United States Environmental Protection Agency Hazardous Waste Engineering Research Laboratory Cincinnati OH 45268 Research and Development EPA/600/S2-86/049 Aug. 1986 vxEPA Project Summary Reclamation of Alkaline Ash Piles Wladyslaw Wysocki and Ronald D. Hill As part of the U.S. Environmental Pro- tection Agency's (EPA) Scientific Activities Overseas program a contract was award- ed to Poltegor, the Central Research and Design Institute for Openpit Mining, Wro- claw, Poland in 1974, to study vegetation stabilization of ash piles resulting from the burning of lignite and bituminous coal. Two ash piles were selected for study, i.e., ash from a lignite power plant and a bitumi- nous plant. The first phases of the project included analyses of the ash, greenhouse studies of ash amendment and fertilizer treatments, field experiments evaluation of various treatment methods to improve the soil characteristics of the ash, and evalua- tion of various grasses, legumes, trees, and shrubs for planting on ash piles. These research results were published in an EPA publication in 1979, "Reclamation of Alka- line Ash Piles and Protection of Their En- vironment Against Dusting," EPA-600/ 7-79-128. Following these studies it was recommended that the project be contin- ued to obtain long-term data on the sur- vival and growth of the plants and to ob- tain information on the development of a food crop (barley) on ash piles where the ash had gone through a period of soil development. Major conclusions drawn from this study are: (1) The chemical and minera- logical composition and physics-chemical properties of ashes significantly affect classification of ashes regarding their soil formation ability; (2) The toxicity of the ashes to plants was caused by the high pH (9.0-12.8), salinity (up to 2%), boron (up to 50 ppm), sandy-clay composition, un- balanced chemical composition, and soil color (caused high temperatures); (3) The best yields of pioneer grasses and legumes were obtained from plots covered with 20 cm of soil; (4) Yields of grasses and leg- umes decreased 44-53% where fertiliza- tion of the plots stopped; (5) Yields of winter barley were dependent on the neu- tralization and fertilization treatment ap- plied prior to introducing pioneer plants. The best results were obtained after ap- plying fertile soil; and (6) Ash piles can be utilized for production of fodder and cereals after earlier neutralization and fer- tilization. The introduction of trees and shrubs does not appear to be practical because of the shallow layer of soil form- ed that limits deep root penetration. This Project Summary was developed by EPA's Hazardous Waste Engineering Research Laboratory, Cincinnati, OH, to announce key findings of the research pro- ject that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction The U.S. Environmental Protection Agency conducted a cooperative research project in Poland with Poltegor, the Cen- tral Research and Design Institute for Openpit Mining. This project dealt with developing methods to reclaim and vege- tate ash disposal ponds. Ashes produced from coal-fired power plants create major solid waste disposal problems in both the United States and Poland. The magnitude of this problem is illustrated in Table 1. As noted, both bituminous and lignite coals are burned in Polish power plants. In Poland ashes are classified by the type of combusted coal and the chemical compo- sition of the ash. For example, ash from lignite can be divided into three classes ac- cording to its chemical composition: (1) sulphate-calcium from the Konin lignite region; (2) silicate-aluminum from the Miocene deposit of Turoszaw; (3) calcium- ------- aluminum from the Miocene deposits of Belchatow. From the reclamation standpoint, the method of ash disposal is important. When the ash is disposed by hydraulic transpor- tation, the disposal area is characterized by having a dike of mineral soil, and level top. Considerable fractionation taking place during settling results in a stratified structure within