EPA-450/3-77-004b
January 1977
     POPULATION EXPOSURE
                TO OXIDANTS
     AND NITROGEN DIOXIDE
             IN LOS ANGELES
                   VOLUME II:
       WEEKDAY/WEEKEND
            AND POPULATION
          MOBILITY EFF1CTS
  U.S. ENVIRONMENTAL PROTECTION AGENCY
      Office of Air and Waste Management
   Office of Air Quality Planning and Standards
   Research Triangle Park, North Carolina 27711

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                                     EPA-450/3-77-004b
              POPULATION EXPOSURE
*
J-   TO OXIDANTS AND NITROGEN DIOXIDE
                   IN LOS ANGELES
       VOLUME II: WEEKDAY/WEEKEND
     AND POPULATION MOBILITY EFFECTS
                             by

                 Yuji Horie, Anton S. Chaplin, and Eric D. Helfenbein

                      Technology Service Corporation
                        2811 Wilshire Boulevard
                      Santa Monica, California 90403
                        Contract No. 68-02-2318
                        Project No. DU-76-C190
                      Program Element No. 2AF643
                     EPA Project Officer: Neil H. Frank
                          Prepared for

                   ENVIRONMENTAL PROTECTION AGENCY
                     Office of Air and Waste Management
                   Office of Air Quality Planning and Standards
                   Research Triangle Park, North Carolina 27711

                          January 1977

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This report is issued by the Environmental Protection Agency to report
technical data of interest to a limited number of readers.  Copies are
available free of charge to Federal employees,  current contractors and
grantees, and nonprofit organizations - in limited quantities - from the
Library Services Office (MD-35) ,  Research Triangle Park, North Carolina
27711;  or,  for a fee, from the National Technical Information Service,
5285 Port Royal Road, Springfield, Virginia 22161.
This report was furnished to the Environmental Protection Agency by
Technology Service Corporation, 2811 Wilshire Boulevard, Santa Monica,
California 90403, in fulfillment of Contract No. 68-02-2318, Project No.
DU-76-C190,  Program Element No.  2AF643. The contents of this report
are reproduced herein as received from Technology Service Corporation.
The opinions, findings,  and conclusions expressed are those of the
author and not necessarily those of the Environmental Protection Agency.
Mention of company or product names is not to be considered as an endorse-
ment by the Environmental Protection Agency.
                    Publication No. EPA-450/3-77-004b
                                  11

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                          TABLE OF CONTENTS


 Section                                                             Page


       LIST OF FIGURES	   11i

       LIST OF TABLES	     v

1.     INTRODUCTION 	     1

       1.1  RECEPTOR POINTS 	     3
       1.2  WEEKDAY-WEEKEND DIFFERENCE	     3
       1.3  POPULATION MOBILITY 	     4
       1.4  ISOPLETH MAPS 	     5

2.     OVERVIEW OF POPULATION AND AIR QUALITY IN THE
       LOS ANGELES BASIN	     7

       2.1  POPULATION PROFILE	    10
       2.2  AIR POLLUTION PROFILE	    17
       2.3  INTERFACING POPULATION AND AIR QUALITY DATA	    21

3.     WEEKDAY-WEEKEND DIFFERENCE IN AIR QUALITY AND POPULATION
       EXPOSURE	    27

       3.1  WEEKDAY-WEEKEND DIFFERENCE IN Ox	    28
       3.2  WEEKDAY-WEEKEND DIFFERENCE IN N02	    39
       3.3  RELATING WEEKDAY-WEEKEND DIFFERENCE IN
            EMISSIONS TO AIR QUALITY	    46

4.     EFFECTS OF DAILY POPULATION MOBILITY ON POPULATION
       EXPOSURE	    49

       4.1  POPULATION-AT-RISK DISTRIBUTION FOR STATIC
            AND MOBILE POPULATIONS  	    50
       4.2  SIGNIFICANCE OF POPULATION MOBILITY IN POPULATION
            EXPOSURE ESTIMATES	    58

5.     CONCLUDING REMARKS 	    65

REFERENCES	    69

APPENDICES

A.     DATA ON TOTAL POPULATION, WORKERS BY RESIDENCE, AND
       WORKERS BY EMPLOYMENT LOCATION IN 1973	    A-l

B.     AIR QUALITY DATA FOR QX AND N02 IN THE LOS ANGELES AQCR. .  .    B-l

C.     MONITORING STATIONS AND RECEPTOR POINTS	    C-l

D.     METHODOLOGY TO CHARACTERIZE POPULATION EXPOSURE	    D-l

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                                         LIST OF FIGURES
             Figure No.                                                     Page

               2.1       Topographical Features of the Los Angeles Basin .    8

               2.2       Location of Monitoring Stations 	    9

               2.3       Boundaries Showing 1973 Analysis Area, and
                           Los Angeles AQCR	    11

               2.4       Regional Statistical Areas Developed by Southern
                           California Association of Governments 	    12

               2.5       Population Density in Persons per Square Mile
                           in 1970	    13

               2.6       Number of Persons Employed per Square Mile in
                           1970	    15

               2.7       Net Influx of Population (Workers) During Working
                           Time in Persons per Square Mile in 1970 ....    16

               2.8       Diagram of Creating a Demographic Network for
                           Metropolitan Los Angeles AQCR	    23

               2.9       Locations of the 99 Receptor Points Assigned to
                           the Study Region	    25

               3.1       Isopleths of Percent of Days on Which the NAAQS
                           for Oxidant was Exceeded in 1973	    29

               3.2       Isopleths of Mean Duration (hours) on Days When
                           the NAAQS for Oxidant	    31

               3.3       The Difference in Percent of the Number of Days
                           on Which the NAAQS for Oxidant was Exceeded in
*                          1973, Weekday Minus Weekend 	    32

«              3.4       Population Exposed to 0  Daily Maximum Hourly
                           Concentration Above tne NAAQS at Various
                           Frequencies	    34

               3.5       Population Exposed to 0  Hourly Concentration
                           Above the NAAQS at Various Frequencies  ....    35

               3.6       Isopleths of Percent of Days on Which the
                           California One Hour Standard for NO, was
                           Exceeded in 1973	L	38

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                        LIST OF FIGURES (Cont'd)
Figure No.                                                     Page

  3.7       Isopleths of Mean Duration (Hours) on Days When
              the California One Hour Standard for N0? was
              Exceeded in 1973	 .  . .     40

  3.8       The Difference in Percent of Days on Which the
              California One Hour Standard for NO? was
              Exceeded in 1973, Weekday minus Weekend  ...     41

  3.9       Population Exposed to N02 Daily Maximum Hourly
              Concentration Above the California One Hour
              Standard at Various Frequencies  	     43

  3.10      Population Exposed to N02 Hourly Average
              Concentration Above the California One Hour
              Standard at Various Frequencies  	     44

  4.1       Workers Exposed to Ox Hourly Concentration Above
              the NAAQS During Working Time at Their
              Residence and at Their Work Place	     51

  4.2       Exposure of all Workers to Oxidants Above the
              NAAQS During Working Time (1), Non-Working
              Time (2), Combination of (1) and (2) as (3)
              and Total Time  (--)	    54

  4.2a      Probability Density  Distribution of Workers
              Exposed to Hourly  0> Above the NAAQS	     55

  4.3       Population Exposure  to Oxidants Above the NAAQS.     57
                                   IV

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                            LIST OF TABLES
Table No.                                                      Page

  2.1       Percent of Days the NAAQS for Ox Was Exceeded
              and the Mean Duration in Hours (x,x) in 1973 .     19

  2.2       Percent of Days the California Standard for N02
              was Exceeded and the Mean Duration in Hours
              (x.x) in 1973	     20

  3.1       Regionwide Impact of Weekday-Weekend Phenomena on
              Population Exposure to Photochemical Oxidants     36

  3.2       Regionwide Impact of Weekday-Weekend Phenomena
              on Population Exposure to Nitrogen Dioxide . .     45

  4.1       Effect of the Consideration of Population Mobility
              on the Estimates of Population Exposure to
              0₯ in the 1973 Study Area	     60
               /\

  4.2       Effect of Consideration of Population Mobility
              on Estimates of Population Exposure to N0£
              in the 1973 Study Area	     60
  A-l       Total Population, Workers by Residence, and
              Workers by Employment Location in 1973  ....    A-2

  B-l       Corrected Ox Daily Maximum Hourly Average
              Concentrations in 1973	    B-2

  B-2       Corrected Ox Hourly Average Concentrations in
              1973	    B-5

  B-3       N02 Daily Maximum Hourly  Average Concentrations
              in 1973	    B-9

  B-4       N0£ Hourly  Average Concentrations in  1973  ...    B-l2

  C-l       Locations and Addresses of Air Monitoring
              Stations	    C-2

  C-2       Receptor Points Assigned  to the Los Angeles
              AQCR	    C-5

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                      1.   INTRODUCTION

     We have divided this report on the  subject of  population  exposure
to photochemical  pollutants  in the Los Angeles  Basin  into  three  volumes.
Volume I is an executive  summary which contains the highlights of
Volumes II and III.  Volume  III is entitled,  "Population Exposure  to
Oxidants and Nitrogen Dioxide in Los Angeles  -  Long Term Trends, 1965-1974."
In Volume III, trends in  photochemical air pollution  in the Los  Angeles
Basin are discussed from  two new aspects,  characterization of  air
quality relative to the standards and quantification  of population ex-
posure to air pollution.
     In this report, Volume  II, two primary purposes  of the study  are
described.  They are:
     (1)  analysis of the weekday-weekend  effect on photochemical  air
pollution and
     (2)  analysis of the effect of diurnal population mobility  on
population exposure estimates in the Los Angeles Basin.
     The analyses were performed by characterizing  local  air quality  in
relation to the air quality  standard and by quantifying exposure of the
population to air pollution.  This was accomplished through the  use of
Ox and N02 data for 1973.  This year was selected because it provided the
most air quality monitoring  sites producing data for  the analysis.  Most
of the past analyses of air  quality data are expressed in  concentration
                                              o
units such as ppm (parts per million) and ug/m  (micrograms per  cubic
meter).  It is not that these units are hard to understand, but  rather

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this form of air quality presentation is inadequate because it does not
indicate adverse effects on public health explicitly or quantitatively.
     The air quality standards  have been set to  protect the public  health
(primary standards)  or the public welfare (secondary standards).  Quanti-
fication of the observed air quality in relation to the primary standard
should indicate explicit adverse impacts with respect to public health.
Therefore, hourly Ox air quality data are examined  in relation to the
primary National Ambient Air Quality Standard (NAAQS, 160 yg/m  or  approxi-
mately 8 pphm for one hour average concentration).   Because there is no
NAAQS for short-term NOp concentrations, hourly  N0~ air quality data are
examined in relation to the California Ambient Air  Quality Standard
                3
(CAAQS, 470 yg/m  or approximately 25 pphm for one  hour average concentra-
tion).  In this report, air quality is expressed in percentage of the time
the standard was exceeded and in mean duration of the excess air pollution
in hours per day.

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1.1  RECEPTOR POINTS
     To determine population exposure to air pollution, air quality measure-
ments taken at widely separated monitoring stations are used to describe the
spatial distribution of air pollution levels.   Using the statistics of popula-
tion and employment prepared by the Southern California Association of
Governments (SCAG),  the spatially distributed population is approximated by
99 receptor points.  Each receptor point represents the local population
size, the spatial position of the local population, and the area in which
the local population resides.  The air quality at each receptor point is
estimated by spatially interpolating the air qualities observed at the
three nearest monitoring stations to that receptor point.  In this manner,
the region's demographic data are merged with the air monitoring data to
estimate short-term air quality (hourly concentration and daily maximum
hourly  concentration) experienced by the Los Angeles population.
1.2  WEEKDAY-WEEKEND DIFFERENCE
     In order to investigate the weekday-weekend difference in air quality,
hourly concentration data were divided into weekdays and weekends  and were
summarized in percentile concentration distributions.  For each of given
percentiles (maximum,  1, 3, 5, 10, 25, 50, and 75%), the percentile con-
centration at each receptor point was estimated by spatially interpolating
the observed percentile concentrations at the nearest three monitoring
stations to that receptor point.  Repeating this procedure for all the
percentiles, percentile statistics of interpolated concentrations  at each

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receptor point were created for all  time,  weekdays,  and  weekends.   The per-
centile indicating the percentage of the time (hours or  days)  the  standard
was exceeded was determined to quantify air quality at each receptor point
in relation to the standard.
1.3  POPULATION MOBILITY
     The population-at-risk distribution,  which describes the percentages
of the population exposed to a concentration above the standard for a given
fraction of the time, is used to report the short-term exposure of the popu-
lation quantitatively.  In determining population exposure to atmospheric
pollutants, a difficulty arises.  Since people move around with time, the
air pollution concentration must be known as a function of both time and
the person's spatial  position at that time.  This difficulty associated with
population mobility  is  partially solved in this report  by employing the
quasi-stationarity assumption  that  people stay near a given location during
a categorized  time period.

      The effect of diurnal population mobility between  residence  and work-
 place on population exposure estimates was investigated in the following
 manner.  Hourly concentration data were divided into working time (weekday
 7 A.M. to 6 P.M.) and non-working time.  The hourly concentration data for
 working time were merged with employment data to estimate exposure of the
 workers population at their place of employment.   The hourly concentration
 data for nonworking  time were merged with residential population data for

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workers to estimate the exposure of the workers population at their place
of residence.  Exposure of the worker population during all time was com-
puted by combining the exposure during working time and non-working time.
The exposure of non-workers was based on their place of residence and the
concentration data for all time.  Exposure of the total population during
all time was then computed by combining two subpopulations» the workers
population and the non-workers population.
1.4  ISOPLETH MAPS
     The percentage of days on which the standard was exceeded was computed
by using the air monitoring data of daily maximum hourly concentrations while
the percentage of hours the standard was exceeded was computed from those of
hourly concentrations.  Using the percentage of days exceeded and the percen-
tage of hours exceeded, the mean duration of excess air pollution in hours
per day was computed at each receptor point.   The spatial  variations of air
quality during all time, weekday, and weekend were  then  presented in isopleth
maps of the percentage of days the standard was exceeded and of the mean dura-
tion of excess air pollution in hours per day.  The isopleth maps describing
the percentage of days the standard was exceeded during weekday and weekend
were used to examine the weekend-weekday difference in 0  and N09 air quality.
                                                        A       <_

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     2.  OVERVIEW OF POPULATION AND AIR QUALITY IN THE LOS ANGELES BASIN

     Among the nation's 247 Air Quality Control Regions (AQCR's), the
Los  Angeles AQCR is special in that it is defined by its geographical
boundaries (mountains and ocean) whereas the great majority of AQCR's
are  defined by their administrative boundaries (state and county lines).
Figure 2.1 depicts the topographical features of the Los Angeles Basin.
The  AQCR  (the area surrounded by solid lines) covers six different
counties:  all of Orange and Ventura counties, and part of Santa Barbara,
Los  Angeles, San Bernardino, and Riverside counties.
     The difference between the AQCR boundaries and the county boundaries
makes it difficult to obtain demographic data specific to the AQCR.   In the
analysis of population exposure to air pollution, the spatial distribution
of population as well  as the population size must be known.   However, a cen-
sus  tract is too small for the spatial  unit because there are less than 50
air monitoring stations in the region.   During our search for the population
data to be used for the population exposure analysis, we found that  the
Regional  Statistical  Areas (RSA's) developed by the Southern California
Association of Governments (SCA6) were a proper spatial  unit for aggregating
the population data.
     The year of 1973 was chosen for this study because in that year the
largest number of stations reported at least 50% of the possible obser-
vations.   Figure 2.2 depicts the location of the 26 air monitoring stations
which were used for the detailed analysis made with the 1973 air quality
and population data.   The vast majority of stations produced data that ex-
ceeded 80% completeness.   The oxidant data at four stations, Point Mugu (3),
Chino (18), Upland (21),  and Redlands  (26), failed to meet our criterion

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Figure 2.1.  TOPOGRAPHICAL  FEATURES  OF THE LOS ANGELES BASIN.

