United States
                   Environmental Protection
                   Agency
Water Engineering
Research Laboratory
Cincinnati OH 45268
                   Research and Development
EPA/600/S2-86/115 Apr. 1987
                                                                                 /it
&EPA         Project  Summary
                   Nitrate  Removal  from
                   Contaminated Water  Supplies:
                   Volume I. Design and Initial
                   Performance  of a  Nitrate
                   Removal  Plant
                   Gerald A. Guter
                    This report reviews the design, con-
                   struction, and operation of a 1-mgd
                   nitrate removal plant in  McFarland,
                   California. The plant treats groundwater
                   pumped from one of the wells supplying
                   water for domestic use. Nitrates are
                   reduced from approximately 15.8 mg/L
                   NO3-N to well below the maximum
                   contaminant level (MCL) of mg/L
                   NO3-N.  Included in  the design con-
                   siderations are such  factors as water
                   supply, health and safety, level of tech-
                   nology, location, capacity, regeneration
                   frequency, water quality, operational
                   sequence,  brine disposal, automatic
                   operation, and performance monitoring.
                   The procedures for both manual  and
                   automatic operation are discussed.
                    Continuous daily (24-hr) operation of
                   the plant was made possible by auto-
                   matic operation. The presence of the
                   operator is required for approximately
                   1  hr per day to check performance.
                   Automatic nitrate monitoring of product
                   water was  performed once  an hour
                   through the use of modified ion chro-
                   matography. Daily records of flows,
                   water quality, electrical consumption,
                   salt usage, and manhours were kept to
                   determine operating  costs. The total
                   wastewater produced by the nitrate
                   plant was 3.39% of the amount of water
                   delivered to the distribution system from
                   the well. The treated water was 75% of
                   water delivered. Saturated brine was
                   0.09%, dilute brine was 0.49%, rinse
                   water was 1.76%, and backwash water
was 1.14%.  All percentages were of
the blended water delivered to the dis-
tribution system.  All waste from the
plant was discharged to the McFarland
municipal wastewater treatment sys-
tem, with ultimate discharge to 128
acres of cotton and alfalfa crops.
  The amount of water treated by each
ion exchange vessel before regeneration
was 165,000 gal (260 bed volumes
(BV)).  The amount of salt  used per
regeneration was 6.35 Ib/ft3 of resin.
  Capital costs totaled $311,118 for a
3-ft bed system, and $355,638 for a
5-ft bed system. Operation and main-
tenance costs were $0.13 per thousand
gal when the system was operating at 1
mgd. Total costs,  including operations
and maintenance (O&M) and amortized
capital, were $0.25 per 1000 gal when
operating at design capacity of 1  mgd.
  Thlf Profect Summary was developed
by EPA'* Water Engineering Reaearch
Laboratory, Cincinnati, OH, to announce
key finding* of the research project that
I* fully documented In a separate report
of the tame  title  (tee Protect Report
ordering Information at back).


Introduction
 This report reviews the  operation of a
1 -mgd nitrate removal plant at McFarland,
California. The  plant and supporting
equipment are described, and an analysis
of the capital cost of construction and the
operation and maintenance (O&M) costs

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are also presented. The data on which
this report is based were obtained during
the initial adjustment period of the plant
and during the first 6 months of automatic
operation ending November 30,1984.
  The plant uses the ion exchange pro-
cess with commercially available resin.
The process design is based on the re-
search and pilot studies performed under
a previous cooperative agreement with
the U.S.  Environmental Protection Agency
(EPA). The design and operation of the
plant were supported  by the McFarland
Mutual Water Co. (McFMWCo) and EPA
under  cooperative agreement Nos.
CR808902-010 and  CR808902-020.
Construction of the plant was made pos-
sible with funds from McFarland Mutual
Water Company, The Kern Co. Community
Development  Agency, and  the Kern
County  Water Agency. The Community
Development Agency  is funded  by the
U.S.  Department of Housing and Urban
Development (HUD).
  This report is the first of a two-volume
final report under the existing grant and
is restricted to the general subject of the
initial operation of the plant. The second
volume  will include a report on the con-
tinuing operation of the plant for several
additional months.
 Plant Design
  A flow diagram is shown in Figure 1.
 Feed water is supplied directly from the
 well pump into two of the vessels in the
 service cycle. Vessel 1 is 50% exhausted
 when Vessel 2 starts its service period.
 When Vessels 1 and 2 are in service. No.
 3 is in regeneration or standby. After No.
 1 is exhausted, 2 and 3 are  in service,
 etc. Service is stopped in any one vessel
 by an electrical signal from a flow totalizer
 or by a manual signal.
  Electrical conductivity is monitored at
 well supply and product water locations
 to detect any brine leakage into the pro-
 duct water. Alarm and shut down occur if
 product conductivity rises above that of
 supply  water.  Nitrate levels are  also
 monitored in the blended product water
 and excess nitrate can also cause auto-
 matic alarm and shut down.
  Major consideration was given to the
 following  elements of plant design:
    Water Supply
    Health and Safety
    Level of Technology
    Location
    Capacity
    Regeneration Frequency
    Water Quality
    Operational Sequence
    Brine Disposal
    Automatic Operation
    Monitoring of Performance

