United States
Environmental Protection
Agency
Air and Energy Engineering
Research Laboratory
Research Triangle Park NC 27711
                                                                        11/
Research and Development
EPA/600/S2-84-118  Nov. 1985
Project  Summary
Control  of  Industrial  VOC
Emissions by  Catalytic
Incineration
Michael A. Palazzolo
  This two-phase study was part of a
comprehensive assessment  of the
performance, suitability, and costs of
various  technologies to control the
emission of volatile organic compounds
(VOCs), including the use of catalytic
incineration. In Phase 1, information
was assembled from the literature on
the use and cost of using catalytic
incineration for VOC control. Phase 2
was a testing program (involving eight
industrial catalytic incinerators) designed
to increase  the catalytic incinerator
performance data base.
  This Project Summary was developed
by EPA's Air and Energy Engineering
Research Laboratory, Research Triangle
Park, NC, to announce key findings of
the research project that is fully docu-
mented in nine separate volumes (see
Project Report ordering information at
back).
Introduction
  The emission of volatile organic
compounds (VOCs) from industrial plants
significantly increases  ambient levels of
photochemical oxidants,  ozone, and
smog. Control of industrial  VOC emis-
sions, therefore, can result in substantial
environmental benefits. Catalytic incin-
eration has been evaluated as an indus-
trial VOC control technology. This study
was part of a comprehensive assessment
of the performance, suitability, and costs
of various VOC control technologies.
Objectives of the program were two-fold:
(1) to provide an overview of how catalytic
incineration is applied to control industrial
VOC emissions and to assess the overall
performance typically achieved in various
applications,  and (2) to gather actual
performance data through an EPA-
 sponsored testing program on operating
 industrial catalytic incinerators.
   These objectives were met in two
 phases. In Phase 1,  information was
 assembled from the literature on the use
 and cost of using catalytic incineration for
 VOC control.  This work involved: (1) a
 review of current and developing catalytic
 incineration technology, (2) an assess-
 ment of the overall performance of
 catalytic incinerators, (3) a review of
 applications where catalytic incinerators
 are used, (4)  a comparative analysis of
 catalytic incineration with other compet-
 ing VOC controls, (5) an examination of
 available methods for  testing emissions
 from catalytic  incinerators, and (6) an
 assessment of the  need for additional
 performance test data.
   Based on the recommendations of
 Volume 1 of this report (prepared follow-
 ing Phase 1), that additional performance
 test data were needed to more fully
 characterize catalytic incinerators. Phase
 2 was  initiated. Phase  2, designed to
 increase the catalytic incinerator perform-
 ance data base by testing eight catalytic
 incinerators at industrial sites, included
 site identification and selection, test plan
 development, and performance data
 collection.
   The output from Phase 2 consisted of a
 series of reports documenting the per-
 formance of eight catalytic incinerators at
 six industrial sites. Performance was
 measured at several process conditions
 at each site visited. The results of Phase 2
 are presented in Volume 2 (the final
 report) and in Volumes 3 through 8 (test
 reports on the individual sites).
   This Summary is divided into two parts,
 reflecting the work under Phases 1  and 2
 (emissions control by catalytic incinera-

-------
tion  and catalytic incinerator  perform-
ance, respectively).


Phase 1.  Control of Industrial
VOC  Emissions by Catalytic
Incineration
  This portion of the Summary describes
the technology, performance, and current
usage and applications; compares cataly-
tic incineration  with other VOC control
alternatives; discusses test methods; and
indicates a  need for additional test data.

