EPA-450/3-92-015
PRODUCTION OF ACETAL, AMINO, AND PHENOLIC RESINS
Emission Standards Division
U S. Environmental Protection Agency
Region 5, Library (PL-12J)
77 West Jackson Boulevard, 12m Floor
Chicago, IL 60604-3590
U.S. Environmental Protection Agency
Office of Air and Radiation
Office of Air Quality Planning and Standards
Research Triangle Park, North Carolina 27711
July 1992
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This report has been reviewed by the Emission Standards
Division of the Office of Air Quality Planning and Standards,
EPA, and approved for publication. Mention of trade names or
commercial products is not intended to constitute endorsement
or recommendation for use.
Copies of this report are available, as supplies permit
through the Library Services Office (MD-35), U.S.
Environmental Protection Agency, Research Triangle Park, NC
27711, (919) 541-2777, or for a nominal fee, from National
Technical Information Services, 5285 Port Royal Road,
Springfield, VA 22161, (703) 487-4650.
11
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TABLE OF CONTENTS
CHAPTER 1 INTRODUCTION 1-1
CHAPTER 2 PHENOLIC RESINS 2-1
2.1 Introduction 2-1
2.2 Process Description 2-1
2.2.1 Resoles 2-1
2.2.2 Novolaks 2-9
2.3 Emissions 2-12
2.3.1 Batch Process 2-12
2.3.2 Continuous Process 2-14
2.3.3 Emission Rates 2-15
CHAPTER 3 AMINO RESINS 3-1
3.1 Introduction 3-1
3.2 Process Description 3-9
3.3 Emissions 3-11
CHAPTER 4 ACETAL RESINS 4-1
4.1 Introduction 4-1
4.2 Process Description 4-1
4.2.1 Acetal Homopolymer Resin Process . . . 4-1
4.2.1.1 Purification Process 4-4
4.2.1.2 Polymerization 4-4
4.2.1.3 End Capping 4-5
4.2.1.4 Finishing 4-5
4.2.2 Acetal Copolymer Resin Process .... 4-5
4.2.2.1 Trioxane Formation
and Purification 4-6
4.2.2.2 Copolymerization 4-6
4.2.2.3 Stabilization 4-7
4.2.2.4 Finishing 4-7
4.3 Emissions 4-8
CHAPTER 5 MAJOR SOURCE FACILITIES 5-1
5.1 Introduction 5-1
5.2 Major Sources . . 5-2
111
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TABLE OF CONTENTS
(Concluded)
APPENDICES .......... A-l
APPENDIX A FACILITY EMISSIONS AND CONTACTS ...... A-2
APPENDIX B WORKSHEETS ..... .... B-1
IV
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LIST OF TABLES
Table Page
1-1 PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES . 1-2
2-1 PHENOLIC RESIN PRODUCTION FACILITIES 2-2
2-2 REPORTED EMISSION RATES FOR THE
PHENOLIC RESIN PROCESS 2-15
3-1 UREA-FORMALDEHYDE RESIN FACILITIES 3-2
3-2 MELAMINE-FORMALDEHYDE RESIN FACILITIES .... 3-6
3-3 REPORTED EMISSION RATES FOR THE
AMINO RESIN PROCESS 3-12
4-1 ACETAL RESIN FACILITIES 4-2
4-2 REPORTED EMISSION RATES FOR THE
ACETAL RESIN PROCESS 4-8
5-1 PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES
NOT GIVEN IN TRIS 5-3
5-2 MAJOR SOURCE FACILITIES 5-4
A-l EMISSIONS AND TECHNICAL CONTACT BY FACILITY . . A-3
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LIST OF FIGURES
Figure page
2-1 One-step or two-step batch processes for the
production of phenolic resins 2-7
2-2 A continuous process for the production
of phenolic resins 2-11
3-1 A batch process for the production
of amino resins 3-10
4-1 A batch process for the production
of acetal resins 4-3
VI
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CHAPTER 1
INTRODUCTION
Title III of the Clean Air Act Amendments of 1990 (CAA)
requires development of air emission standards for all major
sources, and selected area sources, emitting any of the 189
hazardous air pollutants (HAP's) identified in Section 112 of
the CAA.
The production of phenolic, amino, and, acetal resins is
being reviewed, so that ultimately a National Emission
Standard for Hazardous Air Pollutants (NESHAP) can be
developed based on candidate Maximum Achievable Control
Technology. The intent is to regulate emissions from process
vents, equipment leaks, wastewater collection and treatment,
storage, and transfer sources. Only those emissions that
directly result from the manufacture of the resins will be
considered for regulation.
This report is intended to provide a general overview of
the production of phenolic, amino, and acetal resins by
explaining their processes, identifying plant locations, and
determining which facilities would potentially be subject to
MACT based on their reported controlled emission estimates.
Amino resins primarily consist of urea-formaldehyde and
melamine-formaldehyde resins. The category of "amino resins"
is used rather than "formaldehyde resins" since phenolic and
acetal resins are also produced with formaldehyde.
The 1991 Directory of Chemical Producers lists 129
facilities that produce one or more of these resins.1 These
facilities, which are operated by approximately 70 companies,
are listed in Table 1-1. A list of production facilities and
1-1
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TABLE 1-1. PHENOLIC, AHINO, AND ACETAL RESIN FACILITIES
Company
Akzo America Inc., Reliance
Universal Inc., Sub.
Allied-Signal
American Cyanamid Co. Polymer
Prods. Div.
AMETEK, Inc.
Apex Chemical Corp.
Ashland Oi I, Inc.
Auralux Corp.
BASF Corp.
Borden, Inc.
Location
Columbus, OH
Louisville, KY
Green Island, NY
Charlotte, NC
Kalamazoo, MI
Wallingford, CT
Wilmington, DE
Elizabethport, NJ
Calumet City, IL
Cleveland,
OH
Norwich, CT
Anaheim, CA
Detroit, MI
Demopolis, A I
Diboll, TX
Fayetteville, NC
Fremont, CA
Kent, UA
La Grande, Or
Louisville, KY
Phenolic
Resins
X
X
X
X
X
X
X
X
X
X
X
X
Ami no Resins
Urea
X
X
X
X
X
X
X
X
X
X
X
X
X
Melamine
X
X
X
X
X
X
X
X
X
Acetal
Resins
I
ro
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TABLE 1-1. PHENOLIC, AMINO, AND ACETAL RESIN-FACILITIES (Continued)
Company
Borden, Inc.
Borden, Inc. Perkins Ind. Sub.
Borden, Inc. Acme Resin Corp.
Brand-S Corp. Cascade Resins
Div.
BTL Specialty Resins Corp.
Capital Resin Corp.
Cargill, Inc. Chemical Prods.
Div.
C.L. Industries
C.N.C. International L. P.
Commercial Products Co., Inc.
Cook Composites & Polymers
Location
Missoula, MT
Sheboygan, UI
Springfield,
OR
Alexandria, LA
High Point, NC
Forest Park,
1L
Eugene, OR
Malvern, AR
Blue Island, IL
Toledo, OH
Columbus, OH
Carpentersvi 1 le, IL
Forest Park, GA
Lynwood, CA
Georgetown, IL
Woonsocket, RI
Hawthorne, NJ
North Kansas City, MO
Phenolic
Resins
X
X
X
X
X
X
X
X
X
Ami no Resins
X
X
X
X
X
X
X
x
X
X
X
X
X
X
X
x
X
X
X
X
X
x
X
Acetal
Resins
I
00
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TABLE 1-1. PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES (Continued)
Company
Courtaulde U.S. Inc. (DeSoto
Aerospace)
D.B. Western
Delta Resins & Refract. Corp.
The Dexter Corp.
Dock Resins Corp.
DuPont Co. Polymer Prods. Div.
Dyno Polymers (Minnesota) Inc.
(Brancor)
Dyno Polymers Inc.
(RVP Corp.)
Eastern Color & Chemical Co.
Exxon Corp.
General Electric Co.1
The P. D. George Co.
Georgia-Pacific Corp.
Location
Berkeley, CA
Las' Vegas, New Mexico
Detroit, HI
Milwaukee, wl
Birmingham,
AL
Waukegan, IL
Linden, NJ
Parkersburg, WV
Virginia, MN
White City, OR
Providence, RI
Houston, TX
Coshocton,
OH
St. Louis,
Mr>
Albany, OR
Columbus, OH
Conway, NC
Crossett, AR
Elk Grove, CA
Eugene, OR
Phenolic
Resins
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Amino Resins
Urea
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
X
Acetal
Resins
X
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TABLE 1-1. PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES (Continued)
Company
Georgia-Pacific Corp.
Guardsman Products, Inc.
Hercules Inc. Operations Div.
Hercules Inc. Resins, Div.
Heresite Protective Coatings
Inc.
Hickson DanChem Corp.
Hoechst Celanese Corp.
Hugh J. Resins
Insulating Materials
Location
Grayling, MI
Louisville, MS
Lufkin, TX
Peachtree City, GA
Port Wentworth, GA
Russellvi lie, SC
Taylorsvi I le, MS
Ukiah, CA
Vienna, GA
Grand Rapids, MI
Chicopee, MA
Milwaukee, UI
Portland, OR
Savannah, GA
Hattiesburg, MS
Manitowoc, WI
Danville, VA
Mount Holly, NC
Bishop, TX
Long Beach,
CA
Schenectady, NY
Phenol ic
Resins
X
X
X
X
X
X
X
X
X
X
X
X
X
Ami no Resins
X
X
X
X
X
X
X
X
X
x
X
X
X
x
x
X
X
x
X
X
X
Acetal
Resins
X
I
en
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TABLE 1-1. PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES (Continued)
Company
WAX Corp. IVAX Ind., Inc.
Textile Products Div.
Lawter International
Hasonite Corp.
Minnesota Mining &
Manufacturing
Co.
Monsanto Co.
National Casein Co.*
Neste Resins Corp.
Occidental Petroleum Corp.
Perstorp, Inc.
Pioneer Plastics Corp.
Location
Rock Hill, SC
Moundville, AL
Gulf port, MS
Cordova, IL
Cottage Grove, MN
AHHyston, OH
Springfield, MA
Chicago, IL
Tyler, TX
Anda I us i a ,
AL
Moncure, NC
Spokane, WA
Springfield,
OR
Toledo, OH
Winnfield, LA
Kenton, OH
Niagara Falls, NY
North Tonawanda, NY
Florence, MA
Auburn, ME
Phenolic
Resins
X
X
X
X
X
X
X
X
X
X
X
X
X
Ami no Resins
Urea
X
X
X
X
X
X
X
X
X
X
X
X
Me I ami ne
X
X
X
X
X
X
X
X
Acetal
Resins
en
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TABLE 1-1. PHENOLIC, AM1NO, AND ACETAL RESIN FACILITIES (Continued)
Company
===^==^==^===
Plastics Eng. Co.
Plastics Manufacturing Co.
PMC, Inc.
PPG Ind., Inc.
Reichhold Chemicals, Inc.
;
Res i nail Corp.
Rhone-Poulenc Inc.
Schenectady Chemicals, Inc.
SEQUA Corp.
Simpson Timber Co.
Southeastern Adhesives Co.
Spaulding Composites Co., Inc.
Spur lock Co.
Stuart- Ironsides, Inc.
Sybron Chemicals Inc.
Synthron, Inc.
Ultraform Co.
^=====:^^==
Sheboygan,
UI
Dallas, TX
Fords, NJ
Circleville, OH
Oak Creek, WI
Bridgeville, PA
Severn, NC
Louisville, KY
Rotterdam
Junction, NY
Schenectady, NY
Chester, SC
Portland, OR
Lenoir, NC
Ridgeway, VA
De Kalb, IL
Tonawanda, NY
Waverly, VA
Columbus, OH
Elmwood Park, NJ
Wellford, SC
Horganton, NC
Theodore, AL
=============
Phenol ic
Resins
X
X
X
X
X
X
X
X
X
X
-
Aminc
Urea
X
X
X
X
X
X
X
X
X
X
Resins
Me I ami ne
===========
X
X
X
X
X
X
X
X
=
Acetat
Resins
s=
X
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TABLE 1-1. PHENOLIC, AMINO, AND ACETAL RESIN FACILITIES (Concluded)
Company
Unilever U.S., Inc. National
Starch & Chemical Co., Sub.
Union Carbide Corp."'
Valentine Sugars, Inc.
Valspar Corp.
McUhorter, Inc., Sub.
Uestinghouse Electric Corp.
West Point-Pepperell, Inc.
Griftex Chemicals, Sub.
Location
Salisbury, NC
Somerset, NJ
Lockport, LA
Garland, TX
Kankakee, IL
Hampton, SC
Manor, PA
Opelika, AL
Phenol ic
Resins
X
X
X
X
Ami no Resins
Urea
X
X
X
Me I ami ne
X
X
X
Acetal
Resins
Source: Reference 1.
General Electric Company may no longer be a manufacturer of formaldehyde-based resins.
National Casein facilities may no longer be manufacturers of formaldehyde-based resins; they may only be involved in storage and
distribution.
Union Carbide Corporation facility may have been bought by Georgia-Pacific.
-------
their locations is given for each resin in their respective
chapters. For each major resin a process description and
emission sources and estimates are provided. The process
descriptions include the raw materials and the process steps
used in the production process. In addition, they provide the
general chemical reactions that occur to produce these resins.
The potential emission streams and the emission factors are
also given for each resin process. The report concludes by
identifying resin facilities that were determined to be major
sources of HAP's* using the controlled emission data obtained
from the Toxic Release Inventory System (TRIS) data base.
The CAAA of 1990 defines a major source as "... any
stationary source or group of stationary sources located
within a contiguous area and under common control that emits
or has the potential to emit considering controls, in the
aggregate, 10 tons per year or more of any [HAP] or 25 tons
per year or more of any combination of [HAP's].11
1-9
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REFERENCES
1- 1991 Directory of Chemical Producers. United States of
America. Menlo Park, Calif.: Chemical Information
Services, Stanford Research Institute, 1991.
1-10
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CHAPTER 2
PHENOLIC RESINS
2.1 INTRODUCTION
Phenolic resins are in general condensation products of
formaldehyde and phenol.1-2-3 Besides formaldehyde,
acetaldehyde or furfuraldehyde is sometimes used but in
smaller quantities.2 In addition to phenol, other phenolic
starting compounds include alkyl-substituted phenols, such as
cresols, xylenols, p-tert-butylphenol, p-phenylphenol, and
nonylphenol.2 Table 2-1 lists facilities that produce these
resins according to the 1991 Directory of Chemical Producers.4
The phenol-formaldehyde resin was the first synthetic
thermosetting polymer produced. It was discovered in 1907 by
Baekeland and in 1911 was trademarked "Bakelite." It can be
used in a variety of materials, such as bonding powders, paint
and baked enamel coatings, plywood and glass-fiber composites,
brake linings, clutch facings, electrical devices, etc.5
Resoles and novolaks are two types of phenolic resins
produced.1>2-3 Resoles are produced in a one-step process
either as an aqueous syrup (liquid resole) or as a varnish
(solid resole is dissolved in an alcohol or organic solvent).
Novolaks are produced in a two step process to form molding
powders.1
2.2 PROCESS DESCRIPTION
2.2.1 Resoles
In the production of resole resins, a mole ratio of
formaldehyde to phenol between 1 and 3 is generally used
2-1
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TABLE 2-1. PHENOLIC RESIN PRODUCTION FACILITIES
Company
Allied-Signal, Inc.
Engineered Materials Sector
Friction Materials
Division
AMETEK, Inc.
Haveg Division
Ashland Oil, Inc.
Ashland Chemical, Inc.,
subsidiary
Foundry Products Division
BASF Corporation
Coatings and Colorants
Division
Borden, Inc.
Borden Chemical Division
Adhesives and Chemicals
Division
Perkins Industries,
subsidiary
ACME Resin Corporation,
subsidiary
Brand-S Corp.
Cascade Resins, Division
BTL Specialty Resins Corporation
Capital Resin Corporation
C. L. Industries, Inc.
Delta Resins & Refractories
Corporation
Location
Green Island, New York
Wilmington, Delaware
Calumet City, Illinois
Cleveland, Ohio
Anaheim, California
Demopolis, Alabama
Diboll, Texas
Fayetteville, North
Carolina
Fremont, California
Kent, Washington
La Grande, Oregon
Louisville, Kentucky
Missoula, Montana
Sheboygan, Wisconsin
Springfield, Oregon
Alexandria, Louisiana
Forest Park, Illinois
Eugene, Oregon
Malvern, Arkansas
Columbus, Ohio
Georgetown, Illinois1
Detroit, Michigan
Milwaukee, Wisconsin
2-2
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TABLE 2-1.
PHENOLIC RESIN PRODUCTION FACILITIES
(Continued)
Company
The Dexter Corporation
Dexter Packaging Products
Division
Dexter Specialty Coatings
Division
Dyno Polymers (Minnesota) Inc.
(Brancor)
Dyno Polymers, Inc. (RVP Corp.)
General Electric Company2
GE Plastics
Electromaterials
Business
Department
The P.O. George Company
Georgia-Pacific Corporation
Chemical Division
Heresite Protective Coatings,
Inc.
Hoechst Celanese Corp.
Chemicals
Specialty Chemicals
Hugh J. -Resins Company
Insulating Materials, Inc.
Location
Birmingham, Alabama
Waukegan, Illinois
Virginia, Minnesota
White City, Oregon
Coshocton, Ohio
St. Louis, Missouri
Albany, Oregon1
Columbus, Ohio
Conway, North Carolina
Crossett, Arkansas
Elk Grove, California
Eugene, Oregon
Grayling, Michigan
Louisville,
Mississippi
Lufkin, Texas
Peachtree City,
Georgia
Port Wentworth,
Georgia
Russellville, South
Carolina
Taylorsville,
Mississippi
Ukiah, California
Vienna, Georgia
Manitowoc, Wisconsin
Mount Holly, North
Carolina
Long Beach, California
Schenectady, New York
2-3
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TABLE 2-1.
PHENOLIC RESIN PRODUCTION FACILITIES
(Continued)
Company
Lawter International, Inc.
Masonite Corporation
Alpine Division
Minnesota Mining & Manufacturing
Company
Speciality Adhesives and
Chemical Division
Neste Resins Corporation
Occidental Petroleum Corporation
Occidental Chemical
Corporation,
subsidiary
Plastics & Polymers Group
Durez Division
Plastics Engineering Company
PMC, Inc.
PMC Specialties Group
Division
Reichhold Chemicals, Inc.
Reactive Polymers Division
Resinall Corporation
Schenectady Chemicals, Inc.
Simpson Timber Company
Oregon Overlay Division
Spaulding Composites Company,
Inc.
Stuart-Ironsides, Inc.
Location
Moundville, Alabama
Gulfport, Mississippi
Cordova, Illinois
Cottage Grove,
Minnesota
Andalusia, Alabama
Moncure, North
Carolina
Spokane, Washington
Springfield, Oregon
Toledo, Ohio
Winnfield, Louisiana
Kenton, Ohio
Niagara Falls, New
York
North Tonawanda, New
York
Sheboygan, Wisconsin
Fords, New Jersey
Bridgeville,
Pennsylvania
Severn, North
Carolina1
Rotterdam Junction,
New York
Schenectady, New York
Portland, Oregon
De Kalb, Illinois
Tonawanda, New York
Columbus, Ohio
2-4
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TABLE 2-1. PHENOLIC RESIN PRODUCTION FACILITIES
(Concluded)
Company
Union Carbide Corporation3
Union Carbide Chemicals and
Plastics Company, Inc.,
subsidiary
Solvents and Coatings
Materials Division
Valentine Sugars, Inc.
Westinghouse Electric Corporation
Copper Laminates Division
Electrical Materials
Division
Location
Somerset, New Jersey
Lockport, Louisiana
Hampton, South
Carolina
Manor, Pennsylvania
Source: Reference 4.
These were given as "phenolic resins - unspecified."
General Electric Company may no longer be a manufacturer of
formaldehyde-based resins.
Union Carbide Corporation facility may have been bought by
Georgia-Pacific.
2-5
-------
with a basic catalyst such as sodium, barium, or calcium
hydroxide? sodium carbonate; or an organic amine.2-3 The
conventional mechanism of polymerization is shown in the
following equations.2
-ONa*
-M,O
CH2 - 0
ON«
Hf
CH OH
The extent of polymerization and the functionality (total
number of unsubstituted positions on the benzene ring that are
ortho or para to the hydroxyl group) are determined by the
specific application intended for the materials. The
materials can be high in molecular weight and viscosity.
Resole resin production is conducted in a batch process.
Figure 2-1 shows a diagram for a typical batch process for
resoles and novolaks.1 Items 9 through 12 do not apply to the
resoles process. The numbers used in the following process
description refer to Figure 2-1. The process for resoles will
produce either liquid or solid resoles.1-2-3-4
Liquid resoles (aqueous syrup) can be produced in large-
capacity reactors because their viscosities can be controlled
and they do not have to be discharged as rapidly as solid
resoles.
2-6
-------
ro
i
STOHIQE 111 or
5«i solution? fi]
c.v.tl
OIQIIIC
rreo
COKKM3ITC
10 LIQOID
nH'o.cW IMIMMIM
ro fNcinuirai
1,,! rO
Rt IllCe If riOCMSI3 3IIOUI
CKIOINQ
MAC?
UCOVtM/riNIM
Figure 2-1
One-step or two-step batch processes for the
production of phenolic resins. (Reference 1, p. 109)
-------
Solid resoles generally require a relatively small
reactor (10m3) to allow rapid discharge since near the end of
the reaction the viscosity increases rapidly and to maintain
thermal stability. An agitator is used to prevent
local gelation and provide power to circulate the viscous
fluids.2 A batch cycle normally takes eight hours.
Raw materials in the production of the resoles are molten
phenol (1), formaldehyde (37 or 50 percent solution) (2), and
an organic solvent (3). Molten phenol which is fed through a
weigh tank (4) and the desired basic catalyst, such as sodium
hydroxide, are charged first to the reactor (6). Next 37 or
50% aqueous formaldehyde is fed through a weigh tank (5) and
added to the reactor at a rate to maintain a temperature of 60
to 70°C (140 to 158°F). The desired reaction temperature,
approximately 80 to 100°C (176 to 212°F), is achieved by
heating the mixture in a reaction vessel that has an internal
coil or external, temperature-controlled jacket, is agitated,
and uses vacuum reflux. The temperature is maintained for 1
to 3 hours. The reaction is monitored at short intervals by
measuring the viscosity or gel time (set up time) on a sample
from the reactor contents. When the desired end point is
reached, the reaction mixture is neutralized with an acid such
as acetic, formic, sulfuric, or phosphoric acid. Evaporation
of the water (dehydration) is performed in the reactor under a
vacuum until the desired syrup concentration is achieved. The
reaction contents are then cooled as rapidly as possible by
discharging to cooled engineered surfaces, such as air cooled
floors, moving belts, or trays in racks. The aqueous syrup is
then filtered and stored (7), usually in a refrigerator, until
it is to be used.
After the dehydration step is completed, a solvent, such
as methanol (3), is added to the solid resole and the product
is recovered as a varnish solution. It is then stored (8)
until it is to be used. In either liquid or solid resoles,
additives and modifiers may be introduced during different
steps of the process.
