United States
                  Environmental Protection
                  Agency
                  Research and Development
Environmental Monitoring
Systems Laboratory
Las Vegas NV 89114
EPA-600/S4-84-046 June 1984
<>EPA         Project  Summary
                  Geothermal  Environmental
                  Impact Assessment:
                  An  Approach  to  Groundwater
                  Impacts from  Development,
                  Conversion,  and Waste Disposal

                  J. W. Hess, S. W. Wheatcraft, J. E. Edkins, R. L. Jacobson, and D. E. Zimmerman
                   Groundwater monitoring  for the
                  impacts  of geothermal  energy
                  development, conversion  and  waste
                  disposal is  similar  to groundwater
                  monitoring for other purposes, except
                  that additional information is needed
                  concerning the geothermal reservoir. In
                  the research  described here, a six-step
                  methodology, including failure analysis
                  and computer-based contaminant
                  transport and geochemical models to
                  design groundwater monitoring  plans,
                  was developed. Failure data  analyses
                  indicate that production and  injection
                  wells have the highest probability of
                  failure and should be the focal points for
                  groundwater monitoring. Groundwater
                  monitoring techniques fall into four
                  categories: 1)  monitoring the
                  injection/production  well, 2)
                  monitoring in the saturated  zone, 3)
                  monitoring intheunsaturated zone, and
                  4) monitoring on or above the ground
                  surface. Location  of the  monitoring
                  wells and  the variables to,measure in
                  them may be determined with the aid of
                  computer  contaminant transport and
                  geochemical   models. POLUTE  is  a
                  nondispersing contaminant transport
                  groundwater  computer  model  that
                  enables  the user to  locate  a
                  contaminant  plume at any given time.
                  Prediction  of  resultant  fluid
                  chemistries from a leaked geothermal
                  fluid may be  essential to unambiguous
                  evaluation of geothermal fluid impact at
                  remote  groundwater monitoring sites.
This can be accomplished through the
use of geochemical models.
  Illustrative  examples  were run  to
demonstrate the first four steps of the
six-step methodology. Results indicate
that the key to groundwater monitoring
is the continuous  measurement  of
physical, and chemical characteristics
of injection fluids in the production and
injection wells.
  This report was submitted in fulfill-
ment of Grant No.  R 806457 by the
Desert Research Institute under the
sponsorship of the U.S. Environmental
Protection  Agency. This report covers
the period from April 17, 1979 to July
16,1982 and work was completed as
of July 16, 1982.
  This Project Summary was developed
by EPA's  Environmental Monitoring
Systems Laboratory, Las Vegas. NV, to
announce key findings of the research
project that is fully documented in a
separate report of the same title (see
Project Report ordering information at
back).

Introduction
  The research described here used the
guidelines developed by Weiss, Coffey,
and Williams (1979) as a base and refined
a six-step methodology to include failure
analysis and computer-based contami-
nanttransport and geochemical models.
This groundwater monitoring methodol-
ogy enables one to design a monitoring
plan to predict and detect changes  in

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groundwater quality due to geothermal
development.

Methodology
  The variations in physical settings and
human  activities  at  or  near potential
geothermal energy areas preclude  one
monitoring plan that is applicable to the
release of geothermal fluid on the surface
as well as below the surface. Thus, the
monitoring method  developed  empha-
sizes groundwater impacts resulting from
the release  of geothermal  fluid  into
groundwater from a production or injec-
tion well. Inherent in the methodology is
prediction of the possible impacts if a geo-
thermal fluid release should occur.  The
methodology contains the following steps:
  1.  Define baseline conditions, includ-
     ing   geology,  hydrology,   water
     quality, geothermal system, plant
     design,  existing  surface  and
     groundwater  usage,   and  other
     existing waste disposal systems.
  2. Perform failure analysis, compare
    the site characteristics to the results
    of industry-wide failure analysis to
    predict the most likely mode of fluid
    release.

  3. Forecast aquifer conditions: predict
    travel  times and chemical concen-
    trations in the geothermal reservoir
    and overlying aquifers through the
    use of solute transport and geochem-
    ical  models.  Predict  potential
    impacts, define limits of detection
    and use to design monitoring plan.
  4.  Select monitoring sites and tech-
     niques.

  5.  Design  monitoring  plan  and
     alternatives,  based on the above
     steps  and legal  and institutional
     constraints.

