United States
                    Environmental Protection
                    Agency
Robert S. Kerr Environmental
Research Laboratory
Ada OK 74820
                    Research and Development
EPA-600/S2-84-098  June 1984
v>EPA         Project  Summary
                    Annotated Literature References
                    on Land Treatment of Hazardous
                    Waste
                    William C. Galegar and B. J. Tillman
                     This report represents one of a five-
                    part  response  to the  cooperative
                    agreement  "Land Treatment  Tech-
                    nology Development Systems for Haz-
                    ardous Wastes." This  part provides
                    technical literature annotations of land
                    treatment processes   for chemical,
                    hazardous, and industrial solid wastes.
                    Since the concept of land treatment
                    is relatively new for industrial waste.
                    information is widely scattered. Approx-
                    imately 832 publications, through  the
                    year of 1982, were reviewed and anno-
                    tated for this report.
                     The other activities of this study were
                    (1) prepare a master research plan for
                    land treatment of hazardous waste, (2)
                    conduct a feasibility study for selecting
                    a pilot plant facility for land treatment,
                    (3) develop the mechanism for a quick
                    data base accessibility, and (4) provide
                    for  the  peer  review  of  proposals,
                    programs, projects, and publications on
                    land treatment. A sixth activity  —  the
                    development of a Land  Treatment
                    Technology  Panel  was added  by
                    amendment.
                     The remaining activities are
                    documented by internal  ORO reports
                    since they supply data needs specific to
                    the internal planning and management
                    processes of the Hazardous Waste Land
                    Treatment (HWLT)  program. Any
                    portions  of  interest  to  designers,
                    managers, or   operators  of   HWLT
                    systems are being incorporated in more
                    comprehensive  publications, such as
                    the forthcoming site selection manual.

                     This Project Summary was developed
                    by EPA's Robert S. Kerr Environmental
                    Research  Laboratory, Ada,  OK,  to
announce key findings of the research
project that is fully documented in a
separate report of the same title (see
Project Report ordering information at
back).

Introduction
  Land treatment is noted in the Re-
source  Conservation  and Recovery Act
(RCRA, Public Law 94-580) and the pro-
posed regulations issued by the  U.S.
Environmental  Protection  Agency's
Office of Solid Waste as one of the tech-
nologies for management of  hazardous
waste. This technology currently is being
utilized for the disposal of industrial
hazardous waste. The term, "land treat-
ment," implies that the land or soil is used
as a medium to treat hazardous waste; a
land treatment facility is defined as "that
portion of a facility of which  hazardous
waste is applied onto or incorporated into
the  surface soil." This  technology is
considered to  be  a  viable  waste
management option for selected hazard-
ous wastes with potential economic and
environmental  advantages over  other
options.
  Land treatment  must  be viewed,
planned and managed with  the  same
degree of  care and attention  given any
other technical process operation. The
objective of land treatment technology is
to design and operate the system to utilize
the  natural biological, chemical  and
physical processes  in  the  soil for
degrading,  attenuating,  or  otherwise
rendering   innocuous those wastes
receiving such treatment. The waste-soil
complexities  and  natural  process
interactions must  be  appreciated and
understood if  land treatment is  to be

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  acceptably  practiced  and  its  use
  expanded.

  Annotated Technical Literature
    The   available   literature  on   land
  treatment  indicates  that  a  properly
  designed and  operated  land  treatment
  facility can provide sound, environment-
  ally  safe  disposal of waste residuals
  through  the  biological, chemical and
  physical interactions occurring in the soil.
  Attenuation of the organic constituents
  occurs largely as a result of degradation
  by the soil microbiota, while immobiliza-
  tion of metallic contaminants occurs as a
  result of the physical-chemical properties
  of  the  soil.  There  is,  however,
  considerable information that must be
  acquired to: (a) satisfy the  regulator,
  designer, operator, and general public on
  important  issues  related  to  this
  technology, (b) establish a high degree of
  confidence in soil treatment systems; and
  (c) utilize this  technology to  its  fullest
  potential.
    Land treatment encompasses a unique
  and novel approach to degrade noxious
  and  unwanted waste constituents  to
  environmentally  acceptable  products.
  This  degradation  is  accomplished  by
  chemical, physical and microbial action
  analogous  to  that  experienced  in
  biological treatment  processes.  The
  upper soil mantle  is utilized to trap the
  contaminants and make them available
  for microbial  action. Through  proper
  management of  land processes,  soil
  characteristics may be altered to make a
  more productive soil, vegetation and a
  cost-effective  treatment  process.
  Concepts of land treatment processes for
  industrial waste are relatively new, and
  information  is  widely scattered,  if in
  existence at all.
         An extensive search of the literature
       was made to secure and summarize that
       pertinent to this  effort. Each  piece of
       information was collated with the major
       divisions  in  the  research  plan.  This
       consisted of: (1) site selection, (2) design,
       (3)  operation  and  management,  (4)
       monitoring of land treatment systems, (5)
       closure/post-closure, and (6) economics.
       A total of 832 articles are summarized.
         Results  indicate  land  treatment  of
       selected organic waste to be an attractive
       alternative cost-effective  method.  This
       compilation should be useful  to those
       having a need to rapidly review available
       information in the areas identified above.
         Jean Galegar is with East Central Oklahoma State University, Ada. OK 74820.
         M. L. Wood is the EPA Project Officer (see below).
         The  complete  report, entitled  "Annotated Literature  References  on Land
            Treatment of Hazardous Waste," (Order No. PB 84-195 270; Cost: $34.00,
           subject to change) will be available only from:
                 National Technical Information Service
                 5285 Port Royal Road
                 Springfield.  VA 22161
                 Telephone: 703-487-4650
         The EPA Project Officer can be contacted at:
                 Robert S. Kerr Environmental Research Laboratory
                 U.S. Environmental Protection Agency
                 P.O. Box 1198
                 Ada. OK 7482O
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