600R81102
                                                                ^7~Ci-
SPA  QUALITY  ASSURANCE  OFFICER'S  HANDBOOK
                              Voiume i
                              n n : c a"  As""' "tcrc0
                                     PfOt«ct»on Agencyj
                       R.Ag«t-    dbrary
                       210   -h Dearborn Street
                       Chicago, UUnott 606QA
                      Ouclity Assurance Management Stcff
               Office of Monitoring Systems ana Quality Assurance
                    U. S.  Environmental  Protection Aasncy
              -;•• '..  -.; .   , .  .fOl M Street,,; s;.w..  ./•.
                          •Washington, O'.C. ' 20^60 '     -    '

-------
                                                 Section  No.  Introduction
                                                 Revision No.  	C \ 	
                                                 Date:  _  . February , VoT
                                                 Page   "  "	OT
                               INTRODUCTION

      This  directory  of  services,  materials,  and  performance  evalua-
tions,  available  from the two  Environmental  Monitoring Systems  Labora-
tories  (EMSLs),   locatsq  in  Las Vegas,  Nevaca,  anc  Sesaarcn  Triangle
Park, North  Carolina, and the one  Environmental Monitoring  and  Support
lascratcry  (also  EMSL),  located in  Cincinnati,  Ohio,  is offered  by the
Quality Assurance  Management Staff  (QAMS)  in  response to many  requests
from 'reel ana!  and program  office  Quality  Assurance  (OA Officers.   Its
surpass 'is  to  olace  uncer cne  cover information  recarc-ing  availaoility
of  ,T atarials  and  technical  assistance  frcrn  the  QRD/EMSL  faci 1 ities.
These materials  are  inaae availacle  to autncrized  laboratories  free  of
charge,   =1 enough  there .•nay be  !"estricticns   in seme  instances  en  hew
these s aisles  are  usea anc  how  results of analyses  are reported.   The
niLTi^ if  crircioai  ccr.tac": for  :.iasa CA  materials  anc  services  are
inclucac tc  facilitate tne  flew  of  information;  where telepncne  numbers
are not croviaed  for the  principals,  it  is requested that  inquiries  be
mace througn correspcnaence.

      This ccmoendicir,  is  providea  in a loose-leaf format  sc that  pages
                      i
can easily  be  replaced as  infcreation is  accec,  aelezec,  cr otherv^'---
revisec.   Our   intent  is  to   revise   tnis  aocument   as  circumst?" .~i
require.   GAMS welcomes  comments  ana  suggestions   for ennancir.g  the
utility  of tnis publication.

-------
                                           Section No.    EMSL-CI
                                          .Revision No.       ?
                                          'Date:     February 1981
                                           ?aae    1      or  :,-
                      EMSL  - CINCINNATI
                    26 W. St. Clair Street
                   Cincinnati, Ohio   45258
                  Director:   Robert L, Bcotn

                WATEK AND WASTEWATHS  ANALYSIS
                                                    wt * W T w ^ i ^ii^
       Quality Centre! Saruie ?rccr^~
(II)   7ne EPA Repository for Toxic  an.c  Hazardous  Mata?
(Ill)  Surrogates and Internal Starca-ds
(IV}   Perfcrrnanca Evaluation Stut'-ii.
(V)    Special Stuciss
(VI)   Alternate Test Procedures
(VII)  Development of Monitoring Methocs  ana  Standards

7ne cet. ', "• follow:

-------
                                                 Section No.    -EMSL-C.:
                                                 Revision No.       0
                                                 Date:    February  ISSi
                                                 Pace    ?     or    '.L
I.    QUALITY CONTROL  SAMPLE  PROGRAM

      Quality  Control  (QC)  samples  are  furnished  without  charge  to
interested  governmental,  industrial,  commercial,  and  private  labora-
tories  for  use  as  secondary checks  on their  within-laboratory  quality
control programs.   The sarnoles  are  intended as  indeoendent  measures  of
tacrsr.icue and  perfcrT.ancs,  net  as replacement  for the standards, repli-
cates, -or- so ike samples -run  routinely- .as  part. of. ,.tne , .laboratory' s  own
QC program..   •                         •  •

      ""hsrs  is  ",z  certification  or  other  "crrral   evaluative functic-
"=5: u It ire -^rcm  tne  usa  cf  QC  sanroles.    No  reoorts  are precarec  anc
there  is  no  recuirernent for use  cf specific  methocolcgy  in  tr.ese  GC
analyses.  Tne  Quality Control  Sanole Program  now covers water Quality,
cr^Kir-g  ^atar,  anc  t~c  r^iority pol                             ~"
w— j. , C — <. ^ anc u— o.
       ..- •--•A ^ c"r\c ' ""no v  cr.^c  T^^Tr*  ^MH  tJ
       ,~;~ C.'n f\X.'Jii i OKI  i UK  ivw^iL  AnU  rt
      LMSL-Cincinr.ati  has  established the  EPA Reccsitory  for  Tcxic and
razaraous -Materials  to  provias  a  continuing  source  cf
r.atcr* als, standards  and  -eferenc- comocuncs  needed  bv  EPA.
                               *
tne  Repository  will  proviae  the  Priority  Pollutants,  but  will  be
excanaec  scon  to cover all  trace organics of  interest to  tne Agency.
For examole, personnel  .are being, acaea  to support tne  broacer nescs o*
tne'  Hazardous'  Wastes  Program.  '•' Also,   EMSl-CI'  wvll:  aco'uire  a  gas
cnromatograpn/mass  spectrcmetry  (GC/MS)  library  of   acorcxinately  2CCG
trace organic  compounds wr.ich  have  been  characterlzsc  anc  storsc  in a

