United States Environmental Protection Agency Water Engineering Research Laboratory Cincinnati OH 45268 Research and Development EPA/600/S2-86/115 Apr. 1987 /it &EPA Project Summary Nitrate Removal from Contaminated Water Supplies: Volume I. Design and Initial Performance of a Nitrate Removal Plant Gerald A. Guter This report reviews the design, con- struction, and operation of a 1-mgd nitrate removal plant in McFarland, California. The plant treats groundwater pumped from one of the wells supplying water for domestic use. Nitrates are reduced from approximately 15.8 mg/L NO3-N to well below the maximum contaminant level (MCL) of mg/L NO3-N. Included in the design con- siderations are such factors as water supply, health and safety, level of tech- nology, location, capacity, regeneration frequency, water quality, operational sequence, brine disposal, automatic operation, and performance monitoring. The procedures for both manual and automatic operation are discussed. Continuous daily (24-hr) operation of the plant was made possible by auto- matic operation. The presence of the operator is required for approximately 1 hr per day to check performance. Automatic nitrate monitoring of product water was performed once an hour through the use of modified ion chro- matography. Daily records of flows, water quality, electrical consumption, salt usage, and manhours were kept to determine operating costs. The total wastewater produced by the nitrate plant was 3.39% of the amount of water delivered to the distribution system from the well. The treated water was 75% of water delivered. Saturated brine was 0.09%, dilute brine was 0.49%, rinse water was 1.76%, and backwash water was 1.14%. All percentages were of the blended water delivered to the dis- tribution system. All waste from the plant was discharged to the McFarland municipal wastewater treatment sys- tem, with ultimate discharge to 128 acres of cotton and alfalfa crops. The amount of water treated by each ion exchange vessel before regeneration was 165,000 gal (260 bed volumes (BV)). The amount of salt used per regeneration was 6.35 Ib/ft3 of resin. Capital costs totaled $311,118 for a 3-ft bed system, and $355,638 for a 5-ft bed system. Operation and main- tenance costs were $0.13 per thousand gal when the system was operating at 1 mgd. Total costs, including operations and maintenance (O&M) and amortized capital, were $0.25 per 1000 gal when operating at design capacity of 1 mgd. Thlf Profect Summary was developed by EPA'* Water Engineering Reaearch Laboratory, Cincinnati, OH, to announce key finding* of the research project that I* fully documented In a separate report of the tame title (tee Protect Report ordering Information at back). Introduction This report reviews the operation of a 1 -mgd nitrate removal plant at McFarland, California. The plant and supporting equipment are described, and an analysis of the capital cost of construction and the operation and maintenance (O&M) costs ------- are also presented. The data on which this report is based were obtained during the initial adjustment period of the plant and during the first 6 months of automatic operation ending November 30,1984. The plant uses the ion exchange pro- cess with commercially available resin. The process design is based on the re- search and pilot studies performed under a previous cooperative agreement with the U.S. Environmental Protection Agency (EPA). The design and operation of the plant were supported by the McFarland Mutual Water Co. (McFMWCo) and EPA under cooperative agreement Nos. CR808902-010 and CR808902-020. Construction of the plant was made pos- sible with funds from McFarland Mutual Water Company, The Kern Co. Community Development Agency, and the Kern County Water Agency. The Community Development Agency is funded by the U.S. Department of Housing and Urban Development (HUD). This report is the first of a two-volume final report under the existing grant and is restricted to the general subject of the initial operation of the plant. The second volume will include a report on the con- tinuing operation of the plant for several additional months. Plant Design A flow diagram is shown in Figure 1. Feed water is supplied directly from the well pump into two of the vessels in the service cycle. Vessel 1 is 50% exhausted when Vessel 2 starts its service period. When Vessels 1 and 2 are in service. No. 3 is in regeneration or standby. After No. 1 is exhausted, 2 and 3 are in service, etc. Service is stopped in any one vessel by an electrical signal from a flow totalizer or by a manual signal. Electrical conductivity is monitored at well supply and product water locations to detect any brine