on data from Reference 6
Based on data from Reference 6
Based on data from Profiles 42317
and 42318
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
Based on data from Profile 41351
AP-42 (Reference 1) - generic size
44104
distribution
AP-42 (Reference 1) - generic size
distribution
B-12
-------
APPENDIX B REFERENCES
1. AP-42 (GPO 055-000-00251-7), Compilation of Air Pollutant Emission Factors,
Volume I: Stationary Point and Area Sources, Fourth Edition, U. S.
Environmental Protection Agency, Research Triangle Park, NC, September 1985.
2. AP-42 (GPO 055-000-00252-5), Compilation of Air Pollutant Emission Factors,
Volume II, Mobile Sources, Fourth Edition, U. S. Environmental Protection
Agency, Research Triangle Park, NC, September 1985 (Appendix L).
3. U. S. Environmental Protection Agency. Air Emissions Species Manual,
Volume II, Particulate Matter Species Profiles. Publication No. EPA-450/2-
88-003b, Research Triangle Park, NC, April 1988, page 314.
4. Anthropogenic Sources and Emissions of Alkaline Particulate Matter in Canada
(Prepared by Meteorological and Environmental Planning, Ltd. and Ontario
Research Foundation for Air Pollution Control Directorate), 1984.
5. National Inventory of Natural Sources and Emissions of Alkaline Particulates
(Prepared by the Environmental Applications Group, Ltd. for Environment
Canada), 1982.
6. Rau, J. A. and J. J. Huntzicker, Oregon Graduate Center, Size Distribution
and Chemical Composition of Residential Wood Smoke, Presented at the 78th
Annual Meeting of the Air Pollution Control Association, Detroit, MI,
June 16-21, 1985.
B-13
-------
B-14
-------
APPENDIX C
ASSIGNMENT OF SOURCE CLASSIFICATION AND
AREA SOURCE CODES BY PROFILE NUMBER
C-l
-------
C-2
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS
SCC SCC DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBER
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100201
10100203
10100401
10100401
10100401
10100401
10100401
10100401
10100401
10100401
10100401
10101201
10200401
10200401
10200401
10200500
10200903
EXTERNAL COMBUSTION BOILERS
ELECTRIC GENERATION-BITUMINOUS
COAL-PULVERIZED COAL.WET BOTTOM
EXTERNAL COMBUSTION BOILERS-
ELECTRIC GENERATION-BITUMINOUS
COAL-CYCLONE
EXTERNAL COMBUSTION BOILERS-
ELECTRIC GENERATION-RESIDUAL
OIL-GRADE 6 OIL:NORMAL FIRING
EXTERNAL COMBUSTION BOILERS-
ELECTRIC GENERATION-SOLID
WASTE-SPECIFY WASTE MATERIAL
EXTERNAL COMBUSTION BOILERS-
INDUSTRIAL-RESIDUAL OIL-
GRADE 6 OIL
EXTERNAL COMBUSTION BOILERS
INDUSTRIAL-DISTILLATE OIL
EXTERNAL COMBUSTION BOILERS-
INDUSTRIAL-UOOD/BARK WASTE-WOOD
FIRED BOILERO50.000 LB STEAM)
11202
11203
11204
11205
11206
11207
11208
11209
11210
11211
11213
11214
11215
11301
11212
11502
11503
11504
11505
11506
11507
11508
11509
11510
11301
13502
13503
13504
12301
12705
C
C
C
C
C
E
E
E
E
E
E
D
D
E
E
E
E
D
D
D
E
E
D
27
29
30
32
33
34
35
36
37
38
40
41
42
43
39
45
47
49
51
53
55
57
58
60
43
63
64
65
61
62
C-3
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
