United States
                     Environmental Protection
                     Agency
Industrial Environmental Research
Laboratory
Cincinnati OH 45268
                     Research and Development
EPA-600/S2-83-002  July 1983
SER&          Project  Summary
                     Reduced-Pollution  Corrosion-
                     Protection   Systems

                     Christian J. Staebler, Jr. and Bonnie F. Simpers
                      This  study  evaluated  newer less
                    polluting  metal plating materials and
                    processes as potential alternatives to
                    currently used plating systems. Viable
                    replacements  were  established  for
                    cyanide cadmium, cyanide copper, and
                    hexavalent  chromium electroplating.
                    Available alternatives to solvent-borne
                    paints and phenolic-type paint strippers
                    have  slightly lower  performance
                    characteristics  than  their  higher
                    polluting  counterparts.  Through
                    comprehensive testing  performance
                    characteristics were established  for
                    replacement systems of each type. The
                    performance,  economic,  and
                    environmental aspects of  the  new
                    coating systems  were compared  to
                    those for a control system currently in
                    use.
                      Alternative  coating  systems
                    evaluated for cyanide cadmium electro-
                    plating  included non-cyanide cadmium
                    electroplating, mechanical plating  of
                    cadmium and tin-cadmium, spray-and-
                    bake aluminum-filled  resin coatings,
                    and  ion-vapor-deposition   (IVD)  of
                    aluminum. Each  of  these alternatives
                    eliminated the cyanide waste treatment
                    problem  and  the  last  two  also
                    eliminated the use of cadmium, another
                    toxic material. Although none of the
                    systems evaluated can be considered a
                    better alternative to cyanide cadmium
                    electroplating, each exhibited  certain
                    advantages  while offering the same
                    basic performance as cyanide cadmium
                    plating. Non-cyanide copper electro-
                    plating  (the alternative evaluated for
                    cyanide copper electroplating) and tri-
                    valent  chromium electroplating (the
                    alternative  to hexavalent  chromium
                    electroplating) were shown to provide
                    performances  comparable  to their
                    higher polluting,  higher  waste
                    treatment requirement control systems.
  Water-borne  paints and  power
coatings, both of which eliminate the
need for solvent collection systems in
coating applications were evaluated as
potential alternatives for solvent-borne
paints.  Although  the  performance
characteristics  of these water-borne
paints  and  powder  coatings  were
shown to be comparable to those for
the solvent-borne control system, no
single  system  provided  equivalent
performance for all characteristics.
  Evaluation of  non-phenolic  paint
strippers against  phenolic strippers
demonstrated the effectiveness of the
non-phenolic strippers in eliminating
the phenolic waste disposal problem.
Both acid and non-acid immersion and
brush-on type strippers were evaluated.
  This Project Summary was developed
by  EPA's  Industrial  Environmental
Research Laboratory, Cincinnati. OH.
to  announce  key  findings  of the
research project that  is  fully
documented in a separate report of the
same title (see Project Report ordering
information at back).

Introduction
  Mounting concern over environmental
pollution, in light of more stringent EPA
and OSHA regulations, has prompted the
metal finishing industry to expand use of
newer,  less-polluting  corrosion
protection systems in place of currently
used  organic  solvent  systems and
cyanide or cadmium plating solutions.
The  aerospace  and  metal finishing
industries have  available many new
coating systems that can be considered
as non-polluting or as having reduced-
pollution characteristics compared to the
currently used systems. Corrosion resist-
ance data for these systems are  limited,
however, especially with respect to long-
term exposure.  As a result, customer

