United States Environmental Protection Agency Air and Energy Engineering Research Laboratory Research Triangle Park NC 27711 Research and Development EPA/600/S7-85/006 Sept. 1985 &ERA Project Summary Economics of Nitrogen Oxides, Sulfur Oxides, and Ash Control Systems for Coal-Fired Utility Power Plants J. D. Maxwell and L R. Humphries An EPA-sponsored economic evalua- tion was made of three processes to reduce NOX, SO2, and ash emissions from coal-fired utility power plants; one based on a 3.5% eastern bitumi- nous coal; and the other two, on 0.7% western subbituminous coal. NOX con- trol is based on an 80% reduction from current new source performance stan- dards (NSPS); S02 and fly ash control are based on meeting the current NSPS. Selective catalytic reduction (SCR) is used for NOX control with both coals. Limestone scrubbing and a cold- side electrostatic pradpitator (ESP) are used with the 3.5% sulfur coal. Lime spray dryer flue gas desurfurization (FGD) and a baghouse for particulate collection are used with one 0.7% sulfur coal; and limestone scrubbing and a hot-side ESP, with the other. The eco- nomics consist of detailed breakdowns of the capital investments and annual revenue requirements. For systems based on a 500-MW power plant, capi- tal investments range from $167 to $187 million (333 to 373 $/kW) and first- year annual revenue requirements from $54 to $60 million (29 to 33 mills/kWh). The 3.5% sulfur coal case is highest be- cause of the higher SO2 control costs. The case with the spray dryer and bag- house is marginally lower in cost than that with limestone scrubbing and hot- side ESP. Costs for NOX control range from 25 to 50% of the total costs, largely because of the high cost of the catalyst. The costs of the overall sys- tems and the relationships of the com- ponent costs are complexly interrelated because of the interactions of the three processes. This Project Summary was devel- oped by EPA '9 Air and Energy Engineer- ing Research Laboratory, Research Tri- angle Park, NC, to announce key findings of the research project that is fully documented in a separate report of the same title (see Project Report or- dering information at back). Introduction Most NOX emission control require- ments now in force are being met by modifications to the boiler combustion process, including: staged combustion (bias firing, burners out of service, and overfire air), flue gas recirculation, low excess air, and dual-register burner de- signs. Advanced burner and furnace de- signs now under development have the potential to provide significantly lower NOX emissions than today's standards. These new combustion systems include fuel-staging and after-burning. How- ever, these new designs are still several years from commercial availability. If stricter regulations were adopted in the near future, these combustion modifica- tion methods would not—at least for several years—be adequate, and flue gas treatment would be necessary. The most highly developed method of flue gas treatment for NOX control is selec- tive catalytic reduction (SCR) in which flue gas is treated with ammonia and passed over a solid catalyst to reduce the NOX to molecular nitrogen. The ------- need for flue gas treatment to meet NOX emission limits would probably be met by the use of SCR processes, several variants of which are offered commer- cially. A generic SCR process, derived from these commercial processes, is therefore used in all three cases. Limestone scrubbing remains the predominant method of flue gas desul- furization' (FGO), increasingly with pro- visions to produce gypsum by forced or natural oxidation to reduce waste dis- posal problems. The use of low-sulfur coal has, however, led to the rapid adoption of spray dryer FGD in which the flue gas is contacted with a fine spray of absorbent that evaporates to solid particles in the spray dryer and can be collected as a solid. More -than a dozen spray dryer FGD systems have been selected by utilities for low- and medium-sulfur coal applications in the last 5 years. This trend is represented by the use of a lime-based spray dryer sys- tem in case 2, one of the low-sulfur coal cases. For case 1, the high-sulfur coal case, and case 3, the other low-sulfur coal case, conventional limestone FGD systems producing gypsum are used. The use of low-sulfur coal has also led to the adoption of new methods of fly ash control because the ash is difficult to collect in conventional cold-side (af- ter the boiler air heater) electrostatic precipitators (ESPs) that have served as the industry standard for many years. In many such cases, hot-side (before the air heater) ESPs have been used be- cause the higher ash temperature im- proves the electrical properties of the ash that affect the efficiency of collec- tion. In both