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APPENDIX B
CRYOGENIC PRECONCENTRATION AND DIRECT FLAME
IONIZATION DETECTION (PDFID) METHOD
*. -- I
u - \
-------
r.
-------
COMPENDIUM METHOD TO-12
DETERMINATION OF NON-METHANE- ORGANIC
COMPOUNDS (NMOC) IN AMBIENT AIR USING
CRYOGENIC PRE-CONCENTRATION AND
DIRECT FLAME IONIZATION DETECTION
(PDFID)
QUALITY ASSURANCE DIVISION
ENVIRONMENTAL MONITORING SYSTEMS LABORATORY
U.S. ENVIRONMENTAL PROTECTION AGENCY
RESEARCH TRIANGLE PARK, NORTH CAROLINA 27711
MAY, 1988
-------
Revision 1.0
June, 1987
METHOD T012
METHOD FOR THE DETERMINATION OF NON-METHANE ORGANIC COMPOUNDS (NMOC)
IN AMBIENT AIR USING CRYOGENIC PRECONCENTRATION AND DIRECT FLAME
IONIZATION DETECTION (PDFID)
1. Scope
1.1 In recent years, the relationship between ambient concentrations
of precursor organic compounds and subsequent downwind concentra-
tions of ozone has been described by a variety of photochemical
dispersion models. The most important application of such models
is to determine the degree of control of precursor organic com-
pounds that is necessary in an urban area to achieve compliance
with applicable ambient air quality standards for ozone (1,2).
1.2 The more elaborate theoretical models generally require detailed
organic species data obtained by multicomponent gas chromatography (
The Empirical Kinetic Modeling Approach (EKMA), however, requires
only the total non-methane organic compound (NMOC) concentration
data; specifically, the average total NMOC concentration from 6
a.m. to 9 a.m. daily at the sampling location. The use of total
NMOC concentration data in the EKMA substantially reduces the
cost and complexity of the sampling and analysis system by not
requiring qualitative and quantitative species identification.
1.3 Method T01, "Method for The Determination of Volatile Organic
Compounds in Ambient Air Using Tenax« Adsorption and Gas
Chromatography/Mass Spectrometry (GC/MS)", employs collection
of certain volatile organic compounds on Tenax* GC with subse-
quent analysis by thermal desorption/cryogenic preconcentration
and GC/MS identification. This method (T012) combines the same
type of cryogenic concentration technique used in Method T01
for high sensitivity with the simple flame ionization detector
(FID) of the GC for total NMOC measurements, without the GC
columns and complex procedures necessary for species separation.
-------
T012-2
1.4 In a flame ionization detector, the sample is injected irito a
hydrogen-rich flame where the organic vapors burn producing
ionized molecular fragments. The resulting ion fragments are
then collected and detected. The FID is nearly a universal
detector. However, the detector response varies with the species
of [functional group in] the o^anic compound in an oxygen atmos-
phere. Because this method employs a helium or argon carrier
gas, the detector response is nearly one for all compounds.
Thus, the historical short-coming of the FID involving varying
detector response to different organic functional groups is
minimized.
1.5 The method can be used either for direct, in situ ambient
measurements or (more commonly) for analysis of integrated
samples collected in specially treated stainless steel canisters.
EKMA models generally ri -;ire 3-hour integrated NMOC measurements
over tr c a.m :o 9 a eriod end are used by State or local
agencies .0 pre..-re St. implementation Plans (SIPs) for ozone
control to achieve compliance with the National Ambient Air
Quality Standards (NAAQS) for ozone. For direct, in situ ambient
measurements, the analyst must be present during the 6 a.m. to
9 a.m. period, and repeat measurements (approximately six per
hour) must be taken to obtain the 6 a.m. to 9 a.m. average
NMOC concentration. The use of sample canisters allows the
collection of integrated air samples over the 6 a.m. to 9 a.m.
period by unattended, automated samplers. This method has
incorporated both sampling approaches.
2. Applicable Documents
2.1 ASTM Standards
D1356 - Definition of Terms Related to Atmospheric
Sampling and Analysis
£260 - Recommended Practice for General Gas Chromato-
graphy Procedures
£355 - Practice for Gas Chromatography Terms and
Relationships
-------
T012-3
2.2 Other Documents
U. S. Environmental Protection Agency Technical Assistance
Documents (4,5)
Laboratory and Ambient Air Studies (6-10)
3. Summary of Method
3.1 A whole air sample is either extracted directly from the ambient
air and analyzed on site by the GC system or collected into a
precleaned sample canister and analyzed off site.
3.2 The analysis requires drawing a fixed-volume portion of the
sample air at a low flow rate through a glass-bead filled trap
that is cooled to approximately -186°C with liquid argon. The
cryogenic trap simultaneously collects and concentrates the
NMOC (either via condensation or adsorption) while allowing
the methane, nitrogen, oxygen, etc. to pass through the trap
without retention. The system is dynamically calibrated so
that the volume of sample passing through the trap does not
have to be quantitatively measured, but must be precisely
repeatable between the calibration and the analytical phases.
3.3 After the fixed-volume air sample has been drawn through the
trap, a helium carrier gas flow is diverted to pass through
the trap, in the opposite direction to the sample flow, and
into an FID. When the residual air and methane have been
flushed from the trap and the FID baseline restabilizes,
the cryogen is removed and the temperature of the trap is
raised to approximately 90°C.
3.4 The organic compounds previously collected in the trap revol-
atilize due to the increase in temperature and are carried into
the FID, resulting in a response peak or peaks from the FID.
The area of the peak or peaks is integrated, and the integrated
value is translated to concentration units via a previously-
obtained calibration curve relating integrated peak areas with
known concentrations of propane.
3.5 By convention, concentrations of NMOC are reported in units of
parts per million carbon (ppmC), which, for a specific compound,
is the concentration by volume (ppmV) multiplied by the number
of carbon atoms in the compound.
-------
T012-4
3.6 The cryogenic trap simultaneously concentrates the NMOC while
separating and removing the methane from air samples. The
technique is thus direct reading for NMOC and, because of
the concentration step, is more sensitive than conventional
continuous NMOC analyzers.
Significance
4.1 Accurate measurements of ambient concentrations of NMOC
are important for the control of photochemical smog because
these organic compounds are primary precursors of atmospheric
ozone and other oxidants. Achieving and maintaining compliance
with the NAAQS for ozone thus depends largely on control of
ambient levels of NMOC.
4.2 The NMOC concentrations typically found at urban tes may
range up to 5-7 ppmC or higher. In order to determine transport
of precursors into an area, measurement of NMOC upwind of the
area may be necessary. Upwind NMOC concentrations are likely
to be less than a few tenths of 1 ppm.
4.3 Conventional methods that depend on gas chromatography and
qualitative and quantitative species evaluation are excessively
difficult and expensive to o- rate and maintain when sp--. ated
measurements are not needed. The method described here -volves
a simple, cryogenic preconcentration procedure with subsequent,
direct, flame ionization detection. The method is sensitive and
provides accurate measurements of ambient NMOC concentrations
where speciated data are not required as applicable to the
EKMA.
Definitions
[Note: Definitions used in this document and in any user-prepared
Standard Operating Procedures (SOPs) should be consistent with ASTM
Methods D1356 and E355. All abbreviations and symbols are defined
within this document at point of use.]
-------
T012-5
5.1 Absolute pressure - Pressure measured with reference to absolute
zero pressure (as opposed to atmospheric pressure), usually ex-
pressed as pounds-force per square inch absolute (psla).
5.2 Cryogen - A substance used to obtain very low trap temperatures
in the NMOC analysis system. Typical cryogens are liquid argon
(bp -185.7) and liquid oxygen (bp-183.0).
5.3 Dynamic calibration - Calibration of an analytical system with
pollutant concentrations that are generated in a dynamic, flow-
ing system, such as by quantitative, flow-rate dilution of a
high concentration gas standard with zero gas.
5.4 EKMA - Empirical Kinetics Modeling Approach; an empirical model
that attempts to relate morning ambient concentrations of non-
methane organic compounds (NMOC) and NOX with subsequent peak,
downwind ambient ozone concentrations; used by pollution control
agencies to estimate the degree of hydrocarbon emission reduction
needed to achieve compliance with national ambient air quality
standards for ozone.
5.5 Gauge pressure - Pressure measured with reference to atmospheric
pressure (as opposed to absolute pressure). Zero gauge pressure
(0 psig) is equal to atmospheric pressure, or 14.7 psia (101 kPa).
5.6 in situ - In place; in situ measurements are obtained by direct,
on-the-spot analysis, as opposed to subsequent, remote analysis
of a collected sample.
5.7 Integrated sample - A sample obtained uniformly over a specified
time period and representative of the average levels of pollutants
during the time period.
5.8 NMOC - Nonmethane organic compounds; total organic compounds as
measured by a flame ionization detector, excluding methane.
5.9 ppmC - Concentration unit of parts per million carbon; for a spe-
cific compound, ppmC is equivalent to parts per million by volume
(ppmv) multiplied by the number of carbon atoms in the compound.
5.10 Sampling - The process of withdrawing or isolating a representative
portion of an ambient atmosphere, with or without the simultaneous
isolation of selected components for subsequent analysis.
-------
T012-6
6. Interferences
6.1 In field and laboratory evaluation, water was found to cause a
positive shift in the FID baseline. The effect of this shift
is minimized by carefully selecting the integration termination
point and adjusted baseline used for calculating the area of
the NMOC peak(s).
6.2 When using helium as a carrier gas, FID response is quite
uniform for most hydrocarbon compounds, but the response can
vary considerably for other types of organic compounds.
7. Apparatus
7.1 Direct Air Sampling (Figure 1)
7.1.1 Sample manifold or sample inlet li - to bring
sample air into the analytical system.
7.1.2 Vacuum pump or blower - to draw sample air through a
sample manifold or long inlet line to reduce inlet
residence time. Maximum residence time should be no
greater than 1 minute.
7.2 Remote Sample Collection in Pressurized Canisters (Figure 2)
7.2.1 Sample canister(s) - stainless steel, Summa»-polished
vessel(s) of 4-6 L capacity (Scientific Instrumentation
Specialists, Inc., °.0. Box 8941, Moscow, ID 83843), used
for automatic collection of 3-hour integrated field
air samples. Each canister should have a unique identi-
fication number stamped on its frame.
7.2.2 Sample pump - stainless steel, metal bellows type
(Model MB-151, Met Bellows Corp,., 1075 Providence
Highway, "haron, 02067) capable of 2 atmospheres
minimum output pre -jre. Pump must be free of leaks,
clean, and uncontamlnated by oil or organic compounds.
7.2.3 Pressure gauge - 0-30 psig (0-240 kPa).
7.2.4 Solenoid valve - special electrically-operated, bistable
solenoid valve (Skinner Magnelatch Valve, New Britain,
-------
T012-7
CT), to control sample flow to the canister with negligi-
ble temperature rise (Figure 3). The use of the Skinner
Magnelatch valve avoids any substantial temperature rise
that would occur with a conventional, normally closed
solenoid valve, which would have to be^ energized during
the entire sample period. This temperature rise in the
valve could cause outgasing of organics from the Viton
valve seat material. The Skinner Magnelatch valve
requires only a brief electrical pulse to open or close
at the appropriate start and stop times and therefore
experiences no temperature increase. The pulses may
be obtained with an electronic timer that can be pro-
grammed for short (5 to 60 seconds) ON periods or with
a conventional mechanical timer and a special pulse
circuit. Figure 3 [a] illustrates a simple electrical
pulse circuit for operating the Skinner Magnelatch
solenoid valve with a conventional mechanical timer.
However, with this simple circuit, the valve may
operate unpredictably during brief power interruptions
or if the timer is manually switched on and off too
fast. A better circuit incorporating a time-delay
relay to provide more reliable valve operation is
shown in Figure 3[b].
7.2.5 Stainless steel orifice (or short capillary) - capable
of maintaining a substantially constant flow over the
sampling period (see Figure 4).
7.2.6 Particulate matter filter - 2 micron stainless steel
sintered In-line type (see Figure 4).
7.2.7 Timer * used for unattended sample collection. Capable
of controlling pump(s) and solenoid valve.
7.3 Sample Canister Cleaning (Figure 5)
7.3.1 Vacuum pump - capable of evacuating sample canister(s)
to an absolute pressure of <5 mm Hg.
7.3.2 Manifold - stainless steel manifold with connections
for simultaneously cleaning several canisters.
7.3.3 Shut off valve(s) - seven required.
7.3.4 Vacuum gauge - capable of measuring vacuum in the manifold
to an absolute pressure of 5 mm Hg or less.
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T012-8
7.3.5 Cryogenic trap (2 required) - U-shaped open tubular trap
cooled with liquid nitrogen or argon used to prevent con-
tamination fr m back diffusion of oil from vacuum pump,
and to provide clean, zero air to samr°e canister(s).
7.3.6 Pressure gauge - 0-50 psig (0-345 kPa),-to monitor
zero air pressure.
7.3.7 Flow control valve - to regulate flow of zero air into
canister(s).
7.3.8 Humidifier - water bubbler or other system capable of
providing moisture to the zero air supply.
7.4 Analytical System (Figure 1)
7.4.1 FID detector system - including flow controls for the
FID fuel and air, temperature control for the FID, and
signal processing electronics. The FID burner air,
hydrogen, and helium carrier flow rates should be set
according to the manufacturer's instructions to obtain an
adequate FID response while maintaining as stable a flame
as possl* le throughout all phases of the analytical cycle.
7.4.2 Chart recorder - compatible wi~h the FID output signal,
to record FID response.
7.4.3 Electronic integrator - capable of integrating the area
of one .r more !D response peaks and calculating peak
area corrected ror baseline drift. If a separate inte-
grator and chart recorder are used, care must be exer-
cised to be sure that these components do not interfere
with each other electrically. Range selector controls
on both the integ ~or and t FID analyzer may not pro-
vide accurate range ratios, .~ individual calibration
curves should be prepared for each range to be used.
The integrator should be capaoie of marking the beginning
and ending of peaks, constructing the appropriate base-
line between the start and end of the integration period,
and calculating the peak area.
-------
T012-9
Note: The FID (7.4.1), chart recorder (7.4.2), inte-
grator (7.4.3), valve heater (7.4.5), and a trap heat-
ing system are conveniently provided by a standard lab-
oratory chromatograph and associated integrator. EPA
has adapted two such systems for the PDFID method: a
Hewlett-Packard model 5880 (Hewlett-Packard Corp., Avon-
dale, PA) and a Shimadzu model GC8APF (Shimadzu Scientific
Instruments Inc., Columbia, MD; see Reference 5). Other
similar systems may also be applicable.
7.4.4 Trap - the trap should be carefully constructed from a
single piece of chromatographic-grade stainless steel
tubing (0.32 cm O.D, 0.21 cm I.D.) as shown in Figure 6.
The central portion of the trap (7-10 cm) is packed with
60/80 mesh glass beads, with small glass wool (dimethyldi-
chlorosilane-treated) plugs to retain the beads. The
trap must fit conveniently into the Dewar flask (7.4.9),
and the arms must be of an appropriate length to allow
the beaded portion of the trap to be submerged below
the level of liquid cryogen in the Dewar. The trap should
connect directly to the six-port valve, if possible,
to minimize line length between the trap and the FID. The
trap must be mounted to allow the Dewar to be slipped
conveniently on and off the trap and also to facilitate
heating of the trap (see 7.4.13).
7.4.5 Six-port chromatographic valve - Seiscor Model VIII
(Seismograph Service Corp., Tulsa, OK), Valco Model 9110
(Valco Instruments Co., Houston, TX), or equivalent.
The six-port valve and as much of the interconnecting
tubing as practical should be located inside an oven or
otherwise heated to 80 - 90°C to minimize wall losses
or adsorption/desorption in the connecting tubing. All
lines should be as short as practical.
7.4.6 Multistage pressure regulators - standard two-stage,
stainless steel diaphram regulators with pressure gauges,
for helium, air, and hydrogen cylinders.
7.4.7 Pressure regulators - optional single stage, stainless
steel, with pressure gauge, if needed, to maintain
constant helium carrier and hydrogen flow rates.
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T012-10
7.4.8 Fine needle valve - to adjust sample flow rate through
trap.
7.4.9 Dewar flask - to hold liquid cryogen to cool the trap,
sized to contain submerged portion of^trap.
7.4.10 Absolute pressure gauge - 0-450 mm Hg,(2 mm Hg [scale
divisions indicating units]), to monitor repeatable
volumes of sample air through cryogenic trap (Wallace
and Tiernan, Model 61C-ID-0410, 25 Main Street, Belle-
ville, NO).
7.4.11 Vacuum reservoir - 1-2 L capacity, typically 1 L.
7.4.12 Gas purifiers - gas scrubbers containing Drierite* or
silica gel and 5A molecular sieve to remove moisture
and organic impurities in the helium, air, and hydrogen
gas flows (Alltech Associates,, Deerfield, IL). Note:
Check purity of gas purifiers prior to use by passing
zero-air through the unit and analyzing according -o
Section 11.4. Gas purifiers are clean if produce
[contain] less than 0.02 ppmC hydrocarbons.
7.4.13 Trap heating system - chromatographic oven, hot water,
or other means to heat the trap to 80° to 90°C. A simpl
heating source for the trap is a beaker or Dewar filled
with water maintained at 80-90°C. More r seatable types
of heat sources are recommended, including a temperature
programmed chromatograph oven, electrical heating of
the trap itself, or any type of heater that brings the
temperature of the trap up to 80-90°C in 1-2 minutes.
7.4.14 Toggle shut-off valves (2) - leak free, for vacuum valve
and sample valve.
7.4.15 Vacuum pump - general purpose laboratory pump capable
of evacuating the vacuum reservoir to an appropriate
vacuum that allows the desired sample volume to be
drawn through the trap.
7.4.16 Vent - to keep the trap at atmospheric pressure during
trapping when using pressurized canisters.
7.4.17 Rotameter - to verify vent flow.
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T012-11
7.4.18 Fine needle valve (optional) - to adjust flow rate of
sample from canister during analysis.
7.4.19 Chromatographic-grade stainless steel tubing (Alltech
Applied Science, 2051 Waukegan Road, Deerfield, IL, 60015,
(312) 948-8600) and stainless steel plumbing fittings -
for interconnections. All such materials in contact
with the sample, analyte, or support gases prior to
analysis should be stainless steel or other inert
metal. Do not use plastic or Teflon* tubing or fittings.
7.5 Commercially Available PDFID System (5)
7.5.1 A convenient and cost-effective modular PDFID system suit-
able for use with a conventional laboratory chromatograph
is commercially available (NuTech Corporation, Model 8548,
2806 Cheek Road, Durham, NC, 27704, (919) 682-0402).
7.5.2 This modular system contains almost all of the apparatus
Items needed to convert the chromatograph into a PDFID
analytical system and has been designed to be readily
available and easy to assemble.
8. Reagents and Materials
8.1 Gas cylinders of helium and hydrogen - ultrahigh purity grade.
8.2 Combustion air - cylinder containing less than 0.02 ppm hydro-
carbons, or equivalent air source.
8.3 Propane calibration standard - cylinder containing 1-100 ppm
(3-300 ppmC) propane in air. The cylinder assay should be
traceable to a National Bureau of Standards (NBS) Standard Refer-
ence Material (SRM) or to a NBS/EPA-approved Certified Reference
Material (CRM).
8.4 Zero air - cylinder containing less than 0.02 ppmC hydrocar-
bons. Zero air may be obtained from a cylinder of zero-grade
compressed air scrubbed with Drier!te» or silica gel and 5A
molecular sieve or activated charcoal, or by catalytic cleanup
-------
T012-12
of ambient air. All zero air should be passed through a liquid •
argon cold trap for final cleanup, then passed through a hyrdo-
carbon-free water bubbler (or other device) for humidification.
8.5 Liquid cryogen - liquid argon (bp -185.7°C) or. liquid oxygen,
(bp -183°C) may be used as the cryogen. Experiments have shown
no differences in trapping efficiency between liquid argon and
liquid oxygen. However, appropriate safety precautions must be
taken if liquid oxygen is used. Liquid nitrogen (bp -195°C)
should not be used because it causes condensation of oxygen and
methane in the trap.
9. Direct Sampling
9.1 For direct ambient air sampling, the cryogenic trapping system
draws the air sample directly from a pump-ventilated distribution
manifold or sample line (see Figure 1). The connecting line shoul
be of small diameter (1/8" 0.0.) stainless steel tubing and as
short as possible to minimize its dead volume.
9.2 Multiple analyses over the sampling period must be made to estab-
lish hourly or 3-hour NMOC concentration averages.
10. Sample lect .n v Pressurized Canister(s)
For inte^.-atea pressurized canister sampling, ambient air is sampled
by a metal bellows pump through a critical orifice (to maintain
constant flow), and pressurized into a clean, evacuated, Summa*-
polished sample canister. The critical orifice size is chosen so
that the canister is pressurized to approximately one atmosphere above
ambient pressure, at a constant flow rate over the desired sample
period. Two canisters are connected in parallel for duplicate samples
The canister(s are then returned to the laboratory for analysis,
using the PDFID analytical system. Collection of ambient air samples
in pressurized canisters provides the following advantages:
o Convenient integration of ambient samples over a specific
time period
o Capability of remote sampling with subsequent central
laboratory analysis
o Ability to ship and store samples, if necessary
-------
T012-13
o Unattended sample collection
o Analysis of samples from multiple sites with one analytical
system
o Collection of replicate samples for assessment of measurement
precision
With canister sampling, however, great care must be exercised in
selecting, cleaning, and handling the sample canister(s) and sampling
apparatus to avoid losses or contamination of the samples.
10.1 Canister Cleanup and Preparation
10.1.1 All canisters must be clean and free of any contaminants
before sample collection.
10.1.2 Leak test all canisters by pressurizing them to approxi-
mately 30 psig [200 kPa (gauge)] with zero air. The
use of the canister cleaning system (see Figure 5) may
be adequate for this task. Measure the final pressure -
close the canister valve, then check the pressure after
24 hours. If leak tight, the pressure should not vary
more than +_ 2 psig over the 24-hour period. Note leak
check result on sampling data sheet, Figure 7.
10.1.3 Assemble a canister cleaning system, as illustrated in
Figure 5. Add cryogen to both the vacuum pump and zero
air supply traps. Connect the canister(s) to the mani-
fold. Open the vent shut off valve and the canister
valve(s) to release any remaining pressure in the canis-
ter. Now close the vent shut off valve and open the
vacuum shut off valve. Start the vacuum pump and evacuate
the canister(s) to £ 5.0 mm Hg (for at least one hour).
[Note: On a daily basis or more often if necessary, blow-
out the cryogenic traps with zero air to remove any
trapped water from previous canister cleaning cycles.]
10.1.4 Close the vacuum and vacuum gauge shut off valves and
open the zero air shut off valve to pressurize the canis-
ter(s) with moist zero air to approximately 30 psig [200
kPa (gauge)]. If a zero gas generator system is used,
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T012-1'
the flow rate may nee be limited to maintain the
zero air quality.
10.1.5 Close the zero shut off valve and allow canister(s) to
vent down to atmospheric pressure through the vent shut
off valve. Close the vent shut off valve. Repeat steps
10.1.3 through 10.1.5 two additional times for a total of
three (3) evacuation/pressurization cycles for each set o
canisters.
10.1.6 As a "blank" check of the canister(s) and cleanup proce-
dure, analyze the final zero-air fill of 100% of the
canisters until the cleanup system and canisters are
proven reV :ble. Th check can then be reduced to a
lower perct-itage of canisters. Any canister that does
not test clean (compared to direct analysis of humidified
zero air of less than 0.02 ppmG) should not be utilized.
10.1.7 The canister is then re-evacuated to £5.0 mm Hg, using
the canister cleaning system, and remains in this con-
dition until use. Close the canister valve, remove the
canister from the canister cleaning system and cap
canister connection with a stainless steel fitting. The
canister is now ready for collection of an air sample.
Attach an identification t o the neck of each
canister for field notes ar .nain-of-custody purposes.
10.2 Collection of Integrated Whole-Air Samples
10.2.1 Assemble the sampling apparatus as shown in Figure 2.
The connecting lines between the sample pump and the
canister(s) should be as short as possible to minimize
their volume. A second canister is used when a duplicate
sample is desired for quality assurance (QA) purposes
(see Section 12.2.4). The small auxiliary vacuum pump
purges the inlet manifold or lines with a flow of
several L/min to minimize the sample residence time.
The larger metal bellows pump takes a small portion of
this sample to fill and pressurize the sample canister(s]
Both pumps should be shock-mounted to minimize vibration
Prior to field use, each sampling system should be leak
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T012-15
tested. The outlet side of the metal bellows pump can
be checked for leaks by attaching the 0-30 psig pressure
gauge to the canister(s) Inlet via connecting tubing and
pressurizing to 2 atmospheres or approximately 29.4 psig.
If pump and connecting lines are leak free pressure should
remain at +2 psig for 15 minutes. To check the inlet
side, plug the sample inlet and insure that there is no
flow at the outlet of the pump.
10.2.2 Calculate the flow rate needed so that the canister(s)
are pressurized to approximately one atmosphere above
ambient pressure (2 atmospheres absolute pressure)
over the desired sample period, utilizing the following
equation:
11)160)
where:
F * flow rate (cm^/min)
P « final canister pressure (atmospheres absolute)
s (Pg/Pa) + 1
V « volume of the canister (cm3)
N « number of canisters connected together for
simultaneous sample collection
T * sample period (hours)
Pg « gauge pressure in canister, psig (kPa)
Pa « standard atmospheric pressure, 14.7 psig (101 kPa)
For example, if one 6-L canister 1s to be filled to 2
atmospheres absolute pressure (14.7 psig) in 3 hours,
the flow rate would be calculated as follows:
F « 2 x 6000 x 1 « 67 cm3/min
3 x 60
10.2.3 Select a critical orifice or hypodermic needle suitable
to maintain a substantially constant flow at the cal-
culated flow rate into the canister(s) over the desired
sample period. A 30-gauge hypodermic needle, 2.5 cm
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T012-16
long, provides a flow of approximately 65 cm3/min with
the Metal Bellows Model MBV-151 pump (see Figure 4).
Such a needle will maintain approximately constant flow
up to a canister pressure of about IQ-psig (71 kPa),
after which the flow drops with increasing pressure.
At 14.7 psig (2 atmospheres absolute pressure), the
flow is about 10% below the original flow.
-10.2.4 Assemble the 2.0 micron stainless steel in-line particu-
late filter and position it in front of the critical
orifice. A suggested filter-hypodermic needle assembly
can be fabricated as illustrated in Figure 4.
10.2.5 Check the sampling system for contamination by filling
two evacuated, cleaned canister(s) (See Sect--n 10.1)
with humidified zero air through the sampli system.
Analyze the canisters according to Section A*.4. The
sampling system is free of contamination if the canister:
contain less than 0.02 ppmC hydrocarbons, similar to
that of humidified zero air.
10.2.6 During the system contamination check procedure, check
the critical orifice flow rate on the sampling system
to insure that sample flow rate remains relatively con-
stant (+10%) up to about 2 atmospheres abso'iute pressure
(101 kPa). Note: A drop in the flow rate may occur
near the end of the sampling period as the canister
pressure approaches two atmospheres.
10.2.7 Reassemble the sampling system. If the inlet sample lin<
is longer than 3 meters, install an auxiliary pump to
ventilate the sample line, as illustrated in Figure 2.
10.2.8 Verify that the timer, pump(sl and solenoid valve are
connected and operating properly.
10.2.9 Verify that the timer is correctly set for the desired
sample period, and that the solenoid valve is closed.
10.2.10 Connect a cleaned, evacuated canister(s) (Section 10.1)
to the non- itaminated sampling system, by way of the
solenoid valve, for sample collection.
-------
T012-17
10.2.11 Make sure the solenoid valve Is closed. Open the
canister valve(s). Temporarily connect a small rotameter
to the sample inlet to verify that there is no flow.
Note: Flow detection would indicate a leaking (or open)
solenoid valve. Remove the rotameter after leak de-
tection procedure.
10.2.12 Fill out the necessary information on the Field Data
Sheet (Figure 7).
10.2.13 Set the automatic timer to start and stop the pump
or pumps to open and close the solenoid valve at the
appropriate time for the intended sample period.
Sampling will begin at the pre-determined time.
10.2.14 After the sample period, close the canister valve(s) and
disconnect the canister(s) from the sampling system.
Connect a pressure gauge to the canister(s) and briefly
open and close the canister valve. Note the canister
pressure on the Field Data Sheet (see Figure 7). The
canister pressure should be approximately 2 atmospheres
absolute [1 atmosphere or 101 kPa (gauge)]. Note: If
the canister pressure is not approximately 2 atmospheres
absolute (14.7 psig), determine and correct the cause be-
fore next sample. Re-cap canister valve.
10.2.15 Fill out the identification tag on the sample canister(s)
and complete the Field Data Sheet as necessary. Note
any activities or special conditions in the area (rain,
smoke* etc.) that may affect the sample contents on the
sampling data sheet.
10.2.16 Return the canister(s) to the analytical system for
analysis.
11. Sample Analysis
11.1 Analytical System Leak Check
11.1.1 Before sample analysis, the analytical system is assemble
(see Figure 1) and leak checked.
-------
T012-18
11.1.2 To leak check the analytical system, place the six-port
gas valve in the trapping position. Disconnect and cap
the absolute pressure gauge. Insert a pressure gauge
capable of recording up to 60 psig at the vacuum valve
outlet.
11.1.3 Attach a valve and a zero air supply to the sample
inlet port. Pressurize the system to about 50 psig
(350 kPa) and close the valve.
11.1.4 Wait approximately 3 hrs. and re-check pressure. If
the pressure did not vary more than +_ 2 psig, the
system is considered leak tight.
11.1.5 If the system is leak free, de-pressurize and reconnect
absolute pressure gauge.
11.1.6 The analytical system leak check procedure needs to
be performed during the system checkout, during a serie
of analysis or if leaks are suspected. This should be
part of the user-prepared SOP manual (see Section 12.1}
11.2 Sample Volume Determination
11.2.1 The vacuum reservoir and absolute pressure gauge are
used to meter a precisely repeatable volume of sample
air through the cryogenically-co"1ed trao, as follows:
With the sample valve closed ana ie vacuum valve open
the reservoir is first evacuated with the vacuum pump
to a predetermined pressure (e.g., 100 mm Hg). Then
the vacuum valve is closed and the sample valve is
opened to allow sample air to be drawn through the
cryogenic trap and into the evacuated reservoir until
a second predetermined reservoir pressure is reached
(e.g., 300 mm Hg). The (fixed) volume of air thus
sampled is determined by the pressure rise in the
vacuum reservoir (difference between the predetermined
pressures) as measured by the absolute pressure gauge
(see Section 12.2.1).
-------
T012-19
11.2.2 The sample volume can be calculated by:
s (Ps)
where:
Vs = volume of air sampled (standard on3)
AP = pressure difference measured by gauge (mm Hg)
Vr = volume of vacuum reservoir (cm3)
usually 1 L
Ps = standard pressure (760 mm Hg)
For example, with a vacuum reservoir of 1000 cm3 and a
pressure change of 200 mm Hg (100 to 300 mm Hg), the volume
sampled would be 263 cm3. [Note: Typical sample volume
using this procedure is between 200-300 cm3.]
11.2.3 The sample volume determination need only be performed once
during the system check-out and shall be part of the
user-prepared SOP Manual (see Section 12.1).
11.3 Analytical System Dynamic Calibration
11.3.1 Before sample analysis, a complete dynamic calibration
of the analytical system should be carried out at five or
more concentrations on each range to define the calibra-
tion curve. This should be carried out initially and
periodically thereafter [may be done only once during
a series of analyses]. This should be part of the
user-prepared SOP Manual (See Section 12.1). The
calibration should be verified with two or three-point
calibration checks (including zero) each day the analyt-
ical system is used to analyze samples.
11.3.2 Concentration standards of propane are used to calibrate
the analytical system. Propane calibration standards
may be obtained directly from low concentration cylinder
standards or by dilution of high concentration cylinder
-------
T012-20
standards vrith zero air (see Section 8.3). Dilution
flow rates must be measured accurately, and the combined
gas stream must be mixed thoroughly for successful cali-
bration of the analyzer. Calibration standards should
be sampled directly from a vented manifold or tee. Note:
Remember that a propane NMOC concentration in ppmC is
three times the volumetric concentration in ppm.
11.3.3 Select one or more combinations of the following parameters
to provide the desired range cr ranges (e.g., 0-1.0 ppmC
or 0-5.0 ppmC): FID attenuator setting, output voltage
setting, integrator resolution (if applicable), and sample
volume. Each individual range should be calibrated sep-
arately and should have a separate calibration curve.
Note: Modern GC integrators may provide automatic ranging
such that several decades of concentration may be covered
in a single range. The user-prepared SOP manual should
address variations applicable to a specific system design
(see Section 12.1).
11.3.4 Analyze each calibration standard three times according
to the procedure in Section 11.4,. Insure that flow
rates, pressure gauge start id stop readings, initial
cryogen liquid level in the .awar, timing, heating, inte-
grator settings, and other enables are the same as
those that will be used dur analysis of ambient
samples. Typical flow rates jr the gases are: hydrogen,
30 cm-*/minute; helium carrier, 30 cm3/minute; burner
air, 400 cm^/minute.
11.3.5 Average the three analv«es for each concentration standard
and plot the calibrate curve(s) as average integrated pea
area reading versus concentration in ppmC. The relative
standard deviation for the three analyses should be less
-------
T012-21
than 3% (except for zero concentration). Linearity should
be expected; points that appear to deviate abnormally
should be repeated. Response has been shown to be linear
over a wide range (0-10,000 ppbC). If nonlinearity is
observed, an effort should be made to identify and correct
the problem. If the problem cannot be corrected, addi-
tional points in the nonlinear region may be needed to
define the calibration curve adequately.
11.4 Analysis Procedure
11.4.1 Insure the analytical system has been assembled properly,
leaked checked, and properly calibrated through a dynamic
standard calibration. Light the FID detector and allow to
stabilize.
11.4.2 Check and adjust the helium carrier pressure to provide the
correct carrier flow rate for the system. Helium is used
to purge residual air and methane from the trap at the
end of the sampling phase and to carry the re-volatilized
NMOC from the trap into the FID. A single-stage auxiliary
regulator between the cylinder and the analyzer may not
be necessary, but is recommended to regulate the helium
pressure better than the multistage cylinder regulator.
When an auxiliary regulator is used, the secondary stage
of the two-stage regulator must be set at a pressure
higher than the pressure setting of the single-stage
regulator. Also check the FID hydrogen and burner air
flow rates (see 11.3.4).
11.4.3 Close the sample valve and open the vacuum valve to
evacuate the vacuum reservoir to a specific predetermined
value (e.g., 100 mm Hg).
11.4.4 With the trap at room temperature, place the six-port
valve in the inject position.
11.4.5 Open the sample valve and adjust the sample flow rate
needle valve for an appropriate trap flow of 50-100
cm3/min. Note: The flow will be lower later, when the
trap is cold.
-------
T012-22
11.4.6 Check the sample canister pressure before attaching it
to the analytical system and record on Field Data
Sheet (see Figure 7). Connect the sample canister or
direct sample inlet to the six-port valve, as shown in
Figure 1. For a canister, either the canister valve
or an optional fine needle valve installed between the
canister and the vent is used to adjust the canister
flow rate to a value slightly higher than the trap
flow rate set by the sample flow rate needle valve.
The excess flow exhausts through the vent, which
assures that the sample air flowing through the trap
is at atmospheric pressure. The vent is connected to
a flow indicator such £ rotair, -;er as an indication of
vent flow to assist in adjusting the flow control
valve. Open the canister valve and adjust the canister
valve or the sample flow needle valve to obtain a
moderate vent flow as indicated by the rotameter. The
sample flow rate will be lower (and hence the vent
flow rate will be higher) when the the trap is cold.
11.4.7 Close the sample valve and open the vacuum valve (if
not already open) to evacuate the vacuum reservoir.
With the six-port valve in the inject position and the
vacuum valve open, open the sample valve for 2-3 minutes
[with both valves open, the pressure reading won't
change] to flush and condition the inlet lines.
11.4.8 Close the sample valve and evacuate the reservoir to
the predetermined sanr'e startinc pressure (typically
100 mm Hg) as indicated by the absolute pressure gauge.
11.4.9 Switch the six-port valve to the sample position.
11.4.10 Submerge the trap in the cryogen. Allow a few minutes
for the trap to cool completely (indicated when the
cryogen stops boiling). Add cryogen to the initial
level used during system dynamic calibration. The level
of the cryogenic liquid should remain constant with
respect to the trap and should completely cover the
beaded portion of the trap.
