United States      Office of Air Quality      December 1979
          Environmental Protection  Planning and Standards     uecemoer
          Agency        Research Triangle Park NC 27711
&EFA     Summary of Group II
          Control Technique
          Guideline Documents
          for Control of Volatile
          Organic Emissions
          from Existing
          Stationary Sources

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                                 EPA-450/2-80-001
  Summary of Group II  Control
Technique Guideline Documents
  for Control of Volatile Organic
      Emissions from  Existing
         Stationary Sources
                     by

          Stephen V. Capone and Malcolm Petroccia

                 GCA Corporation
              GCA/Technology Division
                 Burlington Road
                Bedford, MA 01730
               Contract No. 68-02-2607

               Work Assignment No. 39


            EPA Project Officer: Tom Williams



                  Prepared for

         U.S. ENVIRONMENTAL PROTECTION AGENCY
            Office of Air, Noise, and Radiation
          Office of Air Quality Planning and Standards
         Research Triangle Park, North Carolina 27711

                 December 1979

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This report is issued by the Environmental Protection Agency to report
technical data of interest to a limited number of readers.  Copies are
available free of charge to Federal employees, current contractors,
general public, grantees, and nonprofit organizations  - as supplies
last - from the Library Services Office (MD-35) , U.S.  Environmental
Protection Agency, Research Triangle Park, North Carolina 27711; or for
a nominal fee, from the National Technical Information  Service,
5285 Port Royal Road, Springfield, Virginia 22161.
This report was furnished to the Environmental Protection Agency by GCA
Corporation, Technology Division, Burlington Road, Bedford, Massachusetts
01730 in fulfillment of Contract No. 68-02-2607, Work Assignment No. 39.
This document has been reviewed by the Office of Air Quality Planning
and Standards, U.S. Environmental  Protection Agency, and approved for
publication.  Approval does not signify that the contents necessarily
reflect the views and policies of the Environmental Protection Agency,
nor does mention of trade names or commercial products constitute
endorsement or recommendation for use.
                    Publication No. EPA-450/2-80-001

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                                        ABSTRACT
r
                             Huideline (CTC) documents have been prepared by the
      January  1978  (Croup I) was published in December 1978.

                                            summarizes the CTG documents issued
       facility.
                                             iii

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                                  CONTENTS


                                                                	ill
Abstract 	
                                                              	    1
   1.  Introduction	        ...    1
            Background 	          3
            Purpose of Document	•  •  •  *	    s
   2.  Surface Coating of Miscellaneous Metal Parts and Products  ....    5
   3   Surface Coating of Flat Wood Paneling  	
   4!  Manufacture of Synthesized Pharmaceutical Products	    >
   5.  Manufacture of Pneumatic  Rubber Tires  	  •    ^
   6.  Manufacture of Vegetable  Oil	
   7.  Graphic Arts - Rotogravure and Flexography	
   8   Perchloroethylene  Dry  Cleaning Systems	    2Q
   9.  Leaks  from Petroleum Refinery Equipment  .  .  .  .  •  •  •  •	
   10.  Petroleum Liquid  Storage in  External Floating  Roof Tanks  ....    ^
   11.  Leaks  from Gasoline  Tank Trucks  and Vapor  Collection Systems.  .  .    26

                                                    	    28
 References 	
                                       v

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                                  SECTION 1

                                 INTRODUCTION
BACKGROUND






have been published.*
     Eleven  CTGs covering  15 VOC  source  categories were published  prior  to
January  1978.   These first eleven CTGs were:

     .    Surface  Coating  of Cans,  Coils  Paper   Fabric,  Automobiles
          and  Light-Duty Trucks  (EPA-450/2-77-008).

    ' .    Surface  Coating  of Metal Furniture (EPA-450/2-77-032).

      ,     Surface  Coating  for  Insulation of Magnetic Wire
           (EPA-450/2-77-033).

      .     Surface  Coating of Large Appliances (EPA-450/2-77-034).

      •    Storage of Petroleum Liquids in Fixed Roof Tanks
           (EPA-450/2-77-036).

      •    Bulk Gasoline Plants (EPA-450/2-77-035).

      .    Solvent Metal Cleaning (EPA-450/2-77-022).

      •    Use  of  Cutback  Asphalt (EPA-450/2-77-037).

      •    Refinery Vacuum Producing  Systems, Wastewater
           Separators and  Process Unit Turnarounds
            (EPA-450/2-77-025).
      T^^nT^d not have to be adopted for these stationary sources
   if a state can demonstrate attainment of the photochemical oxxdant standard
   by photochemical  dispersion modeling.

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     •    Hydrocarbons from Tank Truck Gasoline Loading Terminals
          (EPA-450/2-77-026).

     •    Design Criteria for Stage I Vapor Control Systems,
          Gasoline Service Stations, U.S. EPA, OAOPS, November 1975.

For each source category, a CTG document describes the source, identifies the
VOC emission points, discusses the applicable control methods, analyzes the
costs required to implement the control methods, and recommends regulations
for limiting VOC emissions from the source.

     A document entitled "Regulatory Guidance for Control of Volatile Organic
Compound Emissions from 15 Categories of Stationary Sources," EPA-905/2-78-001,
was published in April 1978.  This document provided guidance to the states in
preparing RACT regulations for the 15 source categories listed above.

     In December 1978, a document entitled "Summary of Group I Control Tech-
nique Guideline Documents for Control of Volatile Organic Emissions from
Existing Stationary Sources," EPA-450/3-78-120, was published.  This document
provided an overview of the affected source facilities, the magnitude of the
VOC emissions emitted from the facilities, and the recommended VOC emission
limits.

     EPA published an additional 10 CTG documents (Group II) in 1978.  The
10 source categories covered were:

     •    Leaks from Petroleum Refinery Equipment (EPA-450/2-78-036).

     •    Surface Coating of Miscellaneous Metal Parts and Products
          (EPA-450/2-78-015).

     •    Manufacture of Vegetable Oil (EPA-450/2-78-035).

     •    Surface Coating of Flat Wood Paneling (EPA-450/2-78-032).

     •    Manufacture of Synthesized Pharmaceutical Products
          (EPA-450/2-78-029).

     •    Manufacture of Pneumatic Rubber Tires (EPA-450/2-78-030).

     •    Graphic Arts - Rotogravure and Flexography
          (EPA-450/2-78-033).

     •    Petroleum Liquid Storage in External Floating Roof Tanks
          (EPA-450/2-78-047).

     •    Perchloroethylene Dry Cleaning Systems (EPA-450/2-78-050).

     •    Leaks from Gasoline Tank Trucks and Vapor Collection Systems
          (EPA-450/2-78-051).

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      regulatory guidance  document was  developed from  these Group  II CTGs.
                          £,rt\.— tJ"/ f. ij  vy^-r, ~--	    .
                          in preparing  RACT regulations for the 10  industrial
Hjouau^-w-'v---1*""*-- — —1»         *^
categories covered by the Group II CTG documents.

PURPOSE OF DOCUMENT
     The purpose of this report is  to summarize the Group II CTG documents.
The summaries are  intended to present an overview of ^Y^^^L.! tJe~
ities The magnitude of the VOC emissions emitted from the  facilities,  and the

ShrJ6,:^^  ^^^^ r^j^

Er^r^;^^^^^
                     areas where difficulties  exist in converting CTG infor-
                                    • •1 m__*_-_  -> C -I«J..«rt+--V--»T  f* ^\TTVfn£in t"G f^n { , I (-T
 from other sources.