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V 	
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Santa
Barbara
County
                                        Los Angeles
                                                                                        0   5  in  15 20 25
                                                                                               Miles


                                                                                       County Boundary

                                                                                       AQCR Boundary
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8
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1. Ojai
2. Camarillo
3. Point Mugu
4. Newhall
5. Reseda
6. West L.A.
7. Lennox
8. Burbank
9. Los Angeles
10. Pasadena
11 . Long Beach
12. Azusa
13. Whittier
14.
15.
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17.
18.
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20.
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22.
23.
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25.
26.
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Anaheim
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El Toro
Upland-ARB
Upland
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Riverside
Riverside
San Bernardino
Redlands
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San Bernardino County

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                                                        Orange County
              Stations for N0? only
        0     Stations for N02 and Ox
Figure 2.2  Location of Monitoring Stations.

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                                  10
for a valid station-year, i.e., more than 50% of possible observations.
Therefore, the remaining 22 stations were selected for the analysis of pop-
ulation exposure to 0Y air pollution, while all the 26 stations were used
                     A
for the N02 analysis.  Considering the area coverage of these stations, the
study area for the 1973 analysis was selected as shown in Figure 2.3.  It
can be seen that the 1973 Analysis Area approximately corresponds to the
Los Angeles AQCR minus a portion of Santa Barbara County whose population
data were not available foom the SCAG statistics.
2.1  POPULATION PROFILE
     The Southern California Association of Governments (SCAG) provides
statistics of total  population (at place of residence) and of total  employ-
ment (at place of work).   These SCAG statistics are aggregated into each of
the 55 Regional Statistical  Areas (RSA's) which cover the six counties of
Ventura, Los Angeles, Orange, San Bernardino, Riverside, and Imperial (Fig. 2.4).
Because we also need to know the number of workers at their place of residence
for computing population exposure during non-working time, the aggregated sta-
tistics of workers by residence for each RSA were computed from the 1970 cen-
sus tract data by using the conversion table prepared by SCAG, which indicated
the number of census tracts belonging to each RSA (Appendix A, Table Al).
     The spatial  distribution of total  population density is shown in Fig-
ure 2.5.  A high population density area centers at the Los Angeles CBD and
extends to the southern half of Los Angeles County and portions of Orange
and San Bernardino Counties.   The lowest population density is found in the
mountainous areas (Figs.  2.1  and 2.5).

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Ventura
County
                               Los Angeles County
                                                        /     San Bernardino County
    0   5  10  15 20 25

          Miles
                                                                      Riverside
                                                                      County
                                                  Orange
                                                  County
Santa
Barbara
County
                                                                                            	j_ 	.	
1973 Analysis

County Boundary

AQCR  Boundary
                      Figure 2.3.  Boundaries Showing 1973 Analysis Area, and Los Angeles AQCR.

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                                      19    -SR37
 REGIONAL STATISTICAL AREAS
Stut/iim Cahfamio tsstciotita of Cennaeiils
     Figure 2.4.   REGIONAL STATISTICAL AREAS DEVELOPED BY  SOUTHERN CALIFORNIA
                    ASSOCIATION  OF GOVERNMENTS

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                                   14
     Figure 2.6 depicts the spatial  variation of workers  population  density
at their place of employment.   The spatial  distribution pattern  is somewhat
similar to that of total  population  density.   Because  most workers com-
mute from their residence to their workplace, the number  of  workers  at their
place of residence and that at their place  of employment  are quite different
for individual RSA's.  Workers population density at their place of  residence
was computed for each RSA and then was subtracted from that  at their place of
employment.  The difference indicates the influx of workers  to that  RSA during
working time.  In this manner the daily population movement  in the Los Angeles
Basin was determined as shown in Figure 2.7.   The greatest daily migration
occurs at the Los Angeles CBD and the Southgate area.   A  moderate daily migra-
tion is seen at Long Beach, Inglewood, the  central part of Orange county,
Pomona, the central San Fernando Valley, and Oxnard.
     The study region  (Fig. 2.3) includes 8,612 square miles (22,295 square
kilometers) and 9.9 million people.  The population figure was arrived at by
interpolating SCAG population estimates for 1970 and 1975.  The number of
workers in 1973 who worked inside of the study region were 4,083,358, while
those who  1ived inside of the study region  were 4,110,024.  This small dif-
ference in the number  of workers is due to  the diurnal migration of
workers from their place of residence to their place of employment.

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                                                         WORKERS PER SQUARE MILE


                                                                 103 ^ 105

                                                                 10  a, 103

                                                         ffila  -10  % 10

                                                                 •i f\ O   T f\
Figure 2.7.   THE  NET  INFLUX OF POPULATION (WORKERS) DURING WORKING TIME  IN
             PERSONS  PER SQUARE MILE IN 1970

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                                    17
2.2  AIR POLLUTION PROFILE
     A percentile concentration  distribution is used in this study to char-
acterize annual  short-term  (one  hour) exposures of the population to 0  and
                                                                     /\
N02 air pollution.  The  short-term exposure of the population is character-
ized by two parameters:   (1)  the frequency of occurrence that an ambient
concentration exceeds  the concentration threshold equal to the air quality
standard or a multiple of the standard, and (2) the mean duration of the
excess air pollution above  the threshold in hours per day.
      Using the California ARE  data tape of hourly average concentration,
 the percentile concentration statistics were developed for the  22  air
 monitoring stations that were  selected for the detailed analysis of
 population exposure to 0  air  pollution in 1973, and for the 26 air
                         A
 monitoring stations selected for N02.  In order to examine the  "weekend
 effect" on air quality and population exposure, the percentile
 concentration statistics of  hourly concentrations and daily maximum
 hourly concentrations were computed for three time categories: all time,
 weekday, and weekend.  In order to incorporate daily population mobility
 between residence and workplace into the population exposure analysis,
 the percentile concentration statistics of hourly concentrations were
 computed for the three  additional  time categories; working time (weekday
 7 A.M.  to 6 P.M.), non-working  time, and weekday non-working time.  The
 percentile concentrations  at each  of the  22  air monitoring stations for
 Ox and  the 26 stations  for N02  are  all  presented in  Appendix  B(Tables 81
 through B4).   In those  tables,  time categories  1,  2,  3,  4,  5,  and 6

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                                   18
refer, respectively, to all  time,  weekday, weekend, working time, non-
working time, and weekday non-working  time.
     The 0  air quality observed at each  station  during weekdays and  that
          /\
during weekends is summarized in Table 2.1 by the percent  of  days on  which
the National Ambient Air Quality Standard (NAAQS) was  violated  and  the mean
duration in hours of such violations.   Our results confirm previous  re-
ports. '   Some coastal stations (Anaheim, El Toro, West L.A.,  Lennox) have
a higher percentage of days exceeded over weekends than over  weekdays, in-
dicating that the air at these stations tends to  be more polluted during
weekends than weekdays.  The majority of monitoring stations, however, have
a lower percentage of days exceeded during weekends than weekdays.   It
should be noted that the mean durations of NAAQS  violations  at the  four
coastal stations are all shorter over weekends than over weekdays.   There-
fore, the air pollution dosage (time integral of  concentration) at  these
station sites may not necessarily be higher  during weekends  than weekdays.
      Table  2.2 presents the summary of weekday-weekend difference 1n N0?
 air quality at each monitoring station.  It can  be seen  that  the  great
 majority of stations have a lower percentage of  days exceeded and a
 shorter rcean duration of California one-hour standard violations
 during weekends than weekdays.  Therefore,   the  N02 air quality at these
 station sites is better during weekends than weekdays.   However,  at the
 three stations in Costa Mesa, Riverside-Magnolia, and Whittier, the  oppo-
 site is true.  The N02 air quality at these three stations  is  worse  during
 weekends than weekdays.

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                                   21
     Referring to Figure 2.2 which shows  the location of each  monitoring
station, we can get a rough picture of the spatial  distribution of pollutant
levels.  Oxidant air pollution exceeded the NAAQS more than 30% of days  on
both weekdays and weekends at Noroco-Prado Park,  Riverside (two stations),
San Bernardino, Upland, L.A. Downtown, Azusa, Burbank, Reseda, Pomona,
Newhall, and Pasadena.  All of these stations are located in the Los Angeles
Downtown area or further inland.   In contrast, stations such as
Costa Mesa, El Toro, Long Beach,  and Lennox which exceeded the NAAQS less
than 20% of days over both weekdays and weekends  are all located near the
coast.
     For N02, the stations in commercial  or industrial centers (L.A. down-
town, Burbank, West L.A., Long Beach, and Lennox) exceeded the CAAQS more
than 5% of days during weekdays but far less frequently during weekends.
Stations distant from the Los Angeles CBD (El Toro, Norco Prado Park, Riverside-
Rubidoux, San Bernardino, Redlands, Chino, Upland,  Camarillo,  and Newhall)
exceeded the CAAQS less than 1% of days over both weekdays and weekends.
2.3  INTERFACING POPULATION AND AIR QUALITY DATA
     The task of interfacing the population data  and the air quality data
starts with a search for a proper regional map on which the monitoring sta-
tions and the receptor points can be located.  A  receptor point is used to
aggregate the local populations in the areas in which they reside.  For the
Los Angeles AQCR, a regional map showing the boundaries of the Regional
Statistical Areas (RSA's) was available (Fig. 2.4).  A number  of receptor
points were assigned to each RSA according to the size of the  population

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                                   22
and the land area.   The criteria used for  determining  the  number  of  recep-
tor points assigned to each RSA is  as follows:
     1.  Regardless of the size of  the population and/or the land area,
         each RSA is represented by at least one  receptor  point.
     2.  An additional receptor point is assigned for  each increment of
         200 square miles or each increment of  a  resident  population of
         200,000.
For example, an RSA having a resident population  of 500,000 and a land
area of 70 square miles is represented by  three receptor points (one for
RSA and two for population of 400,000), while another  RSA  having  a popula-
tion of 150,000 and an area of 300  square  miles is represented by two recep-
tor points (one for RSA and one for land area of  200 square miles).
     The number of people at each receptor point  is computed in the  following
manner:  The total  population or the total employment  in each RSA is computed
by making a linear interpolation between the SCAG estimates for two  time
points.  For the study year 1973, the interpolation is made of 1970  and 1975
data.  The number arrived at by interpolation is  divided by the number of re-
ceptor points in that RSA and the result  is assigned to each receptor point.
For subpopulations such as workers and non-workers population, the number of
people of a given subpopulation at each receptor  point are given by  the pro-
duct of (total population) x (percent of subpopulation) where the percentage
is computed from the 1970 census data for  the RSA to which the receptor point
belongs.
     A diagram showing how to create a demographic network is given  in Fig-
ure 2. 8.   First, the regional map of RSA's prepared by SCAG is copied by

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                      23
       SEARCH  FOR  POPULATION DATA AND REGIONAL MAP
 POPULATION  DATA
 AGGREGATED  INTO
 RSA's
 ADDITIONAL DEMOGRAPHIC
 DATA AGGREGATED  INTO
 RSA's THROUGH  PRO-
 CESSING THE CENSUS
 DATA
 CREATE THE POPULATION
 DATA SET FOR RSA's
 ASSIGN THE NUMBER OF
 RECEPTORS TO EACH RSA
 ACCORDING TO SOME RE-
 CEPTOR PLACEMENT CRI-
 TERIA
 CREATE THE POPULATION
 DATA SET FOR RECEPTORS
MAP OF REGIONAL
STATISTICAL
AREAS (RSA)
DIGITIZE THE
BOUNDARIES
OF RSA's
PLACE THE MONI-
TORING STATIONS
ON THE MAP
PLACE THE RECEPTOR
POINTS ON THE MAP
DETERMINE THE GEO-
GRAPHICAL BCUNDARY
OF THE STUDY AREA
              PREPARE THE  COMPUTER-READY  DATA
              SETS OF POPULATION,  AIR QUALITY,
              MONITOR LOCATION  AND RECEPTOR
              LOCATION
Figure 2.8.    Diagram of Creating  a  Demographic Network
              for Metropolitan  Los Angeles  AQCR.

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                                  24
using a digitizer.   Using the UTM coordinates given in SAROAD  format or the
site addresses (Appendix C, Table Cl)  the air monitoring stations  are located
on the digitized map through a coordinate transformation  (Fig. 2.2).  In
order to determine a scale factor for the coordinate transformation, the
locations of  the Los Angeles Downtown station and the Azusa station are
determined from their site addresses.   The receptor points are located at
their proper  places within the corresponding RSA.  The receptor locations
are  shown in  Figure 2.9;  their coordinates are found in Appendix C,
Table C2.
     Next, we need  to determine  the exposure of a  person to air pollution.
Thus,  the spatial location of the person  and the air  quality of his  location
must be  known as a  function  of time.  In  the present  study, however, we are
not interested in the actual  exposures  of an individual  person to air  pollu-
tion,  but rather we are interested  in the ensemble of potential exposures
of a large  population,  say 10,000 people.   For  this purpose,  an appropriate
 estimate of air quality at each  receptor point  should be sufficient to make
 an estimate of population exposure  at that particular locale,  if  the assump-
 tion is  made that  the  population size and sub-population composition will
 be quasi-stationary over a year. This  assumption  should be good  for the
 analysis of exposure of part of the population such as elderly and school-
 age populations because these populations tend to be locationally fixed,
 i.e., most school-age  children and elderly people stay close to their
 resident locations most of the time.
      However, the above assumption  would not hold for the other portions
 of  the population, particularly the All Workers population because a large

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                                                                                                                               IN;
                           figure 2.9.   LOCATIONS OF THE 99 RECEPTOR  POINTS  ASSIGNED TO THE STUDY REGION

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                                 26
percentage of that population spends a substantial  part of their time at
their working places where the air environment may  be quite different from
that of their residential locations.  Therefore,  a  special analysis has
been performed for the 1973 air quality data and  the population data.  The
All Workers population data are aggregated  into each RSA:  (1) by their
residence locations and (2) by their working places. The air quality data
are classified by time categories;  (1) non-working time and (2) working
time (weekday 7 A.M. to 6 P.M.).
     As mentioned earlier,  the spatially distributed population  is aggregated
at each receptor  point.   The air  quality at a receptor point  was  estimated by
interpolating the observed  air quality at  the three nearest neighboring moni-
                                4
toring stations to that  point as
                                                                     (2.1)
where C^ is the concentration estimated at j-th receptor point  (x-,y.)»
       J                                                         J   J
C.j(i=l,2,3) are the concentrations observed at the three nearest neighboring
stations, i-th (i=l,2,3) air monitoring stations  (x.) around the j-th  recep-
tor point, and d. is the distance between the i-th monitoring station  and the
j-th receptor point, i.e.,
                                           (y. - y..)