-------
T012-23
11.4.11 Open the sample valve and observe the increasing pressure
on the pressure gauge. When it reaches the specific pre-
determined pressure (typically 300 mm Hg) representative
of the desired sample volume (Section 11.2), close the
sample valve.
11.4.12 Add a little cryogen or elevate the Dewar to raise the
liquid level to a point slightly higher (3-15 mm) than
the initial level at the beginning of the trapping.
Note: This insures that organics do not bleed from the
trap and are counted as part of the NMOC peak(s).
11.4.13 Switch the 6-port valve to the inject position, keeping
the cryogenic liquid on the trap until the methane and
upset peaks have deminished (10-20 seconds). Now close
the canister valve to conserve the remaining sample in
the canister.
11.4.14 Start the integrator and remove the Dewar flask containing
the cryogenic liquid from the trap.
11.4.15 Close the GC oven door and allow the GC oven (or alter-
nate trap heating system) to heat the trap at a predeter-
mined rate (typically, 30°C/min) to 90°. Heating the trap
volatilizes the concentrated NMOC such that the FID pro-
duces integrated peaks. A uniform trap temperature rise
rate (above 0°C) helps to reduce variability and facili-
tates more accurate correction for the moisture-shifted
baseline. With a chromatograph oven to heat the trap,
the following parameters have been found to be acceptable:
initial temperature, 30°C; initial time, 0.20 minutes
(following start of the integrator); heat rate, 30°/minute;
final temperature, 90°C.
11.4.16 Use the same heating process and temperatures for both
calibration and sample analysis. Heating the trap too
quickly may cause an initial negative response that
could hamper accurate integration. Some initial exper-
imentation may be necessary to determine the optimal
heating procedure for each system. Once established,
the procedure should be consistent for each analysis
as outlined in the user-prepared SOP Manual.
-------
T012-24
11.4.17 Continue the integration (generally, in the range of
1-2 minutes is adequate) only long enough to include
all of the organic compound peaks and to establish the
end ooint FID baseline, as illustrated tn Figure 8.
The integrator should be capable of marking the begin-
ning and ending of peaks, constructing the appropriate
operational baseline between the start and end of the
integration period, and calculating the resulting
corrected peak area. This ability is necessary because
the moisture in the sample, which is also concentrated
in the trap, will cause a slight positive baseline
shift. This baseline shift starts as the trap warms
and continues until all of the moisture is swept from
the trap, at which time the baseline returns to its
normal level. The shift always continues longer than
;he ambient organic peak(s). The integrator should be
programmed to correct for this shifted baseline by
ending the integration at a point: after the last NMOC
peak and prior to the return of the shifted baseline to
normal (see Figure 8) so that the calculated operational
baseline effectively compensates for the water-shifted
baseline. Electronic integrators either do this auto-
matically or they should be programmed to make this cor-
rection. Alternatively, analyses of humidified zero air
prior to sample analyses should be performed to determine
the water envelope and the proper blank value for
correcting the ambient air concentration measurements
accordingly. Heating and flushing of the trap should
continue after the integration period has ended to
insure all water has been removed to prevent buildup of
water in the trap. Therefore, be sure that the 6-port
valve remains 1n the inject position unt*l all moisture
has purged from the trap (3 minutes or longer).
-------
T012-25
11.4.18 Use the dynamic calibration curve (see Section 11.3)
to convert the integrated peak area reading into
concentration units (ppmC). Note that the NMOC peak
shape may not be precisely reproducible due to vari-
ations in heating the trap, but the total NMOC peak
area should be reproducible.
11.4.19 Analyze each canister sample at least twice and report
the average NMOC concentration. Problems during an
analysis occasionally will cause erratic or incon-
sistent results. If the first two analyses do not
agree within +_ 5% relative standard deviation (RSD),
additional analyses should be made to identify in-
accurate measurements and produce a more accurate
average (see also Section 12.2.).
12. Performance Criteria and Quality Assurance
This section summarizes required quality assurance measures and pro-
vides guidance concerning performance criteria that should be achieved
within each laboratory.
12.1 Standard Operating Procedures (SOPs)
12.1.1 Users should generate SOPs describing and documenting
the following activities in their laboratory: (1)
assembly, calibration, leak check, and operation of the
specific sampling system and equipment used; (2) prepara-
tion, storage, shipment, and handling of samples; (3)
assembly, leak-check, calibration, and operation of the
analytical system, addressing the specific equipment used;
(4) canister storage and cleaning; and (5) all aspects of
of data recording and processing, including lists of
computer hardware and software used.
12.1.2 SOPs should provide specific stepwise instructions and
should be readily available to, and understood by, the
laboratory personnel conducting the work.
-------
T012-26
12.2 Method Sensitivity, Accuracy, Precision and Linearity
12.2.1 The sensitivity and precision of the method is proportional
to the sample volume. However, ice formation in the
trap may reduce or stop the sample flow "during trapping
if the sample volume exceeds 500 em3. Sample volumes
below about 100-150 cm3 may cause increased measurement
variability due to dead volume in lines and valves. r
most typical ambient NMOC concentrations, sample vol -S
in the range of 200-400 cm3 appear to be appropriate.
If a response peak obtain--i with a 400 cm3 sample is
off scale or exceeds the calibration range, a second
analysis can be carried out with a smaller volume. The
actual sample volume used need not be accuratelv known
if it is precisely repeatable during both calit .tion
and analysis. Similarly, the actual volume of the
vacuum reservoir need not oe accurately known. But the
reservoir volume should be matched to the pressure
range and resolution of the absolute pressure gauge so
that the measurement of the pressure change in the reser-
voir, hence the sample volume, is repeatable within 1%.
A 1000 cm3 vacuum reservoir and a pressure change of
200 mm Hg, measured with the specified pressure gauge,
have provided a sampling precision of +_ 1.31 cm3. A
smaller volume reservoir may be used with a greater
pressure change to accommodate absolute pressure gauges
with lower resolution, and vice versa.
12.2.2 Some FID detector systems associated with laboratory
chromatographs may have autoranging. Others may
provide attenuator control and internal full-scale
output voltage selectors. An appropriate combination
should be chosen so that an adequate output level for
accurate integration is obtained down to the detection
limit; however, the electrometer or Integrator must not
be driven into saturation at the upper end of the
calibration. Saturation of the ele *-ometer may be
indicated by flattening of the calibration curve at
-------
T012-27
high concentrations. Additional adjustments of range
and sensitivity can be provided by adjusting the sample
volume used, as discussed in Section 12.2.1.
12.2.3 System linearity has been documented (6) from 0 to 10,000
ppbC.
12.2.4 Some organic compounds contained in ambient air are
"sticky" and may require repeated analyses before they
fully appear in the FID output. Also, some adjustment
may have to be made in the Integrator off time setting
to accommodate compounds that reach the FID late in the
analysis cycle. Similarly, "sticky" compounds from
ambient samples or from contaminated propane standards
may temporarily contaminate the analytical system and
can affect subsequent analyses. Such temporary contam-
ination can usually be removed by repeated analyses of
humidified zero air.
12.2.5 Simultaneous collection of duplicate samples decreases
the possibility of lost measurement data from samples
lost due to leakage or contamination 1n either of the
canisters. Two (or more) canisters can be filled simul-
taneously by connecting them in parallel (see Figure 2(a))
and selecting an appropriate flow rate to accommodate
the number of canisters (Section 10.2.2). Duplicate (or
replicate) samples also allow assessment of measurement
precision based on the differences between duplicate samples
(or the standard deviations among replicate samples).
13. Method Modification
13.1 Sample Metering System
13.1.1 Although the vacuum reservoir and absolute pressure gauge
technique for metering the sample volume during analysis is
efficient and convenient, other techniques should work also.
13.1.2 A constant sample flow could be established with a vacuum
pump and a critical orifice, with the six-port valve being
switched to the sample position for a measured time period.
-------
T012-28
A gas volume meter, such as a wet test meter, could
also be used to measure the total volume of sample air
drawn through the trap. These a1*'"native techniques
should be tested and evaluated a: -art of. a user-prepared
SOP manual.
13.2 FID Detector System
13.2.1 A variety of FID detector systems should be adaptable to
the method.
13.2.2 The specific flow rates and necessary modifications for
the helium carrier for any alternative FID instrument
should be evaluated prior to use as part of the user-
prepared SOP manual.
13.3 Range
13.3.1 It may be possible to crease the sensitivity of the
method by increasing i..e sample volume. However,
limitations may arise such as plugging of the trap by ice.
13.3.2 Any attempt to increase sensitivity should be evaluated
as part of the user-prepared SOP manual.
13.4 Sub-Atmos-^eric P-»ssure Canister Sampling
13.4.1 Collection ..id analysis of canister air samples at sub-
atmospheric pressure is also possible with minor modifi-
cations to the sampling and analytical procedures.
13.4.2 Method TO-14, "Integrate Canister Sampling for Selective
Organics: Pressurized and Sub-atmospheric Collection
Mechanism," addresses sub-atmospheric pressure canister
sampling. Additional information can be found in the
literature (11-17).
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1. Uses, Limitations, and Technical Basis of Procedures for Quantifying
Relationships Between Photochemical Oxidants and Precursors.. ETA"-
450/2-77-21a, U.S. Environmental Protection Agency, Research Triangle
Park, NC, November 1977.
2. Guidance for Collection of Ambient Non-Methane Organic Compound
(NHOC) Data for Use in 1982 Ozone SIP Development, EPA-450/4-80-011.
U.S. Environmental Protection Agency, Research Triangle Park, NC,
June 1980.
3. H. B. Singh, Guidance for the Collection and Use of Ambient Hydrocarbons
Species Data in Development of Ozone Control Strategies, EPA-45Q/480-008.
U.S. Environmental Protection Agency, Research Triangle Park, NC,
April 1980.
4. R. M. Riggin, Technical Assistance Document for Sampling and Analysis
of Toxic Organic Compounds in Ambient Air. EPA-600/483-027, U.S.
Environmental Protection Agency, Research Triangle Park, NC, 1983.
5. M. J. Jackson, et^,al_., Technical Assistance Document for Assembly and
Operation of the Suggested Preconcentration Direct Flame lonization
Detection (PDFID) Analytical System, publication scheduled for late
1987; currently available in draft form from the Qualilty Assurance
Division, MD-77, U.S. Environmental Protection Agency, Research
Triangle Park, NC 27711.
6. R. K. M. Jayanty, et^^l_., Laboratory Evaluation of Non-Methane Organic
Carbon Determination in Ambient Air by Cryogenic Preconcentration and
Flame lonization Detection, EPA-600/54-82-019, U.S. Evirontnental Protec-
tion Agency, Research Triangle Park, NC, July 1982.
7. R. D. Cox, et_ al_., "Determination of Low Levels of Total Non-Methane
Hydrocarbon Content 1n Ambient Air", Environ. Sci. Technol., 1£ (1):57,
1982.
8. F. F. McElroy, £t£l_., A Cryogenic Preconcentration - Direct FID (PDFID)
Method for Measurement of NMOC in the Ambient Air. EPA-600/4-85-063,
U.S. Environmental Protection Agency, Research Triangle Park, NC,
August 1985.
9. F. W. Sexton, et_ jil_., A Comparative Evaluation of Seven Automated
Ambient Non-Methane Organic Compound Analyzers. EPA-600/54B2-046,
U.S. Environmental Protection Agency, Research Triangle Park, NC,
August 1982.
10. H. 6. Richter, Analysis of Organic Compound Data Gathered During 1980
in Northeast Corridor Cities. EPA-450/4-83-017, U.S. Environmental
Protection Agency, Research Triangle Park, NC, April 1983.
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11. Cox, R. D. "Sample Collection and Analytical Techniques for Volatile
Organic* in Air," presented at APCA Speciality Conference, Chicago, II,
March 22-24, 1983.
12. Rasmussen, R. A. and Khalil, rt.K. " Atr-ipher . .alocarbons:
Measurements and Analyses of -elected Trace Gase^,'1 Proc. NATO ASI on
Atmospheric Ozone, 1980, 209-231.
13. Oliver, K. D., Pleil J.D. and McClenny, W.A. "Sample Intergrity of
Trace Level Volatile Organic Compounds in Ambient Air Stored in
"SUMMA*" Polished Canisters," accepted for publication in Atmospheric
Environment as of January 1986. Draft available from W. A. McClenny,
MD-44, EMSL, EPA, Research Triangle Park, NC 27711.
14. McClenny, W. A. Pleil J.D. Holdren, J.W.; and Smith, R.N.; 1984.
" Automated Cryogenic Preconcentration and Gas Chromatographic
Determination of Volatile Organic Compounds," Anal. Chem. 56:2947.
15. Pleil, J. D. and Oliver, K. D., 1985, "Evaluation of Various Config-
urations of Nafion Dryers: Water Removal from Air Samples Prior to
Gas Chromatographic Analysis". EPA Contract No. 68-02-4035.
16. Oliver, K. D.; ~Tei1, and McClenny, W. A.; 1986. "Sample Integrity
of Trace Level .latile Organic Compounds in Ambient Air Stored in
Summa* Poll shea Canisters," Atmospheric Environ. 20:1403.
17. Oliver, K. D. Pleil. J. D., 1985, "Automated Cryogenic Sampling and
Gas Chromatographic Analysis of Ambient Vapor-Phase Organic Compounds:
Procedures and Comparison Tests," EPA Contract No. 68-02-4035,
Research Triangle Park, NC, Northrop Services, Inc. - Environmental
Sciences.
-------
T012-31
CANISTER
VALVE
CANSfTER
ABSOLUTE
PRESSURE GAUGE
ft} SAMPLE
VACUUM O . /
CANISTER i
SAMPLE jjj]
frj ROTAMETER
RA, Q> ^ ~~ '
V9 (OPTIONAL RNE
x-S. NEEDLE VALVE) FK
LVE ' ' I-LAS>K
^. + \ U-- GLASS
f A J^ BEADS
l^r
TRAP ^=^
^~~^^ CRYOGENIC
TRAP COOLER
(LIQUID ARGON)
PRESSURE
GAS REGULATOR
\S^ rn
> | [^ X^\
___ GAS
PURIFIER H2
INTEGRATOR PRESSURE
RECORDER ____ REGULATOR
1 _] fo**ff)
L~^ L^-£
AIR
FIGURE 1. SCHEMATIC OF ANALYTICAL SYSTEM FOR
NMOC—TWO SAMPLING MODES
-------
T012-32
SAMPLE
IN
CRITICAL
ORIFICE
AUXILIARY IN
VACUUM
PUMP
PRESSURE
GAUGE
MET, -
BELLOWS
PUMP
CANISTER(S)
FIGLfRE 2. SAMPLE SYSTEM FOR AUTOMATIC COLLECTION
OF 3-HOUR INTEGRATED AIR SAMPLES
-------
T012-33
R 100K
TIMER 1/V^^^.
SWITBH 1^]
115 VAC | R:
0— -t
d, 450 V [
f 100K
yvwv
-i i +1
A Czl1
.() 40Lild,450V
Y
RED r
TO
Di
BLACK
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DC DJ
WHITE
MAGNELATCH
SOLENOID
VALVE
COMPQNEVTS
Cwwcnor C\ and Cj - 40 ut 450 VDC (Sorogu* AMI* TVA in: or
i ind «j - OS
RED
/ 9 °2
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+
BRIDGE
RECTIFIER
AC
12.7K 2.7K / ^
R1 R» /*M.
ci f j RELAY
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1^
COMPQNEffTS 2P ^
Br«et f)K««f - 200 PRV. 1 J A (RCA. SK HOS or •QumMrtf) 400 Vo
0«XM D1 «na O: . 1000 PflV. 2J A (RCA, SK X61 or >qM»oloin| NOr
WMTTE
t
J-POLARI2!
MAGNELATCH
SOLENOID
VALVE
•D
Atom* TVAN US2 or
Rtlty - 10.000 Ohm coil. IS m* IAMF "oMr ond BrumMM. KCP I.
flmswr MI «na BZ • 0.4 wan. SH lOMrone*
FIGURE 3[b], IMPROVED CIRCUIT DESIGNED TO HANDLE POWER INTERRUPTIONS
FIGURE 3. ELECTRICAL PULSE CIRCUITS FOR DRIVING
SKINNER MAGNELATCH SOLENOID VALVE
WITH A MECHANICAL TIMER
-------
TO12-34
•P SERIES COMPACT. INLINE FILTER
W/2 urn SS SINTERED ELEMENT
FEMALE CONNECTOR, 0.25 in O.D. TUBE TO
0.25 in FEMALE NPT
HEX NIPPLE. 0.25 in MALE NPT BOTH ENDS
30 GAUGE x 1.0 in LONG HYPODERMIC
NEEDLE (ORIFICE)
F= MALE CONNECTOR. 0.25 in O.D. TUBE TO
O.JS in FEMALE NPT
THERMOGREEN LSI 6 mm (0.25 in)
SEPTUM (LOW BLEED)
0.25 in PORT CONNECTOR W/TWO 0.25 in NUTS
FIGURE 4. FILTER AND HYPODERMIC NEEDLE
ASSEMBLY FOR SAMPLE INLET FLOW
CONTROL
-------
T012-35
3-PORT
GAS
VALVE
ZERO AIR
SUPPLY
V
VENT VALVE
CHECK VALVE
CRYOGENIC
TRAP
VACUUM VACUUM PUMP
PUMP SHUT OFF VALVE VENT VALVE
ZERO AIR
SUPPLY
VENT SHUT OFF
VALVE
X
/
CRYOGENIC
TRAP
VENT SHUT OFF
VALVE
HUMIDIFIER
— PRESSURE
GAUGE
VACUUM SHUT OFF
VALVE
VENT
&
ZERO SHUT OFF
VALVE
VACUUM
GAUGE
VACUUM GAUGE
SHUT OFF VALVE
FLOW
I CONTROL
tVALVE
VENT SHUT OFF
VALVE
MANIFOLD
A A
CANISTER VALVE
SAMPLE CANISTERS
FIGURE 5. CANISTER CLEANING SYSTEM
-------
T012-36
TUBE LENGTH: -30 cm
O.D.: 0.32 cm
I.D.: 021 cm
CRYOGENIC LIQUID LEVEL
60/80 MESH GLASS BEADS
(TO FIT DEWAR)
FIGURE 6. CRYOGENIC SAMPLE TRAP DIMENSIONS
-------
T012-37
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-------
T012-38
NMOC
PEAK
Ill
CO
1
(0
cc
o
END
INTEGRATION
CONTINUED HEATING
OF TRAP
WATER-SHIFTED
BASELINE
OPERATIONAL BASELINE
CONSTRUCTED BY INTEGRATOR
TO DETERMINE CORRECTED AREA
NORMAL BASELINE
TIME (MINUTES)
FIGURE 8. CONSTRUCTION OF OPERATIONAL BASELINE
AND CORRESPONDING CORRECTION OF
PEAK AREA
-------
APPENDIX C
1989 NMOC MONITORING PROGRAM SITE DATA
-------
APPENDIX C -- LIST OF FIGURES
Figure Page
C-l Plot of NMOC concentration for Alpine, CA C-l
C-2 Plot of NMOC concentration for Bakersfield, CA C-4
C-3 Plot of NMOC concentration for Beaumont, TX C-7
C-4 Plot of NMOC concentration for Chicago, IL (Sears Tower) . . . C-10
C-5 Plot of NMOC concentration for Chicago, IL (CTA) C-13
C-6 Plot of NMOC concentration for Dallas, TX C-16
C-7 Plot of NMOC concentration for El Cajon, CA C-19
C-8 Plot of NMOC concentration for El Paso, TX C-22
C-9 Plot of NMOC concentration for Fremont, CA C-25
C-10 Plot of NMOC concentration for Grand Rapids, MI C-28
C-ll Plot of NMOC concentration for Houston, TX C-31
C-12 Plot of NMOC concentration for Long Beach, CA C-34
C-13 Plot of NMOC concentration for Lexington, KY C-37
C-14 Plot of NMOC concentration for New York, NY (P.S. 59) C-40
C-15 Plot of NMOC concentration for Montgomery, AL C-43
C-16 Plet of NMOC concentration for New York, NY (Mabel Dean) . . . C-46
C-17 Plot of NMOC concentration for Newark, NO C-49
C-18 Plot of NMOC concentration for Plainfield, NJ C-52
C-19 Plot of NMOC concentration for Raleigh, NC C-55
C-20 Plot of NMOC concentration for Reseda, CA C-58
C-21 Plot of NMOC concentration for St. Louis, MO C-61
C-22 Plot of NMOC concentration for Sacramento, CA (T St) C-64
C-23 Plot of NMOC concentration for Sacramento, CA (Avalon Dr) . . . C-67
cah.!74f
-------
APPENDIX C -- LIST OF TABLES
Table
C-l
C-2
C-3
C-4
C-5
C-6
C-7
Page
SUMMARY
SUMMARY
SUMMARY
SUMMARY
SUMMARY
SUMMARY
SUMMARY
C-8 SUMMARY
C-9 SUMMARY
C-10 SUMMARY
C-ll SUMMARY
C-l2 SUMMARY
C-13 SUMMARY
C-14 SUMMARY
C-15 SUMMARY
C-l6 SUMMARY
C-l7 SUMMARY
C-18 SUMMARY
C-l9 SUMMARY
C-20 SUMMARY
C-21 SUMMARY
C-22 SUMMARY
C-23 SUMMARY
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
OF THE 1989 NMOC DATA
FOR ALPINE, CA (ALCA) C-2
FOR BAKERSFIELD, CA (BACA) ... C-5
FOR BEAUMONT, TX (BMTX) C-8
FOR CHICAGO, IL (C3IL.) C-ll
FOR CHICAGO, IL (C6IL) C-14
FOR DALLAS, TX (DLTX) C-17
FOR EL CAJON, CA (ELCA) C-°0
FOR EL PASO, TX (ELTX) 23
FOR.FREMONT, CA (FECA) C-26
FOR GRAND RAPIDS, MI (GRMI) . . . C-29
FOR HOUSTON, TX (H1TX) C-32
FOR LONG BEACH, CA (LiBCA) .... C-35
FOR LEXINGTON, KY (LXKY) .... 8
FOR NEW YORK, NY (M1NY) C-41
FOR MONTGOMERY, AL (MGAL) .... C-44
FOR NEW
-------
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- s.
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8
id
8
8
CO
8
8
O
.0
U-«
CO
O
O
O
O
O
6
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c-i
-------
TABLE C-1. SUMMARY OF THE 1989 NMOC DATA FOR ALPINE, CA (ALCA)
Sampling Period: 9:00 a.m. to Noon
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
H-Jun-89
15-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
30-Jun-89
03-Jul-89
05-Jut-89
07-Jul-89
10-Jul-89
11-JUI-89
12-Jul-89
13-JUI-89
H-Jul-89
17-Jul-89
18-JUI-89
19-Jul-89
20-Jul-89
20-Jul-89
21-Jul-89
24- Jut -89
25-Jul-89
26- Jut -89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
156
156
157
158
159
160
163
164
165
166
166
167
170
171
172
173
174
177
177
178
179
180
181
181
184
186
188
191
192
193
194
195
198
199
200
201
201
202
205
206
207
209
212
213
214
215
1016
1017
1033
1060
1091
1109
1133
1181
1183
1231
1232
1240
1270
1273
1301
1359
1365
1385
1386
1400
1426
1453
1478
1479
1516
1510
1594
1609
1628
1681
1701
1725
1742
1784
1807
1817
1818
1861
1884
1906
1927
1984
1994
2024
2059
2086
98
72
825
672
97
899
645
407
87
406
707
726
75
39
718
899
155
53
850
640
672
914
36
501
136
765
921
773
307
775
770
13
833
626
804
123
153
924
84
713
406
698
857
27
109
640
15.9
15.9
15.0
16.0
14.5
15.0
16.0
15.0
15.0
16.5
16.5
16.0
14.2
15.0
15.5
15.0
15.0
17.0
17.0
11.0
15.5
15.5
16.0
16.0
15.0
15.0
14.0
14.0
14.0
14.5
15.0
14.0
15.0
14.5
14.5
16.5
16.5
10.5
14.0
16.0
15.0
15.5
15.0
15.0
16.5
16.0
15.0
16.0
14.0
16.0
14.0
14.0
15.0
14.0
14.0
13.5
13.5
12.0
10.0
14.0
15.0
14.0
14.0
16.0
16.0
12.0
15.0
15.0
15.0
15.0
13.0
14.0
12.0
12.0
15.0
12.0
14.0
14.0
14.0
14.0
20.0
16.0
16.0
10.0
15.0
14.0
15.0
16.0
15.0
14.0
16.0
16.0
B
C
B
B
B
D
A
D
D
A
A
A
C
D
B
C
D
B
C
D
C
A
A
A
B
C
C
B
D
A
B
A
A
A
A
8
C
D
D
D
C
0
D
A
C
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.069
0.065
0.101
0.101
0.080
0.163 0.203
0.093
0.155
0.112
0.196
0.195
0.201
0.414
0.115
0.087
0.203
0.097
0.046
0.066
0.109
0.163
0.115
0.101
0.079
0.209
0.242
0.180
0.121
0.117 0.160
0.262
0.110
0.081
0.155
0.156
0.269
0.771
0.862
0.281
0.122
0.162
0.172
0.115
0.123
0.093
0.390
0.171
C-2
-------
TABLE C-1. SUMMARY OF THE 1989 NMOC DATA FOR ALPINE, CA (ALCA)
Sampling Period: 9:00 a.m. to Noon
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
04-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
H-Aug-89
15-Aug-89
15-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
28-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07- Sep-89
08-Sep-89
1 Sep-89
12-Sep-89
13- Sep-89
14- Sep-89
19- Sep-89
20-Sep-89
21 -Sep-89
22-Sep-89
25 -Sep-89
25 -Sep-89
26-Sep-89
27-Sep-89
28- Sep-89
29-Sep-89
29- Sep-89
216
219
220
221
221
222
223
226
227
227
229
230
233
234
234
235
236
237
240
240
242
243
244
248
249
250
251
254
255
256
257
262
263
264
265
268
268
269
270
271
276
276
2112
2124
2155
2178
2177
2200
2232
2260
2309
2279
2344
2341
2391
2418
2417
2440
2452
2487
2563
2526
2538
2591
2627
2635
2654
2730
2728
2743
2773
2795
2807
2903
2898
2944
2974
2984
2983
3019
3028
3075
3098
3097
825
669
878
304
677
148
786
618
11
837
774
661
815
38
146
675
671
104
97
793
916
126
89
11
43
718
84
71
801
16
31
22
50
801
25
62
652
767
52
639
697
872
15.0
16.0
15.0
16.0
16.0
9.0
16.0
10.0
14.5
15.0
15.5
15.5
15.0
15.0
15.0
14.5
15.0
14.0
14.5
15.5
14.5
14.5
14.5
14.5
15.0
15.5
13.0
15.0
15.0
14.0
14.5
14.0
14.5
15.0
14.0
15.0
15.0
15.0
14.0
15.3
15.5
15.5
14.0
15.0
14.0
15.0
16.0
9.0
16.0
10.0
14.0
14.0
14.0
14.0
14.5
14.0
14.0
14.0
15.0
14.0
14.0
15.0
14.0
12.0
14.0
14.0
14.0
15.0
14.0
14.0
14.0
13.0
14.0
14.0
14.0
14.0
14.0
14.0
15.0
14.0
14.0
15.0
16.0
16.0
C
D
A
A
A
D
D
C
A
A
A
C
D
D
D
D
D
B
C
C
D
A
D
B
B
B
C
B
D
C
B
A
B
C
B
B
A
C
A
D
D
B
Mean OAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.096
0.152
0.104 0.128
0.155
0.158
0.164
0.111
0.147
0.163
0.191
0.141
0.124
0.074
0.078
0.081
0.096
0.067
0.102
0.122
0.193
0.154
0.111
0.097
0.082
0.080
0.056
0.090
0.144
0.123
0.118
0.070
0.063
0.091
0.038
0.080
0.147
0.159
0.068
0.122
0.098
0.116
0.082
C-3
-------
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C-4
-------
TABLE C-2. SUMMARY OF THE 1989 NMOC DATA FOR BAKERSFIELD, CA (BACA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
16-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
06-Jul-89
07-Jul-89
07-Jul-89
10-JM-89
11-Jul-89
12-Jul-89
13-Jul-89
14-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
156
157
157
158
159
160
163
164
167
167
170
171
172
173
174
177
178
178
179
180
181
184
187
188
188
191
192
193
194
195
198
199
200
201
202
202
205
206
207
208
209
212
213
214
215
216
1013
1048
1047
1061
1095
1116
1157
1170
1242
1243
1267
1286
1321
1344
1368
1382
1407
1408
1436
1448
1493
1537
1564
1574
1536
1614
1643
1653
1691
1714
1739
1768
1787
1830
1851
1852
1868
1890
1923
1949
1979
1998
2020
2040
2075
2101
25
814
43
857
39
303
123
19
18
105
854
79
704
50
929
198
140
715
126
129
187
30
793
92
762
. 409
868
190
713
148
169
21
38
689
74
815
17
659
403
677
828
789
642
306
705
924
16.5
9.0
9.0
9.0
10.0
9.0
14.0
14.0
10.0
8.5
9.5
9.5
10.0
10.0
12.0
12.0
10.0
10.0
10.0
10.0
10.5
10.0
10.5
10.0
10.0
10.0
11.0
10.0
10.0
10.0
10.0
11.0
13.0
13.0
10.0
10.0
10.0
10.0
10.0
11.0
11.0
10.0
10.5
10.0
19.0
13.5
11.0
10.0
11.0
12.0
19.0
14.0
14.0
9.5
10.0
12.0
11.0
12.0
12.0
14.0
14.0
10.0
12.0
10.0
10.0
13.0
12.0
10.0
10.0
11.0
10.0
11.0
12.0
12.0
12.0
11.0
11.0
15.0
15.0
12.0
12.0
9.0
13.0
12.0
12.0
13.0
10.0
12.0
12.0
C
c
D
D
B
C
B
B
B
B
D
B
C
D
C
D
C
C
B
B
B
C
B
B
B
D
D
A
B
B
A
D
C
D
D
B
C
B
C
C
D
C
A
C
A
0
Mean
NMOC
ppmC
0.801
0.256
0.224
0.847
0.621
0.910
0.904
1.337
0.204
0.170
1.359
0.565
0.916
0.781
0.993
0.332
0.556
0.533
0.366
0.380
0.342
0.771
1.071
0.861
0.863
0.909
0.238
0.497
0.528
0.690
0.775
0.655
1.290
1.053
1.090
1.121
0.575
0.898
0.494
0.947
0.985
0.336
0.479
0.950
0.868
1.746
QAD AREAL
NMOC NMOC
ppmc ppmc
0.727
0.447
0.920
0.556
1.068
1.008
C-5
-------
TABLE C-2. SUMMARY OF THE 1989 NMOC DATA FOR BAKERSFIELD, CA (BACA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
10-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
2£ jg-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
11-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
14-Sep-89
15-Sep-89
18-Sep-89
20-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
29-Sep-89
219
220
221
222
222
227
228
229
230
233
234
235
236
237
240
24C
243
244
248
249
250
254
254
255
256
257
258
261
263
265
268
269
269
270
271
272
272
2133
2160
2183
2194
2195
2273
2305
2321
2357
2383
2407
2423
2463
2473
2568
2300
2585
2612
2633
2669
2687
2755
2754
2763
2791
2825
2833
2874
2919
2972
2992
3006
3005
3038
3058
3105
3106
66
17
118
84
37
635
634
53
400
691
15
808
720
770
109
9C
H~
672
681
842
839
46
51
705
850
309
665
669
21
691
131
659
673
623
63
665
123
13.0
10.0
10.0
13.5
13.5
13.0
11.0
10.0
10.0
12.0
10.0
11.0
11.5
11.0
8.0
7.5
10.0
10.0
10.0
14.0
14.0
10.5
10.0
10.0
10.0
10.5
9.5
10.0
10.0
15.5
15.5
9.0
9.0
13.5
13.5
14.0
11.0
11.0
16.0
16.5
12.0
13.0
12.0
12.0
14.0
12.0
13.0
13.0
13.0
15.0
16.0
10.0
9.0
12.0
12.0
13.0
16.0
16.0
12.0
11.0
11. -0
12.0
11.0
12.0
13.0
12.0
16.0
16.0
12.0
11.0
14.0
16.0
A
C
D
C
C
B
B
B
C
A
B
B
C
D
A
D
C
A
A
A
A
C
A
C
D
D
A
D
D
A
C
D
A
D
C
B
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
2.498
1.070
0.756
0.670
0.723
1.019
1.548
0.279
0.645 0.699
0.478
0.876
0.222
0.544
0.799
1.217
0.993
1.591
0.949
1.155
1.440
0.304
0.929
0.516
1.262
1.242
0.935
1.129
0.150
o.?-?
1. 1
0.. i
1.23-
1.222
0.697
0.763
0.624
0.572
C-6
-------
X
8
o>
eo
o
(0
.o
"3
Q)
O
I
O
O
JO
a.
CO
6
0)
C-7
-------
TABLE C-3. SUMMARY OF THE 1989 NMOC DATA FOR BEAUMONT, TX (BMTX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
12-Jul-89
12-Jul-89
13-Jul-89
K-Jul-89
17-Jul-89
18-JUI-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
156
157
158
159
159
160
163
164
165
166
167
170
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
193
193
194
195
198
199
200
201
202
205
206
207
207
208
209
212
213
214
215
1020
1036
1052
1084
1083
1074
1149
1173
1196
1228
1220
1277
1278
1291
1311
1323
1340
1396
1415
1431
1433
1463
1519
1535
1560
1575
1625
1674
1675
1686
1711
1746
1769
1793
1839
1838
1855
1899
1932
1931
1942
1953
1995
2045
2043
2072
642
718
765
192
722
872
145
306
797
642
114
60
689
765
624
794
112
181
407
685
93
148
928
50
21
842
404
852
6
878
853
726
638
131
630
45
823
43
115
669
148
501
671
96
53
166
16.0
16.0
16.0
23.0
23.0
15.0
15.0
17.0
17.0
18.0
17.0
22.0
22.0
17.0
17.0
17.0
16.0
16.0
16.0
17.0
16.0
17.0
17.0
16.0
17.0
17.0
17.0
23.0
23.0
16.0
16.0
17.0
17.0
19.0
16.0
16.0
16.0
24.0
24.0
17.0
16.0
17.0
16.0
16.0
16.0
16.0
16.0
16.0
22.0
22.0
15.0
15.0
16.0
17.0
15.0
14.0
24.0
24.0
17.0
16.0
16.0
16.0
16.0
16.0
17.0
15.0
16.0
18.0
14.0
14.0
14.0
15.0
21.0
22.0
14.0
16.0
17.0
17.0
16.0
18.0
16.0
16.0
16.0
24.0
24.0
15.0
16.0
17.0
16.0
15.0
17.0
D
A
C
D
C
C
C
B
B
D
D
A
B
C
A
B
C
C
D
D
A
A
C
D
D
C
D
C
C
C
C
B
C
D
D
A
C
D
D
D
A
C
A
D
C
A
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.529
0.909
0.348
0.332
0.307
0.355 0.369
0.451
0.515
1.015
0.427
1.592
0.406
0.454
0.776
0.647
0.546
0.754
0.252
0.529
0.219
0.872
0.310
0.440
1.669
0.571
0.926
0.743
1.648
1.758
0.703
0.392 0.467
0.363
0.513
0.614
3.443 3.319
0.952
1.096
0.608
0.348
0.341
0.341 0.400
0.948
0.423
0.254 0.298 0.313
0.232
0.503
C-8
-------
TABLE C-3. SUMMARY OF THE 1989 NMOC DATA FOR BEAUMONT, TX (BMTX)
Sampling Period: 6:00 a.m. to 9:00 a
.m.