-------
                                                 Section No.  -MSI-
                                                 Revision >lo.      C
                                                 Date:    • :goruary 19S1
computer  data  base  as  part cf  a  contract administered  by  the  Health
Effects  Research  laboratory  -  Cincinnati.   Because  a  nuptier  of  the
toxic  or  hazartacus  cornpouncs  are  increasingly difficult  to  obtain  as
.manufacturing  ana cnrn^ercial  uses  are  restricted,  the Reoository  has
oeen  giver,  the  staff,  ecuicrr.ent  and  facilities  neeced  to  purify  ar.a
upgrade  chemicals,  and  to   perform   come lex  chemical  syntheses  for
•jnattainci la ccmcouncs

-------
                                           Section No.   EMSl-C
                                           Revision No.  _     0
                                           Date:    February  i
                                           Pace    A     cr   "
                           Table C-l
  \

      QUALITY CONTROL SAMPLES FOR WATER  QUALITY ANALYSES

DEtfANO ANALYSES  -  30D,  COD,  TCC

MINERAL/PHYSICAL ANALYSES  - sec: us:,  potassium,  calcium, magnes-
ium,  DH,  sulfate,  chloride,  fluoride,   alkal inity/acicity,   total
hardness, total  dissolved  solias,  ana specific conductance
Nliirt.-Ni- — nitrate— N»  aji-Ticmc— >•<,  \js ican •— <>, crwnc3,.C33r,a~s,  ird
total-? :  • "• ""••   !" •••-••-••••    --..'.            ...
  ACE  NETAL-S -  El-jminum,  anii^cny,  arsenic,  beryl
TRACE METALS -  anfirr.or.y,  ma 11'LT.,  and si'.vsr

^INEAR ALKYLATE  S'JL'ONATE - LAS, the  an ionic  surfactant stancarc/
MQi^ T^CT
CHLORCPHYLL - ScectroDno'ome'cric anc rluorcrne'ric analyses

MUNICIPAL  DIGESTED  SLUuGE - 25  inorganic  and  general :rgani:  -ir-
air.oicrs

OIL'AND GREASE

PETRCLELM  HYDRQCARSONS  - two  crucs  oils,  No.  2  rue]  oil,   ana
Sunicer C (API Reference  Oils  for characterization analyses)

PHENOL (^AAP Ms-hoc)   ....

PESTICIDES -  alcrin,  dieTarin,  DDT,''DDE, DDD,  hecta-cn'lc'r, chl'or-
cane

PCLYCHLCRINATED 3IPHENYLS  - Aroclcr  1254 anc 1015

VOLATILE ORGANIC - six to  nine  ccnccuncs,  including THM's

-------
                                                  Section  No.    EMSL-CI
                                                  Revision No..
                       u
                                                  Date:     February i98i
                                                  Paae     -of   •;
-------
                                                      Section No.   EHSL-CI
                                                      Revision No.       0
                                                      Date:    February  iSSi
                                                      Pace     c-    or    id
 *          To  establish  Qualitative  identification  and   determine   purity,
      Repository  compounds  are  qualitatively and  quantitatively measured  by
      at least two  independent  methodologies  by the Repository staff  and  sub-
 ~    saauently verified  by at  least t*o  referee laboratories.   Significant
      aifferencss are resolvea before release of a  compound.

            Tares grades of materials will be established
•            •
            (1) .-Quality Assurance Star.aarcs "'(CAS)'_>  $'9 bercsnt surity
            [2]   Quality Assurance Reagents (OAR; 95-98 3ereant surity
*           (3;   Guci'ty  Assurance  Tecnr.ical  Material-:  (CAT;  <  93   pa-cert
            The Raccsitory  will  move as  many  ccrnccuncs as  oossible frcrr. the

      tacnniques.    Multiccn:pcnent  materials,   sucn  as  po lycnlorinatac  'z~-
      pnenyls  (PCS's)  ana  toxaonene, will  be  categorized  as  CAR  or  CAT anc
      wil| net ba purified  further.   A  list cf the first Repository mataria" 3
      to 6e distributee in January 19S1 is given in Table C—.

-------
                                             Sect-ion  No.    E^,SL-OI
                                             Revision  No. ;	Q
                                             Oate:     FeL-uary ISS:
                                             Pace     7     or    14.
                             Taole C-i

      REPOSITORY MATERIALS TO 3E  DISTRIBUTED IN JANUARY 1981

    Concentrations are 5,000 ug of OAS-oure  compouna per ml of
             methanol solvent unless  otnerx'ise noted.
ECC4 Senzsne  (1C,COO  uC/rnL)

E007 -1,2,4—Trich-lorobenzene
cr,rn  ir ortacrtren0
£{JC6 'Ch'lorefaenzerre-
     r .ucrantnene
EG54 Nitrobenzene
                                                       "^». Ci w
EC'S 1 N-N-; trcs cc - -rs-orocy 1 am' ne

EC55 ^-n-tjuty'1 prthalata

EOS9 Dimethyl ohthalate

E079 Phenanthrene
El04. PC3-Arcc',cr 12-2  (CA")
EI09 ?C3-A.roc:cr 1250  (OAT)