SCC SCC DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBE
10201201 EXTERNAL COMBUSTION BOILERS- 15101
INDUSTRIAL-SOLID WASTE-SPECIFY
WASTE MATERIAL
10201301 EXTERNAL COMBUSTION BOILERS- 14102
INDUSTRIAL-LIQUID WASTE-SPECIFY
WASTE MATERIAL
10201302 EXTERNAL COMBUSTION BOILERS-
INDUSTRIAL-LIQUID WASTE-
WASTE OIL
30102712 CHEMICAL MANUFACTURING-
AMMONIUM NITRATE PROD.-
PRILLING TOWER(HI DENS)
30102803 CHEMICAL MANUFACTURING-
NORMAL SUPER PHOSPHATE
ROCK UNLOADING
30102804 CHEMICAL MANUFACTURING-
NORMAL SUPER PHOSPHATE
ROCK FEEDER SYSTEM
30102823 CHEMICAL MANUFACTURING-
NORMAL SUPER PHOSPHATE
AMMONIATOR/GRANULATOR
30102823
30102824 CHEMICAL MANUFACTURING-
NORMAL SUPER PHOSPHATE
DRYER
30102825 CHEMICAL MANUFACTURING-
NORMAL SUPER PHOSPHATE
COOLER
30102923 CHEMICAL MANUFACTURING-
TRIPLE SUPER PHOSPHATE
-AMMONIATOR/GRANULATQR
30102924 CHEMICAL MANUFACTURING-
TRIPLE SUPER PHOSPHATE
-DRYER
30103001 CHEMICAL MANUFACTURING-
AMMONIUM PHOSPHATES-
DRYERS & COOLERS
14101
25409
25408
25408
25412
25413
25412
25412
25408
25408
25411
D
D
68
67
66
72
71
71
76
78
76
76
71
71
74
C-4
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
SCC
SCC DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBER
30103002 CHEMICAL MANUFACTURING-
AMMONIUM PHOSPHATES-
AMMONIATOR/GRANULATOR
25411
74
30103003 CHEMICAL MANUFACTURING-
AMMONIUM PHOSPHATES-
SCREENING/TRANSFER
25411
74
30103004 CHEMICAL MANUFACTURING-
AMMONIUM PHOSPHATES-
BAGGING/HANDLING
25411
74
30104501
30104501
30113004
CHEMICAL MANUFUACTURING-
ORGANIC FERTILIZER-
GENERAL -.MIXING/HANDLING
CHEMICAL MANUFACTURING-
AMMONIUM SULFATE-
ROTARY DRYER
25415
25414
25410
D
E
32
80
73
30113005 CHEMICAL MANUFACTURING-
AMMONIUM SULFATE-FLUID
BED DRYER
25410
73
30300502
30300509
30300512
30300514
30300514
30300514
30300515
30300515
30300515
PRIMARY METAL PRODUCTION-
PRIMARY COPPER SMELTERS-
MULTIPLE HEARTH ROASTER
PRIMARY METAL PRODUCTION-
PRIMARY COPPER SMELTERS-
FLUIDIZED BED ROASTER
PRIMARY METAL PRODUCTION-
PRIMARY COPPER SMELTERS-
FLASH SMELTING
PRIMARY METAL PRODUCTION-
PRIMARY COPPER SMELTERS-
REVERBERATORY FURNACE: FUGITIVE
EMISSIONS
PRIMARY METAL PRODUCTION-
PRIMARY COPPER SMELTERS-
CONVERTER:FUGITIVE EMISSIONS
29209
29209
29207
29203
29204
29210
29205
29206
29211
D
D
D
D
95
95
93
89
90
96
91
92
97
C-5
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
SCC
SCC DESCRIPTION
PROFILE DATA DOCUMENT
NUMBER QUALITY PAGE NUMBE
30300524 PRIMARY METAL PRODUCTION- 29208
PRIMARY COPPER SMELTERS-
MULTI-HEARTH ROASTER/REVERBERATORY
FURNACE,OR FLUID BED ROASTER/
ELECTRIC FURNACE&CONVERTOR
30300813 PRIMARY METAL PRODUCTION- 28304
SINTERING-UINDBOX
30300913 PRIMARY METAL PRODUCTION- 28307
STEEL PRODUCTION-BASIC OXYGEN
FURNACE: OPEN HOOD-STACK
30300999 PRIMARY METAL PRODUCTION- 28306
STEEL PRODUCTION-OTHER
NOT CLASSIFIED
30301009 PRIMARY METAL PRODUCTION- 29310
LEAD SMELTERS-LEAD DROSSING
30301021 PRIMARY METAL PRODUCTION- 29311
LEAD SMELTERS-BLAST FURNACE