Julian Sample Sample Sai, .. Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
04-Aug-89
04-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
U-Aug-89
15-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
25-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
29-Sep-89
29-Sep-89
216
216
219
220
221
222
223
226
22"
227
228
229
230
233
234
235
237
237
240
241
242
243
244
248
249
250
251
251
254
255
256
257
258
261
262
262
263
264
265
268
269
270
272
272
2090
2089
2103
2162
2187
2220
2204
2249
2281
2280
2266
2325
2333
2375
2396
2434
2485
2484
2566
2512
2543
2592
2613
263-
265J
2684
2690
2691
2753
2746
2768
2805
2847
2861
2886
2885
2918
2923
2958
2989
3015
3030
3108
3065
151
162
685
622
765
189
86
20
32
142
156
145
656
620
17
25
99
897
188
894
680
686
825
100
165
649
176
192
929
774
77
99
6
814
644
108
679
90
166
705
689
678
786
804
22.0
22.0
17.0
18.0
17.0
16.0
16.0
16.0
21.0
21.0
15.0
16.0
17.0
16.0
15.0
22.0
22.0
17.0
16.0
18.0
18.0
16.0
17.0
16.0
18.0
23.0
23.0
17.0
18.0
16.0
16.0
17.0
18.0
22.0
22.0
18.0
17.0
17.0
18.0
18.0
18.0
24.0
24.0
22.0
22.0
16.0
16.0
17.0
16.0
16.0
16.0
21.0
21.0
14.0
16.0
16.0
16.0
16.0
15.0
22.0
22.0
17.0
16.0
17.0
17.0
16.0
16.0
16.0
18.0
23.0
23.0
17.0
17.0
16.0
16.0
16.0
16.5
20.0
22.0
18.0
16.0
16.0
18.0
18.0
18.0
24.0
24.0
C
c
C
B
C
B
B
B
B
B
C
A
D
B
C
D
C
A
D
B
A
D
B
B
D
D
A
B
D
D
C
C
A
C
D
C
A
D
A
B
A
A
B
A
Mean QAD
NMOC NMOC
ppmC ppmc
0.965
0.966
0.663
0.586
0.902
0.569
0.454
0.730
0.863
0.831
0.681 0.755
0.752
1.093
1.162
0.809
1.275
1.443 1.410
1.349
1.157
0.708
3.134
0.930
0.980
0.802
0.484
0.621
1.223
1.179
0.910
0.566 0.590
0.820
0.282
0.318
0.545
0.425
0.556
0.537
0.556
4.047
0.608
0.519
1.657
1.355
1.322
AREAL
NMOC
ppmc
0.793
1.018
0.916
0.589
0.676
0.848
0.371
C-9
-------
CO
o
o
05
CO •
Q «
O
o
8
in
8
8
CO
8
O)
CO
o>
CO
o
0)
CO
.o
6
.o
"5
o
o
o
o
O
O
o
•5
CD
8 a
S LL
C-10
-------
TABLE C-4. SUMMARY OF THE 1989 NMOC DATA FOR CHICAGO, IL (C3IL)
Sampling Period: 6:00 a.m. to 9:00 a.m. Sampling Location: 90th Floor, Sears Tower
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
05-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
05-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
U-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
26-Jul-89
26- Jut -89
27-Jul-89
28-Jul-89
31-JUI-89
01-Aug-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
156
156
158
159
160
163
164
165
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
186
188
W
l»2
193
194
195
198
199
200
201
202
205
207
207
208
209
212
213
213
214
215
216
1043
1044
1073
1094
1085
1136
1174
1194
1193
1216
1255
1252
1280
1326
1334
1332
1384
1402
1421
1476
1473
1496
1555
1554
1593
1601
1632
1699
1696
1754
1748
1804
1797
1816
1871
1870
1934
1933
1951
1964
2028
2018
2019
2046
2088
2123
115
171
679
91
17
883
8
649
685
307
928
814
676
17
13
813
627
147
176
675
783
897
165
661
837
621
20
105
673
766
675
96
825
774
661
775
71
720
925
622
666
45
658
36
783
630
17.0
17.0
12.0
12.0
12.0
12.0
12.0
19.0
19.0
12.0
12.0
12.0
12.0
11.0
11.8
12.0
12.0
11.0
11.0
12.0
12.0
12.0
18.0
18.0
11.0
12.0
10.0
11.0
12.0
13.0
12.0
11.0
11.0
12.0
12.0
12.0
18.0
18.0
12.0
12.0
12.0
20.0
20.0
11.0
12.0
13.0
16.0
16.0
11.0
11.0
10.0
10.0
10.0
18.0
18.0
8.0
8.0
8.0
10.0
9.0
9.0
10.0
10.0
10.0
9.0
10.0
12.0
8.0
16.0
16.0
10.0
8.0
8.0
8.0
8.0
10.0
10.0
10.0
10.0
12.0
11.0
11.0
16.0
17.0
11.0
11.0
11.0
17.0
17.0
10.0
11.0
12.5
B
C
D
A
D
D
A
A
C
C
B
D
C
C
C
C
A
C
D
C
D
C
C
A
B
C
B
B
C
C
C
D
C
A
C
C
D
D
B
D
C
B
B
D
B
D
Mean
NMOC
ppmC
0.493
0.504
0.454
0.448
0.369
0.214
0.343
0.171
0.199
0.296
0.676
0.268
0.142
0.140
0.363
0.460
0.354
0.359
0.393
0.076
0.265
0.104
0.058
0.070
0.175
0.312
0.332
0.271
0.200
0.147
0.417
0.224
0.217
0.103
0.084
0.248
0.350
0.348
0.294
0.098
0.225
0.138
0.142
0.352
0.291
0.953
QAD AREAL
NMOC NMOC
ppmc ppmc
0.390
0.357
0.254
0.133
C-ll
-------
TABLE C-4. SUMMARY OF THE 1989 NMOC DATA FOR CHICAGO, IL (C3IL)
Sampling Period: 6:00 a.m. to 9:00 a.m. Sampling Location: 90th Floor, Sears Tower
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
14-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01 • --'0-89
06-3ep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
.9-Sep-89
219
220
221
222
223
226
227
228
229
229
230
233
234
235
236
237
240
241
242
243
244
249
249
250
251
254
255
256
257
263
264
265
268
269
270
271
272
272
2120
2119
2174
2234
2223
2283
2277
2316
2338
2339
2416
2378
2400
2436
2446
2561
2558
2517
2536
2582
2605
2638
2663
2699
2722
2738
2774
2788
2828
2908
2935
2964
2981
3027
3044
3064
3048
3049
815
165
61
810
804
713
925
102
57
638
715
1
130
914
724
810
86
790
654
631
138
726
93
723
122
793
302
175
162
899
722
181
162
121
698
57
890
38
12.0
12.0
11.0
14.0
12.0
12.0
12.0
11.0
18.0
18.0
12.0
11.0
11.0
11.0
12.0
13.0
11.0
12.0
12.0
12.0
11.0
13.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
15.0
13.0
12.0
14.0
13.0
14.0
10.0
10.0
9.0
10.0
10.0
12.0
12.0
10.0
17.0
18.0
11.0
10.0
10.0
10.0
11.0
9.5
10.0
10.0
10.5
10.0
9.0
12.0
10.0
11.0
10.0
10.0
12.0
10.0
10.0
10.0
15.0
10.0
12.0
10.0
12.0
15.0
17.0
18.0
c
A
D
C
D
D
D
A
8
D
A
D
A
C
C
D
B
A
A
C
A
D
C
C
C
D
B
A
B
C
C
D
D
C
B
A
A
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC pr""- ppmc
0.330
0.187 244
0.232
0.764
0.211
0.242
0.252
0.304
0.141
0.150
0.080
0.542
0.233
0.093
0.075
0.160
0.159
0.274
0.244
0.182
0.154
0.574
0.160
0.221
0.260
0.561
0.114
0.045
0.042
0.130
0.720
0.198
0.239
0.141
0.078
0.409
0.190
0.209
C-12
-------
8
o>
o
a
c
<
o
o
O)
cd
.y
6
g
15
-------
TABLE C-5. SUMMARY OF THE 1989 NMOC DATA FOR CHICAGO, IL (C6IL)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
14-Jun-89
15-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
OS-Jul-89
06-Jul-89
06-JUI-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
14-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
21-Jul-89
24-Jul-89
26-Jul-89
27-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
OI-Aug-89
02-Aug-89
02-Aug-89
03-Aug-89
156
157
157
158
159
160
163
164
165
166
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
187
188
191
192
193
194
195
198
199
200
202
205
207
208
208
209
212
213
214
214
215
1026
1041
1042
1072
1093
1089
1135
1175
1180
1207
1208
1254
1253
1279
1327
1333
1331
1383
1401
1422
1477
1472
1495
1566
1587
1588
1592
1602
1633
1698
1697
1755
1749
1805
1796
1876
1869
1918
1963
1962
1965
2027
2037
2061
2060
2085
646
871
644
10
916
305
914
119
670
405
678
833
43
831
837
106
12
924
178
720
121
46
819
400
172
704
850
823
126
670
678
848
46
60
303
93
129
118
180
198
188
780
895
193
788
178
14.0
15.0
16.0
11.0
10.0
14.0
13.0
13.5
14.0
15.0
15.0
14.0
13.5
15.0
14.0
14.0
14.0
13.0
15.0
14.0
14.0
14.0
13.0
14.0
16.0
16.0
14.0
14.0
14.0
14.0
14.0
14.0
13.0
14.0
14.0
14.0
14.0
14.0
15.0
15.0
14.0
14.0
14.0
15.0
15.0
11.0
11.5
15.0
15.0
10.5
10.0
14.0
14.0
13.0
14.0
15.0
15.0
11.0
11.0
14.5
14.0
14.0
13.5
13.0
15.0
14.0
11.0
14.0
12.0
12.0
14.0
14.0
12.0
12.0
13.0
12.0
12.0
14.0
13.0
14.0
14.0
14.0
14.0
14.0
15.0
15.0
14.0
15.0
14.0
15.0
15.0
11.0
C
B
D
C
B
A
C
A
C
A
D
C
B .
B
D
A
A
A
D
C
D
C
D
C
A
B
*
D
A
D
D
D
B
A
A
D
C
C
B
D
B
A
C
C
B
B
Mean
NMOC
ppmC
1.290
0.542
0.553
0.729
1.741
0.546
0.221
1.046
0.531
0.270
0.362
0.499
1.378
0.764
0.460
1.030
0.790
1.178
2.147
1.013
0.473
0.658
0.449
0.880
1.155
1.157
0.791
0.294
1.175
1.356
1.573
0.728
0.973
0,676
0.713
0.226
0.686
0.958
0.473
0.485
0.532
0.326
0.836
1.494
1.319
0.617
QAD AREAL
NMOC NMOC
ppmc ppmc
1.048
0.537
0.719
\
0.365
014
-------
TABLE C-5. SUMMARY OF THE 1989 NMOC DATA FOR CHICAGO, U (C6IL)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
04-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
H-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
01-Sep-89
06-Sep-89
07-Sep-89
08-Sep- -9
11-Sep-89
12-Sep-89
K-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
2. 5ep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
29-Sep-89
216
219
220
221
222
223
226
227
228
229
230
233
234
235
236
237
240
241
242
243
244
244
249
250
251
254
255
257
261
262
263
264
265
268
269
270
271
272
272
2122
2121
2118
2173
2231
2224
2282
2276
2317
2331
2415
2389
2401
2437
2447
2560
2557
2518
2535
2581
2606
2661
2637
2695
272J
2739
2776
2818
2877
2902
2907
2926
2971
2982
3041
3043
3073
3071
3072
692
153
113
697
673
50
27
928
406
853
839
807
630
868
302
929
687
46
673
691
19
129
796
644
178
786
104
301
161
17
184
626
188
301
306
667
51
628
702
11.0
11.0
14.0
15.0
15.0
14.0
14.0
14.0
14.0
14.0
13.0
16.0
17.0
13.0
14.0
14.0
17.0
13.0
14.0
14.0
13.0
13.0
14.0
14.0
15.0
14.0
14.0
14.0
14.0
14.0
14.0
13.0
14.0
14.0
12.0
14.0
14.0
14.0
14.0
11.0
10.0
12.0
15.0
15.0
12.0
14.0
13.0
15.0
14.0
14.0
16.0
16.0
14.0
14.0
15.0
17.0
14.0
15.0
14.0
12.0
14.0
15.0
15.0
15.0
14.0
14.0
14.0
13.5
14.0
14.0
11.0
14.0
15.0
15.0
16.0
11.0
17.0
17.0
B
D
C
c
B
D
C
C
C
D
B
D
C
C
D
A
B
D
D
B
A
A
B
D
B
D
C
C
D
B
D
C
A
A
A
B
D
B
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.489
0.868
0.659 0.718
0.960
0.234
1.442
0.645
0.628
0.963
1.952
0.397
1.781
2.663
0.733
0.225 0.271
0.182
0.394
0.811
0.889
0.732
0.859
0.901
0.833
1.200
1.227
2.520
0.771
0.164
1.113
0.664
1.290
0.126
0.896
0.596
0.730
0.268
0.170
1.175
1.162
C-15
-------
X
co
CO
"03
Q
I
(0
o
£
8
8
8
CO
8
CM
8
CM
8
CM
O
CO
CM
CM
-8
8
0
8
o>
CO
=s
CO
Q
CO
0)
58 §
I o
18
O
E
O
o>
O)
LL
C-16
-------
TABLE C-6. SUMMARY OF THE 1989 NMOC DATA FOR DALLAS, TX (DLTX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
H-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-.lun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
12-Jul-89
13-Jul-89
U-Jut-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
21-Jul-89
24-Jul-89
25-JUI-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-AU9-89
02-AU9-89
156
157
158
159
160
160
163
164
165
166
167
170
171
171
172
173
174
177
178
179
180
181
184
186
187
188
191
192
193
193
194
195
198
199
200
201
202
202
205
206
207
208
209
212
213
214
1028
1062
1098
1117
1132
1131
1201
1190
1217
1234
1268
1294
1309
1310
1328
1367
1390
1428
1430
1467
1499
1521
1545
1556
1583
1620
1639
1670
1705
1704
1717
1738
1767
1789
1829
1854
1888
1887
1891
1920
1943
1987
1997
2036
2044
2065
56
620
924
193
93
900
618
768
668
157
56
162
30
622
143
724
679
669
33
623
137
162
4
899
659
100
22
788
686
894
42
723
39
72
808
920
3
126
98
635
91
181
156
786
104
823
15.0
16.0
16.0
15.0
15.0
15.0
16.0
17.0
17.0
15.0
15.0
17.0
17.0
17.0
16.0
17.0
16.0
17.0
16.0
18.0
15.0
16.0
16.0
16.0
18.0
15.0
15.0
>F.O
16.0
16.0
15.0
16.5
15.0
16.0
17.0
15.5
15.0
15.0
15.0
17.0
16.0
16.0
16.0
16.0
15.0
16.0
16.0
16.0
15.5
15.5
16.0
16.0
17.0
16.5
14.0
14.0
14.0
16.0
17.0
17.0
16.0
16.0
18.0
17.0
16.0
18.0
15.0
16.0
15.0
15.0
16.0
14.0
14.0
17.0
18.0
18.0
16.0
17.0
16.0
16.0
17.0
16.0
16.0
16.0
16.0
18.0
15.0
16.5
16.0
17.0
16.0
15.0
A
A
A
A
D
D
D
D
C
C
A
D
A
C
A
D
D
A
D
B
D
B
A
D
C
C
A
D
C
C
C
B
B
B
C
A
D
B
A
D
B
C
B
A
A
A
Mean OAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.734
0.967
0.477
0.302
0.760
0.802
0.222
0.178
0.605
0.423 0.450
1.611
1.486
0.673
0.672
0.541
0.179
0.361
0.488
0.271
0.375
0.292
0.271
0.514
0.522
0.876
0.651
0.252
0.244
0.190
0.215
0.494
0.366
0.301
0.158
0.266
0.394
0.668
0.316
0.446
0.549
0.390
0.296
0.426
0.411
0.421
0.151
C-17
-------
TABLE C-6. SUMMARY OF THE 1989 NMOC DATA FOR DALLAS, TX (DLTX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
03-Aug-89
03-Aug-89
04-Aug-89
07-AU9-89
08-Aug-89
09-Aug-89
10-Aug-89
H-Aug-89
H-Aug-89
15-Aug-89
1; jg-89
1 .g-89
18-«ug-89
21-Aug-89
22-Aug-d9
23-Aug-89
23-Aug-89
24- '-j-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
14-Sep-89
15-Sep-89
18-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
215
215
216
219
220
221
222
223
226
227
228
229
230
233
234
235
235
236
237
240
241
242
243
244
248
249
250
250
251
254
255
256
257
258
261
261
262
263
264
265
268
269
270
271
272
2116
2115
2137
2166
2186
2206
2238
2245
2268
2293
2335
2355
2385
2402
2424
2456
2455
2475
2493
2507
2548
2589
2622
2644
2656
2692
2711
2712
2745
2767
2787
2804
2830
2858
2889
2888
2917
2920
2965
2993
3016
3035
3070
3099
3116
670
704
656
628
197
42
71
644
140
652
788
658
77
870
864
702
789
185
684
192
72
77
114
792
189
838
97
184
L3
837
137
113
19
193
164
91
304
11
45
107
309
857
800
670
305
1/.0
17.0
16.0
16.0
16.0
16.5
17.0
18.0
16.0
17.0
17.5
17.0
16.0
'".0
.0
1o.5
16.5
16.0
16.0
16.0
16.0
15.0
16.0
17.0
15.0
15.0
15.0
15.0
15.0
16.0
15.0
15.0
16.0
17.0
16.0
16.0
17.0
16.0
16.0
16.0
16.0
17.0
17.0
17.5
16.0
17.5
18.0
17.0
17.0
16.0
17.0
16.0
18.0
16.0
17.0
17.0
17.0
16.0
16.0
16.0
18.0
18.0
14.0
17.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
17.0
17.0
14.0
16.0
16.0
16.0
16.0
16.0
16.1
16.4
17.0
16.0
16.0
16.0
16.0
16.0
18.0
18.0
16.0
D
B
C
D
C
C
B
B
C
D
C
B
C
C
A
A
A
D
B
C
A
B
D
A
A
D
A
A
C
A
A
B
B
D
C
C
B
C
C
D
D
D
C
D
D
Mean OAD AREAL
NMOC ~C K«—
ppmC IK pp c
0.116
0.114
0.141
.247
0.260
0.808
1.009
0.173
0.433
0.487
0.452
0.284
0.732
0.202
0.280
0.530 O.H5
0.515
0.523
0.420
0.577
0.675
0.427
0.307
0.227
0.518
0.378 0.443
0.369
1.356
.243 0.284
0.152
0.334
0.160
0.160
0.393
0.612
0.527
0.651
0.540
1.074
0.484
0.832
0.408
0.598
1.097
1.129
0.312
0.591
0.459
0.294
0.250
0.468
C-18
-------
o
CO
O
QJ
o
UJ
i
tO
o>
8
8
8
eo
8
oi
8
C-19
-------
TABLE C-7. SUMMARY OF THE 1989 NMOC DATA FOR EL CAJON, CA (ELCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
K-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
K-Jul-89
17-Jul-89
17-Jul-89
19-Jul-89
20-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-JUI-89
28-Jul-89
31-JUI-89
02-Aug-89
03-Aug-89
W-Aug-89
07-Aug-89
156
157
158
158
159
160
163
164
165
166
167
170
170
171
172
173
174
177
178
179
179
180
181
184
186
187
188
191
192
193
194
195
198
198
200
201
205
206
207
208
209
212
214
215
216
219
1011
1037
1066
1067
1092
1110
1134
1182
1184
1218
1241
1259
1258
1274
1302
1351
1366
1387
1399
1424
1423
1452
1486
1517
1511
" 1549
1595
1610
1627
1680
1700
1724
1751
1750
1806
1827
1877
1905
1928
1926
1983
1992
2058
2087
2111
2125
666
623
676
780
790
663
182
680
772
828
674
806
644
844
309
22
860
663
894
49
164
770
43
645
638
193
929
900
173
672
64
63
8
838
618
100
719
31
165
107
400
60
772
92
722
129
14.0
14.2
16.0
16.2
13.5
11.0
13.0
14.2
14.0
13.0
14.0
16.0
16.0
14.0
14.5
14.0
13.5
14.2
13.0
19.0
19.0
17.0
16.0
16.2
16.5
15.5
16.5
16.0
16.0
16.5
16.0
15.5
15.0
15.0
19.0
15.0
16.0
15.5
16.0
15.5
15.5
15.0
16.5
15.0
16.5
16.5
14.0
15.0
16.0
16.0
14.0
11.0
14.0
14.0
14.0
11.0
12.0
12.0
14.0
14.0
15.0
14.0
14.0
14.0
14.0
20.0
20.0
18.0
16.0
17.0
18.0
15.0
15.0
15.0
15.0
17.0
15.0
16.0
16.0
16.0
14.0
14.0
17.0
16.0
16.0
16.0
16.0
16.0
17.0
16.0
17.0
16.0
D
A
C
c
B
C
C
A
B
C
D
B
A
A
A
D
C
A
C
D
C
C
B
B
D
A
D
A
C
D
B
A
C
A
C
C
D
B
A
A
C
D
D
D
D
A
Mean
NMOC
ppmC
0.147
0.152
0.152
0.148
0.092
0.194
0.187
0.287
0.497
0.315
0.225
0.486
0.738
1.008
0.699
0.397
0.101
0.169
0.286
1.205
1.321
0.411
0.165
0.528
0.746
0.282
0.245
0.088
0.122
0.262
0.592
0.587
0.197
0.219
0.202
0.437
0.195
0.174
0.301
0.330
0.429
0.189
0.328
0.271
0.305
0.342
QAD AREAL
NMOC NMOC
ppmc ppmc
0.241
0.430
OJ1»
0.134
0.357
0.230
C-20
-------
TABLE C-7. SUMMARY OF THE 1989 NMOC DATA FOR EL CAJON, CA (ELCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
11-Aug-89
U-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-S°o-89
05-i -89
06-Sep-39
07-Sep-89
08-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
U-Sep-89
15-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
26-Sep-89
27-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
29-Sep-89
220
221
222
223
223
226
227
228
229
230
233
234
237
240
241
241
242
243
244
248
249
250
251
251
254
255
256
257
258
262
263
264
265
269
270
270
272
276
276
2154
2188
2201
2225
2226
2259
2278
2310
2345
2340
2390
2399
2486
2562
-315
2516
2537
2590
'628
36
>2
i.,-29
2710
2709
2742
2772
2796
2808
2849
2901
2897
2943
2975
3018
3025
3024
3074
3095
3096
770
864
1
18
674
856
719
176
654
680
916
624
123
831
14
784
711
75
161
38
63
642
831
894
153
916*
148
79
765
146
723
-'6
:4
642
676
925
618
765
823
16.5
15.0
15.5
15.0
15.0
15.0
16.5
16.0
16.0
16.0
16.0
17.0
15.0
16.0
15.0
15.0
15.5
15.0
14.0
21.0
15.5
15.0
15.0
15.8
15.5
15.5
16.0
16.5
15.5
17.0
16.5
15.5
16.5
16.0
16.0
16.5
15.0
15.0
16.0
16.0
16.0
1o.O
16.0
16.0
17.0
16.0
17.0
17.0
16.0
18.0
16.0
17.0
16.0
16.0
17.0
16.0
16.0
22.0
17.0
18.0
15.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
18.0
17.0
16.0
16.0
16.0
16.0
18.0
16.0
16.0
C
A
D
A
A
C
D
D
A
B
D
B
B
B
B
B
C
C
B
A
D
D
B
A
A
D
A
C
B
B
A
A
D
B
B
B
D
B
D
Mean OAD AREAL
NMOC NMOC NMOC
ppnC ppmc ppmc
0.147 0.164
0.166
0.274
0.370
0.376
0.285
0.263
0.185
0.203
0.196
0.128
0.567
C.115 0.41;
0.208
0.595
0.595
0.250
0.512
0.355
1.280
0.926
0.726
0.279
0.655
0.265
0.184
0.665
1.733
1.280
0.229
0.395
0.632
1.654
1.358
0.427
0.427
1.077
0.883
0.883
C-21
-------
X
CO
CO
QL
UJ
o
H—
§
13
o
g
o
o
O
O
.g
a.
CO
6
CD
o>
C-22
-------
TABLE C-8. SUMMARY OF THE 1989 NMOC DATA FOR EL PASO, TX (ELTX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
12-Jun-89
13-Jun-89
K-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
04-Jul-89
05-Jul-89
06-Jul-89
07-Jjfl-M
10-JOI-89
11-Jul-89
12-Jul-89
13-Jul-89
13-Jul-89
14-Jul-89
17-JUI-89
18-Jul-89
19-Jul-89
20- Jut -89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
156
157
158
159
160
163
163
164
165
166
167
170
171
172
172
173
174
177
178
179
180
181
184
185
186
187
188
191
192
193
194
194
195
198
199
200
201
201
202
205
206
207
208
209
212
213
1038
1030
1055
1080
1104
1146
1145
1155
1198
1238
1237
1269
1284
1304
1303
1347
1348
1388
1414
1427
1465
1489
1505
1533
1534
1538
1598
1618
1640
1659
1702
1703
1718
1747
1766
1786
1823
1824
1840
1867
1898
1897
1971
1982
1999
2032
60
114
131
789
181
112
197
705
501
770
662
675
864
774
895
1
96
900
768
189
105
662
112
634
184
68
309
7
777
197
304
796
75
161
780
162
409
772
20
875
113
806
776
42
804
686
11.0
11.0
10.0
11.0
9.5
14.0
14.0
11.0
10.0
10.5
10.0
10.0
11.0
14.5
14.5
11.0
11.0
11.0
12.0
11.0
11.0
11.0
11.0
12.0
11.0
13.0
11.0
11.0
12.0
11.0
14.5
14.5
11.0
8.0
12.0
11.0
15.0
15.0
11.0
12.0
8.0
12.0
9.0
13.0
12.0
12.0
9.0
9.0
8.0
10.0
8.0
13.0
13.0
9.0
10.0
6.0
6.0
7.0
10.0
13.0
13.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
10.0
9.0
10.0
13.0
10.0
8.0
10.0
11.0
14.0
14.0
10.0
10.0
10.5
9.5
14.0
15.0
10.0
10.0
10.0
13.0
12.0
11.0
10.5
11.0
A
A
D
B
C
A
A
B
C
C
D
C
A
C
B
D
C
D
D
D
C
D
D
C
D
A
A
C
A
D
C
D
C
0
C
D
B
C
C
D
C
C
B
D
A
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.331
0.579
0.165
0.826
0.209
0.125
0.126
0.551
0.310
0.355
0.293
0.655
0.661
0.389
0.416
0.176
0.324
0.453
0.141
0.262
0.440
0.309
0.242 0.360
0.434
0.339
0.134
1.247 1.306
0.549
0.488
0.227
0.340
0.348
1.266
0.144
0.195
0.283 0.345
0.230
0.292
0.436
0.248
0.194
2.442
0.396
1.683
0.303
0.271
C-23
-------
TABLE C-8. SUMMARY OF THE 1989 NMOC DATA FOR EL PASO, T)< (ELTX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
02-Aug-89
03-Aug-89
04-Aug-89
04-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
14-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
24-Aug-89
25-Aug-89
26-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
14-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
214
215
216
216
219
220
221
222
223
226
227
228
229
230
233
234
235
236
236
237
?40
241
242
243
244
248
248
249
250
251
254
255
256
257
258
261
262
263
263
264
265
268
269
270
271
276
2049
2042
2092
2091
2140
2148
2161
2216
2215
2251
2274
2294
2328
2353
2380
2386
2430
2445
2444
2476
2495
2511
2546
2602
2615
2643
2642
2652
2678
2685
2748
2762
2797
2826
2823
2859
2904
2939
2938
2921
2960
3001
3008
3034
3060
3092
135
108
303
626
180
803
801
780
169
309
123
665
899
12
164
711
150
162
148
309
674
652
640
137
661
695
914
772
108
171
711
75
138
685
631
697
15
84
684
929
680
900
668
178
837
108
11.0
12.0
14.0
14.0
12.0
12.0
13.0
12.5
11.0
12.0
12.0
12.0
12.0
12.0
11.5
12.5
11.5
14.5
14.5
12.0
12.5
12.5
12.0
11.5
12.0
15.0
15.0
12.5
11.5
12.0
12.0
11.0
12.0
12.5
12.5
12.0
11.0
15.0
15.0
12.0
12.0
12.0
12.0
13.0
12.0
12.0
10.0
11.0
13.0
13.0
10.0
11.0
10.0
11.0
10.0
10.0
10.0
10.0
10.0
10.5
10.0
12.0
10.0
12.5
13.0
10.0
12.0
10.5
10.5
10.0
10.0
13.0
13.0
14.0
10.0
10.0
10.0
10.0
10.0
11.0
11.0
10.0
10.0
13.0
13.0
10.0
11.0
10.0
11.0
12.0
11.0
10.0
c
D
C
C
D
D
D
C
A
D
C
C
D
A
D
C
C
B
A
D
C
C
C
C
D
D
C
C
D
B
B
D
C
B
A
D
A
D
D
0
C
A
D
C
A
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.308
0.612
0.092
0.106
0.295
0.186
0.365
0.918
0.201
0.191
0.661
0.339
0.869
0.568
0.105
0.375
0.775
0.358
0.357
0.601
0.601
0.333
0.387
0.578
0.458
0.464
0.403
0.555
0.395
0.763
1.029
0.433
0.204
0.148
0.937
0.687
0.770
0.531
0.538
0.669
0.184
1.430
0.331
0.585
1.950
1.359
C-24
-------
8
8
8
to
o>
CO
O>
<
O
o
-------
TABLE C-9. SUMMARY OF THE 1989 NMOC DATA FOR FREMONT, CA (FECA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
29-Jun-89
30-Jun-89
03-JUI-89
OS-Jul-89
06-JUI-89
07-Jul-89
10-Jul-89
11-JUI-89
12-Jul-89
13-Jul-89
U-Jul-89
17-Jul-89
18-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
156
157
158
159
160
160
163
164
165
166
167
170
172
173
174
177
178
179
180
180
181
184
186
187
188
191
192
193
194
195
198
199
199
200
201
202
205
206
207
208
209
209
212
213
214
215
1031
1035
1051
1122
1101
1100
1152
1172
1200
1223
1209
1293
1345
1329
1324
1374
1464
1461
1457
1456
1485
1518
1542
1540
1578
1615
1638
1657
1692
1719
1734
1781
1780
1795
1842
1834
1874
1894
1922
1946
1985
1986
1993
2035
2054
2074
30
50
897
838
74
89
68
13
852
137
31
857
784
146
305
848
63
809
118
18
831
833
674
925
38
153
37
657
631
25
637
674
914
10
104
819
687
102
854
171
157
305
660
839
618
719
22.5
18.0
18.0
18.0
16.0
16.0
20.0
18.0
18.0
18.0
18.0
20.0
18.0
17.0
17.0
20.0
18.0
19.0
16.0
16.0
20.0
20.0
20.0
18.0
17.5
*.o
17.5
19.0
18.5
17.0
20.5
16.0
16.0
17.5
17.5
17.5
21.0
17.5
17.5
17.5
13.0
16.0
21.0
18.0
19.0
18.5
24.0
18.0
18.0
18.0
17.0
17.0
22.0
20.0
19.0
16.0
19.5
22.0
16.0
17.5
15.0
19.0
19.0
20.0
16.0
17.0
21.0
22.0
20.0
18.0
16.0
20.0
15.0
19.0
18.0
19.0
22.0
18.0
18.0
18.0
18.0
18.0
22.0
18.0
19.0
19.0
14.0
17.0
21.0
19.0
20.0
20.0
B
D
D
A
D
D
C
B
B
B
A
A
A
A
D
A
D
C
D
C
B
C
D
B
A
C
C
B
D
A
A
D
A
A
B
A
B
B
A
B
A
B
C
0
A
D
Mean DAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.701
0.153
0.196 0.192
0.198
0.199
0.198
0.319
0.286
0.408
0.304
0.306 0.394
0.389
0.930
1.267
0.777
0.371 0.378
0.131
0.139
0.291
0.455
0.636
0.925
1.078
2.490 2.303
0.519
0.713
0.232
0.124
0.498
0.283
0.245 0.300
0.283
0.307
0.240
0.189
0.268
0.581
0.189
0.206
0.190
0.396
0.343
0.434 0.407
0.176
0.534
0.393
C-26
-------
TABLE C-9. SUMMARY OF THE 1989 NMOC DATA FOR FREMONT, CA (FECA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
04-Aug-89
07-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
ll-Aug-89
14-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-*jg-89
25-«ug-89
28-Aug-89
29-Aug-89
30-Aug-89
31 -Aug-89
0*-Sep-89
01-Sep-89
05-Sep-89
06-Sep-89
Or-Sep-89
08-Sep-89
13-Sep-89
H-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
19-Sep-89
20-Sep-B9
21-Sep-89
22-Sep-89
2S-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
28-Sep-89
29-Sep-89
216
219
219
220
221
222
223
226
228
229
230
233
234
235
236
237
240
241
242
243
244
244
248
249
250
251
256
257
258
261
262
262
263
264
265
268
269
270
271
271
272
2099
2129
21:3
2164
2179
2202
2229
2243
2299
2336
2359
2379
2406
2443
2465
2569
2529
2504
2550
2588
2617
2618
2623
2664
:689
2715
2800
2821
2841
2867
2883
2884
2922
2924
2973
2990
3031
3063
3113
3112
3117
68
403
775
776
150
894
157
707
45
409
14
628
64
662
722
122
707
667
804
660
22
627
146
768
96
674
c:40
27
885
409
176
697
790
61
773
86
631
660
677
677
897
17.0
18.0
18.0
18.0
17.5
17.5
17.5
21.0
17.0
18.0
17.5
20.5
17.5
18.0
18.5
17.0
20.5
18.0
.18.0
18.0
15.5
15.5
21.0
18.5
17.5
18.0
18.0
17.0
17.5
20.0
16.0
16.0
18.0
17.5
18.0
13.5
17.0
18.0
17.0
17.0
18.0
18.0
19.0
19.0
19.0
18.0
19.0
19.0
20.0
19.0
19.0
19.0
20.5
18.0
20.0
20.0
18. C
22.0
20.0
18.0
20.0
15.0
16.0
22.0
20.0
19.0
20.0
18.0
18.0
18.0
20.0
18.0
18.0
20.0
19.0
20.0
14.0
20.0
20.0
17.0
18.0
19.0
B
8
B
C
A
C
D
C
C
B
D
B
A
C
D
D
A
A
D
B
C
C
C
C
D
D
B
D
A
D
C
D
C
C
C
C
D
B
C
B
A
Mean
NMOC
ppmC
0.361
0.441
0.592
0.216
0.217
0.246
0.152
1.141
0.267
0.185
0.289
0.312
0.259
0.142
0.769
0.948
0.414
0.214
0.147
0.709
0.~27
0.672
0.776
1.217
1.920
0.601
1.001
1.011
0.462
0.329
0.769
0.707
0.164
1.158
1.376
1.224
0.502
0.783
0.364
0.330
0.537
QAD AREAL
NMOC NHOC
ppmc ppmc
0.447
1.112
0.273
0.659
C-27
-------
CO
.— E
Q. 2
CO c?
* H
"° i
2 1
o *
8
m
8
8
CO
8
CM
8
8
6
§
o>
CO
0.
cd
QC
cc
o
o
o
O
O
JD
a.
6
C-28
-------
TABLE C-10. SUMMARY OF THE 1989 NMOC DATA FOR GRAND RAPIDS, MI (GRMI)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
14-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
14-Jul-89
17-Jul-89
18-JUI-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
03-Aug-89
04-Aug-89
156
157
158
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
191
192
193
194
195
198
199
200
201
202
205
206
207
209
212
213
214
215
215
216
1015
1059
1068
1069
1081
1102
1141
1158
1202
1205
1215
1263
1285
1320
1330
1325
1392
1398
1435
1425
1462
1522
1544
1557
1582
t603
^504
1634
1658
1685
1720
1761
1776
1790
1825
1836
1881
1889
1915
1945
2000
2029
2053
2093
2094
2077
687
75
79
813
147
894
686
791
130
728
77
656
667
812
722
109
856
686
797
631
654
872
618
895
45 %
640
182
93
874
12
305
711
715
783
900
79
777
662
304
673
674
644
907
850
138
143
11.0
14.0
18.0
18.0
14.0
14.0
15.0
14.0
14.0
14.0
18.0
14.0
14.0
15.0
15.0
14.0
14.0
14.0
15.0
15.0
15.0
14.0
15.0
14.0
14.0
18.0.
18.0
14.0
14.0
14.0
14.0
15.0
15.0
15.0
14.0
14.0
15.0
15.0
14.0
14.0
15.0
15.0
14.0
20.0
20.5
14.0
10.0
13.0
18.0
18.0
14.0
13.0
14.0
14.0
13.0
14.0
16.0
12.0
14.0
13.0
15.0
13.0
14.0
14.0
15.0
15.0
15.0
14.0
15.0
13.0
12.0
17.0
18.0
14.0
14.0
12.0
14.0
15.0
14.0
15.0
14.0
14.0
15.0
14.5
14.0
15.0
15.0
14.0
14.0
21.0
22.0
14.0
D
A
C
C
B
D
B
A
D
C
0
C
D
A
B
A
D
B
A
D
D
D
D
B
D
B
C
C
D
C
C
B
B
C
A
D
C
C
A
A
A
A
D
B
D
A
Mean QAO AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.456
0.432
0.661
0.644
0.607
0.396
0.666
0.312 0.389
0.271
0.362
0.432
0.602
0.265
0.327
0.554
0.916
1.181
0.529 0.472
0.513
0.203
0.924
0.548
0.460
0.905
0.585
£,213
ft. 243
0.269
0.206
0.473
0.449
1.001
0.966
0.344
0.375
0.236
0.925 1.008 1.017
0.968 0.948
1.080 1.115
0.376
0.714
1.213
0.503
0.586
0.567
1.408 1.370
C-29
-------
TABLE C-10. SUMMARY OF THE 1989 NMOC DATA FOR GRAND RAPIDS, MI (GRMI)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
07-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
H-Aug-89
H-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
21-Aug-89
22-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-.9
01-Sep-89
05-Sep-0?
