United States
                    Environmental Protection
                    Agency
Air and Energy Engineering
Research Laboratory
Research Triangle Park NC 27711
                    Research and Development
EPA/600/S2-87/007 May 1987
SEPA         Project  Summary
                    Evaluation  of the  Problems
                    Associated with  Application  of
                    Low  Solvent Coatings to
                    Wood  Furniture
                    Carl Uhrmacher
                      The coatings manufacturing industry
                    has advanced the state-of-the-art for
                    producing low volatile organic com-
                    pound (VOC) based finishes for wood
                    furniture. These improved coatings have
                    the potential to overcome earlier objec-
                    tions of the furniture industry to at-
                    tempts to regulate lower VOC emissions
                    in this industry. The objective of this
                    project  was to evaluate a low-VOC
                    finishing system for the manufacture of
                    wood furniture and to compare its per-
                    formance in the manufacturing process
                    to an equivalent conventional solvent
                    based system. The production of furni-
                    ture finished with a conventional sol-
                    vent-based system and several  days
                    production of wood furniture finished
                    with a low-VOC system were observed
                    and evaluated. All furniture was pro-
                    duced under a single contract with the
                    General Services Administration (GSA),
                    and was to be similar in color and style.
                    In the low-VOC system, a waterborne
                    combined toner and washcoat, a cata-
                    lyzed sealer, and a catalyzed topcoat
                    were used in place of part of the normal
                    coatings used in the conventional finish-
                    ing system.  All problems, processing
                    changes, personnel comments, and pro-
                    duction figures were noted and analyzed.
                    The reduction  in  VOC emissions was
                    estimated from consumption data ob-
                    tained during the  observation period.
                    The manufacturing economics, process
                    changes, impacts on the environment,
                    potential effects on worker health, and
                    changes in energy requirements were
                    evaluated for these low-VOC coatings.
  This Project Summary was developed
by EPA's Air and Energy Engineering
Research Laboratory, Research Triangle
Park, NC, to announce key findings of
the research project that Is fully docu-
mented In a separate report of the same
title (see Protect  Report ordering In-
formation at back).

Introduction
  In 1979, the U.S. Environmental Pro-
tection Agency (EPA) issued draft control
technique guidelines for volatile organic
emissions (VOCs) resulting from the
application of coatings in the manufacture
of wood furniture. The industry, as repre-
sented by several trade associations, and
several individual companies objected to
the suggested use of new furniture coat-
ing technology based on the use of water-
borne coatings in lieu of the conventional
solvent-borne coatings.
  Since 1979, the coatings manufacturing
industry has advanced the state-of-the-
art for the production of low-VOC coat-
ings. Their  efforts have improved low-
VOC coatings, including high solids, cata-
lyzed high solids, and waterborne coatings.
These  improved coatings could help to
overcome the earlier objections of the
furniture industry to the use of low-VOC
coatings.
  The  General  Services Administration
(GSA), in cooperation with EPA and the
U.S. Army, awarded a contract to United
Globe Corporation, a division of Turner
Furniture Industries, for the manufacture
of traditional style household wood furni-
ture for use by Army personnel stationed

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overseas. A special clause in this contract
required that 1000 buffets be finished
with  a  low-polluting coating system,
defined  by GSA and EPA to be one that
contains less than 100 Ib VOC/1000 ft2
of surface area finished (45.4 kg/92.9
m2).

Objective
  The objective of this  project was to
determine the effects of using a low-VOC
coating  system in lieu of a conventional
solvent  system  in the manufacture of
comparable or equivalent wood furniture.
The major elements in the manufacturing
process  to  be evaluated in this study
included:
  • Variances  in equipment  require-
    ments, to accommodate the low pol-
    luting system.
  • Variances in the number or sequence
    of processing steps.
  • Manufacturing problems associated
    with the low polluting systems.
  • Variations in labor and energy re-
    quirements.
  • Finishing system effects on process
    economics.
  • Reduction in pollution  achieved by
    use of  the low-VOC coating system
    compared with  use of conventional
    coating systems.
  This report does not present opinions
about the aesthetic quality or commercial
acceptability of the low-VOC finishes
since the primary objective of this project
was to determine the effect of low-VOC
coatings on the manufacturing and fin-
ishing processes. The furniture produced
during this program was required to meet
minimum GSA standards for quality and
color.

Materials and Procedures

Coating Material
  All of the coating materials used in the
low-VOC trials and  in the conventional
GSA finishes are  listed, along with their
density and VOC content, in Table 1.
The Furniture
  The finishing of GSA contract furniture
that was coated with conventional sol-
vent-borne coatings was observed. This
furniture was a mix of the bedroom and
dining room suites produced  with  the
same finish. Buffets were chosen by GSA
to be used  in the trials. One thousand
buffets were produced with the new finish
and were to blend in  with the  non-test
dining room furniture.
Procedures
  No air samples were collected for this
project because of the plant configuration.
It was assumed that all volatile material
eventually was released to the atmo-
sphere,  that total  emissions could be
calculated from density,  and that VOC
content  data could be  determined by
laboratory analysis.