cases, however, strict fly ash emission regulations (e.g., the 1979 NSPS) strained the capabilities of then- existing ESP technology, leading to the rapid adoption of fabric filter baghouses for fly ash control. Baghouses, which are proving quite effective, have also been the predominant choice for use with spray dryer FGD in which the fly ash and FGD wastes are collected to- gether. These uses are represented by a conventional cold-side ESP in case 1, a baghouse in case 2, and a hot-side ESP in.case 3. Process Descriptions The base case designs are applied to a new 500-MW boiler fired with pulver- ized coal that operates 5,500 hr/yr for 30 years. The boiler meets the 1979 NSPS NOX emission requirements by combustion modifications. The emis- sion control systems are designed for an 80% reduction in these NOX emis- sions and for reduction of S02 and fly ash emissions of the 1979 NSPS levels. The designs upon which the costs are based include all equipment involved in the collection and disposal of wastes, including a common onsite landfill, and all boiler modifications—air heater modifications and larger induced-draft (ID) fans—made necessary by the pres- ence of the emission control systems. Major conditions are shown in Table 1. The SCR systems consist of two trains of insulated reactors with ash hopper bottoms (except in case 3 with an up- stream ESP) and provisions for chang- ing catalyst beds. The beds are com- posed of 0.15- by 0.15- by 1-m honeycomb blocks in metal modules. Flue gas is ducted from economizer (or hot-side ESP) outlet and returned to the air heater. Modifications to the air heater to accommodate ammonia salt buildup are included. An ammonia stor- age and handling system to inject an ammonia/air mixture in the inlet duct is provided. An economizer bypass to maintain the reactor temperature dur- ing low-load operation is included. The catalyst life is assumed to be 1 year, with changes during scheduled boiler outages. The limestone FGD systems consist of multiple trains of spray tower ab- sorbers connected to a common inlet plenum and discharging to the stack plenum. Each train consists of a presat- urator, the absorber with a hold tank and the associated absorbent recircula- tion system (and an oxidation tank in case 1), and a booster fan. A steam re- heater is included in case 1 to provide a stack temperature of 175°F. Flue gas is bypassed in the low-sulfur coal case to eliminate reheating costs (in this case, a less expensive alternative than full scrubbing at the low removal efficiency required). A single slurry preparation area supplies the system. The gypsum waste is dewatered in a thickener and rotary vacuum filters and trucked 1 mile to the landfill. A spare absorber train and emergency bypasses for half of the scrubbed flue gas are provided in all cases. A similar arrangement is used for the spray dryer system in case 2, except that the baghouse booster fans also serve for the spray dryer system. The spray dryers are cylindrical vessels with conical bottoms with single rotary at- omizers. The absorbent slurry consists Table 1. Major Design Conditions Case 1 Case 2 Case3 Coal and boiler conditions Coal Coal sulfur, % as fired Coal ash, % as fired Btu/lb, as fired Sulfur emitted, % of total Fly ash, % of total ash NOX emitted, lb/106 Btu" Boiler size3, MW Heat rate, Btu/kWh Emission control Nox control Nox reduction, % So2 control Absorber trains13 Bypassed flue gas, % SC>2 removal, overall % SC<2 removal, absorber % fly ash control Fly ash removal, %c East. bit. 3.36 15.1 11,700 92 80 0.6 500 9,500 SCR 80 Limestone FGD 5 0 89 89 Cold-side ESP 99.7 West, subbit. 0.48 6.3 8,200 85 80 0.5 500 10,500 SCR 80 Lime spray dryer 4 12 65 73 Baghouse 99.9 West, subbit. 0.48 6.3 8,200 85 80 0.5 500 10,500 SCR 80 Limestone FGD 5 28 65 90 Hot-side ESP 99.6 a. Based on coal consumption and heat rate. b. Including one spare train. c. In collection device, excluding upstream fallout. 'Readers more familiar with metric units are asked to use the conversion factors provided at the end of this Summary. ------- of slaked lime and recycled solids from the baghouse. The ash control systems consist of the ESPs or baghouses (two parallel identi- cal units), hoppers, conveying systems, a bottom ash dewatering system, stor- age silos for fly ash, and equipment for trucking the waste to the landfill. The bottom ash is collected in a conven- tional hopper and sluiced to the dewa- tering system. Fly ash is conveyed to silos with a vacuum-pneumatic system. The mixed fly ash and FGD waste in case 2 is conveyed by a pressure- vacuum pneumatic system. Economic Procedures The economics consist of the capital investment in 1982 dollars and the first- year and levelized annual revenue re- quirements in 1984 dollars. The annual revenue requirements consist