06- Se
07- Se .,
08-Sep-89
11-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
U-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
28-Sep-89
29-Sep-89
219
220
221
222
223
226
226
227
228
229
233
234
234
235
236-
237
240
241
242
243
244
248
249
250
251
254
254
255
256
257
258
261
262
263
264
265
268
269
270
271
271
272
2104
2163
2180
2214
2208
2257
2258
2272
2295
2337
2387
2398
2397
2429
2461
2468
2565
2506
;7
2598
2621
2634
2651
2679
2702
2707
2708
2777
2801
2819
2840
2873
2878
2905
2928
2967
2969
2997
3017
3046
3045
3061
929
91
175
64
75
728
797
705
179
198
625
118
129
172
644
140
783
786
775
656
90
150
41
848
3
659
784
107
62
819
98
683
842
41
838
834
883
6
126
806
797
169
15.0
14.0
15.0
14.0
14.0
17.5
17.5
14.0
12.0
12.0
14.0
18.0
18.0
14.5
14.5
14.5
16.0
15.5
16.0
15.8
14.0
14.5
14.5
14.5
14.2
20.0
20.0
14.5
15.0
15.0
15.0
16.0
15.0
14.5
15.0
14.5
14.5
14.5
16.0
21.0
21.0
15.0
15.0
14.0
14.0
13.0
14.0
19.0
19.0
14.0
13.0
12.0
14.0
17.0
18.0
14.0
15.0
14.0
15.0
14.0
14.0
14.0
13.0
14.0
14.0
14.0
14.0
19.0
19.0
15.0
14.0
15.0
14.0
14.0
14.0
14.0
14.0
14.0
15.0
14.0
14.0
19.0
20.0
15.0
C
A
C
C
D
A
D
A
C
A
D
D
D
B
D
D
A
D
D
D
A
A
D
C
D
A.
C
D
C
C
D
D
A
A
D
D
C
D
C
C
B
D
Mean QAD AF ,L
NMOC NMOC . .oC
ppmC ppmc ppmc
0.263
1.880
1.394
0.552
1.414
0.407
0.424
0.218
0.636
0.701
0.364
0.532
0.520
0.622
0.409
0.384
0.405
0.270
0.288
1.405
0.37C
0.31:
0.5E
0.40:
0.374
0.462
0.405
0.263
0.483
0.436
0.876
1.253
1.582
1.445
1.669
1.319
0.588
0.337
1.088
0.927
0.787
0.462
C-30
-------
X
O
fc
.g
"S
-------
TABLE C-11. SUMMARY OF THE 1989 NMOC DATA FOR HOUSTON, TX (H1TX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
13-Jun-89
14-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
1«-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
14-Jul-89
14-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
03-Aug-89
04-Aug-89
07-AU9-89
08-Aug-89
10-Aug-89
11-Aug-89
157
158
159
160
163
164
164
165
166
167
170
171
172
173
173
174
177
178
179
180
181
184
186
187
188
191
192
193
194
195
195
198
199
200
201
202
205
207
208
209
215
216
219
220
222
223
1025
1053
1103
1123
1151
1162
1161
1197
1222
1224
1260
1283
1317
1306
1305
1339
1389
1410
1429
1460
1501
1523
1539
1562
1580
1623
1635
1636
1693
1728
1729
1736
1771
1770
1841
1831
1880
1917
1954
1944
2076
2079
2105
2152
2213
2218
691
635
652
658
96
46
657
796
15
786
166
870
74
643
108
780
182
.927
874
697
25
825
883
161
667
104
807
669
86
114
650
501
691
7
658
705
628
784
150
14
72
112
172
688
161
90
11.5
12.0
13.0
13.0
12.0
19.0
19.0
13.0
12.0
13.0
12.0
12.0
12.0
19.0
19.0
13.0
12.0
12.0
12.0
13.0
13.0
12.0
12.0
12.0
13.0
If
13.0
13.0
12.0
19.0
19.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
19.0
12.0
12.0
10.0
13.0
13.0
13.0
12.0
18.0
18.0
13.0
10.0
11.0
10.0
12.0
12.0
18.0
20.0
13.0
12.0
12.0
12.0
13.0
13.0
12.0
10.0
12.0
11.0
12.0
13.0
13.0
12.0
19.0
20.0
12.0
14.0
12.0
14.0
13.0
14.0
14.0
12.0
12.0
13.0
11.0
13.0
20.0
13.0
13.0
D
C
A
D
B
B
A
D
D
C
D
C
D
B
B
D
A
A
B
D
C
D
D
A
B
A
D
D
A
C
D
D
A
C
D
A
C
A
C
8
C
A
0
D
B
C
Mean OAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.550 0.566
0.712
0.363
0.882
0.241
0.516 0.549
0.538
0.398
0.413
0.599
0.365
0.437
0.612
0.889
0.769
1.998
0.482
0.180
0.307
0.358
0.473
0.444
0.631
1.113
1.074
1.044
1.353
0.518
0.379
0.254
0.251
1.156
0.438
0.594
0.499
0.961
0.809
0.514
0.817
1.495
1.390
1.248
0.446
0.244
0.298
0.640
C-32
-------
TABLE C-11. SUMMARY Of THE 1989 NMOC DATA FOR HOUSTON, TX (H1TX)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID r-nister F assure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
U-Aug-89
K-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
07-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
12-Sep-89
U-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
226
226
228
229
230
233
234
235
236
237
237
240
241
242
243
244
248
250
250
251
254
255
255
257
258
261
262
263
264
264
265
268
269
270
270
271
272
2246
2270
2300
2323
2332
2370
2404
2428
2426
2469
2470
2564
2501
2549
2580
2594
2631
2646
2647
2700
2752
2769
2749
2799
2835
2856
2899
2913
2936
2937
2959
2999
3010
3023
3022
3037
3076
185
814
178
920
900
68
688
765
780
20
182
635
676
71
927
828
21
637
696
854
618
45
776
783
660
625
106
43
724
854
770
407
794
645
672
683
175
12.0
12.0
12.0
12.0
12.0
'.2.0
;3.o
12.0
12.0
19.0
19.0
12.0
12.0
12.0
12.0
12.0
20.0
20.0
12.0
12.0
12.0
12.0
12.0
12.0
12.0
11.0
19.0
19.0
12.0
12.0
12.0
19.0
19.0
12.0
12.0
12.0
12.0
12.5
12.0
12.5
13.0
14.0
14.0
13.0
19.0
19.0
13.0
13.0
12.0
12.0
12.0
12.0
20.0
20.0
12.0
14.0
11.0
12.0
12.0
12.0
12.0
12.0
12.0
20.0
20.0
13.0
13.0
12.0
18.0
19.0
13.0
12.0
D
D
C
C
D
D
C
A
D
A
C
C
A
C
B
B
C
A
C
D
B
D
C
D
A
D
B
B
A
A
B
B
A
B
B
C
C
Mean QAD AREAL
NMOC NMOC -Z
ppmC ppmc ppmc
1.093
0.873
1.449
1.193
1.643
1.880 1.973 1.792
0.873
0.655
0.497
1.811
1.807
1.084
0.834 0.869
0.401
0.470
0.933
1.024
1.303
1.357
2.614 2. -7
1.247
1.063
0.741
0.329
0.545
0.939
0.244
0.746
0.532
0.267
0.982
0.227
0.497
0.602
0.562
0.986
0.461
C-33
-------
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C-34
-------
TABLE C-12. SUMMARY OF THE 1989 NMOC DATA FOR LONG BEACH, CA (LBCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
13-Jun-89
13-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
20-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
13-Jul-89
U-Jul-89
17-Jul-89
19-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
28- Jut -89
31-Jul-89
02-Aug-89
03-Aug-89
04-Aug-89
07-Aug-89
09-Aug-89
H-Aug-89
U-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
18-Aug-89
156
158
159
160
164
164
165
166
167
171
171
172
173
174
178
179
180
181
186
187
188
191
194
195
198
200
200
201
202
205
207
208
209
209
212
214
215
216
219
221
223
226
228
229
230
230
1039
1057
1082
1106
1165
1163
1195
1226
1244
1276
1275
1318
1355
1346
1409
1432
1459
1488
1543
1565
1577
1619
1688
1712
1737
1801
1800
1833
1853
1875
1916
1950
1974
1973
1996
2052
2069
2095
2134
2182
2212
2252
2298
2330
2360
2361
776
92
107
155
54
839
61
118
129
107
762
171
10
84
907
99
64
197
630
166
138
920
90
839
171
106
306
183
166
11
874
70
189
928
25
689
123
868
680
668
89
696
666
28
860
828
6.0
14.0
16.0
16.0
9.0
19.0
12.0
12.0
13.0
17.0
19.0
13.0
13.5
13.5
17.5
13.0
16.3
15.0
22.0
12.0
12.0
12.7
12.4
13.0
12.5
13.0
13.0
11.7
11.5
15.0
15.0
13.5
17.0
17.0
13.0
12.5
11.5
11.7
12.0
12.0
14.0
13.0
12.5
11.5
13.0
13.0
5.0
14.0
16.0
10.0
9.0
18.0
12.0
14.0
10.0
17.0
19.0
12.0
10.0
13.0
17.0
13.0
16.0
14.0
20.0
12.0
12.0
14.0
12.0
14.0
16.0
16.0
16.0
13.0
12.0
15.0
15.0
14.0
16.5
16.5
16.0
14.0
13.0
14.0
14.0
13.0
14.0
16.0
15.0
11.0
14.0
16.0
C
B
A
B
B
A
D
B
D
C
A
D
A
C
A
A
C
D
C
D
B
A
A
D
C
B
B
A
D
D
B
C
B
A
C
A
D
D
C
D
A
A
C
B
C
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.797
0.606
0.746
2.253
0.700
0.697
1.112
0.932
0.875
1.786
1.732
0.639
0.851 0.921
0.377
0.785
0.391
1.101
0.443
1.538
0.527
0.587
0.472
0.982
0.789 0.841
0.394
0.597
0.336
0.625
1.001
0.475
0.508
0.564
0.570
0.589
0.340
0.775
0.401
0.630 0.684
0.564
0.701
0.877
0.694
0.427
0.313
0.394
0.475
C-35
-------
TABLE C-12. SUMMARY OF THE 1989 NMOC DATA FOR LONG BEACH, CA (LBCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psip Channel
21-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
28-Aug-89
31-Aug-89
01-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
13-Sep-89
U-Sep-89
15-Sep-89
18-Sep-89
20-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
02-Oct-89
233
235
236
237
240
240
243
244
249
250
251
254
256
257
258
261
263
263
264
265
268
270
271
272
275
2382
2432
2460
2494
2483
2482
2595
..r.3
_-i5
2703
2698
2753
2813
2820
2822
2868
2880
2879
'48
2966
2995
3042
3069
3101
3115
767
165
621
854
178
157
663
121
155
17
180
407
37
156
900
686
702
620
856
792
14
895
807
147
607
15.0
14.0
13.0
13.0
18.9
18.9
12.0
11.5
20.0
11.5
11.5
12.5
12.0
11.9
11.5
12.7
17.0
17.0
11.5
12.0
12.0
12.0
12.0
11.5
12.8
16.0
14.0
12.0
13.0
17.0
18.0
14.0
12.0
22.0
13.0
13.0
13.0
13.0
12.0
13.0
15.0
17.0
18.0
11.0
14.0
15.0
14.0
14.0
13.0
16.0
c
B
B
A
D
A
D
D
A
D
C
D
C
D
C
A
D
D
C
B
C
A
A
C
C
Mean QAD AREAL
NMOC NMC. NMb.
ppmC ppmc ppmc
0.670
0.479
0.242
0.397
0.747
0.741
0.464
0.846
2.860
0.903
0.718
0.554
0.778
1.541
2.181
0.514
1.961
1.945
2.557
1.645
1.970
0.579
1.240
1.373
0.661
C-36
-------
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C-37
-------
TABLE C-13. SUMMARY OF THE 1989 NMOC DATA FOR LEXINGTON, ICY (LXKY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
12-Jun-89
13-Jun-89
14-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06- Jut -89
07- Jut -89
07-Jul-89
AO-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
H-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
156
157
158
159
160
163
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
208
209
212
213
214
215
1012
1075
1099
1156
1153
1144
1143
1167
1199
1210
1264
1262
1287
1322
1362
1393
1394
1466
1446
1484
1494
1524
1546
1591
1586
1585
1613
1641
1673
1684
1741
1775
1785
1792
1826
1848
1893
1919
1955
1956
1957
1981
1991
2033
2071
2073
15
853
622
630
100
654
677
640
179
Tib
165
672
136
652
51
119
687
775
169
844
662
780
301
695
10
663
813
3
98
681
188
50
793
872
404
704
778
22
32
894
41
142
38
114
621
819
13.0
13.0
14.0
15.0
13.0
18.0
19.0
14.0
13.0
14.0
13.0
14.0
13.0
13.0
13.0
13.0
14.0
14.0
13.0
13.0
14.0
14.0
13.0
14.0
18.0
18.0
14.0
13.0
13.0
14.0
13.0
13.0
14.0
13.0
13.0
14.0
14.0
13.0
13.0
18.0
18.0
13.0
13.0
13.0
14.0
13.0
13.0
13.0
14.0
14.0
11.0
19.0
19.0
13.0
12.5
14.0
10.0
11.0
12.0
13.0
13.5
12.0
14.0
13.0
13.0
13.0
14.0
12.0
11.0
12.0
16.0
16.0
12.0
12.0
12.0
12.0
13.0
13.0
14.0
12.5
12.0
14.0
14.0
12.0
14.0
17.0
18.0
12.5
13.0
12.0
14.0
13.0
B
D
A
A
C
A
A
D
C
B
C
A
D
C
C
C
D
D
A
D
C
A
B
D
B
B
D
B
A
D
C
B
A
0
C
A
D
B
D
A
A
C
B
D
A
D
Mean
NMOC
ppmC
0.249
0.192
1.032
0.723
0.123
0.184
0.191
0.335
0.216
0.113
0.138
0.213
0.240
0.157
0.309
0.432
0.808
0.473
0.232
0.119
0.201
0.113
0.081
0.512
0.518
0.502
0.267
0.281
0.183
0.207
0.204
0.425
1.545
0.192
0.288
0.322
0.188
0.866
0.892
0.362
0.361
0.270
0.248
0.185
0.426
0.587
QAD AREAL
NMOC NMOC
ppmc ppmc
0.240
0.165
0.279
0.253
1.601
0.335
C-38
-------
TABLE C-13. SUMMARY OF THE 1989 NMOC DATA FOR LEXINGTON, ICY (LXKY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
04-Aug-89
07-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
IO-Aug-89
11-Aug-89
U-Aug-89
15-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
12-Sep-89
13-S-0-89
H-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
216
219
219
220
221
222
223
226
227
227
228
229
230
233
234
235
236
237
240
241
242
242
243
244
248
249
250
251
254
255
255
256
257
258
261
262
262
264
265
268
268
269
270
271
277
2107
2131
2130
2165
2184
2203
2235
2244
2313
2312
2306
2326
2352
2384
2427
2467
2478
2474
2567
2510
2533
2534
2576
2641
2632
2717
2720
2724
2770
2784
2783
2806
2829
2842
2857
2915
2916
2962
2963
2978
2977
3009
3029
3062
3094
100
98
687
97
501
671
25
637
10
301
642
66
60
631
166
407
18
96
642
84
175
722
620
669
172
870
823
677
724
186
778
147
68
726
109
695
115
64
303
675
129
32
625
715
899
13.0
18.0
18.0
13.0
13.0
14.0
13.0
14.0
18.0
18.0
14.0
13.5
13.0
14.0
13.0
13.0
13.0
13.0
14.0
13.0
18.0
18.0
14.0
13.0
14.0
13.0
13.0
14.0
14.0
18.0
18.0
13.0
12.0
14.0
17.0
14.0
13.0
13.0
13.0
18.0
18.0
13.0
14.0
14.0
13.0
12.0
18.0
18.0
12.0
12.5
14.0
13.0
14.0
18.0
18.0
14.0
12.5
12.5
13.0
13.0
13.0
12.0
12.0
14.0
13.0
18.0
18.0
14.0
13.0
13.0
13.0
13.0
14.0
13.0
18.0
18.0
12.0
12.0
14.0
11.0
14.0
14.0
13.0
13.0
18.0
19.0
12.0
14.0
15.0
14.0
D
D
C
D
D
D
C
C
B
B
D
C
D
D
D
D
C
C
C
C
C
B
A
C
B
C
A
B
D
D
A
D
B
B
A
C
D
B
A
0
C
C
B
A
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.203
0.085
0.088
0.320
1.010
0.331
0.477
1.091
1.796
1.771
0.409
0.372
0.195 0.217
0.256
0.369
0.312
0.413
0.166
0.449
0.332
0.279
0.308
0.315
0.220
0.213 0.659
0.346
0.399
0.213
0.111
0.184
0.194
0.169
0.222
0.242
1.397
0.170
0.221
0.152
0.134
0.308
0.298
0.325
0.126
0.322
0.359
C-39
-------
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C-40
-------
TABLE C-14. SUMMARY OF THE 1989 NMOC DATA FOR NEW YORK, NY (M1NY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
06-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
H-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
26-Jun-89
27-Jtm-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
OS-Jul-89
07-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
14-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
157
157
158
159
160
163
164
165
166
167
170
171
172
173
174
177
177
178
179
180
181
184
186
188
188
191
192
193
194
195
198
199
200
201
202
202
205
206
207
208
209
212
213
214
215
216
1045
1046
1065
1090
1119
1139
1166
1186
1213
1235
1251
1282
1316
1337
1360
1378
1379
1405
1420
1445
1487
1509
1528
1589
1590
1612
1629
1678
1695
1722
1758
1752
1799
1835
1862
1863
1872
1904
1938
1960
1976
2011
2013
2055
2081
2110
812
921
165
810
794
304
927
36
920
720
875
925
72
883
789
404
621
788
406
31
306
303
72
53
688
774
687
35
784
623
146
870
895
112
92
807
33
921
765
770
695
8
678
637
807
404
23.0
23.0
13.0
14.0
14.0
14.0
16.0
14.0
14.0
14.0
14.0
14.0
14.0
14.0
14.0
26.0
26.0
14.0
14.0
14.0
14.0
14.0
14.0
25.0
25.0
14.5
18.0
17.0
17.5
17.5
17.0
17.0
16.5
17.0
24.0
24.0
14.0
14.0
14.5
14.5
14.0
14.0
14.0
14.0
14.0
22.0
22.0
13.0
14.0
14.5
14.0
14.0
13.0
14.0
12.0
12.0
15.0
13.0
14.0
14.0
26.0
26.0
14.0
13.0
14.0
14.0
14.0
14.0
24.0
24.0
16.0
16.0
17.0
17.0
18.0
18.0
18.0
17.0
17.0
24.0
24.0
15.0
14.0
14.0
15.0
14.0
14.0
14.0
15.0
15.0
14.0
B
D
B
D
B
C
B
C
D
C
D
D
C
D
A
B
C
A
B
C
A
D
C
B
A
D
B
A
B
B
A
C
B
C
B
D
C
C
A
0
C
C
B
D
B
B
Mean
NMOC
ppmC
0.630
0.608
0.515
1.387
0.727
0.594
0.803
0.307
0.262
0.864
0.751
1.235
0.570
0.944
0.928
0.791
0.799
0.822
0.515
0.255
0.414
0.601
0.339
0.603
0.526
0.397
0.394
0.392
0.775
1.114
0.309
0.681
0.721
0.573
0.282
0.301
0.554
0.850
0.417
0.873
0.645
0.520
0.353
0.630
0.640
0.773
QAD AREAL
NMOC NMOC
ppmc pprcc
0.785
0.567
0.670
0.403
C-41
-------
TABLE C-14. SUMMARY OF THE 1989 NMOC DATA FOR NEW YORK, MY (M1NY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pre .-e Radian
Sampled Sampled Number Number (psig) ( 3) Channel
07-Aug-89
08-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
14-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
18-Sep-89
19-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
28-Sep-89
29-Sep-89
219
220
220
221
222
223
226
227
228
229
229
230
233
234
235
236
237
240
241
242
243
243
244
248
249
250
251
254
255
256
257
261
262
262
263
264
265
268
269
270
271
271
272
2126
2157
2156
2175
2196
2236
2254
2287
2301
2348
2349
2363
2377
2411
2442
2450
2488
2528
2522
2553
2603
2604
2626
2620
2659
2697
2723
2740
2771
2782
2810
2869
2882
2881
2912
2931
2957
2988
3012
3039
3055
3054
3103
6
766
848
19
181
137
686
52
135
692
670
651
834
197
93
659
646
848
668
66
113
45
91
70
25
305
634
689
777
112
860
825
171
305
624
707
632
75
96
72
669
842
924
14.0
27.0
27.0
17.0
17.0
16.5
18.0
16.0
16.0
28.0
28.0
15.0
14.0
14.0
14.0
14.0
14.5
14.0
14.0
14.0
27.0
27.0
14.0
14.0
14.0
14.0
14.5
14.0
12.0
14.0
13.0
14.0
28.0
28.0
18.0
18.0
16.0
18.0
16.0
17.5
27.0
27.0
14.0
13.0
27.0
27.0
17.0
17.0
17.0
18.0
17.0
17.0
28.0
28.0
14.0
13.0
14.0
14.0
15.0
15.0
14.0
15.0
14.0
28.0
29.0
14.0
14.0
14.0
15.0
15.0
14.0
13.0
14.0
13.0
14.0
28.0
28.0
19.0
18.0
16.0
18.0
16.0
18.0
28.0
28.0
14.0
C
D
D
C
C
C
A
A
D
B
D
A
C
A
D
C
C
B
D
D
B
D
A
B
B
D
B
D
C
C
B
B
D
C
B
D
D
0
C
C
C
0
A
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.308
0.345
0.342
0.356
0.799
0.220
1.107
2.043
0.795
0.359
0.312
0.318
0.739
0.456
0.614
0.315 0.333
0.258
0.596
0.538
0.807
0.335
0.334
0.912
0.406
0.211
0.967
1.329
0.524
0.339
0.471
0.349
0.392
0.263
0.241
0.434
1.968
0.416
0.398
0.513
0.360
0.5 J.
0.568
0.780
C-42
-------
s
8
8
8
CO
8
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8
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0)
O
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.O
2
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O
O
O
O
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s
Q_
6
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IT
C-43
-------
TABLE C-15. SUMMARY OF THE 1989 NMOC DATA FOR MONTGOMERY, AL (MGAL)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07- Jut -89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
U-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
19-Jul-89
20-Jul-89
ZI-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
(W-Aug-89
07-Aug-89
156
157
158
159
160
160
163
164
165
167
170
171
172
173
178
179
180
180
181
184
186
187
188
191
192
193
194
195
198
199
200
200
201
202
205
206
207
208
209
209
212
213
214
215
216
219
1014
1032
1063
1128
1114
1113
1164
1171
1219
1225
1300
1314
1313
1342
1468
1443
1454
1455
1520
1526
1527
1576
1622
1642
1671
1683
1690
1764
1773
1763
1808
1809
1832
1849
1883
1924
1914
1952
2022
2021
2023
2068
2066
2106
2102
2135
406
856
777
807
621
641
629
848
659
773
638
138
808
400
670
680
791
814
786
131
96
70
28
705
99
62
302
121
634
301
36
857
663
640
868
57
796
645
176
726
131
808
28
767
774
102
14.0
14.0
14.5
14.5
14.5
14.5
14.5
14.0
14.4
14.3
18.0
14.0
14.2
14.1
13.9
14.1
13.9
14.0
14.1
15.5
16.9
16.0
16.0
16.2
16.0
16.0
15.9
16.0
16.1
15.9
12.6
12.6
16.0
16.2
16.0
16.1
16.0
16.2
14.0
14.0
16.2
16.7
16.3
16.5
16.3
16.1
14.0
12.0
14.0
14.0
14.0
14.0
14.0
13.0
10.0
10.0
15.5
12.0
13.0
12.0
12.0
12.0
13.0
13.0
16.0
12.0
14.0
13.0
15.0
15.0
14.0
13.0
12.0
12.5
16.0
15.0
12.0
12.0
15.0
16.0
16.0
16.0
16.0
14.0
13.0
13.0
16.0
16.0
16.0
16.0
16.0
15.0
A
A
A
C
D
D
B
C
C
B
A
A
D
A
C
B
C
D
C
B
0
D
C
A
B »
C
D
B
D
D
B
B
D
D
D
C
C
A
C
D
0
0
B
B
A
D
Mean
NMOC
ppmC
0.186
0.231
0.220
0.181
0.184
0.207
0.232
0.197
0.198
0.190
0.144
0.197
0.189
0.299
0.221
0.292
0.201
0.159
0.238
0.124
0.187
0.170
0.222
0.210
0.378
0.349
0.191
0.395
0.153
0.186
0.203
0.144
0.216
0.146
0.113
0.316
0.122
0.184
0.446
0.397
0.252
0.158
0.260
0.280
0.262
0.190
QAD AREAL
NMOC NMOC
ppmc pproc
0.240
0.405
0.453
0.225
0.154
0.214
C-44
-------
TABLE C-15. SUMMARY OF THE 1989 NHOC DATA FOR MONTGOMERY, AL (MGAL)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
11-Aug-89
H-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
22-Sep-89
25-Sep-89
28-Sep-89
29-Sep-89
220
221
222
223
223
226
227
228
229
230
233
234
235
236
237
240
241
241
242
243
244
248
249
250
251
254
254
255
256
257
258
261
262
263
264
265
265
268
276
272
2172
2205
2221
2228
2227
2271
2275
2304
2334
2354
2408
2403
2471
2462
2570
502
^523
2524
2579
2600
2704
2726
2719
2713
2716
2736
2737
2786
2846
2815
2811
2896
2914
2934
2932
2953
2954
2996
3091
3104
663
646
806
726
660
689
667
783
645
871
33
305
63
637
131
27
61
3
767
857
164
868
33
807
36
131
18
656
126
828
183
192
661
93
916
138
157
186
921
21
16.0
16.4
17.3
14.0
14.0
16.3
16.8
16.3
16.4
16.1
16.0
16.0
14.0
16.8
15.9
16.0
13.1
13.3
16.1
16.1
16.3
16.3
16.0
16.0
16.9
13.2
13.3
15.2
14.5
14.5
15.0
15.0
15.5
13.9
13.5
13.5
13.5
15.6
15.0
15.0
16.0
16.0
16.0
12.0
14.0
15.0
16.0
15.0
15.0
15.0
15.0
15.0
14.0
15.0
15.0
14.5
13.0
13.0
15.0
14.0
16.0
16.0
15.0
15.0
14.0
8.0
11.0
14.0
14.0
15.0
13.0
14.0
15.0
13.0
13.0
12.0
12.0
14.0
15.0
14.0
c
D
D
C
A
B
C
D
A
B
B
D
C
C
B
C
B
A
D
D
B
B
D
D
C
C
D
C
C
B
A
A
C
C
D
B
C
C
A
C
Mean QAD AREAL
NMOC NMOC n.--,*~
ppmC ppmc ppmc
0.089 0.135
0.133
1.075
0.106
0.130
0.100
0.134
0.231
0.315
0.104
0.124
0.243
0.206
0.230
0.240
0.142 0.178
->9
0.321
0.220
0.219 0.247
1.133
0.164
0.093
0.166
0.167 »
0.185
0.195
0.126
0.138
0.238
0.193
0.098
0.149
0.147
0.124
0.268
0.271
0.087
0.091
0.143
C-45
-------
5 i
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o
N.
CM
CM
CM
O
8
8
in
8
8
CO
8
CM*
8
•
o
CO
O
Q
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J3
cr
O
O
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O
O
O
O
O
o
ZE
CD
6
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C-46
-------
TABLE C-16. SUMMARY OF THE 1989 NMOC DATA FOR NEW YORK, NY (MNY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
05-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
23-Jun-89
23-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
30-Jun-89
03-Jul-89
OS-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
U-Jut-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
156
156
160
163
164
165
166
167
170
171
172
174
174
178
179
180
181
181
184
186
187
188
191
192
193
194
195
198
199
200
201
201
202
205
206
207
208
209
212
213
214
215
216
219
220
221
1018
1019
1112
1140
1168
1185
1214
1236
1250
1281
1312
1357
1358
1406
1419
1448
1497
1498
1508
1548
1551
1581
1611
1630
1679
1694
1723
1757
1753
1798
1821
1822
1828
1885
1903
1937
1961
1975
2010
2012
2062
2083
2109
2127
2159
2176
172
45
84
856
106
687
169
635
89
807
161
100
823
150
828
776
188
15
660
870
834
646
97
907
864
698
677
87
883
722
147
834
767
37
182
814
878
1
860
184
10
853
409
147
182
171
19.5
19.5
16.0
16.0
15.0
16.5
16.0
16.0
16.0
17.0
16.0
18.0
18.0
16.0
16.0
17.0
20.0
20.0
16.0
14.0
14.0
15.0
14.0
14.5
14.5
16.0
16.0
14.0
14.0
15.0
18.0
18.0
16.0
15. S
16.0
16.0
16.0
15.0
16.0
15.0
18.0
24.0
15.0
14.0
16.0
15.0
18.0
19.0
15.0
16.0
15.0
16.5
16.0
14.0
13.0
16.0
16.0
18.0
18.0
14.0
15.0
16.0
17.0
18.0
16.0
14.0
12.0
12.0
14.0
14.0
14.0
16.0
16.0
14.0
14.0
16.0
18.0
18.0
16.0
16.0
16.0
16.0
15.0
15.0
16.0
15.0
18.0
24.0
14.0
14.0
14.0
14.0
8
C
C
D
C
B
C
D
C
D
B
B
C
D
A
D
A
A
D
C
C
A
A
B
B
A
D
D
D
D
B
D
D
A
B
B
C
D
D
C
B
B
B
A
C
B
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.618
0.620
0.568
0.658
0.716
0.312
0.436
0.687 0.718
0.718 0.736
0.951
1.424
1.010
1.140
0.514
0.518 0.476
0.222
0.447
0.378
0.553
0.316
0.492
0.789
0.568
0.628
0.407
0.606
0.793
0.216
0.515
0.778
0.409
0.447
0.393
0.730
0.886
0.306
0.803
0.511
0.448
0.236 0.332
0.710
0.529
0.295
0.333
0.279
0.127
C-47
-------
TABLE C-16. SUMMARY OF THE 1989 NMOC DATA FOR NEW YORK, NY (MNY)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
10-Aug-89
11-Aug-89
H-Aug-89
15-Aug-89
16-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-AU9-89
28-AUS-39
29-Aug-89
30-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
18-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27- ep-89
28-Sep-89
28-Sep-89
29-Sep-89
222
223
226
227
228
228
229
230
233
234
235
236
237
240
241
242
242
243
244
248
249
250
251
254
255
256
257
261
261
262
263
264
265
268
269
270
271
271
272
2197
2230
2253
2286
2285
2284
2358
2362
2376
2412
2441
2451
2489
2559
2521
2532
2531
2593
2625
2619
2666
2696
2725
2741
2775
3785
2809
2864
2863
2895
2911
2929
2976
2987
3013
"32
^i53
3052
3102
3
681
718
186
112
151
813
92
91
41
105
30
677
689
31
181
794
860
645
814
105
50
635
687
722
188
875
649
715
100
180
718
772
31
16
143
155
825
43
15.0
16.0
16.0
14.0
17.0
17.0
15.0
14.0
14.0
14.0
13.5
13.0
14.0
14.0
13.0
15.0
15.0
14.0
14.0
14.0
14.0
14.0
14.0
14.0
14.0
13.0
13.0
16.0
16.0
12.0
12.0
12.0
13.0
13.0
12.0
14.0
16.0
16.0
12.0
15.0
14.0
15.0
14.0
15.0
17.0
15.0
14.0
13.0
13.0
12.0
12.5
14.0
14.0
12.0
12.5
14.0
13.0
• - -
13.0
n.o
12.0
13.0
12.0
12.0
14.5
14.5
12.0
12.0
12.0
13.0
12.0
11.0
12.0
16.0
16.0
12.0
D
C
D
D
C
B
D
D
B
B
C
B
D
C
C
C
B
D
B
D
D
C *
D
C
C
C
D
C
C
B
C
C
A
A
C
C
C
B
D
Mean QAD AREAL
NMOC )C NMOC
r TC .TIC ppmc
0.603
0.281
0.912
1 .OCW>
0.556
0.566
0.405
0.259
0.826
0.230
0.617
0.376
0.192
0.305
0.433
0.571
0.501
0.301
0.377
0.328
0.453
1.210
1.609
0.538
0.336
0.528
0.605
0.273
0.322
0.154
0.378
1.164
0.458
0.355
0.318
1.032
0.680
0.565
0.706
C-48
-------
C-49
-------
TABLE C-17. SUMMARY OF THE 1989 NMOC DATA FOR NEWARK, NJ
Sampling Period: 6:00 a.m. to 9:00 a-.m.
Julian Sample Sample Sample Analysis
: Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (pstg) Channel
05-Jun-89
06-Jun-89
07-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
U-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
156
157
158
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
178
179
180
181
184
186
187
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
209
212
213
214
215
216
1034
1054
1078
1079
1096
1137
1138
1188
1189
1211
1212
1271
1308
1307
1341
1380
1381
1376
1377
1482
1480
1512
1553
1552
1607
1608
1677
1707
1706
1759
1760
1779
1802
1803
1857
1902
1901
1935
1936
2008
2009
2014
2026
2057
2113
2114
162
689
1
831
823
400
62
164
7
11
121
660
131
838
145
658
104
175
698
122
719
39
691
305
143
175
66
198
707
407
768
30
109
53
773
185
179
164
631
52
838
691
301
899
623
885
15.4
15.6
6.5
17.2
14.5
15.0
15.2
18.4
15.0
14.5
15.2
16.4
15.0
14.9
15.0
16.0
15.0
18.5
18.5
14.2
16.0
15.5
15.9
16.2
15.6
15.0
16.8
15.2
15.9
15.0
16.0
16.0
16.2
14.8
16.0
15.2
16.0
17.3
16.1
14.6
15.0
16.1
15.0
14.9
15.3
14.5
14.0
15.0
6.0
16.0
14.0
15.0
15.0
18.0
14.0
15.0
14.0
16.0
14.0
14.0
14.0
16.0
14.0
18.0
18.0
14.0
14.0
15.0
14.0
14.0
10.0
15.0
14.0
14.0
16.0
15.0
16.0
16.0
16.0
14.0
15.0
15.0
16.0
18.0
16.0
14.0
14.0
16.0
15.0
14.5
16.0
14.0
B
B
C
C
A
C
B
B
D
A
B
B
0
C
C
D
D
C
C
C
C
D
D
D
D
A
D
B
A
C
D
C
C
C
D
D
A
B
B
D
D
B
A
A
C
A
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.297
0.562
0.607
0.521
0.678
0.720
0.624
3.699
0.240
0.305
1.090
0.505 0.844
1.361
0.379
0.505
0.507
0.363
0.636
0.640
0.433
0.158
0.239
0.630
0.255
0.282
0.569
0.658
0.509
0.353
0.417
1.112
0.197
2.302 2.174
0.606
0.524
0.235
1.167 , '^
0.594
0.852
0.935
0.417
0.510 0.555
0.337
0.917
0.520
0.637
C-50
-------
TABLE C-17. SUMMARY OF THE 1989 NMOC DATA FOR NEWARK, NJ (NUNJ)
Sampling Period: 6:00 a.m. to 9:00 a.~
"
Julian Sample Sample Sample Analysis
Date Date 10 Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
08-Aug-89
09-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
U-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
18-*ug-89
21 ^jg-89
22-Aug-89
23-Aug-89
24-Aug-89 .