2-8
-------
2.2.2 Novolaks
In the production of novolak resins, a mole ratio of
formaldehyde to phenol is normally between 0.70 and 0.85.2-3
Oxalic acid is normally the catalyst used in the process;
however, acid catalysts such as hydrochloric acid, sulfuric
acid, sulfonic acid, p-toluene and phosphoric acid are
sometimes used.2 When an acid catalyst is used, phenol and
formaldehyde react by way of electrophilic substitution.2-3
The general mechanism for polymerization is given in the
following equations.2-3
lew
CH2OH
fart
CH2OH
H
Novolak compositions with average molecular weight less than
2,500 are achieved by the repetitive reactions.2
For the batch process of novolak resin production, a two-
step process is generally used. Figure 2-1 shows a diagram
for a typical batch process. The numbers used in the
following process description refer to Figure 2-1.1-2-3
The phenol, which is stored in alloyed steel tanks (l) at
60'C (140'F), is weighed (4) and transferred to the reactor
(6) where it is heated to 95°C (203°F). The acidic catalyst,
2-9
-------
which is usually oxalic acid, is then added to the reactor.
After the acidic catalyst has been added, an aqueous
formaldehyde solution that is in a storage tank (2) is stirred
into the reactor. The solution is stirred at a rate designed
to maintain a gentle boiling of the mixture. When the
addition of the formaldehyde solution is finished, the
temperature of the mixture is maintained until the reaction
has used all of the formaldehyde. Water and unreacted phenol
are removed at atmospheric pressure by heating the reaction
mixture to approximately 132°C (270°F) using an external
heating jacket. The reaction mixture is
heated further to 160°C (320°F) and using vacuum and injection
of live steam the residual volatiles are removed from the
resin. When the desired melting point is achieved, the resin
is fed to a heated vessel. It is then flaked (9) onto a
continuous cooling belt. The flake may then be fed to a
grinder (10) to form a powder resin. The powder resin may be
blended with additives in a ribbon blender (11). The product
may then be sent to a pelletizer (12).
Figure 2-2 shows a diagram for a typical continuous
process for the production of novolak.2'3 The following steps
occur in the continuous process for novolak resin production,
and the numbers used in the process description refer to
Figure 2-2.2>3
Phenol (1) , formaldehyde (2), and catalyst (3) are
charged to a first stage reactor. The quantity of each is
measured and controlled automatically. This first reactor is
stirred and has an external heating jacket. The phenol and
formaldehyde reaction is started in the reactor. The material
is then transferred to a second stage reactor (5) where the
reaction is continued and completed. The reaction rate is
enhanced by using a pressure less than 7 atmospheres and a
temperature range between 120 and 180°C (248 to 356°F). The
reaction mixture from the second reactor is transferred into a
flash drum (6), which is used as a liquid-vapor separator.
2-10
-------
ho
I
llj
n Continuous
Vdlsllllalion
Cooling bell
Figure 2-2. A continuous process for the production of phenolic resins
(Reference 2, p. 392)
-------
The flashed vapor is condensed and then collected in a
receiver (7). It is then purified in the purification section
(8). The liquid phase in the flash drum forms two layers.
The upper layer is an aqueous layer containing small amounts
of phenol. It is removed from the flash drum and is purified
in the purification section (8). The bottom layer is the
resin layer, which is pumped to a distillation column for
more treatment. The distillation column (9) is used to remove
the water remaining in the resin. The vapor stream, which is
mostly water with a tiny amount of phenol, is condensed and
sent to the purification section (8) . The dewatered resin
stream is then sent to a belt flaking machine (10).2'3
2.3 EMISSIONS
2.3.1 Batch Process
Figure 2-1 shows the emission streams, which are
represented by the numbers in square brackets, for the
phenolic resin production processes. In the batch process,
three main categories of emissions exist--storage tanks,
polymerization reactors, and process tanks.1 Liquid
extraction or carbon adsorption may be used to control
emissions from these categories.
The first category represents the storage tanks for the
liquid monomer, solvent, and organic additives. The emissions
from these fixed roof tanks result from normal breathing and
filling.1
The phenol storage tanks contain liquid phenol that is
kept at approximately 60°C (140°F) by employing internal steam
coils. The emission stream from these tanks should be phenol
vapor and air, which enters the tank from the atmosphere.1
The formaldehyde storage tanks contain a 37% or 50%
aqueous solution of formaldehyde. Internal steam coils are
used to maintain a temperature of 40'C (104°F). The emission
stream from these tanks should consist of air, which enters
the tank from the atmosphere, formaldehyde, water vapor, and
2-12
-------
methanol vapor (the formaldehyde solution may contain up to 15
percent methanol).1-5
The storage tanks for organic solvents, organic
additives, and catalysts are kept at ambient temperatures. The
emissions from these tanks should consist of vapor from these
substances and air, which enters the tanks from the
atmosphere.1 These emissions result from working and
breathing losses.
The emissions from each process tank are relatively
small; however, the total emissions from the tanks are similar
to the emissions from the main streams in the process. The
total uncontrolled storage emission rate is reported as
approximately 0.14 lbs/1000 Ibs resin1. This reported
emission factor, however, is derived from a 1979 study which
may not be consistent with the approved AP-42 methodology that
EPA intends to use in the future to estimate storage tank
emissions. Methanol will probably be emitted in the largest
quantities; ethanol (a non-HAP), phenol, and formaldehyde will
be the next major pollutants, all in the same range; and the
catalyst will be emitted in a much smaller amount.1
The weigh tank operations will contribute a small amount
of VOC emissions, which occur when these tanks are charged
with phenol and formaldehyde. The weighed material is fed
directly into the reactor. The charged material will be the
only VOC emission in the exhaust stream. Nitrogen blanketing
may be necessary on some or all of the tanks which vent to an
incinerator because of explosive range considerations.1
The second category covers the emissions resulting from
the polymerization reactor. This emission stream comes from
vents associated with the reactor. The first stream vent is
used for the condenser during charging and for the cycle of
the reaction requiring atmospheric dehydration. The emission
stream occurring during charging will have phenol and
formaldehyde mixed with air and water vapor at a temperature
of 35°C (95°F). During dehydration, the emission stream will
consist of phenol, formaldehyde, and water vapor with a
2-13
-------
temperature of 25°C (77°F). The second vent is downstream
from the vacuum equipment, which is attached to the overhead
condenser during the process of dehydration under vacuum and
refluxing. The emission stream is usually at 25-35°C (77-
95°F) and consists of formaldehyde, air, water vapor, some
phenol, and some other reaction products. The emissions are
on the same order of magnitude as the emissions from the
storage tanks.1 The total uncontrolled emission rate is
reported as 0.22 lbs/1000 Ibs resin.1
The third category consists of product and product blend
tanks. The emissions result from normal breathing and filling
losses. In general, fixed roof tanks are used at ambient
temperatures. Phenol, formaldehyde, and the solvent used for
that particular resin will be in the emission stream. The
emissions combined from these products are as large or larger
than any other emission streams in the process. The total
uncontrolled emission rate is reported as approximately 0.24
lbs/1000 Ibs resin.1 This reported emission factor, however,
is derived from a 1979 study which may not be consistent with
the approved AP-42 methodology that EPA intends to use in the
future to estimate storage tank emissions.
In addition to these categories, fugitive emissions may
occur at process vents, condenser, sample ports, and vacuum
lines. Also, the washing of the reactor kettles and water
washing of the resins during preparation may result in
formaldehyde, phenol, and other emissions. Finally, emissions
may occur intermittently at safety blow-off values.6
2.3.2 Continuous Process
The emission streams, which are represented by numbers in
sguare brackets, for the continuous process are shown in
Figure 2-2 and would involve storage tanks, condensers,
distillation column, and holding tanks. The storage and
holding tanks should have emissions similar to the batch
process. The process equipment is slightly different;
therefore, the process emissions will be different from the
batch process.
2-14
-------
2.3.3 Emission Rates
Table 2-2 provides reported emission rates for the
phenolic resin process based on the raw material usage.6-7
TABLE 2-2. REPORTED EMISSION RATES FOR THE
PHENOLIC RESIN PROCESS
Category
Storage
Process
Pollutant
Formaldehyde
Phenol
Formaldehyde
Phenol
Emission Rate
0.06-0.4 Ib/ton of 37%
formaldehyde used
0.04 Ib/ton of phenol used
0.3-3 Ib/ton of 37%
formaldehyde used
0.7 Ib/ton of phenol used
Source: References 6 and 7.
2-15
-------
REFERENCES
! Polymer Industry Ranking by VOC Emissions Reduction That
Would Occur From New Source Performance Standards. C.N.
Click and O.K. Webber, Pullman Kellogg Houston, TX, 1979.
2. "Phenolic Resins", Kirk-Othmer Encyclopedia of Chemical
Technology. 3rd, Edition, Vol. 17.
3« Phenolic Resins Chemistry. Applications and Performance.
Andre Knop, Louis A. Pilato, Springer-Verlay, New York,
1985.
4- 1991 Directory of Chemical Producers. United .States of
America. Menlo Park, Calif.: Chemical Information
Services, Stanford Research Institute, 1991.
5- Hawlev's Condensed Chemical Dictionary, llth Ed., Revised
by N. Irving Sax and Richard L. Lewis, Sr., Van Nostrand
Reinhold Company, New York, 1987.
6 Locating and Estimating Air Emissions From Sources of
Formaldehyde. EPA-450/4-84-007e. March 1984.
a. Human Exposure to Atmospheric Concentrations of
Selected Chemicals, Volume 2. U. S. Environmental
Protection Agency. Research Triangle Park, N.C.,
February 1982. Appendix A-15.
b. Hewlett, L. T. Formaldehyde Institute, Scarsdale, N.
Y., Letter to Tom Lahre, Office of Air Quality
Planning and Standards, U. S. Environmental
Protection Agency, Sept. 29, 1983.
7. U.S. Environmental Protection Agency. Crosswalk/Air
Toxic Emission Factor (XATEF) Data Base. Office of Air
Quality Planning and Standards, Technical Support
Division, Research Triangle Park, NC. July 1990.
2-16
-------
CHAPTER 3
AMINO RESINS
3.1 INTRODUCTION
Amino resins are resins that are produced by the reaction
of formaldehyde with an amino compound, a compound that
contains the amino (NH2) group. Some of the amino compounds
used include melamine, urea, and urea derivatives.
Melamine resins are used as molding compounds, in
laminating adhesives, for leather processing for decorative
plastic items, etc. Urea resins are used in flexible foams,
installation, dinnerware, interior plywood, etc. Urea resins
were the first plastics in which white, pastel, and colored
products could be produced.1 The melamine resins were
introduced in 1939 and the urea resins were introduced in
1929.2
The reaction of formaldehyde with an amino compound
creates three dimensional, cross-linked polymers.3 Urea is
the most commonly used amino compound due to the fact that (1)
urea-formaldehyde is the largest selling resin and (2)
melamine, the amino compound used to make melamine-
formaldehyde, is made from urea. Urea and melamine compounds
give simple methylol compounds and low molecular weight
polymers.3 Tables 3-1 and 3-2 list facilities that produce
these resins according to the 1991 Directory of Chemical
Producers.4
3-1
-------
TABLE 3-1. UREA-FORMALDEHYDE RESIN FACILITIES
Company
Azko America, Inc.
Coatings Division
Reliance Universal Inc.,
subsidiary
American Cyanamid Company
Polymer Products Division
Apex Chemical Corporation
Auralex Corporation
BASF Corporation
Coatings and Colorants
Division
Borden, Inc.
Borden Packaging and
Industrial Products
Division
Adhesives and Resins
Division
Perkins Industries,
subsidiary
BTL Specialty Resins
Corporation
Capital Resin Corporation
Cargill, Incorporated
Chemical Products
Division
Location
Louisville, Kentucky
Charlotte, North
Carolina
Wallingford, Connecticut
Elizabethport, New
Jersey
Norwich, Connecticut
Detroit, Michigan
Demopolis, Alabama
Diboll, Texas
Fayetteville, North
Carolina
Fremont, California
Kent, Washington
La Grande, Oregon
Louisville, Kentucky
Missoula, Montana
Sheboygan, Wisconsin
Springfield, Oregon
High Point, North
Carolina
Blue Island, Illinois
Malvern, Arkansas
Toledo, Ohio
Columbus, Ohio
Carpentersville ,
Illinois
Forest Park, Georgia
Lynwood, California
3-2
-------
TABLE 3-1.
UREA-FORMALDEHYDE RESIN FACILITIES
(Continued)
Company
C.N.C. International L.P.
Commercial Products Company,
Inc.
Cook Composites and Polymers
Courtaulde U.S. Inc
Courtaulde Coatings, Inc.
subsidiary
(DeSoto Aerospace)
D.B. Western
New Mexico Adhesives
Dyno Polymers, Inc. (RVP
Corp.)
Eastern Color & Chemical
Company
Georgia-Pacific Corporation
Chemical Division
Guardsman Products, Inc.
Hercules Incorporated
Operations Division
Resins Division
Hickson DanChem Corporation
Location
Woonsocket, Rhode Island
Hawthorne, New Jersey
North Kansas City,
Missouri
Berkeley, California
Las Vegas, New Mexico
White City, Oregon
Providence, Rhode Island
Albany, Oregon
Columbus, Ohio
Conway, North Carolina
Crossett, Arkansas
Elk Grove, California
Eugene, Oregon
Grayling, Michigan
Louisville, Mississippi
Lufkin, Texas
Peachtree City, Georgia
Port Wentworth, Georgia
Russellville, South
Carolina
Taylorsville,
Mississippi
Ukiah, California
Vienna, Georgia
Grand Rapids, Michigan
Chicopee, Massachusetts
Milwaukee, Wisconsin
Portland, Oregon
Savannah, Georgia
Hattiesburg, Mississippi
Danville, Virginia
3-3
-------
TABLE 3-1.
UREA-FORMALDEHYDE RESIN FACILITIES
(Continued)
Company
Hoechst Celanese Corp.
Chemicals
Specialty Chemicals
IVAX Corporation
IVAX Industries, Inc.
Textile Products
Division
Monsanto Company
Monsanto Chemical Company
National Casein Company1
Neste Resins Corporation
Occidental Petroleum
Corporation
Occidental Chemical
Corporation, subsidiary
Polymers and
Plastics Group
Durez Division
Perstorp, Inc.
Perstorp Compounds, Inc.
Pioneer Plastics Corporation
Plastics Manufacturing Company
PPG Industries, Inc.
Coatings and Resins Group
Rhone-Poulenc, Inc.
Performance Resins &
Division
Specialty Resins
Unit
Location
Mount Holly, North
Carolina
Rock Hill, South
Carolina
Springfield,
Massachusetts
Chicago, Illinois
Tyler, Texas
Andalusia, Alabama
Moncure, North Carolina
Springfield, Oregon
Toledo, Ohio
Winnfield, Louisiana
Niagara Falls, New York
Florence, Massachusetts
Auburn, Maine
Dallas, Texas
Oak Creek, Wisconsin
Louisville, Kentucky
3-4
-------
TABLE 3-1.
UREA-FORMALDEHYDE RESIN FACILITIES
(Concluded)
Company
SEQUA Corporation
SEQUA Chemical Inc.,
subsidiary
Chemicals Division
Southeastern Adhesives Company
Spurlock Company
Sybron Chemicals Inc.
Textile Specialty
Chemicals Group
Synthron, Inc.
Unilever United States, Inc.
National Starch and
Chemical Corporation,
subsidiary
Valspar Corporation
McWhorter, Inc. ,
subsidiary
Location
Chester, South Carolina
Lenoir, North Carolina
Ridgeway, Virginia
Waverly, Virginia
Elmwood Park, New Jersey
Wellford, South Carolina
Morganton, North
Carolina
Salisbury, North
Carolina
Garland, Texas
Kankakee, Illinois
Source: Reference 4.
National Casein facilities may no longer be manufacturers of
formaldehyde-based resins; they may only be involved in
storage and distribution.
3-5
-------
TABLE .3-2. MELAMINE-FORMALDEHYDE RESIN FACILITIES
Company
Akzo American, Inc.
Coatings Division
Reliance Universal Inc. ,
subsidiary
American Cyanamid Company
Polymer Products Division
Auralux Corp.
BASF Corporation
Coatings and Colorands Division
Borden, Inc.
Borden Packaging and Industrial
Products Division
Adhesives and Resins
Division
BTL Specialty Resins Corp.
Capital Resin Corporation
Cargill, Incorporated
Chemical Products Division
C.N.C. International L.P.
Cook Composites and Polymers
D. B. Western
New Mexico Adhesives
Dock Resins Corporation
Dyno Polymers, Inc. (RVP Corp.)
Eastern Color & Chemical Company
Exxon Corp.
Exxon Chemical Company,
Division
Exxon Chemical Americas
Location
Columbus, Ohio
Louisville, Kentucky
Charlotte, North
Carolina
Kalamazoo, Michigan
Wallingford,
Connecticut
Norwich, CT
Detroit, Michigan
Diboil, Texas
Kent, Washington
Sheboygan, Wisconsin
Springfield, Oregon
Blue Island, Illinois
Toledo, Ohio
Columbus, Ohio
Carpentersville,
Illinois
Lynwood, California
Woonsocket, Rhode
Island
North Kansas City,
Missouri
Las Vegas, New Mexico
Linden, New Jersey
White City, Oregon
Providence, Rhode
Island
Houston, Texas
3-6
-------
TABLE 3-2.
MELAMINE-FORMALDEHYDE RESIN FACILITIES
(Continued)
Company
Georgia-Pacific Corporation
Chemical Division
Guardsman Products, Inc.
Hoechst Celanese Corp.
Chemicals
Specialty Chemicals
Insulating Materials, Inc.
Monsanto Company
Monsanto Chemical Company
Neste Resins Corporation
Perstorp, Inc.
Perstorp Compounds, Inc.
Pioneer Plastics Corporation
Plastics Manufacturing Company
PPG Industries, Inc.
Coatings and Resins Group
Rhone-Poulenc, Inc.
Performance Resins and
Coatings Division Specialty
Resins Unit
SEQUA Corporation
SEQUA Chemicals, Inc.,
subsidiary
Chemicals Division
Sybron Chemicals Inc.
Textile Specialty Chemicals
Group
Synthron, Inc.
Location
Albany, Oregon
Conway, North Carolina
Vienna, Georgia
Grand Rapids, Michigan
Mount Holly, North
Carolina
Schenectady, New York
Addyston, Ohio
Springfield,
Massachusetts
Moncure, North Carolina
Springfield, Oregon
Toledo, Ohio
Winnfield, Louisiana
Florence, Massachusetts
Auburn, Maine
Dallas, Texas
Circleville, Ohio
Oak Creek, Wisconsin
Louisville, Kentucky
Chester, South Carolina
Elmwood Park, New
Jersey
Well ford, South
Carolina
Morganton, North
Carolina
3-7
-------
TABLE 3-2.
MELAMINE-FORMALDEHYDE RESIN FACILITIES
(Concluded)
Company
Unilever United States, Inc.
National Starch and Chemical
Corporation, subsidary
Valspar Corporation
McWhorter, Inc. , subsidiary
West Point - Pepperell, Inc.
Griff tex Chemicals, subsidiary
Location
Salisbury, North
Carolina
Kankakee, Illinois
Opelika, Alabama
Source: Reference 4.
3-8
-------
3.2 PROCESS DESCRIPTION
The overall reaction for amino resin formation is similar
to phenol-formaldehyde resole formation (see Chapter 2).5 The
first step, known as methylolation or hydroxymethylation, is
the addition of formaldehyde to the amino compound. This step
is shown in the following equation:
R-NH2+HCHO~R-NH- CH2 OH
This step is usually catalyzed by a base compound since the
compounds are more stable under alkaline conditions.3
The second step is known as condensation, methylene
bridge formation, polymerization, resinification, or simply
cure. During condensation, water is removed from the monomer
units and amino units are joined with methylene links as
follows:
RNH- CH, OH+H?NR~RNH- CH, A/H- R+H, O
This step is catalyzed by acids and often by heat.3
The process to produce either urea or melamine
formaldehyde resin is similar and will be discussed as a
general amino resin process; often, the same equipment is used
to produce both resins.5
Amino resins are made by a simple batch process. The
initial product is a concentrated syrup which is then sold or
processed further into solids. Figure 3-1 is a schematic
representation of the batch process, and the numbers following
refer to this figure.6
Formaldehyde solution (52% at 59 °C (138°F)) is drawn from
storage (1) and fed to a resin reactor (2,000-10,000 gallons)
(2), where the amino compounds, catalysts, and additives are
mixed in.6 (One additive for melamine resins is an alcohol
such as methanol or butanol, which helps stabilize the
compound.)5 The reactor is agitated continuously and the
mixture is heated to the desired temperature by steam heat in
3-9
-------
i
i
o
VAPOR
RETURN
FORMALDEHYDE SOLUTION.
52* 8 138«F (FIXED ROOF)
STM
FAN
r LT-* REFLUX
[2] ^CONDENSER
HOO
CAUSTIC L-JlTfilii
VACUUM
PUMP
PRILLED
UREA
(SOLfD)
DRYER
PURGE
FORMALDEHYDE
SCRUBBER
HOOD^\L-J
SY'RUP PRODUCT
"TO DRUMS
RESIN I
IMPREGNATOR
(MIXER)
AIR
(UAKK-lll')i
TO
INCINERATOR
RESIN SYRUP OR TANK CARS
STORAGE
PROCESS
SEUER
,MOLDING POWDER
PRODUCT TO FURTHER
SIZE PROCESSING
& PACKAGING
FEED
REACT
RECOVERY/FINISH
Figure 3-1
A batch process for the production of amino resins
(Reference 6, p. 257)
-------
the jacket of the reactor. The progress is monitored by
periodically sampling for viscosity. When the desired
viscosity has been reached, the batch is cooled in the reactor
and the syrup is concentrated by evaporation of water with a
vacuum. The pH is adjusted and the syrup is pumped through a
filter (3) and into a syrup storage tank (4). The syrup is
then stored for sale, concentrated further or processed into a
powder. The solid powder can consist of either an unfilled
powder, which is manufactured by spray drying, or a filled
powder in which a solid is saturated with syrup (5). The
powder is then dried (6) and pulverized. The powder can be
sold as a powder or it can be deaerated into granules.6
3.3 EMISSIONS
The possible emission streams, which are represented by
numbers in square brackets, are shown in Figure 3-1.
Emissions may result from tanks and reactors since they are
vented. These emissions may contain formaldehyde, methanol,
or other solvents used in the process.3 Emissions from the
storage tanks occur from normal breathing and filling.5-6
Removal of water from the reactor under vacuum during the
polymerization process may result in formaldehyde emissions.
The use of pumps, valves, relief valves, and flanges may
result in equipment leaks that will attribute to the fugitive
emissions. 7
Table 3-3 provides reported emission'rates for the amino
resin process based on the raw material usage.7
3-11
-------
TABLE 3-3. REPORTED EMISSION RATES FOR THE
AMINO RESIN PROCESS
Category
Storage
Process
Pollutant
Formaldehyde
Formaldehyde
Emission Rate
(Ib/ton of 37% formaldehyde used)
0.06 - 0.4
0.30 - 3.0
Source: Reference 7.
3-12
-------
REFERENCES
! Havley's Condensed Chemical Dictionary, llth Ed., Revised
by N. Irving Sax and Richard J. Lewis, Sr., Van Nostrand
Reinhold Company, New York, 1987.
2. Austin, George T., Shreve's Chemical Process Industries.
5th Edition, McGraw-Hill Book Company, New York, 1984.
3. "Amino Resins and Plastics", Kirk-Othmer Encyclopedia of
Chemical Technology. 3rd Edition, Vol. 17
4- 1991 Directory of Chemical Producers. United States of
America. Menlo Park, Calif.: Chemical Information
Services, Stanford Research Institute, 1991.
