United States
 Environmental Protection
 Agency     	
 Air and Energy Engineering
 Research Laboratory
 Research Triangle Park NC 27711
 Research and Development
 EPA/600/S8-89/061 Mar. 1990
 Project Summary
 Municipal  Waste  Combustion
 Assessment:  Fluidized  Bed
 Combustion
 L.P. Nelson
  This report describes an assess-
ment of combustion control practices
to minimize  air •emissions from
refuse-fired fluidized bed combustors
(FBCs). The three FBC configurations
are described along with the design
and  operating  characteristics  of
each, and the manufacturers  of
refuse-fired FBCs are  identified. The
waste-fired FBC population is over-
viewed, including existing, planned
and/or projected, and recently can-
celled facilities. Operating and emis-
sions data are presented for the two
existing  U.S.  facilities  and one
Swedish circulating bed plant
  The  good combustion  practice
(GCP) design, operating/control, and
verification recommendations  devel-
oped  for FBCs as  part of this
assessment  are  summarized. The
GCP recommendations  comprise a
set of specifications and procedures
designed  to  minimize emissions  of
organic compounds. Quantitative rec-
ommendations are provided  for a
number of the components; where
lack of data or dependence on site-
specific factors  precludes  quantita-
tive guidance, generic recommenda-
tions are presented.
  Two  model plants  developed  to
represent  the population  of  FBCs
projected  to  be  placed in  operation
after the end of 1989 are described.
The  models are  evaluated  to
determine  the extent  to which the
GCP recommendations are  incorpor-
ated within the projected population.
  This Project  Summary was
developed  by EPA's Air  and Energy
Engineering  Research  Laboratory,
Research  Triangle  Park,  NC, to
 announce key findings of the research
 protect that is fully documented in a
 separate report of the same title (see
 Pro/ect Report ordering information at
 back}.

 Introduction
   Based upon its analysis of Municipal
 Waste Combustors  (MWCs),  EPA has
 determined that MWC emissions may
 reasonably be anticipated to contribute to
 the endangerment of public  health and
 welfare and warrant further regulation. As
 a  result, EPA's Office of Air Quality
 Planning and Standards  is developing
 emission standards for new MWCs under
 Section 111(b) of the Clean Air Act (CAA)
 and guidelines for existing MWCs under
 Section 111(d) of the CAA. In support of
 these regulatory development efforts,  the
 Air and Energy  Engineering Research
 Laboratory in EPA's Office of Research
 and Development has conducted an in-
 depth assessment of combustion control
 practices to minimize air emissions from
 MWCs. This report documents the results
 of that assessment for one specific MWC
 technology:  fluidized bed combustors
 (FBC).
    Objectives of this report were to
 identify the population  of  existing and
 planned refuse-fired  FBC facilities in  the
 U.S., examine the design characteristics
 and operating practices  employed, define
 one or more model plants representative
 of the projected population, and develop
 recommendations for implementing good
 combustion practices for  the control of
 organic emissions from FBCs.

 Two Types of Combustors
   Two types of FBCs are currently used
or projected for use for refuse firing in the

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U.S., bubbling bed  FBCs and circulating
fluid  beds  (CFBs).  The  two  are
distinguished  primarily  by  the  bed
configuration. The relatively low fluidizing
air velocity in the bubbling bed produces
a stationary  bed (consisting  of approx-
imately 99% inert material and 1% fuel)
that resembles a violently boiling liquid.
The higher fluidizing  air velocity  of the
CFB entrains a significant portion of the
bed material and  carries  it out of the
reactor vessel. Solids  are disengaged
from the  CFB  gas  stream  in  a hot
cyclone and reinjected into the reactor.
  The existing population of  waste-fired
FBCs in the U.S. consists of four units at
two facilities. All  of the units  in the
population are  bubbling beds.  The
Western Lake Superior Sanitary District
(WLSSD) co-fires  120 tons/day of RDF
and 350 tons/day of  wood chips  in two
Energy Products of Idaho FBC units at
their French Island  Generating  Facility in
La  Crosse,  Wl. Both facilities  have
demonstrated  total  tetra-  to octa-chlor-
inated dibenzo-p-dioxin and dibenzofuran
(CDD/CDF) emissions  rates  below  20
ng/Nm3 in compliance tests.
  The planned and  projected  refuse-
fired FBC population includes two units at
one facility in the construction  stage and
13 to 16 units at  seven facilities in the
feasibility study  or  early planning stage.
Seven  other facilities  that  were included
in EPA's list  of planned  and projected
facilities in  May 1988 have  either been
cancelled or altered the project in a way
that caused  its  removal from the FBC
population.

