United States Environmental Protection Agency Air and Energy Engineering Research Laboratory Research Triangle Park NC 27711 Research and Development EPA/600/S2-87/007 May 1987 SEPA Project Summary Evaluation of the Problems Associated with Application of Low Solvent Coatings to Wood Furniture Carl Uhrmacher The coatings manufacturing industry has advanced the state-of-the-art for producing low volatile organic com- pound (VOC) based finishes for wood furniture. These improved coatings have the potential to overcome earlier objec- tions of the furniture industry to at- tempts to regulate lower VOC emissions in this industry. The objective of this project was to evaluate a low-VOC finishing system for the manufacture of wood furniture and to compare its per- formance in the manufacturing process to an equivalent conventional solvent based system. The production of furni- ture finished with a conventional sol- vent-based system and several days production of wood furniture finished with a low-VOC system were observed and evaluated. All furniture was pro- duced under a single contract with the General Services Administration (GSA), and was to be similar in color and style. In the low-VOC system, a waterborne combined toner and washcoat, a cata- lyzed sealer, and a catalyzed topcoat were used in place of part of the normal coatings used in the conventional finish- ing system. All problems, processing changes, personnel comments, and pro- duction figures were noted and analyzed. The reduction in VOC emissions was estimated from consumption data ob- tained during the observation period. The manufacturing economics, process changes, impacts on the environment, potential effects on worker health, and changes in energy requirements were evaluated for these low-VOC coatings. This Project Summary was developed by EPA's Air and Energy Engineering Research Laboratory, Research Triangle Park, NC, to announce key findings of the research project that Is fully docu- mented In a separate report of the same title (see Protect Report ordering In- formation at back). Introduction In 1979, the U.S. Environmental Pro- tection Agency (EPA) issued draft control technique guidelines for volatile organic emissions (VOCs) resulting from the application of coatings in the manufacture of wood furniture. The industry, as repre- sented by several trade associations, and several individual companies objected to the suggested use of new furniture coat- ing technology based on the use of water- borne coatings in lieu of the conventional solvent-borne coatings. Since 1979, the coatings manufacturing industry has advanced the state-of-the- art for the production of low-VOC coat- ings. Their efforts have improved low- VOC coatings, including high solids, cata- lyzed high solids, and waterborne coatings. These improved coatings could help to overcome the earlier objections of the furniture industry to the use of low-VOC coatings. The General Services Administration (GSA), in cooperation with EPA and the U.S. Army, awarded a contract to United Globe Corporation, a division of Turner Furniture Industries, for the manufacture of traditional style household wood furni- ture for use by Army personnel stationed ------- overseas. A special clause in this contract required that 1000 buffets be finished with a low-polluting coating system, defined by GSA and EPA to be one that contains less than 100 Ib VOC/1000 ft2 of surface area finished (45.4 kg/92.9 m2). Objective The objective of this project was to determine the effects of using a low-VOC coating system in lieu of a conventional solvent system in the manufacture of comparable or equivalent wood furniture. The major elements in the manufacturing process to be evaluated in this study included: • Variances in equipment require- ments, to accommodate the low pol- luting system. • Variances in the number or sequence of processing steps. • Manufacturing problems associated with the low polluting systems. • Variations in labor and energy re- quirements. • Finishing system effects on process economics. • Reduction in pollution achieved by use of the low-VOC coating system compared with use of conventional coating systems. This report does not present opinions about the aesthetic quality or commercial acceptability of the low-VOC finishes since the primary objective of this project was to determine the effect of low-VOC coatings on the manufacturing and fin- ishing processes. The furniture produced during this program was required to meet minimum GSA standards for quality and color. Materials and Procedures Coating Material All of the coating materials used in the low-VOC trials