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                                  27
     3.   WEEKDAY-WEEKEND DIFFERENCE IN  AIR QUALITY  AND POPULATION  EXPOSURE

     It is very costly to test the effectiveness of various  oxidant control
strategies on real-world photochemical  air pollution by imposing additional
emission controls.  One possible way of assessing the impact of emission
changes on levels of the two major photochemical pollutants, QX and N02
prior to the imposition of additional controls is to examine the weekday-
weekend differences in air quality of the two pollutants and relate them
to the weekday-weekend differences in the level of precursor pollutant emis-
sions.  If enough weekdays and weekends are examined so that net meteorologi-
cal differences between weekday and weekend are minimized, it should be possible
to assess what impact the different levels of precursor emissions has had
on absolute levels and spatial patterns of ambient QX and N02.
      In this report, the weekday-weekend differences in air quality are studied
by examining the  frequency of violations of the air quality standards at each
of the  99 receptor points whose  locations  are  shown  in  Figure  2.9.  Using the
local  population  size  assigned  to each  receptor point,  the weekday-weekend
difference in  population exposure to the  two  pollutants is  thereby  examined.
In order  to determine  how often  the NAAQS for Ox and the CAAQS for  N02 were  vio-
lated at  various  parts of the Los  Angeles  Basin, the  percentile concentration
distributions  of  hourly concentrations  and daily maximum hourly concentrations
for 0  and N09 were computed  from the original  hourly concentration data fur-
      X       £
nished  by the  California Air  Resources  Board.   These percentile concentration
statistics are presented in Appendix B  (Tables  Bl  through B4), which  show that
the percentile concentrations for all  time, weekdays, and weekends  are used

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                                   28
for the analysis of weekday-weekend difference in air quality and popula-
tion exposure.  The percentile concentrations for working  time,  non-working
time, and weekday non-working time were prepared for studying the effect of
diurnal population mobility.
     Comparing the percentile concentration at each receptor point  to the
air quality standard  (NAAQS for DX and CAAQS for N02),  the frequency of vio-
lations of the standard  (hereafter termed "risk frequency") is  determined by
the percentile concentration which equals the air quality  standard.   If
the  standard  falls  between  two  percentile  concentrations,  the  logarithm of the
percentile  is determined by linear  interpolation  of the corresponding con-
centation values.   From hourly  concentrations,  the percentage  of hours
that the standard  is  violated (hereafter termed "hourly risk frequency")
is computed.   Similarly, the percentage of days that the standard is
violated  (hereafter termed  "daily risk frequency") is computed from daily
maximum hourly concentrations.   Using hourly risk frequency and daily  risk
frequency,  the average number of hours per day that the standard is violated
on days with  standard violations (hereafter termed "mean  duration") is also
computed  at each receptor point.  A more exact definition of each term
 used in this  report is given in Appendix D.
 3.1    Weekday-Weekend Difference in CL
-^—^^—^^^——^^^^^^^"j^™^™™*^"^™*™^"^™™"™^"™™^^^™™~"™—"•™^"^"—™™^™~y^
      The spatial variation of Ov air quality over  the  Los Angeles  AQCR is
                                A
 shown in Figure 3.1  in terms of the percent of days on which the NAAQS is
 exceeded.  It can be seen  that in the coastal areas, the  NAAQS  was  vio-
 lated about  10% of the days or about 37 days per year  while in  the  inland

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     30
i
                                                                                                                ro
                                                                                                                10
       Figure 3.1.  ISOPLETHS of percent of days on which the NAAQS for oxidant was exceeded in 1973.

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                                   30
areas it was violated as many as 50% of the days  or 183 days  per year.
Figure 3.2 shows isopleths of the average duration in hours per day on
those days with the NAAQS violations.  In the coastal areas the average
duration was about three hours per day while in the inland areas it was
longer than five hours per day.  From these two figures, we can compute
the approximate number of hours the NAAQS was exceeded in 1973 at various
locations.  For example, in the coastal areas, the number of hours exceeded
should be approximately (37 days/year) x (3 hours/day) =111  hours per year
while in the inland areas it should be 183 x 5 - 915 hours per year.
     The  spatial  distribution  of Ov  air quality during weekdays and that
                                  A
during weekends were  determined by computing  the  percent  of days exceeded
during each period.   Then, subtracting the percent of days exceeded during
weekends  from  that during weekdays,  Figure 3.3 was obtained to  show the
weekday-weekend difference in  air quality  in  terms of the frequency of NAAQS
violations.  It is seen  that  the coastal region has  a negative  value indi-
cating poorer  air quality during weekends  than weekdays,  and that  the  inland
region has  a positive value  indicating a better air  quality during weekends
than weekdays.  A ridge  on which there is  no  difference  in air  quality be-
tween weekdays  and weekends  divides  the Los Angeles  AQCR  into  the  above  two
regions.  The  ridge runs  along the Santa Monica Mountains to the Los Angeles
CBD,  and  along  the Santa Ana  Mountains that separate Orange County and
Riverside County.   These results are consistent with previous  reports  about
the weekend effect on Ov air pollution.5»6»7'8

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                                                                                                          co
Figure 3.2  ISOPLETHS of mean duration (hours) on days when the NAAQS for oxidant
            was exceeded in 1973.

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                                                                                                              ro
Figure 3.3.  The difference in percent of the number of days  on which  the  NAAQS  for oxidant
             was exceeded in 1973,  weekday minus  weekend.   (Dark  line  equals  zero  percent.)

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                                  33
     Noting that the National  Ambient Air Quality Standards (NAAQS) have
been set to protect the public health, the percent of time (days or hours)
the NAAQS for 0  was violated would be indicative of the state of air quality
               A
to which the public is  exposed.  The people in the Los Angeles AQCR, there-
fore, are stratified according to the frequency of the NAAQS violations.
 Figure 3.4 shows the  three distributions of the population stratified
 according to the percent of days exceeded during all time, weekday, and
 weekend. It can be seen from the figure that more people incur the most
 frequent as well as the least frequent daily exposure above the NAAQS
 during weekdays than  weekends.  This is because the frequency of Ox ex-
 posure above the NAAQS is more uniform through the Basin on weekends.
 On the average, however, the population in the Los Angeles Basin receives
 1.5 percent less frequent daily exposure above the NAAQS during weekends
 (Table 3.1).
      Figure 3.5 shows the distribution of the population exposed at various
 percents of hours the NAAQS was exceeded during all time, weekday, and week-
 end.  The relations of the three curves are essentially the same as those
 seen in Figure 3.4.  Also recall from Table 2.1 that the average duration
 of 0  exposure is generally less on weekends including the coastal stations.
     A
 Therefore, it can be concluded that although poeple in the coastal areas
 are subjected to a more frequent exposure during weekends than weekdays,
 the population in the Los Angeles Basin on the whole are less frequently
 exposed to a concentration above the NAAQS during weekends than weekdays.
 These findings should be emphasized because the previous reports on the
                                                        c c -i o
 weekend effect have not considered population exposure. f0>/'

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                                              34
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                Figure 3.4  POPULATION EXPOSED TO  DX DAILY MAXIMUM HOURLY  CONCENTRATION

                            ABOVE THE NAAQS AT VARIOUS FREQUENCIES (1  FOR  ALL TIME,

                            2 FOR WEEKDAY, 3  FOR WEEKEND).

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                                             35
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                                    36
Table 3.1  Regionwide Impact of Weekday-Weekend Phenomena on Population
           Exposure to Photochemical  Oxidants.
Time Period
All Time
Weekday
Weekend
Weekday/Weekend
Di f f erence
Percent of Days Exceeded
29.7 (29.4)
30.1 (29.7)
28.6 (28.6)
+1.5 (+1.1)
Percent of Hours Exceeded
6.16 (5.96)
6.31 (6.04)
5.77 (5.77)
+ 0.54 (+0.27)
    (    ):  computed based on the mobile population assumption.

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                                   37
     The regionwide impact of the weekday-weekend phenomena on population
exposure to photochemical oxidants has been determined by computing the pop-
ulation weighted risk frequency for both hourly concentrations and daily
maximum hourly concentrations.  The results are summarized in Table 3.1.
The regional averages of daily risk frequency and hourly risk frequency are,
respectively, 29.7  percent of the days and 6.16 percent of the hours.   In
other words, an average person in the Los Angeles AQCR was exposed in 1973
to a concentration above the NAAQS 109 days per year or 540 hours per year.
     The regional averages of daily risk frequency are 30.1 percent of the
days during weekdays and 28.6 percent of the days during weekends.  The re-
gional averages of hourly risk frequency are 6.31 percent of the hours during
weekdays and 5.77 percent of the hours during weekends.  Therefore, it can  be
said that  in 1973 an average person in the Los Angeles Basin received a less
frequent exposure above the NAAQS during weekends than weekdays by 1.5 per-
cent of the days or by 0.54 percent of the hours.
     Table 3.1 also presents the regional averages of risk frequency,'Which
were computed by considering diurnal population movement between residence
and workplace.  These refined estimates of regional average risk frequency
are close  to but a little less than those based on the static population
assumption., i.e., people are locationally fixed to the place of their resi-
dence.  According to the refined estimates, an average person in the Los Angeles
Basin received less frequent exposure above the NAAQS during weekends than
weekdays by 1.1 percent of the days or by 0.27 percent of the hours.  The de-
tailed method of how to compute population exposure by considering diurnal
population mobility is described in Section 4.

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                                                                                                       00
                                                                                                       00
Figure 3.6  ISOPLETHS of percent of days  on which the California one-hour standard
            for NOp was exceeded in 1973.

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                                  39
3.2    Weekday-Weekend Difference in  NOp
     The spatial  variation of N02 air quality over  the  Los  Angeles AQCR  is
shown in Figure 3.6 in terms of the percentage of days  on which  the  California
Ambient Air Quality Standard (CAAQS)  was  exceeded.   It  can  be  seen from  the
figure that the percentage of days exceeded is the  greatest (about 5% of
days) in the urban core areas consisting  mainly of  Los  Angeles and Long  Beach
Cities and decreases toward the surrounding areas where the CAAQS was ex-
ceeded only 1% of the days or less.   The  spatial  distribution  pattern of the
percentage of days exceeded is somewhat similar to  that of  population den-
sity  (Fig. 2.5) and that of employment density (Fig.  2.6).   This similarity
between NO^ air quality and human activity distribution pattern  would be in-
dicative that H^2 air quality is more strongly affected by  local emissions
than 0  air quality whose spatial distribution pattern  does not  show any
      A
particular resemblance to either the population density pattern  or the em-
ployment density pattern.
     Figure 3.7 shows the spatial variation of the  mean duration of  stan-
dard violations in hours per day.  The longest duration (3.5 hours per day)
occurred at the northern part of Orange County.  It is  interesting to note
that the spatial  pattern of the mean duration shifts  south-eastward  from
that of the percentage of days exceeded.
     Figure 3.8 was prepared  to  show  the  weekday-weekend difference in  air
quality.  The air quality difference  is  expressed  in terms of the  difference
in the percentage of days exceeded during  weekdays and weekends.   It can be
seen from the figure that most of Orange  and  Riverside counties have a  nega-
tive value indicating a poorer air quality during  weekends than weekdays,  and

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Figure 3.7.  ISOPLETHS OF MEAN DURATION  (HOURS)  ON DAYS WHEN THE CALIFORNIA ONE-HOUR STANDARD
             FOR N02 WAS EXCEEDED IN  1973

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Figure 3.8.  THE DIFFERENCE  IN  PERCENT OF  DAYS ON  WHICH THE CALIFORNIA ONE-HOUR STANDARD
             FOR N02 WAS EX(
             ZERO PERCENT.)
FOR N02 WAS EXCEEDED IN 1973,  WEEKDAY MINUS WEEKEND.   (DARK LINE EQUALS

-------
                                  42
that the majority of Ventura, Los Angeles, and San Bernardino counties  have a
positive value indicating a better air quality during weekends  than  weekdays.
     Using the static population assumption, the distribution   of  the population
exposed at various frequencies of standard violations (population-at-risk dis-
tribution)  has  been determined for both N02 hourly average concentrations
and N02 daily maximum hourly concentrations.   Figure 3.9 shows  the  distribu-
tions of the population exposed at various percentages  of days  exceeded
during three time periods; all time, weekdays, and weekends.   It can  be
seen that the entire population is exposed for a smaller percentage of days
during weekends than weekdays.  An average person in the Los Angeles  AQCR
is exposed  to N02 air pollution above the CAAQS 4.4% of the days during
weekdays, and only 2.1% of the days during the weekends (Table 3.2).
     The distribution of  the  population exposed at various percentages of
hours exceeded is shown in Figure 3.10.  Again, the entire population is
exposed for a smaller percentage of hours above the CAAQS during weekends
than weekdays.  Therefore, it can be concluded that people in the Los Angeles
AQCR are less frequently  exposed to a concentration above the CAAQS during
weekends than weekdays because of the markedly better N02 air quality over
weekends.
     The regionwide  impacts  of weekday-weekend  phenomena on population ex-
 posure  to  N02  are summarized in Table 3.2.  The regional averages  of daily
 risk  frequency  and  hourly risk frequency  are, respectively, 3.7 percent  of
 the days  and 0.46 percent of the  hours.   In other words, an average  person
 in the Los Angeles  Basin  was exposed  in  1973  to a concentration above  the
 CAAQS 14 days  per year or 40 hours  per year.   The regional  averages  of

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                                           43
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                                     45
Table 3.2  Regionwide Impact of Weekday-Weekend Phenomena on Population
           Exposure to Nitrogen Dioxide.
Time Period
All Time
Weekday
Weekend
Weekday/Weekend
Di f fere nee
i 	 	 —
Percent of Days Exceeded
3.7 (3.8)
4.4 (4.5)
2.1 (2.1)
t2.3 (+2.4)
Percent of Hours Exceeded
0.46 (0.50)
0.57 (0.63)
0.18 (0.18)
+0.39 (+0.45)
    (    ):  computed based on the mobile population assumption,

-------
                                   46
daily risk frequency are 4.4 percent of the days during weekdays and 2.1 per-
cent of the days during weekends.  The regional averages of hourly risk fre-
quency are 0.57 percent of the hours during weekdays and 0.18 percent of the
hours during weekends.  Therefore, it can be said that in 1973 an average
person in the Los Angeles Basin received a less frequent exposure above the
CAAQS during weekends than weekdays by 2.3 percent of the days or by 0.39
percent of the hours.
     Table 3.2 also presents the regional averages of risk frequency, which
were computed by considering diurnal population movement between residence
and workplace.  The refined estimates of regional average risk frequency
are close to but a little greater than those based on the static population
assumption.  According to the refined estimates, an average person in the
Los Angeles Basin received less  frequent exposure above the CAAQS during
weekends than weekdays by 2.4 percent of the days or by 0.45 percent of the
hours.  The detailed  method for  computing population exposure for a mobile
population  is discussed  in the next  section.
3.3  RELATING WEEKDAY-WEEKEND DIFFERENCE IN EMISSIONS TO AIR QUALITY
     According to a TRW study , auto use on weekends is less than on week-
days in the Los Angeles Basin.   It is estimated that total auto trips de-
crease around 22% on weekends while total VMT (Vehicle Miles Traveled) de-
creases around 30%.   Although a number of unknown factors such as stationary
source contributions and relationships between VMT and emissions are involved,
we can expect similar decreases in emissions of precursor pollutants (hydro-
carbons and oxides  of nitrogen) on weekends.

