United States
                    Environmental Protection  .
                    Agency
Municipal Environmental Research XN
Laboratory
Cincinnati OH 45268
                    Research and Development
EPA-600/S2-83-100  Dec. 1983
&ERA         Project  Summary
                    Mobile  System for  Extracting
                    Spilled  Hazardous  Materials
                    from   Excavated  Soils
                    Robert Scholz and Joseph Mifanowski
                      A technique was evaluated for the
                     scrubbing  or cleansing of excavated
                     soils  contaminated  by  spilled  or
                     released  hazardous  substances.
                     Laboratory tests were conducted with
                     three   separate  pollutants  (phenol,
                     arsenic trioxide, and polychlorinated
                     biphenyls [PCB's]) and two soils of sig-
                     nificantly  different character
                     (sand/gravel/silt/clay   and  organic
                     loam).
                      The tests show  that scrubbing of
                     excavated  soil on  site is an efficient
                     approach for freeing soils of certain
                     contaminants but that the effectiveness
                     depends on the washing fluid (water +
                     additives) and on the soil composition
                     and particle-size distribution. Based on
                     the test results, a full-scale, field-use,
                     prototype  system was designed,
                     engineered, fabricated, assembled, and
                     briefly tested under conditions where
                     large (>2.5 cm) objects were removed
                     by a bar screen. The unit is now ready
                     for field demonstrations.
                      The system includes two major soil
                     scrubbing  components: a water-knife
                     stripping and soaking  unit of  novel
                     design for  disintegrating the soil fabric
                     (matrix)  and solubilizing the
                     contaminant from  the larger particles
                     (>2  mm)  and  an existing,  but  re-
                     engineered, four-stage countercurrent
                     extractor for freeing the contaminants
                     from smaller particles (<2 mm). The
                     processing rate of the system is  2.3 to
                     3.8 mVhr (4 to  5 ydVhr), though the
                     water-knife  unit  (used  alone) can
                     process 11.6 to  13.5 mVhr (15 to 18
                     ydVhr). The complete system requires
                     auxiliary equipment, such as the EPA-
                     ORD   physical/chemical  treatment
                     trailer, to process  the wastewater for
recycling; under some circumstances,
provision must be made to confine and
treat released gases  and  mists.
Treatment  residues  consist  of
skimmings from froth flotation, fine
particles  discharged with  the used
washing fluids, and spent carbon. The
principal  limiting constraint on the
treatability of soils is clay content (high
weight-percent), since breaking down
and  efficiently treating  consolidated
clays is impractical or not economically
attractive. Most inorganic compounds,
almost all water soluble or readily oxi-
dizable organic chemicals,  and some
partially miscible-in-water organics can
be treated with water or water plus an
additive.
  During limited laboratory extraction
tests,  phenol  was  very  efficiently
removed  from both  organic and
inorganic  soils, whereas  PCB and
arsenic clung more tenaciously to the
soils and were released less readily into
the washing fluids. The extent to which
the system has practical, cost-effective
utility in a particular situation cannot be
determined until preliminary, bench-
scale lab work has been performed and
acceptable limits of residual concentra-
tions in the washed soil are adopted.
Laboratory tests show that soil scrub-
bing  has  the  capability  of  vastly
speeding up the release of chemicals
from soils, a process that occurs very
slowly under natural  leaching
conditions.
  Note that this system requires exca-
vation of the soil, which can subse-
quently be replaced or transported to a
low-grade  landfill. In situ washing of
contaminated soil, a process in which
the contaminated area is isolated for

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example, by grouting, and then water-
flushed with removal of the wash water
at a well-point is an alternative. The
overall efficiency of the  soil washing
system is greater than that currently
being achieved by in situ  methods.
  Based on the laboratory program, a
series   of  steps   (water-knife   size
reduction;   soaking;  countercurrent
extraction;  hydrocyclone separation;
and  waste  fluid treatment for reuse)
was selected  as the  most  suitable
process sequence for  the  prototype
system. The system was constructed
for the U.S. (EPA)  and is now  being
subjected to field evaluation. However,
soils rich in humus, organic detritus,
and  vegetative  matter  can  present
special problems in the  extraction of
certain hazardous substances, which
may not partition between the solid and
fluid phases to a practical and necessary
extent.
  This Project Summary was developed
by EPA's Municipal Environmental Re-
search Laboratory, Cincinnati, OH, to
announce key findings of the research
project that is fully documented in a
separate report of the same title (see
Project Report ordering information at
back).