Water Supply
  The McFMWCo supplies water from its
well and through its distribution system
for municipal use. The only water source
at present is underlying groundwater. Six
wells are located in McFarland. Well No.
3 has been discontinued  for public use
because of too high nitrate levels. Well
No. 2 is the location of th nitrate plant
now is operation. Recent analysis of Wells
1 and 4 shows nitrate above the maximum
contaminant level (MCL).
  Table 1  presents data  on the water
quality of four wells with  high nitrate
levels. Because  of recent projected de-
velopment trends, two new wells were
constructed to serve the developing areas
in a remote part of the City and operation
will begin shortly.


Health and Safety
  Health and safety were  the major con-
siderations; and therefore,  they  took
precedence where design conflicts arose.
The  plant design was reviewed by the
California State Division of Health, which
issued an operating permit on May 13,
1983. Before issuing the permit, a design
review was conducted. The major  con-
cerns were that:
1. Brine be isolated from the brine water
   supply  system (this  is accomplished
   with a double check valve).
2. Waste brine  and wash  water be
   isolated from the distribution system
   (this is accomplished by double valves
   or a block and bleed arrangement).
3. Nitrate levels in supply water be kept
   below 10 mg/L NO3-N and preferably
   below 7 mg/L NO3-N.
4. A Class 2 State-certified operator be
   made responsible for plant operation
   (two employees  of  McMWCo will
   quality for this certification).


Level of Technology
  The technology used in the mechanical
design and planning for the plant relies
heavily on that used in the water soften-
ing industry. The chemical process design
is based on research on the use of anion
exchange  resins completed under pre-
vious EPA grants. Although that research
indicated  efficiency  might be conven-
tional, commercial available strong-base
anion  exchange  resin  was used  as  a
basis for design.
Location
  Plant location at one of the well sites
was dictated by the already-in-place well
and distribution system, which have been
in use for more than  30 years and  are
typical for small communities dependent
on  groundwater.  McFarland can draw
water from  any of the six wells  that
supply water to an interconnected dis-
tribution system. Because the system has
no  central distribution point, the plant
had to be designed to operate from a
single well.  Well pumps operate on a
demand  basis; consequently, the plant
had to be able to operate in an automatic
on-off basis.  The design was  made to
accept water directly from the well pump,
treat  it for nitrate removal, and allow
treated water to  flow directly into  the
distribution system without directing it to
a central part of the system and without
storage.

Capacity
  The delivery capacity of Well No. 2 is
approximately 695 gpm (1  mgd on a
continuous basis). With nitrate-nitrogen
levels in  the  16-mg/L range, a  7-mg/L
product   can  be achieved  by  reducing
nitrate to 0  in 70% of the water anc
blending with untreated water. Studies
show a decreased regeneration efficiency
as nitrate leakage in  treated water ap
proaches zero.
  The plant was sized to treat the tola
well production rate, to provide a blendin<
facility to allow a range of treatment leve
from partial to complete, and to  providi
sufficient capacity to meet rising nitrati
levels.
Regeneration Frequency
  Anion  exchange resins require regen
eration with a sodium chloride brine. Fo
uninterrupted service,  it is  necessary ti
have a standby regenerated bed of resii
in a second vessel starting intooperatioi
when the  first starts its  regeneratioi
cycle.
  Regeneration times (about 120 min ii
McFarland)  are fixed  regardless of  be<
size, whereas bed exhaustion times o
service periods vary with bed size  an
capacity  (see Table 2). Bed exhaustioi
time  should  be longer than the regen
eration time if two beds are allowed.
   Long   standby periods require large
beds  and  added  resin  inventory  an
equipment costs.  Bed size is also limite
in  that  deeper beds  give  higher back
pressure and large area beds give lowt
flow  rates  (hydraulic loading), whic
promote reverse adsorption or dumpin
of nitrate from resin to product water.

