United States Environmental Protection Agency Municipal Environmental Research Laboratory . _ . Cincinnati OH 45268 ' "i * Research and Development EPA-600/S2-83-109 Feb. 1984 4>ERA Project Summary Potential Clogging of Landfill Drainage Systems Jeffrey M. Bass, John R. Ehrenfeld, and James N. Valentine The potential clogging of landfill drainage systems was investigated with particular emphasis on hazardous sites. The study accomplished five basic tasks: (1) to provide general background on the subject of drain clogging; (2) to investigate some cemented materials found in a drain at a landfill in Boone County, Kentucky, and to determine possible causes; (3) to examine the potential for clogging in hazardous waste leachate collection systems; (4) to identify preventive or remedial techniques for drain clogging; and (5) to identify avenues or research and devel- opment that might minimize the like- lihood or impact of clogging. Study results indicate that clogging is likely to occur in a probabilistic manner during the active and post-closure operational lifetime of a hazardous waste landfill, but preventive and remedial techniques can be used to avoid or mitigate clogging. Preventive methods (including increased safety factors or redundancy in design, moni- toring, periodic inspection.and mainte- nance) are far superior to remedial techniques. Repair or replacement is expensive and potentially dangerous in the hazardous environment at secure landfills. Present regulations for hazard- ous waste landfills provide no guidance on engineering, design, or operational practices to prevent clogging or remedy a malfunctioning system. This Project Summary was developed by EPA's Municipal Environmental Research Laboratory, Cincinnati, OH, to announce key findings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction Clogging caused by a variety of mechani- sms is common to drainage systems of all kinds — agricultural irrigation, sanitary landfills, septic system leach fields, etc. Concern is particularly great over the potential clogging of leachate collection systems in hazardous waste landfills. Not only are the consequences of failure much higher at a hazardous waste site, but excavation and replacement are no longer simple last resorts. In response to this concern, this report investigates the potential clogging of landfill drainage systems with particular emphasis on hazardous waste sites. The study was designed to accomplish the following tasks: 1. To provide general background on the subject of drain clogging; 2. To investigate cementitious materi- als found in gravel around a drain at a U.S. Environmental Protection Agency demonstration sanitary landfill in Boone County, Kentucky, and to determine possible causes; 3. To examine the potential for clog- ging in hazardous waste leachate collection systems; 4. To identify and describe potentially useful preventive or remedial techni- ques to avoid, minimize, or eliminate drain clogging; and 5. To identify fruitful avenues for research and development to mini- mize the likelihood or impact of clogging. The study was initiated with a literature review of field experience and a limited laboratory study of the materials recovered from the Boone County Landfill. ------- Information Base To assess the potential for clogging of leachate collection systems, information was obtained from the following areas: 1. Regulations to the Resource Con- servation and Recovery Act (RCRA), 2. Design of leachate collection sys- tems, 3. Leachate characteristics, 4. Mechanisms of drain clogging, and 5. Relevant experience. Literature from related fields such as agricultural drainage and irrigation systems provided most of the background because information and direct experi- ence with leachate collection systems in general is sparse. Although many differ- ences exist between conditions of leachate drains and other kinds of drains, basic mechanisms leading to clogging are similar in all systems. In particular, a paper prepared for EPA by GCA Corpora- tion (C.W. Young, T.J. Nunno, M.R. Jasinski, D.R. Cogley, and S.V. Capone, "Clogging of Leachate Collection Sys- tems Used in Hazardous Waste Land Disposal Facilities," Draft White Paper, U.S. Environmental Protection Agency, Washington, D.C. In press) was used as a starting point for the research in this report. Clogging Mechanisms Clogging mechanisms are occurrences or natural processes that inhibit the flow of leachate to or through the leachate collection system. Such as system at a landfill is considered to be clogged if it cannot maintain the leachate depth over the liner at less that 30-cm limit required in the RCRA standards. The majortypesof clogging mechanisms in leachate collec- tion systems are physical, chemical, biochemical, and biological mechanisms. Physical mechanisms are the most common, most well understood causes of drain failure. Physical factors tend to predominate in many drainage system cloggings, though any combination of factors might occur. Physical