United States
                    Environmental Protection
                    Agency
 Water Engineering
 Research Laboratory
 Cincinnati OH 45268
                    Research and Development
 EPA/600/S2-87/107 Apr. 1988
&ERA          Project Summary
                   Treatment of Municipal
                   Wastewaters  by  the  Fluidized
                    Bed  Bioreactor Process
                    0. Karl Scheible and Gary M. Grey
                     A 2-year, large-scale pilot investiga-
                    tion was conducted at  the City of
                    Newburgh Water  Pollution Control
                    Plant, Newburgh, NY, to  demonstrate
                    the application of the fluidized  bed
                    bioreactor process to the  treatment of
                    municipal  wastewaters.  The  reactor
                    was 1.2 m wide, 1.8m  long, and 6
                    m high, with a typical active  bed
                    volume of 9 m3. The bed  medium was
                    quartzite sand with a nominal diameter
                    of 0.5 mm. Oxygenation  was accom-
                    plished by a device installed  below
                    grade (providing approximately 14m
                    static head); the oxygen source was on-
                    site liquid  oxygen tanks. The waste-
                    water feed was primary effluent drawn
                    from the main plant.
                     The experimental effort investigated
                    the ability of the process to treat
                    municipal  wastewater to secondary
                    levels. Process design elements such as
                    removal rates,  temperature effects,
                    oxygen transfer rates, oxygen require-
                    ments, sludge  production, and  bed
                    maintenance  and control  were evalu-
                    ated. Additionally, the studies  evalu-
                    ated the stability of the process under
                    high hydraulic peak loads typical of
                    combined sewer systems.
                     The plant primary effluent had an
                    average 5-day  biochemical oxygen
                    demand (BOD) of 103 mg/L, a  chem-
                    ical oxygen demand (COD) of 287
                    mg/L, and an average total suspended
                    solids (TSS) of 109 mg/L. An organic
                    loading rate of 0.2 to 0.3 gm BOD/gm
                    volatile suspended solids/day  is sug-
                    gested in  order to  meet secondary
                    treatment  levels. Suspended  solids
                    removals are relatively low through the
                    reactor; the results indicate that final
                    clarification would be required for the
plant to meet a 30 mg/L TSS limita-
tion. The oxygenator exhibited good
performance (greater than 80% oxygen
transfer) at gas to liquid ratios less than
0.04.
  The system exhibited good stability
under high short-term peak hydraulic
loadings.  Maximum to  average raw
flow ratios up to 5 could be handled
without bed washout. Special reactor
modifications to yield an expanded
upper section allowed a ratio as high
as 10 to 1 without loss of the bed. The
system exhibited relatively quick recov-
ery to normal treatment efficiency after
the hydraulic surges.
  Applications appropriate to the pro-
cess are for secondary treatment and
as a roughing  treatment process  in
plant upgrades.
  This Project Summary was devel-
oped  by  EPA's Water Engineering
Research Laboratory, Cincinnati, OH,
to announce  key findings of the
research project that is fully docu-
mented in a separate report of the same
title (see Project  Report  ordering
information at back).

Introduction
  Fluidized biological reactors represent
a newly developed and innovative tech-
nology that combines the advantages of
activated sludge  and trickling filtration.
It attempts to combine the efficiency of
the suspended growth system with the
stability and efficient operation of the
attached growth process. Within the
fluidized bed reactor,  a  fixed film  of
biologic growth is allowed to develop on
the surface of a granular medium, such
as sand. Wastewater, which  has been
oxygenated, flows upward through the

