United States
                  Environmental Protection
                  Agency	
Risk Reduction
Engineering Laboratory
Cincinnati OH 45268
                  Research and Development
 EPA/600/S2-88/060  Feb. 1989
x°/EPA        Project  Summary
                  Demonstration  and
                  Evaluation  of  the  CAPTOR
                  Process  for  SewageTreatment
                  Paul F. Cooper
                    The sanitary engineering field has
                  demonstrated substantial interest in
                  recent years in the potential benefits
                  of high  blomass  wastewater
                  treatment. For the  most part, this
                  interest has focused on processes
                  that use various forms of support
                  media  that  have  the ability to
                  colonize  high  concentrations of
                  aerobic bacterial growth. One such
                  concept is  the CAPTOR process*
                  developed Jointly by the University of
                  Manchester Institute of Science and
                  Technology  (UMIST) and Simon-
                  Hartley, Ltd., in the  United Kingdom.
                  This high biomass approach uses
                  small reticulated polyurethane pads
                  as the bacterial growth medium. The
                  pads are added to standard activated
                  sludge  aeration  tankage, and the
                  system  is operated without  sludge
                  recycle, essentially converting a
                  suspended growth process to a fixed
                  film process. Excess  growth is
                  removed  from the  pads  by
                  periodically  passing them through
                  specially designed pressure rollers.
                    The Water Research Centre (WRC)
                  and Severn-Trent Water Authority
                  conducted a full-scale evaluation of
                  the CAPTOR process for  uprating the
                  activated  sludge  plant  at the
                  Freehold Sewage Treatment  Works
                  (near  Stourbridge in  the  West
                  Midlands area of England) to achieve
                  year-round nitrification. The  pro-
                  cess suffered initially from several
                  * Mention of trade names or commercial products
                   does not constitute endorsement or recommen-
                   dation for use
 major design  and operational prob-
 lems. The  report describes how
 resolution of  these  problems was
 achieved in pilot-scale  studies at
 the WRC's Stevenage  Laboratory
 before implementing the  design and
 operating changes so determined on
 the two full-scale CAPTOR trains at
 Freehold.
  Whereas  the pilot-scale studies
 were  successful in  providing solu-
 tions to basic design and operational
 flaws, they were not able to develop
 techniques for improving CAPTOR
 process  effluent quality.  CAPTOR
 performance was adversely affected
 throughout the project by high levels
 of suspended solids  in the process
 effluent  in both pilot-  and field-
 scale studies. These high solids
 levels prevented the uprated system
 at Freehold from achieving nitrifica-
 tion.
  This Project Summary  was  devel-
 oped  by EPA's Risk Reduction  Engi-
 neering Laboratory, Cincinnati, OH, to
 announce key findings of the research
 project that Is fully documented In a
 separate report of the same title (see
 Project Report ordering information at
 back).

 Introduction
  The CAPTOR process originated from
 research work on pure systems in  the
 Chemical  Engineering Department of
 UMIST. Single strands of stainless steel
 wire were woven into a knitted formation
 and then crushed into a sphere of about
 6 mm (0.25 in.) diameter. These particles
 of known  surface area were used  for

-------
modeling liquid-fluidized  bed systems.
From this work derived the idea of using
porous support  pads  for growing
biomass at high  concentrations  that
could  be used  in  wastewater treatment
systems. The idea  was jointly developed
and  patented  by  UMIST  and  their
industrial  partner  Simon-Hartley,  Ltd.
The  present  form  of  the  CAPTOR
process uses 25 mm x 25 mm x 12 mm
(1  in.  x 1  in.  x  0.5  in.)  reticulated
polyether foam  pads containing pores
nominally of about 0.5 to 0.9 mm (0.02 to
0.035 in.) diameter and 94% free space.
  Simon-Hartley, Ltd.  conducted  pilot-
plant work that indicated it was possible
to achieve

• biomass concentrations of 7,000 to
  10,000 mg/L,
• waste sludge concentrations of 4% to
  6% dry solids using a special pad
  cleaner,
• improved oxygen transfer efficiencies,
  and
• high BOD volumetric removal rates