     Cost estimates in the  CTG documents were normally developed by use of
 model facilities to represent typical,operations.   Applicable alternative
 controls were costed for these model facilities.  As  such, these costs, even
 with tJe broad ranges provided for several of the source categories, may not
 encompass the actual cost incurred at any specific facility.

     The CTG document summaries which follow include  a brief discussion of the
 VOC source category and emission control  techniques,  as well as a  tabular
 presentation of the following information for each source category:

     Affected Facilities - Types of operations, facilities, or
          equipment covered by the CTG

     Number of Affected Facilities - A national count of  the
          operations, facilities, or equipment  specified

     VOC Emissions Nationwide -  Estimate of  annual emissions from
          the source  category

     VOC Emission Range  per Facility - Estimate of annual emissions
          from a typical facility in  the source category

      100 Ton/Yr Source  Size - The estimated size  of  a facility
          which would emit 100 ton/yr of VOC if uncontrolled

      CTG Emission Limit  -  VOC emission limits as  recommended in
           the CTG document

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VOC Reduction Per Facility - Percent emission reduction which
     can be effected by use of CTG recommended controls

Costs — Values in parentheses represent net savings

     Capital — purchase and installation costs

     Annualized — includes operating cost, annualized capital
          charges plus tax and interest, less value of
          recovered VOC.  Only primary heat recovery or fuel
          value credit considered

     Cost Effectiveness — Cost of control measure per ton
          of VOC controlled.

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                                   SECTION 2

                       SURFACE COATING OF MISCELLANEOUS
                          METAL PARTS AND PRODUCTS1


     Tills CTG document provides guidance on VOC emission control for job shop
and original equipment manufacturing industries which apply coatings on metal
substrates, except those industries which were covered by previous CTG docu-
ments   T^ recolended emission limits in this CTG are also intended to apply
to S; coating of hardware for wood and metal cabinets and the coating of metal
pails and drums.  There are many dissimilarities between the plants and in-
dustries represented by this category.

     Slaving is the more common method of applying coatings for single-coat
operations, but flow coating and dipping  are also  used   For two-coat opera-
tions the primers are more likely  to be applied either by flow or dip coating
while the topcoats are almost  always sprayed.

     The coated parts are often conveyed  through a flashoff tunnel to evapo-
rate solvent and allow the coating to  flow  out properly.  After coating and
flashoff,  the parts are baked  in single or  multiple pass bakxng ovens.  Some
products are air or forced air dried.

     The recommended  emission limits  are  based on  the  use of coatings low  in
organic  solvents.  The  CTG document recommends four  different  emission  limi-
 tations  based on  the  type of  coating,  the number of  colors  or  color  changes
 and the  method  of  drying.  The applicable control  technology to meet the emis-
 sion limitations  includes process  modifications  (such  as  conversion  to  water-
 borne,  electrodeposition, higher  solids or powder  coatings)  and  exhaust gas
 treatment  (such as incineration and carbon adsorption).

      Due to the large number  of different coating  processes and  the  varJous
 methods  of controlling VOC  emissions from each of  these processes,  there-  are
 significant variations in the cost-effectiveness  of  control options  for this
 CTG category.   The CTG document provides cost estimates for small,  medium and
 large model plants for seven different types of  coating operations  and between
 four and six control options depending on the type of coating operation.

-------An error occurred while trying to OCR this image.

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                                  SECTION 3

                   SURFACE COATING OF FLAT WOOD PANELING2


     Factory finished flat wood products includes printed interior panels made
of hardwood plywood and thin particle board (1/4 inch or less); natural finish
hardwood plywood panels; and hardboard paneling with Class II finishes.  ANSI
Class II finishes meet less stringent requirements than Class I coatings; spe-
cifically there are no heat, humidity or steam requirements.

     Different forms of roll coating are the favored procedures for applying
coatings to flat woods.  However, curtain coating, spray coating, and brush
coating techniques are also used.  The basic series of coatings applied to
printed interior panels consist of filler, basecoat, inks and topcoat.  Natural
hardwood plywood panels usually have the real wood surface modified in color
and appearance by a series of stains, toners, fillers, sealers, glazes, and
topcoats.

     For purposes of recommending levels of control, flat wood interior panel
products have been divided into three subcategories:

     1.   Printed interior wall panels made of hardwood plywood and
          thin particle board  (1/4 inch  or less);

     2.   Natural finish  hardwood plywood; and

     3.   Class  II  finishes  for hardwood paneling.

 Class  I hardwood panels,  particle board  used  in  furniture,  insulation board,
 and  softwood  plywood  are  not  considered  in this  CTG document.  The  emissions
 from inks used  to print simulated grain  or decorative  patterns on printed
 interior panels  are  covered  in  this  CTG  category,  and  should not  be  considered
 a Graphic Arts  activity.

     Recommended VOC limitations  are given in kg/100 m2  (lb/1000  ft2) of  sur-
 face covered  to  allow panel  coaters  maximum  flexibility  in  adjusting VOC  con-
 tent of  the different  coatings  so as to  meet  the emission limitation while
 maintaining product  quality.   In  each case,  the aggregate of the  VOC emissions
 from al] coating applied  shall  be used  for comparison  to the recommended  emis-
 sion limitations.   In general,  the  emission  limitations  are based on the  use  of
 a combination of water-borne coatings and  solvent-borne  coatings  within a pro-
 duct line.   Other  applicable methods of  VOC  reduction  include  add-on devices
 (incinerators and  carbon  adsorbers), ultraviolet curing,  and electron beam
 curing.

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     SUMMARY OF CTG DOCUMENT  FOR  FACTORY  SURFACE  COATING OF
                           FLAT  WOOD PANELING
Affected
facilities
(p. 1-2)*
Number of
affected
facilities
(p. 1-2)*
VOC
emlHuions
nationwide
VOC
emlBH ton
range! per
facility
(Table 2-2
p. 2-5)*
100 tons/yr
source size
(calculated)
CTC
emisBion
limit
(p. v)*
VOC
reduction
ler facility
(Table 2-1
P. 2-4)*
CoHtH
(Table 3-2
p. 1-9)*