-------
medium at velocities sufficient to expand
the bed. This expansion, or fluidization,
occurs when the drag due to the upward
fluid velocity  is greater than the down-
ward force due to gravity. The fluidization
separates  the particles and  allows
microorganisms to attach and  grow on
all surfaces of the medium. Thus, the very
large surface area available can produce
high volatile solids concentrations, often
several times greater than in suspended
growth  reactors. The attachment of
microorganisms to the  medium  also
reduces subsequent requirements  for
wastewater clarification.
  A  portion of the effluent stream is
recycled; the ratio of recycle to raw flow
affects  both  column  expansion and
oxygen transfer, and often serves as a
process control parameter. In the major-
ity of reported studies, the reactors had
been operated on constant flow regimes,
with recycle ratios ranging from zero to
three for municipal sewage. The recycle
mode can also provide stability in appli-
cations  with  high  influent hydraulic
variability.
  Control of the biomass  film thickness
and sludge wasting are accomplished by
a sand-biomass separation device. This
generally operates  by shearing  the
biomass from  the sand, separating the
sludge from the sand, then returning the
sand to the reactor.
  One advantage of the  fluidized  bed
process is its reduced land area require-
ment, due to its ability to carry a high
biomass  inventory.  Typical  volumetric
organic loading rates of 3 to 20 kg BOD/
m3-d and mass organic loading rates -of
0.2 to 2.0 kg BOD/kg VSS-d (where VSS
is  volatile suspended solids) have been
reported. Typical rates for conventional
activated sludge treatment are 0.3 to 2
kg BOD/m3-d and 0.2 to 0.6 kg BOD/kg
VSS-d, respectively.
  In  this project a  large-scale pilot study
was  conducted at the Newburgh,  NY,
Water Pollution Control Plant to inves-
tigate the application of the fluidized bed
bioreactor process to  the treatment of
municipal wastewaters. The study was
directed to the system's ability to achieve
secondary treatment levels of 30 mg/L
TSS  and BOD, and its stability under the
hydraulic variability associated with a
plant receiving combined sanitary  and
storm wastewaters. A large-scale Dorr-
Oliver Oxitron* pilot plant was set up on-
* Mention of trade names or commercial products
 does not constitute endorsement or recommenda-
 tion for use.
site  and continuously  monitored for
treatment performance; specific studies
and tasks were also directed to assessing
the unit  operations that comprise the
process.

Program Objectives and Scope
of Work
  The study  included the installation of
a fluidized bed bioreactor pilot system.
This system  was operated over a period
of approximately 18  months, receiving
settled primary effluent  from the New-
burgh  Water  Pollution  Control  Plant.
Sampling of influent, effluent, and the
reactor was conducted  to assess per-
formance under variable loading condi-
tions and to  evaluate bed stability.
Specific task elements  addressed  bed
maintenance requirements,  solids  set-
tleability, oxygenation capacity, and bed
wasting and sand-biomass  separation
procedures.
  The objectives of the program are as
follows:
  1.  To demonstrate the ability of the
     fluidized  bed bioreactor process to
     achieve secondary treatment levels
     (30 mg/L TSS and BOD);

  2.  To  assess the  stability of  the
     process and its ability to handle the
     highly  variable  hydraulic  loads
     characteristic  of  a   combined
     sanitary-stormwater  collection
     system  during rainfall  runoff
     events;

  3.  To  evaluate  the  operation  and
     maintenance  requirements of the
     fluidized  bed process as applied to
     the treatment of a municipal treat-
     ment plant primary effluent;

  4.  To define and establish the major
     process parameters that influence
     the design and  operation of the
     fluidized bed reactor, such  as
     hydraulic and organic  loading
     rates, oxygen transfer and utiliza-
     tion efficiencies,  biomass-sand
     separation efficiency, bed control,
     sludge production, and  wasting
     requirements; and

  5.  To develop cost information for the
     fluidized bed process relative to its
     application to  municipal waste-
     waters.

Description of Facilities
  The fluidized bed pilot plant facility was
located at the Newburgh Water Pollution
Control Plant, Newburgh, NY. The city is
approximately 100 kilometers (60 miles)
north of  New York City. The treatment
plant is a conventional secondary acti-
vated sludge facility, treating domestic
and industrial wastes,  and discharging
to the Hudson River. The plant services
a  population of approximately 20,000;
industrial inputs are  primarily dye mills
and commercial laundry wastewaters.


Description of the Pilot Plant
  The Oxitron  pilot  plant  was a  skid
mounted, field assembled plant designed
by  Dorr  Oliver, Inc., Stamford, CT, to
demonstrate the capabilities of fluidized
bed reactors. This same  system  had
previously  been  used  to demonstrate
nitrification  of domestic wastewaters at
the Greenwich Wastewater Treatment
Plant in Greenwich, CT. The facility was
situated  in  an  area of the Newburgh
Water Pollution Control Plant that had
been set aside for future expansion.
  Figure 1 presents a process schematic
of the pilot plant showing all major unit
operations.  The 1,900-L influent head
tank  located near the primary effluent
channel  was consistently fed by one of
two submersible pumps. Primary effluent
was  pumped  to  the  tank at a  rate
generally in excess of  1,500  L/min.
Excess flow passed through an overflow
pipe  back  into the primary  effluent
channel. A  float valve  was provided to
activate a low level alarm and automat-
ically shut off the pilot plant system if
the level of  the head tank dropped as a
result of interrupted  feed supply. A 25-
cm-diameterPVC pipe supplied feed from
the  head tank to the  influent pump
located in the  pilot plant  building. The
influent pump was an Aurora, 23-cm, 15-
hp centrifugal  pump with a pressure
relief  bypass  loop.  Normal  operating
pressure of this pump was 2.8  to 3.2
kg/cm2.  Maximum flow was approxi-
mately 950 L/min, depending on system
pressure.
  The raw  wastewater  feed was then
passed  through a rotary strainer to
remove  large  solids and  protect the
reactor distributor nozzles from plugging.
The strainer was backwashed twice per
day or  more  frequently  as  needed.
Pressure gauges on both sides  of the
strainer  were used to  monitor its per-
formance.  Generally,  under normal
operation conditions, a pressure drop of
under 0.2 kg/cm2 was maintained.