failure can be due to inadequate capacity, structural failure, or sedimentation or filtration. Chemical mechanisms for clogging involve the formation of insoluble precipi- tates that are deposited on the surfaces inside of drain pipes, in openings (slots), and in the drain-pipe envelopes (gravel and geotextile filters). The most common form of chemical buildup is calcium carbonate. Manganese carbonate (rhodo- chrosite) and other insoluble forms (sulfides and silicates) have been found in clogged or partially encrusted drainage systems. Biochemical mechanisms occur when inorganic precipitates are formed in conjunction with biological systems in addition to the other simpler mechanisms. The principal products resulting from biochemical mechanisms are iron com- pounds — Fe(OH)3 or FeS (though manganese compounds may also be involved). These compounds are deposit- ed on pipe surfaces and in the envelope material. The deposits generally contain organic material as well in the form of adherent, sometimes filamentous slimes and organic complexes. Biological mechanisms are formed when organisms grow to fill the intersti- ces in the drain envelope and interfere with normal flow of leachate. For such growth to occur, bacteria must be present in a supportive environment. Many bacteria are known to use hazardous organic chemicals for food and can grow at the temperature, pH, and oxygen content found in landfills. Heavy metals often present in hazardous waste landfills may be toxic or inhibitory to the clog-form- ing species. Analysis of Deposits Found at the Boone County, Kentucky, Landfill When Test Cell 1 of the Boone County, Kentucky, field site was dismantled in September 1980 after 9 years of testing, a section of partially cemented gravel was discovered in the drain envelope extend- ing 2.2 to 4.2 m (6.5 to 13.5 ft) from the collection sump (bulkhead). The discovery of the cemented section was significant because the test cell had been constructed to provide a better understanding of such processes. Analyses included a physical examination of the cement material (scanning electron microscopy, optical microscopy, and X-ray diffraction and fluorescence analysis) and a chemical analysis of the mass to determine primary chemical constituents. Results of these studies lead to the preliminary conclusion that the cement is principally a calcium-iron-magnesium product containing significant proportions of carbonate (gas evolution) and phosphate. In addition, a relatively large proportion of fine silica appears to be dispersed in the cement. The lack of significant X-ray diffraction patterns suggests that the cement is an amorphous material rather than composed of discrete crystalline phases. Little can be said about the clogging mechanisms at work here, but carbonate incrustation is likely to have contributed. The role of iron is not yet clear. In addition to determining the cement composition, it is important to know why the cementation occurred only in a limited portion 2.2 to 4.2 m (6.5 to 13.5 ft) above the collection sump of the upper drain. One explanation is that conditions in the wastes above that section were different from those elsewhere, but data are not sufficient to follow that approach. Differences in operating procedures during the first 7 months of test cell operation caused leach- ate to back up in the pipe and could have caused at least the beginnings of the cementation. Further investigation is needed for a more definitive conclusion, however. Potential for Clogging at Hazardous Waste Landfills The potential for clogging of leachate collection systems at hazardous waste landfills is of particular concern since ex- cavation and replacement are not simple last resorts (as they are in sanitary land- fills) and since the consequences of failure are very high. Unfortunately, direct assessment of clogging potential at hazardous waste or sanitary landfills is difficult because little experience has been had with modern leachate collec- tion systems. Thus it is useful to compare the clogging potential of these systems with agricultural drainage systems, where clogging is clearly a serious prob- lem. Table 1 indicates that relative poten- tial for clogging of agricultural drains and leachate collection systems at sanitary and hazardous waste landfills based on the major potential clogging mechan- isms. Crushing problems appear to be more likely to occur at both hazardous waste and sanitary landfills, whereas chemical, biochemical, and biological clogging appear less likely to occur in hazardous waste systems. This differ- ence is primarily due to the lower pH range and the potential toxicity of chemi- cal constituents to indigenous bacteria. Sedimentation and pipe deterioration are also potential problems in hazardous waste systems. Prevention and Remedies Preventive and remedial measures can be used to address problems with drain clogging. Preventive measures are inten- ded to interrupt the sequence of causal steps necessary for a clogging