SLAG POURING
30400107 SECONDARY METAL PRODUCTION- 20103
SECONDARY ALUMINUM-HOT DROSSING
PROCESSING
30400214 SECONDARY METAL PRODUCTION- 29502
-REVERBERATORY FURNACE-CHARGE
WITH COPPER
30400215 SECONDARY METAL PRODUCTION- 29501
-REVERBERATORY FURNACE-CHARGE
WITH BRASS & BRONZE
30400299 SECONDARY METAL PRODUCTION- 20503
-FUGITIVE EMISSIONS-OTHER
NOT CLASSIFIED
30400401 SECONDARY METAL PRODUCTION- 20405
-SECONDARY LEAD SMELTING-
POT FURNACE
30400402 SECONDARY METAL PRODUCTION- 20403
-SECONDARY LEAD SMELTING-
REVERBERATORY FURNACE
30400413 SECONDARY METAL PRODUCTION- 20404
-SECONDARY LEAD SMELTING-
94
85
87
86
98
99
103
111
110
109
107
105
106
C-6
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
SCC SCC DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBER
SMELTING FURNACE:FUGITIVE
30400499 SECONDARY METAL PRODUCTION- 20402
-SECONDARY LEAD SMELTING-
OTHERWISE NOT CLASSIFIED
30400499 " •• 20406
30500609 MINERAL PRODUCTS-CEMENT 27205
MANUFACTURING, DRY PROCESS-
PRIMARY CRUSHING
30500610 MINERAL PRODUCTS-CEMENT 27205
MANUFACTURING, DRY PROCESS-
SECONDARY CRUSHING
30500618 MINERAL PRODUCTS-CEMENT 27204
MANUFACTURING, DRY PROCESS-
CEMENT SILOS
30500619 MINERAL PRODUCTS-CEMENT 27204.
MANUFACTURING, DRY PROCESS-
CEMENT LOAD OUT
30501504 MINERAL PRODUCTS- 27502
GYPSUM MANUFACTURE-CONVEYING
30501508 MINERAL PRODUCTS- 27502
GYPSUM MANUFACTURE-STOCKPILE
GYPSUM ORE
30501520 MINERAL PRODUCTS- 27503
GYPSUM MANUFACTURE-
DRYING KILN
30501607 MINERAL PRODUCTS- 27601
LIME MANUFACTURE-RAW MATERIAL
TRANSFER & CONVEYING
30501608 MINERAL PRODUCTS- 27601
LIME MANUFACTURE-RAW MATERIAL
UNLOADING
30501615 MINERAL PRODUCTS- 27601
LIME MANUFACTURE-PRODUCE TRANSFER
AND CONVEYING
30502001 MINERAL PRODUCTS- 44103
STONE QUARRYING/PROCESSING-
PRIMARY CRUSHING
E
D
104
108
116
116
115
115
117
117
118
119
119
119
257
C-7
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
sec
30601201
30600201
30600201
30600201
30600201
SCC DESCRIPTION
PETROLEUM INDUSTRY-FLUID
COKING UNITS
PETROLEUM INDUSTRY-FLUID
CATALYTIC CRACKING UNITS
(FCC)-FLUID CATALYTIC CRACKING
UNIT
H H
M H
rt M
PROFILE
NUMBER
26206
26203
26204
26205
26209
DATA
QUALITY
D
C
C
D
D
DOCUMENT
PAGE NUMBE
131
123
125
126
133
30601401 PETROLEUM INDUSTRY-
PETROLEUM COKE CALCINING-
COKE CALCINER
26206
128
30601401
30700106
30900202
30988801
30988802
31000101
31000101
31000101
31000101
31401101
31401102
40400302
PETROLEUM INDUSTRY-PETROLEUM
COKE CALCINING-COKE CALCINER
PULP&PAPER INDUSTRY-SULFATE
(KRAFT) PULPING-LIME KILN
FABRICATED METAL PRODUCTS-
ABRASIVE BLASTING OF METAL PARTS-
SAND ABRASIVE
FABRICATED METAL PRODUCTS-
FABRICATED METALS, FUGITIVE
EMISSIONS-SPECIFY IN COMMENTS
FABRICATED METAL PRODUCTS-
FABRICATED METALS, FUGITIVE
EMISSIONS-SPECIFY IN COMMENTS
OIL 4 GAS PRODUCTION-CRUDE
OIL PRODUCTION-COMPLETE WELL:
FUGITIVE EMISSIONS
TRANSPORTATION EQUIPMENT-
AUTO BODY SHREDDING-
PRIMARY METAL RECOVERY LINE
TRANSPORTATION EQUIPMENT-
AUTO BODY SHREDDING-
MULTIPLE CHAMBER INCINER.