E022 2-ChlcroDher.cl

Elll .Toxao-feane- {-QAT.)-'   ... .
EOo-i bis i 2-E'riy i  nexy t ,'•  cni

£063 Oletnyl onthalate

E073 Fluorane

EC3^ Toluene (10,000  uc/mt)

E107 =03-^rcc:or  1222  (OAT)

E11C ?CE-Aroclcr  1015  (OAT)

EOS3 Phenol

-------
                                                    Section No.   EMSL-CI
                                                    Revision No.       0
                                                    Data:    February 1951
                                                    Paae     s      c*    id
it"
    .
             fTr <"sMcr>i "unc **T.  r\!TC-vu  s~T" '-TV- r ~
             M I L. <_v,rV'jLnLJj ntiu  ;,r<  ^- — -3
a".cre23Jii ..  £/.arrnle5 of  so/ne_  of tne  s.ui — ccats  ••cmoc'jros
c r ip^ ^.rQ c  trict  a*"'3 • b*ino  cor^idsrsc  for  inc'''">"cn   in  ".^.

-------
             Table C-5
            METHOD  52^
                              Section  No.   iMSL-CI
                              Revision  No.     •  0
                              Date:     February  19;
                              Pace     a     CT    <.
        ] benzene
 d,5 -benzene
 cp— to 1 iiene
 1,4-d if luorocer'zsne

 -> - -, _; — " Y " >•> — r. •* a r\ ~

••dlbrontof Tuoro oenz ene
 oromocr1crcmetnan=
 A         * .— ' "1 j. ._.  J1H. «fc -
 ^ »i-f • f^ ^^ *l  I -mr,    *T ^ ' ^ ^ *1 /-



 u 9 ""i- ^ ^ • u *










            METHOD  62:



^-f luorcohencl
rcertaf 1 'jcroonenc"!
 GS—Dne^c";
 d-^-Z-n •; crccrsro"

 /•  -• t  _.;•_,.,»_.,.  «_*-jr-,,
 —, — —<„ : _ rcmc—- •	c  , j
r^*  — i'*^T*'~'3nT ^ "ti^ —
 . —i l ««>j i ^Gl! I i , i 'C
 ceCaf"ucrcc icneny"
          ha lens
•<;*•./*—• y £T*en e
 d* ~— C^'T" v^ inc

-------
                                                 Section  No.    -MSL-CI
                                                 Revision No.       Q
                                                 Data:     February I9Si
                                                         10    OT   ", 1
IV.   PERFORMANCE EVALUATION STUDIES
                                            '                         V

      Performance Evaluation  Stucles have  tne primary purpose  of  regu-
larly evaluating  performance  of  laboratories  as  requirea  oy  E?A  man-
Gates or  by  program request.   One or  t>o  sample concentrates  for  each
oarametcr croup cf  Interest are sent  to  participating laboratories  for
s- Ik Ing  Into  a labcrtcry-pure water,  ana analyses  w'tnln  a  set  tlir.e
Interval... ;  Performance., Is,  juc.gsa.. .ircnv  analyses, in  a  lacoratcry-cure
water r = ther tnan wastawaters  In  orcer tc remove variable  31"-'?  -natr-ix
           • i'rcrn ~re eval uatlcris
      ,re  -er-crranca evaluation  stua:es  sresent.y  avai.aoie  re*-  i.-A
laccratcrles, E?A extramural  prefects,  and the State  arc  local  agencies
fcllc^,   /*1~  tr.e a-croxlmata  oerlocs curlnc  wnlcn sa,T,c:es  rav :e  re-

-------
                                            Section No.    EMSL-CJ
                                            Revision No. 	0
                                            Date: 	February  I1,  j
                                            Pace    •,';     or -  id"
                            Table  C-7

 WATER SUPPLY  STUDIES FOR DRINKING WATER CERIFICATICN PROGRAM


 Parameters - all MCI Parameters:

    Trace Metals - Ag, As,  3a,  Cd,  Cr,  Pb,  He, Se
    Nitrate/Fluoride
    Lincane, Encrin, Metncxycnlor,  Tcxaohene

    Chloroform, 3rcrrx:fornis  Brcnodicnlororretbane,
     . Ch 1 orod i b rcrr.ome tn ane
           1-Free Chlorine,  Turbidity
                                           i  i •*'*   <~ ' — ^
                            i Cu i S  ~—C


                    'jfi-rr  DQI i MTTnw ^""sr.Trx
                    ™ ^ 1 ^ •)  Wlr^wti Itit^^T/wwlWIUf^  < "^ IM
            Potassium,  Calcium,  Magnesium,  Cinlcrice, F'ucrice,
            Suit ate
 Nutrients - Aranonia-M, Nitrate-N,  Kjelaanl—N, Orthcphcspnate,
             Total -3
 Demands  - BCD,  TOC, COD
 Trace Metals - Al, As, Be, Cd,  Cc,  Cr,  Cu,  Fe, Hg, Mn, Ni,  Pb,  V,
               • Se, Zn, Sb, Ti,-.Ag..- -  •    ••  • .         .-•';•
'•Halogenated Purgeab1.es (1.1)   '•   .     .-      .-•''..   --'"••
 "C3!s - 1C15 ana 125^
 Pesticides - Alarin, Dielarin,  GOT,  DDE,  DDD, Heotacnlor.
              Chlortiane, Cyanide

         Study Me.                   S_ajnole  Request Pericc

           WP007                           3/si - S/S1
           WPOC8                           9/81 - 2/82
           WPOC?                           3/SI - 3/52

-------
                                                 Section No.   g-'SL-CI
                                                 Revision 'No.      S
                                                 Date:  	' rebruary 1981
                                                 Pace   i >•     of   i~i
V.    SPECIAL STUDIES

      Priority  Pollutant  Categories  for  GC  analyses  - 12  categories
available.   Priority Pollutants  for  GC/MS  Analyses  (as Volatile  and
Senri-Vo 1 atila Compcuncs).