of operat- ing and maintenance costs plus capital charges. The capital charges are lev- elized in both the first-year and levelized annual revenue requirements; whereas, the operating and maintenance costs are also levelized in the latter. The lev- elizing factor in all cases is 1.886, which represents a 6% annual inflation and a 10% discount rate over the 30-year life of the project Costs include all those associated with the construction and operation of the systems, including modifications to the boiler air heater and the incremental increase in the boiler ID fans to account for the pressure drop in the emission control equipment that is not compen- sated for by separate booster fans. Con- struction and operating costs of the landfill are also included. Costs are divided into three sections, representing NOX, S02, and ash control, and are further divided into categories j-epresenting particular unit operations within the processes. Where equipment or operations serve more than one pro- cess (incremental increases in boiler ID fans and the common landfill, for exam- ple), the costs are prorated using the appropriate factors (pressure drops or waste volume, for example). Baghouse costs are not prorated, however, be- cause of the effect of flue gas volume on baghouse costs. Results Capital investments and annual rev- enue requirements are summarized in Tables 2 through 5. With the choice of processes determined, at least in part by the type of coal, and the costs of the individual processes influenced by Table 2. Summary of Capital Investments in $l06a-b Capital investment, mid-1982 $ $We NO, SO2 Paniculate Total Base case, 500 MW, 80% NOX removal Case 1 41.9 101.8 Case 2 50.1 54.0 Case 3 48.1 69.4 Case variation, 200 MW, 80% NOX removal Case 1 20.6 58.2 Case 2 24.2 31.7 Case 3 24.3 41.4 Case variation, 1,000 MW, 80% NOX removal Case 1 77.7 175.7 Case 2 94.8 97.4 Case3 91.2 121.1 Case variation, 500 MW, 90% NOX removal Case 1 48.2 101.9 Case 2 55.5 54.0 Case 3 53.9 69.4 42.9 62.6 53.5 22.6 31.4 27.8 73.3 110.7 94.6 42.9 62.7 53.5 186.6 166.7 171.0 101.5 87.3 93.5 326.6 302.9 306.9 193.0 172.2 176.8 "Table 1 lists the major design conditions for each case. bAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. Table 3. Summary of Capital Investments in $/KWa-b Capital investment, mid-1982 $ $/kW NO, S02 Paniculate Total Base case, 500 MW, 80% NOX removal Case 1 83.7 203.7 Case 2 100.2 108.0 Case 3 96.1 138.7 Case variation, 200 MW, 80% NOX removal Case 1 103.1 291.0 Case 2 121.0 158.3 Case 3 121.6 206.9 Case variation, 1,000 MW, 80% NOX removal Case 1 77.7 175.7 Case 2 94.8 97.4 Case 3 91.2 121.1 Case variation, 500 MW, 90% NOX removal Case 1 96.4 203.8 Case 2 111.0 108.0 Case3 107.8 138.8 85.8 125.3 107.1 113.2 157.2 139.0 73.3 110.7 94.6 85.8 125.4 107.1 373.2 333.4 342.0 507.3 436.6 467.5 326.6 302.9 306.9 386.0 344.3 353.6 'Table 1 lists the major design conditions for each case. bAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. ------- Table 4. Summary of Annual Revenue Requirements in $106 ** Annual revenue requirements, 1984 $ First year Levelized $10* $106 NOX SO, Paniculate Total SO, Paniculate Total Base case, 500 MW, 80% NOX removal Case 1 21.9 28.8 9.8 60.4 35.8 41.0 12.8 89.7 Case 2 26.5 12.7 14.4 53.6 43.5 16.9 19.0 79.4 Case 3 24.7 18.0 12.1 54.8 40.4 24.9 15.8 81.0 Case variation, 200 MW, 80% NOX removal Case 1 9.7 16.3 5.2 31.2 15.6 23.1 6.9 45.6 Case 2 11.6 7.6 7.7 26.8 18.7 10.1 10.4 39.2 Case3 11.1 11.0 6.6 28.7 17.8 15.3 8.8 41.9 Case variation, 1,000 MW, 80% NOX removal Case 1 41.5 48.8 16.1 106.4 68.1 69.2 20.9 158.2 Case 2 51.2 22.2 24.5 97.9 84.2 29.2 31.8 145.1 Case 3 47.9 30.3 20.5 98.7 78.4 41.4 26.4 146.3 Case variation, 500 MW, 90% NOX removal Case 1 26.1 28.8 9.8 64.6 42.9 41.0 12.8 96.7 Case 2 30.1 12.7 14.4 57.2 49.5 16.9 19.0 85.4 Case3 28.6 18.0 12.1 58.6 46.8 24.9 15.8 87.5 'Table 1 lists the major design conditions for each case. bAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. Table 5. Summary of Annual Revenue Requirements in Mills/KWH6 a-b Annual revenue requirements, 1984 $ First year Levelized Milts/kWh NO, SO, Paniculate Total NOr SO? Paniculate Total Base case, 500 MW, 80% NOX removal Case 1 8.0 10.5 3.5 22.0 13.0 14.9 4.7 Case 2 9.6 4.6 5.2 19.5 15.8 6.2 6.9 Case3 9.0 6.5 4.4 19.9 14.7 9.0 5.7 Case variation, 200 MW, 80% NOX removal Case 1 8.8 14.8 4.7 28.4 14.2 21.0 6.3 Case 2 10.6 6.9 7.0 24.4 17.0 9.2 9.4 Case 3 10.1 10.0 6.0 26.1 16.2 13.9 8.0 Case varaition, 1,000 MW, 80% NOX removal Case 1 7.5 8.9 2.9 19.3 12.4 12.6 3.8 Case 2 9.3 4.0 4.5 17.8 15.3 5.3 5.8 Case3 8.7 5.5 3.7 18.0 14.3 7.5 4.8 Case variation, 500 MW, 90% NOX removal Case 1 9.5 10.5 3.5 23.5 15.6 14.9 4.7 Case 2 10.9 4.6 5.2 20.8 18.0 6.2 6.9 Case3 10.4 6.5 4.4 21.3 17.0 9.0 5.7 32.6 28.9 29.5 41.5 85.7 38.1 28.8 