-------
                                      VORTEX
                                      Flow
                                      Meters
                                      (to flow
                                      recorder)
                                                   Self-priming Centrifugal Pump
                                                              (rudder impeller)
                                              D.O. Probe
                                              (Controls
                                              Oi feed)
 Submersible
 Pump (2) \
                      /  //DSM
                    /^-Screen
                    ^-'   (Solids/Sand
                           Separation)

                             Waste
                             Biomass
                                                                       Waste
                                                                       Tank
         Primary
         Effluent
         Channel
                           Rotostrainer
                           Backwash
                                                                  Waste

                                                  Oxygenator
                                                  Pit
                                                  (29' Depth—below grade)
Figure 1.    Process schematic of the fluidized bed pilot facility.
  Feed then passed through a Keystone
control valve and Ball Vortex flow meter.
The control  valve could be manually or
automatically  operated. The automatic
mode was used to provide diurnal flow
variation similar to that of the Newburgh
treatment plant flow. A signal from the
Newburgh plant flow meter was used to
drive the pilot plant control valves. The
flow meter was a circulating cage type
that proved to be very reliable. Occasion-
ally, the flow meters were electronically
calibrated and balanced.  The  meters
were  also connected  to remote  flow
recorders and totalizers at  the control
panel.
  The raw wastewater, combined  with
the recycle waters, then flowed to the
oxygenator where  oxygen gas  was
injected to satisfy oxygen requirements
for  aerobic  biological  treatment.  The
oxygenator provided gas/liquid  contact
to maximize dissolution of oxygen into
the influent  wastewater. At the inlet to
the oxygenator, the  combined influent
and recycle  streams were mixed under
pressure  with gaseous oxygen.  The
oxygenator was below grade to provide
approximately 14 m  of static head (the
difference between the top of the reactor
and the bottom of the oxygenator pit).
This pressure enhanced oxygen transfer
and allowed dissolved oxygen levels of
up  to  60  mg/L  to  be achieved.  The
internal  design  of the  oxygenator
ensures that gas/liquid contact is max-
imized for efficient oxygen transfer. The
gas recycle loop allows recirculation of
undissolved oxygen.
  The  biological support medium  was
quartzite sand with a median particle size
of approximately 0.50 mm.  At start-up,
the reactor was charged with 4 m3 of
medium. Sand was  also added to  the
reactor throughout the study to compen-
sate for attrition losses.
  The reactor was a 1.2 m by 1.8 m steel
tank, 6.1 m high. The tank was comprised
of four flanged sections, the uppermost
and lower two sections had  clear acrylic
windows  on  one side to allow visual
observation. A scale was added to  the
windows to indicate  bed height.  The
zero point of the scale was 32 cm from
the bottom to compensate for the dis-
tributor piping and plates. The distributor
plates directed the flow upward; note that
the nozzles were pointed downward. Two
1.8-m-long,  multi-V-notch  weir plates
were located 5.5 m from the bottom of
the tank. Effluent dissolved oxygen was
measured by a  Beckman dissolved oxy-
gen analyzer.

  A portion of the pilot plant effluent was
recycled to  the reactor to  reduce  the
strength of the incoming wastewater
when  necessary, and to maintain  bed
fluidization during  low flow periods  and
during influent flow interruptions. The
recycle tank split  the reactor overflow
into a recycle  stream and an  effluent
stream. The reactor overflow was intro-
duced  into the recycle tank through a
tangential inlet to set up a circulating
pattern within the  tank.  This action
imparted an outward velocity to any solid
particles  entering the  recycle  tank.

