United States Environmental Protection Agency Chesapeake Bay Program Annapolis MD 21401 Research and Development EPA-600/S3-83-048 Aug. 1983 Project Summary Baseline Sediment Characteristics and Sedimentation Patterns on the Virginia Portion of the Chesapeake Bay R J. Byrne, C. H. Hobbs, III, and M. J. Carron The distribution patterns of sediment physical properties, deposition patterns, and sediment accumulation rates pro- vide an integrating framework for in- vestigating the concentration and dis- tribution of toxic substances. Over 2,000 surface-sediment grab samples (1.4 km grid) reveal that the bottom of Chesapeake Bay, Virginia, is signifi- cantly sandier than previously reported; about 65 percent of the area is sand. Nine hundred samples, selected to avoid the coarser sands, were analyzed for total carbon, organic carbon, and sulfur contents. There are strong cor- relations between these characteris- tics and sediment type, especially weight-percent clay. Additionally, there is a good relationship between the organic carbon and sulfur contents. The project includes an attempt at constructing a sediment budget using published values for silt and clay es- tuarine advection and contributions from shore erosion measured against the residual accumulations. The re- sidual accumulation of silt and clay is an order of magnitude larger than pre- viously estimated. This study indicates that the residual bottom-accumulation of sand may be greater than the shore erosion con- tribution by a factor of 40. It is evident that additional understanding of sed- iment flux through both the Bay mouth and the mouths of the flanking tribu- taries is required. This Project Summary was developed by EPA's Chesapeake Bay Program. Annapolis. MD. to announce key find- ings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction An important reason for the study of the physical characteristics of the bottom sed- iments of Chesapeake Bay is that the sediments are the loci of interaction be- tween toxic substances that have been introduced into the Bay system and the biological communities that use the same system Whether the biological elements make permanent use by residing in the Bay, or temporary use through migration or seasonal habitation, they all are to some extent dependent on the sediments and the sediment-formed strata which form the physical structure over and through which the biota are distributed. If, as often has been postulated, there are discrete relationships between the substances of concern and sediment types, knowledge of the sediments is critical to understand- ing the problem of toxic substance. Thus, the first objective of this study was to discern the sedimentological characteris- tics of the bottom sediment at a sufficient sample density so that reasonable inter- polations could be made from a sample subset which is analyzed for various toxic substances and other related parameters. ------- A second objective was to supply maps of the characteristics of the bottom sedi- ments to support interpretations made in other phases of the E PA's Chesapeake Bay Program, specifically those phases deal- ing with the transportation of materials and with the history of recent sedimentation. A third objective of this project was to provide a comprehensive statement of the "condition" of the bottom sediments of the Virginia portion of Chesapeake Bay against which future sediment samples and characteristics could be compared. This study was integrated wth a similar study in the Maryland portion of the Bay conducted by the Maryland Geological Survey (MGS). Thus, compatible Bay-wide data will be available to those persons making interpretations and decisions af- fecting the region. Procedure and Methodology The methods used in this study matched, to the extent possible, those of the Mary- land Geological Survey's parallel study of the Maryland portion of the Bay. The two studies used essentially identical proto- cols for the analyses of sediment charac- teristics and chemistry. However, the treatment of the rates of deposition and the information derived were somewhat different due to differences in the avail- ability of data from bathymetric surveys and in the formatting for automatic data processing. Bottom samples were acquired with a stainless steel Smith- Maclntyre grab sam- pler which has a volume of approximately 0.01 m3. When the sampler was on deck, at least two subsamples were taken from the sediment surface. Surface samples were skimmed from the top centimeter for the carbon and sulfur analyses. These were placed in labelled plastic vials and promptly refrigerated or iced. The second subsamples were several hundred grams of material from the top 4 to 6 cm. These were placed in large plastic envelopes with top fasteners and, although not refrig- erated, care was taken to avoid long ex- posure to environmental extremes. The total field collection was 2,172 sample sets from 2,018 locations. The smaller subsamples, for carbon and sulfur anal- yses, were transported on ice from the ship and then frozen and held until pre- treatment for analysis. Upon delivery to the laboratory, the larger subsamples, secured for water content and size anal- yses, were mixed and split into at least three subsamples. Because the sediments range in size from granules to clays, different analytical techniques were required on different fractions of the samples. The sand fraction was analyzed in a Rapid Sediment Analyzer (settling tube), the granules by conven- tional sieving, and the fines by Coulter Counter. Approximately 900 samples were se- lected for carbon and sulfur analyses. The primary interest was in the chemical al- liances with the finer grained sediments; therefore, the samples were selected on the basis of an inferred minimum of 1 5 percent mud by weight. After being dried and powdered, the samples for sulfur and total carbon analyses received no further pretreatment The samples to be analyzed for organic carbon were digested with 10 percent HCI to remove carbonate. The analyses were made on LECO equipment using standard procedures. All were made in at least duplicate. Results and Conclusions The silts and clays are generally con- fined to the several deep channels within the system and to the shallower, more pro- tected areas such as Mobjack Bay. The deep channel near the southern portion of the Eastern Shore peninsula is an anomaly as it contains only sands. The distribution of the fractional ac- cumulations of sand, silt, and clay sug- gests that the principal clay sources are from the northern Bay followed by the Bay mouth, that the principal sources of silt are the Bay mouth followed by the northern Bay, and that the Bay mouth is the prin- cipal source of sand. The estimates of a sediment budget were constructed for the Virginia portion of the Bay using measured values for the contribution from shore erosion and re- sidual bottom accumulation, and literature values for silt and clay importation from Maryland waters. The residual bottom accumulation of silt and clay exceeds the values from the estimated sources by a factor of 1 2. The measured values of the silt and clay contribution from shore erosion are an order of magnitude less than previously estimated. Bottom accum- ulation of sand exceeds that contributed from shore erosion by a factor of 40. Previous attempts at constructing a sed- iment budget have dealt only with sus- pended sediments and with shore erosion as the sole contributor of sand. The patterns of deposition and the magnitudes of sand accumulation clearly indicate that there is a strong advection of nearshore sands into the Bay mouth and up the Bay stem. R. J. Byrne, C. H. Hobbs III. andM. J. Carron are with the Virginia Institue of Marine Science. Gloucester. MA 23062. Duane Wilding is the EPA Project Officer (see below}. The complete report, entitled "Baseline Sediment Characteristics and Sedimenta- tion Patterns on the Virginia Portion of the Chesapeake Bay," (Order No. PB 83-224 899; Cost: $16.00. subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Chesapeake Bay Program U. S. Environmental Protection Agency 2083 West Street, Suite 5G Annapolis, MA 21401 ft US. GOVERNMENT PRINTING OFFICE 1983-659-017/7153 ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Postage and X"™^^ Fees Paid I ^^H Protection 1 ^St Agency 1 ^MJj EPA 335 l^*^ Official Business Penalty for Private Use $300 RETURN POSTAGE GUARANTEED Third-Class Bulk Rate ------- |