United States Environmental Protection Agency Air and Energy Engineering Research Laboratory Research Triangle Park, NC 27711 Research and Development EPA/600/S8-89/060 May 1990 x>EPA Project Summary Municipal Waste Combustion Assessment: Waste Co-Firing V.J. Landrum and P.J. Schindler This report provides an overview of waste co-firing and auxiliary fuel fired technology and identifies the extent to which co-firing and auxiliary fuel firing are practiced. Waste co- firing is defined as the combustion of wastes (e.g., sewage sludge, medical waste, wood waste, and agricultural waste) In a unit designed to burn municipal solid waste (MSW) or refuse derived fuel (RDF) as a major fraction of total fuel Input Auxiliary fuel firing is defined as the practice whereby coal, fuel oil, or natural gas is fired in a municipal waste combustor under condititions when waste feed quantities are interrupted. This is a fairly common practice for dedicated RDF boilers, and there may be additional mass burn MWCs that meet the definition of auxiliary fuel firing. This report includes descriptions of technologies used by facilities that meet these definitions, characterizes the population, and discusses design and operating practices and available emissions data from each facility. THe report concludes with a discussion of recommended good combustion practices for waste co-firing combustors and auxiliary fuel fired MWCs. This Project Summary was developed by EPA's Air and Energy Engineering Research Laboratory, Research Triangle Park, NC, to announce key findings of the research project that is fully documented In a separate report of the same title (see Project Report ordering Information at back). Introduction Waste co-firing is defined as the combustion of wastes (e.g..sewage sludge, medical waste, wood waste, and agricultural waste) in a unit designed to burn MSW or RDF as a major fraction of total fuel input. All MWC designs have the potential to be waste co-firing units: however, some facility operating permits specify the extent to which waste can be co-fired. Auxiliary fuel firing is defined as the practice whereby coal, fuel oil or natural gas is fired in a municipal waste combustor under conditions when waste feed quantities are interrupted. This is a fairly common practice for dedicated RDF boilers, and there may be additional mass burn MWCs that meet the definition of auxiliary fuel firing. Refuse Derived Fuel Firing RDF combustion technology includes suspension firing, semi-suspension firing, and fluidized bed combustion. Suspension firing is restricted largely to fossil fuel co-fired units. Nearly all dedicated RDF combustors are spreader stokers, which burn RDF in a semi- suspension mode. The RDF is normally injected into the combustor through airswept distributors on the front wall of the furnace. A portion of the fuel burns in suspension and the remainder falls to a traveling grate where burnout is completed. All RDF spreader stokers use waterwall boilers to produce steam and, in some cases, generate electricity, and most of these units are equiped with oil or natural gas burners that can provide up to 100% of design heat input. A Fluidized Bed Combustor (FBC) is a reaction vessel containing a bed of inert solid particles (typically sand, limestone, or alumina), which is fluidized by the upward flow of gas (air). Combustion in the FBC occurs primarily within the bed, which is interspersed with the fluidizing air and particles of fuel and ash. FBCs are characterized by extremely efficient mass and heat transfer, i.e. very uniform temperatures and mass compositions are ------- observed in both the bed and the freeboard. Efficient mass and heat transfer allows both conventional and waste fueled FBCs to operate at lower excess air and temperature levels than conventional combustion systems. Waste fired FBCs typically operate at excess air levels between 30 and 100% (5-10% 02 in the dry flue gas) and at bed temperatures around 815°C. There are many types of mass burn MWCs in the existing population of facilities, including large field-erected units with individual capacities of 100- 1000 tpd (91-907 tonnes/day), and modular shop-fabricated units of 5-120 tpd (4.5-109 tonnes/day). The large mass burn systems include conventional mass burn waterwall combustors, rotary waterwall combustors, and refractory wall incinerators. All of the large mass burn units operate in an excess air mode, with typical excess air levels of 30-150%. Most modular mass burn units include multiple combustion chambers, with the waste burning in the primary chamber and burnout of combustible products being completed in a secondary chamber. Several MWC facilities meet the definition of waste co-firing combustors by burning sewage sludge, medical waste, or wood waste, in a unit designed to burn MSW or RDF as a major fraction of total fuel input. Six plants that routinely burn sewage sludge with municipal solid waste have been identified in the existing MWC population. The plants include units using conventional mass burn waterwall combustors, mass burn refractory wall combustors, modular excess air com- bustors, and FBCs. The average sewage sludge mass input ranges from 1-10% for five facilities and is 74% for the FBC facility which was primarily designed as a sewage sludge incinerator. An additional facility has sewage sludge handling equipment, although it has never been used, and plant personnel report that there are no future plans to co-fire sludge. At least nine facilities in planning, permitting, and construction phases may burn a mixture of MSW and sewage sludge. At least 15 MWC facilities have previously accepted or are currently accepting medical waste, including three mass burnwaterwall, three mass burn refractory, three modular starved air, five modular excess air, and one FBC. Medical waste ranges from less than 1- 50% by weight of the total feed. The design and operating characteristics of these facilities are described in the "Municipal Waste Combustion Assessment, Medical Waste Combustion Practices at MWC Facilities, July 1989, EPA-600/8-89-062." Many new MWC projects are planned for construction in the next few years. All of these facilities have the potential to accept medical waste along with MSW. Existing facilities also have the potential to begin accepting medical waste with their MSW. There are strong economic incentives