      AuCiticnal  information  cc-ncarning auallty ccrtrol  samples,  toxic
anc nazarcaus materials  rssocsizcry, ana surroga*3 ccmpouncs  ana inter-
nal stancarcs may be optained from:

                            Ocnn Wi ntar ,  C'.'. i ef
                         '"'•ual't'*-' .-ssurarcs 3rincri

-------
                                                 Section No.   EMSL-CI
                                                 Revision No. 	n
                                                'Date:    February  981
                                                 Page    15    or	

VI.   ALTERNATE TEST PROCEDURES

      In adaiticn  to  these services and materials,  EMSL-Cincinnati also
provides direct  supncrt by  administering  the  Alternate  Test Procedure
Program in bctn  the  National Pollutant Discharge  Elimination System and
the National  Interim  Primary Drinking Water Regulations.   All alternate
test  procedures   intended  for  limited use aoolications  that  are  con-
sidered for  approval  at the  state and regional  level  are  forwarded to
•MSL-Cincinnati  for  technical 'review  and  consistency  witn  previous
actions.   Raccnsnencaticns   are provided  tc  trie  reauesting  region  ar.c
acorocriate  program  office.   Acolicaticns  fc~  nationwide  aocrcva!  are
*''^mi"""a/*  "^"<3'~~ 1 >' ^"  '"h*  'j"7*Q<"*'^y*  •*"f  rvicr _^"i^,cinr'""'  ~""r  ~^f"*^ii~•$~.
review and  appropriate acriinistrative  actions  to result  in publ "idcticn
in  the Federal Register.

      Information  recarding   alternate  test procedures  'nay  DS  obtained
from:

                               Larry  Lcbring
                            Actina OA  Officer

-------
                                                 Section  No,
                                                 Revision No.       0~"
                                                 Date:  .   February 1SS1
                                                 Page     1 -    of   1 «i

VII.  DEVELOPMENT OF MONITORING METHODS  AND  STANDARDS

      Indirect  support  is  also  provided  by  developing  standardized
analytical  test  procedures  "o   identify  and  measure   pollutants  and
quality  characteristics,  both  cnemical  and  biological,  in  drinking
water,  ambient  receiving  waters,  and effluents.   EMSl-Cincinnati  also
cevelcns  auality  assurance manuals for  use  in water colluticn  measure-
ments.,   .._''_

      Ir.fores*ion  rsgarc'r.g tre  cevslocrier," cf  new  ~cri~cr"rc  r.ethocs
arc srancards ~av ^a attained frcm tr.e Dir£c~2r,  Sooert  '_.  3cc*r..

-------
                          jjCticr  No.
                          Revision  Ho.
                                                      U
                                                  or

   .c  'JV ;m."'=  • -C .. '.CIlGsi  -ffl'^H
  .... -,f •

yfca:  values  cs'ained  oy  ctr.er  sartic'ipc-

 1s  ri"';-.'"ISC  tc i3CM Ocrfici^cn": .   T's oroq:




         ».".-: i. C "  ".""T" . aOCri'CT" . s^, .

•-.arra;  suai'.'y ccntro i  procra.Ti in  coerancn  10 an sura
                           i r ;


-------
                                         Section  No.
                                         Revision No.
                                         Daze      Fecruar
                                         Pact     ?      or
CT  iTi^U'id  C0i1t2 1
                                        VdriOuS  IS'v'ciS Of  **,:ijlO
^C^w^i wi*wt  >w^«

• -T-y-.r, i i  ;  ; te-  ' iirv ts  T
:r. i<3 or. i  'jiincmin 'iy  b is i s .
                           ~ *-1 n ", *^ c
                        cntzinInc  urarriurr—22S  2rs

-------
                                            '  Seen on  No.  	
                                              Revision  No. 	0
                                              Date:     ;ebruarv  -?*'.
                                              Pace     •>     j"

        »• u  u i * •* -
                            " " '   ";• i i .•-„!" f    >•»;-; ' -A" • ' ;r ._.'; _!
       wo-;ncii-a  -ime'sr air  f-iltert  are
cuar'isr ; ,  -or
,",-, r'2 a."  -i". cer-: ari  Sent ^c  e=cn
                                              CCHtE 1 n "i HC
                                           :s,  t;/u=  :r  dna-j-


-------
                                         Data:     Fasr'jary 193:

                                         Pace      I     of   2G "
i       i
                                       T
                                       C
     -31   _ -.
                  -1   «
                  •f   =
                  a   5

-------
„-.   3
                                         i2C • • -' i
                                         Data:      -aaraary i •.-":.
          <  -k.   ;:  '
               I   i  i
          i  3J  If"
          i  - i
               I
             I.
             •;

