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2.1 METALS AND PARTICULATE MATTER EMISSIONS
For the secondary lead smelter study, the EPA was
interested in assessing the emissions of several metals:
arsenic (As), antimony (Sb), cadmium (Cd), chromium (Cr),
nickel (Ni), manganese (Mn), lead (Pb), and mercury (Hg).
Particulate, metallic HAPs,, and moisture present in the
Tejas, Schuylkill, and East Penn furnace baghouse inlets
were collected utilizing the methodology for the EPA
reference method 5 multi-metals test train, "Determination
of Metals Emissions in Exhaust Gases from Hazardous Waste
Incineration and Similar Combustion Processes"
(EPA/530-SW-91-0101, December 1990). These tests were
performed simultaneously with the particulate and lead
emission testing discussed below. Sections 4 and 6 of
method 5 specify the analytical procedures and calculations
used for particulate determination. Mercury was analyzed by
cold vapor atomic absorption spectroscopy and the other
metals were analyzed using inductively coupled plasma atomic
emission spectroscopy or atomic absorption spectroscopy.
2.2 LEAD AND PARTICULATE MATTER EMISSIONS
EPA reference method 12 sampling trains were used to
collect particulate, lead, and moisture present in the
following gas streams at Tejas and Schuylkill: furnace
baghouse outlets; wet scrubber outlets; and sanitary
baghouse inlets and outlets. Method 12 was also used at the
East Penn furnace baghouse outlet, wet scrubber outlet, and
the ventilation and hooding baghouse inlet and outlet.
Particulate determination was identical to that described in
section 2.1, above. Lead was analyzed using atomic
absorption spectroscopy.
2.3 SEMI-VOLATILE ORGANIC EMISSIONS
Semi-volatile organics were collected by SW-846
method 0010 at the Tejas furnace baghouse inlet and the
Schuylkill furnace afterburner inlet location. Both tests
were performed simultaneously with the PCDD/PCDF and the
HC1/C12 testing. A modified method 5 train as specified in
method 0010 was used at the East Penn blast furnace*outlet.
B-14
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method 8270 for high resolution gas chromatography (HRGC)
with low resolution mass spectrometry (LRMS) was used for
the analysis procedures.
2.4 VOLATILE ORGANIC EMISSIONS
The volatile organics in the Tejas furnace baghouse
inlet and the Schuylkill furnace afterburner inlet were
determined using a method 0030 volatile organic sampling
train (VOST) and EPA TO-14 procedures. The sampling period
was based on the EPA reference method 25A total hydrocarbon
readings. The Tejas volatile organic testing was performed
in conjunction with the semi-volatile and aldehyde/ketone
sampling; the volumetric flow rates from the latter tests
were used in calculating the volatile organic emission
rates. The TO-14 procedures were used simultaneously with
the VOST train at both sites, since the volatile organic
concentrations were expected to be high. The volatile
organics in the condensate samples were analyzed using
method 8240 for the Tejas site and using HRGC/LRMS for the
Schuylkill site.
The emissions at the East Penn furnace outlet were
determined only by VOST. The volatile organics in the VOST
tube samples were identified and quantified using the
method 5040 purge-trap-desorb (P-T-D) GC/MS procedure.
2.5 PCDD/PCDF EMISSIONS
PCDD/PCDF concentrations and mass rates at the Tejas
and the Schuylkill furnace baghouse outlets and wet scrubber
outlets and the East Penn wet scrubber inlet and outlet were
measured using an EPA reference method 23 sampling train.
Method 23 gives a detailed specification of the analysis
procedure using HRGC and high resolution mass spectrometry
(HRMS). Additionally, baghouse dust samples were obtained
directly from bins that collect baghouse fines at the Tejas
site and from the baghouse screw conveyor at the Schuylkill
site. The dusts were analyzed using method 8290 procedures.
2.6 ALDEHYDE/KETONE EMISSIONS
Method 0011 was used to determine aldehydes and ketones
in both the Tejas and the Schuylkill furnace baghouse inlet
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gas emission streams and the East Penn furnace outlet gas
stream. The sampling runs were performed simultaneously
with the semi-volatile and volatile organic runs. The
analytical procedures were performed as specified in
methods 0011 and 0011A using high-performance liquid
chromatography (HPLC).
2.7 FILTERABLE PARTICULATE, PM10, AND CONDENSIBLE
PARTICULATE EMISSIONS
Filterable particulate was determined from the multi-
metals test train at the Tejas furnace baghouse inlet and
from the method 12 sampling conducted at the Tejas and the
Schuylkill furnace baghouse outlets, scrubber outlets, and
sanitary baghouse inlets and outlets.