Results

Re/eases to the Atmosphere
  The use of the low-VOC system in this
study reduced  the  amount of VOCs re-
leased to the atmosphere. There was a
40% reduction  based on the EPA labora-
tory analysis of the coating  system. Of
the 50.8 Ib (23 kg) reduction: 59% was
produced by using the waterborne coating
in place  of the washcoat and toner; 12%,
by using the catalyzed sealer; and 23%,
by using the catalyzed topcoat.
  The goal of 100 Ib VOC emitted/1000
ft2 coated was met with this system. The
total was estimated to be 75.7 lb/1000
ft2 (34.3 kg/93 m2), a reduction of 50.8
Ib/1000 ft2 (23 kg/93 m2). The use of the
waterborne coating accounted for 29.9 Ib
(13.6 kg) of this reduction, the catalyzed
                              sealer for 6.1 Ib (2.8 kg), and the catalyzi
                              topcoat for 11.6 Ib (5.2 kg). The resul
                              are summarized in Table 2.
                               So//d Waste
                                There was an increase in the amou
                               of solid waste generated as sludge trapp
                               in the water pan booths after the sprayi
                               of the high solids catalyzed coatings. TF
                               was estimated by plant personnel to be
                               30% increase over the normal conve
                               tional coatings. This is not a major e
                               vironmental problem for this plar
                               because these sludges, which are meti
                               free, can be burned in a  state-approv
                               incinerator.

                               Analysis

                               Waterborne Toner/Washcoat
                                The major problem with the waterbon
                               coating was grain raising caused by tl
                               water in the formulation. This caused tl
                               surface to be rough and  required ext
                               sanding. This also opened the grain ai
                               allowed the wipe stain (filler) to penetra
                               too deeply and produce too dark a cole
                               Extra retarder had to be  added to  tt
                               filler, and the furniture had to be wipe
Table 1.
Coating
Density and VOC Content of Coatings

                 Coating Manufacturer's Lab
                                                            EPA Lab
                              Density
                 Ib/gal.    kg/I
         %VOC
          (wt)
                                               Density
       Ib/gal.     kg/I
                %VOC
                  (wt)
Waterborne

Catalyzed Sealer
with Catalyst'

Catalyzed Lacquer
with Catalysf
                Low-VOC GSA Coating System

                 7.54    0.9035    43

                 7.75    0.9287    73
                  7.88    0.9443
                  7.65
0.9167
64
7.77
7.76

7.65
7.63
0.9308
0.9298

0.9164
0.9148
42.3

71.0
73.9

64.5
68.0
Conventional GSA Coatings
Sap Stair?
Toner
Washcoat
Wipe Stairf
Shade*
Sealer
Lacquer
6.74
6.63
7.00
7.44
6.65
7.10
7.55
0.8076
0.7945
0.8388
0.8915
0.7969
0.8508
0.9047
97
99
92.1
79
98
81
82
6.73
6.63
6.96
7.11
6.70
7.22
7.53
0.8068
0.7942
0.8342
0.8526
0.8034
0.8652
0.9025
97.8
97.6
92.5
83.4
99.0
82.9
78.9
8 Based on laboratory analysis of freshly catalyzed material.
b Same coating used in both systems.

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 Table 2.
VOC Reduction
Coating
GSA Sap Stain"
Toner
Washcoat
GSA Wipe Stain"
GSA Shade Stain"
Sealer
Catalyzed Topcoat
GSA Lacquer
Total VOC used
for conventional
system'
Ib/IOOO ft2
13.4
17.3
17.6
26.7
1.6
22.3
N/A
27.6
Total VOC used
for low-VOC
system'
lb/10OO ft2
10.6 c
j „
27.2
0.7
16.2
16.0
NA
VOC Reduction"
lb/1000 ft2
-2.8
\ -29.9
+O.5
-0.9
-6.1
+16.0
-27.6
Emitted per 1000 ft2

Net VOC reduction
                     126.5
75.7
                                                       -50.8
"Metric conversion: 1 lb/1000 ft2 = 0.0049 kg/m2.
* Coating used by both systems.
with naphtha to remove the excess stain.
The resultant problem with the filler could
be solved, but the grain-raising problem
remained throughout the trial, and proce-
dural changes during the manufacturing
process did not mitigate the problem.