and in the conventional GSA finishes are listed, along with their density and VOC content, in Table 1. The Furniture The finishing of GSA contract furniture that was coated with conventional sol- vent-borne coatings was observed. This furniture was a mix of the bedroom and dining room suites produced with the same finish. Buffets were chosen by GSA to be used in the trials. One thousand buffets were produced with the new finish and were to blend in with the non-test dining room furniture. Procedures No air samples were collected for this project because of the plant configuration. It was assumed that all volatile material eventually was released to the atmo- sphere, that total emissions could be calculated from density, and that VOC content data could be determined by laboratory analysis. Results Re/eases to the Atmosphere The use of the low-VOC system in this study reduced the amount of VOCs re- leased to the atmosphere. There was a 40% reduction based on the EPA labora- tory analysis of the coating system. Of the 50.8 Ib (23 kg) reduction: 59% was produced by using the waterborne coating in place of the washcoat and toner; 12%, by using the catalyzed sealer; and 23%, by using the catalyzed topcoat. The goal of 100 Ib VOC emitted/1000 ft2 coated was met with this system. The total was estimated to be 75.7 lb/1000 ft2 (34.3 kg/93 m2), a reduction of 50.8 Ib/1000 ft2 (23 kg/93 m2). The use of the waterborne coating accounted for 29.9 Ib (13.6 kg) of this reduction, the catalyzed sealer for 6.1 Ib (2.8 kg), and the catalyzi topcoat for 11.6 Ib (5.2 kg). The resul are summarized in Table 2. So//d Waste There was an increase in the amou of solid waste generated as sludge trapp in the water pan booths after the sprayi of the high solids catalyzed coatings. TF was estimated by plant personnel to be 30% increase over the normal conve tional coatings. This is not a major e vironmental problem for this plar because these sludges, which are meti free, can be burned in a state-approv incinerator. Analysis Waterborne Toner/Washcoat The major problem with the waterbon coating was grain raising caused by tl water in the formulation. This caused tl surface to be rough and required ext sanding. This also opened the grain ai allowed the wipe stain (filler) to penetra too deeply and produce too dark a cole Extra retarder had to be added to tt filler, and the furniture had to be wipe Table 1. Coating Density and VOC Content of Coatings Coating Manufacturer's Lab EPA Lab Density Ib/gal. kg/I %VOC (wt) Density Ib/gal. kg/I %VOC (wt) Waterborne Catalyzed Sealer with Catalyst' Catalyzed Lacquer with Catalysf Low-VOC GSA Coating System 7.54 0.9035 43 7.75 0.9287 73 7.88 0.9443 7.65 0.9167 64 7.77 7.76 7.65 7.63 0.9308 0.9298 0.9164 0.9148 42.3 71.0 73.9 64.5 68.0 Conventional GSA Coatings Sap Stair? Toner Washcoat Wipe Stairf Shade* Sealer Lacquer 6.74 6.63 7.00 7.44 6.65 7.10 7.55 0.8076 0.7945 0.8388 0.8915 0.7969 0.8508 0.9047 97 99 92.1 79 98 81 82 6.73 6.63 6.96 7.11 6.70 7.22 7.53 0.8068 0.7942 0.8342 0.8526 0.8034 0.8652 0.9025 97.8 97.6 92.5 83.4 99.0 82.9 78.9 8 Based on laboratory analysis of freshly catalyzed material. b Same coating used in both systems. ------- Table 2. VOC Reduction Coating GSA Sap Stain" Toner Washcoat GSA Wipe Stain" GSA Shade Stain" Sealer Catalyzed Topcoat GSA Lacquer Total VOC used for conventional system' Ib/IOOO ft2 13.4 17.3 17.6 26.7 1.6 22.3 N/A 27.6 Total VOC used for low-VOC system' lb/10OO ft2 10.6 c j „ 27.2 0.7 16.2 16.0 NA VOC Reduction" lb/1000 ft2 -2.8 \ -29.9 +O.5 -0.9 -6.1 +16.0 -27.6 Emitted per 1000 ft2 Net VOC reduction 126.5 75.7 -50.8 "Metric conversion: 1 lb/1000 ft2 = 0.0049 kg/m2. * Coating used by both systems. with naphtha to remove the excess stain. The resultant problem with the filler could be solved, but the grain-raising problem remained throughout the trial, and proce- dural changes during the manufacturing process did not mitigate the problem. Catalyzed Sealer Three problems occurred with this coating: "setting-up," "orange peel," and worker complaints about eye irritation and smell. Setting-up refers to thickening of the catalyzed material when stored. The coating used had a 1 -day pot life, and the attempt to extend its pot life failed during the evaluation. Catalyzed Topcoat Two major problems were observed with the catalyzed topcoat: "bridging" (i.e., the topcoat along the molding edge remained wet or tacky after drying in the oven); and worker complaints about blowdown that made working conditions sticky. Concern was voiced about "print- ing" (i.e., the soft surface imprinting with packing material), although there was no evidence