At the Tejas facility,, combined methods 201A and 202
were used to collect PM^o anc* condensible particulate in the
furnace baghouse inlet and outlet, wet scrubber outlet, and
sanitary baghouse inlet and outlet streams. A volumetric
gas flow balance was not achieved across the furnace
baghouse and scrubber due to air leaks and the introduction
of dilution air. Additionallly, the baghouse outlet did not
meet the minimum criteria dictated by method 1 since two
separate exhaust ducts serve as an outlet. However, the
streams were well mixed at the outlet and so testing was
performed on only one of the exhaust ducts at a time.
At the Schuylkill site, method 201A particle size
distribution tests were performed at the baghouse inlet and
method 202 was used to determine condensible particulates at
the baghouse inlet. Combined methods 201A and 202 were used
to determine particle size distribution and condensible
particulates at the sanitary baghouse inlet and outlet.
Combined methods 201A and- 202 were also used at the
East Penn furnace outlet, furnace baghouse inlet and outlet,
wet scrubber outlet, and the ventilation and hooding
baghouse inlet and outlet gas streams to determine particle
size distribution and condensible particulate.
Testing for filterable particulate, PM10, and
condensible particulate at the Tejas and Schuylkilt sites
B-16
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was performed simultaneously across the furnace baghouse and
scrubber and at the sanitary baghouse inlet and outlet.
Section 5 of method 202 and sections 4 and 6 of
method 5 detail the analytical procedures and calculations
used at all the sites.
2.8 HYDROCHLORIC ACID AND CHLORINE EMISSIONS
Proposed method 26A (59 FR 19306; April 22, 1994)
procedures were used to measure hydrochloric acid and
chlorine concentrations, mass rates, and removal efficiency
at the Tejas furnace wet scrubber outlet, the Schuylkill
furnace afterburner outlet and scrubber outlet, and the East
Penn furnace's wet scrubber inlet and outlet. A Modified
method 26 test train was used at the Tejas furnace baghouse
outlet and the furnace scrubber outlet to collect the non-
isokinetic gas sample, method 26 also was used at the RSR
Corporation baghouse outlet. The analytical method detailed
in the Schuylkill and East Penn reports is the SW-846
method 9056 used to determine Cl~ anions. The chloride
content of each sample was analyzed by ion chromatography.
2.9 THC EMISSIONS
THC at the Tejas furnace baghouse inlet and outlet and
wet scrubber outlet were monitored continuously using EPA
reference method 25A flame ionization detection (FID)
procedures. This procedure was also used at the Schuylkill
furnace afterburner inlet, outlet, and scrubber stack and
the East Penn furnace's baghouse inlet, outlet, and wet
scrubber outlet. THC monitoring at the furnace baghouse
inlet at these sites was conducted simultaneously with the
VOST sampling. THC emissions at the RSR and the Gulf Coast
baghouse outlets and at the GNB furnace charging hood were
also measured using method 25A.. The THC measurements at RSR
were conducted concurrently with the CO measurements.
The RSR furnace used natural gas. Natural gas is 90 to
95 percent methane, and, although methane is not considered
a THC, it responds positively on a THC analyzer. Therefore,
the measured THC concentrations would be overstated by the
amount of any unburned methane that was present in the stack
B-17
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gas. To correct for this bias, it was necessary to measure
the unburned methane present. Methane was measured by
collecting two canister samples and methane was analyzed
using EPA reference method 18, GC/FID.
2.10 CO. SCH. AND OPACITY EMISSIONS
EPA reference method 10 procedures and a GEM system
were used to determine the CO concentrations at the Tejas
furnace scrubber stack, the Schuylkill afterburner inlet and
scrubber stack, and the East Penn scrubber outlet.
Method 10 was also used downstream of the baghouse at RSR.
The sample was analyzed using a non-dispersive infrared
(NDIR) analyzer. The sampling was conducted concurrently
with the RSR THC measurement runs.
Tejas and East Penn CEM systems were used to monitor
SO2 emissions at the furnace wet scrubber exhaust stack. A
Schuylkill CEM system was used at the afterburner inlet.
A Tejas opacity monitor was used to monitor opacity at
the baghouse outlet.
3.0 PERFORMANCE TEST METHODS
The following subsections discuss the recommended test
methods for determining compliance with a standard for each
of the potentially regulated pollutants. The particular
measurement methods and procedures to be used depend upon
the requirements of the standard and test procedures
specified in the applicable regulation.
Performance test methods and procedures are used to
determine the overall control efficiency of add-on pollution
control systems. Add-on control systems are composed of two
parts: a capture system, and a control device (e.g.,
afterburner, baghouse, or scrubber). The control efficiency
of each component is determined separately and the overall
control efficiency is the product of the capture system and
control device efficiency. (Note: The measured overall
control efficiency will not reflect control or emission
reduction due to process and operational changes.)