for other MWCs to accept medical waste; much higher tipping fees can be charged for medical waste than for MSW. As a result of these incentives, there is a high potential for additional MWCs to accept medical waste routinely. Wood waste is routinely fired in three MWC facilities. The annual average mass input of wood waste is 10-40%. At least 13 facilities in planning, permitting, and construction phases may burn a mixture of wood and MSW. Auxiliary Fuel Firing Auxiliary fuel firing is limited to MWCs that produce steam, and is generally practiced only as necessary to maintain steam load when waste supplies are curtailed or interrupted. Although some mass burn facilities may fire auxiliary fuel when waste is not available, auxiliary fuel firing is more commonly practiced by RDF spreader stokers than by other designs. Because of the manner in which feeding takes place (air swept distributors), plugging of feed mechanisms is a more persistent problem in RDF spreader stokers. Therefore, it is necessary to have the ability to fire an auxiliary fuel in order to maintain steam load when these problems occur. These facilities are described briefly below. Most RDF spreader stoker facilities are equipped with natural gas as the auxiliary fuel with rated capacities of 14-100%. Coal can provide 100% of the rated capacity for these facilities.At least one additional RDF-fired facility was designed to burn RDF and/or coal. However, the units have not burned coal for several years, and there are no plans to resume this practice. Two additional facilities have been identified that plan to co-fire RDF and coal in FBC boilers. Currently, no chlorinated dibenzo-p-dioxin/chlorinated dibenzofuran (CDD/CDF data are available from RDF spreader stokers co- firing coal. Testing at Mid-Connecticut in 1988-89 should provide these data. Emissions were tested at the Albany, NY facility in 1984 while firing 100% RDF and also while firing RDF with 15% natural gas. CDD/CDF emissions were measured in the stack during both tests. The tetra- through hepta-CDD/CDF homolog groups were quantified (no octa- CDD/CDF) for both test conditions. Total CDD/CDF emissions were 440 ng/dscm while firing 100% RDF, and 840 ng/dscm while firing 85% RDF with 15% natural gas. The natural gas burners are on the rear wall of the boiler about half way between the traveling grate and the over fire air ports. It is suspected that, when the gas burners are operating, mixing patterns may be disrupted in the boiler, increasing vertical gas velocities in the lower portion of the combustion chamber. This may allow pockets of unburned material (gaseous and solid) to escape from the boiler without being properly mixed, resulting in higher CDD/CDF emissions in the stack. The existing population of waste co- fired MWCs includes all combustor designs, and each of these combustors can potentially burn a wide variety ol waste and fossil fuel mixtures. The currently available emissions data base does not support any conclusion that, foi a given combustor design, CDD/CDF emissions from waste co-firing facilities will differ substantially from 100% MSV\ or RDF combustion. CDD/CDF emission; have been measured from man} combustion sources, including units tha burn sewage sludge, wood, coal, ant medical waste. However, for these fuels CDD/CDF emission levels appear t( depend more on combustion condition: than on waste feed characteristics. Good Combustion Practices The good combustion practice developed for MSW and RDI combustors are based on two mai concepts: 1) Sufficient mixing must be achieve at a temperature adequate t maximize the destruction of trac organics. 2)Conditions that promote lo temperature formation of trac organics must be minimized. These basic concepts apply to all MW systems, and hence, to all waste co-firir MWCs. They are necessary conditior for minimization of CDD/CDF emissions. The requirements that will minimu CDD/CDF emissions do not change wi waste feed. However, when firing mixture of wastes and/or fossil fuel conditions may arise that will lirr operation. For example, the high moistu content of sewage sludge may impose maximum sludge firing rate to mainte the required temperature at the fu mixed location. A typical sewage sludi with 20% solids and a dry heating val ------- of 7000 Btu/lb (1.63 x 10? J/kg) will have net as-fired heat input near zero. .'herefore, the heat required to maintain temperatures in the combustor must be contributed from an additional source. It may be necessary for mass burn systems to have air preheat or to fire an auxiliary fuel when burning MSW/sludge mixtures. These considerations are important when designing new systems or retrofitting existing MWCs to fire sludge along with MSW. Sometimes, excess air levels and combustion air distributions will also change slightly when co-firing waste. Combustion of wood waste, particularly in RDF spreader stokers, may contribute to high carryover of entrained particulate matter, which may contribute to low- temperature downstream formation mechanisms that lead to higher CDD/CDF emissions. As a result, it is important to design all systems to minimize the potential for these conditions. Auxiliary fuel firing in MWCs should be designed so that adequate mixing at necessary temperatures occurs for all firing conditions. This can beaccomplished by conducting flow modeling studies on new and existing boilers to determine the optimum location and firing rate for auxiliary fuel burners that will be used in combination with MSW or RDF combustion. By applying appropriate design and operating practices to ensure good mixing, auxiliary fuel firing MWCs can maintain low emissions of air pollutants. ------- V. Landrum and P. Schindler are with Energy and Environmental Research Corp., Durham, NC 27707. James D. Kilgroe is the EPA Project Officer (see below). The complete report, entitled "Municipal Waste Combustion Assessment: Waste Co-Firing," (Order No. PB90-161 001/AS; Cost: $15.00, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Air and Energy Engineering Research Laboratory U.S. Environmental Protection Agency Research Triangle Park, NC 27711 U.S.OFFICIAL MAIL United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 /ju - |^ K XP\-L ,^»LTV /JSE S300 s * * _/ a METER £- — 6000444 U.S.POSIAGf s 0 2 5 - Official Business Penalty for Private Use $300 EPA/600/S8-89/060 000085833 PS ------- |