5- Polymer Industry Ranking by VOC Emissions Reduction That
Would Occur From New Source Performance Standards. C.N.
Click and-O.K. Webber, Pullman Kellog, Section 7,
Houston, TX, 1979.
6- Polymer Industry Ranking by VOC Emission Reduction That
Would Occur From New Source Performance Standards. C.N.
Click and O.K. Webber, Pullman Kellog, Section 20,
Houston, TX, 1979.
7- Locating and Estimating Air Emissions From Sources of
Formaldehyde. EPA 450/4-84-007e, March, 1984.
a. Human Exposure to Atmospheric Concentrations of
Selected Chemicals, Volume 2. U. S. Environmental
Protection Agency. Research Triangle Park, N.C.,
February 1992. Appendix A-15.
b. Hewlett, L. T. Formaldehyde Institute, Scarsdale, N.
Y., Letter to Tom Lahre, Office of Air Quality
Planning and Standards, U. S. Environmental
Protection Agency, Sept. 29, 1983.
3-13
-------
CHAPTER 4
ACETAL RESINS
4.1 INTRODUCTION
Acetal resins are formed from the polymerization of
formaldehyde to give high molecular weight polymers and
copolymers.1 The polymerization occurs by ionic mechanisms
occurring in either an aqueous or nonaqueous system.2 The
resulting basic polymer structure, which has a repeating
carbon-oxygen linkage, is called polyoxymethylene (-OCH2-)n.1-2
Acetal resins are engineering plastics that are used in
industrial parts, automotive and appliance parts, as
substitutes for metals, as hardware, etc. They are strong,
tough, rigid and resilient.3
An acetal copolymer is formed from the polymerization of
trioxane, which is formed from the trimerization of
formaldehyde, and a copolymer, which is typically a cyclic
ether such as ethylene oxide. The copolymer usually has an
ethylene linkage (H2C-CH2) that sometimes interrupts the
oxymethylene structure.1 Table 4-1 lists the facilities that
produce acetal resins according to the 1991 Directory of
Chemical Producers.4
4.2 PROCESS DESCRIPTION
4.2.1 Acetal Homopolvmer Resin Process
The general steps involved in the acetal homopolymer
resin process include monomer purification, polymerization,
end-capping, and finishing. Figure 4-1 shows a general
process description for the production of polyacetal resins.
The numbers used in the following discussion refer to this
figure.5
4-1
-------
TABLE 4-1. ACETAL RESIN FACILITIES
Company
E.I. du Pont de Nemours
& Company, Inc.
Polymer Products
Department
Hoechst Celanese Corp.
Advanced Materials
Engineering Plastics
Ultraform Company
Location
Parkersburg,
West Virginia
Bishop, Texas
Theodore,
Alabama
Annual
Capacity
(millions of
pounds)
100
165
35
Source: Reference 4.
4-2
-------
Mtli lb« littin ! Ikll limn tftil|iil« (oltitUI
MllllMI IMKII. II illCUlltl U IhS till.
AQUEOUS
FORMALDEHYDE
STORAGE
ORGANIC
COMONOMER
SOLVENT
SOLVENT!
POLYOL8
ALCOHOLS
DE8ICCANT8
FEED
PREPARATION
TRIOXANE
DISPERSING
AGENT
ANHYDROUS
FORMALDEHYDE
ADDI
POLYMER-
IZATION
| EfSIVf EMISSJONS
I VALVES, PUMPS,FLANGES!
1 1
SOLID
POLYMER
IVES
FINAL
PRODUCT
PREPARATION
CHAIN STABILIZER
TERMINATOR
.ACETAL
RESIN
Figure 4-1. A batch process for the production of acetal resins.
Reference 5, p.50)
-------
4.2.1.1 Purification Process. A purification process is
used to reduce the amount of water and methanol found in the
formaldehyde. Formaldehyde is transferred from storage (1)
into another vessel (2) for purification. Purification can be
achieved by washing the formaldehyde with an inert liquid,
such as a non-volatile polyol; by treatment with P205; by
freeze-trapping the impurities at a temperature slightly above
the boiling point of formaldehyde (-15°C or 5°F); by partial
polymerization to remove chain-transfer impurities; and by
producing hemiformal and then decomposing to purified
formaldehyde.1-2
4-2.1.2 Polymerization. Two polymerization processes
have been discussed in the literature. One polymerization
process involves using an inert solvent at room temperature.
In this process sparingly soluble, gaseous formaldehyde
(boiling point, -19°C or -2°F) is added continuously in
proportion to its polymerization rate. As a result, three
phases are present: formaldehyde gas, formaldehyde solution,
and solid polymer. In this process, the polymer is produced
by crystallization, which is the major driving force.1
Another polymerization process involves the addition of
anhydrous formaldehyde to a diluent. The diluent contains the
initiator, and the diluent mixture is being agitated. The
mass is maintained at sub-zero temperatures. Chain-
termination and transfer agents can be deliberately added to
control the molecular weight. These agents include water,
methanol, formic acid, acetic anhydride, and ethyl acetate.
The polymer reaction is very rapid and may be terminated by
stopping the monomer flow. Filtration and centrifugation can
then be used to isolate the polymer. The polymer may then be
washed and dried at moderate temperatures.
This polymerization process4 of formaldehyde involves an
addition reaction:
- (anionic)
4-4
-------
+O=CH2~- OCH OCHi (cat ionic]
Amines, amides, amidines, phosphines, and ammonium and
sulfonuim salts are used as anionic initiators. Lewis acids,
such as BF3 OEt2 or SNCL4, sulfuric or phosphoric acid, and
stable cations such as that in acetyl perchlorate are used as
cationic initiators.1
4 -2. 1.3 End-Capping. End-capping is the term used for
the process which replaces hydroxyl groups on the ends of the
polymer chain with alkyl or acyl groups. By replacing the
hydroxyl end groups, the polymer is less susceptible to
reactions at elevated temperatures; therefore, the polymer is
more thermally stable. An esterif ication reaction is achieved
by reacting the polymer with acetic anhydride to produce
acetate ester end groups. This reaction is generally achieved
with an excess of purified acetic anhydride that consists of
0.1 wt. % of sodium acetate catalyst.1 The heated mixture is
refluxed for 30 minutes.2 The mixture is cooled and the
granular product is recovered by filtration. The product is
then washed thoroughly with water, then washed with acetone,
and then dried.1-2
4 -2. 1.4 Finishing. Antioxidants and other stabilizers
are added to stabilize the polymer and the process is called
finishing (4). Extrusion is then used to form pellets from
the polymer.1
4-2.2 Acetal Copolymer Resin Process
Copolymerization of trioxane and cyclic ethers produces
acetal copolymers. The general steps of the process are
reported to involve formation of trioxane by trimerization of
formaldehyde, purification of trioxane, copolymerization,
stabilization by alkaline hydrolysis, and finishing.1 Figure
4-1 shows a basic process description for the acetal copolymer
resin process, which is discussed below.
4-5
-------
422.1 Trioxane Formation and Purification. An aqueous
solution of formaldehyde is fed from storage (1), and is
heated with a strong mineral acid (e.g., sulfuric acid) in
another vessel (2) to produce trioxane.1 The process involves
distillation of a 60-65% aqueous formaldehyde solution with 2%
sulfuric acid. Extraction with a water immiscible solvent,
such as trichlorobenzene or methylene chloride, can be used to
extract the trimer from the distillate. Fractional
distillation is then used for purification.2
4-2.2.2 Copolymerization. The copolymerization of
trioxane is achieved by an addition polymerization reacti.on.
The reaction requires a cationic initiator, such as boron
trifluoride etherates, fluroborates, aryldiazonium, iodine,
antimony trifluoride, and some Friedel-Crafts catalysts
(anhydrous aluminum chloride and similar metallic halides).
The initiation step causes ring opening of the trioxane; the
carbonium ion that forms is in equilibrium with formaldehyde.
Polymerization does not start until the equilibrium
concentration of formaldehyde is reduced. As a result, there
is an induction period that is dependent on the initiator and
the reaction procedure. The induction time can be reduced or
eliminated by the addition of free formaldehyde.1
Approximately 0.1 - 15 mole percent of a copolymer, such
as ethylene oxide or 1,3-dioxolane is used for the
polymerization reaction. In general, a polymer with 85 -
99.9% oxymethylene units, -OCH2, is produced.1
Several copolymerization processes have been reported in
the literature. A reciprocating interrupted-thread screw-
mixing device is used in the bulk polymerization process.2
Molten trioxane at 65 to 80°C (149 to 176°F) can be
polymerized using 0.005 - 0.025 wt % boron trifluoride dibutyl
etherate as. the initiator ar a contact time of less than 10
minutes.1 The polymer is recovered in a particle size that is
convenient for following reactions.2 Another continuous
process using molten trioxane uses a moving belt to form a
layer of polymer. This thin layer of polymer is broken to
4-6
-------
form granules. Polymerization can also be achieved by
spreading a film or droplets of trioxane on a rotating drum
whose surface is in contact with catalytic vapors. This thin
layer provides easy temperature control and easy product
handling. Suspension-polymerizaton is another process for
polymerizing trioxane. The molten trioxane droplets are
suspended into a continuous non-solvent liquid phase which is
being agitated.2
4.2.2.3 Stabilization. The copolymer is stabilized by
replacing the hydroxyl end groups with alkyl or acyl groups by
using alkaline hydrolysis. The hydrolysis treatment is done
at a temperature between 100 and 250°C (212 and 482°F) in an
aqueous - miscible organic solvent mixture. Water soluble
alkanols, e.g. isopropyl alcohol, are usually the organic
compounds that are used. A strong basic hydroxide, such as
ammonia, is added in the proportion of 0.01 - 0.2g/g of
copolymer. A contact time of 1-2 minutes is usually enough
time for complete hydrolysis. The temperature decreases and
the polymer precipitates out when excess water is added. Mild
thermal treatment can be used for end-capping. In this
process, formaldehyde evolves from the ends until a carbon-to-
carbon linkage is achieved.2
Another process for stabilization is a variation of the
solution technique. The raw copolymer is washed with an
aqueous alkali or an aqueous alcohol solution. Most of the
wash solvent is then removed and then the copolymer solution
is transferred to a continuous reactor that is well mixed and
at an elevated temperature. After the residual wash solvent
has been in adequate contact with the polymer it is vented.
The product is then formed into strands by extrusion. It is
then converted to pellets.
4-2.2.4 Finishing. Finishing (4) of the copolymer is
obtained by adding antioxidants and other stabilizers. Some
compounds used for this step are nitrogen heterocycles,
polyamides, polyurethanes, and dicyanodiamides. Commercial
pellets are then made from the copolymer by extrusion.1
4-7
-------
4.3 EMISSIONS
Figure 4-1 shows the possible emission streams, which are
designated by circled letters A and B. In the molding or
extrusion step of the process some of the resin can decompose
resulting in formaldehyde evolution. Therefore, an emission
stream of formaldehyde with air may be produced.1
The storage of aqueous formaldehyde prior to its use in
the process may release formaldehyde emissions (A). However,
the feed preparation step is the largest source of process and
fugitive emissions (B) / Table 4-2 provides the reported
rates for the acetal resin process.4-5
The organic liquid and solid wastes produced in the
process are treated by incineration. The aqueous wastes are
treated by an activated sludge plant.1
TABLE 4-2.
REPORTED EMISSION RATES FOR THE
ACETAL RESIN PROCESS
Category
Storage
Process
Pollutant
Formaldehyde
Formaldehyde
Emission Rate
(Ib/ton of 37% formaldehyde used)
0.04 - 0.06
0.18 - 0.74
Source: Reference 5.
4-8
-------
REFERENCES
1. Kirk-Othmer, Encyclopedia of Chemical Technology. Third
Ed., Acetal Resins, Vol. 1.
2. Polvacetals. S.J. Barker, and M.B. Price, American
Elsevier Publishing Co., Inc., New York, 1971.
3. Hawlev's Condensed Chemical Dictionary, llth Ed., Revised
by N. Irving Sax and Richard J. Lewis, Sr., Van Nostrand
Reinhold Company, New York, 1987.
4. 1991 Directory of Chemical Producers. United States of
America. Menlo Park, Calif.: Chemical Information
Services, Stanford Research Institute, 1991.
5. Locating and Estimating Air Emissions From Sources of
Formaldehyde. EPA-450/4-84-007e, March, 1984.
a. Hewlett, L. T. Formaldehyde Institute, Scarsdale, N.
Y., Letter to Tom Lahre, Office of Air Quality
Planning and Standards, U. S. Environmental
Protection Agency, Sept. 29, 1983.
b. Gilby, P.G., E.I DuPont de Nemours and Company,
Inc., Wilmington, Delaware, Letter to Tom Lahre
Office of Quality Planning and Standards, U.S.
Environmental Protection Agency, July 29, 1983.
4-9
-------
CHAPTER 5
MAJOR SOURCE FACILITIES
5.1 INTRODUCTION
The Toxic Release Inventory System (TRIS) data base has
been used to determine which phenolic, amino, and acetal
resin facilities are major sources. The CAAA of 1990
defines a major source as "... any stationary source or
group of stationary sources located within a contiguous area
and under common control that emits or has the potential to
emit considering controls, in the aggregate, 10 tons per
year or more of any [HAP] or 25 tons per year or more of any
combination of [HAP'S]." This definition implies that a
major source is defined by the individual and/or aggregate
source categories within a particular facility. If a single
source category within a facility exceeds or has the
potential to exceed the 10 or 25 tons per year emission
cutoff, then all other source categories within the facility
shall be treated as major sources. In addition, if the
source categories do not individually exceed the emission
threshold, but they collectively exceed or have the
potential to exceed this threshold, then each would be
considered a major source.
The 1991 Directory of Chemical Producers provides 129
facilities that produce one or more of these resins. These
facilities are operated by approximately 70 companies and
are given in Table l-l.
5-1
-------
5.2 MAJOR SOURCES
The TRIS data base did not contain any information on
12 of the facilities. These 12 facilities are given in
Table 5-1. The total HAP emissions (after control) from the
remaining 117 facilities are 9,582 tons per year. Of these
117 facilities, 50 were determined to be major sources*
based on their controlled emission data. The other 67
facilities were determined to be non-major sources based on
their controlled emission data. Table 5-2 lists the major
source facilities and the emissions that identify each
facility as a major source. The total HAP emissions and
technical contact for each facility are given in Table A-l
of the appendix.
The major source findings that are made in this report
do not represent a legal finding by the EPA. This
determination of major sources will be made by each facility
and the EPA as the emission standard is implemented. The
EPA's intent is to determine the potential impact of a
standard by understanding roughly how many major sources are
included in each category.
5-2
-------
TABLE 5-1. PHENOLIC, AMINO AND ACETAL
RESIN FACILITIES NOT GIVEN IN TRIS
Company
BTL Specialty
Resins Corporation
Commercial Products Co. ,
Inc.
DuPont Co. Polymer
Prods. Div.
The P. D. George Co.
Hugh T. Resins
Masonite Corporation
Neste Resins Corporation
Pioneer Plastics Corporation
Sybron Chemicals, Inc.
Ultraform Co.
Valspar Corporation,
McWhorter, Inc., Sub.
Location
Blue Island, IL
Hawthorne , NJ
Parker sburg, WV
St. Louis, MO
Long Beach, CA
Gulf port, MS
Andalusia, AL
Spokane, WA
Auburn , ME
Elmwood Park, NJ
Theodore, AL
Garland, TX
5-3
-------
TABLE 5-2. MAJOR SOURCE FACILITIES
Company
Akzo
American
Inc.
Coatings
Div.
Allied-
Signal Inc.
American
Cyanamid
Co.
BASF Corp.
Borden ,
Inc.
BTL
Specialty
Resins
Corp.
CL
Industries
Cook
Composites
& Polymers
Co.
Location
Louisville,
KY
Columbus , OH
Green
Island, NY
Kalamazoo,
MI
Wallingford,
CT
Charlotte,
NC
Detroit, MI
Louisville,
KY
Springfield,
OR
Malvern,
AR
Georgetown ,
IL
North Kansas
City, MO
Reason Major Source
Toluene = 16.2 tpy
Xylene (mixed isomers) = 46.1
tpy
Phthalic anhydride = 20.6 tpy
Total = 116 tpy
Glycol ethers =17.7 tpy
Methyl ethyl ketone =14 tpy
Total =46.9 tpy
1,1,1-trichloroethane =14.3
tpy
Total =17.8 tpy
Methanol = 33.0 tpy
Total = 38.6 tpy
Formaldehyde =19.4 tpy
Methanol = 29.9 tpy
Total =64.7 tpy
Formaldehyde = 22.5 tpy
Total =29.5 tpy
Xylene (mixed isomers) = 16.8
tpy
Methyl ethyl ketone =11.3 tpy
Total = 39.1 tpy
Methanol = 11.3 tpy
Total =26.4 tpy
Methanol =11.3 tpy
Total = 13.0 tpy
Formaldehyde = 53.3 tpy
Total =68.1 tpy
Epichlorohydrin = 10.1 tpy
Toluene =19.6 tpy
Total =45.0 tpy
Glycol ethers =11.9 tpy
Methyl methacrylat = 20.2 tpy
Styrene = 102.6 tpi
Xylene (mixed isomers) =29.6
tpy
Total = 184.7 tpy
5-4
-------
TABLE 5-2.
MAJOR SOURCE FACILITIES
(Continued)
Company
Dexter
Packaging
Products
Dyno
Polymers
Inc.
Exxon Chem.
Co. Houston
Plant
General
Electric
Co.
Georgia-
Pacific
Corp.
Location
Birmingham,
AL
White City,
OR
Houston, TX
Coshocton,
OH
Louisville,
MS
Taylorsville
MS
Russellville
SC
Crossett, AR
Lufkin, TX
Columbus, OH
Conway , NC
Albany, OR
Reason Major Source
Methyl ethyl ketone =24.2
Xylene (mixed isomers) = 29
tpy
Total =58.3 tpy
tpy
.5
Formaldehyde = 12.7 tpy
Methanol = 104.0 tpy
Total = 117.6 tpy
Propylene oxide = 10.2 tpy
Total = 34.1 tpy
1, 1, 1-trichloroethane = 54
Toluene = 10.9 tpy
Total =77 tpy
tpy
Formaldehyde = 22.1 tpy
Total = 22.6 tpy
Methanol =17.0 tpy
Total = 20.9 tpy
Formaldehyde = 25.3 tpy
Methanol = 204.5 tpy
Total = 232.2 tpy
Methanol = 177.9 tpy
Formaldehyde = 49.9 tpy
Total = 229.6 tpy
Formaldehyde = 17.2 tpy
Total = 24.8 tpy
Methanol =42.3 tpy
Formaldehyde = 22.6 tpy
Total =65.8 tpy
Formaldehyde = 20.8 tpy
Methanol =11.2 tpy
Total = 33.2 tpy
Formaldehyde = 27.9 tpy
Methanol = 301.8 tpy
Total = 330.4 tpy
5-5
-------
TABLE 5-2.
MAJOR SOURCE FACILITIES
(Continued)
Company
Location
Reason Major Source
Guardsman
Products,
Inc.
Grand
Rapids, MI
Toluene =13.3 tpy
Xylene = 21.5 tpy
Total =55.3 tpy
Hercules
Inc.
Operations
Div.
Milwaukee,
WI
1,2-dichloropropane =139 tpy
Total =141 tpy
Savannah, GA
Dichloromethane =26 tpy
Total =27.5 tpy
Hercules
Inc. Resins
Div.
Hattiesburg,
MS
Toluene = 320 tpy
Total = 342 tpy
Hoechst
Celanese
Corp.
Bishop, TX
Formaldehyde = 340 tpy
Methanol = 515 tpy
Acetaldehyde = 19 tpy
Benzene = 14 tpy
Total = 894 tpy
Insulating
Materials
Inc.
Schenectady,
NY
Methyl ethyl ketone = 29.8 tpy
Toluene = 40.8 tpy
Xylene(mixed isomers) = 17.5
tpy
Total =94.4 tpy
Lawter Int.
Inc.
Moundville,
AL
1,1,1-trichloroethane = 29.4
tpy
Total =34.6 tpy
Minnesota
Mining &
Manuf. Co.
Cordova, IL
Dichloromethane = 17.5 tpy
Formaldehyde = 12.9 tpy
Hydrogen fluoride = 40.9 tpy
Toluene =19.4 tpy
Total = 116 tpy
Cottage
Grove, MN
1,1,1-trichloroethane =14.1
tpy
1,1,2-trichloroethane = 15.0
tpy
Methanol = 156.7 tpy
Toluene = 502.0 tpy
Methyl ethyl ketone = 23.2 tpy
Total = 737 tpy
5-6
-------
TABLE 5-2.
MAJOR SOURCE FACILITIES
(Continued)
Company
Monsanto
Co.
Neste
Occidental
Petroleum
Corp.
Perstorp,
Inc.
PPG Ind.
Inc.
Location
Addyston, OH
Springfield,
MA
Moncure , NC
Springfield,
OR
Winnfield,
LA
Niagara
Falls, NY
North
Tonawanda ,
NY
Florence, MA
Circleville,
OH
Oak Creek,
WI
Reason Major Source
Acrylonitrile = 32 tpy
1, 3 -Butadiene = 13 tpy
Methanol =10.6 tpy
Styrene =120 tpy
Total = 183 tpy
Acetaldehyde = 14.2 tpy
Methanol = 28.6 tpy
Vinyl acetate = 30.9 tpy
Total =85.1 tpy
Methanol = 115.2 tpy
Total = 126.5 tpy
Methanol =58.5 tpy
Total =73.6 tpy
Formaldehyde = 11.9 tpy
Methanol = 96.5 tpy
Total = 115.5 tpy
Tetrachloroethylene = 11.2
Total =36 tpy
tpy
Phenol = 10.9 tpy
Total =21.1 tpy
Formaldehyde =35 tpy
Total =35 tpy
Methyl methacrylate = 10.6 tpy
Xylene (mixed isomers) = 15.6
tpy
Toluene = 34.2 tpy
Methyl isobutyl ketone =13.4
tpy
Total = 93 tpy
Methyl ethyl ketone = 11.6
Xylene (mixed isomers) = 10.
tpy
Methyl isobutyl ketone = 18
tpy
Total =52.7 tpy
tpy
2
.5
5-7
-------
TABLE 5-2.
MAJOR SOURCE FACILITIES
(Continued)
Company
Schenectady
Chemicals,
Inc.
Simpson
Timber Co.
Spaulding
Composites
Co . Inc .
Synthron,
Inc.
Unilever
U.S. Inc.,
National
Starch &
Chemical
Co.
Westing-
house
Electric
Corp.
Location
Rotterdam
Junction, NY
Portland, OR
Tonawanda ,
NY
De Kalb, IL
Morganton,
NC
Salisbury,
NC
Hampton, SC
Reason Major Source
Phenol =16 tpy
Formaldehyde = 22.7 tpy
Xylene (mixed isomers) = 171.8
tpy
Total = 232.3 tpy
Formaldehyde =50.7 tpy
Methanol = 508.2 tpy
Total = 560 tpy
Methanol =25 tpy
Total = 28.0 tpy
Methanol = 21.3 tpy
Total =23.3 tpy
Formaldehyde = 12 tpy
Total =18.3 tpy
Allyl chloride = 12 tpy
1, 2-dichloroethane = 198 tpy
Total = 228.9 tpy
Methanol = 2550 tpy
Methyl ethyl ketone =44 tpy
Toluene = 160 tpy
Xylene (mixed isomers) = 32.5
tpy
Glycol ethers =47.5 tpy
Total = 2854 tpy
5-8
-------
APPENDICES
Facility Emissions and Contacts and Worksheets
Appendix A presents facility emissions and contacts
identified. Table A-l provides the total HAP emissions and a
phone number for each facility. Appendix B contains the
worksheets with the emissions data for each compound by
facility.