B-18
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The efficiency of the capture system is defined as the
ratio of the mass of emissions directed to the control
device to the total mass of emissions from the secondary
lead smelter. The mass of pollutant in each applicable vent
is determined by measuring the concentration and the flow
rate using standard U.S. EPA test methods. The recommended
methods are discussed below.
Stack emission testing techniques would be needed to
measure pollutant concentration and gas flow rate in stacks
and ducts such as: inlets and outlets of control devices;
exhaust streams from process equipment; uncontrolled exhaust
streams venting directly to the atmosphere; and intermediate
process streams such as hood exhausts. The particular
streams to be measured depend upon the applicable
regulation.
The results from the pollutant concentration
measurement and flow rate measurement can be combined and
used in several ways. If a regulatory format is a
concentration basis, then only pollutant concentration
measurement is needed and the result can be used directly.
If the regulatory format is a mass emission basis (i.e.,
mass emitted per unit of production, or mass emitted per
unit of time), then the concentration and flow rate results
are combined to calculate the mass emission rate in pounds
per hour or pounds per production unit. If the regulatory
format is an efficiency basis, then mass emission rates are
determined for both the inlet and outlet emission streams
and the efficiency is calculated.
The performance test procedures in the applicable
regulation will define the test length and the conditions
under which testing is acceptable, as well as the way the
reference test method measurements are combined to obtain
the final result.
The three types of control devices that are expected to
be used in the secondary lead smelting industry are
afterburners, baghouses, and scrubbers. The test procedure
to determine efficiency is the same for each control
B-19
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technology. To determine the efficiency of the emission
control device, the pollutant mass flow rate in the inlet
and outlet streams must be determined. To determine the
mass of pollutant in a stream, both the concentration and
flow rate must be measured.. The recommended methods are
discussed below.
The length of a performance test is specified in the
applicable regulation and is selected to be representative
for the industry and process being tested. The length of a
performance test should be selected to be long enough to
account for variability in emissions due to start-up and
shut-down operation times and routine process problems.
Also, the performance test time period should correspond to
the cycles of the emission control device.
The total length of a performance test could vary from
plant to plant. In general, a performance test would
consist of three to six runs, each lasting from 1/2 to 3
hours. It is estimated that, for most operations, the field
testing could probably be completed in 2 to 3 days (i.e.,
two or three 8-hour work shifts) with an extra day for
setup, instrument preparation, and cleanup.
3.1 GAS VOLUMETRIC FLOW MEASUREMENT
Methods 1, 2, 3, 3B, and 4 are recommended as
appropriate for determination of the volumetric flow rate of
gas streams.4 Methods 1 and 2 are used in stacks with
steady flow and with diameters greater than 12 inches.
Method 1 is used to select the sampling site, and method 2
is used to determine the volumetric flow rate using an
S-type pitot tube and a velocity traverse technique.
Methods 3 and 4 provide fixed gases analysis and moisture
content, which are used to determine the gas stream
molecular weight and density in method 2. Method 3B gives
more accurate results than raethod 3.
If the flow in a large duct (greater than 12 inches
diameter) is not steady or continuous, then method 2 may be
modified to continuously monitor the changing flow rate in
B-20
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the stack. A continuous 1-point pitot tube measurement is
made at a representative location in the stack.
Measurement results do not need to be adjusted to dry
conditions (using method 4 for moisture) if the pollutant
concentrations are measured in the gas stream under actual
conditions; for example, if the pollutant concentrations are
reported as parts of pollutant per million parts of actual
(wet) volume (ppmv). If the concentrations are measured on
a dry basis (gas chromatographic techniques or method 25),
then the volumetric flow rate must correspondingly be
adjusted to a dry basis.
3.2 METALS AND PARTICULATE MATTER EMISSIONS
Emissions of PM and trace metals (including lead, Cd,
and, under certain conditions, Hg) can be measured
simultaneously using the methodology for the multi-metals
test train, which is also called the "Determination of
Metals Emissions in Exhaust Gases from Hazardous Waste
Incineration and Similar Combustion Processes"
(EPA/530-SW-91-0101, December 1990).
Method 3B, using the integrated sampling technique, is
recommended for measurement of 02 and C02 when emission rate
correction factor determination is required.
Sections 4 and 6 of method 5 specify the analytical
procedures and calculations used for particulate
determination. Mercury should be analyzed by cold vapor
atomic absorption spectroscopy. The other metals should be
analyzed using inductively coupled plasma atomic emission
spectroscopy or atomic absorption spectroscopy.
3.3 LEAD AND PARTICULATE MATTER EMISSIONS
Method 12 is recommended for measuring particulate,
lead, and moisture. Particulate determination is identical
to that described in section 3.2. Lead can be analyzed
using atomic absorption spectroscopy.
3.4 SEMI-VOLATILE ORGANIC EMISSIONS
Semi-volatile organics should be collected by
method 0010. Method 8270 for high resolution gas
B-21
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chromatography (HRGC) with low resolution mass spectrometry
(LRMS) can be used for the analysis procedures.
