United States Environmental Protection Agency Water Engineering Research Laboratory Cincinnati OH 45268 Research and Development EPA-600/S2-84-200 Mar. 1985 v>ERA Project Summary Technology Assessment of Carver-Greenfield Municipal Sludge Drying Process Henry C. Hyde The innovative and alternative tech- nology provisions of the Clean Water Act of 1977 (PL 95-217) provide financial incentives to communities that use wastewater treatment alterna- tives to reduce cost or energy con- sumption. Some of these technologies have only recently been developed and are not in widespread use in the United States. This document discusses the technical and economic feasibility of using one emerging technology, the Carver-Greenfield* (C-G) municipal sludge drying process, for municipal wastewater treatment facilities. The C-G process uses the principle of multi-effect evaporation and is primarily used in the food, pharmaceutical, and industrial wastewater treatment in- dustries. The C-G process can dry aqeuous solutions or slurries with a wide range of solids contents (4 to 45 percent). The C-G drying process appears to be a cost-effective, energy-efficient meth- od applicable to the wastewater in- dustry. Research and development for application to municipal wastewater solids drying has reached the point for full-scale implementation. This Project Summary was developed by EPA's Water Engineering Research Laboratory, Cincinnati, OH, to announce key findings of the technology assess- ment that is fully documented in a separate report of the same title (see Project Report ordering information at back). * Mention of trade names or commercial products does not constitute endorsement or recommenda- tion for use. Introduction The objective of this technology as- sessment was to evaluate the technical and economic feasibility of using the Carver-Greenfield (C-G) municipal sludge drying process for municipal wastewater treatment facilities. The C-G process uses the principle of multi-effect evap- oration and can dry aqueous solutions or slurries with a wide range of solids contents (4 to 45 percent). The City of Los Angeles Hyperion Energy Recovery System (HERS) project will be the first full-scale municipal wastewater solids facility in the United States using the C-G process when it is placed into operation in 1985. A Trenton, New Jersey, plant is currently under design, and Chicago, Illinois, is seriously considering the process. Full-scale facilities using the C-G process for municipal sludge drying are operating in Japan. The C-G process is patented by De- hydrotech Corporation (formerly Carver- Greenfield Corporation) and is marketed under exclusive license arrangements by the Foster Wheeler Energy Corporation. Use of patented process equipment and appurtenant hardware can be negotiated directly with Dehydrotech. These as- sociated patent issues can increase costs and may create complications with federal funding that can cause delay in project implementation. For the HERS project, however, where the process is being installed, the license fee was approximately $1.4 million or only about 8 percent of the equipment capital cost. Currently, no comparable sludge- drying processes are available. Thermal sludge drying or conditioning processes (e.g., flash drying, wet-oxidation) are ------- based on different thermodynamic prin- ciples and are not analogous to the multi- effect evaporation system. Indirect contact steam dryers are the closest conventional technology to the C-G process. The Carver-Greenfield Process A flow diagram describing how the process fits into a total sludge manage- ment system is shown in Figure 1; the C- G flow diagram is shown in Figure 2. Sludge to be processed is first thickened or dewatered to reduce the amount of water to be evaporated. Thickened sludge is then mixed with an oil (carrying medium) such as No. 2 fuel oil or Isopar L (an Exxon product) at a suggested ratio of 1 part dry solids to 5to 10 parts oil. By use of an oil, fluidity is maintained in all effects of the evaporation cycle: it permits continuous pumping; facilitates heat transfer in the later-stage evaporators where the solids contents are higher as a result of water evaporation; and minimizes formation of scale or corrosion of the heat exchangers. The sludge-oil slurry is then pumped to the multi-effect evaporator where water is vaporized. The remaining solids-oil mixture is subsequently centri- f uged to separate the oil and solids. The oil is recycled and reused and the dry solids (90 percent