Technology Description
  The destruction  of VOCs in an incinera-
tor involves high  temperature oxidation
(burning) of the VOCs to carbon dioxide
and water.  Conventional thermal incin-
erators typically use a supplementary fuel
(e.g., fuel oil or natural gas) to heat  the
VOC-containing waste gas to the required
oxidation temperature, which depends on
the VOCs  being  oxidized,  mixing and
residence time,  and the desired destruc-
tion efficiency.
  Catalytic incinerators are similar to
thermal incinerators; however, a catalyst
bed is  incorporated into the design. The
catalyst allows the oxidation reaction to
proceed at  a lower temperature. In some
applications, catalytic incinerators can be
designed with  flue gas  heat recovery
systems so that no supplemental fuel is
required for self-sustaining operation.
However,  most  catalytic  incinerators
require  some  supplementary fuel to
maintain incinerator operating tempera-
tures during periods when the process is
running at  reduced capacity.
  The catalyst bed usually consists of a
precious metal  deposited on a metal or
ceramic  catalyst support. Platinum  and
palladium  alloys are the  most common
catalysts; however, other precious (and
some  nonprecious) metals are  used.
Common types of catalyst bed geometries
are ribbons, pellets, rods, and honeycombs.
Both catalyst formulation and  substrate
configuration are  considered proprietary
by catalyst  manufacturers.
  Although not required for  operation,
many  catalytic  incinerators  incorporate
some method of recovering (reclaiming)
heat  from  the  hot exhaust exiting  the
catalyst bed. Recuperative heat exchangers
preheat  the VOC-containing waste  gas
and/or  combustion  air prior  to  the
catalyst bed;  the  hot exhaust gases  exit
the catalyst bed.  Recycle heat recovery
systems return  a fraction of the  hot
exhaust gases to the VOC  emitting
process. Another  way to recover heat is
to duct the hot incinerator  exhaust  to  a
waste heat boiler  to produce hot water or
steam. Heat recovery systems may use
combinations of these schemes and may
integrate the system into the overall plant
energy recovery system.
  Catalytic incineration is a relatively
mature VOC control technology, with
about 10 vendors supplying the market.
Although refinements in design are
continually  occurring, no major new
design advances were identified.

Performance
  The performance of a catalytic incinera-
tor is affected by variables including:
operating temperature, space velocity,
VOC concentration and species, catalyst
characteristics, the presence of poisons
or masking agents, and a heat recovery
system. Of these, operating temperature
is a major factor affecting VOC destruction
efficiency. Higher operating temperatures
result in greater VOC destruction; how-
ever, supplemental fuel usage is generally
increased. The optimum operating tem-
perature provides adequate VOC destruc-
tion at minimum fuel cost. Most catalytic
incinerators operate in the temperature
range of 700 to 1100 °F (370 to 590 °C).
  An  analysis of available  test data
indicates that catalytic incinerators can
achieve VOC destruction  efficiencies
greater than 95  percent and VOC outlet
concentrations less than 200 ppm. Some
units achieve efficiencies greater than 98
percent. A few applications with relatively
high inlet concentrations have obtained
efficiencies of greater than 99 percent.
Typically,  however, the incinerator  is
operated at lower temperatures to reduce
supplemental fuel use while still providing
adequate VOC destruction.
Current Usage and
Applications
  Catalytic incinerators are used  in a
number of VOC pollution control applica-
tions: an estimated 500 to 2000 units are
in service. Current applications can be
categorized in three broad process areas:
solvent evaporation, organic chemical
manufacturing, and miscellaneous.
  Solvent  evaporation comprises the
most catalytic incinerator  applications,
including  metal coating (can, coil, wire,
auto/truck, furniture, small parts), paper
coating (adhesive coating, rotogravure
printing, flexography printing), and fabric
coating. These operations  generally
produce waste gas streams  with VOC
concentrations of up to 25 percent of the
lower explosive  limit (LEL), the VOC
concentration at which an explosion can
occur after an initiating spark or flame.
The  two  principal VOC  emitters are
 application stations and ovens/dryers. In
 many processes, the  oven exhaust
 includes solvent vapors captured during
 solvent application. Approximately 60
 percent of the plants identified as using
 catalytic incinerators are solvent coating
 operations.
   The second group of processes includes
.a variety of organic chemical manufactur-
 ing  processes. Air oxidation processes
 used in petrochemical manufacture are
 frequently  suitable for control  with
 catalytic incinerators.  To date,  VOC
 emission streams from the production of
 ethylene  oxide, acrylonitrile, formalde-
 hyde, ethylene dichloride, vinyl chloride
 monomer, and  maelic  anhydride  have
 been controlled with catalytic incinera-
 tors. Waste  gas streams  from  organic
 chemical  manufacturing processes vary
 greatly depending  on the specific chemi-
 cal  being produced and the  type  of
 process.  VOC  concentrations show
 considerable variation,  from 5  to over
 100 percent LEL. The number of catalytic
 incinerators used in the control of organic
 chemical processes is considerably small-
 er compared to solvent evaporation pro-
 cesses. Of the plants identified as using
 catalytic incinerators, about 15  percent
 are organic chemical  manufacturing
 plants.
   The third  group,  miscellaneous pro-
 cesses,  includes a wide variety  of
 industrial VOC emitting processes.
 Catalytic incinerators are being,  or have
 been, applied to varnish cooking, catalyst
 regeneration, foundry core ovens, textile
 manufacturing, kraft pulping, plywood
 veneering, filter paper  processing, and
 gasoline  vapor emission  control. This
 third group comprises about 25  percent
 of the plants identified as using catalytic
 incinerators.