3.5 VOLATILE ORGANIC EMISSIONS
Volatile organic emissions can be determined by many
different methods depending on the circumstances. These
methods are discussed below.5
As described in the source tests, volatile organic
emissions can be determined using a method 0030 (VOST)
sampling train or EPA TO-14 procedures. The volatile
organics in the VOST tube samples can be identified and
quantified using the method 5040 purge-trap-desorb (P-T-D)
GC/MS procedure. The volatiles in the condensate samples
can be analyzed using method 8240.
Another recommended VOC measurement method is
EPA reference method 25A, "Determination of Total Gaseous
Organic Concentration Using A Flame lonization Analyzer"
(FIA). This method measures the expected VOC emissions
accurately, is practical for long-term intermittent testing,
and provides a continuous record of VOC concentration.
Gas chromatography (GC) analysis on integrated bag
samples collected following method 18 may be useful because
results are on the basis of true hydrocarbon concentrations
for each compound in the gas. However, the GC sample
technique is not a continuous measurement and might be
cumbersome and impractical because of the length of the
testing.
Method 25B, "Determination of Total Gaseous Organic
Concentration Using a Nondispersive Infrared Analyzer," is
identical to method 25A except that a different instrument
is used. Method 2SB applies to the measurement of total
gaseous organics consisting primarily of alkanes. The
sample is extracted as described in method 25A and is
analyzed with a NDIR analyzer. One drawback is the fact
that NDIR analyzers are not sensitive in low concentration
ranges (less than 50 ppmv).
Method 25, "Determination of Total Gaseous Nonmethane
Organics Content" can also be considered. A 30- to-
B-22
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60-minute integrated sample is collected in a sample train,
and the train is returned to the laboratory for analysis.
The collected organics are converted in several analytical
steps to methane and the number of carbon atoms (less
methane in the original sample) is measured. Results are
reported as organic carbon equivalent concentration. The
method 25 procedure takes integrated samples instead of
continuously sampling and recording the concentration. As
with method 25B, method 25 is not sensitive in low
concentration ranges (less than 50 ppmv). However,
method 25 has the advantage that it counts each carbon atom
in each compound and does not have a varying response ratio
for different compounds.
3.6 PCDD/PCDF EMISSIONS
The recommended performance test method for PCDD/PCDF
is method 23.6 Sampling of the PCDD/PCDF emissions is
performed using the modified method 5 sampling train
originally described in method 0010 of SW-846, with
methylene chloride and toluene used as the rinse reagents
during sample recovery. The duration of PCDD/PCDF sampling
runs for a particular source should be based on the emission
standard, the expected concentration of 2,3,7,8-TCDD (the
most toxic PCDD/PCDF congener), and the laboratory detection
limit. A typical sampling run time is 4 hours.
The samples are extracted using methylene chloride and
toluene and cleaned up using a variety of silica-, alumina-,
and carbon-based columns. HRGC/HRMS is used for analysis.
Without HRGC, it is impossible to achieve adequate
separation of the PCDD/PCDF isomer groups. Without HRMS, it
is impossible to utilize the isotopically-labeled internal
standards necessary to quantify individual congeners.
HRGC/HRMS also provides the highest sensitivity and,
therefore, the lowest detection limits. The PCDD/PCDF
analysis includes quantification of the 15 2,3,7,8-
substituted congeners (tetra through octa) and the other
non-2,3,7,8-substituted congeners by homologous groups
(tetra-through octa-PCDD/PCDF). At least one isotopically-
B-23
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labeled internal standard per class of chlorination (tetra
through hepta) and per class of compound (dioxin/furan) is
used to characterize and quantify the 15 2,3,7,8-substituted
congeners. The recoveries of the standards are used to
assess and, more importantly, quantitatively correct for
losses during the entire analytical procedure. Surrogate
standards are used to assess losses during sample
collection, while the recovery standards are used to assess
losses during the instrumental analysis. A "confirmational"
analysis is conducted when 2,3,7,8-TCDF is detected using
the 60-m DB-5 column. For confirmation of this isomer,
another column is used to separated it from the close-
eluting isomers.
Method 3B is used to measure ©2 and CO2 for normalizing
the PCDD/PCDF concentrations to a standard basis.
3.7 ALDEHYDE/KETONE EMISSIONS
Method 0011 is the recommended method to determine the
aldehydes and ketones. The recommended analytical
procedures are specified in methods 0011 and 0011A using
HPLC.
3.8 FILTERABLE PARTICULATE, PM10, AND CONDENSIBLE
PARTICULATE EMISSIONS
Filterable particulate can be determined from the
multi-metals test train or from method 12 sampling.
Combined methods 201A and 202 can be used to collect PM^o
and condensible particulate. Method 202 details the
analytical procedures.