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                                                      Ion Exchange System
                                                            Brine
   I
   to
   0)
   c
 r
Pr
       ressure Tank
               J
 7b Distribution
    System
Figure  1.    Flow diagram.
        j   \       (,J  Valves
                                                                                          Legend
                                                                                          Service 1
                                                                                          Service 2
                                                                                          Regeneration
Table 1.
Item
     Composition of McFarland Well Water (ppm) In 1980

                                        Well No.
Date
Calcium
Sodium
Bicarbonate
Chloride
Sulfate
Nitrate-N
TDS
pH
5-8-80
28
50
88
28
51
6.8
235
7.7
4-9-80
88
65
102
86
105*
15.2
466
7.2
5-1-80
156
100
121
94
310
22.1
827
7.3
4-16-80
78
72
95
51
182
10.6
485
7.7
*Analyses on 5/31/78 showed sulfate levels of 261 ppm and nitrate levels of 78 ppm.
Table 2.   Estimated No. of Regenerations per Vessel per Day

                            Percent Treated Water in Blend and Bed Depth
Bed Volumes
Treated
200
300
400
100%
3ft
2.67
2.00
1.33"
5ft
1.60
1.20
0.80+
75%
3ft
2.00
1.50
1.00
5ft
1.20
0.90
0.6
50%
3ft
1.34
1.00
0.67
5ft
0.84
0.60
0.40
25%
3ft
0.67
0.50
0.33
5ft
0.40
0.30
0.20
* Twelve-hour service period per vessel and 6-hr standby per vessel.
+ Twenty-hour service period per vessel and 10-hr standby per vessel.
Water Quality
  Water quality is an extremely important
factor in nitrate ion exchange technology.
Two areas of concern are:
1. All  major anions interfere to  reduce
   bed capacity and change product water
   quality.
2. Resin ion equilibria and flow rate ef-
   fects must be taken into consideration
   to obtain proper bed operation.

Operational Sequence
  The  operational sequence is selected
either through a programmable controller
or manual push-button operation on each
vessel.  Each vessel undergoes the fol-
lowing sequence:
  Service, brine injection, brine displace-
ment,  slow rinse, bachwash/resin de-
classification.
  Under automatic control, any combina-
tion of valve operation can be selected in
one or more programs.

Brine Disposal
  Brine is disposed to the municipal waste
treatment facility. Review by the  City of
McFarland and the California State Water

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Quality Control Board was done through
the environmental impact report process.
The quality of dissolved solids added to
wastewater caused concern for its impact
on soil and groundwater in the disposal
area. Treated wastewater is discharged to
128 acres of agricultural land  used for
growing animal feed and cotton.
  A monitoring program is in effect in the
discharge area to monitor soil, ground-
water, and wastewater.


Automatic Operation
  Automatic operation of the plant  was
considered  essential  to reduce  the
amount of manpower required to sustain
continuous operation.  The only  manual
operations  required were turning  the
system on or off and inspection of  data
and plant operation.

Monitoring of Performance
  Extensive  plant  monitoring  was in-
corporated into the design because this
was  a demonstration  plant and it  was
necessary to  determine operating costs,
performance, and reliability. The methods
of flow and batch measurement presented
no difficulty; however,  the  method of
continuous nitrate  monitoring  was in
doubt  because of the lack  of  reliable
methods. Ion chromatography was chosen
as the method for testing,  since it ap-
peared adaptable to continuous nitrate
monitoring and  had  the capability of
monitoring other ions of interest. This is
also an approved EPA nitrate method.