 Comparison with Other VOC
 Control Alternatives
   Catalytic incineration  is one of several
 available VOC control technologies,
 including carbon adsorption, absorption,
 condensation, thermal incineration, and
 process modifications  which  reduce
 uncontrolled VOC  emissions. Although
 each of these technologies is suitable for
 specific processes, only incineration and
 adsorption are generally applicable to a
 wide variety of VOC emitting processes.
 In most applications, catalytic incinera-
 tion competes directly with thermal
 incineration and carbon adsorption as the
 most cost effective control technique. A
 direct comparison of these three control
 alternatives  provides useful information
 concerning the relative advantages and
 disadvantages of each.

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  Concerning VOC destruction efficiency,
catalytic incineration, thermal incinera-
tion,  and carbon adsorption  all can
potentially achieve VOC removal efficien-
cies  greater than 95 percent.  Because
thermal incinerators can be operated at
extremely high  temperatures (up  to
2000°F— 1090°C—with proper construc-
tion), the ultimate potential efficiency of
thermal incineration is somewhat higher
than either catalytic  incineration and
carbon adsorption. However, all  of  these
technologies  are typically designed and
operated to achieve lower than ultimate
VOC destruction due to cost constraints.
Where  extremely high VOC  removal
efficiencies and/or extremely low VOC
outlet concentrations are required,
thermal incinerators may be preferred.
  Energy  use variations between the
three technologies are significant.  Ther-
mal  incineration  is  the highest energy
user due to the high supplemental fuel
required to preheat the VOC waste gas
stream to oxidation temperature.  If hot
water or steam is required, coincident
with incinerator operation, a waste heat
boiler may be used to recover much of this
heat. Catalytic incinerators require signifi-
cantly less fuel than thermal incinerators
in most  applications.  Compared to a
thermal incinerator  achieving  similar
VOC destruction,  a catalytic  incinerator
can reduce supplemental fuel by  25  to
100 percent, depending on the types and
amounts of heat recovery employed. This
reduction is due to the lower operating
temperature required to sustain catalytic
oxidation. Carbon adsorption systems are
potentially the lowest energy users and,
in fact, usually provide  a net energy
credit, because  of the energy credit
realized in the recovery of VOCs. The
recovered VOCs may be either used as a
fuel or recycled for reuse.
  The ability of each technology to meet
the site-specific needs of a given  applica-
tion differs widely for the three technolo-
gies.  Carbon  adsorption  systems are
generally the  least flexible, requiring: (a)
waste gas temperatures of 100°F (38°C)
or less, (b)  low  levels of waste gas
particles, and (c)  reasonably consistent
waste gas VOC compositions. Considera-
tions (a) and (b) are necessary to prevent
damaging  or  masking the  carbon  beds;
constraint (c)  ensures that  the adsorbed
VOCs can be separated and recycled. Use
of waste gas  coolers, waste  gas filters,
and complex VOC distillation systems can
alleviate these considerations (at higher
costs).
  Catalytic incinerators are more tolerant
of waste gas impurities; however, poisons
(e.g., phosphorus,  bismuth,  lead,  arsenic,
antimony, and mercury) must be avoided.
Catalyst deactivating agents (e.g., sulfur,
halogens, zinc, iron, tin, and silicon) may
be tolerated for short periods. Particles in
the waste gas stream can be tolerated at
low levels; however, erosion  of the
catalyst is accelerated. Sticky substances
which mask the catalyst must be avoided
unless the catalyst is frequently cleaned.
  Since thermal incinerators have limited
constraints associated with waste gas
characteristics, they are ideal for applica-
tions involving the treatment of multiple
streams from different processes.
  Both thermal and catalytic incinerators
are well suited  to retrofit applications
where size and space  are at a premium.
Catalytic incinerators, somewhat smaller
and  lighter  than thermal incinerators,
have a slight advantage in this regard.
  Operation and  maintenance require-
ments also vary considerably among the
three technologies. Carbon adsorption
systems are comparatively complex and
generally have the highest operation and
maintenance requirements. Both cataly-
tic incineration and thermal incineration
have roughly similar operation and
maintenance requirements.
  The cost of applying any of the three
technologies varies greatly depending
on the process. A cost analysis of eight
VOC emission sources indicates catalytic
incineration is the most economical for
processes  with  low  waste  gas VOC
concentrations, and that carbon adsorp-
tion is the most economical for processes
with high waste gas VOC concentrations.
However, many  processes with  high
waste   gas  VOC  concentrations are
unsuitable  for  control with  carbon
adsorption due to either high waste gas
temperatures or the difficulty  in separa-
tion and recovery of the VOC after
adsorption. In these cases, thermal and
catalytic incineration are directly compet-
itive. In the range of VOC concentrations
from 15 to 25 percent LEL, costs of both
incineration techniques are similar.
Thermal incineration  is generally the
lower cost option at the upper end of this
range,  and  catalytic incineration  is
generally the lower cost  option at the
lower end of the range.
  The primary reason for the lower cost
and energy  requirements of catalytic
incineration compared to thermal incin-
eration  is the reduced supplemental fuel
use. A  relatively  new type of  thermal
incinerator,  now  available, reportedly
uses considerably less fuel through the
use of regenerative heat exchange.
Depending on overall costs, this reduction
in fuel use can result in thermal incinera-
tion's  being cost competitive  at  VOC
concentration levels of less than 15
percent LEL.
  The costs of carbon adsorption are very
sensitive to the  economic value of the
recovered  VOC.  Relatively  expensive
VOCs can make carbon adsorption cost
effective for sources with relatively low
VOC concentrations.
  To summarize, catalytic incineration is
well suited to VOC control problems with
the following characteristics:
  — destruction  efficiencies of 95 per-
     cent or higher;
  — VOC concentrations of 20 percent
     LEL or less;
  — high temperature waste gases;
  — mixtures of VOCs where separation/
     recovery would  be difficult for
     carbon adsorption systems;
  — VOCs of relatively low economic
     value;
  — little or no poisons, masking agents,
     or particles; and
  — retrofits where small size and light
     weight are critical.