The affected t.'icl tiles ,-ire factories that surface coat the
following types of flat wood panels:
a. Hardwood plywood
b. Particleboard
c. Hardboard
Affected Facilities Nationwide Total
a. Hardwood plywood 247
b. Particleboard 80
c. Hardboard 67
8.4 x 101* Mg/yr (9.3 x lO4 tons/yr) estimated for 1977 which
represents about 0.5 percent of stationary source estimated
emissions. l l
Potential VOC emissions per coated surface area are:
0.4 to 8.0 kg/100 m? (0.8 to 16.5 lb/1000 ft2)
depending on the coating/curing process as well as the coating
materials used.
Based on the VOC emission range above, a 100 tpy source would
coat a minimum annual throughput of:
3.8 * 10'' to 7.7 x 10fc standard panels/yr
Where a standard panel is 2.97 m2 (32 ft2).
Recommended limitation
Printed hardwood plywood 2.9 kg VOC/100 m?
and particleboard (6.0 Ib VOC/1000 ft2)
Natural finish hardwood plywood 5.8 kg VOC/100 m2)
(12.0 Ib VOC/1000 ft?)
Class II1 finishes for hard- 4.8 kg VOC/100 m2)
board paneling (10.0 Ib VOC/1000 ft2)
70 to 90 percent VOC emission reduction, depending on coating
material and coverage, through use of water-borne coatings,
incineration, adsorption, ultraviolet curing or electron beam
curing.
Basis:
Shifts: 1 2
Panels/yr: 2,000,000 4,000,000
Waterborne UV/Waterborne Waterborne UV/Waterborne
Capital cost 52 155 52 155
($1000)
Annual i/.ecl cost 101 124.6 200 8 234 A
($1000)
Cost effectiveness
($/Mg) 269 292 256 264
($/ton) 244 264 232 240
*The source of the summary information is the indicated page number in "Control of
 Volatile Organic Emissions from Existing Stationary Sources, Volume VII-  Factory
 Surface Coating of Flat Wood Paneling," EPA-450/2-78-032.

'Definition on p. vil  of KPA-450/2-78-032.

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                                  SECTION 4

            MANUFACTURE OF SYNTHESIZED PHARMACEUTICAL PRODUCTS3


     The CTG covers the manufacture of synthesized pharmaceutical products
under SIC codes 2833 and 2834.  Synthesized pharmaceutical products are nor-
mally manufactured in a series of batch operations according to the following
sequence:  (a) reaction(s), (b) product separation, (c) purification, and
(d) drying.  The equipment which emit VOC during this process are:  reactors,
distillation units, dryers, crystallizers, filters, centrifuges, extractors
and VOC storage tanks.  VOC emission rates from each of these sources vary
tremendously, so that typical emission rates by either process component or
facility type are not calculated in the CTG document.

     The recommended control  strategy for reactors, distillation operations,
crystallizers, centrifuges and vacuum dryers that emit 6.8 kg/day  (15 Ib/day)
or more of VOC is Installation of a surface condenser on the equipment uxhaust.
Operation of  the surface  condenser must be such that the exhaust gas temperature
is reduced to:

      (1)  -25°C when condensing VOC of vapor pressure greater  than
          40  kPa  (5.8 psi),*

      (2)  -15°C when condensing VOC of vapor pressure greater  than
           20  kPa  (2.9 psi),*

      (3)   0°C when  condensing VOC of vapor pressure  greater  than
           10  kPa  (1.5 psi),*

      (4)   10°C when condensing VOC of vapor pressure greater than
           7  kPa  (1.0 psi),* and

      (5)   25°C when condensing VOC of vapor pressure greater than
           3.5 kPa (0.5  psi),*

      Additional  controls  are  recommended for  air  dryers,  production equipment
 exhaust systems  and storage and  transfer of liquids  containing VOC.  VOC emis-
 sions from air  dryers  and production  equipment exhaust  systems should be re-
 duced by 90 percent if  they emit  150  kg/day  (330  Ib/day)  or  more and should be
 reduced to 15 kg/day (33  Ib/day)  if  they emit  less than 150  kg/day (330  Ib/day).
 Transfer of liquids containing VOC from trucks or railcars to  tanks with a
 *Vapor pressures as measured at 20°C.

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capacity of more than 7,500 liters (2000 gal) should employ a 90 percent effec-
tive vapor balance system or equivalent.  Tanks storing liquid containing VOC
with a vapor pressure greater than 10 kPa (1.5 psi) at 20°C, should have
pressure/vacuum vents set at ±0.2 kPa (±0.03 psi) except where more effective
controls are used.

     There arc three remaining recommendations to reduce VOC emissions from
pharmaceutical synthesis operations.   First, all centrifuges, rotary vacuum
filters and other filters with exposed liquid surfaces should be enclosed
when processing liquids with a total  VOC vapor pressure of 3.5 kPa (0.5 psi)
or more at 20°C.  Second, all in-process tanks containing liquids with VOC
should be covered.  Third, all leaks  of VOC containing liquids should be re-
paired as soon as possible.
                                     10

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        SUMMARY  OF  CTG  DOCUMENT  FOR  MANUFACTURE  OF SYNTHESIZED
                            PHARMACEUTICAL PRODUCTS
Affected
facilities
(p. 1-4)*
Number of
affected
facilities
(p. 1-2)*

voc
amisulons
nationwide

VOC
etnlsHion
range per
 facility
Synthesized  pharmaceutical manufacturing facilities.  Specific
aources include:
                                               5.  Filters
                                               6.  Extraction equipment
                                               7.  Centrifuges
                                               8.  Crystallizers.
    1.   Dryers
    2.   Reactors
    3.   Distillation Units
    4.   Storage and transfer
        of VOC

Estimated 800 plants nationwide
50,000 Mg/yr (55,000 tons/yr) estimated for 1977 which represents
about 0.3 percent of stationary source estimated VOC emissions.
Not available
100 ton/yr
source size
Not available
 CTG
 amission
 limit
 (p.  1-5)*
 1.  a.  Surface condensers or equivalent control on vents from
        reactors, distillation operations, crystallizers, cen-
        trifuges, and vacuum dryers that emit 6.8 kg/day (15 Ib/day)
        or more VOC.

    b.  Surface condensers must meet certain temperature versus VOC
        vapor pressure criteria.

 2.  Additional specific emission reductions are required for air
    dryers, production equipment exhaust systems, and storage and
    transfer of VOC.

 3.  Enclosures or covers are recommended for rotary vacuum filters,
    processing liquid containing VOC and in-process tanks.

 4.  Repair of components leaking liquids containing VOC.
 VOC
 reduction
 par facility
 Not  available
 Costs
 (pp.  5-14
 to 5-42)*
 Capital  and  Annualized Cost graphs are provided for the following types
 of  control equipment:  conservation vents, floating roofs, pressure
 vessels,  carbon  adsorption systems, thermal and catalytic incineration
 systems,  water cooled condensers, chilled water and brine cooled con-
 densers,  freon cooled condensers, packed bed scrubbers and venturi
 scrubbers.

 Cost  effectiveness  data  is not calculated for typical plants.
  The source of  the  summary  information is the indicated page(s) in "Control of Volatile
  Organic Emissions  from Manufacture of Synthesized Pharmaceutical Products,"
  EPA-450/2-78-029.
                                          11

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                                  SECTION 5

                   MANUFACTURE OF PNEUMATIC RUBBER TIRES4
     The manufacture of pneumatic rubber tires includes the production of
passenger vehicle and light- and medium-duty truck tires, and tires manufac-
tured on assembly lines using automated equipment.

     The general process for tire manufacturing consists of:  (1) preparation
or compounding of raw materials, (2) transformation of these compound ma-
terials into tire components, (3) tire assembly, and (A) molding of the final
product.  Each step employs unit operations that are sources of VOC emissions.