that this occurred. Concern was also voiced about the ability to strip the topcoat if reworking of the finish was required. This could not be determined during this evaluation because no pieces required refinishing. Economic Analysis Coating Cost The low-VOC coating system was less expensive in material costs than conven- tional systems. Using proprietary pricing information, the cost of the low-VOC/ 1000 ft2 coated was estimated to be $101.03, or $4.59/buffet; the cost of the conventional finish was $129.26/1000 ft2 coated, or $5.98/buffet. The resulting material savings for 1000 buffets were estimated to be $1280 in reduced coating usage. Personnel and Personnel Assignments No additional workers were assigned to the finishing room floor for the low- VOC coating trials. However, floor in- spectors were used during the test for wiping or sanding. If this system were to be permanently introduced, additional workers would be necessary. The labor requirements were estimated to increase by 6%. Production Rates Production rates for the low-VOC were not changed from the conventional sys- tem. Line speed was maintained once the initial adjustments were made for introduction of the new coatings. Equipment There was no increase in costs due to new equipment requirements. All low- VOC coatings were applied with in-house equipment. The waterborne coating was pumped from a local pressure pot and not supplied from the pump house as a pre- caution against possible corrosion. Energy There was no increase in the oven temperature during the low-VOC trial. The oven was maintained at approxi- mately 110°F (43°C), and the heat boosters were not used. There were no increases in energy costs from using the low-VOC coatings. Based on estimates of costs given by plant management, there would be no overall net increase in cost to the manu- facturer for this system because the increase in labor would be offset by the decrease in material costs. Health and Worker Safety The more toxic or hazardous system cannot be determined on the basis of information in the Material Safety Data Sheets alone because there is no estima- tion of worker exposure. However, the low-VOC system releases less solvents to the workplace because they are, by definition, lower in VOC. Despite this, there were worker complaints about eye and throat irritation when the catalyzed coatings were being used. The catalysts were p-toluenesulfonic acids, which are known to be mucous membrane irritants. No heavy metals are listed in either system. Conclusions and Recommendations Summary Conclusions The waterborne and catalyzed coatings system used in this evaluation resulted in a 40% reduction of VOC content from the conventional coatings system. The low-VOC system used approximately 34 kg/93 m2 of surface area coated (76 lb/1000 ft2), compared to approximately 57 kg VOC/93 m2 for the conventional coatings system (127 lb/1000 ft2). The contract goal of 100 Ib VOC emitted/1000 ft2 covered (45.4 kg/93 m2) was met. • Catalyzed coatings can be used suc- cessfully in the furniture manufac- turing process. The problems noted during the trial run can be eliminated by providing additional worker train- ing, improving ventilation, making ------- minor adjustments to materials, and using properly adjusted spray equipment. Catalyzed coatings did reduce VOCs by 35% of the total reduction, but their use alone would not have been sufficient to meet the goal specified in the GSA contract, less than 100 Ib VOC emitted/1000 ft2 covered (45.4 kg/92.9 m2). The major factor in achieving the contract reduction goals for VOC usage was the use of the waterborne toner/washcoat which accounted for 59% of the total reduction. Some process modifications from conventional operations may be re- quired to eliminate the problem of grain raising, seeding, and bridging. These problems were successfully addressed during this project to meet GSA specifications. Carl Uhrmacher is with Carltech Associates, Inc., Columbia, MD 21045. Charles Darvin is the EPA Project Officer (see below). The complete report, entitled "Evaluation of the Problems Associated with Application of Low Solvent Coatings to Wood Furniture," (Order No. PB 87- 168 746/AS; Cost: $18.95. subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road . Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Air and Energy Engineering Research Laboratory U.S. Environmental Protection Agency Research Triangle Park, NC27711 United States Environmental Protection Agency Onter for Environmental Research Information Cincinnati OH 45268 / Official Business Penalty for Private Use $300 EPA/600/S2-87/007 0000329 PS 60604 ------- |