BULK PLANTS-PETROLEUM STORAGE
TANKS-OIL FIELD STORAGE OF
26207
27602
25702
25701
25703
1205
1206
1207
1212
17109
17109
1208
C
C
C
129
120
144
143
145
273
274
275"
280
140
140
276
C-8
-------
TABLE C-l. SOURCE CLASSIFICATION CODE ASSIGNMENTS (Continued)
SCC SCC DESCRIPTION
PROFILE
NUMBER .
DATA
QUALITY
DOCUMENT
PAGE NUMBER
40400302
CRUDE OIL-FIXED ROOF TANK:
WORKING LOSS
1209
277
40400303
40400303
40400304
40400304
40400305
40400305
40400305
50100101
50100101
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
50300201
BULK PLANTS-PETROLEUM STORAGE
TANKS-OIL FIELD STORAGE OF
CRUDE OIL-EXTERNAL FLOATING
ROOF TANK W/PRIMARY SEALS:
STANDING LOSS
BULK PLANTS-PETROLEUM STORAGE
TANKS-OIL FIELD STORAGE OF
CRUDE OIL-EXTERNAL FLOATING
ROOF TANK W/SECONDARY SEALS:
STANDING LOSS
BULK PLANTS-PETROLEUM STORAGE
TANKS-OIL FIELD STORAGE OF
CRUDE OIL-INTERNAL FLOATING
ROOF TANK:STANDING LOSS
SOLID WASTE DISPOSAL,GOVT.-
HUNICIPAL INCINERATION-MULTIPLE
CHAMBER
SOLID WASTE DISPOSAL,INDUSTRIAL-
OPEN BURNING-WOOD/VEGETATION
LEAVES
1210
278
1211
1210
1211
1209
1210
1211
17107
17108
42305
42306
42307
42308
42309
42310
42311
42312
42313
42314
42315
42316
C
C
C
C
C
C
E
E
E
E
E
E
E
E
E
E
E
E
E
279
278'
279
277
278
279
137
138
197
198
199
200
201
202
203
204
205
206
207
208
C-9
-------
TABLE C-2. AREA SOURCE CODE ASSIGNMENTS
ASC
ACS DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBER
6
6
6
27
28
29
30
35
35
35
36
36
36
37
37
37
38
38
38
40
40
40
40
RESIDENTIAL FUEL-WOOD
H II
H M
LIGHT DUTY GASOLINE VEHICLES-
L Id I TED ACCESS ROADS
LIGHT DUTY GASOLINE VEHICLES-
RURAL ROADS
LIGHT DUTY GASOLINE VEHICLES-
SUBURBAN ROADS
LIGHT DUTY GASOLINE VEHICLES-
URBAN ROADS
HEAVY DUTY GASOLINE VEHICLES-
LIMITED ACCESS ROADS
M N
H M
HEAVY DUTY GASOLINE VEHICLES-
RURAL ROADS
» M
» II
HEAVY DUTY GASOLINE VEHICLES-
SUBURBAN ROADS
H M
M H
HEAVY DUTY GASOLINE VEHICLES-
URBAN ROADS
• •
* H
HEAVY DUTY DIESEL VEHICLES-
LIMITED ACCESS ROADS
M It
M H
M H
42317
42318
42319
31202
31202
31202
31202
31103
31104
31105
31103
. 31104
31105
31103
31104
31105
31103
31104
31105
32203
32204
32205
32206
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
E
C
209
210
211
220
220
220
-
220
215
217
219
215
217
219
215
217
219
215
217
219
229
231
232
233
41
41
HEAVY DUTY DIESEL VEHICLES-
RURAL ROADS
32203
32204
C
C
229
231
C-10
-------
TABLE C-2. AREA SOURCE CODE ASSIGNMENTS (Continued)
ASC
ACS DESCRIPTION
PROFILE
NUMBER
DATA DOCUMENT
QUALITY PAGE NUMBER
41
41
42
42
42
42
43
43
43
43
55
55
55
57
58
58
58
58
58
62
62
62
62
62
62
62
62
62
62
62
62
110
110
110
110
110
110
110
II ^
It
HEAVY DUTY DIESEL
SUBURBAN ROADS
M
11
H
HEAVY DUTY DIESEL
URBAN ROADS
II
H
II
II
II
VEHICLES-
M
H
H
VEHICLES-
II
II
H
UNPAVED ROAD TRAVEL
II
H
CONSTRUCTION
MISCELLANEOUS WIND
»
H
II
»
AGRICULTURAL FIELD
H
H
M
tl
N
H
N
H
II
N
H
II
H
EROSION
H
II
It
H
BURNING
H
H
H
M
N
M
H
M
H
M
H
TRANSPORTATION COMPOSITE
M
M
M
(1
H
U
II
II
II
II
H
H
32205
32206
32203
32204
32205
32206
32203
32204
32205
32206
41205
44102
44101
44104
41321
41322
41323
41324
41351
42305
42306
42307
42308
42309
42310
42311
42312
42313
42314
42315
42316
33004
33005
33006
33007
33008
33009
33010
E
C
C
C
E
C
C
C
E
C
C
C
C
C
C
C
C
C
C
E
E
E
E
E
E
E
E
E
E
E
E
C
C
C
C
C
C
C
232
233
229
231
232
233
229
231
232
233
149
256
255
258
183
184
185
186
187
197
198
199
200
201
202
203
204
205
206
207
208
234
236
238
240
242
244
246
C-ll
-------
TABLE C-2. AREA SOURCE CODE ASSIGNMENTS (Continued)