Introduction
  The  leaching  of hazardous  materials
from  contaminated  soils  into  ground-
water is recognized as a potential threat
to the  Nation's drinking water supplies.
Such situations occur as the result of
accidental spills of hazardous substances
and  from  releases at the many uncon-
trolled hazardous waste  disposal  sites
now known to exist  across the country.
Current removal/remedial technology is
largely  limited  to the excavation and
transfer of such soils  to suitably sealed or
lined landfills where  uncontrolled leach-
ing cannot occur.
  Onsite treatment can be a more cost-
effective solution to the problem. In some
research  projects,  contaminated  soils
have been  isolated  by injected grout,
trenched slurry  walls, steel piling, etc.,
and  then subjected  to in  situ leaching.
The  effectiveness  of such a  process  is
limited  by,  among  many factors, the
permeability of the soil in its undisturbed
state. Economic and effectiveness factors
cannot be generalized but are situation-
specific.
  An alternative process  is needed for
those situations in which permeability or
other factors  prevent effective in-situ
leaching and  where landfilling is too
costly.  The  proposed technology — the
subject of the current effort — consists of
excavation,  onsite  but  above-ground
treatment of the contaminated soil, and
return of the treated soil to its original
site.Excavation of the soil from its natural
state  opens a  number of  options  for
improved separation of contaminants
through  better (high energyjmixing and
the potential for using different solvents.
Such  cleanups can also  be carried out
more  quickly than they could by the
leaching of  a  more or  less compact
natural soil (cost factors not being consid-
ered). This engineering approach has also
made it possible, or more convenient, to
incorporate any control devices that may
be needed to reduce emissions of particu-
lates or fumes into the air column and/or
to treat the contaminated wastewaters
generated during the processing.
  The purpose of this project was to carry
out appropriate laboratory studies and to
develop,  design, and construct a full-
scale  system capable of treating a wide
range of contaminated soils. The existing
system will be useful for the correction of
long-standing (remedial)  contamination
problems (waste disposal sites), as well
as for the emergency cleanup of spills and
for  the  prompt  removal  of  released
wastes.


Discussion
  To meet the objectives of the program,
specific  criteria  were identified for  the
solvent, the soils, the pollutants, and the
process.
  To  be  suitable for field use in such a
process, the solvent or extracting fluid
should have the following characteristics:

   1. A  favorable separation coefficient
     for  extraction,

  2. Low volatility under ambient condi-
     tions (to reduce air contamination
     effects),

  3. Low   toxicity  (since  traces  of
     extractant  may  remain  in   the
     cleansed soil),

  4. Safety and relative ease of handling
      in the field,

   5.  Recoverability for reuse.

The selected solvent  must be able to
separate the contaminant from the soil,
preferably  using  a minimum volume of
solvent so that the equipment can be kept
compact. In addition, the solvent must be
readily separable  from the  soil fines to
allow return of the decontaminated soil to
the site  and to permit treatment  and
reuse of the solvent. High volatility in the
solvent can contribute to  unacceptable
losses  and can,  when  coupled  with
flammability,   exacerbate   health   and
safety  risks for the workers.
  Following  a  brief  evaluation   and
screening of potential solvents (including
organics), consideration of all the above-
cited factors clearly indicated that water
was suitable  as  the  primary  target
solvent. The  use  of additives  such as
acids  or  bases,  oxidizing  or  reducing
agents, or wetting agents was judged to
be a reasonable approach for enhancing
removal   efficiency.   Though   certain
organic solvents can  meet  most of the
solvent criteria and may  have definite
advantages in specific cases, a  decision
was made early in the project to limit the
investigation to water-based systems.
  The  range of soils that is encountered
in  a cleanup situation is  very broad,
encompassing fine, highly cohesive clays,
sandy  soils, silts,  soils high in  organic
matter, etc. Though  processes can be
devised to handle any or  all of these
materials, certain contaminated soils do
not  require exhaustive extraction  and
others do not lend themselves to an
extractive process. The organic content of
a soil can affect the ease of size reduction
and the efficiency of extraction. The pH of
a soil can affect the extraction efficiency
for a particular contaminant. When the
soils and  contaminants have catonic or
anionic qualities, ion exchange (partition
factors cannot be neglected.
  For purposes of this investigation, two
soils were selected as suitable represent-
atives of many that might be encountered.
These  were  a  granular (sandy),
essentially cohesionless inorganic soil
(containing some  fine sand and about
20% clay) and a highly organic (18.4%,
mostly as peat and humus) commercial
topsoil.
  Though  spill  situations  and  waste
disposal sites  may differ in many ways
(such as the portion of a contaminant that
is tightly  bound to the soil versus the
amount loosely associated  in the voids),
plans for  the test program  emphasized
the  spill   situation  by  using  freshly
prepared  mixtures  of  soil  plus
contaminant. Funding was insufficient to
support work  with aged or weathered
contaminated soils that are more repre-
sentative of dumpsites.
  The  actual  process for  the  planned
system must include excavation  and
transfer  to the  processing equipment,
screening  to  remove  large (>2.5 cm)