  In  1982,  WRC  and  Severn-Trent
Water Authority agreed to jointly evaluate
the CAPTOR process at the Freehold
Sewage  Treatment   Works  near
Stourbridge, West  Midlands. The  Free-
hold   plant  did  not  achieve  any
nitrification  in the winter  and only partial
nitrification  in  the  summer.  Freehold's
activated sludge  system consisted of five
trains  equipped with tapered fine bubble
dome diffusers arranged  in  a grid (floor
coverage) configuration. The system was
modified as shown  in Figure 1 to split the
wastewater flow  into two equal volumes.
Half went to two trains that were modified
by adding  CAPTOR pads  to the first
quarter of two aeration basins,  and the
other  half  went  to  two  trains  that
remained  unaltered and  served  as a
control  The  CAPTOR modified  trains
were each equipped with a CAPTOR pad
cleaner (Figure  2), and the CAPTOR
pads were  prevented from escaping into
the remainder  of the  experimental
system aeration  basins by  screens
placed at  the  effluent ends of  the
CAPTOR zones.
  The  Simon-Hartley design predicted
that, with a concentration of 40 pads/L,
an annual average removal of 75% of the
BOD5  coming into the  plant could  be
achieved in the CAPTOR zones, resulting
in a  reduced  food-to-microorganism
(F/M) loading on the follow-on activated
sludge  stage of 0.08 kg BOD5/day/kg
MLSS.  With  the reduced load,  it was
predicted that the modified system would
achieve year-round  nitrification with an
effluent ammonia nitrogen concentration
of 5 mg/L or less.

Full-Scale Plant Initial Results
  The  Freehold  modified  CAPTOR/
activated  sludge  system  was put  in
operation  in  September   1982  and
                             immediately encountered a major pro
                             lem. The CAPTOR  pads floated on tl
                             surface of the  tanks  and  would  n
                             become incorporated into the tank liqu<
                             A solution was found in November whi
                             three  of the seven  longitudinal rows
                             fine bubble diffusers in the  CAPTC
                             aeration basins were removed. This  w,
                             done  to create a spiral roll in  the tan
                               Return Sludge
                                                              Secondary
                                                              Clarifier
                                                            Control Effluent
   Primary Effluent
                                                            CAPTOR Effluent
Figure  1.
                           Return Sludge

Schematic of Freehold Sewage  Treatment Works showing  incorporation of
CAPTOR/nitrification trains
                                                1 Air-Lift Pump
                                                2 Conveyor Belt
                                                3 Presqueeze Roller
                                                4 Squeeze Rollers
                                                5 Drive Gear
                                                6 Sludge Discharge
                                                7 Pad Discharge
  Figure 2.    Diagram of CAPTOR pad cleaner

-------
 because it was known that coarse bubble
 diffusers had been used in the previous
 work  done  by Simon-Hartley. Coarse
 bubble diffusion  leads to areas of rising
 and falling  liquid  with  quite  large
 channels down which the pads can fall.
 In the existing fine bubble  grid system,
 the falling zones were much smaller and
 did not  allow the pads to fall  and then
 recirculate. The  spiral  roll  modification
 provided the necessary falling zone and
 produced complete  mixing  of  the
 CAPTOR pads.
  Another problem that occurred at this
 time was maldistribution of the pads. The
 flow of  wastewater tended  to push the
 CAPTOR pads  to  the  outlet of  their
 zones, resulting in concentrations of the
 order of 50 to 60  pads/L at that end and
 only 10 to 20 pads/L at the inlet end.
  One  other disturbing feature was the
 rapid deterioration in  the CAPTOR pads.
 The CAPTOR pads  used initially  were
 black and were wearing at such a  rate
 that they would not have lasted for more
 than 3  yr (making  the process  non-
 economic).
  It had also  become  evident  by  this
 time that with the Freehold wastewater it
 would  be possible  to achieve  the
 concentration of 200 mg  biomass/pad
 predicted  by Simon-Hartley. However, it
 was found  that  if the  biomass  was
 allowed to grow beyond 180 mg/pad, the
 biomass in the center of the pad became
 anaerobic. The control  of  pad biomass
 was difficult because the  pad cleaners
 provided  were not  reliable and were
 situated at the CAPTOR zone inlets while
 most of the pads  gravitated to the outlet
 ends of the zones.
  During the period  November 1982 to
 May 1983, while the- above  problems
 were  being  tackled on  the  full-scale
 plant, there were  some occasions when
 the effluent from  the  CAPTOR units was
 reasonable (BOD5 removals of 40% to
 50%),  but  BOD5 removal   never
 approached  the average  of  75%
 predicted  by Simon-Hartley based  on
 their pilot-plant  results.  Poor  BODs
 removals were  being  experienced
 because  the suspended solids concen-
 tration in  the effluent was  always  high
 (>80 mg/L).  Operating  conditions and
 performance results for these early runs
 are summarized  in  Tables 1  and  2,
 respectively.
  By July 1983,  it was obvious that the
 CAPTOR  process was not sufficiently
 developed for the Freehold project to be
 regarded as just an evaluation. A change
 was then made from an evaluation to a
development project  wherein pilot-scale
Table 1. Initial Freehold Operating Conditions

