United States
Environmental Protection
Agency
Municipal Environmental
Research Laboratory
Cincinnati OH 45268
 Research and Development
EPA-600/2-84-050 Apr. 1984
                                                                       r/r,o
Project Summary
 Landfill  Research  at  the  Boone
 County  Field  Site
 Richard J. Wigh
  From June 1971 until August 1980,
 the Municipal Environmental Research
 Laboratory constructed and monitored
 five municipal waste landfill test cells in
 Boone County, Kentucky.  Primary
 objectives were (1) to evaluate leachate
 quantities and characteristics, gas
 composition, temperature conditions,
 and a soil liner for leachate control and
 (2) to compare the performance of a
 field-scale cell with smaller,  similarly
 constructed cells.
  This Project Summary was developed
 by EPA's Municipal Environmental Re-
 search Laboratory, Cincinnati, OH, to
 announce key findings of the research
 project that is fully documented in a
 separate report of the same title (see
 Project Report ordering information at
 back).

 Introduction
  Five  test cells containing municipal
 solid waste  were constructed at the
 Municipal Environmental Research Labo-
 ratory's Boone County Field site near
Walton, Kentucky, during  1971  and
 1972. Cells 1 and 2D were constructed
 similarly to  normal landfill cells  and
 contained 286,000 and 72,450  kg of dry
 refuse, respectively. The base of Cell 1
was lined with a 0.76-mm synthetic liner,
on top of which was placed a 45.7-cm-
thick, compacted, clayey silt liner. Both
the synthetic  and soil  liners were
provided with drains for leachate collec-
tion. A 0.6-m, compacted soil cover was
placed  over  the  refuse in  Cell 1. A
continuous synthetic liner was placed on
the sides and base of Cell 2D. Cover over
the .refuse  consisted of 0.3-m  of com-
pacted soil beneath a 0.3-m surficial layer
of pea gravel. A grid of 150-mm-high clay
dikes was constructed within the gravel
to promote uniform percolation into the
refuse. (See Figure 1).
  Cells 2A, 2B, and 2C were constructed in
identical, cylindrical steel pipes, 1.83 m in
diameter by 3.66 m long. These small-
scale cells contained approximately 2100
kg of dry refuse each. These units were
constructed to compare performance of
small-scale systems with the field-scale
cell (2D) and to evaluate variations within
identical cells.
  Cell construction data are summarized
in Table 1. All cells were monitored for
leachate quantity and characteristics, gas
composition, temperature, and settlement
until they were closed in August 1980.

Findings

Leachate Volume
  Leachate was initiallly collected from
both the upper and lower pipes of Cell 1
approximately 2 months after construc-
tion. The observation unit adjacent to the
cell in which leachate was collected
collapsed in  February 1979,  and after
that, volume  measurements  were not
possible. At that time, 1.07 million liters
of leachate—representing  27.5% of the
precipitation recorded at the site—had
been collected.
  The leachate volume predicted by using
the water balance method  is shown
together with the cumulative leachate
volume in Figure 2. At the time leachate
volume measurements ceased, 1.07
million liters had been collected—only a
6% difference from the 991,600 liters
predicted by the water balance method. If
yearly average evapotranspiration values
had been used, rather than ones computed
from actual climatic conditions (precipita-
tion and temperature) experienced, the
difference would  have been 33%. This

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 To Equipment Storage Shed
 and Site Office Trailer
             Leachate
          Spray Irrigation
               Area
                                                                         -N-
                                                                          I
                                                               Observation
                                                               Gallery
                                                               Instrumentation
                                                               Shed
                                                   Weather Station
                          Leachate Holding Pond
                                                                 Scale: 1"~ 50'
Figure  1.    Site layout of Boone County test cells.
 Table 1.    Summary of Cell Data
                                                  Test Cell
Item
Cover soil classification
Depth of soil cover, m
Surface area of refuse, mz
Maximum depth of refuse, m
Mass of refuse, kg (dry)
Dry density of refuse, kg/m3
Moisture content of refuse.
% wet wt.
1
CL*
0.60
432.3
2.56
286,000
429
27.6

