United States
                  Environmental Protection
                  Agency
Water Engineering
Research Laboratory
Cincinnati OH 45268
                  Research and Development
EPA/600/S2-87/014  June 1987
&EPA         Project Summary
                   Reduction  of Total  Toxic
                   Organic Discharges and  VOC
                   Emissions from Paint  Stripping
                   Operations  Using  Plastic Media
                   Blasting
                  C. D.Wolbach and C. McDonald
                    Three depainting methods were
                  compared for their ability to strip
                  Army communications  shelters:
                  chemical stripping, sandblasting, and
                  plastic media blasting (PMB). Each
                  process was studied with respect to
                  the economics, the environmental
                  impact, and the  quality of the
                  product Currently,  large pieces of
                  military  equipment constructed of
                  various  alloys and  composite
                  materials are either sandblasted or
                  chemically stripped. These methods
                  have economic and environmental
                  drawbacks. PMB is being  evaluated
                  by the U.S. Air Force for depainting
                  military  aircraft, and is  currently
                  being introduced  to commercial
                  aviation. The purpose of this study
                  was to determine if the PMB method
                  is   applicable   to    Army
                  communications  shelters and
                  whether it would be advantageous
                  for the  Army to convert to this
                  procedure both from the perspective
                  of process efficiency  and pollution
                  reduction.
                    Chemical   stripping    of
                  communications  shelters was
                  studied at McClellan Air Force Base,
                  Sacramento  Air Logistics Center
                  (SAALC). Sandblasting and PMB
                  were  studied at  the Sacramento
                  Army  Depot  (SAAD). Each process
                  was studied for  paint  removal
                  efficiency, surface quality equipment
                  requirements, labor and material
 costs, and quantities and type of
 waste pollutants generated.
  The PMB process was determined
 superior to the chemical  stripping
 process and marginally better than
 sandblasting based upon  the
 evaluation criteria.  This  report
 presents study results of  the three
 methods evaluated and  compares
 their respective efficiencies,
 processing  costs,  and  waste
 generation.
  This  Project  Summary was
 developed by EPA's Water Engineering
 Research Laboratory, Cincinnati, OH,
 to announce key findings  of the
 research project  conducted in
 cooperation with the U.S. Army Toxic
 and Hazardous Materials Agency and
 is fully documented in a separate
 report of the same title (see Project
 Report ordering information at back).

 Introduction
  Until  recently there have been three
 main methods for depainting large
 equipment - sandblasting, vegetable-
 matter blasting, and chemical stripping.
 Vegetable-matter blasting  has
 decreased significantly in use because it
 generates dust with a high explosive
 potential and does not perform  well
 against many of  the newer paints.
 Sandblasting cannot be used on many
 composites and is very difficult to use on
 soft alloys and light, thin  materials.
 Chemical stripping generates large

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quantities of contaminated waste waters
that are classified  as hazardous  under
the  Resource  Conservation  and
Recovery  Act (RCRA). Plastic Media
Blasting (PMB) has been identified as a
viable paint removal method for aircraft
and other equipment constructed of soft
metal  alloys such  as  aluminum alloys.
Ths report presents the results of a study
comparing the technical  performance,
the economics, and the environmental
costs  of PMB. chemical stripping,  and
sandblasting.
   EPA  has promulgated  an  effluent
regulation governing  the  discharge of
liquid  waste from   metal-finishing
operations.  Under RCRA other  forms of
waste discharge  have also come under
increasing regulatory  pressure including
paint-stripping discharges. The  U.S.
Army  operates  several metal-finishing
facilities that  have  large  depainting
operations.  Thus,  the  Army  is
investigating  methods  of reducing
hazardous waste from  these facilities.
The U.S. Army  Toxic  and  Hazardous
Materials Agency  jointly  conducted  a
study with  EPA specifically  for  the
purpose of determining  if PMB could be
a  viable substitute in  performance  and
environmental safety for  the Army's
paint-stripping  processes now used  for
U.S. Army communications shelters.
   The  study of  the  various paint-
removing methods took place  between
July  and   November  1985.  The
observations of chemical stripping were
held  at  McClellan  Air  Force  Base
(SAALC) between July  24 and  July 26,
1985.  The observations of sandblasting
and demonstration test  of the PMB
process were held  between October 23
and  November 1,  1985,  at  the
Sacramento Army Depot  (SAAD).  The
same type of equipment was depainted
at both facilities.
Conclusions and
Recommendations
• PMB process is an economically and
  environmentally viable alternative
  technology to chemical  stripping and
  sandblasting for  depainting  major
  pieces  of equipment fabricated from
  aluminum.  In particular,  it is a viable
  and desirable  replacement for the
  current methods of depainting military
  communication shelters,  which are
  typically minimally corroded aluminum.
• PMB's economic  superiority  to
  sandblasting is  predominate only when
  the hand  sanding  necessary  with
  sandblasting  is   taken   into
  consideration. PMB generates a much
  smaller volume of waste  in a more
  easily  handled form  than  does
  sandblasting or chemical stripping.
• The economics of the  PMB process
  are strongly dependent on the recycle
  rate of the media through the process.
• PMB will  not clean  heavy corrosion
  (such as rust).
• The PMB process requires a  slightly
  higher skill level than  sandblasting.
• Although the plastic media is normally
  considered inert, it is recommended
  that a study be  undertaken to establish
  the toxicity and hazard potential of the
  dust from the PMB process.
• Several other questions with respect to
  treatability  should also be addressed.
  They include:
  -  Can  the waste material  be
    incinerated?
  -  What  are   the  products  of
    incineration?
  -  Can heavy metals from the entrained
    paint  waste  be  pacified  or
    recovered?
  -  Can the waste material be cofired as
    a fuel supplement?

