United States Environmental Protection Agency Office of Research and Development Washington DC 20460 EPA/600/M-90/020 November 1990 Vol.2 ORD ENGINEERING HIGHLIGHTS A bi-monthly compilation of EPA's Office of Research and Development engineering research activities and results and related research activities in pollution prevention and mitigation. To discuss any of these activities, contact the ORD lead person listed below. For general information, contact Darlene Williams of the Office of Technology Transfer and Regulatory Support, Phone : FTS 382-7891. Research in Progress Reopening of Oil and Hazardous Materials Simulated Environmental Test Tank (OHMSETT) Facility The OHMSETT Interagency Technical Committee (OITC) met on September 10 and 11, 1990, at the offices of the Department of Interior's Minerals Management Service (MMS) in Herndon, VA, to review progress on reopening the OHMSETT facility and to begin planning for the first test season. OITC members represent MMS, Coast Guard, Navy, and EPA, who have all historically funded oil spill research at the facility. OHMSETT was designed and constructed on the grounds of a Navy Base in Leonardo, NJ, under an EPA contract in the early 1970's. EPA conducted oil spill cleanup research at OHMSETT until 1989, when the facility was turned over to the Navy. The MMS has an agreement with the Navy to conduct similar research at the facility and will complete basic refurbishment of the facility. They estimate that the facility will open mid-1991. The research projects to be conducted at OHMSETT will include evaluations of chemicals that enhance mechanical recovery of oil, further development and evaluation of sensors to locate/detect oil pockets, and evaluation of novel skimming methods, especially those most suitable in broken ice fields or brash ice. EPA's role in future activities will be primarily advisory. The OITC will also address the provisions in the new Oil Pollution Act that prescribe committee involvement with approximately 8 other U.S. Agencies not currently on the OITC. (Rich Griffiths, RREL, FTS 340-6629) Nonfriable Asbestos Demonstration Conducted Recent research of asbestos tile removal conducted in test cells indicate that the aggressive dry removal method is undesirable. Six test cells (approximately 15' x 36' each) were constructed at Fort Sill, OK, to measure asbestos fiber emissions resulting from asbestos floor tile removal from concrete floors. Initially each cell was decontaminated by: 1) Dry HEPA Vacuuming, 2) Wet Wipe Cleaning, 3) Wet Mopping and Wet Vacuuming, and 4) HEPA Negative Air Machine Recirculation for 100 Minutes (equivalent to 50 cell air changes). Aggressive leaf blower testing was then conducted and the Transmission Electron Microscope (TEM) indicated a low level of airborne asbestos (0.004 structures/cmS). A static test prior to tile removal was then conducted with no asbestos structures observed. The floor tile was then removed using the #4 Scenario of Removal, Aggressive Dry Removal from concrete floor by hand, utilizing a maximum of workers to accomplish removal in minimal time. An average airborne level of 0.116 asbestos structures/cm3 resulted from the aggressive dry removal method, indicating the undesirability of this technique. (Thomas J. Powers, RREL, FTS 684-7550) CIS Cooperative Agreement With Ohio River Valley Water Sanitation Commission RREL and the Ohio River Valley Water Sanitation Commission signed a cooperative agreement to develop geographic information systems (GIS). The objective of the two year project is to develop and demonstrate a GIS that integrates: (1) a graphic mapping system with a water quality model modified for the Ohio River and, (2) a historical and ongoing data base of spatially related Ohio River Basin information. This research involves spill tracking and water quality characterization of real and simulated interstate spills to the Ohio River. Data output will include information necessary to provide notification of utilities at risk, determination of environmentally sensitive areas, and identification of spill response resources and Ohio River access points. Spatially related data bases such as SARA Title III chemical inventory data, land use, groundwater quality, and political boundaries will be included in the GIS for analysis. Tasks include: (1) comparing the cost and benefits of treating industrial and municipal wastes at the source instead of at downstream water utilities, (2) evaluating the relationship of stream water quality standards to various small systems' abilities to meet the Safe Drinking Water Act requirements, (3) determining the contributions of contaminated groundwater and surface run-off to river quality degradation, and (4) mapping areas near the Ohio River with large quantities of hazardous chemicals or potential for uncontrolled discharges into the water supply. (James Goodrich, RREL FTS 684-7605) Radon Diagnostics and Mitigation Program Expanded in Schools AEERL's radon program in schools has been expanded by addressing new geographic areas, soils, and construction types. Radon diagnostics were recently performed in two schools in Colorado and two schools in Washington with elevated radon levels. Measurements indicated that the radon problems in two of the schools would best be solved by installing active subslab depressurization (ASD) systems and