Plant Performance

Salt Dosage Brine  Use Factor
and Nitrate Leakage
  If a Type I or II strong-base anion resin
is used, the amount of salt  required for
regenerating  a nitrate-spent bed can be
easily estimated  from  the  chemical
analysis of water from Well 2 obtained in
January 1984. This estimate resulted in
the use of 1.5 BV of 6% salt as regenerant
to treat  165,900 gal for each service
cycle or 260 BV (N). This gives an ap-
proximate nitrate leakage of 6.3 mg/L
N03-N. Salt dosages were initially higher
than  the target value of 1.5 BV of 6%
brine because of the inability of the brine
system to deliver  a  consistent  brine
dosage. Consistent brine dosages were
obtained  later by reprogramming  to
terminate the batch on flow instead of
time. Table 3 compares the actual chemi-
cal data obtained over the 6-month period
with those estimated for a plant using a
260-BV service period.
  Nitrate leakages obtained by the plant
are in good agreement with the predicted
values. Also, any failure to obtain proper
declassification will give an erroneous
nitrate analysis. The nitrate leakages in
Table 3 are from grab samples for certified
lab analyses and are subject to variations
of sampling and analytical errors.
  The plant Brine Use Factor (BUF) values
(Table 4) are the average monthly values.
This data show that the plant is about 3%
less efficient than predicted. This result
is quite remarkable considering  the  as-
sumptions inherent in the method used
for making these predictions.

Dilute Brine Quantity
  The quantities of both  saturated and
diluted brine are given in Table 5 together
with other quantities used for each of the
6 months.
  The amount of saturated brine is noted
to be approximately 0.09% of the total
water produced, or 0.12% of the amount
treated. The corresponding percentages
for diluted brine are 0.49% and 0.65%,
respectively.
Rinse,  Water Backwash,
and Total Wastewater
  The amounts of water used for rinsii
backwash, and total wastewater are lisl
in Table  5.
  The plant automatically monitors cc
ductivity of rinse water. About 30% exec
rinse water is used because conductar
falls to a constant value at about  20
gal. Rinse water was not reduced duri
this period to allow excess rinsing.
  The total wastewater over the 6-mor
period is 3.39% of the blended water a
4.52% of the treated water.
  Total water recovery is 96.7% over 1
6-month period.
  This high water recovery, which is ev
subject  to improvement,  is one of t
main  advantages of the ion exchan
process over the reverse osmosis proce
for nitrate removal.
Power Consumption
  Daily records of power consumption
the plant have been maintained to obtz
electrical power costs for well operati
and well plus nitrate plant operation. T
Table 3.    Summary Comparison of Actual Chemical With Predicted Data
                        Plant Data
                Estimated*
Date
6-84
7-84
8-84
9-84
10-84
11-84
Averages
Nitrate**
Leakage
2.9
3.2
2.3
0.7
2.9
3.8
2.6
Salt
Ib/ft3
5.94
6.36
6.46
6.48
6.35
6.55
6.35
BUF+
8.3
9.2
11.8
11.4
11.3
9.7
10.3
Nitrate**
Leakage
4.0
3.4
2.7
2.5
2.4
3.3
2.8
Salt
Ib/ft3
5.94
6.36
6.46
6.48
6.35
6.55
6.36
BUF
9.8
9.4
10.8
10.9
10.0
8.8
10.0
*For 260 BV service.
                   Equivalents of Chloride in Fresh Regenerant
+Brine Use Factor =	
                Equivalents of Nitrate Removed from Influent Water
^Concentration of nitrate listed as mg NO3-N/L
   To convert to mg N03/L multiply by 4.43
           Estimates of BUF for Full Bed Use and Partial Bed Use
BUF
Date
6-84
7-84
8-84
9-84
10-84
11-84
Average
260 BV
9.8
9.4
10.8
10.9
10.0
8.8