     Recommended levels of control are applicable to four of the unit opera-
tions which are major sources of VOC emissions at a tire manufacturing plant.
The operations are undertread cementing, treadend cementing, bead dipping,
and green tire spraying which account for 83 percent of potential VOC emis-
sions from a typical tire manufacturing plant.  Compounding, milling, tread
and sidewall preparation, calendering, molding and curing, and finishing are
not recommended for control because of their lower emission factors.  Latex
dipping is not frequently employed and will be covered under a textile manu-
facturing CTG.  Tire building, although a significant source, is not recom-
mended for control because the machines occupy about 25 percent of a plant's
floor space over which the VOCs are emitted at very dilute concentrations.  A
plant which manufactures a part of a pneumatic rubber tire by employing one
or more of the four affected unit operations is also recommended for control.
The manufacture of tire treads for the tire recapping industry should be con-
trolled while the actual recapping operation is not recommended for control.

     Quantitative emission limitations are not recommended.  However, VOC
emissions from the four affected unit operations can be effectively reduced
by application of carbon adsorption or incineration systems if capture hoods
and ductwork are designed in accordance with good engineering practice.  The
recommended scheme for reducing VOC emissions from green tire spraying is
conversion to water-based sprays.  The expected reduction in VOC emissions is
shown in the following table.
                                      12

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    SUMMARY OF  CTG DOCUMENT FOR MANUFACTURE OF  PNEUMATIC RUBBER TIRES
Affected
facilities
(PP. 1-1,
1-3)*

Number of
affected
facilities
(p. 2-2)*
VOC
emissions
nationwide
 (p.  1-2)*
    nting,  bead dipping,  tread end cementing,  and green tire  spraying.
Maximum
        of 62 rubber tire plants nationwide
1976 VOC emissions estimate from rubber tire manufacturing totalled
88,200 Mg/yr (97,200 tons/yr).  This quantity represents 0.6 percent
of'total national VOC emissions from stationary sources.
VOC
emission
range per
facility
 (p. 1-2)*
The average  tire plant is estimated to release 4,000 kg per day
(8,820 Ib/day) of emissions or 1,000 Mg VOC per year (1,100 tons/yr),
 100 tons/yr
 source size
 (p. 2-8)*
 The  model  plant,  producing  16,000  tires/day, has potential to emit
 1  A60  Mg/yr  (1,600  tons VOC/yr).   Therefore a plant producing approxi-
 mately 1,000 Lires/day would be  a  potential 100 tons/yr source.	
 CTG
 emission
 limit
 (p. 4-2) *
 VOC emissions  reduction  from  the  affected  operations  is  recommended
 through  use  of carbon  adsorption  or  incineration.  Water-based  coat-
 ings may be  used for green  tire spraying.
 VOC
 reduction
 per facility
 (p. 1-4) *
 a.   Carbon adsorption gives  an overall efficiency  of  62-86  percent  in
     reducing VOC emissions,  when applied to the affected operations.

 b.   Incineration gives an overall efficiency of 59-81 percent  when
     applied to the affected  operations.
 c.   Water-based coatings, applied to green tire spraying, provide an
     overall emission reduction efficiency of 97 percent.
 Costs
 (pp. 4-11,
 4-15) *
 Basis:  A model 16,000 tires/day plant using the various control
         technologies recommended on the following affected operations.
         All costs are based on January 1978 dollars.
                 Capital cost
                 ($1000)

                 Annual!zed cost
                 ($1000)
                 Cost effectiveness
                 ($/Mg)
                 ($/ton)
                                       Undertread
                                       cementing
                        130-340


                         92-280
                        166-505
                        150-458
                                   Bead dipping
  115-250

   70-985
1,400-20,800
1,340-18,800
              Tread end
              cementing
  135-375


  100-340
1,140-3,880
1,000-3,500
             Green tire
              spraying
 15-450

118-490
202-839
184-763
  *The  source of  the summary information is the indicated page(s) in "Control
   of Volatile Organic Emissions from Manufacture of Pneumatic Rubber Tires,"
   EPA-450/2-78-030.
                                           13

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                                  SECTION 6

                        MANUFACTURE OF VEGETABLE OIL5
     This guideline provides information on the vegetable oil process as well
as guidance on the planning and analysis required for the control of VOC emis-
sions at vegetable oil extraction facilities.  At the time this document was
published, EPA acknowledged that there were uncertainties about the testing
methods.  EPA also had a field testing program that was developing useful data
in the area of testing and monitoring.  Initial results from several scheduled
field tests indicated that the measured data are significantly more variable
than had been anticipated.  Consequently, in a letter dated June 22, 1979
(see next page), EPA asked the States to defer any regulatory action for veg-
etable oil plants until after the field testing program is completed and all
the data analyzed.  It is anticipated that the testing program will be com-
pleted in mid-1980.  Since the original CTG document may be modified, it is
not summarized in this report.
                                      14

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SUBJECT
   FROM
                   UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
                      Office of Air  QualHy, Plaiming and Standards
                      Research Triangle  Park,  North Carolina 27711
   DATE   JUN 2 2 1979
Initial  Results of Emission  Testing  of Volatile Organic Compounds from
Vegetable Oils Manufacture n
Walter C. Barber, Director ^
Office of Air Quality Planning
                                            Standards   (MD-10)
     T0   Director, Air and Hazardous Materials Division, Regions I-X

               As  you  are  aware,  in June 1978 EPA published a Control Techniques
          Guideline  (CTG)  for  the manufacture of vegetable oils   Control  of
          Volatile Organic Emissions  from Manufacture of Vegetable Oils,
          EPA-450/2-78-035, June  1978).  That document stated that the regulatory
          Guidelines  were  based on  engineering calculations and that further
          verification of  these emission levels would be made upon review of data
          developed  in conjunction  with New  Source  Performance Standard development,

               Initial results from the first of several scheduled field tests
          indicate that the measured  results are significantly more  variable than
          originally anticipated.  Accordingly,  I  have concluded  that it would  be
          prudent to defer regulatory action for vegetable oil plants until after
          the test program is completed  this fall  and all  the  data have been
          analyzed.

               States should not be required to  adopt  rules for  this CTG category
          during  1979.  Further  information will  be provided on  this matter after
          the  completion  of the  field test program.

          cc:  Don Goodwin
               Jack  Fanner
               Fred  Porter
               George Walsh
   EPA Fo.m 1320-6 (R»v- 3-76)
                                        15

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                                  SECTION 7

                 GRAPHIC ARTS - ROTOGRAVURE AND FLEXOGRAPHY6
     The graphic arts industry encompasses printing operations which fall into
four principal categories:  letterpress, offset lithography, rotogravure and
flexography.  This guideline is applicable to the flexographic and rotogravure
processes as applied to both publication and packaging printing.  Letterpress
and offset lithography printing are not affected since these processes use
inks containing small quantities of volatile organic compounds.

     In flexographic printing, the image areas are raised above the nonimage
surface.  The distinguishing feature is that the image carrier is made of
rubber and other elastomeric materials.  In the gravure method of printing,
image areas are recessed relative to nonimage area.  The image carrier is a
copper-plated steel cylinder usually also chrome plated to enhance wear
resistance.

     The emission limits are based on the use of VOC capture and control equip-
ment, water-borne inks or high solids inks.  Emission limits vary for opera-
tions using capture and control equipment, primarily because the expected
capture efficiencies vary with the type of printing operation.

     If water-borne inks are used as a control technique, the volatile frac-
tion of the ink must contain 25 percent or less by volume organic solvent and
75 percent or more water.  High solids inks must contain 60 percent or more
by volume nonvolatile material.