25-Aug-89
25-Aug-89
28-Aug-89
29-AU9-89
30-Aug-89
31-Aug-89
01-Sep-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
29-Sep-89
29-Sep-89
220
221
221
222
223
226
227
228
229
230
230
233
234
235
236
237
237
240
241
242
243
244
244
248
249
250
251
254
255
256
258
261
262
263
263
264
265
268
269
270
272
272
2199
2169
2170
2263
2264
2265
2297
2364
2365
2419
2420
2388
2448
2449
2433
2480
2479
2503
2542
2541
2587
2649
2648
2655
2688
2686
2780
2794
2793
2834
2860
2909
2910
2941
2940
2980
2979
3014
3077
3079
3114
3118
875
126
927
857
22
36
872
404
685
83
669
501
766
878
42
890
153
852
788
774
107
666
74
657
688
109
833
680
652
676
172
924
890
70
831
777
783
778
885
671
624
686
15.0
18.2
18.2
15.0
15.0
14.5
15.0
15.5
15.9
17.6
17.6
15.6
14.9
14.4
15.7
17.9
17.9
15.0
16.0
15.8
15.0
19.0
19.0
16.5
16.7
17.1
15.4
16.0
16.2
16.1
15.0
15.0
15.8
18.0
18.0
15.8
15.8
17.5
15.2
17.0
16.1
17.2
15.0
17.0
18.0
16.0
15.0
14.0
14.5
15.0
16.0
17.5
18.0
14.0
15.0
14.0
15,0
17.0
18.0
14.5
15.0
15.0
14.0
16.0
19.0
17.0
17
13.
15.0
15.0
16.0
16.0
13.0
15.0
16.0
18.0
18.0
16.0
15.0
16.0
14.5
17.0
16.0
17.0
C
B
0
B
C
B
D
C
A
C
C
C
D
0
B
C
A
0 .
C
A
A
C
C
0
C
C
D
0
C
C
C
A
A
0
0
i
B
D
D
A
C
0
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.254
0.319
0.298
1.097
0.263
1.356
1.981
0.551
0.586
0.324
0.296
0.216
0.307
0.497
0.315
0.248
0.177
0.979
0.450
0.740
0.370
0.788
0.839
0.272
0.600
1.708
1.679
0.470
0.329
0.491
0.532
0.614
0.299
0.463
0.518
2.124
1.042
0.270
0.602
0.205
0.522
0.814
051
-------
-
CL
s
8
8 8
CO CM
o=
^
o
i^
CM
CM
8
o
CO
.Q
•s
O
CO XN
OJ O
o g O
5 S O
00
6
-------
TABLE C-18. SUMMARY OF THE 1989 NMOC DATA FOR PLAINFIELO, NJ (PLNJ)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
09-Aug-89
10-Aug-89
11-Aug-89
14-Aug-89
14-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
25-Aug-89
28-Aug-89
28 jg-89
29-Aug-89
30-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
12-Sep-89
13-Sep-89
U-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
21-Sep-89
22-Sep-89
26-Sep-89
27-Sep-89
27-Sep-89
28-Sep-89
28-Sep-89
29-Sep-89
29-Sep-89
221
222
223
226
226
227
228
229
230
233
233
234
235
237
240
240
241
242
243
244
248
249
250
251
"5
<:56
257
258
261
262
263
264
264
265
269
270
270
271
271
272
272
2193
2255
2256
2314
2315
2303
2343
2342
2409
2413
2414
2453
2454
2525
2513
2514
2607
2608
2586
2660
2670
2680
2681
2781
2789
2824
2872
2875
2927
2933
2930
2985
2986
3026
3040
3051
3050
3056
3057
3110
3111
698
684
895
777
184
193
885
121
655
6
304
704
803
79
53
176
856
87
875
815
773
662
624
142
303
713
52
663
150
66
696
848
102
165
189
643
656
819
852
692
640
15.8
15.8
14.1
13.9
13.9
14.2
14.0
14.1
15.7
13.3
13.3
13.0
14.8
14.3
13.6
13.6
14.2
13.9
14.3
14.2
14.8
15.9
15.9
14.2
14.3
15.5
13.9
15.0
14.2
15.3
15.4
13.5
13.6
14.0
14.3
14.8
14.8
14.2
14.4
15.2
15.2
15.0
19.0
17.0
16.0
17.0
17.0
14.0
12.0
18.0
16.0
16.0
16.0
18.0
17.0
16.0
16.0
17.0
16.0
15.0
17.0
18.0
18.0
18.0
16.0
16.0
15.0
16.0
16.0
16.0
16.0
18.0
15.0
16.0
16.0
17.0
18.0
18.0
18.0
18.0
17.0
18.0
B
B
D
A
D
C
C
i
C
D
D
C
C
A
D
A
C
A
C
D
C
B
A
D
C
A
C
D
D
C
B
C
C
C
B
B
B
C
B
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.525
0.969
0.160
0.764
0.758
0.888
0.405
0.274
0.294
0.353
0.351
0.161
0.425
0.152
0.607
0.638
0.565
0.371
0.105
1.147
0.268
0.540
1.508
1.479
0.168
0.359
0.451
0.267
0.163
0.513
0.431
0.982
1.018
1.134
0.541
0.162
0.134
1.503
1.570
0.542
0.557
C-54
-------
TABLE C-18. SUMMARY OF THE 1989 MMOC DATA FOR PLAINFIELD. NJ (PLNJ)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
OS-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
H-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
OS-Jul-89
10-Jul-89
11-JUI-89
12-JUI-89
14-JUI-89
17-Jul-89
18-JUI-89
18-Jul-89
19-Jul-89
20-Jul-89
21-JUI-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
07-Aug-89
08-Aug-89
156
157
158
159
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
179
180
181
184
186
191
192
193
195
198
199
199
200
201
202
205
206
207
208
209
212
213
214
215
216
219
220
1040
1097
1105
1076
1077
1148
1147
1179
1178
1256
1257
1272
1349
1350
1343
1403
1404
1475
1451
1450
1474
1513
1530
1529
1631
1676
1646
1756
1858
1783
1782
1859
1860
• 1907
1908
1959
1958
2006
2007
2015
2025
2056
2151
2153
2167
2198
806
198
715
895
176
890
842
33
719
834
777
825
897
646
172
839
115
8
666
723
11
676
808
106
57
119
778
801
676
4
724
186
28
143
652
790
697
137
681
872
18
920
914
834
629
35
15.4
14.0
15.4
13.4
13.4
14.1
14.1
13.9
15.4
14.4
15.2
14.2
14.4
15.5
14.7
14.2
14.0
13.5
14.0
14.0
14.2
15.9
15.1
14.8
14.1
14.1
15.3
15.3
14.1
14.1
14.3
15.6
15.6
15.7
15.5
15.2
14.0
15.0
14.1
14.1
14.0
14.0
14.0
14.8
14.3
18.0
16.0
17.0
16.0
16.0
16.0
16.0
11.0
15.0
14.0
15.0
16.5
17.0
18.0
16.0
16.0
16.0
16.0
17.0
17.0
15.0
18.0
18.0
18.0
14.0
16.0
18.0
18.0
17.5
17.0
17.0
17.0
17.5
18.0
14.5
18.0
18.0
14.0
18.0
17.0
17.0
16.0
16.0
16.0
17.0
15.0
A
B
C
C
D
B
D
C
D
A
D
A
D
C
0
A
D
A
C
D
C
C
B
A
A
B
C
C
D
D
A
A
A
A
C
D
B
A
C
D
C
D
C
A
A
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.407
0.384
0.438
0.377
0.370
0.524
0.184
0.524
0.249 0.297
0.368
1.077
0.723 0.721
0.686
0.327
6.664
0.968
0.241
0.757
0.287
0.235
0.072
0.170
0.273
0.288
0.316
0.128
0.218
0.550
0.104
0.457
0.304
0.610
1.796
1.334
0.734
1.189
0.203
0.327
0.226
0.500
0.201
0.753
0.493
0.359
0.290
0.104
C-53
-------
~
12
co
a:
o
6
g>
LL
C-55
-------
TABLE C-19. SUMMARY OF THE 1989 NMOC DATA FOR RALEIGH, NC (RLNC)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date 10 Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
13-Jun-89
14-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
29-Jun-89
30-Jun-89
05-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-fl9
14-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
31-Jul-89
01-Aug-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
05-Aug-89
156
157
158
159
160
163
164
164
165
166
167
170
171
172
173
174
177
178
180
181
186
186
187
188
191
192
193
194
195
198
199
200
201
202
205
205
206
207
208
212
213
213
214
215
216
217
1009
1010
1049
1050
1071
1125
1126
1127
1176
1177
1249
1246
1248
1295
1296
1370
1371
1372
1502
1503
1506
1547
1571
1570
1597
1650
1651
1649
1730
1731
1732
1777
1812
1815
1864
1865
1886
1896
1913
1970
2004
2005
2038
2041
2080
2082
698
179
136
12
833
878
697
809
913
192
916
914
801
810
179
671
834
45
74
108
767
804
84
684
33
52
685
875
91
136
184
138
667
309
899
135
803
649
192
185
84
684
192
57
107
198
17.0
16.0
15.0
17.0
17.0
17.0
16.0
16.0
18.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
16.0
16.0
17.0
16.0
16.0
15.0
17.0
16.0
17.0
17.0
17.0
16.0
16.0
16.0
17.0
18.0
16.0
0.0
14.0
16.0
15.0
18.0
16.5
15.0
15.0
16.0
15.0
15.0
16.0
17.0
16.0
15.0
17.0
17.0
17.0
15.0
15.0
19.0
17.0
14.0
14.0
15.0
18.0
16.5
17.0
16.0
16.0
17.0
17.0
16.0
16.0
14.0
17.0
14.0
16.0
17.0
15.0
16.0
16.0
16.0
17.0
16.0
15.0
15.0
14.0
16.0
16.0
16.0
16.0
15.0
15.0
16.0
16.0
16.0
16.0
C
0
B
D
D
D
A
A
C
B
C
D
A
C
B
A
B
D
A
C
C
A
C
D
D
D
B
C
C
D
B
A
A
C
C
A
C
D
A
B
B
B
B
D
C
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.286 0.291
0.166
0.190
0.108
0.158
0.150
0.252
0.228
0.344
0.177
0.228
0.206
0.138
0.110
0.193 0.279
0.104
0.551
0.321
0.158
0.059
0.110
0.116
0.136
0.156
0.276
0.325
0.268
0.126
0.097
0.052
0.066 0.101
0.169
0.087
-0.386 0.419
0.153
0.208
0.258
0.386
0.089
0.204 0.249
0.054
0.043
0.113
0.277
0.269
0.120 0.175
C-56
-------
TABLE C-19. SUMMARY OF THE 1989 NMOC DATA FOR RALEIGH, NC (RLNC)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
06-Aug-89
07-Aug-89
08-Aug-89
09-Aug-89
11-Aug-&9
12-Aug-89
14-Aug-89
15-Aug-89
16-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
12-Sep-89
13-Sep-89
13-Sep-89
14-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
218
219
220
221
223
224
226
227
228
228
229
230
233
234
235
236
2".~
240
241
242
243
243
• 244
248
249
249
250
251
254
255
256
256
257
258
261
262
263
264
265
268
269
270
271
272
2084
2141
2142
2147
2189
2191
2241
2242
2288
2289
2311
2319
2393
2394
2395
2571
2671
2672
2572
2573
2575
2574
2597
2673
3085
2674
2675
2676
2751
2750
2759
2758
2852
2853
2851
2855
3084
3080
3086
3083
3087
3088
3082
3081
38
14
130
720
162
166
627
72
46
100
37
157
857
180
667
\&
395
'06
871
900
658
698
98
622
839
790
899
890
61
86
834
871
794
72
169
197
36
635
868
37
894
68
27
875
16.0
16.0
16.0
18.0
16.0
16.0
16.0
16.0
15.0
15.0
16.0
16.0
17.0
19.0
17.0
19.0
17.0
17.0
17.0
17.0
17.0
17.0
18.0
19.0
16.0
18.0
ia.o
18.0
17.0
17.0
16.0
16.0
17.0
17.0
17.0
17.0
16.0
17.0
17.0
17.0
16.0
17.0
18.0
16.0
15.0
13.0
12.5
17.0
16.0
16.0
16.0
15.0
15.0
16.0
16.0
16.0
18.0
17.0
18.0
17.0
17.0
16.0
16.0
16.0
16.0
16.0
19.0
16.0
18.0
18.0
17.0
17.0
17.0
14.0
15.0
17.0
17;0
17.0
14.5
16.0
18.0
16.0
16.0
16.0
18.0
18.0
17.0
A
A
B
D
0
D
A
B
B
C
C
D
A
C
B
A
B
A
A
B
D
B
B
B
C
D
C
A
D
C
B
B
D
A
A
A
C
A
A
D
C
B
D
D
Mean QAD AREAL
NMOC • • NMOC NMOC
ppmC ppmc ppmc
0.079
0.099
0.054
0.046
0.074
0.083
0.201
0.056 0.075
0.405
0.391
0.116
0.056
0.146
0.198
0.176
0.183
0.083
0.142
0.220
0.210
;\080
0.086
0.265 0.310
0.052
0.050
0.054
0.092
0.226
0.525
0.163
0.098
0.083
0.135
0.137
0.092
0.065
0.068
0.053
0.065
0.046
0.086
0.049
0.056
0.232
C-57
-------
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C-58
-------
TABLE C-20. SUMMARY OF THE 1989 NMOC DATA FOR RESEDA, CA (RSCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
20-Jun-89
22-Jun-89
22-Jun-89
23-Jun-89
04-Jul-89
06-Jul-89
07-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
13-JUI-89
14- Jut -89
17- Jut -89
18-Jul-89
20-Jul-89
21-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
27-Jul-89
28-JUI-89
31-Jul-89
01-Aug-89
03-Aug-89
04-Aug-89
07-Aug-89
08-Aug-89
10-Aug-89
11-Aug-89
14-Aug-89
15-Aug-89
17-Aug-89
18-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
24-Aug-89
28-Aug-89
29-Aug-89
29-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
171
173
173
174
185
187
188
188
191
192
194
195
198
199
201
202
202
205
206
208
209
212
213
215
216
219
220
222
223
226
227
229
230
230
233
234
236
240
241
241
243
244
248
250
251
254
1292
1336
1335
1356
1561
1559
1596
1579
1616
1645
1687
1716
1735
1765
1837
1819
1820
1879
1895
1941
1980
2002
2030
2078
2108
2132
2146
2207
2211
2248
2267
2329
2366
2367
2381
2410
2457
2490
2519
2520
2599
2614
2640
2677
2718
2747
4
193
853
113
642
123
658
924
135
79
181
806
107
860
122
99
119
684
172
646
916
718
86
833
121
145
183
662
70
43
114
56
113
155
722
842
921
718
145
899
32
806
183
697
56
403
18.0
18.0
18.0
18.0
18.0
17.0
14.0
14.0
17.0
17.0
17.0
17.0
17.0
17.0
17.0
13.0
13.0
18.0
17.0
17.0
17.0
18.0
17.0
17.0
17.0
17.0
17.0
18.0
17.0
16.5
18.0
19.0
12.5
13.0
19.5
19.0
19.0
19.5
18.0
18.0
18.0
25.0
17.0
19.0
18.0
19.0
14.0
14.0
14.0
12.0
12.0
12.0
8.0
10.0
12.0
14.0
12.0
15.0
14.0
14.0
14.0
13.0
13.0
15.0
14.0
14.0
14.0
15.0
16.0
14.0
14.0
14.0
13.0
15.0
14.0
14.0
15.0
15.0
10.0
12.0
19.0
16.0
16.0
16.0
15.0
15.0
15.0
21.0
14.0
16.0
15.0
15.0
C
B
8
B
B
D
C
B
C
D
A
D
0
D
C
B
D
A
C
D
D
B
D
D
D
C
A
D
D
D
A
C
C
C
C
A
B
A
B
0
C
A
B
D
C
C
Mean OAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
1.876
1.102
1.102
0.340 0.408
1.134
1.238
0.842
0.820
0.323
0.314
1.236
1.414
0.483
0.571
1.289
1.262
1.275
0.399 0.446
0.555
1.100 1.143
1.209
0.904
0.912
1.125
1.260
0.863
0.417
0.455
0.913
1.002
0.648 0.666
0.417
0.635
0.536
0.209
0.879
0.380
1.370
1.735
1.703
1.843 1.729 1.799
3.990
1.930
1.630
1.258
1.470
C-59
-------
TABLE C-20. SUMMARY OF THE 1989 NMOC DATA FOR RESEDA, CA (RSCA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure
Radian
Sampled Sampled Number Number (psig) (psig) Channel
12-Sep-89
12-Sep-89
U-Sep-89
15-Sep-89
18-Sep-89
18-Sep-89
21-Sep-89
21-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
28-Sep-89
29-Sep-89
29-Sep-89
255
255
257
258
261
261
264
264
265
268
269
271
272
272
2766
2765
2816
2848
2871
2866
2946
2945
2970
2991
3011
3107
3089
3090
185
770
140
810
852
698
10
634
788
762
928
657
403
145
18.0
18.0
18.0
19.0
19.0
19.0
18.0
18.0
19.0
19.0
19.0
19.0
18.0
18.0
14.0
14.0
15.0
15.0
14.0
15.0
15.0
15.0
16.0
16.0
16.0
16.0
15.0
17.0
D
A
A
C
C
B
B
B
C
D
B
C
B
0
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.550
0.535
1.867
3.000
0.593
0.424
2.839
2.800
3.222
1.890
2.327
2.216
1.420
1.407
C-60
-------
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o
CD
03
OJ
ro
o
m
o
CO
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O
O
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C-61
-------
TABLE C-21. SUMMARY OF THE 1989 NMOC DATA FOR ST. LOUIS, HO (S2MO)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
14-Jun-89
H-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
03-Jul-89
05-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
13-Jul-89
14-Jul-89
17-Jul-89
18-Jut-89
19-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
04-Aug-89
157
158
159
160
163
164
165
165
166
167
170
171
172
173
174
174
177
178
179
180
184
186
187
188
191
192
193
194
194
195
198
199
200
200
201
202
205
206
207
208
209
212
213
214
215
216
1027
1056
1120
1121
1129
1187
1203
1204
1227
1247
1266
1288
1319
1361
1369
1368
1397
K13
1458
1444
1525
1541
1558
1621
1617
1652
1656
1727
1726
1713
1744
1772
1810
1811
1843
1850
1878
1900
1925
1948
1972
2003
2051
2048
2067
2100
166
650
864
184
774
183
90
696
775
666
661
135
872
778
68
842
304
801
657
916
17
56
185
789
627
405
15
776
828
.854
157
400
696
786
688
685
657
680
90
723
696
15
106
186
652
631
16.0
16.0
15.0
15.0
16.0
15.0
16.0
16.0
15.0
16.0
16.0
14.0
14.0
16.0
16.0
16.0
14.0
15.0
14.0
10.5
16.0
16.0
17.0
17.0
16.0
16.0
15.0
16.0
16.0
16.5
16.5
16.5
17.0
17.0
16.5
16.5
17.0
17.5
16.0
17.0
16.5
16.0
16.0
16.0
17.0
17.0
16.0
15.0
15.0
15.0
16.0
14.0
16.0
16.0
12.0
12.0
12.0
14.0
14.0
16.0
14.0
15.0
13.0
14.0
13.0
11.0
15.0
15.0
16.0
16.0
16.0
14.0
15.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
17.0
17.0
16.0
17.0
16.5
15.0
15.0
16.0
16.0
16.0
A
A
B
D
0
C
A
C
B
C
0
0
0
D
C
B
A
A
D
A
C
0
A
0
C
B
A
D
C
A
C
C
B
B
D
B
B
A
B
C
C
C
D
C
C
A
Mean
NMOC
ppmC
0.951
1 .967
0.870
0.240
0.269
0.303
0.519
0.524
0.303
0.848
0.364
0.661
0.791
1.048
0.691
0.724
0.932
0.338
0.682
0.334
0.187
0.490
1.415
1.034
0.388
0.900
0.481
0.659
0.706
0.432
1.049
2.132
0.335
0.210
0.350
0.498
0.596
0.850
0.821
0.453
0.404
1.653
0.685
2.090
0.622
0.447
QAD AREAL
NMOC NMOC
ppmc ppmc
0.345
0.964
0.805
0.434
C-62
-------
TABLE C-21. SUMMARY OF THE 1989 NMOC DATA FOR ST. LOUIS, MO
-------
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TABLE C-22. SUMMARY OF THE 1989 NMOC DATA FOR SACRAMENTO. CA (S3CA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
13-Jun-89
U-Jun-89
16-Jun-89
19-Jun-89
20-Jun-89
21-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
03-Jul-89
03-Jul-89
05-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
H-Jul-89
17-Jul-89
18-Jul-89
19-Jul-89
24-Jul-89
25-Jul-89
25-Jul-89
26-Jul-89
28-Jul-89
31-Jul-89
OI-Aug-89
01-Aug-89
02-Aug-89
04-Aug-89
08-Aug-89
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
U-Aug-89
156
157
158
159
160
163
164
164
165
167
170
171
172
174
177
178
179
180
181
184
184
186
191
192
193
194
195
198
199
200
205
206
206
207
209
212
213
213
214
216
220
220
221
222
223
226
1022
1029
1070
1124
1115
1150
1159
1160
1206
1245
1261
1289
1299
1395
1375
1411
1434
1491
1492
1515
1514
1563
1624
1637
1655
1689
1745
1740
1774
1794
1882
1909
1910
1921
1978
2034
2017
2016
2047
2117
2144
2145
2171
2217
2237
2250
157
661
784
673
793
126
42
188
671
776
793
692
62
705
766
773
864
183
635
186
696
60
772
652
644
406
656
813
789
642
623
61
668
620
62
638
56
831
11
762
119
39
30
789
407
773
9.5
10.0
10.0
18.5
13.5
12.0
18.0
18.0
17.5
9.8
10.0
16.0
9.8
9.8
20.0
8.0
8.8
8.0
8.2
18.0
18.0
8.0
18.0
8.0
8.0
7.8
10.6
19.0
8.0
9.0
11.0
18.0
9.0
18.0
8.5
7.0
7.0
8.0
19.0
18.0
18.0
7.8
18.0
8.0
8.0
10.0
11.0
11.0
20.0
14.0
14.0
18.0
18.0
17.0
8.0
9.0
18.0
10.0
10.0
20.0
8.0
8.0
9.0
8.0
20.0
20.0
6.0
18.0
9.0
9.0
7.0
13.0
20.0
10.0
10.0
13.0
20.0
19.0
11.0
18.5
10.0
8.0
8.0
9.0
20.0
16.0
18.0
9.0
20.0
9.0
10.0
B
C
A
C
C
C
A
A
0
C
A
D
B
C
B
B
B
B
D
C
A
C
B
C
0
0
B
0
B
0
A
C
0
A
C
D
B
B
C
C
B
C
0
B
C
C
Mean QAO AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.333
0.221
0.208
0.161
0.180
0.115
0.164
0.155
0.236
0.199
0.198
0.166
0.129 0.173
0.329
0.097 0.128
0.101
0.097
0.322
0.116
0.224
0.216
0.958 -.
I
0.281
0.121
0.095
0.248
0.242
0.302
0.183
0.311
0.171
0.186
0.206
0.170
0.191
0.164
0.264
0.310
0.299
0.204
0.207
0.212
0.134 0.175
0.150
0.162
0.547
C-65
-------
TABLE C-22. SUMMARY OF THE 1989 NMOC DATA FOR SACRAMENTO, CA (S3CA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Nuioer (psig) (psig) Channel
IS-Aug-89
16-AU9-89
17-Aufl-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-AU9-89
30-Aug-89
30-Aug-89
31-AU9-89
01-Sep-89
05-Sep-89
06-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
11-Sep-89
14-Sep-89
15-Sep-89
18-Sep-89
19-Sep-89
20-Sep-89
20-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
227
228
229
229
230
233
234
235
235
236
237
240
241
242
242
243
244
248
249
249
250
251
254
257
258
261
262
263
263
269
270
271
272
2269
2296
2346
2347
2320
2371
2435
2439
2438
2459
2477
2497
2544
2540
2539
2551
2596
2616
2658
2657
2701
2693
2778
2827
2837
2870
2887
2891
2892
3047
3033
3066
3068
790
188
672
794
;>#
107
695
49
838
723
778
37
719
678
762
28
301
143
304
35
10
924
64
675
306
671
35
628
728
627
774
71
406
8.8
18.0
18.3
18.3
8.0
8.0
20.0
20.0
20.0
11.0
11.0
20.0
11.0
20.0
20.0
11.5
23.0
12.0
19.0
19.0
20.0
6.0
18.0
20.0
7.0
20.0
7.0
20.0
20.0
14.0
20.0
12.5
12.0
9.0
18.0
20.0
20.0
10.0
8.0
20.0
17.0
19.0
11.0
11.0
19.0
10.0
20.0
20.0
10.5
22.0
11.0
17.0
19.0
1...0
6.0
19.0
20.0
6.0
19.0
6.0
20.0
20.0
15.0
20.0
14.0
15.0
A
D
B
•\
C
c
A
A
B
C
B
C
C
0
0
A
0
D
0
B
C
A
A
0
C
C
0
D
D
D
C
D
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppnic ppmc
0.340
0.111
0.103
0.105
0.178 0.233
0.177
0.092
0.163
0.163
0.128
0.647
0.160
0.075
0.354
0.382
0.986
0.223
2.452 2.434
0.079
0.094
0.600
0.174
1.357
1.046
0.348
0.150
0.374
0.690
0.609
0.392
0.382
0.729
0.297
C-66
-------
O
•t
o
£ *
2 I
03 8
CO 2
8
8
Tt
8
CO
8
cxi
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00
o>
CO
Q
jO
CO
O
CD
2
O
CO
CO
CD
O
O
O
O
O
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Q_
CO
OJ
O
CD
0)
LL
OUJdd -
C-67
-------
TABLE C-23. SUMMARY OF THE 1989 NMOC DATA FOR SACRAMENTO, CA (S4CA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
05-Jun-89
06-Jun-89
07-Jun-89
08-Jun-89
09-Jun-89
12-Jun-89
13-Jun-89
U-Jun-89
14-Jun-89
15-Jun-89
16-Jun-89
19-Jun-89
21-Jun-89
22-Jun-89
23-Jun-89
26-Jun-89
27-Jun-89
28-Jun-89
29-Jun-89
30-Jun-89
05-JUI-89
OS-Jul-89
06-Jul-89
07-Jul-89
10-Jul-89
11-Jul-89
12-Jul-89
13-Jul-89
U-Jut-89
17-Jul-89
19-Jul-89
20-Jul-89
21-Jul-89
24-Jul-89
25-Jul-89
26-Jul-89
26-Jul-89
27-Jul-89
28-Jul-89
31-Jul-89
31-Jul-89
01-Aug-89
02-Aug-89
03-Aug-89
(K-Aug-89
07-Aug-89
156
157
158
159
160
163
164
165
165
166
167
170
172
173
174
177
178
179
180
181
186
186
187
188
191
192
193
194
195
198
200
201
202
205
206
207
207
208
209
212
212
213
214
215
216
219
1024
1023
1064
1142
1154
1130
1169
1192
1191
1221
1239
1265
1315
1338
1364
1391
1412
1481
1483
1500
1531
1532
1567
1584
1626
1644
1672
1721
1715
1743
1791
1814
1856
1873
1892
1929
1930
1947
1977
1990
1989
2031
2050
2070
2136
2138
121
788
870
684
66
860
53
63
148
623
723
91
691
819
677
7
302
726
157
854
626
637
12
718
689
115
692
791
666
108
97
627
929
692
842
64
105
169
75
83
813
79
665
842
406
645
12.0
16.0
16.0
16.0
14.0
15.5
15.5
17.0
17.0
16.0
16.0
16.0
16.5
15.0
16.0
15.0
15.0
16.0
15.5
16.0
18.0
18.0
15.0
16.0
16.0
15.0
16.0
16.0
16.0
15.0
15.0
16.0
16.0
16.0
15.0
17.0
17.0
15.0
16.0
17.0
17.0
15.0
16.0
15.0
16.0
16.0
12.0
18.0
16.0
18.0
12.0
17.0
18.0
18.0
18.0
12.0
17.0
14.0
18.0
17.0
17.0
17.0
17.0
18.0
17.0
16.0
18.0
19.0
15.0
16.0
16.0
18.0
17.0
18.0
18.0
17.0
17.0
15.0
17.0
19.0
17.0
19.0
19.0
17.0
17.0
17.0
19.0
17.0
17.0
16.0
17.0
17.0
A
B
B
B
D
C
C
C
A
D
C
C
D
B
D
B
B
B
8
D
A
C
B
C
D
C
C
B
B
A
D
D
C
A
B
0
D
C
B
0
A
C
C
C
D
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.180
0.154
0.152 0.256
0.125
0.210
0.127 0.135
0.153
0.217
0.205
0.144
0.156
0.114
0.120
0.281
0.182
0.066
0.076
0.064
0.131
0.138
0.244
0.273
0.487
0.591
0.199
0.124
0.081
0.172
0.190
0.202
1.610
0.131 0.200
0.225
0.142
0.176
0.190
0.195
0.327
0.416
0.092
0.101
0.129
0.181
0.274
0.146
0.166
068
-------
TABLE C-23. SUMMARY OF THE 1989 NMOC DATA FOR SACRAMENTO, CA (S4CA)
Sampling Period: 6:00 a.m. to 9:00 a.m.
Julian Sample Sample Sample Analysis
Date Date ID Canister Pressure Pressure Radian
Sampled Sampled Number Number (psig) (psig) Channel
08-Aug-89
09-Aug-89
10-Aug-89
11-Aug-89
U-Aug-89
U-Aug-89
15-Aug-89
16-Aug-89
17-Aug-89
18-Aug-89
21-Aug-89
22-Aug-89
23-Aug-89
24-Aug-89
25-Aug-89
28-Aug-89
29-Aug-89
30-Aug-89
31-Aug-89
31-Aug-89
01-Sep-89
05-Sep-89
06-Sep-89
07-Sep-89
08-Sep-89
12-Sep-89
13-Sep-89
H-Sep-89
15-Sep-89
15-Sep-89
18-Sep-89
20-Sep-89
21-Sep-89
22-Sep-89
22-Sep-89
25-Sep-89
26-Sep-89
27-Sep-89
28-Sep-89
29-Sep-89
220
221
222
223
226
226
227
228
229
230
233
234
235
236
237
240
241
242
243
243
244
248
249
250
251
255
256
257
258
258
261
263
264
265
265
268
269
270
271
272
2158
2181
2210
2233
2262
2261
2291
2302
2356
2368
2374
2421
2431
2464
2472
2491
2509
2552
2577
2578
2611
2650
2667
2694
2714
2764
2798
2817
2838
2839
2865
2925
2947
2956
2955
2998
3007
3036
3078
3100
155
305
778
643
106
772
104
122
62
775
21
90
657
696
801
823
171
5U1
197
683
720
715
646
632
673
925
74
105
155
914
122
833
850
646
137
53
302
99
15.0
15.0
16.0
16.0
17.0
17.0
15.0
15.0
15.0
16.0
16.0
16.0
16.0
16.0
16.0
15.0
15.0
18.0
18.0
15.0
16.0
16.0
16.0
16.0
16.0
16.0
16.0
17.0
17.0
16.0
16.0
16.0
17.0
17.0
16.0
16.0
16. a
16.0
15.0
17.0
16.0
18.0
14.0
19.0
19.0
17.0
14.0
15.0
18. C
17
1;
18. „
18.0
18.0
14.0
18.0
16.5
17.0
17.0
16.0
18.0
18.0
18.0
18.0
17.0
18.0
16.0
18.0
18.0
9.0
17.0
17.0
18.0
18.0
18.0
16.0
17.0
18.0
18.0
C
C
D
D
D
A
D
A
A
A
A
B
C
C
C
D
D
D
C
B
C
B
B
C
D
B
B
D
D
B
B
A
B
B
A
A
C
Mean QAD AREAL
NMOC NMOC NMOC
ppmC ppmc ppmc
0.239
0.139
" 1C
.6
0.552
0.571
0.362
0.165
0.072
0.122
0.093
0.072
0.106
0.139
0.414
0.178
0.062
0.139
0.364
0.199
0.310
0.233
0.109
0.213
0.203
0.277
0.700
1.098
0.313
0.306
0.103
0.336
0.967
1.510
1.534
0.166
0.211
0.155
0.596
0.248
C-69
-------
V..
-------
-------
APPENDIX D
1989 NMOC MONITORING PROGRAM
INVALIDATED AND MISSING SAMPLES
-------
I "
-------
APPENDIX D
1989 NMOC PROGRAM
VOID OR INVALIDATED SAMPLES - CHRONOLOGIAL
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
Site
S2MO
M1NY
C3IL
MNY
MNY
MNY
H1TX
RSCA
RSCA
RSCA
RSCA
BACA
MGAL
RSCA
GRMI
BACA
RSCA
S3CA
MGAL
MNY
MGAL
S2MO
RSCA
S4CA
RSCA
M1NY
S3CA
C3IL
PLNJ
PLNJ
LBCA
PLNJ
NWNJ
ELCA
S4CA
S3CA
C6IL
ELCA
H1TX
S3CA
C6IL
ALCA
C3IL
BACA
H1TX
ELCA
GRMI
Date
06/05/89
06/05/89
06/06/89
06/06/89
06/08/89
06/06/89
06/05/89
06/09/89
06/12/89
06/12/89
06/13/89
06/14/89
06/15/89
06/15/89
06/16/89
06/15/89
06/16/89
06/09/89
06/23/89
06/28/89
06/26/89
06/30/89
06/30/89
07/03/89
07/03/89
07/06/89
07/07/89
07/06/89
07/07/89
07/06/89
07/12/89
07/13/89
07/17/89
07/18/89
07/18/89
07/19/89
07/20/89
07/21/89
07/25/89
07/27/89
07/25/89
07/27/89
07/25/89
07/25/89
07/31/89
08/01/89
07/27/89
Description
Canister leak
Solenoid failure
Pump not connected to system
Leak in system
Leak in system
Leak in system
Pressure too high
Bad fitting on pump
Bad fitting on pump
Bad fitting on pump
Bad fitting on pump
Defective orifice
Power outage
Bad fitting on pump
Sampled room air
Collection missed
Bad fitting on pump
Wrong orifice used
Sampled room air
No pressure
Pump malfunction
Pump malfunction
No pressure
Timer misprogrammed
Canister valve not opened
Canister valve not opened
Sampled room air
Defective orifice
Double collection
Double collection
Timer left in manual mode
No pressure
Unknown
Canister valve not opened
Timer misprogrammed
Orifice improperly installed
Timer in manual mode
Defective orifice
No pressure
Canister valve not opened
Collection missed
Rotameter improperly installed
Collection missed
Unknown
Canister valve not opened
Canister valve not opened
No pressure
Assigned
Canister
Equipment
Operator
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Equipment
Operator
Operator
Equipment
Operator
Operator
Canister
Equipment
Equipment
Canister
Operator
Operator
Operator
Operator
Equipment
Operator
Operator
Operator
Canister
Unknown
Operator
Operator
Operator
Operator
Equipment
Canister
Operator
Operator
Operator
Operator
Unknown
Operator
Operator
Equipment
D-l
-------
APPENDIX D
1989 NMOC PROGRAM
VOID OR INVALIDATED SAMPLES - CHRONOLOGIAL
#
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
Site
H1TX
S3CA
S3CA
NWNJ
H1TX
RLNC
H1TX
ELCA
BMTX
BACA
BACA
FECA
BACA
BACA
GRMI
H1TX
FECA
FECA
C6IL
S3CA
S3CA
M1NY
C3IL
C3IL
C6IL
C6IL
C6IL
S4CA
BACA
C6IL
S3CA
S2MO
S3CA
S3CA
FECA
PLNJ
BMTX
MGAL
MGAL
Date
08/02/89
08/03/89
08/07/89
08/07/89
08/08/89
08/10/89
08/09/89
08/29/89
08/24/89
08/29/89
08/30/89
08/15/89
08/14/89
08/11/89
08/18/89
09/06/89
09/11/89
09/12/89
09/13/89
09/13/89
09/13/89
09/15/89
09/15/89
09/15/89
09/15/89
09/15/89
09/18/89
09/19/89
09/19/89
09/19/89
09/22/89
09/21/89
09/21/89
09/25/89
09/25/89
09/25/89
09/28/89
09/26/89
09/27/89
Description
No pressure
Timer in manual mode
Canister not connected
Power outage
No pressure
Final pressure to high
Final pressure to high
Timer misprogrammed
Cracked fitting
Defective orifice
Canister not connected
Sampled room air
Timer malfunction
Canister valve not opened
Canister valve not opened
Power outage
Timer misprogrammed
Timer in manual mode
Canister valve not opened
Unknown
Unknown
Power outage
Duplicate orifice not used
Duplicate orifice not used
Duplicate orifice not used
Duplicate orifice not used
Canister valve not opened
No pressure
No pressure
Canister valve not opened
Oriface cleaned with alcohol
Stripped thread on canister valve
Oriface cleaned with alcohol
Oriface cleaned with alcohol
No pressure
Power outage
Defective fitting
Double collection
Double collection
Assigned
Equipment
Operator
Operator
Equipment
Operator
Equipment
Equipment
Operator
Canister
Equipment
Operator
Operator
Operator
Operator
Operator
Equipment
Operator
Operator
Operator
Unknown
Unknown
Equipment
Operator
Operator
Operator
Operator
Operator
Canister
Canister
Operator
Operator
Canister
Operator
Operator
Operator
Equi •iient
Equipment
Operator
Operator
D-2
-------
APPENDIX E
PDFID INTEGRATOR PROGRAMMING INSTRUCTIONS
/•
-------
-------
INTEGRATOR PROGRAMMING INSTRUCTIONS
Instructions for programming the integrators are as foljows,
Be sure to press ENTER after each key sequence.