leakage into the pro- duct water. Alarm and shut down occur if product conductivity rises above that of supply water. Nitrate levels are also monitored in the blended product water and excess nitrate can also cause auto- matic alarm and shut down. Major consideration was given to the following elements of plant design: Water Supply Health and Safety Level of Technology Location Capacity Regeneration Frequency Water Quality Operational Sequence Brine Disposal Automatic Operation Monitoring of Performance Water Supply The McFMWCo supplies water from its well and through its distribution system for municipal use. The only water source at present is underlying groundwater. Six wells are located in McFarland. Well No. 3 has been discontinued for public use because of too high nitrate levels. Well No. 2 is the location of th nitrate plant now is operation. Recent analysis of Wells 1 and 4 shows nitrate above the maximum contaminant level (MCL). Table 1 presents data on the water quality of four wells with high nitrate levels. Because of recent projected de- velopment trends, two new wells were constructed to serve the developing areas in a remote part of the City and operation will begin shortly. Health and Safety Health and safety were the major con- siderations; and therefore, they took precedence where design conflicts arose. The plant design was reviewed by the California State Division of Health, which issued an operating permit on May 13, 1983. Before issuing the permit, a design review was conducted. The major con- cerns were that: 1. Brine be isolated from the brine water supply system (this is accomplished with a double check valve). 2. Waste brine and wash water be isolated from the distribution system (this is accomplished by double valves or a block and bleed arrangement). 3. Nitrate levels in supply water be kept below 10 mg/L NO3-N and preferably below 7 mg/L NO3-N. 4. A Class 2 State-certified operator be made responsible for plant operation (two employees of McMWCo will quality for this certification). Level of Technology The technology used in the mechanical design and planning for the plant relies heavily on that used in the water soften- ing industry. The chemical process design is based on research on the use of anion exchange resins completed under pre- vious EPA grants. Although that research indicated efficiency might be conven- tional, commercial available strong-base anion exchange resin was used as a basis for design. Location Plant location at one of the well sites was dictated by the already-in-place well and distribution system, which have been in use for more than 30 years and are typical for small communities dependent on groundwater. McFarland can draw water from any of the six wells that supply water to an interconnected dis- tribution system. Because the system has no central distribution point, the plant had to be designed to operate from a single well. Well pumps operate on a demand basis; consequently, the plant had to be able to operate in an automatic on-off basis. The design was made to accept water directly from the well pump, treat it for nitrate removal, and allow treated water to flow directly into the distribution system without directing it to a central part of the system and without storage. Capacity The delivery capacity of Well No. 2 is approximately 695 gpm (1 mgd on a continuous basis). With nitrate-nitrogen levels in the 16-mg/L range, a 7-mg/L product can be achieved by reducing nitrate to 0 in 70% of the water anc blending with untreated water. Studies show a decreased regeneration efficiency as nitrate leakage in treated water ap proaches zero. The plant was sized to treat the tola well production rate, to provide a blendin< facility to allow a range of treatment leve from partial to complete, and to providi sufficient capacity to meet rising nitrati levels. Regeneration Frequency Anion exchange resins require regen eration with a sodium chloride brine. Fo uninterrupted service, it is necessary ti have a standby regenerated bed of resii in a second vessel starting intooperatioi when the first starts its regeneratioi cycle. Regeneration times (about 120 min ii McFarland) are fixed regardless of be< size, whereas bed exhaustion times o service periods vary with bed size an capacity (see Table 2). Bed exhaustioi time should be longer than the regen eration time if two beds are allowed. Long standby periods require large beds and added resin inventory an equipment costs. Bed size is also limite in that deeper beds give higher back pressure and large area beds give lowt flow rates (hydraulic loading), whic promote reverse adsorption or dumpin of nitrate from resin to product water. ------- Ion