ASC
ACS DESCRIPTION
PROFILE
NUMBER
DATA
QUALITY
DOCUMENT
PAGE NUMBER
^
110
111
111
111
112
112
112
112
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
113
115
115
115
115
115
115
It H
LIGHT DUTY DIESEL VEHICLES
ii »
» N
TIRE WEAR
n
n
M
PAVED ROADS
II
II
H
II
n
H
H
U
M
H
II
II
M
It
It
U
H
H
N
H
VOLCANIC ASH
M
H
n
N
N
33011
32102
32103
32104
34003
34004
34005
34006
41111
41112
41113
41114
41115
41116
41117
41118
41119
41120
41121
41122
41123
41124
41131
41132
41133
41134
41135
41136
41137
43304
43305
43306
43307
43308
43309
C
C
C
C
E
E
E
E
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
C
c
'" C
c
E
E
E
E
E
E
247
224
226
228
249
250
251
252
153
155
156
157
159
160
161
162
164
166
167
168
169
171
173
174
175
176
177
178
179
188
189
190
191
192
193
C-12
-------
APPENDIX D
PM PROFILE COMPOSITING PROCEDURE
D-l
-------
D-2
-------
APPENDIX D
PM PROFILE COMPOSITING PROCEDURE
Composite profiles were prepared for several of the new PM species
profiles appearing in this document. In addition to the 147 new profiles
identified in this addendum, 11 composites were developed for source
classification codes (SCC's) that had multiple profile assignments.
Composites were only prepared after a careful examination of the individual
profiles assigned to the same SCC to ensure that the same source type existed
and that the data could logically and technically be composited. Composites
were not prepared for road dust profiles because of the unique site-specific
applicability of these profiles.
In the broadest sense, the composites represent-average values for each
specie emitted by the source type/SCC in question. The objective in providing
composites is to simplify the use of profiles for all user groups whether they
are compiling emission estimates or conducting source-receptor modeling.
Composites are generated strictly from calculational procedures and therefore
may be computed in a variety of ways. The methods used to produce the
11 composite profiles in this addendum to the Species Manual are summarized in
this appendix.
The first step in the compositing process was to identify SCC's that had
multiple profile assignments. Once this was done, the individual profiles
within a given SCC were evaluated for consistency (i.e., were they actually
all describing the same source type). Often an SCC may be general enough that
several related but slightly differing operations are categorized together.
To ensure suitability for compositing, the emission source type must be the
same among profiles and other factors governing emissions such as fuels or
materials processed and control equipment must be the same. Where these
factors were all consistent, compositing was possible.
Once the individual profiles to be composited had been determined, the
species present in each profile were evaluated to determine which could be
composited. For the purposes of this addendum to the PM Species Manual,
D-3
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composites were only prepared for species that were analyzed in each
individual profile assigned to the same SCC (i.e., same source type,\control
device, etc.). For example, if there were five profiles to be composited and
two of the five did not analyze for silver in any size range, then silver was
not made a part of the composite. A specie was included as long as each
profile was analyzed for it in at least one particle size range.