11/22
6/1 -
9/15-
Period
- 12/31/82
7/7/83
- 1 114183
Wastewater
Flow/ Train (mgd)
1.50
1.38
1.35
First-Stage
CAPTOR HRT (min)
43
48
47
Second-Stage
Activated Sludge
System HRT (min)
127
137
143
Table 2. Initial Freehold Performance Results
                                       Experimental System
Parameter
(mg/L)
11/22- 12/31/82
BOD5
SS
NH4-N
Oxidized-N
6/1/-7/7I83
BODS
SS
NH4-N
Oxidized-N
9/15-11/4/83
eoDs
SS
NH4-N
Oxidized-N
Primary
Effluent

114.
101.
22.1

142.
122.
26.3

136.
144.
26.4
CAPTOR
Zone Effluent

45.
81.
18.2

78.
90.
20.2
0.5

78.
104
20.6
2.0
Final
Effluent

13.
19.
23.5
2.2

10.
14.
24.9
3.2

12.
17
6.1
12.2
Control System
Effluent

19.
25.
24.4
3.3

22.
29.
24.9
2.7

15.
23.
6.0
11 6
studies would be used to find solutions to
the operating problems described above
before  attempting  further full-scale
evaluation at Freehold. Simon-Hartley
became partners, and funding  was
obtained from the  Department  of Trade
and  Industry.  Each  of the  partners
contributed 25% of the overall costs.

Development Project
(Pilot-Scale Studies)
  The development project began  with
two levels of pilot-scale studies carried
out at the WRC Stevenage Laboratory:

1.  Initially, small  tanks (265  L = 70 gal)
   were  utilized to characterize  CAPTOR
   process  performance  under  very
   controlled conditions.
2.  This  was  followed  by larger-scale
   tests  in a hydraulic test rig (HTR),
   volume =  30 m3 (7,930 gal), where
   various inlet and outlet arrangements,
   aeration patterns, and cleaning  rates
   could  be assessed  under near full-
   scale plant conditions.


  The results of the small-tank and HTR
studies were to be used in deciding what
modifications could  be implemented  on
the full-scale plant  at Freehold. The
governing principle  was  that no  major
modification could be made  on the full-
scale  plant  until  it  had  first  been
assessed on the HTR.
  At this time, it was  also  decided  to
evaluate  two  variations of the CAPTOR
process.   Linde AG of West Germany
was testing a process similar  to CAPTOR
called  the LINPOR process. LINPOR
differed from CAPTOR in that sponge
pads were placed directly into the  mixed
liquor of an activated sludge aeration tank
rather than in a separate stage before the
activated sludge tank. It was decided to
test this process variation using CAPTOR
pads rather than  LINPOR pads  in  the
265-L   (70-gal)   tank  arrangement  at