It should be noted that Neste Resins Corporation bought
Chembond Corporation, Dyno Polymers Incorporated bought RVP
Corporation and Brancor, and Courtaulde bought DeSoto
Aerospace. Therefore, the TRIS information for the Winnfield,
Louisiana facility of Neste Resins was obtained using Chembond
Corporation as the company name. The information for the
other facilities was obtained using Neste Resins Corporation.
In addition, the TRIS information used for Dyno Polymers
Incorporated in White City, OR, was that obtained for the RVP
Corporation, and the information for the Dyno Polymers
Incorporated in Virginia, MN, was that obtained for Dyno
Polymers (Minnesota) Incorporated. The information used for
Courtaulde was that obtained from DeSoto.
A-l
-------
APPENDIX A
FACILITY EMISSIONS
AND CONTACTS
A-2
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY
Company
==========================
Akzo America Inc.,
Reliance Universal
Inc., Sub.
Allied-Signal
_
American Cyanamid
Co. Polymer Prod«?
Div.
AMETEK, Inc.
Apex Chemical Corp.
Ashland Oil,
Inc.
Auralux Corp.
~
Location
======================
Columbus, OH
Louisville, KY
Green Island,
NY
Charlotte, NC
Kalamazoo, MI
Wallinford, CT
Wilmington, DE
Elizabethport,
NJ
Calumet City, IL
_
Cleveland,
OH
Norwich, CT
=================
Total
HAP
Emissions
(tpy)
46.9
116.3
17.8
29.5
38.6
64.7
0.8
20.8
3.1
1.5
^^^ i .--^_.___^_
Technical
Contact
..
George R.
Pilcher
Mike L.
Wright
Tom A.
Ragosta
Heath Howie
Dr. Robert L.
Green
C. J.
Cappannari
Leon
Debrabander
George
Hairston
Charles M.
Kriston
Donald J.
Matson
Raymond V.
Kusiak
===========================,
Phone Number
(614) 294-3361
(502) 367-6111
(518) 270-0322
(704) 394-4361
(616) 349-6677
(203) 284-4210
(302) 995-0463
(908) 354-5420
(708) 891-8230
(216) 961-4690
(203) 886-2616
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
BASF Corp.
Borden, Inc.
Location
Anaheim, CA
Detroit, MI
Demopolis, AL
Diboll, TX
Fayetteville,
NC
Freemont, CA
Kent, WA
La Grande, OR
Louisville, KY
Missoula, MT
Sheboygan, WI
Springfield,
OR
Total
HAP
Emissions
(tpy)
11.6
39.1
7.6
8.2
18.1
3.3
3.8
4.9
26.4
8.5
11.8
13.0
Technical
Contact
John G. Zomer
Allen C.
Kinsler
Kim B.
Townsend
Gary Roberts
J. M. Barker
Frank Tejera
Bruce A.
Johnson
Eric P.
Steppling
Harold G.
Armstrong
Douglas R.
Anderson
W. B. Miner
Greg
Wilberger
Phone Number
(714) 879-4600
(313) 861-1000
(205) 289-0840
(409) 829-5566
(919) 483-1311
(415) 657-4500
(206) 852-9300
(503) 963-7155
(502) 449-6280
(406) 728-2690
(414) 458-5545
(503) 746-8461
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
, Inc. Perkins
ub.
, Inc. Acme
Corp.
S Corp.
e Resins Div.
ecialty
Corp.
I Resin Corp.
L, Inc.
il Prods. Div.
Location
- "'.
Alexandria, LA
High Point, NC
Forest Park,
IL
Eugene , OR
Malvern, AR
Blue Island, IL
Toledo, OH
Columbus, OH
Carpentersville,
IL
Forest Park, GA
Lynwood , CA
===^^==
Total
HAP
Emissions
(tpy)
1.5
0.005
3.9
8.5
68.1
NT1
1.4
8.6
6.0
12.6
4.7
Technical
Contact
"
Gary Sherwood
Diane Strayer
Emmett Dunham
David
Carstens
Urban W.
Horinek
Dean E.
Meadows
Barbara
Truelsen
Barbara
Truelsen
Barbara
Truelsen
Phone Number
========;
(318) 445-6115
(206) 455-4400
(312) 343-1900
(503) 343-2111
(501) 332-5293
(201) 647-4700
(419) 244-5856
(614) 445-7177
(708) 551-3182
(708) 551-3182
(708) 551-3182
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
CL Industries
C.N.C. International
L. P.
Commercial Products
Co. , Inc.
Cook Composites &
Polymers
Courtaulde U.S. Inc.
(DeSoto Aerospace
Coatings)
D.B. Western New
Mexico Adhesives
Delta Resins &
Refract. Corp.
The Dexter Corp.
Location
Georgetown, IL
Woonsocket, RI
Hawthorne , NJ
North Kansas
City, MO
Berkeley, CA
Las Vegas, NM
Detroit, MI
Milwaukee, WI
Birmingham,
AL
Waukegan, IL
======
Total
HAP
Emissions
(tpy)
45.0
5.7
NT1
184.7
14.5
-
2.5
3.0
58.3
21.0
Technical
Contact
Arman
Melikyan
Timothy L.
Haradon
Cecilia
Turula
Craig
Bostwick
Graham Swann
Jesse Adams
David
Horstman
David
Horstman
Stephen D.
Morris
Stephen D.
Morris
Phone Number
(217) 662-2136
(401) 769-6100
(201) 427-6887
(816) 391-6343
(510) 526-1525
(505) 425-5932
(313) 368-7000
(313) 368-7000
(708) 623-4200
(708) 623-4200
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
>
Company
Dock Resins Corp.
DuPont Co. Polymer
Prods. Div.
Dyno Polymers
(Minnesota) Inc.
(Brancor)
Dyno Polymers Inc.
(RVP Corp.)
Eastern Color &
Chemical Co.
Exxon Corp.
General Electric
Co.2
The P. D. George Co.
ueorgia faciric
Corp.
=========^== ===_.
Location
Linden , NJ
Parkersburg, WV
Virginia, MN
White City,
OR
Providence, Rl
Houston , TX
Coshocton ,
OH
St. Louis,
MO
Albany, OR
Columbus , OH
Conway, NC
Crossett, AR
=====
Total
HAP
Emissions
(tpy)
0.6
NT1
1.5
117.6
4.5
34.1
76.9
NT1
330.4
65.8
33.2
229.6
Technical
Contact
Joseph
Barbanel
Walt Stewart
Lester Pernu
Thomas M.
Gilsdorf
Truman Clary
J. Paul Reed
Larry A.
Hicks
Thomas J.
Moehl
S. A. Correll
Steve A.
Correll
Steven A.
Correll
Phone Number
(908) 862-2351
(304) 863-4274
(218) 749-6440
(503) 826-2651
(401) 331-9000
(713) 671-8676
(614) 623-5328
(314) 621-5700
(503) 928-4171
(404) 521-4651
(404) 521-4651
(404) 521-4651
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Georgia-Pacific
Corp. (Continued)
Location
Elk Grove, CA
Eugene , OR
Grayling, MI
Louisville, MS
Lufkin, TX
Peachtree City,
GA
Port Wentworth
Russellville, SC
Taylorsville, MS
Ukiah, CA
Total
HAP
Emissions
(tpy)
5.3
9.4
0.8
22.6
24.8
5.6
11.5
232.2
20.9
6.5
Technical
Contact
S. A. Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steven A.
Correll
Steve A.
Correll
Phone Number
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
(404) 521-4651
00
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Georgia-Pacific
Corp. (Continued)
Guardsman Products,
Inc.
Hercules Inc.
Operations Div.
Hercules Inc.
Resins, Div.
Heresite Protective
Coatings Inc.
Hickson DanChem
Corp.
Hoechst Celanese
Corp.
==^==^===
Location
Vienna , GA
Grand Rapids, MI
Chicopee, MA
Milwaukee, WI
Portland, OR
Savannah , GA
Hattiesburg, MS
Manitowoc, WI
Danville, VA
Mount Holly,
NC
Bishop, TX
Total
HAP
Emissions
(tpy)
15.7
55.3
11.5
140.7
1.6
27.5
342.1
1.9
18.0
2.3
894.1
Technical
Contact
Steven A.
Correll
Bruce L.
Katje
Kurt S. Moore
Charles W.
Fisher Jr.
Jack L.
Coalson
C. M.
MacDonald
Charles
Jordan
D. Edward
Blake
K. W. Kunkle
Robert J.
Cundiff
Frank L.
Salinas Jr.
Phone Number
(404) 521-4651
(616) 957-2600
(413) 536-6426
(414) 461-4000
(503) 224-1200
(912) 964-2121
(601) 545-3450
(414) 684-6646
(804) 797-8116
(704) 822-2113
(512) 584-6396
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Hugh J. Resins
Insulating
Materials
IVAX Corp. IVAX
Ind., Inc. Textile
Products Div.
Lawter International
Masonite Corp.
Minnesota Mining and
Manufacturing Co.
Monsanto Co.
National Casein Co.3
" " - -
Location
Long Beach,
CA
Schenectady, NY
Rock Hill, SC
Moundville, AL
Gulf port, MS
Cordova, IL
Cottage Grove,
MN
Addyston, OH
Springfield, MA
Chicago, IL
Tyler, TX
======
Total
HAP
Emissions
(tpy)
NT1
94.2
3.5
34.6
NT1
116.0
736.5
182.9
85.1
0.3
0.3
Technical
Contact
Allan L.
Drake
Christine
Keenan
Andrew
Kwiatkowski
Mark A.
Sattizahn
Thomas F.
Baltutis
D. R. Day
C. L. Kupstas
Bob Burns
Frank Dalhoff
Phone Number
(310) 432-5918
(518) 395-3375
(803) 366-9411
(205) 371-2235
(601) 863-5772
(309) 654-2291
(612) 458-2000
(513) 467-2217
(413) 730-2454
(312) 846-7300
(903) 877-3443
3>
I»
O
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Neste Resins Corp.
(Chembond)
Occidental Petroleum
Corp.
Perstorp, Inc.
Pioneer Plastics
Corp.
.
Location
Andalusia,
AL
Moncure, NC
Spokane, WA
Springfield,
OR
Toledo, OH
Winnfield, LA
Kenton, OH
Niagara Falls,
NY
North Tonawanda,
NY
Florence, MA
Auburn , ME
=====:
Total
HAP
Emissions
(tpy)
NT1
126.5
NT1
73.6
2.6
115.5
9.7
36.5
21.1
35.0
NT1
Technical
Contact
R. W.
Humphreys
Dean A.
Trotter
Jack D.
Wickham
Jimmy
Atherton
Gerald E. Ice
H. E. Pierce
Charles E.
Noll
Karl B.
Weckstrom
Tom Crosby
Phone Number
(205) 222-7581
(919) 542-2526
(509) 924-8000
(503) 746-6501
(419) 726-5013
(318) 628-2138
(419) 675-5300
(716) 278-7370
(716) 696-6343
(413) 584-2472
(207) 784-9111
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Plastics Eng.
Co.
Plastics
Manufacturing Co.
PMC, Inc.
PPG Ind. , Inc.
PPG Ind. , Inc.
Reichhold Chemicals,
Inc.
Resinall Corp.
Rhone-Poulenc Inc.
Schenectady
Chemicals, Inc.
SEQUA Corp.
Location
Sheboygan, WI
Dallas, TX
Fords, NJ
Circleville, OH
Oak Creek, WI
Bridgeville, PA
Severn, NC
Louisville, KY
Rotterdam
Junction, NY
Schnectady, NY
Chester, SC
Total
HAP
Emissions
(tpy)
0.9
4.5
2.6
5.4
93.1
52.7
4.3
3.9
22.3
232.3
19.7
4.7
Technical
Contact
Dave Griffin
Michael L.
Miller
Charles
Horberg
David Weber
Maryann
Lepone
Cameranesi
R. S. Roth
Marty Evans
O. R. Spencer
Thomas
Windish
H. G. Wertz
Joseph M.
Sanocki
Phone Number
(414) 458-2121
(214) 330-8671
(908) 738-4300
(614) 474-3161
(414) 764-6000
(412) 257-6908
(919) 585-1445
(502) 635-8843
(518) 370-4200
(518) 370-4200
(803) 385-5181
ro
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Simpson Timber Co.
Southeastern
Adhesives Co.
Spaulding Composites
Co., Inc.
Spurlock Co.
Stuart-Ironsides ,
Inc.
Sybron Chemicals
Inc.
Synthron, Inc.
Ultraform Co.
Unilever U.S. , Inc.
National Starch &
Chemical Co., Sub.
Location
Portland, OR
Lenoir, NC
Ridgeway, VA
De Kalb, IL
Tonawanda, NY
Waverly, VA
Columbus, OH
Elmwood Park, NJ
Well Ford, SC
Morganton, NC
Theodore, AL
Salisbury, NC
Total
HAP
Emissions
(tpy)
559.6
5.5
6.5
23.3
28.0
4.4
0.03
NT1
6.5
18.3
NT1
0.5
228.9
Technical
Contact
Walter F.
McBride
Don Barrier
Richard Wells
Gregory A.
Stubbs
Kirk
Passopulo
John F. Pike
Michael R.
Lenkiewicz
James W.
Gilpin
Richard D.
Franklin
Phone Number
(503) 289-1111
(704) 754-3493
(703) 956-3176
(815) 758-8181
(716) 692-2000
(804) 861-2479
(708) 655-8671
(201) 791-0981
(803) 439-6333
(704) 892-3283
(205) 653-0050
(704) 633-1731
CO
-------
TABLE A-l. EMISSIONS AND TECHNICAL CONTACT BY FACILITY (Continued)
Company
Union Carbide
Corp . 4
Valentine Sugars,
Inc.
Valspar Corp.
McWhorter, Inc.,
Sub.
Westinghouse
Electric Corp.
West Point-
Pepperell, Inc.
Griftex Chemicals,
Sub.
Location
Somerset, NJ
Lockport , LA
Garland, TX
Kankakee, IL
Hampton, SC
Manor, PA
Opelika, AL
Total
HAP
Emissions
(tpy)
0.1
9.4
NT1
11.1
2853.5
12.2
4.1
Technical
Contact
Dr. Ken Szoc
Tom
Wilczewski
William
Stewart
H. K. Wagers
Angelo
Garfalo
J. M.
Birdsong
Phone Number
(908) 563-5764
(504) 532-2541
(214) 276-5181
(612) 332-7371
(803) 943-2311
(412) 864-8211
(404) 645-4000
1 NT = Not in TRIS database.
General Electric Company may no longer be a manufacturer of formaldehyde-based
ITGS ins
National casein facilities may no longer be manufacturers of formaldehyde-based
resins: they may only be involved in storage and distribution.
Union Carbide Corporation facility may have been bought by Georgia-Pacific.
-------
APPENDIX B
WORKSHEETS
B-l
-------
Worksheets
CO
i
| Facility/Location
1
t
| Akzo/Columbus OH
+
| Akzo/Louisvilte KY
+
(Altied-Signal/Green Island NT
| Amer. Cyanamid/Charlotte NC
+
| Amer. Cyanamid/Katamazoo HI
+ ... ....
| Amer. Cyanamid/Uall igford CT
+
| AMETEK/Uilmington, DE
+ . ....
| Apex Chem./Elizabethport NJ
+ .
| Ashland Oil/Calumet City, IL
+ - ..
| Ashland Oil/Cleveland OH
+ . .
| Aura lux/Norwich CT
+
| BASF/Anaheim CA
+
| BASF/Detroit HI
+ .
| Borden/Demopois AL
| Borden/Oiboll TX
+ -
| Borden/Fayettevi 1 1 NC
+
| Borden/Freemont CA
>-
| Borden/Kent UA
JAcetaldehyde (Acetonitrile JAcrylamide (Acrylic acid (Acrylonitrile JAllyl chloride JAniline JAntimony Conpds I Asbestos Iflenzene
I Ibs/yr | Ibs/yr j Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr j Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr
1 1 1 1 1 | || | ,
1 1 1 1 1 1 II ||
1 1 'I 1 1 II 1 181 |
1 1 1 1 1 1 II ||
1 1 1 998| | | | , , ,
1 1 1 0| 2| 1 | ,| , J
1 1 1 1 1 1 II ||
''III 1 II o| I
1 1 I | 10 | | || , ,
1 1 1 1 1 1 II ||
'III 1 II it
1 ', 1 1 11 I || ||
1 1 I | 20 | | || , ,
'iiii i ii i ;
1 1 I 1 1 1 II II
i i i i i i ii , ;
1 ! 1 1 1 1 II | I
1 i i i i i ii i i
-------
CO
l
CO
Borden/La Grande OR
I i , * ..... * .............. + ............... + ........ + ................ + ........ +.
' ' '
; ................................ ............. ............. ........... ......... ' ii i i
| Borden/Louisville KY I i , ............ + ............... + ........ + ................ + ........ +
' ........
,
............. ............. J ........... ! ............. I . ' i
| Borden/Missoula HT I i . ......... + ............... + ........ + ................ + ........ +
; ................................ I ............. ! ............. i ........... ].. ' i ii ii .......
| Borden/Sheboygan UI I i . + .............. + ............... + ........ + ................ + ........ +.
' i
I Borden/Springfietd OR | i . """* + * + + + +
| Borden. Perk ins/Alexandria LA | | ! * + + + + + +
| Borden, Perk ins/High Point NC I | ! ? * * + + + + .
; ' I ! J i i ii i ,
| Borden,Perkins/Uest Memphis AR | | , + + + + .*
| Borden,Acme/Forest Park IL | | , * * + + + +
| Dyno(Brancor)/Virginia HN | I j * + + + + + +
| Brand-S,Cascade/Eugene OR | | , * * * + + + +
+ - ' 'I I I Ii .
I
.
I
i
I
I Capital/Colunbus OH
I i
| i
I Cargill/CarpentersviUe IL I i
; ................................ * ............. !
| Cargill/Forest Park GA I |
; ................................ * ............. ;
I Cargill/Lynwood CA
I ........... *
' ........... ;
.............. *
'
+ ........ +
i i
+ ........ +
U99
-------
j Facility/Location JAcetaldehyde |Acetonitrile (Acrylamide |Acrylic acid (Acrylonitrile |AUyl chloride (Aniline (Antimony'coopds (AsbestoslBenzene"
I L.!b!'vL. ' lbs/yr ' lbs/yr ' lbs/yr ' lbs/yr ' lbs/yr I lbs/yr I lbs/>"- I lbs/v I lb*/y
CL Ind/Georgetown IL
274
CMC Int./Uoonsocket RI |
| Commercial Prod/Hawthorne NJ
| Cook Comp/North Kansas City HO | |^ | | i i .
| Courtautde/Berkeley CA | | I 0 I I I i
| DB Uestern/Lcs Vegas NH
CO
Delta Resins/Detroit HI |
| Delta Resins/Hi Iwaukee UI |
Dexter /Birmingham AL
1
Dexter/Waukegan IL
I
| Dock Resins/Linden NJ |
5 |
1 |
| DuPont/Parkersburg WV | |
| Dyno/Uhite City OR | |
t . ... +
| Eastern Color/Providence RI | |
| Exxon/Houston TX | |
| General Elec./Coshocton OH | |
| PD George/St. Louis HO | |
+ .... ...... + . +_
| Georgia-Pacific/Albany OR I I
164 | |
+ -i-
I I
+ «.-
-------
| Georgia-Pacific/Colunbus OH |
| Georgia-Pacific/Conway MC |
| Georgia-Pacific/Crossett AR |
| Georgia-Pacific/Elk Grove CA |
| Gerogia-Pacific/Eugene OR |
| Georgia-Pacific/Grayling Ml |
I
!
M^*^
pi;;ziiii::;i:;;:::i:ii:::::;r:;f::
i i i i ; ; ; ;
,
! * * * * + +
| Georgia-Pacific/Louisville MS |
| Georgia-Pacific/Lufkin TX |
(Georgia-Pacific/Peachtree City G|
|Georgia-Pacific/Port Wentworth G|
|Georgia-Pacific/Russellville SC |
(Georgia-Pacific/Taylorsville MS |
| Georgia-Pacific/Ukiah CA |
| Georgia-Pacific/Vienna GA |
| Guardsman/Grand Rapids MI |
| Hercules/Chicopee MA |
+ ...
- - - - +_
| Hercules/Milwaukee UI |
| Hercules/Portland OR |
I
'
I I
.............
.............
...........
i ,
J ........... |
i .
! ........... ]...
- + + --
I I
- + + --
I I
-+ +--
I I
I I
+ ........ +
ii
...........
,
! ........... ]
,
' '
-------
j Facility/Location |Acetaldehyde (Acetonitrile JAcrylaniide (Acrylic acid (Acrylonitrile
] I lbs/yr I lbs/y I lbs/V I lbs/yr I lbs/yr \ lbs/yr
| Hercules/Savannah GA I I | i , ,
' lbs/yr '
* ........ *
lbs/yr i
*
| Hercules Resins/Hattiesburg MS | | j i i .
| Hersite/Hanitowoc UI | | j i , !
| Hickson/Oanville VA | | i i , t
* ........ *
* ........ *
(Hoechst Celanese/Hount Holly NC I
,
I
I
| Hoechst Celanese/Bishop TX | 38000 | | I I I
| Hugh J. Resins/Long Beach CA | I I I I I
«^ | Insulating Mat/Schenectady NY | | I i i
| IVAX Corp/Rock Hill SC | | j i . !
+ + + ' ' I
| Lawter Int/Moundville AL | | | i , .
* + + + + +
| Masonite/Gulfport MS | | i .
''' ........ ..........
I
I ........ I
* ........ *
11
""*
* ........ *
'I
* ........ *
0 |
*
* ........
| 28000
* ........
Gro-ve HN I I
| Honsanto/Springfield HA | 28300 |
| National Casein/Chicago IL | I
* ................................ ' ............. !
| National Casein/Tyler TX | |
| Neste Resins/Andalusia AL I I
1
I ....... izi'j .............. I
I 1 ............. i ........ ^"i
| | 520 j 250 |
I i , .
! ........... ! ............. J .............. !
| i , .
i i , *
I ! I
J
* ........
I "09
* ........
J ........
* ........ *
] i
"+
+
-------
I Neste Resins/Morxcure NC |
| Neste Resins/Spokane UA |
| Neste Resins/Springfield OR |
| Neste Resins/Toledo OH |
| Neste Resins/Uinnfield LA |
| dec(dental/Kenton OH |
| Occidental/Niagara Falls NY |
| Occidental/North Tonawanda NY |
| Perstorp/Florence MA |
| Pioneer Plastics/Auburn ME |
| Plastics Eng/Sheboygan UI |
| Plastics Manuf/Dallas TX |
| PMC Inc/Fords NJ |
| PPG ind/Circleville OH |
| PPG Ind/Oak Creek UI |
| Reichhold/Bridgeville PA |
| Resinall/Severn NC |
| Rhone-Poulenc/Louisville KY I
| . * ...... * ............... + ........ +
! ............. ! ........... ! ............. ! ....... ! ' i
......... * ........ *
+ ........ + ........
i i
I i
! ............. !
| I
I i
'
.