-------
                                  47
     The reduced levels of precursor pollutant emissions  on  weekends  should
be compared with decreases in population  exposure to QX and  N02 during  week-
ends.  From Table 3.1, population exposure to QX decreases on weekends  by
(1.5/30.1) x 100 = 5.0% in daily risk frequency and (0.54/6.31) x 100  =  8.6%
in hourly risk frequency.  From Table 3.2, population exposure to N02 de-
creases on weekends (2.3/4.4) x 100 = 52% in daily risk frequency and
(0.39/0.57) x 100 = 68% in hourly risk frequency.   Therefore, the decrease
in population exposure to Ox is less than that in precursor  pollutant emis-
sions while that in population exposure to N02 is greater than that in  pre-
cursor pollutant emissions.

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                                  49
       4.  EFFECTS OF DAILY POPULATION MOBILITY ON POPULATION EXPOSURE

     In the preceding sections, the analysis of population exposure to
photochemical air pollution was made based on the static population as-
sumption which assumes that every person stays close to his resident
location.   As mentioned  in Section 2.3,  the static population assumption
should be adequate for quasi-stationary  segments  of the population  such
as elderly and school-age, but would not hold for the working population
because that population  spends a large part of their time at their  working
places where the air environment may be  quite different from that of their
residential locations.
      Therefore,  in  this section,  Worker  population  is  treated as follows:
 Exposure  of  the  population  to  0Y  air  pollution above  the NAAQS during working
                                Ai
 time  (weekdays  from 7 A.M.  to  6 P.M.) occurs  at  their place  of employment
 and exposure during non-working time  (the  rest of the time)  occurs  at  their
 place of residence.   Distribution of  people  exposed at various risk fre-
 quencies  (hereafter termed  "population-at-risk distributions") is  computed
 separately during working time and non-working time.   Population-at-risk
 distribution during all  times  is  then computed from those  during working
 time  and non-working  time.   Population-at-risk distribution for  the non-
 workers population  is computed by using the static population assumption.
 Finally,  the population-at-risk distribution for the  total  population  is
 computed by  combining those of Workers  and Non-Workers.

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                                    50
 4.1   PQPULATIQN-AT-RISK DISTRIBUTION  FOR STATIC AND MOBILE POPULATIONS
      For the mobile population  analysis, the exposure of workers during
 working time is  assumed to  occur  at their place of employment.  For the
 static  population analysis, it  is assumed to occur at their place of residence.
 Therefore,  the difference in the  exposure of the mobile population and the
 static  population occurs during working time only.  Figure 4.1 was prepared to
 show the difference in  0  exposure of Workers during working time at their
                         /\
 residence and at their  work places.  The Worker population at their work place
 was  computed from the employment  statistics prepared by the Southern California
 Association of  Governments  (SCAG)1  (Table Al).  The Workers population at
                                                      2
 their residence was computed  from the 1970  census data  and   SCAG's estimates
 of total population in  1970 and 1975  (Table Al).  It  is seen  from the figure
 that the population exposure  at their work  places is  less  than  that at their
 residences.  Therefore, it can be said with respect  to Ox  air pollution  in  the
 Los Angeles AQCR,  that workers on the whole benefit  by working  at places with
 a cleaner air  environment than they would  have if  they stayed home during
 working  time.
      In  order to obtain the population-at-risk  distribution  for the mobile
 workers  during all  time from those during working time  and non-working time,
 we have  to  go back  to a risk frequency  of an  individual worker, and have to
 compute  the risk frequency  of  that worker during  all  time  from those during
working time and non-working time (Appendix  D).  This  is quite a contrast to
 the static workers whose population-at-risk  distribution during  all time  is
 computed from a  risk frequency during all  time.

-------
o
c
O
£
XJ
O)

1C

(/)



 cu
 o
 O)
 V)
 o
 Q.
 X
 O)
 S-
 
-------
                                     52
     A difficulty arises in computing  the risk frequency of a mobile  worker
during all time from that during working time at his work place and that during
non-working time at his residence.   The  difficulty is caused by the lack of
Information of an individual  worker's  mobility between residence and work place.
Although  we have  information about  the worker population at their  work  place
and their  residence, we do not  have an origin-destination  relationship  that
informs us of each  individual worker's residence  and  work  place.
     To alleviate the  difficulty caused  by the  lack  of  origin-destination  in-
formation, the  hypothesis is employed that exposures of a worker during working
time and  during non-working time are  statistically  independent.  Under  this
hypothesis, the probability density of a worker having  a given  risk frequency
during all time is  given by the convolution of  those  during  working  time and
non-working time as:
                      j
      Prob(R*  = J) = ]T) Prob(R*w yi =  k)Prob(R* T /T  = j - k)     (*-D
                     k=o                        n  n

where R*  is the risk frequency  during all time  T, R*  that  during working time
Tw and R* that during non-working time T  .  The  following relationship exists
between R*, R*, and RJj,

                         R* " RW VT +  R*n VT                     (4"2)

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                                      53
     The population-at-risk distribution for the mobile  workers  analysis
during all time was determined from those during working time  and  non-
working time by using Eqs. (4-1) and (4-2).   The resulting  population-
at-risk distribution during all time (curve 3)  1s compared in Fig. 4.2   with
that for the .static workers   analysis  during all time  (dashed curve),  that
at work places during working time (curve 1), and that  at residence  locations
during non-working time (curve 2).  The results clearly show that irrespective
of the mobile or the static assumption, the greatest exposure of  the Workers
population occurred during working time.  This finding  is consistent with our
understanding that oxidant air pollution is confined to  daylight  hours.  At the
same time, this fact may support the importance of population mobility considera-
tion in a population exposure estimate.  By comparing the population-at-risk
distribution for the mobile population (curve 3) to that for the  static  popu-
lation  (dashed curve) which would have resulted from v/orkers always staying at
their residence locations, some differences are noted.  To highlight the
differences between the two curves, their histograms are shown in Figure 4.2a.
It is seen that fewer members of the mobile workers population are annually sub-
jected  to the most frequent, as well as the least frequent, exposure to 0
                                                                         /\
above the NAAQS than those of the static workers population.
     The influx of workers into the business districts  during working time  is
exhibited in Figure 2.7.  A comparison of this population mobility map and  the
isopleth map of oxidant air quality (Figure 3.6) shows  that the daytime  popula-
tion  moves  from residential areas of the highest 0  concentrations as well  as
                                                   A
of the  lowest 0  concentrations to the business districts where the oxidant

-------
                                                54
o
c:
O)
3
cr
OJ
s_
O)
•4->

-------
                                  55
O)
J=.
•!->

(U

O
JD
(O

 X
o
     20-
5

0)

3
(/)
O
CL
X
CU

00
S-
cu
_i^
s_
o
O)

>>
jQ
to
JZ

2
Q-
    15-
      5-J
               I	
                            Mobile Workers
                     	1
                                         Static Workers  	
                                                    I	
                           6           10          14

                         Percent of hours above  the  NAAQS
                                                               18
         Figure 4.2a   PROBABILITY DENSITY DISTRIBUTION  OF  WORKERS

                       EXPOSED TO HOURLY Ox ABOVE THE  NAAQS

-------
                                      56
air quality is in between the two extremes.  These patterns of workers' daily
mobility would explain the differences observed in the distribution of expo-
sures between the mobile workers analysis  and static workers analysis.
     Although the incorporation of population mobility  consideration into
population exposure analysis has resulted  in  a lower estimate of  population
exposure to 0  than the static population  assumption, the  same  consideration
             A
would result in a less conservative estimate  of population exposure to NCL.   The
reason for this is that the daytime population moves from residential  areas  of
lower NOg concentrations to the business districts where  NO, concentrations  are
 higher.   Therefore,  the population mobility  consideration in population
 exposure analysis  for Los Angeles would be more crucial for N02 and primary
 pollutants such  as  TSP, CO, S02 and hydrocarbons produced in commercial
 districts in identifying  the  population at an extreme  risk than for Ox and
 other secondary  pollutants  such as sulfate,  nitrate and photochemically
 produced aerosols  which are subject to  transport.
      The 0  population-at-risk  distribution  for the mobile total population
           A
 during  all  times was obtained  by  linearly combining those for the mobile workers
 population and the  non-workers  population.   In Figure  4.3 the population-at-risk
 distribution of  the mobile  total  population  (curve 3)  is  compared to that of
 the static total population  (dashed curve).   The comparison shows that the static
 population assumption overestimates the number of people of the Total population
 who were exposed at the highest and the lowest risk frequency but underestimates

-------
                                             57
0)

3

CT

0)
S-
IV
4J
CO
c
<0
                         C5  -  1  STD


                             1  r  flLL WORKERS


                             2  =  NON-WORKERS


                             3  -  MOBILE POPL


                             DflSH - STflTIC P0PL
s_
o


•a
a>

o
CL
X
c
o    _
f-    IT
+J    O
ca


Q.
O
a.


o

c
o
u

£
     o
     o
5             10             15


    Percent of hours  above the NAAQS
                                                                   20
25
        Figure 4.3  POPULATION EXPOSURE TO  OXIDANTS ABOVE THE NAAQS

                    (1 FOR WORKERS,  2  FOR NON-WORKERS,  3 FOR MOBILE

                    TOTAL POPULATION,  and ~  FOR  STATIC TOTAL POPULATION).

-------
                                  58
the number of people who were exposed at a risk frequency 1n the middle  range.
Figure 4.3 also shows that Workers  were  exposed at  a  smaller range of risk
frequency than Non- Workers.
4.2    Significance of Population Mobility in Population Exposure Estimates
     It was shown in the preceding section that incorporation of daily popula-
tion mobility into the analysis improves our estimates of the distribution of
population subjected to different degrees of exposure to air pollution.   However,
in reporting the state of air quality over a given region, it is more  relevant
to know the change of some index from one year to another year  than  to know a
detailed population distribution for different degrees of exposure when  the
latter is difficult to estimate correctly.  Thus, we ask, 1s the static  popu-
lation model adequate for estimating gross indices of population exposure such
as regional average of risk frequency R?
     In computing the regional  average of risk frequency for a mobile popula-
tion, we do not have to have the population-at-risk distribution which  required
a complex computation involving the convolution given by Eqs. (4-1) and (4-2).
The regional average of risk frequency during all time T can be  computed
directly from those during working  time  TW and non-working time  Tn as
                  R(CS) -  TW{RW(CS) + Tn Rn(Cs)>/T                   (4-3)
where "R(CS) is the average risk frequency during all  time,  ^y(Cs)  that during
working time aiio T\ (o^/ c.n&c during iiou-workl ng time.   This was  clone  for  bocu
weekdays and all time.

-------
                                     59
     Using Eq. (4-3), the average risk frequency for the mobile workers popula-
tion during weekdays was computed from that for Workers at their work place
during working time and that for Workers at their residence during weekday
non-work time.  The average risk frequency for the static worker's population
during weekdays was computed from that for Workers at their residence during
working time and that during weekday non-working time.   Similarly, the average
risk frequency for the mobile workers population during all times was computed
from that for Workers at their work place during working time and that for
Workers at their residence during non-working time.  And the average risk
frequency for the static workers during all times was computed from that for
Workers at their residence during working time and that during non-working
time.
     The average exposure of the mobile workers population and that of the
static workers population to QX are given in Table 4.1, while those to N02
are given in Table 4.2.  The average exposure of the mobile total population
and that of the static total population are also given in Tables 4.1 and 4.2.
The average exposure of the Total population Prt (either mobile or static)
                                              Q          -         -..^. . HL ._..._L.
was computed from that of Workers population P., and that of Non-worker
                  R(CS) = {Pw *W(CS) + Pn Rn(Cs)}/PQ                  (4-4)
population Pn by
     Table 4.1 shows that the static population model estimated the average
risk frequencies for Workers population during all times as 5.87 percent of
the total number of hours and 28.8 percent of the total number of days, while

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                                   60
 Table  4.1  Effect of the Consideration of Population Mobility on the
           Estimates of Population Exposure to 0  in the 1973 Study Area.
Time Model
Static
Weekday Mobile
Amount of
Misestimate
Static
All Time Mobile
Amount of
Misestimate
Workers
5.
5.
+0.
5.
5.

+0.
961
53
43
87
57

46
(29
(28
(+1
(29
(28

(+0
• 8)2
.8)
.0)
.0")
.7)

.7)
Total
6.
6.
+0.
6.
5.

+0.
Population
22
04
18
09
96

13
(30.
(29;
(+0.
(29.
(29.

(-1-0.
1)
7)
4)
7)
4)

3)
          1.  Percent of hours above the NAAQS.

          2.  Percent of days above the NAAQS.


Table 4.2  Effect or the Consideration of Population Mobility on the Estimates
           of Population Exposure to N02 in the 1973 Study Area.
Time Model
Static
Weekday Mobile
Amount of
Misestimate
Static
All Time Mobile
Amount of
Misestimate
Workers
0.5943(4.56)4
0.726 (4.92)
-0.132 (-0.36)
0.476 (3.86)
0.570 (4.12)
-0.094 (-0.26)
Total Population
0.572 (4.37)
0.626 (4.55)
-0.054 (-0.18)
0.460 (3.74)
0.499 (3.84)
-0.039 (-0.10)
          3. Percent of hours above the California one-hour standard.
          4. Percent of days above the California one-hour standard.