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confidence in these systems is not high
and this has inhibited their widespread
utilization.  Understandably, the  metal
finishing  industry  is  reluctant  to  the
introduction of new systems for which
supporting  test  data  are limited  and
manufacturing  costs  are not  clearly
defined. The  approach  taken in  this
project was to evaluate and demonstrate
the durability of  these new systems by
conducting extensive tests to  meet the
acceptance criteria of the aerospace and
metal finishing industries.
Conclusions
Replacement Coatings for
Cyanide-Cadmium
Electroplating
  Several replacement systems are avail-
able for cyanide-cadmium electroplating,
including non-cyanide cadmium electro-
plating, mechanical  plating, spray-and-
bake aluminum  coating, and ion-vapor-
deposited  (IVD) aluminum.  These
systems, each of which has advantages
and  disadvantages  compared  to
conventional  cadmium  electroplating,
can provide protection equivalent to that
given by cyanide cadmium electroplating
for various applications and cause fewer
harmful  environmental   effects  than
cyanide cadmium electroplating. Kadizid*,
a  non-cyanide  cadmium  electroplating
system, provides excellent adhesion and
corrosion  resistance with no  sign  of
hydrogen  embrittlement   while
eliminating the  need for cyanide waste
treatment.  Transiflo*, a  mechanically
plated  cadmium coating, provides  good
adhesion and excellent corrosion resist-
ance  with  no  sign  of hydrogen
embrittlement.  No waste treatment is
required for the  Transiflo plating system.
Alumazite Z*, a spray-and-bake aluminum
coating, provides excellent adhesion and
corrosion  resistance with no  sign  of
hydrogen  embrittlement.Since  no
cyanides or cadmium is required with use
of  Alumazite  Z,  waste  treatment
problems are eliminated. Ivadize*, an ion-
vapor-deposited (IVD) aluminum coating,
provides  excellent adhesion  and
corrosion resistance  with no potential  for
hydrogen   embrittlement.  Again,   no
cyanide or  cadmium is  used  in the
process and, as before, waste treatment
problems are eliminated.
'Mention of trade names or commercial products
 does not constitute endorsement or recommenda-
 tion for use by the U.S Environmental Protection
 Agency.
Replacement Coatings for
Organic Solvent-Borne Paints
  Now available are water-borne paints
and powder coatings that conform to the
requirements of MIL-C-81773 (polyure-
thane topcoat). The hazards associated
with the use of solvent-borne paints, as
well as the  need for solvent collection
facilities, are eliminated with the use of
either  of  these  replacement  coatings.
Three  of  the  water-borne  paints
evaluated,   including   one  air-drying
system and two  bake-curing  systems,
have coating properties close to those for
the control system. These include film
properties  (appearance, adhesion,
impact, and flexibility), fluid resistance,
and weatherability.  Five of the  powder
coatings  evaluated  also  have  coating
properties similar to those of the control
system. These  include film properties
(appearance,   adhesion,  impact,   and
flexibility),  fluid  resistance,  and
weatherability.

Replacement Coatings for
Cyanide Copper Electroplating
  A non-cyanide copper electroplating
system is available which  is capable of
performance   equivalent  to  that  of
currently  used   cyanide-type  copper
electroplating systems per MIL-C-14550.
Enthobrite Cu-942 provides  excellent
adhesion,  solderability,   and  decarb
protection  with  no  sign  of  hydrogen
embrittlement while eliminating the need
for cyanide waste treatment.

Replacement Coatings for
Hexavalent Chromium Plating
  A trivalent chromium plating system,
evaluated as a replacement for decorative
hexavalent  chromium  electroplating,
provided performance equivalent to that
for  the   hexavalent  system  while
eliminating  the  toxicity   and  waste
treatment  problems  associated  with
hexavalent  chromium.   Trichrome
showed good appearance, adhesion, and
corrosion  resistance, with  no  sign of
hydrogen embrittlement.

Replacement Coatings for
Phenolic Paint Strippers
  Several  acid and  non-acid,  brush-on
and immersion-type, non-phenolic paint
strippers   show  promise as  potential
replacements for phenolic  paint strip-
pers. The performance of these systems
approximates  that  of  the  standard
phenolic paint stripper (MIL-R-81294) in
appearance, removal power, rinsability,
coating  and  remover  residue,  and,
refinishability.
  This technology development program
established the availability of many new
less-polluting corrosion  protection
systems as viable alternatives to present
high-pollution  systems. This effort has
encouraged manufacturers to develop or
improve less-polluting metal finishing
systems. If the development efforts are
continued, aerospace and metal finishing
firms should be able  to implement the
following  new systems  with a  high
degree of confidence:

  •  Water-borne,  chemical   milling
      maskant  systems evaluated under
      the present project. These systems
      show promise as replacements for
      high-polluting systems. Additional
      pilot-plant (50-gallon)  testing  on
      both typical flat and curved panels
      are  needed  to  demonstrate the
      viability of these  systems for future
      and  most current commercial and
      military aircraft. This testing would
      provide  the data   needed  to
      implement   the less-polluting,
      water-borne  maskants within the
      critical timeframe on  such new
      aircraft as the 757 and 767  com-
      mercial  airliners and ATF,  FSW,
      V/STOL, AV-8B, and F-18 military
      aircraft.

  •  Improved water-borne paints, paint
      strippers,  and  spray-and-bake
      corrosion protection coatings are
      under  development  by  several
      manufacturers.  Development  of
      these new products is seen to be a
      direct result of thefavorablepublic-
      ity that this program has received.