Exchange System Brine I to 0) c r Pr ressure Tank J 7b Distribution System Figure 1. Flow diagram. j \ (,J Valves Legend Service 1 Service 2 Regeneration Table 1. Item Composition of McFarland Well Water (ppm) In 1980 Well No. Date Calcium Sodium Bicarbonate Chloride Sulfate Nitrate-N TDS pH 5-8-80 28 50 88 28 51 6.8 235 7.7 4-9-80 88 65 102 86 105* 15.2 466 7.2 5-1-80 156 100 121 94 310 22.1 827 7.3 4-16-80 78 72 95 51 182 10.6 485 7.7 *Analyses on 5/31/78 showed sulfate levels of 261 ppm and nitrate levels of 78 ppm. Table 2. Estimated No. of Regenerations per Vessel per Day Percent Treated Water in Blend and Bed Depth Bed Volumes Treated 200 300 400 100% 3ft 2.67 2.00 1.33" 5ft 1.60 1.20 0.80+ 75% 3ft 2.00 1.50 1.00 5ft 1.20 0.90 0.6 50% 3ft 1.34 1.00 0.67 5ft 0.84 0.60 0.40 25% 3ft 0.67 0.50 0.33 5ft 0.40 0.30 0.20 * Twelve-hour service period per vessel and 6-hr standby per vessel. + Twenty-hour service period per vessel and 10-hr standby per vessel. Water Quality Water quality is an extremely important factor in nitrate ion exchange technology. Two areas of concern are: 1. All major anions interfere to reduce bed capacity and change product water quality. 2. Resin ion equilibria and flow rate ef- fects must be taken into consideration to obtain proper bed operation. Operational Sequence The operational sequence is selected either through a programmable controller or manual push-button operation on each vessel. Each vessel undergoes the fol- lowing sequence: Service, brine injection, brine displace- ment, slow rinse, bachwash/resin de- classification. Under automatic control, any combina- tion of valve operation can be selected in one or more programs. Brine Disposal Brine is disposed to the municipal waste treatment facility. Review by the City of McFarland and the California State Water ------- Quality Control Board was done through the environmental impact report process. The quality of dissolved solids added to wastewater caused concern for its impact on soil and groundwater in the disposal area. Treated wastewater is discharged to 128 acres of agricultural land used for growing animal feed and cotton. A monitoring program is in effect in the discharge area to monitor soil, ground- water, and wastewater. Automatic Operation Automatic operation of the plant was considered essential to reduce the amount of manpower required to sustain continuous operation. The only manual operations required were turning the system on or off and inspection of data and plant operation. Monitoring of Performance Extensive plant monitoring was in- corporated into the design because this was a demonstration plant and it was necessary to determine operating costs, performance, and reliability. The methods of flow and batch measurement presented no difficulty; however, the method of continuous nitrate monitoring was in doubt because of the lack of reliable methods. Ion chromatography was chosen as the method for testing, since it ap- peared adaptable to continuous nitrate monitoring and had the capability of monitoring other ions of interest. This is also an approved EPA nitrate method. Plant Performance Salt Dosage Brine Use Factor and Nitrate Leakage If a Type I or II strong-base anion resin is used, the amount of salt required for regenerating a nitrate-spent bed can be easily estimated from the chemical analysis of water from Well 2 obtained in January 1984. This estimate resulted in the use of 1.5 BV of 6% salt as regenerant to treat 165,900 gal for each service cycle or 260 BV (N). This gives an ap- proximate nitrate leakage of 6.3 mg/L N03-N. Salt dosages were initially higher than the target value of 1.5 BV of 6% brine because of the inability of the brine system to deliver a consistent brine dosage. Consistent brine dosages were obtained later by reprogramming to terminate the batch on flow instead of time. Table 3 compares the actual chemi- cal data obtained over the 6-month period with those estimated for a plant using a 260-BV service period. Nitrate leakages obtained by the plant are in good agreement with the predicted values. Also, any failure to obtain proper declassification will give an erroneous nitrate analysis. The nitrate leakages in Table 3 are from grab samples for certified lab analyses and are subject to variations of sampling and analytical errors. The plant Brine Use Factor (BUF) values (Table 4) are the average monthly values. This data show that the plant is about 3% less efficient than predicted. This result is quite remarkable considering the as- sumptions inherent in the method used for making these predictions. Dilute Brine Quantity The quantities of both saturated and diluted brine are given in Table 