-------
Centrifugal forces push the sand parti-
cles,  in  the  event that  they  should
overflow the reactor, to the periphery of
the tank where they settle out into the
conical  section of the tank. A  bottom
drain was provided to allow for cleaning
this accumulation from the tank.
  Effluent left the recycle tank by over-
flowing the center launder. Recycle flow
was withdrawn from the tank through
a submerged outlet in  the conical tank
section, and  was  pumped through  a
Keystone butterfly flow control valve, a
Ball Vortex flow  meter, and combined
with the influent raw wastewater before
entering the oxygenator. A check valve
was located in the recycle line to prevent
backflow during periods when the recy-
cle pump was  shut down.
  A ratio control station was installed in
the pilot plant to allow pilot plant flows
to vary  as  the Newburgh wastewater
treatment plant flow varied. The operator
had the option of operating the pilot plant
under constant influent and recycle flow
or an automatic mode where a signal
from the Newburgh flow meter controlled
the pilot plant flow. The automatic mode
could be operated in two ways: constant
recycle with  varying  influent flow,
providing a variable hydraulic flux; or
constant total  flow, with recycle  and
influent flow varying to provide a con-
stant hydraulic flux.
  The bed wasting  operation  is critical
for  effective bed control  and mainte-
nance of thin  biofilms. A rubber-lined
centrifugal  pump transported the sand
and biomass to a gravity screening device
(Dorr-Oliver DSM) and provided  the
shearing force necessary to dislodge the
biomass from the sand media. With the
aid  of spray  water, sheared biomass
passed through the screen and sand
media was retained and returned to the
reactor.  The waste  biomass  was  col-
lected in the waste tank and pumped to
the main plant's recycle pit after volume
measurement and sampling for TSS and
VSS.

Small-Scale Pilot Plant
  As previously stated, the maximum
feed flow from the reactor influent pump
was approximately 950 L/min, depend-
ing  on the operating  pressure  of  the
reactor.  The lowest available flow (to
maintain fluidization) was approximately
380 L/min (176 L/min per m2 based on
influent flow). This provides a maximum
to average flow ratio of 2.5:1. One goal
of the project  was  to  test the system
 under higher maximum to average ratios
 than was possible with the  large pilot
 system.  Dorr-Oliver supplied a smaller
 pilot  plant to evaluate stormwater
 impact. This smaller unit is  shown on
 Figure 2. The reactor consisted of two
 sections of clear acrylic pipe. The lower
 section was 15 cm in diameter, while the
 upper section was interchangeable. Two
 upper sections  were used, one 15-cm-
 diameter section  to  provide  a  straight
 column,  and  one  23-cm  section  to
 provide an expanded column.
   Influent to the column was taken from
 the pilot plant distributor  and went
 through  a booster pump and  rotometer.
 This configuration permitted a maximum
 hydraulic loading of 2,100 L/min per m2,
 corresponding to a ratio  of 12:1  when
 using the pilot  plant minimum  influent
 hydraulic flux for fluidization.
   A small DSM screen was set up to
 accomplish wasting from the small unit.
 Wasting was done manually.
Rdtometer\\
                             Drain

                     From Main Reactor
                     Distributor
       Influent Pump
 Figure 2.  Schematic of small pilot unit used
          during a portion of the studies.
Experimental Program
  The experimental phase of the project
covered a total period of 19 months, from
September 1983 through March 1985.
The reactor was operated under constant
raw  wastewater conditions from Sep-
tember 1983 through September 1984.
During the final portion of the study,
December 1984  through March 1985,
the raw flow was automatically adjusted
to be proportional to  the  Newburgh
plant's raw flow rate. The recycle, in this
case, was automatically adjusted in order
to maintain a  constant flux through the
reactor. Operating periods and  number
of samples taken were as follows:

  1.  09/15/83  to  11/10/83,  28
     samplings;

  2.  02/06/84  to  03/08/84,  31
     samplings;

  3.  03/21/84   to  04/09/84,  15
     samplings;

  4.  04/16/84   to  05/22/84,  28
     samplings;

  5.  06/26/84   to  07/24/84,  22
     samplings;

  6.  08/16/84   to   08/21/84,   4
     samplings;

  7.  08/29/84  to  10/09/84,  31
     samplings;

  8.  12/19/84  to   01/04/85,   8
     samplings;

  9.  01/21/85  to  02/08/85,  10
     samplings;

10.  02/14/85 to  02/20/85, 4
     samplings; and

11.  02/28/85  to   03/14/85,   7
     samplings.