Evaluation of Results
Replacement Coatings for
Cyanide-Cadmium
Electroplating
  Cadmium  is normally  plated  from
cyanide-type electroplating  baths. The
high  level  of  toxicity of  these  baths
necessitates the costly waste treatment
procedures  using  either  chlorine  or
hypochlorites  be  used to destroy the
cyanide  before   disposing  of  these
solutions. Several cyanide-free cadmium
electroplating  baths are now available;
preliminary investigations indicate that
these  baths have potential  as
replacement  systems.  Mechanical
plating  of  powdered cadmium  also
provides   a  potential  alternative for
cyanide-type   cadmium  electroplating.
\

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Several  aluminum  coatings are  also
available as potential replacements for
cadmium  plating,  lon-vapor-deposited
(IVD)  aluminum  and  aluminum-filled
resin  spray-and-bake coatings are  of
particular interest because they would
eliminate toxicity problems related to the
use of cadmium.
  Four types of  potential replacement
coatings  (Table 1) for cyanide cadmium
plating   (non-cyanide  cadmium,
mechanical  plating,  spray-and-bake
aluminum, and  IVD  aluminum)  were
tested to determine  the best system
available in each  category and to aid in
evaluating the relative merits of the four
types.  Three  non-cyanide  cadmium
plating  systems  were  evaluated   as
potential  replacements  for cadmium
cyanide electroplating. These  systems,
Lea-Ronal's Kadizid, Lea-Ronal's Cad-AI,
and  Enthone's Enthobright CAD-935,
were  evaluated  in  Hull  cell  tests  to
determine  throwing   power  and
brightness. Cadmium and tin-cadmium
applied by mechanical plating were also
considered  as potential replacement
systems  for cadmium cyanide electro-
plating. The  3M Company's  Transiflo
process was used to apply these coati ngs.
Two spray-and-bake aluminum coatings
were evaluated  as potential  replace-
ments for  cyanide cadmium  plating.
Alumazite Z from Tiodize and HiKote 3
from Hi Shear were applied to 4130 steel
panels with and  without MIL-P-23377
epoxy primer. The coatings were tested to
determine their adhesion, corrosion, and
fluid resistance.  Panels  of  4130 steel
were coated with aluminum by McDonnell
Douglas using their ion-vapor-deposition
(IVD)  process.  A  chromate  conversion
coating was applied to the coated panels.
  The  relative  corrosion  resistance  of
each  coating system was determined
using the 5%-salt spray  corrosion test.
Two to four panels of each system were
subjected to 5%-salt spray until failure.
Cyanide  cadmium-plated  panels  were
also  run as  controls.  The corrosion
resistance of a coating system, measured
as time to failure, varies with  the sub-
strate to which it is applied.
  Sustained load testing was conducted
on selected coating systems  to evaluate
the potential for  embrittlement failure
resulting   from  hydrogen  absorption.
Notched  tensile specimens  made from
both  300M  and  4340  high-strength
steels  were  coated with the  various
coating systems and subjected to a static
load at 75% of  the  ultimate  notched
tensile strength for 200 hr or until failure.
The ultimate notched tensile  strength
Table 1.    Cyanide Cadmium Replacement Coatings
Cyanide
Cadmium
• Readily
available
Non-Cyanide
Cadmium
• Reduces
waste treat-
Mechanical
Plating
Advantages
• Eliminates
cyanides
Spray-and-Bake
Aluminum
• Eliminates •
cyanides
IVD
Aluminum
Eliminates
cyanides
                  ment req.

   Techniques   • Eliminates
   well-established   cyanides
   Proven system • Conversion
                  costs low
                 Eliminates     •  Eliminates    •  Eliminates
                 hydrogen         cadmium        cadmium
                 embrittlement

                              •  Reduces waste •  Eliminates
                                 treatment req.    waste treat-
                                                ment req.
• Eliminates •
hydrogen
embrittlement
• Uses conven- •
tional spray
equipment

• Can be formu-
lated for max
performance
Eliminates
hydrogen
embrittlement
Use to 5fO°C
(950°F) (CD
limited to 232°C
(450°F)



   Uses toxic
   chemicals
•  Higher
   makeup cost
Disadvantages

Requires new
equipment
Organic solvent*
collection
system req.
Requires new
equipment
   Requires costly
   waste treatment
              •  Part size
                 limited
was determined by continuously loading
uncoated specimens until failure.
  The  performance  characteristics  of
each of the systems selected as replace-
ments  for  cyanide  cadmium  plating
approximated  those  of  the  cyanide
cadmium  control  coating.  Adhesion,
corrosion   resistance,   and  hydrogen
embrittlement were evaluated for each of
the selected coatings  (Table  2).  The
adhesion of non-cyanide cadmium plate,
spray-and-bake  aluminum, and  IVD
aluminum  was  excellent.  Satisfactory
adhesion  was   obtained  with  the
mechanical plating and cyanide cadmium
control   coatings.   When  considered
against the minimum requirements of the
QQ-P-416 and MIL-C-81562 specifica-
tions, corrosion resistance of the selected
coatings  is excellent.   IVD aluminum
showed excellent corrosion resistance on
4130 steel  with  minimal  variation  in
results  for  the   IVD  aluminum.  The
Alumazite Z coating also showed slightly
improved corrosion resistance  over the
cyanide cadmium plate for 4130 steel. No
hydrogen  embrittlement occurred as a
                         result of coating application for any of the
                         selected coatings.