Test Methods
  For an overall  assessment of the per-
formance of catalytic incineration in a
given application, both process/incinera-
tor  characterization and emission mea-
surements are required. Process/incin-
erator  measurements collected include
temperatures, pressures, flow rates, and
fuel use. Emission measurements include
VOC concentrations and gas flow rates in
the inlet and outlet of the incinerator.
  A variety of VOC measurement methods
are available. To ensure that data  are
collected using standardized and accep-
ted procedures, EPA reference methods
were  recommended. A combination of
Method 25A and draft Method 18
provides several advantages.  Method
25A, utilizing a flame ionization analyzer
(FIA), could be run continuously over
several days to allow the effect of process
fluctuations to be assessed. A disadvan-
tage of  Method 25A  is the  lack of
compound specific VOC concentration
information (the FIA gives only a relative
concentration with respect to a calibration
gas). Method 18 involves gas chromato-
graphic analysis  which provides com-
pound  specific concentrations.

Need for Test Data
  The  information data base collected
prior to the current testing program was
judged deficient in several respects.
Available data had  been collected with
varying test procedures and were lacking
in documentation. Most  emission data
were collected with the sole objective of
determining compliance with emission

-------
standards. For this reason, other factors
pertinent to catalytic incineration  per-
formance (e.g.,  fuel  use) were neither
measured nor recorded.
  It was recommended at the conclusion
of Phase 1 of this study that a comprehen-
sive testing program be initiated to test in
the field  a  variety of operating catalytic
incinerators. The remainder  of  this
Summary discusses results of the tests
that were  initiated as a result of this
recommendation.

Phase 2.  Performance of
Catalytic Incinerators at
Industrial Sites
  This portion of the Summary describes
test site selection criteria, the testing
approach and methods, and test results.