26.4 26.6 35.2 31.1 31.8 "Table 1 lists the major design conditions for each case. bAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. ------- other processes in the system, eco- nomic comparisons on a process-by- process basis must be interpreted with care, as seen in the detailed breakdown of the base case costs. Base Case Capital Investments Breakdowns of the base case capital investments are shown in Table 6. The case 1 (3.5% sulfur coal, SCR, limestone FGD, and cold-side ESP) capital invest- ment is $187 million (373 $/kW), of which NOX control accounts for 22% of the total; S02 control, 55%; and particu- late control, 22%. The case 2 (0.7% sul- fur coal, SCR, spray dryer FGD, and bag- house) capital investment is $167 million (333 $/kW), and the breakdown is 30%, 32%, and 38%. The case 3 (0.7% sulfur coal, hot-side ESP, SCR, and lime- stone FGD) capital investment is $171 million (342 $/kW), and the breakdown is 28%, 40%, and 32%. The low percent- age for S02 control in case 2 with the spray dryer results from the paniculate collection costs for FGD waste being combined with the fly ash collection costs and assigned to particulate control costs. NOX Control For NOX control, the most important capital cost is the initial catalyst charge, which is almost one-third of the total capital investment. Most of the remain- ing capital costs are for the reactor and the associated internal and external cat- alyst supports and handling system, and for the incremental fan cost and flue gas ductwork associated with flue gas handling. The remaining capital costs- ammonia storage and injection system, air heater modification, waste disposal (of spent catalyst), land, and royalties— are relatively minor. Incremental fan costs are minor; 90% of the flue gas- handling costs is for ductwork. Most of the capital costs are directly related to the flue gas volume, particu- larly for the major cost areas. As a re- sult, the total capital investment for NOX control in case 1 is lowest because of lower flue gas volume with the high-Btu coal. Case 3 is slightly lower than case 2 because of the absence of fly ash. Air heater modification costs are associated with the increase in size, the more tightly packed elements, and the use of thicker and more corrosion- resistant elements. The ammonia storage and injection costs are almost the same for all three cases. The only cost differences result from differences in the injection grid, which vary with the flue gas duct size and design. S02 Control The capital investments for SO2 con- trol are highest for case 1 and lowest for case 2, but the capital investment for case 2 does not contain the costs for FGD waste collection. In all three cases, most of the costs are associated with the S02 absorption area (the absorbers and the absorbent liquid system or the spray dryers) and the flue gas-handling area (fans and ductwork). These two areas account for 65% of the process equipment costs in case 1 and about 80% of the process equipment costs in cases 2 and 3. The higher capital investment for case 1 (as compared with case 3) is al- most entirely related to the larger quan- tities of SO2 removed. The materials handling (limestone), feed preparation, Table 6. Base Case Capital Investment Comparison8 Case 1,$1000s Process capital NH3 storage and injection Reactor Flue gas handling Air heater Materials handling Feed preparation SO2 absorption Oxidation Reheat Solids separation Lime particulate recycle Particulate removal and storage Particulate transfer NOX 1,314 7,829 3,843 819 S02 11,343 2,528 4.717 20,411 2,677 3,653 3,681 Particulate Total 1,314 7,829 1,311 16,497 819 2,528 4,717 20,411 2,677 3,653 3,681 10,509 10,509 5,636 5,636 NOX 1,328 9,278 4,543 1,220 Case 2, $1000s S02 7,374 1,132 1,258 12,992 2,140 Particulate Total 1,328 9,278 4,961 16,878 1,220 1,132 1,258 12,992 2,140 15,446 15,446 6,779 6,779 NOX 1,297 8,453 5,386 861 Case 3, $1000s S02 Particulate 11,175 4,290 1,266 2,363 18,070 2,265 14,354 4,378 Total 1,297 8,453 20,851 861 1,266 2,363 18,070 2,265 14,354 4,378 Total process capital, $1000s Other Capital Investment 13,805 49,010 17,456 80,271 16,369 24,896 27,186 68,451 15,997 35,139 23,022 74,158 Waste disposal direct investment Land Catalyst Royalty Other» Total, $1000s Total, $/kW° 19 10 12,028 463 15,530 41,855 83.7 4,011 458 48,360 101,839 203.7 3,344 377 21,710 42,887 85.8 7,374 845 12,028 463 85,600 186,581 373.2 34 15 14,678 563 18,431 50,090 100.2 527 75 28,478 53,976 108.0 2,749 326 32,388 62,649 125.3 3,310 416 14,678 S63 79,297 166,715 333.4 30 15 13,455 563 18,001 48,061 96.1 847 113 33,272 69,371 138.7 2,628 313 27,583 53,546 107.1 3,505 441 13,455 563 78,856 170,978 342.0 'Table 1 lists the major design conditions for each case. bConsists of costs for "services, utilities, and