The only exception to this general rule was Profile 11215, which
included several species that did not occur in every input profile. The seven
input profiles for the composite contained only five species that were shared
by all profiles. Since the number was so few, an optional approach was used
to increase the number of species in the composite. For the purposes of the
composite Profile 11215, a specie was composited if it occurred in at least
four of the seven input profiles. This increased the number of species in the
composite to 19.
Once the target list of species to be composited was established, the
compositing procedure became a simple calculational exercise. Similar specie
values within each particle size range were arithmetically averaged to produce
the composite values. In cases where a specie was analyzed for in most but
not all particle size ranges, the missing range was excluded from the
averaging procedure. For example, if there were three profiles with arsenic
values but in one profile the 2.5-10 urn size range was not evaluated, the
composite profile for arsenic at 2.5-10 urn would be based on an average of two
values instead of three.
Data quality assignments for the composites were based on the quality
ratings of the individual contributing profiles. If all of the individual
profiles for a composite were- of like quality, e.g., C, then the composite was
also rated at C. If the individual profiles had varying quality ratings, then
a subjective decision was made regarding the overall trend of the data
ratings. If the majority of individual profiles in a composited group had a
lower rating (e.g., three were D's and two were C's), then generally the lower
rating was assigned to the composite. Because of the nature of the composting
process, data quality rating assignments for the composites tended to be
conservative so as to not over emphasize the usefulness of the composites.
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Uncertainty was not evaluated for the 11 composites prepared for this
addendum. The reasons for this decision were that several of the individual
profiles did not address uncertainty and the technical validity of averaging
the available uncertainty estimates in a composite is questionable.
D-5
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D-6
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APPENDIX E
DOCUMENTATION OF THE MOBILE SOURCE
PROFILE DEVELOPMENT PROCEDURES
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APPENDIX E
Documentation of the Mobile Source Profile Development Procedures
The purpose of this appendix is to provide a description of the
calculation procedures used to develop VOC speciation profiles for the Light-
Duty Gasoline Vehicles (LDGV) category. The specific profiles of concern are
1101, 1203, and 1204. The Light-Duty Gasoline Vehicles Profile 1101 was
developed using the 46 in-use passenger car study conducted by Sigsby, et al.1
Exhaust and evaporative (hot soak) emission composition data collected during
this study were composited using information from AP-42, Volume II (fourth
edition).2 Data generated by Sigsby, et al did not contain measurements of
diurnal emission composition. Therefore, diurnal emission composition data
were estimated using data from a study by Black and High and another study by
Gabele.3-4
The data set from the 46-car study was representative of in-use vehicles
from 1975 to 1982. For model years prior to 1975 and after 1982, it was
assumed that the data for model years 1975 and 1982, respectively, would be
representative.
The following procedure was used in developing Profile 1101:
(a) For each car, estimate average exhaust emission composition from
the Federal Test Procedures (FTP), New York City Cycle (NYCC), and
Crowded Urban Expressway (CUE) test data:
Exhaust average car - (FTP + NYCC + CUE)/3
(b) For each model year, calculate average exhaust emission
composition:
n
Exhaust average model year » iml exhaust average car/n
where n is the number of cars tested for a given model year.
(c) For each model year, calculate average hot soak evaporative
composite:
n
Hot soak average model year - *mi hot soak car/n
(d) Estimate an average diurnal evaporative composition using the data
from References 3 and 4. Assume this represents all model years.
(e) For each model year, estimate average evaporative emission
composition:
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Evaporative average model year » (0.265 x hot soak average model
year + 0.735 x average diurnal)/2
The weighting factors 0.265 and 0.735 were estimated from
Reference .5..
(f) Estimate weighting factors for exhaust and evaporative emissions
for model years 1968-1987. Use AP-42 (pp. H-4,6) for LDGV at low
altitude (including tampering).
estimate accumulated mileage
estimate evaporative emissions
estimate exhaust emissions
estimate fraction of evaporative emissions (fev)
estimate fraction of exhaust emissions (fex)
(g) Estimate weighted average exhaust/evaporative emission composition
for each model year:
Exhaust/evaporative average model year -
f.x(exhaust average model year) + f.v(evaporative average model year)
(h) Estimate travel fraction (ftr) for each model year from 1968-1987.
Use the procedure in AP-42 (pp. H-11,12).
(i) Weight the profiles from (g) by travel fractions estimated in (h).