].... '
i +
........ * ................ + ........ + ........
.1... i i i i i i
j i i ill i i ; ; ;
..; ; ; ' ""I ; ; ; ;i
. 1 ; ; p; ; ;
..! i iiiiii: i i i i i
..j i ! i :i::::i::i:::::i::i::
iiijii:p:::i::::j:;;:::;i:::i:::;::r:;r:
]II i i »i i ; ; ; ;
; i j j ; j ; ; ;
i i i i \ j j j
1 i M «S| j ; ; ; ;
-------
03
I Facility/Location (Acetaldehyde |Acetonitrile (Acrylamide (Acrylic acid
1 | lbs/yr | Ibs/yr j lbs/yr | lbs/yr
(Schenectady/Rotterdam Junction N| | | i
| Schenectady/Schenectady NY | | 1 i
| SEQUA/Chester SC | | 1 5 1 3
| Simpson Timber/Portland OR | | | i
+ + + «. +
| Southeastern Adh/Lenoir NC | | | |
| Southeastern Adh/Ridgeway VA | | 1 i
| Spaulding Comp/De Kalb 1L | | | i
| Spaulding Comp/Tonawanda NY | | 1 i
| Spur lock/Waver I y VA | | I i
| Stuart- Ironsides/Columbus OH | | | i
* + + + +
| Sybron Chem/ElmMood Park NJ | | | i
* + + + +
| Sybron Chen/Well ford SC | | | i
| Synthron/Horganton NC | | 1 i
| Ultraform/Theodore AL | | 1 i
(Unilever Nat Starch/Salisbury NC| | | 326 | 1215
* + + + +
| Union Carbide/Somerset NJ | | | i Q
| Valentine Sugars/Lockport LA | | | |
+ ..... ^
| Valspar.McUhorter/Garland TX | | | i
(Acrylonitrile |Allyl chloride (Aniline (Antimony Compds | Asbestos | Benzene
I Ibs/yr | lbs/yr j Ibs/yr j Ibs/yr | lbs/yr | lbs/yr
1 1 II II
1 . 1 II II
1 1 II II
* 1 II II
'I II II
'I II II
1 1 II II
1 1 1 509 | ||
'I II II
* +--- + +
* * + + + +
II II | ,
* * + + + *
1 1 II || 1498
'I II II
' I II II
I 11763 | 2A002 | | | 1
1 21 I II |(
'I II II
'I II I I
-------
i "'"'" r~^
| Valspar.Mcwhorter/Kankakee IL I i , + + + + + «...
; * ! ; ].. i ' ii o i ,
| Westinghouse Elect/Hampton SC | | , * + + + +
| Uestinghouse Elect/Manor PA I i , * + * +
\ \ I I i
....
|Uest Point-PepperelI/Opelika AL | | , + + + + +
""
164 | 181 | 44493
°-628 I 0.082 | 0.0905 (22.2465
"* + + -f -f
CO
I
-------
j Facility/Location JBenzoic trichloride JBenzyl chloride iBiphenylH.Vbutadiene
J ................................ ] tb°^ ] lbs/yr I lbs/yr I lbs/y
| Akzo/Coluifcus OH | I I! -
| Akzo/Louisville KY | | III
|Allied-Si9nal/Gr-en Island NY | | I j j
| Ibs/yr | lbs/yr | lbs/yr | Ibs/yr
....... * .............. *
I I ........ I .............. *
1 ........ 1 ........ 1 .............. +
Amer. Cyanamid/Charlotte NC
I
Araer. Cyanamid/Kalamazoo HI
Amer. Cyanamid/Wallisford CT
I
CD
I
O
AMETEK/Wihnington, DE
Apex Chem./Elizabethport NJ
Ill |
I i I ........ ? .............. *
| Ashland Oil/Calumet City. IL | | | j j ............... j ........ * ........ * .............. *
* ................................ + .................... + ................ + ........ + .............. { ............... | I ' I
| Ashland Oil/Cleveland OH | | III ......... 1 ........ 1 ........ * .............. *
| Auralux/NorMich CT | | | | | ..... ! ........ * ........ * .............. *
| BASF/Anaheim CA | J j ........ J .............. j ............... J ........ j ........ J .............. J
| BASF/Detroit Ml | | J J ........... J ............... J ........ J ........ J .............. J
|
Borden/Demopois AL
I
Borden/Diboll TX | | III I ..............
| Borden/Fayettevill NC | | i i | * ....... * ........ * .............. *
| Borden/Freemont CA I I i i , , + ....... * .............. +
+ ...................... . ......... ........... . J i i i
Borden/Kent UA
,
-------
| Borden/La Grande OR I
| Borden/Louisvilte KY |
| Borden/Missoula MT |
| Borden/Sheboygan Ul I
+----------_-.__
.- , + _
| Borden/Springfield OR I
+-----------..-__
. - + -
| Borden,Perkins/Alexandria LA |
+----------..-...
-+--
| Borden,Perkins/High Point NC |
| Borden,Perkins/Uest Memphis AR |
| Borden,Acme/Forest Park IL |
| Oyno(Brancor)/Virginia HN |
+ -.--.____.
--...-..._....+_.
| Brand-S,Cascade/Eugene OR I
chloride I8jphenyill.3-but.dien. |cadmiun, con^ds |catechollchtorinejcht"oroben;ene"ichioro,ne;hane"
>S^r | lbS/yr I lbs/Vr I Ibs/yr | Ibs/yr | Ibs/yr | ibs/yr | ,bs/yr
+ * * * ! ! !
! ] J -.I I
« . "1 ; ; ; ;
...-"X^:i:::;;:i:;;:ii::;T ; ;
j j ;. i ' i i
; i i j ""] ;
11 ' i ""i i i
i i
i iii i
I
|
I
| CargiU/Carpentersville IL |
| Cargi I I/Forest Park GA |
| Cargitl/lynwood
CA
-------
I
ro
[1:^
| CL Ind/Georgetown IL | i . . * * * * +
| CMC Int./Woonsocket RI | j j 499 1 1 + * * *
* * + + + . Ill |
I Commercial Prod/Hawthorne NJ | i , * * + +
| Cook Coup/North Kansas City MO | i ! * * * * +
| Courtaulde/Berkeley CA | i ! ? * * * * +
| DB Western/Las Vegas NH I i , t * * * + +
* ' ! J ! ! iii i
| Delta Resins/Detroit HI I i . . * * + +
+ ' I i ]... . Ill |
| Delta Resins/Milwaukee Ul I i , . * * + +
* ! ; ] ]_ .1 iii i
| Dexter/Birmingham AL I i , t * * * * +
; i ! J ! !. 111 i
I Oexter/Waukegan IL I i , . * * + +
* : 1 I i i iii i
| Dock Resins/Linden NJ I i , . * * * * +
; i ! ! ! iii i
| DuPont/Parkersburg UV I i , . * * * +
; ' i ! ! !... ; i i i
| Dyno/Uhite City OR | j III * * *
| Eastern Color/Providence RI I i ! * * * + +
; ! ! 1 ! ; i i i
| Exxon/Houston TX I i , . * + +
* : ! °.! !. i iii i
| General Elec./Coshocton OH I i , . * * + +
* - ! J ] ]... ' iii i
| PO George/St. touis MO I | , . * * * +
* - ! ! J ! ' iii i
| Georgia-Pacific/Albany OR I i , . * + + * +
' l|| I I I I
-------
CO
I
I facility/Location
I
| Georgia-Pacific/Colunbus OH |
| Georgia-Pacific/Conway NC |
+ --
... + __
| Georgia-Pacific/Crossett AR |
| Georgia-Pacific/Elk Grove CA |
| Gerogia-Pacific/Eugene OR I
.
] ........ ]
JBiphenyMU-butadiene (Cad-niun con,pds |Catechot Ichiorinelchtorobenzene'lchio^hane"
/yr I lbs/y I lbs/y I Ibs/yr | I bs/yr | 1 bs/yr
i "j j i i
j i i 'iiiziiiri i
.j i j i i >* I i
1 j i j "iijiz j
| Georgia-Pacific/Grayling HI
+
| Georgia-Pacific/Louisville MS
+
| Georgia-Pacific/Lufkin TX
(Georgia-Pacific/Peachtree City
|Georgia-Pacific/Port Wentworth
|Georgia-Pacific/RusseUville SC
|Georgia-Pacific/Taylorsville HS
*
| Georgia-Pacific/Ukiah CA
+
| Georgia-Pacific/Vienna GA
f
| Guardsman/Grand Rapids HI
+ - __
| Hercules/Chicopee HA
+
| Hercules/Milwaukee UI
+
| Hercules/Portland OR
-+ ,
- +
J
1
- + -
G|
G|
1
1
1
-+
1
f
1
t
1
+
1
f
1
+ ' 1 'I! |
! j... i i ; ; ; ;
, * * + + +
j i. i i iii i
i iii ; ; ;
+ i iii i
i ! ! ! j i i i
j I I ; ; ; j j
i I i I ; ; ; ;
+ + + i i i
j i i i iii ;
i ; ! i i ; ; ;
j ; i ; ; ; ; ;
! i ; ; ; ; ; ;
* + + + +
! ! ! i iii i
, . '". * 1
-------
H-
I Facility/Location
I j
| Hercules/Savannah GA |
* +-.
| Hercules Resins/Hattiesburg MS |
+ +-
| Hersite/Manitouoc Ul |
+ +--
| Hickson/Danville VA |
+ +--
(Hoechst Celanese/Hount Hotly NC |
| Hoechst Celanese/Bishop TX |
| Hugh J. Resins/Long Beach CA |
| Insulating Mat/Schenectady NY |
| WAX Corp/Rock Hill SC |
| tauter Int/Moundvilte AL |
+ +--
| Masonite/Gulfport MS |
j ...... 3M^::a9?.G:?re.HN..;...
; ...... M??!an!°^ddy:!on.°H i
| Monsanto/Springfield MA |
| National Casein/Chicago IL I
* ................................ ;
| National Casein/Tyler TX |
| Neste Resins/Andalusia AL
.
j
"* * + * + + +
|Biphenyl|1.3-butadiene ICadmim, eonpds |Catechol|chlorine|Chlorobenzene (Chloromethane
| Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr I Ibs/yr
*
! | ; i i i i
I 16000 I I III I
+ -.- +
..] j ; ; i i i
11 I III | 8840
* * * + + + «.
J 23J I ] J J '
II I || 520 | I
i j j j I i i
j j j"""""" j j j i
; i i "_"T j i ;
...i i i i j j j
I i i i i ]
: ; ;
..., ! ! ! ! «i i
I I I o | o | I
I I 26000 | 11 | | | |
! ; ; ".."III'lLll" ;
; + * * * ' !
11 i iii i
* I
ii i iti i
-------
co
i
-...«««,. "
I Neste Resins/Moncure MC |
| Neste Resins/Spokane WA |
| Neste Resins/Springfield OR |
| Neste Resins/Toledo OH |
| Neste Resins/Uinnfield LA |
| Occidentat/Kenton OH |
| Occidental/Niagara Falls NY |
| Occidental/North Tonauanda NY |
| Perstorp/Florence HA |
| Pioneer PIastics/Auburn HE |
| Plastics Eng/Sheboygan UI |
| Plastics Manuf/Dallas TX |
* +--.
I PMC Inc/Fords NJ |
| PPG Ind/Circleville OH |
+ +---
I PPG Ind/Oak Creek UI |
| Reichhold/Bridgeville PA |
| Resinail/Severn NC |
i* B.phenyl 1.3-butadiene |Cadn,iun, coopds |Catechol |chlorine|chlorobenzene Ichloronethane
I Ibs/yr | lbs/yr | lbs/yr j lbs/yr j lbs/yr ! lbs/yr ( ibs/^
! *
-] I !.. iii i
--J ' i i i illli
ii i iii
"
..! i i--IIIIZIZII""IIZ
1608i
i
i
i
i
+ + + ' I
,, . . * * + + +
:.'... ' ' ii 116°° i 26 i
---^---I~IIIIIIIIIIZ'i
-; | ! i ! ! ill:
..! 1 J i... i i i
1 i i iii j
"I | - !
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Rhone-Poulenc/Louisville KY I
........ .......
. ............... + ........ + ........ + .............. + ..............
! ........ .. ' iii i
, "" + ............... * ........ + ........ + .............. + .........
' ' I III |
-------
41 i
C i
a i
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I :
: §
Facility/Location
chenectady/Rotterdam Junct
i- + *
j
Schenectady/Schenectady
+
SEQUA/Chester SC
+
_
S
Simpson Timber/Portland
+
_
0
&.
i
c
t.
.
_^
5
X
1
:
;
.
,
Spaulding Comp/De Kalb II
^ »
^
Spaulding Comp/Tonauanda 1
^^^
-
5
X
.
+
^~
§
Stuart - 1 rons ides/Col umbus
_
1 ""
T
Sybron Chem/Elmwood Park N
.
o
§
rj
1
i
1
i
.
o
at
§
O)
.
^
Ultraform/Theodore AL
u
z
X
E
1
1
'
t_
Union Carbide/Somerset NJ
,
"
<
/alentine Sugars/Lockport 1
_
I
.
*v
B-16
-------
CO
I
I -,^.,(, j^-=-'j^
I (bs/yr | Ibs/yr | Ibs/yr
+
| Valspar.McUhorter/Kankakee IL | i . * +
| Uestinghouse Elect/Hanpton SC | i ! * * + + + +
| Westinghouse Elect/Manor PA I i . , * * * + +
|Uest Point-Pepperell/Opelika AL | | ! ! * * * * +
-------
00
I Akzo/Colunbus OH | 1500 |
| Akzo/Louisville KY | I
(All fed-Signal/Green Island NY | I
| Amer. Cyanamid/Charlotte NC | I
| Amer. Cyanamid/Kalamazoo HI | I
* + +
| Aroer. Cyanamid/Walligford CT | |
| AHETEK/Uilmington, OE | |
| Apex Chem./Elizabethport NJ | |
+ + +.
| Ashland Oil/Calumet City. IL | |
| Ashland Oil/Cleveland OH | |
| Auralux/Norwich CT | |
| BASF/Anaheim CA I I
....
|
"* * * * + *
|m-cresol|o-cresol|p-cresol| Cumene (Dibutyl phthalate |1.2-dichloroethane
| Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr j Ibs/yr
J I j j I |
J . J I I 1 1
I I <7j j 1 |
I I I I I I
J J j j I I
.; j j j j I
J J j j "j I
I I I I " | 130 |
J I j I I |
I 3 I I
| Borden/Demopois AL |
| Borden/Diboll TX |
| Borden/Fayettevill NC |
+ +
| Borden/Freemont CA I
i
i j i "T
i i I I 7
j j "j j r
Borden/Kent WA
|
-------
ro
i
I Facility/Location
I
1
| Borden/La Grande OR |
| Borden/Louisville KY |
| Borden/Hissoula NT |
| Borden/Sheboygan Ul I
cresoit;r '~;;;";~ ';^
//r
. ...... -.... .
| Borden/Springfield OR |
| Borden,Perk ins/Alexandria LA |
| Borden,Perkins/High Point NC |
| Borden.Perk ins/West Memphis AR |
+ +..
| Borden,Acme/Forest Park IL |
| Dyno(Brancor)/Virginia MN |
| Brand-S,Cascade/Eugene OR |
t lbs/yr I lbs/*r I «**/W I Ibs/yr | ibs/yr
...J ' ' I I I I
+ + + + + +
I 20 I 20 | 10 | 998 | | |
...j "8i i i i i j
..j i i j.. j i i
1 ill i i j
; * ** *' !
j i i i i i |
i i I I I i
I
I
I
I
+-
I Cargill/Carpentersville IL- |
| Cargi U/Forest Park GA |
| Cargill/Lynuood CA I
10 |
i
I
10 |
o I
III I
-------
.acmty/Location .chr.,- Conuds ,cobal, C^s , Cresol(mUed iso^s.^reso^creso^creso;^^^
__._ f | lbs/yr I lbs/y I lbs/V I Ibs/yr I Ibs/yr | Ibs/yr | ibs/yr
| CL Ind/Georgetoun IL | i i . * * * +
| CNC Int./Woonsocket Rl | | i ! * * * * *
| Commercial Prod/Hawthorne NJ | | i . t * * * *
| Cook Comp/North Kansas City HO | 998 | 509 | i j I ? * *
| Courtaulde/Berkeley CA | o | I it I * * *
| DB Western/Las Vegas NH | j i j * * * * *
| Delta Resins/Detroit HI | | i . * * * *
| Delta Resins/Milwaukee UI j | i . ""* * * * *
| Dexter/Birmingham AL | | i "tin*l 1 * * * *
| Dexter/Uaukegan IL | 993 I i 400 i i * * * *
| Dock Resins/Linden NJ | j i . * * * * *
| DuPont/Parkersburg UV | | i . * * * +
| Dyno/White City OR | j i t j j * * *
| Eastern Color/Providence RI | j i . t * * * *
| Exxon/Houston TX I I i . * * * *
* ! ! ! ; ; i i i i
| General Elec./Coshocton OH I | I I I * * + *
| PO George/St. Louis HO | | i . ""* * * * *
| Georgia-Pacific/Albany OR I I i , , + * *"" *
1 ' I III i
-------
ro
+
| Georgia-Pacific/Coluifcus OH | i
| Georgia-Pacific/Conway NC | i
| Georgia-Pacific/Crossett AR | i
* * + -
| Georgia-Pacific/Elk Grove CA | i
| Gerogia-Pacifie/Eugene OR | i
| Georgia-Pacific/Grayling HI | i
| Georgia-Pacific/Louisville MS | i
| Georgia-Pacific/Lufkin TX | i
(Georgia-Pacific/Peachtree City G| i
* * +--
|Georgia-Pacific/Port Uentworth G| i
|Georgia-Pacific/RussellviUe SC | i
|Georgia-Pacific/TaylorsviUe HS | |
| Georgia-Pacific/Ukiah CA | i
| Georgia-Pacific/Vienna GA | i
| Guardsman/Grand Rapids Ml | 15 i
I Hercules/Chicopee HA | i
; * * ** «.
h-cresol|o-cresol|p-cresol| Cunene |oibutyl phthalate |1.2-dichloroethane
| tbs/yr | Ibs/yr j Ibs/yr | Ibs/yr | Ibs/yr | (bs/vr
* ........ + ........ * ........ * ........ +
i . i i i i
+
+ .........
+
+ .........
,
!
..' ' j j j"
' i i "i i"
"* + * * +-
"* + * * *-
..] I I I I
..J | J j j
j i j j r
j i j j r
j 'l"~li~"~~~j ["
j i j "i r"
.; j j" j r
i j i ""i r"
+ ...........
+ .............
+ .......
..........
+ ____
..............
+--
...............
+
Hercules/Hi luaukee UI
i
| Hercules/Portland OR I i
-------
CD
I
| Hercules/Savannah GA |
| Hercules Resins/Hattiesburg MS |
| Hersite/Manitowoc Ul |
| Hickson/Danville VA |
(Hoechst Celanese/Mount Holly NC |
| Hoechst Celanese/Bishop TX |
+ +--
| Hugh J. Resins/Long Beach CA |
+ +--
| Insulating Mat/Schenectady NY |
| IVAX Corp/Rock Hill SC |
| Lawter Int/Houndville AL |
* +--
| Masonite/Gulfport HS |
| 3H/Cordova IL |
| 3H/Cottage Grove HN |
| Honsanto/Addyston OH |
| Monsanto/Springfield HA |
+ + --.
| National Casein/Chicago IL |
| National Casein/Tyler TX |
| Neste Resins/Andalusia AL I
...............
j i
| i
................
I 0|
"i- +--
I 630 |
I I
- + + --
I I
- + + --
I I
* +
|m-cresol|o-cresol|p-cresol| Cumene joibutyl phthalate |1,2-dichloroethane
| Ibs/yr | Ibs/yr \ Ibs/yr | Ibs/yr | Ibs/yr | ibs/yr
+ *-' + * +
I I I I I |
j j j i ""i j
i i i i i i
i i i i "i i
* *
27 I I I so | | |
* * + + + +
I I I I I I
i i j j i i
720 I I | | 1310 | [
"* + * * +
I I I I I |
* *
I I I I 509 | |
...J j j j j |
....i j j j j i
I I
I I
|
.
* ........ * ........ + ........ * ........ +
j i i i i
I 1 ....... * ........ * ........ +
-------
ro
Facility/Location
r;:,r° i
' '
I Neste Resins/Honcure NC I
| Neste Resins/Spokane UA |
+..-..__
+-_
| Neste Resins/Springfield OR |
+
" +-
| Neste Resins/Toledo OH |
| Neste Resins/Winnfield LA |
| Occidental/Kenton OH |
| Occidental/Niagara Falls NY |
| Occidental/North Tonawanda NY |
| Perstorp/Florence MA |
+-
+
| Pioneer Plastics/Auburn HE |
| Plastics Eng/Sheboygan Ul |
| Plastics Manuf/Dallas TX |
I PMC Inc/Fords NJ |
I PPG Ind/Circleville OH |
....
i
J .............. ]
i
(bs/yr | lbs/yr
+ ........ * ........ * ........ + ................. +
i i i i , .................
+ ........ + ........ + ........ + ................. +
...................
....... *
* ........ + ........ + ........ +
i i i i
* ........ * ........ + ........ +
+....
.............
*
" ...................
..... *
i j
""*
24 I
..........
........
I PPG Ind/Oak Creek UI I
+ ................................ *
| Reichhold/Bridgeville PA I
* ................................ :
I Res i nail /Severn NC I
; ................................ '
| Rhone-Poulenc/Louisville KY I
.............. ..
i .
I .............. i
i
I .............. |
i , .
; ........... !°.J.
i *
] .............. J
* ........ * ........ + ........ +
i i i i
* ........ * ........ + ........ +
i i i i
* ........ * ........ + ........ +
* ........ * ........ + ........ +
* ........ + ........ + ........ +
I » I | |
+ ........ * ........ + ........ +
i i i i
+ ........ + ........ + ........ +
i i u» i i
+ ........ + ........ + ........ +
i i i i
* ........ + ........ + ........ +
j i j j i i
i i I i i *
+ ........
"" ...................
i
I
I
-------
CO
A>
(Schenectady/Rotterdam Junction Ml
+ ................................ I
| Schenectady/Schenectady NY I
+ ......................... * j
| SEQUA/Chester SC |
| Simpson Timber/Portland OR |
| Southeastern Adh/Lenoir NC I
* ................................ I
| Southeastern Adh/Ridgeway VA I
* ................................ :
| Spaulding Ccop/Oe Ka.b ,L |
+ ................................ >
I Spaulding Conp/Tonawanda NY I
* ................................ I
| Spurlock/Uaverly VA I
* ................................ ;
| Stuart- Ironsides/Columbus OH |
| Sybron Chera/ElmHood Park NJ |
| Sybron Chem/Uellford SC |
| Synthron/Morganton NC |
| Ultraform/Theodore AL |
(Unilever Nat Starch/Salisbury NC|
* ................................ +
| Union Carbide/Somerset NJ |
| Valentine Sugars/Lockport LA |
| Valspar.HcWhorter/Garland TX
..............
. Vr ' 'bS/yr I 'bS/yr I lbs/yr I lbs/*r I ">s/yr I lbs/yr
i """* ........ * ........ * ........ + ........ * .................. + ...................
I W8 I | U98 | 2562 | | |
i '"* ........ * ........ + ........ * ........ * .................. + ...................
