United States Environmental Protection Agency Research and Development Environmental Monitoring Systems Laboratory Las Vegas NV 89114 EPA-600/S4-84-046 June 1984 <>EPA Project Summary Geothermal Environmental Impact Assessment: An Approach to Groundwater Impacts from Development, Conversion, and Waste Disposal J. W. Hess, S. W. Wheatcraft, J. E. Edkins, R. L. Jacobson, and D. E. Zimmerman Groundwater monitoring for the impacts of geothermal energy development, conversion and waste disposal is similar to groundwater monitoring for other purposes, except that additional information is needed concerning the geothermal reservoir. In the research described here, a six-step methodology, including failure analysis and computer-based contaminant transport and geochemical models to design groundwater monitoring plans, was developed. Failure data analyses indicate that production and injection wells have the highest probability of failure and should be the focal points for groundwater monitoring. Groundwater monitoring techniques fall into four categories: 1) monitoring the injection/production well, 2) monitoring in the saturated zone, 3) monitoring intheunsaturated zone, and 4) monitoring on or above the ground surface. Location of the monitoring wells and the variables to,measure in them may be determined with the aid of computer contaminant transport and geochemical models. POLUTE is a nondispersing contaminant transport groundwater computer model that enables the user to locate a contaminant plume at any given time. Prediction of resultant fluid chemistries from a leaked geothermal fluid may be essential to unambiguous evaluation of geothermal fluid impact at remote groundwater monitoring sites. This can be accomplished through the use of geochemical models. Illustrative examples were run to demonstrate the first four steps of the six-step methodology. Results indicate that the key to groundwater monitoring is the continuous measurement of physical, and chemical characteristics of injection fluids in the production and injection wells. This report was submitted in fulfill- ment of Grant No. R 806457 by the Desert Research Institute under the sponsorship of the U.S. Environmental Protection Agency. This report covers the period from April 17, 1979 to July 16,1982 and work was completed as of July 16, 1982. This Project Summary was developed by EPA's Environmental Monitoring Systems Laboratory, Las Vegas. NV, to announce key findings of the research project that is fully documented in a separate report of the same title (see Project Report ordering information at back). Introduction The research described here used the guidelines developed by Weiss, Coffey, and Williams (1979) as a base and refined a six-step methodology to include failure analysis and computer-based contami- nanttransport and geochemical models. This groundwater monitoring methodol- ogy enables one to design a monitoring plan to predict and detect changes in ------- groundwater quality due to geothermal development. Methodology The variations in physical settings and human activities at or near potential geothermal energy areas preclude one monitoring plan that is applicable to the release of geothermal fluid on the surface as well as below the surface. Thus, the monitoring method developed empha- sizes groundwater impacts resulting from the release of geothermal fluid into groundwater from a production or injec- tion well. Inherent in the methodology is prediction of the possible impacts if a geo- thermal fluid release should occur. The methodology contains the following steps: 1. Define baseline conditions, includ- ing geology, hydrology, water quality, geothermal system, plant design, existing surface and groundwater usage, and other existing waste disposal systems. 2. Perform failure analysis, compare the site characteristics to the results of industry-wide failure analysis to predict the most likely mode of fluid release. 3. Forecast aquifer conditions: predict travel times and chemical concen- trations in the geothermal reservoir and overlying aquifers through the use of solute transport and geochem- ical models. Predict potential impacts, define limits of detection and use to design monitoring plan. 4. Select monitoring sites and tech- niques. 5. Design monitoring plan and alternatives, based on the above steps and legal and institutional constraints. 6. Implement monitoring plan and modify as experience dictates. Failure data analysis indicates that production and injection wells have the highest probability of failure and should be the focal points for groundwater monitoring. Additional years of operating experience using currently developed technologies are needed to estimate failure rates confidently. Groundwater monitoring techniques fall into four 2 categories: 1) monitoring the injection/production well, 2) monitoring in the saturated zone, 3) monitoring in the unsaturated zone, and 4) monitoring on or above the ground surface. Monitoring the injection/production wells can best be accomplished by borehole geophysics and measurements of annulus fluid properties. Techniques include acoustic borehole televiewers, flow meters, cement logs, conductivity probes, temperature probes, and pressure gauges. Monitoring in the saturated and unsaturated zones generally will involve the use of monitoring wells in which chemical and physical measurements can be