     A potential issue in this CTG category is whether a particular operation
is a coating or printing operation.  A coating operation is the application of
a uniform layer of material across the entire width of a web.  A printing
operation is the formation of words, designs and pictures, usually by a series
of application rolls each with only partial coverage.  All units in a machine
which contains both coating and printing units will be considered as perform-
ing a printing operation.  However, the printing of simulated grain or decora-
tive patterns on printed interior panels is not covered in this CTG category,
and should be considered as a Flat Wood Paneling coating activity.
                                      16

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       SUMMARY  OF CTG DOCUMENT  FOR GRAPHIC  ARTS
                              AND FLEXOGRAPHY
ROTOGRAVURE
Affected
facilities
(p. 1-0*
Nunfcer of
affected
facilities
(p. 2-5)*
VOC
emissions
nationwide
(p. 2-8)*
VOC
emission
range per
facility
(calculated)
100 tons/yr
source size
CTG
emission
limit
(pp. 1-2,
1-3) *
VOC
reduction
per facility
Costs
(pp. 4-8
4-13) *
Flexographic and rotogravure processes
packaging printing.
applied to publication and
a. Publication printing is done in large printing plants, m.mbi-r In,-.
less than 50 in total.
b. There are approximately 13 to 14 thousand gravure printing unlis
and 30 thousand flexographic printing units.
a. Gravure 100,000 Mg/yr 1976 (110,000 tons/yr)
b. Flexography 30,000 Mg/yr 1976 (33,000 tons/yr)
This represents about 0.8 percent of stationary source estimated
emissions. ' '
a. Cravure 7.4 Mg/printing unit per year
(8.2 tons /unit)
b. Flexography 1 Mg/printing unit per year
(1.1 tons/printing unit per year)
A plant will be a potential 100 tons/yr VOC source if it uses
110-180 Mg (120-200 tons) of ink per year, where the solvent
concentration is 50-85 percent.
!
1
	 1

Use of water-borne or high solids inks meeting certain composition
criteria or the use of capture and control equipment which provides:
a. 75 percent overall VOC reduction where a publication
rotogravure process is employed;
b. 65 percent overall VOC reduction where a packaging roto-
rotogravure process is employed; or,
c. 60 percent overall VOC reduction where a flexographic
printing process is employed.
Same as CTG limit above.
VOC control option
Ink usage,
Mg/yr
(tons/yr)
VOC concentration ppm
Capital cost
Annual! zed cost
Cost effectiveness
S/Mf,
$/ton
Incinerator
7
(7.7)
500
94,000
24,900
8,360
7,570
'
Incinerator
2,500
(2,750)
500
1,110,000
1,665,500
1,650
1,480

Carbon
adsorption
3,500
(3,860)
1,200
701,000
72,800
51
46

Carbon
adsorpt Ion
7 ,000
(7,720)
2 , 400
701 ,000
(41,700)1-
(lr-)l
I ] O>
*The  source of the summary information  is the indicated  page number in "Control of
 Volatile Organic Emissions from Existing Stationary Sources, Volume VIII:  Graphic
 Arts - Rotogravure and Flexography," EPA-450/2-78-033.

'''Numbers in parentheses arc savings.
                                        17

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                                 SECTION 8

                  PERCHLOROETHYLENE DRY CLEANING SYSTEMS"
     The dry cleaning industry is segregated into three categories:  (1) coin-
operated, (2) commercial, and (3) industrial.  The principal steps in the dry
cleaning process are identical to those of ordinary laundering in water:
(1) one or more washes (baths) in solvent; (2) extraction of excess solvent
by spinning; and (3) drying by tumbling in an air stream.

     The CTG recommended emission limitation is based on use of a carbon
adsorption system, good maintenance practices and reduction of VOC emissions
from filtration and distillation wastes.  The carbon adsorption system should
reduce VOC emissions to 100 ppm or less before dilution.  Good maintenance
practices include repairing all gaseous and liquid leaks.  Diatomaceous earth
filters should be reduced to no more than 25 kg of solvent per 100 kg of wet
waste materials.  Residue from solvent stills should contain no more than 60
kg of solvent per 100 kg of wet waste material.  Filtration cartridges should
be drained in the filter housing for at least 24 hours before being discarded.

     The CTG document indicates that most, if not all, coin-operated facilities
will have Insufficient space or steam capacity to install a carbon adsorption
system.  These facilities should be exempted from having to install adsorption
equipment, but should be required to meet the other housekeeping type of
requirements.
                                     18

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       SUMMARY  OF CTG  DOCUMENT FOR  PERCHLOROETHYLENE DRY  CLEANING SYSTEMS
Affected
facilities
(p. 2-1)*
Number of
affected
facilities
(calculated)
VOC
emissions
nationwide
(pp. 1-2,
2-1) *
Affected facilities are coin-operated, commercial, and industrial dry
cleaning systems which utilize perchloroethylene as solvent.
a.  Coin-op
b.  Commercial
c.  Industrial
 14,900
 44,600
    230
a.  Coin-op
b.  Commercial
c.  Industrial
 21,400 Mg/yr
123,000 Mg/yr
 13,600 Mg/yr
 (23,500 tons/yr)
(135,000 tons/yr)
 (15,000 tons/yr)
The estimated 158,000 Mg VOC/yr is 0.9 percent of total stationary
source estimated emissions.
VOC
emission
range per
facility
(l>. 5-2)*
100 tons/yr
source size
(extrapolated)
                      Uncontrolled VOC emissions
Type of plant
a.  Coin-op
b.  Commercial
c.  Industrial
       1,460
       3,240
      32,400
    (Ib/yr)
    (3,200)
    (7,200)
   (72,000)
A large industrinJ dry cleaning plant, processing 750 Mg (825 tons)  of
clothes per year, would be a potential 100 tons VOC per year source.
CTG
emission
limit
(pp. .6-1
6-4)*
a.  Reduction of dryer outlet concentration to less than 100 ppm VOC,
    by means of carbon adsorption.  (Facilities with inadequate space
    or steam capacity for adsorbers are excluded.)

b.  Reduction of VOC emissions from filter and distillation wastes.
c.  Eliminate liquid and vapor leaks.
VOC
reduction
per facility
(pp. 2-5,
2-7)*
Carbon adsorption applied to commercial and industrial plants will
reduce overall VOC emissions by 40-75 percent.
Costs
(p. 4-5)*
Basis;   Carbon adsorbers for a commercial plant cleaning 46,000 kg
        (100,000 lb)  of clothes per year.
                        Cap!tal cost

                        Annualized cost

                        Cost  effectiveness
                                     $4,500

                                       $300

                                        $90. credit/Mg

                                        $80 credit/ton
*The source of the summary  information  is  the  indicated  page number  in  "Control  of
 Volatile Organic Emissions  from Perchloroethylene  Dry Cleaning  Systems,"  EPA-450/2-78-050.
                                           19

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                                    SECTION 9

                    LEAKS  FROM  PETROLEUM REFINERY  EQUIPMENT8


      Petroleum  refineries produce  gasoline, aromatics, kerosene,  distillate



 finery VOC emissions, that have been addressed in previous CTG documents  are
 fixed roof storage tanks; vacuum producing systems, wastewater separators  and
 process unit turnarounds; and gasoline  transfer operations.       Parators> and