Experimental Results
  Average results for the 11 periods of
operation are shown in Table 1. Reten-
tion  times, based on bed height,  but
assuming  empty  bed volume,  ranged
between 20 and 40 min. High volatile
solids inventories and use of pure oxygen
permit these short contact times. BOD
removals, based on total influent BOD,
but soluble effluent BOD, were above
70% with the exception of  one time
period. BOD removals were  based on

-------
 Table 1.   Reactor Performance Summary Table§
Period Number
Dates
Number of Weeks
Hydraulic Data
Raw Flow (L/min)
Recycle Flow (L/min)
Total Flow (L/min)
Ratio Recycle/Raw
Hydraulic Flux (m/min)
Retention Time*
- RawFlow (min)
Biochemical Oxygen Demand-5 Day (BOD)
BOD Influent Img/L)
SBOD Influent (mg/L)**
BOD Effluent (mg/L)
SBOD Effluent (mg/L)
BOD Loading Rate (kg/d/kd VS)
BOD Loading Rate (kg/d/m3)
SBOD Loading Rate {k$/ d/kg VS)
SBOD Loading Ra'j (kg/d/m3
BOD Remove (Percent)-\
BOD Ft movalRate (kg/ d/kg VS)\
BOD ' emovalRate (kg/d/m3)
SBC > Removal Rate (kg/ d/kg VSjtt
SB D Removal Rate (kg/d/m3)
5 upended Solids (SS)
Total Suspended Solids (mg/L)
- Influent TSS
/A - Effluent TSS
Volatile Suspended Solids (mg/L)
- Influent VSS
- Effluent VSS
TSS Removal (percent)
Bed Characteristics
Total Solids (kg)
Total Solids (gm/L)
Total Volatile Solids (kg)
Total Volatile Solids (gm/L)
Calculated Film Thickness (um)
Total Bed Height (m)
Percent Fluidization
1
9/15/83-
11/10/83
9
335
664
998
2.0
0.46
25. J
138.4
59.5
87.6
32.2
0.44
7.72
0.19
3.4
77.2
0.37
6.05
0.11
1.46

116.4
71.1
87.3
56.6
39.0

5750.0
565.0
149.0
16.8
28.3
3.9
157.0
2
2/6/84-
3/8/84
5
305
580
885
1.9
0.41
29.0
71.7
44.0
38.5
19.6
0.26
3.42
0.16
2.1
71.1
0.21
2.81
0.11
1.37

65.8
44.4
44.3
31.2
32.5

4540.0
493.0
123.0
13.3
123.0
4.1
240.0
3
3/21/84-
4/9/84
4
332
641
962
1.9
0.44
29.9
37.8
23.3
17.3
10.4
0.11
1.31
0.07
0.83
60.4
0.09
1.01
0.04
0.44

50.5
29.5
33.3
22.1
41.5

4332.0
420.0
119.0
11.5
78.0
4.6
298.
4
4/16/84-
5/22/84
6
341
488
834
1.4
0.39
27.9
56.1
28.5
44.5
12.8
0.20
2.56
0.11
1.41
72.7
0.16
1.86
0.06
0.70

64.4
47.8
50.5
37.5
25.8

4662.0
475.0
128.0
12.8
79.5
4.4
262.0
5
6/26/84-
7/24/84
5
311
625
936
2.0
0.43
27.1
71.9
33.2
42.6
15.9
0.36
3.55
0.16
1.6
74.8
0.29
2.95
0.10
0.83

75.9
33.2
54.9
24.1
56.3

4060.0
420.0
92.00
9.6
145.0
3.9
299.0
6
8/16/84-
8/21/84
1
417
647
1064
1.6
0.49
22.3
125.5
34.3
45.8
8.5
0.63
7.53
0.18
2.1
87.4
0.14
2.63
0.05
1.60

44.5
38
33.5
30.0
15.0

5034.0
554.0
115.0
12.6
15.0
4 3
200.0
 %Note that calculated values are accomplished on single points, and then averaged.
 *Based on empty bed volume, at average bed height.
•*SBOD is soluble BOD; SCOD is soluble COD.
 ffiOD or COD removal determined by total influent minus soluble effluent.
 HSBOD or SCOD removal determined by soluble influent minus soluble effluent.

-------
Table 1.    (Continued)
Period Number
Dates

Number of Weeks
7
8/29/84-
10/9/84
7
a
12/19/84-
1/4/85
3
9
1/21/85-
2/8/85
3
10
2/14/85-
2/20/85
1
11
2/28/85-
3/14/85
3
Hydraulic Data

Raw Flow (L/min)                        382           413           375         384         466
Recycle Flow (L/mm)                     622           636           665         511         448
Total Flow (L/min)                      1005           978           913         915         914

Ratio Recycle/Raw                         1.6           1.5           1.8         1.3          1.O
Hydraulic Flux (m/mm)                     0.46          0.45          0.42        0.42        0.42

Retention Time'                          24.3          24.1          27.1        23.6        19.9
- RawF/ow (min)