Process Descriptions
  The project was conducted in two
phases. The first  phase  entailed
preparing a summary of current activity
in  the  PMB field. The  second  phase
included a  comparative  study  of  three
major  methods   of  depainting  army
communications shelters.
  In Phase II, observations were  made
on each depainting process as it was
applied to  similar  communications
shelters. A list of the equipment, the area
depainted, and the time required is given
in  Table  1.   Small  communications
shelters resemble pickup campers and
measure approximately 1.8 m long by 1.8
m  wide by 2.0   m tall. Medium-size
shelters resemble a large box  on  skids
measuring approximately 3.5 m  long by
2.1  m  wide by  2.0  m  tall. Both  size
shelters are constructed of an aluminum
composite laminate with  an outer skin
thickness of about 1.0 mm and an inner
skin  thickness of  0.8 mm.  The core is
foamed plastic resin to which the skins
are bonded.
  Chemical stripping involves applying a
liquid solvent  to the object  by spraying,
painting, or dipping.  The  stripper  is
allowed to set until the paint softens. The
softened paint  is then removed either by
scrubbing with brushes or spraying with
high pressure water. The process  is
completed when  the surface  has been
 Table 1.     Equipment Cleaned in Project

                                 Equipment Item
         Total Area Cleaned (m2)     Total Clean Time (min)
                  Rate (m2/min)
Chemical Stripping


Sandblasting





Hand Sanding

PMB




1"
2
3
4
5
6"
7
8'
9
10
11
12"
13
14
IS"
16"
31.8
16.8
35.9
17.6
17.6
17.6
22.2
22.2
22.2
6.6
3.35
61.0
33.0
33.0
68.8
33.0
702
1126
1345
24.4
26.7
66.0
33.0
67.3
23.8
97.1
50.0
440
221
230
258
160
0.045
0.015
0.027
0.725
0.662
0.268
0.673
0.330
0.934
0.068
0.067
0.139
0.150
0.144
0.266
0.206
   * Item painted in camouflage pattern.

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cleaned to the bare metal, rinsed, and
dried. The water used  to  wash off  the
paint  and stripper is one  of the waste
products from  this process.  The  liquid
waste will contain high  levels  of  toxic
organic chemicals  as  well  as  paint
sludge. It is also estimated that  >90% of
the solvents  in  chemical paint stripper
volatilize to  the air.  Thus  the  chemical
stripping process  results in  air, water,
and solid waste pollution.
   Sandblasting  is  the  process  of
impacting sand onto  a surface using
pneumatic pressure.  Sand  is usually
blasted at about 4.9  to  5.6  kg/cm2
pressure when  used on aluminum.
Sandblasting  relies  on  the  abrasive
nature of the sand  to  break the  paint
layer and erode  the  paint from  the
substrate. The residual sand and paint
dust  combination  is  collected  and
disposed of in landfills.  Dependent upon
the concentration of toxic metal  pigments
in the sand, it  may be  considered a
hazardous  waste.  An  additional
environmental contaminant  is suspended
dust that may escape the blasting facility.
   PMB  is  similar  to sandblasting
although blasting takes  place at a much
lower pressure (1.4 to 2.8  kg/cm2). The
blasted  media  can  be  recovered  and
recycled,  thus leaving  for disposal a
residue of only paint dust and chips and
a few percent by weight of blasted media
from  attrited  media  dust.  The  residue,
however,  is a  dry solid that  must be
treated  as  a  hazardous  waste.  The
volume  of waste  is  significantly lower
                            than that generated during sandblasting
                            or chemical stripping.