Control Integrator
Oven Temp 90
Oven Temp Limit 405
Oven Temp ON
Oven Temp OFF
List Oven Temp
(A listing should say OvenTemp X°C Setpt 90°C Limit 405°C)
Oven Temp Initial Time 0.20
Oven Temp Initial Value 90
Oven Temp Pgrm Rate 30.00
Oven Temp Final Value 90.00
Oven Temp Final Time 4.00
Oven Temp Equil Time 1.00
Detector A ON
Signal A
Chart speed 4.00
%0ffset 10
Zero
Attn 2A 4
Run Time Annotation ON
Run Table Annotation ON
Clock Table Annotation OFF
Program Annotation OFF
Oven Temp Annotation OFF
Report Annotation OFF
Slave Integrator
Detector 8 ON
Signal B
Chart speed 4.00
%0ffset 10
Zero
Attn 2A 4
Run Time Annotation ON
Run Table Annotation ON
Clock Table Annotation OFF
Program Annotation OFF
Oven Temp Annotation OFF
(should say ***Warning***Oven Temp now owned by Chnl 2)
Report Annotation OFF
E-l
-------
INTEGRATOR PROGRAMMING INSTRUCTIONS (Continued)
Control Integrator
Oven Temp Annotation OFF
(should say ***Warning***Oven Temp now owned by Chnl 1)
Run Time 0.01 Intg OFF
Run Time 0.01 Valve 5 ON
Run Time 0.01 Page
Run Time 0.02 List Attn2A
Run Time 0.04 Oven Temp ON
Run Time 0.20 Valve 2 ON
Run Time 0.21 Valve 2 OFF
Run Time 0.22 Intg ON
Run Time 0.23 Set BL
Run Time 0.23 List Intg
Rum Time 1.87 Set BL
Run Time 1.88 Intg OFF
Run Time 1.89 List Intg
Run Time 1.90 Chart Spped 1.5
Run Time 3.44 Valve 2 ON
Run Time 3.45 Valve 2 OFF
Run Time 3.46 Valve 2 ON
Run Time 3.47 Valve 2 OFF
Run Time 3.48 Valve 2 ON
Run Time 3.49 Valve 2 OFF
Run Time 3.50 STOP
Slave Integrator
Run Time 0.01 Intg OFF
Run Time 0.01 Page
Run Time 0.02 List Attn2A
Run Time 0.22 Intg ON
Run Time 0.23 Set BL
Run Time 0.23 List Intg
Rum Time 1.87 Set BL
Run Time 1.88 Intg OFF
Run Time 1.89 List Intg
Run Time 1.90 Chart Spped 1.5
Run Time 3.50 STOP
Control Integrator
Det 1 Temp 250
Det 1 Temp Limit 405
Inj 1 Temp 31
Inj 1 Temp Limit 405
Aux 1 Temp 90
Aux 1 Temp Limit 405
Flow A 30
Flow A Limit 500
E-2
-------
INTEGRATOR PROGRAMMING INSTRUCTIONS (Continued)
Slave Integrator
Flow B 30
Flow B Limit 500
Control Integrator
Valve 1 OFF
Valve 2 OFF
Valve 3 OFF
Valve 4 OFF
Valve 5 ON
Valve 6 OFF
Valve 7 OFF
Valve 8 OFF
Valve 9 OFF
Valve 10 OFF
Valve 11 OFF
Valve 12 OFF
Threshold 1
Peak Width 0.04
Slave Integrator
Threshold 1
Peak Width 0.04
Control Integrator
20 Valve 5 OFF
25 List Valve 5
30 Oven Temp Initial Value 30
35 Oven Temp OFF
40 Wait 2
60 Start
70 Oven Temp 90
80 Vale 5 ON
Sync ON
E-3
-------
-•*
-------
APPENDIX F
1989 NMOC DAILY CALIBRATION DATA
-------
f
-------
TABLE F-l. DAILY CALIBRATION DATA SUMMARY (CHANNEL A)
Julian
Cal Cal
Date Date
06/05/89
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/13/89
06/14/89
06/15/89
06/16/89
06/19/89
06/20/89
06/21/89
06/22/89
06/23/89
06/26/89
06/27/89
06/28/89
06/29/89
06/30/89
07/03/89
07/05/89
07/06/89
07/07/89
07/10/89
07/11/89
07/12/89
07/13/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/25/89
07/26/89
07/27/89
07/28/89
07/31/89
08/01/89
08/02/89
156
157
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
209
212
213
214
Intial
Zero
A.C.
10.900
10.615
2.935
14.190
10.275
5.070
3.995
5.985
4.860
9.130
5.070
8.210
7.725
2.275
6.410
7.850
4.670
4.140
4.560
7.510
5.380
6.295
5.250
4.215
5.925
7.380
4.455
3.410
6.090
0.000
4.550
4.685
4.250
2.950
5.275
6.325
2.800
3.660
3.430
3.885
4.015
5.575
Final
Zero
A.C.
10.900
10.615
10.930
6.055
10.000
5.070
6.170
9.890
4.335
9.130
7.480
8.875
7.725
10.215
6.410
3.765
4.565
4.140
3.090
6.325
0.000
4.485
3.910
6.250
5.950
7.380
0.000
3.410
5.655
0.000
4.390
7.490
3.590
7.275
5.225
4.930
11.280
4.245
3.430
3.645
7.330
10.705
Initial
Zero
ppmC
0.003284
0.003226
0.000889
0.004325
0.003107
0.001551
0.001212
0.001825
0.001489
0.002809
0.001535
0.002487
0.002309
0.000686
0.001923
0.002361
0.001389
0.001240
0.001364
0.002264
0.001608
0.001865
0.001546
0.001238
0.001742
0.002169
0.001305
0.000997
0.001783
0.000000
0.001332
0.001370
0.001244
0.000865
0.001546
0.001856
0.000819
0.001072
0.001021
0.001157
0.001204
0.001674
Final
Zero
ppmC
0.003284
0.003226
0.003290
0.001844
0.003037
0.001551
0.001878
0.003049
0.001333
0.002809
0.002268
0.002691
0.002334
0.003079
0.001923
0.001128
0.001388
0.001240
0.000932
0.001909
0.000000
0.001317
0.001149
0.001838
0.001759
0.002193
0.000000
0.000997
0.001670
0.000000
0.001286
0.002217
0.001061
0.002148
0.001542
0.001473
0.003320
0.001259
0.001021
0.001090
0.002196
0.003173
Initial
Cal
Factor
0.000301
0.000304
0.000303
0.000305
0.000302
0.000306
0.000303
0.000305
0.000306
0.000308
0.000303
0.000303
0.000299
0.000302
0.000300
0.000301
0.000297
0.000300
0.000299
0.000302
0.000299
0.000296
0.000294
0.000294
0.000294
0.000294
0.000293
0.000292
0.000293
0.000293
0.000293
0.000293
0.000293
0.000293
0.000293
0.000293
0.000292
0.000293
0.000298
0.000298
0.000300
0.000300
Final
Cal
Factor
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000301
.000304
. 000301
.000304
.000304
.000306
.000304
.000308
.000307
.000308
.000303
.000303
. 000302
.000301
.000300
.000300
.000304
.000300
.000302
.000302
.000298
. 000294
.000294
.000294
.000296
.000297
.000295
.000292
.000295
.000291
.000293
.000296
.000296
.000295
0.000295
0
0
0
0
0
0
0
. 000299
.000294
.000297
.000298
.000299
.000300
.000296
Cal
Factor
Drift
0
0
0
0
-0
0
-0
-0
-0
0
-0
-0
-0
0
0
0
-0
0
-0
-0
0
0
0
-0
-0
-0
-0
0
-0
0
0
-0
-0
-0
-0
-0
-0
-0
0
-0
0
0
.000000
.000000
.000002
.000000
.000001
.000000
.000001
.000003
.000001
.000000
.000000
. 000000
.000003
.000000
.000000
.000001
.000007
.000000
.000003
.000000
.000001
.000003
. 000001
.000000
.000002
.000003
.000002
.000000
. 000003
. 000001
.000000
. 000003
.000003
.000002
.000002
.000005
.000002
.000004
.000000
.000001
.000000
.000004
Cal
Factor
X Drift
0.000000
0.000000
0.561268
0.097962
-0.435600
0.000000
-0.341099
-1.088544
-0.329681
0.000000
-0.129774
-0.080692
-1.110452
0.105912
0.000000
0.360888
-2.194403
0.000000
-0.867026
-0.108887
0.435590
0.846345
0.244776
-0.162985
-0.553429
-1.099212
-0.714895
0.000000
-0.891716
0.459737
0.001611
-1.195837
-0.998934
-0.669453
-0.696826
-1.802933
-0.671883
-1.255266
0.000000
-0.430754
0.086014
1.273258
F-l
-------
TABLE F-l. DAILY CALIBRATION DATA SUMMARY (CHANNEL A)
Julian
Cal Cal
Date Date
08/03/89
08/04/89
08/07/89
08/08/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/16/89
08/17/89
08/18/89
08/21/89
08/22/89
08/23/89
08/24/89
08/25/89
08/28/89
08/29/89
08/30/89
08/31/89
09/01/89
09/05/89
09/06/89
09/07/89
09/08/89
09/11/89
09/12/89
09/13/89
09/14/89
09/15/89
09/18/89
09/19/89
09/20/89
09/21/89
09/22/89
09/25/89
09/26/89
09/27/89
09/28/89
09/29/89
10/02/89
215
216
219
220
221
222
223
226
227
228
229
230
233
234
235
236
237
240
241
242
243
244
248
249
250
251
254
255
256
257
258
261
262
263
264
265
268
269
270
271
272
275
Intlal
Zero
A.C.
4.460
5.820
3.090
4.975
0.785
2.325
3.325
0.000
0.000
3.930
3.600
3.900
4.770
5.250
13.950
3.855
3.250
2.670
4.535
3.750
2.195
3.620
2.740
2.880
3.615
4.350
5.050
4.770
4.880
3.700
2.675
2.150
3.620
5.835
4.135
3.440
4.205
3.530
2.520
4.890
3.475
3.795
Final
Zero
A.C.
5.645
0.690
3.980
0.000
8.595
7.900
12.075
9.525
4.165
5.585
7.395
5.480
4.580
8.670
11.420
4.915
0.000
0.000
4.835
3.750
1.990
3.620
6.005
15.565
0.000
4.350
5.050
3.965
4.775
3.700
5.630
0.000
5.835
3.345
0.000
3.440
4.205
3.530
0.000
4.890
3.475
3.795
Initial
Zero
ppnC
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
001325
001701
000898
001444
000230
000680
000972
000000
000000
001154
001055
001154
001423
001533
004193
001136
000962
000798
001325
001118
000645
001064
000808
000853
001061
0.001287
0.001485
0.001394
0.001431
0.001084
0.000785
0.000624
0.001048
0.001694
0.001192
0.000990
0.001208
0.001022
0.000734
0.001415
0
0
.001010
.001092
Final
Zero
ppmC
0.001680
0.000201
0.001165
0.000000
0.002524
0.002402
0.003500
0.002793
0.001223
0.001647
0.002199
0.001647
0.001349
0.002575
0.003404
0.001492
0.000000
0.000000
0.001434
0.001118
0.000593
0.001064
0.001783
0.004587
0.000000
0.001287
0.001485
0.001170
0.001407
0.001084
0.001645
0,000000
0.001694
0.000968
0.000000
0.000990
0.001208
0.001022
0.000000
0.001415
0.001010
0.001092
Initial
Cal
Factor
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000297
000292
000291
000290
000293
000293
000292
000291
000291
000294
000293
000296
000298
000292
000301
000295
000296
000299
000292
000298
000294
000294
000295
,000296
,000294
0.000296
0.
,000294
0.000292
0.000293
0.000293
0.000293
0.000290
0.000290
0.000290
0.000288
0
.000288
0.000287
0
0
0
0
0
.000290
.000291
.000289
.000291
.000288
Final
Cal
Factor
0.000298
0.000291
0.000293
0.000295
0.000294
0.000304
0.000290
0.000293
0.000294
0.000295
0.000297
0.000301
0.000295
0.000297
0.000298
0.000303
0.000297
0.000295
0.000297
0.000298
0.000298
0.000294
0.000297
0.000295
0.000296
0.000296
0.000294
0.000295
0.000295
0.000293
0.000292
0.000292
0.000290
0.000289
0.000292
0.000288
0.000287
0.000290
0.000295
0.000289
0.000291
0.000288
Cal
Factor
Drift
-0.000001
0.000002
-0.000002
-0.000005
-0.000000
•-0. 00001 2
0.000003
-0.000002
-•0.000003
-•0.000001
-0.000004
-0.000005
0.000004
-0.000005
0.000002
-0.000009
-0.000001
0.000004
-0.000004
0.000000
-0.000004
0.000000
-0.000002
0.000001
-0.000003
0.000000
0.000000
-0.000003
-0.000001
0.000000
0.000001
-0.000002
-0.000001
0.000001
-0.000004
0.000000
0.000000
0.000000
-0.000003
0.000000
0.000000
G . 000000
Cal
Factor
% Drift
-0.188203
0.581712
-0.666674
-1.633820
-0.059249
-3.960407
0.875000
-0.698089
-0.957405
-0.395674
-1.474376
-1.541833
1.280209
-1.739579
0.828477
-2.989675
-0.464852
1.416399
-1.516439
0.000000
-1.501712
0.000000
-0.634905
0.495894
-0.931626
0.000000
0.000000
-0.981665
-0.475028
0.000000
0.437559
-0.687442
-0.279998
0.381854
-1.402463
0.000000
0.000000
0.000000
-1.165454
0.000000
0.000000
0.000000
F-2
-------
TABLE F-l. DAILY CALIBRATION DATA SUMMARY (CHANNEL A)
Cal
Date
10/03/89
10/04/89
Julian
Cal
Date
276
277
Intial
Zero
A.C.
3.490
2.360
Final
Zero
A.C.
0.000
2.360
Initial
Zero
ppmC
0.001011
0.000680
Final
Zero
ppmC
0.000000
0.000680
Initial
Cal
Factor
0
0
.000290
.000288
0
0
Final
Cal
Factor
.000291
.000288
Cal
Factor
Drift
-0.000002
0.000000
Cal
Factor
% Drift
-0.595562
0.000000
F-3
-------
TABLE F-2. DAILY CALIBRATION DATA SUMMARY (CHANNEL B)
Julian
Cal Cal
Date Date
06/05/89
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/13/89
06/14/89
06/15/89
06/16/89
06/19/89
06/20/89
06/21/89
06/22/89
06/23/89
06/26/89
06/27/89
06/28/89
06/29/89
06/30/89
07/03/89
07/05/89
07/06/89
07/07/89
07/10/89
07/11/89
07/12/89
07/13/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/25/89
07/26/89
07/27/89
07/28/89
07/31/89
08/01/89
08/02/89
156
157
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
209
212
213
214
Intial
Zero
A.C.
0.000
0.000
0.000
0.000
0.525
1.540
0.000
0.000
0.000
0.000
0.000
0.865
0.315
2.800
1.285
0.120
0.000
0.000
0.000
8.245
1.775
0.000
0.000
0.000
2.875
0.000
0.450
1.630
0.000
1.520
0.000
1.820
0.000
1.310
0.940
0.000
0.000
0.935
1.025
0.000
1.365
0.000
Final
Zero
A.C.
0.000
0.000
1.480
0.000
0.000
1.540
0.000
0.000
0.000
0.000
0.000
2.175
0.315
5.910
1.285
0.000
0.000
0.000
0.000
7.635
0.000
0.000
0.000
0.000
5.750
0.000
0.000
1.630
0.000
0.000
0.000
3.235
1.890
1.515
2.375
0.000
0.000
0.000
1.025
0.000
3.160
2.675
Initial
Zero
ppmC
0.000000
0.000000
0.000000
0.000000
0.000162
0.000477
0.000000
0.000000
0.000000
0.000000
0.000188
0.000270
0.000097
0.000000
0.000397
0.000037
0.000000
0.000000
0.000000
0.001848
0.000546
0.000000
0.000000
0.000000
0.000000
0.000000
0.000137
0.000497
0.000000
0.000932
0.000000
0.000553
0.000000
0.000398
0.000288
0.000000
0.000000
0.000285
0.000316
0.000000
0.000420
0.000000
Final
Zero
ppmC
0.000000
0.000000
0.000452
0.000000
0.000000
0.000477
0.000000
0.000000
0.000000
0.000000
0.000000
0.000681
0.000098
0.001837
0.000397
0.000000
0.000000
0.000000
0.000000
0.002377
0.000000
0.000000
0.000000
0.000000
0.001747
0.000000
0.000000
0.000497
0.000000
0.000000
0.000000
0.000987
0.000579
0.000464
0.000725
0.000000
0.000000
0.000000
0.000316
0.000000
0.000973
0.000827
Initial
Cal
Factor
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
.000305
.000305
.000305
.000310
.000308
.000309
.000309
.000311
.000309
.000311
.000313
.000313
.000309
.000310
.000309
.000308
.000309
.000309
.000309
.000310
.000307
.000307
.000304
.000305
.000304
.000305
.000305
.000305
.000302
.000303
.000303
.000304
.000303
.000304
.000306
.000305
.000303
.000304
.000308
.000307
.000307
.000309
Final
Cal
Factor
0.000305
0.000305
0.000305
0.000311
0.000308
0.000309
0.000310
0.000309
0.000310
0.000311
0.000312
0.000313
0.000312
0.000311
0.000309
0.000310
0.000314
0.000309
0.000311
0.000311
0.000308
0.000304
0.000302
0.000304
0.000304
0.000308
0.000307
0.000305
0.000303
0.000305
0.000303
0.000305
0.000306
0.000307
0.000305
0.000307
0.000306
0.000307
0.000308
0.000309
0.000308
0.000309
Cal
Factor
Dri ft
0.
0.
-0.
-0.
0.
0.
-0.
0.
-0.
0.
0.
-0.
-0.
-0.
0.
-0.
-0.
0.
-0.
-0.
-0.
0.
0.
0.
0.
-0.
-0.
0.
-0.
-0.
0.
-0.
-0.
000000
000000
000000
000001
000000
000000
000002
000001
000001
000000
000001
000001
000003
000000
000000
000002
000005
000000
000002
000001
000000
000003
000002
000000
000000
000003
000002
000000
000001
000002
000000
000002
000003
-0.000003
0.
-0.
-0.
-0.
0.
-0.
-0.
-0.
000001
000002
000003
000003
000000
000002
000001
000000
Cal
Factor
% Drift
0.000000
0.000000
-0.032930
-0.267073
0.005440
0.000000
-0.587934
0.467012
-0.202326
0.000000
0.409948
-0.249473
-1.066989
-0.114349
0.000000
-0.681143
-1.520471
0.000000
-0.686530
-0.420167
-0.146081
0.888594
0.597033
0.052633
0.059573
-0.828714
-0.726438
0.000000
-0.454025
-0.770036
0.000000
-0.526010
-0.895876
-0.996205
0.226881
-0.516808
-1.023768
-0.831039
0.000000
-0.594243
-0.176448
-0.060981
F-4
-------
TABLE F-2. DAILY CALIBRATION DATA SUMMARY (CHANNEL 8)
Julian Intial
Cal Cal Zero
Date Date A.C.
08/03/89
08/04/89
08/07/89
08/08/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/16/89
08/17/89
08/18/89
08/21/89
08/22/89
08/23/89
08/24/89
08/25/89
08/28/89
08/29/89
08/30/89
08/31/89
09/01/89
09/05/89
09/06/89
09/07/89
09/08/89
09/11/89
09/12/89
09/13/89
09/14/89
09/15/89
09/18/89
09/19/89
09/20/89
09/21/89
09/22/89
09/25/89
09/26/89
09/27/89
09/28/89
09/29/89
10/02/89
215
216
219
220
221
222
223
226
227
228
229
230
233
234
235
236
237
240
241
242
243
244
248
249
250
251
254
255
256
257
258
261
262
263
264
265
268
269
270
271
272
275
0.000
0.000
0.000
1.640
0.000
0.375
0.910
0.000
0.000
0.000
0.905
0.000
0.000
0.825
3.055
0.000
0.000
0.585
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.870
0.000
0.000
3.825
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Final
Zero
A.C.
0.000
0.000
2.735
1.640
0.000
0.000
2.440
0.000
0.000
0.000
4.405
0.000
2.225
1.855
5.540
0.000
0.595
0.000
2.030
0.000
0.000
0.000
2.000
2.530
0.000
0.870
0.000
0.000
5.335
0.000
0.905
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Initial
Zero
ppmC
0.000000
0.000000
0.000000
0.000000
0.000000
0.000113
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000190
0.000424
0.000000
0.000000
0.000604
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000264
0.000000
O.OOOQQO
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
Final
Zero
ppmC
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000000
000000
000830
000498
000000
000000
000734
000000
000000
000000
001328
000000
000686
000571
001695
000000
000183
000000
000619
000000
000000
000000
000612
0.000779
0.000000
0.
000264
0.000000
0.000000
0.001624
0.000000
0.000277
0.000000
0.000000
0.000000
0.000000
0
.000000
0.000000
0
0
0
0
0
.000000
.000000
.000000
.000000
. 000000
Initial
Cal
Factor
0.000308
0.000305
0.000301
0.000299
0.000301
0.000301
0.000301
0.000302
0.000301
0.000301
0.000302
0.000298
0.000304
0.000303
0.000304
0.000303
0.000310
0.000304
0.000305
0.000304
0.000304
0.000303
0.000305
0.000304
0.000304
0.000304
0.000304
0.000304
0.000303
0.000303
0.000303
0.000299
0.000299
0.000298
0.000299
0.000299
0.000298
0.000301
0.000304
0.000300
0.000300
0.000297
Final
Cal
Factor
0.000309
0.000302
0.000303
0.000304
0.000304
0.000302
0.000301
0.000303
0.000306
0.000302
0.000302
0.000297
0.000308
0.000308
0.000306
0.000314
0.000308
0.000308
0.000305
0.000304
0.000303
C ^00303
0.; 30306
0.000308
0.000304
0.000304
0.000304
0.000306
0.000304
0.000303
0.000306
0.000299
0.000298
0.000301
0.000300
0.000299
0.000298
0.000301
0.000303
0.000300
0.000300
0.000297
Cal
Factor
Drift
-0.
0.
-0.
-0.
-0.
-0.
0.
-0.
-0.
-0.
0.
000001
000003
000003
000005
000003
000001
000000
000002
000005
000001
000001
0.000001
-0.
-0.
-0.
-0.
0.
000004
000005
000002
000011
,000001
-0.000004
-0.
0.
0.
0.
-0.
-0.
-0.
0,
0.
-0
••0,
,000000
,000000
,000001
, 000000
.000001
, 000004
.000000
,000000
.000000
.000002
.000001
0.000000
-0.
0
0
-0
-•0
0
0
0
0
0
0
0
. 000003
.000000
.000002
.000003
.000001
.000000
.000000
.000000
.000001
.000000
.000000
.000000
Cal
Factor
X Drift
-0.220733
0.925512
-0.883351
-1.553606
-1.011834
-0.327116
0.102413
-0.646297
-1.596068
-0.365781
0.231768
0.330627
-1.447874
-1.499200
-0.695325
-3.600472
0.408081
-1.190001
-0.061877
0.000000
0.213428
0.000000
-0.320421
-1.166536
-0.031004
0.000000
0.000000
-0.648759
-0.384231
0.000000
-1.078605
0.099762
0.503915
-1.115485
-0.302059
0.000000
0. 000000
0.000000
0.294636
0.000000
0.000000
0.000000
F-5
-------
TABLE F-2. DAILY CALIBRATION DATA SUMMARY (CHANNEL B)
Cal
Date
10/03/89
10/04/89
Julian
Cal
Date
276
277
Intial
Zero
A.C.
0.000
0.000
Final
Zero
A.C.
0.000
0.000
Initial
Zero
ppmC
0.000000
0.000000
Final
Zero
ppmC
0.000000
0.000000
Initial
Cal
Factor
0
0
.000297
.000299
0
0
Final
Cal
Factor
.000301
.000299
Cal
Factor
Drift
-0.000004
0.000000
Cal
Factor
X Drift
-1.253519
0.000000
F-6
-------
TABLE F-3. DAILY CALIBRATION DATA SUMMARY (CHANNEL C)
Julian
Cal Cal
Date Date
06/05/89
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/13/89
06/14/89
06/15/89
06/16/89
06/19/89
06/20/89
06/21/89
06/22/89
06/23/89
06/26/89
06/27/89
06/28/89
06/29/89
06/30/89
07/03/89
07/05/89
07/06/89
07/07/89
07/10/89
07/11/89
07/12/89
07/13/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/25/89
07/26/89
07/27/89
07/28/89
07/31/89
08/01/89
08/02/89
156
157
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
209
212
213
214
Intial
Zero
A.C.
0.000
0.000
0.925
0.000
0.000
6.510
0.000
2.075
0.000
0.000
0.720
0.000
0.000
0.000
0.000
1.880
0.-000
7.075
1.855
10.560
0.310
3.495
0.380
1.315
0.000
0.000
0.730
0.000
0.000
1.225
0.000
0.000
0.000
1.235
0.950
0.865
1.395
0.000
0.000
0.000
0.000
0.000
Final
Zero
A.C.
0.000
0.000
0.000
0.865
0.000
6.510
0.000
0.000
0.000
0.000
0.000
4.880
0.000
1.765
0.000
0.000
0.000
7.075
3.505
0.000
0.000
4.735
0.000
0.340
8.300
0.000
0.000
0.000
0.855
4.970
0.000
0.000
0.000
0.000
3.830
3.895
4.095
2.250
0.000
0.000
1.420
0.000
Initial
Zero
ppmC
0.000000
0.000000
0.000287
0.000000
0.000000
0.002016
0.000000
0.000643
0.000000
0.000000
0.000224
0.000000
0.000000
0.000000
0.000000
0.000581
0.000000
0.002196
0.000573
0.003310
0.000096
0.001076
0.000117
0.000400
0.000000
0.000000
0.000222
0.000000
0.000000
0.000372
0.000000
0.000000
0.000000
0.000377
0.000288
0.000265
0.000426
0.000000
0.000000
0.000000
0.000000
0.000000
Final
Zero
ppmC
0.000000
0.000000
0.000000
0.000267
0.000000
0.002016
0.000000
0.000000
0.000000
0.000000
0.000000
0.001519
0.000000
0.000549
0.000000
0.000000
0.000000
0.002196
0.001093
0.000000
0.000000
0.001456
0.000000
0.000104
0.002556
0.000000
0.000000
0.000000
0.000262
0.001526
0.000000
0.000000
0.000000
0.000000
0.001166
0.001192
0.001256
0.000682
0.000000
0.000000
0.000436
0.000000
Initial
Cal
Factor
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000307
000303
000310
000305
000309
000310
000309
000310
000309
000309
000311
000311
000311
000311
000311
000309
000307
000310
000309
000313
000311
000308
000307
000304
000305
000307
000304
000303
000305
000304
000301
000306
000306
000305
000303
000307
000305
000305
000310
000310
000310
000310
Final
Cal
Factor
0.000307
0.000303
0.000306
0.000309
0.000308
0.000310
0.000309
0.000311
0.000313
0.000309
0.000311
0.000311
0.000311
0.000311
0.000311
0.000311
0.000309
0.000310
0.000312
0.000315
0.000309
0.000307
0.000307
0.000306
0.000308
0.000306
0.000306
0.000303
0.000306
0.000307
0.000301
0.000306
0.000307
0.000307
0.000305
0.000306
0.000307
0.000303
0.000310
0.000311
0.000307
0.000312
Cal
Factor
Drift
0
0
0
-0
0
0
-0
-0
-0
0
0
-0
-0
0
0
-0
-0
0
-0
-0
0
0
-0
-0
-0
0
-0
0
-0
-0
0
-0
-0
-0
-0
0
-0
0
0
-0
0
-0
.000000
.000000
.000004
.000005
.000000
.000000
.000000
.000001
.000004
. 000000
.000001
.000001
.000000
.000000
.000000
.000002
.000001
.000000
.000003
.000001
.000002
.000000
.000000
.000002
.000003
.000001
.000002
.000000
.000001
.000003
.000000
.000000
.000001
.000002
.000001
.000001
.000001
.000002
.000000
.000001
.000003
.000002
Cal
Factor
% Drift
0.000000
0.000000
1.162502
-1.523787
0.112705
0.000000
-0.108095
-0.300575
-1.397509
0.000000
0.227065
-0.210027
-0.003374
0.014707
0.000000
-0.666836
-0.470070
0.000000
-1.009925
-0.360721
0.620594
0.137097
-0.037251
-0.593701
-0.922116
0.226307
-0.614882
0.000000
-0.459346
-1.127941
0.000000
-0.002155
-0.258112
-0.705133
-0.400412
0.214445
-0.488261
0.641400
0.002075
-0.455049
0.889591
-0.720842
F-7
-------
TABLE F-3. DAILY CALIBRATION DATA SUMMARY (CHANNEL C)
Julian
Cal Cal
Date Date
08/03/89
08/04/89
08/06/89
08/07/89
08/08/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/16/89
08/17/89
08/18/89
08/21/89
08/22/89
08/23/89
08/24/89
08/25/89
08/28/89
08/29/89
08/30/89
08/31/89
09/01/89
09/05/89
09/06/89
09/07/89
09/08/89
09/11/89
09/12/89
09/13/89
09/14/89
09/15/89
09/18/89
09/19/89
09/20/89
09/21/89
09/22/89
09/24/89
09/25/89
09/26/89
09/27/89
09/28/89
215
216
218
219
220
221
222
223
226
227
228
229
230
233
234
235
236
237
240
241
242
243
244
248
249
250
251
254
255
256
257
258
261
262
263
264
265
267
268
269
270
271
Intial
Zero
A.C.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.395
0.000
0.000
3.885
0.000
0.000
0.605
0.000
3.445
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Final
Zero
A.C.
0.000
8.880
0.000
0.565
2.260
0.000
0.000
0.000
2.860
1.040
0.000
5.655
0.295
0.000
0.000
1.075
0.000
5.750
0.000
0.000
3.445
0.000
0.000
17.805
0.855
0.000
0.000
0.000
0.000
0.000
0.000
1.315
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Initial
Zero
ppmC
0.000000
0.000000
0.000000
0.000000
0.000000
o.cooooo
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000117
0.000000
0.000000
0.001187
0.000000
0.000000
0.000187
0.000000
0.001056
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
Final
Zero
ppmC
0.000000
0.002743
0.000000
0.000172
0.000691
0.000000
0.000000
0.000000
0.000875
0.000316
0.000000
0.001721
0.000091
0.000000
0.000000
0.000335
0.000000
0.001823
0.000000
0.000000
0.001056
0.000000
0.000000
0.005563
0.000266
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000400
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
0.000000
Initial
Cal
Factor
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
0.
000310
000303
000301
000304
000302
000306
000303
000302
000302
000302
000303
000303
000295
000306
000311
000306
000311
000307
000309
000307
000306
000305
000307
000308
000303
000307
000307
000304
000307
000303
000303
000305
000299
000302
,000301
,000301
,000300
,000299
.000298
0.000301
0.000302
0.000300
il
al
Factor
0.000311
0.000309
0.000301
0.000304
0.000306
0.000307
0.000299
0.000303
0.000306
0.000304
0.000302
0.000304
0.000308
0.000312
0.000315
0.000312
0.000322
0.000317
0.000310
0.000304
0.000306
0.000311
0.000307
0.000312
0.000311
0.000308
0.000307
0.000304
0.000307
0.000304
0.000303
0.000304
0.000305
0.000301
0.000302
0.000300
0.000300
0.000299
0.000298
0.000301
0.000305
0.000300
Cal
Factor
Drift
-0.
-0.
0.
0.
-0.
•-0.
0.
-•0.
-•0.
-0.
0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
-0.
0.
0.
-0.
0.
-0.
-0.
-0.
0.
0.
0.
-0.
0.
0.
-0.
0.
-0.
0.
0.
Cl.
0.
0.
-0.
0'.
000001
000006
000000
000000
000004
000001
000004
000001
000003
000002
000001
000001
000013
000006
000005
000006
000011
000010
000001
000003
000000
000006
000000
000005
000008
000000
000000
000000
000000
000001
000000
000001
000005
000001
000001
000001
000000
000000
000000
000000
000002
000000
Cal
Factor
X Drift
-0.476143
-1.975971
0.000000
0.116014
-1.403917
-0.282915
1.279521
-0.337705
-1.106086
-0.753107
0.373168
-0.406379
-4.541017
-1.886510
-1.467086
-1.981042
-3.505237
-3.373133
-0.208303
1.016790
0.000000
-2.105117
0.000000
-1.505648
-2.778766
-0.022856
0.000000
0.000000
0.055230
-0.364337
0.000000
0.202849
-1.751838
0.434796
-0.397107
0.410038
0.000000
0.000000
0.000000
0.000000
-0.807703
0.000000
F-8
-------
TABLE F-3. DAILY CALIBRATION DATA SUMMARY (CHANNEL C)
Cal
Date
09/29/89
10/02/89
10/03/89
10/04/89
Julian
Cal
Date
272
275
276
277
Intial
Zero
A.C.
0.000
0.000
0.000
0.000
Final
Zero
A.C.
0.000
0.000
0.000
0.000
Initial
0.
0.
0.
0.
Zero
ppmC
000000
000000
000000
000000
0
0
0
0
Final
Zero
ppmC
.000000
.000000
.000000
.000000
Initial
Cal
Factor
0.000302
0.000299
0.000301
0.000300
Final
Cal
Factor
0.000302
0.000299
0.000302
0.000300
Cal
Factor
Drift
0.000000
0.000000
-0.000002
0.000000
Cal
Factor
% Drift
0.000000
0.000000
-0.534528
0.000000
F-9
-------
TABLE F-4. DAILY CALIBRATION DATA SUMMARY (CHANNEL D)
Julian
Cal Cal
Date Date
06/05/89
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/13/89
06/14/89
06/15/89
06/16/89
06/19/89
06/20/89
06/21/89
06/22/89
06/23/89
06/26/89
06/27/89
06/28/89
06/29/89
06/30/89
07/03/89
07/05/89
07/06/89
07/07/89
07/10/89
07/11/89
07/12/89
07/13/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/25/89
07/26/89
07/27/89
07/28/89
07/31/89
08/01/89
08/02/89
156
157
158
159
160
163
164
165
166
167
170
171
172
173
174
177
178
179
180
181
184
186
187
188
191
192
193
194
195
198
199
200
201
202
205
206
207
208
209
212
213
214
Intial
Zero
A.C.