Biochemical Oxygen Demand-5 Day (BOD)
BOD Influent (mg/L)
SBOD Influent (mg/L)'"'
BOD Effluent (mg/L)
SBOD Effluent (mg/L)
BOD Loading Kate (kg/d/kd VS)
BOD Loading Rate (kg/d/m3)
SBOD Loading Rate (kg/d/kg VS)
SBOD Loading Rate (kg/d/m3
BOD Removal (Percent ft
BOD Removal Rate (kg/d/kg VStf
BOD Removal Rate (kg/d/m3)
SBOD Removal Rate (kg/d/kg VS)tt
SBOD Removal Rate (kg/d/m3)
Suspended Solids (SS)
Total Suspended Solids (mg/L)
- Influent TSS
- Effluent TSS
Volatile Suspended Solids (mg/L)
- Influent VSS
- Effluent VSS
TSS Removal (percent)
Bed Characteristics
Total Solids (kg)
Total Solids (gm/L)
Total Volatile Solids (kg)
Total Volatile Solids (gm/L)
Calculated Film Thickness (fim)
Total Bed Height (m)
Percent Fluidization
121.1
54.3
66.5
17.1
0.49
6.86
0.20
2.9
86.9
0.36
5.27
0.13
1.84

138.6
65.3
98.2
47.6
53.0
5238.0
548.0
136.0
14.2
14.5
4 3
205.0
128.6
62.1
95.0
33.5
0.89
8.00
0.44
3.9
73.9
0.32
2.95
0.11
1.09

126.3
88.8
95.8
65.7
29.7
5865.0
543.0
97.0
8.9
88.8
4.6
200.0
151.9
72.5
83.7
26.2
0.56
7.80
0.27
3.8
82.6
0.43
5.98
0.17
2.24

154.8
97.0
122.1
78.0
37.3
4938.0
449.0
150.0
13.6
98.9
4.7
279.0
111.5
59.5
55.0
22.0
0.59
7.74
0.33
4.3
79.3
0.27
5.65
0.09
0.41

116.8
80.3
83.8
69.8
31.3
4919.0
534.0
114.0
12.5
66.8
4.2
212.0
120.6
59.1
50.6
24.0
0.54
8.28
0.26
4.1
80.5
0.49
6.55
0.15
2.38

94.6
62.0
73.0
47.7
34.0
5350.0
523.0
158.0
15.9
118.4
4.3
221.0
 §/Vofe that calculated values are accomplished on single points, and then averaged.
 "Based on empty bed volume, at average bed height.
 **SfiOD is soluble BOD; SCOD is soluble COD.
 ffiOD or COD removal determined by total influent minus soluble effluent.
 ttSBOD or SCOD removal determined by soluble influent minus soluble effluent.

-------
soluble effluent BOD because the exist-
ing  system did  not provide adequate
suspended solids removal. Final clarifi-
cation is considered necessary to assure
effluent suspended solids below 30
mg/L. The unusually high BOD removals
experienced in periods 6 and 7 occurred
after the reactor was recharged  with
clean  sand and are attributed to devel-
opment of a dense, thin biofilm.
  A number of  short-term  runs were
made  using  the  small  pilot unit  with
expanded top sections shown in Figure
2. Results of a run made on February
20,  1985, are shown in Figure 3. The
maximum hydraulic flux attained in the
lower  section of  the column was  over
2,000 L/min per  m2 with the bed being
maintained about 0.5 m below the point
of washout. Although  the degree  of
pollutant removal was small during  high
                                 flux, the bed could be contained in the
                                 reactor and the biofilm was not lost from
                                 the sand particles. The large pilot plant
                                 was run on February 20 at the highest
                                 feed rate possible with available pumping
                                 capacity, but the maximum flux was only
                                 500 L/min per m2. Pollutant removal was
                                 better from this system  than from the
                                 small pilot system.

