&EPA
United States
Environmental Protection
Agency
Office of Air Quality
Planning and Standards
Research Triangle Park NC 27711
EPA-450/3-85-006
February 1985
C,
Air
Hazardous Waste
Ranking
Assessment of Air
Emissions from
Hazardous Waste
Treatment, Storage,
And Disposal
Facilities
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EPA-450/3-85-006
Hazardous Waste Ranking
Assessment of Air Emissons from
Hazardous Waste Treatment, Storage, and
Disposal Facilities
Prepared by
GCA'Technology Division
GCA Corporation
Under EPA Contract No, 68-02-31 68
U-S. Enwronmenfal Prrt-rtinn A
R-S
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DISCLAIMER
This report has been reviewed by the Office of Air Quality Planning and Standards, U.S. Environmental
Protection Agency, and approved for publication as received from GCA/Technology Division, GCA Corporation
Approval does not signify that the contents necessarily reflect the views and policies of the U.S. Environmental
Protection Agency, nor does mention of trade names or commercial products constitute endorsement or
recommendation for use. Copies of this report are available from the National Technical Information Services,
5285 Port Royal road, Springfield, Virginia 22161.
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SPECIAL NOTE
(No
fi
Eme
No.
Gag
S
wa«
r-'
dir
of
A D-ft Final Report (Dece-ber 1982) and a Revised Draft Final Report
vember 1933) previously developed for this project were prepared and
nished to U.S. Environmental Protection Agency, Ofrice of Solid kaste anc
rgency Response (OSWER) , Land Disposal Branch, under Contract
63-02-3153 (Technical Service Area 3, Assignment No. 82). Ms. Alic C.
non served as EPA Projeect Officer and Dr. Seong T. Hwang of ^^f
ved as Task Officer for these efforts. On Decker 23, 1933, hazardous
t» treatment, storage, and disposal facility (TSDF) area source e~.xss.ons
ulator.- develo,.ent"was transferred fron OS-TR to the Ortice or Air Qu,
_._ a.d standards (OAQPS). This Final Report was prepared «*« "e
ection of E?A/OAC?S Task Officer, Kent C. Kustvedt, in partial fulriUn-.en
f Contract No. 63-31-6
Assignment No. 3
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CONTENTS
Figure .................................. v
Tables .................................. .v
Acknowledgment .............................. V11
1. Introduction and Summary ............. ........
Introduction ......................... ^
Project Methodology ...................... 2
Hazardous Waste Pr iorit ization Ranking Results ........ 2
Input Data Development ................ '. ' * '
2. Estimation of Total Hazardous Waste Quantities and Distribution . . 12
Hazardous Waste Quantity Determination ............ 12
Dist-ibution of Waste Between TSDF Unit Processes ....... 16
Results ........... ................ "
3. Development of Waste Characterization Data ............. *°
Data Sources ......................... ^
Data Source Quality ...................... ^
Characterization Methodology ................. 5<+
Characterization Results ................... ^
4. Compilation of Chemical Properties and Health Effects Data ..... 61
Chemical and Physical Properties Data ............. 61
Health Properties Data .................... 6°
5. Hazardous Waste Ranking Methodology ................ 7^
Development of Hazard Factors ................. ^
Hazardous Waste Prioritization Ranking Results ........ 77
Q f~
Conclusions ..........................
_=_ ....................... 33
Aendices
A. Waste Type Descriptions and Properties
3. Comoutar'outout of Hazardous Waste Prioritization Ranking Scores
iv
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FIGURE
Number Page
1 Hazardous waste type ranking methodology 3
TABLES
noer
Page
1 Listing of Ten Highest Ranked Waste Types Based on Toxicity
Criteria for Aqueous and Non-Aqueous TSDF Categories 4
2 Listing of Ten Highest Ranked Chemical Constituents Based on
Toxicity Criteria for Aqueous and Non-Aqueous TSDF Categories . . 5
3 Listing of Ten Highest Ranked Waste Types Based on Carcinogenicity
Criteria for Aqueous and Non-Aqueous TSDF Categories 6
4 Listing of Ten Highest Ranked Chemical Constituents Based on
Carcinogenicity Criteria for Aqueous and Non-Aqueous TSDF
Categories 7
5 Preliminary Screening of Waste Volume by Waste Types 13
6 Preliminarv Screening of Waste Volume in Aqueous Processes by
Waste Type 2S
7 Preliminary Screening of Non-Aqueous Processes by Waste Type ... 38
8 EPA Hazardous Waste Codes for Which Waste Characterization Data
Exists 50
9 Example of Mitre Report Data: Facility 108 53
10 Waste Characterization Results ^7
11 Summary of Pertinent Chemical Property Data 62
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TABLES (continued)
Number Page
12 Correlating Constants for Activity Coefficients at Infinite
Dilution, Homologous Series of Solutes and Solvents ....... 67
13 Modification of Terms in the Basic Activity Coefficient
Equation 69
14 Correction Factors for Log Y^} per Group 70
15 Maximum Allowable Concentrations at 10~5 Risk Level 72
16 Waste Type Toxicity Ranking Scores for Aqueous and Non-Aqueous
TSD" Categories 73
17 Chenical Constituent Toxicity Ranking Scores for Aqueous and
Non-Aqueous TSDF Categories 82
15 Vaste Type Carcinogenicity Ranking Scores for Aqueous and
Non-Aqueous TSDr Categories 8-+
19 Chemical Constituent Carcinogenicity Ranking Scores for Aqueous
and Non-Aqueous TSDF Categories 87
VI
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ACKNOWLEDGMENT
A number of EPA and GCA staff members contributed to this preliminary
study of T3DF air emissions. Mr. Jon Perry of OSWs Land Disposal Branch
served as the Task Officer during the initial stages of the program.
Dr. Seong T. Hwang assumed Task Officer responsibility partway through the
effort, and his guidance was especially helpful. Mr. Ed Martin and Ms. Karen
walker of OS'.v's Technology Branch assisted in program planning, coordination
and work plan development. Their contribution in obtaining waste character-
ization data is gratefully acknowledged. A number of additional OSW staff
members also contributed to data collection and program planning efforts. GCA
staff who assisted in the large data manipulation task include Ron Bell, Tom
Fitzgerald, and Michael Kravett.
VI 1
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SECTION 1
INTRODUCTION AND SUMMARY
INTRODUCTION
The hazardous waste prioritization presented in this report was designed
to provide a first cut estimate of the inhalation health impact potential of
hazardous wastes currently being disposed in the United States. The primary
objective of this wasta prioritizaticn ranking was to identify a select group
(^"hazardous wastes for subsequent analysis of air emissions under other
projec t s.
This report provides several ranking schemes to prioritize select RCRA
wastes based on potential health impacts from TSDF air emissions The ef.ort
presented herein is an expansion of a previous effort which ranked RCRA
chemicals on the basis of volatility and toxicity.l The revised ranking
r-Ues on a more sophisticated definition of volatility, and addresses health
impacts on the basis of both inhalation toxicity and carcinogenicity. The
-evised prioritization presented in tnis report was tailored to respond to
review comments received from the Land Disposal and Technology Branches or
OSW the Office of Health and Environmental Assessment (OHEA)/Wasnington, ,ne
Environmental Criteria Assessment Office (ECAO)/Cincinnati, and tne Carcinogen
Assessment Group (GAG)/Washington.
Revisions incorporated into the revised ranking in response to review
comments included the following.
. Development of separate prioritization rankings for toxic and
carcinogenic effects.
Inclusion of data to permit the accounting of hazardous constituent
concentration in the wastes.
. Consideration of TSDF process category by segregating processes into
aqueous and nonaqueous types.
Development of hazardous waste rankings based on: (1) waste type;
and (2) chemical constituent.
Th» rosultin- waste ranking provides a numerical comparison of potential
ai- emission hazard for a waste- It involves the computation of inhalation
coxicitv and carcinogenicity hazard factors for each waste evaluates These
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factors are defined as the ratio of the equilibrium gas concentration for a
compound (Ceq^) to either the Threshold Limit Value (TLV) for the
calculation of toxicity hazard factors or the maximum allowable concentration
at the 10-3 Risk Level (10~5 RL) for carcinogenicity hazard factors.
These ratios allow for the relative comparison of air hazards associated with
the toxicity or careinogenicity of a waste.
The remainder of this section provides an overview of the project metho-
dology and the results of the hazardous waste air emissions prioritization.
Each element of the study is discussed in detail in the remaining sections of
the report. Hazardous waste volume determinations and characterization are
discussed in Sections 2 and 3, respectively. Section 4 presents the
assessment of chemical properties, toxic and carcinogenic effects. The hazard
factor development and ranking results are presented in detail in Section 5.
PROJECT .METHODOLOGY
A four step procedure, illustrated in Figure 1, was employed for the
development of the hazardous waste prioritization. The first step involved
waste volume determinations and characterization of waste types. The initial
selection of candidate wastes for the prioritization ranking was to a limited
extent based on the preliminary waste volume results and the availabilitv of
characterization data. Chemical and health effects properties (toxicity and
carcinogenicity) were assessed for the chemical compounds identified in the
second step of this ranking method. The third step involved the computation
o: aqueous and nonaqueous hazard factors for each waste type and chemical
compound. The final step involved the weighting of hazard factors according
to waste volumes for the associated waste types.
HAZARDOUS WASTE PRIORITIZATION RANKING RESULTS
The hazardous waste prioritization ranking procedure described above
produced eight listings of hazardous waste types and chemical compounds.
Separate listings for toxic and carcinogenic effects represents the two aajor
categories of ranking lists provided. These two categories are addressed
separately since no common basis of comparison is currently available which is
acceptable^to the scientific community. Subcategories within these two aajor
groupings include: (1) separate listings for aqueous and nonaqueous TSDF
types; and (2) separate listings by hazardous waste type and chemical compound
type. Tables 1 through 4 summarize these results for the top ten waste types
and chemical compounds in each category. Complete listings of hazard scores
for all data analyzed are presented later in Section 5 of this report.
In general, the ranking scores for aqueous TSDF wastes were several
orders of magnitude greater than those for nonaqueous TSDF processes due to
the hydrophobic nature of many of the hazardous constituents analyzed. The
low solubility (water) of many of these chemical compounds results in a high
activity coerricient used in calculating the vapor phase equilibrium
c Dicentrat ion round in tne numerator of the hazardous factor expression. This
general trend indicates that nonaqueous disposal processes such as landfarmin-
or landrills would tend to pose less of a relative air emissions health impact
tnen aqueous TSDF processes.
2
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STEP 3
STEP i
WASTE TYPE CHARACTERIZATION
WASTE VOLUME RANKING
BY TSDF TYPE
CH-MICAL PROPERTIES AND HEALTH EFFECTS ASSESSMENT
.' PARTITIONING TO AIR TOXICITY AND
CARCINOGENICITY
vASTE TYPE AND CHEMICAL COMPOUND
HAZARD RANKING
FINAL WASTE TYPE RANKING
Hazardous wasta tvoe ranking methodologv
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TAHI.K 4. LIST INC OF TKN II1 CHF.ST KANKl'l) CIIKN I CAI, CONST IT1IKNTS HASH!) ON CAKC INOC.KN 1 C 1TY CR1TKR1A
I--OK Aqill'OIJS AND NON-AQUKOUS TSUI- CATKCOKI MS
No n- Aqueous, TSDF C.I tegor 1 es,'1
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''Aiueoub (Al)) TSDF CdtugorK-s.
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Note Chat ranking scores for the carcinogenicity hazard assessment tend
to be higher than these for the toxicity assessment. This is primarily
because the 10~^ risk level concentrations selected as the carcinogenicity
indicator parameter tends to be very low concentrations, producing
correspondingly high hazard factor scores. The reader is cautioned thai the
toxicity and carcinogenicity rankings presented in this report provide a basis
for relative comparison of wastes within each ranking list and cannot be
compared against each other. Simply stated, direct comparison of toxicity
hazard scores to carcinogenicity hazards scores presented in this report is
not advisable.
Table 1 presents the waste type toxicity ranking scores for the ten
highest scored waste types from aqueous and nonaqueous TSDF categories. Note
that the volume-weighted scores shown are greater for aqueous wastes in spite
of larger nonaqueous waste volumes. Five waste types common to both lists
presented in Table 1 include:
D001 - Ignitable wastes, not otherwise listed;
D002 - Corrosive wastes;
KQ29 - 1,1,1-TCE steam stripper waste;
F002 - Spenc halogenated solvents; and
U019 - Benzene, discarded off-specification wastes.
The ^eneric D-tvpe wastes were found in great volume (D001 also showed a very
high hazard factor). In general, the remaining wastes showed both high hazard
factors and large waste volumes.
Table 2 presents the results of the toxicity ranking scores for the ten
highest scored chemical constituents. As expected, the chemical constituent
results follow trends similar to the waste type ranking. Seven waste
constituents common to both lists presented in Table 2 include:
U122 - Formaldehyde;
U043 - Vinyl chloride;
"J079 - 1,2-dichloroethylene;
U019 - Benzene;
U196 - Pyridine;
U239 - Xylene; and
U226 - 1,1,1-trichloroethane.
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- Of chese wastes, xylene and 1 ,2-dichloroethylene , were among the eight
i'l-,~*li contributors to TSDF constituents identified in an earlier study^ on
n'-ional emissions estimates from TSDFs.
o- 3 presents the results of the carcinogenicity ranking
,,_ -e ten highest scored waste types from aqueous and nonaquoues TSDF
""1 Vo-ies Final volume-weighted scores were approximately four orders of
~,"nitude greater for aqueous TSDFs, than for the nonaqueous category. Seven
waste types found in both categories include:
K016 - Carbon tetrachloride production heavy ends;
K073 - Chlorinated hydrocarbon wastes from chlorine production;
F002 - Spent halogenated solvents;
D003 - Reactive wastes, not otherwise listed;
F001 - Spent halogenated degreasing solvents;
D001 - Ignitable wastes, not otherwise listed; and
U019 - Benzene, off-specification discarded.
~-e top two K-tvpe wastes (K016 and K073) are listed here primarily due to
."ery high hazard factors. The other generic F and D type wastes appear due to
substantial waste volumes.
Table 4 oresents the waste type carcinogenicity ranking results by
--e-ni-al constituent type for the top ten chemical compounds. Note that only
:en chemical compounds were included in this analysis because characterize^ «
aata were not found for many of the carcinogens identined by CAG.
Tae prioritization rankings presented above provide a comparative
analysis for the potential health impacts associated with air emissions from
hazardous waste handling. Note that the scores presented are oased on waste
volumes handled on a national scale- Local conditions, including waste
volumes handled and disposal practices, may affect the relative impact of air
emissions from one waste to another.
INPUT DATA DEVELOPMENT
The following discussion briefly summarizes the development of input data
reouired to produce the hazardous waste prioritization ranking.
Waste Volume and Distribution
GCA used RCRA Part A permit application data to estimate waste volumes
for the waste ranking analysis. Initial Part A results which predicted 4_
billion tonnes of waste clearly suggested the need for statistical screening
-p-hods to eliminate erroneous data resulting from reporting errors and
r-dundant waste accounting. GCA employed a statistical outlier screening
ion
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methodology aided by information obtained from other data sources, including
the Westat telephone verification survey,^ the RIA site visit questionnaire
data, and other E?A-sponsored studies.^"'
The outlier screening analysis rejected 76S of the original 150,000 Part
A waste streams, reducing the total waste volume to 107 million tonnes. The
Part A data were further screened to correct for the redundant accounting of
offsite waste disposal. The redundancy correction reduced the total estimated
hazardous waste annual quantity to 92 million tonnes.
Use of the statistically-cleaned Part A data was complicated by its
inherent vagueness with respect to wastes processed by two or more TSDFs.
Much of the Part A wastes were processed by more than one unit operation, and
no volume distribution among processes was provided. Consequently, several
assumptions were required to distribute waste volumes among TSDF unit
processes as described in Section 2. While the assumptions may be completely
inadequate in some cases, it is felt that the method of redistribution is
reasonably representative of the entire waste population. Independent
comparisons of corrected Part A data waste volumes to Westat verification
data^ showed agreement to within 2 percent for volumes handled by four TSD?
unit processes which could be compared.
Waste Characterization
Waste characterization data and chemical property information were
required for input to the hazardous waste ranking. The goal was to rank the
emissions risk potential for all selected chemicals based on their presence in
both the chemical-specific (U and P) waste codes, and the generic waste codes,
(K, D and F). Wnen it became clear tnat no comprehensive RCRA waste
characterization effort had been conducted for all TSDF types and waste codes,
GCA collected and compiled available data from several EPA programs. Waste
characterization data were summarized for 47 generic waste codes and 54
chemical specific codes, representing almost 50 percent (30 million tonnes) of
the total waste volume reported in the statistically-screened Part A data for
the unit processes under study.
Data from multiple reference sources^"^ characterizing single waste
codes were averaged using a volume weighting procedure. The weighted concen-
tration data were converted to mole fractions for use in the AERR models.
These data were combined with the screened Part A volume data to produce
constituent quantity data for each TSDF unit process for emission estimates.
Chemical Properties and Health Effects Data
Chemical properties of the 54 hazardous constituents selected for study
were summarized for use in the waste ranking efforts. Upon examination of
approximately 95 percent of the total wasta volume reported, GCA determined
that 100 waste types had data appropriate for the computation of a toxicity or
care inogsr.icitv hazard factor. Many chemicals such as arsenic and chromium
either had no vapor pressure data available or had vapor pressures
10
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-r.ificantly less than 1 mmH> at 25°C. Chemicals lacking published vapor
-^s^ure data or necessary health properties data are not listed in this
ioritization report.
Similarly, sufficient carcinogenicity data were found for oaly 52
he-.ical compounds. The chemical, physical, and health properties data that
.ore compiled are presented in Appendix A. Details on the chemical property
aca estimation techniques employed and health effects data obtained are
ncluded with a summary of these data in Section 4 of this report.
11
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SECTION 2
ESTIMATION OF TOTAL HAZARDOUS WASTE
QUANTITIES AND DISTRIBUTION
RCRA Part A per.it application file (screened to remove outliers);
Part A verification data developed for OSW by Westat;3
. Land application data compiled for OSW by K. W. Brown, Inc;4
. Limited data from the land disposal and storage RIA program;
EPA reports; 5, 6 and
Other technical literature.
for
nt of ««.
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ent,re waste stream to
quantity of ^"
facilities which c
streams prior to treatment,
report the combined volume
wastes are shipped to of *
waste is well defined; ^
also representative of the
transportation costs would
nhazardous material.
s streams with hazardous
would frequently
»"ra e^ o V ^^ ^re hazardoU9
as h««dou8. ticy of hazardous
hipped or received. It is
.ru. stream quantity since
"Jual h. untiecessary 8hlpp«ig of
Preclu°* majority of hazardous
U'-ly that significant
'"
ultiple RCRA ^.ardous
dictate reporting wastes by
define that particular waste
comprised of multiple codes
under each code. In ad^J
streams denoted by U and P
£
,e
streams denoted by U and P was.e co
their generic counterparts CD, F ana
e used to
for waste streams
e voluffle may be reported
constituents of waste
mav also be reported under
Erroneous data are reported
instance, Part A.da = a_ contained eigh .sin -ng 1Q m,lUon
ific facilities with "^^"^^tic quantity because total
ic tons. Tnis is ^"^.^"imated as 41 million metric
1^ ^Sl-1 Sl^Sr.?^"^ .illi« -s, recent estate.
Statistical elimination of erroneously reported., is^indere. by
Q
A f^nm E^A was found to contain data for
The Part A data tape received from t.A listed waste
Ta^dous waste sites throughout tne ^'^7^47,177 individual
.es "for u? to 495 separate waste cod"' * avera<,ina 16 waste types per
waste stream-were reported on th«> *«* ' ^ in°dicated that _ the voiunes
-;:;te--jroSna::K:ct n ^^ -«** -d/- pr°8ra^ing e
13
-------
.
in the Part A data.
^:^:
developed to eliminate outliers from the data:
.
ii » Fi Jht waste volumes were affected by this step,
C^e3 total' volume reported fro, 4 billion to 541 million metric tons
standard deviation, and sample size, were developed for the
regaining 76,3^7 waste streams by waste code.
for each reported waste volume was:
If tiw _> tUw, 0.01),
Chen reject that volume;
for
iw
S
/N
w V w
where ,
tiw = t statistic for observation "i" of waste "w" ,
QNT-W = volume reported for observation "i" of waste "v" ,
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Q1*TW = mean volume for waste "w",
Sw = standard deviation of volume reported for waste "w", and
Nw = sample size of volume reported for
facilities h*H 6 .°Utiers indicated that a small number of
s- :
ton,
n
adaxtLonal 2,50o waste steams previously excluded from the data set Thus
retined outlier analysis eliminated 763 or 1.0 percent of the 76 84 total'
Redundant Waste Quantity Correction
arnuJ"^ ^f SCeP ^ the W3Sta V°Lurae ^termination involved makin-
allowances for wastes that were disposed offsite and thus counted o3o-e than
once under the Part A reporting requirements. Under this corrective s^eme
all wastes tnat reported storage in tanks or containers onlv were ass^ed t'o
be 100 percent reported elsewhere as well. Waste stored^nTy in surtace
impoundments and waste piles were assumed to be 50 percent reported etsewhere
oc^j MaVinf :tl°r WaSte/eduCCion ^^^ evaporation etc! was assumed to
, of hazardous wastes are disposed offs'te
Resourcesy;oardC(l5gperceno!7Wlth ^ re*Oft*d by thC Califo"ia Air *
15
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next
OF WASTE BETWEEN TSDF UNIT PROCESSES
* nex step in determining annual hazardous waste quantities involved
allocation among the TSDF processes. Unfortunately, this task was
- Mi -a ted because the Part A applications were extremely vague in this
~^'a ^The main complication arises when a facility reported more than one
^:-'unit process for a given waste stream. Facilities were permitted to
;^o- as many as six TSDF processes for each waste code. The following
discussion presents methods developed to handle these Part A reporting
problems.
GC^v initially determined that estimating waste distribution between
o'o-esses would be best accomplished by extrapolating from waste streams
Bridled by a single unit process. These single process streams accounted for
approximately 40 percent of the total waste streams reported, by frequency.
-owever, based on further analysis of other distribution schemes, GCA
concluded that the single process apportionment scheme did not adequately
cescribe the distribution of wastes among TSDF processes.
The following methodology was then developed for allocating waste
Guantities between processes:
. Waste streams reportedly handled by a single process would remain
allocated to that process;
. Waste streams reportedly handled only by storage processes would be
equally distributed among storage processes listed;
Waste streams reportedly handled only by treatment/disposal
processes would be evenly allocated among those treatment/disposal
processes ; and
Waste streams reportedly handled by storage and treatment /disposal
processes would first be evenly allocated among the storage
processes; i.e. GCA assumed all of the waste was stored in some
fashion. Secondly, all of the waste handled in storage containers
and tanks and 50 percent of the waste handled in storage impoundments
and waste piles was assumed to then be evenly distributed among the
reported treatment/disposal processes. This assumption is similar
to that used in the redundant waste quantity correction. _It
attempts to account for the degree of waste volume reduction which
takes place when wastes are stored in open air processes.
A major limitation of the distribution scheme selected for hazardous
waste rankin" is that wastes are assumed to exhibit an equal distribution
between reported processes. It is highly likely that when site owners
reported multiple processes, there are several combinations which generally
have a disproportionate amount of waste going to one of the processes. _For
e^-nple, when" a disposal process (e.g., landfill) is listed in combination
with' a treatment process (e.g., treatment tank), it is likely that more than
=0 oercent of the waste is handled in the treatment process. This follows
fro-, thp fact that wastes will likely be treated and then disposed rather than
16
-------
the reverse. Another limitation of this distribution scheme is that wastes
are not distributed among processes in the same proportion in the Part A
data. Streams which contain a high liquid content will not be landfilled,
incinerated, or stored in a waste pile, to a significant extent.
RESULTS
The results of the Part A analysis with the corrected waste volumes are
presented in Table 5 wherein waste types or codes (as described in the Federal
Register8) are listed in order of decreasing disposal volume. Chemical
specific waste codes (U and P codes) and generic waste stream specific codes
(D, F and K codes) are defined in Appendix A, Tables A-l and A-2,
respectively. The data in Table 5 indicate the total waste volume for each
code in metric tons, the percent of total U.S. volume and the cumulative
percent accounted for by the listed waste codes. The total U.S. volume, after
data corrections described previously, is 91.6 million metric tons. The
highest volaine waste type is D002--nonlisted corrosive wasteswith an annual
disposal volume of about 25.6 million metric tonnes (MT) or 27.9 percent of
the'total corected Part A volume. Other high volume wastes include D007
(chromium waste), DOOO (any combination of arsenic, barium, cadmium, and
chromium waste), K062 (wasta pickle liquor), and D003 (nonlisted reactive
wastes).
Tables 6 anc 7 present similar data for aqueous and nonaqueous processes,
respectively. As part of the revised ranking approach presented in this
report, GCA' took into consideration influence of the TSDF process
subcategorv. TSDF processes were divided into aqueous and nonaqueous
categories as follows:
Aqueous Processes
S04 - Storage Surface Impoundment
T01 - Treatment Tank
T02 - Treatment Surface Impoundment
D33 - Disposal Surface Impoundment
Nonaqueous Processes
S03 - Waste Piles
D30 - Landfill
D31 - Land Application
Not= tnat storage tanks (502) were originally included in the ranking.
However, the impact of storage tank emissions was found to be very low
compared to ot.ier T3D? processes.2 Thus, storage tanks (S02, were removed
from the TSDF population for this study.
17
-------
IA5LE 5.