or greater) are discharged for further processing or disposal Multi-effect Evaporation Multi-effect evaporation affords an economy of scale over single-effect operations through the reuse of heat. The C-G process employs reverse flow, multi- effect evaporation with steam being added to the first effect. In a three-effect system, vapor from the first effect is used to heat the solution in the second effect, and the vapor from the second furnishes heat to the third. Vapor from the last effect is removed, condensed, and discharged. The oil-sludge mixture flows in the opposite direction from effect to effect, counter to the vapor flow between effects. Through the reuse of heat in the multi-effect process, the amount of water removed per pound of steam supplied increases with increasing number of effects. In its simplest theoretical form, a single-effect evaporator can evaporate a maximum of 1 kilogram of water per kilogram of steam supplied, and a double- effect evaporator will evaporate 2 kilo- grams of water per kilogram of steam supplied, etc., because of the reuse of heat. The amount of kilojoules (Btu's) required per kilogram (pound) of water removed will depend on the number of effects used. For a single-effect unit, about 2300 kilojoules per kilogram (1000 Btu's per pound) of water removed is required for a double-effect unit, 1150 kilojoules per kilogram (500 Btu's per pound) of water removed, etc. A vacuum Dewatering Partial Water Removal Evaporation of Water Sludge Drying Combustion Energy Recovery End Products for Reuse or Sale Sludge (Thickened/Unthickened) Dewatering Basic Carver-Greenfield Multi-Effect Evaporator with Hydroextractor (Optimum Oil Recovery, Use of Light Weight Oil) (See Figure 2) Pyrolyzer Boiler and/or Gas Turbine "Use of heavier weight oil only; non-hydroextraction recovery system. figure 1. Sludge management system utilizing the C-G process. Pelleted Dry Fuel Fuel Oil lor Sale Oil for * Reuse Fertilizer Steam for Evaporation Steam for Electricity Steam for Sale Electricity for Sale Ash ------- Steam Feed (Water/ Solid) Oil Oil Mixing Multiple-Effect Evaporation J Oil/Solid Separation Condensate/Oil Separation Condensate Solid* Product Recycle Oil •igure 2. Carver-Greenfield block flow diagram. s applied to the various effects to reduce he liquid vaporization temperature and o maintain a positive temperature difference within each effect so that heat :an be transferred. Conventional heat Irving processes normally require 3450 o 4600 kilojoules per kilogram (1500 to 2000 Btu's per pound) of water removed. 'herefore, in comparison, the C-G jrocess is an energy efficient sludge frying process. It would appear that an infinite economy )f scale would result from the use of an nfinite number of effects. Several actors, however, limit the number of iffects in a system. Each affect operates >nly on a fraction of the total temperature Jrop across the system. The total drop is leldom larger than that employed in iingle-effect evaporation, and the capacity ier unit area of heating surface is •educed proportionately. Thus, a savings n fuel requirements may be realized hrough multiple-effect operation, but iquipment costs will be greater. Cur- rently, the system being constructed by he City of Los Angeles will use four sffects. In most cases no more than three •31 four effects are economical, but the ictual number is largely influenced by sre vail ing fuel costs. Most proposals for treating municipal Judge with the C-G process include a ;ombustion reactor to recover the heat i/alue of the dried product. Theoretically, his is an attractive combination of processes since water can be evaporated with multi-effect efficiency before com- bustion or gasification. Fuel gases produced during pyrolysis or waste heat from an incincerator can then be used to supply the energy requirements of the C- G process. The dried product may also be marketed as a soil conditioner. Technology Assessment Procedure There are over 70 operating C-G installations throughout the world. For the most part they are used in industry for drying various industrial waste streams. Two plants, the Fukuchiyama City and Hiroshima plants in Japan, process municipal sludge from conventional activated sludge treatment plants. Several full-scale systems have been in continuous operation in other industries (e.g., Adolf Coors Company, Golden, Colorado). This technology assessment was based on an independent review of several operating pilot-scale and full-scale facilities. Much of the design and cost