Test Site Selection Criteria
  The catalytic incinerator tests examined
catalytic  incinerator  performance from
two perspectives: (1)  how well the
technology  performed when  applied  to
industries  that typically use catalytic
incineration, and  (2) how incinerator
performance relates to  a  variety  of
process variables.
  During Phase 1 of this study, 149 sites
using catalytic incinerators were identi-
fied. These sites formed the basis of the
site  selection task. (Note:  This  list  of
plants is a  random compilation of sites
based on available data. As such, the
relative number of plants identified in any
industrial sector may be biased due to the
availability  of information in that sector.)
  Of the 149  sites  identified, 86 (58
percent) represent four industries: metal
can coating, magnet wire production,
organic chemical  manufacturing, and
printing. To test  at least one incinerator in
each of these four major industries using
catalytic incineration, 8 to 10 plants were
contacted  in each category. Industry
participation in the  test program  was
strictly voluntary; several factors (eco-
nomic and operational) resulted  in
several plants being tested in some areas
and none in others. Catalytic incinerators
were ultimately tested in four industries:
metal can  coating, coil coating, magnet
wire production, and graphic arts printing.


Testing Approach and Methods
  Evaluating the performance of indus-
trial catalytic incinerators consisted of (1)
developing  plant-specific test plans and
test methods to characterize incinerator
performance,  and (2) several  days  of
comprehensive  on-site testing for each
incinerator. Testing  focused  on simul-
taneously monitoring  inlet and outlet
VOC  concentrations  and measuring
incinerator operating conditions.
  The primary test method used to
measure incinerator destruction efficien-
cy was EPA Method  25A. Draft  EPA
Method 18 was also used as an auxiliary
method to determine destruction efficien-
cies and to speciate components in the
gas stream.  Samples of the incinerator
inlet and outlet gas streams were drawn
continuously  from the  stack  through  a
heated probe,  pump, and Teflon" umbilical
to a mobile laboratory for analysis.


Results  of Testing
   Eight catalytic incinerators were tested
at six industrial sites between November
1982 and March 1983. All eight were
used to control  VOC  emissions from
solvent evaporation processes. In these
processes, pigments,  inks,  or  resins
dissolved in organic solvents are applied
to metal or paper surfaces. The solvents
are then driven off the surfaces in drying
ovens, and the oven exhaust is ducted to
a catalytic incinerator for solvent destruc-
tion.  Incinerators at can coating, coil
coating, magnet wire,  and graphic arts
printing plants were tested.
   Incinerator performance  was charac-
terized in terms of destruction efficiency,
outlet solvent concentration, and energy
usage. Inlet and outlet solvent concentra-
tions were monitored with hydrocarbon
analyzers  during a nomimal 1-week test
at each site.  Incinerator design and
operating  data (e.g., operating tempera-
ture,  solvent type, and catalyst volume
and age) were collected on each  incin-
erator to document the operating condi-
tions during the test. Waste gas charac-
teristics  and  design and  operating
parameters  for  each  incinerator  are
shown in Table 1.
   Performance  data collected during
typical plant operation are summarized in
Table 2. Four of  the eight incinerators
showed destruction efficiencies in excess
of 90 percent  under typical plant and
incinerator operating conditions. These
incinerators were applied in can coating,
coil  coating,  and graphic arts printing.
Destruction  efficiencies for each  incin-
erator generally  varied over a narrow
range for different coatings or inks.
   A  fifth  incinerator  showed slightly
lower efficiencies, between 88 and 94
percent. This incinerator was also applied
in can coating.
   The three  remaining incinerators all
showed comparatively low destruction
efficiencies of about 80 percent. The low-
er efficiencies at two of these sites are
attributed to the catalyst condition. One
catalyst bed was fouled or deactivated by
high temperature operation or material
masking, and the other appears to have
been deactivated by  normal catalyst
aging. The  lower efficiency at the third
site is due  to a  lower  solvent-laden air
(SLA) residence time.  This incinerator,
which  was much  older, had a  SLA
residence time approximately half that of
the newer incinerators tested.
  Two of the three  incinerators that
showed  comparatively low destruction
efficiencies were applied in the graphic
arts printing industry, and the third was
applied to a magnet wire coating line.
  Outlet total hydrocarbon (THC) concen-
trations based  on EPA  Method 25A
ranged widely for the eight incinerators,
from 46 to  1590 ppmv carbon. However,
measured  outlet concentrations were
below  350 ppmv for  six of the eight
incinerators.
  Energy usage for most of the incinera-
tors ranged from 78 to 268 kJ/Nm3(2.1 to
7.2 Btu/scf) of waste  gas treated. One
incinerator had an estimated energy
usage of 782 kJ/Nm3 (21 Btu/scf).
  Comparison of destruction efficiencies
measured according to Method 25A and
Method 18 showed good agreement.
  At several test sites, the incinerator
operating  temperature was varied to
observe  the  effect of temperature  on
performance. As expected, destruction
efficiency increased  with increasing
operating  temperature. However, the
relative effect of temperature on destruc-
tion efficiency  varied widely for the
different incinerators. Of five incinerators
for which the temperature was varied,
two showed  a fairly small  effect of
temperature and three showed a  com-
paratively large  effect. The largest
increase in efficiency for a temperature
rise of 14°C (25°F) was 2.5 percent, from
84.0 to 86.5 percent.
  Inlet  concentration  as  measured  by
Method 25A was also observed to have
an  effect on destruction efficiency. For
similar  catalyst  bed inlet temperatures,
destruction efficiency increased with
increasing inlet concentration. Inlet
concentrations generally  varied.for
different coatings and coating rates. The
effect of inlet concentration was found to
be  greatest for incinerators operating at
efficiencies below 85 percent.