-------
                                               Section  No.    EMSL-L7
                                               Revision  No.       0
                                                         February 1981
                                               Pace      o     or     /n
                               Table L-A
        RATIOS OF ACTIVITY MEASUREMENTS PERFORMED  UNDER  THE E?A
      rRACEASILITY PROGRAM WITH N8S, JANUARY 1974  TO  JANUARY 1980
                                                        £?A  Value
                                  Nucllda               NSS  value

i r«ct  7r ac.=£o i 1 ", "y :.
           jubnritt^c to NSS
                                                            ^G JT
                                    'Sr
                                   90Sp

  iNSo-oreua  ;<2  sarnoles  ssnr
  to the  EMSL-LV       -            14C

                                                         0.577
                                                         0.99=
                                                         1.015
                                                         O.S95

                                                         I. 027

-------
                                 CONTENTS
Section
INTRODUCTION


£MSl-£INCINNATI



EMEl-LAS VE3A2
Paaes
  WM>




   1



  14


  ?n
Revision    Cats
   /•»
   u
   0


   n
2/81


2/31
                                              i r>
                                              i w

-------
                                                   Section No.    --aSl-lV
                                                   Revision No.  ^^^
                                                   Data:  •  February .
                                                   Page   ->3      or
                           Table  L-A. (Continued'
                                     NuclIda
1?A VclL'S

N8S Value
Irci1**?ct Tricssol 1 i~v (Ccntlnuscj:
                          sart
                                                              n ccc,
                                                              w • ^ "— ^*

                                                              0.319
                                         :U
                                      "
                                      ,, Ac
                                           "
                                                              *  -^ *~ f,7
                                                              ^ * v ^- -*
                                                                C—, JHS *
                                                               .^•c_
                                                              » . 
-------
Section No.  EMSL-LV
Revision No. 	0_
Date: 	^
Pace    n    OT
                                                          >reoruarv ::?fti
                                                                    in.
       AQUEOUS  CALIBRATED SAMPLES
      The  inventory  of calibrated samples consists  of a number of cali-
brated  racionuclice  solutions   (Table  L-5).   Except  for  Ioaine-121,
every effort: is mace to  maintain this inventory  so that  samples can be
s.nioced  in a timely manner.   Iodine-131  is preDared  bimonthly anc dis-
"r'outao  to requestors on  record.  While  cne types  of calicratec sam—
u-les  in  tne  inventory vary  during  the  year, -every  effort  is  made- to
'oeo  ~r.°  tali orated solution  s ancles listecs  in  Taole  L-2  in  stoc:: ana
       i-rc-cr.aut  the year, trsa  acciticnal  racicr.ucl ice solutions listac
 ' ~  Taule L—5 are  calibrates anc  mace  available for  distribution.   Tie
'C'-ality  .-iSurancs Division  will  :btain,  calibrate,   anc  distribute any
scl'Jticr"  ire  rrscar^c *s time: rsmits^  and  as the Division  is  5.0! s to
•^aimrain  :ne aoove  inventory.
 . as ie  L-C  are ca:"orEt2C-.  Letters  w* i ;  oe sent  to  orevicus  recuestors
 cf  low—level  racicnucl ice  solutions  to  efficiently  allocate  tr.e  ais-
 tributicn cf  these solutions.

-------
                                                    Section No.
 131-
"223.




:ALIHRATED
Type-
Emission
5—
M ^
-
v
2 — , ?
3—
'S-Y "
3 —
3-,r
T
S-.T
5-,r
3-.T
•r
2-,T
S-,T
3->T
•••4 . ._ .
3-



Tab!
RAO I ON UCL IDE
Half-Life
12.35 v
• ' 5730 '/•••
312.5 a
- '"^ - - -
5 .271 y
32 y
244.,! d
30 . 5 c
255 a
452 d
250.3 d
2.77 d
3.04. c
10.5 y
2.052 y
20.17 a
234. 3 a
' 1500. y • •
3.75 y
A
\
1
i

e 1-5
SAMPLES KEPT
Major Sanma
Peak (MeV)
_
—
0.523
U . «^i
AHA,
	
" ' 1 * C'
—
0.312
G.QSS
0.553
O ^ *? C
w • ^"^i
0.254
0.235
0.505
0.552
0.134
r~* '
—
Revision- No.
Date: Fenr
Page 12

IN INVENTORY
Abundance

—
9S.97S
iC . 0
100
—
30.73
—
20.5
3.72
94,5
29.6
31.2
52.4
97 .5
33.0
10.3
• '•;-—-
—
0
tiary isai
or 20


aorn/ c*
' 0 00r>
10,000
< r< ^rr-
*<, , ^wL-
w W , J U vj
-" ^cn
•^•w ? WwW
10,CCG
• 150,000
15'*^
150,000
-0.2 uCi/c
30,000
220,000
-0.4 yCi/g
150, CCC
iC,COO
20,300
220, COO
• .10., 000 ".
30,000
                          .7 x !£T

-------
                                    Section No.
                                    Revision No.	
                                    Oara:    Fecruar • IBS'.
                                                                    0
                                                         '

                          Table  1-3  (Continues)
SO-CDS
  Type                   Major Sairma      Gamma
Emission   Half-Life      Peak (MeV)   Abundance
                                                                 cnni/c
                                                                      *

   Tr,
   1 t 1
                ~~
          1.4 x 10xL y

               72 .y
                       4.5 x 1C- y
                          L V  '    ' /
                          > A  iw   J


                          1 -1 . -1 V
                                                                  10,000





                                                                   5,OCO


                                                                  • ",  *»nr.
                                                                  , j , - L'j
'Apcroximata. activity (ccnj/g) cf tne  isotcoe  en  the caia cal Itritc'-.