that the problems in the other two schools would best be addressed initially by modifying the operation of the school's ------- heating, ventilating, and air-conditioning systems. Detailed mitigation system designs will be prepared and installed by the schools and evaluated by EPA. It is also expected that one of the Colorado schools will be used for long-term research in conjunction with EPA's Regional Radon Training Center at Ft. Collins, Colorado. (Kelly Leovic, AEERL, FTS 629-7717) Field Study of Oil Biodegradation A field study evaluating two commercial microbial products used for enhancing oil biodegradation in Prince William Sound was recently completed. The study involved a statistically designed experiment with four treatments on four similar beach segments. Nutrients and products were applied every 4 days, and samples were collected every 9 days. Samples were processed for growth of oil degraders, disappearance of aliphatic hydrocarbons as measured by gas chromatography, and decrease in oil residue weight All four plots receiving one of the commercial products developed sulfide odors after 9 days, suggesting the onset of anaerobic conditions. These conditions were not observed with any other treatment A progress report will be prepared containing results and conclusions obtained from analytical chemistry and microbiology data. (Dr. Albert D. Venosa, RREL, FTS 684-7668) Radon Mitigation Program Re-directed A recent peer review of the existing-house portion of AEERL's indoor radon mitigation program drew support for a re-direction of the program recently implemented by the Laboratory following an intensive strategic planning effort. The re-direction involved an increased emphasis on basic research, and a de-emphasis of field demonstration of radon mitigation systems in existing houses. The field demonstration effort had previously been the central component of the existing-house program. This re-direction was implemented based upon the recognition that the field demonstration effort for existing houses has now largely accomplished its purpose of developing and demonstrating existing technology. More basic research is needed in order to define promising new approaches to existing and innovative mitigation techniques before further field demonstrations for existing houses are warranted. (Bruce Henschel, AEERL, FTS 629-4112) Hold Placed on Construction of Environmental Technology and Engineering Facility (E-TEC) On September 13, 1990, the Senate Appropriations Committee recommended that construction of RREL's E-TEC Facility be placed on hold. EPA is planning to build and operate an environmentally safe place to conduct controlled hazardous waste tests of Superfund treatment technologies. This fully-permitted facility will be able to accommodate a wide range of technology evaluations, from laboratory-scale to full-scale. Although the committee supports research and development of innovative hazardous waste treatment technologies, they froze all funds previously appropriated for the facility until the environmental concerns of local officials are satisfied and the support of the State is secured. EPA contends that the proposed facility is safe and that the State fully supports the project. After obtaining support from local and State officials, EPA plans to make a formal request for the additional construction funds needed.(Daniel Sullivan, RREL, FTS 340-6677) Biorestoration of Jet Fuel Contaminated Aquifer RSKERL obtained background data for a field investigation on the biorestoration of an aquifer contaminated with JP-4 jet fuel at a U.S. Fuel Supply Depot in Hanahan, SC. The U.S. Geological Survey (USGS) is currently engaged in the design and construction of a full-scale remediation system employing infiltration galleries to deliver nitrate and nutrients to the aquifer. RSKERL acquired continuous core samples to delineate the vertical extent of contamination and to provide aquifer material for microcosm studies by both the USGS and RSKERL. In addition, cluster monitoring wells were placed to provide water quality information at various depths and existing wells were sampled. RSKERL is considering the site for a possible cooperative agreement with the USGS for a second field study on nitrate-based biorestoration. (S. Hutchins, RSKERL, FTS 743-2327) MINTEQ Model Updated MINTEQ A2, a computer model for estimating the dissolved fraction of heavy metals in ground or surface water at a waste site, has been improved and updated. MINTEQA2 is a geochemical equilibrium speciation model with a database that includes many of the heavy metals that are of concern at Superfund and other waste sites. The model calculates the mobile fraction of total metal by estimating the precipitated and adsorbed fractions. When used in conjunction with a hydrologic transport model, downgradient metal concentrations can be estimated in ground or surface waters. In this latest release (version 3.00), MINTEQ A2 has been updated to provide a built-in file of adsorption reactions applicable to many aqueous systems of concern to EPA. Also, an option that allows titrations to be modeled has been added, the execution speed of the model has been improved, and its output has been made easier to understand. (David Brown, ERL-Athens, FTS 250-3310) Technology Transfer Field Seaming Procedures RREL hosted a meeting of representative