                         Replacement Coatings for
                         Organic Solvent-Borne Paints
                           Paints are used in many decorative and
                         corrosion  protection  applications  for
                         home appliances,  automobiles,
                         aluminum  siding,  garden   furniture,
                         aircraft   skins,  and  many  other
                         applications.  Maskants are   used  to
                         protect parts from being etched during
                         the chemical milling process. Currently
                         used paint and maskant systems employ
                         organic solvents as volatile components.
                         Toxicity   of  these   organic   solvents
                         requires that stringent pollution-control
                         procedures be  followed in the use of
                         these systems  to  meet  established
                         standards for maximum discharge levels.
                         Besides   increasing  costs,   additional
                         problems associated with using organic
                         solvent   paints  include   flammability,
                         rising prices, and decreasing availability
                         of the solvents. The use of water as the
                         solvent component virtually eliminates

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Table 2.    Cyanide Cadmium Replacement Coatings: Performance Summary

                                        Corrosion resistance,
                                           hr to failure**
System
Cyanide cadmium
electroplate*
Non-cyanide cadmium
electroplate* (Kadizid)
Mechanical cadmium
plating* (Transit lo)
Spray-and-bake aluminum
f Alumazite Z)
IVD aluminum* (Ivadize)
Adhesion
(bend test)
Good
Excellent
Good
Excellent
Excellent
4130 4340
576 2514
— 2°76t
	 2574
700 	
7752 	
Hydrogen
D6AC embrittlement
2172 Pass
	 Pass
3522 Pass
	 Pass
	 	
 *Chromate conversion coating applied to plated panel.
 **Average of four panels.
 t/4 verage of two panels.
these problems. Several of  the water-
borne  paints currently  available  have
been  designed   to  withstand  the
applications mentioned  above.  Powder
coatings,  applied  by  fluidized  bed  or
electrostatic powder spray, also eliminate
the  problems  associated  with  organic
solvents.  Many different resins  have
been used for these 100%-solids resin
systems, each  with  a different set  of
properties. Formulations of  the  same
basic resin can be varied to adjust some of
these  properties.  Several water-borne
maskants have been developed to replace
the  organic   solvent-type systems
currently  used  for   chemical  milling
applications.
  Twelve water-borne  paint systems,
obtained  from  eight  companies,  were
evaluated. Seven of these systems cure
at  room  temperature;  five  require  a
higher  temperature cure. Each of the
systems,  as well  as  the solvent-based
control, were applied to aluminum panels
that had been pretreated and alodined.
Each topcoat was applied to the primer
supplied  for the  system;  in addition,
several of the topcoats  were applied to
the  solvent-based epoxy primer. The
panels  were  then  subjected  to
preliminary screening tests.  These tests
were performed in accordance with the
requirements of MIL-P-23377 and MIL-
C-81773.  Of  the  properties  tested,
adhesion, impact, and  flexibility were
considered most important. Test results
were analyzed to select the best coatings
for further testing. Three of the coatings,
Aquathane II and epoxy primer (air dry),
Aqualure 634-W-804  with Aqualure
primer (bake cure) and LP-3724 with LP-
3779 primer (bake cure) provided the best
combination of properties based on these
criteria.
  Eight powder coatings (acrylic, epoxy,
polyamide, polyester [three types], nylon
and vinyl) were evaluated. Each of these
resins  was  applied  by  electrostatic
powder spray to steel  and aluminum
panels.  Nylon   was  also   applied  to
aluminum and steel panels by a fluidized
bed. A  primer was used for the nylon and
polyamide coatings. Coated panels were
subjected to preliminary screening tests
according to  MIL-C-81773  procedures.
As was the case with the water-borne
paints,  adhesion, impact, and flexibility
were considered the most important of
the properties tested. Some of the resins
were applied  at two coating thicknesses
to evaluate the effect of thickness on
coating properties.
  Candidate water-borne maskants were
subjected to preliminary screening tests
to  evaluate   appearance,   peelability,
etchant resistance, line definition and
scribability. Each of the maskants had a
uniform appearance with nopin-holingor
bubbling. The thickness of the Adcoat and
Dee  Aircraft  maskants  was  12  mils
(0.0005  in.)  while that of the Turco
material was  8 mils (0.0003  in.).
  Final  characterization tests  of  the
selected  water-borne  paints  and powder
coatings  included  additional  fluid
resistance tests, higher impact levels,
and  hydrolytic stability  evaluation. The
performance  of the water-borne paints is
comparable to that of the organic solvent
paint  control  with   respect  to  most
properties; the bake-cure systems  were
slightly better than the  air-dry systems.
The selected  powder coatings performed
as well  as or  better  than the  organic-
solvent paint control in most cases. The
nylon powder coatings provided the best
overall performance.
  The selected water-borne paints and
powder coatings applied to aluminum
test  panels  were also subjected  to 12
months of outdoor (southerly) expos ure at
Grumman's Test Site located in the U.S.
Coast Guard Station at Fire Island, N.Y.
The epoxy/polyurethane control system,
as well as the Aquathane II and Aqualure
634-W-804 paint systems and the acrylic
powder coating, resisted the 12-month
weathering  period  rather well. The
coated panels experienced no significant
loss  in properties.  The  epoxy powder
coating on  aluminum  test panels also
showed no significant loss  in properties
despite chalking  and a severe loss of
gloss; however, this coating on steel test
panels  had  severe corrosion after  6
months'  exposure.  Although the  oven-
cured, water-borne paint  system  (LP
3778  primer  and LP 3724  topcoat)
showed no corrosion after 12 months'
exposure,  its  adhesion,  flexibility, and
impact  resistance  decreased  after  3
months' exposure. Polyester 156 coating
applied to aluminum test panels experi-
enced a slight decrease in impact  resist-
ance. When applied to steel test panels,
however,  the  Polyester   156 coating
showed evidence of corrosion around the
panel edges after 3 months' exposure,
with a slight decrease in flexibility and
impact resistance. Both the  nylon powder
spray and fluidized-bed coating exhibited
a sharp loss in gloss and a decrease in
flexibility  and  impact  resistance, even
though no loss of adhesion occurred. The
substrate used did not appear to affect the
wearability of these coatings. The  acrylic
and  polyamide  powder spray  coatings
showed  evidence of  corrosion after  3
months'  exposure and severe corrosion
after 6  months'  exposure,  and  were
unable to  undergo  testing  after  12
months' exposure  (corrosion was too
severe).