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 objects, size reduction to maximize soil-
 solvent contact,  extractive  treatment,
 separation of contaminated solvent from
 (relatively) decontaminated soil particles,
 and return of the soil (either "as is" or
 after drying) to the excavation.
   Excavation can be readily handled by
 conventional  earthmoving  and
 construction  machinery. Size  reduction
 of  soils  can  be  accomplished  with
 various,  commercially  available
 equipment, including  rotary  scrubbers,
 log  washers,  attrition scrubbers,  and
 high  intensity water-knives.  The
 properties of each were considered, and
 the water-knife was chosen as the most
 versatile unit; it was also suitable for both
 disintegrating  clay-like lumps and for
 scrubbing the loosely  held contaminant
 from the  resulting smaller  (>2  mm)
 components.
   For the decontamination process to be
 effective  with  a  wide range of water-
 insoluble  and tightly held contaminants
 on small  particles  (>2 mm),  follow-on
 multi-stage extraction  was judged to be
 necessary. The use  of  countercurrent
 extraction allows  several   stages  of
 extraction with minimum solvent use.
 Clearly, the final system also  requires
 equipment to separate fines  from the
 solvent, both between extraction stages
 and  after   the  last  stage.  Gravity
 separators,  clarifiers,  and filters were
 generally inappropriate for the planned
 system; hydrocyclones were selected for
 evaluation.
   The  three  hazardous  contaminants
 selected for testing were phenol, arsenic
 trioxide, and PCB's. These were chosen
 because of the frequency with which they
 are encountered in spills and the range of
 physical   and  chemical  characteristics
 they offer. Laboratory tests were carried
 out  to assess the  effects of different
 water-based  solvents and different pro-
 cessing   conditions  on  these  three
 chemicals mixed with the two soil types
 noted earlier. The results of these studies
 were then used to design the full-scale
 prototype.

 Equipment Evaluation
 Size Reduction  and Extraction
  A  series of tests was conducted with
the water-knives, first using a local, avail-
able,  uncontaminated  soil  sample.
Numerous approaches to exposing  the
soil to the water-knife jets were tried and
abandoned (refer to the full report). Only
when  the soil was  contained  in a
truncated,  cone-shaped,  tilted rotary-
screen drum (2-mm mesh openings) was
the desired lump breaking obtained. The
first tests were performed in an 18-in.
trash basket (top ID = 15 in.; bottom ID =
12  in.) in which  50% of  the bottom
sidewall (up to 8 in.) was cut away in four
sections that were overlain with various
mesh"  screens.  (The  device  was  re-
engineered for the actual testing.) In the
bench  apparatus,  approximately  two-
thirds of the soil was washed out through
the  screen  within  the  first  2 min of
treatment with4.5L/min(1.2 gal/min)of
water at a pressure of 4.9 kg/cm2 (70 psi)
and a drum speed of 10 to 20 rpm. Further
experiments indicated that a three step
sequence was needed to achieve the best
decontamination:

  1. Low-pressure wash,

  2. Soaking, followed by stripping, and

  3. Low-pressure fresh-water wash.


Liquid-Solid Separation

  To study the separation of  soil fines
from water,  a full-sized hydrocyclone
(227 L/min) was used  with different
inflow rates (and pressures) and different
concentrations of both soils. Though the
results of these tests  show that the
hydrocyclone is suitable for each soil,
they also indicate that the solids were
better  concentrated in the  underflow
from the inorganic soil. With both soils,
the  overflow contained a  small  but
significant amount of fines (0.7% to 3.7%),
which would require additional separation.
Passing   this  overflow through   the
hydrocyclone in a second treatment was
not notably  effective in  removing these
fine solids.
  Because  the  hydrocyclone was too
large for routine use in the laboratory
study of contaminant removal from soil,
simply gravity settling in a  beaker was
evaluated and found to represent a good
simulation of the separation achievable
with the hydrocyclone.

Extraction Tests
  Tests were carried out with the three
chemicals (all three were not used in all
experiments) to establish the following:

  a) probable loading on a soil column,

  b) distribution on particles of different
     sizes, and

  c) effect of extraction with different
     sovents on  particles  of different
     sizes.
Column Loading Studies
  A  stock solution  of the contaminant
equal in volume to the void space in the
column was added to a 15.2-cm (6.0-in.)
column of soil (various moistures and
densities) and allowed to drain for 24 hr.
The   contaminant  remaining  in   the
column was calculated on a dry weight
basis, based on the  amount of fluid that
drained from the column.  Modified gas
chromatographic and atomic absorption
methods  (described  more fully in  the
report) were used. Results obtained with
the three materials are shown in Table 1.
Note the  heavy loading of phenol, which
represents the situation that might exist
shortly after a  spillage onto soil.

Distribution Tests
  Different procedures were used with
phenol and with arsenic trioxide to evalu-
ate  their distribution  on particles  of
different sizes. For phenol, dry soils were
first  size-classified with a sonic fraction-
ation device.  Each fraction was then
wetted with a stock solution of phenol.
After 18 hr, the fractions were rinsed
with water and analyzed. For arsenic, the
soil from the column dosing tests was
dried,  size  fractionated,   and  then
analyzed.  High recoveries  (based  on
analyses) were achieved in both cases.
  With phenol, these tests indicated that
approximately  90%  of the contaminant
was  absorbed (or retained interstitially)
on the larger particles (0.6 to 2 mm*) of
the  organic  soil.   These  somewhat
unexpected  results  also appear to be a
consequence of nonuniform distribution
of organics in  the different particle-size
fractions. Tests confirmed that the fine
particles  contained  predominantly
organic degradation products rather than
plant tissues, which remained primarily
with  the  larger  particles. Such
differences may make it necessary, in
some  cases,  to  presoak  the  soil  for
efficient extraction.
  Unexpected results were also obtained
when testing the distribution of phenol on
the  inorganic   soil.  The  relatively low
adsorption  by  the  finer  particles  was
attributed  to   differences  in  internal
porosity   and  chemical  composition
between  the large  and small particles
rather than the proportionately greater
surface area  (calculated on a  weight
basis) of the fine particles.
  The  results  obtained  with arsenic
trioxide on the organic soil were similar to
those obtained with phenol.  With  the
                                                                                  1 Nominal sizes are given for screens.

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inorganic  soil,  however,  the  arsenic
compound  exhibited  the  normally
expected relationship between  particle
size  (i.e.,  surface  area)  and  amount
adsorbed. That is to say, because of the
greater  surface-to-mass  ratio,  more
adsorption occurs per unit weight of fines.
  PCB's were not tested  to  any  great
extent because of their low solubility and
the hazards  involved in working  with
them. Time and funding constraints also
influenced this decision to curtail PCB
studies.

 Water-Knife Stripping Tests
  Contaminated  soil   samples  were
 subjected to 1 min  of stripping by the
 water knife to remove particles smaller
 than 2 mm. Residual contaminants on the
 remaining (larger than 2  mm) particles
 were then determined. The results (Table
 2) show the value of additional washing
 or extraction, at least  for phenol and
 arsenic trioxide.