PRELIMINARY SCREENING OF WASTE VOLUME BY WASTE TYPES
LCTED VOLUMES)
3-
T C
->7
ASTE TYPEa -ASTE VOLUME"
Q g, ^ ^^5
ncoo"~ 25,564,063. 67
r :C7 10,959,1 33.23
30CC 6,630,247.63
KC-2 2,741,269.72
3C02 2,627,759.20
F007 2,596,874.67
*'~jl\ 1,698,264.10
PC14 1,172,405.61
K : 2 7 1,106,976.17
^--4 1 , 089,792 .69
- " " 1^ncq=iqi
K * 1 c ,,vo-i*'--'«-
-p-r 998,701 .44
Ko"lO 963,099.01
K 3.4 J 958 ,726 .16
w - a 7 847,602.51
7h 79 a « ^ 7
-i - ; ^ 772,232.35
c-i= 765,700.34
- I - -, 745,368.22
< - = i 674,184.16
,< ^ I ~ 6"4,348.P9
,< - - 2 596,079.02
K ;i i 591 ,455 .75
3(i-;t 562,207.01
~-'i clT,"'i99.9£
i - - i 413,iQ".43
<-..; 390.097.64
TQ-= 357,485.02
- r- ; 5 3 1 d , 2 0 6 . 3 1
~-'~--i 290,244.74
rwwj *_^^'t-
-l r i : 227,742.44
*^-7/-/1,.-IC
--12 £^7,fc4l3.--
r ^ - 222,661.5''
K-37 193,235.99
'r-- 1^-n4'0.'*£
r-^p 174,504.25
OC11 172,754.91
, ^s = 171,371.44
p?3; 167,017.60
'I--7 166,263.10
<~{a 159,^20.38
K05C 159, 012. "7
X- i l = 4.8el«pl
H^J^^ i*.^^1-1 * -*
.^-77 154,41C.tl
^=2 150,099.99
<:Z3 147,961.64
c - = 144,955.05
^131 143,333.98
c C 1 s l'*T,3-i6.c^
^'7c 137,c'44.8t
KOc, 2 135,050.29
PERCEiT Cl"
1C 0.0000
27.9302
11.96A1
1.5112
2. 9928
2.8637
2.835C
2.3402
1.854C
1.6462
1.2799
1.2C85
1.1897
1.0982
1. Oa 03
1.0514
3.9255
0.8569
0.8420
0.835?
0.6137
0. 73 tO
0 . 7C 3>
0.6:07
0.6^17
. . a i - ..
0 5 6 A 5
0.4511
0. 42S9
C. 34 74
C . 3 1 1 9
C. 2" ?6
0. 24C5
0.2431
0.2110
o. 197:
0.19",5
0.1=56
0. 1371
0.1323
0.1815
0.1746
0.1736
0 » 1 6 Q 1
0. 16? 6
C. 1639
"i 1 C. T ^
1 b 1 -
0.15 s.2
0. 1565
n. 1^ "* '
1 c '-
Ij X *. "-
0. 14 74
^UHlivL Kt.p(i-t
.
27.9302
39.8943
47.4055
5C.3933
53.2670
56.1021
58.4423
60.2963
61.9425
63.2224
6H.4309
65.6206
6 t . 7 1 J> s
6 7 . 8 :; = i
6 c . c 6 0 -
69 .9072
7C .8 327
71.6917
72.5347
12 .3706
7 4 . 1 ? 4 4
7 u . a 2 ' 4
7C .6 21 6
7c .2 74 =
"* C " "
i C . . <- < L.
7 7 . 5 3 4 j
' " * - ~ -
7? .5 i5 6
7fc .7714
7C .3617
7 Q . 7 0 9 1
ri ; . 0 2- 0
80.2746
,3 r e 7 "t *
6 " 7 6 £ *-
£0.9771
6 1 . 1 74 2
SI .3647
^ * ~ - - -
61 . 7 + 0 3
f 1.9227
fc2. 1 0^-2
82 .2 788
02.452-*
8^ ' ^ i ii
^ . C *. - **
£2 .7 90 :
82.9539
a '. ' 154
63.273=
d3 .4 302
33.5334
63.73-0
a 3 . c rt 1 4
id
-------
TABLE 5 (continued)
(CORRICTED VCLUKE.S)
es
^ c
c; £
57
C, fi
59
t ~
61
62
£3
64
65
6 6
67
6£
- 9
7"
7 '
' i
7C
73
T.
7 =
7f
77
7 J
70
?, ~
c ^
0<-
33
p.i
85
86
87
68
S9
ar<
91
92
93
94
q c
96
97
96
99
170
: "i
1 72
" 3
1 "4
i 7 =
1 '6
4 r -»
1 35
W4STE TYPE3
FOI :
'<046
U 0 « 3
L'228
FOI 7
X 022
U 0 1 2
U051
'J234
U2?7
K05 S
3012
o 01 0
<035
< ? 1 *
'!016
K 1 S Q
^ J J v
K 05 7
K C2 '"
" 1C&
K Z^ 4
c O"1*
c ^r 4
IJ 1 i, i
, - - -
KC1 »
p 3-*«
^*> t "X
k. V, _
KC43
K D . 5
U23 ?
U02D
U151
UC3C
K 0*2
K 033
K OC5
K C C 6
POS2
K:: 3
U22 D
'J 1 7 ft
K C^ 0
0017
K30*.
U18P
KQO 7
F:I i
j o c 2
K n6 "
^ n T c.
K337
K ::<
L' 0 1 9
-ASTE VOLUME
132*238.38
126-.C5C.3S
126*005.23
12't»3
1 C6 . 176.27
lto,632 .77
104,0^3.81
102.625.59
97,oi2.£b
96.621.72
7 1 , 4 5 7 . 3 9
0 1 ,39S.2C
9C.417.3t
9 0 ,26 0.2 1
S 9 , C 2 7 . C. 9
S5 ,33". 72
%3 ,96} .56
82,364.^5
9 C , 1 3 2 . - 3
31, 121. C1
78,821 .28
7ri,384.4 2
76,836.7:
76,319.38
74 , 7^1 .66
74,6*6.07
7 4 . u 9 3 . C Z
70.463.70
67,79<- .5 7
67 ,2"6.7e
6>o, :64 .84
66.032.99
65,853.59
65 , 746.64
65,522.19
64,988.32'
6^,712.33
64,297.15
64,144.07
63,986.40
63,011 .1 3
62,030.81
61,332.13
61,338.73
59, 958. 14
59,925.77
PERCENT
0. 14 44
C. 1376
C. 1376
C.135S
C. 1294
C.125C
C. 1231
C. 1214
C.1206
C.I 185
0. 1176
C. 1161
C. 1159
0. 1153
C. 1136
C.112C
0. 1062
C. 1T55
C. 0995
0.0993
0. 0987
C. 0985
C. 0972
0. 0932
C. 0917
C. 0899
0. 0£97
o. :? et
0.0860
C. 065t
0. C339
C. 0633
0. 0816
C . C8 1 5
0. 0£ 13
0. 0769
C. C74C
C. 0734
0.0721
0. 0721
C. 0719
C. 071S
0. 0715
0. 0709
C. C70c
0. 07 02
C. 0700
0. 0699
o. C6 ee
C. 0677
0. 0676
C.0670
0. :&55
0. CbS"
CUMULATIVE PERCEJ.T
84.0253
84.1634
84.300^
8"* .4367
84 .5651
R4 .69U
&4.6132
8^.9346
85.7552
85.1737
85.4774
65.5233
e5.63c7
85.7522
?. 5 . 5 i "» 3
85 .97 75
86 . C759
&6.1755
86.2756
3=.5777
1 1 . 9 3 4 5
37.0231
87.17 91
fi 7 . 1 9 4 7
5 7 . 2 7 £c
b7.3f 19
"?7.443j
87.5350
87.6333
6 7 . 75 73
37.3377
o7.90 28
P7 . 97<>c>
e .J . c 4 - s
fc ^ . 1 1 H6
8 <: 1 q 7 I
8 c . 26 1 1
8 r .33 I"7
e e . a : i q
e=.4719
pa. 541 =
cc . 6 1 36
fi 5 . 6 7 ? 2
a 6 . 74 5r
r .94 J
19
-------
TABLE 5 (continued)
(CORRECTED VOLUMES)
OSS
lie
1 1 1
112
112
115
1 16
1 17
IIP
119
12:
i t- i
1 " 0
- *» "I
124
-c:
1 27
129
129
t 1 "
1 _ j.
T T
13**
i 1C
"*" "~
1 1 '-
1 37
1 3 n
13?
i **:
i*:
1^2
1 <*3
^44
1^C
1 u7
* a C
* v.
1 c 2
C T
1 -*»
" C =
157
1 " o
- a
1 6 :
" " *
iASTE TYPE a
K C 2 2
LJ " 7 "
i n t (L
" 1 *5 1
'«. *. (- >
i ' o r o
-. ^ ^ -
= 074
0016
K o c e
? 093
'J 0 0 9
U 05 6
P073
0110
U070
U09 i
' i n T **
J J ' ti
'J 3 5 7
' r c, "
L-071
= 1 1 1
U079
'J 0 R 9
'J 0 9 '.
'J 0 9 H
'J 2 4 -
j 24 0
t - . ~
i ' ^ i, =
.'A3TE VCLOfEb
59,191.31
53,462.94
58,27 r. o -
56,270.31
5 8 . C 7 6 . 3 C
57,827.72
57,626.45
57,209.02
56,878.85
55,91C .02
55.556.91
5-*, 322- 6 4
53,361 .Oa
52,144.22
5 2 329 .55
51,546.33
51,434.15
z 1 ,334 .32
51.27K.79
53,939.94
- " 7 0 - 1 "*
3^,7S-?.i -
49,197.30
49.162.25
47,549.39
47.037.17
~i . "5 : .2 1
-5 .527 .6c
45,511.^4
4 5 , 4. 7 8 . 2 0
4 5 , 41 t .£ 3
\ c ' T^ = * 7 T
4 5 , 3 3 c . o 2
4 5 . 2 4 7 . 3 ft
45,214.07
"* "* ^
a 4 , 7 S .? . 7 c.
4^,720.75
44.573.78
4 4 ' o^ '- " ^ n
44,232.40
44,201.73
43.7^0.65
43,508.44
4l,425*n2
43,379.02
* 2 , 29'.. 45
PERCEM CU
C. C6 46
C. 0628
V
C. 06 2b
C. 0631
C. 0629
C. 0625
0.0621
C. 0610
C. 0607
C. 0599
C. 058?
" n ^ ri ^
C. 056S
0. 0562
C. C562
C. 0-561
0. 0560
0. 0556
C. 055n
0. 0554
^ ^>c 1 7
v . , - w *
0. 0527
0. 05 lq
" /« C" * A
». . " w 1 **
C C 3 u 3
0.0497
C. 0497
^ . !- 4 "3 t
0. 04=6
C. Ot 95
0. 0495
C. 04 9o
1* . lr^7~
f * A Q 4
V * . ^ ' ^
0. 04 94
C. 0492
0. 04 £9
C. 04 39
C. 04 38
CI-% A 3 7
. ^4 c* /
0. 0487
0. 0487
C. C4fi2
0. 0482
0. 0433
C. 0478
C ? ** 7 *
G ?4 7^
0.0474
0. 0473
PuLAIlVt. I- :. K L L
a o . o c = 2
69.0721
89.1357
p O Q ^i*
89.2:28
89.3259
89.38B8
ft 9 . 4 5 1 2
89.5134
89.5744
39.6251
89 .6943
89.7527
8 0 . fe i 0 7
89 .6675
89.9237
89.97=9
90.0260
90.0923
90-14 l~
9 0 . 2 5 1 4
9 " . ' 1 2 ^
r- - 1 C 1
7 - « " 1 - -
a 0 . 47 02
9 " . 52 16
r: - t 7 -j
J ^i . - ' - J
90.6215
9. .6712
9 " . 72 09
9 r .77 !5
90.32 00
90.369"
a r . 91 c;
T - 7 * ' -^
90.96c4
91.017?
91 .0671
91.1163
* * * c - «-
91.2141
r-i * ~ C "^ "
9 j.
-------
G£S
WASTE TYPE a
TABLE 5 (continued)
(CORRECTED VOLUMCS)
WASTE VOLU?S.b PL KG C
;. fERCLKT
163 F104
1 64 PC 54
163 0337
166 KOfi
167 P C 7 6
1 6 S K 0 2 fl
1 f 5 * 39 1
1 72 U03 7
171 tjill
172 L23S
1 7 T 1 ' 1 1 ~
174 UC5 3
1 ~"c -1 3 2 i
176 =068
1 77 U 06 5
1 7 £ c 3 3 9
1 ^9 - 3o r
183 ^ 3 c ~
31 *" 1 ~ "
1 p 2 '.. 138
1-3 J 1 : 7
1 ? - I' 3 2 «
1 £ c _ 3 ? Q
i a i P 3 ^ ?
137 '. 3 2 r
1 oc 'J r ^ f-
1 ? ^ J 3 4 6
193 'j C 4 2
i c. 1 L " ~ 7
1 a 2 C "* 4 1
; "j 3 L 0 2 3
19- U 3 9 3
15" -'021
1=7 P 3 ° 7
15o F113
19° ' C14
2:? ^C57
2 3 1 =118
232 J335
2 " 3 U 0 2 5
2t4 =027
235 '385
236 0035
2 " 7 3 ?4 6
2'e 'J 0 2 2
23=! ' 0 2 £
213 U ? 5 9
211 c 32 6
212 =?4 5
2 1 T ,' 3 fi 6
21- ^293
21= i j " a 7
216 '.31 =
43, 19 2. 57
42,625.82
42 .267.35
42,148.69
42,338. 4r
4 1,915. 1C
41,762.75
41,741.35
4 1 ,398.25
41,337.01
41,185.88
4 0,955.67
43,725.85
43,647.33
43,634.40
42.537.87
4^,437.75
4 0,426 .36
4 3 .408.61
43.323.73
» 3 1 9 8 . 1 3
40,153.43
40-143.89
42. 03 2.4"
40,377.04
u ^ ,n7t. 1°
42,375 .77
a 2 , 374.^9
£4 " 1 ~* 1 ' "*
ft^reT*.?;
4 3 . 0 4 1 . H fi
43 ,037.15
^ « - T 7 . '
4C 331 .92
40,231.52
42.330.46
43,329.79
42,n25.74
4 2 , 229 .6,1
4 2 ,02c.62
40,028.4e
4 C, 32o.45
40,228.35 -
40,028.37
4 0, 02c .2 <
40,028.15
40,025.12
«0,027.92
40,027.92
43,027.89
40.027.87
4^,327.83
40,327.83
C. 3472
0. 04&5
C. 0461
C.C460
c. 3459
C. C453
C. T456.
0. 3456
C. C452
I * *.**«!
0. "45?
G. 34 47
r 34 4c
3.3444
C. 244>
C. 3442
3. 0441
2 . 34 4.1
C . 2441
C . 3 * 4 o
c. 3435
0 . 243?
C. 3t 3 =
J - ** _ C
C. C^ 3t
" a ** -* "* ^
C . 24 33
3. 34 37
C . 3437
C. 34 37
0. 3437
2. 3437
G-0437
0 . 0437
C. C437
3. 3437
c. 34 37
0. 0437
C. 0437
G. 34 37
0. 3437
c. 3437
0.3437
C. C4 37
C. 34 37
C. 0437
0. C437
C - ^ '
C. 0437
3. 2437
C . 04 37
C . C«37
C. 3-37
3. 2437
0 1 . 8 8 C 5
91.9333
51.9752
92.0252
92.2711
92.1169
0 2 . 1 f 2 5
92 .20 si
52.2533
92.2534
92.3433
92.3^=1
52 . 4 "» 2"
92.4769
92.5212
92.5655
92 .639t
52.6537
92.6973
9- 7 u * Q
*. ' *
92.7-57
5 2 . c 2 56
92.8735
92 .5: 72
92. 9c 12
93.3347
53 . 3 4 c~.
93.3=22
C t 11;-'
92 .1797
93.2234
93.2672
9 3 . 3 1 : a
Q 3 . >, c a i
Q 3.39 =3
53.442"
93 .4 At7
9 3 . 5 2 ?i
93.573!
9 3 . 6 1 r *
93.66 - =
93.7342
93 .74 7q
9 3 . 7 = 1 r
=3.83:3
53 .c7 J2
93.9227
92 . 56 ±4
9 - . 3 1 3 ;
9 4 . 3 5 2 K
r " . 2 5 7 5
n - i - 1 r
C ^ . ' - ^, G
9 < . 2 2 >-. c
21
-------
WASTE TYPE:"3
217
228
219
223
221
222
222
224
225
226
227
22S
229
IT"
271
27*
23 =
2 36
227
2 36
5 'a
2*2
243
244
2* =
246
2*7
24 =
2*9
252
251
O C O
233
S ~ ^
3 = 3
2 3 c
257
<: t:i
262
263
26*
U'062
L'049
PC67
P 04 2
UC59
U'C3C
P0*3
C'384
U01 0
L.1 0 9 0
P 03 4
U096
PC75
K373
P 139
"031
-Oil
U323
P 365
cir 7
'J159
PC9°
J 2 2 w
P 012
PI:*
C 1 " i
273
- C32
K 37 *
= 016
D3u 7
PCI 7
< 01 7
U22 7
-22?
L3C 3
U221
U211
J 120
'.' 3 6 7
U 1* 3
'.081
< 3" i
TABLE 5 (continued)
(CORRECTED VOLUMES)
'JASTE VOLUME
40,027.73
40,027.71
4 0, 027.69
40 ,027.64
40.027.62
40,027.47
4 0,027.42
40,027.42
40,013.91
40,017.63
39,992.97
39.94 7.21
29, 946 . 4 2
29,691. 12
29,256.39
29,183.27
39.133.96
39,073.73
3S ,89* .77
39, 892.55
38,701.86
3S.557.49
33.111.47
38,083.5*
3o ,375. 57
35.322.2°
3i,331.33
2 7, 995.42
27,917.57
27.1 26. 2G
27,369.24
36, 996.2 1
26,665.26
36,073.82
26 . 3<-3 .73
3 5 , 9 ft 1 . C 0
25 . 95 "> . * '
25.036.3*
3*. 536 .9*
33,839.1 3
22,799.27
22.395.CC
21. lie. ^Z
3C , 84 C .32
3 C, 5 7 7. 94
33.4C5.21
29.735.96
29,1^3.73
"9.142.S5
2 s . 7 7 2 . 2 1
2^.6-5.27
2 3 , 2 7 4 . 3 f.
27, 67=. 92
PERCENT
0. 0437
C. 0437
0. 0437
G. C437
C. C437
C. 0437
0. C437
C. 0437
0. 0437
0. 0437
0. C*37
0. 04 3£
0. 3*36
C. C433
C. 3*29
0. 04 2c
0. C427
C. 3*27
C.3425
C. 3425
C. 0423
C. 2" 21
0. 3* 16
C. C* 16
0. 0*16
C. 0* 15
C. 3* 15
c. 3* i:
C. 3*15
C. 34 14
C. C*05
3. O* C5
0.0*04
0. 04 CC
3. 0394
0. 3393
0. 2293
C. 0392
C. 0387
0. 02 78
0. 33 7C
C.0369
C. 3354
0. 0344
C. 3337
0. 3334
C . 33 "* "
0. 3324
0. 0219
C. 3218
C. 3214
3. 3217
0. 02 09
3. 33 3*
CUMULATIVE PERCE'.T
94.2722
94.31SC
94.35 97
9*.4034
94.4471
94.49:6
94.52*5
94.57S2
94 .6218
94.6655
94.7352
9«.7523
94.796*
9*.6297
9*.882=
94.9254
C 4 m 0£ 6]^
95.0137
95.3522
95.C957
V5.127=
95.3*63
95.3878
95."736
95.ei:-
95 .5527
C5.5932
95 .6236
95.6736
95.713C
95.7523
95.7916
95.63 3^
95.66 91
95.9C69
95.9439
95.9*3':
96.C5 35
96.0842
96.1176
96.153^
96.18 32
96.2151
96.2* 69
9c.2783
96 .2396
96.243*
9b.2 739
-------
TABLE 5 (continued)
(CORRECTED VCLl-PES)
OES
WASTE TYPE3 *ASTL VOLUME1
PE SCENT
CO^OLATIVE FERCEM
271
272
273
274
275
276
277
278
279
28"
2 al
2 P2
233
2 fc4
265
2 8 =
267
286
26^
^ 9
291
Q *>
2 9t
2ce
2 --
2-7
t. -- w
2C9
t " ~
1-1
302
3"3
3 04
T ^ c
T " t
3 07
^ C9
3 1:
3 11
312
117
314
31 =
316
317
3 :e
315
3 °1
- -^
1 ~ T
3 ~ a
U165
'J115
U161
K083
U135
U031
FOC5
U236
PlOo
U235
U196
U 149
U 1 C 3
U151
U2 0 9
j 2 o e
D 1 *> **
c 1 <^ £
K 064
ui : i
'AT'
w J 0 -
U 2 ~ 3
I 1 > I Q
'J - 1 O
i f\ a >
< ?n- 1
K 05 c.
r*. Or 7
< 06 &.
- 3r. 1
= 037
< 3cc
U lc 5
P 36 r.
J Oc.2
U317
U n B **
UC55
U172
Ull 7
'J 1 J 5
|J 2 1 3
U C2 6
J106
P 06"
= 033
PC50
c rjft 7
a Caa
= 1C2
J067
UQ7"
U 0 6 C
JO 3 5
= 00 c
P 01 5
27,683.57
27,427.73
27, 176.20
27,023.71
26,405.17
26,239 .6 1
26,181.52
25,923.61
25,360.78
25,826.32
25, "23. 26
25 ,266.20
25, 136 .R4
25.305.50
2", 995. 09
24,369.25
" ii - 7 O c S 1
£.**< / J _- * J I
2^»oi3.29
2** t 6C9.c6
9u.£,n3 1Q
c H f Q L, 7 i7
2 * , 6 0 6 . 6 6
"7 il £v "* A. C "*
2-* . 606 .24
2<* ,563 .59
23 .587 .H8
23,473.39
23,06'-. 6£
21,937, 09
22. 303. 2 S
22.326.96
21,300.03
21,551.32
21 ,45 r- "i ~j t
' ^ £- It,
n . n ? 7 r
L «.«_ ' -
C. 0269
3. 0269
n « -^ -
w Q J
C. 0269
C. C269
0. 0269
0. 02 6
-------
TABLE 5 (concinued)
(CORRECTED VOLUMES)
C5S
325
T 2 ^
327
32?
32°
333
3 31
332
333
334
335
t. 1 -
337
3 3£
TIC
~* H ~
341
342
343
344
3 ac
' «~
3 "7
3 ag
1 4 Q
353
T = '"
~
T = ~
3 C 4
35;
3 56
3 57
7 " f
T Q
T ' r
T ,
T £ ~
! i^
36-
T 6 ~
1 - i.
7 " 7
36?
369
3 73
T T i
3 72
3 73
1 7 *
1 -»=;
7 7-
7 7 7
1 -> P
WASTE TYPE
U073
U04 1
U114
'J 047
PC87
PC23
U157
DD2P
U173
U011
U If. 4
'J192
U137
U068
U184
'J098
U212
U141
P 049
i 1 « 1 n
'J 1 J 7
U 1 9 3
U21 4
3 ^ 1 6
'J 2 1 5
D 1 1 C
u :ie
'11 ""> Q
J i - j
U 1 3 1
L'2 Z "
U C 9 7
U236
'-'150
c C6 9
u 1 7 4
11177
w 1 1 I
U176
''179
W A ' 7
Ulo 3
'J 14 3
J 1 6 3
= 119
'063
K 07 3
L.127
U129
J029
^13 1
U 1 2 3
E 1 0 5
"394
U2"4
= 09 5
5 n 92
U 2 r 5
.ASTE VOLUME
20.487.68
23.484.37
23,48] .55
20.478.02
20, 446 . 49
2C.445. Ofc
20.443.64
23.443.60
20.442.89
20.441.53
20.436.49
20.435.9°
20,435.39
20,435.30
23, "34. 39
23, "34. 22
23,^34.01
23,-»33.94
23,433.36
*7 H i T 7 D 7
t_ _i<^._ O»Ot
23,433.76
23,433.73
23 ,"33 .4 4
23,"33.2T
^ r 4 ^ ^ n c
20,432.67
- n 4 T - ^ =
s - -
20,432.45
23,432 .4-*
23,432.35
23,432 .26
23,432.16
2", 432. "5
20, "32. 01
20,432.00
-v * ^ t 7 ^ n
23,"32.30
23 ,<*31 .£9
2 0, 3S9 . 32
2 3 , 327 .d :
23,253 .59
20, 159 .-t 1
19 ,667 .26
19.613.25
19,611 .36
19,548.5 0
19 ,526 .£ C
19,520.29
19, 089.59
13,937.34
13,564.23
13,505.15
18,437.67
FERCEMT C
0. 0224
0. 3224
0. 0224
C. 3224
C. 0223
C. 3223
C. 0223
O.G223
0. 0223
C. 0223
C. C223
C. 3223
C.0/23
C.3223
C. 3223
C. C223
0. 3223
0. 3223
C. 3223
r i? 23
_ * - 1 £. **f
C. 0223
0. 3223
3.0223
0. 3223
C. 32 23
C. 3223
0. 32 23
C. 0223
G. 3223
3. 02 23
0. 3223
0. 0223
3. 3223
" . " " ' 3
C. 0223
C. C223
0. 3223
3. 3223
0. 3223
0. 0222
0. 3221
0. 0223
0. C215
C. 3214
0. 32 1"
C. 0213
C. 3213
0. 3213
0. 32 CP
0. 3207
C. 023,3
0. 32 02
C. 3201
U^ULA 1 IVc. I-5.R
97.7616
97.7635
97.S363
97.6286
9 7 . 8 5 1 1
97.8733
97.6956
97.31 79
97.94:2
97.9625
97.9849
9? . 33 72
9 c . 3 2 9 5
96.0513
9 3 . 0 7 H 1
30.3964
"3.1107
93.1410
9 - . 1 6 3 3
Q? . ' s r 6
93 .20 79
98.2332
9 S . 2 c 26
9c 2749
98.2972
9^.3195
J o . 3 4 1 c
9 3 . 3 5 6 4
9 6 . 4 C 8 7
90.4310
9fc.4533
9? .475c
9 ? . 4 5 7 9
98.52 32
qp .5425
9 c . 5 b 4 3
93.5=71
9 S .63 9-»
96.631^
9o .65 35
9 3 .o760
95 .69^:
99. 7195
9£ . 74 39
98.7=23
9B.7337
? ? . 8 0 5 :
98.82=3
98 . P" 71
9d.c678
5 3 . 8 5 P 1
9 1 . 9 0 ? 3
98.92 5"
24
-------
TABLE 5 (concinued)
OSS
WASTE TYPE
ASTE
(C3RRECT1C VOLUES)
b
CUMULATIVE
379
36:
3al
382
383
384
385
336
387
388
739
39-
3 = 1
392
TCI
3 9-
3 c =
"* C i
3=7
39c
399
: :
ft i «
4 "2
ft - 3
404
ft ^c
4 : 6
4 t 7
ft ^G
4 1:
ft i
4 12
"13
ft 1.