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                                     61
the mobile population model  as 5.57 percent of the hours  and 27.4 percent of
the days.  For the total  population, the static population model  estimated
the average risk frequencies during all  times as 6.09 percent of the hours and
29.0 percent of the days, while the mobile population model as 5.96 percent
of the hours and 28.9 percent of the days.  The relative  misestimates of the
average risk frequency for Workers population by the static population model
are (0.46/5.57) x 100 = 8.3% in hourly risk frequency and (1.4/27.4) x 100 =
5.1% in daily risk frequency.  These misestimates for Workers population
should be compared to those for the Total population which are (0.13/5.96) x
100 = 2.2% in hourly risk frequency and (0.1/28.9) x 100  = 0.3% in daily
risk frequency.  Therefore it can be said that the relative misestimates for
0  by using the static population model  are less than 9% for Workers
 A
population and less than  3%  for Total  population.
     From Table 4.2, the corresponding relative misestimates for N0£ by the
static population model are  (0.094/0.570) x 100 = 16.5% in hourly risk
frequency and  (0.26/4.12) x 100 = 6.3% in daily risk frequency for Workers
population, and (0.039/0.499)  x 100 = 7.8%  and (0.10/3.84)  x  100  =  2.6%  for
Total  population.   Therefore,  it  can be  said  that the relative misestimates
for N02  by  using  the  static  population model  are  less than  17% for  Workers
population  and 8% for Total  population.
     The above analysis  shows  that  the magnitude of relative  misestimates  by
the static  population model   is  greater  for Workers  population than  Total
population, and for N02  than  Ox.  These  findings  are consistent with our
understanding  that since Workers  population constitutes only  about  40% of

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                                    62
Total population, the effects of diurnal population mobility are less pro-
nounced when considered for the Total population, and that since N02 concen-
trations are highest in business districts, while Ov concentrations are
                                                   A
moderate, the effects of population mobility are more pronounced for N02.
Analytical Errors
     When the mobile population model is applied to estimate population ex-
posure, the air quality data as well as the population data have to be pre-
pared for a number of different time categories.  The generation of the
percentile concentration statistics from each subset of the air quality
data introduce some error in the approximate population-at-risk distributions.
This resulted in small errors in the computations of the population exposure
parameters from each subset of the air quality and the population data.  Let
us compare the numbers appearing in Tables 3.1 and 3.2 with those appearing
in Tables 4.1 and 4.2 which were prepared independently of Tables 3.1 and
3.2.  For example, the average risk frequency of 0Y for the static total
                                                  «
population during weekday is 6.22 percent of hours in Table 4.1 while 6.31 per-
cent of hours in Table 3.1.  The error [6.22-6.31| = 0.09 is caused by sub-
division of the air quality data  iuring weekday into those during working time
and those during weekday non-work time.  This error caused by the air quality
data subdivision should be compared with the error caused by the two different
models, |6.22-6.04]  = 0.18.  The magnitude of the former error reaches as much
as 50% of the latter.
     From the facts described above, the mobile population model which de-
mands far greater amounts of data preparation, processing, and analysis than
does the static population model can be said to be of a limited value in

-------
                                    63
computing the gross indices of population exposure.   However, the population
mobility consideration is critical  for correctly identifying the population-
at-risk, particularly for exposure of Workers population to primary pollutants
which are spatially correlated with employment locations.

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                                    65
                             5.   CONCLUDING  REMARKS

     Population exposure methodology was  developed and applied to analyze the
weekday-weekend effect and the effect  of  diurnal population mobility on popula-
tion exposure estimates for two  photochemical  pollutants, 0₯ and NOo in the
                                                          A       £
Los Angeles Basin.   The following paragraphs summarize the findings and con-
clusions reached in this report.
Population Exposure Methodology
     t     Population  exposure methodology was developed to
           specify local and/or  regional air  quality relative to
           the  standards and  to  quantify population exposure to
           air  pollution.
     e     Two-new parameters, "risk- frequency," and "mean
           duration" were introduced,  and the  method for
           determining  these  parameters from  air quality and
           population  data was developed.
     •     For  each of  the  two    parameters a computer  algorithm
           was  developed to obtain  a distribution function and
           an aggregated index.
     •     The methodology and the  computer algorithms  for
           determining  the population exposure variables for a
           mobile population were developed.
     •     Computer software for  drawing a digitized regional
           map, isopleth map, and cumulative  and density
           distribution charts were developed.

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                                   66
Weekday-Weekend Effects
      •     Spatial analysis of 0  and N0? air quality over the
                                 /\       £
            Los Angeles Basin was performed by (1) computing
            isopleths of daily risk frequency indicating a
            percentage of days on which the standard was exceeded
            and (2) computing isopleths of mean duration
            indicating an average number of hours per day for
            those days with violation of the standard.
      •     For 0 , the coastal region where the standard was
                 J\
            exceeded less than 20% of the days was more polluted
            (by about 3% of the days) during weekends than
            weekdays.  The inland region where the standard was
            exceeded more than 40% of the days was less polluted
            (by about 7% of the days) during weekends than
            weekdays.
      •     On an annual basis the population on the whole is
            exposed to Ox air pollution exceeding the NAAQS on a
            smaller  percentage of ooth hours and days during
            weekends  than weekdays.  Therefore, it can be said
            that  although oxidant concentrations become  higher
            over  weekends than weekdays at some coastal  stations,
            the average exposure of the basinwide population  to Ox
            is  lower on weekends.

-------
                                 67
     •     For N02, the Los Angeles CBD and the surrounding area
           where the California standard was exceeded more than
           4% of the days were less polluted (by about 4% of
           the days) during weekends than weekdays.  Most of the
           Orange county and the Riverside county portion where
           the California standard was exceeded less than 3% of
           the days were more polluted (by about 1% of the days)
           during weekends than weekdays.  This increase in N02
           air pollution over weekends would probably be
           attributed to the v/eekend pleasure drives toward these
           areas.
     •     The population  on the  whole  is  exposed to N02 air
           pollution exceeding the California standard much less
           during weekends than weekdays in both the percentage
           of days and the percentage  of hours.

Effects of Daily Population Mobility on Population  Exposure
      •     Because of the daily population migration from
            residence areas of the worst Ox air pollution as well
            as the least 0  air pollution to the business
                          A
            districts of moderate 0₯ air pollution, fewer workers
                                   A
            are annually subjected to the most frequent as well as

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                        68
the least frequent exposures above the NAAQS than
there would be if they stayed home all the time.
Workers on the whole benefit by receiving less
frequent exposure above the NAAQS at their place of
employment.
Because of the daily population migration from
residence areas of moderate to low N02 air pollution
to the business districts of high N02 air pollution,
most workers receive more frequent exposure above the
California standard at their work places than they
would have if they stayed home all the time.
Population mobility considerations are important for
determining the population-at-risk accurately.  This
is particularly true for the workers  population.
However,  the population mobility  consideration is  not
very critical in  determining the aggregated  indices of
population exposure.

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                                  69


                              REFERENCES


 1.  "Suggested Revision of SCAG Growth Forecast Policy (June 1975), As
    Modified  (December 1975)," Southern California Association of
    Governments, Los Angeles, California, December 1975.

 2.  "Census Tracts," Bureau of the Census, U.S. Department of Commerce,
    Series PHC(l), May 1972.

 3.  "Directory of Air Quality Monitoring Sites—Active in 1973," USEPA,
    OAQPS, EPA-450-2-75-006, March 1975.

 4.  Horie, Y., and A. C. Stern, "Analysis of Population Exposure to Air
    Pollution in New York-New Jersey-Connecticut Tri-State Region," USEPA,
    OAQPS, EPA-450/3-76-027, March 1976.

 5.  California Air Resources Board, "Weekday vs. Weekend Oxidant Concen-
    trations," California Air Quality Data, Vol. 6, No. 3, 1974.

 6.  Elkus, B., and K. R. Wilson, "Air Basin Pollution Response Function:
    The  Weekend Effect," Paper submitted to Science, University of California,
    San  Diego, undated.

 7.  Martinez, E. L.  , and E. L. Meyer, Jr., "Urban-Nonurban Ozone Gradients
    and  Their Significance," Specialty Conference on "Ozone/Oxidants-
    Interactions with the Total Environment," Edited by Air Pollution
    Control Association, pp. 221-233, Dallas, Texas, March 10-12, 1976.

 8.  Cleveland, W. S., T. E. Graedel, B. Kleiner, and J. L. Warner, "Sunday
    and  Workday Variations  in Photochemical Air Pollutants in New Jersey
    and  New York," Science. Vol. 186, pp. 1037-1038, December 13, 1974.

 9.  TRW, "Episode Contingency Plan Development for the Metropolitan Los
    Angeles Air Quality Control Region," Final Report to USEPA Region  IX,
    December  1973.

10.  Parzen, E., "Stochastic Processes," Chapter 1, Holden-Day, San
    Francisco,  1967.

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                      A-l
                   APPENDIX A
DATA ON TOTAL POPULATION, WORKERS BY RESIDENCE, AND WORKERS
           BY EMPLOYMENT LOCATION IN 1973

-------
                           A2
Table Al.
Total Population, Workers by Residence,   and
  Workers by Employment Location in 1973.
RSA Land Area
No. (Sq. Mile)
Ventura Co.
1
2
3
4
5
6
Los Angeles
Co.
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
San Bernardino
Co.
28
29
30
31
32
33
34

919.0
325.0
194.0
137.0
150.0
139.0


92.2
379.0
974.0
678.0
527.0
144.0
39.9
76.5
86.9
74.4
97.1
67.9
95.2
60.6
101.0
120.0
6.2
71.4
146.0
170.0
60.0


236.0
231.0
806.0
9484.0
3034.0
3452.0
2880.0
Total
Population

358
114378
147812
73477
64178
10639


24313
55252
54036
32696
1889
554377
260043
268710
13970
309625
918773
521836
422898
423399
796281
606388
86028
407910
660751
458794
150001


244144
304250
22365
7898
79582
26400
5893
Workers* by
Residence {%)

33.6
39.3
35.7
35.3
38.5
41.2


40.7
37.7
39.3
35.3
34.5
45.0
48.8
39.1
46.1
48.7
48.1
47.4
39.2
41.9
35.8
41.5
44.0
45.0
43.1
38.4
38.9


37.6
34.8
38.6
20.9
31.0
21.1
39.4
Workers by
Employment Location

98
39742
59934
4278
15370
3327


9480
7024
14936
14791
1371
202137
136963
58246
2881
137786
440289
256858
151449
194268
480957
163131
326976
140960
246729
121606
66249


75212
45054
6125
4122
29055
9717
2513

-------
                           A-3
Table AT.  Total Population,  Workers  by Residence,   and
             Workers by Employment Location  in 1973.
RSA
No.
Orange Co.
35
36
37
38
39
40
41
42
43
44
Riverside Co.
45
46
47
48
49
50
51
52
53
54
Imperial Co.
55
Land Area
(Sq. Mile)

28.8
45.6
49.8
62.4
100.0
71.1
101.0
52.2
205.0
90.4

61.1
354.0
289.0
129.0
504.0
238.0
709.0
478.0
347.0
4070.0

4241.0
Total
Population

167859
179490
317642
267211
184327
51876
46988
286413
30956
28439

38989
236657
26006
40472
13414
27540
3561
58977
40546
16476

79747
Workers* by
Residence (%}

38.9
42.7
42.7
38.4
42.5
36.2
37.1
41.4
36.5
19.3

34.6
36.3
22.4
28.3
30.0
31.1
34.6
39.1
39.9
36.8

33.9
Workers by
Employment Location

37579
92794
111836
53574
88399
12756
10338
119225
5680
24253

7587
82241
8009
10511
3082
6203
903
19117
15155
7049

2)937

-------
                                  B-l
                              APPENDIX  B


            AIR QUALITY DATA FOR QX  AND N02 IN


Table Bl   Corrected Ox daily maximum hourly average concentrations in
           1973 (1 for all times, 2 for weekdays, 3 for weekends).

Table B2.  Corrected Ov hourly average concentrations in 1973 (1  for all
           times, 2 for weekdays, 3 for weekends, 4 for working time, 5 for
           non-working time, 6 for weekday non-working time).

Table B3   N09 daily maximum hourly average concentrations for 1973 (1 for
           alf times,  2 for weekdays, 3 for weekends).

Table B4   NO? hourly  average concentrations  in  1973  (1 for all times, 2 for
           weekdays, 3 for weekends, 4  for working time, 5 for non-working
           time,  6  for weekday non-working time).

-------
                                        B-2
        Table Bl.  Corrected Ox daily maximum hourly average concentrations  in  1973
                  (1 for all times,  2 for weekdays, 3 for weekends).   All
                  values in pphm.
                                                 PERCENTILE
HO.   STATION    DBS.
MAX
1
5
25
50
75
1 ANAHEIM
1
2
3
2 A 2 US A
1
2
3 .

361
259
102

365
261
104

26. B
26.2
23. B

46.0
46.0
35.0

20.0
20.0
23.0

35.8
38.4
31 .3

17.6
15.0
19.3

30.0
32.1
29.3

14.
13.
18.

28.
28.
28.

3
B
0

0
B
2

1B.B
10.0
12.2

23.9
••>-? 7
£. •_' . J
24.0

7.
7.
7.

16.
17.
15.

0
0
B

1
B
0

4.0
4 .0
5. a

3.0
3.9
7.4

2.0
2.0
3.0

3.0
3.0
4 .0
3 BURBAHK-PALJ1
i
2
3
365
261
104
29.0
29.0
21.0
23.3
25.6
20.4
20.0
20.3
19.0
13.
17.
18.
0
,3
.0
16.0
16.0
15.0
11.
11.
9.
0
1
4
6.0
6.0
6.0
3.0
3.0
3.0
4 CAMARILLO-PALM
1
2
3
5 COSTA MESA
1
2
3
6 EL TORO
1
2
3
7 LA HABRA
i
2
3
3 LENNOX
i
2
3
9 LONG BEACH
1
-. 2
3
357
255
102

343
252
91

357
256
101

362
260
102

365
261
104

364
261

26.0
26.0
17.0

21.0
21.0
19.0

19.0
19.0
18.0

30.0
30.0
24.0

24.0
24.0
14.0

20.0
20.0
11.0
17.8
21.4
15.8

17.9
16.0
19.0

15.3
13.8
17.4

24.0
23.3
24.0

12.5
11.0
13.4

13.8
16.4
9.7
14.0
14.8
13.3

14.1
14.0
15.7

11 .0
11 .0
12.5

22.0
21 .0
23.3

10.0
10.0
9.6

9.0
9.0
8.0
13
13
11

12
11
13

10
10
10

20
19
23

8
8
8

3
7
8
.0
.0
.3

.3
.8
.8

.0
.B
.3

.0
.0
.0

.1
.3
.2

.0
.0
.0
11.0
11.0
9.2

9.0
9.0
9.B

3.0
7.0
9.0

15.0
15.0
18.2

6.0
6.0
7.0

7.0
6.0
7.0
3.
9.
8.

7.
7.
7.

5.
5.
6.

