vvEPA
                                 United States
                                 Environmental Protection
                                 Agency
                                 Municipal Environmental Research
                                 Laboratory
                                 Cincinnati OH 45268
                                  Research and Development
                                 EPA-600/S2-81-029  Apr 1981
Project Summary
                                 Removal  of  Nitrate from
                                 Contaminated  Water
                                 Supplies for  Public  Use
                                 Gerald A. Guter
                                   The general applicability of three
                                 treatment processes for removal of
                                 nitrate from public water supplies are
                                 evaluated: reverse osmosis (RO), ion
                                 exchange, and the combination of RO
                                 followed by ion exchange. The
                                 evaluation consists of using labora-
                                 tory size and field-test equipment to
                                 establish design criteria and operating
                                 experience useful for designing a full-
                                 scale plant of approximately 1 mgd
                                 capacity.
                                   Ion exchange column tests were
                                 conducted with five strong-base anion
                                 exchange resins on nitrate-laden
                                 waters of various anion compositions.
                                 From this work, estimates of product
                                 water quality and the bed  volume
                                 capacity for feedwater of any compo-
                                 sition can be made. Also, a working
                                 hypothesis was developed from an
                                 analysis of the data about how the
                                 chemical structure  of resins can be
                                 practically altered to obtain nitrate
                                 selectivity.
                                   A 20-inch diameter pilot anion
                                 exchange column containing 4.36 cu.
                                 feet of  resin, was designed and
                                 operated for over 1  year. Data from
                                 this column operation are used to
                                 verify estimates of pilot column
                                 performance and  to project the cost
                                 for equipment and regenerant for a
                                 well site installation to treat up to 1
                                 mgd. Because of the interim nature of
                                 this report, only preliminary data are
                                 reported on the operation of a 20,000-
                                 gallon per day RO system.
                                   This Project Summary was devel-
                                 oped by EPA's Municipal Environ-
                                 mental Research Laboratory, Cincin-
                                 nati, OH, to announce key findings of
                                 the research project that is fully
                                 documented in a separate report of the
                                 same title (see Project Report ordering
                                 information at back).

                                 Introduction
                                   Three treatment processes were
                                 objectively evaluated for removing
                                 nitrate from public water supplies:
                                 reverse osmosis (RO), ion exchange,
                                 and RO followed by ion exchange. Both
                                 laboratory and field equipment were
                                 used  to establish design criteria  and
                                 operating experience usefulfor
                                 designing full-scale plants of approxi-
                                 mately 3,800 m/day (1-mgd) capacity.
                                   Work emphasizing the ion exchange
                                 process was done during the period July
                                 1978  to April 1980, and work is
                                 continuing on ion exchange and  RO.
                                 The remainder of the project will be
                                 discussed in the final report under this
                                 grant.  Note that ion exchange experi-
                                 ments are  being continued under  this
                                 program and could alter conclusions
                                 reported here concerning the cost of the
                                 ion exchange process.

                                 Methods and Materials
                                   All tests were conducted at a well site
                                 (No. 3) owned and operated by  the
                                 McFarland  Mutual Water Company in
                                 McFarland, California. Nitrate-nitrogen
                                 levels  for this water were 16 to 23

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mg/L, well above the 10-mg/L maxi-
mum contaminant level. Sulfate levels
were greater than 300 mg/L.
  Site improvements were designed for
well No. 3 to accommodate equipment
for conducting both field and laboratory-
scale experiments. Water was supplied
directly to a concrete pad and trailer
from an existing surge tank. All product
and wastewaters were discharged from
the pad directly into the city sewer
system. The 9.1- x 9.8- m (30- x 32-ft)
pad was large enough to accommodate
a field test ion exchange system, a field
test RO system, and a single module RO
system with the necessary tanks for
temporary water storage. A  trailer
adjacent to the pad housed a field office
and limited laboratory facilities.
  A  source of well  No. 3 water was
available in the trailer for experimental
tests on various ion exchange resins in
5.1- cm (2-in.) diameter columns.
Synthetic mixtures were prepared and
pumped directly at measured flow rates
through the ion exchange columns. Five
ion  exchange  resins were selected for
study with the 5.1 - cm (2-in.) laboratory-
size  ion exchange columns. The
selection was based on previous work,
which tested 32 commercially available
anion exchange resins for application of
both single-bed and two-bed processes.
Because only the single-bed process
was chosen for this study, tests were
limited to strong-base anion exchange
resins. The previous study and discus-
sions with resine  manufacturers indi-
cated that  none of the resins would
exhibit exceptional selectivity for nitrate
ion  over other major anions
  A Culligan HI-FLO 5 Water Softener
Model 1 50* was installed and operated
on the pad at well No. 3  The completely
automatic water softener was converted
to a semiautomatic anion exchanger by
installing an industrial timer and anion
exchange resin (Duolite A-101D).
Conclusions