the ash bed. There is also considerable cementation. When the dry ash is pneumatically disposed, belt trans- ported, or hauled by trucks, the disposal area has a level surface and heterogeneous chemical and grain size composition. Hydraulic transport is more favorable from the reclamation viewpoint since con- siderable amounts of toxic boron and chlorides are leached from the ash and the pH is lower (8-9 as compared to 12-12.8, for dry deposition) as a result of the salts being leached. The chemical and physical properties of typical Polish ashes can be seen in Table 2. The small grain size of the ashes makes them very susceptible to wind and water erosion. In addition, they have unfavorable soil/gas properties, low water holding ca- pacity, and poor nutrients sorptive proper- ties. Silica is the main component of ashes, however, considerable amounts of alumi- num oxide (ashes from Turoszaw), calcium (ashes from Konin), and iron (bituminous ashes) are found. Fresh ashes are highly alkaline with a pH up to 12.8. Upon aging, salts are leached from the ash and the pH decreases. Except for potassium and bo- ron the nutrient content is low. Toxic levels of boron and sulphur, as well as magnes- ium and iron, are sometimes found. Bitu- minous ashes may contain relatively high concentrations of P2O5, but under highly alkaline conditions, it is not available to plants. Chloride concentration up to 2 per- Table 1. Ash Production (million metric tons and cubic meters) 1977 mil tons mil cubic meters mil tons 1990 mil cubic meters estimated data Poland Bituminous Lignite Total 17.5 12 29.5 30 24 54 30 35 65 50 70 120 USA Total 67.8 296 125 537 Table 2. Properties of Power Plant Ashes Ashes from Ashes from /ignite Parameters Grain-size composition (percent) fraction more than 1 mm fraction /ess than 1 mm 1.0 - 0. 1 mm 0. 1 - 0.02 mm less than 0.02 mm pH in KC Salinity (mg NaCI in 1 dm3) Assimilable components (mg/100 g) PyOc K2O Mg CaC03 (percent) Microelements (ppm) B Cu Mr, Mo Zn bituminous coal 2 37 37 26 8.4 - 12.8 0.8-5.1 94 19 13 2.25 48 20 0 0.6 32 Turow power plant 0 8 76 16 8.2 2.1 6.2 30 27 0.25 7.75 12.3 8 2.0 13 Konin power plants 2 36 36 28 8.2 - 12.81 more than 9 0.7 55 more than 60 32 20-35 0.0 8 0.2 0.5 cent by weight has been found in some ashes. This level of chloride inhibits plant germination and growth. As noted, both the physical and chemi- cal properties of ash make it a difficult material to reclaim by revegetation. Research Objectives The objective of this investigation was to solve the following problems: (1) con- trol of air and water erosion from ash disposal areas, (2) vegetation of ash dis- posal areas with grass and legumes; (3) reclamation of ash disposal areas for forest production; and (4) reclamation of ash disposal areas for agricultural cultivation. Research Plan Two ash disposal sites were selected for study. The first area was located at the Halemba power plant which is fired with bituminous coal mined underground from the Upper Silesia Coal Region. The second area was located at the Konin power plant which is fired with lignite coal mined by surface extraction methods from the Konin Basin. Both power plants hydraulically trans- ported their slag and fly ash to earth diked basins (4.6 m high). The earth dikes at Hal- emba were raised to a second level with ash. Pot Experiments In order to select the treatments to be applied to the ash in field tests, a series of greenhouse pot experiments was con- ducted. Twenty-seven different treatments were evaluated utilizing White Mustard (Synapis alba) as the test plant. Each treat- ment was replicated four times. The re- sults of pot studies are shown in Tables 3 and 4. The different treatments were compared on the basis of dry mass of plant material produced (average of four re- plications) with the control pot (fertile soil + fertilizer) being rated as 100. Details of these studies are available in reference 1. Results of the pot experiments indicated that methods to improve alkaline soil con- ditions such as