4 1 c
4 If
" : 7
4 1 c
4 1 c
"2"
421
422
423
4^4
4 ?-
" ,.=
"27
4 - 1
ft -a
43'
u 3
"32
I! 13 6
U189
F356
P073
PC96
PGC4
PC14
'J C S 3
U 1 2 1
(J120
P 0-5 9
P 01 ?
~C5c
U12f
K 099
J 12r
K 09 8
u 1 6 7
r 02 4
!J 1 0 2
Jii e
U 2 C 2
Jiff
'J 1 6 8
P 00 9
F 0:3
~ 123
C 1 1 ::
P 12 :
J 24 2
j 03 t
F C P. 9
UlOf
U C 6 1
u 2 3 2
= 071
K 052
'j 17:
-0:1
- 1 5 6
I 1 5 2
J * c -
w 1 C'> '
J 1 " r
J15 3
uii c
U 2 C 7
"077
'.' 1 b 3
'J 0" 8
^ i " "~
^ I" f
Ij 1=4
T T
13,389.34
17,323.71
1 7,578 .57
17,529.14
17,478.73
16»71C .40
16,373.67
16,351.66
16,282 .94
15,669.6?
15,247.73
15,137.69
15,001.22
14,989.61
1 4,969. 08
14, 674 . 25
14.515.48
1 3,767.72
13, 736.02
1 3, 728. £ 3
13.725.71
1 7. 724 .50
13,722.26
13,720.20
1 3 . 4 9 C . 3 C
1 2 . 3 " 3 . 0 c
1 1 .9^7.29
1 1,299.39
11« 28?. 66
1 1 , ni 6 ~" 7
1 1,995.75
1 C , 8 5 - . 3 2
1 0 . 6 3 7 . 5 C
1 0 , 8 0 7 . 5 t
lj,73c.:2
1 0 , i - i
X W 1 t- 1
C.0122
C. 0118
C. 0118
C . r 1 1 S
0. 01 17
o. n 14
C. 01 1"
C. 01 13
C. 01 12
C. 0111
C . 0 1 0 3
0. 01 05
0. 0105
~ - 1 c
C. C1C5
C. 105
C. 1 05
C . 1 0 5
C. 1 Oc
0. 1 04
C . 104
* * * \
C. 104
C. i 04
98.9485
98 .9871
99. C063
99. 0253
99 .C43i-
99.36 15
99.C793
99.0971
99.1142
99.13 ?fc
99.14 74
99.16 37
99.16"!
9^.2125
99.2263
99.2433
99.2583
99.2733
9 9 . 2 fc c 3
9 9 . 3 C 3 3
99.3183
99.33 22
99.34s;
9 c . 1 6 i 4
99.374C
« (- ^ - ,
9? .399C
Q u 1 1 T
' ? . " 1 13
99 .42 23
=9."351
9 = .ftft 7-
9 9 . 4 f ;, =1
99 ."705
99.4^1=
<5 9 , ft Q j j
99 .5046
99.5 1 58
99.5269
99.5376
9 9. 5 "82
9 9 . 2 " 6 7
99.56=2
93.57 ?7
=9.59-?
99.6' "f-
99.6111
99.6215
99.632:
99 .6"2"
9 9 . 6 ° 2 8
99.6633
9 ? . c 7 3 '
25
-------
CeS
473
a34
4 35
436
4 37
438
47?
4 40
4. 41
4 43
444
445
4 4~
4 47
4 4 g
440
450
451
452
4=3
454
4 55
456
457
4 ~ S
4 59
46"
4 61
4 C-2
463
4 --
4 65
4 66
467
469
4 7?
4 71
4 72
473
4 74
4 7C
4 7£
477
478
4 79
4 o"
4-3
4 E4
.'ASTE TYPE'"5
U 2 2 2
U187
U14 6
U21 7
U128
U15S
U21S
U225
U171
U 0 4 5
KOQ6
U 01 3
U147
U'37;
U 1 9 7
U224
U142
'J 1 9 0
K C84
'J 2 1 9
< 09 T
U124
U 14n
132
n== t
015 1
P 39,-.
K 06 3
KC55
'< i n -
uo^
1134
P052
0 7 9
<= OS6
D J « n
= 117
TABLE 5 (continued)
(CORRECTED
ASTE VOLUME.*1
9,547.70
9,547. 36
9 ,547. 14
9 , 5 4 f . fi 2
9,546 .52
9 ,546 .41
9 ,546.38
9,546.12
9,545.74,
9,520.75
9 , 1 8 5 .
-------
TABLE 5 (continued)
0
1
n
4
a
ti
4
<»
4
a
4
4
ft
^
*
r,
£ S
°7
S8
c9
9;
91
92
92
JH
9^
9f
97
"c
3 ~
-
i
wAGTE
'JO 4
un
U17
D " 1
TYPE3
;
n
c
9
P 032
'J 22
K10
K 1 0
K 39
KIT
413
< 1 C
< 07
ML
L1 24
a
4
?
7
1
5
2
{.
2
2
«
r
:
3
o
Q
. r. ^ o f-
*
:oo
r r o
n
^i
°9
93
a ?
99
99
99
99
9 c
99
99
99
P C
1 ""
1C
1 "!
.9825
.98 47
.9863
. 9 d 9 "
.9912
.9934
.9944
.9C o<*
.99^4
-9Q?4
.9984
.9994
f\ r ^ ^
.OCO:
. 3 : : :
"See Appendix A, Tables A-l and A-2 for definition.
Metric tons per year based on corrected Part A data.
27
-------
TABLE 6.
PRELIMINARY SCREENING OF WASTE VOLUME IN AQUEOUS
PROCESSES BY WASTE TYPE
(SOI »TC1,102,C8 3)
b
5S -ASTE TYPEa
: TOTAL
2 DOO 2
i D007
« 0 C 0 C
= K 0 6 2
c- 0 ° 0 3
7 F 0 0 7
8 K G 1 6
9 D 0 0 1
ir F 006
11 oo:*
,-, K OC 2
, -j ,/ O 1 1
* 'N 1 .1
-
1 = "^09
\i. * Q4 7
7 K 0 4 Q
*, / x
; F 3 0 1
s " 3 3 f
K 0 7 1
K 0 4 S
~ ~ K A c 'L
f. *- r\ ^ i
- 7 * r. 1 2
2 4 2006
2C - 0 1 *
27 < 06 5
- a -, ^ r =
T - K 37 9
T , K 05 r
7 - K 0 = 7
77 j ^ 7 7
T i fr n n 7
. - - ' -
3= K. 05 2
37 3311
73 ° 0 1 r
"* 5 K G 2 0
i * ^ 0 C c
a " C 0 1 3
i, i p 3 o 2
44 F 0 1 0
4= K 06 1
4 £ ^ 0 ^ ^
a? ? :: £
& £ K C ^ *
a a c ^ c 4
r r n 1 c
w 1
. t_ -, - ^ -
53 c 31 7
.ASTE VOLUfF
54 ,837,56^ .93
8, 105,694 .89
6, 303, f 96.95
1 ,939,330.85
1,614,165. 02
1,780,570.53
1,162,479 .2C
1,001,215.71
998,309 .74
801,839.24
686.906.69
674,"'t9.54
514,364.64
472,996.54
362, 099 .16
3ai,Oo2.C5
373,043.43
370.367.66
318,637.66
310.55C .93
2o2,436 .46
- - c- ~
-* ^f*.
^ _ f. f, ^
165. 7"7 .64
127,630.30
134,291.56
125,313 .71
124.266.52
114,509.56
113,321 .29
113,675.36
,_p ->Q
39.6998
54 .431*
65.9767
69.5132
72.8214
76 .068 4
79.1883
PC .0 14 0
81.8245
63.2966
84.5494
65.77=2
86.7172
87.6 192
66.4 61 6
69.1755
89. 8 735
90.5537
91.2291
91.3132
92.3765
92. HC15-
C t 7 C " T
93.7746
C 4. ? " * 7
34 .4 2-4
94.6 7-4
94.^205
9^ .1 "65
95. 3751
95.583^
55.7916
95.9969
96 .1 854
96.3423
9i_ .4810
56. t 152
5o.7t02
9 6 . ? 6 1 0
56.9917
97.0993
37.2135
97.3212
57.4209
97.5172
97.6114
97.695o
57.7732
97 .8 **4 £
37 .9 142
97.9 R04
9f .0 432
9 o.l 030
-------
TABLE 6 (continued)
U22 0
K069
'J21 :
1' 01 9
'w 0 4 4
DO""
r o 1 7
Jlf 9
* 0 i "
1.123 =
J12 2
< 0 6 c
J 2 2 6
J052
U 22 8
U23 9
'J 012
* 1C 0
U223
uii:
'_' 0 5 S
'J 0 7 3
J 076
K 0 £ 2
? 074
K 02 4
'J C o 0
'J i 4 0
0
3 0 9 9
,,1-T
= 121
' 04 f-
WASTE VOLUME
30,353.78
29,258.35
22.720.37
22,660.94
22,680.91
21.579.31
21.166 .02
2 0,326.1 1
20,511.28
2 0 , 5 .1 7 . 8 7
19,154.01
13,119.16
18,142.3 0
16,635.31
16, 592. 84
15,666.85
15.509.42
14 ,oci5 .42
13,597.16
13,516.01
13,339.76
1 2 , 9 ; Z , 3 4
12,596.43
12.225.16
11.974.67
11,64^.7?,
11,571.21
11,218.44
13,972.58
10,806.52
10,747.07
1 0 ,675.99
10.44 1 .36
1 0»40ft .46
10,069.77
9.597.80
9, 54*. 56
9,335.90
9-.osi.ee
3,921.33
3*919.07
b , 6 7 0 . 6 fi
3,869.0 1
7" It C £_ *
» c 4 . .6 »
7,276.39
7,2^-7.58
7,156.32
7,153.19
7.150.75
_ n Q .- - -
6.9°4.57
6,913.56
6,909.78
6,837.14
PERCENT
C. C554
0. C5 34
C. C114
C.041*
C. 01 11
C. 039*
0. C391
C. 03fcO
C.0375
C. 0371
C. C349
C. 0331
0. 0325
0. 0303
0. C3C3
C. 0266
C. 0283
C. 0271
C. 02 48
0. 0246
0. 0243
0. 02 36
0. 0230
0. 0223
r ". -^ 1 D
L . w1 ~ 1 e
C . 0212
-,_,.,
- * -^ -1 *
r ^ ^ r c,
L - t - -
0. 0200
0. 0197
0.0196
C . ' 1 9 5
C . 0 1 9 0
C. 0190
C . 0 1 £ 4
C. 017^
C. 0174
C . 0 1 7
C . 0 1 6 5
0.0163
0. 0163
C. 0162
C . 1 1 6 2
0". 1 il T
J A *t ^
C. 0133
f -^ * ~t 7
I .. i O _-
C.0131
0. 013C
0. 0130
r <- 1 -.253i
98.2945
96.33"8
93.3752
98.4143
96.4523
9 £.4 ft 98
9B.5272
96.5i21
98.5952
J c . 61 ol
93 .65 84
9 6 . 6 ? 8 7
9o.7173
98 .7456
5r . 772 7
96.7975
96.8221
9b .64 65
9 T . 8 7 01
9c . 69 31
93.91:4
96 .9372
96.9564
Q (. 07'^ =
^ r ^ ' , ^
G s . o " o :
99.02 00
99.039T
99.05 93
99. 078s-
93 . 09 7r
C C ^1
T 9 . » 1 ^ c
99.1352
99. 1527
99.1701
9 9 . 1 r, 7 1
99. 2r 36
99.21 99
99 .2361
= = .2523
9 9 .26 rt5
99 . 2s 26
99.2961
99.3093
99.3224
99.3334
99 .3464
99 .36 14
99 .3741
9 9 . 3 -7 6 7
'-> G . 3 9 9 3
9 " 4 i 19
29
-------
TABLE 6 (continued)
CS34 ,T01.T32,C83)
b
CBS
1 "9
110
1 11
113
1 14
115
1 16
117
1 19
' 2'
, :-
113
1 "'
126
- 7
^ /
- =
IT-
1"?1
1*1
* 1 -
^IT
r i "
- 7=
13 =
< 7 7
. ~ '
139
' 41
< 42
143
144
" 4 ^
1 4i
1 i7
1 "6
145
* e -
= i
132
1 53
1 5<-
1 c-
- i.
1 ?7
1 I r,
1:5
16'
- 1
1 ~ r
bASTE TYPE3
K022
U227
Ull 3
= 011
U135
F 312
U161
U092
U127
L' 0 7 0
'J072
I1 071
Q l i n
.lit.
U 2 0 9
U208
L1 1 3 1
J125
U12?
1 l *> 7 Q
w J f ?
U231
^ n -I r
< " 4 T
K 35 0
K 3' =
- 0 -
K3C3
UC33
y r. - t
K ^ T i
i\ , . ^
K 032
U115
P122
KOO 7
U 165
<053
K391
K 36 4
U 3 5 1
P073
r 3 1 9
K"1 2
K 0-5
U125
UC56
K 06 7
K 36 8
L'031
U 0 3 9
U 33 3
= 3 3 5
< 3 2 5
1 \ * Q C
U 35 7
*AST: VOLUME "
6,890.50
6 ,859 .22
6 ,356 .8 i
6, 35 ft. 31
6,793.01
6,794.96
6,766.35
6, 677. T2
6 ,671. 12
6 ,603 .93
6,627.03
6,624.65
6,620.01
6,638.81
6,638.33
6 .633 .43
6,631.71
6,631.63
, f ~. r< Q ^
6 ! 6 0 3 '. 9 1
6,600.79
6,231.05
5 ' ' * 1s
5,356. 13
5 . 3 3 fc . 3 2
4 Q i- " =, ii
4 , C 4 0 . 3 1
4.662.51
li ^- £, "* '1
4 ' 447* 47
" , 3 9 C . T 9
4,256.43
4.164.04
4,325.16
3 ,596.62
3,951.17
3 , 3 5 1 . ?. 9
3 ,893 .91
3,493.74
3,394.76
3 ,347. "9
2 , 5 n 1 . 6 6
2,877.11
2,759.63
2,712.25
2,546.74
2, 544:. 11
2 ,c 31 . ft9
2,474.01
2 , **48 . 5fi
2 ,"36.75
2,396.16
2,376.»2
PERCENT c
C. 31 26
C. 0125
C. 0125
0. 0125
C. 0124
C.C124
C. 0123
0. 0122
C. 0122
0. 3121
C. 0121
C . C 1 2 1
0.0121
0. 3121
0. 0121
C. 0123
0. 3120
0.0123
C. 012°
0.0123
0. 012°
0. 31 13
" n 1 1 1
C. 0392
C. 0392
r , n i j o
C. 0363
r n 1 a c
0 * " J O -*
r , r " o ""
r m 01
c. cran
C.P07S
0. 0376
0. 0373
C. C073
0.0073
0. 3371
0. 3371
C. 3364
3. 3062
C. 3056
C.3C54
0. 3052
C. 0050
0. 03 49
C. 3346
o. ro4o
C. 0046
C. CQ45
0.3345
3. 0344
0.0044
0. 3043
C. 034C
UPULATIVt f-LK
99.4245
95.43 70
95.4455
99.46 20
95.4744
99 .4S£3
95 .4991
55.51 13
55.5234
95.5356
99.5477
95.5'57
J9.571S
99.5639
59.535=
99.63r:
99.62 30
39.6320
95.6441
95 .6 = 61
99.66 81
55.6755
59.6897
g c ff. c cq
99.7:81
C5.71 73
99.73"3
9 9 T ** c ^
9 9 .7C "-
99.7:c8
95.766,:
99. 7741
9 5 . 7 S 1 5
95. 78*^2
93 .7ct!
99. r 3 3 1
99. »i 32
9 3 . 8 1 ft 6
99.8228
Q? . 82 R4
95.8338
95.6350
95. 8^4;
95.8451
95.8537
95. 8583
99.862=
99.8674
59. 87lfi
95.0762
95.38 J6
9 9 . 8 P <»9
95.0892
30
-------
,ASTE TYPE:
TABLE 6 (continued)
« tr ^
"33 .6C
<"« 5 . a 1
t 33.1T
"32 . "5
, ^ - n ,
** *. ^ ^
"13.59
7r>B.i7
361.37
3 5Q . 26,
3 4" . PC
331.56
329.66
305.?=
3:7.75
0. CO 42
C.0?42
C. CD"2
c. :c42
C.G042
0. DC39
0 . C C 3 8
o. c: 3?
^ . C ° 36
C . C C 3 3
C. 0032
:. c j 30
0. 0030
C . C 0 2 9
c. 0:25
c. 2:22
C. 0019
c . o c i e
C . C 0 1 7
C. ".016
C. 001"
C . 0 0 1 3
c . c 0.1 r
C. 0012
C . " 0 1 2
: . o c- 1 c
C. 001C
:. :;io
c . r c i o
o. ;o ic
0 . 0 0 1 C
c. o: C5
C. 0009
C. 00 09
0 . 0005
:. 000=
C. 0006
0.0003
c. r? oe
r ^ " ~v
c . - u J C
r " <"> ^ .4
'. . - .' w r
0 . 0 0 0 P
C . 0 0 0 £
c. o:ce
c. o: ot,
C. 0009
C. 00 07
C. OOC7
C. 0007
0. 0006
r, A o * ^
0. C30^
c. :oo6
C. 0006
99.8934
99.8576
99. 9C 18
99.9060
9 9 . 9 1 C 1
9<=.91 Hi
99.91 79
99.9216
99 .°2~'
59.9206
93.9313
9 9 . 9 3 -4 a
55.9373
99.94 :i
99.5" 32
5 'i . 9 4 5 "
9=.9" 73
99 .9"51
99 .95 "9
95.9525
95.9539
95.9551
99.9=64
99.5*57-
rz * o c 7
, - t> *
5 .- . 5 5 .- i
= 5.96 :^
99.9=1?
99 .96 2?
95.96 37
9 9 . 96 4 7
95. =6 56
95.96=:
99.9=7"
°9.5cr ?
95. 96 5]
95.5700
9C .97 OS
99.97:7
95.9725
95.97 33
55.97"!
55.5""Q
95.97"?
55 .9765
99. 9~72
99.977C
99. 97^6
55.5"a3
95.9759
c a ^ a ; ~^
9 5 . = c 1 1
c c . = 3, 1 7
5 a . 5 < 22
3L
-------
TABLE 6 (continued)
OES
WASTE TYPE
(SO*,TCltTC2.C83)
WASTE VOLUfEb PERCENT
CU"ULATiVE
'.Ct'.T
2 1 7
2 1£
2 1 --
220
221
222
223
22*
*5 -> C
<1 *. ~
226
227
"28
229
230
231
232
2-i T
j_
2 3 *
2 35
-.ti.
237
23r
2 ""?
2-:
,
~ u ~
2*3
2 " =
2 a6
2 *7
o - "
2-9
2 = ~
^ r -
2 "2
2=3
- r M
2 = --
2 r r
^ Q 7 "
t,r -
~ - c
2 ~ -
2 e 1
7 ^2
2 - ""
- -*
2 - =
0 £-
" ~ 7
0 - 6
? ^ --
277
= 022
K05 6
U2*. t
J 1 C- 5
L'169
U156
L1 1*9
'J C * 5
D Qfc P
K059
D 06 *
r 00 ?
POO*
I' 121
U213
f 02 1
p P ^ i
r 03 3
PC**
? 12 ?
Ulf 2
PG03
P 1 0 2
J 151
! PI "* r-
J U - n
p 32 !
' t 1 ° C,
^ 1 C 7
= 09*
D 05 1
e 05 G
p r ^ ^
'J 0 6 0
PC5 v
U 1 0 6
'.'132
? 099
'Jl**
J 06 1
L 0 3 9
'J 0 0 7
= 0 * 0
Jll *
0 0* 1
UCC6
F065
P082
U029
Jill
1 ' r. c T
'J "T "
Jl* 7
-.1*7
302.87
282.61
272.38
273.98
258.76
250.51
2**. 82
2* 1 . 3-
227.93
227.10
173.61
172.75
1 r- 1 . 2 8
1**.97
1** . *c
1*2.28
1 "^ 7 * £-
131.92
119.37
1 i 1 . * 9
1 0 6 .* e
108.03
106.92
10*. 05
111 *; t
91.6,6
89.55
8* . 0 7
81.0*
71.13
J r, p ~
C" *L -1 -
61.72
60.16
58.51
57.1 =
£6.37
56.15
5-t.5£
^i " a
*.' f."1
5 C . * 7
* ^ r* ^
C. CO 02
C. 0002
0. 0002
0. 0002
n * n ^ n ^
C " C 0 "*
C« CC C2
C .? -* 2 «i
C. 0002
f. ^ n p ^
L . J J L t.
r , i o n'j
0. 00 02
0. 00 01
0. 00 01
r, ft n *> +
C. 0031
C. 0001
0. 0001
C. 0001
0. 0001
0. 0001
C. 0001
0.0001
0.0001
C . 0001
0.0001
0. 3C 01
0.00:1
0. OOC1
C. 0001
0.0001
C. 0001
C. 00 01
0. CO 01
' C. 0001
C. OOC 1
0.3001
9 9. So 26
99 .9F33
99.9638
99.96 *3
99.96*8
99.9852
99.9857
99.9861
99.9865
=9.9869
99.9P72
99 . 96 76
99.9875
99.9681
9 7. 9br*
99.98 Sf.
c g . g p g 9
99.9691
99.9S93
99.9o
-------
TABLE 6 (continued)
DBS
WASTE TYPE'
(S3 4 , Tf.lt TO 2 «C8 3)
WASTE VOLUME13 F
271
272
273
274
27=.
276
277
276
279
28C
261
232
2c3
23*
2 8 =
2 £ ^
237
2e&
289
2 o n
291
292
293
O Q4
295
296
297
256
799
3 " C
3C1
3 "2
3C3
3 :*
3 "5
3 Cf
T ~ 7
3"3
3C9
31"
311
3 1 £.
313
314
315
316
3 17
7.16
319
3 2 n
32:
Ull 7
U069
L'341
U038
U244
UC48
U381
KC57
U237
UC86
U1C8
U132
= 336
J37n
U124
= 397
|J 0 2 5
= 347
t 02 1
j 19 4
F OC7
U31 7
U C 3 *
Ull Q
U 0 6 &
U31 *
P323
D 02 4
J164
Ull 9
UC23
U-398
J382
- C28
U155
'J21 ?
J 1 0 1
UC24
Pi 05
U235
J186
= 11 y
U139
D 1 1 9
Pile
U192
P334
U342
: i ^ q 7
PT3a
L'14l
U135
43
4 1
36
38
35
35
33
32
31
29
29
29
28
28
27
26
2fa
26
26
26
25
25
25
°5
25
25
25
25
25
25
25
24
24
24
24
2"
24
2"
24
2*
24
2 4
24
24
24
24
24
24
24
23
2 3
23
23
.95
.87
.96
.75
.65
.57
.17
.11
.SI
.56
.99
.76
.G3
.34
. 05
.47
.86
.65
.64
.41
.01
.62
C c
.48
. 3"
.27
*» r
.17
. 1."
. i :
.34
. 31
.55
. 88
.85
.82
.81
. 63
.63
.62
.58
.5?
. *9
.42
.?:
.23
.19
. 19
.19
1 r.
.93
.53
.92
.91
0
C
c
c
0
0
f
Q
0
Q
0
C
c
c
c
r
I
c
0
c
c
^
r
C
5
0
0
c
c
f>
c
r
c
0
0
3
C
n
Q
C
n
c
3
0
C
c
0
0
fl
3
c
c
0
c
c
*
*
30
CO
00
30
33
30
33
30
00
03
33
3C
01
01
01
01
01
01
Cl
Cl
01
01
01
01
. CQ01
*
.
»
C3
CC
P f*
30
n ~
o:
o:
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03
33
r« ^s
CC
~ n
T
33
CC
CC
C3
uC
C 3
33
CD
33
00
33
CD
CO
3D
33
CC
n "
w w
CD
3D
t n
C3
33
09
CC
33
C C
V A
31
CD
30
n ^
o r
u U
00
« n
03
CO
CC
" rt
CC
CC
CC
OC
CC
U C
OC
DC
DC
30
CO
OC
CC
C 3
OC
CC
n A
3 C
OC
30
n *
n f
O J
0 ^
00
o ^
CC
33
99
a Q
99
99
o a
99
59
9 9
59
5 9
99
9 5
9 9
99
99
99
99
99
53
99
9 -
99
c 9
99
99
9 9
q ^
99
99
99
99
95
99
99
99
99
99
qq
95
95
c c
59
99
99
9 9
eg
(- q
99
CC
59
c -s
59
59
.9937
.993£
.9938
.9535
.9943
.9943
.9='41
.9942
.97^*2
.9943
.9943
.9944
.95 * =
.99<*r:
. 9946
.9°4C
.9947
. 99"7
.9947
.99*8
.99*8
.95*9
.9949
.9^53
.9=53
.99:1
Q Q C I
1 ' J i
.99=2
.9952
.9553
. 9953
.99C-+
.595*
. 995*
.9=55
.9955
.9956
.5 = 56
.9 = 57
.5957
.995?.
.995S
.9558
.99:9
.9959
.99-:
.9963
q a ^ i
. 7 . C J
.9961
. 99 = 2
99;2
. 3C A?
.59 = 1
.596?