                                 Conclusions
                                   The fluidized  bed  aerobic bioreactor
                                 process  appears technically viable  for
                                 application to the secondary treatment
                                 of  municipal wastewaters.  Improve-
                                 ments must be made  to the sand-
                                 biomass  separation system  for  more
                                 effective operation. Estimated  installed
                                 and operating costs are in the range of
                                 other biological treatment methods.
                                 Organic  loadings between 0.2 and 0.3
                           kg BOD/kg VSS-day would be required
                           to yield soluble effluent BOD levels less
                           than 20 mg/L. Final clarification will be
                           necessary to assure effluent suspended
                           solids levels less than 30 mg/L.
                             The process is particularly suited for
                           applications in which land is limited, and
                           where roughing treatment is appropriate.
                           In this case, the process, at  loadings of
                           0.4 to  0.5 kg BOD/kg  VSS-d can  be
                           expected to accomplish greater than 50%
                           BOD removal. Intermediate clarification
                           would not be  needed if followed  by a
                           conventional biological system for final
                           treatment.
                             There  is a  correlation  of effluent
                           suspended solids concentration with the
                           TSS and total BOD loading to the reactor.
                           Impractically  low  loadings would  be
                           required  in order  to  meet secondary
                           effluent TSS limits without final clarifi-
                            Oxitron Pilot Plant
    o
   u.
1600

1200

 800

 400

   0
                                       r- Total


                                      r~ Recycle
                               I	I
                                       Raw
                                           I    I    I   I
         <8am 10 12pm 24   6   81012  2am 4   6
to
Q
O
^UU
150
100
50
0
8
800
600
400
200
O
r -,
„ j,i.r~. , /-Influent
| L.I .r^ 	 - 1 /
i L — 	 f- 	
f-1 ~! /-Effluent,
~~ "'_.. ~ ~ "i. j — _ - — —t
1 1 1 1 1 1 1 1 1 1 1
am 70 12pm 24 6 81012 2am 468
r~ Soluble Influent
	 t |— i — | / y— Influent
— \ * H'»* y i ^
	 i *" ....' ' *
: ,..,r" Ux- 	

^•Soluble Effluent ' 	
I 1 I I i i I i i I i
                                  8  10   12  2am 4  6
BOD (mg/L
JUU
200
100
O


/— Influent
y- Soluble Effluent
~~ , i I I I i
, i
1

_ ————__ .
         \8arn 10  12pm 2   4
                       68   1012 2am 4

                        Time (day)
6   8
                                                                             Expanded Section Reactor
750
100
50
n
r i- T
fj 1 — 1 1 r- In fluent
i
"V- Effluent
1 1 1 1 1 i i i 1 1 1
                                                                      8am 10  12pm 246
                                                                   8001	
                                                                                        8  10  12  2am 4
                                                                   600

                                                                   400

                                                                   200
                                                                                           Influent
                                                                                                    • Soluble
                                                                                                     Influent
                                                                           I
                                                                                   I	I
                                                                                           I
                                                                                               Soluble Effluent
                                                                                                       .   .
                                                                                                       i _ i
                                                               Sam 10 12pm 246   81012 2am 4   6
Sam 10 12pm 24   6   81012 2am  4  6

                      Time (day)
Figure 3.   Flow and influent/effluent COD, BOD. and TSS data from the February 20. 1985 hydraulic variability evaluation.

                                                                                7
JUU
200

n
f-1 l—j r- Influent
_ ~ •*" \ ^ _ /- Soluble Effluent
, i i IT "i — r-r~r-r~7—*