addition of sulphuric acid, flowers of sulfur, and gypsum were suc- cessful to a limited degree. It was also evi- dent that the Konin ash was a more dif- ficult material on which to establish vegetation than was the Halemba ash. Field Experiments - Grasses and Legumes Based upon the results of the pot ex- periments, a field study was designed. Nine different ash treatments designed to change the soil properties, plus a control ------- Table 3. Results of Pot Experiments with Halemba Ash Treatment Rating 1. control 1 - fertile soil + NPK 2. ash + NPK + m + 1 cm layer of silt 3. ash + NPK + low moor peat 31.4 g/pot 4. ash + NPK + m - at 80% max. water capacity 5. ash + NPK + m + low moor peat 31.4 g/pot 6. ash + NPK + m - strongly pressed 7. ash + NPK + m + light soil 125% of volume) 8. ash + NPK + m + high moor peat 31.4 g/pot 9. ash + NPK + m + green manure from legumes 80. 5 g/pot 10. ash + NPK + m + high moor peat 31.4 g/pot 1 1. ash + NPK + m + green manure from cereals 80.5 g/pot 12. ash + 2 (NPKMg) 13. ash + NPKMg 14. ash + 2 (NPK Mg) + high moor peat 31.4 g/pot + sulphur 10 g/pot 15. ash + NPK + m 16. ash + NPK + m + sulphuric acid 125 ml/pot 17. ash + NPK + m + gypsum 31.4 g/pot 18. ash + NPK + m + high moor peat 31.4 g/pot + sulphur 10 g/pot 19. ash + NPK + m + low moor peat 3 1.4 g/pot + sulphur 10 g/pot 20. ash + 2 (NPKMg) + 2 m + low moor peat 31.4 g/pot 21. ash + low moor peat 31.4 g/pot 22. ash + NPK + m + green manure from cereals 322 g/pot 23. ash + 25% of barren river sand 24. ash + high moor peat 31.4 g/pot 25. ash + NPK + m + green manure from legumes 322 g/pot 26. control III = pure ash 2 7. control II = washed barren river-sand Note: m - microelements. NPK - Nitrogen, Potash and Potassium fertilizer. 100.0 89.3 88.3 85.6 81.9 81.4 80.8 79.7 78.5 78.5 75.4 74.2 72.6 71.8 70.1 68.6 66.9 54.2 47.7 42.3 38.4 34.1 33.3 32.8 13.6 12.4 7.3 Table 4. Results of Pot Experiment with Konin Ash Treatment 1. control I - fertile soil + NPK & Mg 2. ash + NPK + m + low moor peat 31.4 g/pot 3. ash + NPK + m 4. ash + NPK + m + high moor peat 31.4 g/pot 5. ash + NPK + m + 1 cm layer of silt 6. control III = pure ash 7. ash + NPK Mg 8. ash + NPK + m + light soil - 25% capacity 9. ash + NPK + m + high moor peat 31.4 g/pot 10. ash + NPK + m + green manure from cereals 31.4 g/pot 11. ash + NPK + m + low moor peat 31.4 g/pot 12. ash + NPK + m + sulphuric acid 1 n 125 ml/pot 13. ash + 25% of barren river sand 14. ash + low moor peat 31.4 g/pot 15. ash + high moor peat 31.4 g/pot 16. ash + NPK + m + green manure from legumes 80.5 g/pot 17. ash + NPK + m + gypsum 31.4 g/pot 18. ash + NPK + m + strongly pressed 19. ash + NPK + m - at 80% max. water capacity 2O. control II = washed barren river sand 21. ash + 2 (NPK Mg) + 2m + low moor peat 31.4 g/pot 22. ash + NPK + m + low moor peat 31.4 g/pot + sulphur 10 g/pot 23. ash + NPK + m + high moor peat 31.4 g/pot + sulphur 10 g/pot 24. ash + 2 (NPK MG) + 2 m + high moor peat 31.4 g/pot 25. ash + NPK + m + green manure from cereals 322 g/pot 26. ash + 2 (NPK Mg) 27. ash + NPK + m + green manure from legumes 322 g/pot Rating 100.0 59.9 57.6 52.6 51.1 44. 1 43.5 42.9 40.1 38.7 31.1 31.1 26.O 20.3 20.3 18.9 14.1 14.1 8.4 7.3 6.8 3.4 2.5 2.3 2.3 1.7 1.1 Note: m - microelements. NPK - Nitrogen, Potash and Potassium fertilizer. were included (Table 5). In addition, four plant combinations were tested. Each plot was replicated four times. Thus, a total of 120 plots of 4 x 5 m were utilized. Covering the ash with a thick layer of soil (greater than 30 cm) had been shown by other investigators (2, 3) to be an ef- fective method of establishing vegetation on ash. Since layers of this thickness are very costly and had already been proven successful, this study concentrated on thinner layers, i.e., 20, 10, and 5 cm. Some NPK (N-nitrogen, P-P2O5, K-K20) fertilizer was applied to the ash when treatment took place. More was applied during sowing of the seed and as top- dressing. In the following years the plots were fertilized in the spring and after the first