      Even though present estimates show that petroleum refinery leaks are a
 significant .source of VOC emissions, the emission factors which yield ?hese
 estimates are based on 20-year old data.  Emission factors for petroleum re-

  oLT^ak ePrV6akS 3re belng UPdated' ^ P'^nary data indicate the
 total Jeak emission rate is greater than present estimates.
      The CTG document recommends a two-phase program of monitoring and main-

       V'rvor   V°C emiS?10nS fr°m Petr°leUm refiner>' ei«iP"en? Tea™
 A 10,000 ppm VOC concentration,  when tested in the manner described in
 Appendix B of the document,  constitutes a leak.   The monitoring plan consists
 of annual inspection of pump seals,  pipeline valves in liquid Lrvice  and
 process  drains;  quarterly  inspection of compressor seals,  pipelinf valves in

 in8YeM    Y    PrGSSUre  reUef ValV6S ln gas Servlce;  ««d  weekly visual
 inspection of pump  seals.  The maintenance portion of the  program consists of
 repairing any detected  leaks within  15  days.   In  some cases  ifwill not be
 possible  to  compete the repair  until  the  next scheduled  unit turnaround

 £ cer af fT*"  "^ "^  ^ rGPalred UDtil  the  ne— ^  shutdown occurs.
         f ,lnsta"ces «»re  than unit  shutdown repairs  will  be  necessary  to
               g  "°mPnent  lnt° comPliance-   Temporary variances  should  be
                                                         ^^enance or equip-
fn,  I!'0 CT(;,als« ^commends recording and reporting requirements to facili-
tate the monitoring and maintenance program.   A leaking components monitoring
         M     "**   ^ C°ntainS "**"&** information on leaks and their
         Also quarterly reports should be submitted to the air pollution con-
         c  certif
                                                     o   e ar pouto
trol agency certifying that the monitoring has been performed according

                            " "^"^ **** ^ «" «* "*»*
rrecHt1^ CTG ^^T" d°eS n0t PreSent calculati°ns fpr recovered product
credits or cost-effectiveness ratios because emission reduction factors were
                                     20

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not available.  The necessary factors became available in January 1980 and
have been used to calculate the emission reduction and cost-effectiveness
figures presented in the following table.13
                                     21

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  SUMMARY OF  CTG  DOCUMENT FOR LEAKS FROM PETROLEUM REFINERY  EQUIPMENT
 Affected
 facilities
 (p. 6-1)*
 Petroleum refinery equipment including pump seals,  compressor
 seals, seal oil degassing vents, pipeline valves,  flanges and
 other connections, pressure relief devices, process drains
 and open ended pipes.                                     '
 Number of
 affected
 facilities
 There were 311 petroleum refineries in the nation as  of
 January 1, 1979.12
 VOC
 emissions
 nationwide
 (p.  5-1)*
 The estimated VOC emissions nationwide  are  170,000 Mg/year
 or about ]  percent of the total  VOC emissions  from stationary
 sources.
 VOC
 emissions
 range  per
 facility
 (p.  3-2)*
 The potential  VOC emissions  per leaking source range from 1.0 to
 10 kg/day.
100 ton/year
source size
(p. 1-3, 2-3)*
 vnr/       n                               to emit O.A to 3.7 Mg
 VOC/year  (0.5  to 4.1  ton/yr).  A refinery with between 25 and
 227  leaking  components would emit 100 tons/year of VOC.  A
 model medium size refinery may have 90,000 leaking components.
CTG
emission
limits
(p. 1-3)*
 If  a  leaking component has a VOC concentration of over 10 000 ppm
 at  the potential leak source, it should be scheduled for main-
 tenance and repaired within 15 days.
VOC
reduction per
facility
(calculated)
vearTofvoc P"vent/fe r^ease °f 1821.1  Kg/year  (2007.4  ton/
year) of VOC at a model medium size refinery  (15,900  m3/day) by
reducing emissions from 2933.6 Mg (3233.5 ton)  to 1112.5 Mg
(1226.1 ton) per year.13
Costs
(p.  4-8)*
Basis:  A monitoring and maintenance program for a 15,900 m3/day
(100,000 bbl/day) refinery (Fourth quarter 1977  dollars).

  Instrumentation Capital Cost        8,80p

  Total Annual!zed Costs            115,000

  Cost Effectiveness $/Mg           (86.85)tl3

                     $/ton          (78.81.)tl3
 The  source  of  the summary  Information is the indicated page number(s) in "Control
     ?r/    Or8anlc  Compound Leaks from Petroleum Refinery Equipment,"
   —     ~*  ~
Numbers  in parentheses are savings.
                                      22

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                                 SECTION 10

                    PETROLEUM LIQUID STORAGE IN EXTERNAL
                            FLOATING ROOF TANKS9


     Petroleum liquid storage in external floating roof tanks occurs at pe-
troleum refineries, terminals, tank farms and along pipelines   The recom-
mended control technology Us retrofitting certain affected tanks with rim-
mounted secondary seals.

     There are several exceptions to the general requirement that all exter-
nal floating roof petroleum liquid storage tanks larger than 150,000 liters
(40,000 gal) must have secondary seals.  The exempt liquid storage tanks are
those which:

     1.   are used to store waxv, heavy pour crude oil;

     2.   have capacities less than  1,600,000  liters  (420,000 gal)
          and are used to store  produced  crude oil and  condensate
          prior  to lease custody transfer;

     3.   contain a  petroleum  liquid with  a  true vapor  pressure  of
          less than  10.5 kPa  (1.5 psi);

     4.   contain a  petroleum  liquid with  a  true vapor  pressure
          less than  27.6 kPa  (4.0 psi);  and

           (a)  are of welded  construction;  and

           (b)  presently possess a  metallic-type  shoe seal,  a  liquid-
               mounted  liquid  filled type seal, or other  closure
               device of demonstrated  equivalence;

      5.    are  of welded  construction,  equipped with  a metallic-type  shoe
           primary  seal  and  have  a  secondary seal  from the top  of the
           shoe seal  to  the  tank  wall (shoe-mounted secondary seal).

      Tanks  storing waxy, heavy pour crude oil  are exempted because  waxy depo-
 sits  on the tank wall would damage  the secondary  seal.   If the tank is of
 riveted construction and not used  for lease custody  transfer,  the only exemp-
 tion  IK when true  vapor pressure is less than  10.5 kPa.  If the vessel is
 welded construction (and  also not  used for lease  custody transfer)  the vapor
 pressure exemption becomes  a function of the existing primary seal type.   If
 the seal Is a metallic-shoe type,  liquid-mounted  foam type, liquid-mounted
 liquid filled type,  or  equivalent,  the minimum true  vapor pressure for exemp-
 tion rises to 27.6 kPa  (4.0 psi).   For other primary seals on welded tanks,
 the minimum vapor  pressure  for exemption remains  at  10.5 kPa (1.5 psi).

                                      23

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Finally, if the tank is of welded construction,  equipped with a metallic shoe
seal and has a secondary seal from the top of the shoe seal to the tank wall
(shoe mounted secondary seal) it is not an affected facility.