-------
                                                  Section  v!o. ^	
                                                  Revisio: :No.'	0
                                                  Cats:     reoruary 1551"
                                                  Paae     TZ    or*   20
                                 Table  1-5

            CALIBRATED SADIONUCLIDE SAMPLES- SUPPLIED AS NEEDED
Isotcce
  Type-                   Major  Gairnia      Garnna
Emission    Half-Lifs     Peak  (MeV)   Abundance
                                          nm/ c
                                                                        *
 -ic-
   W-J
              3-,-r
 32.30 G

•3 — 7 n'' /-
* V • ^ V** '-i
               7f, 3 ^
               / W • NT »"A
                                          r,
                                          0.220
                             4..S Q   - - -  LOSS-
                                          0.255
                                          .3.2        6^0,300

                                          'G "-H        ''C  000


                                           y .30    = u .c  yu "• ; -.
                             SO.i

                             = 0  ?
                                         „ C U -
— ' 7 w —
95Ir a-,r 62.
10°Ru r 23
"So 3~jT 5C
1350a r 127
ldiCa " S-.T 22
He S-,T ^c
1
107 d
.98 d
.25 c.
.20 c
S *» H
.50 a
.c9 c
2£ y
w
^
t
n
W
(^
u
0
c
w
w
n
w
.S26
• / -/
.497
.502
-_5c
.1-5
. 4. / -
.570
99 .25
5~.2
35 . 4
97.9
30.0
••a . 0
-_ . Z
97.3
150,000
** *^ O ^ ^ O
•v« W W ^ •** ^* W
220,000
160,000
150,000
-cr r"-.r
w C* -J , WWW
150,000
^i W •) ^ W\J
       Iir.ais  activity  (cprn/g)   of  the'  isctcoe  on' the  data  calibratac,

-------
                                                  Section No.    EMSL-LV
                                                  Revision  Mo.0
                                                  Date:
                                                  Pace    i s     or*
                                                     February  iiSi
V.
SPECIAL REFESEflCE MATERIALS
      Calibrated  soil  sainoles'for  use as  reference  materials  are  also

available.  These  sarroles have  been cried, ground  to pass a  170—rcssh cr
a  200-rsesn  scrserr,   and   carefully  blended.   Reports   of   calibration
                                            »
accessary  the saisples.   The  sarr.Dles  are   packaged  in  glass  containers
wnicr. contain  accroximatal v 10  crams  'a) of soil.   Soils  availacle are:
                        n
           arjc '3r"ntonrTT!3-r3r. arf^^-TVTTV  •' —
           ^•iU •»<* W 1  >J *\ I»*l*i4bte<^* <^ «v *. I T 1 V T  ^
                                     'U   :^  253 'uCi/c

                                     ;'J   :   12 3d 'c

      3 i' utec  - -i t:np 1 ende

         Tnis  is  aparoxlrnately a  10:1 cilution  of the  stanaara  pitcn-

         b.leriae: cilutad. with low^acti.vity soil..  ''  •    .    • '•   •••  :'.

-------
                                            Section  No.  •   EMSL-LV
                                            Revision No.:(j
                                            Data:     February LS81
                                            Paae    16    OT    20
 Standard Monazlta Grg

    Principal  radicnuclldes

                               232
    and aoDrcxImate activity -    Th  :  1.5
-------
                                             Section  No.
                                             Revision  No.
Diluted Uranium Mill Tailings

   A  7;l  diVj±--,

   -•^" r-;-!-.= "


   arc  icoro
!C*":V •>•*"/ - "~R =  •  T 2
• W — • r . «. _' •"•     tS
-------
        RiiVI
        Cats
                                                 Feor'jarv 1981
; _   «; v   w
         - cnm, c
Tr   t.v.s  serves.
 7""^ "V.1"-!  "^  "<*  — » - - * ^
 .--•>.  1 *  I • W  i—.- J v- ww


Iaocratcry  nay   elec"

- Ti  ••' — ••-— -3— 3r-  .in   ~wti
                           l p c - • > >j

                        D  receive

-------
                                           Section ?!o.     g*SL-I.V
                                           •'.evislcn  'o.        j
                                           Tate:      r'eoruary
           --"_ i.--ii:r,.v* ir.  *h9 "! secretory  intarccrrparlson

          -j::si or  :.i.i r?rT,s  inc'i-jisc dt  tna  arc  cr'  t^-
      , ^^. 4 — .
               -3r^er>t..;l  P*-ot£Ct1on Agency
               .-/ ".-.-,it:r'jjj- \riwcM5S Ls
• c a c -'« ^ • -i c tn oa re fr
                                           702-795-21^1
                                          7C2 -7 33-257-
                                              -/ rC—iilJ1


                                              -^95-2571

-------
                                        Section No.    ESSJ.-LV
                                        Revision  No.       0
                                        Data:     Feoruary ISSl"
                                        Paae    ?n     of   ->n
                07 Kaaiocneflns"ry Labora-carles:
                                        ~o^ ^ n t* **5 ** ** *•
                                        /02-/9o-2i^o
                                        FTS 595-2233
     £,
^•:!cn of Laboratories Analyzing Hazardous
                                        702-793-21^3
                                         "~      -^-
             -Ns-cn'ocs '/arraatlan. and- -Eaulval-ency: ..

