United States
                     Environmental Protection
                     Agency
Industrial Environmental
Research Laboratory
Research Triangle Park NC 27711
                     Research and Development
EPA-600/S9-84-012 June 1984
&EPA          Project  Summary
                    EADS  Liquid  Effluents  Data
                    System  1982  Annual  Report
                     J. Patrick Reider
                      This report is the first data summary
                     of wastewater sampling and analysis
                     results compiled in EPA's Liquid Efflu-
                     ents Data System (LEDS).  LEDS is a
                     component of a group of related
                     computerized data bases — the Envi-
                     ronmental Assessment Data Systems
                     (EADS) — that describe multimedia
                     discharges from  energy systems and
                     industrial processes. EADS was designed
                     to aid researchers in environmental
                     assessment, source characterization,
                     and  control technology  development.
                     This report summarizes data compiled
                     from the implementation of LEDS in
                     1980 through 1982. It lists the sources
                     reported in LEDS, feed materials used,
                     chemical analysis data on  hazardous
                     and priority pollutants, and the number
                     of samples for each source.
                      This Project Summary was developed
                     by  EPA's Industrial Environmental
                     Research Laboratory. Research Triangle
                     Park. NC. to announce key  findings of
                     the research project that is  fully docu-
                     mented in a separate report of the same
                     title  (see  Project Report ordering
                     information at back).

                     Introduction
                      The Liquid  Effluents  Data System
                     (LEDS) is  a computerized information
                     system that contains results of sampling
                     and  analysis of wastewater  discharges
                     from energy  systems and  industrial
                     processes. LEDS  is one of four waste
                     stream  data bases that  make up the
                     Environmental  Assessment Data Systems
                     (EADS). LEDS became operational in
                     June 1980. This annual report describes
                     LEDS and  its growth, contents,  and
                     future within EADS.
                      EADS is a comprehensive system of
                     computerized  data bases that describe
                     energy systems,  industrial  processes,
control technologies,  and  process dis-
charges. Moreover, EADS is a protocol for
data analysis and evaluation that allows
users to make consistent and meaningful
interpretations of the data collected and
reported. The EADS  protocol  may be
applied to any type  of sampling and
analysis activity in which discrete samples
are collected.
  EADS consists of four operational data
bases for multimedia product, process, or
waste streams sampled and analyzed,
that are supported  by  a variety of
reference data bases and data evaluation
programs. The four sampling and analysis
data bases now in operation are the Fine
Particle Emissions  Information System
(FPEIS), the Gaseous Emissions Data
System (GEDS), LEDS, and the Solid
Discharge Data System (SDDS).
  Each data base contains extensive in-
formation on the source of the discharges,
on applied control technologies, on fuels
or feedstocks, and on the composition of
each discharge. EADS applies  to most
sources, including industrial processes,
energy systems,  and wastewater treat-
ment plants. The structure of EADS and
the types of data  contained  in it are
discussed in the full report
  The vast and growing volume of samp-
ling and analysis data produced by EPA,
its  contractors, and other agencies
required a mechanism to consolidate
such data. These  organizations have
produced and still are producing a broad
range of data from a variety of industrial
and energy sources, and  sampling and
analysis methods  and protocols are
constantly evolving. EADS was created to
provide a comprehensive  and diverse
repository for multimedia environmental
sampling and analysis data to consolidate
the data in a central location where they
can be readily available  to the user