2A
CL
0.30
2.627
2.56
2,046
304.3
22.5

2B
CL
0.30
2.627
2.56
2,113
314. J
27.1

2C
CL
0.30
2.627
2.56
2,135
317.6
24.1

2D
CL
0.30
72.83
2.44
72,450
407.7
31.8

"USCS soil classification
large difference indicates that  leachate
volume design calculations should be
based  on extreme  as well as average
values. Leachate was also collected during
the  summer and  fall,  which  is rarely
predicted by the water balance method.
  One of the objectives of the Cell 1 tests
was to evaluate the effectiveness of the
soil  liner in containing leachate.  The
quantity  of leachate  from the pipe
beneath  the soil  liner was equal to or
greater than that volume from the upper
pipe untilJanuary 1972. This was caused
by leaving the valve closed on the upper
pipe except for weekly sampling, thereby
inducing sufficient head to cause leakage
into the  lower  pipe.  Flow quantity
remained relatively constant after 1972
through a wide yearly variation in total
leachate flow; this indicated soil liner
saturation and relatively constant head
and soil permeability throughout the later
years of cell life. Tests of the soil liner at
closure showed reductions in permeabil-
ity of the  soil of 2 to  3 orders of
magnitude, from the original 2x1 CT5 to 4
x 10~7to2x1CT8cm/sec.
  Although greater than 99% of the total
leachate flow  was collected from the
upper pipe, it appears that the Hypalon®*
liner and the soil liner were functioning
together and that the large percentage of
the leachate collected in the upper pipe
was not due to the soil alone. Apparently
the Hypalon® sheet blocked deep perco-
lation, forcing flow  along the refuse-soil
interface, and resulted  in the  high
percentage of leachate being collected in
the upper pipe. If a free-draining granular
layer  had been placed  between the
Hypalon® and the base of the soil liner, a
more definitive evaluation of the soil liner
effectiveness could  have been made.
  The experimental design for Cells 2A-
2D called for the input of approximately
500 mm of precipitation each year into all
of the cells. Average annual rainfall at the
site exceeded 1,000 mm, so all.of the cells
were periodically covered—the cylinders
with caps, and 2D with  nylon-reinforced
Hypalon®. Generally,  about 100 mm of
precipitation fell on the cells before they
were covered for a 2-  to 3-month period.
During the final year  of the project, the
covers  were  left off. Evaporation  and
transpiration losses were further reduced
by use of the 0.3-m gravel layer overlying
the  soil cover; this layer prevented
vegetative growth and shielded the water
stored on top of the soil cover from direct
sunlight. Leachate  volume collected
from the four cells is  shown in  Figure 3.
'Mention of trade names or  commerical products
 does not constitute endorsement or recommenda-
 tion for use.

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n
O
I
•g
jmulative Lea
O



1.400
1,200
1,000
800
600
400
200
O - Leachate volume
A - Leachate volume estimated by water balance

L
A
O
O A
0 A
0 ° ° ° A
o A - -
O
o A
o
Q ^
1973 1974 1975 1976 1977 1978 1979
Time - years
Figure 2.   Cumulative leachate volume for Cell 1.
  Test Cell 2C produced very  little
leachate  during the reporting period  in
comparison with that produced  in Cells
2A  and 2B. A test boring in the cell
showed  no free  water stored in the
cylinder. The assumption was that a leak
had developed at a welded joint near the
surface of the soil cover and very little of
the precipitation had actually entered the
refuse mass.
  Leachate quantities collected  from
Cells 2A and 2B at the end of the project
differed by only 5%. Leachate collected
from 2D began to exceed precipitation in
mid-1975. At project completion, leachate
equal to  7,000 mm of precipitation had
been collected, whereas the  input was
only 4,570 mm. Possible causes of this
large difference might have been leakage
through the sidewalls and liner of the cell
or through the Hypalon® cover that was
periodically placed on the cell.
  Graphic predictions of refuse field
capacity  compared well with moisture
contents of refuse samples taken during
closure. Based on the experience with the
four cells, an appropriate design value for
field capacity would be 55% moisture on a
wet-weight basis.