GCP Recommendations
  QCP recommendations  consist of
combustor design  and  operating
specifications  and  procedures designed
to minimize  emissions  of organic  com-
pounds. GCP  recommendations  were
presented  in the Report to Congress for
three  MWC technologies; these  recom-
mendations  have  subsequently  been
updated to account for recent data and
expanded to cover the full range of MWC
technologies. The design  and operating
parameters  affected by  the  GCP
recommendations  are: Fuel feeding,
temperature  at fully  mixed conditions,
combustion air capacity and distribution,
mixing, particulate  matter carryover,
auxiliary fuel capacity,  and downstream
gas  temperature.  These  components
were  selected  because  each is indi-
vidually necessary to the implementation
of proper organic emissions control and
the set, as a whole, is sufficient to ensure
adequate control. Quantitative  GCP
recommendations were developed during
this assessment  for the temperature  at
fully  mixed  conditions,  overfire  air
capacity, downstream  gas temperature,
and  CO in  flue gas;  generic  recom-
mendations were identified for the other
components.
   GCP  recommendations in EPA's 1987
Report  to Congress  for  other MWC
technologies specified a  mean fully
mixed temperature of 980°C; however,
these recommendations were  based on
the need  to maintain a  conservative
minimum temperature of  900°C where
significant   spatial  and  temporal
temperature  variations  have been
observed. FBC systems inherently have
extremely  efficient  mixing  and  uniform
temperature cross-sections, so the appli-
cation of a safety factor to account for
temperature  variations is not necessary.
Compliance tests for the two existing U.S.
FBC facilities conducted at between 815
and  870°C  resulted  in low CDD/CDF
emissions. Also, precedence for  a lower
temperature requirement has been estab-
lished in  permit  limits  set  by the
Pennsylvania Department of Environmen-
tal Regulation for the  Erie County  CFB
(790 °C)  and the Wisconsin Department
of Natural  Resources  for the  French
Island facility (815°C). These factors sup-
port  the establishment of 815°C as the
GCP  recommendation  for fully mixed
temperature in FBCs.
   The compliance tests at the NSP and
WLSSD  FBC facilities  were  conducted
while the  units  were  operating  with
approximately 40 and 0% of total air as
overfire  air,  respectively. Both  compli-
ance  tests resulted  in  low CDD/CDF
emissions. However, the WLSSD system
is  designed  such that  RDF  is  injected
near the bottom of the bed. In systems
where overbed feed is employed, overfire
air above the feeders may be essential to
ensuring good mixing of fuel  and air.
Thus, FBC  design recommendations
include  incorporation  of an overfire air
system capable of supplying 40% of the
total combustion  air. The 40% figure is
based on  engineering judgment of the
overfire air jet momentum requirements.
   Pilot  scale and field  test data from a
wide  variety of  sources  support the
existence  of a  mechanism whereby
CDD/CDF is formed downstream of the
combustor by the catalytic action  of fly
ash  constituents  on  the  gas  stream.
Formation  has  been observed  at
temperatures  between 200 and  400°C,
with maximum formation at about 300 °C.
Downstream  formation is  thought to be
minimized if the gas and solids residence
time at  between 200  and 400 "C are
minimized, i.e., the quench rate  through
these temperatures  is  maximized.  Ir
terms     of    practical     GCfi
recommendations, the system should b«
designed such that the gas temperature
at the inlet to the  ESP  or  baghouse i:
maintained below 230 °C.
   Flue gas CO concentration is a goo<
measure  of  combustion  conditions. A!
such, it  serves as a  convenient,  thougt
inexact,  surrogate parameter  fo
CDD/CDF emissions,  which also hav<
been correlated to good combustion. Th<
Gotaverken CFB in  Sundsvall, Sweden
maintained  CO concentrations below 5(
ppm.  The WLSSD FBC also producet
CO levels of less than  50 ppm. The NSF
CO emissions of nearly  300 ppm, havi
been attributed to the compactness of th<
freeboard. Less than  2.7 m of  furnaci
height separates the top  of the bed fron
the entrance to  the first  convectivi
section.  While  this  space may  bi
sufficient for  oxidation of gas-phase or
ganics   which  occurs  essential!
instantaneously (assuming the other GCI
recommendations are  in  place), it is nc
sufficient to complete oxidation of CO t
C02. Thus, 50 ppm (4-hour average) ha
been specified as the flue  gas CO GCI
recommendation for FBCs.
   Two   FBC  model  plants   wer
developed to provide the basis for EP,
health and economic impact analysis c
the MWC regulation.  Separate  model
were required because of the significar
variation between bubbling  bed and CFl
CDD/CDF emissions.  The  bubbling be
model plant represents the population c
new bubbling bed facilities expected  t
be  placed in operation  after regulatio
proposal  at the  end of 1989. Based o
existing performance and emissions dat;
the bubbling bed model plant was judge
to incorporate all of the GCP design an
operation/control  recommendations. Th
CFB model  plant was  based  on th
Gotaverken design, the only CFB desig
in the planned/projected  population. Tr
CFB  model plant   was  judged 1
incorporate  all  of  the  GCP  recon
mendations except minimizing particula
matter (PM) carryover. If the primary P'
control device allows a significant fractic
of the PM to pass into the boiler, organ
and organic precursor material adsorbs
on the PM may escape destruction. Fie
test data from a mass burn waterwall ar
an  RDF  spreader stoker  MWC ha\
shown a  strong correlation between  P
carryover and CDD/CDF emissions. Tl
relatively high CDD/CDF emissions fro
the CFB  model plant are also attribuft
to  this  mechanism. Unless a  mo
efficient primary PM  collection  devii
can  be incorporated into  the  desig

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further reductions in  organic emissions
may have to be effected  through in-
furnace sorbent injection and/or add-on
pollution control devices.

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  L.P. Nelson is  with Energy and Environmental Research  Corp., Durham, NC
        27707.
  James D. Kllgroe is the EPA Project Officer (see below).
  The complete report, entitled "Municipal Waste Combustion Assessment:
        Fluidized Bed Combustion," (Order No. PB 90-164 0541 AS; Cost: $15.00,
        subject to change) will be available only from:
           National Technical Information Service
           5285 Port Royal Road
           Springfield, VA 22161
           Telephone: 703-487-4650
  The EPA Project Officer can be contacted at:
           Air and Energy Engineering Research Laboratory
           U.S. Environmental Protection Agency
           Research Triangle Park, NC 27711
United States
Environmental Protection
Agency
                           Center for Environmental Research
                           Information
                           Cincinnati OH 45268
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