5 together with other quantities used for each of the 6 months. The amount of saturated brine is noted to be approximately 0.09% of the total water produced, or 0.12% of the amount treated. The corresponding percentages for diluted brine are 0.49% and 0.65%, respectively. Rinse, Water Backwash, and Total Wastewater The amounts of water used for rinsii backwash, and total wastewater are lisl in Table 5. The plant automatically monitors cc ductivity of rinse water. About 30% exec rinse water is used because conductar falls to a constant value at about 20 gal. Rinse water was not reduced duri this period to allow excess rinsing. The total wastewater over the 6-mor period is 3.39% of the blended water a 4.52% of the treated water. Total water recovery is 96.7% over 1 6-month period. This high water recovery, which is ev subject to improvement, is one of t main advantages of the ion exchan process over the reverse osmosis proce for nitrate removal. Power Consumption Daily records of power consumption the plant have been maintained to obtz electrical power costs for well operati and well plus nitrate plant operation. T Table 3. Summary Comparison of Actual Chemical With Predicted Data Plant Data Estimated* Date 6-84 7-84 8-84 9-84 10-84 11-84 Averages Nitrate** Leakage 2.9 3.2 2.3 0.7 2.9 3.8 2.6 Salt Ib/ft3 5.94 6.36 6.46 6.48 6.35 6.55 6.35 BUF+ 8.3 9.2 11.8 11.4 11.3 9.7 10.3 Nitrate** Leakage 4.0 3.4 2.7 2.5 2.4 3.3 2.8 Salt Ib/ft3 5.94 6.36 6.46 6.48 6.35 6.55 6.36 BUF 9.8 9.4 10.8 10.9 10.0 8.8 10.0 *For 260 BV service. Equivalents of Chloride in Fresh Regenerant +Brine Use Factor = Equivalents of Nitrate Removed from Influent Water ^Concentration of nitrate listed as mg NO3-N/L To convert to mg N03/L multiply by 4.43 Estimates of BUF for Full Bed Use and Partial Bed Use BUF Date 6-84 7-84 8-84 9-84 10-84 11-84 Average 260 BV 9.8 9.4 10.8 10.9 10.0 8.8 100% Use 8.9 8.1 8.9 8.5 7.3 7.4 Salt Dose (Ib/ft3) 260 BV 5.94 6.36 6.46 6.48 6.35 6.55 100% Use 5.94 6.36 6.46 6.48 6.35 6.55 % Brine Savings Potential for 1OO% Bed Use 9.2 13.8 17.4 22.0 27.0 15.9 17.6 ------- Table 5. Secondary Plant Performance Factors Thousands of Gallons Product Water Date 6-84 7-84 8-84 9-84 10-84 11-84 Totals % of Blend % of Treated Blend 5307 3595 3002 4245 4738 3771 24598 100 133 Treated 3516 2673 2617 3433 3055 3163 18457 75.0 100 Sat. Brine 4044 3291 3272 4307 3752 4012 22678 0.09 0.12 Water Used, Gal Dilute Brine 37670 29270 7710 22300 16620 7190 120760 0.49 0.65 Rinse Water 80990 68640 62340 77340 67360 77060 433730 1.76 2.35 Backwash 52422 44780 47640 57350 46130 31440 279762 1.14 1.52 Total Waste 171082 142690 117690 156990 130110 1 15690 834252 3.39 4.52 pressure drop through the ion exchange system is approximately 10 psi. Power readings were taken with the well pump- ing directly into the system and were compared with readings taken while the plant was in operation. Of the total power consumed at the site, 10% was required for the operation of the plant, yielding 0.244 kWh per 1000 gal as the power requirement for plant operation. Power for the brine pump and air compressor are considered negligible. The cost of this power obtained from the billing of Pacific Gas and Electric Co. is $0.08183 per kWh, making power cost for plant operation $0.019967 per 1000 gal, or $19.97 per million gal of blended water delivered to the system. Cost Analyses Capital costs for the McFarland plant are summarized in Table 6. Costs are given for two different vessel heights. The 6-ft height accommodates the 3-ft bed depth and the 10-ft height accom- modates a 5-ft bed depth. The cost of the extra side height is the most economical way of increasing bed capacity. O&M costs (Table 7) reflect actual salt and power costs for the 6-month period. The costs presented for normal plant main- tenance, miscellaneous costs, and resin replacement may be changed if firm data on resin loss can be obtained. No loss of resin capacity has been detected from the operating data obtained thus far. The 1 -hr per day operator cost is still believed to be adequate, since this is mainly a record keeping and inspection effort. Table 8 summarizes the total treatment costs. The amortized annual capital cost per 1000 gal is based on 100% use of the 1 -mgd capacity. The McFarland plant was only operated at 13.7% of its full capacity during this initial period (see Table 9). In this case the amortized annual capital cost per 1000 gal is 7.30 times that shown in Table 8 or $.832 per 1000 gal. As annual plant production falls from 100% to 0% of full capacity use, this cost rises from $0.114 to infinity. O&M cost per 1000 gal are estimated to remain approximately as given in Table 7 regard- less of