-------
Stevenage. WRC named  this process
variation  CAST (CAPTOR in activated
sludge treatment).  A  control activated
sludge pilot unit was operated in parallel
with the CAST unit.
  In  addition, a  single aeration  tank,
volume  = 236 L (62 gal),  filled with 40
CAPTOR pads/L,  was fed  effluent from
the above activated sludge  control unit to
assess the potential  of CAPTOR  as  a
second-stage  nitrification  process.
Neither pad cleaning nor final clarification
was necessary with this process variation
because  of  the  low sludge yields
characteristic  of nitrifier growth

Small-Tank Results
  These  studies  were  conducted  using
two  well-mixed  CAPTOR  tanks  in
series. A range  of  loading and  pad
cleaning  rates were  used to evaluate
process  removal  capabilities  for
CAPTOR. The intermediate effluent was
used as a measure of process efficiency
of the primary  reactor and the  final
effluent  for  the  entire system.  This
permitted plotting (Figure 3) of % BOD5
removal (total and soluble) vs volumetric
organic loading rate over the  range of  1
to 3.5 kg BOD5/day/m3  (62  to  218
lb/day/1,000  ft3).  High and  low  pad
cleaning  rates are differentiated in Figure
3 as >16% and  <16% of the total pad
inventory/day, respectively.
  Total  BOD5 removal efficiency  was
less  than  soluble  BOD5 removal
efficiency because of  the oxygen
demand  exerted  by  the biomass solids
lost in the process effluent. The higher
pad cleaning  rates are believed to  have
contributed to the improved total and
soluble BODg removals shown in Figure
3, although  low  bulk liquid DO's  may
have  adversely  affected  removals on
some of the low cleaning  runs.  Low
cleaning rates   (<16%/day)  were
detrimental  to soluble  BOD5 removal
efficiency because of a gradual decline
in activity of the biomass  remaining  in
the pad. Cleaning rates  greater  than
24%/day, however, resulted in  reduced
biomass levels  in  the  pads and  a
reduction in performance.

HTR Results
   The problem  of  maldistribution   of
CAPTOR pads in the aeration tank (i.e.,
crowding of pads into the effluent end  of
the tank when  operated  in plug flow
fashion as at Freehold) was solved in the
HTR  by  modifying the flow pattern  to
transverse flow (across the width  of the
tank rather than  down the  length). When
implemented later  at Freehold,  this
 100-

  so-


  so-


  70-

5
s 60-

I 50.

3
3 4°-
3
  30


  20


  70


   0
                                        /Vofe.  7 lb/day/1,000 ft3 =
                                              0.16 kg/day/m3
           —-c  Total BOD 5 - High Cleaning
            *  Total BOD5 - Low Cleaning
            +  Soluble BODs - High Cleaning
            M  Soluble BODs - Low Cleaning
           —i—
            25
Figure 3.
                  50    75     100    125   150     175    200

                  Volumetric Organic Loading Rate (lb/day/1,000 ft3)

          Small tank CAPTOR total and soluble BOD;, removals at high and low pad
           cleaning rates
                                                                225   250
Table 3. HTR Operating Conditions and Process  Performance
                                                       Period
               Parameter
                                           10/8-12/7/84
                                                             12/12/84-2/21/85
Volumetric loading (Ib BOD 5I day 11, 000 ft3)'
HRT (hr)
Pads/L
Biomass/pad (mg)
Equivalent MLSS (mg/L)
F/M loading (kg BOD5/day/kgMLSS)
SRT(days)
DO (mg/L)
113
232
40
121
4,840
0.37
323
4.2
213
1.52
40
126
5.040
0.68
1 72
4.7
 Total BOD5 (mg/L)
 Soluble BOD5 (mg/L)
 SS (mg/L)

 Total BOD5 removal (%)
 Soluble BOD5 removal (%)
 SS removal (%)
                                          In

                                          175
                                           86
                                          116
Out