9
9
3

5
5
6

5
5
6
1
0
0

0
0 •
0

1
0
0

.0
.0
.0

.0
.0
.0

.0
.0
.0
6.0
6.0
6.0

5.0
5. B
5.0

4.0
4.3
4.0

5.0
5.0
5.0

3.0
3.0
4.0

3.0
3.0
4.0
4.B
4.0
4.0

4.0
3.0
4.B

3.0
3.B
3.B

3.0
2.4
3.S

3.0
3.0
3.0

2.0
2.0
3.0
10 L.A. DOWNTOWN
i
2
3
365
261

52.0
52.0
25.0
30.3
31.0
23.7
19.4
19.6
17.3
17
17
17
.0
.0
.0
13.0
13.0
14.0
10
10
10
.0
.0
.0
6.0
6.0
6.0
3.2
3.2
«.E

-------
                                       B-3
     Table Bl  (Continued)
HO.  .STATION   OBS.
MAX
    PERCENTILE
3       5       IB
25
                                                                                75
11 NEWHALL
1 363
2 260
3 103
12 NORCO-PRADO PRK
1 363
2 261
3 102
13 OJAI
1 202
2 143
3 59
14 PASADENA-WALNUT
1 364
2 260
3 104
15 POMONA
1 364
2 263
3 104
16 RESEDA
1 365
2 261
3 104
17 RIVERS I DE-MAGNOL
1 355
2 255
3 100

36
36
32

35
35
26

22
22
16

45
45
30

32
31
32

28
28
22
IA
36
36
27

.0
.0
.0

.0
.0
.0

.0
.0
.0

.0
.0
.0

.0
.0
.0

.0
.0
.0

.0
.0
.0

29.0
29.0
27.6

25.8
25.8
24.3

18.4
19.0
15.6

35.8
37.8
28.1

29.8
28.6
32.0

24.0
24.8
21 .4

30.7
31 .0
27.0

27.0
27.6
22.6

23.0
22.6
23.3

16.0
16.2
14.0

23.0
29.2
27.0

24.8
24.0
25.7

22.0
23.0
20.0

25.0
25.8
23.4

25
26
21

20
20
20

14
15
14

26
25
26

24
23
24

20
20,
13.

23.
24.
23.

.0
.0
.3

.0
.0
.6

.3
.0
.0

.0
.8
.0

.0
.4
.0

.0
.0
.2

0
6
0

22.0
23.0
18. 1

16.0
16.0
16.2

13.0
13.0
12.0

22.0
22.0
22. 0

20.0
20.0
21.0

17.0
17.0
16.0

20.9
21.0
20.0

16.0
17.0
13.0

11.0
12.0
9.0

9.0
9.0
8.0

16.0
16.0
14.0

14. 0
15.0
13.0

13.0
13.0
11.0

15.0
16.0
12.4

6
6
4

6
6
6

6
6
5

8
9
7

7
8
7

6
-j
1"
5

7
7
7

.0
.0
.9

.0
.0
.0

.0
.0
.9

.3
.0
.0

.0
.0
.0

.0
.0
.0

.0
.0
.0

3.0
3.0
3.0

3.0
3.0
3.0

4 .0
4.0
4.0

4.0
4 .B
5.0

3.0
3.0
4.0

3 .0
3.0
3. a

3 . 3
3 .8
4.0
- 18 RIVERS I DE-RUBIDOUX
1 365
2 261
3 104
19 SAN BERNADINO
1 353
2 255
3 98
20 UPLAND-ARE
1 303
2 215
3 38
31
31
26

34.
3S.
34.

51.
51.
36.
.0
.0
.0

0
0
0

0
0
0
27.3
29.6
26.0

28.0
27.8
31 .7

41.8
45.5
35.5
24.0
25.1
23.3

26.0
26.0
25.4

35.0
35.9
34.0
23.
24.
22.

23.
23.
20.

32.
33.
28.
0
0
0

0
6
5

5
9
0
21.0
21.0
19.0

19.0
20.9
17.0

29.0
29.0
26.6
14.0
15.0
12.4

15.0
16.0
11.9

22.0
23.0
19.0
-7
f
3
7

6
7
6

14
15
10
.0
.0
.0

.0
.0
.0

.0
.0
.4
3 .0
3 0
3 8

3 .0
3.0
3.0

5 .2
5 .0
6 . S

-------
                                       B-4
     Table  Bl  (Continued)
                                               PERCENTILE
NO.  STATION    DBS.     MAX      1       3       5       IB      25      50      75
21 WEST L.A.-WSTWOOD
i
2
3
22 UHITTIER
1
2
3
364
260
104

364
263
1B4
39.
39.
16.

23.
28.
27.
Q
a
0

a
G
0
21
22
15

24
23
25
.0
.6
.4

.8
.0
.7
14
15
14

19
18
21
.0
.2
.a

.0
.6
.1
13.
13.
13.

17.
15.
19.
B
B
B

B
4
2
11.
11.
11.

12
12.
16.
B
B
B

B
B
B
8.
8.
8.

8.
8.
8.
0
B
4

B
4
B
5
5
5

5.
5
5
.a
.4
.0

.a
.0
.a
3
3
3

3
3
4
.a
.0
.0

.B
B
.0

-------
                                         B-5
HO.   STATION
Table B2.   Corrected Ox hourly average concentrations in 1973 (1 for all
           times, 2 for weekdays, 3 for weekends, 4 for working time, 5
           for  non-working time, 6 for weekday  non-working time).  All
           values in pphm.                 PERCENTILE

         OBS.     MhX      1       3       5
1Q
1 ANAHEIM
1 8173
2 5823
3 2353
4 2735
5 5438
6 3085
2 AZUSA
1 8162
2 5774
3 2388
4 2671
5 5491
6 3 1 33
3 BURBAHK-PALH
1 8315
2 5923
3 2392
4 2795
5 5520
6 3128
4 CANARILLO-PALH
1 7888
2 5627
3 2261
4 27B4
5 5184
6 2923
1. COSTA HESA
1 7439
2 5359
3 2B80
4 2557
5 4882
fa 2802
6 EL TORO
1 8B37
2 5725
3 2312
4 2720
5 5317
6 3005

26
26
23
26
23
"7

46
46
35
46
35
23

29
29
21
29
21 .
11

26.
26
1 7
26.
17.
14

21 .
21.
19.
21.
19.
14.

19.
19.
18.
19.
18.
9 .

.0
Q
a
.0
. a
.0

B
.B
B
0
.B
B

.B
.0
,B
. B
.B
B

0
B
0
B
B
B

B
B
B
B
B
B

B
B
0
B
B
B

11
11
13
14
9
5

24
25
24
28
20
7

16
16
15
19
12
5

12
12
11
14
9
8

IB
IB
12
12
8
7

8
8
9.
10.
8.
6.

.B
.B
.a
.3
.a
B

.a
.0
.0
.7
.B
.B

.0
.B
.B
.0
.8
.B

.0
.0
.0
.0
.0
.0

.a
.0
.0
.8
.6
.0

.0
.0
.0
.0
.0
B

7
7
"7
ia
6
4

18
•* o
18
23
12
4

13
13
11
i —
.1 J
8
3

9
9
9
11
3
•7

3
7
t
8
3
7
5.

6
6.
6 .
f' .
5
5

.0
.a
a
. a
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.a

.a
.a
.0
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.0
3

0
.0
.a
a
.0
.a

.0
P
. £j
.a
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.0
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.a
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a
.0
a
a
a

i-jj
fa
£,
8
5
3

4 cr
i-J
15
14
20
9
4

IB
11
9
14
6 .
3

8,
9 .
8.
10.
r ,
6.

6
t' ,
7 .
8 .
6 .
5.

5 .
5.
5.
r
5 .
4

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.B
.B
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.B
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.0
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.B
B
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B
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B
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4,
4.
=;
6.
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2

IB.
11.
9.
15.
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7 .
7 .
6.
11 .
4.
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r .
r .
"7
8.
6.
5.

5
5
5
6.
5.
4.

4.
4.
4.
n;
4.
3

.B
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0
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.0
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.B
.0
.B
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.0
a

0
a
.0
.0
0
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0
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i"i
0
B
B

B
B
B
B
B
B

B
0
B
0
B
0

cl .
ci
3
3
1
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4.
4
4
9
2.
•~j
c. .

3 .
3
3 .
to .
9
1.

5.
4.
5.
6.
4.
3.

-.} .
3.
4.
4.
3.
2.

3.
3.
3.
3 .
p
ci .

.B
.0
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a
.0
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.a
.0
.0
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.0
0

.B
B
B
.a
B
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0
B
0
0
0
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a
.0
B
0
B
B

B
B
B
0
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0
0
i
i
i
1
0
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•-.
£.
2
2
•7
1
1

i
1
i
3
i
1

f
£.
•-,
c.
4
c_
2

2
i
•;•
~<
1
B

1
i
1
A
•}
1
i

.a
8
.a
. Li
.a
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,~i
3
LI
.a
.0
.0
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.a
.a
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.a
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.a
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                                                                                   a .a
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                                                                                   a .0
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                                                                                   I  Ll

                                                                                   1 .0

                                                                                   1  Q
                                                                                   i .!
                                                                                   i  s
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                                                                                   i .a
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                                                                                   a  E
                                                                                   a  Q
                                                                                   a  Q

-------
                                  B-6
Table B2  (Continued).
STATION   OBS
                                         PERCENTILE
5
IB
5 a
7 LA HABRA
1 8144
2 5793
3 2346
4 2737
5 5407
6 3361
8 LEHHOK
i 3316
2 5343
3 2373
4 2816
5 55BB
6 o i 27
9 LONG BEACH
i 82B1
2 5856
3 £345
4 2756
5 5445
b 3100
10 L.A. DOWNTOUH
i 8357
2 5933
3 2424
4 2733
5 5624
6 32BS
H NEWHttLL
1 3273
2 5929
3 2344
4 2824
5 5449
6 3105
12 NORCO-PRADO PRK
1 84B8
2 5999
3 24Q1
4 2723
5 5683
6 ?27?

30.
30.
24
3D
2 4
r,
o .

24 .
24
14.
24
14.
IB.

20.
20.
11 .
~i n
c. U
•i >
•L * .
6

52.
52
d j .
52
25
15

36
36
32
36
T -"V
O £-
19

35
35
26
35
26
22

B
a
2
n
i
0

a
a
s
s
B
0

e
0
s
a
B
e

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.0
. a
.a
s

s
0
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a

.a
.a
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a
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0

16
15
i o
19
13
4

-7
i
6
->
•,
8
6
5

•7
7
7
9
6
4

15
15
14
23
12
6

23
•••« -•*
c. *t
20
26
17
10

17
17
17
2B
14
f

.B
.0
.0
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.B
.a

.a
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10.
10.
11 .
13.
7 .
3.

j
tj
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5
5
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5
5
5
o
4
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O

11
ia
11
14
8
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18
19
16
23
12
6

13
13
12
16
8
4

a
a
a
a
u
0

0
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9
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4.
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16
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ia
11
9
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-------
Table B2 (Continued).
                                     B-7
MO. STATION
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-------
                                        B-9
       Table B3.   NO? daily maximum hourly average  concentrations in 1973 (1  for
                  alt times, 2 for weekdays,  3 for  weekends).  All values in  pphm.
NO.
STAilON   OBS.
MAX
PERCENTILE

  5       10
25
50
1 ANAHEIM
1
.-t
c.
3
: AZUSA
i
2
3

329
235
94

361
261
IBB

49
49
35

32
32
22

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33
31
34

29
29
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27

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1
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364
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6 COSTA RESA
i
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7 EL TORO
i
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8 LA HABRA
i
2
3
9 LENNOX
1
2
3
10 LONG BEACH
1
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3
356
254
102

340
247
93

353
259
94

355
255
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356
257
99

363
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101
18
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-------
                                     B-10
H 0
     Table B3 (Continued).
STATION    DBS
PERCENTILE

     5       IS
25
11 L.A. DOyNTOWN
1 353
2 259
3 "54
12 HEWHftLL
i 368
2 263
j IBB
13 NORCO-PRADO PRK
1 352
2 258
3 94
14 OJAI
1 322
2 228
3 94
15 PASADEHA-yALHUT
1 364
2 260
3 184
16 PT. MUGU
1 342
2 244
3 98
17 POMONA
1 365
2 261
3 1E4
IS RESEDA
1 353
2 255
3 98
19 RJVERSIDE-HAGHOL
1 365
2 261
3 184
28 RIVERSIDE-RUBIDO
i 356
2 256
3 100

58.
58.
26.

2B.
20.
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17.
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12.
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33 .
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16.0
12. B

9.8
1B.0
8.B

15.0
16.0
1,1.4

12.B
12.0
11. B

18.0
13. S
8.3

6.0
7.8
5.4

5.3
5.4
4.B

3.0
3.0
3.0

11 .0
12. B
9.0

6.8
6.3
5 3

10.3
11 .0
9.0

7.0
7.9
6.8

10.9
12.8
8.B

9 . 8
9.8
7.0
                                                                            7.0
                                                                            3 .0
                                                                            6.8
                                                                            4.0
                                                                            4 .3
                                                                            4.E
                                                                            4.S
                                                                            4  8
                                                                            3.8
                                                                             2.8
                                                                             2 .8
                                                                             2.8
                                                                             8.8
                                                                             8.9
                                                                             7 .8
                                                                             4 .0
                                                                             4.B
                                                                             3 .g
                                                                             8 .8
                                                                             7  8
                                                                             5.0
                                                                             5.8
                                                                             5  B
                                                                             7  8
                                                                             8.8
                                                                             6  4
                                                                             6 8
                                                                             7.8
                                                                             6 8

-------
Table B3 (Continued).
                                    B-ll
rlO STAlIOH
21 REDLANDS
^
£
3
21 8AH BERNADI
1
c.
3
23 UPLAND-ARB
i
c.
3
24 UPLAND-C1VI
1
i.
2
3
25 yEST L.A.-M
1
d
•j
26 WHITHER
1
2
3
UBS

363
259
104
HO
356
258
98

3B1
215
86
C CTR
297
211
86
STWOOD
358
26B
98

357
258
99
PERCENTILE
n4v 1 3 5

18
18
18.

19.
19,
13,

24
24
18,

36 ,
36.
19.

47.
47.
31.

48.
48.
36

B
B
B

B
. B
.0

.0
B
B

B
B
.B

B
.0
B

. 0
.0
. B

16
16
16

16
16
12

23
23
17

23
24
16

36
39
30

31
29.
33

8
8
. 7

.B
.8
4

.a
.3
.1

.4
.B
•2

8
.4
.4

. i'
.8
6

14
14
13

14
15
11

23
21
15

17
20
12

3B
"^2
25

26
25
28.

.a
6
•3

. B
.a
a

.4
.a
.8

.a
.0
.B

*-t
8
.4

.0
.7
.4

13
13
13

13
14
ia

19
2B
15

15
16
12

28
28
23

23
23
24

.B
.B
.0

.B
.B
5

.B
.B
.B

<=:
.8
.0

.B
.4
.5

.5
,B
.4
i

11
12.
11 .

12
13.
q

17.
18.
13.

13
15.
IB.

22.
24.
19.

2B.
20.
17.
L0

B
.0
.0

B
. 0
.B

B
.0
B

0
B
.0

6
B
.0

.0
B
.0
25

8.
3.
j" .

IB.
IB.
8

13.
14.
11.

IB.
11.
8.

16.
17.
13.

14.
15.
11.

0
B
B

B
B
B

0
0
B

a
0
9

0
0
9

.0
B
B
5B "!