1987
Profile 1101 - 196a fer model year x (Exhaust/evaporative
average model year)
In the profile data, 15 percent of n-butane in exhaust emissions was assumed
to exist as 1,3-butadiene.6'7 Also,, the split between cyclohexane and benzene
in the cyclohexane/benzene peak was assumed as 50/50.3
The approach used for developing Profiles 1203 and 1204 to represent
exhaust and evaporative emissions, respectively, from light-duty vehicles was
similar to that used for Profile 1101. For Profile 1203, steps (c), (d), (e),
(f), and (g) outlined for Profile 1101 were not applied. Step (i) was applied
after the exhaust average model year term replaced the exhaust/evaporative
average model year term. For Profile 1204, steps (a), (b), (f), and (g) were
not applied. In the final step (i), the exhaust/evaporative average model
year term was replaced by the evaporative average model year and the ftr model
year term was applied to only the hot soak average model year position.
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FACTORS USED IN DEVELOPING PROFILE 1101
Year f.x fev ftr
1968
1969
1970
1971
1972
1973
1974
1975
1976
1977
1978
1979
1980
1981
1982
1983
1984
1985
1986
1987
.67
.67
.68
.71
.72
.72
.72
.70 .
.69
.68
.84
.83
.69
.66
.63
.60
.56
.50
.40
.33
.33
.33
.32
.29
.28
.28
.28
.30
.31
.32
.16
.17
.31
.34
.37
.40
.44
.50
.60
.67
.004
.003
.005
.007
.011
.016
.021
.028
.034
.041
.049
.056
.065
.074
.084
.097
.110
.123
.135
.038
f., - exhaust average model year emission composition.
f.v = evaporative average model year emission composition
ftr = travel fraction for each model year.
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APPENDIX E REFERENCES
1. Sigsby, J. E., Jr. et al. Volatile Organic Compound Emissions from 46
In-Use Passenger .Cars. Environmental Science and Technology, Volume 21,
No. 5, 1987. pp. 466-475.
2. U. S. Environmental Protection Agency. Compilation of Air Pollutant
Emission Factors, Volume II - Mobile Sources, AP-42 (fourth edition).
September 1985.
3. Black, F. and L. High. Passenger Car Hydrocarbon Emissions Speciation.
EPA Report No. EPA-600/2-80-085. U. S. Environmental Protection Agency,
Research Triangle Park, North Carolina. May 1980.
4. Telecon. Gunseli Shareef, Radian Corporation with P. A. Gabele, U. S.
Environmental Protection Agency. July 1987. Diurnal emission
composition data.
5. Black, F. HC Emissions from Late Model Gasoline Motor Vehicles. U. S.
Environmental Protection Agency, Research Triangle Park, North Carolina.
1987.
6. Memorandum from John E. Sigsby, Jr., U. S. Environmental Protection
Agency/Atmospheric Sciences Research Laboratory to John Summerhays,
U. S. Environmental Agency/Region 5. January 30, 1987. Review of
report "Air Toxics Emission Inventory for the Southeast Chicago Area".
7. Telecon. Gunseli Shareef, Radian Corporation with Penny Carey, U. S.
Environmental Protection Agency/Office of Mobile Sources. March 24,
1987. Percentage of 1,3-butadiene in vehicle emissions where it is
reported as n-butane/ 1,3-butadiene.
8. Memorandum from Gray, C. L., U. S. Environmental Protection Agency to J.
Calcagni, U. S. Environmental Protection Agency and W. Laxton, U. S.
Environmental Protection Agency. March 23, 1989. Motor Vehicle VOC
Speciation for SIP Development.
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TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT MO. 2.
EPA-450/2-88-003c
4. TITLE AND SUBTITLE
Addendum To The Air Emissions Species Manual
7. AUTHOR. PERFORMING ORGANIZATION NAME AND ADDRESS
Radian Corporation
Post Office Box L3000
Research Triangle Park, NC 27709
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
OAR, OAQPS, AQMD, NPPB, PCS (MD-15)
Research Triangle Park, NC 27711
3. RECIPIENT'S ACCESSION NO.
5. REPORT DATE ,non
October 1989
6. PERFORMING ORGANIZATION CODE
la. PERFORMING ORGANIZATION REPORT NO.
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-02-4286, W/A #: 91
13' TYP^Fna!P
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