0.000
0.000
4.395
0.000
0.000
7.320
4.375
0.000
0.000
0.000
0.000
2.995
0.000
0.000
0.000
0.000
0.000
6.840
0.035
0.710
0.000
2.255
5.350
0.000
0.000
0.000
0.000
0.220
0.000
0.540
0.000
7.030
0.000
0.000
0.000
0.000
4.515
0.000
0.000
0.000
0.000
5.865
Final Initial Final Initial Final Cal Cal
Zero Zero Zero Cal Cal Factor Factor
A.C. ppmC ppmC Factor Factor Drift % Drift
0.000 0.000000 0.000000 0.000304 0.000304 0.000000 0.000000
0.000 0.000000 0.000000 0.000299 0.000299 0.000000 0.000000
0.000 0.001374 0.000000 0.000313 0.000302 0.000010 3.350653
0.000 0.000000 0.000000 0.000304 0.000304 0.000001 0.272276
0.450 0.000000 0.000135 0.000302 0.000300 0.000002 0.671377
7.320 0.002253 0.002253 0.000308 0.000308 0.000000 0.000000
0.000 0.001342 0.000000 0.000307 0.000311 -0.000005 -1.509456
0.000 0.000000 0.000000 0.000307 0.000308 -0.000001 -0.294841
0.480 0.000000 0.000149 0.000307 0.000310 -0.000003 -0.942282
0.000 0.000000 0.000000 0.000306 0.000306 0.000000 0.000000
0.000 0.000000 0.000000 0.000310 0.000309 0.000000 0.111115
2.480 0.000920 0.000763 0.000307 0.000307 -0.000000 -0.149677
0.000 0.000000 0.000000 0.000305 0.000309 -0.000004 -1.298378
2.015 0.000000 0.000618 0.000307 0.000307 0.000000 0.136536
0.000 0.000000 0.000000 0.000308 0.000308 0.000000 0.000000
0.000 0.000000 0.000000 0.000308 0.000307 0.000001 0.196775
0.0000.0000000.0000000.0003010.000296 0.000005 1.782288
6.840 0.002105 0.002105 0.000308 0.000308 0.000000 0.000000
1.175 0.000011 0.000363 0.000306 0.000309 -0.000003 -1.003048
1.715 0.000220 0.000533 0.000310 0.000310 -0.000001 -0.310233
0.000 0.000000 0.000000 0.000306 0.000305 0.000001 0.307133
5.075 0.000689 0.001542 0.000305 0.000304 0.000002 0.540610
7.640 0.001627 0.002320 0.000304 0.000304 0.000000 0.131631
2.235 0.000000 0.000676 0.000302 0.000302 -0.000001 -0.271935
0.000 0.000000 0.000000 0.000302 0.000304 -0.000002 -0.638951
0.000 0.000000 0.000000 0.000303 0.000303 0.000001 0.195601
0.000 0.000000 0.000000 0.000302 0.000303 -0.000001 -0.416619
0.220 0.000066 0.000066 0.000300 0.000300 0.000000 0.000000
0.000 0.000000 0.000000 0.000303 0.000303 0.000000 0.113669
4.695 0.000163 0.001426 0.000302 0.000304 -0.000001 -0.475004
0.000 0.000000 0.000000 0.000302 0.000302 0.000000 0.000000
1.535 0.002123 0.000462 0.000302 0.000301 0.000001 0.216507
0.115 0.000000 0.000035 0.000301 0.000302 -0.000000 -0.144582
3.890 0.000000 0.001186 0.000301 0.000305 -0.000004 -1.201915
6.175 0.000000 0.001895 0.000305 0.000307 -0.000001 -0.441588
4.885 0.000000 0.001479 0.000303 0.000303 0.000000 0.083444
2.670 0.001357 0.000812 0.000301 0.000304 -0.000003 -1.164375
6.160 0.000000 0.001852 0.000301 0.000301 0.000001 0.277864
0.000 0.000000 0.000000 0.000307 0.000307 0.000000 0.000000
0.000 0.000000 0.000000 0.000307 0.000310 -0.000003 -0.901830
3.620 0.000000 0.001132 0.000306 0.000313 -0.000006 -1.993076
0.000 0.001788 0.000000 0.000305 0.000307 -0.000002 -0.657493
F-10
-------
TABLE F-4. DAILY CALIBRATION DATA SUMMARY (CHANNEL 0)
Julian
Cal Cal
Date Date
08/03/89
08/04/89
08/06/89
08/07/89
08/08/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/16/89
08/17/89
08/18/89
08/21/89
08/22/89
08/23/89
08/24/89
08/25/89
08/28/89
08/29/89
08/30/89
08/31/89
09/01/89
09/05/89
09/06/89
09/07/89
09/08/89
09/11/89
09/12/89
09/13/89
09/14/89
09/15/89
09/18/89
09/19/89
09/20/89
09/21/89
09/22/89
09/24/89
09/25/89
09/26/89
09/27/89
09/28/89
215
216
218
219
220
221
222
223
226
227
228
229
230
233
234
235
236
237
240
241
Z42
243
244
248
249
250
251
254
255
256
257
258
261
262
263
264
265
267
268
269
270
271
Intial
Zero
A.C.
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.465
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
1.780
0.000
12.730
0.000
0.360
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.350
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
Final Initial Final Initial Final Cal Cal
Zero Zero Zero Cal Cal Factor Factor
A.C. ppmC ppmC Factor Factor Drift X Drift
0.000 0.000000 0.000000 0.000307 0.000308 -0.000001 -0.358708
3.050 0.000000 0.000925 0.000300 0.000303 -0.000004 -1.208061
0.000 0.000000 0.000000 0.000299 0.000299 0.000000 0.000000
0.000 0.000000 0.000000 0.000300 0.000300 0.000000 0.029398
2.315 0.000000 0.000697 0.000299 0.000301 -0.000002 -0.616333
0.000 0.000000 0.000000 0.000301 0.000302 -0.000001 -0.336481
0.000 0.000000 0.000000 0.000300 0.000303 -O.G3Q003 -1.107990
0.000 0.000739 0.000000 0.000300 0.000300 -0.000000 -0.144798
0.000 0.000000 0.000000 0.000300 0.000306 -0.000006 -1.855203
3.710 0.000000 0.001132 0.000299 0.000305 -0.000006 -1.921009
0.000 0.000000 0.000000 0.000299 0.000302 -0.000002 -0.779748
4.565 0.000000 0.001370 0.000300 0.000300 -0.000000 -0.003137
0.000 0.000000 0.000000 0.000306 0.000292 0.000014 4.460500
0.000 0.000000 0.000000 0.000294 0.000298 -0.000004 -1.423636
0.000 0.000000 0.000000 0.000299 0.000306 -0.000007 -2.272854
0.575 0.000000 0.000174 0.000297 0.000302 -0.000004 -1.498292
0.000 0.000000 0.000000 0.000303 0.000309 -0.000006 -2.056354
0.000 0.000000 0.000000 0.000305 0.000312 -0.000006 -2.074276
0.000 0.000538 0.000000 0.000302 0.000304 -0.000002 -0.588713
8.890 0.00000^ 0.002642 0.000303 0.000297 0.000005 1.816768
12.7; 0.003872 0.003872 0.000304 0.000304 0.000000 0.000000
0.000 0.000000 0.000000 0.000302 0.000308 -0.000006 -1.993487
0.360 0.000109 0.000109 0.000303 0.000303 0.000000 0.000000
2.140 0.000000 0.000665 0.000304 0.000311 -0.000007 -2.357163
0.375 0.000000 0.000116 0.000303 0.000310 -0.000006 -2.121072
0.000 0.000000 0.000000 0.000303 0.000304 -0.000001 -0.327210
0.000 0.000000 0.000000 0.000304 0.000304 0.000000 0.000000
0.000 0.000000 0.000000 0.000302 0.000302 0.000000 0.000000
0.000 0.000000 0.000000 0.000303 0.000303 -0.000001 -0.205518
0.000 0.000000 0.000000 0.000309 0.000309 0.000000 0.023649
2.350 0.000709 0.000709 0.000302 0.000302 0.000000 0.000000
0.000 0.000000 0.000000 0.000303 0.000303 -0.000001 -0.185613
0.000 0.000000 0.000000 0.000299 0.000302 -0.000003 -1.101487
0.000 0.000000 0.000000 0.000300 0.000298 0.000002 0.784490
0.000 0.000000 0.000000 0.000298 0.000301 -0.000003 -1.012285
0.000 0.000000 0.000000 0.000298 0.000297 0.000000 0.154848
0.000 0.000000 0.000000 0.000297 0.000297 0.000000 0.000000
0.000 0.000000 0.000000 0.000297 0.000297 0.000000 0.000000
0.000 0.000000 0.000000 0.000296 0.000296 0.000000 0.000000
0.000 0.000000 0.000000 0.000299 0.000299 0.000000 0.000000
0.000 0.000000 0.000000 0.000300 0.000303 -0.000004 -1.190461
0.000 0.000000 0.000000 0.000297 0.000297 0.000000 0.000000
F-ll
-------
TABLE F-4. DAILY CALIBRATION DATA SUMMARY (CHANNEL 0)
Cal
Date
Julian
Cal
Date
Intial
Zero
A.C.
Final
Zero
A.C.
Initial
Zero
ppmC
Final
Zero
ppmC
Initial
Cal
Factor
Final
Cal
Factor
Cal
Factor
Drift
Cal
Factor
% Drift
09/29/89 272 0.000 0.000 0.000000 0.000000 0.000299 0.000299 0.000000 0.000000
10/02/89 275 0.000 0.000 0.000000 0.000000 0.000297 0.000297 0.000000 0.000000
10/03/89 276 0.000 0.000 0.000000 0.000000 0.000296 0.000299 -0.000003 -0.970956
10/04/89 277 0.000 0.000 0.000000 0.000000 0.000296 0.000296 0.000000 0.000000
F-12
-------
APPENDIX G
1989 NMOC IN-HOUSE QUALITY CONTROL SAMPLES
-------
vj
-------
TABLE G-l. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL A)
Julian QC Calculated Measured
Date Date I.D. NMOC NMOC
Analyzed Analyzed Number ppmC ppmC
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/14/89
06/21/89
06/23/89
06/26/89
06/28/89
06/29/89
06/30/89
07/03/89
07/06/89
07/10/89
07/12/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/26/89
07/27/89
07/28/89
07/31/89
08/02/89
08/04/89
08/07/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/21/89
08/23/89
08/25/89
08/28/89
08/30/89
08/31/89
09/01/89
09/05/89
157
158
159
160
163
165
172
174
177
179
180
181
184
187
191
193
195
198
199
200
201
202
205
207
208
209
212
214
216
219
221
222
223
226
227
233
235
237
240
242
243
244
248
1002
1003
1004
1058
1086
1111
1233
1298
1297
1354
1373
1418
1447
1471
1573
1599
1654
1682
1708
1734
1762
1788
1813
1866
1600
1912
1939
1988
2039
2064
2096
2143
2168
2190
2222
2318
2369
2422
2458
2498
2527
2530
2601
0.455
0.545
0.766
0.406
0.464
0.597
1.815
0.512
0.158
0.284
0.394
0.325
17.557
16.763
8.767
8.395
5.459
1.231
0.757
0.478
0.320
0.260
0.207
0.242
8.767
0.193
0.151
0.132
0.291
0.491
0.271
0.345
0.612
0.117
1.144
0.701
0.998
3.744
1.714
0.636
0.472
0.688
0.142
0.458
0.546
0.754
0.364
0.466
0.649
1.784
0.486
0.147
0.292
0.433
0.304
17.251
17.557
8.401
8.767
5.682
1.298
0.772
0.490
0.333
0.252
0.217
0.245
8.431
0.196
0.171
0.126
0.275
0.504
0.255
0.342
0.612
0.110
1.095
0.667
0.984
3.847
1.703
0.598
0.606
0.677
0.167
NMOC
Bias
ppnC
0.003
0.001
-0.012
-0.042
0.002
0.052
-0.031
-0.026
-0.011
0.008
0.039
-0.021
-0.306
0.794
-0.366
0.372
0.223
0.067
0.015
0.012
0.013
-0.008
0.010
0.003
-0.336
0.003
0.020
-0.006
-0.016
0.013
-0.016
-0.003
0.000
-0.007
-0.049
-0.034
-0.014
0.103
-0.011
-0.038
0.134
-0.011
0.025
NMOC
Percent
Bias
0.659
0.257
-1.567
-10.345
0.431
8.710
-1.708
-5.078
-6.962
2.817
9.898
-6.462
-1.743
4.737
-4.175
4.431
4.085
5.443
1.982
2.510
4.063
-3.077
4.831
1.240
-3.833
1.554
13.245
-4.545
-5.498
2.648
-5.904
-0.870
0.000
-5.983
-4.283
-4.850
-1.403
2.751
-0.642
-5.975
28.390
-1.599
17.606
G-l
-------
TABLE 6-1. NMOC INHCUSE QUALITY CONTROL SAMPLES (CHANNEL A)
Date
Analyzed
09/07/89
09/08/89
09/13/89
09/14/89
09/15/89
09/20/89
09/22/89
Julian
Date
Analyzed
250
251
256
257
258
263
265
QC
I.D.
Number
2629
2645
2735
2757
2779
2854
2906
Calculated
NHOC
ppmC
0.916
0.707
0.656
1.049
1.089
0.246
0.357
Measured
NMOC
ppmC
0.931
0.689
0.708
1.080
1.170
0.248
0.347
NMOC
Bias
ppmC
0.015
-0.018
0.052
0.031
0.081
0.002
-0.010
NMOC
Percent
Bias
1.638
-2.546
7.927
2.955
7.438
0.813
-2.801
G-2
-------
TABLE G-2. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL B)
Julian QC Calculated Measured
Date Date 1.0. NMOC NMOC
Analyzed Analyzed Number ppmC ppmC
06/06/89
06/07/89
06/06/69
06/09/89
06/12/89
06/14/89
06/21/89
06/23/89
06/26/89
06/28/89
06/29/89
06/30/89
07/03/89
07/06/89
07/10/89
07/12/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/26/89
07/27/89
07/28/89
07/31/89
08/02/89
08/04/89
08/07/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/21/89
08/23/89
08/25/89
08/28/89
08/30/89
08/31/89
09/01/89
09/05/89
157
158
159
160
163
165
172
174
177
179
180
181
184
187
191
193
195
198
199
200
201
202
205
207
208
209
212
214
216
219
221
222
223
226
227
233
235
237
240
242
243
244
248
1002
1003
1004
1058
1086
1111
1233
1298
1297
1354
1373
1418
1447
1471
1573
1599
1654
1682
1708
1734
1762
1788
1813
1866
1600
1912
1939
1988
2039
2064
2096
2143
2168
2190
2222
2318
2369
2422
2458
2498
2527
2530
2601
0.461
0.529
0.759
0.404
0.454
0.564
1.821
0.508
0.163
0.284
0.393
0.325
17.557
16.975
8.767
8.449
5.458
1.227
0.753
0.477
0.318
0.260
0.207
0.242
8.767
0.193
0.151
0.128
0.291
0.492
0.267
0.334
0.612
0.117
1.149
0.686
0.975
3.804
1.681
0.627
0.461
0.686
0.139
0.458
0.546
0.754
0.364
0.466
0.649
1.784
0.486
0.147
0.287
0.433
0.289
17.321
17.557
8.404
8.767
5.682
1.298
0.772
0.490
0.333
0.252
0.211
0.242
8.506
0.191
0.158
0.126
0.279
0.504
0.255
0.342
0.614
0.110
1.095
0.667
0.984
3.847
1.703
0.598
0.606
0.677
0.167
NMOC
Bias
ppmC
-0.003
0.017
-0.005
-0.040
0.012
0.085
-0.037
-0.022
-0.016
0.003
0.040
-0.036
-0.236
0.582
-0.363
0.318
0.224
0.071
0.019
0.013
0.015
-0.008
0.004
0.000
-0.261
-0.002
0.007
-0.002
-0.012
0.012
-0.012
0.008
0.002
-0.007
-0.054
-0.019
0.009
0.043
0.022
-0.029
0.145
-0.009
0.028
NMOC
Percent
Bias
-0.651
3.289
-0.659
-9.901
2.643
15.071
-2.032
-4.331
-9.816
1.056
10.178
-11.077
-1.344
3.429
-4.141
3.764
4.104
5.786
2.523
2.725
4.717
-3.077
1.932
0.000
-2.977
-1.036
4.636
-1.563
-4.124
2.439
-4.494
2.395
0.327
-5.983
-4.700
-2.770
0.923
1.130
1.309
-4.625
31.453
-1.312
20.144
G-3
-------
TABLE G-2. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL B)
Date
Analyzed
09/07/89
09/08/89
09/13/89
09/14/89
09/15/89
Julian
Date
Analyzed
250
251
256
257
258
QC
1.0.
Number
2629
2645
2735
2757
2779
Calculated
NMOC
ppmC
0.919
.0.691
0.656
1.049
1.089
Measured
NMOC
ppmC
0.931
0.689
0.689
1.077
1.180
NMOC
Bias
ppmC
0.012
-0.002
0.033
0.028
0.091
NMOC
Pe ent
Bias
].306
-0.289
5.030
2.669
8.356
09/20/89 263 2854 0.209 0.248 0.039 18.660
09/22/89 265 2906 0.358 0.347 -0.011 -3.073
G-4
-------
TABLE 6-3. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL C)
Julian QC Calculated Measured
Date Date 1.0. NMOC NHOC
Analyzed Analyzed Number ppmC ppmC
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/14/89
06/21/89
06/23/89
06/26/89
06/28/89
06/29/89
06/30/89
07/03/89
07/06/89
07/10/89
07/12/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/26/89
07/27/89
07/28/89
07/31/89
08/02/89
08/04/89
08/07/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/21/89
08/23/89
08/25/89
08/28/89
08/30/89
08/31/89
09/01/89
09/05/89
157
158
159
160
163
165
172
174
177
179
180
181
184
187
191
193
195
198
199
200
201
202
205
207
208
209
212
214
216
219
221
222
223
226
227
233
235
237
240
242
243
244
248
1002
1003
1004
1058
1086
1111
1233
1298
1297
1354
1373
1418
1447
1471
1573
1599
1654
1682
1708
1734
1762
1788
1813
1866
1600
1912
1939
1988
2039
2064
2096
2143
2168
2190
2222
2318
2369
2422
2458
2498
2527
2530
2601
0.456
0.542
0.741
0.403
0.456
0.600
1.833
0.513
0.160
0.284
0.386
0.325
17.557
16.993
8.767
8.177
5.430
1.221
0.743
0.480
0.320
0.261
0.207
0.242
8.767
0.193
0.151
0.127
0.291
0.494
0.269
0.342
0.612
0.117
1.150
0.679
0.983
3.701
1.690
0.623
0.470
0.708
0.148
0.458
0.546
0.754
0.364
0.466
0.649
1.784
0.486
0.147
0.292
0.433
0.296
17.122
17.557
8.187
8.767
5.682
1.298
0.772
0.490
0.333
0.252
0.211
0.243
8.143
0.193
0.187
0.126
0.275
0.504
0.255
0.342
0.609
0.109
1.095
0.667
0.984
3.847
1.703
0.598
0.606
0.677
0.167
NMOC
Bias
ppmC
0.002
0.004
0.013
-0.039
0.010
0.049
-0.049
-0.027
-0.013
0.008
0.047
-0.029
-0.435
0.564
-0.580
0.590
0.252
0.077
0.029
0.010
0.013
-0.009
0.004
0.001
-0.624
0.000
0.036
-0.001
-0.016
0.010
-0.014
0.000
-0.003
-0.008
-0.055
-0.012
0.001
0.146
0.013
-0.025
0.136
-0.031
0.019
NMOC
Percent
Bias
0.439
0.812
1.754
-9.677
2.193
8.167
-2.673
-5.263
-8.125
2.817
12.176
-8.923
-2.478
3.319
-6.616
7.215
4.641
6.306
3.903
2.083
4.063
-3.448
1.932
0.413
-7.118
0.000
23.841
-0.787
-5.498
2.024
-5.204
0.000
-0.490
-6.838
-4.783
-1.767
0.102
3.945
0.769
-4.013
28.936
-4.379
12.838
G-5
-------
TABLE G-3. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL C)
Date
Analyzed
09/07/89
09/08/89
09/13/89
09/14/89
09/15/89
09/20/89
09/22/89
Julian
Date
Analyzed
250
251
256
257
258
263
265
QC
1.0.
Number
2629
2645
2735
2757
2779
2854
2906
Calculated
NMOC
ppmC
0.941
0.697
0.656
1.049
1.089
0.238
0.353
Measured
NMOC
ppmC
0.931
0.689
0.706
1.084
1.178
0.248
0.347
NMOC
Bias
ppmC
-0.010
-0.008
0.050
0.035
0.089
0.010
-0.006
NMOC
Percent
Bias
-1.063
-1.148
7.S22
3.337
8.173
4.202
-1.700
G-6
-------
TABLE 6-4. NMOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL D)
Julian QC Calculated Measured
Date Date I.D. NMOC NMOC
Analyzed Analyzed Number ppmC ppmC
06/06/89
06/07/89
06/08/89
06/09/89
06/12/89
06/14/89
06/21/89
06/23/89
06/26/89
06/28/89
06/29/89
06/30/89
07/03/89
07/06/89
07/10/89
07/12/89
07/14/89
07/17/89
07/18/89
07/19/89
07/20/89
07/21/89
07/24/89
07/26/89
07/27/89
07/28/89
07/31/89
08/02/89
08/04/89
08/07/89
08/09/89
08/10/89
08/11/89
08/14/89
08/15/89
08/16/89
08/23/89
08/25/89
08/28/89
08/30/89
08/31/89
09/01/89
09/05/89
157
158
159
160
163
165
172
174
177
179
180
181
184
187
191
193
195
198
199
200
201
202
205
207
208
209
212
214
216
219
221
222
223
226
227
233
235
237
240
242
243
244
248
1002
1003
1004
1058
1086
1111
1233
1298
1297
1354
1373
1418
. 1447
1471
1573
1599
1654
1682
1708
1734
1762
1788
1813
1866
1600
1912
1939
1988
2039
2064
2096
2143
2168
2190
2222
2318
2369
2422
2458
2498
2527
2530
2601
0.453
0.525
0.743
0.393
0.454
0.592
1.821
0.597
0.155
0.284
0.383
0.325
17.557
16.712
8.767
8.384
5.490
1.214
0.742
0.464
0.312
0.252
0.207
0.242
8.767
0.193
0.151
0.124
0.291
0.484
0.262
0.336
0.612
0.117
1.138
0.674
1.047
3.811
1.710
0.651
0.508
0.676
0.138
0.458
0.546
0.754
0.364
0.466
0.649
1.784
0.486
0.147
0.284
0.433
0.306
16.991
17.557
8.378
8.767
5.682
1.298
0.772
0.490
0.333
0.252
0.206
0.238
8.431
0.190
0.190
0.126
0.267
0.504
0.255
0.342
0.603
0.108
1.095
0.667
0.984
3.847
1.703
0.598
0.606
0.677
0.167
NMOC
Bias
ppmC
0.005
0.021
0.011
-0.029
0.012
0.057
-0.037
-0.111
-0.008
0.000
0.050
-0.019
-0.566
0.845
-0.389
0.383
0.192
0.084
0.030
0.026
0.021
0.000
-0.001
-0.004
-0.336
-0.003
0.039
0.002
-0.024
0.020
-0.007
0.006
-0.009
-0.009
-0.043
-0.007
-0.063
0.036
-0.007
-0.053
0.098
0.001
0.029
NMOC
Percent
Bias
1.104
4.076
1.480
-7.379
2.643
9.628
-2.032
-18.593
-5.161
0.000
13.055
-5.846
-3.224
5.056
-4.437
4.568
3.497
6.919
4.043
5.603
6.731
0.000
-0.483
-1.653
-3.833
-1.554
25.828
1.613
-8.247
4.132
-2.672
1.786
-1.471
-7.692
-3.779
-1.039
-6.017
0.945
-0.409
-8.141
19.291
0.148
21.014
G-7
-------
TABLE 6-4. NHOC INHOUSE QUALITY CONTROL SAMPLES (CHANNEL D)
Date
Analyzed
09/07/89
09/08/89
09/13/89
09/14/89
09/15/89
09/20/89
09/22/89
Julian
Date
Analyzed
250
251
256
257
258
263
265
QC
I.D.
Number
2629
2645
2735
2757
2779
2854
2906
Calculated
NHOC
ppenC
0.967
0.747
0.656
1.049
1.089
0.233
0.351
Measured
NMOC
ppmC
0.931
0.689
0.704
1.073
1.170
0.248
0.347
NMOC
Bias
ppmC
-0.036
-0.058
0.048
0.024
0.081
0.015
-0.004
NMOC
Percent
Bias
-3.723
-7.764
7.317
2.288
7.438
6.438
-1.140
-------
APPENDIX H
MULTIPLE DETECTOR SPECIATED THREE-HOUR SITE DATA SUMMARIES
-------
'.* *
\
-------
APPENDIX H -- LIST OF TABLES
Table Page
H-l MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR C3IL . H-l
H-2 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR C6IL . H-4
H-3 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR GRMI . H-7
H-4 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR MNY . . H-10
H-5 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR M1NY . H-13
H-6 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR NWNJ . H-16
H-7 MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR PLNJ . H-l9
/ "%
-------
-------
TABLE H-1. MULTIPLE DETECTOR SPECIATEO THREE-HOUR DATA SUMMARY FOR C3IL
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans- 1,2-D ich loroethylene
1 , 1 - 0 i ch I oroethane
Chloroprene
Bromochloromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-D ich I oroethane
Benzene
Tr ich loroethylene
1,2-Dichloropropane
Bromodichloromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 ,2-Trichloroethane
Tetrach loroethyl ene
D i bromoch 1 oromethane
Ch lorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-D ich lorobenzene
p-D i ch 1 orobenzene
o-D ich lorobenzene
07/17/89
1748
0.417
<1.00
<0.10
<0.20
<0.20
0.05 H
<0.20
0.05 H
<0.11
<0.04
<0.04
0.10 H
<0.01
<0.01
<0.01
0.15 L
<0.04
2.25 H
<0.01
<0.04
<0.01
<0.04
2.38 M
<0.04
<0.02
<0.07
<0.01
<0.02
0.36 H
1.82 H
0.53 H
<0.01
<0.01
0.03 L
<0.09
<0.02
08/09/89
2174
0.232
3.27 L
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.09 M
0.14 L
<0.04
1.34 H
0.37 H
<0.04
<0.01
<0.04
2.30 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.24 H
1.34 H
0.41 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/11/89
2223
;
0.211
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
1.32 H
<0.04
<0.04
0.06 M
<0.01
<0.01
3.13 H
0.14 U
<0.04
0.90 H
0.58 M
<0.04
0.08 M
3.65 H
<0.02
<0.04
<0.02
<0.07
<0.01
<0.02
0.20 H
0.97 H
0.36 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/14/89
2283
0.242
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
0.13 M
<0.01
<0.01
0.83 L
0.14 L
<0.04
0.89 H
0.14 L
<0.04
<0.01
<0.04
1.45 H
0.31 L
<0.02
0.88 L
<0.01
<0.02
0.19 H
0.85 H
0.31 H
<0.01
<0.01
<0.02
<0.09
<0.02
•\
08/15/89
2277
0.252
1.73 L
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
0.08 H
<0.01
<0.01
1.13 M
0.15 L
<0.04
0.89 H
0.74 H
<0.04
<0.01
<0.04
3.41 M
<0.04
<0.02
1.33 L
<0.01
<0.02
0.29 H
1.37 H
0.46 H
<0.01
<0.01
<0.02
0.84 L
0.07 L
H High confidence level
M Medium confidence level
L Low confidence level
(Continued)
WHM/015
H-1
-------
TABLE H-1. C3IL (Continued)
Sample Date
Sample 10
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chi oromethane
Vinyl chloride
1,3 -Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
Bromoch I oromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1 ,2-Dichloroethane
Benzene
Trichloroethylene
1 ,2-Dichloropropane
B romodi ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1,1,2-Trichloroethane
Tetrachloroethylene
0 i bromoch I oromethane
Chi orobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xy 1 ene
Bromoform
1,1,2,2-Tetrachloroethane
m-D i ch I orobenzene
p-D i ch I orobenzene
o-D i ch I orobenzene
H High confidence level M
0 Duplicate sample R
08/16/89
2316
0.304
<1.00
<0.10
<0.20
<0.20
<0.10
0.07 H
<0.10
<0.11
<0.04
<0.04
0.13 L
<0.01
<0.01
2.52 H
0.13 L
<0.04
1.14 H
0.51 H
<0.04
<0.01
<0.04
3.76 M
0.22 L
<0.02
1.82 L
<0.01
<0.02
0.37 H
1.84 H
0.56 H
<0.01
<0.01
0.02 L
<0.09
<0.02
Medium confidence
Replicate analysis
08/17/89
23380
0.141
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
2.04 H
<0.04
<0.04
<0.06
<0.01
<0.01
1.12 H
0.12 L
<0.04
0.53 H
0.21 H
<0.04
<0.01
<0.04
1.18 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.12 H
0.59 H
0.16 H
<0.01
<0.01
<0.02
<0.09
<0.02
level
08/17/89
2338R
0.141
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
2.25 H
<0.04
<0.04
<0.06
<0.01
<0.01
1.15 H
0.13 L
<0.04
0.57 H
0.37 M
<0.04
<0.01
<0.04
1.28 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.12 H
0.64 H
0.22 H
<0.01
<0.01
<0.02
<0.09
<0.02
L Low confidence
08/17/89
23390
0.150
•0.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
1.94 H
<0.04
<0.04
<0.06
<0.01
<0.01
1.10 H
0.13 L
<0.04
0.56 H
0.26 H
<0.04
<0.01
<0.04
1.16 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.12 H
0.59 H
0.21 L
<0.01
<0.01
<0.02
<0.09
<0.02 ,
level
08/18/89
2416
0.080
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.83 M
0.14 L
<0.04
0.25 H
0.16 L
<0.04
<0.01
<0.04
0.24 H
<0.04 .
<0.02
0.09 L
<0.01
<0.02
0.04 M
0.18 H
0.06 H
<0.01
<0.01
<0.02
<0.09
<0.02
(Continued)
UHH/015
H-2
-------
TABLE H-1. C3IL (Continued)
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
P ropy I ene
Chloromethane
Vinyl chloride
1,3- Butadiene
Bromomethane
Chloroethane
Methyl ene chloride
trans-1,2-Dichloroethylene
1 , 1 -Di Chloroethane
Chloroprene
Bromochloromethane
Chloroform
1 , 1 , 1-Trichloroethane
Carbon tetrachloride
1,2-Dichtoroethane
Benzene
Trichtoroethylene
1 , 2-0 i ch I oropropane
B romod i ch 1 ororne thane
c i s - 1 , 3 -D i ch I oropropy I ene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 , 2- Tr i ch I oroethane
Tetrachloroethylene
0 i bromoch I or omethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m-Di chlorobenzene
p-Oi chlorobenzene
o-Di chlorobenzene
08/21/89
2378
0.542
08/22/89
2400
0.233
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
1.61 L
<0.04
<0.04
<0.06
<0.01
<0.01
1.29 L
0.13 U
<0.04
2.44 H
0.65 L
<0.04
<0.01
<0.04
6.59 H
<0.04
<0.02
1.15 L
<0.01
<0.02
0.67 H
3.59 N
1.09 N
<0.01
<0.01
<0.02
0.20 H
<0.02
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
•cO.04
<0.06
<0.01
<0.01
0.75 L
0.15 L
<0.04
1.24 H
<0.01
0.46 H
<0.01
<0.04
3.07 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.22 H
1.16 H
0.36 L
<0.01
<0.01
<0.02
0.08 M
<0.02
=======rs=s=sBS====ss=ss=ss==s==s====:
H High confidence level
=======================
Medium confidence level
Low confidence level
WHM/015
H-3
-------
TABLE H-2. MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR C6IL
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3 -Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
B romoch I oromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1.2-Dichloroethane
Benzene
Trichloroethylene
1 , 2 • D i ch 1 oropr opane
Bromod i ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1 ,3-Dichloropropylene
1 , 1 ,2-Trichloroethane
Tet rach I oroethy I ene
D i bromoch loromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2, 2-Tetrachloroethane
m- D i ch I orobenzene
p- D i ch I orobenzene
o-Dich I orobenzene
07/17/89
1749
0.973
<1.00
<0.10
<0.20
<0.20
1.04 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.03 M
<0.01
<0.01
1.35 M
0.14 L
<0.04
8.16 H
0.39 L
<0.04
<0.01
<0.04
10.53 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.20 H
6.95 H
2.23 H
<0.01
<0.01
<0.02
1.15 M
<0.02
08/09/89
2173
0.960
<1.00
<0.10
<0.20
<0.20
0.77 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.03 M
<0.01
<0.01
1.39 M
0.16 L
<0.04
5.35 M
0.44 M
1.04 M
<0.01
<0.04
9.25 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.09 H
6.28 H
2.09 H
<0.01
<0.01
<0.02
0.82 L
<0.02
08/11/89
2224
1.442
Concentration, ppbv
17.33 L
<0.10
<0.20
<0.20
1.07 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06 .