 93
 24
 120
216
 85
178
Out

 129
 33
 160
                                             47
                                             72
                                            - 3
             40
             61
             10
"1 lb/day/1,000 rfl = 0.016 kg/day/m3
pattern resulted in a fourfold decrease in
flow velocity.
  Several  mixing intensities and diffuser
arrangements  were  tried to decrease
biomass shedding  into  the  process
effluent. It became  obvious, however,
that production of effluent biomass solids
was not significantly affected by changes
in mixing  intensity  or  diffuser arrange-
ment.  High  effluent suspended  solids
proved to  be far more dependent on pad
cleaning rate, biochemical activity of the
                                        biomass, and biomass growth directly
                                        the liquor.
                                          Using the  transverse flow scheme ai
                                        a  regular pad cleaning regimen,  HI
                                        CAPTOR process performance  w;
                                        similar to that experienced in  the  sm
                                        tanks. Operating parameters and proce
                                        performance are summarized  in Table
                                        for two different volumetric  loading rates
                                          Respiration studies  conducted  usir
                                        pads taken from the HTR  indicated th
                                        biomass held within the  pads  respires

-------
Table 4.  Operating Conditions and Performance Results - CAST vs Activated Sludge

                                                      System
Parameter
Volumetric loading (Ib BOD5/day/l,000 ft3)"
HRT (hr)
Pads/L
Biomass/pad (mg)
Equivalent MLSS in pads (mg/i)
MLSS in suspension (mg/L)
Total MLSS (mg/L)
F/M loading (kg BOD5/day/kg total MLSS)
SRT, based on total MLSS (days)
DO (mg/L)

Total BOD5 (mg/L)
Soluble BOD5 (mg/L)
SS (mg/L)
Total BOD5 removal (%)
Soluble BOD5 removal (%)
SS removal (%)
CAST
148
1.8
34
116
3,930
3,720
7,650
031
3.6
25
In. Out
178 12
101 5
121 15
93
95
88
Activated Sludge
148
1.8
—
—
-
6,030
6,030
039
3.0
3.0
ln_
178
101
121
89
96
81










Out
20
4
23



"1 Ib/day/1,000 ft3 = 0.016 kg/day/m3
up to 40% to 50% less than equivalent
biomass  in  free suspension.  Any
increase in net biomass  concentration
achieved in a CAPTOR reactor above
that  in a conventional activated sludge
reactor  may  not  produce  noticeable
benefits, therefore, due  to  the  lower
specific activity.  These  observations
suggest that  diffusion limitations  were
occurring in the CAPTOR pads.


CAST Results
  The CAST  variation of  CAPTOR  was
operated in  conjunction  with a  final
clarifier to settle the mixed liquor solids
component of the total biomass inventory
and  return  it  to  the aeration  tank.
CAPTOR pads and  biomass  retained
therein  were kept in the  reactor  by
screens. Operating and  performance
data are compared in Table  4 for the
CAST  unit and the  parallel  activated
sludge control unit for a  25-day period
(November  5-30, 1984)  when  the
volumetric  loadings  and  hydraulic
residence  times (HRT's)  for both  units
were identical.
Nitrification Results
  Small-tank nitrification experiments
were conducted on the CAPTOR process
from November 1984 to February 1985.
Biomass concentrations per pad ranged
from  99  to  124  mg.  With  a pad
                                      concentration  of 40/L,  equivalent  MLSS
                                      levels varied from 3,960 to 4,960 mg/L.
                                      Liquor  DO  concentrations were  main-
                                      tained  between  6.4 and 8.4  mg/L,  and
                                      liquor temperature ranged from 11.5° to
                                      6.5°C.
                                        Secondary effluent from the  control
                                      activated  sludge pilot  unit used  in the
                                      CAST  experiments was  applied to the
                                      nitrification reactor over a  range of
                                      loading conditions. These loading con-
                                      ditions  and corresponding performance
                                      data  are  summarized  in  Table 5.
                                      Essentially complete  nitrification  was
                                      achieved at TKN and ammonia nitrogen
                                      loadings  of  approximately   0.25  kg/
                                      day/m3 (15.6  lb/day/1,000 ft3) and  0.20
                                      kg/day/m3  (12.5 lb/day/1,000  ft3),
                                      respectively.