33
-------
TABLE 6 (continued)
(SO* iT01» TC2 ,Dd3)
C5S
-j f c
326
327
32fi
329
33"
3 "* 1
332
33*
33=-
T ~t T
_, , /
3 3Q
3 ^*
3*2
3*3
T £i i;
3*5
3*6
3 *7
3*9
35C
t =k
-j c; "i
35*
35 =
356
3=7
353
3 =°
36C
362
363
~i ~
3 :
i d ^
367
36A
T iC
37"
371
3 72
373
3 7-
T 7 ^
t "7 '
^ / -
3 7 =
WASTE TYFEa
1 1 1 " ~
U t_ t- t-
'JOS *
JOC5
J138
U0*6
LI 137
'J 1 1 "-
U 2 0 3
U C 9 7
P065
UC67
r " A c
O k. O --
- 0 1 7
o - - 7
w1 t- '
P 093
"M ' t
U066
U01C
J - O
U 1 5 fi
U015
'J C 1 6
U027
U 086
U 1 5 "
'J 15 7
UC99
p f 1 C.
U 0 * 9
"069
L' 0 6 2
U039
U183
'J 0 * 7
'J 0 5 9
U225
uos :
P C 7 _
11-
J 20 2
p 1 r Q
L! 2 1 8
'J 1 8 *
J132
'J17*
U177
> 1 *** 1 P
J ^> i "/
^ C ** w
OO7t
^ C ' ^
u
WASTE VOLUME
23. 9C
23.8*
23. a*
23.63
23.83
23.63
23.82
23.78
23.77
23.75
23. 7f
23.7*
23.7-
23.7*
23.7*
23.7*
23.73
23.72
23.72
23.72
23. 71
-7 71
c. J ' i
23.71
2 3* 71
- -> 71
_ ^ ' »
23.71
23.69
23.69
23.69
23 . 68
23 .65
23.66
- -i / £.
*_ J . D -
23.65
23.65
23.65
21. b =
23.65
23.63
" T .6 T
*- > D «
23.63
23.62
23.62
23.62
23.61
23.61
23.59
23.59
23 .59
23.59
23.59
PERCENT
C. COOC
C. 0000
0 . u 0 0 ^
C. 00 OG
c. cooo
C . 00 C C
C. i^c"
0. OCOC
0. OOOC
0. COOO
c. cooo
c. ccoo
C. CO CC
c. cooo
c. cooo
c. ccoo
o. :c oo
C. OOOC
0. CC 00
< r n i r
c . ~ - -» -
C. 00 GC
0. COOO
c . c c cc
V . - - V ^
A p r "i
_ . 3 j u -i
c. cc oc
c . : : c o
0. CO 00
C. CC 00
0. OQ CO
0. 00 00
C. COOC
o. On CO
c.cooo
G. "000
C. OOOC
n i n o n
c. cooo
C. 0000
0.0000
0.0000
c. coo:
c.cooo
o. ooc:
C. QGCC
o.ooco
0. COOO
C. OOOC
c. oocc
c.ococ
C. CO CO
0. CO 00
CLP.LLATIV- ^-*Li
99.996*
99 .996*
95.9965
99.9965
99.9566
99.9566
55.9967
55.95=7
95.9Q6S
99.9968
99 .9Q69
99.99^5
59.9565
59.9570
99.9970
99.9971
95.9971
99.9972
99.9972
55.95 72
99.9573
9?. 9973
5=.9?7*
95.997*
59.9975
Q c . Qa 7^
r ' T T*
95 .9976
55.9976
95.99 77
95.99 77
99.997f
59.9973
99.9978
99 .9979
a 9 . 99 79
99.9980
a a .go o 0
95.9981
9 S 9 9 6 1
99.99ol
99.9=32
99.9982
99 .9983
99.9983
99.99t*
99.998*
99 .9985
99.9=35
99.9985
95.5536
59.99S6
59.9987
:V.T
-------
TABLE 6 (continued)
(SC«tT01»T02»Oa3>
A3TE TYPE3
JASTt VOLUN.il
PERCENT
CUMULATIVE
:M
379
381
3 ?2
383
^ £
357
3 £9
T C ~
T -
7 C '
3 "3
7 a-
~ '^.
\~~,
1 a 7
w ' '
~ c *
T c G
O . -
- "
ft , -
ft 72
ft ~ 3
ft Of
*:?
4. "Q
*
ft 1 -
" 11
" 13
a . t
ft, * r
ft " -
ft 17
4 1 P
4 * c
* - "
4 " "
422
ft 23
ft 24
ft2 =
ft 27
4 - C
ft ~ 9
ft I "
ft 31
ft 32
P C« 2
P0**5
P 0*9
P Oft ft
P112
J03C
! | 1 4 T
U i ~ »
0172
L 17 3
U179
U 1 6 2
U 131
U 2 C £
'J C i 1
0 i < i
>J 1 1 t-
i - a 7
U 2 ^ r
c ' > 7
~ ~ '
C " fi T
V C *
U 1 7 1
K 05 5
DC 7;
, ! Q -
\» i ~
'J 3 9 b
P 03 9
P rv 1 H
P * r i
U 22 i
P 07 7
? 0 1 3
U201
P078
U 2 * '
J091
^ n c fe
U 1 9 7
F08C
'J 1 6 3
U12T:
< 03"
- 03 5
- - - j
p : 15
'J 1 ~ r
< 012
^ ^ c -*
23.59
23.55
23.5^>
23.5?
23.59
23.59
23.55
23.55
23.59
m ^ S "
23.35
23.55
23.59
23.59
O » C, "3
ii _J -T -
23.25
23.20
2 3 . 1 H
22.7^
2 2 . fe =
2 2 . ca
21.02
i a q c
i . . 7 -
19.09
15.27
13.37
12.35
10.3 =
9.7C
9 . 4 7
9.10
8.17
7.58
o, .3 0
ft.5^
3 . *« 7
2.59
(i
2*.15
i*o
1-7C
1* S2
^ -*
* * >-
1.03
0 .51
i_ * ^j *.
0.6?
0.^1
0.61
0.60
0.63
C. COCO
C.DCOC
C. 3CCC
0. 0000
C. COOP
C. 0000
0. 0000
c.oooo
0. COOO
<) n f\ r^ o
C. 0000
0. 0000
Ci " % n
. w tt J s
C. 00 00
^ n r r ^
C. ODCO
c. oooc
c.oooo
c. croo
C. 0000
c. oooc
0.0000
« n r n
C. 00 00
p ^ "* 0 **
U - w » «
n i ^ r r
L. '^ , « L.
c. :ooo
0. CO 00
c. o: co
:. oooo
G. 00 CC
C. OC 00
c. on QO
C. 00 00
C. COOO
0. 00 OC
C^ « n n
. . U -
C . 0000
U v 3 v w
n» n C C C
o. :: o:
p , n n q
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c.occo
* "i n n o
:. oc ?o
0. 00 00
C. CO 00
_ _
j . L w -
c. :o c?
^ -. P r,
V - -' - -
U * W - - !-
95.9967
95.993?
99.9981=
99 .9969
99 .9989
99 .9990
95.9950
99.9951
95.9^91
95.9951
9 9 . 9 9 ~ 2
99.99V2
99.5993
99.95=3
7 j * - 7
Q Q Q G C ij
55.995ft
99.999=
99. 9595
95.5996
99.99 ?b
99.999=
99.9997
59.9957
CO . QC <37
99. 555£
Q C » *5 *9 ^O
5Q .999d
09.999?
09 ,gq 99
99.5559
99.5=9?
q C . QQ 99
c 9 . gc 99
99.995=
95.9539
Q C Q Q QQ
1 _ 0 . - . - -
i o o . a c : o
i o o .0: ;o
1 C C . 0 0 0 0
-
^ ::";;:;
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35
-------
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r - > r . n -1 T. 0000*3 U C ' C
---.,.,-. -T 0000*0 -C'*
w i. - J 0 V I " " - . -,
[ 30 00 '0 - - -
. r ^ , ., Y r ^ n n o :c*c
r"^-,.-:T COC3*3 CO*C
--30'OOT OOOO'O - -
; - 3 c 3 : : o 3 c : o c * j
C 0 C * 3 C I 0033*3 .. ^ * C
:::c-:;i 30 c: -3 ic*:
3C:C-::T 0003-3 - :
----,.--- ^0 00 '0 oC * -
r.";."-T -*o--3 '
--"--.-,- T 0000-3 0 C ' 3
i^.JO---1 > -v - -
.-_^.-,-T "n r c. * 3 j-w
. i ' * *, r " ^ wWUW" wwj
r--p.--r CCw-V, L w .
w L U - " n
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c::c-:ci :=c:-3 ^c-o
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----;;! 0000-3 ^ " * -
Cc:^-"-T 0003-0 2^'C
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1' "--,.-'- 1 03 00 '3 s: * 3
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vLwwJ'-** ^-'n
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c r ~, n ~ 7 ^ U w j j wv.
° r^ -'0*3 "2'i
-- ^r .- r T 0300*0 =>-">
OU^U.i-t w ,-,«^
c,-n.,-T occo-o !-?:
C'OC"1''! 0000*3 p2*J
-000*001 3300*3 *£*-
OCOO'COT 0000-3 C9* 0
- n - r < -> I OOOO'O - ^ 2
Z" . or T 0000 "^ 03*0
U L J u Lot
f - u C "
= :o d zs "
£10= "d"
= . . / -= fl
3 - . V ^i 17
I 0 T V i i- *
S o ~ "> 9 ^. 17
"
ioO > 'i"
9£3 V ti '
; sc > -i *
:CiH =q"
i 90 i -' ^
ttsr, ??«
i ° T M 3 7 *7
/ c ^ 9 v
3 : c r, : 5 v
3 3 0 d 3 ^ *
~ r T s T 9 17
S9T n 35t/
B : o d - = "
r T T c " = 17
; 7 7 2 17
L I ; i , « - "
- a o r. c : "
c A n *i T 3 ^
r " " P w 3 ^7
"TCP - ^ ^
630 c S?1?
7&0 0 i*7 '
Ttsn 0*17
3&cn T"
9 30 1 . J*1'
3 1?t II D^ "
9 T r, i- "- °
c,9on ''i:17
7 s o n c t ^
S50
2 83 '301 » TOl* »70S )
9 31SY1
-------
065
TABLE 6 (coatinued)
~3TE TYPE"
.ASTE:
( SC4,T 01.TC2,08 3)
b
PEnCLfiT
aSee Appendix A, Tables A-1 and A-2 for definition.
by.etric tons per year based on corrected Part A data.
«
4
4
It
4
*
a
4
*
a
4
4
^
C
S7
S3
69
^:
91
92
G3
a"
' -
97
9S
n:
> 1
P
p
p
F
p
P
U
U
"
I
L
1
0£
oe
07
05
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C
11
0*<
10
- *
~1
2Z
23
?4
i
2
a
T
7
C
r
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9
7
7
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c
^
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r
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.
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C. COOC
C . C 0 0 C
0. 03CC
c. ore?
Cf> ^ p ^
» C j C i.
C. QC GD
0. CC 0 C
o r> r* f .~
\j , fc L j
r, r n ~* i
** ** n A "
t. * * . _ w
CA r> p -^
J t. . J
C. COCC
c. co:c
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1
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C C
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37
-------
:A3-S '
PRELIMINARY SCREENING OF NON-AQUEOUS PROCESSES BY WASTE TYPE
T : T ;, L
* - - ^
u C - 7
U _ w W
~ c - 1" *
C " *
7 sec o
t * - = -
i "! ? - - e
^ ; A j 3 0
^ C 1 1
- -> K C ** c
*" T I ~
1 - -J L - -
Z. * - "
_ 7 < - - i
* ' - " - -
* " " z . .j
*. - J " "
- - - - -
, , ,
2 a ^ ^ " ?
: : ^ - - -
.3 "._-*
: 7 ' : : :
:« ^: 7.
- " ^ * t r
Z " '-
- _ - - " -
f 3 * " " *
J; ^:;:
i ~ - - .
T ^ * ' ' '
-'-,'''-
1 - ^ I, -
^ - - ^
- > '
-- J - * ~
-'E39.97e.fc3 1'JJ.u.i.i.
'" I-T 3^- - --':--i
7, .--5-.=": C.33-.3 r'"""'
75. »-=.'-: ;.32i- :"';r-i
7i..-i.tc, ..3ic. :","V«
7« , I 79 . 7: .. 3i±- ^- '; _-
7»,ls;.l7 C . 3 '. 1 3 '"":'''.
7-':--'"' :" T '- = , ^ -9
71.^'~.bu 0.3-^' _*.';-'
= 7,:.-.t7 :.26t: 55.. J-.
ti.7ii.2b
;7.;;7e
-------
TABLE 7 (continued)
(f. 0 i . L a G , 3 = 1)
.iSTL VCIJI'E' Ft'CtM CflLATIVE Pt^C-l'.T
i;<. Lt.a3t:
i »5 5S. J7t)5
5 . :. .c : I i 7.8851
iT.i^t.il Z.lc-J oC.C*"?-
J7.ic-l.6i C.»59C nc.3^5^
3 ;.>..-, ;. it7: i<:. = 3t-
3-j.«=-.-! :..'tJ cc.dilr
3
-------
TABLE 7 (continued)
(t: i «io c, jc 11
3;.iC:.7.
11,: =1 =." i
1^.57.,.: i
Jc.lll.i'-J C.liJC e.5.411-
ia. v ;».t 7
j£.:7:.:0 ;.:tis ts.siT-.
7: .(,791
?:.»! 3?
7 1 . ; 5 : c
7. .7".; =
7 : . a y - -
7. .i.1. -i
7 .' . 1 C 1 -
7:.:: .=
7 :. 15 Cfc 73 .-...:
.7 :.:;:3 73.33::
j- :.:::: 7;-.7. jj
33f,19.ol :.13Ci
3r«tis.3: :.:: ;i
:'..-.:3. = i :. is :i
1-,-»L'-«-el. C-.-C- 7r_.c~Z'-
^" ---w ^-i.-- '!!''-
3*_.-^i.«" _..--- //.-.--
77.13'.:
40
-------
TABLE 7 (continued)
.ASTE
35,3S 7.7i
3 S . 3'; 7 . 2 2
it. 3?7.21
35,397.io
35,39 7.;3
3t,39C.'=>l
f-ERCEM
C. 15CC
;. i; c;
« i - j c
1« 1 J u -
0. 1SCO
c. it o:
CL"l,LA7IVE
77.33CB
77.6C55
77.7=18
T I- . 1 -^ * '
70.6^37
7S.9=L?
/ s . t e t =
? s . 7 o -- 1
.;-.:
33. 7^^^
c«.;-J3
o i 7 7 1
6 -**? j ^
c - . e i - 3
-------
TABLE 7 (continued)
( SC3 .183. 361)
-i
0-S
(j -1 " 2 C **.«» - i C. li 76
- - ^ >'.?&_).£* C . 1 3 fc n
s;ii. 31.di5.9b C.litS
- - " *" T - a "" i~ C " i ** c
j!22 il.503.7-. 0-1335
fai! Jl.i72.= 7 0.1JJ9
F011 31 ,2'jb. 3C C. 132*
n 24' 32 ,77 7.1b C. 1J3»
r-;t i:.oiS.9£ C. 12 99
K " i " 1",i5fe.o9 2 i 2 7 b
ji;= ~27,02<..*2 :-ii79
029 27.7ii.=>S: C.I 175
= - s. 05 29
' i 2i,2'-.Sc 2.2900
"~,^"-f 2:.9^.5» c.;eo9
^22 7 2:.9o;.i= ; :£<>»
* " 7 ^ ;;.79C.:7 C.23ol
i = - 2:, 72:. T- :. :s 7a
" " "< 'C..-7-.72 C.:o7i
;""' ;2,5fco.= l 2.;oi2
T-' 1"5o'*.7r C.i.371
"-^Z r:!i:9* *>'- o.0o73
" ~ " " 2 '. , * 9 3 . 1 o C . C 3 £ 9
r ;ot 2 ;.29r..&3 C. C860
i< - 7 3 l^.tC'-.'i 0 . C b 3 i
R-:: uli-i.2.: a.2777
t;ci I7,o96.-.* 0.27S3
u2l! :7!i7a!22 G.0734
p;r ; 1 7,307.0 2 C. 07ii
'^ '. = 5 17.;^fa.to C.0731
^;- 5 i 7,ifce.g5 0. J7t7
K;s- 17,157.27 C.C727
,;a; lt.52b.9fc C.3713
J.MuLATI*it rE62
SL.i-'ii
b 5 . * 6 * ^
5 - .0 2 1 :
b5. 72 '-3
n5.89:a
6e.G2:i
bc.1591
oc. 2921
£ t 4 t *-
06.35-9
bi.66-3
bt .ol 2;
S7.0»ej
o7.1e3%
67.2769
87.393.
6 7 3 0 ib
67.61 Jl
o7.72 1 =
07.8273
o t . 30 CB
8o.-91b
3 0 20 1 3
he . b 7 '.' 3
Go. /- 3
a c 3* y
co. 935 =
e 7 . 0 2 32
t9.i: >
o-.l-J'-
b 9 . 2 S s 7
S9.3718
b9 . »-2 e =
69 5* 4fc
o<,.fc3:i
69.71 3*
09.7911
b 9 . dc 76
09.9*19
90. Olio
92.0922
9C.lt Jc
92.23fc7
93.3:9-.
7 0 . 3o 21
9oi52=2
92.59;;
-------
TABLE 7 (continued)
OsS
2 71
272
2 72
C 7«
z 7:
2 7i
2 77
27^
2 7 =
2s"
2 o 1
2 52
2 w?
2 4
Z c -
2 9fc
2 57
~ - a
2 -9
:.."
292
292
29°*
2 ~>~-
2=6
297
^ = -
: =9
3 ";
2 :i
2 "2
2 :^
2 ~ 4
2 " :
2 Zr
* '.
2 ! ?
31."
2 1:
212
3 2
J **
7 u
1 ±
3 7
3 c
31?
7 - '
2 " '
-, . -
i - i
USGTE: TYPE;
P327
< ;s3
j:?-*
0 :99
Kit 7
K J7-
C 1 1 I
Ul-C
Jl 72
P122
'* (. 1 C
02-23
ui:2
U 169
Li:e
C J t T
UCe7
r 34 H
U Co b
0211
J4. 9
v. 2" o
U21 3
w :2 1
'0=7
^ C fc
u : 2
k/2
v 2 t
^:72
» :t.»
J 32"
f\\~-
* 1 1 ^
u i i
vj b V _
W 1 J t.
r : ^ 7
Jll-
015 /
ul7;
r C 2 2
s 11 2
U029
F 32 B
PC-9
Jl lo
- ;£
oi^i
^ <
J 1 Q
_ 1" 1
.AST: voutM£i
lc.7oc.*«2
1 1 . 7 5 5 . C 2
Is. 727.92
Ic .59'. .5 j
lfe.297.7i
lo i3bo.o 0
ie%321 .* 7
16,27 j. 71
16 . 2b* .31
It, 111.56
io,:t'j.22
i6,:2:.*3
It , 332. :b
16.j2-t.2t
li, 991 .4,1
15.551 .st
15 ,945 .2 3
15,9" I.H:
1 5 .9 2 2 . < 7
1 5 , 9 1 o . 1 i
it q a ; 7
15.93o.32
15.9JC.-.C
15.6 r, 2.»_9
At.ci2.il
i 5 . = 7 1 . M 2
i 5 , 5 7 :.-,«.
i 5 ,c 7; . 7-7
i t .969 .o2
1 5 3 i -i . i «
15. ;t-. :-,
1 ;.:-".:-
15 . it . . = 2
* ^. * s - ^. SC.
" - * i
15 ,ii- .-5
ir, 314.95
il.3ll.tC
1 5 . d 1 1 . 5 Q
1 i , o 1 1 . 1 4
it.aCt.52
15.i02.24
15.!i:2.o2
15.o:2.--£
15.aC2.27
1 5,i02 . I i
15,o:i.77
Ft^CEM
a. 07i:
c. :7 1 j
c. ;7 at
C. C7C3
C. ^695
0. 569*
0. 3c92
C. Cb69
C. C689
C. Cb83
c. :t oi
C. C£ 75
C. 267S
C. :679
C. 2678
C. It 76
C. :67c
C 26 75
C. Cfa 75
C. :b75
C. Z6 75
C. 2c 74
C. Ce 74
C. Co 74
;. "a 74
:. :t7j
C. ;=72
c. :s 72
C. C672
:. := 72
0. Ji 72
:. :6 '2
C. C6 72
C . 1671
c. :c 7i
" . ^6 7 '
;! := 7c
;. C6 7C
C- Ofc 70
;. ;£ 7:
c. :fa 7;
o. :=7c
c. ;67:
;. ct 7;
c. :fa 7:
C. Co 7i
0. J67C
C. je7C
C. C67C
C. Ca 7C
c. := 7:
CU^'-LATIVL FEC
9C.iS7 =
9:. 72=5
9;.Bi92
51 . 379 =
5C.9491
9 1 . 0 1 o j
91.367=
51.15-=
91.2254
»i .29 jT
5 1 . 2o 1 i
91.4297
91. -976
9 1 .bt.55
2 2
92. 2-27
9 2 . 3 ; o i
92.275'+
>-.« « 4 7
9; . ; i ::
92.5772
92 .B4,-
9^ .71 1 t
94. 77?:
92.04^2
9 2 . c i 2 2
9 ,_ . 9 o _ t
C ' 1 * «
92.2HSC
92.2157
92. 2 "-7
92 <> 97
S^, . il =c
92 .5
-------
TABLE 7 (continued)
: 7-;
< s:i .is :.c = i)
T£ T
-------
TABLE 7 (continued)
C-S ,iS~~ TV'L .ASTE VCL'J^L PfcHCEAl CUMULATIVE PERCEI'T
379 c::9 11,dOt.71 C.CSOCi 97.771:
3s: L'i2c :i,7i:.'js c.;»97 97.82:5
3il !J123 Ii.2oi.l5 :.3<.77 S7.e£65
iit^i-.c: :.'.". 7,- 97.sit2
Ilt23rt.»l 0.>7b 57.9a3i-
il.22.tifc C.C<-71 93.0114
ll.ll-i.td C.3-.7J 9t.G3dc
7 9 = .2i:'-
j.on i.2=ii.,8 :.;;s7 59-23^:
= JC, et2a°.99 C.C267 59.2=3:
L2:7 ci^^7.9t C.02fcc 95.25.3
j2:3 a. 2 3 . .30 :.l.fcr 37.3171
°;2" o!:7i'.^b 1..2oi 55.37.2
C.OIoc 55.35^
4O
-------
J" -76* 66
56-9-66
9*7
?«.&6'66 -»c::*o ?/-
i>3co '3 :/.:&
^p^rv.l 3 i. * ^ 6
60:: :
511: *o
si;: :
6:c: -
(peninquco)
: t".:n ii»
T9::-o
-------
TABLE 7 (continued)
<97
wAiTE TYPE
465 PC83
1 e : ? 0 o i
19: Pio:
-AST: V-L
Si. 72
90.72
9;. 7:
90. /r
3C.7;
9;. 7;
$3.7:
93.7;
90. 7C
C'jfUL»TIV£
c. c: j<>
0. GiC"
3. DOC*
99.9951
99.99=:
c. oc co
aSee Appendix A, Tables A-l and A-2 for definition.
^Metric tens per year based on corrected"Part A data.
47
-------
SECTION 3
DEVELOPMENT OF WASTE CHARACTERIZATION DATA
Waste stream characterization was identified as a key input parameter to
the revised hazardous waste ranking of chemical compounds at TSDFs. GCA
consulted the literature and contacted OSW's Waste Characterization Branch to
obtain useable waste characterization data. When it became clear that no
single data base existed, EPA directed GCA to compile existing characterization
data for use in the national emissions estimates-
DATA SOURCES
In order to obtain waste characterization data on the multitude of
hazardous waste streams handled at various TSDFs, _GCA reviewed the following
references for useable waste stream characterization data:
Mitre Corporation Working Paper WPS3-00065, "Composition of_
Hazardous Waste Streams Currently Incinerated", April 1933 ;3
Industrial Economics Corporation, Draft Report, "Interim Report on
Hazardous Waste Incineration Risk Analysis", August 1982;°
ICF Incorporated, "RCRA Risk/Cost Policy Model-Phase II Report",
August 1932; 9
RCRA background listing documents from the RCRA Docket;
Waste code delisting information from the RCRA Docket; and
Waste stream data from the RIA data base.
The first four data sources listed above were the only sources readily
available for complete analysis and, although limited in many respects, they
represented the best available data on industrial wastes. RCRA delisting
information was limited and provided incomplete analyses of constituents
likely to be found in waste streams- The RIA data were not made available in
time for this review. In addition, GCA contacted OSW's Waste Characterization
group for access to the industry studies data. However,_no data_were received
from this source due to apparent problems with data confidentiality.
-------
GCA summarized existing characterization data for 99 RCRA waste codes, 52
of which were single constituent codes (U and P). These 99 codes represent
about 50 percent of the total waste volume reported in the screened RCRA
Pare A data base. Table 8 lists the generic waste codes identified in each of
of the primary waste characterization data sources. The terra generic wasts
code is defined herein as those wastes with the following EPA waste code
designations.
DXXX-waste codes identified in §261.21, §261.22 and §261.23 of the
Federal Register as nonlisted ignitable, corrosive, reactive or EP
toxic wastes.
FXXX-waste codes identified in §262.31 of the Federal Register as
hazardous wastes from nonspecific sources.
KXXX-waste codes identified in §261.32 of the Federal Register as
hazardous wastes from specific sources.
A more complete listing of chemical specific and generic waste code
definitions is presented in Appendix A, Tables A-l and A-2, respectively.
DATA SOURCE QUALITY
The following three limitations generally applied to the waste stream
characterization data base:
laboratory of analytical techniques were frequently undocumented;
errors were evident in estimation and extrapolation procedures used
in the reference;
evidence of serious inconsistency within the same reference and
between references were noted.
A certain bias of the characterization data may be inherent with using
the Mitre and ISC data, since these two studies provided analysis of
potentially incinerable waste streams. It is anticipated that these data may
be biased towards higher volatile organic compound concentrations normally
found in incinerated wastes. The following discussion presents salient
information about the three data sources which form the basis for the waste
characterization data compiled for the national emissions estimates.
Mitre Working Paoer WP83-Q00655
The purpose of the Mitre study was to provide baseline information of
hazardous waste streams currently incinerated. Additionally, this report:
provided an assessment of risks and benefits associated with alternate
aporoaches to incineration.