liner installers from the thermoplastics industry to develop a draft document for field seaming polyvinyl chloride, chlorinated polyethylene, chlorosulfonated polyethylene and ethylene interpolymer alloy geomembranes for waste management facilities. During the four day meeting the group discussed geomembrane and equipment preparation, test strips, the actual seaming process, procedures to follow after seaming and unusual seaming conditions. The information developed will be combined with an existing Agency manual on high density polyethylene to provide the Agency, States and engineering community with a state-of-the-art resource document on field procedures. The manual is expected to make a major impact on improving the performance of liners in field installations. (Robert E. Landreth, RREL, FTS 684-7871) ------- Membrane Workshop The American Water Works Association, EPA's Office of Drinking Water, and RREL's Drinking Water Research Division met with several membrane manufacturers, and university and private sector researchers to discuss the feasibility of using ultrafiltration membranes for removing precursors of disinfection by-products from drinking water. Presentations and discussions were held on research that has been or is being done with membranes relative to drinking water, future research anticipated, types of membranes available and expected in the future, and the possibility of membranes being designated as Best Available Technology for future federal regulations. (Ben Lykins, RREL, FTS 684-7460) Landfill Design Criteria Exposition The EPA exposition on landfill design criteria was attended by over 1,000 representatives from federal, state and local governments, consultants, equipment manufacturers and suppliers, and the general public. The meeting consisted of technical sessions on all aspects of municipal solid waste management including legal requirements, recycling, disposal, composting and leachate treatment. Individual technical sessions focused on the current state of scientific and technical knowledge in solid waste management. In reviewing the newer equipment, a seaming machine for synthetic liners was on display during the exposition that may be beneficial to the liner installation industry. (Robert E. Landreth, RREL, FTS 684-7871) RREL Engineers Lecture to Graduate Students A lecture entitled "Cost Modeling for Drinking Water Unit Process" was presented to about 15 University of Cincinnati graduate students and their professors. The lecture represents the last of a series of 13 lectures given by RREL staff to the students as part of their graduate course, "Advanced Physical-Chemical Treatment." (Robert M. Clark, RREL, FTS 684-7201) Cable News Network Coverage A Cable News Network (CNN) Science News film crew interviewed key personnel and videotaped experiments in progress at the AREAL Fluid Modeling Facility in Research Triangle Park on September 5, 1990. The three-minute presentation was aired on October 12-13,1990 on CNN News, CNN Headline News, and on the program entitled: "Science and Technology Week" which aired on October 14,1990. The presentation showed the simulation of flow and dispersion of atmospheric pollutants in the 60-foot long wind tunnel and the 80-foot long water tank. Last year, the Fluid Modeling Facility was featured in a national television production program entitled, "How about... in Science". (Bill Snyder, EMSL-LV, FTS 629-1198) SCAMP Research RSKERL hosted a meeting to plan research to be carried out under the Subsurface Cleanup and Mobilization Processes (SCAMP) initiative. SCAMP research will start this fiscal year and is designed to acquire information that will allow the development of a decision-making framework for evaluating the appropriateness of pump and treat remediation of contaminated ground water and to assist the Superfund program in improving its efficiency. The information will include site characterization, immiscible fluid flow, heterogenous media, sorption, accelerated remediation, and technical assistance. Meeting participants included representatives from EPA Headquarters and regional offices, universities, engineering consultants, and RSKERL staff. A final research plan for SCAMP is expected to be completed early in 1991. (S. Schmelling, RSKERL, FTS 743-2434) Pollution Prevention Manuals Published Six pollution prevention publications were published during the past two months. These guides provide an overview of the operation that generates wastes within industries and institutions, identify techniques that would allow companies to reduce their wastes through source reduction and recycling, and provide a set of self-auditing checklists to assist these industries in setting up a waste reduction program. The Pollution Prevention Research Branch is working on eleven additional industry specific manuals for this year. (Lisa M. Brown, RREL, FTS 684-7634). EMSL-LV Monitors Space Shuttle Launch ORD scientists, as part of an interagency emergency response team, monitored the recent launch of the space shuttle DISCOVERY. Because EPA establishes guidelines for radiation levels in the environment, Agency scientists and staff have supported space launches since the 1960's and more recently through their participation with the Federal Radiological Monitoring Assessment Center, an interagency organization that responds to radiological