I 6000 | | 998 | | | j
i ..... * ........ * ........ * ........ * ........ * .................. + ...................
i * ........ * ........ * ........ * ........ * .................. * ...................
i * ........ * ........ * ........ + ........ * .................. + ...................
i ....................... J... Jill 499 |
i t ........ * ........ + ........ * ........ * .................. * ...................
I ......... j i i i i i
, 3£)0 j -J ........ j ........ * .................. * ...................
+ ............. ''Ill I
i ""*. ........ * ........ * ........ * ........ + .................. * ...................
i ...................... | I I I I 509 |
i ........ ? ........ * ........ * ........ * ........ * .................. + ...................
] ....................... i ] i i i i
i ! ........ * ........ * ........ * ........ * .................. + ...................
i t ........ * ........ * ........ * ........ * .................. + ...................
i ""* ........ * ........ * ........ * ........ + .................. * ...................
. ..... * ........ * ........ * ........ * .................. * ...................
i ....... j ........ * ........ * ........ + ........ * .................. + ...................
i ! ........ * ........ * ........ * ........ * .................. + ...................
! ....................... ] I I I | | 395904
i "| ........ + ........ + ........ * ........ * .................. + ...................
i * ........ * ........ + ........ * ........ * .................. + ...................
i ! ........ * ........ + ........ * ........ * .................. + ...................
-------
~
CO
en
I Valspar.McUhorter/Kankakee IL I I "i
+ ................................ ; .............. .; ........ |
| Uestinghouse Elect/Hanpton SC I i !
| Uestinghouse Elect/Manor PA I
+
|Uest Point-Pepperell/Opelika AL
+
I Total Ibs/yr
; ......... -
I Total tons/yr
io i
+
100° I
56°° i i i i i
* ........ * ........ + ........ + ........ +
.....
3558 .
........... -' ......... "59.
I }m.
i .......... .: J ....... °:5795J
22297j 2°'
...... + ........ * ........ * ........ * ........ «.
":^5J...0:°:.].2:28:5J..2;554 J 2-*65 '
-------
I Akzo/Columbus OH | I
| Akzo/Louisville Kr | I
|AUied-Signal/Green Island NY | |
| Amer. Cyanamid/Charlotte NC | I
* - + +-.
| Amer. Cyanamid/Kalamazoo Ml | I
| Amer. Cyanamid/Ualligfo'rd CT | I
| AHETEK/Uilfflington, DE | |
* + *--
| Apex Chem./Elizabethport NJ | |
| Ashland Oil/Calumet City, IL | |
| Ashland Oil/Cleveland OH | 1326)
| Auralux/Noruich CT | |
| BASF/Anaheim CA | I
| BASF/Detroit HI | I
| Borden/Demopois AL | I
| Borden/Diboll TX | I
| Borden/Fayettevitl NC | I
| Borden/Freemont CA | |
, '"* ................ * .................... * ................... * .................
j ? ................ * .................... * ................... + .................
i ? ................ * .................... * ................... * .................
i ! ................ * .................... * ................... + .................
! ............... ' ..... io i i i
III ................ * ................... * .................
i . ........... j .................... * ................... * .................
, ....... J ................ * .................... * ................... * .................
' ............... J.. ' I I
. . ........... | .................... + ................... + .................
- ---+ ................ + .................... + ................... ^ .................
............. *
*
* .................
* ................ * ....................
+ .................
i
....
*
*
+ .................
"*
*
+ .................
* ................
- + -
I
- + --
* ....................
..............
.........
+
* ................... + .................
+ .................
Borden/Kent UA
-------
r\3
I Borden/La Grande OR |
| Borden/Louisville KY |
| florden/Hissouta MT |
| Borden/Sheboygan Ul |
| Borden/Springfield OR |
+ +--
| Borden.Perkins/Alexandria LA |
| Borden,Perk ins/High Point NC |
| Borden,Perkins/West Memphis AR |
+ +--
| Borden,Acme/Forest Park IL |
! ............... * ................ + .................... + ................... + .................
] ...... 'i i
* ............. + .................... +
+ .................
................
Dyno(Brancor)/Virginia HN I
'
Brand-S, Cascade/Eugene OR
i i ; i ::;v:
; ; i i i ;;;;;;;;;;;;
j i...'i"iiiizri i
' j r;;;;;; ;
i i
I BTL/Blue Island !L
.................... ..
+
I
+--.
| Cargill/Carpentersvitle IL |
| CargiI I/Forest Park GA |
+ .................
I Cargill/Lynwood
CA
I
-------
I":-^!^
| CL Ind/Georgetown IL | i . * * * +
| CMC Int./Uoonsocket Rl | | ! * * * *
| Commercial Prod/Hawthorne NJ | I , * * * +
| Cook Comp/North Kansas City HO | I , * * * +
| Courtaulde/Berkeley CA | i . + + * +
| DB Western/Las Vegas NH | | +---- + + + +
| Delta Resins/Detroit HI | I . * * * +
' I Delta Resins/Hitwaukee Ul I i , * * * +
' III i
| Dexter/Birmingham AL I i , * * + +
499
. ......... ...............
| Dexter/Uaukegan IL | i . * ............... * .................... + ................... + .................
| Dock Resins/Linden NJ i . ...... * ................ * .................... + ................... + .................
.
......
| OuPont/Parkersburg WV | i . ...... * ................ + .................... + ................... + .................
| Dyno/White City OR i . ....... * ................ * .................... + ................... + .................
; ; : ' i i
I Eastern Color/Providence RI | 998) , + +
* * + + + ! ' I
| Exxon/Houston TX | i , * +
| General Elec./Coshocton OH | | j * + * +
| PD George/St. Louis HO | i , * + + +
; ' 1 ! i i i
| Georgia-Pacific/Albany OR I i , * + +
1 III i
-------
i tO
I 3
i (A
: >.
't phthalate
bs/yr
' £
i 1
; .5
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i a i_
>
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+
Pacific/Crossett AR
B
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.
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:
i
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.
n
,
^^
i-Paci fie/Eugene OR
i
_ .
_ .
Pacific/Grayling HI
,
__
:if ic/Taylorsville HS
^
n
i
i
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D
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'
n
X
f
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1
QC
5
jles/Chicopee HA |
... . . . __+
i
-.
(V
~
B-29
-------
~:^
Hercules/Savannah GA | 51830 | i ! ................ * .................... + ................... * .................
Hercules Resins/Hattiesburg MS I I i ! * * +
' III i i
*
| Hersite/Manitowoc Ul | j . * * * +
| Hickson/Oanville VA | I * * +
(Hoechst Celanese/Mount Holly NC | | i ? + * *
| Hoechst Celanese/Bishop TX | 1000 | I i * * *
| Hugh J. Resins/Long Beach CA I I i * * * +
* 'III
03 * --- + + + 'I I |
do | Insulating Mat/Schenectady NY | i * * * +
| WAX Corp/Rock Hill SC | | , ooa I * * *
+ - + + I I | |
| Lanter Int/Moundville AL | | i * * * +
| Masonite/Gulfport MS | i * * +
| 3H/Cordova IL | 35000 | i ! * * *
| 3M/Cottage Grove MN | | * * + -
| Monsanto/Addyston OH | I i + * +
| Monsanto/Springfield MA | | i * * +
| National Casein/Chicago IL | I i * * *
| National Casein/Tyler TX | | ""* * + +
| Neste Resins/Andalusia AL | i + * +
-------
oo
CO
Neste Resins/Moncure NC
i
*. ............... + ................ * .................... + ................... + .................
| Neste Resins/Spokane UA | i
| Neste Resins/Springfield OR | i
| Neste Resins/Toledo OH I i
* ................................ ' ................ !
| Neste Resins/Uinnfield LA I i
+ ................................ ! ................ !
| Occidental/Kenton OH | i
| Occidental/Niagara Falls NY | i
| Occidental/North Tonauanda NY I i
* ....................
* ....................
* ................
+ .................
* ................ + ....................
I Perstorp/florence MA I i
| Pioneer PI astics/Auburn HE | i
| Plastics Eng/Sheboygan Ul | i
| Plastics Manuf/Dallas TX | i
j. I
+ ...................
* .................... +
* *
I
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I
I
I PPG Ind/Circleville OH | 1210 i
* + + --
I PPG Ind/Oak Creek Ul | i
| Reichhold/Bridgeville PA | i
| Resinail/Severn NC | i
* + + ---
| Rhone-Poulenc/Louisville KY I i
+ *
+ .......
....
+ -
10
-------
CO
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(Schenectady/Rotterdam Junction N|
| Schenectady/Schenectady NY |
I SEQUA/Chester SC j
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| Simpson Timber/Portland OR |
* +
| Southeastern Adh/Lenoir NC |
| Southeastern Adh/Ridgeway VA |
| Spaulding Comp/De Kalb IL |
| Spaulding Conp/Tonauanda NY |
| Spurlock/WaverIy VA |
| Stuart-Ironsides/Coluifcus OH |
| Sybron Chem/Elmwood Park NJ |
| Sybron Chem/Uellford SC |
| Synthron/Morganton NC |
| Ultraform/Theodore AL |
(Unilever Nat Starch/Salisbury NC|
| Union Carbide/Somerset NJ |
| Valentine Sugars/Lockport LA |
| Valspar,McWhorter/Garland TX |
I
... + + I lb«/yr I Ibs/yr
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Akzo/Colunbus OH
JEthyi acrylate JEthylbenzenejEthylene Glycol JEthylene oxide J F«ld^T«^i"^«"I^i^;;^«;«
.;...._'J... Vl> ] /Vr ' lbs/yr I lbs/^r I lbs/y I Ibs/yr
.; i 22"i j j J 35499"!
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IAllied-Signal/Green Island NY |
| Amer. Cyanaraid/Charlotte NC |
| Amer. Cyanamid/Kalamazoo HI |
993
..
| AHETEK/Uilmington, DE I
* ................................ '
| Apex Chem./Elizabethport NJ I
* ................................ !
| Ashland Oil/Calumet City. U I
* ................................ ;
| Ashland Oil/Cleveland OH I
+ ................................ ]
! ....... Au:a:^No±h.c: ....... j
! ........ BASF?nahe:m." ......... !
| BASF/Detroit MI I
* ................................ I
| Borden/Demopois At I
* ................................ !
| Borden/Diboll TX I
* ................................ !
| Borden/Fayettevill NC I
+ ................................ I
| Borden/Freemont CA I
* ................................ !
| Borden/Kent UA I
1
I I 7509 |
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I 893 | 43 |
* + +-
............
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; J ............ ]
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| 44994 | |
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I 7300 | 998 |
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| 38785 | |
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. ........ * ............... + .............. + ............... + ........
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* ................................ +
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106600
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| Cargill/Carpentersville IL I
; ................................ *
I Cargi I I/Forest Park GA I
; ................................ '
| Cargill/Lynwood CA I
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| CMC Int./Uoonsocket Rl I | , ..... ! ................ + ............... * .............. * ............... + .........................
* ................................ I ................ ! ............... | ............ ] I I 2100 | ,
| Commercial Prod/Hawthorne NJ | I i t ............... * ............... * .............. * ............... + .........................
| Cook Conp/North Kansas City HO I I i ""* ................ * ............... + .............. + ............... + .........................
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* + + I j 7 I I | 15 |
| DB Western/Las Vegas NH | | i j * * * +
| Delta Resins/Detroit HI I i , . * * * +
* I i ] J ' I 998 | ,
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+ + I ] I I | 998 | |
| Dexter/Birmingham AL | i 2Q i * * * * +
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* + «. { | I I | 16000 |
| Dock Resins/Linden NJ | j ,6 , J * * + +
| DuPont/Parkersburg UV | i , * * * + +
| Dyno/Uhite City OR | i . * * + +
+ + I J | I I 25400 | |
| Eastern Color/Providence Rl | I i ? * * * +
| Exxon/Houston TX I | i . * * + +
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| General Elec./Coshocton OH | | i I * + * +
| PD George/St. Louis HO j | ? * * + +
| Georgia-Pacific/Albany OR | i + + + +--
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* ................................ * ................
| Hercules Resins/Hattiesburg MS I 12700 I
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| Hersite/Manitouoc Ul I i
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| Hickson/Danville VA I i
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................................ ' ................ '
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............... .......... ~ ............... .........................
I WAX Corp/Rock Hill SC |
| Lawter Int/Moundvitle AL |
| Hasonite/Gulfport MS |
| 3M/Cottage Grove MN j
| Monsanto/Addyston OH |
| Monsanto/Springfield MA |
| National Casein/Chicago 1L |
| National Casein/Tyler TX |
j Neste Resins/Andalusia AL j
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Neste Resins/Spokane UA
^ j_ L
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.............. * ............... *
................ I
jSchenectady/Rotterdam Junction Nl I i ,
* ................................ ! ................ ; ............... J ............ ] ................
Schenectady/Schenectady NY I I i . '" ""* ............... * .............. *
i ' "8
__ + ._. i ' i »**»/ 71 | iDs/yr
; ; + ** A530°! !
+ + ] J I 1799 | . | 098 | U98 |
| SEQUA/Chester SC I i 12 i ! * * * +
+ + J ' I I | 1800 | 19 |
| Simpson Timber/Portland OR I I i . * * * +
+ I ^ 'I I | 101308 | |
| Southeastern Adh/Lenoir NC I I i , * * * *
+ + f.J.... ' ' I a500 I |
| Southeastern Adh/Ridgeway VA I III ! * * *
+ I ' ' J I | 7615 | I
. + * + + + . '
| Spaulding Comp/De Kalb IL I | i , . " * *
* * I ] I I . I 336 I |
| Spaulding Comp/Tonawanda NY I I i , * * * *
* I I I ] I | 998 | 998 |
| Spur lock/Waver I y VA I i , ! * * * *
* - * I I ] | I «00 | |
| Stuart-Ironsides/Columbus OH | | i . * * * +
| Sybron Chem/Elmwood Park NJ | | i ! * + * +
| Sybron Chem/Wel I ford SC | 10 | I 998 I y] + * *
| Synthron/Horganton NC I i OQ., i . * + * +
Ultraform/Theodore AL
I I | 24000
(Unilever Nat Starch/Salisbury NCl 829 I I i ! + + +
+ + { | ' ' I | 2718 | |
| Union Carbide/Somerset NJ | | J2 i ? + + * +
| Valentine Sugars/Lockport LA | I i . * * * +
Valspar.McWhorter/Garland TX | | i , * * + +
-------
I Valspar.McWhorter/Kankakee IL
| Uestinghouse Elect/Hanpton SC
| Uestinghouse Elect/Manor PA
|West Point-Pepperetl/Opelika AL
I Total tons/yr
+ '^
9,8, ........................
+ ...........
95000
..
... °9 I A99
............... * ............... + ..............
I I 1*070
U98
i 998 , 998 ,
+ .............. + ............... +.
31:6065J ........ -
CD
-------
CD
ro
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facility/Location
Akzo/Colunbus OH
Akzo/louisville KY
"""*--------»-------.-..._._.
JAUied-Signal/Green Island NY
+-
|
+-
|
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i
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!
!
!
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Amer. Cyanamid/Chartotte NC
Amer. Cyanamid/Kalamazoo HI
.__
Amer. Cyanamid/Ualligford CT
AHETEK/Wilmington, OE
Apex Chem./Elizabethport NJ
Ashland Oil/Calunet City, IL
Ashland Oil/Cleveland OH
Auralux/Norwich CT
BASF/Anaheim CA
BASF/Detroit HI
Borden/Demopots AL
*
Borden/Oiboll TX
Borden/Fayettevill NC
Borden/Freemont CA
Borden/Kent WA
"* + +
JHexachlorocyclopentad-ene (Hydrochloric acid ,Hydro9en Fluoride |Uad Cwvds |Haleic anhydride |Hanganese Co^s ,HerCUry Co^Hethanol
.] .'* \ .lbS^ \ lb^ 1 lbs'*r 1 ^s/yr | lbs/yr | lbs/yr | lbs/yr
-' ! ' i ii
, , * * + * + t
.; ; ' .' i «w i | | U549
1 i i i i I I I ii/o
i , . "* + * + +
-! ; ] '1 1 1 | 825
1 "° 1 1 1 1
-+ \ ' '1 1 1 | 65900
-* ' ' 1 40 1 | j 59880
, . * * * * * *
-i "8. ! ' i ii
i , ; ; * *
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i , ... * * + + * *
.1 ! 15t ' 'I 2" I I | 9A79
.; ; ' l «i ; ; ;-;»
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' ! I I I I 1998
1 . * * * * + *
! J ' 1 II 1960
i | ; ; + - *
+ .«. ! it i | | 13800
i . * * + * * *
J \ 1 1 1 20 | | , ow
j - "* * + + +
+ + ' '1 1 | | 10999
| . 1 * * + * + *
+ + ] '1 A99 1 1 | 15099
! ...J ! 'I 1 || 2,49
. * + + +__ .
' 1 0 j II 1 ,
II \ j 5599
-------
+-
I Borden/La Grande OR |
| Borden/LouisvHle KY |
| Borden/Missoula NT |
| Borden/Sheboygan UI |
| Borden/Springfield OR |
| Borden.Perkins/Alexandria LA |
| Borden.Perkins/High Point NC |
| Borden.Perkins/West Menphis AR |
| Borden,Acme/Forest Park IL |
| Oyno(Brancor)/Virginia HN |
| Brand-S.Cascade/Eugene OR I
; + *+* +
ac.d Hydrogen Fluoride (Lead Corcpds |Haleic anhydride (Manganese Coopds JMercury ConpdslHethanol
I Ibs/yr | Ibs/yr | lbs/yr | lbs/yr | lbs/yr | Ibs/yr
. *
! I I I | 7739
.'i ; ; ; *
I I | 22600
+ + +
I I
I I
I |
+ +
|| 22799
+ .............. + ........
+ +
I I U98
I
998
STL/Blue Island IL
|| 26100
......... + ............ * ................. * ................. + .............. + ........
| Cargill/Carpentersville IL |
| CargiIt/Forest Park GA |
| Cargill/Lynwood CA |
* + *
... ! ' ' 2°2 i i i
I I | 1017 | I J
1 I | 162 | | I
-------
1
+
1
+
1
+
1
+
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1
+
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+-
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Facility/Location |H
CL Ind/Georgetown IL |
CMC Int./Woonsocket Rl |
+-
Commercial Prod/Hawthorne NJ |
, . . +_
Cook Comp/North Kansas City MO |
Court aulde/Berkeley CA |
.... . _ +_
DB Western/Las Vegas NN |
. +_
Delta Resins/Detroit HI |
... ., ^_
Delta Res ins/Mi I uaukee Ul |
" »-
Dexter/Bir»ingham AL |
--- +--
Dexter/Uaukegan IL |
. . +_m
Dock Resins/Linden NJ |
. . ..... i...
DuPont/Parkersburg UV |
»--
Dyno/Uhite City OR |
Eastern Color/Providence Rl |
... +__
Exxon/Houston TX |
General Elec./Coshocton OH |
+--
PD George/ St. Louis MO |
- + __
Georgia-Pacific/Albany OR |
lexachlorocyclopentad.ene l^rochloric acid (Hydrogen Fluoride |Lead Compds JMaleic anhydride (Manganese Coopds (Mercury Compds|Methanol
+ S/yP ' 'bS/yr ' lt>S/yr 1 lbs/yr 1 lbs/y 1 lbs/yr | lbs/yr
"* * * * + *
+ ] '1 1 1 | 7095
i.
-------
I Facility/Location |Hexachlorocyclopentadiene (Hydrochloric acid (Hydrogen
1 J lbs/yr 1 tbs/*r 1 »*>
| Georgia-Pacific/Colunbus OH 1 i ,
* !
| Georgia-Pact fic/Conway NC 1 I i
+ ' ' 1
| Georgia-Pacific/Crossett AR | i
+ + ' 1
| Georgia-Pacific/Elk Grove CA 1 i ,
* ! ! !
| Gerogia-Paci fie/Eugene OR | I i
* + +.
| Georgia-Pacific/Grayling HI | i 2 i
* + * ;
| Georgia-Pacific/Louisville MS | i i
+ + _ '
| Georgia-Pacific/Lufkin TX 1 i i
* ! ! !
(Georgia-Pacific/Peachtree City Gl I i
(Georgia-Pacific/Port Uentworth Gl | ,
JGeorgia-Pacific/RussellviUe SC | i -7U ,
+ + ' 1
(Georgia-Pacific/Taylorsville MS | 1 i
* 1 ;
| Georgia-Pacific/Ukiah CA | i ,
+ + + +
| Georgia-Pacific/Vienna GA | I ,
* ! ! M
| Guardsman/Grand Rapids HI ( ) ,
| Hercules/Chicopee MA | i ,
* + + +
| Hercules/Hi luaukee UI 1 i ,, ,
1 2153
+ + '
| Hercules/Portland OR | i .
Fluoride (Lead Cs I ~ ""* + *
s/yr | Ibs/yr | Ibs/yr j Ibs/yr j lbs/yr | lbs/yr
+ * + + +
II 1 || 84510
* + + + +
I III 22407
+ + + + +
II 7 | | | 355838
* * + + +
II I | | 2280
+ + + + +
I III U20
* * * + +
'I I II
* * + + +
+ + + + +
II I || 12533
+ * * + +
II i i
'I 1 | | 770
II i i
'I 1 || 2777
* * + + t
1 1 1 | | 409085
1 1 i i
'I 1 | j 34028
+ * + * *
1 1 1 1 1
+ + + + +
'I 1 || 17900
+ + * *
1 "8 1 | ( I 8500
* * +
'I 1 l|
+ + + + +
'I 1 ||
+ + * + +
II 1 II
-------
I
en
+- _. +
j Facility/Loc.tion JHexachlorocyclopentadiene (Hydrochloric acid (Hydrogen Fluoride (Lead Conpds |Haleic anhydride (Manganese Con^ds |Me
) 1 lbs/yr 1 lbs/y 1 Ibs/yr | Ibs/yr | Ibs/yr | Ibs/yr |
| Hercules/Savi;i.;,,.h GA | I i i
| Hercules Resins/Hattiesburg MS | | i 1 1 520 1
| Hersite/Manitowoc Ul | 1 i .
| Hickson/Danviile VA | | 3o90 i .
| Hoechst Celanese/Mount Holly NC | | u i i ,
| Hoechst Celanese/Bishop IX j I i gg40 . .
| Hugh J. Resins/Long Beach CA | 1 i i ,
| Insulating Mat/Schenectady NY 1 I i i , .... ,
4 . ' ' 1 | 484 1 |
| IVAX Corp/Rock Hill SC | | i , .
| Lawter Int/Moundville AL | | i , ,
| Masonite/Gulfport MS | | i . .
| 3M/Cordova IL | | | 81floo j ( Q (
| 3H/Cottage Grove MN | | 1540 i ^QQ , .
| Monsanto/Addyston OH | | | | j WQ ^
| Monsanto/Springfield MA | | i .
| National Casein/Chicago IL | I i . , *
| National Casein/Tyler TX | | i , . *
| Neste Resins/Andalusia AL | I i 11
rcury Compds|Methanol
lbs/yr | lbs/yr
;
;
+
i
+
| 6800
+
| 491
+
+
I
+ -
I
| 1899
- -i
| 2699
I
| 10700
| 313300
+
2 | 21100
+
| 57100
I
I
: --
-------
ro
| Facility/Location
| Neste Resins/Moncure NC
| Neste Resins/Spokane UA
f-.-.... . _ . _ ....
| Neste Resins/Springfield OR
| Neste Resins/Toledo OH
| Neste Resins/Uinnfield LA
+ - - -
I Occidental/Kenton OH
+ . ---.,,_._
| Occidental/Niagara Falls NY
| Occidental/North Tonawanda NY
| Perstorp/Florence HA
+-- ._
| Pioneer PI as tics/ Auburn ME
t
| Plastics Eng/Sheboygan UI
| Plastics Manuf/Dallas TX
+
| PMC Inc/Fords NJ
+
| PPG Ind/Circleville OH
+- -
| PPG Ind/Oak Creek UI
| Reichhold/Bridgeville PA
| Res i nail /Severn NC
| Rhone-Poulenc/Louisville KY
-- + . .... ......