made, water samples collected, or borehole geophysics run. Location of the monitoring wells and variables to measure in them may be determined with the aid of computer contaminant transport and geochemical models. POLLUTE is a nondispersing contaminant transport groundwater computer model that can be applied to an anisotropic aquifer which is bounded by impermeable and/or equal potential boundaries. The location distribution coupled with the isochron distribution output from POLLUTE enables the user to locate a contaminant plume at a given time. The well flow distribution enables the user to determine, under a given scenario, what will be contaminated, how much contaminant will be intercepted, and how long it will take for the well to become contaminated. Advective contaminant transport models (which ignore dispersion) are normally adequate for purposes of designing geothermal monitoring networks. POLLUTE, the model developed for this study, is specifically designed to be of maximum usefulness and minimum cost to run and intercept for monitoring network design. Use of an advective model such as POLLUTE eliminates the need for large amounts of hydrologic data and permits optimization of the geothermal monitoring network. Care must be taken to understand that the model will not predict exact arrival times of contaminants at discharge areas. The arrival times predicted by POLLUTE will be equivalent to the breakthrough of the 50% contaminant concentration. This is not seen as a great disadvantage, since advective-dispersion models are probably inaccurate even when dispersivity values have been measured. For any given geothermal system, there are five possible geochemical mechanisms by which leaked geothermal | fluid chemistries might be altered. Four of the five mechanisms are related to solution and precipitation reactions resulting from 1) aqueous redox potential changes, 2) temperature changes, 3) pressure change effect on dissolved gases, and 4) exposure of fluids to new mineral assemblages. The fifth mechanism involves cation exchange reactions. Prediction of resultant fluid chemistries may be essential to unambiguous evaluation of geothermal fluid impact at remote groundwater monitoring sites. Computerized geochemical modeling methods are recommended for application to geothermal monitoring problems when used by experienced personnel on a site-specific basis. Steps should include 1) selection and field supervision of essential baseline data collection directed to modeling needs, 2) determination of the degree of model sophistication required and selection of appropriate geochemical program types based on prior field data evaluation for the Known Geothermal Resource Area (KGRA) in question, and 3) interpretation of results, including selection of diagnostic remote monitoring parame- ters and identification of information | gaps requiring further evaluation. " Because adequate redox information was generally lacking in the analyses taken from the literature, more effort should be made to quantify this parameter in geothermal fluids. Redox information should be evaluated and comparisons made between a number of direct and indirect methods. Redox information is important to studies involving corrosion of plant facilities as well as to impacts on nonthermal environments. It is very important to measure comparable data at all sites at a given KGRA for both thermal and nonthermal waters. Monitoring on or above the surface includes tests on surface equipment, surface water measurements, surface geophysics and remote sensing. Surface geochemistry techniques such as radon and mercury detectors may have monitoring applications. Three illustrative examples are presented to demonstrate the six-step methodology. The methodology was applied to the Raft River KGRA in Idaho and to hypothetical examples of leakage from a lagoon and contaminant plume tracking and interception. The results of these examples indicate that the key to groundwater monitoring is to measure^ physical and chemical characteristics^ continuously on production and injection ------- wells. As an example, a change in annulus pressure may indicate leakage through the injection tubing and would be the first indication of a leak into a ground- water system. At most sites, the immediate groundwater systems are already naturally affected by the geothermal fluid. This makes early detection of the geothermal fluid more difficult in monitoring wells. Monitoring wells can be used to assess the impact of a leak, that is, to determine if there is a detectable change in water quality. J. W. Hess, S. W. Wheatcraft, J. E. Edkins, R. L Jacobson. D. E. Zimmerman, are with Water Resources Center, Desert Research Institute, University of Nevada System, Las Vegas, NV 89109. Leslie Dunn is the EPA Project Officer (see below). The complete report, entitled "Geothermal Environmental Impact Assessment: An Approach to Groundwater Impacts from Development, Conversion, and Waste Disposal," (Order No. PB 84-198 639; Cost: $23.50, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield. VA 22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Environmental Monitoring Systems Laboratory U.S. Environmental Protection Agency Las Vegas, NV89114 U.S GOVERNMENT PRINTING OFFICE, 1984 — 759-015/7731 ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Official Business Penalty for Private Use $300 ------- |