Replacement Coatings for
Cyanide  Copper Electroplating
  Copper  is   normally   plated   from
cyanide-type electroplating baths. The
high  level  of  toxicity of  these  baths
necessitates the use of expensive waste
treatment  procedures involving  either
chlorine  or  hypochlorites to destroy the
cyanides  before  disposing   of  these
solutions.  Several  cyanide-free copper
electroplating baths are available and
have potential to become  replacement
systems. Five cyanide-free systems were
evaluated and compared to the standard

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 Table 3.    Non-Cyanide Copper Plating: Screening Tests
                           Hull cell tests
                                           2.5 liter (0.66-gal) solution tests
System
Mac Dermid Rocheltex
(cyanide type control)
Lea-Ronal Cu-Pure

Enthone Cu-942
Bright
range,
A/m2
(A/ft2)
11-387
(1-36)
11-324
(1-30)
11-1290
Throwing
power
Good
Good

Excellent
Current
density,
A/m2
(A/ ft2)*
270
(25)
390
(36)
780
Surface
condition
Smooth
Smooth

Smooth
Edges
Slight
burning
Some
burning
No
Comments
Excessive
gassing
Some
foaming
No gassing
Plating rate,
/jm/min
(mil/min)
0.495
(0.020)
0.406
(0.0161
0.813
RMS
value
55-100
60-125

45-55
Heat treat
evaluation
Some
decarb
Minute
decarb
No
Harstan Fluoborate


M&TAC-94


M&T Pyrophosphate
(1-120)

11-774
(1-72)

11-324
(1-30)

11-234
(1-22)
                                             (72)
                     and bright  burning    or foaming  (0.032)
                                                                                                             decarb
Poor
Good
Poor
 ^Optimum current density as determined by Hull cell tests.
Mac Dermids' Rocheltex cyanide copper
plating  system. These include Cu-Pure
and Unichrome Pyrophosphate (alkaline
types),  Enthobrite Cu-942  and AC-94
Bright Acid Copper (acid sulfate types),
and Copper Fluoborate  (acid fluoborate
type).  The  five  non-cyanide,   copper
plating  systems were screened  in Hull
cell tests to determine bright range and
throwing power (Table 3). Cu-Pure and
Enthobrite Cu 942 were selected for final
screening  because they had the best
combination  of  cost,  maintenance
requirements, and bright range/throwing
power of the systems evaluated. Because
the Enthobrite Cu-924 system did not gas
or foam, gave a smooth bright plate with no
edge burning, had  a 60-100 percent higher
plating rate, and provided better protection
against  steel  decarburization,   it was
selected for further testing. Sustained-
load tests were conducted to determine
the extent of hydrogen absorption in acid
copper-plated  material and  to evaluate
the potential for embrittlement failure. All
specimens  exceeded the minimum test
requirements without failure.
  The characterization of Enthobrite Cu-
942 showed that this non-cyanide copper
plating  system exceeded the require-
ments established for copper plating in
MIL-C-14450 (Table 4). The adhesion and
solderability of the copper  plate were
excellent.   No  hydrogen embrittlement
was evident in notched tensile tests of the
Cu-942-plated specimens. The  Cu-942
plating  adequately  protected the  steel
from  decarburization  during   heat
treatment.
                 Table 4.   Enthobrite Cu-942 Non-Cyanide Copper Plating Characterization Tests

                    Property                  Procedure                       Results
                 Thickness
                 Adhesion

