United States
 Environmental Protection
 Agency
 Industrial Environmental
 Research Laboratory
 Research Triangle Park NC 27711
 Research and Development
 EPA-600/S2-84-140  Sept. 1984
 Project  Summary
 Demonstration  of  Vapor  Control
 Technology for Gasoline  Loading
 of  Barges
 S. S. Gross
  The objective of the program was to
 demonstrate a safe cost-effective way
 to  control gasoline vapors emitted
 during barge loading.  Refrigeration,
 carbon adsorption, oil absorption, and
 incineration were reviewed in terms of
 their  safety,  economics,  and
 performance.  Two   barge  terminals
 were used as the  design  basis for
 extending  their existing truck loading
 vapor control systems (oil absorption
 and incineration) to include the barge
 loading facilities.  Although fabrication
 drawings  were  prepared  for  both
 terminals,  the barge vapor  collection
 system  was  installed  only at the
 terminal  using   incineration.
 Arrangements were also made to lease
 a barge with vapor collection piping and
 add additional equipment to reduce the
 likelihood of barge explosion or overfill.
 However,  before start-up  of  the
 demonstration,  the program  was
 curtailed. The system is still in place and
 could be considered for future  field
 demonstrations.
  This Project Summary was developed
 by  EPA's  Industrial Environmental
 Research Laboratory.  Research
 Triangle  Park. NC. to announce key
 findings of the research project that is
 fully documented in a separate report of
 the same title (see Project Report order-
ing information at back).


 Introduction
  Vapors emitted during the loading of
gasoline  into cars, trucks,  and barges
contribute to the  formation  of smog.
 Equipment is available which can control
these vapors at truck loading facilities, as
 well as at larger gasoline retail outlets.
  However, gasoline vapor emissions are
 not controlled at barge loading terminals
 because it has not been demonstrated
 that the more complex safety and design
 considerations have  been  adequately
 addressed.
  This  report  discusses various vapor
 control technologies and their application
 to barge loading of gasoline. Two vapor
 control technologies were selected from
 the  review:  one, based on  an  oil
 absorption system, would recover the
 gasoline; and the other, based on incin-
 eration  has   lower  installation   and
 operation costs, but no recovery.
  Two  existing terminals were used as
 the design basis for projected demonstra-
 tion of the two control technologies. Both
 terminals  had existing vapor  control
 systems at the truck loading  area. One
 terminal had an  installed oil sorption
 system, with an  additional uninstalled
 scrubber;  the  other had an  installed
 incinerator. Each  vapor control system
 had enough excess capacity to handle the
 vapors from the barge loading facilities.

  The terminal with  the  incineration
 system  was selected as a demonstration
 site. The  on-shore  vapor  collection
 system  was connected to an existing
 incineration system with the correspond-
 ing safety and flow control equipment. A
 barge with vapor collection piping was
 leased.  Equipment such as  overflow
 alarms  and flame arresters were also
purchased for installation on the barge to
reduce the risk of overfill or explosion.
Quality  assurance and quality control
plans were submitted  to the EPA for
approval. The QA/QC plan detailed the

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sampling,  data collection, and handling
procedures.
  Just before start-up, the program was
curtailed.
  During  the study  phase,  80  mg  of
hydrocarbons/L was considered the level
achievable using reasonably available
control technology (PACT). This standard
was applied to bulk loading at gasoline
truck terminals.  Subsequently,   EPA
issued  a  new  source  performance
standard (NSPS)  of 35 mg/L. The actual
emission level that may be chosen for
barge loading will be based on perform-
ance  and  cost  considerations,   not
necessarily the 80 (or more recently 35)
mg/L standard used at truck loading. The
80 mg/L standard that existed at the time
of the study was chosen only as a base
line for cost and performance considera-
tions and does not reflect EPA's attitude
toward a standard for barge loading.

Conclusions
  Of the vapor recovery systems, calcu-
lations showed that  oil absorption was
the most economical, followed by carbon
adsorption and  refrigeration.  However,
selection  of a particular vapor control
technique depends on site-specific condi-
tions.
  While calculations indicated a possible
payback with a  vapor recovery  system,
often the  payback period is longer than
the expected life of the recovery equip-
ment.
  Generally,  users  felt  that  vapor
recovery  systems   at  truck   loading
facilities are not significantly more eco-
nomical than  incineration  because  of
their higher capital and operating costs.
  Prior  EPA reports cite  80  mg  of
hydrocarbon/L of gasoline loaded as the
level achievable  with reasonably avail-
able control technology (RACT)  at truck
loading. This is  about a 90%  control.
Because  of  the  lower  efluent
concentrations  at barge loading, a 90%
control level may be  significantly below
80   mg/L.  Existing  vapor   recovery
systems can meet the 80 mg/L emission
level. However, if the emission concen-
tration  is reduced significantly, major
upgrading of the vapor recovery equip-
ment may be necessary.
  Incineration may be the lowest cost
(equipment and  operating) approach to
vapor  control,   especially  at  smaller
terminals.  However,  no  payback  is
possible,  and   there   are   additional
safety considerations.
  For the two  installations  discussed
here, passive safety equipment (e.g..
pretested  and/or  approved  flame
arresters) would  provide  an adequate
level of safety. Because of the short vapor
lines  and  prior testing  of the flame
arresters, active  safety systems (e.g.,
inerting,  vapor  saturation, and dilution)
were not used since they did not improve
the overall safety of the system. However,
in some  cases  (e.g., long vapor lines),
active safety systems should be strongly
considered.
  Equipping a barge with a vapor collec-
tion   system   when constructed  is
significantly less expensive than  a later
retrofit.
  Because the terminal operator may not
own  or operate the barge, legal questions
concerning safety and cost liability remain
to be answered.

Recommendations
  If  the  control of gasoline vapors at
barge loading facilities is desired by the
EPA, a field demonstration will be valua-
ble for safety and economic analysis of an
operational vapor collection and  control
system.
  Vapor control systems were examined
for two  gasoline terminals:  one used
vapor recovery; the other,  incineration.
Demonstrations at  both would  aid in
comparing  the  two  vapor control
technologies.
  The actual benefits of a vapor recovery
system are difficult to measure because
of the   small  fractions   of  gasoline
recovered  compared to   the  volume
transferred.  Continuous  monitoring of
the  influent and effluent  hydrocarbon
concentrations would help the user real-
ize the possible payback advantages  of a
vapor recovery  system. In any case,  the
use   of  continuous  monitoring
instruments on  the exhaust of the vapor
control units could be considered. The
performance of the  units is unknown,
unless monitored more than occasionally.

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      S. S. Gross is with MSA Research Corporation, Evans City, PA 16033.
      SamuelL. Rakes is the EPA Project Officer (see below).
      The complete report, entitled "Demonstration of Vapor Control Technology for
         Gasoline Loading of Barges." (Order No. PB 84-239 425; Cost: $10.00, subject
         to change) will be available only from:
              National Technical Information Service
              5285 Port Royal Road
              Springfield. VA 22161
              Telephone: 703-487-4650
      The EPA Project Officer can be contacted at:
              Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
              Research Triangle Park, NC 27711
   irU S GOVERNMENT PRINTING OFFICE, 1984—759-015/7820
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
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