. * + + + +
| eX8C °r°^°Pentadlene (Hydrochloric acid JHydrogen Fluoride (Lead Compds JHaleic anhydride (Manganese Compds (Mercury Compds (Methanol
-- + ' _ ] lb*/yr ] lbs/yr 1 lbs/y 1 lbs/yr | lbs/yr | lbs/yr
-- + + ) ' 1 1 I | 230499
..! i j i i ; ; ;
+ + 4. .
i i + + +
- + + ... ' 1 1 | | 116999
i - ;
-* ; ! 'I I II 2030
-i ! 10| 'I 1 I I 193113
j i :::j i ; ; ; ;
.! :°°2.i : ! 2o'°.i ; ; » I » I ""=60"
I I 499 | I, * * *
-* + I ' ' I I 5725
.; i L. i ; i ; ;
.; j j. i i ; ; ;
.! ; i it i i i ,«
.! j ; i i ; ; ;
! ! °! ii i i i ,m
J ] I | 53 | 993 | | !
' ! | 'I "I I | 1142
i i ; ; + * * *
J - ' 1 II 1242 ( I ,
i , j + + * * ;
1 iii,; ; ;--
-------
|Schenectady/Rotterdam Junction N| 4Q10 . * * * + +
*-.- --( II I .
* + + I ' ' I I I 13270
| Schenectady/Schenectady NY | i . * * * + +
+ * ' ' .11 499 I I , 1/00
+ +
SEOUA/Chester SC I i . *
| Simpson Timber/Portland OR | i . * * * + +
* + + + I ' I I (1016379
| Southeastern Adh/Lenoir NC | j , * * + +
; ................................ .......................... .................. .................. ... i ^
| Southeastern Adh/Ridgeway VA | i . ....... ................. * ................. + .............. + ........
| Spaulding Comp/De Kalb IL | i ! ............. * ............ + ................. * ................. + .............. « ........
+ ................................ + .......................... + .................. I ............ | I I | | 42600
| Spaulding Comp/Tonauanda NY I I . ......... * ............ + ................. + ................. + .............. + ........
* ................................ * .......................... ] .................. ! .............. "I I l| 50100
| Spurlock/Uaverly VA | i . "* ................. + ................. + .............. + ........
+ ................................ * .......................... ! .................. ! ......... "I I l| 4200
| Stuart-lronsides/Colunfcus OH | i . ......... "* ................. * ................. + .............. + ........
| Sybron Chem/Elnwood Park NJ | i . .............. * ............ * ................. + ................. + .............. + ........
| Sybron Chem/Uellford SC I I ,. ! ................. + ............ + ................. * ................. + .............. + ........
Sybron Chem/Uellford SC I I ,.
_____ ' I 20 I
10 I
I V I
| Synthron/Morganton NC I i ., . * * + + +
i Wo i i i .
; * * ! iii 9000
| Ultraform/Theodore AL I i . + + +
; : ! ! ! ' i ii
(Unilever Nat Starch/Salisbury NC| i , " "* * + +
* * i ! ' I 10 I I | 10622
| Union Carbide/Somerset NJ | i . * * + +
| Valentine Sugars/Lockport LA | i , + + + + +
; * - ' 1 | ' i ii
| Valspar.McUhorter/Garland TX | i . + + ----- + +
-------
1
1
1
+-
1
f-
1
f-
1"
1
1
+-
+ 4
acuity/Location JHexachlorocyclopentadiene [Hydrochloric acid (Hydrogen Fluoride
1 tbs/y 1 Ibs/yr | ibs/yr
Valspar.McWhorter/Kankakee II | i t
+ ' '
Uestinghouse Elect/Hampton SC 1 i
1 1
--.-_______ --------------- -.4.. ._..._.
Uestinghouse Elect/Manor PA | i
+ _ '
est Point-Pepperel I/Opel ika AL 1 i . ! '
' | *»UQ 1
' 1002 1 43277 | 9798Q
Total tons/yr | 0 501 1
--.....^ ""------------------+----.-.-_.._.-..._.
* »
|Lead Compds |Maleic anhydride (Manganese Compds (Mercury Compds|Hethanol
tbs/yr | lbs/yr | Ibs/yr | Ibs/yr | Ibs/yr
1 ° 1 1 | 1 499
* 4 ;
1 1 | (5100000
h- ---------- -4_ ....... mi . .
---4-.--.. .._-. + . _ + __
I.
I 4" I I | 998
I I i .
1 1 1 | 4997
1061 I 90°9 I 52 | 36 | 1E+07
+ + 4 4
°-5305 1 4-5(*5 | 0.026 ) 0.018 (5191.26
+
ro
i
-------
en
O
| Facility/Location ' JMethylenebiS(phenylisocyanate) |4,4-Methylenedianiline (Methyl ethyl ketone (Methyl isobutyl keione
| Ibs/yr | lbs/yr
| Akzo/Columbus OH I i , ,__, . * *
+ I ' I 27999 | 2200 ( 1299 |
| Akzo/Louisville KY I i i * *
+ I J I . 9222 | 8265 | 2470 |
JAllied-Signal/Green Island NY j i * * *
| Amer. Cyanamid/Charlotte NC | I i . * *
| Amer. Cyanamid/Kalamazoo HI I i , . * *
+ ; ; J i i i
| Amer. Cyanamid/UalIigford CT I I i . * *
1 I I | 148 I 549
+
| AMETEK/Uilmington. OE | j i .
| Apex Chem./Elizabethport NJ | j ? * *
| Ashland Oil/Calumet City, IL | H6 | | uj j ! *
* * + * | ' I
| Ashland Oil/Cleveland OH | 0| I * *
+ + ' ' I I I 37
Auralux/Norwich CT | i i
1240 | 39
BASF/Anaheim CA I i , ,
I I 9100
BASF/Detroit Ml I i .
I
............ * .................... * ............
2260° I | 1498
Borden/Demopois AL | i
| Borden/Diboll TX | i . .................... * ............
| Borden/Fayettevill NC I i , * ...................... * .................... * ............
* ........... :. .................... ! ............................... ; I I i
Borden/Freemont CA
i
- ............... «. ............................... +
Borden/Kent WA I i
-------
* «.
Facility/Location lnofh,,i*. u- / L. . * ""* + *
1 iHethyleneb.sCphenyUsocyanate, M-Hethylenediani line (Methyl ethy, ketone (Hethy, isobutyl ketone (Methyl .thac.y.ate (Naphthalene"
+ 1 ius/yr | Ibs/yr | Ibs/yr 1 IK I
| Borden/La Grande OR | .
+ * +
| Borden/Louisville KY | .
| Borden/Hissoula HI | ,
; * !
1 Borden/Sheboygan Ul |
* +
1 Borden/Springfield OR |
; * +
1 Borden, Perk ins/ Alexandria LA |
* + +
| Borden, Perk ins/High Point NC | I
TO * + '
m 1 Borden, Perkins/West Mentis AR 1 I ,
11 + 1
- + _
| Borden.Acme/Forest Park IL | 20 i
1 Dyno(Brancor)/Virginia HN | ,
* + )
| Brand- S, Cascade/Eugene OR |
+ '
I BTL/Malvern AR | .
+ i
| STL/Blue Island IL 1 ,
+ ' 1
BTL/Toledo OH 1 ,
* ' 1
Capital/Columbus OH 1 ~ ,
; i °J
| Cargill/Carpentersville IL | (
; * !
| Cargill/Forest Park GA | ,
; * ;
1 Cargill/Lynwood CA 1 ,
* + +
1 1 1 |
1 1 1 |
- J ' 1
! ' 'i
. 1 ' ' i
""i ; ; ;
+ +
. i i i ;
* + + «.
1 i i i
1 ' ii
- ! ' ' I
; ; ; ;
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11 II
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. ! ' i i
+ + i
1 1 | 8,
... ! ' 1 "1
: * * +
AO
-------
CO
ro
| CL Ind/Georgetown IL |
| CNC Int./Uoonsocket Rl |
* +--
| Commercial Prod/Hawthorne NJ |
* +--
| Cook Comp/North Kansas City HO |
| Courtaulde/Berkeley CA |
| DB Western/Las Vegas NM |
* +--
| Delta Resins/Detroit MI |
| Delta Res ins/Mi Iuaukee Ul |
| Dexter/Birmingham AL |
| Dexter/Uaukegan IL |
| Dock Resins/Linden NJ |
| DuPont/Parkersburg UV |
| Dyno/Uhite City OR |
| Eastern Color/Providence Rl I
I
998 |
998 |
+ * +
(Methyl ethyl ketone (Methyl isobutyl ketone (Methyl methacrylate (Naphthalene
1 lbs/yr I >bs/yr | lbs/yr | lbs/yr
i::::::r:::::::; ;
..! , i j ;
-! i ! ZIII
01 17AOO I *\tnf\ i
I i<:«yy | 2499 | 40499
* *
I 193°° I 90 | 2040 |
* ;
| 998
* ....................... * .................... + ............
998
........
. * ....................... * .................... + ............
I «8300 I 3840 | 998 |
* .................... * ....................... + .................... + ............
I 380° I «000 | | 499
"* .................... * ....................... * .................... + ............
J 106 I I 184 I
"* .................... * ......... .............. * .................... + ............
* .................... * ....................... * .................... t ............
+ ....................... * .................... + ............
998
| Exxon/Houston TX |
| General Elec./Coshocton OH |
+ +---
| PD George/St. Louis MO |
| Georgia-Pacific/Albany OR |
*
+ .................... + ............
-------
CD
I
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I Georgia-Pacific/Colurtxjs OH |
| Georgia-Pacific/Conway NC |
| Georgia-Pacific/Crossett AR |
| Georgia-Pacific/Elk Grove CA |
| Gerogia-Pacifie/Eugene OR |
| Georgia-Pacific/Grayling HI |
| Georgia-Pacific/Louisville HS |
| Georgia-Pacific/Lufkin TX |
JGeorgia-Pacific/Peachtree City G|
JGeorgia-Pacific/Port Wentuorth G|
JGeorgia-Pacific/RussetlviUe SC |
JGeorgia-Pacific/Taytorsville HS |
| Georgia-Pacific/Ukiah CA |
| Georgia-Pacific/Vienna GA |
| Guardsman/Grand Rapids HI |
| Hercules/Chicopee HA |
| Hercules/Hiluaukee UI I
I
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CD
cn
| Facility/Location |
jSchenectady/Rotterdam Junction N|
| Schenectady/Schenectady NY |
| SEQUA/Chester SC |
| Simpson Timber/Portland OR |
* +-
| Southeastern Adh/Lenoir NC |
* +-.
| Southeastern Adh/Ridgeway VA |
| Spaulding Comp/De Katb IL |
+ +--
| Spaulding Comp/Tonawanda NY |
+ +--
| Spurlock/WaverIy VA |
| Stuart-lronsides/Colunfcus OH |
| Sybron Chem/Elmuood Park NJ |
| Sybron Chem/UelI ford SC |
| Synthron/Morganton NC |
| Ultraform/Theodore AL |
(Unilever Nat Starch/Salisbury NC|
| Union Carbide/Somerset NJ |
+ +--
| Valentine Sugars/Lockport LA |
| Valspar.HcUhorter/Garland TX |
]lbS/yr I lbs/V I Ibs/yr I ,bs/yr
*. * * +
] I 998 | |
* * * +
----i'-^''-"^-^^3::::::i;:::::::;:i::::;::i;
i j i ; ! :::
] i i i ,
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I I 20 I | I
! ! ; j ' j 509'
J J I I I "iwa"
' I I 540 | |
iiii:::::::i ; ; ;
; ; ; ; ;
i i I ; ;
-------
I Valspar.McWhorter/Kankakee IL |
| Uestinghouse Elect/Hanpton SC |
| Westinghouse Elect/Manor PA |
* + -
(West Point-PepperelI/Opelika AL I
* +
JMethyl ethyl ketone |Methyl isobutyl ketone (Methyl methacrylate (Naphthalene
] lb^r j lbs/>"- I tbs/yr | lbs/yr
I 1498 I 499 | i
I 88000 | | I
+ + + +
; ; i i
Total tons/yr
7670
+ .................... + ............
59.96 , W.W1 , 3 835
CD
I
-------
ri^i^l^^
| Akzo/Columtous OH I lii * * * + +
1 I 509 I | i ,
* + + + + ' * II | 6999
| Akzo/Louisville ICY | | i , ""* * * * +
* + + * + ] I I 1H°8 I | 32434
(AUied-Signal/Green Island NY | 4| 2016 | I I * * * +
| Amer. Cyanamtd/Charlotte NC | I I i * * * * +
| Amer. Cyanamid/Kalamazoo HI | I I i * * * * +
| Amer. Cyanamid/UdU igford CT | °l I I 1 + + * *
| AMETEK/Uilmington, DE | | 509 I 1 ] + * * *
tn I Apex Chem./Elizabethport NJ | | i i "* * * + *
°° + ' + + + + | ' 'I I
| Ashland Oil/Calumet City, IL | | 390! | i + * + +
+ + t + [ J I | 6489 | | 11W1
| Ashland Oil/Cleveland OH | | 276 I I I * * * *
| Auralux/Norwich CT | I i * * + + +
| BASF/Anaheim CA | | i , * * * + +
* * * + + | , ' I 53 I | 1920
| BASF/Detroit HI | III + * + *
| Borden/Demopois AL I I 509 I I ! + * + *
+ * I ! ! !. iii i
| Borden/Oiboll TX | | 998 I I * + + *
| Borden/Fayettevill NC | | 998 I I "I + * * *
| Borden/Freemont CA I I 509 I I I * + * +
+ ' ' I I I i i
+ + + + ' II j
i oo i ucn/ikcnt WA I I «;rio I t --"»----.-.-+ --.__.__ __ » + _ __
I i -*ov i i i .
11 I I II I
-------
| Borden/La Grande OR |
| Borden/Louisville ICY |
+ ................................ *
| Borden/Missoula MT |
+ ................................ *
| Borden/Sheboygan UI |
| Borden/Springfield OR |
* ................................ *
| Borden, Perk ins/Alexandria LA I
| Borden, Perk ins/High Point NC |
| Borden, Perkins/West Menphis AR I
* ................................ :
| Borden, Acme/Forest Park IL |
| OynoCBrancoD/Virginia HN |
; ................................ *
| Brand-S, Cascade/Eugene OR
I 509 I
-- + + -
| 4700 |
| 998 |
| 998 |
-- + + -
| 998 |
--« + -
- + 4-
; *- * * +
Phthahc anhydride (Propionaldehyde |Propylene oxide (styrene |Tetrachl0roethylene |Toluene
' 'hcA" I lbs/V I tbs/yr | Ibs/yr | (bs/yr
I I I I
^
I
998
12100
............... *
* ................
| 2899 I
I 998 I
' ........ !
+
+ ................ +
+ ........ *
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+ ........ *
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+ ........
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* ................................ I
I BIL/Toledo OH I
* ................................ !
I Capital/Columbus OH |
* ................................ +
| Cargill/Carpentersville IL I
* ............................ --!
| Cargill/Forest Park GA I
* ................................ I
I Cargill/Lynwood CA I
i i
I ........ I ............ I..
| 998| I
* ........ + ............ *
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................ + ........ + .................... *
15A7 '
i i
* ........ *
I 3770 |
I 6699
+ ........
i 2620
+ ........
, 7600
+ ........
- 2660
-------
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Georgia-Pacific/Columbus OH
2074 I I ""* ................ + ........ * .................... * ........
| Georgia-Pacif ic/Conway NC
+----___.___ ^
| Georgia-Pacific/Crossett AR
+ ._.___ _.._,.
| Georgia-Pacific/Elk Grove CA
| Gerogia-Paci fie/Eugene OR
+
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| Georgia-Pacific/Louisville MS
+ .
| Georgia-Pacific/Lufkin IX
(Georgia-Pacific/Peachtree City
|Georgia-Paci fie/Port Wentworth
|Georgia-Pacific/Russellville SC
|Georgia-Pacific/Taylorsville MS
| Georgia-Pacific/Ukiah CA
| Georgia-Pacific/Vienna GA
| Guardsman/Grand Rapids Ml
| Hercules/Chicopee MA
+
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-! !...J J ' i ii 'I
i i is; i i ; ;
-. 1 1 ' I I 1
..! !..."!!.! 1 i i ii "I
-! i...~! ; ; i i ; ;
j! 1..."! ] ! iZIZIIIIIIIJ
' !--.*"! ! !.. ; i I i
i i M i i i ; ; ;
j i.j"7.i i i i ; ; ;
.J I..:.! i ! i. i ; ;
1 | 2100 | | 111 * *
.! ! J ] ""1 1 1 «M | ;«oo
.; ! ! ; j i i ; ;
.; ! i ! ; i i ; ;
1 ' ' ' i i ; ; ;
-------
co
I Hercules/Savannah GA |
+ +
| Hercules Resins/Hattiesburg MS |
| Hersite/Manitowoc Ul |
| Hickson/Danville VA |
|Hoechst Celanese/Hount Holly NC |
+ +
| Hoechst Celanese/Bishop TX |
| Hugh J. Resins/Long Beach CA |
| Insulating Mat/Schenectady NY |
| WAX Corp/Rock Hill SC |
| Lauter Int/Moundvilie AL |
+ +
| Masonite/Gulfport MS |
Phthalic anhydride (Propionaldehyde jPropylene oxide |Styrene |Tetrachloroethylene JToiuene
...» + + lbS/Vr ' lbS/Vr I lbs/>"- I lb^/yr I Ibs/yr | ibs/yr
..; ; i ^iiiiiii!ii:i:iii:::::::i:i
.. + + ] ' I II | 640600
-.1 M LlIIIII i i i i
..! ! ! ! ' i '! i""I*
..I....2:*.! J j i *i "1 il
-i---"i ; ; i :::iij i
i ii i i i ; ;
I i«»o I I i "". '. ' *
.., , ' 'III I 81500
i i i ; ; ; ; ;
; ; ; ; ; ; ; i
1 I 998 I
-+ * + + + ' ' I
I 3M/Cordova IL I
* ................................ I
| 3M/Cottage Grove HN |
+ ................................ +
| Monsanto/Addyston OH I
* ................................ J
| Monsanto/Springfield MA I
* ................................ ;
| National Casein/Chicago it |
* ................................ *
| National Casein/Tyler TX I
* ..................... . .......... !
I
........ ............
| 1250 | ,
° I I 15 | , 38700
"Q"* ................ * ................ * ........ + .................... + ........
' I I I |1004000
.......... * ................ * ........ * .................... * ........
| |
+ ........ +
II
«M , 2610
+ ................ * ........ * .................... + ........
' ' I
...................... * ........ * .................... * ........
i i i i
I
-------
03
CO
| Neste Resins/Moncure NC |
| Neste Resins/Spokane UA |
| Neste Resins/Springfield OR |
| Neste Resins/Toledo OH |
| Neste Resins/Uinnfield LA |
+ *--
| Occidental/Kenton OH |
| Occidental/Niagara Falls NY |
| Occidental/North Tonawanda NY |
| Perstorp/Florence MA |
| Pioneer Plastics/Auburn ME |
| Plastics Eng/Sheboygan UI |
| Plastics Manuf/Dallas TX |
I PMC Inc/Fords NJ |
+ + --.
| PPG Ind/Circleville OH |
| PPG Ind/Oak Creek Wl |
| Reichhold/Bridgeville PA |
| ResinalI/Severn NC |
| Rhone-Poulenc/Louisville KY |
| A100 j
.
............... ................ + ................ + ........ + .................... + ........
| 14500 i .
| 1621 i .
| 13895 I i
i 17062 i !
* ........ ' ............ I
| I n ,
«. ........ + ............ ]
I 21820 I I
I
*
........ * ................ *
* ................
* ........
| I I
I 5W8 i ,
'
............ + ................
*
i
+
*
23400 | 16000
* ........
| 499
+ ........
+ ........ +
.
........... ................ *
- + + +--
I 1^98 | |
i j "7"
i i i
| 885 | I
i
* ................ + ........ +
I I 998 |
* ................ * ........ +
i i 1*0 1
156A
I I I** |
* ................ + ........ *
I | 4744 |
* ................ + ........ +
I
| 1031
| 68300
| 15378
I
348
-------
oo
i<^^
|Schenectady/Rotterdam Junction N| | 44267 | I 1 * * * +
* + + + I ; I II | 7622
| Schenectady/Schenectady NY ( I 9499 i i ! * * * +
* + + ' ) _J I I 999 | | K98
| SEQUA/Chester SC I I | , * * * * +
+ ! ] J J I «0 | | 1860 | |
| Simpson Timber/Portland OR | j 1583 | * * * * +
| Southeastern Adh/Lenoir NC | | i i * *" * * +
| Southeastern Adh/Ridgeuay VA | | i i ! * * * +
| Spaulding Comp/De Katb IL ( | 633 | I ""] * * * *
| Spaulding Comp/Tonawanda NY | | 1399 I i ! * * * *
| Spur lock/Waver I y VA | III * + * *
| Stuart -Irons ides/Columbus OH | | 20 I I \ * * * *
| Sybron Chem/ElmMood Park NJ | II i * * * * +
| Sybron Chem/Wellford SC | | i i * * * + +
* + + + ' ] I II 998 | 1559
| Synthron/Morganton NC | III + * + *
| Ultraforro/Theodore AL | III * * * *
(Unilever Nat Starch/Salisbury NC| I i i
| Union Carbide/Somerset NJ | I i , * + + + +
| Valentine Sugars/Lockport LA | | 92/1 I i | + * *'
1 ' i i "" ""i i"
-------
I Facility/Location |t
* +-
+ *-
| Westinghouse Elect/Hanpton SC |
+ + -
(West Point-Pepperel I/Opel ika AL |
+ + _
1 Total lbs/yr |
| Total tons/yr 1
'CklL/yTS ! Ibl/yr I^^T 1 PhthaUC "**"" |Pr°Pi°naldehyde ^°^ <««* Istyrene |Tetrachloroethylene (Toluene
yr ' Ibs/yr | lbs/yr | lbs/yr | lbs/yr lbs/yr \ lbs/yr
0 1 1 | 499 | |
+ + +
1 20 1 1 | |
* + -.
1 1 1 1 |
* 1 218904 | 0 | 61397 | ;50 |
0.002 (109.452 | 0 | 30.6985 | 0.225 |
----- -f- + -,..