     The affected tank size changes from 150,000 liters (40,000 gal) to
1,600,000 liters (420,000 gal) only for tanks storing produced crude oil and
condensatc prior to lease custody transfer (oil  field production storage).
This exception applies to tanks storing petroleum liquid from the time it is
removed from the ground until custody is transferred from the production
operation to the transportation operation.

     A rim-mounted secondary seal is continuous  and extends from the floating
roof to the tank wall, above, and covering the entire primary seal.  Installed
over mechanical shoe seals, liquid mounted primary seals or vapor mounted
primary seals, rim-mounted secondary seals effectively reduce VOC emissions.
In order for the secondary seal to be effective, the accumulated area of gaps
exceeding 0.32 cm  (1/8 in.) in width between the secondary seal and the tank
wall should not exceed 2].2 cm7 per meter of tank diameter (1.0 in.2 per foot
of tank diameter).

     Several ancillary control techniques are recommended in the CTG document.
These include keeping covers, seals and lids closed except when in actual use
and providing projections below the liquid surface on certain openings.  Also
automatic bleeder vents should be kept closed except when the roof is floated
off or  landed on the roof leg supports, and rim vents should be set to open
only when  the roof is being floated off the roof leg supports.  Finally, roof
drains  should be provided with slotted membrane fabric covers or equivalent.
                                      24

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            SUMMARY  OF CTG DOCUMENT FOR  EXTERNAL FLOATING ROOF TANKS
Affected
facilities
(p. 1-2)*
Number of
affected
facilities
(p. 2-1) *
voc
emissions
nationwide
(p. 1-2)*
VOC
emission
range per
facility
(pp. 3-3,
3-9)*
 100 tons/yr
 source size
 CTG
 emission
 limit
 (PP. 5-1,
 5-4)*
 VOC
 reduction
 per  facility
 (pp.  3-3,
 3-9)*
 Costs
 (PP. 4-9,
 4-12) *
External floating roof tanks larger than 150,000 liters (40,000 gal)
storing petroleum liquids.   See exceptions noted in text.
There is an estimated 13,800 internal and external floating roof tanks
that are larger than 150,000 liters (40,000 gal).   The number of ex-
ternal floating roof tanks is not available.
An estimated 65,000 Mg (71,630 tons) of VOC was emitted in 1978 which
represents about 4.0 percent of stationary source estimated emissions.
The emission range for a 30.5 m (100 ft) diameter tank storing 41.4 kPa
(6 psi) vapor pressure gasoline is 212 Mg/yr (233 tons/yr) for a slightly
gapped primary seal to 2.2 Mg/yr (2.4 tons/yr) for a tight rim-mounted
secondary seal over a tight primary seal.
No single  floating  roof tank  is expected to emit more than 100
tons/yr. ] r'

A continuous  secondary  seal or  equivalent  closure  on all affected
storage tanks, plus  certain inspection and recordkeeping requirements.
 Ranges  from  about  200  to  2 Mg/yr  (220  to  2.2  tons/yr).
                Basis:
         External floating  roof  tank  30.5 m  (100  ft)  in  diameter with  a
         capacity of  8.91 *  106  liters  (55,000 bbl)  controlled by  a rim
         mounted  secondary  seal.

         Capital  cost          16.9
         ($1000)
                         Annualized  cost
                         ($1000)

                         Cost  effectiveness
                         ($/Mg)
                         ($/ton)
                                                3.3
                               (66)f-3,655
                               (59)f-3,316
 *The source of the summary information  is  the  indicated  page(s)  in  "Control of Volatile
  Organic Emissions from Petroleum Liquid Storage  in  External  Floating  Roof Tanks,"
  EPA-450/2-78-047.

 ^Numbers in parenthesis indicate credits.
                                             25

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                                  SECTION 11

                  LEAKS FROM GASOLINE TANK TRUCKS AND VAPOR
                            COLLECTION SYSTEMS10
     The Intent of this guideline is to define leak tight conditions and re-
lated te.st procedures for vapor collection systems and tank trucks while
loading and unloading at bulk plants, bulk terminals and service stations.
The two separate affected facilities are gasoline tank trucks that are
equipped for vapor collection and vapor collection systems at bulk terminals,
bulk plants, and service stations that are equipped with vapor balance and/or
vapor processing systems.  The control approach is a combination of testing,
monitoring, and equipment design requirements to ensure good operation and
maintenance practices.

     Annual testing of gasoline tank trucks is recommended.  The test consists
of pressurizing to 4,500 Pa (18 in.  of water) and evacuating to 1,500 Pa
(6 In.  of water).   The truck tank should not sustain a pressure change of more
than 750 Pa (3 in. of water) in 5 minutes under either condition.  Each truck
tank should display a sticker indicating the date it last met this pressure
and vacuum test criteria.

     The vapor collection and vapor processing equipment should be designed
and operated to prevent gauge pressure in the tank truck from exceeding
4,500 Pa (18 in. of water) and prevent vacuum from exceeding 1,500 Pa (6 in.
of water).  In addition, vapor concentration at 2.5 cm around the perimeter
of a potential leak source should be below 100 percent of the lower explosive
limit (LEI.,, measured as propane) at all times when measured by a combustible
gas detector.

     The CTG document provides detailed descriptions of the testing of tank
trucks  and vapor collection systems.  In addition, calibration procedures for
the combustible gas detectors which are recommended for use by regulatory
agencies for compliance monitoring are provided.  Recordkeeping and reporting
requirements are also discussed in the CTG document.

     Additional information on control techniques, costs, and monitoring pro-
cedures IH presented in a report entitled "Evaluation of Vapor Leaks and
Development of Monitoring Procedures for Gasoline Tank Trucks and Vapor
Piping," EPA-450/3-79-018, April 1979.
                                     26

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       SUMMARY OF CTG DOCUMENT FOR  LEAKS  FROM  GASOLINE TANK TRUCKS AND
                                VAPOR COLLECTION SYSTEM
Affected
facilities
(p. 2)*
Number of
affected
facilities
VOC
emissions
nationwide
a.  Gasoline tank trucks  that  are equipped for vapor collection.
b.  Vapor collection systems at bulk  terminals, bulk plants, and service
    stations that are equipped with vapor balance and/or vapor processing
    systems.
                Not available
                Not available
VOC
emission
range per
facility
                Not available
 CTG
 emission
 limit
 (pp.  1
 and  2)
 VOC
 reduction
 per facility
The control approach is a combination of  testing, monitoring, and equip-
ment design to ensure that good maintenance practices  are employed to
prevent leaks from truck tanks or tank compartments  and vapor collection
systems during gasoline transfer at bulk  plants, bulk  terminals, and
service stations.  A leak is a reading greater than  or equal to  100
percent of the LEL at 2.5 cm from a potential leak source as detected by
a  combustible gas detector.
                Not available
 Costa
                Not available
 *The source  of  the summary information is the indicated page number  in  "Control of Volatile
  Organic  Compound Leaks from Gasoline Tank Trucks and Vapor Collection  Systems,"
  EPA-450/2-78-051.
                                             27

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                                 REFERENCES
 1.   Control of Volatile Organic Emissions from Existing Stationary Sources -
      Volume VI:  Surface Coating of Miscellaneous Metal Parts and Products,
      U.S. Environmental Protection Agency, Office of Air Quality Planning and
      Standards, June 1978, EPA-450/2-78-015.