6
6
5

"7
t
8
5

10
12
9

7
7
6

1 1
12
9

i
ia
8

.B
0
. B

.8
.0
0

.0
.0
.B

.0
.0
.B

0
.0
.0

a
0
a

4
4
4

e
5
4

8
8
6

5
5
4

y
3
6

7
g
6

a
LI
F

a
. y
D

n
. 0
'e

£
.a
.0

n
2
. I'

.0
.a
.0

-------
                                    B-12
   Table B4.   NC>2 hourly average concentrations in 1973 (1 for al.l times-, 2 for
              weekdays,.3 for weekends, 4 for working time, 5 for non-working
              time, 6  for weekday non-working time).  All values in pphm.
                                           PERCENTILE
.VfATIOK    DBS
1
10
25
53
I riHAHEIi
.1
-i
-j
&
5
6
2 AZUSH
i
2
3
4
n
6
3 S URBAN
i
C-
3
••?
*?
5
6
-4 C A MAR I
i
c.

4
c
,_{
6
5 CHIHO
1

"f
4
5
vj
6 COSTA
•i
.i
c~

i
't
rr
^.
K
734B
5l8l
v - =•;*
L' 4 4 1
4 8 99
274B

SB 96
p H 3 c
2264
2513
5533
3319
K-PALM
8462
6013
2449
2666
5796
3347
LLQ-PALM
7778
5533
2245
2691
5087
2 y 4 k1

7458
5332
2126
2286
5172
3B46
MESn
7634
5486
2148
2598
^~ H "? • "
•- tj _• _'
i H 8 3

49.
4*
7 ^
4C;
35.
24.

32
V* C .
22 .
32.
31.
31 .

38.
38.
29
38
3 6 .
36 .

18
18
IB.
it
18
H C'
i U

2 ^
2 Cl
22
23
2*
2C1

29
2?
28
V M
CL O
*"• '.~
cl £

B
B
PI
0
S
0

E
B
B
0
0
ti

8
B
S
i
a
B

B
B
. a
. s
8
.0

u
. B
.a
.B
.a
s

a
i3
a
B
.E
0

21 .0
23 B
J tj 3
22. B
21 .B
17.8

20.0
21 .1
16 .0
23.0
19. a
23. a

24.8
26. a
19.3
2 8 . B
21 .0
22. B

8.0
9 B
P.B
9 .3
8.0
9 .a

14. B
is .a
11 .a
is. a
13. a
14 9

17.0
15.0
19.0
16.0
17. a
1 5 0

15 .0
15 .0
13 0
17 .B
14 0
1 ••; £S
i c. . Ll

1 .-; p
i O . i.'
1? B
12 .0
19 0
15.0
16 .0

19 .0
20.0
,5.0
23 3
'! £ '"3
17 0

7.0
7 0
6 . id
7.0
7 .0
7.0

11 .0
11 0
10 .0
11 .0
10.0
11 .0

12. a
il 8
15.0
11 0
13 .0
12.3

12.
12.
12 .
14 .
11 .
10.

14.
15.
11 .
16.
13.
14 .

16 .
17.
12.
20 .
14.
14

6
6
6
6
6
.-•
b

10
10
9
10
9
13

10
10
11
9
~ r?
13

0
B
B
0
0
B

B
B
B
B
B
0

B
0
B
.0
.B
.B

.B
.B
.3
.B
.B
.B

.B
.B
.B
.0
.B
.B

.0
.B
.B
.0
. 3
.B

9.0
9 0
8.0
11.0
8.0
8.0

12.0
12. D
9 B
13. B
11.0
12. a

13. B
14.0
1B.B
16.0
11.0
12. B

5.B
5. B
5.0
5.0
5. 0
5.0

8. 0
8 0
7 B
8.0
8.B
8 0

7. B
7.B
8. B
7.3
7. 0
7.0

6. 0
7.0
6. B
7.0
6.0
6. B

8.0
9. 0
6.3
1B.0
8.B
8.B

9.B
1B.0
7.0
12.0
S 0
8.B

4.0
4.0
3. 0
3.3
4.0
4.B

6.3
6. 0
5.3
6. B
5. a
6.3

4.3
5.3
4.0
4.3
4.3
5.0

4 0
5.8
4 0
5 0
4 .0
4 .0

5 0
6.0
4.3
6 .0
5.0
6.0

6.0
7 0
6.0
8.0
6.0
6.0

2.0
3.0
2.0
2 .0
3.0
3.0

4 *""*
*t K3
4 .0
3.0
4.3
4.3
4.0

2.3
2 B
2.3
2 .0
2.0
3.0

3 0
3 B
3 0
3.0
3.0
3.0

3.0
4 .0
3.0
4 .0
3.3
3.0

4.0
4.3
4.0
5.0
4.0
4.0

1 .0
2.0
1 .0
1 .0
2.0
2.0

3.3
3 .0
2.0
3.0
3.3
3.0

1 .0
1 .0
1 .0
1 .0
1 .0
1 .0

-------
0- b

t! !=
3' £
B S
B b
B £
3' £
B 'i
B £
B' S
       d i
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B 9
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p r
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8
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b
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66£3
S68S
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          9
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                      01
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                                                                 f9
                                     £1-8

-------
Table B4 (Continued).
                                  B-14
NO. STATION
OBS .
HA
X
1
PERCENTILE
3 5
10 .
25
5B
75
13 HORCO-PRADO PRK
1
.-:
C.
3
4
5
6
14 OJAI
1
2
3
4
5
6
3329
5798
2231
2616
5413
3182

7234
5392
2142
2363
4871
2729
17.
17.
1 3
16
17.
17.

12.
12.
IB.
12.
11.
11.
B
B
e
a
B
B

B
B
B
B
B
B
1B.B
ia.a
9.0
IB. a
9.3
IB. a

7.B
7.B
6.B
7.0
6.B
7.0
7.0
3 .a
7. a
s. a
7.0
s. a

5 B
5. a
5. a
5.0
5 a
5.0
7.
7 .
6.
7
k.
7.

4 .
5.
4.
4.
5.
5.
B
B
0
a
a
0

e
a
a
e
0
B
5.B
6. a
5.0
5. B
5.0
6.B

4.B
4.0
4.B
3.1
4.0
4.0
4.0
4.3
3.0
4.3
4.0
4.B

3.0
3.0
2. a
2.0
3.0
3.0
2.0
2.3
2.0
2. 8
2.0
3. B

2.0
2.3
2.0
2. a
2.3
2.0
2.3
2.2
1 .3
2.3
i .a
2.0

1 .0
1 .3
1 .3
1 .0
1 .0
1 .0
15 PASADEHA-WALNUT
1
2
3
4
5
6
16 , P'T. HUGU
4
•*J
C.
%™i
4
5
6
1? POMONA
i
-i
i
3
4
5
6
18 RESEDA
1
2
7
4
KT
fa
8394
5935
2459
26 IB
5784
3325

7317
5184
2133
232B
4997
2864

8353
5961
2392
2578
5783
3391

8063
58B9
2254
2598
5465
3211
33.
33.
20.
33.
30.
30.

33.
33.
14.
33.
16.
16,

36
36
24
36
33
33

19
19
15
19
19
19
B
B
B
B
B
B

B
B
B
.0
.0
2

,B
.B
.B
.B
.0
.a

.a
.a
.B
. a
. B
.3
20. a
21 .a
14.0
23. a
is. a
2B.0

12.0
12.6
9 .3
14 .0
13.0
ii .a

20.0
21 .0
18.0
21 .a
28.0
2B.5

12. B
13. 8
10.0
13. a
12 a
12.0
16.0
17.0
ii B
18.0
14.0
16.0

9.3
1B.0
8.0
11 .a
3.0
9 .a

16.0
17.0
14.0
17.3
16.0
17 .0

10. B
10.0
9.0
11 .0
10.0
10.0
14.
15.
10 .
16.
13.
14.

8
8
7
9
7
8

15
15
12
16
14
15

9
9
8
9
9
9
0
s
.e
B
a
a

.0
.0
.s
.0
.B
.0

.0
.a
.a
.a
.s
.a

.a
.a
.0
.a
.0
.0
12.0
13.0
9.0
14. B
ii. a
12.0

6. a
7.0
5.B
7.0
6. 0
6.0

12. a
13.0
13. B
13.0
11. B
12.0

3.0
8.B
7.0
8.0
7.B
8.B
9.S
1S.B
7.B
13. B
8.B
9.0

4.B
5.0
4.B
4.B
4.0
5.B

9.0
10. B
7.0
10. 3
8.0
9.0

6.0
6.0
5.0
5.0
6.0
6.0
6. a
7. a
6.0
8.8
6.0
7.0

2.0
2.0
2.0
2.0
2.0
3.0

6.0
7.0
6.0
7.3
6.0
7.0

4.B
4. 3
4.0
4.0
4.8
4.3
4.3
5.0
4.0
5.8
4.3
5.3

1 .3
1 .3
1 .0
1 .3
i .3
1 .3

5.3
5.0
4.3
5.8
4.0
5.3

3.3
3.0
2.3
2.8
3.8
3.0

-------
 Table B4  (Continued).
               B-15
                                          PERCENTILE
.TttilON    088
I"- H rt
10
--I C
C- w
19 RIVERSIDE-MAGNOL
1
CL
3
4
c:
.j
b
2E RIVERSIDE-
-i
cL
"7
4
P,
6
21 REDLANDS
I
•"r
C.
3
4
5
6
22, SAN BERNAD
4
I
^
3
4
5
6
23 UPLAHO-AR8
4
I
cl
3
4
5
6
24 UPLAND-CIV
1
cl
3
4
rr
•_>
6
8506
6054
2452
2bbb
5848
3388
RUB1DO
7545
5345
2208
2565
4388
~i ~? A n
c. f oa

85B9
6B31
2478
2743
5766
3288
1NO
748B
5413
2B67
222Q
526B
31-33

6371
4495
1876
2157
4214
2338
1C CTR
6568
4575
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18.
18.
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24.
24
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36.
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-------
                                       B-16
        Table  B4  (Continued).

                                              PERCENTILE


HO.   STATION    DBS.     MAX      1       3       5       10      25      5B      75
25 WEST L.A,
i
2
3
4
5
6
26 WHITTIER
i
2
3
4
5
6
-i-JSTUOOD
8207
59 38
2299
2685
5598
3299

8364
5775
2289
2491
5573
3284
47.
47.
31.
47.
31.
31.

48.
48.
36
48
36
29
B
e
e
e
a
B

B
3
.a
.B
.0
.B
23
24
19
28
19
18

23
21
2B
22
19
18
.B
.E
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.B
.B
.B

.8
.a
.8
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.7
.6
18.
18.
15.
22,
15
15

16
16
15
18
15
14
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.B

.a
.a
.B
.a
.a
.a
15.
16.
14.
19.
13
13

14
14
13
16
13
13
,B
.B
B
,B
.B
.B

.B
.B
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12.
13.
11.
15.
11.
11.

11.
12.
IB.
13.
IB
IB
B
B
B
B
B
B

B
B
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.B
.B
.B
3
9
8
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8
8

8
8
7
9
7
8
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.B
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6,
6 ,
6
7
6
6

6
6
5
6
5
6
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.a
.a
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.a
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4. a
4. a
4.8
5.B
4.B
4.3

4 .3
4.S
4 .8
5.B
4. 8
4. B

-------
                                   C-l
                              APPENDIX C
                  MONITORING  STATIONS AND  RECEPTOR  POINTS

Table Cl.   Locations and addresses  of Air  Monitoring  Stations,
Table C2.   Receptor points assigned to  the Los  Angeles  AQCR.

-------
                            C-2
Table Cl.   Locations and Addresses  of  Air  Monitoring  Stations

1. Anaheim #050230001101 (30176)
1010 S. Harbor Blvd., Anaheim, Orange County
2. Azusa #050500002101 (70060)
803 Loren Ave., Azusa, Los Angeles County
3. Burbank #050900002101 (70069)
228 W. Palm, Burbank, Los Angeles Bounty
4. Camarillo- #051030001101 (56408)
Palm
70 Palm Drive, Camarillo, Ventura County
5. Chino-River- #051300001101 (36173)
side Ave.
Central & Riverside, Chino, San Bernardino Cty.
6. Costa Mesa- #052390001101 (30186)
Harbor
2631 Harbor Blvd., Costa Mesa, Orange County
7. El Toro #052390001101 (30186)
3022 El Toro Rd., El Toro, Ora.ige County
8. La Habra #053620001101(30177)
621 W. Lambert, La Habra, Orange County
9. Lennox #053900001101 (70076)
11408 La Cienega Blvd., Lennox, LA County
10. Long Beach #054100002101 (70072)
3648 N. Long Beach Blvd., Long Beach, LA Cty.
11. L.A. Down- #054180001101 (70001)
town
434 S. San Pedro St., Los Angeles County
UTM
N = 3,742,467
E = 415,477
N = 3,777,371
E = 414,892
N = 3,782,904
E = 379,353
N = 3,787,765
E = 312,275
N = 3,760,145
E = 436,087
N = 3,721,444
E = 414,449
N = 3,716,916
E = 436,027
N = 3,753,372
E = 411,824
N = 3,755,070
E = 373,477
N = 3,743,190
E = 390,007
N = 3,767,650
E = 385,310
X-Y Coord.
Y = 1340
X = 1824
Y = 1634
X = 1819
Y = 1681
X = 1520
Y = 1722
X = 954
Y = 1489
X = 1998
Y = 1124
X = 1998
Y = 1124
X = 1998
Y = 1432
X = 1794
Y = 1446
X = 1470
Y = 1346
X = 1610
Y = 1552
X = 1570

-------
                                   C-3
Table Cl (Continued).

12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
Newhall #055120001101 (70081)
24811 San Fernando Rd., Newhall , LA Cty.
Norco-Prado #055160001101 (33140)
Park
8850 Archibald Ave., Norco, Riverside Cty.
Ojai #055340001101 (56402)
401 Signal Hill St., Ojai, Ventura Cty.
Pasadena- #05570004101 (70083)
Walnut
1196 E. Walnut St., Pasadena, LA County
Point Mugu #056030001101 (56(409)
Naval Air Station, Ventura County
Pomona #056040001101 (70075)
924 N. Garey Ave., Pomona, LA County
Redlands #056200001101 (36165)
216 Brookside Ave., Redlands, San Bernardino
County
Reseda #054200001101 (70074)
18330 Gault St., Reseda, Los Angeles County
Riverside- #056400003F01 (33146)
Magnolia
9002 Magnolia Ave., Riverside, Riverside Cty
Riverside- #056535001101 (33144)
Rubidoux
5888 Mission Blvd., Rubidoux, Riverside Cty.
UTM
N = 3,805,831
E = 359,188
N - 3,756,446
E = 445,122
N = 3,813,704
E = 293,772
N = 3,779,120
E = 396,420

N = 3,767,844
E = 430,882
N = 3,768,069
E = 482,902
N « 3,785,129
E = 358,851
N = 3,751,835
E = 463,036
N = 3,757,641
E = 462,161
X-Y Coord.
Y = 1874
X - 1350
Y = 1458
X = 2074
Y = 1940
X = 798
Y = 1649
X - 1664
Y = 1630
X = 933
Y = 1554
X = 1900
Y = 1556
X = 2393
Y = 1699
X = 1347
Y = 1419
X = 2225
Y - 1468
X = 2218

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                                    C-4
Table Cl (Continued).