            *"                          702-795—211'-
.-•./     ' . j'-'.i ,i :n-5iis  evaluaclors   of   laaorancrles
               i
,....,,!•.,..  ^., .4^..^^^  war=r  or analyzing  hazardous

c-ff-.rs  -nnsulta-icn and  asslstar.ca  en raclatlcn  ana  nazarccus

                          itv  assuranca srccecurss.

-------
                                  Section  No,    £MSL-«T?
                                 Revision  No.       Q
                                 Data:
                                 ?saa     1      or
        13;.  - ^cARCH TRUHGLE PARK
               Mail Drop  75
       Triingi*  Pane, North Carolina   277'
       Qi-sctcr:   Thomas S. Hauser
^ Au-di-t. Ma-taria is  Ava-i-lacle       -  •

-------
           Table R-l
                             Section No. ________________
                             Revision No. 	p
                             Oats:'    February Ijcl
                             Page    2     or     10
    -;•- r> _-r-..; a. w.-r
     .1 »• w-r\j " .* ^(^ «.
         ~ AVAH AB!_r A^
         —' /*, Y M i i.j*i»*4»-» r\«*
 Concsntraiion  Ranee
                                                                 dit C'jroos2
; -. - -  •ifte

'viijiu^e/ E'.r r.r:
 icveril "eve's  ~rcn 50 to I £00  pern

 Several "evels  "rcm 50 is 10,COC -cm

 2  levels frcrn 3  "o  5 oercent:

 3  levels from I  to  S percent

 3  levels frctn 30  to 50 ppm
 5«»/s5i-^'j  ] av/s 1 ^ """"CrT! ^ ^ "" " " "C  ~~~
 Several  levels from  1 to 10 pom

 2  pom methane with prcoane ranging
 from  0.3 to 6 pprn

 Several , levels frcra  S to 300 ppn

 Several  levels --crn  5 -o 20,000 -c~

 Several  levels from  1000 ~o 5000 pom
 of metnane,  and 200  to  700 par. of
 eihane

.Several.' . 1 eve Is. from  5 • tc 700 '.pom -

 Srfvoral  levels from  5 to 700 ppm

Several  levels from  5  to 700 pom

Several  levels from  5  to 700 porn
                                                                 13

-------
                                                   Secri on•No.   -?-
-------
                                                  Section No.      _...
                                                  Revision No. 	0
                                                  Data:    February .I9c
                                                                of
                                 Tails R-2
   PERFORMANCE AUDIT MATERIALS  AVAILABLE AS STATIC AND  FILTER SAMPLES

Tr:s-                      Description ana Audit Purpose
Ambient SQ? S armies       Freeze-dried  mixtures  of  sodium  sulfite  and
          w
                          potass i urn  tatracnlcrcrnercuma  ;'TC.MN   in   5—7,1
...-.-   -   , --   .-   . . glass. . vials;  sets  of  five,  vials/arasu les   ccn—
                          taininc  -   to   5-   uc   SCu   ecuivalent   a = cr:.
                                                             to   c. Ju  u'- •' rn
               '                                      "
                          acent,  s~rnuiate  arno~ent saiuOicS  rroni  w.-x.  to
                          ,"*  C~   ™/-»1  ' * ^.  *• —  ** P ."•   -.' — -'  11 fl  N     !'»---  *••«
                          u.c/  -j^/rn!  \-^  .0  iL1-  -^/->-   nw« ,•.    v_sr  --
                          audit E?A ecuivalent  .Trethccs ;'manual •netr.ccj).
                          ^e=d  ritrate  aecositec  en   1/2"   x   3"  clas^
                          fiber  ~rlter  strios.   Samoles  sinrjlate   col —
                          lectec  concentrations  from   2.~   to   If  ug, 7"
                          cf  leac.   Nine  levels  are  availaole,   L'se to
                          audit EPA reference metrsco.

-------
 i yse
Amcient Sulfate-
Nitrata Sauries.
                                                  Sv tti on No.   "MSI-37?
                                                  Re-jision No.      0
                                                  Oa.a:  ^	^
                                                  Paae     5    CT
                                                         February 1981
                         Table R-2 (Continued)

                        Description ana Aucrt Purpose
                        Sccium  sulfate ana potassium  nitrate  aeoositec
                       •on  1/2."  x  8" glass-fiber  filter strips.   Sam-
                        ples   simulate  collected  concentrations   from
                       -Q..-5 to  «.Q -yc/fn"1. of .sulfate,  anc  from Q.c  to
                        15  ua/m"  cf nitrate.   Nine  levels -are  avail-
cient Arsenic Sarnies
                          Ars^
           xice  ^c^i~<;"]~ —^  "^p,  * '*?"
fiber  filter  strips.   Samples  siimjlata  col-
lected  concentrations  from 0.02  "o  1.0  uc/ir
                          Acueous  potassium   nitrate  that   simulate
                          source  emission   concentration   of  150-
                          9CC-*T.g .NO^/cso.Ti.   Sano'es  are furnished  as
                          set of five  aiffersnt  concentrations.
                          aucit  E?H  Reference Metncc  7.
Source SO^ Sancles
                       Dilute  sulfuric  acid  that  simulate  a source
                       emission   concentration

                                                        2QO-
                                         7nr,r. -"•
                                         Cw \J**>—'>''-
                         .2CSQ7..- .. am? as. • .are  fumi.shec'. as.  a  set  o
                         five  cifferent'  concentrations.   Use  to  auci
                         EPA Reference  Memoes 6 anc 5.