                                      Full-Scale Plant Results  after
                                      Modifications
                                        Following the  successful testing of the
                                      transverse mixing  arrangement  in the
                                      HTR at Stevenage, the  two Freehold
                                      CAPTOR  trains were  modified.  Modi-
                                      fications commenced in November 1984
                                      and  were  completed  in mid-March
                                      1985.
Table 5. CAPTOR Nitrification Operating Conditions and Performance Data
Parameter
HRT (hr)
TKN loading
(lb/day/1,000 ft3)"
NH4-N loading
(lb/day/1,000 ft3)"
Total BOD5 in (mg/L)
Total BOD5 out (mg/L)
SS in (mg/L)
SS out (mg/L)
TKN in (mgiL)
TKN out (mg/L)
TKN removal ("/<>)
NH4-N in (mg/L)
NH4-N out (mg/L)
NH4-N removal (%)
NO3-N out (mg/L)
1 1/08/84-
11/28/84
1.9
36.2
30.6
21.
21.
22.
14.
46.
28.
39
39.
23.
41.
5.
12/03/84-
12/20/84
46
150
125
23.
19.
27.
22.
46.
10.
78.
36.
6.
83.
29
7/03/85-
1/18/85
4.2
20.6
16.9
52.
44.
53.
52.
57.
38.
33.
44.
29
34.
13
1/21/85-
2/08/85
40
162
13.1
13
17.
21.
26.
43.
6.
86.
35.
3
94
36
2/11/85-
2/15/85
2.7
28.7
20.6
22.
16.
39.
16.
51.
15
71.
37
12
68
32
"7 lb.day/1,000 ft3 - 0.016 kg/day/m3

-------
  The modifications involved

• splitting each of the CAPTOR trains,
  C1  and C2, into  two compartments,
  C1A and C1B  and C2A and C2B, as
  shown in Figure 4;

• feeding  influent flow  along long weirs
  at the side of the trains instead of at
  the narrow inlet ends;

• modifying the  aeration pipework  to
  place all three  rows of dome diffusers
  directly  below the outlet  screens
  (covering about 25% of the width of
  the tanks), thereby creating a spiral roll
  of pads and liquid counter-current to
  the  flow of wastewater  entering along
  the weirs on the sidewalls;

• installing two extra pad cleaners so
  that each CAPTOR sub-unit  was
  provided with a cleaner; and

• installing fine  screens at the  outlet
  from the primary clarifiers to  reduce
  the  quantity of floating plastic  material
  entering  the  CAPTOR  units  that
  created problems with the cleaners

  The objective  of  the  first  three
modifications was to  achieve  uniform
mixing of the pads in the CAPTOR units
and prevent  the situation that had
occurred  previously  where high  con-
centrations of pads  (50  to  60  pads/L)
collected at the outlet end and very low
concentrations (10 to 20 pads/L)  at the
inlet end. Pads were removed from the
tanks during the modifications. After the
modifications were  completed,  the
number of pads  in  each compartment
was equalized at about 35/L
  The changes  were  completely suc-
cessful in obtaining  uniform distribution
and complete mixing in of the CAPTOR
pads. A  lithium chloride tracer test con-
ducted on the modified tanks indicated
that no dead zone was occurring in the
"eye" of the roll. Formation of  floating
pad rafts (which had  occurred at the
outlet  end of the tank with  the  original
arrangement) was completely eliminated.
The  modifications,  however,  had  no
effect  on the high  level of suspended
solids present in the liquor.
  The performance of the modified
CAPTOR system  and  the  parallel
activated sludge train was monitored
from  April  1  to July 23,  1985.  The
average   volumetric   loading   rate to
each  train was 1.24 kg BODs/day/mS (77
lb/day/1,000 ft3), and the average HRT in
each train (excluding sludge recycle) was
2.55  hr. The results of these tests are
presented in Table 6.
Before Modifications
                                                          Screens
       oo