mechanism to occur. Prevention of drain clogging can be accomplished in the following areas: — design and construction, — operation and maintenance, — waste disposal, and — treatment. Remedial measures are intended to eliminate the clogging problem once it ------- Table 1. Relative Potential for Clogging of Leachate Collection Systems Mechanism Agricultural Drains Sanitary Landfills Hazardous Waste Landfills Significant Differences fof+, -) Physical: Crushing Sedimentation Deterioration Chemical (CaCOa) Biochemical (Ochre, Fe) Biological Compact/on, greater equipment loading Less careful design and construction possible Chemicals, solvents, low pH not expected Lower pH Toxicity to indigenous bacteria, lower pH Toxicity to indigenous bacteria, lower pH * = possible, * less likely, and * = more likely. has occurred. Remedial measures for clogged drain systems include: — excavation and replacement, — physical methods, and — chemical methods. Examples of preventive and remedial measures are presented in Tables 2 and 3. Conclusions The following conclusions are based on information and analyses summarized in the full report. 1. Based on the analysis presented in the full report and on past experi- ence with agricultural drainage sys- tems, sanitary landfills, and (to a limited extent) hazardous waste landfill leachate collection systems, it is reasonable to expect clogging to occur in a probabilistic manner dur- ing the active and post-closure operational lifetime of a hazardous waste landfill. 2. Mechanisms that affect other types of systems are expected to con- tribute to clogging in hazardous waste landfills. This study was limited to an examination of clog- ging in the drainage system per se — that is, the pipes, envelope, and out- let system. {The regulatory defini- tion of "clogging" as used here could also involve localized blockages within the waste mass that rest on the liner and create leachate head greater than the permissible limit, but this potential problem was not examined in depth.) 3. Landfill operators exhibited a vary- ing degree of concern over the clog- ging potential of drainage systems. Most appeared to view the potential problem as unimportant in both de- sign and operational considerations and felt that conventional practices should be adequate to prevent or remedy clogging. Only one source noted that the prevention and mitigation of clogging received care- ful and special attention in their de- sign and operational considerations. 4. Established preventive and remedial techniques to avoid or mitigate clog- ging can generally be used at hazardous waste sites. Acid flush- ing should be used with great care, particularly if cyanides are known to be present. 5. Preventive methods (including in- creased safety factors or redun- dancy in design, monitoring, perio- dic inspection, and maintenance) are far superior to remedial tech- niques. Repair and replacement are often considered quite practical in other settings, but they are expen- sive and potentially dangerous in the hazardous environment at se- cure landfills. 6. The present regulations regarding hazardous waste landfills do not ap- pear to treat clogging system design and head buildup with the same thoroughness and level of detail as liner design or loss of integrity. The regulations give substantial discre- tion to regional administrators with regard to the drainage system. Nei- ther the regulations nor other sup- porting documents provide guid- ance on engineering, design or op- erational practices to prevent clog- ging or remedy a malfunctioning system. Recommendations A number of recommendations for fur- ther research on leachate collection sys- tems can be made based on the results of this study. The recommendations listed below are given with the understanding that it is important to integrate technical solutions with practical experience and expectations. Technical solutions arising from laboratory-based research and de- velopment alone are not likely to be im- plemented if they are considered too ex- pensive or too complicated to apply under existing or future conditions. Conducting technical research in conjunction with experience on operating leachate collec- tion systems can help avoid this problem. 1. Specific design and construction guides should be developed for leachate collection systems — simi- lar, perhaps, to the EPA Technical Resource Documents, which provide guidance for the design and con- struction of liner systems. Such a guide could be used by the Regional Administrators in approving facili- ties, or by the Administrator in preparing regulations for leachate collection systems. Aspects of any of the following recommendations could also be included in this task. 2. Specific operational procedures should be developed to prevent clogging. An effective program of treatment and maintenance can control the factors needed for cloging mecha- nisms to occur and and thereby avoid the clogging problems. This task should include a cost analysis of alternative preventive approaches. 