-------
                                                              0
                                               Sect 'on  No.
                                               ,Rev 'ion Mo."
                                               Date."'    February 1931"
                                               Page     6     OT    10
                           Tafcle  R-3

PERFORMANCE AUDIT MATERIAL AVAILABLE  AS  FLOW  MEASUREMENT OP/ ICE
pe
                 Description  and Aucir  Purpose
    t HI-Vol
 " -cVlC2
                 Raferenca consists of  a  set  cf  resistance nla-as

                 to  simulate  -various-  fiT-tar   loadina   ccnd-itions

                 used zc ccnfinr.  flo\w  calibraticn fcr une  rneasur'r-
                   c  Hicn— Vciune  vHi— Vc
                                   «  ^ O""
                 pericalcal ly be  unavailacle  aue to survey • cc

-------
                             ~M! --3TP

                                                 Section  No.
                                                 Revision No.  _
                                                 Data:     Feoruary 1581
                                                 Paae      7
                             OT
II.   QA TECHNICAL SERVICES AVAILABLE


      A  Standards  Laboratory  has  been  established  at  EMSL/R7?.   The
Standards  Laboratory  offers calibration,  standardization  and  certifi-

cation  of  client-owned  sairale, materia^.. . There  is no  charge  for  this
service.   Where asolicable,  csrtificaticns  are referenced  directly  tc
NBS Stancarn Reference Materials.   The fcllcwinc services are  offeree:
           .£ T- - - , r - j - - r -, ,--.  ,    ,....., r . r^^f v, -^ j-»<




          •» «« j^ ••«   j» «^ •* »m  ^« ** gj ^ «.* -e*  /^ y*  3 | ( r", *"* "*" '^
                                                  cua ' if  ana ' '•/'"'-:i*"s
3 r* "*
                                       sc~a hycr
      3.  Verification  of perrneaticn _*uDe rates  (gravimetric
          •-car  ~uit necascari ;y  :e  il-itsd  to  ret  ever  four rjc
          any one- type  per year.  Tne customer will specify
          ature  at  wnich  calibration is  needed,   Stancarciz=<:
          tions  are  to  be  preferred.
          ticna i  inrormaf.on anc aucit ~atarials  for the aocve  rrccriir.s

.T.ay be octainscs from the follcwinc:
      Static ana Filter Ssanies,  Hi-Vol,  ana Organic Ccmoressed  Gases

          CONTACT;.'_ .Robert. L.  Lamoe   ..- ;• ,      ,,'.  •..',,  ,  .'   .-..-•
                  '' "'Quality" Assurance Division • (MC-77)
                    Environmental  Monitoring Systems Lacoratory
                    U. S.  Environmental  Protection Agency
                    Research  Triangle Park,  NC 27711
                      Telephone:   ="75:   529—531
                                   Ccnmertilal:   (SIS) 5^1—521

-------
r   .                                  '                  Section No.   EMSL-aT7
           I                                             Revision No.5
                                                        Data:    February ih-ei
                                                        Page    g     of*    I"Q"
•
v
             Technical Services and  Inorganic Compressed Gases

                 CONTACT:  3eme I.  Bennett
f                          Quality Assurance  Division  (MO-77)
                           Environmental Monitoring  Systejns laboratory
                           U. S. Environmental  Protection Acency
                           Research  Triangle  Parx,  NC  27711
                             Teleohone:  FTS:   529-2265
                                         Ccnmercial:   (919^ 5^-1-5265
             £.v.2L-rtT? "as a":2C estaclisr.ec aucit scnscules  "cr  c-rTicierr. air a

       staticnary  sources.   """he  scnecul^s  arc  sncvn   in  "Tai;-2  .1—i  ar.c  .R-

       resuectively,  along  *ith  rssoective  indiviauals  *o  ccntac*:  for ;nfc

       Tia-icn.

-------
                                   Section No.-	
                                   Revision No.~     •Q
                                   Date:    February  i9i
                                   Page    9     or    10
                   Table R-4

       AMBIENT AIR 1981 AUDIT SCH£DUU

       -January 5         ?b

       February 2.   -   SC~^  '      —   CO

       Marrn  20-     -'   SO? bubbler
                          * "•• *» — I
       June ZS       -   cb
       Aucu^r 31
       Ocrcc2r  5     -   SO?  bucoler

       Novemaer 20   -   NO?  bucblsr
Rocert L. lames
Duality Assurance  Division  (MD-77)
Environmental Monitoring  Systems  Lanorstcry
U. S, Environmental protection  Agency
Sesfiarci' Triangle  Park, ..NC.  2.7711.,   .,»• --,
"  Teleoncne:  FTS: • 52S-4531 •
              Ccrnnerclal :"%-.(919)  541-^521

-------
                              •"»!
US  r  ^enmtntal Protection Awncy
Repi*:r V, Library                  "
2:H>  Stfuth  Dearborn Street
Chicago, UUoola

-------
                                  Section No.   -MSL-RTP
                            !      Revision  No.       *)
                                  Cdta:     February  .96-
                                  ?aae    1C     or"    10
                  Taola R-5

           SOURCE 1931 AUDIT DATES
    Method 5       3GM
CONTACT:
Robert G. Fuarst
Cuality Assuranca Division (MD-77)
Envircnmental Mcni~rr:nc Systcrs Laccritc
U. S. Envlron^er.Zc 1  ?rc~ac*icn Acency
Rese^rcii  Triancie ?srx, MC 27711
  Tslennone:  F7S:  62S-c573
              Cannsrcial:   (319) 5^1-2573

-------