Leachate Characteristics
  Leachate samples from the test cells
were generally analyzed biweekly. A
summary of  peak concentrations and
values recorded at closure is included in
Table  2.  Many of the peaks occurred
within a  relatively short  time period,
during which  the cells were reaching
field capacity. Apparently those peak
concentrations resulted during the initial
water contact, when  the supply  of
teachable substances and the contact
time were both high.  Note that  these
leachate concentrations were  from
relatively shallow (2.5 m) batch cells in
which there was no daily or intermediate
cover soil.
  Total solids concentration history and
mass removal curves for four of the test
cells are presented in Figures 4 and 5.
The concentration or cumulative  mass
removal  has been  plotted against the
cumulative leachate volume rather than
       time,  since the  leachate concentration
       trends and subsequent mass removals
       are more related to leachate volume than
       to time. Leachate  volume  and  mass
       removal data are also normalized by
       dividing by the dry weight of the refuse to
       account for the different sizes of the cells.
         Typical of many of the parameters was
       a pattern of increasing concentration
       until field capacity was reached, followed
       by a gradual decline. Individual leachate
       sample concentrations showed no dilu-
       tion effects during periods of high flow.
       This pattern  was adequately described
       with  a simple  exponential equation
       developed by considering  the cell as  a
       well-mixed reactor. The least squares fit
       of the  equation to  the concentration
       history of COD for Cell 2A is depicted in
       Figure 6. Though such an  equation was
       useful in describing leachate character-
       istics  over  the 9-year period  of the
       experiment, its  accuracy for long-term
       predictions  remains  uncertain. This
       uncertainty is exemplified by the findings
       that the total chloride remaining  in
       samples of 9-year-old refuse  was 70
       times greater than the leachate chloride
       predicted by the equation. Since some of
       the chloride remaining in the refuse may
       not be teachable,  verification  of the
       equation would require that  studies  be
       conducted  well  beyond the amount of
       leachate per unit of dry refuse reached in
       this research program.
         One of the primary objectives of Cell  1
       was to evaluate the  effectiveness of soil
  6,000
  5,OOO
  4,000
  3,000
•£ 2,000
-2

I
0  7,000
                    1.000
2,000
3,000
4.000
5,000
                              Cumulative Precipitation, mm
Figure 3.    Leachate volumes for Cells 2A-2D.

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 Table 2.   Leachate Concentrations*
 Parameter
               Test Celt 1 Upper
               Concentrations
             Peak      At Closure
    Test Cell 2D
   Concentrations
Peak      At Closure
    Test Cell 2A
   Concentrations
Peak      At Closure
   Test Cell 2B
  Concentrations
Peak     At Closure
pH (lowest)
pH (highest)
COD
BOD5
Kjeldahl-N
Ammonia-N
Orthophosphate
Sulfate
Alkalinity
Acidity
Conductivity
Total Solids
Sodium
Potassium
Chloride
Iron
Magnesium
Manganese
Calcium
Zinc
Hardness
5.10
7.07
37,500
30.000
700
552
61
1.160
8.870
3.620
12.200
23.600
1.040
1.950
1.749
616
374
184
2.360
104
7,500
__
--
250
43
23
18
1.4
9
760
660
930
1.400
42
41
66
200
27
1.9
190
0.3
590
4.6
7.0
41.869
79. 120
1,413
947
82
1.280
8.963
5.057
16.OOO
36,252
1,375
1,893
2,940
1,492
411
58
2.300
67
6.713
__
--
600
4OO
14
10
1.6
23
460
560
87O
1,200
25
24
73
210
19
1.6
130
0.4
400
4.4
6.2
57.370
62,560
1.560
1.035
390
2,215
1 1.535
6,720
1 7,000
46,484
1.900
2,225
3,558
1,547
486
109
2.470
150
7.067
	
--
6.100
5.000
63
23
42
30
710
1,400
1.400
2,700
33
31
96
520
18
4.7
170
0.3
570
4.4
6.0
61.600
72.220
1.897
1.185
185
2.275
13,880
6.843
18.000
45.628
1.700
2.939
2.450
2.902
617
115
4.000
360
10.575
__
—
6,400
5,700
43
3O
31
41
830
1.30O
1,600
3,000
23
3O
99
480
22
5.1
290
1.4
8W
 *Concentrations in mg/L, except for pH and conductivity (micromhos/cm).
liners for leachate control. Less  than
9,000 liters of leachate was  collected
from the drain pipe beneath the soil liner
during  the  first  7-1/2 years  of  the
project—a total that  represented less
than a third of the soil pore volume. Even
after 9 years, iron and COD values were
only 50%  of those for leachate that had
not passed through the soil liner. Total
solids attenuation averaged 31% over the
project. Desorption from  the soil of
hardness, chloride, calcium, and sulfate
                             occurred  during  the later  part of the
                             study. A complete evaluation of the soil
                             liner's efficiency  in collecting and
                             attenuating leachate could  not be per-
                             formed because of interference from an
                             underlying synthetic liner, variable soil
                             thickness, and a small hole discovered in
                             the soil liner during closure.
                               Leachate samples from Cell 1 were
                             used for bioassays during 1972. The 96-
                             hour LC5o was 2.5% and 2.1% for two
                             series  of  tests on  fathead minnows.
                                                             o	2A
                                                             A	2B
                                                             O	2D
                                                             A— 1
 Figure 4.
           Cumulative Leachate Volume—L/kg of dry refuse