 Chemical Extraction Tests
   Since water is not the optimum extract-
 ant for all contaminants tested, and since
 most  of  the  contaminants  will  be
 absorbed by and adsorbed on the smaller
 (<2 mm) particles, a series of tests with
 the   following aqueous solutions was
 conducted  to determine  whether
 extraction efficiency could be improved:

   water + sulfuric acid to pH  1

   water + sodium hydroxide to pH  11

   water + 7.5% sodium bisulfate

   water + 5.0% sodium hypochlorite

   water + 1.0% TWEEN 80

   water + 1.0% MYRJ 52

   water + 5.0% methanol

   For the  inorganic soils contaminated
 with phenol, all extractions were highly
 efficient,  with  removals greater than
 87%. Only for the organic soil could the
 difference  between  solvents  be
 considered significant, with the sodium
 hydroxide  solution  being  the  most
 effective  solvent. A portion of the data
 presented in the report is summarized in
 Table  3.  The  relative  and  actual
 importance of the residual contaminant
 on the soil should  not be ignored, nor
 should the fraction of solvent remaining
 in the soil (not shown  in Table 3). When
 the residual  level  of  contamination  is
Table 1.   Maximum Column Loadings
Contaminant
Organic Soil
fmg/g soil)
Inorganic Soil
 (mg/g soil)
Phenol

Arsenic trioxide

PCB
  453.2

    5.0*

   25.6
   48.3

    0.75*

    3.0
*As arsenic (As).
 Table 2.   Effect of Washing on Large Particles'
Soil
Inorganic



Organic



Test
Time
(min)
15
30
60
120
15
30
60
120
Phenol
97.9
98.2
98.8
99.1
60.7
79.2
86.0
91.6
% Removal
As203
28.9
52.1
42.2
52.1
47.7
55.8
54.0
59.0
PCB
21.4
50.0
21.4
28.6




 *2 to 12.7 mm
 Table 3.    Solvent Extraction: Representative Single- Washing Tests*
Contam-
inant
Phenol


Asi03



PCB



So//**
/
O

1

O

1

0

Solvent
Water
Water
NaOH (pH 1 1)
Water
H2SOt fpH 1)
Water
H2SOt fpH 1>
Water
1% 7 ween 80
Water
1% Tween 80
Initial
Soil Dose
(mg/g dry
soil)
48
452

0.75

5

3

26

%
Removal
98.6
77.8
88.4
42.7
85.3
75.0
85.0
24.6
37.5
48.3
23.8
Supernatant
Concentration
(mg/L)
1,190
17,600
20.000
16
32
375
425
72
110
418
366
Residual Soil
Concentration
mg/g
0.68
100.4
52.5
0.43
0.11
1.25
075
2.66
1.88
13.2
19.5
  * Extractant to dry solids  10:1 (w/w).
 ** I = inorganic; O = organic.

 sufficiently low, the treated soil may no
 longer require disposal as a hazardous
 material, e.g., in a safe landfill.
   Samples  of phenol-contaminated
 organic and inorganic soils were  also
 subjected to multiple extractions. These
 tests  demonstrated  that  continued
 removal of phenol did occur, even when
 the  extractant  was  recovered solvent
 (water) from a previous stage and already
 contained  phenol.  Residual   phenol
 concentrations of 30 mg/kg (0.03 mg/g)
 of  soil  were  achieved  after  four
 countercurrent  extractions  of  the
 inorganic soil.


 Prototype Design and
 Construction
 The  process sequence  for  full-scale
 treatment (Figure 1) was finalized, based
 on  the  laboratory   experiments.  The
 sequence  includes  initial  removal of
 oversized chunks (>2.5 cm), water-knife

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scrubbing to deconsotidate the remaining
soil matrix and to strip any contaminant
loosely absorbed on the solids(>2 mm) or
held in the void spaces of the soil, and
four-stage,   countercurrent   extraction
coupled  with  hydrocyclone separation
after  each extraction  stage  to separate
the solids (<2 mm) from the liquid. Froth
flotation is used to give maximum mixing
of extractant and soil in  each stage. The
overhead extract  (mostly sorbent) from
the  first stage extractor  hydrocyclone
contains the highest level of dissolved (or
dispersed) contaminants and fines. This
extract must be clarified and then treated
(possibly with activated carbon) before it
is recycled.
   Note that: chunks (>  2.5  cm) are not
normally  processable  in  the system
except for moderate washing on  a bar
screen*; the 2.5-cm to 2-mm as well as
the <2-mm fraction, will be used to fill in
the excavation; all processing fluids must
be appropriately  treated.  All  dust and
vapor  emissions should be ducted to an
air cleaner or scrubber before discharge.
   The basic  system  was  constructed
according to the design shown in Figure 1.