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Table 1.      Waste Gas Characteristics and Incinerator Design and Operating Parameters
Plant ID
(Incinerator No 1 Process
Plant C- 1 127)



Plant C-1 128)



Plant C-4



Plant C-2


Plant C-3 1201


Plant C-3 121)


Plant C-5

Plant C-6

Can
coating


Can
coating


Can
Coating


Graphic
arts
printing
Graphic
arts
printing
Graphic
arts
printing
Magnet
wire
Coil
coating
Waste Gas Waste Gas
Flowrate* Temperature
Nm*s Iscfml °C (°F)
36 (7600f 121



3 2 167801" 89



2 52 IS33OI 164



09 {2000) 127


126 12660) 177


220 14670) 178


0 28 (603) 233

533 I113OO) 143

1250)



(190)



(327)



1260)


(350)


(352)


(451)

(290)

Mafor
Solvents
Identihecf
Toluene,
xylenes.
ethyl
benzenes
MIBK.
xylenes*
methyl ethyl
benzenes
MIBK.
ce/lusolve.
xylenes.
ethylbenzene*
C12toC18
hydrocarbons

C12toC18
hydrocarbons

C12 to C18
hydrocarbons

Phenol,
cresots
MEK,
toluene*
Average
Temperatures' Catalyst Bed
Catalyst Inlet/Outlet Pressure Drop
°C m kPa fH&l
363/396



316/410



332/393



493/438


372/379


353/412


393/507

285/427

1685/745) 0 60



(600/770) 0.57



(630/740) 042



(920/820 f 2 5


(701/713) 025


(667/774) 0 25


(740/945) 0 17

(545/800) 0 42

(24)



(23)



(1.7)



(10)


(10)


(10)


fO 7)

(17)

SLA
Catalyst Residence
Age Time
Catalyst months sec
Ceramic 8 003
honeycomb


Ceramic 23/
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Table 2. Summary of Performance Data for Typical 0
Plant ID Coatings Hours of
(Incinerator No.j° Process Tested Data0
Plant C-1 (27)

Plant C-1 (28)

Plant C-1 (28)

Plant C-4

Plant C-2


Plant C-3 (20)


Plant C-3 (21)


Plant C-5
Plant C-6
Can
coating
Can
coating
Can
coating
Can
coating
Graphic
arts
printing
Graphic
arts
printing
Graphic
arts
printing
Magnet wire
Coil coating
1

3

7

2

1


1


5


1
5
27.6

7.8

26.0

13.0

23.0


5.5


7.2


13.8
27.0
Operating Conditions3
Method 25A Concentrations"
Inlet, ppmv
4000-5810

2840-7760

2270-5755

5480-7560

1020


1240


1370-4030


8720
6220-12.860*
Outlet, ppmv
181-275

173-321

46-341

385-687

169


241


90-165


1590
272-305
Destruction
Efficiency
%e
95.4-96.4

93.4-95.9

96.3-98.6
(91.7-93.4f
88.7/94.0

81.2


80.1


93.4-95.9


80.6
96.5-97.5
Average
Energy Usage'
kJ/Nm (Btu/scfJ Heat Recovery, %
270

230

230

260

780


160


80


240
150
(7.2)