plant usage. The high cost of capital amortization of a partially used plant must be taken into consideration when assessing the cost impact on the consumer. The true water cost that the consumer must pay for operating the plant at less than full capacity can be estimated by comparing consumer costs with and without the plant. True consumer costs for this report reflect the fact that the consumer receives water from the plant as well as from other wells in the system. In this case the capital cost associated with water supply capital costs in McFarland is the capital cost of wells, the distribution system, and related facilities and improvements (not including a nitrate plant), CS, plus the capital costs shown in Table 8, CP. The total consumer cost of amortizing the capital costs (per 1000 gal of water con- sumed) by producing a fraction of 1 mgd from existing facilities and the remainder from the nitrate plant is: Total capital cost/1000 gal = (CS + CP)/ 1000 gal. where: CS = cost of wells, distribution system, related facilities, improvements. CP = capital costs for nitrate plant. The additional annual amortized capital cost that the consumer must pay for partial (or full) use of the nitrate plant is the amortized capital cost, $41,773, for the nitrate system as shown in Table 8. The added cost due to O&M of the nitrate plant during this report period is 0.137 times the O&M cost of Table 7. The total added consumer cost during this report period due to nitrate treatment of 13.7% of the water supplied to the system is: $/1000 gal = $0.114 + 0.137 x $0.131 or $0.162 These cost analyses will be presented in more detail when all costs over a 2-year period of operation are available and will be discussed in Volume II of this report. Conclusions and R ecommendations 1. The plant was automatically operated for a 6-month period and exhibited the following performance char- acteristics averaged over the oper- ating period: a. Nitrate leakages averaged 5.2 mg/L N03-N (23.2 mg/L N03) in a blend of treated and untreated water. b. The blend consisted of 76.1% treated water and 23.9% un- treated water. c. Brine dosages were 6.36 Ib of salt per ft3 of resin, or 2.49 per 1000 gal of blended water. d. Brine efficiencies averaged 10.3 equivalents of chloride per equi- valent of nitrate removed and varied from a low of 8.3 to a high of 11.8. e. Water recovery was 96.7% of the water pumped. The remaining 3.3% was discarded as waste brine and wastewater. f. Wastewater per 1000 gal of blended watr consisted of 0.92 gal of saturated brine (4.9 gal of dilute brine), 17.6 gal of rinse water, and 11.4 gal of backwash water. 2. Maximum automation was used successfully to satisfy the minimal manpower requirements of a small water system operator. The plant was designed and is being demon- strated primarily with the needs of small communities in mind where wells and distribution systems are already in place. The plant operates at a well site rather than as a central treatment plant. 3. Raw water composition varied during this period of operation. Nitrates varied from 16.0 to 11.1 mg/L N03-N. This provided the opportunity to measure the effect of changing water composition on plant per- formance. 4. Resin beds were operated at 76% capacity during this initial adjust- ment period to prevent overruns that could occur because of operation problems. ------- Table ft Capital Costs for McFarland in 1983 Vessel Size Item I.X. Vessels (3 included) Onsite construction Brine tank Other Resin 225 ft3 (3 ft depth) 424 ft3 (5 ft depth) Sub total Engineering & administration 15% Total 6'D x 6'H $ 96,511 81,151 18,700 40,045 35,OOO $271,407 40.711 $311.118 6'D x WH* $111.741 81.154 18,700 40,045 56,610 $309,250 46.388 $355,638 * McFarland plant. Table 7. Operation and Maintenance Costs Item Operation (1 hr/day) Normal O&M. .02X(355,638) Power, boost pump (.093/kWhj* Resin replacement (5 yrs) Salt ($31 .50/ton). (7O% treated in blend f Miscellaneous Total O&M Annual Cost $ 4.745 7,113 7,289 1 1.522 14.314 3,000 $ 47.983 $/ 1000 gal $ 0.013 0.019 0.020 0.032 0.034 0.008 $ 0. 131 *244 million gal based on. 08183C per kWh. +2490 Ib/'million gal. Table 8. Total Capital and O&M Costs Item Capital costs - $355.638 (20 years @ 10%) Operation & maintenance Total Annual Cost $41.773 47.983 $89.756 $/ 1000 gal $0.114 0.131 $0.245 5. The effect of operating at less than 100% of the bed capacity is esti- mated to be a decrease of brine efficiency of approximately 18%. 