United States
Environmental Protection
Agency
 Chesapeake Bay
 Program
 Annapolis MD 21401
 Research and Development
EPA-600/S3-83-048 Aug. 1983
 Project  Summary
Baseline Sediment
Characteristics  and
Sedimentation   Patterns  on  the
Virginia  Portion of  the
Chesapeake  Bay
 R J. Byrne, C. H. Hobbs, III, and M. J. Carron
  The distribution patterns of sediment
 physical properties, deposition patterns,
 and sediment accumulation rates pro-
 vide an integrating framework for in-
 vestigating the concentration and dis-
 tribution  of toxic substances. Over
 2,000 surface-sediment grab samples
 (1.4 km grid) reveal that the bottom of
 Chesapeake  Bay, Virginia,  is  signifi-
 cantly sandier than previously reported;
 about 65 percent of the area is sand.
  Nine hundred samples, selected to
 avoid the coarser sands, were analyzed
 for total carbon, organic  carbon, and
 sulfur contents. There are strong cor-
 relations  between these  characteris-
 tics and  sediment type, especially
 weight-percent clay. Additionally, there
 is a good relationship between the
 organic carbon and sulfur contents.
  The project includes an attempt at
 constructing a sediment budget using
 published values for silt and clay es-
 tuarine advection and contributions
 from shore erosion measured  against
 the  residual  accumulations. The re-
 sidual accumulation of silt and clay is
 an order of magnitude larger than pre-
 viously estimated.
  This study indicates that the residual
 bottom-accumulation of sand  may be
 greater than the shore erosion  con-
 tribution by a factor of 40. It is evident
 that additional understanding  of sed-
 iment flux through both the Bay mouth
 and the mouths of the flanking tribu-
 taries is required.
  This Project Summary was developed
by EPA's Chesapeake Bay Program.
Annapolis. MD. to announce key find-
ings of the research project that is fully
documented in a separate report of the
same title (see Project Report ordering
information at back).

Introduction

  An important reason for the study of the
physical characteristics of the bottom sed-
iments of Chesapeake Bay is  that the
sediments are the loci of interaction be-
tween toxic substances that have been
introduced into the Bay system and the
biological communities that use the same
system  Whether the biological elements
make permanent use by residing  in the
Bay, or temporary use through migration
or seasonal habitation, they all are to some
extent dependent on the sediments and
the sediment-formed strata which form
the physical structure over and through
which the biota are distributed. If, as often
has been postulated, there are discrete
relationships between the  substances of
concern and sediment types, knowledge
of the sediments is critical to understand-
ing the problem of toxic substance. Thus,
the first objective of this  study was to
discern the sedimentological characteris-
tics of the bottom sediment at a sufficient
sample density so that reasonable inter-
polations could be made from a sample
subset which is analyzed for various toxic
substances and other related parameters.

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  A second objective was to supply maps
of the characteristics of the bottom sedi-
ments to support interpretations made in
other phases of the E PA's Chesapeake Bay
Program, specifically those phases  deal-
ing with the transportation of materials and
with the history of recent sedimentation.
  A third objective of this project was to
provide a comprehensive statement of the
"condition" of the bottom sediments of
the Virginia portion of Chesapeake Bay
against which future sediment  samples
and characteristics could be compared.
  This study was integrated wth a similar
study in the Maryland  portion of the Bay
conducted  by the  Maryland  Geological
Survey (MGS). Thus, compatible Bay-wide
data will be available  to those persons
making interpretations and decisions af-
fecting the  region.