                 Decarburization
                 protection

                 Solderability
                 Hydrogen
                 embrittlement
                              Permascope
                              Sheet bend

                              Metallographic
                              examination

                              Solder 232°C (450°F)-
                              sheet bend
                              75% UNTS/200 hr
28-33 ^m @ 0.813 fjm/min
(1.1-1.3 mils @ 0.032 mils/min)

Excellent*
No decarburization


Excellent*


Pass
                 *Copper plate immediately following nickel strike.
                 Replacement Coatings for
                 Hexavalent Chromium Plating
                   Chromium is  normally  plated  from
                 hexavalent  chromic acid electroplating
                 baths for decorative application such as
                 home   appliances,  marine  hardware,
                 automobile  hardware, zinc die casting,
                 brass forgings,  and steel stampings. The
                 toxicity  and waste treatment require-
                 ments of hexavalent chromium compared
                 to those of trivalent chromium make a
                 trivalent chromium  plating system
                 desirable. Substrates to which chromium
                 plating  are commonly applied include
                 1010-1020 steel and 4340 high-strength
                 steel.   The  pretreatment  procedure
                 includes  vapor  degreasing,  alkaline
                 cleaning, and   reverse-etching  of the
                 metal  surface  to  be  plated. A  nickel
                 underplate  is  required  for  decorative
                                               chromium plating to provide good plate
                                               adhesion  and  maximum  corrosion
                                               protection. The performance of trivalent
                                               chromium plating on buffed and unbuffed
                                               1010 steel panels  was screened  with
                                               respect to appearance, corrosion-resist-
                                               ance and adhesion (Table 5). These tests
                                               showed that the  appearance of both the
                                               trivalent and hexavalent chromium plate
                                               was excellent. Both types  were smooth
                                               and bright, with the trivalent plate being
                                               somewhat brighter than the hexavalent
                                               plate. By comparison, the unbuffed panel
                                               plated with  trivalent  chromium  was
                                               bright but not smooth, magnifying the
                                               orange-peel effect of the unbuffed panels.
                                               Plate adhesion was evaluated by bending
                                               the panels  to break and examining the
                                               break at  4X magnification for lifting or
                                               peeling. No separation was evident at the

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Table S.   Trivalent Chromium Plating: Evaluation of Properties
Property
Appearance
Trichrome*
lunbuffed
1010 steel)
Bright
Trichrome*
(buffed
1010 steel)
Smooth and very bright
Hexavalent
Chromium'' (buffed
1010 steel)
Smooth and bright
Adhesion (bend test)        Poor

Corrosion (salt spray)        96 hr**
  Good

  282 hr**
Good

96 hr**
  * 25.4 nm (1.0 mil) semi-bright nickel
   10.2 urn (0.4 mil) bright nickel
   0.25 um (0.01 mil) chrome (trivalent or hexava/ent).
 ** Each of 4 panels failed at 96 hr.

*»* A verage of 4 panels: 2 failed at 48 hr, 1 failed at 288 hr, 1 failed at 744 hr.
chromium-nickel  interface, the  nickel-
nickel interface, or the nickel-base metal
interface  on  either  the trivalent  or
hexavalent  chromium  plates  on  the
buffed panels. The adhesion of the plate
to the unbuffed panel, on the other hand,
was poor (the underplate lifted from the
substrate and the chromium  separated
from   the  underplate).  This  loss  of
adhesion  was apparently  due  to  the
roughness of the substrate.  Corrosion
resistance was determined by exposure
of four plated panels to 5%-salt spray
solution   until failure.  Two trivalent
chromium, Jsuffed panels failed at 48 hr,
one at 288 hr and one at 744 hr (an
average  of  282  hr).  This average is
considerably  higher than that obtained
with the hexavalent chromium panels, all
four of which failed at 96 hr. Although the
variation  in  the  trivalent   chromium
results indicates that this bath may need
further work to  provide  consistently
higher corrosion protection, the results
do  show that trivalent chromium  has
excellent potential for providing improved
corrosion protection over the hexavalent
chromium   while   maintaining  the
performance in other properties.
  In addition to the above tests hydrogen
embrittlement tests were performed to
provide final  characterization  of  the
chromium plating systems. Six notched
tensile specimens of 4340 steel were
heat treated  to 1790-1930 MPa (260-
280 ksi) and plated with duplex nickel and
chromium. Three specimens were plated
with  trivalent chromium and  three
specimens were plated with hexavalent
chromium. All specimens were baked for
3 hr at 191 °C (375°F) following plating to
provide embrittlement relief. Three bare
control specimens were installed in a
universal   testing  machine  and
continuously loaded  until  failure
occurred  to  determine the ultimate
notched  tensile  strength  (UNTS).  The
average UNTS was found to be 56.5 MPa
(389.3 ksi). The plated specimens were
then subjected to a sustained load of 75%
of the ultimate notched tensile strength
for 200 hr. The trivalent chromium-plated
specimens  exceeded  the  200-hr
exposure with no failure. The hexavalent
chromium-plated specimens all failed in
less than 7 hr; however, since chromium
plating on high-strength steel is normally
baked  for  23 hr to  provide complete
hydrogen  embrittlement  relief,
hexavalent chromium-plated specimens
should pass  the  notched tensile test.
Differences in the nickel baths used for
the trivalent  and  hexavalent chromium
specimens may have contributed to these
test failures.