49
-------
TABLE 8. EPA HAZARDOUS WASTE CODES FOR WHICH WASTE
CHARACTERIZATION DATA EXISTS
Waste
code
DOOL
D002
D003
F001
F002
F003
F004
F005
F006
F017
KOG1
K009
K u 1 0
KOI1
KOI2
K013
K014
K015
K016
KOI 7
KOL8
KOI 9
K020
K021
K022
K025
K026
Mitrea TEC
report report
X
X
X
x x
XV
A-
X
X
X
X
X
X
X
X
x x
X
x x
x x
X
x x
X
X
X
X
X
(continued)
50
report
X
X
X
X
X
X
X
X
X
X
X
-------
TABLE 8 (continued)
Waste Mitre3 IEC°
code report report
K027 X X
K028 X
K029 x
K030
K043 x x
K049 X X
K050 x
K051 x x
K052 x
K053 X
K060
K070 X
SO 7 3 X X
K033 X
K085 X
K086 X
KOS7
K095 X
KG 9 6 X
K105
Total 29 22
ICFC
report
X
X
X
X
X
X
X
X
19
^'Composition of Hazardous Waste Streams Currently
Incinerated," Mitre Corporation, Working Paper WP830006:>,
April 1933. . ,
b"IrLtarim Report on Hazardous Waste Incineration RISK
Analysis," Industrial Economics, Inc., Draft Report,
August 196:. n
c"RCRA Ris,c/0o3t Polity Model - Phase II Report,
Incorporated, August 1982.
51
-------
This study identified 413 waste streams with 237 different chemical
constituents. However, not all waste streams were useable in GCA s
characterization, since individual waste streams were often comprised o._a
mixture of two or more EPA waste codes as shown in the example provided la
Table 9. For a waste stream such as the one shown in Table 9, determination
determination of the proper distribution of chemical constituents to
individual waste codes could not be determined. Thus, 36 waste streams of
this type could not be used in GCA's waste characterization data base.
In the Mitre report, 140 of the 237 constituents are listed in ^
Federal Register as RCRA hazardous waste. The compounds reported in this
study are denoted by the RCRA K, F, D, U, and P codes waste type codes. The
remaining constituents included 85 specific compounds not listed ^in the
Federal Register that were denoted by a C code, and 13 nonspecific (e.g.,
"tars") compounds denoted by a G code. For each constituent, data were
provided on the concentration and the total constituent quantity in the waste.
Mitre data were obtained exclusively from industrial incinerators or
hazardous waste and thus, the study is limited in scope and the data should be
biased towards high Btu content wastes. The Mitre data may also be limited by
the accuracy of analytical techniques employed. Data were rounded off to the
nearest integer, tenth, or hundredth. This may have introduced an uncertainty
factor when the concentration quantities were later manipulated by GCA.
Industrial Economics Corporation (IEC)6
Trie IEC presents data on- incinerator facilities including operating
practices, identification of waste streams incinerated, waste toxicities, and
human population exposure. A calculational technique was provided to estimate
human health effects and to indicate potential risks expected across the
exposed population. Waste characterization data centers upon those wastes
which are "potentially incinerable."
Ther^ a^-e 10? waste streams identified in the IEC report, of which 48
are K waste codes, two are F waste codes and 52 are IEC codes. The IEC codes
contained no organic constituents, thus they were eliminated from
consideration. Due to unavailable quantity or constituent concentration aata
for most waste streams, only 22 streams were usable for characterization. A
total of 71 chemical constituents were identified in these streams.
For many waste streams, only partial information was provided. Various
chemical constituents were identified as present in a waste stream, although
no concentration data were available. Many of the waste quantitites were based
upon "professional judgment," while in some cases the numbers were based upon
actual sampling data. Thus, the accuracy of the numbers may vary widely. A
measure of this variability was not identified by the authors. Additionally,
many constituents were identified inconsistently; several constituents
appeared under different synonyms for different streams (i.e., Perchloroethy-
lene and Tetrachloroethylene were used interchangeably) and several constitu-
ents were identified under general classifications (i.e., Tetrachloroethanes ) .
52
-------
TABLE 9. EXAMPLE OF MITRE REPORT DATA: FACILITY 108*
latu Waste Abh Chlorine Water Heating Constituent
10 am Lt'A hazardous amount, content, content, content, vain.;, Constituent concentration,
||) waste co.le I/year peicellt pelcent |.el..enl IHu/ll) co.le percent
| D001 181.00 20 > ' 10000 0002 1.0
F001 1,!>88. 110 ^^20 8.0
FOOT JL^1.'1:.'^-! ":''U J'°
I'DTAl. J,r>K).00 (I22U 3.0
112)9 12.0
C041) 2.0
C0(>y r).0
U15'J )0. ()
11226 2.0
Amount ol
const it tie nt ,
I /year''
(6. 00
.'87. 00
108. 00
108. 00
.4 JO. 00
72.00
1 7'J.OO
i, cm. oo
72.00
JSonri-f: KelLToace 5.
''t/yuar - mi;trie Cons>/year.
-------
ICF, Incorporated9
The purpose of this study was to provide a description of the
characteristics of waste streams from industrial and several nonindustrial
sources. From these data a model was developed to generate "risk scores" for
hazardous waste streams and their constituents.
There were 83 waste streams from industrial and nonindustrial (i.e., PCB
wastes) sources identified in this report. Of the 83 waste streams, 35 did
not have an applicable EPA waste code number. Eighteen waste streams were
mixtures identified by more than one EPA waste code. Thus, chemical
constituents which corresponded to individual waste codes could not be
segregated for these waste streams- Of the remaining waste streams, two were
identified by the same EPA code (FOOD and were subsequently combined as one
stream. Ten of the remaining waste streams contained only inorganic
constituents and were not considered in the analysis. The remaining 19 waste
streams, which were appropriate for characterization contained 29 chemical
constituents. All of these constituents were noted as hazardous (RCRA).
Analytical data were reportedly based upon varying degrees of
approximation. The resultant uncertainty factors included in the report
ranged from +15 to +40 percent for each waste stream. Several of the waste
streams were defined by using "highly approximate, artificial
characteristics." In addition, there was uncertainty as to whether all
cnemical constituents were actually listed in the ICF tables, as the ICF
report typically identified less chemical constituents for waste codes than
were identified in the other two characterization reports.
CHARACTERIZATION METHODOLOGY
Each waste characterization study contained tabulated data including the
following information:
identification of each waste stream by one or more EPA hazardous
waste codes ;
total waste stream quantity generated on an annual basis;
chemical constituent codes identified within a particular waste
stream; and
the concentration of each chemical constituent on a weight percent
basis.
Using the data provided in each waste characterization report, volume weightec
average chemical constituent concentrations were determined for each waste
code. However, this analysis was only possible where a waste stream was
identified by a single EPA hazardous waste code. Waste streams with multiple
waste code listings did not provide a complete breakdown matching each
chemical constituent to its respective waste code. In this latter case, all
chemical constituents were grouped together for the entire waste stream, and
these data were not useful.
-------
Volume or mass-weighting of the concentration data was employed in
averaging data from different data sources. This weighting method places
greater confidence in concentration data taken from larger waste stream
volumes.
In addition to the generic waste types discussed above, GCA also analyzed
U and P waste codes, which represent commercial chemical product wastes
identified as acute hazardous and toxic wastes, respectively. The Mitre
report characterized these wastes as pure compounds containing 100 percent
(106 ppm concentrations) of the "U" code constituent type. While the Mitre
data may be accurate for incineration, it is unlikely that pure volatile
organic compounds are disposed as free liquids or solids. GCA assumed for the
purposes of this characterization that these compounds would be found in
one (1) percent concentrations by weight (10^ ppm concentrations). This
concentration is considered to be reasonable since this estimate may represent
either a nonrecoverable concentration, or a waste concentration fixed by a
sorbent. This waste dilution assumption should have minor impact on the
chemical prioritization ranking. However, the impact of this assumption may
be substantial with respect to the waste code ranking results.
Once the average constituent concentrations were developed for each waste
code, the weight-based concentrations were converted to mole fractions. The
mole fraction of constituent i in waste type k, is expressed as the weight
fraction of i, divided by the molecular weight of i, multiplied by the average
molecular weight of waste type k:
MW,
Mv = r K
i,k i,k MW.
where MF. , = mole fraction of constituent i in waste type k;
1 , :C
C. , = weight concentration of constituent i in waste type k;
i, tc
MW. = molecular weight of compound i; and
MW ,= average molecular weight of waste type k.
cC
The average molecular weight of waste type k (MW^) was estimated by taking
the weighted average of all constituents"in waste type k. Note that the
molecular weight of unknown constituents labeled "others" (MWothers) was
assumed to be equal to the average of all known constituents excluding water.
The weight fraction of all unknown constituents is defined as one (1) minus
the weight fraction of all known constituents (including water).
CHARACTERIZATION RESULTS
The results of the waste characterization effort for 47 generic waste
codes are presented in Table 10. The waste codes are listed in the left hand
vertical column of Table 10 and the waste constituents are listed across the
55
-------
too of the table. Because of the large number of waste constituent* (5:0
lasted or each code, the constituents for each waste code are listed on
sav-ral pa^es. Single constituent waste nole fractions for selected U co-e
wastes areVesented in the bottom row of Table 10 As noted earlier, t.ese
mole fractions are based on single constituent weignt fractions of
on.e (1) percent by weight.
5fa
-------
TAR Mi 10. WASTR CIIAKACTKKI NATION RESULTS
WASTIi
CODE
WASTIi CONSTITUENTS CONCENTRATION IN MOLE FRACTION3
u....; ijm.3
1 "II J
} .1,1,
1 111 /
1 ('"1
1 U.I '
lull
1 II 1 ..
1 ul
1 ..| 4
1 u 1 ',
1 u 1
1 "1 "
1 »l
I ii| -
1 . . ii
1 ' 1
1 '. .
I".'
1 '. .
1 ". '
1 ul
I '.',''
1 ' ' U
> " " ..
1 ii ; .
I"-,'.. ,
1 i ' 'j ,. i
( -d
1 1 ..', u
u 1 . . 3 S E - t
' .Vlc'.'j)
i . i . u . '. '. U '
i u
0 0
,,:,,\ i. 3
' ' i . 4 _ V 4 r.
1 I.I . 1 , 1 1 1 , {
i .mils ;.i ' . >..'..
J ;'
i II
,J
,,
'J
U
1,
''I
II
<>
, 1
.,
,.
',':
u
,
|
.J
1
'
,'
. . . i E
JE 4
i :." < r r,
4'. , ... 4'
i
*
j
-------
.1)
WASTE
com-:
I . li.F
WASTE CONSTITUENTS CONCENTRATION IN MOLE FRACTION
mi.
, t I >
u i . : 11 i -
Ul
oo
| 'V . nul 8* I'
-------
C >
_ c c c o - o
, c o c c >-
£
>
W;
n
r^
z.
C/2
O
z.
r-s
>
5
z.
3
-------
WASTE
CODE
COTiE H2.
Du.-l I.I ME-
*
F""l
FuM -
Fi,"4
F'io5
f ......
F"l 7
1 "n|
1 i "j w
1 .il<<
1 "1 1
1 " 1 -
1 " 1 4
1 U 1 J
1 " 1
1 " 1
t " 1 '
I'll'
1 1 ."
1 '. 1
1 '. .
1 .'.'.,
WASTE CONSTITUENTS CONCENTRATION IN MOLE FRACTION
3 ii ; :
6 3.808E-4 '
0 u
U *J
0 B . 8 3 3 E - 0
0 . 1 I « d 7 ji u
1 1 f 1
U *J
0 u
u 0
u 'J
0 '>
0 "
g "
u 'J
u u
u o
U U
u o
0 "
G U
o . M : 3 1 o a
u . I 8< / 4 ^ 4
U , i»
u ll
U ii
1 ... 0
! , .- .ul 751 i 7 I)
I ' ' '
1 ' "
I 04 >
i " ", i
i ' ,
i
i u -
1 " jl>
i «--,(.
i "> '
\ ' < C.
1 J "'
11)11-.. '' ."0104
U .1.^4177
0 "
U i'
0 0
0 0
0 0
II O
u u
u ')
u "
U ll
0 .1634*41
0 u
38 . u 0 1 3 6 1 0
u_:8 ui:i A'P^'J I'"*5 ll"78 u-" WATER OTHER
.9U3E-7 t.40"E-4 » t " '| 0).-^'t!i .',361794 .f^^;^
u 'i « " ,o5!4|fi8 .IU54J8J 1
1 4 ; 9 ;, j 5 .) " Gl.c.5?E-4 .35:t7«^l.l38dl37.
1.M3UM .0026659 o " ,u .H45967I .3.3633O .
0 ,, u ..43j')( .17J8t)7 .01794.5 .
M u " " '_' 0 u
" u ., " " .nu'.ol'i . ,7/c,.vv .094193'i
u u u ll " "' <77- ' . J J) '5u3 . J07/S41: .
' ,, i. v " « .^57a..i .o|7S..ir
g '1 " > > 5711541
0 0 ii " " " "7 1 e.76» .."U 4u ' 1
0 ,i ' " " " . ". 3ia:"«
" ;' :: ., " - o .v-5^..,
',' ij u " " " .11321'! .S6«;it 1
0 ii o " " " " "
II " 0 " U 1
y II H 'J 1
(> u i. " " " .97857-31 .n2ii4;5.l
g 0 n " ° (> .7>837fro .."I4lo'p
(, ,) " " " " . «59" 1 3D .1 4u9*. ;£,
(J 0 i1 '' ^ " 'J . 8oiyi4 4 f,
0 U n " w (l . y>39i64i? . "1"1 'i 1 o
g u U " " " 0 .4 1 T'l 3"
,) u PI " " '' 0.1 98" ! 3t,
u 0 u ° " " .8630582 ."188d8ii7
,j i, » " " " 0 .99:375;
0 u " " " " .45^987; .4805884
,, u 0 ' " " ... ,»u27t44
o 0 " '' " 1.1 .66 2 SO '" 7
0 o 0 " tj (t . '5 37 7 6 1 . "4 4 :5 2 3
.001381-^ .OU13215 . OU 1 2 3 20 .'J').*""7 ."0167"'- .»o|71.J >c,| |
SUM
oi 6 ii j;-^
. niji'.O 7 t
. M U 5 I 1 7
9 9 7 o " 4 v
9 9 » 9 ? 'j
o o i -v i M , ;
1 .
1
>5»4 '7 1
1
1
1
1
1
1
1
^ ; 4 ". 4 1
i .
i
i
i .
i
i
i
i
i
i
i
i
i
i
i
i
i
i
i .
i
!
. 9 7 7 3 7 u i
1
1
1
-------
SECTION 4
COMPILATION OF CHEMICAL PROPERTIES
AND HEALTH EFFECTS DATA
This section briefly summarizes the data compiled on the chemical
constituents identified in the waste characterization portion of this report.
Two types of data were identified and compiled: (1) the chemical and/or
physical properties:
molecular weight
vapor pressure
solubility
Henry's Law Constant
activity coefficient
and, (2) the toxic and carcinogenic effects:
Threshold Limit Value (TLV)
maximum allowable concentration at the 10~3 Risk Level.
CHEMICAL AND PHYSICAL PROPERTIES DATA
Chemical and physical properties data are particularly important to the
waste ranking, since'the hazard factor calculation, based on chemical
equillibria,"requires knowledge of these properties. Specifically, the
molecular weight, vapor pressure, solubility, and activity coefficients
associated with each chemical compound were employed to assess the gas phase
equilibrium concentrations used in the ranking procedure. Additional details
the hazard factor calculation are provided in Section 5 of this report.
on
All chemical property data were compiled for a temperature of 25°C. The
literature provided calculational techniques to estimate these data when not
readily avaiiaole in tabular form. Table 11 summarizes the key data used in
tne development of the hazardous waste ranking. Following discussions
indicate how the data were manipulated into the desired form.
Dl
-------
TA3LE 11. SUMMARY OF PERTINENT CHEMICAL PROPERTY DATA
'..'a s t e
c o c e
UOO'l
U0^2
U003
U007
U003
L'009
L'012
L'019
P02S
'JO 31
U211
L'052
l"X-
I-037
I'O 5 5
"r'57
n->n
':~2
jo:3
U ^1
1-1
T '
CC-q
L * <
'JO ' "
r- - o -^
; 1 "
ar^ -
L'135
" 'iO
Ul-7
L'15-
UO-5
U15a
! ' A '
L'O 80
U165
" ^2
1 " 1 3 ~
:IQO
U 19"?
--> ; r
U"'"
U223
U226
'J22S
U 1 2 1
AO1 ^ 5
'-. C -* 3
Mol -i-
we i :'" c
, ,
58
4 1
71
72.1
53.1
93
7S.12
125.6
7^
153.8
103
119.4
112.56
; 2 0
93
1 4 7
147
9"
92.5
83
' ^ r'
106.6
7_
oa
3 "'
-: -
2C
3
7^
Q ^
32
50.5
"* 7
100
85
123.2
j-.-: i <
9- . 1 1
148
T S
* C, ~ 3 ^
G " . 1 3
1~4
' ^ " . 4 1
131.39
12" .4
14-.-
62 .5
Vapor
pressure
(TT^.Hg)
Q16
2-36
90
.012
,45
114
.75
95.2
1.21
7
109
4
1^2
12
4.6
4.3
1.4
.8
407
17
85
40
10
520
82
3500
7- A
QO )
15200
12
.3
114
760
100
7.5
438
.23
_ 2
34 1
.03
23
IS. 6
.08
123
Q0
7J6
4 .4
26"^
Ac:ivitv
4.2
2;. 6
10 .SO
34.07
10.7
34
94
2094
2093
42.9
95
132
209
95
1
1C4Q5
52000
52000
3S2
28
105
33Q
15190
121
3'2
1 / > ")
1.29
T
1
1
31
141
1.53
55.06
5a
794
95.06
71504
2933
41
2655
1522
382
I
382
382
1
1619
382
62
-------
M0lecular Weight and Vapor Pressure
Molecular weights were obtained from the published literature,10,12
,.,Ue aporoximately 60 percent of the vapor pressure data were also
Bailable. Vapor pressure data not found in the published ^te"£« «
emulated in one of two ways. Where vapor pressure data were available
several known temperatures, the Clausius-Clapeyron equation" ^ ^P^
For those compounds for which these data were not available, the Antione
coefficients and equation were used.I7*
The Clausius-Clapeyron equation provides an approximate relationship
between vapor pressure and absolute temperature:
where: P° = vapor pressure (tnmHg);
.IHy = latent heat of evaporation;
R = the gas constant;
T = absolute temperature (°K); and
3 = a compound specific constant.
According to this equation, a plot of In P° versus 1/T would yield a
straight line with slope -H/R and intercept B. Tnus, if two vapor pressures
a-e k-own C?°i P°7) along with their corresponding temperatures (.!]_,
TT) a third vapor pressure at it's corresponding temperature can be
determined by solving for -1^/R and 3 as follows:
--«, V2 ln (PYPV ;
.1H
In P +
The vaUdity of this estimation technique is dependent upon the _
assumption that ^ does not vary with temperature. While this assumption
is frequently invalid, the equation provides reasonably good results i. usea
o interpolate vapor pressure over a relatively small temperature range.13,1-+
Multiple vapor pressure values for a number of compounds at various
temperatures were available in the Chemical Engineer s Handbook
Antoine's equation is a three constant vapor pressure correlation
represented as follows:
-------
where: P° = vapor pressure (mrnHg)
t = temperature (°C)
a, b, c = Antoines coefficients, chemical specific.
The Antoine coefficients were mainly obtained from Lange's Handbook of
Chemis try. * "- For vapor pressure values ranging from 10 to 760 ramHg, there
is an estimation error of approximately 3 percent. For low volatility
compounds (10~3 to \Q mraHg), the error can be as high as 86 percent. 14-
Solubility in Water
Approximately 60 percent of the solubility data were directly obtained
from published literature sources. The remaining data were calculated from
the following equation:
Log 1/S = 1.214 log KQW - 0.85
where KQW = octanol water partition coefficient
S = solubility, mg/1 at 25°C
Although tnis equation is subject to several data limitations,^"* it provides
approximately two-thirds of the estimates within a factor of 10.
Vaoor Phase Equilibrium Calculation
The simplest approach for determining vapor-liquid equilibrium is to
assume an ideal liquid with an ideal gas. From Raoult's Law, phase
equilibrium is determined by the partial pressure of a component in the vapor
phase:
P = Y D°
1 XLP 1
where ?£ = partial pressure of compound i
XL = mole fraction of compound i in the liquid phase
P°i = true vapor pressure of compound i
However, this equation is of limited use since the assumption of an ideal
solution is generally unrealistic. The ideal solution assumption is only
approximately valid if the solution is comprised of species of similar
molecular weight and chemical structure.
To correct for deviations from Raoult's Law, it is necessary to include
tne activity coefficient such that:
-------
ent.14
Che purposes of this task, the activity coefficient becomes a key
^ane'cer in determination of vapor-liquid equilibrium particularly in the
',se' of aqueous mixtures. Thus, the use of activity coefficients is essential
- che following sCorage, treatment and disposal processes where the
;sj~ption of dilute aqueous solution holds:
f . S04 - Storage Surface Impoundments
O O .< OI m °
T01 - Treatment Tank
T02 - Treatment Surface Impoundment
D83 - Disposal Surface Impoundment
;ula°edafrotn r the remaining processes, it is assumed that waste mixtures are generally
similar chemical nature and not dilute aqueous mixtures, thus, Y^_ is
proximately unity.
civicy Coefficient^
Several methods for the estimation of activity coefficients are presented
Che Handbook of Chemical Property Estimation Methods.14
\ £, provides All activity coefficients were estimated using the infinite dilution
-.ivity coefficient correlation shown below:14
103 v? = Aj. 2 * B2 VN2 + C1/N1
Jo t*O
juasp ire: subscript 1 refers to solute and 2 refers to solvent, and
i' in the vapo A^ 2 = coefficient which depends on the nature of solute and
- ^ solvent functional groups;
BT = coefficient which depends only on nature of solvent functional
group;
Ci = coefficient which depends only on solute functional group;
D = coefficient independent of solute and solvent functional group;
F2 = coefficient which essentially depends only on nature of solvent
->f an ideal functional group;
ion is only
similar Ni, N-? = number of carbon atoms in solute and solvent, respectively.
s correlation requires knowledge of the molecular structure of the compound
arv to inciade-n was obtained from Che licerature.10» 17~22 For the case of water as a
vent, Che above equaCion simplifies to:
-------
This equation serves as Che basic equation which varies slightly
according to which chemical class a compound is assigned. Once a compound was
categorized into one of the chemical classes shown in Table 12, Table 13
indicates which of the nine equation modifications will be incorporated into
the basic equation. Table 14 presents correction factors which had to be
taken into consideration for each compound.
Large percentage errors can be tolerated in estimating activity
coefficients. For example, a +10 percent variation in Y°° does not effect
predictions of vapor-liquid equilibria. In general, this method is capable of
predicting Y=° to within _+25 percent of the true value. Pierotti et al.23
gave an overall average deviation of 8 percent in Y", although in isolated
instances errors as high as 350 percent were shown. In three instances,
values were not obtained for Y^ and assumed to be equal to 1.
Henrv ' s Law-Constant
Some of the Henry's Law Constants (Hj_) were taken directly from the
literature. 23-2o por t-ne majority of compounds, the following equation was
used:
1 atm
x
i (mmHg) 760 mmHg
where: ?°^ = vapor pressure of compound i
S1 = solubility for compound i
M'.-«^ = molecular weight of compound i.
When the above equation is used, the data must be for the same temperature
(25°C) and physical state of the compound. Appendix A, Table A-3, contains a
summary of the chemical and/or physical properties compiled for the chemicals
identified in this report.
HEALTH PROPERTIES DATA
As part or GCA's revised ranking approach, it was determined that the
wastes should be evaluated based on both carcinogenicity and toxicity.
Thresnold Limit Value (TLV) data was used for the^evaluation of toxic effects
while maximum allowable concentrations at.the 10~5 Risk Level were used for
assessing the impact of carcinogenicity.
Toxicity Threshold Limit Values
Threshold Limit Values for several chemicals were compiled for previous
cnemical ranking efforts conducted fay GCA.^ Other TLV data were available
from data puolished annually bv the American Conference of Governmental
Industrial Hvjiier.i s t s . - ? The TLV refers to maximum airborne concentrations
to whicn nearlv all workers nay be repeatedly exposed (8 hr/day, 40 hr/week/
without adverse effect. In general, TLV data are well documented and based on
-------
TABL5 12 CORRELATING CONSTANTS FOR ACTIVITY COEFFICIENTS AT INFINITE
DILUTION, HOMOLOGOUS SERIES OF SOLUTES AND SOLVENiSa
Basic Equation
_,- u
Solute Solvent
(1) «>
n-Ac.ds Water
n-Primary alcohols Water
Secondary alcohols Water
Tertiary alcohols Water
Alcohols, general Water
n-Allyl alcohols Water
n-Aldenydes Water
n-AinencaldcnvCes Water
n.Keiones Water
n-Acetals Water
n-Ethers Water
/vNitnles Water
n-AUene nitnies Water
Temp. A, 2 B, C, D
ro .
