United States
 Environmental Protection
 Agency
 Industrial Environmental
 Research Laboratory
 Cincinnati OH 45268
 Research and Development
 EPA-600/S2-84-115 Aug. 1984
 Project  Summary
 Logan  Wash  Field  Treatability
 Studies  of  Wastewaters from  Oil
 Shale  Retorting  Processes
 B.O. Desai, D.R. Day. and I.E. Ctvrtnicek
  Treatability studies were conducted
on retort water and gas condensate
wastewater from modified in-situ oil
shale retorts to evaluate the effective-
ness of selected treatment technologies
for removing  organic and inorganic
contaminants. At retorts operated by
Occidental Oil Shale, Inc., at Logan
Wash, Colorado, treatability studies
were conducted on retort water using
filter coalescing, steam stripping, acti-
vated sludge treatment (both with and
without powdered  activated carbon
addition), sand filtration, and granular
activated carbon adsorption.  Retort
water had high  concentrations of
ammonia-nitrogen, total Kjeldahl nitro-
gen, alkalinity, dissolved organics,
phenols, sulfide, total dissolved solids,
boron, potassium and sodium. Steam
stripping removed ammonia-nitrogen,
alkalinity, and sulfide from retort water
and organics  removal was low. Gas
condensate wastewater had high con-
centrations of ammonia-nitrogen, total
Kjeldahl nitrogen, dissolved organics,
alkalinity, phenols, sulfide, and pyridine
compounds. The overall scheme for the
gas condensate treatment removed
ammonia-nitrogen, total Kjeldahl nitro-
gen, alkalinity, sulfide,  biochemical
oxygen demand, dissolved organic
carbon, chemical oxygen demand, and
phenols.
  This Project Summary was developed
by EPA 's  Industrial Environmental
Research Laboratory. Cincinnati, OH,
to announce key findings of the research
project that is fully documented in a
separate report of the same title (see
Project Report ordering information at
back).
Introduction
  To assess the characteristics and
treatability of wastewaters generated
from the processing of oil shale, the U.S.
Environmental Protection Agency (EPA)
contracted with Monsanto Research
Corporation (MRC) in 1979 to conduct a
five-phase program entitled "Assessment
of Oil Shale Retort Wastewater Treatment
and Control  Technology." The program
had the following objectives (phases):
    I  Summarize available information
      concerning oil shale  retort waste-
      water sources and characteristics;
    II  Identify control  technologies that
      are potentially applicable for treat-
      ment of the identified wastewater
      streams;
   III  Design pilot-scale units capable of
      evaluating the applicable technol-
      ogies at oil shale processing sites;
   IV  Construct the pilot-scale units;
      and
   V  Operate the  units  and evaluate
      treatment technology perform-
      ance.
Based on the results of Phases I and II, it
became apparent that not much informa-
tion existed  on  which  to  evaluate and
select potentially applicable technologies
for testing and  that laboratory bench-
scale testing and wastewater characteri-
zation were warranted. Wastewater cha-
racterization and bench-scale treatability
studies were conducted using samples of
oil shale wastewaters  available at the
time. Steam  stripping, hyperfiltration,
carbon adsorption (batch isotherm and
column), and activated sludge treatment
tests were conducted on a bench-scale
level. The results of these studies and the

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information previously collected during
Phases I  and II were used to select the
treatment schemes and units  for con-
struction  and field testing under the
follow-up Phases III through V. The
schemes and units approved by EPA with
some modifications were field tested at
the modified  in situ retorts operated by
Occidental Oil Shale,  Inc., in  Logan
Wash, Colorado.
  Oil shale retorts generate gases and an
oil/water mixture from  shale pyrolysis,
combustion of carbonaceous residues, and
decomposition of inorganic carbonates.
As shown in Figure 1, off-gases generated
from an  in-situ  retort  exit the  retort
bottom and are brought to the surface for
treatment. The retort oil/water mixture
accumulates in the product collection
sump at the retort bottom and is subse-
quently  pumped  out  and treated to
recover  the  bulk  of the shale oil. The
separated gas condensate and  retort
waters are the wastewaters which were
studied at the Logan Wash field site.
  At Logan  Wash, treatability studies
were conducted for three weeks on retort
water using  filter coalescing,  floccula-
tion/clarification, and steam stripping
technologies (Figure 2). Also, studies were
conducted for 14 weeks on gas conden-
sate wastewater using filter coalescing,
steam stripping, conventional and pow-
dered activated carbon  (PAC)  activated
sludge treatments,  sand filtration, and
granular  activated carbon adsorption
technologies (Figure 3).
  The test equipment and supporting
field laboratory for conducting the
treatability studies were either provided
by EPA or procured by MRC. Equipment
layout at the trial location is shown in
Figure 4. Analytical  methods utilized
adhered  to  Standard  Methods when
applicable.
Test Results