miscellaneous;" all six items of "indirect investment;" "allowance for start-up and modifications;' "interest during construction;" and "working capital" as listed in the appendix tables of the full report. CAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. ------- and solids separation area costs are roughly two times higher and waste dis- posal costs are almost five times higher for case 1 than for case 3. In addition, the S02 removal requirements in case 1 require both full scrubbing—necessitat- ing steam reheat of the flue gas—and forced oxidation, neither of which is necessary in case 3. SOX control in case 2 is the least ex- pensive, primarily because of lower costs in the S02 absorption area (be- cause there is no liquid recirculation system) and in the flue-gas-handling areas (because of the lower pressure drop in the spray dryers and the econ- omy of scale with fan costs prorated be- tween S02 and particulate control). An accurate comparison of S02 control capital investment in cases 2 and 3, however, must include the costs of par- ticulate collection, which are discussed in the following section. Particulate Control The capital investments for particu- late control are $43 million for case 1, $63 million for case 2, and $54 million for case 3. In all three cases, the particu- late removal and storage area accounts for about 60% of the total particulate control process equipment costs, with the ESPs or baghouses and their hop- pers accounting for most of the area cost. The cold-side ESPs of case 1 have an installed cost of $5.9 million, and the hot-side ESPs of case 3 have an in- stalled cost of $9.8 million. Most of this difference is a result of the larger flue gas volume in case 3—both in an abso- lute sense and because the ESPs in case 3 operate at a higher temperature. The baghouses have an installed cost of $7.4 million. Much of the cost difference between cases 2 and 3 is a result of the larger size of the baghouses and the corresponding larger and more com- plex hoppers required. Particulate transfer process equip- ment costs are $5.6 million for case 1, $6.8 million for case 2, and $4.4 million for case 3. Case 2 has a more compli- cated pressure-vacuum conveying sys- tem, which accounts for most of the cost difference between cases 2 and 3. Flue-gas-handling costs are $1.3 mil- lion for case 1, $5.0 million for case 2, and $4.4 million for case 3. The lower costs for case 1 result from the smaller absolute volume and lower tempera- ture of the flue gas. In addition, the costs for cases 1 and 3 are almost totally composed of the cost of ductwork since the incremental fan costs are negligible. In the case of the baghouses, however, fan costs are significant, about equal to ductwork costs, because of the large pressure drop through the baghouses. Base Case Comparisons - An- nual Revenue Requirements The base case annual revenue re- quirements are shown in Table 7. The first-year annual revenue requirements for case 1 (3.5% sulfur coal, SCR, lime- stone FGD, and cold-side ESP) are $60 million (22 mills/kWh) with 36% associ- ated with NOX control, 48% with SO2 control, and 16% with particulate con- trol. For case 2 (0.7% sulfur coal, SCR, spray dryer FGD, and baghouse), the first-year annual revenue requirements are $54 million (19.5 mills/kWh) with 49% associated with NOX control, 24% with S02 control, and 27% with particu- late control. For case 3 (0.7% sulfur coal, hot-side ESP, SCR, and limestone FGD), the first-year annual revenue require- ments are $55 million (19.9 mills/kWh) with 45% associated with NOX control, 33% with SO2 control, and 22% with par- ticulate control. The levelized annual revenue require- Table 7. Annual Revenue Requirement Element Analysis for Base Cases 500-MW Unit with 80% NOX Removal* Case 1 Direct costs Ammonia Catalyst Lime/limestone Operating labor and supervision Process Landfill Steam Electricity Fuel Maintenance Analysis Other NOX 364 13,899 66 3 51 278 1 586 46 13 S02 1,216 658 523 1,369 2,146 162 4,276 104 27 Particulate 230 436 581 135 1,025 6 19 Total 364 13,889 1,216 954 962 1.420 3,005 298 5,887 156 59 NOX 336 16,962 66 5 65 492 1 695 46 17 Case 2 SO, 708 263 83 780 18 1,599 88 16 Particulate 296 435 966 95 1,811 6 36 Total 336 16,962 708 625 523 65 2,238 114 4,105 140 69 NOX 336 15,549 66 4 63 391 1 679 46 41 Case3 S02 186 594 127 1,477 28 3,005 69 19 Particulate 230 393 993 87 1,299 6 36 Total 336 15,549 186 890 524 63 2,861 116 4,983 121 96 Total direct costs, $1000 INDIRECT COSTS Overheads Capital charges Total first-year annual revenue requirements 57000s Mills/kWhi> 15,307 10,481 421 6,153 21,881 8.0 3,337 14,970 28,788 10.5 2,432 1,018 6,304 9,754 3.5 28,220 18,68S 3,555 4,776 487 27,427 7,363 60,423 26,535 22.0 9.6 1,220 7,934 12,709 4.6 3,645 1,529 9,209 14,383 5.2 25,885 17,176 