3.9 HYDROGEN CHLORIDE EMISSIONS
Hydrogen chloride emissions should be measured using
proposed method 26A.7 A three-run performance test using
proposed method 26A offers the-additional advantage that PM
can be measured using the same sampling train, if desired.
3.10 THC EMISSIONS
THC should be monitored continuously during each test
using method 25A flame ionization detection (FID)
procedures.
B-24
-------
3.11 CARBON MONOXIDE EMISSIONS
Performance testing for CO should be conducted using
method 10 (an instrumental method) or method 10B.8
3.12 SULFUR DIOXIDE EMISSIONS
It is recommended that SO2 emissions be measured using
method 6 or method 6C (an instrumental method).9
3.13 OPACITY
Determination of the opacity of emissions should be
conducted using method 9.10
4.0 MONITORING SYSTEMS AND DEVICES
For some sources, continuous emissions monitoring
systems (CEMs) are used to demonstrate compliance with
emission standards on an on-going basis. For other sources,
the purpose of monitoring is to ensure that the process and
emission control equipment are properly operated and
maintained after the performance test. This may be
accomplished by direct monitoring of the regulated
pollutant(s) or monitoring of surrogate pollutants or
operational parameters.1]-
4.1 COMBUSTION PARAMETER MONITORING
Combustibles in the lead charge are burned off during
the first hour after charging. The CO concentration exiting
the furnaces is a direct indicator of the completeness of
combustion. CO monitors are often installed preceding the
pollution control device(s); however, if other gases are to
be monitored, installation of the CO and associated monitors
at the control device outlet or stack location may be
possible.12
Equipment for monitoring combustion temperature is
typically an integral part of the process monitoring system
installed for use in operation.
4.2 MONITORING OF CONTROL DEVICE GAS TEMPERATURES
For some control devices, the exhaust stream
temperature has been identified as an indicator of control
efficiency, and temperature monitors are available.13 A
B-25
-------
monitoring location at the exit of a control device or inlet
to a particulate control device is required.
Temperature monitoring devices are routinely used in
other process locations and installation and operation would
be easily accomplished.
4.3 SO2 MONITORING
Emission monitoring of SO2 is indicative of the
emission level of SO2 and the relative level of HCl.
Monitoring SO2 at the inlet and outlet of control equipment
indicates the efficiency of the device for that pollutant.
Equipment is available for monitoring SO2 and monitoring
technology has evolved significantly since 1980. Many EPA
studies have shown that reliable data can be obtained from
properly designed, operated, and maintained SO2 CEMs when
appropriate quality assurance procedures are applied.14
Performance specifications for SO2 monitors are
contained in Performance Specification 2, Appendix B, 40 CFR
part 60. Quality assurance, procedures for SO2 CEMs used to
demonstrate compliance with emission standards or percent
removal efficiency requirements are contained in Appendix F,
Procedure 1 of 40 CFR part 60 (promulgated June 4, 1987).
4.4 OPACITY MONITORING
Monitoring equipment is commercially available and
routinely used to monitor the opacity of emissions.15 For
secondary lead smelters, the effluent opacity would be
indicative of operation and maintenance of the particulate
control equipment.
Opacity monitors are installed in the breeching duct or
in the discharge stack downstream of the particulate control
device. The appropriate measurement location depends upon
source-specific factors such as effluent ductwork
configuration, presence of vibration, ease of access to the
location, etc. The orientation of the measurement path is
prescribed by applicable regulations for a selected
measurement location. Detailed information is available on
installation, operation, maintenance, and quality assurance
activities for opacity monitors. Performance specifications
B-26
-------
for these instruments are contained in Performance
Specification 1, Appendix B, 40 CFR part 60. These
requirements were first promulgated on October 6, 1975;
substantial revisions were issued on March 30, 1983.
B-27
-------
5.0 REFERENCES
1. Draft Emission Test Report. HAP Emission Testing on
Selected Sources at a Secondary Lead Smelter, Tejas
Resources, Inc. Terrell, Texas. US EPA: EMB.
December 1992.
2. Medical Waste Incinerator Study: Emission Measurement
and Continuous Monitoring. TSD Project No. 86/19. US
EPA: Office of Air Quality and Standards. October 8,
1992. p. 1.
3. Reference 1.
4. Surface Coating of Plastic Parts for Business Machines
- Background Information for Proposed Standards.
U. S. Environmental Protection Agency. Research
Triangle Park, North Carolina. Publication
No. EPA-450/3-85-019a. December 1985. pp. D-13 -
D-14.