Retort Water - Overall
Treatment
  Retort water was  treated primarily to
remove oil and grease, suspended solids,
ammonia,  and  alkalinity.  The filter
coalescer, flocculator/clarifier,  and
steam stripper in series  were used to
remove these pollutants. The overall
treatment scheme was very effective for
ammonia and alkalinity removal (Figure 5).
Relatively high sulfide, TKN, and phenols
removals were also achieved. Due to low
levels of oil and  grease, and suspended
solids, the scheme was not effective in
removing these pollutants.
                                                         Product Oil
^ Off-Gas
\~~ (Noncondensible)
•
Gas Condensate ^ „ , 1
Water "*" Conderuen |
Air/Steam—^ m
-»•
Oil /Water
Separation
\
Retort Water

               Rubblized
                Shale
                                                  \OH/Water
                                    Product
                                Collection Sump

Figure 1.   Production of gas condensate and retort waters by modified in-situ (MIS) retorting.
Raw Retort
Water
                                                    Flocculator
                                                    Clarifier
                                                      I
                                                    Steam
                                                    Stripper
Figure 2.   Retort water treatment scheme.


Gas Condensate - Overall
Treatment
  Filter coalescing, steam stripping,
conventional activated sludge treatment,
sand  filtration, and GAC adsorption
comprised the overall treatment scheme
for the gas condensate. The scheme was
very effective in removing ammonia,
organics, sulfide, alkalinity,  and solids
from  the gas condensate.  Assuming
conditions  listed below,  the scheme
would produce a final effluent with the
expected composition presented in Table
1.

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                                                         Activated Sludge
                                                                                  Waste
                                                                                  Sludge
                       Overhead
                       Vapor
  _ Raw Gas
  ' Condensate
     Filter
     Coalescer
 Light ±
 Oils "
Steam,
          Steam
          Stripper
Gravity
Separator
                                          Aeration Basin
                                          (With/Without
                                          Powdered
                                          Activated Carbon)
                                                                 Return Sludge
                                                                Granulated.
                                                                Activated
                                                                Carbon
                                                                Columns
                                                                                                         Discharge
 Light
 Oils
Figure 3.    Gas condensate wastewater treatment schemes.
  Steam stripper:
  GL/ratio =0.15 kg/liter
          (1.2lb/gal)
Activated sludge system:
  Hydraulic retention time = 16 hours
  Sludge age = 32 days
GAC column:
  Contact time = 19 minutes
  The other treatment scheme comprised
filter coalescing,  steam  stripping, and
GAC adsorption. The scheme was effec-
tive  in  removing ammonia, organics,
sulfide, alkalinity,  and solids from the gas
condensate.  But, the  performance  of
granular activated carbon adsorption was
relatively poor and this scheme was less
effective in removing pollutants than the
one with  an  activated sludge system
included.

Conclusions
  Pilot-scale field treatability studies on
real-time  oil shale wastewaters from
Occidental in-situ MIS  retorts  demon-
strated that retort water had high concen-
trations of ammonia,  TKN, alkalinity,
dissolved organics, phenols, sulfide, and
TDS;  and gas condensate had high
concentrations of ammonia, TKN, dis-
solved organics, alkalinity, phenols, and
sulfide. Steam stripping was effective in
removing  ammonia and  alkalinity from
the retort water.  Steam  stripping, acti-
vated sludge treatment - both  conven-
tional and PAC, sand filtration, and GAC
adsorption were  effective  in removing
ammonia, alkalinity, TKN, nitrate, soluble
COD, soluble BODs.  DOC, phenols,
sulfide, and TSS from the gas condensate.
                           Pollutant removal  efficiencies across
                           individual treatment units for retort water
                           and gas condensate treatment schemes
                           are presented in Tables 2 and 3, respec-
                           tively.

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                                                Wastewater
                                                Supply Tank
                                                28 kiloliters
                                                (6.000 gallons)
                                                                                   Elevation: 18 meters (60 ft)
                                                                                             Above Product Level
  Retort
  Water
  Trailer
  2.4 m,x'13.7 m
  <8'x45')
   Trickling
   Filters
   (Not Used)
        •5

