United States Environmental Protection Agency Industrial Environmental Researc Laboratory Cincinnati OH 45268 Research and Development EPA-600/S2-81-009 Feb. 1981 Project Summary Assessment of Organic Emissions in the Flexible Packaging Industry Inks, coatings, and adhesives used in the manufacturing of flexible pack- aging materials must be dried before the product can be stored or used fur- ther. This step is accomplished in the drying portion of the process machine, where heated air is blown over the web of material as it passes through the machine. It is the discharge of solvents removed by the heated air during the drying process that gives rise to emis- sions of volatile organic compounds (VOC). The purpose of this project was to study emissions of volatile organic com- pounds by the flexible packaging indus- try and to determine the effectiveness and cost of available means for control- ling these emissions. The Flexible Pack- aging Association (FPA) cooperated in the program by conducting a survey to provide current data about the flexible packaging industry, particularly with regard to the solvents used and experi- ence with control systems A questionnaire was designed to pro- vide data on solvent use and emissions from the flexible packaging industry. Of the 1,136 questionnaires mailed out, 13.6% resulted in responses that have been incorporated into this analysis. This survey covers responses from 154 flexible packaging plants, containing 799 prime machines. This Project Summary was devel- oped by EPA's industrial Environ- mental Research Laboratory, Cincin- nati, OH, to announce key findings of the research project that is fully docu- mented in a separate report of the same title (see Project Report order- ing information at back). Survey Results The largest annual solvent use reported in this survey was for a two-plant com- plex using almost 9 million Ib/yr; the smallest plant use was less than 1,000 Ib/yr. Eighty-one plants use less than 500,000 Ib of solvent per year. Although these 81 locations account for more than 50% of the total number of plants, they use less than 5% of the total solvents reported in the survey. Inks account for approximately 50% of the total solvents used by the respon- dents. More than 17% was used in coat- ings, a similar amount in adhesives, and about 14% was used in varnishes, clean- ers, and other uses combined. Table 1 gives a summary of some of the survey data. Itcanbeseenthatflexo- graphic presses are the most common type of machine, and also that these presses were smaller on the average. Gravure presses were the next most com- mon, and as they were generally consid- ably larger, these presses consumed the most solvent. A broad range of both water- soluble and insoluble solvents were used, a fact which can complicate efforts to reclaim solvents. ------- <«' Table 1 . Flexible Packaging Machine Data Machine Type Presses Priming Combination Flexo Gravure Laminators Coalers Stations Machines TOTAL No. Reporting 366 153 88 59 47 86 799 Percent 46 19 11 7 6 11 100% Solvent Usage"' (MM Gal/year) Alcohols 26.2 7.0 2.3 2.4 4.1 2.0 44.0 Ketones .3 5.3 5.3 2.6 0.8 1.3 15.6 Esters 8.2 21.6 3.8 3.0 0.6 0.8 38.0 Hydrocarbons 2.2 14.9 6.8 11.3 0.5 0.6 36.3 Other 2.2 0.6 0.6 0.3 0.1 0.7 4.5 TOTAL 39.1 49.4 18.7 19.6 6.1 5.4 138.4 Median Stack Volume, 5,000 16,000 8,000 11,000 10.000 8,000 SCFM™ Exhaust VOC Martian nnm131 ^fl 1 4O ?4<3 4OO 1 fifi Median 1,000's nnnnrlv/ \iaar fil~l 1 77 5O 1 f!1 K7 (1) 146 plants reporting usable data out of 154 responding (2) 498 machines reporting usable data out of 799 responding (3) 71 1 machines reporting usable data out of 799 responding 2. Average costs per pound of solvent Cost Estimates vapor removed ranged upward from less To obtain an estimate of the cost of than $0.10/lb VOC. The distribution of controlling VOC, the costs of incinerators these costs (in percent) for various con- is almost always economical. The 70% heat recovery level considered here was found to be economical in most cases in spite of the higher capital costs. Units with up to 90% heat recovery are avail- able at increased capital costs. 4. In general, the annual costs for such items as capital, maintenance, labor, fuel, and water increase almost in pro- portion to the amount of contaminated air sent through the control device (SCFM). As the amount of VOC in the incoming air increases, the cost of incin- eration decreases, since the heat-value of the VOC replaces part of the fuel re- quired to reach incineration temperature; the cost of activated carbon adsorption increases, since regeneration is more fre- quent and there may be cost of conden- sate disposal if the solvent is water solu- ble. This study indicates that when condensate disposal is required, the break-even point is in the range of 500 to 700 ppm VOC; below this point, acti- vated carbon usually is less expensive; and above, incineration with heat recov- ery will be less costly, with, of course, some overlap. When the solvents are not water soluble and condensate dispo- sal is thus not required, this break-even range increases to 900 to 1,000 ppm. and activated carbon adsorption units were obtained from manufacturers and from the literature. There was consid- erable variation in the cost figures ob- tained, especially in the costs of inciner- ators, where the spread in values was approximately ±50%. Equations were developed to estimate capital and annual costs of equipment to control VOC emis- sions based on machine size and opera- tion. Cost figures based on annual cost and dollars/pounds of VOC removed were calculated for 342 machines that had responded to the survey with sufficient data. Costs were calculated for thermal incineration without heat recovery, ther- mal incineration with 70% heat recovery, activated carbon with steam regenera- tion, without credit for recovered solvent, and activated carbon, including a conden- sate disposal charge. From the cost data, the following conclusions can be drawn: 1. For 84% of the machines, activated carbon was the least expensive VOC con- trol method; incineration with 70% heat recovery was less costly on 15% of the machines, and incineration without heat recovery was least expensive on only 1 % of the machines. When a charge for condensate disposal was included, acti- vated carbon adsorption was still the least expensive option for 70% of the machines. trol technologies are shown in Table 2. 3. For activated carbon units, the costs associated with capital charges, main- tenance, and labor are the major part of the annual costs, ranging from 60% for some of the larger, more heavily used machines, to over 90% for smaller units that are used only on a part-time basis. When condensate disposal is necessary, this cost can vary from less than 10% of the total annual cost to over 80% if this control technique were to be applied to a gas stream of high VOC content. For incinerators, except when the VOC content of the exhaust is high and for very small or rarely used units, fuel costs are the major portion of the annual ex- penses; and because of this, heat recovery Table 2. Cost Range ($/lb VOC) Under $0.50 $0.50-$1.00 $1.00-$3.00 Over $3.00 Carbon (D 31 22 29 18 Adsorption (2) 8 34 37 21 Least Expensive Incineration Technique No Heat Recovery 1 12 30 57 70% Heat Recovery 17 20 32 31 (2) 19 27 35 19 (1) Charge for disposal of steam regeneration condensate not included. (2) Includes charge for activated carbon steam regeneration condensate disposal. ------- WAPORA. Inc.. Chevy Chase. MD 20015 authored this Project Summary. Ronald J. Turner is the EPA Project Officer (see below). The complete report, entitled "Assessment of Organic Emissions in the Flexible Packaging Industry," (Order No. PB 81-135 378; Cost: $12.50; subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Industrial Environmental Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 > U.S. GOVERNMENT PRINTING OFFICE: 1W1 -757-064/0260 ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Postage and Fees Paid Environmental Protection Agency EPA 335 Official Business Penalty for Private Use $300 IERL0167053 US EPA REGION V LIBRARY 230 S DEARBORN ST CHICAGO IL 60604 ~l ------- |