   The water-knife  unit (rotary  drum-
screen scrubber)  consists of a tilt-skip
loader and  hopper feed from which the
soil moves into a tillable 19-m (21 -ft) long
by 1.4-m (4.5-ft)  ID cylinder fitted with
end pieces, water-knives, and a rotating
mechanism (Figures 2, 3, and 4).
   Soil  is  metered  from the tilt-skip
reservoir hopper at rates up to 18 ydVhr
onto   a  manually washed  bar screen
where  >2.5-cm  (1-in.)  chunks are
rejected. The solids then  pass into the
tilted drum-screen scrubber where it is
subjected to first-stage water-knife strip-
ping, water soaking, and finally second-
stage water-knife stripping using fresh or
partially recycled water. The first section
of the scrubber cylinder is  1.3-m (4-ft)
long and is fabricated from 2-mm mesh
(HYCOR   Contra-Shear  screen)  and
equipped  with  internal  water-knives.
 Solids then move into the 5-m  (15 ft)
 soak cylinder that is fitted with a baffle
plate  that  has a 0.5-m (22-in.)  center
opening through which solids pass into a
0.7-m (2-ft) long screened,  water-knife
rinse zone. Fines (<2 mm) pass through
the screens, as does the wash water. The
coarse particles are voided at the end of
                                                                            +2 mm Scrubbed Soil
* There are two bar screens. The soil is hosed-reused
 on a 7.5- or 5-cm (3- or 2-in.) upper screen in the
 skip-hopper from which large or nondisintegrable
 chunks are raked off. Washed chunks that pass the
 upper screens  are rejected and removed at  the
 second (lower) bar screen (<2.5 cm [1  in.]).
Contaminated
    Soil
                                              Counter-Current
                                                 Chemical
                                                 Extractor
          Oversize
          Non-Soil
          Materials
         and Debris
Figure 1.
                Makeup Water
                                       Spent Carbon

            Process flow scheme for soil scrubber.
 Figure 2.    Fully constructed rotary drum screen scrubber.
the drum. The unit can be backflushed as
needed. The  screens resist  buildup of
fines (blinding). The actual arrangement
of the water-knives and other details of
construction are  given  in the  project
report.
  From the water-knife and soaker unit,
the slurry (<2-mm particles) is pumped to
the countercurrent extractor. The four-
stage  countercurrent  extraction  unit
(Figures 5 and 6) has been modified from
the  so-called  EPA beach  sand froth

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                                                           Metering Hopper
                Tilt Skip
                Hopper up to
                Load Metering
                Hopper
                                                            Drum-Screen
                                                            Soil Scrubber
Hand Wash
Large
Stones
Figure 3.    Soil loading and metering system (cross sectional side view).
                                                             Initial
                                                          Spray Zone
                                                                         Soil In
                                                              Outer Shell
                           A. Drum cross section

                           ,~ 16 Inches
                                  Baffle
                                             Soil Surface
                                                                Inner
                                                                Cylinder
Figure 4.
       Soak Zone
 Channel Formed by     Screen
 Soil and Drum Wall

                 B. Drum Isometric

Soak zone description.

                        6
flotation unit.*  Basically, the  washing
chamber  was  partitioned  into  four
sections (3-ft long X  4-ft wide  X 5-ft
deep),  each  of  which has an aerator
agitator and a hydrocyclone with  pumps
and  piping.  Flow of solids (<2mm) and
fluid is countercurrent with clear water
being introduced at the fourth (discharge)
chamber (Figure 6). The extraction unit
has  an on-board  diesel generator; the
water-knife unit requires external  power.
The  underflow (solids-rich) slurry from
the fourth hydrocyclone is discharged to a
drying bed.
  To  achieve mobility, the water-knife
unit  is skid-mounted  for  transport by
semi-trailer; the countercurrent extractor
is integrally attached to a separate semi-
trailer. Refer to Figures 2 and 5 for details.
Calculations   indicate  that the total
system has a throughput range of 2.3 to
3.8  mVhr  (3-5 ydVhr), but  that the
water-knife  unit alone can process  11.5
to 13.5 mVhr (15 to 18 ydVhr).