25 -1.00 0.622 0.490 0
50 -080 0.590 0.290 0
100 -0.620 0.517 0.140 0
25 -0.995 0.622 0.558 0
60 -0.755 0.583 0.460 0
100 -0.420 0.517 0.230 0
25 -1.220 0.622 0.170 0
60 -1.023 0.583 0.252 0
100 -0.870 '0.517 0.400 0
25 -1.740 0.622 0.170 0
60 -1.477 0.533 0.252 0
100 -1.291 0.517 0.400 0
25 -0525 0.622 0.475 0
60 -0.33 0.583 0.39 0
100 -0.15 0517 0.34 0
25 -1.180 0622 0.558 0
60 -0929 0.583 0.460 0
ICO -0 650 0.517 0.230 0
25 -0780 0.622 0.320 0
60 -0.400 0.583 0.210 0
100 -0.3- 0.517 0 0
25 H3 720 0 622 0.320 0
60 -0=40 0.533 0.210 0
100 -0.293 0.517 0 °
25 -1 475 0.622 0.500 0
60 -1.040 0.553 0.330 0
100 -3.521 0517 0.200 0
25 -2.556 0.622 0.486 0
60 -2.184 0583 0.451 0
100 -1.780 0517 0.426 0
20 -0.770 0.640 0.195 0
25 -0537 0522 0.760 0
60 -0.363 0533 0.413 0
100 -0095 0.517 0 0
25 -0520 0522 0.760 0
60 -0323 0.583 0.413 0
ICO -0074 0517 0 0
p, LJd -3 J-*~
Modif
0 a
0 3
0 a
0 a
0 a
C 3
0 i>
0 "
0 b
0 c
0 =
0 c
0 d
0 d
0 d
0 a
0 a
0 a
0 a
0 a
0 a
0 a
0 a
0 a
0 b
0 b
0 b
0 e
0 e
0 e
0 b
0 a
0 a
0 a
0 a
0 a
0 3
-
-------
TABLE 12 (continued)
Solute
(1!
n-Esters
n-Formates
n-Monoa!kyl chlorides
n-Paraffms
/J-Alkyibenzenes
Alcohols, general
n-Ketones
Water
Water
Water
Ketones
AldehyCes
Esters
Aceta's
Parar'ins
Paraffins'
Water1
Water i
Solvent Temp. A, 2 B2
(2] <°C)
Water
Water
Water
Water
Water
Paraffins "
Paraffins
/7-Alcohols
jffc-Alcohols
/i-Ketones
/7-Alcohols
n-Alcohols
n-Alcohols
n-Alconois
Ketones
/?-Alcohols
Paraffins
/7-Alkylbenzenes
20
20
20
16
25
25
60
100
25
60
100
25
60
100.
80
25
60
100
25
SO
100
25
60
25
60
100
60
25
50
90
25
60
100
25
25
-0930
-0.585
1.265
0.6S3
3.554
1.960
1.460
1.070
0.0877
0.016
-0.067
0.760
0.680
0.617
1.208
1.857
1.493
1.231
-0.088
-0.035
-0.035
-0.701
-0.239
0.212
O.C55
0
-1.10
0
0
0
0.37
0.80
0.72
2.55
3.04 -*
0640
0640
0.640
0.642
c,
0.260
0.260
C.073
a
0.622 -0.466
0
0
0
0
0
0
0
0
0
0
0
0
0
0.176
0.128
0.112
0.1 70
0,138
0.176
0.138
0.112
0.138
O.J82?
0.475
0.390
0.340
0757
0.680
0.605
0
0
0
0
0
0
0
0.50
0.33
0.20
0.220
0.210
0.260
0.240
0.220
0.451
0
0.11450
0.0746
0.176
0.133
0.112
0
0
0
0
0
0
0
0
D
0.
0
0
0
0
-0.00049
-0.00057
-0.00061
-0.00049
-0.00057
-0.00061
0
0
0
0
0
0
0
-000049
-0.00057
-0.00061
-0.00049
-0.00057
-0.00049
-000057
-0.00061
-O.OOC57
-0.00049
-000057
-000061
-0.00049
-0 00057
-0 00061
0
0
F: Basic Equation
Modification
0
0
0
0
0
0
c
0
0
0
0
-0.630
-0.440
-0.280
-O.CGO
-1.019
-0.73
-0.557
-0530
-0.440
-0.280
-0630
-0.440
-0.630
-0.440
-0.280
-0.440
0.402
0.4C2
0.402
-0.630
-0.440
-0.280
3.88
-3.14
b
a
a
a
f
d
d
a
b
b
b
a
a
a
c
c
c
c
9
9
9
9
9
9
h
i
i
i
aSource: Reference 14.
DMcdifica;ions to the basic infinite dilution equation are sho'v'n
in Table 13.
-------
TABLE 13. MODIFICATION OF TERMS IN THE BASIC ACTIVITY
COEFFICIENT EQUATION
Modification of terms
a. B2N,
1 1
b
1 1
B-NI C| _!_ + _L+-?T7-VNr relates to R~ in R'(R")C(OR")2
f. B,
\ -' ' / v
h c f _L , _L 4. J- ). N- plates to R" m R' (R"l C (OR"),
h- C'\N; N;' N;-/'
N N. = total numoer of caroon atoms m molecules land 2. respectively.
N''N , N"' - number of carbon atoms ,n resSect,ve branches of brancned compounds, counting the
polar grouping; thus, for r-butanol, N' - N" - N'" - 2.
Eninei coninbuted Sv the jutnor of win cfiapttr.
aSource: Reference 1-.
-------
TABLE 14. CORRECTIOM FACTORSb FOR LOG Yi, PER GROU?a
Group A
F
Cl
Br
1
OH
(alcohols!
(phenols)
COOH
(in side chain)
(on ring)
0.14
0.70
0.92
1.40
-1.90
-1.70
-1.70
-0.70
Group
NH,
N0:
(hydrocarbons)
(m-, p-phenols)
(m-, p-anilines)
CHj (N, >8)
C=C (in side chain)
C=C (in side chain)
Polycyclic hydrocarbons
(naphthenes and biphenyls)
A
-1.35
0.15
0.30
1.00
-0.25
-0.30
-0.46
1.11 per addi-
tional ring
"Groups are attached to ring unless otherwise specified
'°Source: Reference li.
70
-------
extensive e:
^ ri,-, However one valid argument against the use of
xperimental da,a. Howe/er presenting is that the adverse
~ " -
j .-
v
'Irsus minor skin irritation for another.
.,jnoAenicitv - 1Q~5 Risk Level
it risk estimates define in quantitat j^^^ af ftned^af
as £
the
ilo'centrat"" of'l vgM of the agent in the air that they breathe
The maximum allowable concentrations at 1Q-5 Risk Level were
f~om potency slope data based on ingestion experimental data. The
of increased cancer risk is detined as:
p = 1 - exp (qi*d)
where; qi* = potency slope derived from experimental data
d = dose rate (rag/day)
? = probability of increased cancer cases
.,,3:
rate! (d) can be expressed in terns of pollutant concentration,
sn°wn d = (2.357 x
ES=SS :»;=£=::::,
the 10-3 Risk Level concentration can be shown to be:
qi"
-ab- 15 provides a summarv of the allowable concentrations at ^
R-k Levll 'or?52 compounds for' which the_Carc inogen Assessment Group (CA«,
t:,,::-'J" bas.d on iagestion carcinogenicity data and convertea. ...e da.a
r;-Ta.;ie IE is lifted by available carcinogenicity stucy results.
71
-------
TA3LE 15. MAXIMUM ALLOWABLE CONCENTRATIONS AT 10~5 RISK LEVEL
Compound ^
. 146
Acr/lonitnle _5
. n 1.2 x 10
Aflatoxin B, _2
Aldrin (dinethanonaphthalene)
Allyl chloride (3-chloropropene) ' 4 _
2.5 x 10
Arsenic _3
B [a] P 3-°Xl°
.673
Benzene _/
1.5 x 10 "*
Ber.zidine _-,
7.2 x 10
Beryllium _o
fj , 5.2 x 10
Cadraium (.dust;
.269
Carbon tetrachloride
2.2 x 1C "
Chiordane
Chlorinated ethanes
.507
1,2-dichloroetnane
611
1,1,2-trichloroethane
1,1, 2,2-tetrachloroethane '3
, 2.46
Hexacnxoroethane
.318
Chloroform _,
8.5 x 10
Chrorniun ~
4.2 x 10
DDT _9
. , . i -i -51 \ 2.1 x 10
Dichlorooenzidine k3,J -;
1,1-dichloroethylene (vinylidene chloride) -238 _
1.2 x 10~J
Dieldrin
11 3
Dinitrotoluene (2,4-) _ _^
Diphenvlhydrazine (1,2-) (hydrazobenzene) * 5 x 10
, , . 3.54
Epicnloronydrin _T
Bis(2-chloroethyl)ether
0 . 3.8 x 10~3
Bis vchloronetivy jJe tner
=^=^==
(continued)
-------
TABLE 15 (continued)
Compound
Ethylene dibromide (EDS)
, -, -A 5.6 x icf
Ethylene oxide
1. 64
Formaldehyde _
, . 1.0 x 10~
Heptachlor _
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclohexane
u i A 7.4 x 10
Technical grade
n ,_ . 3.1 x icfJ
Alpha isomer
1.9 x 10
Beta isomer _?
. 2.6 x 10~~
Ganma isoraer 7
.. , -, 3.0 x 10~"
Nickel
Ni trosainines _-,
,. . 1.4 x 10
Diaethy1introsaraine
. 8.0 x 10~4
Diethylnitrosamine _
6.4 x 10
Dibutylnitrosaraine _9
, . , . 1.6 x 10 ~
N-nitrosopyrrolidine _3
N-nitroso-N-ethylurea ' x _^
N-nitroso-N-niethylurea
N-nitroso-diphenylaaine
8.1 x 10 J
PC3s
Pnenols (2,4,6-trichloropheno1) l' ° _,
8.2 x 10~°
Tecrachlorodioxin
. 659
Tetrachloroethylene _ 9
3.1 x 10~^
Toxaphene
, . 2.78
Trichloroetnylene
2.0
Vinvl chlonce
-------
SECTION 5
HAZARDOUS WASTE RANKING METHODOLOGY
The hazardous waste prioritization methodology described below was
designed to provide a first cut estimate of the inhalation health impact
potential of various hazardous wastes currently being disposed in the United
States. Previous prioritization efforts,1 designed to screen hazardous
wastes for air emissions study, were determined to be inadequate in scope.
The revised prioritization approach described below was based upon
consultation with EPA's Office of Solid Waste, Office of Health and
Environmental Assessment (OHEA)/Washington, Environmental Criteria Assessment
Office (ECAO)/Cincinatti, and Carcinogen Assessment Group (CAG)/Washington.
Changes implemented with the revised ranking methodology included: (1) the
development of separate prioritization systems for toxic and carcinogenic
effects; (2) the inclusion of data for consideration of a hazardous
constituent concentration; and (3) consideration of TSDF disposal practices.
The following section discusses the hazard factor assessment employed in
developing the hazardous waste air emission prioritization. The basic
elements of the ranking methodology, as previously illustrated in Figure 1,
include the following:
hazardous waste quantity and distribution determination;.
hazardous waste characterization;
chemical properties and health effects data compilation;
hazard factor development; and
quantitv-weignted hazardous waste ranking.
The following discussion presents the reasoning behind the evolution of the
hazard factor. The closing portion of this section presents the results of
the hazardous waste ranking efforts.
DEVELOPMENT OF HAZARD FACTORS
The selectee approacn towards a numerical comparison of potential hazard
for wastes involves the calculation of toxicity and carcinogenicity hazard
factors. These factors were obtained by combining the health effects
information and vapor p^.ase concentration data for individual chemical
constituents of each waste code. The toxicity hazard factor is defined as the
74
-------
ratio of the gas phase equilibrium concentration to the Threshold Limit Value
(TLV) for a given substance. The care inogenicity hazard factor is similarly
defined as the ratio of the gas phase equilibrium concentration to the maximum
a,.owa3le concentration at the 10~5 Risk Level (10~5 RL). These ratios,
which bear analogy to a risk assessment procedure, yield unitless numbers that
are useful in comparing wastes on the same basis in a relative manner. In
general, lower ratios correspond to lower potential hazard.
Gas Phase Equilibrium Concentration (CQ )
Since^the emission rate is somewhat proportional to the equilibrium gas
concentration, the downwind concentration can be assumed proportional to the
equilibrium gas concentration. Tne gas phase equilibrium concentration
^Ceq'i for a compound is defined as follows:
(C ). =
X. V. P°.MW
.
eq i RT
= mole fraction of compound i in waste mixture (based on waste
characterization data);
'i = activity coefficient of compound i;
?i = vapor pressure of compound i;
--''£ = molecular weight of compound i;
R = universal gas constant;
T = temperature.
After computation of the molar gas volume at 25°C (24.45 I/mole), writin- the
expression for R in the desired units, and converting from ag/m3 to pom °the
equation reduces to: ' '
^eq'i = (Xi V (pi' rnmHS) d-3153 x 103)
In the initial ranking scheme proposed by GCA, a chemical's vapor equilibrium
concentration was calculated. After conversion to units of ppm and ppb th-
equation reduced to: '
Concentration (ppra) = (P°, mraHg) (1.3158 x 1Q3)
Concentration (ppb) = (?°, mraHg) (1.3158 x 10^)
Ihe revised ranking calculation of gas phase equilibrium concentration is a-.
extension or tne vapor equilibrium concentration in that it considers X-
mole fraction data and considers '.;_, activity coefficient data.
-------
( .«
activity coefficient CO. The act! nona,ueous »aste mixtures , I.e
assuming pure hydrocarbon mixtures.
vj^vrd Factor Calculation
' " Once the gas phase equilibrium concentrations were
effect, information and vapor P^-V^^SS^^al constituents of each
develop a relative hazard factor for «0^itucnt hazard factors were
'
category (aqueous and nonaqueous)
factor computation bears analogy to a risk "«"«f £
r^^ssiss: K ="-
ind.xe, for noxicity and c.r=ino8«ni=ity.
.u U.1..V.U.. ra r .sir:".*.^
Risk Level ware obtained from the e a concentration data
TOX
XICITY HAZARD FACTOR = (C^
TLV.
CARC1NOGENICITY HAZARD FACTOR =
C(10~5RL)i
where: (Ceq)i - the equilibrium gas concentration of compound i
= the
Threshold Limit Value of compound i
-
levelTt which one additional cancer death will
occur in one hundred, thousand) .
T,e toxicity and carcinogenicity ^^
method for comparing relative nazards or wastes ^ ^ 20Q ^^ mg
the basis of TLV alone, Methyl -thyl
-------
Upon examination of approximately 95 percent of the total waste volume
identified in Table 7, data appropriate for computation of the toxicity and
carcinogenicity hazard factors were found for approximately 100 waste types.
Chemicals such as arsenic, chromium, and cadmium as well as many others either
had no published vapor pressures or values significantly less than one mmHg at
25°C. Summaries of the chemical specific and generic waste types evaluated by
the aforementioned analysis are provided in Appendix A, Tables A-l and A-2.
Waste Volume Weighting
To account for a given wastes disposal volume, the toxicity and
carcinogenicity hazard factors were multiplied by the wastes' aqueous and
nonaqueous disposal volume (as presented in Tables 6 and 7, respectively) to
yield a waste volume-weighted prioritization ranking. This number accounts
for all specified criteria; constituent concentration, gas phase equilibrium
concentration, health effects properties (toxicity and carcinogenicity), and
reported aqueous and nonaqueous waste volume. The Part A waste volumes were
divided into aqueous and nonaqueous (i.e., TSDF type) categories, so that the
relative risk for a waste may oe evaluated based on disposal method.
HAZARDOUS WASTE PRIORITIZATION RANKING RESULTS
Table 16 presents the waste type toxicity ranking scores for the 63 waste
tvpes witn sufficient data. The toxicity hazard factor and volume-weighted
toxicity hazard scores are shown in Table 16 for both aqueous and nonaqueous
TSDF categories. Note that the volume-weighted aqueous TSD? scores are
generally greater tnan tne nonaqueous scores in spite of larger nonacceous
waste volumes (shown earlier in Table 7). This general trend is mostly due to
greater volatility and toxicity shown by the aqueous wastes as indicated by
the significantly higher hazard factors for these waste types. This
demonstrates tne importance of consideration of the activity coefficient in
these calculations. The following five waste types were found in the top ten
hazard scores for both TSDF categories:
D001 - Ignitable wastes, not otherwise listed;
D002 - Corrosive wastes, not otherwise listed;
F002 - Spent halogenated solvents;
F003 - Spent non-'nalogenated solvents;
V043 - Vinyl chloride
The o-eneric D-tvpe wastes were found in greater volume and D001 also had a
very high hazard factor. In general, the remaining wastes showed both high
hazard factors and large waste volumes.
77
-------
TABLE 16. WASTE TYPE TOXICITY RANKING SCORES FOR AQUEOUS
A:;D NON'-AQUEOUS TSD
_
Waste type
code
^
D001
D002
DO 03
F001
F002
FOU3
"004
F005
F006
F017
K001
K010
KOI 1
X012
K013
KOI 4
K015
KOI 6
K.01 7
K013
KOI?
K020
K021
K022
K.025
K02t>
K02Q
K04S
K049
Toxicity
hazard factor
f nr
i 3 7 4 0 .
4 C 5 i 2 . 14
. 659520 1
1 . 1 - 0 i 'i 5
226320 . 4
65450269
. 0 c 13422
.0127491
Volume -weigh ted
eoxicity h«x«rd
for
aqueous
TSDF., «
3.620E14
5.S30E13
9.216E1 1
1.081E12
t.2«SE13
6.646E13
2.525E10
9 . 7 2 0 E 1 1
1 . S13EI 3
6 . 3 3 1 E 1 2
3. 150E10
2.503SE3
31617544
4345. 177
3223156?
9 . « 1 4 S E 9
1 .033E10
7.943E12
236670.6
1 .934E1 1
2'.3S2?E9
5300335.
4544. 753
5 3 3 . 2 6 0 1
75 I41c79
1 . 5o8El 1
19705 .33
4S71 .40?
»A,u«ou. T30F categorie. include treatoent tank and treatment, «o»ge. and
dl.po.al .ur£-c. impoundment, fcn-.queou. TSCF categoriea include Uodfill, l.nd
application, and waata pila-
t>B«»*d on non-.queous activity coefficient (1.0).
cwei^ed by non-aqueous waste coae volume (metric ton./yr).
dB.sed on aqueou. activity coefficient estimated by infinite dilution procedure.
Weighted by aqueous waste code volume (metric ton./yr).
(continued)
-------
TABLE 16 (continued)
Waste type
code
K051"
K053
K060
K073
K083
K083
K08a
K087
K096
K103
uoo:
U002
UOO 3
U007
U008
U009
uo ; 2
UO 1 o
F028
U031
U2 1 1
U0«4
U037
U033
U037
U07C
UO'2
U079
U041
Ul 1 2
Toxic icy
hazard factor
for
non-aqueous
TSDFs,4
(Ceq)NA/TLV
I . 1 16E-4
7.524771
9 . 163E-5
2024! . 75
1 .85071 1
19.31010
215.0553
.4472925
406i3. 14
183.9972
43300
33.83
Mi.2
13.73
1 . 59
10200
90.5
60900
4780
1 « . 4 1
27200
3630
3630
32*0
110.4
23oO
9C 1 . 6
2340
614.3
60 .33
Volume-veighted
toxicity hazard
for
non-aqueous
TSDFs,b
34.63334
3997.242
4.483362
3.0806E8
31010.32
331303.4
3894876 .
36233. 30
3.0723E8
230420.2
3 . 3330E9
1365593.
2241268 .
492978.8
56983 .78
3.61 47E8
3216732
2 . 3098E9
75338340
3087 1 o . 1
4.331 3E3
1 . 3C70E3
1 . 3187E3
a . 2732E8
3 ' 1 3 o 3 0
83146440
32226790
83102760
9713769.
1906937.
Toxicity
hazard factor
for
aqueous
TSDFs,c
(Ceq)AQ/TL.V
.0015053
67C.6315
.0012361
6 ? 5 8 3 0 3 .
1 o 7 . 3 0 1 7
40416.04
24516.37
6.033976
15533320
4 5 '.. 8 7 9 0 .
709300
S32 .643
1537.668
4 6 i . 4 6 2 5
17.013
408000
8 5 t"i 7
1 .2752E3
100143*0
332.6?°
2iSiSSOO
o
344750
1 . 7 2 "- 3 E i
1 .2272E3
> o ? S 3 2 0 0
597SSO
f200.4
6355.65
Volume-weighted
toxicity hazard
for
aqueous
TSDFs,d
VAQ(Ceq)AQ/TLV
467.4871
2676490 .
16.80579
5.3374E"
60397 .7 1
12=23973
3.S407E8
690950 . 6
0
0
1 .352E1 1
1 U5697 1 0
3765749 .
23423. 13
79314.61
1 . OC93E?
8 1 6 5 ^> 1 ^ ?
1 . &07E1 2
2.501 1 S3
205*221 .
1 . 9 3 0 E 1 1
0
1 .152E1 '.
1 .26AE10
60472262
3 . 1 o 6 1 1 1
3 . 1 0 7 E : 1
5 .9005E9
722416. B
6867*154
«/W:ueous TSDF categories Include treatmeat tank, and treatment, storage, and
disposal jurface Impoundment. Non-aqueous TSDF categories Include laadflll, land
application, and waste pile.
bSaied on non-aqueous scci.va.cy coefficient (1.0).
c^i^nced Sy non-«queoi.s waste code volume (metric Cons/yr).
d3*,ed on »qurou, scttvLCy coefficient estimated Dy infinite dilution procedure.
«w«ijnced by aqueous waste code volume (metric tons/yr).
(continued)
79
-------
TABLE 16 (continued)
tf a 1 1 « type
code
Ul 13
Ul 1 7
U077
U122
U123
U140
UM7
U134
U043
Ul 59
U 1 o 1
U080
U16!
Uls9
U188
U 190
U '. 9 6
L!2 1 0
U220
U226
U228
U043
U078
U239
Toxic ity
hazard factor
for
non-aqueous
TSDFs,*
(Ceq)NA/TLV
79 10
933
756
20100
56.13
33.28
119.89
6.48
6100
96.12
284
2.49
3 . 0*
1 720
2 .33
129
1 9oOC
205
88.63
240
1250
753000
5i400
2910
Vo luae-we ighted
toxicity hazard
for
non-aqueous
TSDFs,b
VNAewe ighted
toxicity hazard
for
aqueoua
TSDFs,d
VAQ(Ceq)AQ/TLV
2.246E10
b080 185
2.290E10
3. 1538ES
300626. £
10236229
2162S1 .6
1475S5.8
1 .3975E3
645073^2
1 .S259E9
i O 7 «. t ,
S.7-J33ES
t ~. i o i, r o
1 . ..1~3£>7
6 7 3 2 9 o . 1
4794930
7 . 557S I 0
1.01 44E9
9.7905E8
4 . 9698E9
i . 333E12
: . 9 1 1 s : i
4 . -i 3 1 E 1 1
TSDF cacegorie« Include treatment tank, and treatment, itorage, and
dl»poi«l aurface impoundment. Non-aqueoua TSDF categories include landfill, land
application, and wa»te pile.
b3*ind on non-aqueou» activity coefficient (1.0).
c«i«i£fu
-------
Table 17 presents the results of the toxicity making scores by chemical
constituent. As expected, the chemical constituent results follow the same
trends as did the waste type results. Aqueous hazard factors were generally
several orders of magnitude higher than nonaqueous hazard factors. The volume
weighted ranking scores were generally three to four orders of magnitude
greater for the aqueous TSDF category.
A review of the top ten waste constituents listed in each TSDF category
shows that the following five waste constituents appear in both categories:
UQ19 - Benzene
U043 - Vinyl chloride
U196 - Pyridine
U211 - Carbon tetrachloride
* U239 - Xylene
All of these wastes exhibit relatively high toxicity hazard factors. Most of
the listed chemicals have low TLVs, while 1,2-dichloroethylene ana vinyl
chloride were particularly volatile. Note that xylene showed a low solubility
in water and high activity coefficient, thus contributing to its high hazard
r actor.
Table 16 presents tne waste type carcinogenicity ranking results for the
33 waste types with sufficient data. As noted earlier, the higher aqueous
vapor phase equilibirun concentration Ceq tends to produce higher ranking
scores for the aqueous TSDF category wastes. In general, the aqueous hazard
factors were two to t'""»e orders of magnitude greater than the nonaqueous.
The final volurie weighted scores were approximately four orders of magnitude
greater for the aqueous wastes.
A review of the top ten waste codes in each TSDF category shows that the
following seven waste types are found in both categories:
K315 - Carbon tetrachloride production heavy ends;
K073 - Chlorinated hydrocarbon wastes froa chlorine production;
« F002 - Spent halogenated solvents;
D003 - Reactive wastes, not otherwise listed;
a FG01 - Spent halogenated degreasing solvents;
81
-------
TABLE 17. CHEMICAL CONSTITUENT TOXICITY RANKING SCORES FOR
AQUEOUS AND NON-AQUEOUS TSDF CATEGORIES3
. . 1
Chemical
constituent
code
U001
U002
U003
U007
UOOS
UOC9
T ' A 1 -)
U V i *_
?02S
U Z 3 1
U^ * 1
». i i
I A e >
L V -J «i
u C*1 4
UOC7
U055
U057
U070
U07 2
L'079
UC41
U 1 i 2
U< i *\
i i j
C"l * Q
0 ' 7
U i 7
u * i /
IT * 7 7
U V / /
U 1 22
IM ? 1
U i 4. J
U 1 4 7
Toxic ity
hazard factor
for
non-aqueous
TSDFs,b
(Ceq)NA/TLV
47066. 35
3112.34 1
2 3 1 7 . 3 3 0
13.75
1 .647576
11211.13
100.9943
71393.06
47^9.210
30 .65693
4429S . 12
16581 .?4
2 4 : 9 6 . i 2
8260
2i;c. ?o;
93 1 . ?^52
623 -c.9 17
399.7541
7910
9 0 4 0 . -, o 1
1:25.305
75o
261 16. 23
60.92737
f. S . 0 4 9 5 1.
Volume-weighted
toxicity hazard
for
non-aqueous
TSDFs,c
3.4103E9
1 .7215E3
492973 . 3
76051 .40
3.615?E3
5 . S2 2 C E9
771246.4
1 . 5 -' 5 5 E 9
g.H9 49 .6
". . 4 b 5 ? E 3
1 . 456oE?
6.2732E3
4 S 3 0 7 1 i .
96517590
32263117
5 . 3 ' 2 2 E 9
9956205.
6 1 i 0 * 0 S 3
6 . 0 0 ' 1 E $
37794390
263^5456
2.7294E9
2122803.
3 2 9 c, 3 ° o .
t . 0300ES
Toxicity
hazard factor
for
aqueous
TSDFs,d
(Ceq)AQ/TLV
7 3 4 2 4 2 . S
76?o3 . 60
25235.73
463 .4625
17.62906
4 0 S 1 0 ? . 6
94 93 .515
1 . 4951E3
1315.132
3 5 ti 1 5 6 S 3
* o 5 o . 6 5 £
1 60 37 1 o .
~ . 5 * * 7 « 3
2 . 72C:?E3
32035. 12
434o2l39
76910221
174e3.37
-1977 .33
3274740
2 . 6 0 3 7 E 3
135045 ,?