5,505 3,236 24,506 477 7,065 53,627 24,718 19.5 9.0 2,277 10,198 17,980 6.5 3,044 1,157 7,871 12,072 4.4 25,725 3,911 25,134 54,770 19.9 Levelized annual revenue requirements $1000s Mills/kWht- 35,816 13.0 41,031 14.9 12,811 4.7 89,658 32.6 43,521 15.8 16,940 6.2 18,967 6.9 79,428 28.9 40,359 24,875 14.7 9.0 15,794 5.7 81,028 29.5 'Table 1 lists the major design conditions for each case. hAII values have been rounded; therefore, totals do not necessarily correspond to the sum of the individual values indicated. ------- ments are $90 million (33 mills/kWh), $79 million (29 mills/kWh), and $81 mil- lion (30 mills/kWh) for cases 1, 2, and 3, respectively. For cases 1, 2, and 3, re- spectively, 40%, 55%, and 50% of the total levelized annual revenue require- ments are associated with NOX control; 46%, 21%, and 31% with S02 control; and 14%, 24%, and 19% with paniculate control. The cost per ton of pollutant removed is presented for the base cases in Table 8 based on each of first-year and levelized annual revenue requirements. A comparison on this basis indicates that NOX control is significantly less cost effective than S02 and paniculate con- trol. For example, with first-year annual revenue requirements, the costs in Table 8 range from about 3,500 $/ton to 4,600 $/ton for NOX control, from about 500 $/ton to over 1,900 $/ton for S02 control, and from 60 $/ton to 130 $/ton for particulate control. NOX Control The first-year annual revenue require- ments for the NOX control processes in cases 1, 2, and 3, respectively, are $22 million (8 mills/kWh), $27 million (10 mills/kWh), and $25 million (9 mills/ kWh). In all cases, the catalyst replace- ment costs are the overwhelmingly dominant cost elements; over 90% of the direct costs and two-thirds of the total annual revenue requirements are for the yearly replacement of catalyst. Except for this cost, the annual revenue requirements are modest, appreciably less than the costs for similar cost cate- gories for S02 and paniculate control. S02 Control The first-year annual revenue require- ments for the S02 control processes are $29 million (11 mills/kWh), $13 million (5 mills/kWh), and $18 million (7 mills/ kWh) for cases 1, 2, and 3, respectively. Again, case 2 with the spray dryer does not include costs associated with opera- tion of the baghouse. Excluding capital charges (which are proportional to capi- tal investment) and overheads (which are proportional to the direct costs), the direct costs of the annual revenue re- quirements reflect appreciably wider differences in operating costs. The di- rect costs are $10.5 million, $3.6 million, and $5.5 million for cases 1, 2, and 3, respectively. Maintenance costs are the highest element of direct costs in all three cases, followed again in all three cases by electricity costs. Steam for re- Table 8. Cost per Ton of Pollutant Removed for Base Cases 500-MW Unit with 80% NOX Removal $/ton, 1984$ First year Case 1 Case 2 Case3 NOX 3,490 4,600 4,280 SO2 470 1,370 1,930 Paniculate 60 130 110 NOX 5,710 7,540 6,990 Levelized SO2 670 1,820 2,680 Paniculate 80 170 140 heating the flue gas is the third largest direct cost (13% of the total) in case 1, a cost not incurred by cases 2 and 3, which have bypass reheat. These costs and the. remaining direct costs are all higher for case 1 than the correspond- ing costs for cases 2 and 3, a result of the large quantity of S02 removed for case 1. With the exception of lime costs, which are 20% of the total direct costs, case 2 has lower direct costs in every category as compared with case 3. Paniculate Control The first-year annual revenue require- ments for particulate control are $10 million (4 mills/kWh), $14 million (5 mills/kWh), and $12 million (4 mills/ kWh) for cases 1, 2, and 3, respectively. The annual revenue requirements for case 2, however, also include the collec- tion of the spray dryer FGD solids. Among the direct costs, maintenance costs are the highest direct cost in all three cases, followed by electricity costs and labor costs. Maintenance costs are highest for case 2, which are about 75% higher than case 1 and 40% higher than case 3. Electricity costs are lowest for case 1 and highest for case 3, while case 2 has only slightly lower electricity costs than case 3. Labor costs do not differ appreciably, although process labor in case 2 is about 25% higher than in cases 1 and 3. Energy Requirements The energy consumptions of the base cases, expressed in Btu equivalents, are shown in Table 9. The total energy requirements range from 4.89% of the boiler capacity for case 1 to 2.31% of the boiler capacity for case 2. The NOX con- trol energy requirements are the lowest in all three cases and most are for the incremental electricity consumption of the boiler ID fan that compensates for the relatively small