cutting. The amount of NPK applied was determined from the pot study and from analysis of soil samples. Different amounts were used at Halemba and Konin. Details of the fertilization program are given in reference 1. The four seed mixtures used in the field trials are shown in Table 6. Seed bed preparation was begun by loosening the ash. At Halemba mechanical equipment was used for this purpose, while at Konin it was necessary to loosen the ash with explosives. The amendments and initial portions of fertilizer were rototilled into the ash to a depth of 20 cm. After 6-10 days the remaining mineral fertilizer was raked in. A few days later the various seed mix- tures were broadcast, raked in, and rolled. Cuttings were taken from the plot in the spring and fall. Dry matter yields were determined and analyses of plant matter were made to determine the uptake of heavy metals by the plants. Five years of data were collected. Field Experiments - Agricultural Crops One object of this research study was to determine if an agricultural crop could be grown on the reclaimed ash. It was highly unlikely that a crop could be sown directly into ash. A more promising techni- que was to build up the ash into a material with suitable physical and chemical soil properties by utilizing soil amendments and plants. After several years of this man- agement, an agricultural crop could be planted. The 120 field test plots used in the earlier study were perfect for such a project. The 10 treatments in the earlier study could be used to determine which were best for preparing the ash for later use for growing agricultural crops. Winter barley (Hordeum vulgare) was selected as the test crop. Deep-rooted ------- crops were unsuitable because of the thin soil layer that had been formed. In the fall of 1979 the plots were plowed and har- rowed, and fertilizer was applied (P205-90 kg/ha, K20 - 100 kg/ha). Winter barley (200 kg/ha) was seeded and lightly har- rowed. Details are available in the full report. The barley crop was harvested in 1980 and 1981 and the dry matter yield was measured. Field Experiments - Forest Culture The field test on forest cultivation in- cluded the evaluation of 12 trees and shrub species (Table 7). These species were selected because of their previous use in vegetating disturbed land. The trees were planted in pits dug in the ash. The size of the pits and treatments are shown in Table 8. The willow and poplar cuttings were not placed in pits, but were planted in ash that had been top dressed similar to grass plots 1 (20 cm soil), 2, 3, and 8 in Table 5. The criteria used to assess the vigor and growth of the trees and shrubs were: (1) to determine the survival rate of each spe- cies, and (2) to measure the increase in height. Visual observations of the plants were made for signs of disease and stress. These observations and measurements were made each May and September over a 6-year period. Details of the tree and shrub studies are available in reference 1. Other Studies During the course of the study, soil sam- ples were taken and analyzed from each Table 5. Ash Treatment Plots 1. Covering of ash with fertile soil layer of 20, 10 or 5 cm plus addition of NPK fertilizer. 2. Covering of ash with 1 cm layer of ben- tonite (100 m3/ha) plus NPK fertilizer (Halemba only). 3. Covering of ash with 5 cm layer of tertiary sand (500 +/ha) mixed with coal plus NPK fertilizer (Konin only). 4. Mixing of low moor peat (10 Mg/ha dry basis) plus NPK fertilizer. 5. Mixing of garden peat (10 Mg/ha dry basis) plus NPK fertilizer. 6. Mixing of farm manure (20 Mg/ha) plus NPK fertilizer. 7. Mixing of corn green manure plus NPK fer- tilizer with double dose of phosphate. 8. Addition of NPK fertilizer only. 9. Addition of NPK fertilizer with double dose of phosphate. 