259792
37920.77
7'3 60921
2926 .131
10597 .90
Volume-weighted
toxicity hazard
for
aqueous
TSDFs,e
1 .376E1 1
1 .207E10
1 .S24E10
23423. 13
696127 .5
2.3925E3
2 . 2 2 7 E 1 3
2.62 i4ES
6 1 5 0 S 1 6 4
9 . 125E1 2
95412037
1 . 202Z1 1
1 ~ C 1 T < ^
l.wvi^.O
o t 3 */ 2 E 1 2
1 . 411E12
3. 107E1 1
4 .507E1 1
9590J7. 4
2.354E10
2.24iEl^
1 . 105E1 3
C.2071E9
3.290E1C
1 . 0 5 7 E I 0
6733031 .
2.4015E3
1 . 224E1 1
us TSDf categories include treatment tank and treatment, storage, and
dlspoial surface iapoundaent. Non-aqueous TSDF categories include landfill, land
application, and waste pile.
on non-squeou« activity coefficient (1.0).
c«eij?ntea by non-»queou» waste volumes for all wastes containing that chemical, constituent.
db«sed on aqueous activity coefficient estiaatea by infinite dilution procedure.
'Weijyit^d by aqueous volumes containing that chenical constituent.
(continued)
-------
TABLE 17 (continued)
Chemical
const iturnt
<.0 7 1 3
50001 1 4i
92830762
34433736
5 . 2&50ES
1502^036
4 3 2 n 3 0 / 1
4 1 2 3 s - . .:
1 . 1573Ei
1 . 3- 5:F?
1 . 3 4 2 oE3
74:4-325
1 .S:.7:E9
7 . 7420ES
36970222
6 . 2 3 ' E 1 0
2 . 0 C 3 - E ?
9.9C^:E9
1 . 03 iEl 1
Toxicity
hazard factor
for
aqueous
TSDF»,c
422f -746
934352 . 7
12000&.2
13222376
6944 120 .
729057 . 9
2 . 901 1ES
21544800
1.0666E?
2 .3067E9
Volume -weighted
toxicity hazard
for
aqueous
TSDFs,d
VAQ(Ceq)AQ/TLV
4 . 5265E9
2 . 4594E?
S.4367E9
4 . 6 1 3E1 0
1 .764E1 1
3.096E12
2 . 647E10
12494556
3 . 4 3 1 E 1 2
7 . 170E1 2
2 . i o 2 E 1 0
1 . 7 C 3 E 1 1
1 .039E1 2
4 . 5 9 2 .-_, E S
1 . 8 0 " E 1 3
1 . 9 1 1 E 1 1
4 . 473E1 4
5 . 4<:4E1 4
ou« TSDF categories include treataent tank and treatment, storage, and
dijposal surface inpoundaenc. Noa-«queoug rSDF categories include landfill, land
application, and waste pile.
°Sa§«d on non-»queou» activity coefficient (1.0).
c««ignted oy non-aqueout waste voluc«s for all wastes containing that chemical constituent,
dia«ed on aqueous activity coefficient estimated by infinite dilution procedure.
Weighted by aqueous volumes containing that chemical constituent.
(continued)
S3
-------
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3 a
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or
U
~6-
>
H
o> rx- <> o ^^ (^i o -o n (^i -- o ~. < i - . l ro ^ f i o - ' to >r
CN I*", to ^ o o -r t>. i-O r- v i n * t
ir> «r «r j> r- o -o » -r - o i^ o 10 o> <>- t -f
.« ,-4 «J ,1- - tv, M _,,,,,.,-,,, ., _ ^- _ _ ^ ,
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-------
TABU', 18 (con! inued)
.i ft I noj;eii It Ity
baAild tart.n
tor
i- ly|n
tan I linden l < 11 y
llli.H'l ||>I
non-a<(nemt ,
Vo lume -we I yhted
lia/ard lor
IbUI's.,1-'
(VAf,)(Cuq)Al)/(1|r'> rlbk)
n'
; K ,;
; F
V. .,
6;° ^
3*3 F ;
: c
4.729EII
7.43I2E9
Hi,4 i 4.a4t-4I.g -../.-.I.!-. '9'fM"' J.187Elc,
llu/8 9.4ntui:J j. 34 .'1.14 . !^_.'_'_"
l u ,, .,,1 ...ni ,, e hiuninnil.m'iil . Non-aqiieons; TSDK catfRorl es
.A.,,,. -, ISDI- .-..lc,J,.lU-b In. Inde t,eato,.'Ut lank and II. H.nenl. si,-la,;., and ,llM-.,s.,l s,. < I e l,,,i,.,M,,,m. I
,,, l,,,le I iii,lllll, land ai-i-llc.il ,,-n, an,I uai.te. (. l U-.
I'll.,.,,d on noil-aqueous a, livlty coetlicienl (l.U).
^ ,J.'iBhted by ,,.>n-aq».',..is waste code volnini; (metric tons/yi).
,!,,,, ,.,,.=, activity coefUclcnt est,mated by ,nl,,ute dilution ^oc.dure.
Ji-i,lil«.,l by aqueous waste code volume (nieliic lons/yr).
-------
D001 - Ignitable wastes, not otherwise listed; and
U019 - Benzene, discarded off specification wastes.
Tae top two K-type wastes (K016 and K073) are listed here primarily due to
very high hazard factors. The other generic F and D type wastes showed
substantial waste volumes.
Table 19 presents the waste type carcinogenicity ranking results by
chemical constituent type for only ten chemical compounds. As expected the
aqueous category showed notably higher ranking scores than did the nonaqueous
category.
CONCLUSIONS
The foregoing analysis has provided a means of comparing specific
chemicals with each other with respect to the degree of air hazard. Tae
Toxicity and Carcinogenicity Hazard Factors are useful tools for relative
comparisons, especially on a national level. However, other factors including
TSD-specific criteria and exposed populations would also have to be weighed
prior to any decisions regarding chemicals to be sampled, etc. Although we
have^evaluated approximately 100 waste types, this analysis may omit specific
chemicals that are equally or more hazardous than those listed in this
report. In addition, it is noted that site specific hazards due to local
Disposal patterns and volumes may differ substantially from the results
presented in this study.
-------
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: 1 3 1 L : r t
: 1 3 i L r- ' i
1 1 3 ( t f ' f f
rj i n / / : r
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-------
REFERENCES
1. Roeck, D. R. and A. M. Kiddie. Assessm"* °* *** FacilitieS (TSDFs) and
Hazardous Waste Treatments, Storage and D posa l/;"£ ize cheaical
December 1932.
Division8to'u^.E.p'.A., Office of Solid Waste. August 1933.
- "as-a- I-v Reoort on the Telephone Verification Survey of Haza
J' Wasce^TSDFs'Regulated Under RCRA in 1981^ Submitted^ US. ^-,
o-Tsolid Waste°in November 1932. U.S. EPA-63-Oi- --
_. K. W. Brown and Associates, Inc. Hazardous ^^lTL^,Tr2^^n,^_sw_374
__. - ^ 1 * 1 * T *---i-tr-iHianT^'T>i .7 1 7 O ' w «J I-,*--
^__ Submit-
. arown dLi^ .-xjo>^^^>^' j . _, , ~ '
-o U.S. E?-^, Office of Solid Waste in reoruary
5 v^ro Cor,. Composition of Hazardous Waste streams Currently Incinerated.
Suomitted'to U.S". EPA, Office of Solid Waste in April 1983. US.
EPA-63-01-6092.
b.
U.S. EPA-SW-39-J-.
7. State of California Air Resources Board. Letter^dated^uly^, ^1933 to
3. Federal Register, Volume 45. May 19, 1980. pp. 33119-33133.
9. ICF Incorporated. RCRA Risk/Cost Policy Model - Phase II Report.
August 1932.
n. Perrv, R. H. and C. H. Chilton. Chemical Engineers Handbook, 5tn Editio:
McGraw Hill Inc. 19/3.
- D,^ J. (Editor). Langes Handbook of Chemistry, 12th Edition. McGraw
rUll'lnc/ 1979.
R^, _ p.. C., J. ":. Prausnitz, and T. x. S/.-ervood. rroper.ie^
3ra'-,T .-. i -
-------
13. Feider, R. M. and R. W. Rousseau. Elementary Principles of Chemical
Processes. John Wiley & Sons, Inc. 1973.
1-f. Lyman, W. J., W. F. Reehl and D. H. Rosenblatt. Handbook of Chemical
Property Estimation Methods - Environmental Behavior of Organic
Compounds. McGraw Hill Inc. 1932.
15. National Climate Center; Ashville, North Carolina. Comparative Climate
Data through 1973. Average Annual Wind Speeds for U.S. Locations.
15. Freeman, R. A. Stripping of Hazardous Chemicals from Surface Aerated
Waste Treatment Basin. APCA/WPCF Specialty Conference on Control of
Specific (Toxic) Pollutants, Gainsville, Florida. February 13-16, 1979.
1.. Morrison, R. T. and R. N. Boyd. Organic Chemistry. Allyn & Bacon Inc.
1973.
IS. Handbook of Chemistry and Physics, 5th Edition. Chemical Rubber
Pubiisniag Co. 1976.
li. Screitwieser, A. and C. ri. Heathccck. Introduction of Organic
Chemistry. Macmillan Publishing Co., Inc. 1976.
2G. Wincnolz, :'.. (Editor). Merck Index, 9th Edition. Merck & Co., Inc.
21. Lewis R. and R. Tatker (Editors). 1930 Registry of Toxic Effects of
Cnenical Substances, Volumes I and II. U.S. Dept. of Health and Human
Services. FeDruary 1932.
22. Stevens, R. PnD. (Editor). Dictionary of Organic Chemistry, 4th Edition.
Oxford University Press. 19b9.
23. Mac .cay, D. Environmental and Laboratory Rates of Volatilization of Toxic
Chemicals from Water. Academic Press, Inc. 1981.
2J-. Mackay, D. ana 3. J. Leinonen. Rate of Evaporation of Low-Solubility
Contaminants from Water Bodies to Atmosphere. Environmental Science of
Technology, Vol. 9, No. 13. December 1975. p. 1179.
2j. Shea, T. T. A Simplified Method for Estimation of Hazardous Emissions
from Waste Lagoons. New Yor.< State'Dept. of Environmental Conservation.
Albany, New York. 1932.
25. Maney, W. R., J. H. Smita, and R. T. Bodoll. Aquatic Fate Process Data
for Organic Priority Pollutants. SRI International. EPA-440/4-31-OU.
3ecenoer 1932.
-,. .-\ Tie near. C jnr erer.c ^ o: Governmental Industrial liygienists. TLV's
Tr.rasnold Limit Values f:>r Chemical Substances in Work Air Adopted D--
-------
APPENDIX A
WASTE TYPE DESCRIPTIONS AND PROPERTIES
-------
TABLE A-l. SL1-iM\RY OF SPECIFIC WASTE TYPES SELECTED FOR ANALYSIS
Waste Code
Stream Description
U001
U002
U003
U007
U008
U009
U012
U019
P02S
UC3L
P022
U211
U052
UO^-r
U054
L" 0 3 7
U055
U057
U070
U072
U079
U092
t'0-rl
U112
UL13
C049
U177
U 0 7 7
U122
Acetaldehyde
Acetone
Acetonitrile
Aerylamide
Acrylic acid
Aerylonitrile
Aniline
Benzene
Benzyl chloride
Butanol
Carbon disulfiae
Carbon tetrachloride
Cresols
Chloroform
Cresylic acid
Chlorobenzene
Camene
Cydohexanone
o-dichlorobenzene
p-dichloroethane
1,2-dichloroethane
Dinethylamine
Epichlorohydrin
Ethyl acetate
E-chyl aery late
Etnyl benzene
Ethyl ether
Etnylene dicnioride
Fonaaldehvde
-------
TABLE A-l (continued)
Waste Code
Stream Description
U123
P0o3
U134
UL35
U140
U147
U154
U0^5
UL59
U161
UGSO
U165
UI69
U188
U190
U19o
U210
U220
U223
U22o
U228
U121
AC 5 5
UO-3
U073
U239
Formic acid
Hydrocyanic acid
Hydrofluoric acid
Hydrogen sulfide
Isobutanol
Maleic anhydride
Methanol
Methyl chloride
Methyl ethyl ketone
Methyl isofautyl ketone
Methylene chloride
Naphthalene
Nitrobenzene
Phe no 1
Phthalic anhydride
Pyridine
Tetrachloroethylene'
Toluene
Toluene diisocyanate
1»1,1-trichloroethane
Trichloroethylene
Trichlorotrifluoroetnane
1,2,3-trichloropropane
Vinyl chloride
Vinylidene chloride
Xylene
-------
TABLE A-2. GENERIC WASTE TYPES SELECTED FOR ANALYSIS
Waste Coae Stream Description
D;J01 A solid waste exhibiting the characteristics of ignitability,
but is not listed as a hazardous waste in Subpart D.
D°°- A solid waste exhibiting the characteristics of corrosivity,
but is not listed as a hazardous waste in Subpart D.
0003 A solid waste exhibiting the characteristics of reactivity, but
is not listed as a hazardous waste in Subpart D.
The spent halogenated solvents used in degreasing,
tetrachloroethylene, trichloroethy lene, methylene cnloride,
1, 1,1-trichloroethane, carbon te trachloride, and the
cniorinated f luorocarbons, and sludges from the recovery of
tnese solvents in degreasing operations.
The spent halogenated solvents, tetrachloroethylene, neihylene
chloride, trichloroethy lene, 1, 1, 1-trichloroethane,
cnloro benzene, 1, 1, 2-trichloro-l, 2, 2-trif luoroethane,
o-dichlorobenzene, t richlorof luorome thane and the still bottoms
from the recovery of these solvents.
The spent non-haiogenatea solvents, xylene, acetone, ethyl
acetate, ethyl benzene, ethyl ether n-butyl alcohol,
cyclohexanone, and the still bottoms from the recovery of these
solvents.
The spent non-halogenated solvents, cresol and cresylic acid,
nitrobenzene, and the still bottoms from the recovery of taose
solvents.
The spent non-haloganatee solvents, mechanol, toluene, raetny
ethyl ketone, methyl isobutyl ketone, carbon didulfide,
isoDutancl, pyridine and the still bottoms from the recover/ of
these solvents.
r°°° Wastewater treatment sludges from electroplating operations.
F00/ Paint residues or sludges from industrial painting in the
mecnanical and electrical products industry.
Bottom sediment sludge from the treatment of wastewaters from
wooc preserving processes that use creosote and/or
pentachlorophenol.
(continued)
93
JrOG;>
-------
TA3LE A-2 (continued)
Waste Code
Stream Description
KG 09
K010
Distillation bottoms from the production of acetaldehyde from
ethylene.
Distillation side cuts from the production of acetaldehyde from
ethvlene.
K011
Bottom stream from the wastewater stripper in the production of
acrylonitrile.
Still bottoms from the final purification of acrylonitrile ir.
tne production of acrylonitrile.
Bottom stream from the acetonitrile column in the production of
ac rylonit rile.
K013
Bottoms from the acetronitrile purification column in the
production of acrylonitrile.
Still bottoms from tne acetronitrile purification column in tne
production of ac ry lone rile.
Heavy enas or distillation residues from the production of
carbon tetrachloride.
Heavy ends (still bottoms) from the purification column in the
production of epichlorohydrin.
Heavy ends from fractionation in ethyl chloride production.
Heavy ends from the distillation ot ethylene dichloride ir
etnylene dichloride production.
Heavy ends from the distillation of vinyl chloride monomer
production.
Aqueous spent antimony catalyst waste from fluoromethanes
production.
Distillation bottom tars from the production of phenol/acetone
from cumene.
Distillation bottoms from the production of nitrobenzane
nitration of benzene.
-------
TABLE A-2 (continued)
Wast a Code
Stream Description
K026
K027
K029
K030
KO'-S
K0-f9
KG D'L
K053
K06C
K073
K083
KC35
K035
KOS7
K096
K105
Stripping still tails from the production of methyl ethyl
pyridines.
Centrifuge residue from toluene diisocyanate production.
Waste from the product stream stopper in the production of
1, 1, 1-trichloroethane.
Column bottoms or heavy ends from the combined production of
trichloroethylene and perchloroethylene.
Dissolved air flotation (DAF) float from the petroleum refining
i r.d u s t ry .
Stop oil emission solids from the petroleum refining industry.
API separator sludge from the petroleum refining industry.
Chrome (clue) trimmings generated by subcategories of tne
leatner tanning and finishing industry (deleted by 45 FR 72039,
October 30, 1930) .
Ammonia still time sludge from coking operations.
Chlorinated hydrocarbon wastes from the purification step of
the diaphragm call process using graphite anodes in chlorine
production.
Distillation bottoms from aniline production.
Distillation of fractionating column bottoms from the
production of chioro benzenes.
Sludge from treatment of process wastevater and/or acid plant
blowaown from primary zinc production.
Decanter tank tar sludge from coking operations.
Heavy ends from the heavy ends column from the production of
1,1, 1-trichloroethane.
Seoarated aqueous stream from the reactor product washing step
in the production of chlorobenzene.
-------
TAIH.K A-'}. SUMMARY 01' CHKM[CAL 1'KOI'KKTY DATA FOR KI>A CONST!TUKNT CODES
I'' I. I ' '.. I .Mill III.
""'" ' y I mil l. (-' |,i II).. n inn l. I
' iy!'. '»- I'l-M" ".". i' "H
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111)! I, 2 , 4~ii u h lorupLiLMioxydOft it- Jic nl
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U I 2H Huxuch I oio butadiene
U| JO Muxach lotucydopen tad lent*
COfj 1 llcxauo
1,272 1-llux.iiiol
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0.081
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0.229
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1.211x10
1. lid 9x10
0.271
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5.614x10
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50
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TABLE A-'i (coiit.ii
'I)
,,,,,
II 1 ', 2
II .' J J
III 1, J
U 1 9 1
i IIH.'
i 2/9
l, 2 / S
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1 069
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mi' thy 1 lien/enaiiu ne
1 hy I M.-lliacry 1 ate
Mi; 1 hy Ipyr id nnl ( 2 -p ico 1 i ne )
ipholine (dietliy l.-m- iiuide oxide)
upleiii- (l)npieiie)
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Al
IV
IV
1'e
I'll
I'll
PI,
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cohol-octyl < 1-oi.lanol)
ul ai-li 1 01 o benzene
ntai-hloroethane (I'entalln)
nt act, toropbenol (ch loiophen)
.:nii-elln ( p-e tlioxyd 1 ace t anillde)
osgeni: (carbonic acid diUiloride)
thalicacld ( 1 , 2-be uzened icai boxy 1 ic acid)
perazine (d le t hy lened lamlne)
I'l op a no) ( 1 bopropy 1 a Icohn 1 )
ClO'i ft op 1 onaldeliy de (pfopanal)
1,219
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cm
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11219
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opylene glycol ( 1 , 2-pr tipa ned 1 ol )
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btyrene (e thy 1 enebenzene , vlnly benzene)
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t
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. 0 5 /
.108 1.12x10"^
.064 6.8 xlO
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300
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7.28
(cont uiut J)
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-------
APPENDIX B
COMPUTER OUTPUT OF HAZARDOUS WASTE
PRIORITIZATION RANKING SCORES
102
-------
w
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TABLE B-l (continued)
: JEE
L' '.' '.' i
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104
-------
TABLE B-l (continued)
U 0 T 0
U 0 71
U 0 . V
U 1 1 2
2 " 1 t.
r, ,'1 r. [
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3.723SE3 24054.4 1.2272E3 463S3200
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S 9 3 -3 £ 0 17200.4 o ;--.,
o*1032l 1 ~ i -i 3 . 3 -
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-------
TABLE B-l (continued)
UH3 C04<= U117 U077
U122
U123
U14.
w - *-
;::;
L' *.' '.' *
,_ . . -
E >J G 3
FGG1
FGG2
F G G 3
FGG4
F 0 0 5
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* V V
F017
r* '.' ' .' *
--'-'* -
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r '"' 1 3
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TABLE B-2 (continued)
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:lude landfill, land arr>licaticn, and waste pile.
-------
TABLE B-3.
WASTE TYPE VOLUME WEIGHTED TOXICITY HAZARD BY WASTE CONSTITUENT
FOR AQUEOUS TSDF CATEGORIES*
u : o :
U003
U0 0 7
IK"!'1:
w - J-
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£, ,-, - 0 C' 0
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-------
TABLE B-3 (continued)
UOi'' P023 U031 U:ii U052 U044
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TABLE B-3 (continued)
U055 U05- U070 U072 U07* UO-U
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CODi
Ul 1 3
TABLE B-3 (continued)
C04* U117 U07
ui::
U123
u 14 o
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B 0 0 2
D 0 0 3
F001
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-------
TABLE B-3 (continued)
CCEE U147 U134 U045 U15':' Ulol UC? ! U i ;o
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DC 02
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U U 1.- C
TABLE B-3 (continued)
u i s 3 u i 9 o u t'' t. u : i o u:: o u;
D 0 0 1
D 0 0 2
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TABLE B-3 (continued)
POO:
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i3 volun:e-wei5hted toxicity hazL. ._ . , ,. ^,^&^ ra^<
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123
-------
TABLE B-4. WASTE TYPE VOLUME-WEIGHTED TOXICITY HAZARD BY WASTE CONSTITUENT FOR
NON-AQUEOUS TSDF CATEGORIES*
U " 0 1 U 0 0 2 U 0 0 3 U 0') 7 U C 0 I
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0 C. 0 0 0 0 0 0 0 c. 0 0 , 0 0 0 0 0
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tn I
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(T1 ___-..--. C' O
O O (JJ O O O _ - O v <-
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tn '.--' '-
o- o ° ° ° oo ° l'J'r' ° '
-------
TABLE B-4 (continued)
u : 5
U070
U079
U 0 4 1
ui i:
0
0
0
0
0
0
o
0
0
0
C
C
o
o
(j
o
1 J
o
,:
0
0
0
o
0
0
0
0
o
0
o
0
0
o
0
0
0
0
0
c
o
0
0
0
0
9 i 7 0 2 o . 3
0
0
0
0
c
o
(j
0
0
0
0
0
0
("l
0
o
o
o
o
0
f,
0
0
0
o
0
o
0
0
0
0
0
0
0
0
0
0
112*8 3 2 7
0
0
0
0
0
o
0
o
0
0
0
0
0
0
0
o
i"l
o
0
0
0
o
0
0
0
0
0
o
0
0
0
0
0
' u ^ 4_ J_ I »_ /
(j
0
0
0
0
c
0
0
0
0
0
0
0
0
0
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0
o
0
o
0
0
0
0
0
o
0
0
0
0
0
0
0
c
0
o
0
o
41227.01
2.4435E3
0
0
0
0
0
0
0
0
0
0
o
0
0
o
0
o
0
0
o
0
0
0
0
0
0
4 . 5 3 2 >5 E 9
0
0
0
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0
0
0
0
0
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4. 1 143E3
0
0
0
0
0
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0
0
o
0
c
c
0
0
0
0
0
0
0
240420.7
0
o
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0
0
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0
0
o
0
0
0
0
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0
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0
0
0
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* : o 0 ? 0 . 7
0
5 1 0 9 9 5 '' 0
0
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0
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0
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0
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0
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0
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c
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0
0
0
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0
0
: 2 2 2 i 7 9 0 3 3 1 0 2 7 o 0
1 5
3,-, ~
-------
TABLE B-4 (continued)
U 1 1 3
U07
U 111
U123
0 4
0
0
0
0
0 1
o
0
0
0
0
o
o
o
o
o
0
IJ
0
0
o
}
0
0
o
o
o
0
0
0
o
0
0
0
0
0
0
0
6. 00Q1E3
4 5 -'5'-'. 3
0
0
0
0
.35S2E3 2
0
0
0
0
0
0
0
0
0
A
U
0
0
I J
U
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0
0
Ij
o
0
0
0
0
0
0
0
0
o
f;
0
0
0
o
o
0
0
0
0
2565? 6 4
o
0
0
0
0
0
0
0
o
0
0
0
0
0
o
0
o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
15223^2;
0 2
0 3
0
o
0
0
0
0 3
0
0
0
0
0
o
0
0
0
0
0
'J
0
o
0
0
0
0
0
o
0
0
0
o
0
0
0
0
0
" 0
0
2 i S 3 5 4 5 o
.056oE? 1653150. 224323.3
9255931 632.4449 0
0 0 0
o o o
0 0 0
o o o
o o o
35665.3 0 2531073.
0 0 0
c o o
0 0 0
o o o
o o o
t ) 0 0
( ; 0 0
U 0 0
0 0 '-
o o o
o o o
o o o
o o o
o o o
0 0 0
o o o
0 l' 0
o o o
o o o
o o o
o o o
o o o
o o o
o o
o o o
o o
o o o
o o
0 (.' ' '
o o
0 0 ''-'
6.3323E3 46 3'^0. o 541-i'c . '?
i.OO?lE3 1.3o27E3
127
-------
TABLE B-4 (continued)
U14'
U 1 5 4 U 0 4 5
U155
U i 6 1
U 0 S 0
UU5
246015:
77*474'
649535
4 7
0 95.115
46953 40539.
0
0
29
65
0
0 7576374.
' 0
0
0
o
0
o
o
0
0
0
0
o
0
0
0
0
0
0
c
0
o
0
o
0
o
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20 0 3 7.73
0
0
0
13063358
0
0
0
0
0
0
0
0
1*735404 1
0
65599. 0 3
1405.722
531124.3
3432670 3
0
39337761
0
0
0
0
0
0
15999?
0
0
o
0
0
0
0
0
0
0
0
0
o
0
0
10 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Io74026
,6 1
0
o
0 1
0 2
0
27265203
0
425124.1
0
0
o
0
0
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0
0
0
0
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0
0
0
o
0
0
0
0
0
0
o
o
0
0
0
0
5025943
3052E3
0
o
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0
0
0
0
0
0
1476422'
u
0
0
0
0
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1 0 0 5
0
0
0
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0
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0
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IJ
IJ
0
0
1 . 0 3 0 0 E :
5 00 01146 ° 2 3 3 07 3 i
34483936 5.2o50E3 1502:
-------
TABLE B-4 (continued)
U 1 3 3 U 1 9 0 U 1 * 6 U 2 1 C U 2 2 0 U 2 2 :
0
0
0
0
o
0
15645041
0
0
o
0
c
0
o
0
f,
V
o
0
r,
o
0
0
0
0
0
0
0
0
0
0
o
0
o
0
0
o
0
232769.3 65 3
01.1
0
0
0
0 18 .