100% Use
8.9
8.1
8.9
8.5
7.3
7.4

Salt Dose (Ib/ft3)
260 BV
5.94
6.36
6.46
6.48
6.35
6.55

100% Use
5.94
6.36
6.46
6.48
6.35
6.55

% Brine Savings
Potential for
1OO% Bed Use
9.2
13.8
17.4
22.0
27.0
15.9
17.6

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 Table 5.    Secondary Plant Performance Factors
Thousands of
Gallons
Product Water
Date
6-84
7-84
8-84
9-84
10-84
11-84
Totals
% of Blend
% of Treated
Blend
5307
3595
3002
4245
4738
3771
24598
100
133
Treated
3516
2673
2617
3433
3055
3163
18457
75.0
100
Sat.
Brine
4044
3291
3272
4307
3752
4012
22678
0.09
0.12
Water Used, Gal
Dilute
Brine
37670
29270
7710
22300
16620
7190
120760
0.49
0.65
Rinse
Water
80990
68640
62340
77340
67360
77060
433730
1.76
2.35
Backwash
52422
44780
47640
57350
46130
31440
279762
1.14
1.52
Total
Waste
171082
142690
117690
156990
130110
1 15690
834252
3.39
4.52
pressure drop through the ion exchange
system is approximately 10 psi. Power
readings were taken with the well pump-
ing directly into the system and were
compared with readings taken while the
plant was in operation. Of the total power
consumed at the site, 10% was required
for the operation of the plant,  yielding
0.244  kWh  per 1000 gal as the power
requirement for plant operation. Power
for the brine pump and air compressor
are considered negligible.
  The  cost of this power obtained from
the billing of Pacific Gas and Electric Co.
is $0.08183 per kWh, making power cost
for plant operation $0.019967 per 1000
gal, or $19.97 per million gal of blended
water delivered to the system.

Cost  Analyses
  Capital costs for the McFarland plant
are summarized in Table 6.  Costs  are
given for two different vessel  heights.
The 6-ft height accommodates  the 3-ft
bed depth and the 10-ft height accom-
modates a 5-ft bed depth. The cost of the
extra side height is the most economical
way of increasing bed capacity. O&M
costs (Table  7) reflect actual  salt and
power  costs for the 6-month period. The
costs presented for normal plant main-
tenance, miscellaneous costs, and resin
replacement may be changed if firm data
on resin loss can be obtained. No loss of
resin capacity has been detected from
the operating data obtained thus far. The
1 -hr per day operator cost is still believed
to be adequate, since  this is mainly a
record  keeping and inspection effort.
  Table 8 summarizes the total treatment
costs. The amortized annual capital cost
per 1000 gal is based on 100% use of the
1 -mgd capacity. The McFarland plant was
only operated at 13.7% of its full capacity
during  this initial period (see Table 9). In
this case the amortized annual capital
cost per 1000  gal  is  7.30 times  that
 shown in Table 8 or $.832 per 1000 gal.
 As annual  plant production  falls  from
 100% to 0% of full capacity use, this cost
 rises from  $0.114 to infinity.  O&M cost
 per  1000 gal are estimated  to remain
 approximately as given in Table 7 regard-
 less of plant usage.  The high cost  of
 capital amortization of a  partially  used
 plant must  be taken  into consideration
 when assessing the cost impact on the
 consumer.  The true water cost that the
 consumer  must pay  for operating the
 plant at  less than full capacity can  be
 estimated by comparing consumer costs
 with and without the plant.
  True consumer  costs for this report
 reflect the fact that the consumer receives
 water from the plant as  well as  from
 other wells in the system. In this case the
 capital cost associated with water supply
 capital costs in McFarland is the capital
 cost of wells, the distribution system, and
 related facilities and improvements (not
 including a nitrate plant), CS, plus the
 capital costs shown in Table 8, CP. The
 total  consumer  cost of amortizing the
 capital costs (per 1000 gal of water con-
 sumed) by producing a fraction of 1  mgd
 from existing facilities and the remainder
 from the nitrate plant is:
  Total capital cost/1000 gal = (CS + CP)/
 1000 gal.
  where: CS = cost of  wells, distribution
              system, related facilities,
              improvements.
         CP = capital  costs for  nitrate
             plant.
  The additional annual amortized capital
cost that the consumer must  pay for
partial (or full) use of the nitrate plant is
the amortized capital cost, $41,773, for
the nitrate system as shown in Table 8.
  The added cost due to O&M  of the
nitrate plant during this  report period is
0.137 times the O&M cost of Table 7.
  The total added consumer cost during
this report period due to nitrate treatment
of 13.7% of the water supplied to the
system is:
  $/1000 gal = $0.114 + 0.137 x $0.131
  or           $0.162
  These cost analyses will be presented
in more detail when all costs over a 2-year
period of operation are available and will
be discussed in Volume II of this report.
Conclusions and
R ecommendations
  1. The plant was automatically operated
    for a 6-month period and exhibited
    the  following  performance char-
    acteristics averaged over the oper-
    ating period:
    a. Nitrate  leakages  averaged 5.2
       mg/L N03-N (23.2 mg/L N03) in
       a blend of treated and untreated
       water.
    b. The blend  consisted  of 76.1%
       treated water and  23.9%  un-
       treated water.
    c. Brine dosages were  6.36  Ib of
       salt per ft3 of resin, or 2.49 per
       1000 gal of blended water.
    d. Brine efficiencies averaged 10.3
       equivalents of chloride per equi-
       valent  of  nitrate  removed  and
       varied from a low of 8.3 to a high
       of 11.8.
    e. Water recovery was 96.7% of the
       water  pumped. The remaining
       3.3% was  discarded  as waste
       brine and wastewater.
     f. Wastewater  per  1000 gal of
       blended watr consisted of 0.92
       gal of saturated brine (4.9 gal of
       dilute  brine), 17.6 gal of  rinse
       water,  and 11.4 gal of backwash
       water.
  2. Maximum automation  was  used
    successfully to satisfy the minimal
    manpower requirements of a small
    water  system operator. The  plant
    was designed and is being demon-
    strated primarily with the needs of
    small communities in mind where
    wells and distribution systems are
    already in place. The plant operates
    at a well site rather than as a central
    treatment plant.
  3. Raw water composition varied during
    this  period of operation.  Nitrates
    varied from  16.0 to  11.1 mg/L
    N03-N. This provided the opportunity
    to measure the effect of changing
    water  composition on  plant  per-
    formance.
  4. Resin beds were operated at 76%
    capacity during this initial adjust-
    ment period to prevent overruns that
    could occur because of operation
    problems.