Total solids concentration history for Cells 1, 2A, 2B. 2D.
                                Microbiologic studies of leachate and
                                waste samples indicated that significant
                                numbers of fecal indicators had continued
                                to survive and  reproduce for  9 years.
                                Pathogens were also identified in waste
                                sampled from  Cell  1  at closure, even
                                though inoculated bags containing
                                poliovirus type 1 and Salmonella derby
                                indicated inactivation within  10 days of
                                the initial construction of Cell 1.

                                Gas, Temperature, and
                                Settlement
                                  Gas  samples were obtained from
                                various locations within the cells. Oxygen
                                was  depleted quickly in all cells, and
                                thereafter it generally remained  at less
                                than  3% at most probe locations for the
                                entire project.  The  characteristic early
                                carbon dioxide  bloom appeared in all
                                cells. Within 2 weeks after cell construc-
                                tion, COz levels reached as high as 45% in
                                the center of Cell 1 and 38% in the center
                                of Cell 20. Levels in the small-scale cells
                                were slightly lower. Peak levels  of CO2
                                were reached in all cells at aboutthe time
                                field  capacity was achieved. Thereafter,
                                levels dropped  slowly to 30% to 40% at
                                the  conclusion  of  the project. Carbon
                                dioxide levels ranged from  5% to 20%
                                higher by volume in Cell 2D than in the
                                small-scale cells for the first 3 years, but
                                they were similar thereafter.
                                  Very little methane was detected until
                                the  cells reached field capacity. The
                                earliest appearance of methane in Cell 1
                                was at the base of the cell and beneath
                                the liner. Methane concentrations greater
                                than  10% were not detected in the small-

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scale cells until  2  years after similar
levels were reached in 2D. Peak methane
concentrations recorded in the small cells
were 25% in 2A, 20% in 2B, and 26% in
2C. The peak concentration detected in
20 was  57.9%. Though results  were
erratic, methane levels in the small cells
appeared to be similar.  Little similarity
existed between the methane history in
2D and in the small cells, 2A, 2B, and 2C.
  60
350
                                        Thermocouples and thermistors were
                                      placed at various locations within the five
                                      cells and in the surrounding soil. Peak
                                      temperatures  as  high as 124°F were
                                      recorded near the surface of 2A and 2B.
                                      Peaks declined with depth in the small
                                      cells, but they were similar at three levels
                                      within 2D. After about 1-1/2 years, soil
                                      and refuse temperatures at  similar
                                      depths  were  generally within  a few
 ,40
\
o
I
30
  20
                                                               	-o
 Figure 5.
  50
              12345

                      Cumulative Leachate Volume—L/kg of dry refuse

          Total solid mass removal for Cells 7, 2A, 2B. 2D.
V
.0
 I30
I
I 20
 Figure 6.
              12345
                  Cumulative Leachate Volume—L/kg of dry refuse

          Comparison of COD concentration for Cell 2A. (*€q. 4 of full report)
degrees, indicating  the  end of active
aerobic decomposition. Except near the
surface of Cell 1, lower annual tempera-
tures were recorded  in the soil, and the
highs were about the same  in both the
refuse and the soil. Atime lag  also existed
between soil and refuse peaks.  This
amplitude difference and  time lag was
thought to be due to  specific  heat
differences or  perhaps minor residual
aerobic activity within the refuse.
  Settlement in the small-scale cells was
quite similar, with more than half the
total recorded during  the first 14 months
following cell construction. Final settle-
ment in these cells ranged from 15.2% to
17.1% of total cell refuse depth. Settle-
ment over  the  surface of 2D averaged
only 10.6% of  refuse  depth, probably
because of the 30% higher initial in-place
refuse density than in  2A, 2B, and 2C.
Estimated total settlement at the deepest
point in Cell  1  was  12%  of  the refuse
depth.  The initial refuse density in Cell 1
was 35% higher than that in 2A, 2B, and
2C.