information was derived from the City of Los Angeles and the Los Angeles-Orange County Metropolitan Area (LA/OMA) regional sludge study. Process Capabilities and Limitations The C-G process has several capabilities and limitations based upon a review of pilot-scale and full-scale facilities. Important capabilities include: • The C-G process can dry aqueous solutions or slurries with a wide range of solids contents (4 to 45 percent). The process can handle any type of municipal sewage sludge, can be designed to handle any feed concentration, and can evaporate water to any degree of dryness. • Multi-effect evaporation consumes only a fraction of the energy required by other heat drying processes. • If the dried sludge is used as a fuel, the process may be self-sufficient in energy and in some cases provide excess energy for export such as with the City of Los Angeles HERS project. • Polychlorinated biphenyls (PCB's) and other organic contaminants are destroyed when sewage oil is burned as a fuel in a boiler. • The process produces a dry, easy-to- handle product that is sterilized during evaporation. The reduced volume of fully dried sterile product may be safely disposed of or may be used as a fertilizer and soil condi- tioner. • Since it operates in a completely closed system, odors are contained within the system. The odoriferous and other noncondensable gases contained in the sludge feed, which evolve during evaporation, can be added to the air intake of the boiler for combustion. • The dried solid product can be stored for an indefinite period. Two significant limitations of multi- effect evaporation are increasing viscosity and resistance of the liquid to heat ex- change as it is concentrated. If the in- crease in viscosity is sufficient, the mate- rial can clog or scale the evaporator tubes of the heat exchanger and prevent evaporation. To eliminate this problem, using a fluidizing medium will keep the material in a fluid state in each effect. In- corporating a fluidizing oil with the multi- effect evaporators is the basic principle of the C-G process. Design Considerations General design criteria are listed in Table 1. The minimum number of effects and the required evaporation efficiency depend on site-specific conditions. A two-effect system may be most econom- ical in some cases. Redundancy or reliability requirements also help deter- mine the number of effects required. The ------- Los Angeles design incorporates three trains of four effects each, with each train capable of handling 50 percent of the average design load. This level of redundancy is dictated by the large quantity of sludge being processed, the lack of alternative disposal options in emergency situations, the need to handle peak sludge production rates, and esti- mated downtime for routine main- tenance. The City of Trenton, however, will use a single process train, sized for above-average production rates and designed to operate 5 days a week. Isopar will probably only be used as fluidizing oil where a very high grade product is to be produced, e.g., in food or pharmaceutical applications. Other petroleum based oils are more readily available and less expensive for sludge processing. Operational Considerations The C-G process is quite flexible in terms of variations during operation. The heart of the process is the multi-effect evaporator train, which consists of feed and circulation pumps, heat exchanger, vapor chamber, and connection piping. As such, the system is mostly composed of nonproprietary equipment that is available from more than one manu- facturer. These equipment sections (e.g., an evaporative effect unit) are amenable to duplication or bypass arrangement to ensure 100 percent reliability. Thus, an extra evaporative effect (pumps, heat exchanger, vapor chamber) may be added in case one of the effects is shut down temporarily for any reason. Reliability without extra equipment can be ensured by bypass arrangements: a normal four- effect system can be operated as a three- effect system using slightly more process steam and higher temperature drop across the system with attendant decrease in efficiency. With these and certain other essential spare equipment arrangements, the C-G system can cope with upset conditions without having 100 percent redundancy. The C-G process poses no special maintenance problems. The maintenance effort required in the dry materials phase and distallate condensing operations will be greater, however, than in other process segments. All required main- tenance