United States Environmental Protection Agency Industrial Environmental Research Laboratory Research Triangle Park NC 27711 Research and Development EPA-600/S9-84-012 June 1984 &EPA Project Summary EADS Liquid Effluents Data System 1982 Annual Report J. Patrick Reider This report is the first data summary of wastewater sampling and analysis results compiled in EPA's Liquid Efflu- ents Data System (LEDS). LEDS is a component of a group of related computerized data bases — the Envi- ronmental Assessment Data Systems (EADS) — that describe multimedia discharges from energy systems and industrial processes. EADS was designed to aid researchers in environmental assessment, source characterization, and control technology development. This report summarizes data compiled from the implementation of LEDS in 1980 through 1982. It lists the sources reported in LEDS, feed materials used, chemical analysis data on hazardous and priority pollutants, and the number of samples for each source. This Project Summary was developed by EPA's Industrial Environmental Research Laboratory. Research Triangle Park. NC. to announce key findings of the research project that is fully docu- mented in a separate report of the same title (see Project Report ordering information at back). Introduction The Liquid Effluents Data System (LEDS) is a computerized information system that contains results of sampling and analysis of wastewater discharges from energy systems and industrial processes. LEDS is one of four waste stream data bases that make up the Environmental Assessment Data Systems (EADS). LEDS became operational in June 1980. This annual report describes LEDS and its growth, contents, and future within EADS. EADS is a comprehensive system of computerized data bases that describe energy systems, industrial processes, control technologies, and process dis- charges. Moreover, EADS is a protocol for data analysis and evaluation that allows users to make consistent and meaningful interpretations of the data collected and reported. The EADS protocol may be applied to any type of sampling and analysis activity in which discrete samples are collected. EADS consists of four operational data bases for multimedia product, process, or waste streams sampled and analyzed, that are supported by a variety of reference data bases and data evaluation programs. The four sampling and analysis data bases now in operation are the Fine Particle Emissions Information System (FPEIS), the Gaseous Emissions Data System (GEDS), LEDS, and the Solid Discharge Data System (SDDS). Each data base contains extensive in- formation on the source of the discharges, on applied control technologies, on fuels or feedstocks, and on the composition of each discharge. EADS applies to most sources, including industrial processes, energy systems, and wastewater treat- ment plants. The structure of EADS and the types of data contained in it are discussed in the full report The vast and growing volume of samp- ling and analysis data produced by EPA, its contractors, and other agencies required a mechanism to consolidate such data. These organizations have produced and still are producing a broad range of data from a variety of industrial and energy sources, and sampling and analysis methods and protocols are constantly evolving. EADS was created to provide a comprehensive and diverse repository for multimedia environmental sampling and analysis data to consolidate the data in a central location where they can be readily available to the user ------- community. To meet this provision, EADS was designed to accommodate a variety of multimedia data from assorted sampling and analysis programs. One requirement of an environmental data base was that a consistent format be used to facilitate accurate, reliable data assessments. More specifically, it was essential that data be reported in similar units and be compiled with consistency in engineering conditions, technical bases, etc. To meet this need, EADS was developed to provide a standardized and uniform protocol for reporting sampling and analysis data. A critical need existed for current information and standardized data analysis procedures. Thus, EADS was created to supply current sampling and analysis data for evaluation and to provide standard methods for retrieving and analyzing the data. LEDS, for example, has been useful to EPA's Office of Research and Development in developing the Wastewater Treatability Manual. EADS is updated and expanded constantly, and a Program Library aids users in data evaluation through the utilization of standard reports and analysis software. Finally, and possibly most important, EADS was created to document the quality of the data reported. EPA is committed to producing environmental data of high quality and to providing a cost-effective way to document results of sampling and analysis programs so that data quality may be determined. EADS is an integral component of IERL—RTP's approved Quality Assurance (QA) Program Plan and contains QA parameters to help the user interpret the data. The broad applicability and comprehensiveness of EADS make it particularly suitable for a QA documentation role. Data from EADS have been used to model process engineering emissions, to design and evaluate control technology, and for many other applications. Because of the sensitive nature of some stationary source emissions data, EADS provides a special feature that protects cofidential or proprietary source data. With this feature, EPA does not know the identity of the source. This feature enables the EADS to obtain, store, and use multimedia emis- sions data that would otherwise be un- available. Confidentiality, already used extensively, has been a great aid in obtaining data which probably would not have been available otherwise. EADS is user-oriented. A LEDS User Guide documents instructions for data encoding and submittal, along with methods for data retrieval. LEDS data may be retrieved either by direct computer access to the data base and its user program or by written or verbal request to EADS technical support staff. Use of the LEDS data and analysis software is described in the LEDS User Guide. The documentation is revised easily, and supplements are issued as needed. A key component of the design effort for the EADS data bases isflexibility. User needs will change, and EADS can adaptto these changes to remain a useful infor- mation resource. EADS has undergone several improvements since it became operational in 1980, and will undergo additional changes as needed. EADS is still the only sampling, analysis, and engineering data system available that is completely integrated across media boundaries. Description