<0.01
<0.01
2.54 M
0.17 L
<0.04
8.30 H
1.76 H
<0.04
<0.01
<0.04
27.86 H
<0.04
<0.02
1.77 L
<0.01
<0.02
1.82 H
10.00 H
3.43 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/15/89
2276
0.628
<1.00
<0.10
<0.20
<0.20
0.56 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.52 H
0.20 L
<0.04
3.61 H
0.94 M
<0.04
<0.01
<0.04
9.64 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.73 H
9.50 H
2.76 H
<0.01
<0.01
<0.02
1.21 M
0.40 L
08/16/89
2317
0.963
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
0.24 M
<0.01
<0.01
2.85 H
0.13 L .
<0.04
4.04 H
1.15 M
<0.04
<0.01
<0.04
10.00 H
<0.04
0.03 M
<0.07
<0.01
<0.02
3.00 H
17.41 H
4.89 H
<0.01
<0.01
<0.02
<0.09
<0.02
H High confidence level
M Medium confidence level
Low confidence level
(Continued)
WHM/015
H-4
-------
TABLE H-2. C6IL (Continued)
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3 -Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans- 1,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
Bromoch I oromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1 ,2-Dichloroethane
Benzene
Trichloroethylenc
1 , 2 - D i ch t oropropane
Bromodichloromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t- 1 , 3-0 i ch I oropropy I ene
1 , 1 ,2-Tri chloroethane
Tetrachloroethylene
D i bromoch I oromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m- D i ch I orobenzene
p-Di Chlorobenzene
o-Di Chlorobenzene
H High confidence level M
D Duplicate sample R
08/17/89
2331
1.952
<1.00
19.46 M
<0.20
0.20
1.02 M
<0.20
<0.10
2.78 L
<0.04
<0.04
0.12 L
<0.01
<0.01
6.27 H
0.15 L
<0.04
6.39 H
0.97 L
1.35 H
<0.01
<0.04
23.74 H
1.53 L
0.08 H
2.98 L
<0.01
<0.02
16.48 H
88.90 H
18.64
<0.01
<0.01
<0.02
<0.09
<0.02
Medium confidence
Replicate analysis
08/21/89
2388D
1.811
<1.00
<0.10
<0.20
<0.20
1.64
<0.20
<0.10
<0.11
<0.04
<0.04
0.18
<0.01
<0.01
2.33
0.17
<0.04
8.93
1.19
<0.04
<0.01
<0.04
21.04
<0.04
0.05
<0.07
<0.01
<0.02
3.77
20.98
6.89
<0.01
<0.01
<0.02
<0.09
<0.02
level
08/21/89
2388R
1.811
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
H 1.43 H
<0.20
<0.10
<0.11
<0.04
<0.04
L <0.06
<0.01
<0.01
M 2.13 M
L 0.17 L
<0.04
H 8.68 H
H 1.41 M
<0.04
<0.01
<0.04
H 21.07 H
<0.04
M 0.06 H
<0.07
<0.01
<0.02
H 3.66 H
H 20.16 H
H 6.70 H
<0.01
<0.01
0.02 L
<0.09
<0.02
L Low confidence
08/21/89
23890
1.781
<1.00
<0.10
<0.20
<0.20
1.67 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
2.34 H
0.17 L
<0.04
8.72 H
1.67 L
<0.04
<0.01
<0.04
21.72 H
<0.04
<0.02
<0.07
<0.01
0.03 L
3.65 H
20.02 H
6.48 H
<0.01
<0.01
<0.02
<0.09
0.12 L
level
08/22/89
2401
2.663
1.75 L
<0.10
<0.20
<0.20
0.31 H
<0.20
<0.10
<0.11
<0.04
<0.04
1.30 H
<0.01
<0.01
6.87 H
0.21 L
<0.04
2.20 H
0.92 M
1.64 H
<0.01
<0.04
54.31 H
<0.04
<0.02
1.76 L
<0.01
0.95 H
2.08 H
7.60 H
4.62 H
<0.01
<0.01
<0.02
<0.09
<0.02
(Continued)
UHM/015
H-5
-------
TABLE H-2. C6IL (Continued)
Sample Date
Sample ID
08/31/89
2581
Total NMOC. ppmC
0.732
Compound
Concentration, ppbv
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-0ichloroethylene
1,1-Dichloroethane
Chloroprene
BromochIoromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Oichloroethane
Benzene
Trichloroethylene
1,2-Oichloropropane
BromodichIoromethane
cis-1,3-0ichloropropylene
Toluene
n-0ctane/t-1,3-0ichloropropylene
1,1,2-Trichloroethane
Tetrachloroethylene
Oibromochloromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-D i chIorobenzene
p-D i chIorobenzene
o-DichIorobenzene
H High confidence level
=s=s=s=s=========s==sss=:
M Medium confidence level
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.04
<0.04
0.56 M
<0.01
<0.01
0.98 H
0.11 L
<0.04
3.83 H
0.37 H
<0.04
<0.01
9.05 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.05 H
5.64 H
1.80 L
<0.01
<0.01
<0.02
<0.09
<0.02
:=S=SS=S===5S=S=£=S==SSS=S=SS=S==SS:
============r================
Low confidence level
WHM/015
H-6
-------
TABLE H-3. MULTIPLE DETECTOR SPECIATEO THREE-HOUR DATA SUMMARY FOR GRMI
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans- 1 ,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
8 romoch I oromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
Trichloroethylene
1 ,2-Dichloropropane
B romod i ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-0ctane/t-1,3-dichloropropylene
1,1,2-Trichloroethane
Tetrach I oroethy I ene
D i bromoch I oromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-Di chlorobenzene
p-Di chlorobenzene
o-Di chlorobenzene
H High confidence level M
D Duplicate sample R
07/17/89
1761
1.001
<1.00
<0.10
<0.20
<0.20
0.70 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.13 H
O.01
<0.01
3.43 M
0.14 L
<0.04
3.58 H
7.56 H
<0.04
<0.01
<0.04
15.43 H
1.87 L
<0.02
0.35 H
<0.01
<0.02
1.43 H
8.78 H
2.68 H
<0.01
<0.01
<0.02
<0.09
<0.02
Medium confidence
Replicate analysis
08/03/89
2093D
0.586
<1.00
<0.10
<0.20
<0.20
0.42 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.19 L
<0.01
<0.01
1.55 L
0.18 L
<0.04
2.29 H
0.84 H
<0.04
<0.01
<0.04
4.06 H
<0.04
<0.02
<0.07
<0.01
0.04 M
0.51 H
2.28 H
0.84 L
<0.01
<0.01
<0.02
0.20 M
<0.02
level
i
08/03/89
2093R
0.586
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.45 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.10 H
<0.01
<0.01
1.60 L
0.19 L
<0.04
2.15 K
0.86 H
<0.04
<0.01
<0.04
4.21 H
<0.04
<0.02
0.53 L
<0.01
<0.02
0.53 N
2.30 H
0.90 H
<0.01
<0.01
<0.02
0.24 M
<0.02
08/03/89
2094D
0.567
<1.00
<0.10
<0.20
<0.20
0.42 L
<0.20
<0.10
<0.11
<0.04
<0.04
0.08 H
<0.01
<0.01
1.54 L
0.17 L
<0.04
2.10 H
0.71 H
<0.04
<0.01
<0.04
4.13 L
<0.04
<0.02
0.22 L
<0.01
0.05 L
0.48 H
2.27 H
0.86 H
<0.01
<0.01
<0.02
0.20 M
<0.02
L Low confidence level
08/09/89
2180
1.394
<1.00
<0.10
<0.20
<0.20
0.81 M
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
3.50 H
0.17 L
<0.04
4.73 H
3.14 H
1.14 H
<0.01
<0.04
17.79 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.63 H
9.46 H
2.74 H
<0.01
<0.01
<0.02
<0.09
<0.02
(Continued)
WHM/015
H-7
-------
TABLE H-3. GRMI (Continued)
Sample Date
Sample 10
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chi oromethane
Vinyl chloride
1,3-Butadiene
Bromome thane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Chloroprene
Bromoch I oromethane
Chloroform
1,1,1 -Trichloroethane
Carbon tetrachloride
1, 2-0 i chloroethane
Benzene
Trichloroethyl ene
1 , 2-D ich loropropane
Bromodi ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1 ,3-dichloropropylene
1 , 1 ,2-Trichloroethane
Tet rach I oroethy I ene
0 i bromoch I oromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m-0 i ch I orobenzene
p-Oichlorobenzene
o-Oichlorobenzene
08/11/89
2208
0.414
<1.00
<0.10
<0.20
<0.20
0.96 N
<0.20
<0.10
<0.11
<0.04
<0.04
0.10 H
<0.01
<0.01
2.89 M
0.14 L
<0.04
5.99 H
2.11 H
<0.04
<0.01
<0.04
2.07 H
<0.04
<0.02
<0.07
<0.01
<0.02
2.17 H
11.83 H
3.58 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/14/89
2258
0.424
<1.00
<0.10
<0.20
<0.20
0.10 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.17 H
0.15 L
<0.04
1.64 H
0.73 L
<0.04
<0.01
<0.04
4.96 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.60 H
2.78 H
0.82 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/15/89
2272
0.218
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.17 L
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.85 H
0.20 L
<0.04
1.16 H
0.71 H
<0.04
<0.01
<0.04
4.37 H
<0.04
<0.02
0.14 L
<0.01
<0.02
0.41 H
2.07 H
0.64 H
<0.01
<0.01
<0.02
0.25 L
<0.02
08/16/89
2295
0.636
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.76 L
0.13 L
<0.04
2.89 M
0.44 M
<0.04
<0.01
<0.04
8.45 H
<0.04
<0.02
0.07 M
<0.01
<0.02
0.69 H
4.05 H
1.25 M
<0.01
<0.01
<0.02
<0.09
<0.02
==================
08/17/89
2337
0.701
<1.00
9.58 M
<0.20
<0.20
0.48 N
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
2.21 H
0.13 L
<0.04
2.81 N
0.12 L
<0.04
<0.01
<0.04
10.33 H
<0.04
<0.02
0.25 L
<0.01
<0.02
3.68 H
4.00 H
1.38 H
<0.01
<0.01
<0.02
<0.09
<0.02
High confidence level
Medium confidence level
Low confidence level
(Continued)
WHM/015
H-8
-------
TABLE H-3. GRMI (Continued)
====sss=s==s===s====s================s=======r==========s=s===a===s==================================================
Sample Date 08/21/89
Sample ID 2387
Total NHOC, ppmC 0.364
Compound Concentration, ppbv
Acetylene <1.00
Propylene <0.10
Chloromethane <0.20
Vinyl chloride <0.20
1,3-Butadiene <0.10
Bromomethane <0.20
Chloroethane <0.10
Methylene chloride <0.11
trans-1,2-Dichloroethylene <0.04
1,1-Oichloroethane <0.04
Chloroprene <0.06
Bromochloromethane <0.01
Chloroform <0.01
1,1,1-Trichloroethane 2.88 H
Carbon tetrachloride 0.13 L
1,2-Dichloroethane <0.04
Benzene 1.23 H
Trichloroethylene 0.72 H
1,2-Dichloropropane 0.07 M
Bromodichloromethane <0.01
cis-1,3-0ichloropropylene <0.04
Toluene 3.73 H
n-Octane/t-1,3-dichloropropylene <0.04
1,1,2-Trichloroethane <0.02
Tetrachloroethylene 0.08 L
Oibromochloromethane <0.01
Chlorobenzene <0.02
Ethylbenzene 0.63 H
m/p-Xylene 3.56 H
Styrene/o-Xylene 1.03 H
Bromoform <0.01
1,1,2,2-Tetrachloroethane <0.01
m-Dichlorobenzene <0.02
p-Oichlorobenzene 0.60 L
o-Oichlorobenzene <0.02
=========================================================================r==========================================:
H High confidence level M Medium confidence level L Low confidence level
WHM/015 H"9
-------
TABLE H-4. MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR MNY
=====s======sssss=s%s==ssssa=s=s=ss
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
B romoch I oromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1 , 2 -D i ch I oroethane
Benzene
Trichloroethylene
1 , 2-0 ich loropropane
Bromod i ch 1 oromethane
cis-1,3-Dichloropropylene
Toluene
n-0ctane/t-1,3-dichloropropylene
1,1,2-Trichloroethane
Tetrachloroethylene
D ibromoch I oromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m-Oichlorobenzene
p-Di chlorobenzene
o-Di chlorobenzene
S====3E=====S=S=3B
07/17/89
1757
0.216
<1.00
2.39 M
<0.20
<0.20
0.14 H
<0.20
0.11 L
<0.11
<0.04
<0.04
0.50 L
<0.01
<0.01
0.90 H
0.14 L
<0.04
0.98 H
0.05 H
<0.04
<0.01
<0.04
2.01 H
<0.04
<0.02
4.85 H
<0.01
<0.02
0.19 H
1.16 H
0.44 L
<0.01
<0.01
<0.02
0.13 H
<0.02
=s:=s===s====s=
07/18/89
1753
0.515
8.69 L
<0.10
<0.20
<0.20
0.28 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.09 H-
<0.01
<0.01
1.11 H
0.14 L
<0.04
2.33 H
0.19 M
<0.04
<0.01
<0.04
5.15 H
<0.04
<0.02
3.53 L
<0.01
<0.02
0.59 H
3.33 H
1.19 H
<0.01
<0.01
<0.02
<0.09
0.30 L
SSSSSBS=S=S==SS==S=SSS
08/09/89
2176
0.127
Concentration, ppbv
1.23 L
3.37 H
<0.20
<0.20
0.10 H
<0.20
<0.10
1.87 L
<0.04
<0.04
<0.06
<0.01
<0.01
1.06 H
0.15 L
<0.04
0.94 H
<0.01
<0.04
<0.01
<0.04
3.02 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.23 H
1.32 H
0.52 L
<0.01
<0.01
<0.02
0.17 H
0.23 M
!=S=S===S=======S=Z
08/10/89
2197
0.603
6.94 L
<0.10
<0.20
<0.20
0.29 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
0.10 H
1.27 M
0.16 L
<0.04
2.31 H
0.22 L
•cO.04
<0.01
•cO.04
8.04 H
<0.04
<0.02
3.03 L
<0.01
<0.02
0.56 H
3.82 H
1.33 H
<0.01
<0.01
<0.02
0.30 M
<0.02
s===s=======
08/11/89
2230
0.281
<1.00
<0.10
<0.20
<0.20
0.17 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.56 H
0.14 L
<0.04
1.30 H
<0.01
<0.04
<0.01
<0.04
2.81 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.28 H
1.61 H
0.63 H
<0.01
<0.01
<0.02
0.16 M
<0.02
H High confidence level
M Medium confidence level
Low confidence level
(Continued)
WHM/015
H-10
-------
TABLE H-4. MNY (Continued)
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chi oromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans- 1,2-Dichloroethylene
1 , 1-Di chloroethane
Chloroprene
B romoch I oromethane
Chloroform
1,1, 1 -Trich toroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
Trichloroethylene
1 , 2 - D i ch I or opr opane
B romod i ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-0ctane/t-1,3-dichloropropylene
1 , 1 ,2-Trichloroethane
Tetrachloroethylene
D i bromoch loromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2, 2-Tetrach toroethane
m- D i ch I orobenzene
p-D i ch 1 orobenzene
o-Dichlorobenzene
H High confidence level M
D Duplicate sample R
08/15/89
2286
1.006
<1.00
<0.10
<0.20
<0.20
0.62 M
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.79 H
0.17 L
<0.04
4.18 M
0.21 L
<0.04
<0.01
<0.04
13.38 H
<0.04
<0.02
3.93 H
<0.01
<0.02
1.24 H
6.86 H
2.52 H
<0.01
<0.01
<0.02
<0.09
<0.02
Medium confidence
Replicate analysis
08/16/89
2284D
0.566
<1.00
<0.10
<0.20
<0.20
0.32 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.24 M
<0.01
<0.01
1.20 H
0.18 L
<0.04
2.27 H
<0.01
<0.04
<0.01
<0.04
5.37 L
<0.04
0.11 M
2.00 H
<0.01
<0.02
0.65 H
4.06 H
1.75 H
<0.01
<0.01
0.03 M
<0.09
<0.02
level
08/16/89
2284R
0.566
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.30 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.06 H
0.16 L
<0.04
2.37 H
0.04 H
<0.04
<0.01
<0.04
5.41 M
<0.04
<0.02
1.98 H
<0.01
0.27 M
0.94 L
3.99 H
1.69 M
<0.01
<0.01
<0.02
<0.09
<0.02
L Lou confidence
08/16/89
2285D
0.556
•0.00
<0.10
<0.20
<0.20
0.32 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.09 M
<0.01
<0.01
0.97 H
0.15 L
<0.04
2.32 H
<0.01
<0.04
<0.01
<0.04
5.49 M
<0.04
<0.02
2.58 M
<0.01
0.13 M
0.68 H
3.71 H
1.73 H
<0.01
<0.01
<0.02
<0.09
<0.02
level
08/18/89
2362
0.259
1.02 L
3.02 H
<0.20
<0.20
0.13 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.08 H
<0.01
<0.01
0.58 M
0.15 L
<0.04
1.12 H
0.03 L
<0.04
<0.01
0.29 L
2.54 L
<0.04
<0.02
1.07 L
<0.01
<0.02
0.26 H
1.43 H
0.56 H
<0.01
<0.01
<0.02
<0.09
<0.02
(Continued)
UHM/015
H-ll
-------
TABLE H-4. MNY (Continued)
Sample Date
Sample ID
08/17/89
2358
Total NMOC, ppmC
0.405
Compound
Concentration, ppbv
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Chloroprene
Bromochloromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Oichloroethane
Benzene
Trichloroethylene
1,2-Dichloropropane
BromodichIoromethane
cis-1,3-0 ich loropropylene
Toluene
n-0ctane/t-1,3-dichloropropylene
1,1,2-Trichloroethane
Tet rachIoroethyIene
0ibromochloromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m-0 i chIorobenzene
p-Dichlorobenzene
o-OichIorobenzene
<1.00
6.22 H
<0.20
<0.20
0.16 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.52 H
<0.01
0.10 H
0.93 H
0.14 L
<0.04
1.45 H
0.09 L
<0.04
<0.01
<0.04
3.51 M
<0.04
<0.02
2.46 H
<0.01
<0.02
0.37 H
2.06 H
0.78 H
<0.01
<0.01
0.01 H
<0.09
<0.02
H High confidence level
M Medium confidence level
L Low confidence level
H-12
UHH/015
-------
TABLE H-5. MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR M1NY
==========r=======================:
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Di chloroethane
Chloroprene
Bromoch loromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Di chloroethane
Benzene
Trichloroethylene
1 , 2-D i ch I oropropane
Bromodichloromethane
cis-1,3-Dichloropropylene
Toluene
n-0ctarte/t-1,3-0ichloropropylene
1 , 1 ,2- Tri chloroethane
Tetrachloroethylene
D i bromoch 1 oromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 , 2 , 2 - Tet rach I oroethane
m- D i ch I orobenzene
p-Di Chlorobenzene
o-D ich I orobenzene
H High confidence level M
D Duplicate sample R
r==================r
07/17/89
1758
0.309
<1.00
3.41 M
<0.20
<0.20
0.17 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.71 M
0.16 L
<0.04
1.35 H
<0.01
<0.04
<0.01
<0.04
2.92 M
0.12 H
<0.02
0.61 L
<0.01
<0.02
0.35 H
2.05 H
0.74 H
<0.01
<0.01
<0.02
0.22 H
<0.02
Medium confidence
Replicate analysis
:==«========
07/18/89
1752
0.681
<1.00
8.31 M
<0.20
<0.20
0.54 M
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
0.09 H
1.08 H
0.14 L
<0.04
2.92 H
0.17 L
<0.04
<0.01
<0.04-
6.12 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.64 H
3.94 H
0.14 L
<0.01
<0.01
<0.02
0.35 M
<0.02
level
=as==s==sa==z=======
08/09/89
2175
0.356
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.26 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.88 H
0.14 L
<0.04
1.82 H
<0.01
<0.04
<0.01
<0.04
5.05 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.40 H
2.33 H
0.85 H
<0.01
<0.01
<0.02
<0.09
<0.02
L Low confidence
=================:
08/10/89
2196
0.799
<1.00
<0.10
<0.20
<0.20
0.53 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.36
<0.01
<0.01
3.23 H
0.20 L
<0.04
3.70 H
0.37 M
<0.04
<0.01
<0.04
9.98 H
<0.04
<0.02
1.90 L
<0.01
<0.02
0.93 H
5.58 H
2.17 H
<0.01
<0.01
0.01 L
1.41 L
<0.02
\
level
===============
08/11/89
2236
0.220
<1.00
<0.10
<0.20
<0.20
0.14 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.62 H
0.14 L
<0.04
1.27 H
0.10 L
<0.04
<0.01
<0.04
2.84 H
<0.04
•<0.02
<0.07
<0.01
0.13 M
0.28 H
1.54 H
0.58 H
<0.01
<0.01
<0.02
0.16 M
<0.02
(Continued)
UHH/015
H-13
-------
TABLE H-5. H1NY (Continued)
Sample Date
Sample ID
Total NHOC, ppmC
Compound
Acetylene
Propylene
Chi oromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chlorid"
trans- 1,2-Dich lor. cthylene
1 , 1 -Oi chloroethane
Chloroprene
Bromoch I oromethane
Chloroform
1,1, 1 -Trichloroethane
Carbon tetrachloride
1, 2-0 i chloroethane
Benzene
Trichloroethylene
1 ,2-Dichloropropane
Bromodi ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 ,1 ,2-Tri chloroethane
Tet rach I oroethy I ene
D i bromoch I oromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
S tyrene/o- Xy I ene
Bromoform
1 , 1 , 2 , 2 - Tet rach I oroethane
m-D i ch I orobenzene
p-Di chlorobenzene
o-Di chlorobenzene
H High confidence level M
D Duplicate sample R
08/15/89
2287
2.043
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
0.18 M
<0.01
<0.01
4.87 H
0.23 L
<0.04
7.80 H
0.57 H
<0.04
<0.01
<0.04
25.01 L
<0.04
0.11 H
<0.07
<0.01
<0.02
2.06 M
12.01 M
4.55 M
<0.01
<0.01
<0.02
<0.09
<0.02
Medium confidence
Replicate analysis
08/16/89
2301
0.795
<1.00
14.19 M
<0.20
<0.20
0.52 H
<0.20
1.49 L
2.51 L
<0.04
<0.04
0.09 H
<0.01
<0.01
3.05 H
0.15 L
<0.04
4.31 H
0.16 L
<0.04
<0.01
<0.04
10.15 M
<0.04
<0.02
1.91 L
<0.01
<0.02
1.30 H
7.24 H
2.94 H
<0.01
<0.01
<0.02
<0.09
<0.02
level
08/17/89
2348D
0.359
Concentration, ppbv
<1.00
4.61 M
<0.20
<0.20
0.20 H
<0.20
0.05 L
<0.11
<0.04
<0.04
<0.06 •
<0.01
<0.01
0.88 H
0.13 L
<0.04
1.54 H
0.05 L
<0.04
<0.01
<0.04
3.64 M
<0.04
<0.02
<0.07
<0.01
<0.02
0.37 H
2.11 H
0.80 H
<0.01
<0.01
<0.02
1.14 L
<0.02
L Low confidence
08/17/89
2348R
0.359
<1.00
4.82 L
<0.20
<0.20
0.18 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.05 H
<0.01
<0.01
0.89 H
0.14 L
<0.04
1.58 H
0.05 L
<0.04
<0.01
0.25 L
3.75 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.39 H
2.07 H
0.79 H
<0.01
<0.01
0.02 L
0.97 L
<0.02
level
,789
23490
0.312
<1.00
4.63 L
<0.20
<0.20
0.15 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.05 H
<0.01
<0.01
0.91 H
0.13 L
<0.04
1.59 H
0.07 L
<0.04
<0.01
<0.04
3.68 M
<0.04
<0.02
<0.07
<0.01
<0.02
0.40 H
2.18 H
0.84 H
<0.01
<0.01
<0.02
<0.09
<0.02
(Continued)
WHH/015
H-14
-------
TABLE H-5. M1NY (Continued)
Sample Date 08/18/89
Sample ID 2363
Total NMOC, ppmC 0.318
Compound Concentration, ppbv
Acetylene <1.00
Propylene 4.21 H
Chloromethane <0.20
Vinyl chloride <0.20
1,3-Butadiene 0.17 H
Bromomethane <0.20
Chloroethane 0.74 L
Methylene chloride <0.11
trans-1,2-Dichloroethylene <0.04
1,1-Dichloroethane <0.04
Chloroprene <0.06
8romochloromethane <0.01
Chloroform <0.01
1,1,1-Trichloroethane 0.77 H
Carbon tetrachloride 0.17 L
1,2-Dichloroethane <0.04
Benzene 1.42 H
Trichloroethylene 0.07 M
1,2-Dichtoropropane <0.04
Bromodichloromethane <0.01
cis-1,3-Dichloropropylene <0.04
Toluene 3.50 H
n-Octane/t-1,3-Dichloropropylene <0.04
1,1,2-Trichloroethane <0.02
Tetrachloroethylene 1.57 H
Dibromochloromethane <0.01
Chlorobenzene <0.02
Ethylbenzene 0.42 H
m/p-Xylene 2.33 M
Styrene/o-Xylene 0.84 H
Bromoform <0.01
1,1,2,2-Tetrachloroethane <0.01
m-Dichlorobenzene 0.01 L
p-Dichlorobenzene <0.09
o-Dichlorobenzene <0.02
H High confidence level M Medium confidence level L Low confidence level
UHM/015
H-15
-------
TABLE H-6. MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR NUNJ
=====r===============s=============
Sample Date
Sample ID
Total NMOC, ppmC
Compound
Acetylene
Propylene
Chtoromethane
Vinyl chloride
1,3-Butadiene
Bromome thane
Chloroethane
Methylene chloride
trans- 1,2-Dichloroethylene
1 , 1 -D i ch loroethane
Chloroprene
Bromochloromethane
Chloroform
1,1,1 -Trichloroethane
Carbon tetrachloride
1,2-Di chloroethane
Benzene
Trichloroethylene
1 , 2 - 0 i ch I oropr opane
Bromodichloromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 , 2-Trichloroethane
Tetrachloroethylene
D i bromoch loromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m- D i ch I orobenzene
p-D ich I orobenzene
o-Dichlorobenzene
H High confidence level M
D Duplicate sample R
07/14/89
1760
1.112
<1.00
<0.10
<0.20
<0.20
0.51 H
<0.20
<0.10
5.57 H
<0.04
<0.04
<0.06
<0.01
<0.01
1.79 H
0.14 L
<0.04
2.85 H
1.95 M
<0.04
<0.01
0.92 L
23.67 H
<0.04
0.51 H
1.78 L
<0.01
<0.02
1.04 H
6.66 H
2.18 H
<0.01
<0.01
0.13 L
2.54 L
<0.02
Medium confidence
Replicate analysis
08/08/89
2199
0.254
<1.00
<0.10
<0.20
<0.20
0.11 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.51 L
0.13 L
<0.04
1.15 H
<0.01
0.29 H
<0.01
<0.04
2.40 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.33 H
2.03 H
0.66 L
<0.01
<0.01
<0.02
0.09 H
<0.02
level
08/09/89 08/09/89
2169D
0.319
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.09 M
<0.20
<0.10
0.96 H
<0.04
<0.04
0.07 L
<0.01
<0.01
1.75 H
0.15 L
<0.04
0.94 H
0.36 M
<0.04
<0.01
<0.04
3.82 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.54 H
7.58 H
1.56 H
<0.01
<0.01
0.01 L
<0.09
<0.02
L Low confidence level
2169R
0.319
<1.00
<0.10
<0.20
<0.20
0.07 H
<0.20
<0.10
0.87 L
<0.04
<0.04
0.06 H
<0.01
<0.01
1.69 H
0.14 L
<0.04
0.89 H
0.26 H
<0.04
<0.01
<0.04
3.65 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.46 H
7.20 H
1.54 H
<0.01
<0.01
<0.02
0.08 M
0.90 L
:===£==========
08/09/89
21 700
0.298
<1.00
<0.10
<0.20
<0.20
0.09 H
<0.20
<0.10
0.96 L
<0.04
<0.04
0.07 H
<0.01
<0.01
1.64 H
0.14 L
<0.04
0.92 H
0.31 L
<0.04
<0.01
<0.04
4.00 H
<0.04
<0.02
<0.07
<0.01
<0.02
1.47 H
7.22 H
1.50 H
<0.01
<0.01
0.06 L
<0.09
<0.02
(Continued)
UHM/015
H-16
-------
TABLE H-6. NUNJ (Continued)
. Sample Date
Sample ID
Total NHOC, ppmC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadienc
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1 , 1-0 i chloroethane
Chloroprene
Bromoch 1 oromethane
Chloroform
1,1,1 -Trichloroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
Trichloroethylene
1 , 2 - 0 i ch 1 oropropane
Bromod i ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 ,2-Trich loroethane
Tetrachloroethylene
0 i bromoch I oromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m-Di chlorobenzene
p- D i ch I orobenzene
o-Dichlorobenzene
08/14/89
2265
1.356
<1.00
<0.10
<0.20
<0.20
0.96 M
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
2.02 L
0.17 L
<0.04
5.44 M
0.55 M
0.93 L
<0.01
<0.04
18.21 H
0.61 H
<0.02
0.71 L
<0.01
0.26 H
1.76 H
10.16 H
3.50 M
<0.01
<0.01
<0.02
<0.09
<0.02
08/15/89
2297
1.981
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
2.57 M
0.21 L
<0.04
5.98 N
1.00 L
<0.04
<0.01
<0.04
20.17 M
<0.04
<0.02
1.01 M
<0.01
1.29 M
2.44 H
14.07 M
5.06 M
<0.01
<0.01
<0.02
<0.09
<0.02
08/16/89
2364
0.551
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.29 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.56 M
<0.01
<0.01
1.18 L
0.15 L
<0.04
2.18 H
1.48 H
<0.04
<0.01
<0.04
6.72 H
<0.04
<0.02
0.75 L
<0.01
<0.02
0.96 M
5.01 H
1.78 M
<0.01
<0.01
0.02 L
<0.09
<0.02
08/18/89
2419
0.324
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
1.29 H
<0.04
<0.04
<0.06
<0.01
<0.01
0.60 L
0.14 L
<0.04
1.18 H
0.19 M
<0.04
<0.01
<0.04
8.54 H
<0.04
<0.02
0.15 L
<0.01
<0.02
0.42 H
2.52 H
0.77 L
<0.01
<0.01
<0.02
<0.09
<0.02
\
08/22/89
2448
0.307
<1.00
<0.10
<0.20
<0.20
0.10 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.49 M
0.13 L
<0.04
1.20 H
<0.01
<0.04
<0.01
<0.04
4.43 L
<0.04
<0.02
1.04 L
<0.01
<0.02
0.36 H
2.02 M
0.85 M
<0.01
<0.01
<0.02
0.12 L
<0.02
H High confidence level
M Medium confidence level
Low confidence level
(Continued)
WHH/015
H-17
-------
TABLE H-6. NWNJ (Continued)
Sample Date
Sample ID
08/24/89
2433
Total NMOC, ppmC
0.315
Compound
Concentration, ppbv
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chtoroethane
Hethylene chloride
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Chloroprene
B roroochIoromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Dichloroethane
Benzene
Trichloroethylene
1,2-Oichloropropane
BromodichIoromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1,1,2-Trichloroethane
Tetrachloroethylene
Dibromochloromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1,1,2,2-Tetrachloroethane
m- 0 i chIorobenzene
p-Oichlorobenzene
o-Oichlorobenzene
<1.00
<0.10
<0.20
<0.20
0.16 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.10 M
0.13 L
<0.04
1.33 H
0.11 L
<0.04
<0.01
<0.04
4.48 H
<0.04
<0.02
1.55 M
<0.01
<0.02
0.44 H
2.44 H
0.83 H
<0.01
<0.01
<0.02
<0.09
<0.02
H High confidence level
H Medium confidence level
Low confidence level
WHM/015
H-19
-------
TABLE H-7. MULTIPLE DETECTOR SPECIATED THREE-HOUR DATA SUMMARY FOR PLNJ
=ss=ss==s=s===ss==sss=s=s:=ss:=s:=s==s:s=s=ass=ss===s====sss=s=s:s:====5:ss=s=====s=======;=:=
Sample Date
Sample 10
Total NMOC, ppnC
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3- Butadiene
Sromome thane
Chloroethane
Hethylene chloride
trans-1,2-Dichloroethylene
1 , 1 -D i ch loroethane
Chloroprene
Bromoch loromethane
Chloroform
1,1.1-Trichloroethane
Carbon tetrachloride
1 , 2-0 i ch loroethane
Benzene
Trichloroethylene
1 , 2 - 0 i ch 1 oropr opane
Bromodi Chloromethane
cis-1,3-0ichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 , 2-Trichloroethane
Tetrachloroethylene
Dibromoch loromethane
Chlorobenzene
Ethyl benzene
m/p-Xylene
Styrene/o-Xylene
Sromoform
1,1,2,2-Tetrachloroethane
m- 0 i ch I orobenzene
p-D i ch I orobenzene
o-Dichlorobenzene
H High confidence level M
0 Duplicate sample R
08/08/89
2198
0.104
<1.00
1.52 L
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.28 L
0.14 L
<0.04
0.49 H
<0.01
<0.04
<0.01
<0.04
1.04 H
<0.04
0.01 M
0.04 L
<0.01
<0.02
0.08 H
0.40 H
0.18 H
<0.01
<0.01
<0.02
0.05 L
0.20 L
Medium confidence
Replicate analysis
08/09/89
2193
0.525
<1.00
<0.10
<0.20
<0.20
0.46 H
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
2.04 H
0.13 I
<0.04
2.64 H
<0.01
0.26 H
<0.01
<0.04
6.03 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.51 H
3.18 H
1.18 H
<0.01
<0.01
<0.02
<0.09
<0.02
level
!
08/14/89
2314D
0.764
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.52 H
<0.20
<0.10
9.45 M
<0.04
<0.04
0.10 M
<0.01
<0.01
1.93 H
0.15 L
<0.04
3.38 H
<0.01
<0.04
<0.01
<0.04
9.02 H
<0.04
<0.02
0.78 L
<0.01
<0.02
0.97 H
5.07 H
1.90 H
<0.01
<0.01
<0.02
1.96 M
<0.02
L Low confidence
08/14/89
2314R
0.764
<1.00
<0.10
<0.20
<0.20
0.42 H
<0.20
<0.10
10.29 L
<0.04
<0.04
<0.06
<0.01
<0.01
2.02 H
0.16 L
<0.04
3.36 H
0.60 L
<0.04
<0.01
<0.04
8.05 H
<0.04
<0.02
0.73 M
<0.01
0.03 M
0.97 H
4.74 H
1.75 H
<0.01
<0.01
<0.02
2.30 M
<0.02
level
08/14/89
231 5D
0.758
<1.00
<0.10
<0.20
<0.20
0.45 H
<0.20
<0.10
10.08 M
<0.04
<0.04
<0.06
<0.01
<0.01
1.91 H
0.15 L
<0.04
2.94 H
0.34 H
<0.04
<0.01
0.71 L
8.00 H
<0.04
<0.02
<0.07
<0.01
0.07 H
0.96 H
4.90 H
2.03 H
<0.01
<0.01
<0.02
1.33 L
<0.02
(Continued)
UHM/015
H-20
-------
TABLE H-7. PLNJ (Continued)
Sample Date
Sample ID
Total NHOC, ppmC
Compound
Acetylene
Propylene
Chi oromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Methylene chloride
trans-1,2-Dichloroethylene
1,1-Dichloroethane
Chloroprene
Bromochloromethane
Chloroform
1,1,1-Trich loroethane
Carbon tetrachloride
1 , 2-D i ch loroethane
Benzene
Trichloroethylene
1 , 2-D i ch I oropropane
Bromod i ch I oromethane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1, 1, 2- Tri chloroethane
Tetrachloroethylene
D i bromoch I oromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2, 2-Tetrach loroethane
m-Di chlorobenzene
p-Dichlorobenzene
o-D i ch I orobenzene
08/15/89
2303
0.888
3.89 L
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
1.78 L
0.17 L
<0.04
3.48 H
0.27 L
<0.04
<0.01
<0.04
8.95 L
<0.04
0.07 L
1.30 M
<0.01
<0.02
0.99 H
5.35 H
1.88 H
<0.01
<0.01
0.01 L
1.22 L
<0.02
08/17/89
2342
0.405
<1.00
<0.10
<0.20
<0.20
0.20 H
<0.20
<0.10
<0.11
<0.04
<0.04
0.47 H
<0.01
<0.01
0.87 H
0.14 L
<0.04
1.71 H
0.16 L
<0.04
<0.01
0.30 H
4.61 H
<0.04
<0.02
<0.07
<0.01
<0.02
0.40 H
2.30 H
0.90 H
<0.01
<0.01
<0.02
<0.09
<0.02
08/18/89
2409
0.294
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
<0.06
<0.01
<0.01
0.32 L
0.13 L
<0.04
0.97 K
« '
< ,+
<0.>-,
<0.04
3.11 H
<0.04
<0.02
0.34 L
<0.01
<0.02
0.33 H
1.95 H
1.61 H
<0.01
<0.01
<0.02
0.18 H
<0.02
08/21/89
2413
0.353
<1.00
<0.10
<0.20
<0.20
<0.10
0.06 H
<0.10
1.87 H
<0.04
<0.04
<0.06
<0.01
<0.01
0.91 L
0.15 L
<0.04
2.06 H
<0.01
<0.04
<0.01
<0.04
5.77 H
<0.04
<0.02
0.14 M
<0.01
0.06 L
0.39 H
2.12 H
0.80 H
<0.01
<0.01
<0.02
<0.09
0.26 L
08/22/89
2453
0.161
<1.00
<0.10
<0.20
<0.20
<0.10
<0.20
<0.10
<0.11
<0.04
<0.04
0.31 M
<0.01
<0.01
0.31 M
0.15 L
<0.04
0.92 H
0.19 L
0.04
<0.01
0.04
1.63 H
<0.04
O.02
0.26 H
<0.01
<0.02
0.20 H
1.04 H
0.41 H
<0.01
<0.01
<0.02
0.35 L
0.10 L
H High confidence level
M Medium confidence level
Low confidence level
(Continued)
UHM/015
H-21
-------
TABLE H-7. PLNJ (Continued)
Sample Date 08/23/89
Sample ID 2454
Total NMOC, ppmC 0.425
Compound
Acetylene
Propylene
Chloromethane
Vinyl chloride
1,3-Butadiene
Bromomethane
Chloroethane
Hethylene chloride
trans- 1,2-Dichloroethylene
1 , 1 -D i ch I oroethane
Chloroprene
Bromochloromethane
Chloroform
1,1,1-Trichloroethane
Carbon tetrachloride
1,2-Di chloroethane
Benzene
Trichloroethylene
1,2-Dichloropropane
B romod i ch 1 orornet hane
cis-1,3-Dichloropropylene
Toluene
n-Octane/t-1,3-Dichloropropylene
1 , 1 ,2-Trichloroethane
Tetrachloroethylene
0 i bromoch 1 oromethane
Chlorobenzene
Ethylbenzene
m/p-Xylene
Styrene/o-Xylene
Bromoform
1 , 1 ,2,2-Tetrachloroethane
m-D i ch I orobenzene
p-D i ch I orobenzene
o-D i ch I orobenzene
H High confidence level H Medium confidence level
Concentration, ppbv
<1.00
<0.10
<0.20
<0.20
0.14 M
<0.20
<0.10
<0.11
<0.04
<0.04
0.10 M
<0.01
<0.01
0.73 H
0.15 L
<0.04
1.68 H
<0.01
<0.04
<0.01
<0.04
4.13 L
<0.04
<0.02
<0.07
<0.01
0.04 H
0.37 H
1.84 H
0.68 M
<0.01
<0.01
<0.02
<0.09
<0.02
L Low confidence level
H-22
WHM/015
-------
TECHNICAL REPORT DATA
(Please read Instructions on the reverse before completing)
1. REPORT NO.
EPA-450/4-90-011
2.
3. RECIPIENTS ACCESSION NO.
4. TITLE AND SUBTITLE
1989 Nonmethane Organic Compound And Three-hour
Air Toxics Monitoring Program
5. REPORT DATE
May 1990
6. PERFORMING ORGANIZATION CODE
7. AUTHOR(S)
Radian Corporation
Research Triangle Park, NC 27709
. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68D80014
12. SPONSORING AGENCY NAME AND ADDRESS
Office of Air Quality Planning and Standards
U.S. Environmental Protection Agency
Research Triangle Park, N.C. 27711
13. TYPE OF REPORT AND PERIOD COVERED
14. SPONSORING AGENCY CODE
16. SUPPLEMENTARY NOTES
16. ABSTRACT
In certain areas of the country where the National Ambient Air Quality Standard
(NAAQS) for ozone is being exceeded, additional measurements of ambient nonmethane
organic compounds (NMOC) are needed to assist the affected States in developing
revised ozone control strategies. Because of previous difficulty in obtaining accurate
NMOC measurements, the U.S. Environmental Protection Agency (EPA) has provided
monitoring and analytical assistance to these States, beginning in 1984 and
continuing through the 1989 NMOC Monitoring Program.
17.
KEY WORDS AND DOCUMENT ANALYSIS
DESCRIPTORS
b.lDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Ozone Control Strategies
National Ambient Air Quality Standards
Nonmethane Organic Compound
Monitoring
Analysis
1989 NMOC Monitoring Program
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (This Report)
21. NO. OF PAGES
444
Unlimited
20. SECURITY CLASS (This page)
22. PRICE
EPA Form 2220-1 (R«v. 4-77) PREVIOUS EDITION is OBSOLETE
-------
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-------