Replacement Systems for
Phenolic Paint Strippers
  Paint strippers are widely used through-
out  the  metal-finishing   industry  to
remove paint from parts to permit repair,
inspection, or refinishing. Most  paint
strippers contain chromates, methylene
chloride, phenols, or  strong acids. The
normal procedure involves application of
the paint stripper, allowing it to remain on
the part  for a specified time period and
then washing it off with water. In many
cases, the wash  water containing  the
paint stripper and removed paint is fed
into  drains that go to  leaching ponds or
sewers. This  can result in serious water
pollution, especially when highly toxic
chromates   or  phenols  are  involved.
Several  paint strippers containing no
phenols have been developed as potential
replacements  for  phenolic  paint
strippers.
  The coating used for all paint stripper
tests (MIL-P-23377 epoxy primer/MIL-C-
81773  polyurethane  topcoat  systems)
was applied to 2024-T3 aluminum alloy    i
panels according to conventional proce-    '
dures and air-dried for 7 days prior to use.
The paint surface to be stripped  was
completely covered with remover, either
by  immersion or by  brush.  After the
required  contact  time,  the  area  was
rinsed with water and the loosened paint
removed  by brushing.
  Testing  of  potential   replacement
systems for phenolic paint strippers was
performed to determine the best system
available of each of the four types: acid
brush-on,  non-acid brush-on,  acid
immersion,  and  non-acid  immersion.
Strippers  in  each  category were
subjected to  various  screening  tests
applicable to that category and compared
to the phenolic non-acid brush-on  type
stripper used as a  control. Preliminary
screening  tests  were  conducted  to
determine the stripper's remover power,
rinsability, coating and remover residue,
and general properties.
  Preliminary  screening   tests  were
conducted with the brush-on application
strippers. The performance of the six
candidate non-acid brush-on  strippers
varied widely; the removal power, or time
required  for completion of lifting, ranged
from 20 to more than 80 min. This  time
was determined to  be that  required for
completion of all lifting and wrinkling
action, using a remover volume sufficient
to completely cover the test area. A more
quantitative removal power test, which
determined  the  total area  lifted  in  a
specific time using a specific volume of
remover,  showed  that  two  of  the
removers lifted the paint film in 30 min or
less using a specific remover volume
(Table 6). These removers, Sprazee (BASF
Wyandotte Corp.) and T-5873  stripper
(Turco Co.), also showed good rinsability,
coating residue, and remover residue.
Each of the three candidate acid brush-on
strippers (Oakite Visstrip, Turco T-2822,
and Turco  T-6017) showed  excellent
removal power in both the time and area-
lifted  removal tests. These strippers also
showed  excellent  rinsability,  coating
residue, and remover residue properties.
The removers were then subjected  to
further evaluation. Sprazee and T-5873
strippers were selected from the non-acid
brush-on strippers for further evaluation.
  The refinishing  properties  of  the
selected  brush-on  strippers were
determined by applying the paint system
(epoxy  primer per MIL-C-81773)  to
panels which had  been stripped  with
each candidate system, and then testing
to determine the adhesion,  appearance,
and gloss of the applied paint film. The

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 Table 6.    Brush-On Paint Strippers: Characterization Tests
Manufacturer
Phenolic control
• Turco
Trade
name
T-5469
Appearance
Homogeneous
Consistency
& How
Smooth, even coat
nemover
power,
(time to lift,
min:sec)
5:17
Contact
time
(min:sec)
5:30
Remover
10 ml
(% lifted)
100%
Volume
25ml
(% lifted)
100%
 Non-phenolic non-acid
 •  BASF           Sprazee
 •  Turco           T-5873

 Non-phenolic, acid
 •  Oakite          Visstrip

 •  Turco           7-2822
 •  Turco           T-6017
           Homogeneous       Fairly even coat          56:50         30:00
           Homogeneous       Smooth, even coat        20:05          6:45
           Separated          Smooth, even coat         8:28          5:20

           Homogeneous       Smooth, even coat         8:18          6:20
           Slight separation     Fairly even coat	3:20	3:10
                                                                 82%
                                                                 42%
                                                                 92%

                                                                 99%
                                                                 87%
                                                          97%
                                                         100%
                                                          97%