0
0
o
0
. 1412*22
0
0
0
0
o
0
0
0
0
0
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4 7 1 S . 0 3 i
o
i .477100
0
1 7 i 6 . 7 4 o
233.3793
34.65334
3 c 3.2775
4.435362
0
1336.14 0
0
0
5 o 25 3. 30
0
0
6432- .92
4 6 3.3 1
453E3
0
0
0
21055 2
0
0 1
0
0
o
o
o
0
o
0
o
0
0
0
.
o
U
o
0
0
0 '
0
0
0
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0
0
0
0
0
0
0
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4:3*0 3*
, 4000E9 220115
0
0
0 256193
0 o 0 4 0 6 1
7800.0 0
0
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0
0
0
0
0
0
0
0
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0 414*61
0
0
("l
U
0 :? 3 ^ i 3 1
0
0
0
573216*.
0
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/>
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0
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3.120*E3 35o2
^ . 3245435.
0 25^5965.
0 177 0 573 6
73 660382.6
69 613.2339
0 23547.45
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0 15521 0 3 2
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o o
0 4073 * 5 '- .
75 0
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o o
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0 '.'
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0 0
4*0 3 3 2 '" 1 2 0 .
23207353
0
0
1 9 2 * 1 o . i
3.4530E3
0
0
0
c
0
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0
v
0
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c; "' "~ o 'I; "C ~:
,'. ^, ,' '~ '^ "^ -'
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0
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0
51 i 0 ° i '.
4 :2 ; 3 : 4 i 4 i 2 :: o . 4
1.1573E3 1.33531- 1.341sES 7-;,44325 1.32"Z-
129
-------
TABLE B-4 (continued)
U22S A055 U043 U07S U23*
IS a
2.3
2 .5
c
-. . J
2 ; :
231.4
0
0
6 3 ° E 3
9 0 5 E 3
0
0
0
0
0
o
o
0
0
o
1 J
0
f
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1 75E3
0 3 6 '- 7 v
0
o
/
o
0
0
0
0
0
0
0
0
0
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o
0
2375 0
o
0
0
0
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0
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0
0
0
0
0
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0
o
0
.> jl .. 4-
0
o
(J
0
0
0
0
0
0
0
0
0
0
0
0
o
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0
0
0
1 . 1 2 4 5 E 3
0
0
0
0
0
0
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0
0
0
o
0
0
0
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0
0
0
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0
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0
0
0
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0
0
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0
0
t- . 1 2 1 E i 0 2.0
0
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0
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0
0
Q3°E*
7 . 445'r'E°
90319215
0
991730.5
0
1 .2145E-
0
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4.9696ES
5.8245ES
0
0
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0
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0
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6 3 2 ° 2 5 0 0
1 . 6 0 o E 1 0
1.43 i 2 E ;
1 .o320E3
4. 1554E3
i.Ool2E?
1 .4;'41E9
16435037
2.7301E3
5.4300ES
6.41 6 6 E '-
1 1 0 0 5 3 . *
3 033517 3
10672'; . 2
3 7 5 £ 0.32
4 0 ° 3 3 ? 4 .
1 122o4o5
1 T- ~ "" C T? T
5 . 3 3 c o E :
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2 . 5 1 3 1 E 3
5 .7557E3
r, . 0±~ 11E.I
1 3 1 :- ': 1 3 .
4713. 0 .: -.
501 . 3 ' 4 ;,
5732170.
4 . ' 5 1 3 E '
1743.7-0
J 'i b b / '""'.:
34.653-4
5 ° ° 7 . 2 4 2
4 . J. S 5 3 i 2
3 .030oE3
31010.52
3 J 1 i '.' 3 . 4
3 3 ° 4 3 7 o .
S .-. ' c " . ' 0
5 . 0 ~ 2 3 E ;
4. 5 ',' *^ -' *-
' 4 2 0 E 3 31- ' 7 0 2 2 2 6 . 2 3 4 E1 0 2 . 0 0 3 9 E ? Q . 9 0 9 3 E ?
-acueous volume weighted toxicity hazard factor equals: (Ci,eq/TLV)*(
-- ^eo-5 v.--£te ft;e vDl'urr.c"1. Xon-acueous categories include landfill,
130
-------
TABLE B-5. WASTE TYPE CARCINOGENICITY HAZARD FACTORS BY WASTE CONSTITUENT
FOR AQUEOUS TSDF CATEGORIES*
UI I 1 U 0 4 4 U 0 4 i U i 11
_ - . ,
E 0 ! I
EI 0 ' j 3
F J 0 1
F 0 0 I
F .' 0 ;'
F -! 'j 3
':\ 0 0 i
;; o 1 1
r.oi z
.'- '.. 1 -r
... , _
r ,'i < -'
:: '. ! :
-' ,- - .
:;: i:
r. : i ^
l w _ "T *
r ' =; i
-'-'- -
r. . : 'J
r ;, - :
r - - - -.
, . . -
0
0
o
o
0
0
0
-, < CT tr ~ '"
O O i _/ J -'
i i .: o o s ° :
o
r
0
1 . ^ >"' 1 4 E r'
r,
u
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r,
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o
'.'
0
.
(J
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0
3 . 0 4 : E 1 1
0
0
4 . ~ 7 o E 1 1
0
0
o
0
3 . 0 0 t E 1 1
^
o
0
o
(j
l")
l !
v",
'.'
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'-J
'j
^
u
A
1 .4-IEi 1
' j
0
S. 457E1 i
0
u
0
0
0
0
0
I . 0 1 1 E 1 4
0
0
? . '< 1 ~ E i 1
i . i i o E i :
o
0
o
0
L'
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1 . . ,i ' j i . +
-
.-
i. 1513ES
0
0
0
1. 3I47E9
0
0
0
0
l-'
'j
o
0
v./
3. 150E10
I . 517E10
',
'-
0
<;,
^. . -.' - * - - o
,
r>
,,
0
0
0
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0
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3 . ' '-' 3 i E 3
'j
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tj
0
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fl
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1.)
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i:*5?3.:-5 1:0 -!'.?
1 * '*' * ^ '"' - \>
0 0
0 0
0 0
0 0
i 4 o 3 : :- 5 . o
U c. -' i . : - - t
0 0
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0 0
I.I >.'
0 0
0 0
0 13-7'-c4.
0 1 I : 4 . 1 . 4
0 i ~ 7 'r 7 1 . ;
0 3 : i 3 ~' . '' i
'-, t-^i;-i-
l. v
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o i * i ,-, 4 = : H
1.113Z10 i.O':5Ei: Z.^oOEli 5.3I4E10 3o7iVvS5 437--:7:i 344?5o.o
-------
TABLE B-5 (continued)
U - i >.'
U 0 4 3
DO 01
D 0 0 3
F G G 1
F G u "
i V V *-
F G G 3
FGG5
K.CO 1
?;o 1 1
T- - 1 "L
KG 14
r '"i t -
t . i ->
I. j i ,
K - 1 3:
K ~> ~ *
! ". 7 !
- -~~
'' - 1 :
'. I , ''.
r w - :r
-
I '.' ~ -
t '.- : .'
I j 3 3
F'. 0 !; ~
sun
G 3.5135E?
0 G
2.352E12 0
IT ,-, =; ., r ( 0
G 0
0 0
G 0
0 0
0 l-!
G O
-. - - -? 1 - 0
t", (J
G 0
o . 1 5 3 E 1 G 0
0 0
G 0
G 0
G '"-'
M G
0 G
G '-'
."' 0
3 . G 4 o E 1 0 0
G 'J
o o
4 . G 2 : E : 0 1 . 3 5 1 E 1 2
l.i,GE13 1.334E12
G
0
G
G
0
0
0
0
0
G
G
0
G
0
G
G
i.'
G
(]
t
i
G
G
3.5-3E12
3.3?3E12
1 . 1 35E12
3.513oE?
3.G49E12
3.697E12
5.057E12
4.77oEl 1
e, ? 1.6224
i . 3 1 5 5 E 3
1 1 o G G 3 9 2
2.G57E14
3.o'?31E3
1 .5G24E-
4 . 0 o 1 E 1 2
1 .235E12
1 P o 7 -< - a .
1334.134
177?72.0
^ ,-, r !-! "' , '"' 1
l -. - - 1 = '
4 : - i - .'
1 7 o ;' 5 3 -* 1
o=- 57 i ~^c 2
2 . G G ''' E 1 4
3211557.
1 7 3 o 4 3 2 4
1 . 417E1 3
4.425E1J
- =
G~5 Risl:;. Aqueous TSDF categories include
a2e, and disposal surface impoundments.
132
-------
1A3LE B-6 WASTE TYPE CARCINOGENICITY HAZARD FACTORS BY WASTE
FOR NON-AQUEOUS TSDF CATEGORIES*
C G E E
D 0 C1 1
D 0 0 L
D 0 0 3
F 0 0 1
FOO:
FOO 3
F 0 0 5
11 0 0 1
KOI 1
tl 0 i 3
t.(j I *
r. -: i o
r ."i * ~
i.. '.' i <
K010
u o : i
T- , ~ "
[ ^ -' -
11 0 - i
H 0 - 3
11 j 4 '"
K : 3 1
u - - ^
r .;. ,- r;
t-1 0 7 3
K 0 3 3
u .-:.-.« i>i' uin u'-'44 L"-'-1 Ui- _:::
;, 4 7r,u-E^ l.855oE3 c 47 5 007. (J i;:i^1-1_; - '"-^
f , 0 U / .1 i , O . '
0 1 4".->'E^' 0 0 ° ° |-
0 ' ""^0 1.0519E- 0 0 0 J-|
? . ....-4 ?, 13?44"S 1 o
" --'-" '-'; 0 o 0 445474?. _ _^
'-' ' ,- r, i" 5 1 . *. c '' -
o o o <-» ^ :
,.-.-,o,--, o o (-' 'J i
1 J ' ':' '. :' ' '. ,'-, o o °
i'''1-"-'--- -' . . ; , o o o
0 1 4 " 41 '"^ H '" " /i
0 " 0 I.514E11 0 _^_ ; £
j (-' c' ^ ^ ------ ^ _
u 0 ^
:'"5"'J'o 0 4.3714E? S.5735E3 0 ^ "
0 0 1.50a3E= :.c4^E3 v - 14.;?;^
0 (-' u 1 Ci 1 ') " . --"'44
0 '-' ' i J - - -
? 0 0 0 0 131?-:!;
^ : ; ,-, c o - - i '-' - -
* ( i L1 « - . i - *~ ~
,-j r, u : - i * - '
° J, ; o 0 0 1311733.
Pj 'J ^ " . - - -, - cr
0 0 :-134Ell I..54E11 0 0 ^^^
;. o '-' ° : - ,-.-,- -
: ... .-. o o l- 1 -"--:
'..045SS3 I.S°1SE^ 3.1341E^ 5.6043E3 1 2 1 310 3 ^30 MO 30' _2552 : . 30
T^":7r~"43lOE- 4.307E11 :.i71Ell 145-03oi 43^1143
133
-------
U -J L> b
TABLE B-6 (continued)
HI 10 U043 U073
E001
DO* 1
D0< 3
FOi 1
F0< 2
Put 3
FOt 5
KO 1
KOI 1
KOI 3
KOI 4
f , '-.' i C
K 0 1 7
KOI
K J 1
K011
K 0 - 1
K 0 1 o
Kl-43
K " -1 ~
'' ". -, 1
'/ , = -
K ; J
'' ' i 7 ''
K 1 3 ''
K037
SMGCON.
3134045.
0
0
7 . 4653E9
1 . 313E10
0
0
0
0
0
0
9.31 -. 0 E '"'
0
0
1 . -1,1 1?E3
0
0
o
o
o
,-,
'j
0
7 9 7 3 T 1 3 -
0
0
1 . 0 5 3 9 E 3'
o
9 1 9 7 o 3 4 .
0
0
0
0
0
0
0
0
0
0
o
o
0
0
0
0
o
0
o
o
o
0
0
0
4.S454E9
0
0
0
o
0
0
0
0
0
o
0
0
Ij
0
0
0
0
0
0
o
u
0
0
0
0
o
9 . 4 0 o 0 E c
o . 7 4 3 0 E 3
';' _ / _ 3 0 _ .
1 , 4 5 o 1 E 9
3.5171E9
1 .315E10
1 . 1 3 0 7 E 3
4454745.
5 1 . 1 i 9 1 7
15783379
L '-' 0 0 11.3
1 . 4 3 4 9 E Q
1 . o 0 3 E 1 1
1 1 1 0 7 o c 3
375o037:.
5 . 3 ;' 1 5 E °
1 .7o9~E9
1 4 0 o ° o . 4
1 0 1 . o 0 4 -l
13191. 3 3
171?. 7S5
311.1 379
1 3 1 1 " I 3 ,
1 o 3 . : ; 5 5
1.33'PEl 1
1 3 3 0 ;. "' . 4
1237137.
2. 133E10
3.033E10 4.354*E9 9.40iOE9 7.9°3E:
Factor = Ci,eq/(10 ^ Risk). Nor.-aqueDus TSDF categories include
1, lar.c application, and waste pile.
-------
TABLE B-7. WASTE TYPE VOLUME WEIGHTED CARCINOGENICITY HAZARD BY WASTE CONSTITUENT
FOR AQUEOUS TSDF CATEGORIES* .
UOl?
'_ w i-1 £
DO 01
D 0 0 I
Lt '.' l ' -'
F 0 0 1
F o o :
F 0 0 3
F 0 0 5
HO 01
K 0 1 i
k 'J 1 j'
K 0 i 4
KOli
r" >.' 1 .
t ^ j - .
K '. - '.
KO 1 2
TJ- ' - '
U - - -
. - - 1 -,
ii j ** v
: . v. "1
-
VI -' ~" *
1 1 j :- 'J
K 0 ~ I
r- - ,- -.
t i
r 1
\.
1 1
0
0
0
0
o
4.25i:>E14
0
o
M
, ,»_.-
^ J
u
0
f
-
0
-,
("l
''.i
.")
9.355E17
=i ^ ": I E 1 ?'
0
0
0
0
0
0
6. 171EU
u
0
f
C;
0
o
^ 1
0
,',
t'(
0
0
0
1 . 4'-4E17
0
0
3.123E17
0
0
0
0
0
o
0
2 . 3 5 0 E 1 0
0
-,-[-, T" i c:
1 . 7 3 0 E 1 4
0
0
C
o
IJ
o
0
1 . 3 4 7 E 1 7
0
o . i 5 9 E 1 4
0
0
0
3. 290E1 3
0
0
0
o
0
0
o
o
0
tr ir ; - C ' "
J . J U *. 1-1 1 -^
3 . 5 '"'-' E 1 2
0
o
V.'
0
o
.
(.'
.
u
1 . ': 3 4 E 1 ;
0
0 1.2°7E13
0 2 . 3 7 i E 1 -
0 ''
0 '-'
0 0
0 0
0 S . '"'02E1 i
0 0
0 0
-\
u '-'
0 0
3.32?Eil 0
0
o o
o o
o o
U '-'
-
^
0 0
0 l-'
'*,
'.'
-\ t"t
'
1 1 '.'
T) l.f
1.211E11
0
t_
0
1 15051 3r
0
! 1
0
','
(.
i . ; o ': E i o
i - = T - ~
t _' ----
c ^ 7 1 E i 0
_ -
i .-*'.-! -
it-.-
~ '"',-" E J *
. . . , .
4 3 3 : - '. : :
1 . 1 5 '? - Z '"
SuC-CCfl.
q ;''
"o.7lOE!S 2.35oE20 3.77SS16 3.3^^Eli 1.0-1E13 1.17-si-
135
-------
TABLE B-7 (continued)
U043
u>.y
C 3 ' -
D 0 0 i
E ': '. 1
T~ i"i i I
!':":',.
F 0 ' 3
F 0 '".: 5
KOOi
K ! 1 1
K :> 1 3
u O 1 -T
t - - ,
* v. '- > -
r \i '_ 7
;: .", " '.
r.Oll
K011
. _
t . J - :
KG 4E
5: - -1 °
T- - C" '
Iv .' - -
i". . - ^
;. - :
i: ".' ~ -
K ; '3 J
s:i:-::-.
!-!»»(
1 ,-, 0 1.137E18
i -: 5oil :' _ , , 3,ri - 0 7.i4?Elc
? ^"~l o 5.531E13
!; o 0 1.409E1S
i-'r;:;- ;, o S.I^EI-
-' . 1 - -f - 1 0 05.42 9 E 1 o
° ,:, 0 3. 90 IE 11
'J. f, 0 1150513?
:; j 1 i;i?!H:
,-, 0 o . 1 / -Ei *
./- u 0 1.3'-'1E10
4. 14 IE: 'i : -, - -;-0£U
1 1 '' - :
; f, o ^.^41EU
I ' .-,-,, i c-
1 1 . / C- 1 C. 1 -'
4.11:H13 J : 7.7o,E14
: .-. o i . 3 o 3 E i o
i ' '-1 " _.
0 0 0 45^531.5
r, '.' 5 . o 1 fi A l-
u 1.40 IE 10
\j
,-, 0 1.3454E9
: 0 7. Go IE 10
0 0 433^3^-'
_ , 1 TI 0 1 5 4 1 E 1 7
:'-^-:' : 0 1.1594E9
I o 0 1.023E1I
5.115E- 3.35-E1, :.l£T£li l^Si.
5.54oE13 1.151E17 3.1S7SU ^.4alE..J
. . h^7a_^ factor ecua-s: (wi,eq/(-^
-- w,= - -"--d carcir.cgenic-i-.' u--*<*-- - " - - - ,-.,-1. -;.- f'°at
-7^ _,.:;';; __^ vci;-rie}. Aqueous TSDr cat£gcr...e;= ^..^ ^ ^>-
?eatnent', storage, ar.d disposal s-rrace ispour.c...er.ta.
135
-------
TABLE B-8. WASTE TYPE VOLUME WEIGHTED CARCINOGENICITY HAZARD BY WASTE
CONSTITUENT FOR NON-AQUEOUS TSDF CATEGORIES*
C 0 L c
D : o i
L 0 0 2
D 0 0 3
F001
FOO:
F 0 0 3
FOO 5
KOOi
KOI i
KOI 3
k 0 1 4
r.o ic
:; : 1 7
* . '.' i C
t<~ (,' *_ 'J
K02i
K j 2 :
K ". 1 1'
:1 3 -i 'I
'' ~i »+ '"
.. -^ _ ,
i , '. ~ :
t_ .' -' 'j
K J 7 3
i: :< 3 3
SriGCCN.
SUM
UOO1'
o
0
0
0
0
0
0
0
7 . 3 4 1 E 1 1
1 . 1 3«E1 1
(j
0
0
* ~ " - TT 1 "
0
0
0
0
I./
0
0
0
o
u
0
o
i .079E13
1 .2°3E1 3
UO!"'
i . -:;EI 4
0
5 . 5 0 1 E 1 4
0
o
B .431E12
u
0
0
o
4 C1 .~l " * *T
. / . : c. : ;>
0
u
(j
0
o
0
0
0
o
'^
1}
1 ;
o
C]
1 . 0'-7E14
3. 7 3 IE 14
u:n
o . 40IE1 3
0
0
4. 8?OE1 3
0
0
0
0
0
0
0
i . 515Elo
0
0
3. 314E14
3 . l'-5El 3
0
0
0
i")
0
1)
o
t> ^ 1 ~ 1 =
j j-_"ri* _-
o
0
5.0 7 OS 13
1 .90 -IE 16
U 0 4 4
2.234E11
0
0
0
3 . o 2 i E 1 1
^_i
0
0
0
0
o
o
0
0
6. 331 El 3
5.i26E12
0
0
0
o
'j
0
o
4.03*E15
o
0
2 . 0 0 7 E 1 3
4. 1 32E15
U041
0
0
0
0
0
0
0
0
0
o
u
0
~1 ~1 .", 1 ^" 1 (
o . o : 1 i i 1
IJ
0
tj
o
0
0
o
0
0
o
0
o
0
2 . 0 7 7 E 1 0
3.539E11
U122
3 . 0 7 S E 1 2
5.374E:<:
0
o
0
0
3.305E1 1
0
0
i.'
i_.
0
_-(
>.'
0
u
0
o
o
( '.
0
ij
0
'J
t~l
0
i:). 495E1 1
4.41oE12
U133
-, ,", c "" "' tr r,
1 1
0
u
^ !
V.J
'i
4 0 < : 1 -.. . 5
tj
i.
0
o
1 ;
U
o
i . : 5 3 E : o
T - IT 1 - -
t 4_ -, L ' 4- -
= ," " . " T Z
c t - : = r r
*' - - '-' '.' '.;
1 1*1 -1 ~ *- '"'
i i. "' 'J C > "Z! 21
o
j ; o '. i IT ^
1 . * 1 :' E 1 1
7 . ! 0 2 o E 3
1 . 903S1 1
137
-------
TABLE B-8 (continued)
C C D E U 2 1 0 U 0 4 3 U 0 7 3
DO :
DO'
D0>
FOi
F 0 1
FC<
F 0 '
I" (", '
Iw . '
KO
K '.'
V" .",
i >. .
r.<:
K 'j
k '.'
i'". 0
K 1
K ".-
K 0
:/ -
1 - w
V '.
1',-
K '.'
r. o
K '.'
KO
s;i
.' i
j 2
) 3
Jl
J -_
i.1 ~'
0*5
01
1 1
1 3
1 4
1 _
17
1 3
- -:
1 1
11
1 ;,
^ :.
T "
=
«. 2>
3 3
O /
~- ~ ~ * T
0
0
3 . 4 7 OEM
3 . 132E14
0
0
0
0
0
0
5 . o 2 1 E 1 4
o
0
1 . 1 ° '- E 1 3
0
o
(j
0
I 1
c<
0
0
1 . 2 1 3 E 1 2
0
0
i . 3 1 1 E i 2
0
7 . 1 3 7 E 1 2
0
0
g
0
0
0
0
0
0
o
o
0
o
\J
0
o
0
0
(-;
o
0
0
0
o
3. 91 3E14
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
c
*j
0
0
'-'
0
0
0
0
0
0
3.342E14
7 . 2 4 6 E 1 2
5 . 5 0 1 E 1 4
3.959E14
3. 191E14
S. 631 El 2
3. 305E1 1
4 0 6616.5
7 . 3 4 1 E 1 1
1 . 1 3'?E1 1
4 . 753E13
1 . 5 7 2 E 1 o
3 . 3 3 1 E 1 1
1 .23oE12
4. 332E14
3.753E13
1 . 3 5 3 E 1 0
4251723.
5.02 ..- '* E ?
3 . 3 1 j j r, o
c o 7 i ;, ;: ,;, ,;,
1 . 0 4 5 5 E -;
12^03153
7. 334E15
3.'5391E?
1 . 6 1 9 E 1 1
'-'. 195E14
S'JII 1.743E15 3.''3TE14 3.3-12E14 2.c54Eii
Ncr.-ac-_30us _vcl-jr.e wei2hted carcinc^enicity hazard factor equals:
(Ci,ec,- ^ 10~J Risk; )~'?arc A non-aqueous waste type volume). Non-acusou;
include landfill, land application, and waste-pile.
133
-------
US. Environmental Protection AgertcV
Region V, Libraiy
230 South Dearborn Street
Chicago, 'i;iPO|S 60^,04
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-450/3-85-006
RECIPIEN
4. TITLE AND SUBTITLE
Hazardous Waste Ranking Assessment of Air Emissions
from Hazardous Waste, Treatment, Storage, and Disposal
Facilities
REPORT DATE
February 1985
PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Nunno, Thomas, Andrea Steele, and Barbara Bosy
8. PER
9. PERFORMING ORGANIZATION NAME AND ADDRESS
GCA Corporation/Technology Division
213 Burlington Road
Bedford, Massachusetts 01730
10. PROGR
11. CONTRACT/GRANT NO.
68-02-3168
12. SPONSORING AGENCY NAME AND ADDRESS
U.S. Environmental Protection Agency
Office of Air Quality Planning and Standards
Emission Standards and Engineering Division
Research Triangle Park, North Carolina
13. TYPE OF REPORT AND PERIOD CO'
14. SPONSORING AGENCY CODE
EPA/200/004
15. SUPPLEMENTARY NOTES
16. ABSTRACT This Final Report presents ranking scores for select RCRA wastes that are
likely to be emitted to the ambient air based on: (1) hazardous waste
characterization data (expected constituent concentrations); (2) idealized gas
phase equilibrium concentration; (3) health effects properties (toxicity and
carcinogenicity); and (4) estimated waste volumes disposed by treatment, storage and
disposal facility (TSDF) type. The RCRA Part A permit application data base was
manipulated to generate a list of wastes handled by TSDFs in the United States. This
list of 501 wastes comprises an estimated hazardous waste disposal volume of approxima-
tely 92 million metric tons nationwide. Approximately 100 of the 501 waste types were
evaluated with respect to the four parameters influencing air releases described above.
These 100 wastes were then assigned ranking scores according to the methodology
presented in this report.
The ranking scheme reported here provides a starting point for the selection of
wastes that may have the greatest potential for adversely affecting human health due
to air releases. Using this ranking scheme, specific wastes will be selected for
further study of air emission release rates, dispersion modeling, and field measurement
for validation of release rate models.
4
*
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
Air Pollution
Pollution Control
Hazardous Waste TSDF
Volatile Organic Compounds
Health Effects
Ranking
IDENTIFIERS-OPEN ENDED TERMS
18. DISTRIBUTION STATEMENT
Release unlimited, Available from NTIS
5285 Port Royal Road
Springfield, Virginia 22161
>; SECJR!TX C_ASS Tins Report-
UNCLASSIFIED
20 SECURITY CLASS i Tins pagt ,
UNCLASSIFIED
COSATi Field'Group
21 NO OF PAGES
146
22 PRICE
EPA Form 2220-1 (R»v. 4-77) PREVIOUS^ EDITION is OBSOLETE
139
------- |