emergencies. On this flight, the shuttle carried "Ulysses," a space probe which will ultimately orbit the sun to collect scientific data. Ulysses contains 135,000 Curies of radioactive material, Plutonium-238, to provide electrical power to the Ulysses instrumentation. Under EPA guidance, ten field teams with special portable detection instrumentation established a 32-station air sampling network downwind from the launch site. The air sampling network was activated during the space shuttle fueling process, eight hours prior to the launch, and continued until the shuttle was out of the Earth's orbit. In the event of an accident, EPA would have been able to provide data on crop and population contamination to the Federal Emergency Management Agency, the Department of Agriculture, and state and local authorities. (Robert N. Snelling, Director, EMSL-Las Vegas, FTS 545-2525) REGIONAL ASSISTANCE Multiple Technology Treatability Study Under the direction of RREL's START team, a multiple technology treatability assessment was performed for the Halby Chemical Manufacturer site located in Delaware (Region 3). Four treatment technologies were evaluated: biological, low temperature desorption, solidification/stabizat- ion and flotation. The desorption process was followed by stabilization for a treatment train evaluation. The results suggested that the carbon disulfide and thiocyanate compounds may be able to be degraded with indigenous microorganisms. Low temperature desorption removed the ------- volatile and semi-volatile compounds. The effectiveness of stabilization could not be determined since the raw material did not leach. Flotation was not effective. The Region will combine these data with a risk assessment A valuable engineering study is recommended because of the unique hydrogeological conditions of the site. (Ed Earth, CERI, FTS 684-7566) University Biotechnology Center On October 22, 1990, top ORD officials met with the Chancellor of the University of Florida System and the President of the University of West Florida (UWF) to announce the opening of the Environmental Diagnostics and Bioremediation Center, a biotechnology center at UWF. The Center was funded by a grant from the State of Florida and a cooperative agreement between the EPA and UWF. The Center will initially staff 4 faculty members and post doctoral research assistants who will conduct bioremediation projects at UWF as well as the ERL facility in Gulf Breeze. Cooperative research between UWF and ERL-Gulf Breeze has been going on for a number of years, especially research on development of bioindicators for bioremediation studies. (R.E. Menzer, ERL-Gulf Breeze, FTS 228-9208) Incineration Meeting on Flint, MI Superfund Site A slide presentation on hazardous waste incineration, followed by specific questions on modern transportable incinerators, was given in Hint, Michigan, on August 9. The focus of the four-hour public meeting was the remediation plan developed jointly by EPA and the Michigan Department of Natural Resources for incinerating the remair:ng contaminated soil and water at the 20-year-old Berlin and Farro Superfund site. A large inventory of waste drums and a core volume of the more heavily contaminated soils were removed and incinerated off-site, but the remediation plan now specifies excavation and on-site incineration of residuals. Approximately 150 participating citizens voiced strong objections to any on-site incineration plan because of their recollection of smoke and odors associated with a previous "incinerator" that formerly processed waste at the site during the early 1970's. The citizens requested a follow-up public meeting to include participation by the Regional Administrator and details on other sites successfully remediated by incineration. (Donald A. Oberacker, RREL, FTS 684-7510) Seminar on Solidification/Stabilization, Soil Washing and Extraction RREL presented a brief seminar in Chicago, IL, to the Regional Project Managers and the On-Scene Coordinators regarding potential treatment technologies for lead contaminated soils. Technologies covered in the seminar included solidification/stabilization, soil washing, and extraction. In-situ vitrification, flash smelting, and electrokinetics were also discussed. Results for treatability testing involving these technologies and lead were summarized. Approximately 40 regional personnel attend the two-hour seminar. (David Smith, RREL, FTS 684-7957 or Paul DePercin, RREL, FTS 684-7797) Metal Speciation Studies at Superfund Site The ERL staff used the MINTEQ metal speciation model to analyze potential mobility and bioavailability of cadmium, copper, lead, zinc, and barium in sediments adjacent to the duPont Newport Superfund Site in Delaware. These studies, carried out for Region 3, clarified the need for chemical analyses at the site, as suggested by an earlier ERL technical assistance project. The simulations predicted that oxidizing conditions would, in general, cause the highest degree of solubility in all these metals except barium, which would be most soluble under reducing conditions. (Robert Ambrose, ERL-Athens, 250-3130) United States Environmental Protection Agency Center for Environmental Research Information Cincinnati, OH 45268 BULK RATE POSTAGE & FEES PAID EPA PERMIT NO. G-35 Official Business Penalty for Private Use $300 EPA/600/M-90/020 ------- |