6. Brine efficiency, nitrate leakage, and bed volumes to nitrate breakthrough can be accurately predicted from ion exchange theory. Computer-based programs being developed can simu- late effluent histories and are com- parable to those obtained from the plant. They also give chromato- graphic distributions of ions within spent beds. 7. A 3-ft resin bed depth was used during this period of operation. A 5- ft bed will be used in future tests to obtain comparative data. 8. The power consumed by the plant is 244 kWh per million gal of blended water. This amount is 10% of the total power required for pumping at the well site. 9. Capital costs were $311,118 for a plant with the 3-ft-deep resin bed and $355,683 for a plant with a 5-ft bed. The total costs are $0.245 per 1000 gal of blended water for the 5-ft bed plant (1983 costs). During this report period the plant was operated at only 13.7% capacity. The overall cost to the McFarland community for nitrate removal during this period was $0.162 per 1000 gal of water consumed. 10. The plant is totally automatic in operation with automatic nitrate analysis for monitoring and auto- matic shut down if nitrate exceeds the MCL in the product water. Com- puter printouts of operating data are obtained on a daily basis and if alarms occur. 11. Operator tasks are reduced to ap- proximately 1 hr per day and include routine inspection, maintenance, and recordkeeping. 12. Nitrate removal is economically and technically feasible by the ion ex- change process. The most undesir- able feature is the production and disposal of waste brine. At McFarland during this report period, approxi- mately 1300 Ib of waste salts were disposed of in the plant wastewater daily by discharging to the municipal wastewater system. If the plant were operated 24 hr per day, the daily salt discharge would be 2500 Ib in 33,000 gal of wastewater. Close monitoring of soil and plant condi- tions at the disposal site is being conducted. 13. Although nitrate removal by the ior exchange process is largely being considered as a process adaptable for small communities, it is the lattei who will find the waste disposa problems the most difficult to solve Improvements in the process ar€ still required to reduce quantities ol waste salts. These can probably be accomplished by use of highly selec- tive nitrate resins, brine recircula- tion, recovery and separation ol sodium nitrate and sodium chloride, and close adjustment of plant oper- ation to changes in raw watei composition. 14. Plant shut downs were due to mal- functions of electrical and mechani- cal equipment and leaks in plastic pipe. All repairs were handled b\ water company personnel. 15. The adjustment and operation of the plant was complex because the same microprocessor was used for plam control and data collection and re- porting. Considerable operating time was lost as a result of writing anc testing the data collection portion o' the program. The controller requirec programming by ladder logic, which is cumbersome as a computer lan- guage. A separate computer is re- commended for data collection at t similar installation. 16. Ion chromatography is satisfactory for routine anion analysis and re- search, but it definitely requires im- provement for continuous on-stream plant monitoring. Additional re- search on automatic nitrate analysis is recommended. 17. Further development of the nitrate selective resin is recommended be- cause use of a nitrate selective resin would eliminate the possibility of nitrate dumping and would reduce introduction of chloride into product water. 18. Further research on waste brine disposal and brine reuse is recom- ------- mended to eliminate the buildup of waste nitrate and other salts in the disposal area and underlying ground water. The full report was submitted in ful- fillment of Cooperative Agreement No. CR808902-02-0 by McFarland Mutual Water Company under the sponsorship of the U.S. Environmental Protection Agency. Tab/e 9. Summary of Monthly Data Salt Dose* Date 6-84 7-84 8-84 9-84 10-84 11-84 Averages Ib/ft3 5.94 6.36 6.46 6.48 6.35 6.55 6.36 Ib/ 1000 gal of Blend 2.01 2.42 2.89 2.69 2.10 2.82 2.49 % Treated* Nitrate-N lOOOgal in Blend (mg/L)* in Blend Delivered 66.2 74.0 87.2 80.9 64.5 83.8 76.1 4.8 5.0 5.6 5.3 5.4 5.2 5.2 5.307 3,595 3.002 4,245 4,738 3,771 *Monthly averages. Gerald A. Outer is with Boyle Engineering Corporation, Bakersfiled, CA 93302- 0670. Richard Lauch is the EPA Project Officer (see below). The complete report, entitled "Nitrate Removal from Contaminated Water Supplies: Volume I. Design and Initial Performance of a Nitrate Removal Plant," {Order No. PB 87-145 470/AS; Cost: $18.95, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Water Engineering Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 BULK RATE POSTAGE & FEES F EPA PERMIT No G-3 Official Business Penalty for Private Use S300 EPA/600/S2-86/115 ------- |