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Table ft    Capital Costs for McFarland in 1983
                                                         Vessel Size
Item
I.X. Vessels (3 included)
Onsite construction
Brine tank
Other
Resin 225 ft3 (3 ft depth)
424 ft3 (5 ft depth)
Sub total
Engineering & administration 15%
Total
6'D x 6'H
$ 96,511
81,151
18,700
40,045
35,OOO
$271,407
40.711
$311.118
6'D x WH*
$111.741
81.154
18,700
40,045
56,610
$309,250
46.388
$355,638
* McFarland plant.
Table 7. Operation and Maintenance Costs
Item
Operation (1 hr/day)
Normal O&M. .02X(355,638)
Power, boost pump (.093/kWhj*
Resin replacement (5 yrs)
Salt ($31 .50/ton).
(7O% treated in blend f
Miscellaneous
Total O&M
Annual Cost
$ 4.745
7,113
7,289
1 1.522
14.314
3,000
$ 47.983
$/ 1000 gal
$ 0.013
0.019
0.020
0.032
0.034
0.008
$ 0. 131
*244 million gal based on. 08183C per kWh.
+2490 Ib/'million gal.
Table 8. Total Capital and O&M Costs
Item
Capital costs - $355.638 (20 years @ 10%)
Operation & maintenance
Total
Annual Cost
$41.773
47.983
$89.756
$/ 1000 gal
$0.114
0.131
$0.245
  5. The effect of operating at less than
    100% of  the  bed capacity is esti-
    mated to be  a  decrease  of brine
    efficiency of approximately 18%.
  6. Brine efficiency, nitrate leakage, and
    bed volumes to nitrate breakthrough
    can be accurately predicted from ion
    exchange theory. Computer-based
    programs being developed can simu-
    late effluent histories and are com-
    parable to those  obtained from  the
    plant. They  also give chromato-
    graphic distributions of ions within
    spent beds.
  7. A 3-ft resin bed depth was used
    during this period of operation. A 5-
    ft bed will be used in future tests to
    obtain comparative data.
  8. The power consumed by the plant is
    244 kWh per million gal of blended
    water. This amount is 10% of  the
    total power required for pumping at
    the well site.
  9. Capital costs were $311,118 for a
    plant with the 3-ft-deep resin  bed
    and $355,683 for a plant with a 5-ft
    bed. The total costs are $0.245 per
    1000 gal of blended water for the
    5-ft bed plant (1983 costs). During
    this report period the plant  was
    operated  at  only  13.7%  capacity.
    The overall cost to the McFarland
    community for nitrate removal during
    this period was $0.162 per 1000 gal
    of water consumed.
10. The plant is totally  automatic in
    operation  with automatic  nitrate
    analysis for  monitoring and auto-
    matic shut down if nitrate exceeds
    the MCL in the product water. Com-
    puter printouts of operating data are
    obtained  on a daily  basis  and  if
    alarms occur.
11. Operator tasks are reduced to ap-
    proximately 1 hr per day and include
    routine  inspection, maintenance,
    and recordkeeping.
12. Nitrate removal is economically and
    technically feasible by the ion ex-
    change process. The most undesir-
    able feature is the production and
    disposal of waste brine. At McFarland
    during  this report period, approxi-
    mately 1300 Ib of waste salts were
    disposed of in the plant wastewater
    daily by discharging to the municipal
    wastewater system. If the plant were
    operated 24 hr per day, the daily salt
    discharge would be  2500 Ib  in
    33,000  gal of wastewater. Close
    monitoring of soil and plant condi-
    tions at the disposal site is being
    conducted.
13. Although nitrate removal by the ior
    exchange process  is largely being
    considered as a process adaptable
    for small communities, it is the lattei
    who will  find the waste  disposa
    problems the most difficult to solve
    Improvements in the process ar€
    still required to reduce quantities ol
    waste salts. These can probably be
    accomplished by use of highly selec-
    tive nitrate resins, brine recircula-
    tion, recovery  and separation ol
    sodium nitrate and sodium chloride,
    and close adjustment of plant oper-
    ation to  changes  in  raw watei
    composition.
14. Plant shut downs were due to mal-
    functions of electrical and mechani-
    cal equipment and leaks in plastic
    pipe. All repairs were handled b\
    water company personnel.
15. The adjustment and operation of the
    plant was complex because the same
    microprocessor was used for plam
    control and data collection  and  re-
    porting. Considerable operating time
    was lost as a result of writing anc
    testing the data collection portion o'
    the program. The controller requirec
    programming by ladder logic, which
    is cumbersome as a computer lan-
    guage. A  separate computer is  re-
    commended for data collection at t
    similar installation.
16. Ion chromatography is  satisfactory
    for routine anion analysis and re-
    search, but it definitely requires im-
    provement for continuous on-stream
    plant  monitoring.  Additional  re-
    search on automatic nitrate analysis
    is recommended.
17. Further development of the nitrate
    selective resin is recommended be-
    cause use of a nitrate selective resin
    would  eliminate the possibility of
    nitrate  dumping  and would reduce
    introduction of chloride into  product
    water.
18. Further research on  waste brine
    disposal and brine reuse is recom-