5. Reference 4, pp. D-14 - D-17.
6. Reference 2. pp. 38 - 39.
7. Reference 2. p. 39.
8. Reference 2. p. 39.
9. Reference 2. p. 39.
10. Reference 2. p. 38.
11. Reference 2. p. 30.
12. Reference 2. pp. 31, 33.
13. Reference 2. pp. 35 - 36.
14. Reference 2. pp. 34, 36.
15. Reference 2. pp. 30 - 31.
B-28
-------
-------
APPENDIX C
SECONDARY LEAD SMELTER DATABASE WITH ESTIMATED
DEFAULT VALUES
1.0 INTRODUCTION
In order to estimate emissions and potential control
impacts of the National Emission Standards for Hazardous Air
Pollutants (NESHAP) being developed for the secondary lead
industry, data necessary for estimating impacts were
gathered and entered into the following database sections:
• General facility data (GEN_E.WRI)
• Furnace-specific data (FURN_E.WK1)
• Furnace-specific process fugitives data
(PROFU1_E.WK1)
• Facility-specific process fugitives data
(PROFU2_E.WK1)
• Area fugitives data (ARFUG_E.WRI)
• Baseline controls data
Afterburners (ABURN_E.WK1)
Baghouses (BHOUSE_E.WK1)
The methodologies used to create the database are discussed
in detail in a June 15, 1992, memorandum.1 Revisions to the
original database are described in a May 17, 1993,
memorandum.2
The purpose of this appendix is to document the
methodologies used to develop the default values for
parameters for which actual values were not available
(section 2.0) and to present the database with default
values.
C-l
-------
2.0 PROCEDURES FOR DETERMINING DEFAULT VALUES
Numerous parameter values in the database were not
available; therefore, default values were created when
actual values were not known. The methodologies used to
generate the default values for each parameter in each
section of the database are described in tables 1 through 7.
Where actual values were obtained for all facilities for a
given parameter, the methodology is noted as "complete" in
the tables.
Parameters that were not used to estimate emissions or
potential control impacts are so noted.
The database with the default values added is shown in
attachment 1. Confidential business information has been
blacked out.
C-2
-------
TABLE 1. DEFAULTS GENERATION METHODOLOGIES FOR GEN E.WK1
Parameter
Methodology
Facility ID
Facility Name
City
State
Total Area
Totally Enclosed (Y/N)
Lead Production Capacity
Principal Bottleneck
Hours of Operation
Actual Lead Production Rate
Paste Desulfurization (Y/N)
Number of Blast Furnaces
Number of Reverb Furnaces
Number of Rotary Furnaces
Number of Electric Furnaces
Completea
Complete
Complete
Complete
Not used to estimate impacts.
Not used to estimate impacts.
Complete
Not used to estimate impacts.
Used 8760 as default because
most smelters operate
continuously.
Used average percent of
capacity utilization for known
plants to derive defaults.
Not used to estimate impacts.
Complete
Complete
Complete
Complete
a Complete information was available for this parameter and
no
default values had to be estimated.
C-3
-------
TABLE 2. DEFAULTS GENERATION METHODOLOGIES FOR FURN E.WK1
Parameter
Methodology
Facility ID
Furnace ID
Afterburner ID
Baghouse ID
Scrubber ID
Furnace Type
If Blast, used with Reverb
(Y/N)
Hours in Operation
Actual Charge of Grids, Plates,
and Posts
Actual Charge of Slag
Percent Lead in Slag
Actual Charge of Scrap
Percent Lead in Scrap
Actual Charge of Non-Lead
Agents
Lead Production Capacity of
Furnace
Slag Production at Lead
Production Capacity
Actual Lead Production of
Furnace
Complete
Complete
Complete
Complete
Complete
Complete
Complete
Used 8760 as default because
most furnaces operate
continuously.
Based defaults on actual lead
production and battery
composition data.a
For blast furnaces, based
defaults on average ratio of
slag charged to lead produced.
For other furnaces, 0 used as
default because industry does
not typically charge a
significant amount of slag to
other furnaces.
Not used to estimate impacts.
Used 0 as default since most
smelters charge a relatively
small portion of scrap.
Not used to estimate impacts.
Based defaults on the average
ratio of non-lead agents to
lead production for each
furnace type.
Actual lead production used as
default.
Based defaults on the average
ratio of slag production to
lead production for each
furnace type.
Lead production capacity used
as default.
C-4
-------
TABLE 2. DEFAULTS GENERATION METHODOLOGIES FOR FURN_E.WK1
(Continued)
Parameter Methodology
Actual Slag Production of Based defaults on the average
Furnace ratio of slag production to
lead production for each
furnace type.
Exhaust Rate (dry stand m3/min) Defaults based on average ratio
of exhaust rate to lead
production for each furnace
type.
Exhaust Rate (act. m3/min) Calculated from dry standard
exhaust rate, percent moisture,
and temperature.
Exhaust Temperature Defaults based on average for
Percent Moisture each furnace type.
Percent Oxygen
Lead concentration
Sulfur dioxide concentration
a Reference 3.