pressure loss in the reactors. For SOX control, cases 1 and 3 have large electricity requirements be- cause of the FGD booster fans and the pumping requirement for the absorbent liquid recirculation systems. These are similar in both cases. The electricity re- quirements for the spray dryer in case 2 are lower because there is no liquid re- circulation system. Paniculate control energy requirements in cases 1 and 3 are mostly for-ESP electricity, which is substantially lower for the cold-side ESP. In case 2, most of the electricity is for the booster ID fans that compensate for the relatively higher pressure drop in the baghouse. Power Unit Size Case Variation The capital investments and annual revenue requirements of systems for 200-MW, 500-MW, and 1,000-MW sys- tems are shown in Tables 2 through 5. Compared with the 200-MW systems, the 500-MW systems are 83% to 91% higher and the 1,000-MW systems are 222% to 247% higher in capital invest- ment. In terms of $/kW, the 1,000-MW systems are about one-third less expen- sive, however, because of the economy of scale. The general relationships of the three cases remain the same at all three power unit sizes. The rate of capi- tal investment increase is greatest for the NOX control processes (an increase of 275% to 292% between the 200-MW and 1,000-MW sizes, as compared with 193% to 207% for the S02 control pro- cesses and 224% to 253% for the partic- ulate control processes), and it is also higher for the spray dryer FGD process and the baghouse than for the lime- stone FGD process and ESPs. As a re- sult, the rate of capital investment in- crease with size is greatest for case 2. Compared with the 200-MW systems, the annual revenue requirements of 500-MW systems are 91% to 100% higher, the 1,000-MW systems are 241% to 265% higher, and there is approxi- mately a one-third reduction in costs in terms of $/kWh. As with capital invest- ------- ment, the annual revenue requirements retain the same general relationships at the three power unit sizes, the rates of increase for the NOX control processes are higher (328% to 341% between the 200-MW and the 1,000-MW sizes, com- pared with 175% to 199% for the S02 control processes and 210% to 218% for the paniculate control processes) and the rates for the spray dryer FGD and bag house are higher than those of the limestone FGD systems and ESPs. 2-Year Catalyst Life Case Variation To illustrate the effect of catalyst life on annual revenue requirements, the annual revenue requirement for the three 500-MW base cases were also de- termined for a 2-year catalyst life. The only change in NOX control annual rev- enue requirements is a reduction in the catalyst cost by 50%—$7.0 million, $8.5 million, and $7.8 million for cases 1,2, and 3, respectively. The longer cat- alyst life reduces the annual revenue re- quirements of NOX control by one-third. The annual revenue requirements of the overall systems are reduced by 12% to 16%. 90 Percent NOX Reduction Case Variation To evaluate the economic effects of a 90% reduction in NOX, as compared with the 80% used in the other evalua- tions, the economics of the three 500- MW cases were determined with 90% NOX reduction. The primary differences from the base case conditions are an NH3:NOX ratio of 0.91:1.0 instead of 0.81:1.0, a 12% increase, and an in- crease in catalyst (based on vendor rec- ommendations) of 22.5% for case 1, 15.0% for case 2, and 18.0% for case 3. The capital investments of the NOX con- trol processes are increased 11 % to 15% and the total for the three systems by 3% to 4%, all of which is a result of the increase in NOX reduction. The first-year annual revenue requirements for the NOX process are increased 19%, 14%, and 16% for cases 1, 2, and 3, respec- tively. The effect on the annual revenue requirements of the overall system of increasing the NOX from 80% to 90% is an increase of 7% in all three cases. Ammonia Price Case Variation Changes in the price of ammonia would have little effect on the overall cost of the NOX control process. The an- nual revenue requirements for the NOX Table 9. Comparison of Base Case Energy Requirements Case Steam, 106 Btu/hr Electricity, 106 Btu/hr Diesel fuel, 106 Btu/hr Percent of power unit, input energy Case 1" NOX SOX Paniculate Total Case 2" NOX SOX Paniculate Total Case 3" NOX SOX Paniculate Total 3.15 83.79 0.00 86.94 4,00 0.00 0.00 4.00 3.88 0.00 0.00 3.88 12.97 100.20 27.14 140.31 25.40 40.26 49.85 115.51 20.18 76.20 51.22 147.60 0.01 2.65 2.20 4.86 0.02 0.30 1.55 1.87 0.02 0.46 1.41 1.89 0.34 3.93 0.62 4.89 0.56 0.77 0.98 2.31 0.46 1.46 1.00 2.92 Note: Does not include energy requirement represented by raw materials. "Based on a 500-MW boiler, a gross heat rate of 9,500 Btu/kWh for generation of electricity, and a boiler efficiency of 90% for generation