3. Monitoring methods to detect clog- ging or conditions that promote it should be developed to anticipate problems before they become too serious. Conventional techniques can be applied from related fields such as groundwater hydrology, and new techniques can be developed to indicate when significant clogging processes are occurring. 4. A quantitative analysis should be made of the probability of the various clogging mechanisms. Spe- cific preventive and remedial ap- proaches can then be evaluated in the context of hazardous waste landfills to determine their quantitative effects on clogging potential. This recommendation would involve both a paper study and a field investigation under typical hazard- ous waste landfill conditions. 5. Methods for preventing and correct- ing clogs in drain envelopes or filter ------- Table 2. Preventative Measures for Drain Clogging Category Measure Factors Affected Mechanisms Affected Comments Design and Construction Operation and Maintenance Waste Disposal Treatment pipe diameter 6" pipe in protective cradle, soil cover sealed Joint construction corps grain size distribution criteria submerged outlet slope 2 percent pipe size, estimated flow crushing displacement, slotsize filter material anaerobic conditions flow rate exercise special care in all design in design and construction design for prevention all capacity structural structural, sedimentation sedimentation chemical, biochemical capacity, sedimentation biochemical, biological capacity, sedimentation. structural all care during placement crushing, displacement structural compaction, operation in vicinity of drain regular monitoring and all all inspection of system cleaning all all minimize nutrients dispose biocides, toxics maintain low pH avoid solvents, oxidizing agents biocides acid bacteria bacteria bacteria chemical attact bacteria all biochemical, biological biochemical, biological chemical, biochemical, biological deterioration biochemical, biological all facilitate remedial measures, maintenance use high strength pipe use slotted or perforated pipe options include graded. 2 or more layers geotextile, 4" minimum depth depends also on quantity of flow manholes, c/eanouts, large pipe, etc. most important for first lift of waste identify factors, early stages of clogging for preventative cleaning removes potential clogging in early stages, use flushing, low pressure jet organics, N and P compounds, other chemicals acids, bases, heavy metal wastes contributes to deterioration add directly to collection system kills bacteria, removes early stages TableS. Remedial Measures of Clogged Drains Category Measure effectiveness Comments Excavation and Replacen.snt Physical Methods Chemical Methods same mechanical low pressure jets high pressure jets flushing (sub- irrigation SOz gas SuHamic Acid complete remedy limited for inactive deposits, not effective for slots, but good in combination with other methods effective for ochre. FeS. sediments limited for mature deposits same as low pressure but can cause damage to drain envelope and better for mature deposits less than jets effective for ochre. Mn in 2 cases, ineffective in one case for ochre effective for ochre most expensive option; difficult at hazardous waste sites Koto-rooter, pigs, sewer balls, snakes, buckets 70-140 psi at nozzle 440 - 1300 psi at nozzle rate of use = / lb/7.Sg water, dangerous to personnel and environment, cost is 7 percent of replacement strength required depends on organic matter and age of ochre NaCOa used to neutralize treated live ------- layers should be developed. Currently, no satisfactory remedial methods exist short of excavation and replacement. 6. Experimental data on the perform- ance of leachate collection systems (including detailed leachate flow and composition data) should be gathered at both sanitary and hazardous waste landfills on a continuing basis. Such a data base is vital in evaluating leachate collection system performance and in developing design and operational guides to ensure proper system functioning throughout its required lifetime. The full report was submitted in fulfillment of Contract No. 68-01 -5949 by Arthur D. Little, Inc., under the sponsorship of the U.S. Environmental Protection Agency. Jeffrey M. Bass, John R. Ehrenfeld, and James N. Valentine are with Arthur D. Little. Inc., Cambridge. MA 02140. Michael Slimak is the EPA Project Officer (see below). The complete report, entitled "Potential Clogging of Landfill Drainage Systems," (Order No. PB 84-110 550; Cost: $10.00. subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield. VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Municipal Environmental Research Laboratory U.S. Environmental Protection Agency Cincinnati, OH 45268 ------- United States Environmental Protection Agency Official Business Penalty for Private Use $300 Center for Environmental Research Information Cincinnati OH 45268 ^re-^U-S. 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