C-5
-------
TABLE 3. DEFAULTS GENERATION METHODOLOGIES FOR PROFU1 E.WK1
Parameter
Methodology
Facility ID
Furnace ID
Lead Tapping Baghouse ID
Lead Tapping Scrubber ID
Slag Tapping Baghouse ID
Slag Tapping Scrubber ID
Charging Area Baghouse ID
Charging Area Scrubber ID
Hopper/Skip Hoist Baghouse ID
Hopper/Skip Hoist Scrubber ID
Conveyor (Y/N)
Conveyor Totally Enclosed
(Y/N)
Conveyor Baghouse ID
Conveyor Scrubber ID
Drying Kiln (Y/N)
Drying Kiln Baghouse ID
Drying Kiln Scrubber ID
Complete
Complete
Complete
Complete
Complete
Complete
Complete
Complete
Used "none" as default because
most are not controlled.
Used "N" as default because most
furnaces do not have a conveyor.
Used "Y" as default because most
conveyors at smelters are
totally enclosed.
Used "none" as default because
most are not ventilated to a
control device.
Used "N" as default because most
furnaces do not have drying
kilns.
Complete for furnaces with
drying kilns.
C-6
-------
TABLE 4. DEFAULTS GENERATION METHODOLOGIES FOR PROFU2 E.WK1
Parameter
Methodology
Facility ID
Battery Breaker (Y/N)
Equipment Used
Hours of Operation
Battery Breaker Baghouse ID
Battery Breaker Scrubber ID
Number of Dust Agglomerating
Furnaces
Dust Agglomerating Furnaces
Baghouse ID
Dust Agglomerating Furnace
Scrubber ID
Number of Refining Kettles
Refining Kettles Baghouse ID
Refining Kettles Scrubber ID
Number of Casting Machines
Casting Machine Baghouse ID
Casting Machine Scrubber ID
Complete
Complete
Complete
Used average of known values as
default.
Complete
Complete
Complete
Complete
Complete
Complete
Complete
Complete
Used 1 as default because most
smelters operate only 1 casting
machine.
Used "none" as default because
most smelters do not control
casting machines.
C-7
-------
TABLE 5. DEFAULTS GENERATION METHODOLOGIES FOR ARFUG E.WK1
Parameter
Methodology
Plant Roadways
All Roadways Paved (Y/N)
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Trailer (km/yr)
Battery Receiving/Breaking Area
Area (m2)
Is Area Paved (Y/N)
Totally Enclosed (Y/N)
Area of Open Sides
Roof (Y/N)
Baghouse ID
Scrubber ID
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Trailer (km/yr)
Front-end Loader (km/yr)
Forklift (km/yr)
Materials Storage Area
Area (m2)
Used "Y" as default because
most plant roadways are
paved.
Used "N" as default because
generally stated in
references if performed.
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
Defaults calculated using
ratio of known areas to
known lead production
capacity.
Used "Y" as default because
most battery receiving/
breaking areas are paved.
Used "Y" as default because
most battery receiving/
breaking areas are totally
enclosed.
Default calculated as
average of known values.
Used "Y" as default because
most battery receiving/
breaking areas have roofs.
Used "none" as default
because generally stated in
references if controlled.
Used "N" as default because
generally stated in
references if performed.
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
Defaults calculated using
ratio of known areas to
known lead production
capacity.
C-8
-------
TABLE 5. DEFAULTS GENERATION METHODOLOGIES FOR ARFUG_E.WK1
(Continued)
Parameter
Methodo1ogy
Is Area Paved (Y/N)
Totally Enclosed (Y/N)
Area of Open Sides
Roof (Y/N)
Baghouse ID
Scrubber ID
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Front-end Loader (km/yr)
Forklift (km/yr)
Furnace Area and Refining and
Casting Area
Area (m2)
Is Area Paved (Y/N)
Totally Enclosed (Y/N)
Area of Open Sides
Roof (Y/N)
Baghouse ID
Scrubber ID
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Used "Y" as default because
materials storage areas are
paved.
Used "Y" as default because
most materials storage areas
are totally enclosed.
Default calculated as
average of known values.
Used "Y" as default because
most material storage areas
have roofs.
Used "none" as default
because generally stated in
references if controlled.
Used "N" as default because
generally stated in
references if controlled
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
Defaults calculated using
ratio of known areas to
known lead production
capacity.
Used "Y" as default because
most furnace areas are
paved.
Used "Y" as default because
most furnace areas are
totally enclosed.
Default calculated as
average of known values.
Used "Y" as default because
most furnace areas have
roofs.
Used "none" as default
because generally stated in
references if controlled.
Used "N" as default because
generally stated in
references if performed.