Engineering Aspects
  1. Design parameters have  been
developed and tested for a conventional
single-bed ion exchange process with
downflow  regeneration to remove
nitrate from well waters. Testing was
conducted using both laboratory
"Mention of trade names or commercial products
does not constitute endorsement or recommenda-
tion for use
columns and a 50.8-cm (20-m.)
diameter pilot column.
  2. The study indicates that automatic
ion exchange equipment, which is
commonly used by the water softening
industry, can  be adapted for  nitrate
removal. The equipment can be
installed at a well  site for  direct
treatment of well water a nd operated on
demand without storage.
  3. The selected resin was effective
for nitrate removal at loading rates
above 48.9 m/h (20 gpm/ft2) of bed
area (1.38 bed volumes/min). This rate
was the  upper limit of the test equip-
ment used. Such high  flow rates bring
costs for equipment and resin quantities
to low practical levels
  4  Capital equipment costs for an ion
exchange system to treat half of a 3,800
mVday (1-mgd) production well are
estimated to be less than $90,000
installed. This estimate  is based on
moderate nitrate-nitrogen  levels of less
than 14  mg/L in well water, sulfate
levels of less than 200 mg/L, and
blending  of treated and raw water to
produce a product containing less than
10 mg/L nitrate-nitrogen.
  The corresponding equipment cost
estimate  for a system to treat all water
from a 1-mgd  production well  is less
than $150,000. This figure is based on
high nitrate levels in raw  water (about
23  mg/L as nitrate-nitrogen), high
sulfate levels (about 300 mg/L, and ion
exchange treatment to reduce nitrate-
nitrogen to less than 10 mg/L without
blending.
  5. A significant operating cost for the
process  is the cost of  sodium chloride
used as a resin regenerant. A method is
presented to  estimate  the sodium
chloride requirements for  regenerating
the resin used  in nitrate removal from
waters of various compositions.
Because anion exchange resins are
quite selective for  sulfate ion,  the
presence of sulfate m  raw  water
decreases the efficiency of the resin in
absorbing nitrate.  In   this study,
however, sulfate was  easily removed
from the spent resin  by  the sodium
chloride regenerant m  nearly stoichio-
metric proportions, whereas excess
regenerant is  required for nitrate
removal. Nonetheless, the  overall effect
of sulfate is to increase the salt required
to remove nitrate per  unit quantity  of
water treated. This study also confirmed
that large quantities of  regenerant (320
kg/m3 or 20 Ib/ft3 of resin) are required
to remove most of the  nitrate from the
spent resin.  Not all nitrate need be>
removed,  however, to reduce nitrate-'
nitrogen levels in treated water to less
than 10 nng/L.
  For the McFarland wells, the salt
costs for  lowering nitrate-nitrogen
levels to 7 to 10 mg/L ranges from an
estimated 1.90/1,000 gal of blended
water (or S6.10/acre-ft)forwellNo. 2 to
100/1,000 gal  of treated water (or
$32.50/acre-ft) for  well No. 3. Water
from  the latter well  represents a
particularly difficult water to treat as
nitrate-nitrogen concentrations are
near 23 mg/L, and sulfate levels are
above 300 mg/L. Nitrate-nitrogen
concentrations in well No. 2 are near 14
mg/L, and sulfate levels are near 200
mg/L. Salt requirements for waters of
other compositions are given in the
report text.
  6. To achieve efficient nitrate
removal, good brine and influent flow
distribution  are essential and  may
require modifications of commercially
available softening  equipment. A
method of declassification (thorough
mixing)  of the resin  after downflow
regeneration should also be incorporated
in the regeneration cycle.
  7. During the regeneration cycle,
wastewater is produced that is rich in
sodium sulfate, chloride, and nitrate.
Continuous operation of  well No.  2
would produce  more  than 45.4 m3
(12,000 gal) of wastewater/day.  Con-
tinuous operation of well No. 3 would
produce an average of 146.4 m3 (38,686
gal) of wastewater/day.