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     mended to eliminate the buildup of
     waste nitrate and other salts in the
     disposal area and underlying ground
     water.
  The full report was  submitted in ful-
fillment of Cooperative Agreement No.
CR808902-02-0 by McFarland  Mutual
Water Company under the sponsorship
of the U.S. Environmental  Protection
Agency.
Tab/e 9.    Summary of Monthly Data

                    Salt Dose*
Date
6-84
7-84
8-84
9-84
10-84
11-84
Averages
Ib/ft3
5.94
6.36
6.46
6.48
6.35
6.55
6.36
Ib/ 1000 gal
of Blend
2.01
2.42
2.89
2.69
2.10
2.82
2.49
% Treated* Nitrate-N lOOOgal
in Blend (mg/L)* in Blend Delivered
66.2
74.0
87.2
80.9
64.5
83.8
76.1
4.8
5.0
5.6
5.3
5.4
5.2
5.2
5.307
3,595
3.002
4,245
4,738
3,771

*Monthly averages.
   Gerald A. Outer is with Boyle Engineering Corporation, Bakersfiled, CA 93302-
     0670.
   Richard Lauch is the EPA Project Officer (see below).
   The complete  report,  entitled  "Nitrate Removal from Contaminated Water
     Supplies: Volume I. Design and Initial Performance of a Nitrate Removal Plant,"
     {Order No. PB  87-145 470/AS; Cost: $18.95, subject to change) will be
     available only from:
           National Technical Information Service
           5285 Port Royal Road
           Springfield, VA 22161
           Telephone: 703-487-4650
   The EPA Project Officer can be contacted at:
           Water  Engineering Research Laboratory
           U.S. Environmental Protection Agency
           Cincinnati, OH 45268

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United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
     BULK RATE
POSTAGE & FEES F
        EPA
   PERMIT No G-3
Official Business
Penalty for Private Use S300
EPA/600/S2-86/115

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