C-9
-------
TABLE 5. DEFAULTS GENERATION METHODOLOGIES FOR ARFUG_E.WRI
(Continued)
Parameter
Methodology
Front-end Loader (km/yr)
Forklift (km/yr)
Materials Transport Area
Area (m2)
Is Area Paved (Y/N)
Totally Enclosed (Y/N)
Area of Open Sides
Roof (Y/N)
Baghouse ID
Scrubber ID
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Trailer (km/yr)
Front-end Loader (km/yr)
Forklift (km/yr)
Cast Lead Storage Area
Area (m2)
Is Area Paved (Y/N)
Totally Enclosed (Y/N)
Area of Open Sides
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
Defaults calculated using
ratio of known areas to
known lead production
capacity.
Used "Y" as default because
most materials transport
areas are paved.
Used "N" as default because
most materials transport
areas are not totally
enclosed.
Default calculated as
average of known values.
Used "N" as default because
most materials transport
areas do not have roofs.
Used "none" as default
because generally stated in
references if controlled.
Used "N" as default because
generally stated in
references if performed.
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
Defaults calculated using
ratio of known areas to
known lead production
capacity.
Used "Y" as default because
most cast lead storage areas
are paved.
Used "Y" as default since
most cast lead storage areas
are totally enclosed.
Default calculated as
average of known values.
C-10
-------
TABLE 5. DEFAULTS GENERATION METHODOLOGIES FOR ARFUG_E.WK1
(Continued)
Parameter
Methodology
Roof (Y/N)
Baghouse ID
Scrubber ID
Wet Suppression (Y/N)
Power Washing (Y/N)
Area Vacuumed (Y/N)
Front-end Loader (km/yr)
Forklift (km/yr)
Used "Y" as default because
most cast lead storage areas
have roofs.
Used "none" as default
because generally stated in
references if controlled.
Used "N" as default because
generally stated in
references if performed.
Defaults calculated using
ratio of known vehicle
travel distances to known
actual lead production.
C-ll
-------
TABLE 6. DEFAULTS GENERATION METHODOLOGIES FOR ABURN E.WK1
Parameter
Methodology
Furnace ID
Afterburner ID
Process Equipment Served
Operating Temperature
Residence Time
Exhaust Rate (act. m3/min)
Exhaust Rate (std. m3/min)
Percent Moisture
Percent Oxygen
Complete
Complete
Complete
Minimum known operating
temperature used as default to
be conservative.
Minimum known residence time
used as default to be
conservative.
Calculated from standard
m3/min and temperature.
Defaults calculated using
ratio of known exhaust rates
to known lead production
capacity.
Default based on average of
known values.
C-12
-------
TABLE 7. DEFAULTS GENERATION METHODOLOGIES FOR BHOUSE_E.WK1
Parameter
Methodology
Baghouse ID
Process/Equipment Served
Type of Cleaning
Fabric Type
Exhaust Rate (act. m3/min)
Exhaust Rate (std. m3/min)
Inlet Temperature
Percent Moisture
Percent Oxygen
Fabric Area
Air-to-Cloth Ratio
Number of Bags
Average Pressure Drop
Lead Outlet Concentration
Scrubber Lead Outlet
Concentration (if applicable)
Complete
Complete
Shaker used as default because
most used shaker.
Acrylic bags used as default
because most used acrylic.
Calculated from standard m3/min
and temperature.
Calculated from actual m3/min
and temperature.
Defaults based on average for
the type of equipment served
(furnace or sanitary).
Defaults based on average for
the type of equipment served
(furnace or sanitary).
Calculated from exhaust flow and
air-to-cloth ratio; multiplied
by 1.25 to get gross fabric area
for shaker baghouses; no
multiplier used for pulse jet
and reverse-air baghouses.
If fabric area available, then
calculated from exhaust flow and
fabric area; fabric area divided
by 1.25 to get net air-to-cloth
ratio; if fabric area not
available, then defaults
calculated as average for each
fabric type.
Not used to estimate impacts.
Defaults calculated as average
for type of equipment served
(furnace or sanitary).
Defaults calculated as average
for type of equipment served
(furnace or sanitary).
Defaults calculated as average
for type of equipment served
(furnace or sanitary).
C-13
-------
4.0 REFERENCES
1. Memorandum from Pelt, R., Radian Corporation, to George
Streit, EPA/ISB. June 15, 1992. Development of
Databases for Existing and New Secondary Lead Smelters
(Final).
2. Memorandum from Pelt, R., Radian Corporation, to George
Streit, EPA/ISB. May 17, 1993. Documentation of Input
Data Bases Defaults.
3. Memorandum from Pelt, R., Radian Corporation, to
Secondary Lead Project File. April 22, 1993. Battery
Composition Data (Final).
C-14
-------
-------
ATTACHMENT 1
SECONDARY LEAD SMELTER DATABASE
WITH DEFAULT VALUES
C-15
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