XXX
Primary
Effluent
X X X X X X
/Spiral
Roll
xxxxxxxxxxx
C2 f
\
>^j Activated
I Sludge
Walkway \
Primary
Effluent
| X X X
X X X X X X
. \ ' /
C1 f \i Activated
j ^1 Sludge
xxxxxxxxxxxxxj f
                    Aeration Pipework and Domes Covering 25% of Area

                                       50.2 ft
After Modifications
                                 Screen
                 xxxxxxxxxxx
                       C2A
          n,'<  11  m 1111
  Primary
  Effluent
    Flow Splitter
        Box
                                  X X X X X
                                 -J	
                                                 Activated
                                                 Sludge
iTimmm
                          Screens
                        C1A

                 X X X  X X X
                                  Spiral
                              1C X X X X
'xxxxxxx*xxxx
1111t  t  t  t*t 111
=•••7
Activated
Sludge
                                          Full Length Weir
                       Aeration Pipework
                       and Domes Covering
                       25% of Area

             Note:  1 ft = 0.305 m


Figure 4.    Modifications to Freehold CAPTOR system flow pattern.
  Clearly, the modified  CAPTOR unit
was less effective in removing BOD and
suspended  solids than  the parallel
control  activated  sludge  system  at  the
same volumetric loading rate, despite the
fact  that it carried a  higher  overall
biomass concentration  (4,830 vs  2,623
mg/L). The interstage values in Table  6
show  that the CAPTOR  portion  of  the
modified trains  had  higher effluent
suspended solids  levels than the primary
effluent.
  Throughout the  experiments, problems
were  encountered in  keeping all  the
CAPTOR pad cleaners  in operation. The
Mark II  pad  cleaners developed by
Simon-Hartley were an improvement on
the Mark I units,  but still suffered from
blockages and breakdowns.
                          The  CAST variation  of  the  CAPTO
                        process, which had exhibited somewh
                        better  performance than convention
                        activated  sludge  in  the small  tar
                        experiments, was also  field evaluated
                        Freehold.  The  CAPTOR  trains  wei
                        further  modified so  that  return  sludc
                        could  be  introduced  to  the  CAPTO
                        zones (35 pads/L), providing an activate
                        sludge component throughout the entii
                        aeration tanks, not just in the nitrificatic
                        stage.  CAPTOR  pads were not added
                        the nitrification stages as this would ha\
                        required  substantial  additional  tar
                        modifications.
                          The  full-scale  CAST  system  we
                        operated  in  parallel with  the  activate
                        sludge  control  trains from August  1
                        October  31,  1986.  The  averag

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 volumetric organic  loadings and  HRT's
 (excluding  sludge recycle) for  each
 system were  1.11 kg BOD5/day/m3 (69
 lb/day/1,000 ft3)  and 3.40 hr,  respec-
 tively.
   Performance  data  summarized  in
 Table 7 indicate that, contrary to the
 small tank  results, the  CAST system
 effluent was of poorer quality than that of
 the  conventional  activated  sludge
 system. In addition, difficulties  were
 experienced in supplying sufficient  air to
 the CAPTOR  units.  The maximum air
 supply had been  sized for the CAPTOR
 pads alone, and this was not enough at
 times to  satisfy the oxygen  demand
 created by the biomass on the pads and
 the biomass of the mixed liquor.

 Conclusions
 1. When  the  CAPTOR  process  was
   installed at the Freehold  Sewage
   Treatment Works, several problems
   were immediately evident:

   a. There  were  major problems  with
      respect to pad mixing, suspension,
      and distribution.

   b. The Mark I pad cleaners were not
      reliable.

   c. Performance was adversely af-
      fected  by  the  high  level of
      suspended  solids  in the CAPTOR
      stage effluent.

   The problems of pad mixing  and
   distribution   were  solved by  pilot-
   and full-scale  development work.
   The Mark II  pad cleaners produced by
   Simon-Hartley  were a considerable
   improvement over the Mark I cleaners,
   but minor problems  remained to be
   resolved.

 2  The performance of the  CAPTOR
   process  was still adversely affected
   by the high  level of suspended solids
   in  the CAPTOR  stage effluent  after
   correction of the  pad mixing,  sus-
   pension, and distribution problems.
   This prevented the  achievement of
   nitrification in the follow-on activated
   sludge stage.