A 99 1
+ +
| 990 |
1
22400 | 509967 |
11-2 |254.984 |
| 6399
+
| 320000
| 1998
1
23410 (2435627
11.705 (1217.81
--.._.__ ---- + -------- + -------. -__..._...__ + . .___.._
C30
I
-------
1,1,1-trichloroethane |1.1.2-trichloroethane |1,2.4-Trimethylbenzene |Vinyl acetate
| Akzo/Columbus OH I i , + * *
* I | ; ] | i i
| Akio/Louisville KY | i , * *
lAllied-Signal/Green Island NY I I "* * *
*.. 1 J I 28682 | | |
| Amer. Cyanamid/Charlotte NC | I i * + *
| Amer. Cyanamid/Kalamazoo MI | i , * *
| Amer. Cyanamid/Wal ligford CT | I * * *
| AMETEK/Uilmington. DE | I i * * *
dr, | Apex Chem./Elizabethport NJ | i . * + *
| Ashland Oil/Calumet City. IL | | I * + *
+ + + |'l| 5485
| Ashland Oil/Cleveland OH | | j * * +
| Auralux/NorMich CT I i , * + *
* | | | I I |
| BASF/Anaheim CA I i , "* * +
* I | | I I |
| BASF/Detroit Ml | i . + + +
| Borden/Demopois AL | i * +
| Borden/Oiboll TX | i . + *
| Borden/Fayettevill MC I i , * * +
+ ; | I I | |
| Borden/Freemont CA I i , , + +
*-- I ' I I I
-------
cn
1
1
+
1
f
1
+
1
+
f
+
1
-f -
+ -
+ -
+ -
!
i
+-
i
+-
i
i
+-
+
i
+-
1
T +- .+. ..
JToluene-2 4-dMsocyanate jl.Z.A-triehlorbeniene |1. 1.1-trichloroethane |1.1,2-trichloroethane |1.2.«-Tri«thylbenzene
| .lt>^ I lbs/*r 1 Ibs/yr lbs/yr | (bs/yr
Borden/La Grande OR | i * * *
Borden/Louisville Kr 1 i , + +
;. ' i i i
Borden/Missoula MT | i + *
Borden/Sheboygan UI | . * +
+ + +
Borden/Sprtngfield OR | i * +
+ + + ' 1
Borden, Perk ins/ Alexandria LA | i + * <
* + + 1
Borden,Perkins/High Point NC 1 i * * <
* ! ! i
Borden,Perkins/West Memphis AR | i + + *
- ; ! i i
Borden.Acme/Forest Park IL | i + + <
* ; J i i
Dyno(Brancor)/Virginia MN i * + *
Brand-S, Cascade/Eugene OR | i + * +
BTL/Malvern AR | , * + * +
BTL/Blue Island IL | i + * +
BIL/Toledo OH i * * +
* i J 1 |
Capital/Columbus OH | i + + +
* ; ! i i
Cargill/Carpentersville IL | i * * +
* 1 I 1 1
! J ' 1 |
Cargill/Lynwood CA 1 i , * + +
' ' ' 1 1
+ -. ._..____
(Vinyl acetate
| lbs/yr
1
1
|.
h
-------
.......
I CL Ind/Georgetown IL I I * ...................... * ...................... * ....................... + .............
; ................................ ' ......................... 1 ...................... ] .............. 1958| i i
| CMC Int./Uoonsocket RI | i ...... * ...................... + ....................... + ..............
| Commercial Prod/Hawthorne NJ | i ........ * ...................... + ...................... + ....................... + ..............
| Cook Conp/Horth Kansas City MO | 0 i * ...................... * ...................... + ....................... + ..............
| Courtaulde/Berkeley CA I I "* ...................... * ......... ' ............ + ....................... + ..............
* ................................ ' ......................... ] ...................... ] 39°°l | ,
| DB Western/Las Vegas MM | i ....... * ...................... + ...................... + ....................... + ..............
| Delta Resins/Detroit HI | i * ...................... + ...................... * ....................... + ..............
& | Delta Resins/Milwaukee Ul I I ...... * ...................... * ...................... * ....................... + ..............
C» * ................................ I ......................... ] I 2491 | | |
| Dexter/Birir.ingham AL | i * ...................... * ...................... + ....................... + ..............
| Dexter/Waukegan IL' | i * ...................... + ...................... + ....................... + ..............
| Dock Resins/Linden NJ | i ..... ? ...................... * ...................... * ....................... + ..............
I DuPont/Parkersburg UV | j * + +
| Dyno/Uhite City OR | i * * + +
| Eastern Color/Providence RI I i * + + +
+ I I I 1998 | | (
Exxon/Houston TX | i
al Elec./Coshocton OH | i
+ + ' I mouif | i .
| PD George/St. Louis MO I i * * * +
| I I
I i ?
I
General Elec./Coshocton OH I i . * + +
1 I I 108027 |
I |
j Georgia-Pacifie/Albany OR I i . *
1 III
-------
' 01
i a
', t>
> u
1 -
| C
i N
i |
1 4-1 -V
1 01
i 6 .
i U.
roethane
r
i O X
t .C C
' U i
'
!
u
'
.
1
n
_.
ific/Conuay HC
.
i
n
fic/Crossett AR
.
n
j
>
o
.*
i
'
u
(0
.
t
n
ific/Eugene OR
i
.
i
0.
.
Fie/Grayling HI
u
a
.
i
n
.
CO
X
1
I
%
.
1
D
fic/Lufkin n
.
i
n
/Peachtree City C
-
1
n
C3
>
E
!
>
Q.
i-Pacific
D
/Russell vi He SC
-
i
CA
X
i
L.
"
»
ific/Ukiah CA |
i
.
n
3
'
n
X
I
L
a
ec
3
'
B-60
-------
-Hity/Location
|Toluene.
| Hercules/Savannah GA |
| Hercules Resins/Hattiesburg MS |
| Hersite/Manitowoc UI I
M,2..-tricMor*nZene |^^
] ........ lb^ I lbs"r ' I ">s/yr | lbs/yr ] lbs/yr
i * ..................... + ....................... * ..............
| i * ..................... + ....................... + ..............
i , * ...................... * ....................... + ..............
i i i
I
o
| Hickson/DanvHle VA |
+ .................. . ............. '
JHoechst Celanese/Mount Holly NC |
| Hoechst Celanese/Bishop TX |
| Hugh J. Resins/Long Beach CA |
| Insulating Hat/Schenectady HY |
| WAX Corp/Rock Hill SC |
,
] ..................... J I I | 4420
j ,2| j .................. + ....................... * ..............
i ? ..................... * ....................... * ..............
| . ............... + ....................... * ..............
| ! .................... * ....................... * ..............
| , .......... * ...................... + ....................... * ..............
............. ................ * ...................... ....................... ..............
Hasonite/Gulfport MS
3H/Cordova IL
* ....................... * ..............
+ +
I Monsanto/Addyston OH |
| Monsanto/Springfield MA |
| National Casein/Chicago IL |
+ - +
| National Casein/Tyler TX |
+ -- ---+
j Neste Resins/Andalusia AL |
* .......................
. * ..................... * ....................... * ..............
1 ...................... ) I I 61700
................... * ....................... + ..............
............... + .......................
* ..............
+ .......................
-------
DO
I
| Neste Resins/Moncure NC |
| Neste Resins/Spokane UA |
| Neste Resins/Springfield OR |
| Neste Resins/Toledo OH |
| Neste Resins/Uinnfield LA |
| Occidental/Kenton OH |
| Occidental/Niagara Falls NY |
| Occidental/North Tonawanda NY |
| Perstorp/Florence HA |
| Pioneer Plastics/Auburn ME |
| Plastics Eng/Sheboygan UI |
| Plastics Hanuf/Dallas TX |
+
| PHC Inc/Fords NJ |
I PPG Ind/Circleville OH I
i
e |1.2.4-tr|chlorbenzene |l.1.1-trJchloroethane |1,1.2-tMchloroethane |l.2.4-Trin«thyiben«ne" Ivin^'aceta^e"
I Ibs/yr |
i i i
;::::::;: ; ;
; ; - i ;
j i ' ; ;
j ; i ; ;
i jiizzizzzizzzzzz
:iz:z:izz:±i i i
..... *
+ ....................... + ..............
...
........ + ...................... * ....................... + ..............
I PPG Ind/Oak Creek UI |
| Reichhold/Bridgeville PA I
+ ..............
+ ..............
I Rhone-Poulenc/Louisville
KY
+ ..............
-------
|Schenectady/Rotterdam Junction N|
| Schenectady/Schenectady NY I
11,1,1-trichloroethane |1.1.2-trichloroethane 11.2,4-Trimethylbenzene Ivinyi acetate
_.J lbS^ I »*/yr I Ibs/yr | lbs/yr
| SEQUA/Chester SC I
| Simpson Timber/Portland OR |
| Southeastern Adh/Lenoir NC |
| Southeastern Adh/Ridgeway VA |
| Spaulding Comp/De Kalb IL | .
^, | Spaulding Coop/Tonawanda NY |
| Spurlock/WaverIy VA j
| Stuart-Ironsides/Columbus OH |
*--- +
| Sybron Chem/Elmuood Park NJ |
| Sybron Chem/Wellford SC |
| Synthron/Horganton NC |
| Ultraform/Theodore AL |
+ +
|Unilever Nat Starch/Salisbury NC|
| Union Carbide/Somerset NJ |
| Valentine Sugars/Lockport LA |
| Valspar.HcWhorter/Garland TX I
*
i
+ ..............
+
"
*
* ....................... + ..............
* ...................... +
* ....................... + ..............
* ...................... *
.....
* ...................... *
.. + ..
I
I
+ -
1836 |
+ -
* ....................... + ..............
* ....................... + ..............
*
+ +
* ..................... * ......................
I
919 |
+ -
+
* +
+ .......................
+ ..............
+ - +
-------
^
* ................................
I Vaispar.McWhorter/Kankakee IL I
; ................................ '
| Westinghouse Elect/Hampton SC I
+ ................................ I
| Uestinghouse Elect/Manor PA I
+ ................................ ;
(West Point-Pepperell/Opelika AL |
i lbs/yr i (bs/yr
lbs/yr
? ...................... + + ..............
!... ' i i
. + ...................... * ....................... + ..............
! 23000
* ......................
,
DO
I
CO
......... --
»»i
-------
| Facility/Location
1
+ --
| Akzo/Colunbus OH
+
| Akzo/louisvilte KY
*
(Allied- Signal /Green Island NY
+-- --
| Amer. Cyanamid/Charlotte NC
+
| Amer. Cyanamid/Kalamazoo MI
+
| Amer, Cyanamid/Ualligford CT
+
| AHETEK/Uitmington, DE
__ + -
^ | Apex Chem./Elizabethport NJ
-P* +
| Ashland Oil/Calumet City. IL
+
| Ashland Oil/Cleveland OH
+
| Auralux/Norwich CT
+
| BASF/Anaheim CA
+ _
| BASF/Detroit HI
f ,
| Borden/Demopois AL
f
| Borden/Diboll TX
+
| Borden/Fayettevill NC
+ .-
| Borden/Freemont CA
4 _. _ ^
| Borden/Kent WA
| Xylene (mixed isomers) |o-xylene| Total | Total
1 lbs/yr j lbs/yr jlbs/yr |tons/yr
1 15499 | | 93803 (46.9015
I 92283 | J232653 |116.327
* + -- + +
I 1251 | | 35552 | 17.776
1 5480 | | 58818 | 29.409
I I | 77192 | 38.596
* . _.+ + +_
I 11/15 | (129301 (64.6505
* + + +
1 | ( 1527 | 0.7635
+ -+ + +
1 I | o | o
* " - + +-- +
1 77 | | 41534 | 20.767
* ---- ..+ + +
1 | | 6075 | 3.0375
* * + -- +
1 I | 2996 ( 1.498
I 5100 | | 23136 | 11.568
* + +- +
I 33500 | | 78211 (39.1055
I I | 15137 | 7.5685
* + -+-- +
I I | 16396 | 8.198
* + + + --
I ! | 36206 | 18.103
* + + +
I | | 6657 | 3.3285
+ - - "--+-"-----.+.-..-__+-,.._.
! | | 7606 | 3.803
-------
j Facility/Location | Xylene (mixed isomers) |o-xylene| Totail'iotai
+ ' lbs/yr | Ibs/yr |lbs/yr jtons/yr
+ ' I 20 |
I Borden/Missoula MT | .
f .... ..... '
| Borden/Sheboygan UI | i
I Borden.Perkins/Alexandria LA | ] j ^ j
!..B°[den'PerklnS/Hi9h POI'nt NC ' I I 1° I an i i
I j£VU I I
I Cargill/Lynwood CA I ,,7n , . ,. *
1 137° I | 9315 | 4.6575
-------
I Facility/Location | Xylene (mixed isoraers) |o-xylene( Total | Total
] I lbs/V I Ibs/yr jlbs/yr |tons/yr
JCL |nd/Georgetown IL | 252 ] j 89969 144^9845
J CNC.;n.t;^n^ke| R' J I I il397"l76985"
| Conmercial Prod/Hawthorne NJ | i I 0 I 0
1
+-
1
f-
1
1
1
1
1
1
1
f--
1
+-
1
1
1
Courtaulde/Berkeley CA ,
DB Western/Las Vegas NH |
Delta Resins/Detroit HI |
Delta Resins/Milwaukee Ul |
Dexter/Birmingham AL |
Dexter/Uaukegan IL |
Dock Resins/Linden NJ |
DuPont/Parkersburg UV |
Dyno/Uhite City OR |
Eastern Color/Providence RI (
Exxon/Houston TX |
General Elec./Coshocton OH |
PD George/St. Louis HO |
Georgia-Pacific/Albany OR |
600 | | 28931
1 1 o
I | 4990
I | 5984
59000 | (116651
6800 | | 42090
93 | | 1289
1 | 0
| (235200
998 | ( 8984
10930 | | 68134
17200 ( (153753
I I 0
I (660780
(14.4655
1 o
| 2.495
| 2.992
(58.3255
| 21.045
| 0.6445
1 o
| 117.6
| 4.492
| 34.067
(76.8765
1 o
*
| 330.39
-------
CO
I
I
I Facility/Location | xylene (mixed isomers) |o-xylene| Total | Total
I I lbs/y I Ibs/yr |lbs/yr |tons/yr
| Georgia-Pacific/Colu^us OH | j "
NC | I
A" ! I
.. Grove CA ' w81
I Gerogia-Pacific/EugeneOR | J 'iaaOO | 9^
!..Ceo'9!a:PK'!!^ay!!n9 MI | i
!.Geo'9!a;Pa'!!!^?u!!:ule MS j 1
I ^orgia-Pacific/Lufkin TX | ""j
jGeorgia-Pacific/Peachtree City G| ""]
JGeorgia-Pacific/Port Uentworth G| ] l"2300o"|""\\~j
iGeorgia-Pacmc/RusseUviUe SC | \ "
!Geo'9!a:p!!!!i!'!?ylorsvUte MS'
!-.Ge"9!a:p"!!:^uk::h.CA. j
!...G?°'9'a:pa'i!:^v:enna GA j
| Guardsman/Grand Rapids H, | A3000
j He^u!e?^h:!°pee.MA ; I i"229907^495"
J H:"u!e^M!!wa^ee.u;... ! I
I Hercules/PortUnd OR , j
-------
+
I Facility/Location | xylene (mixed isomers) |o-xylene| Total | Total
] I lbs/y I Ibs/yr (Ibs/yr |tons/yr
| Hercules/Savannah GA | | J 54934 J 27'~~
| Hercules Resins/Hattiesburg HS | 368 | ^^ J342-109"
| Hersite/Hanitowoc Ul | | i 38QO , } g
I Hickson/DanvilleVA | | | 35922 | 17*961
(Hoechst Celanese/Hount Holly NC | 330 | j 4563 | 2~2815
| Hoechst Celanese/Bishop TX ( J |1.«+M|W«!o«"
| Hugh J. Resins/Long Beach CA | I I 0 I 0
co + + '
^ | Insulating Mat/Schenectady Nr | 35000 | |188371 (94.1855
| Lawter Int/Moundville AL | 2209 | (69130(34^65
| Masonite/Gulfport MS | I I 0 I o
J 3M/Cordova IL | H3o0 | |231oo7 J^s.ooo
| 3H/Cottage Grove HN | 10700| |1.5E+06|736.513
| Monsanto/Addyston OH | | J365793 Jj«^"
| Monsanto/Springfield HA | 090 j Juoiso | 85^065
| National Casein/Chicago IL | | | 499 I o 2495
| National Casein/Tyler TX | I | 499 J 0.2495
j Neste Resins/Andalusia AL ( I I 0 I 0
-------
( Facility/Location
1
+
| Neste Resins/Moncure NC
f .
| Neste Resins/Spokane UA
+
| Neste Resins/Springfield OR
| Neste Resins/Toledo OH
+
| Neste Resins/uinnfield LA
| Occidental/Kenton OH
+ _
( Occidental/Niagara Falls NY
^ | Occidental /North Tonawanda NY
| Perstorp/Florence HA
| Pioneer Plastics/Auburn ME
| Plastics Eng/Sheboygan WI
| Plastics Hanuf/Dallas TX
+ ............
I PMC I nc/ Fords NJ
| PPG Ind/Circlevilte OH
| PPG Ind/Oak Creek UI
| Reichhold/Bridgevilte PA
| Resinal I/Severn NC
| Rhone-Poulenc/Louisville KY
| Xylene (mixed isomers) |o-xylene| Total | Total
| Ibs/yr | Ibs/yr | Ibs/yr |tons/yr
1 | (253098 (126.549
+- -- + +
I I I o | o
I | (147198 | 73.599
1 1 | 5286 | 2.643
1 | (230846 (115.423
1 1 | 19415 | 9.7075
I | | 72909 (36.4545
I 509 | ( 42251 (21.1255
1 | | 70000 | 35
1 1(0(0
1 1 | 10753 | 5.3765
I I | 5105 | 2.5525
1 998 | | 10725 | 5.3625
I 31100 | (186148 | 93.074
I 20425 | (105313 (52.6565
I I | 8506 | 4.253
I 998 | | 7789 | 3.8945
I 5431 | | 44597 (22.2985
-------
I Facility/Location |
(Schenectady/Rotterdan, Junction N|
| Schenectady/Schenectady NY ,
1 SEOUA/Chester SC ,
| Simpson T iinber/Port (find OR 1
1 Southeastern Adh/Lenoi r NC 1
| Southeastern Adh/Ridgeway VA |
1
| Spaulding Comp/Tonauanda NY |
+--- .... . ..+.
| Spur lock/Waver 1 y VA |
| Stuart-,ronsides,colu*us OH |
| Sybron Chem/Elmgood Park NJ |
+
1 Sybron Chem/Wel Iford SC 1
| Synthron/Horganton NC |
+ _
| Ultraform/Theodore AL |
+ _
(Unilever Nat Starch/Salisbury NC|
+-- _
1 Union Carbide/Somerset NJ 1
| Valentine Sugars/lockport LA |
Xylene (mixed isomers) |o-xylene| Total | Total
tbs/yr | ibs/yr | lbs/yr |tons/yr
343540 | (464565 (232.283
11700 | | 39482 ( 19.741
1 | 9307 | 4.6535
1 |1.1E*06|559.635
1 | 10997 | 5.4985
* + +
1 | 13087 | 6.5435
I | 46575 (23.2875
I | 5601, ,28.0055
I | 8700 | 4.35
I | 60 | 0.03
I I 0 | 0
998 I | 13060 | 6.53
1 | 36494 | 18.247
I | 0 | 0
207 | (458566 (229.283
1 I 1*8 | 0.074
| Valspar.McWhorter/Garland TX (
I 0
-------
CD
I
CO
I Facility/Location | Xylene (mjxed isomers) |o-xylene| Total)
|lbs/yr Jtons/yr
Valspar.HcUhorter/akee ,L ..... ~ ........ '
| Westinghouse Elect/Hampton SC | 65000
| Uestin9house Elect/Manor PA | 6lw"j
|West Point-PeppereU/OpeUka AL j ................ J
9556W
-------
TECHNICAL REPORT DATA
Please read Instructions on the reverse oetore comoiennel
EPA-450/3-92-015 ' '
4. TITLE ANO SUBTITLE
Production of Acetal , Amino, and Phenolic Resins
7. AUTHORIS1
9. PERFORMING ORGANIZATION NAME ANO AOORESS
Emission Standards Division
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
12. SPONSORING AGENCY JYAME. AND.A.ODRESS . . . ,
Director of Air Quality Planning and Standards
Office of Air and Radiation
U.S. Environmental Protection Agency
Research Triangle Park, North Carolina 27711
5. REPORT DATE
Julv 1992
6. PERFORMING ORGANIZATION CODE
8. PERFORMING ORGANIZATION REPORT NO
10. PROGRAM ELEMENT NO.
1 1 . CONTRACT/GRANT NO.
68D10116
13. TYPE OF REPORT ANO PERIOD COVERED
Final
14. SPONSORING AGENCY CODE
EPA/200/04
15. SUPPLEMENTARY NOTES
16. ABSTRACT
This document provides information obtained on the manufacturing
processes of three formaldehyde-based resins - phenolic, amino, and acetal
resins. It also provides information on the companies that produce these
resins and determines those facilities that are major sources of hazardous air
pollutants (HAP's) based on their controlled emission data. A major source is
defined as "...any source or group of stationary sources located within a
contiguous area and under common control that emits or has the potential to
emit considering controls, in the aggregate, 10 tons per year of any HAP or 25
tons per year or more of any combination of HAP's." The information reported
was gathered to support the development of a potential National Emission
Standard for Hazardous Air Pollutants for the manufacture of these ;
formaldehyde-based resins.
" KEY WORDS ANO DOCUMENT ANALYSIS
» DESCRIPTORS
Formaldehyde-Based Resins
Phenolic Resins
Urea- Formaldehyde Resins
Mel ami ne- Formaldehyde Resins
Acetal Resins
Unlimited
b. IDENTIFIERS/OPEN ENDED TERMS
Hazardous Air Pollutants
19. SECURITY CLASS (ThisKeportJ
Unclassified
2O. SECURITY CLASS fJTUtptgff
Unclassified
c. COSATI Field/Group
156
22. PRICE
EPA Form 2270-1 (R»v. 4-77) PREVIOUS COITION is OBSOLETE
-------
2.
3.
nEPORT NUMBER
!n-,m me LPA report numoer a, .ppears ca IRe , a. f
LEAVE BLANK
RECIPIENTS ACCESSION NUMBER
Keserveu lor use by e^n report recipient.
TITLE AND SUBTITLE
x 01 otherwise' subordinate KlnHUe
"oer and include subtitle tor the >pec,tk ,,,ie.
5. REPORT DATE
6.
7-
NSTRUCTIGNS
' J"U ** JlsolaV^ prommenilv. ist Mibutlc. it uwa in smaller
'" m°'e """> one volume, repeat the primary i.tle aJd volurne
PERFORMING ORGANIZATION CODE
Leave blanK.
AUTHORJS)
(EOFREPORT AND PERIOD COVERED
Ind,cate mtenm ,1M1. etc.. and ,f applicable Stes covered.
SPONSORING AGENCY CODE
Insert appropriate code.
SUPPLEMENTARY NOTES
X 3B3KSSS iS
* "IClI"tal '"
ABSTRACT
s!Ln,"l«m b
KEY WORDS AND DOCUMENT ANALYSIS
(b) IDENTIFIERS AND OPEN-ENDED
ended ternu wn,,en , descnptor fom,
,
«PUI»« mtormauon contamed ,n the report, if the report .ontams a
,he ^
^«««!Mn!!.
18. DISTRIBUTION STATEMENT
ttt
19> "rS-K.JS31?1^ CLASSIFICATION
DO NOT submit cia«,fied report, to ,he Na,,onal Techno ,nform,,,on serv,ce
21. NUMBER OF PAGES
22. PRICE
EPA Form 2220-1 (R,». 4-771 (R.v,,..)
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