O1/.'/
                    United States
                    Environmental Protection
                    Agency
Hazardous Waste Engineering
Research Laboratory
Cincinnati OH 45268
                    Research and Development
EPA/600/S2-85/032  May 1985
&ER&          Project  Summary
                    Demonstration  Test  of  Refuse-
                    Derived  Fuel as a  Supplemental
                    Fuel  in  Cement  Kilns
                    Cliff R. Willey and Carl S. Weinberger
                     Air emission tests consisted of three
                    sampling runs with coal only and three
                    runs with coal and Refuse Derived Fuel
                    (RDF). Sampling was done at the stack
                    following gas cleanup by electrostatic
                    precipitators. Analysis was done for
                    particulates (EPA Method 5), SO,
                    (Method16), chlorides (as HCI) and NO,.
                    A precipitator malfunction and cleanout
                    occurred just prior to the tests.
                     Particulates averaged 0.022 gr/dscf
                    burning coal and 0.059 gr/dscf burning
                    coal and RDF. Chlorides  increased
                    slightly; NO, was not significantly af-
                    fected. SO, results appeared  to  be
                    affected by the precipitator cleanout.
                    Dust buildup in the ESPs was noted
                    when burning  RDF, indicating that
                    some adjustment to the  precipitators
                    may be needed when using RDF to
                    achieve maximum  particulate cleanup
                    of the gas stream.
                     The full report also discusses RDF
                    preparation equipment and RDF feed
                    equipment developed for the tests.
                     This Project Summary was developed
                    by EPA's Hazardous Waste Engineering
                    Research Laboratory, Cincinnati, OH,
                    to announce key findings of the research
                    project that is  fully documented in a
                    separate report of the same title (see
                    Project Report ordering information at
                    back).


                    Introduction
                     The cement manufacturing industry
                    represents an attractive opportunity to
                    recover energy from  municipal solid
                    waste. It consumes significant amounts
                    of energy, 457 trillion Btu per year, and
                    includes 49 plants with capacities to use
over 380 tons per day of refuse derived
fuel. The industry also involves a process
in  which  ash  and  other  products of
combustion become part of the manufac-
tured project, thus minimizing the re-
quirement for ash disposal and reducing
the need for costly additional air pollution
control equipment.
  In spite of this attractiveness, progress
towards the  use of RDF in the cement
industry has been slow, tempered by
industry caution on one hand and a lack of
test information on the other. None of the
tests  in the United States has involved
more than 5 test days.
  In 1975, when discussions were begun
with the Lehigh Portland Cement Com-
pany  regarding potential use of refuse
derived fuel in the production of cement,
it became apparent that even though
there was interest, there also was con-
cern about the untried nature of the fuel.
This concern included:

• ability to supply and feed RDF continu-
  ously,
• firing characteristics and ability to burn
  RDF in suspension,
• effect on RDF chemical composition
  and variations in composition on ce-
  ment quality and chemistry,
• long-term effects on RDF on kiln
  operation and cement production, and
• effect on air emissions.
 The following test program was devel-
oped to address these concerns:

 1.  RDF would first be tested at a coal-
     fired, lightweight shale kiln. The
     advantage of such testing was the
     experience gained with the burning
     characteristics of RDF and with the

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        reliability of RDF feed equipment.
        As part of the test agreement, the
        feed equipment was expected to
        demonstrate 7 days of continuous
        operation before tests could begin
        at the cement plant.
     2.  When the  lightweight  aggregate
        test was satisfactorily demonstra-
        ted, RDF feed equipment would be
        set up at a cement plant to produce
        test quantities of cement for anal-
        ysis (2 to 3 day test).
     3.  Again, based on satisfaction with
        the production step,  an extended
        burn test  involving air emission
        measurements would be run.

   Conclusions
   • Satisfactory Type I and Type II cement
      were produced burning supplemental
      refuse derived fuel with coal. Physical
      properties such  as strength and set
      time were within acceptable limits.
      Chemical composition of cement pro-
      duced with  RDF and coal was not
      significantly  different from cement
      produced with only coal. No alteration
      of the infeed  raw material mix was
      needed to  adjust for differences in
      chemical makeup caused by substitu-
      tion of RDF  for coal. These results
      apply to the test conditions in which up
      to 37 percent of the heat was supplied
      by RDF.
   • Fluff RDF (as well as the primary fuel)
      must burn in suspension to avoid
      causing low oxygen (reducing) condi-
      tion at the kiln bed and subsequent
      unacceptable changes in cement
      chemistry. For the conditions of this
      test, RDF would require  secondary
      shredding to a size 95 percent less
      than 2.5 cm  (1  in.) for suspension
      burning. More or less finely shredded
          RDF may be required for different kiln
          conditions, feed techniques, and feed
          rates.
          Although  stack emission tests were
          probably  affected by a precipitator
          outage and cleaning prior to the test
          period and must be  interpreted with
          caution, none of the emissions tested—
          particulates, chlorides, nitrous oxides,
          and sulfur oxides—appeared to present
          a serious problem. Ash buildup in the
          ESP with time after  starting to burn
          RDF indicated RDF may have affected
          the properties of the dust-fly ash mix
          collected by the ESPs and that some
          adjustment in operating conditions
          might be required if RDF were burned
          on a continuous basis.
 • Fluff RDF can be stored  in transfer
   trailers  and  reliably  fed  from the
   trailers provided: (a) the RDF is only
   moderately compacted in the trailers;
   (b) lump breakers or some other means
   is used to refluff and even out the flow
   of  RDF;  and (c) the  rate of trailer
   unloading and the speed of the feed
   conveyors are controllable.

Recommendations
  Long-term tests of RDF as a cement kiln
fuel should be continued to establish
industry confidence in the use of this fuel.
The best approach may be the develop-
ment of a semi-automated feed station
for continuous RDF fuel use at a cement
manufacturing plant.
          Cliff R. Willey and Carl Weinberger are with the Maryland Department of Natural
           Resources, Annapolis, MD 21401.
          Michael Black and Robert Olexsey are the EPA Project Officers (see below).
          The complete report, entitled "Demonstration  Test of Refuse-Derived Fuel as a
           Supplemental Fuel in Cement Kilns." (Order No. PB 85-180 842/AS; Cost $10.OO,
           subject to change) will be available only from:
                 National Technical Information Service
                 5285 Port Royal Road
                 Springfield, VA 22161
                 Telephone: 703-487-4650
          The EPA Project Officer can be contacted at:
                 Hazardous Waste Engineering Research Laboratory
                 U.S. Environmental Protection Agency
                 Cincinnati, OH 45268
                                            U.S. GOVERNMENT PRINTING OFFICE: 1985-559-016/27058
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Environmental Protection
Agency
Center for Environmental Research
Information
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