procedures should be within the capabilities of well-trained municipal personnel. Equipment durability and reliability are quite good. The employment of proper preventive maintenance pro- cedures for the C-G process can be expected to result in smooth running operation with long life. Table 1. Carver-Greenfield Dehydration Design Criteria Item Criteria Number of effects Evaporation rate Steam characteristics Boiler efficiency Fuel value of extracted heavy oil Fluidizing oil Fluidizing oil make-up Weight of Isopar-L Outfeed 2, 3, or 4 2.3 kg water/kg steam 448.200 Pa (65 psia) saturated 75% 41.850 kj/kg (18.000 Btu/lb) Isopar-L 1% by weight of dry solids fed (assumes hydroextraction is employed for oil recovery) 766 kg/cu m (6.388 Ib/gal) 95% solids Table 2 lists the labor, power, and chemical requirements for the C-G process based on the City of Los Angeles full-scale system. Energy Considerations The overall water evaporation energy requirement of the C-G process is less than, hence more energy efficient than, that of comparable sludge drying processes (Table 3). Cost Comparison The full technology assessment report includes preliminary design criteria and estimated costs for the HERS System at Los Angeles. The estimated total (capital and operating) cost for the C-G system is $39/dry ton, which includes allowance for a license fee. This compares very favorably with that for a rotary dryer, $100/dry ton. Conclusions and Recommendations The C-G dewatering/drying process. appears to be an energy-efficient, cost- effective method applicable to the wastewater industry. Research and development for applica- tion in the municipal wastewater industry has reached the point for full-scale implementation. Progress at Los Angeles, Trenton, and Chicago should be carefully followed. Based on this assessment, the following recommendations are made regarding identified needs to fully develop this technology for the municipal wastewater industry: • Municipal wastewater agencies should consider the C-G process on a site-specific basis because of the variable process configurations, energy and environmental consid- erations, and cost. • Pilot testing of the C-G process is necessary to develop specific design criteria! to guide full-scale projects. • The construction cost and operating characteristics of the full-scale C-G facilities for the City of Los Angeles and City of Trenton should be tracked. Full-scale construction cost and operating information is an Table 2. Example Operation and Maintenance Requirements Design Labor Power used Chemical requirements (carrier oil} 265 dry tons/day @ 20% solids 10 personnel® 1500 hr/yr each 1900 kWh/day 1.200 kg/day or 766 kg/cu m (2.650 Ib/day or 415 gal/day @ 6.388 Ib/gal) Table 3. Comparative Energy Requirements Unit C-G (four-effect) Spray dryer Flash dryer Rotary dryer Indirect steam Other devices that use heat for drying and do not employ multiple- effect evaporation Kj Input/ Kg of Water Evaporated 810-1,050 4,650 minimum 5,210-6.280 5,580-6,510 1.9OO 2,330 (plus heat lost due to in- efficiencies of system) Btu Input/ Ib of Water Evaporated 350-450 2,OOO minimum 2.2OO-2.700 2,400-2.800 1.250 1,000 (plus heat lost due to in- efficiencies of system} ------- important need at this time to determine the widespread viability of the process. • There is a need to disseminate technical and cost information on specific C-G projects in the following areas of concern: — Municipal wastewater residual solids dewatering and drying performance. — Construction and operating cost. — Patent status of light oil tech- nology. The full report was submitted in jlf illment of Contract No. 68-03-3016 by /Wl Consulting Engineers under the lonsorship of the U.S. Environmental rotection Agency. Henry C. Hyde is currently with Henry Hyde & Associates, Sausalito, CA 94965. Robert P. G. Bowker was the EPA Project Officer (see below). The complete report, entitled "Technology Assessment of Carver-Greenfield Municipal Sludge Drying Process," (Order No. PB 85-138 634; Cost: $11.50, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 For further information, contact Harry £• Bostian at: Water Engineering Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 <, US OOVERNUENT PRINTING OFFICE 1966 . 559-111/10793 ------- United States Center for Environmental Research BULK RATE Environmental Protection Information POSTAGE & FEES F Agency Cincinnati OH 45268 EPA PERMIT No G-3 Official Business Penalty for Private Use $300 )„-;•" 4 1 M ~ ; ^:'-'^' ,Ti!4"Y i; C •? K 5 T JL ------- |