 2.   Control of Volatile Organic Emissions from Existing Stationary
      Sources - Volume VII:  Factory Surface Coating of Flat Wood Paneling,
      U.S. Environmental Protection Agency, Office of Air Quality Planning
      and Standards, June 1978, EPA-450/2-78-032.

 3.   Control of Volatile Organic Emissions from Manufacture of Synthesized
      Pharmaceutical Products, U.S. Environmental Protection Agency, Office
      of Air Quality Planning and Standards, December 1978, EPA-450/2-78-029.

 4.   Control of Volatile Organic Emissions from Manufacture of Pneumatic
      Rubber Tires,  U.S. Environmental Protection Agency, Office of Air
      Quality Planning and Standards, December 1978, EPA-450/2-78-030.

 5.   Control of Volatile Organic Emissions from Manufacture of Vegetable
      Oils, U.S. Environmental Protection Agency, Office of Air Quality Plan-
      ning and Standards, June 1978, EPA-450/2-78-035.

 6.   Control of Volatile Organic Emissions from Existing Stationary Sources -
      Volume VIII:   Graphic Arts - Rotogravure and Flexography, U.S. Environ-
      mental Protection Agency, Office of Air Quality Planning and Standards,
      December 1978, EPA-450/2-78-033.

 7.   Control of Volatile Organic Emissions from Perchloroethylene Dry Clean-
      ing Systems,  U.S. Environmental Protection Agency, Office of Air Quality
      Planning and  Standards, December 1978, EPA-450/2-78-050.

 8.   Control of Volatile Organic Compound Leaks from Petroleum Refinery Equip-
      ment, U.S. Environmental Protection Agency, Office of Air Quality Plan-
      ning and Standards, June 1978, EPA-450/2-78-036.

 9.   Control of Volatile Organic Emissions from Petroleum Liquid Storage in
      External Floating Roof Tanks, U.S.  Environmental  Protection Agency,
      Office of Air  Quality Planning and  Standards, December 1978, EPA-450/2-
      78-047.

10.   Control of Volatile Organic Compound Leaks from Gasoline Tank Trucks
      and Vapor Collection Systems, U.S.  Environmental  Protection Agency,
      Office of Air  Quality Planning and  Standards, December 1978,
      EPA-450/2-78-051.

11.   Control Techniques for Volatile Organic Emissions from Stationary Sources,
      U.S.  Environmental Protection Agency, Office of Air Quality Planning and
      Standards, May 1978, EPA-450/2-78-022.
                                     28

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12.    Energy Data Reports, Petroleum Refineries in the United States and U.S.
      Territories, Department of Energy, Energy Information Administration,
      Washington, D.C., dated January 1, 1979, released for printing June 28,
      1979, DOE/EIA-0111/79.

13.   Memorandum  from  S.  V. Capone, GCA/Technology Division, to T. Williams,
      EPA/CPDD.   Cost  Effectiveness for RACT Application to Leaks from Pe-
      troleum Refinery Equipment.  February 1, 1980.

14.   Enforceability Aspects of RACT for Surface  Coating of Miscellaneous
      Metal Parts and  Products, Preliminary Memorandum.  PEDCo.  EPA Contract
      68-01-4147, Task Order No. 121.   January 11, 1980.

15.   Calculations by  R.  K. Burr,  ESED, author of Reference 9.
                                      29

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                                    TECHNICAL REPORT DATA
                                 mill l/jiirnclKins on the riTcnc hc/oic completing)
I  H I I' (1 R 1 N O
 _FPA-450/2-80-001
4. 1 I I L L AND SUB1 Hit
  SUMMARY OF GROUP  II  CONTROL TECHNIQUE GUIDELINE
  DOCUMENTS  FOR  CONTROL OF VOLATILE ORGANIC EMISSIONS
 FROM EXISTING  STATIONARY SOURCES
 Stephen V. Cnpone
 Mslcolm W. IVtroccia
 Pt RF ORMING ORGAN I/ATI ON NAME AND ADDRESS
 CCA CORPORATION
 OCA/TECHNOLOGY D i V ISION
 Burlington Road
 Bedford, Massachusetts  01730
1.2. SPONSORING AGLNCY NAME AND ADDRESS
 U.S. ENVIRONMENTAL PROTECT!ON AGENCY
 Office of Air, Noise, and  Radiation
 Office of Air Quality Planning, and Standards
 Research Triangle  Park,  North Carolina 27711
 15. SUI'PLI MENTAHY NOTES
   P'-ojcct  Officer:  Tom Williams
                                                           3 RECIPIENTS ACCESSIOONO.

                                                           5 REPORT DATE
                                                             _February 1_980 _
                                                           6. PERFORMING ORGANIZATION CODE
                                                           8. PERFORMING ORGANIZATION REPORT NO.

                                                                GCA-TR-79-79-G
                                                           10 PROGRAM ELEMENT NO.
                                                           11  CONTRACT/GRANT NO
                                                               68-02-2607
                                                               Work Assignment No.  39
                                                           13 TYPE OF REPORT AND PERIOD COVERED
                                                                        _   ____
                                                           14. SPONSOR I NG~AG¥rgcV~COD~E
  6. ABSTRACT
        Control Technirnie  Guideline CCTG) documents have been  prepared b/ the Office
   of Air Oualitv  Planning and  Standards of the U.S. F?A to  assist  states in defin-
   ing reasonably  available control  technology (RACT) for the  control  of volatile
   organic compound  emissions  from existing stationary sources.   A  document (EPA-
   450/1-78-120) summarizing the CTG documents issued prior  to January 1978 (Croup I)
   was published in  December 1978.

        This document  (FPA-45D/2-80-001) summarizes the CTG  documents  issued between
   Tnmmrv 1978 and  January 1979 (Group  IT).  A description  of each source category
   is provided, a I on p.  with RACT and  costs to retrofit a model  facility.   The source
   categories  included  are:   leaks from  petroleum refinery equipment,  surface coat-
   ing of miscellaneous metal  parts  and  products, manufacture  of  vegetable oil,
   surface coating of  flat  wood paneling, synthesized pharmaceutical products manu-
   facturing, pneumatic rubber  tire  manufacturing, graphic arts  (rotogravure and
   flexographv), external  floating roof  tanks, perchloroethylene  dry cleaning, and
   leaks from gasoline  tank  trucks and vapor collection systems.
                  IK SCRIPT OHf,

   Air Pollut ion
   Control Guidelines
   Volatile Organic Chemicals
   Organic Compounds
                              K( Y WORDS AND DOCUMENT ANALYSIS
                                            l>. IDENTIFIERS/OPEN ENDED TERMS

                                             Air  Pollution Control
                                             Stationary Sources
                                             Reasonably Available
                                                Control Technology
                                             Organic  Chemical
                                                Emissions
                                             Emission Limitations
ui"> r RIHU rioN s r A u MI NT

Unlimited
EPA Ponn 2220-1 (9-73)
                                             19 SFCURITY CLASS (1 His Report)'
                                               Uncla s sjijfi e d
                                             20        "
                                               Unclassi fied
                                                                        COSATI 1 k'kl/(lroii|i
                                                                       21 NO OF PAGES
                                                                           34
                                                                        22 PRICE
                                           31

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