        1
     Filter
     Coalescer
 Gas
 Condensate
 Trailer
2.4mxil3.7m
 <8'x45l)
                    O O
       EZU
       Laboratory
       Waste Storage
       2 kiloliters
       (500 gal.)
                              Laboratory Trailer
                              2.4 mx 7.6 m
                              (8'x25')
Carbon
Adsorbers
   i
Media
Filters
                        Stripper Skid
                        2.4 m x 6.1 m
                        (8'x20')
                         fSteam
                         \Stripper
                               Q
                                                               Boiler Skid,
                                                               2.4 x 4.6 m
                                                               (8' x 15')
                                                                              Boiler Feed
                                                                       rij- Water Tank
                                                                              130 liters
                                                                       LJ    (35 gal.)
Water
Softener
                                                          Fresh
                                                          Water
                                                          Storage
                                                          15 kiloliters
                             Stripper Overhead _-	
                             Storage 870 liters (230 gal.}
                                       Air
                                       Compressor
                               Trial Location Area
                          __, 18.3 m x 24.4 m (60' x 80')
                               on Product Level
                               Elevation: 2,300 meters
                                        (7.700ft)
                                                   Effluent
                                                   Sump
                                                   Tank
                                                   1.100 liters
                                                   (300 gal.)
                           Fresh Water
                           Supply and
                           Distribution System


                           Elevation: Below Product Level
                                                     Fuel Oil Storage
                                                     15 kiloliters
                                                     (4,000 gal.)
Figure 4.    Equipment general layout at the trial location.

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  700
   901
   70
   60
5  50
o
i
   40
   30
   20
   10
                                                           Ammonia
                                                            ,0
                                                            Alkalinity
                                                             I
                  0.06
                  (0.5)
0.12
(1.0)
0.18
(1.5)
0.24
(2.0)
0.30
(2.5)
            G/L Ratio, kg/steam/liter feed water (Ib steam/gallon feed water)
Figure S.    Percent ammonia and alkalinity removal from retort water as a function of G/L ratio
             in the steam stripper.

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Table 1. Overall Gas Condensate


Parameter
NH3-N
TKN
NO3-N
Soluble COD
Soluble BODs
DOC
Phenols
Sulfide
TSS
VSS
Alkalinity as CaCO3
to pH 4.5
pH*
Oil and greasec
Treatment Scheme Performance Summary
Concentration,
Raw
wastewater
9.000
6,800
1.1
2.700
8OO
890
120
72
7
5

31.000
8.5

mg/L
Final
effluent
90
180
0.4
50
20
25
0.02
2
5
5

350
7.5


Percent
removal
99
97
64
98
98
97
100
97
29
0

99
NA*

'Standard pH units.
"NA - not applicable.
"Oil and grease were at low levels (average 18.6 mg/L) in the gas condensate received for testing;
however, an oil and grease removal treatment step may be necessary if the raw gas condensate has
a relatively high oil and grease level.
Table 2.
Pollutant Removal Efficiencies Across Individual Units for Retort Water Treatment
Scheme*"
Parameter
Oil and grease
Ammonia
TKN
Soluble BODS
DOC
Phenols
TSS
VSS
Alkalinity as CaC03
to pH 4.5
Fluorides
Chlorides
Filter
coalescer
6





21
20




Flocculation
clarification0






0



7
11
Steam
stripper6

97
88
5
4
32



47


"Average removal efficiencies are reported.
''Blanks indicate data not collected.
°Lime dosage at 9O mg/L.
"G/L = 0.18 kg/L (1.5 Ib/gal).

Table 3.     Pollutant Removal Efficiencies A cross Individual Units for Gas Condensate Treatment
            Scheme"'"
                                                Treatment unit
Filter
Parameter coalescer
Oil and grease 28
Ammonia
TKN
Soluble COD
Soluble BODs,
DOC
Phenols
Sulfide
TSS
Alkalinity as CaCO3 to
pH4.5
Steam
stripped

99
96
56

60
29
97

99

Activated
sludge
treatment11

6

59
91
52
93




GAC
Sand adsorption
filter column*



95
70
89
99.5

70


"Average removal efficiencies are reported.
^Blanks indicate data not collected.
CG/L = 0.19 kg/L (1.6 Ib/gal) average.
"Hydraulic retention time =16 hours, sludge age - 32 days.
"Contact time =19 minutes.
                                                                                                      *USGPO:   1984-759-102-10653

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      B.  O.  Desai.  D.  R.  Day,  and  T. E.  Ctvrtnicek are with Monsanto Research
        Corporation, Dayton, OH 45418.
      W. W. Liberick. Jr. is the EPA Project Officer (see below).
      The complete report,  entitled "Logan Wash Field  Treatability Studies  of
        Waste waters from Oil Shale Retorting Processes," (Order No. PB 84-211 143;
        Cost: $17.50, subject to change) will be available only from:
               National Technical Information Service
               5285 Port Royal Road
               Springfield. VA 22161
               Telephone: 703-487-4650
        The EPA Project Officer can be contacted at:
               Industrial Environmental Research Laboratory
               U.S. Environmental Protection Agency
               Cincinnati, OH 45268
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use $300
                                      It-

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