22. San Bernardino #056680001101 (36151)
172 W. 3rd St., San Bernardino, S.B. Cty.
23. Upland-Civic #058440003101 (36174)
Center
155 D Street, Upland, San Bernardino Cty.
24. Upland-ARB #058440004F01 (36175)
1350 San Bernardino Rd., Upland, s.B. Cty.
25. West L. A. #054180002101(70071)
2351 Westwood Blvd., Los Angeles County
26. Whittier #058720001101 (70080)
14427 Leffingwell Rd., Whittier, LA Cty.
UTM
N « 3,773,634
E = 473,637
N = 3,768,863
E = 440,989
N = 3,769,410
E = 442,043
N = 3,767,403
E = 368,178
N = 3,754,019
E = 405,436
X-Y Coord.
Y = 1602
X = 2315
Y = 1562
X = 2039
Y = 1567
X * 2048
Y « 1550
X = 1426
Y = 1437
X = 1740

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                            C-5
Table C2.  Receptor Points Assigned to the Los Angeles AQCR
No.
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
County
Los Angeles
Los Angeles
ii
it
Los Angeles
n
Los Angeles
n
Los Angeles
Los Angeles
n
Los Angeles
n
n
n
n
Los Angeles
n
ii
Los Angeles
n
Los Angeles
Los Angeles
n
H
Los Angeles
n
n
n
n
RSA #
7
12
12
12
13
13
14
14
15
16
16
17
17
17
17
17
18
18
18
19
19
19
20
20
20
21
21
21
21
21
Code #
2071
2121
2122
2123
2131
2132
2141
2142
2151
2161
2162
2171
2172
2173
2174
2175
2181
2182
2183
2191
2192
2193
2201
2202
2203
2211
2212
2213
2214
2215
X-Coord.
1285
1361
1351
1400
1485
1521
1421
1510
1221
1380
1430
1521
1521
1521
1480
1480
1521
1475
1500
1505
1505
1545
1595
1650
1625
1565
1565
1565
1610
1610
Y-Coord.
1610
1670
1720
1630
1645
1650
1730
1710
1550
1570
1465
1510
1550
1590
1530
1580
1440
1460
1410
1320
1365
1350
1330
1320
1390
1420
1470
1520
1520
1470

-------
Table C2 (Continued).
                                     C-6
No.
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
County
Los Angeles
ii
it
Los Angeles
Los Angeles
H
ii
I is Angeles
it
n
n
Los Angeles
Los Angeles
n
Los Angeles
Orange
Orange
Orange
n
Orange
n
Orange
Orange
n
San Bernardino
n
San Bernardino
n
Ventura
n
RSA =
22
22
22
23
24
24
24
25
25
25
25
26
26
26
27
35 .
36
37
37
38
Code #
2221
2222
2223
2231
2241
2242
2243
2251
2252
2253
2254
2261
2262
2263
2271
3351
3361
3371
3372
3381
38 I 3382
41
42
42
28
28
29
29
1
1
3411
3421
3422
4281
4282
4291
4292
1011
1012
X-Coord.
1660
1690
1725 .-
1555
1561
1561
1595
1641
1660
1710
1730
1765
1810
1840
"1900
1710
1800
1765
1785
1708
1750
1911
1825
1840
1960
2000
2190
2335
860
1125
Y-Coord.
1420
1480
1435 '
1545
1585
1640
1595
16?5
1560
1555
1620
1520
1595
1500
1580
1355
1410 '
1320
• 1355
1280
1250
. 1390'
1285
1335
1490
1590
1625 .
1555
1960
2050

-------
Table C2 (Continued),
                                     C-7
No.
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
County
Ventura
ii
it •
Ventura
ii
Ventura
Ventura
Vpntura
Ventura
Los Angeles
ii
Los Angeles
ii
ii
ii
Los Angeles
ii
ii
Orange
Orange
Orange
H
Orange
San Bernardino
H
H
M
H
Riverside
RSA =
1
1
1
2
2
3
4
5
6
8
8
10
10
10.
10
11
11
11
39
40
43
43
44
30
30
30
30
30
45
Code #
1013
1014
1015
1021
1022
1031
1041
1051
1061
2081
2082
2101
2102
2103
2104
2111
2112
2113
3391
3401
3431
3432
3441
4301
4302
4303
4304
4305
5451
X-Coord.
1040.
941
1185 •
940
940
1010
1235
1135
1185
1410
1348
1550
1641
1757
1880
1610
1732
1860 '
1855
1970
2028
2035
1915
2055
2260
2430
2473
2350
2070
Y-Coord.
2005
2115
1935
1745
1870
1675
1740
1645
1835
1935
1855
1878
1950
1895
1865
1750
1710 "
1728
1160
1052
1155
1240
1250
1725
1713
1740
' 1630 •
1650
. 1515

-------
Table C2 (Continued),
                                     C-8
No.
90
91
92.
93
94
95
96
97
98
99
County
Riverside
n
Riverside
n
Riverside
Riverside
n
n
Riverside
ii
RSA $
46
46
47
47
48
49
49
49
50
50
Code t
5461
5462
5471
5472
5481
5491
5492
5493
.5501
5502
X-Coord.
2095
2170'
2280
2330
2455
2185
2273
2395
2430
2475
•
Y-Coord.
1380
1460
1360
1277
1310
1210
1110
1155
14«0
1430

-------
             D-1
        APPENDIX D

METHODOLOGY TO CHARACTERIZE
    POPULATION EXPOSURE

-------
                                   D-2
 FORMULATION OF POPULATION EXPOSURE PARAMETERS

     Suppose a person stays at a place where the air quality is continuously
monitored.  Then, the pollution "dose" of that person over a time period T
             u 1
can be given by
DOSE
                                    = f C(t)  dt                     (D_1)
where C(t) is the concentration reading at time t.  A pollutant concentration
is usually measured at a constant time interval, say, every hour.  Monitored
concentrations are often sorted in ascending order and summarized in percen-
tile concentration statistics.  In this case, Eq. (D-l) reduces to
                                      1
                              DOSE =jf C(f) df                      (D.2)
                                     o
where C(f) is the concentration at the f   percentile.
     From the quantities in Eq. (D-2) we will derive the three exposure param-
eters; "dose rate," "risk frequency," and "mean duration."  The dose rate  is
the average concentration with respect to a subject person and is given, for
the above example, as
                                    1
                               D = f C(f) df                        (D-3)
                                   o
Namely,  the  dose  rate  is equal to the  arithmetic mean concentration averaged
over the time  period T,  i.e., a year in this study.  The risk frequency  is  the

-------
                                    D-3
percentage of time  that a  subject person is exposed to a concentration above
                                  2
a given concentration threshold C>
                               R(CS) = 1 - fs                        (D-4)
 where f  is the percentile given by a  solution  to C(f) = Cs-  The mean  dura-
 tion can be determined when the percentile  concentration statistics are  available
 for both hourly average concentrations and  daily maximum hourly average  concen-
 trations.  It  is given by

                               T - 24 RhoUr'Rday

 where Ru    is  the  risk frequency  for  hourly  average  concentrations  (hourly
 risk frequency) and Rd   the  risk  frequency for daily maximum hourly  average
 concentrations  (daily risk frequency).
      In the real world each  individual moves  around  in space. Therefore, the
 pollution  dose  of  Eq. (D-l)  should be  rewritten as
                                       T
                               DOSE  = /C[r_(t),t] dt                  (D-6)
                                      o
 where jr(t) is  the  spatial  position of  the subject  person  at time  t.   Under
 this situation, the conversion  from Eq.  (D-l)  to  Eq.  (D-2)  is not applicable
 to Eq.  (D-6).   Therefore,  there is no  easy way to  determine, for  the subject
 person, the three exposure parameters  defined  by Eqs.  D-3)   through  (D-5).
      In order to resolve the  above problem, we propose to use the quasi-
 stationarity assumption, i.e.,  each  individual stays  close  to a receptor point,

-------
                                  D-4
say,  his office on weekdays  from 8 A.M.  to  5  P.M.  Suppose that we divide  the  total
time  period T into  two non-overlapping  time  periods, working time TW  and
non-working time T .   Then,  the three exposure parameters  can  be  given by the
following equations:

                          D =  
                       •<(CS>  =  24(Rhour/Rday)
where D  is the dose rate during working time, D  that during non-working
       w                                        n
time, R (CJ the risk frequency during working time, and Rn(C$) that during
       W  O
non-working time.
     The above formulation is derived for a single person.  The next step  is
to  extend the population exposure formulation for a single person  into  that
 for a  population of  millions of parsons.  Suppose that the spatial position of
 the local  population is approximated by a receptor point located approximately
 at the center  of their residence  locations, and that the air quality at  that
 receptor  point is  estimated  from  the nearby monitoring stations by using the
 interpolation  equation  (D-l).  Then, the distribution function  for each of
                                                     Q
 the three  population exposure parameters is given as:

-------
                                   D-5

                            r  I  PT U(D1 - D*)/P                       (D-9)


                            - I PI U[R.(CS) - R*]/P                   {D_10.
                             i

                     S(T*) = I P. tj[T.(cs) _ T*]/PO                  (D.1V
 where P. is the size of the local  population  at the  i-th  receptor point, P

 the total number of people of the  population, and U(x)  the  step function that

 becomes unity when x is zero or positive and  zero when  x  is negative.   D*, R*,

 and T* are, respectively, the threshold values of D,  R(CS)  and T(CS).

     Once the  distribution  function  is  determined for a parameter D,  R, or T,

 the mean  value of  that  parameter over the  entire population is given  by the

 integral  of the distribution  function with respect to the threshold of that

 parameter^ The average dose  rate  D", the average risk frequency ^(C^.)  and the
                                                                    O
 average mean duration ^"(C)  over the entire population  are  given as
                              D  = /  S(D*) dD*                         (0-12)
                                 o
                                  CO
                                =/  S(R*) dR*                         (°-13)
                         ~(CJ = f S(T*) dx*                         (
                                 o
The actual computation of U,  R^(C^)  and T(CS)  was  done by numerically  integrating

the distribution functions S(D*),  S(R*),  and  S(t*), respectively.

-------
                                   D-6
     Suppose that a distribution function is determined for two mutually exclu-
sive populations, working population and non-working population.  Then, the
distribution function, S(R*) for the total population (sum of the two popu-
lations) can be computed from S (R*) of the working population and S_(R*)  of
the non-working population as:

                    S(R*) - [Pw SW(R*) + Pn Sn(R*)]/Po              (D-15)

where P  is the size of total  population  that  is  given by the sum of the working
population PW and the non-working  population Pn-  The linear property of
Eq. (D-15) is also applicable  to the other two distribution functions S(D*)
and S(T*).

-------
                                   D-7
                         REFERENCES  TO APPENDIX  D


1.  Craw,  A.  R.,  "A Contribution  to  the  Problem  of  Placement of Air  Pollution
    Samplers,"  U.S.  Dept.  of Commerce, National  Bureau of  Standards, NBS
    Report #10-284,  May 1970.

2.  Brasser,  L. J.,  "A New Method for the  Presentation of  a Large Number of
    Data Obtained from Air Pollution Survey  Networks," Paper #SU-18B,  Pro-
    ceedings  of the Second International Clean Air  Congress, IUAPPA, Washington,
    D.C.,  USA,  December 6-11,  1970.

3.  Csanady,  G. T.,  "The Dosage-Area Problems  in Turbulent Diffusion,"
    Atmospheric Environment, Vol. 1, 1967, pp. 451-459.

4.  Horie, Y.,  and A.  C. Stern, "Analysis  of Population  Exposure  to  Air
    Pollution in New York - New Jersey - Connecticut Tri-State Region," U.S.
    EPA, OAQPS, EPA-450/3-76-027, March  1976.

-------
                                  TECHNICAL REPORT DATA
                           (Please read Instructions on the reverse before completing)
 REPORT NO.
 EPA-450/3-77-004b
                                                          3. RECIPIENT'S ACCESSION NO.
 TITLE AND SUBTITLE
 Population Exposure to Oxidants  and Nitrogen Dioxide
 in Los Angeles Volume II:   Weekday/Weekend and
 Population Mobility Effects	
            5. REPORT DATE
              January 1977
            6. PERFORMING ORGANIZATION CODE
 AUTHOR(S)
 Yuji Horie, Anton S.  Chaplin,  and Eric D. Helfenbein
                                                          8. PERFORMING ORGANIZATION REPORT NO.
 PERFORMING ORGANIZATION NAME AND ADDRESS
 U.S. Environmental  Protection Agency
 Office of Air and Waste  Management
 Office of Air Quality  Planning and Standards
 Research Triangle Park,  North Carolina 27711
            10. PROGRAM ELEMENT NO.

              2AF643
            11. CONTRACT/GRANT NO.

              68-02-2318
 2. SPONSORING AGENCY NAME AND ADDRESS
 Technology Service  Corporation
 2811 Wilshire  Boulevard
 Santa Monica,  California   90403
                                                          13. TYPE OF REPORT AND PERIOD COVERED
              contractor
             14. SPONSORING AGENCY CODE
 5. SUPPLEMENTARY NOTES
16. ABSTRACT
           A new methodology was developed  to  characterize population exposure  to  air
 pollution  and was applied to analyses of photochemical air pollution and population
 exposure to Ox and N02 in the Los Angeles  Basin.   The analysis was made on  the 1973
 air  quality and population data to examine the weekend effect and the population  mo-
 bility effect on population exposure to the two pollutants.
      N02 air quality was found to be better during weekends than weekdays throughout
 the  region except for Orange County.  Ox air  quality was found to be poorer in the
 coastal region but better in the inland region during weekends than weekdays.   Al-
 though the daily maximum Ox concentration  became slightly higher over weekends at
 some stations in the coastal region, the majority of air monitoring stations in the
 Los  Angeles Basin showed a lower Ox concentration during weekends than weekdays.   As
 a result,  the population on the whole received less exposure to Ox above  the NAAQS
 during weekends than weekdays.
      Because of daily migration from their residence areas to the business  districts,
 workers receive less exposure to Ox and  greater exposure to N02 than do  non-workers
 who  stay near their residences all of tie  time.  The inclusion of population mobility
 in the population exposure estimates proved to be important for determining a distri-
 bution of the population-at-risk,  but it  turned out not to be crucial  for determining
 an aggregated index of population  exposure.	_
17.
                               KEY WORDS AND DOCUMENT ANALYSIS
                  DESCRIPTORS
                                             b.IDENTIFIERS/OPEN ENDED TERMS
                          c.  COS AT I Field/Group
 Photochemical Air Pollution
 Air Quality Monitoring
 Population Exposure
 Data Analysis
 Weekday/Weekend Effect
 Population Mobility
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (ThisReport}
     Unclassified
21. NO. OF PAGES
      Til;
      Unlimited
20. SECURITY CLASS (Thispage)

     Unclassified
                                                                        22. PRICE
EPA Form 2220-1 (9-73)

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