(6.1)

(6.1)

(6.9)

(21)


(4.3)'


(2. If


(6.4 f
(3.9)
39a

46g

46a

None

None


36'


66,


None
31s
"For steady state incinerator and coating process operating conditions.
hTests conducted between November 1982 and March 1983.
cCollected at typical incinerator operating temperature (see Table 1).
aFor the incinerator inlet/outlet gas streams. The range of values represents the range of average concentrations measured during monitoring periods
 for the different coatings tested. Monitoring periods generally exceeded 1 hour, ranging up to about 14 hours. Method 25A results for different
 monitoring periods are summarized in the Site Test Reports, ppmv = parts per million by volume carbon, quantitated against propane standards.
"For all except Plant C- 1:
Destruction efficiency =l^J^Lx 100%, where
M = VOCmass flowrate =
                         V moles C
                                           12° C x rnoles gas , O m* gas
                                                             sec
                            10s moles gas  mole C  0.024m3
    V = VOC concentration, ppmv (in or out)
    Q - gas flowrate, Nm3/sec (in or out)
 For Plant C- 1;
Destruction efficiency =V'"~ V°M* 100%.
                        V,n
'For fuel gas required to heat  waste gas to catalyst bed inlet temperature.
9By recycling incinerator outlet gas to drying oven; represents percent recovery of heat generated by natural gas and fuel combustion in the incin-
 erator.
^Values for one of the seven coatings tested.  This solvent formulation apparently had a greater percentage of MIBK and a higher average solvent
 molecular weight than the others.
'Based on waste gas temperature and catalyst bed inlet temperature.
'By recuperative heat exchange; represents percent recovery of heat required to raise the waste gas temperature to the catalyst bed inlet temperature.
*For gas stream from exhaust oven.
  . S. GOVERNMENT PRINTING OFFICE: 1985/646-116/20717

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     M. Palazzolo is with Radian Corporation, Durham, NC 27705.
     P. J. Chappell is the EPA Project Officer (see below).
     The complete report consists of nine volumes, entitled "Control of Industrial VOC
       Emissions by Catalytic Incineration:"
         "Volume 1. Assessment of Catalytic Incineration and Competing Controls,"
         (Order No. PB 84-225 762; Cost: $16.95)
         "Volume 2. Final Report on Catalytic Incinerator Performance at Six Industrial
         Sites,"(Order No. PB 84-225 770; Cost: $11.95).
         "Volume 3. Catalytic Incinerator Performance at Industrial Site C-1," (Order
         No. PB 84-225 788; Cost: $16.95)
         "Volume 4. Catalytic Incinerator Performance at Industrial Site C-2," (Order
         No. PB 84-225 796; Cost: $11.95)
         "Volume 5. Catalytic Incinerator Performance at Industrial Site C-3," (Order
         No. PB 86-103 199; Cost: $16.95)
         "Volume 6. Catalytic Incinerator Performance at Industrial Site C-4," (Order
         No. PB 84-225 812; Cost: $11.95)
         "Volume 7. Catalytic Incinerator Performance at Industrial Site C-5," (Order
         No. PB 86-103 173; Cost: $11.95)
         "Volume 8. Catalytic Incinerator Performance at Industrial Site C-6," (Order
         No. PB 86-103 181; Cost: $16.95)
         "Volume9. Quality Assurance." (Order  No. PB 84-225 846; Cost: $16.95)
     The above reports will be available only from: (costs subject to change)
            National Technical Information Service
            5285 Port Royal Road
            Springfield, VA 22161
            Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
            Air and Energy Engineering Research Laboratory
            U.S.  Environmental Protection Agency
            Research Triangle Park, NC 27711
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use $300

EPA/600/S2-84/118
         Q000529    PS

         U  S  ?NVIR PROTECTION  AGENCY
         REGION  5  LIEHARY
         230  S  DEARBORN  STREET
         CHICAGO                IL    60604

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