  6.  Implement  monitoring  plan   and
     modify as experience dictates.
  Failure data  analysis indicates that
production and injection wells have the
highest probability of failure and should
be  the focal  points  for  groundwater
monitoring. Additional years of operating
experience  using currently  developed
technologies  are needed  to estimate
failure rates  confidently. Groundwater
monitoring  techniques  fall  into four
                                   2
categories:   1)  monitoring  the
injection/production well, 2) monitoring
in the saturated zone, 3) monitoring in the
unsaturated zone, and 4) monitoring on
or above the ground surface.
  Monitoring  the  injection/production
wells can  best  be  accomplished  by
borehole geophysics and measurements
of annulus fluid properties. Techniques
include  acoustic borehole televiewers,
flow meters,  cement logs, conductivity
probes, temperature  probes,  and
pressure gauges.
  Monitoring   in   the  saturated  and
unsaturated zones generally will involve
the  use of monitoring wells in which
chemical and physical  measurements
can be made, water samples collected, or
borehole geophysics run. Location of the
monitoring   wells and  variables  to
measure in them may be determined with
the  aid of  computer  contaminant
transport and geochemical models.
  POLLUTE   is   a   nondispersing
contaminant   transport  groundwater
computer model that can be applied to an
anisotropic aquifer which is bounded by
impermeable   and/or equal  potential
boundaries.  The  location  distribution
coupled with the  isochron distribution
output  from POLLUTE enables the user
to locate a contaminant plume at a given
time. The well flow distribution enables
the user to determine,  under a given
scenario, what will be contaminated, how
much contaminant will be intercepted,
and how long it will take for the well to
become contaminated.
  Advective  contaminant  transport
models  (which ignore dispersion) are
normally  adequate  for  purposes  of
designing  geothermal  monitoring
networks.   POLLUTE,   the  model
developed for this study, is specifically
designed to be of maximum usefulness
and minimum cost to run and intercept
for monitoring network design. Use of an
advective  model  such   as  POLLUTE
eliminates the need for large amounts of
hydrologic data and permits optimization
of the geothermal monitoring  network.
  Care must be taken to understand that
the model will  not predict exact arrival
times  of  contaminants  at  discharge
areas.  The  arrival times  predicted  by
POLLUTE  will  be  equivalent  to the
breakthrough of the  50% contaminant
concentration. This is not seen as a great
disadvantage, since advective-dispersion
models  are probably inaccurate  even
when  dispersivity values  have  been
measured.
  For any given geothermal system, there
are five  possible  geochemical
mechanisms by which leaked geothermal  |
fluid chemistries might be altered. Four of
the five mechanisms are  related to
solution  and   precipitation   reactions
resulting from 1) aqueous redox potential
changes, 2) temperature  changes, 3)
pressure change  effect on  dissolved
gases, and 4) exposure of fluids to new
mineral  assemblages.  The  fifth
mechanism  involves  cation  exchange
reactions.  Prediction of resultant fluid
chemistries   may be essential  to
unambiguous evaluation of geothermal
fluid  impact  at  remote  groundwater
monitoring sites.
  Computerized  geochemical modeling
methods  are   recommended  for
application  to  geothermal  monitoring
problems when  used by experienced
personnel on a site-specific basis. Steps
should  include  1)  selection  and field
supervision  of  essential baseline data
collection directed to modeling needs, 2)
determination  of  the  degree of model
sophistication  required and selection of
appropriate geochemical program  types
based on prior field data evaluation for
the Known Geothermal Resource Area
(KGRA) in question, and 3) interpretation
of  results,  including  selection  of
diagnostic remote monitoring parame-
ters  and  identification of information  |
gaps   requiring  further  evaluation.  "
Because adequate redox information was
generally lacking in the analyses  taken
from the literature, more effort should be
made to  quantify this  parameter in
geothermal  fluids. Redox information
should be  evaluated  and  comparisons
made between a number  of  direct and
indirect methods.  Redox information is
important to studies involving corrosion
of plant facilities as well as to impacts on
nonthermal  environments.  It  is  very
important to measure comparable data at
all sites at a given KGRA for both thermal
and nonthermal waters.
   Monitoring  on  or above the surface
includes tests on  surface  equipment,
surface water measurements,  surface
geophysics and remote sensing. Surface
geochemistry techniques such as  radon
and  mercury  detectors  may  have
monitoring applications.
   Three  illustrative  examples  are
presented to  demonstrate the  six-step
methodology.   The  methodology  was
applied to the Raft River KGRA in Idaho
and to hypothetical examples of leakage
from  a lagoon and contaminant plume
tracking and interception. The results of
these examples indicate that the key to
groundwater monitoring is to measure^
physical and  chemical characteristics^
continuously on production and injection

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wells.  As  an example,  a change in
annulus pressure may indicate leakage
through the injection tubing and would be
the first indication of a leak into a ground-
water  system.  At  most sites,  the
immediate  groundwater   systems  are
already  naturally affected  by  the
geothermal  fluid.  This   makes  early
detection of the  geothermal fluid more
difficult in monitoring wells. Monitoring
wells can be used to assess the impact of
a leak, that is, to determine if there is a
detectable change in water quality.
J. W. Hess, S. W. Wheatcraft, J. E. Edkins, R. L Jacobson. D. E. Zimmerman, are
  with Water Resources Center, Desert Research Institute, University of Nevada
  System, Las Vegas, NV 89109.
Leslie Dunn is the EPA Project Officer (see below).
The complete report, entitled "Geothermal Environmental Impact Assessment:
  An Approach to Groundwater Impacts from Development, Conversion, and
  Waste Disposal," (Order No. PB 84-198 639; Cost: $23.50, subject to change)
  will be available only from:
       National Technical Information Service
       5285 Port Royal Road
       Springfield. VA 22161
       Telephone: 703-487-4650
The EPA Project Officer can be contacted at:
       Environmental Monitoring Systems Laboratory
       U.S. Environmental Protection Agency
       Las Vegas, NV89114
                                                                              U.S GOVERNMENT PRINTING OFFICE, 1984 — 759-015/7731

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United States
Environmental Protection
Agency
                                       Center for Environmental Research
                                       Information
                                       Cincinnati OH 45268
Official Business
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