                            Results
                               A summary of results of the study
                            based  on area cleaned, process costs,
                            waste  generated, and  cleaning  rate (in
                            m2/min) is presented in Table 2. Waste
                            disposal  quantities  were  estimated by
                            measuring  the  amount  of  waste
                            generated  and normalizing  to  100 m2
                            depainted. These costs were obtained by
                            contacting disposal  companies.  The
                            results are shown in Table  3.  Finally,
                            Table 4 presents the results of chemical
                            analysis for heavy metals of the solids
                            from sandblasting and  PMB.  The  high
                            levels of chromium, lead, and zinc mark
                            the paint  waste  and  are the items of
                            concern which warrant additional study.
                               The  full report was  submitted in
                            fulfillment of Contract  No.  68-02-3993
                            by Acurex  Corporation,  under  the
                            sponsorship of the U.S.  Environmental
                            Protection Agency.
 Table 2.     Summary of Results

  Process
                        Area (m2)
Cost (S/100 m2)
Waste (kg/100m2)
Rate (m2/min)
  Chemical Stripping

  Sandblasting

  Plastic Media
                          85

                         120

                         229
    4,856

      818

      634
    95,500

       545

       120
    0.029

    0.53"

    0.18
   * Does not include required hand sanding.
 Table 3.

  Method
Waste Costs by Process for 100 m2
                               Waste Product
              Amount (per 100 m2)
                 Cost of Disposal ($/iOO m2)
  Chemical Stripping

  Sandblasting
  PMB
                                  Water
                                  Sludge
                                 Sand/Paint
                                 PMB/Paint
                   95,000 L
                     550 L

                     545kg

                     120 kg
                            120"
                            I12t

                             6.4*

                             17.5§
   " 0.125?/L(0.50/gal).
   t $35/175 L drum.
   *$2.100 for90 tons.
   § $35/175 L (50 gal drum with a plastic media density of 1.5 kg/I).

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Table 4.    Chemical Analysis of Sand, Clean PMB, and Waste Samples (mg/kg) for Heavy Metals.
Average PMB t
Clean Sand Used Sand Clean PMB PMB Floor Dust Tunnel Dust" "
Antimony < 0.2 2.4 < 1 4 13
Arsenic 1.8 1 < 1 < 1 < i
Cadmium < 0.2 28 5 16 16
Chromium 7.4 240 5 72 120
Copper 3.8 6.6 2 4 4
Lead 1.2 160 < 1 64 330
Mercury < 0.05 0.75 < 0.01 < 0.01 0.2
Nickel 5.2 8.6 37 81 30
Silver < 0.02 1.8 < 1 < 1 < 1
Zinc 4.8 340 490 570 980
* Fines collected in air vent.
C. D. Wolbach and C. McDonald are with Acurex Corporation, Mountain View,
CA 94039.
Charles Darvin is the EPA Project Officer (see below).
D. E. Renard is the Army Project Officer (see below).
The complete report, entitled "Reduction of Total Toxic Organic Discharges and
VOC Emissions from Paint Stripping Operations Using Plastic Media Blasting, "
(Order No. PB 87-154 4801 AS; Cost: $18.95, subject to change) will be
available only from:
National Technical Information Service
5285 Port Royal Road
Springfield. VA 22161
Telephone: 703-487-4650
The EPA Project Officer can be contacted at:
Water Engineering Research Laboratory
U.S. Environmental Protection Agency
Cincinnati, OH 45268
The Army Project Officer can be contacted at:
U.S. Army Toxic and Hazardous Materials Agency
Aberdeen Proving Ground, MD 21010

United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
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