Theoretical Aspects
  1. Previous studies have shown that
the higher resin selectivity for sulfate
over nitrate gives rise to some chroma-
tographic sulfate enrichment in the
upper portion of spent columns and
nitrate enrichment in the lower portion.
In studies using  McFarland well No. 3
water, such chromatographic separa-
tion was observed only for microporous
Type I resins. Microporous Type II and
macroporous  resins appeared to  have
nearly equal nitrate and sulfate selec-
tivities. The difference in behavior can
be  attributed  to the greater porosity of
microporous Type I resins and/or the
lesser steric requirements of the Type I
resins. This effect has practical signifi-
cance because it indicates that nitrate
selectivity might be increased over
sulfate selectivity by decreasing
porosity and modifying the structure
about the quaternary ammonium ion. To

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be of practical use, resin selectivity for
nitrate must be made to exceed that for
sulfate to reverse the order of the
enriched  portions of the spent resin
column
  2. Although ion exchange can be
used with minimal salt requirementsfor
some waters, the use of sodium chloride
as a regenerant is an obvious disadvan-
tage for extensively employing the
conventional single-bed  ion exchange
process because  of waste disposal
requirements  Spent brine can be
separated into sulfate-rich and nitrate-
rich fractions for recovery purposes, but
little effort has been spent on developing
recovery processes or on using alterna-
tive regenerants that could  make
recovery or reuse more practical.

Recommendations
  1. Pilot column studies  should be
extended  and  conducted on waters of
various compositions to verify the
method of  estimating engineering
design parameters and process require-
ments  These studies should include
Type II resins because of their greater
capacity and potential for upflow
regeneration.
  2. Efforts  should be made to reduce
regenerant requirements to the lowest
level practicable  Such reduction can be
achieved by recycling portions of brine
and brine rinse  as well as  backwash
waters. Upflow  regeneration should
also be studied as a method to achieve a
low nitrate  leakage  into the column
effluent. This  method would make all
treated water blendable with raw water
and could reduce salt requirements per
unit of water produced. The use of RO in
conjunction with ion exchange is
another approach to reducing regener-
ant requirements  RO can reduce the
total dissolved solids (TDS) load on the
resin and  may in some cases provide  a
brine useful  for resin regeneration.
  3. A demonstration plant of 1,900-to
3,800-m3/day (0.5- to 1-mgd) capacity
should be installed  and  operated to
obtain actual  operational experience
regarding  reliability, health, safety, and
costs.
  Although the ion exchange process
has been used  for  many  years for
industrial applications and for removing
hardness  from domestic supplies, no
significant operating experience  has
been obtained on a full-scale domestic
system for nitrate removal  Use of the
process for this purpose cannot be
considered as  a  standard engineering
application until the process has been
successfully demonstrated on a full
scale.
  4.  Efforts to synthesize nitrate-
selective resins should be continued to
make the process more attractive to
sulfate-laden waters. In such studies,
close attention must be paid to the
regeneration requirements of the new
resins.
  This interim report is the seventh of a
series of quarterly progress reports in
fulfillment of a contract under Environ-
mental  Protection Agency Grant  R-
805900-01 to the McFarland Mutual
Water Company of McFarland, California.
The reader should be aware that  ion
exchange  experiments  are being
continued under this program and could
alter conclusions concerning cost of the
ion exchange process reported herein.
  Gerald A. Guter is with Boyle Engineering Corporation, Bakersfield, CA 93302.
  Richard Lauch is the EPA Project Officer (see below).
  The complete report, entitled "Removal of Nitrate from Contaminated Water
    Supplies for Public Use," (Order No. PB  163 206; Cost: $11.00. subject to
    change! will be available only from:
         National Technical Information Service
         5285 Port Royal Road
         Springfield,  VA 22161
          Telephone: 703-487-4650
  The EPA Project Officer can be contacted at: •
         Municipal Environmental Research Laboratory
         U.S. Environmental Protection Agency
         Cincinnati, OH 45268
                                                                                     > US GOVERNMENT PRINTING OFFICE 1961-757-012/7074

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