Conclusions

  The  following  conclusions  can  be
drawn from  the work carried out  during
this program and the knowledge  gained
during that effort:

  1.  Spill-contaminated  soils  can  be
     excavated and treated onsite using
     extraction with water  or  aqueous
     solutions for  many pollutants  that
     are frequently encountered in such
     situations.

  2.  A system capable of decontamina-
     ting 2.3 to 3.8 mVhr (3-5 yd'/hr) of
     soil  has  been  designed  and
     constructed and it is now  available
     for field testing by EPA.

   3. Water-knives function as a compact,
     efficient, and economical  means or
     achieving effective contact between
     contaminated  soil particles  and
     extractant.

  4.  Countercurrent  extraction  is  an
     effective  process  for   removing
     certain   adsorbed   contaminants
     from  soils and,  for  the size  of
     equipment needed, hydrocyclones
     are preferred devices for separating
     the extracted solids from the ex-
     tractant.
 'Garth D. Gumtz, Restoration of Beaches Contamin-
 ated by Oil. EPA-R2-72-045 (Washington, D.C.: US
 EPA, 1972).

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  5. Laboratory  experiments  demon-
    strate   that  soil   characteristics
    (particle size, distribution, organic
    content, pH, ion-exchange proper-
    ties, etc.)  are important factors in
    the  removal  or  retention  of
    contaminants.

  6. In addition to the actual percentage
    of the contaminant  removed, the
    allowable  level  of  pollutant
    remaining in the soil is an important
    factor  in  determining   when
    adequate   decontamination   has
    been  achieved since  the  final,
    residual concentration affects the
    options available for disposal of the
    cleansed solids.


Recommendations


  Based on the observations made during
this' investigation,  several suggestions
are offered for future work.

  1. Laboratory screening tests should
     be performed on a wider range of
     typical  compounds  and  mixtures
     encountered  in   hazardous
     substance spill and  release situa-
     tions to ensure that appropriately
     high levels of decontamination can
     be achieved with this process.

  2. The results of this study apply pri-
     marily to spill situations. Contami-
     nated soils found at waste disposal
     sites   may  exhibit  different
     extraction characteristics because
     of the  extended  soil/contaminant
     contact time and of weathering and
     in situ reactions. Studies are needed
     to establish whether and to what
     extent  such  changes  affect the
     decontamination process.

  3. Other  extractant solutions should
     be evaluated to determine whether
     the efficiency of the process can be
     improved  without  damaging the
     equipment  or  increasing  the
     hazards to which the workers are
     exposed.

  4. A wider  range of soils should be
    examined  to  determine  what
    changes in the system are practical
    to better cleanse soils with charac-
     teristics (e.g., greater cohesiveness
    and adsorptive properties of clay-or-
    silt-rich  soils)  that  differ  signifi-
    cantly from those of the soils already
    tested.
Figure 5.    EPA Froth Flotation System (beach cleaner) modified as a countercurrent
             chemical extractor for soil scrubbing.
  Chemical
  Additive
  (If Needed)
 Spent
Washing
 Fluid
           Raw
           Feed
 Chemical
 Additive
(If Needed)
 Chemical
 Additive
(If Needed)

   J
Fresh
Water
                 Slurry Pump

Figure 6.    Process flow scheme for soil scrubber.

  The  full  report  was  submitted  in
fulfillment of Contract No. 68-03-2696 by
Rexnord, Inc., under the sponsorship of
the  U.S.  Environmental Protection
Agency.
                                                 Clean
                                                 Product

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     Robert Scholz and Joseph Milanowski are with Rexnord Inc., Milwaukee. Wl
       53214
     John E. Brugger is the EPA Project Officer (see below).
     The complete report, entitled  Mobile System for Extracting Spilled Hazardous
       Materials from Excavated Soils." (Order No. PB 84-123 637; Cost: $11.50,
       subject to change) will be available only from:
            National Technical Information Service
            5285 Port Royal Road
            Springfield, VA22161
            Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
            Municipal Environmental Research Laboratory—Cincinnati
            U.S. Environmental Protection Agency
            Edison, NJ 08837
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use $300
US.
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                                                                                     US GOVERNMENT PRINTING OFFICE 1984-759-102/819

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