of steam. bBased on a 500-MW boiler, a gross heat rate of 10,500 Btu/kWh for generation of electricity, and a boiler efficiency of 90% for generation of steam. control processes (in the 500-MW base case) increase only 1.5% to 1.9% as the ammonia price is doubled from the base case value of 155 $/ton to 310 $/ ton. Conclusions The total costs for case 1, based on 3.5% sulfur coal, and cases 2 and 3, based on 0.7% sulfur coal, differ less than 15% in capital investment and an- nual revenue requirements in spite of the differing control processes. This is a result in part of offsetting differences— the much higher SO2 control costs for case 1 are offset by lower fly ash control costs and a smaller flue gas volume. The costs for the two low-sulfur coal cases, one with a spray dryer FGD sys- tem and baghouse and the other-with limestone FGD and a hot-side ESP, dif- fer only marginally in cost. In the two low-sulfur coal cases, the low spray dryer FGD costs and the advantage of combined •particulate collection are off- set by the higher NOX control costs and higher baghouse costs. When only the S02 and fly ash control costs are com- pared, the spray dryer-baghouse case is 5% lower in capital investment and 12% lower in annual revenue requirements than the hot-side ESP and limestone FGD case. The combined emission control pro- cesses increase the power plant capital investment by about 35% on the aver- age, of which the NOX portion is about one-third. Base on levelized annual rev- enue requirements, the average in- crease in the cost of power is about 45%, of which the NOX portion is about half. The energy requirements of 2% to 5% of the boiler input energy are mostly for SO2 and particulate control. For the cases with limestone FGD, S02 control has the highest energy requirements. The use of flue gas treatment for IMOX control, such as the SCR process in this study, would add significantly to emis- sion control costs. An SCR process for a 500-MW power plant would have a cap- ital investment of 80 to 100 $/kW and annual revenue requirements of 8 to 9 mills/kWh. The high cost is largely as- sociated with the catalyst replacement cost, which accounts for 90% of the di- rect costs in annual revenue require- ments. A 2-year catalyst life reduces the annual revenue requirements by over one-third, however, so the costs for NOX control in this study, which are based on a 1-year life, could be substantially re- duced if extended catalyst lives are attained. Other than catalyst life, the main fac- 8 ------- tor affecting N0>< control costs is the flue gas volume which determines the fan and ductwork costs and the catalyst vol- ume. Increasing the NOX reduction effi- ciency from 80% to 90% increases the costs by 10% to 20%, again because of the larger catalyst volume needed. Am- monia costs have almost no effect on costs; doubling the price of ammonia increases the annual revenue require- ments by about 2%. Although the costs of NOX control are in the same general range as those for S02 and fly ash control, if the processes are compared on the basis of the pounds of pollutants reduced, the costs for NOX control are 2 to 10 times greater than for S02 control and 40 to 60 times greater than for ash control. In S02 control, the major costs are as- sociated with the absorption area and flue gas handling (ductwork and fans). These costs do not differ greatly among the three cases because of offsetting dif- ferences—a larger cost for liquid circu- lation in the high-sulfur coal case but a larger flue gas volume in the low-sulfur coal cases, which requires larger equip- ment and has larger fan costs. The higher costs for the high-sulfur coal case are in large part the result of the much larger quantity of sulfur removed: the materials-handling, waste-handling, and disposal costs are two to five times higher for the high-sulfur coal case than for the low-sulfur coal case with lime- stone FGD. Conversion Factors Certain non-metric units are used in this Summary for the reader's conve- nience. Readers who are more familiar with metric units may use the following to convert to that system: Non-metric Times Yields metric Btu °F Ib mi ton 1.06 5/9(°F-32) 0.454 1.61 907.2 kJ °C kg km kg J, D. Maxwell and L R. Humphries are with TV A, Off ice of Power, Muscle Shoals, AL 35660. J. David Mobley is the EPA Project Officer (see below). The complete report, entitled "Economics of Nitrogen Oxides, Sulfur Oxides, and A sh Control Systems for Coal-Fired Utility Power Plants," (Order No. PB 85-243 103/AS; Cost: $28.95, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Air and Energy Engineering Research Laboratory U.S. Environmental Protection Agency Research Triangle Park, NC 27711 if U. S. GOVERNMENT PRINTING OFFKU985/559-111/20695 ------- 2.' fj O I ro a> m 3 TJ U) S 8 ------- |