Procedure and  Methodology
  The methods used  in this study matched,
to the extent possible, those of the Mary-
land Geological Survey's parallel study of
the Maryland portion of the Bay. The two
studies used essentially identical proto-
cols for the analyses of sediment charac-
teristics and  chemistry.   However, the
treatment of the rates of deposition and
the information derived were somewhat
different  due to differences in the avail-
ability of data from  bathymetric surveys
and in the formatting for automatic data
processing.
  Bottom samples were acquired with a
stainless steel Smith- Maclntyre grab sam-
pler which has a volume of approximately
0.01 m3. When the sampler was on deck,
at least two subsamples were taken from
the sediment surface. Surface  samples
were skimmed from the top centimeter for
the carbon and  sulfur analyses. These
were placed in labelled plastic vials and
promptly refrigerated or iced. The second
subsamples were several hundred grams
of material from the  top 4 to 6 cm. These
were placed in large plastic envelopes with
top fasteners and,  although  not refrig-
erated,  care was taken to avoid  long ex-
posure to environmental extremes.  The
total field collection was 2,172 sample
sets from 2,018 locations. The smaller
subsamples, for carbon and sulfur  anal-
yses, were  transported on  ice from the
ship and then frozen and held until  pre-
treatment for analysis. Upon  delivery to
the laboratory,  the  larger  subsamples,
secured for water content  and size anal-
yses, were  mixed and split into at least
three subsamples.
  Because  the sediments  range in  size
from granules to clays, different analytical
techniques were  required on different
fractions of the samples. The sand fraction
was analyzed in a Rapid Sediment Analyzer
(settling tube), the granules  by conven-
tional sieving,  and the fines by Coulter
Counter.
  Approximately 900 samples were se-
lected for carbon and sulfur analyses. The
primary interest was in the chemical al-
liances with the finer grained sediments;
therefore, the samples were selected on
the basis of an inferred minimum of 1 5
percent mud by weight. After being dried
and powdered, the samples for sulfur and
total carbon analyses received no further
pretreatment The samples to be analyzed
for organic carbon were digested with 10
percent HCI to remove carbonate.  The
analyses were made on LECO equipment
using standard procedures. All were made
in at least duplicate.

Results and Conclusions
  The  silts and clays are generally con-
fined to the several deep channels  within
the system and to the shallower, more pro-
tected  areas such as Mobjack Bay. The
deep channel near the southern portion of
the Eastern Shore peninsula is an anomaly
as it contains only sands.
   The  distribution of the fractional ac-
cumulations of sand, silt, and clay sug-
gests that the principal clay sources are
from the northern Bay followed by the Bay
mouth, that the principal sources of silt are
the Bay mouth followed by the northern
Bay, and that the Bay mouth is the prin-
cipal source of sand.
  The estimates of a sediment  budget
were constructed for the Virginia portion
of the Bay using measured values for the
contribution from shore erosion and re-
sidual bottom accumulation, and literature
values for silt and clay importation from
Maryland  waters. The residual  bottom
accumulation of silt and clay  exceeds the
values from the  estimated sources by a
factor of 1 2. The measured values of the
silt and clay  contribution  from  shore
erosion  are  an order of magnitude less
than previously estimated. Bottom accum-
ulation of sand exceeds that contributed
from shore erosion by a factor of 40.
  Previous attempts at constructing a sed-
iment budget have dealt only with sus-
pended sediments and with shore erosion
as the  sole contributor of  sand.   The
patterns of deposition and the magnitudes
of sand accumulation clearly indicate that
there  is a strong advection of nearshore
sands into the Bay mouth and up the Bay
stem.
   R. J. Byrne, C. H. Hobbs III. andM. J. Carron are with the Virginia Institue of Marine
     Science. Gloucester. MA 23062.
   Duane Wilding is the EPA Project Officer (see below}.
   The complete report, entitled "Baseline Sediment Characteristics and Sedimenta-
     tion Patterns on the Virginia Portion of the Chesapeake Bay," (Order No. PB
     83-224 899; Cost: $16.00. subject to change) will be available only from:
           National Technical Information Service
           5285 Port Royal Road
           Springfield, VA 22161
           Telephone: 703-487-4650
   The EPA Project  Officer can be contacted at:
           Chesapeake Bay Program
           U. S. Environmental Protection Agency
           2083 West Street, Suite 5G
           Annapolis, MA 21401
                                                ft US. GOVERNMENT PRINTING OFFICE 1983-659-017/7153

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