-------
cation. Although the effluent TSS levels
were adversely affected at Newburgh by
the  inefficiencies  in the  bed wasting
system, final clarification should still be
required. High rate clarification (50 m3/
mVd) is feasible if coupled with chemical
conditioning. Doses of 10 mg/L alum and
1  mg/L polymer  were found  to be
effective for the Newburgh application.
  The process has the ability to undergo
significant  short term hydraulic peak
loads and  still maintain  bed integrity.
Removal effectiveness  is,  however,
greatly reduced.  A  straight wall reactor
can  operate  at  a  hydraulic  flux of  1
m/min without any loss of bed, approx-
imately 2.5 times  its normal operating
flux. This is equivalent to a maximum to
average raw flow ratio of 4 to 6, effected
by substituting raw flow for recycle flow.
  Modification of the reactor to one with
an  expanded  upper  section (approxi-
mately 2.3 times the cross-sectional area
of the  lower  section) will significantly
enhance the reactor's ability to undergo
hydraulic surges. A flux of 2.5  m/min
was demonstrated  (based on  lower
section  cross-sectional area), with no
loss of bed.  This is equivalent to  a
maximum to  average raw flow ratio of
10. The reactor organic removal efficien-
cies  return  to  normal relatively  quickly
after cessation of the  hydraulic surge.
  Bed stability can be controlled  by the
hydraulic flux and  the average particle
density. The  particle density will be a
function of the average biofilm thickness;
this should  be maintained below 50 //m.
Effective control requires maintenance of
adequate sand and volatile solids levels;
the  bed  must be  monitored by direct
sampling and analysis to accomplish this.
  The sand concentration should aver-
age  400 to 600 g/L through the bed,
under  expanded conditions, with  an
average volatile  solids concentration of
10,000 to 15,000 mg/L. The flux should
be controlled to maintain a bed expansion
of 50% to 100%.
  Maximum oxygen transfer efficiencies
can be accomplished with the oxygenator
at gas to liquid ratios less than 0.03
L/min  02 at standard conditions  per L/
min  wastewater.
  A  key element to the  successful
operation of the f luidized bed is the ability
to maintain and control optimum reactor
bed  conditions. The feed to the reactor
must be kept free  of debris;  this  is
accomplished by screening the primary
effluent (or combined primary effluent/
reactor recycle). The distributor must give
even distribution  of flow across the
                                   8
cross-sectional  area of the  reactor,
without localized velocity gradients! The
distributor ports  must be non-clogging;
pressure drops  should be  monitored
across the  distributor and the system
should provide a means to access the
distributor ports for cleaning.
  The bed wasting operation is critical
for  effective  bed control and mainte-
nance of thin biofilms. Centrifugal pumps
with rubber-lined impellers provide good
shearing  of the biomass from the sand
and the gravity screening device (Dorr-
Oliver DSM) used in this study provided
good separation. Spray water is essential
for effective operation of the  separation
screen.
  The bed wasting operation was labor
intensive and  subject to  significant
equipment problems. The  problems
related primarily to pumping the sand/
biomass  mixture without clogging, and
materials damage. The operation can
also affect the effluent suspended solids
levels  from  the reactor because  of
inefficiencies in separating the biomass
from the sand before the sand is returned
to the reactor.  Improvements to the
existing system  would include a sub-
mersible  pump  to remove  the  sand/
biomass (and shear the biomass from the
sand), a spray water system to enhance
removal of the biomass by the separation
screen,  and  baffles  on the  screen to
prevent flow channelling.
  An alternative  method would be to
install a system  separate  from the
reactor. An agitator would  shear the
biomass, and a  two-stage  rotational
separator  and  gravity settler  would
provide for  separation of the sand from
the biomass and removal of the biomass
and sand slurries.

Recommendations
  The  applications  appropriate to the
fluidized  bed  process are as  a  roughing
treatment system prior to a conventional
treatment system,  or as  a secondary
treatment system for carbonaceous BOD
removal.  It  is  recommended  that the
process be given particular consideration
when  there  is  limited  land available,
significant hydraulic variability, and/or a
proximate, cost-effective source of pure
oxygen. Clarification should be provided
if  the process  must meet secondary
effluent TSS limits.
  In cases where high  hydraulic varia-
bility is expected, it is recommended that
the modified  reactor with the expanded
top section be  used. This  can increase
the capacity  of the system and signifi-
cantly enhance bed stability during short
term hydraulic peak loads.
  Further work  and subsequent demon-
stration is recommended with regard  to
bed wasting and control of bed charac-
teristics. This should address procedures
and equipment  for removing bed sand/
biomass, shearing the excess biomass
from the sand, separation of the sand and
biomass, and effective pumping/trans-
port of the  sand/biomass and  sand
slurries. The  efforts should be directed
to  reducing the labor requirement and
to  designing  more effective  equipment
for  accomplishing these tasks. Consid-
eration should be given to  wholly sepa-
rating this process from the reactor.
  Additional work is needed to demon-
strate the performance of the bioreactor
during the transient conditions of peak
hydraulic loads.  More  information  is
needed on the system's removal efficien-
cies and  oxygen requirements during
these  periods.  This  is necessary  to
optimize designs for possible application
to  the  direct treatment of combined
sewer overflow  wastewaters.
  0. Karl Scheible and Gary M. Grey are with HydroQual. Inc.. Mahwah, NJ
    07430.
  Richard Brenner is the EPA Project Officer (see below).
  The complete report,  entitled "Treatment  of Municipal Wastewaters by the
    Fluidized Bed Bioreactor Process," (Order No. PB 88-140  280/AS; Cost:
    $25.95, subject to change) will be available only from:
          National Technical Information Service
          5285 Port Royal Road
          Springfield, VA 22161
          Telephone: 703-487-4650
  The EPA Project Officer can be contacted at:
          Water Engineering Research Laboratory
          U.S. Environmental Protection Agency
          Cincinnati, OH 45268
                                                              U. S.GOVKNMENT PRINTING OFFICE: 1988/548-158/67108

-------
                                                co

                                                   ™ 0>
         o
 arum*    ip
 MOO**  O
 rt  w    o
 a»
oo
O
*
o
m

3
                                                          TPC


                                                       *  I"
                                                          to

-------