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community. To meet this provision, EADS
was designed to accommodate a variety
of multimedia data from assorted sampling
and analysis programs.
  One requirement of an environmental
data base was that a consistent format be
used to facilitate accurate, reliable data
assessments.  More specifically,  it was
essential that data be reported in similar
units and be compiled with consistency in
engineering conditions, technical bases,
etc. To  meet  this need,  EADS  was
developed to provide a standardized and
uniform protocol for reporting sampling
and analysis data.
  A  critical need  existed  for  current
information and standardized data analysis
procedures. Thus, EADS was created to
supply current sampling and analysis
data  for  evaluation and to provide
standard  methods  for retrieving and
analyzing the  data.  LEDS, for example,
has been useful  to  EPA's Office  of
Research and Development in developing
the Wastewater Treatability Manual.
EADS is updated and expanded constantly,
and a Program Library aids users in data
evaluation through  the utilization  of
standard reports and analysis software.
  Finally,  and possibly most important,
EADS was created  to document the
quality of the data reported. EPA is
committed to  producing  environmental
data of high quality and to  providing a
cost-effective way to document results of
sampling and analysis programs so that
data quality may be determined. EADS is
an  integral  component of  IERL—RTP's
approved Quality Assurance (QA) Program
Plan and contains QA parameters to help
the user  interpret the data.  The broad
applicability and comprehensiveness of
EADS make it particularly suitable for a
QA documentation role.
  Data from EADS have been used to
model process engineering emissions, to
design and evaluate control  technology,
and for many other applications. Because
of the sensitive nature of some stationary
source emissions data, EADS provides a
special feature that protects cofidential or
proprietary source data. With this feature,
EPA does not know the identity of the
source. This feature enables the EADS to
obtain, store, and use multimedia emis-
sions data that would otherwise be un-
available. Confidentiality, already  used
extensively,  has been a great aid in
obtaining data which probably would not
have been available otherwise.
  EADS is user-oriented. A LEDS User
Guide documents  instructions  for data
encoding  and  submittal, along  with
methods  for data  retrieval. LEDS data
may be retrieved either by direct computer
access to the data base  and its  user
program or by written or verbal request to
EADS technical support staff. Use of the
LEDS data  and  analysis software is
described in the LEDS User Guide. The
documentation is revised easily, and
supplements are issued as needed.
  A key component of the design effort
for the EADS data bases isflexibility. User
needs will change, and EADS can adaptto
these changes to remain a useful infor-
mation resource.  EADS has undergone
several  improvements since it became
operational in 1980,  and  will undergo
additional changes as needed. EADS is
still  the  only sampling, analysis, and
engineering data system available that is
completely  integrated across  media
boundaries.


Description of the LEDS Data
Base
  The LEDS data base contains industrial
or energy process source emissions test
data and related source and  control
system  design and operating data. It
describes liquid effluents at  the point
where the liquid sample is collected from
the discharge stream. This is accomplished
through a flexible data  base structure and
in the definitions of the principal data
types that are reported. Data types are
defined as data elements, each describing
a particular piece of information  (e.g., a
source characteristic,  discharge  stream
characteristic, control device or treatment
process,  source operation, test informa-
                            tion, analyses of the fuels a no; feedstocks,
                            sampling activity  information, chemical
                            analyses, radionuclide  analysis, or bio-
                            assay result). The data elements collec-
                            tively describe the entire source test
                            activity. LEDS may contain more  than
                            500 discrete data  elements for each site
                            test activity  reported. The extent (or
                            completeness) of  the data  contained in
                            the data base depends on the objectives
                            of the site test plan.
                              Major categories of data at each level of
                            the data base are given in Figure 1. The
                            data  are  grouped into  four general
                            categories: general source description
                            and related information; design conditions
                            and parameters of the effluent stream and
                            of  the control device or treatment/stor-
                            age/recovery process; test  operating
                            information, including  analysis of any
                            fuels and  feedstock; and sampling
                            activities information, including chemical,
                            physical, radionuclide, and  biological
                            analysis results.

                            Data Summary
                              The LEDS data base is similar in size to
                            GEDS in terms of numbers of samples
                            (about 450), although LEDS contains
                            twice the number of test series. The rate
                            of  growth of LEDS will increase signifi-
                            cantly as emphasis at the Federal and
                            state  levels shifts from air pollution to
                            toxic  and hazardous  waste  problems.
                            Toxic and  hazardous  waste sampling
                            typically  involves either  liquid  or  solid
                            media. Source categories  in LEDS are
                            summarized in Table 1.
 Test Series
 Level


 Stream Design
 Level
               Source Categorization
               Reference Information
       Stream Design
       Information
Test Operating
Level

Sample
Level
                   _L
Fuels/Feedstocks
Characteristics
           Control System
           Design Information
Source/Process
Operating Information
Control System
Operating Parameters
                 Sample Pun
                 Information/Data
                             Sample Component
                             Results/Analysis
                  Inorganic
                  Analysis/
                  Non-Level I
                  Organic
                    Level I
                    Organic Analysis
                    Radionuclides
                    Analysis
                  Bioassay
                  Results
Figure  1.    LEDS structure.

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Table 1 . Summary of Source Categories in LEDS
Print-00 1 Environmental Assessment Data Systems
Source Category Summary
Data Base: LEDS
Where Clause Follows:
WHC355LT 01/01/83

Source Category
Chemical Manufac
Chemical Manufac
Chemical Manufac
Chemical Manufac
Chemical Manufac
Chemical Manufac
Coal Mining
Coal Mining
Combust-Energy
Combust-Energy
Combust-Energy
Combust-Energy
Combust-Energy
Combust-Energy
Combust-Energy
Consumer Services
Consumer Services
Consumer Services
Consumer Services
Consumer Services
Fabricated MTL Prod
Leather Products
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metal Mining
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Metals
Textiles & Products
Textiles & Products
Textiles & Products