10. Control - no treatment. Table 6. Seed Mixtures Used in Field Trials Seed Mix 1 a) Halemba alfalfa (Medicago Sativa) white melilot (Melilotus albus) b) Konin sainfoin (Onobrichis viciaefolia) crown vetch (Coronilla varia) Seed Mix 2 Grass mixture meadow fescue (Festuca pratensis) orchard grass (Dactylis glomerate) smooth bromegrass (Bromus inermis) meadow grass (Poa pratensis) creeping fescue (Festuca rubra) white clover (Trifolium repens) black medic (Medicago Lupulina) white melilot /Melilotus albus) tall rye-grass (Arrhenatherum elatiusi bentgrass (Agrostis stolonifera) Seed Mix 3 alfalfa (Medicago sativa) orchard grass (Dactylis glomerata) Seed Mix 4 white melilot (Melilotus albus) Total Total Total Total Table 7. Species of Trees and Shrubs Grown on Ash 1. Poplar robusta I (Populus robusta Schn.) 2. Poplar robusta II (Popu/us robusta Schn.) 3. White birch (Betula verrucosa Ehrh.) 4. Gray alder (Alnus incana Moench.) 5. Black alder (Alnus glutinosa Geerth.) 6. Locust (Robinia pseudoacacia L.) 7. Larch (Larix decidue Mill.) 8. Pea shrub (Caragana arborescens Lam.) 9. Gray willow (Salix cinerea cross with Salix viminalis) 10. Sea buckthorn (Hippophae rhamnoides) 11. Willow cuttings (Salix alba cross with Salix fragiles) 12. Poplar cuttings (Populus cross with Serotna Hart.) Table 8. Ash Mixtures Used in Tree Pits Seeding rate 50 kg/ha 10 kg/ha 60 kg/ha 140 kg/ha 70 kg/ha 210 kg/ha 12 kg/ha 4 kg/ha 12 kg/ha 5 kg/ha 17 kg/ha 3 kg/ha 7 kg/ha 5 kg/ha 13 kg/ha 4 kg/ha 82 kg/ha 36 kg/ha 6 kg/ha 42 kg/ha 50 kg/ha I. Fertile soil and ash mixed in proportions of 1:3 plus NP Ha Ash mixed with bentonite 9:1 plus NP (Halemba only) lib Ash mixed with tertiary sand intermixed with coal 3:1 plus NP (Konin only) III. Ash mixed with peat (8 kg peat mixed with 1 m3 ash) plus NP IV. Ash plus NP V. Fertile soil plus NP (Konin only) Note: NP - Nitrogen and potash fertilizer Poplars Other trees Bushes Pit Size 0.7 m x 0.7 m x 0.7 m 0.5 m x 0.5 m x 0.5 m 0.3 m x 0.3 m x 0.3 m ------- of the grass plots to determine the chan- ges that were occurring in the soil/ash with time. Results of this study are avail- able in reference 1. Results and Conclusions Grasses and Legumes The total dry matter yields obtained from the various plots for the 1975-1980 period are shown in Table 9. As noted, the 10-20 cm of fertile soil gave the best re- sults. The data also show that fertilization is critical for plant establishment. A grass and legume combination was the best seed mixture at Halemba while medic with orchard grass was the best at Konin. Agricultural Crops The barley yields for 1981 are presented in Table 10. It should be noted that during the 1977-1980 period (before barley was planted) half of the plots were fertilized and the other half were not. Results of the test indicate that a grass-legume cover could sustain itself without further fertili- zation, but the yield was lower. As noted in Table 10, the barley yields were higher on plots that had received organic matter (fertile soil and plants) as a conditioning step. The yields on the bitu- minous ash were also higher than those on the lignite ash. Forest Culture Six years of data have been collected on trees and shrub growth and survival. The survival data are summarized in Table 11. Table 9. Crops of Hay (Total from 1975-8O) From Experimental Plots (Calculated as t/ha of Dry Mass) * Halemba bituminous coal ash Konin lignite ash mixture Plot Treatment Ash + 20 cm of fertile soil + NPK Ash + 10 cm of fertile soil + NPK Ash + 5 cm of fertile soil + NPK Ash + bentonite + NPK Ash + acid tertiary sand + NPK Ash + low moor peat + NPK Ash + high moor peat + NPK Ash + farm manure + NPK Ash + N2PK Ash + N2PK + green manure of corn Ash + NPK Pure ash (control) Pure ash - after second sowing and NPK "Metric tons/ha. Table 10. Crops of Winter Barley (Chaff + grasses with legumes 50.14 38.63 32.69 21.41 30. 