3 The presence of CAPTOR pads in the
  tank liquid did  not  improve  oxygen
  transfer efficiency.

4.  The durability of  the  CAPTOR  pads
   was solved  by  switching to different
   pads. The original black pads (made
   by ScotFoam, Inc., USA)  deteriorated
   rapidly  as  did  the yellow  CAPTOR
,   pads provided by Recticel (Belgium),
Table 6. Full-Scale Performance Results - Modified CAPTOR Activated Sludge System vs
        Conventional Activated Sludge
                                         Experimental System
Parameter
(mg/L)
Total BOD5
Soluble BOD5
SS
NH4-N
Oxidized-N
Primary
Effluent
728.
40.
138.
24.0
—
CAPTOR
Zone Effluent
(C2A & C2B)
122.
28.
754.
24.9
-
Final
Effluent
22.
4.
32.
24.4
0.6
Control
System
Effluent
76.
3.
23.
22.5
2.0
Table 7. Full-Scale Performance Results - CAST vs. Conventional Activated Sludge
Parameter
(mg/L)
Total BOD5
Soluble SO05
SS
NH4-N
Oxidized-N
Primary Effluent
738.
56.
720.
26.7
-
CAST
System Effluent
16.
2
27.
17.2
3.7
Control
System Effluent
W.
2
75.
77.4
7.8
   but the  orange  pads  made  by
   ScotFoam, Inc., were very durable.

5  The peak  biomass concentration  in
   the pads is unpredictable.  It does not
   appear to  be  related to the  BOD
   concentration  of the wastewater.
   There  were indications in the various
   studies, however, that the frequency
   of  pad cleaning (and, hence, the
   biomass/pad  concentration)  was
   critical to  the  performance  of the
   process.  Regular pad cleaning  is
   essential  to  prevent  anaerobic
   conditions  from  developing  m the
   pads.

6. It is possible to  raise the biomass
  concentration in  a CAPTOR stage to
  6,000  to  8,000 mg/L,  but  the
  respiration rate of the  biomass in the
  pads is lower than the respiration of
  the same biomass if freely suspended
  and less than that of normal activated
  sludge. These data  suggest  that the
  geometry of the  CAPTOR pads results
  in diffusion  limitations,  which severely
  restrict the  potential  for  economic
  utilization of the CAPTOR process in
  wastewater treatment.
7. The CAST  variation of the  CAPTOR
   process  performs  well, but it  is
   doubtful if it is economic.

8. CAPTOR  may have some potential as
   an add-on  package for tertiary  nitri-
   fication. However,  this process varia-
   tion may not be cost competitive.

9. The use  of CAPTOR  as a  roughing
   treatment  (followed  by  interstage
   clarification) was estimated to be less
   cost effective than using conventional
   nitrifying biological filters for uprating
   Freehold to  complete year-round
   nitrification. The  CAPTOR  option,
   however,  was projected to be more
   cost  effective  than  extending the
   activated  sludge plant for the same
   purpose.

  The full  report was  submitted  in
fulfillment of  Cooperative Agreement No.
CR810911 by the Water Research  Centre
of Stevenage, England, under the partial
sponsorship  of the U.S.  Environmental
Protection Agency.

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Paul F. Cooper is with the Water Research Centre, Stevenage, Hertsfordshire SG1
  1TH, United Kingdom.
Richard C. Brenner is the EPA Project Officer (see below).
The complete  report,  entitled "Demonstration and  Evaluation  of the CAPTOR
  Process for  Sewage Treatment," (Order No.  PB 89-118 665/AS; Cost: $21.95,
  subject to change) will be available only from:
       National Technical Information Service
       5285 Port Royal Road
       Springfield, VA22161
       Telephone:  703-487-4650
The EPA Project Officer can be contacted at:
       Risk Reduction Engineering Laboratory
       U.S. Environmental Protection Agency
       Cincinnati, OH 45268
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
     BULK RATE
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EPA/600/S2-88/060

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