Performance Comparison
  One of the primary  objectives cf the
research was to compare the  behavior of
a field-scale test cell (2D) with similarly
constructed small-scale cells. We hoped
to determine whether factors of scale
were involved or whether the small cells
produced duplicate results so that future
research efforts might use  small, less
expensive cells to predict field behavior.
  Composition and  initial moisture
content were statistically similar, and
refuse depths varied only 5%. The in-
place wet refuse density  in Cell 2D was
45% greater than the average  refuse
density in the small  cells. Leachate
collected from Cell 2C was so substantially
different from Cells 2A and  2B that the
leachate data  were not used in any
comparative analysis. Leachate produc-
tion from Cell 2D was much greater than
that from the remaining small-scale cells
(2A and 2B), and it exceeded precipitation.
By  the end of the project. Cell 2D had
produced nearly twice  the leachate per
unit of collection surface area than had
Cells 2A and 2B.
  Only minor differences in temperature,
settlement, and gas composition  were
noted when comparing the performance
of the small-scale cells. Temperatures
were essentially the same in 2D as in the
small  cells  except for some surficial
heating as a result of the cover over 2D.
Settlement in the large cell was only two-
thirds of that in the small cells, perhaps
because of the initial 45% greater wet

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refuse density. Compared with Cell 2D,
the small-scale cells (2A, 2B, and 2C)
showed  a substantial difference in
methane gas concentration, with delayed
production and lower concentrations.
  Leachate concentration trends  in Cell
2D  were similar to those in the  small-
scale cells, but typically the magnitude of
peak concentrations and mass removals
were  lower—quite possibly because of
diluting sidewall  leakage. Since  this
leakage could have passed through a
portion of the refuse, it was impossible to
correct the concentration data simply on
the basis of excess water. This large
difference in leachate production from
Cell 2D was probably  sufficient to
preclude comparisons of cell performance
based on leachate characterisitics.
  Graphic comparisons of  weighted
mean leachate concentration histories
and mass removals for Cells 2A and 2B
indicated that performances were gener-
ally similar.  To  compare concentrations
statistically, the Chow test for  stability of
coefficients was used. Essentially, this
method compares the least squares fit of
two linear equations describing the data
from Cells 2A and 2B with the fit of a
single equation  developed  from the
combined set of  data. The  F statistic
calculated from a  ratio of  the residual
sum of the squares of the linear equations
is used as  the measure of statistical
comparability. A  log  transform  of the
exponential equation (Figure 5) was used
for the  necessary  linear  equations and
least squares fitting. Results of this test
showed similarity for  only 3  of 12
leachate parameters for Cells  2A and 2B
at the 0.05 level of significance. Compari-
son of Cell 2A with 2D indicated similarity
for only 1 of 12 parameters. Because of
the lack of statistical comparability, we
could not conclude that similarly con-
structed and operated cells would perform
similarly.

  A 45% greater  initial in-place  wet
refuse density  in  Cell 2D  than  in the
smaller  cells and the  much greater
volume of leachate collected precluded
performance  comparisons between the
different-sized cells. Differences in
settlement, gas composition  with time,
peak leachate concentrations, and mass
removals  were all apparent in the cell
data. Though we cannot conclude that 2D
would have performed differently if the
refuse density and leachate volume had
been the same, these operational problems
are only minor compared with the range
of conditions that may be  encountered in
a field situation. Thus, it is doubtful that
small-scale, batch-type cells can provide
accurate predictions  of sanitary landfill
behavior; but they  may be  useful  in
describing performance ranges.
  The full report was submitted in ful-
fillment of Purchase Order No. C3016NASX
by Regional Services Corporation,  Inc.,
under the sponsorship of the  U.S. Envi-
ronmental Protection Agency.
   Richard Wigh is with Regional Services Corporation, Inc.. Columbus, IN 47201.
   Dirk Brunner and Nor ma M. Lewis are the EPA Project Officers (see below).
   The complete report, entitled "Landfill Research at the Boone  County Field
    Site," (Order No. PB 84-161 546; Cost: $14.50, subject to change) will be
    available only from:
          National Technical Information Service
          5285 Port Royal Road
          Springfield, VA22161
          Telephone: 703-487-4650
   The EPA Project Officers can be contacted at:
          Municipal Environmental Research Laboratory
          U.S. Environmental Protection Agency
          Cincinnati, OH 45268

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United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
     BULK RATE
POSTAGE & FEES PAID
         EPA
   PERMIT No. G-35
Official Business
Penalty for Private Use $300
                                                                                          ft U.S. GOVERNMENT PRINTING OFFICE: 1984-759-102/923

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