Catalyzed Sealer
  Three problems occurred with this
coating: "setting-up," "orange peel," and
worker complaints about eye irritation
and smell. Setting-up refers to thickening
of the  catalyzed material when stored.
The coating used had a 1 -day pot life, and
the attempt to extend its pot life failed
during the evaluation.
Catalyzed Topcoat
  Two  major problems were observed
with the catalyzed  topcoat:  "bridging"
(i.e., the topcoat along the molding edge
remained wet or tacky after drying in the
oven);  and  worker  complaints  about
blowdown that made working conditions
sticky. Concern was voiced about "print-
ing" (i.e., the soft surface imprinting with
packing material), although there was no
evidence that this occurred. Concern was
also voiced about the ability to strip the
topcoat  if reworking of the finish was
required. This could not be determined
during this evaluation because no pieces
required refinishing.
                             Economic Analysis

                             Coating Cost
                               The low-VOC coating system was less
                             expensive in material costs than conven-
                             tional systems. Using proprietary pricing
                             information, the cost  of the low-VOC/
                             1000 ft2  coated was estimated  to  be
                             $101.03, or $4.59/buffet; the cost of the
                             conventional finish was $129.26/1000
                             ft2 coated, or $5.98/buffet. The resulting
                             material savings for 1000 buffets  were
                             estimated to be $1280 in reduced coating
                             usage.
                              Personnel and Personnel
                              Assignments
                               No additional workers were assigned
                              to the finishing room floor for the low-
                              VOC coating trials. However, floor  in-
                              spectors were used during the test  for
                              wiping or sanding. If this system were to
                              be  permanently introduced, additional
                              workers would be necessary. The labor
                              requirements were estimated to increase
                              by 6%.

                              Production  Rates
                               Production rates for the low-VOC were
                              not changed from the conventional sys-
                              tem.  Line speed was maintained once
                              the  initial adjustments were  made  for
                              introduction of the new coatings.
Equipment
  There was no increase in costs due to
new equipment requirements. All low-
VOC coatings were applied with in-house
equipment. The waterborne coating was
pumped from a local pressure pot and not
supplied from the pump house as  a pre-
caution against possible corrosion.

Energy
  There was no increase  in the oven
temperature during  the low-VOC trial.
The  oven  was maintained at approxi-
mately  110°F (43°C),  and  the  heat
boosters were not used. There were no
increases in energy costs from using the
low-VOC coatings.
  Based on estimates of costs given by
plant management,  there would  be no
overall net increase in cost to the manu-
facturer for this  system because  the
increase in labor would be offset by the
decrease in material  costs.
                              Health and Worker Safety
                               The more toxic or hazardous system
                              cannot be  determined on the  basis of
                              information in the Material Safety Data
                              Sheets alone because there is no estima-
                              tion of worker exposure. However, the
                              low-VOC system  releases less solvents
                              to the workplace because they are, by
                              definition,  lower  in VOC. Despite this,
                              there were worker complaints about eye
                              and throat  irritation when the catalyzed
                              coatings were being used. The  catalysts
                              were p-toluenesulfonic acids, which are
                              known to be mucous membrane irritants.
                              No  heavy  metals are listed  in either
                              system.

                              Conclusions and
                              Recommendations

                              Summary Conclusions
                               The waterborne and catalyzed coatings
                              system used in this evaluation resulted
                              in a 40% reduction of VOC content from
                              the  conventional coatings system. The
                              low-VOC system used approximately 34
                              kg/93 m2  of  surface area coated (76
                              lb/1000 ft2), compared to approximately
                              57 kg VOC/93 m2 for the conventional
                              coatings system (127 lb/1000 ft2). The
                              contract goal of 100 Ib VOC emitted/1000
                              ft2 covered  (45.4 kg/93 m2) was met.
                               • Catalyzed coatings can be used suc-
                                  cessfully  in the furniture manufac-
                                  turing process. The problems noted
                                  during the trial run can be eliminated
                                  by providing additional worker train-
                                  ing, improving ventilation, making

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      minor adjustments to materials, and
      using  properly  adjusted spray
      equipment.
      Catalyzed coatings did reduce VOCs
      by 35% of the total reduction, but
      their use alone would not have been
      sufficient to meet the goal specified
      in the GSA contract, less than 100
      Ib VOC emitted/1000  ft2  covered
      (45.4 kg/92.9 m2).
      The  major factor in achieving the
      contract reduction goals for  VOC
      usage was the use of the waterborne
      toner/washcoat which accounted for
      59% of the total reduction.
      Some  process modifications  from
      conventional operations may be re-
      quired to eliminate the problem of
      grain raising, seeding, and bridging.
      These problems  were successfully
      addressed during  this project to meet
      GSA specifications.
          Carl Uhrmacher is with Carltech Associates, Inc., Columbia, MD 21045.
          Charles Darvin is the EPA Project Officer (see below).
          The complete report, entitled "Evaluation of the Problems Associated with
            Application of Low Solvent Coatings to Wood Furniture," (Order No. PB 87-
            168 746/AS; Cost: $18.95. subject to change) will be available only from:
                 National Technical Information Service
                 5285 Port Royal Road                 .
                 Springfield, VA 22161
                 Telephone: 703-487-4650
          The EPA Project Officer can be contacted at:
                 Air and Energy Engineering Research Laboratory
                 U.S. Environmental Protection Agency
                 Research Triangle Park, NC27711
United States
Environmental Protection
Agency
Onter for Environmental Research
Information
Cincinnati OH 45268
                                                             /
Official Business
Penalty for Private Use $300

EPA/600/S2-87/007
                      0000329    PS
                                                     60604

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