82 22.23 23.48 29.45 23.64 0 24.41 Grain) Gathered in orchard grass with lucerne 36.19 27.87 26.40 22.97 28.88 20.99 22.59 27.65 23.52 0 25.67 1981 on Experimental Plots grasses with legumes 45.38 42.61 35.41 35.86 38.37 36.77 41.20 _ 34.82 34.2/ 0 25.27 orchard grass with lucerne 41.42 43.20 36.86 34.24 33.97 32.30 38.25 34.12 30.35 0 29.07 After Fore Crop tin 1975-80) of Grasses Mixed with Legumes (Crop from the Combination A = 1OO.O) Ash from bituminous coal Ash from lignite Method of preparing "ash soil" Combination in 1975 A B C D E F G H 1 0" "Crops on Ash + 20 cm of fertile soil + NPK Ash + JO cm of fertile soil + NPK Ash + 5 cm of fertile soil + NPK Ash + bentonite + NPK Ash + acid tertiary sand + NPK Ash + low moor peat + NPK Ash + high moor peat + NPK Ash + farm manure + NPK Ash + N2PK Ash + N2PK + green manure of corn Ash + NPK Nonfertilized ash (control) combination A on ashes from bituminous coal fertilized in 1976-80 100.0 65.5 65.2 37.7 92.5 26.1 55.8 76.3 61.6 66.4" 100.0 nonfertilized in 1977-80 87.9 78.0 63.0 24.9 75.4 51.2 72.7 48.1 51.9 59.9" fertilized in 1976-80 100.0s 72.7 72.0 66.7 61.0 51.8 56.4 65.2 70.2 36.9" nonfertilized in 1977-8O 88.7 56.7 64.9 50.0 39.0 42.6 53.9 41.1 48.9 17.7b Crops on Combination A on ashes from lignite 68.1 . bAfter fertilization in 1976 and after second sowing with grasses and legumes. ------- Survival was not affected by the pit treat- ment at Halemba, the major difference was due to the particular species grown. Trees at this site were also impacted by air- borne fluorine and SO2 from nearby in- dustry. They were also subject to disease, which may have been a result of their stressed condition. The pit treatment made a major difference in tree survival at Konin. The mixture of ash with soil and soil alone gave the best results. Losses at Konin were attributed to the toxic nature of the ash, atmospheric pollution, and rab- bits eating the young trees. Growth increments were measured for those trees and shrubs that did survive. As noted in Table 11, the pit treatment did not make a major difference in growth at Ha- lemba, but did at Konin. The gray alder had the greatest growth rate at Halemba, while locust was the best at Konin. This project is J-5-533-12 of the Scien- tific Activities Overseas - Special Foreign Currency Program of the U.S. Environmen- tal Protection Agency. References 1. Wysocki, Wladyslaw. Reclamation of Alkaline Ash Piles and Protection of Their Environment Against Dusting. EPA-600/7-79-128, U.S. Environmental Protection Agency, Cincinnati, Ohio, July 1979. 2. Hodgson, D.R. and Townsend, W.N. The Amelioration and Revegetation of Pulverized Fuel Ash. In: Ecology and Reclamation of Devastated Land. Ed- ited by R.J. Hutnik and G. Davis, Gor- don and Breach Publishing, New York, 1973, pp. 247-271. 3. Maly, V.K. Otazce Zemedelski Rekul- tivace Slozist Elektraren. In: Vadecke Prace Vyzkumneho Ustavu Melioraci, Praha 1969, No. 10, pp. 91-108. Table 11. Survival and Growth of Trees and Shrubs on Ashes from Bituminous and Lignite Coal Increment* in height and survival11 ash from coal Halemba bituminous Pit treatment (see table 8) 1 Ha lib III IV V Species of trees and shrubs Poplar 1 Poplar II White birch Gray alder Black alder Black locust Larch Pea shrub Willow Sea buckthorn Willow cuttings Poplar cuttings Average cm 0.33 0.34 0.32 0.32 - 0.17 0.20 0.11 0.74 0.63 0.45 0.37 0.37 0.25 0.14 0.20 0.33 Survival - H H L L M H M H M L L Konin lignite cm 0.38 0.36 0.28 0.26 0.38 0.37 0.30 0.47 0.21 0.48 0.67 0.07 0.35 0.14 0.25 0.24 0.33 Survival _ - M M L H L H L H M M L alncrement of growth during sixth year. bSurvival: H - High, M - Moderate, L - Low. ------- Wladyslaw Wysockiis with the Central Research and Design Institute for Openpit Mining, Poltegor, 53-332 Wroclaw, Poland; the EPA author Ronald D. Hill (also the EPA Project Officer, see below) is with the Hazardous Waste Engineering Research Laboratory, Cincinnati, OH 45268. The complete report, entitled "Reclamation of Alkaline Ash Piles," (Order No. PB 86-183 001/AS; Cost: $28.95, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Hazardous Waste Engineering Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 U.3.OF-sT!CiALW!Ww' ...'35 J-E \,;\~t i ^ _ 1i~L SM»'j ; u .3 L ":: Official Business Penalty for Private Use $300 EPA/600/S2-86/049 0000329 PS U S ENVIR PROTECTION AGENCY RESIGN 5 LIBRARY 230 S DEARBORN STREET CHICAGO IL 60604 ------- |