of the LEDS Data Base The LEDS data base contains industrial or energy process source emissions test data and related source and control system design and operating data. It describes liquid effluents at the point where the liquid sample is collected from the discharge stream. This is accomplished through a flexible data base structure and in the definitions of the principal data types that are reported. Data types are defined as data elements, each describing a particular piece of information (e.g., a source characteristic, discharge stream characteristic, control device or treatment process, source operation, test informa- tion, analyses of the fuels a no; feedstocks, sampling activity information, chemical analyses, radionuclide analysis, or bio- assay result). The data elements collec- tively describe the entire source test activity. LEDS may contain more than 500 discrete data elements for each site test activity reported. The extent (or completeness) of the data contained in the data base depends on the objectives of the site test plan. Major categories of data at each level of the data base are given in Figure 1. The data are grouped into four general categories: general source description and related information; design conditions and parameters of the effluent stream and of the control device or treatment/stor- age/recovery process; test operating information, including analysis of any fuels and feedstock; and sampling activities information, including chemical, physical, radionuclide, and biological analysis results. Data Summary The LEDS data base is similar in size to GEDS in terms of numbers of samples (about 450), although LEDS contains twice the number of test series. The rate of growth of LEDS will increase signifi- cantly as emphasis at the Federal and state levels shifts from air pollution to toxic and hazardous waste problems. Toxic and hazardous waste sampling typically involves either liquid or solid media. Source categories in LEDS are summarized in Table 1. Test Series Level Stream Design Level Source Categorization Reference Information Stream Design Information Test Operating Level Sample Level _L Fuels/Feedstocks Characteristics Control System Design Information Source/Process Operating Information Control System Operating Parameters Sample Pun Information/Data Sample Component Results/Analysis Inorganic Analysis/ Non-Level I Organic Level I Organic Analysis Radionuclides Analysis Bioassay Results Figure 1. LEDS structure. ------- Table 1 . Summary of Source Categories in LEDS Print-00 1 Environmental Assessment Data Systems Source Category Summary Data Base: LEDS Where Clause Follows: WHC355LT 01/01/83 Source Category Chemical Manufac Chemical Manufac Chemical Manufac Chemical Manufac Chemical Manufac Chemical Manufac Coal Mining Coal Mining Combust-Energy Combust-Energy Combust-Energy Combust-Energy Combust-Energy Combust-Energy Combust-Energy Consumer Services Consumer Services Consumer Services Consumer Services Consumer Services Fabricated MTL Prod Leather Products Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metal Mining Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Metals Textiles & Products Textiles & Products Textiles & Products Source Type Gum & Wood Pharmaceuticals Surface Coating Surface Coating Surface Coating Synthetic Rubber Bituminous & Lignite Misc Coals Commercial-lnst Industrial Utility Utility Utility Utility Utility Laundries Laundries Laundries Laundries Laundries Metal Products Tanning /Finishing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Ore Mine & Dressing Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Ferrous Primary Nonferrous Primary Nonferrous Dyeing & Finishing Dyeing & Finishing Dyeing & Finishing Product or Devicle Oils Not Specified Paints Paints Paints Misc Products Bituminous Not Specified Incinerators Gasification Boiler Boiler Boiler Boiler Boiler Automobiles Automobiles Automobiles Other Other Appliances Cured Leather Gbods Bauxite Copper Ferroalloy Iron Iron Lead Lead /Zinc Silver Titanium Uranium Uranium Coke Iron Iron Steel Steel Steel Steel Steel Steel Steel Steel Steel Steel Steel Aluminum Copper Blended Fabric Polyester Fabric Wool Process Type Extraction/Fraction Not Specified Latex Paint MFG Latex/Oil Mix Paints Oil Paint MFG Polymerization Proc Phys-Mech Cleaning Mining Multiple Chamber Entrained Bed Cyclone Horiz Opposed Wall Single Wall Stoker Tangential Rollover Tunnel Wand Commercial Industrial Surface Coating Not Specified Mine Mine/Mill Mine/Mill Mine Mine/Mill Mine/Mill Mine/Mill Mine/Mill Mine/Mill Mill Mine Coke Oven Foundry /Casting Sintering Alkaline Cleaning Basic Oxygen Furnace Coating Cold Rolling Electric Arc Furnace Hot Coating Hot Forming Open Hearth Pipe & Tube Prod Scarfing Vacuum Degassing Foundry /Casting Foundry/Casting Finishing Finishing Finishing SIC 2861 2834 2816 2816 2816 2822 1211 1200 4953 4960 4911 4911 4911 4911 4911 7542 7542 7542 7210 7210 3449 3111 1051 1021 1061 1011 1011 1031 1031 1042 1099 1094 1094 3312 3320 3320 3312 3312 3312 3312 3312 3312 3312 3312 3312 3312 3312 3334 3331 2264 2262 2269 Page: 001 Date: 05/02/83 Number of Test Series 5 9 11 1 2 5 3 " 7 1 1 5 ; 5 2 6 2 1 2 6 8 7 7 1 2 3 1 1 1 3 1 1 1 2 1 6 3 3 6 4 3 4 3 2 3 1 3 2 3 1 12 2 1 Number of Samples 15 18 33 3 6 10 6 19 8 6 17 3 13 2 10 7 4 7 24 28 14 14 2 7 8 2 2 4 8 4 3 2 4 2 16 6 6 12 8 6 8 6 4 6 2 8 4 6 2 24 4 2 ------- LEDS data are characterized by variety in the source categories, in the control device/treatment systems, and in the compounds analyzed. The data base contains information on conventional wastewater pollutants and nonconven- tional inorganic and organic compounds. About half of the test series have been conducted on effluent streams from the metals source category, primarily in ore mining and dressing, and primary ferrous sources. The rest of the test series are in the chemical manufacturing, combustion, consumer products, and incineration source categories. The source categories, control systems, feed materials, and numbers of samples in LEDS are summa- rized in the full report. J. P. Reider is with Midwest Research Institute, Kansas City, MO 64110. Gary L. Johnson is the EPA Project Officer (see below). The complete report, entitled "EADS Liquid Effluents Data System 1982 Annual Report," (Order No. PB 84-194 091; Cost: $8.50. subject to changej will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Industrial Environmental Research Laboratory U.S. Environmental Protection Agency Research Triangle Park, NC 27711 •ft- US GOVERNMENT PRINTING OFFICE, 1984—759-015/7733 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Official Business Penalty for Private Use $300 ------- |