                                                          99%
                                                          98%
   * Gloss on original paint Him: 94.
  **Maximum allowable weight change: aluminum ±0.016%; steel ±0.010%.
 *»•» /y rj — NQ( determined.
Rinsability
Coating
residue
(% removed)
Ftefinishing Corrosion compatibility
properties weight change, %**
Remover
residue Gloss* Adhesion Aluminum
Steel
Excellent
>99%
Much residue
                                                        91
                                          Good
                                                                             0.011%
                                         +0.007%
Good
Excellent
  96%
>99%
Easily rinsed
Much residue
N.D.
 90
N.D.**
Good
N.D.***
+0.007%
 N.D.***
+0.031%
Excellent

Excellent
Excellent
 95%

>99%
>99%
Easily rinsed

Easily rinsed
Easily rinsed
 90     Good         Heavy
                      corrosion
 91     Good         1.36%
 92     Some lifting    7.5%
                                 -0.055%

                                 -0.95O%
                                +0.258%
 appearance  of  each of the refinished
 films was good, with a reduction in gloss
 from the original paint film of only 2 to 4
 units. The adhesion  of refinished films
 was determined by the wet tape test. Good
 adhesion was evident on all but one of the
 refinished films; in that one, which used
 the  Turco T-6017 stripper, the topcoat
 lifted from the primer on one of the two
 panels; the  other panel  showed good
 adhesion. The corrosion compatibility of
 the  selected paint  strippers was  also
 determined  for  aluminum  and  steel
 substrates. As expected, the acid paint
 strippers are not compatible with either
 aluminum or steel  substrates. These
 substrates corroded to varying  degrees
 after one week of exposure to the paint
 stripper  at 38°C (100°F). The  Turco  T-
 5873  non-acid  stripper  also   showed
 corrosion of the steel substrate.
   The performance  of the candidate
 immersion-type   paint strippers  was
 evaluated in tests similar to those used
 for the brush-on type removers; the major
 difference being the paint removal tech-
                   nique. Results are summarized in Table 7.
                   One of the two non-acid immersion-type
                   strippers  evaluated  (Magnus  766)
                   showed good removal power and good
                   rinsability, with  90% paint lifted after a
                   22-min   contact  time.  Two  acid-
                   immersion  paint  strippers  were
                   evaluated; one of these (Oakite Stripper
                   SA)  showed good removal power with
                   excellent rinsability and a coating residue
                   of only 2% after  an 11-min contact time.
                   This stripper left a residue after contact
                   with  the  bare substrate for  15-min at
                   38°C (100°F) and thorough rinsing. The
                   refinishing properties  and  metal
                   compatibility of  the selected  immersion
                   paint strippers were also evaluated. The
                   refinishing properties  of both strippers
                   were good,  with a 5-unit loss of gloss
                   compared to the original paint film and
                   only slight lifting of the paint system and
                   small blisters in  the wet tape test of the
                   Stripper SA-stripped panels.  The corro-
                   sion tests show that the acid stripper was
                   not compatible with either aluminum or
                   steel,  while the  non-acid  stripper
                                              (Magnus 766) was compatible only with
                                              the aluminum substrate.

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    Table 7.    Immersion Paint Strippers: Preliminary Evaluation and Characterization
Manufacturer
Non-phenolic,
non-acid
• BASF
• Magnus
Trade
name

Rapoff
766
Appearance

Separated
Slight separation
Removal power
(time to lift,
min: sec)

>80.00
22:08
Rinsabilitv

Good
Good
Coating
residue
(% removed)

<1%
90%
Remover
residue

Much residue
Some residue
Refinishing
properties
Gloss" Adhesion

	 	
89 Good
Corrosion
compatibility
weight change, %**
Aluminum Steel

	 	
-0.003% -0.112
   Non-phenolic, acid
      Oakite

      Oakite
Stripper EZ

Stripper SA
Separated

Homogeneous
>80:00

 11:08
Fair

Excellent
10%

98%
Slight residue

Much residue
                                                  89    SI lifting      -5.88%  -0.912
     "Gloss on original paint film: 94,
     "Maximum allowable weight change, aluminum - ±0.016%; steel - ±0.010%.
      Christian J. Staebler, Jr., and Bonnie F. Simpers are with Grumman Aerospace
        Corporation. Bethpage, NY 11714.
      Hugh B. Durham is the EPA Project Officer (see below).
      The complete report, entitled "Reduced-Pollution Corrosion-Protection Systems,"
        (Order No. PB 83-153 056; Cost: $13.00, subject to change) will be available
        only from:
              National Technical Information Service
              5285 Port Royal Road
              Springfield, VA 22161
               Telephone: 703-487-4650
      The EPA Project Officer can be contacted at:
              Industrial Environmental Research Laboratory
              U.S. Environmental Protection Agency
              Cincinnati,  OH 45268
                                                                                                                 CO
                                                                                                                 CO
                                                                                                                 C-J
United States
Environmental Protection
Agency
                     Center for Environmental Research
                     Information
                     Cincinnati OH 45268
                                                                            Postage and
                                                                            Fees Paid
                                                                            Environmental
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Penalty for Private Use $300

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