Source Type
Gum & Wood
Pharmaceuticals
Surface Coating
Surface Coating
Surface Coating
Synthetic Rubber
Bituminous & Lignite
Misc Coals
Commercial-lnst
Industrial
Utility
Utility
Utility
Utility
Utility
Laundries
Laundries
Laundries
Laundries
Laundries
Metal Products
Tanning /Finishing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Ore Mine & Dressing
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Ferrous
Primary Nonferrous
Primary Nonferrous
Dyeing & Finishing
Dyeing & Finishing
Dyeing & Finishing

Product or Devicle
Oils
Not Specified
Paints
Paints
Paints
Misc Products
Bituminous
Not Specified
Incinerators
Gasification
Boiler
Boiler
Boiler
Boiler
Boiler
Automobiles
Automobiles
Automobiles
Other
Other
Appliances
Cured Leather Gbods
Bauxite
Copper
Ferroalloy
Iron
Iron
Lead
Lead /Zinc
Silver
Titanium
Uranium
Uranium
Coke
Iron
Iron
Steel
Steel
Steel
Steel
Steel
Steel
Steel
Steel
Steel
Steel
Steel
Aluminum
Copper
Blended Fabric
Polyester Fabric
Wool

Process Type
Extraction/Fraction
Not Specified
Latex Paint MFG
Latex/Oil Mix Paints
Oil Paint MFG
Polymerization Proc
Phys-Mech Cleaning
Mining
Multiple Chamber
Entrained Bed
Cyclone
Horiz Opposed Wall
Single Wall
Stoker
Tangential
Rollover
Tunnel
Wand
Commercial
Industrial
Surface Coating
Not Specified
Mine
Mine/Mill
Mine/Mill
Mine
Mine/Mill
Mine/Mill
Mine/Mill
Mine/Mill
Mine/Mill
Mill
Mine
Coke Oven
Foundry /Casting
Sintering
Alkaline Cleaning
Basic Oxygen Furnace
Coating
Cold Rolling
Electric Arc Furnace
Hot Coating
Hot Forming
Open Hearth
Pipe & Tube Prod
Scarfing
Vacuum Degassing
Foundry /Casting
Foundry/Casting
Finishing
Finishing
Finishing

SIC
2861
2834
2816
2816
2816
2822
1211
1200
4953
4960
4911
4911
4911
4911
4911
7542
7542
7542
7210
7210
3449
3111
1051
1021
1061
1011
1011
1031
1031
1042
1099
1094
1094
3312
3320
3320
3312
3312
3312
3312
3312
3312
3312
3312
3312
3312
3312
3334
3331
2264
2262
2269
Page: 001
Date: 05/02/83
Number of
Test Series
5
9
11
1
2
5
3
" 7
1
1
5
;
5
2
6
2
1
2
6
8
7
7
1
2
3
1
1
1
3
1
1
1
2
1
6
3
3
6
4
3
4
3
2
3
1
3
2
3
1
12
2
1
Number of
Samples
15
18
33
3
6
10
6
19
8
6
17
3
13
2
10
7
4
7
24
28
14
14
2
7
8
2
2
4
8
4
3
2
4
2
16
6
6
12
8
6
8
6
4
6
2
8
4
6
2
24
4
2

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    LEDS data are characterized by variety
  in the  source categories, in the control
  device/treatment  systems, and  in  the
  compounds analyzed. The data base
  contains information on  conventional
  wastewater pollutants and nonconven-
  tional inorganic and organic compounds.
  About  half  of the test series have been
  conducted on effluent streams from the
  metals source category, primarily in ore
  mining and dressing, and primary ferrous
  sources. The rest of the test series are in
  the chemical manufacturing, combustion,
  consumer  products,  and  incineration
  source categories. The source categories,
  control systems, feed materials,  and
  numbers of samples in LEDS are summa-
  rized in the full  report.
         J. P. Reider is with Midwest Research Institute, Kansas City, MO 64110.
         Gary L. Johnson is the EPA Project Officer (see below).
         The complete report, entitled "EADS Liquid Effluents Data System 1982 Annual
           Report," (Order No.  PB 84-194 091; Cost: $8.50. subject to changej will be
           available only from:
                 National Technical Information Service
                 5285 Port Royal Road
                 Springfield, VA 22161
                 Telephone: 703-487-4650
         The EPA Project Officer can be contacted at:
                 Industrial Environmental Research Laboratory
                 U.S. Environmental Protection Agency
                 Research Triangle Park, NC 27711
                                                                              •ft- US GOVERNMENT PRINTING OFFICE, 1984—759-015/7733
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use $300


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