United States
                     Environmental Protection
                     Agency
 Industrial Environmental
 Research Laboratory
 Research Triangle Park NC 27711
                     Research and Development
 EPA-600/S7-84~024b Apr. 1984
&ERt\          Project Summary
                     Evaluation  of  Low  Emission  Coal
                     Burner  Technology  on   Industrial
                     Boilers:   Second  Annual  Report
                     (1980)
                     B.A. Folsom, L.P. Nelson, A.R. Abele,
                     J.L. Reese, and J. Vatsky
                      This report summarizes the second
                     year's effort under EPA  Contract
                     68-02-3127. The objective of the program
                     is to conduct field evaluations of the
                     distributed mixing burner (DMB) on two
                     industrial size boilers. The DMB concept
                     provides for controlled mixing of coal
                     with combustion air to minimize NOX
                     emissions, while maintaining an overall
                     oxidizing environment in the furnace to
                     minimize slagging and corrosion. Major
                     accomplishments  in 1980  included
                     preparation of a measurements protocol
                     which specifies all measurements to be
                     made during the program, baseline tests
                     of the initial host boiler, and initial tests
                     of a prototype DMB designed for the
                     host boiler.
                      This Project Summary was developed
                     by £PA's Industrial Environmental Re-
                     search Laboratory,  Research Triangle
                     Park, NC, to announce key findings of
                     the research project that is fully docu-
                     mented in a separate report of the same
                     title (see Project Report ordering infor-
                     mation at back).

                    Introduction
                      For the last several years, Energy and En-
                    vironmental Research Corporation has been
                    working with the EPA to develop a Iow-N0x
                    pulverized-coal burner. This distributed mix-
                    ing burner (DMB) controls the mixing of coal
                    with combustion air to minimize NOX emis-
                    sions, while maintaining an overall oxidizing
                    environment in the furnace to minimize slag-
                    ging, fouling, and corrosion.  DMBs have
                    been tested at firing rates up to about 100
 x 10* Btu/hr* in single- and four-burner
arrays in two research furnaces. The tests
covered wide ranges of burner adjustments
and operating conditions. When coal was
fired in the research furnaces under optimum
conditions, NOX levels less than 0.15 lb/10*
Btu were obtained. However, the DMB per-
formance has not been evaluated in a com-
mercially operated steam generator. The
objective of this program is to evaluate the
DMB concept on two commercially operated
industrial size boilers. The goal is to attain
NOX emission levels less than 0.2 lb/101 Btu
without adverse effects on boiler operabili-
ty and durability, thermal efficiency, and the
emission of other pollutants. The field evalu-
ations involve: 1) translation of development
burner test data into practical prototype
DMBs, 2)  verification of prototype burner
performance through testing in a research
furnace, 3) construction and installation of
these burners in field boilers and evaluation
of their performance under typical operating
conditions, 4) documentation of the results,
and 5) input to the parallel utility field evalua-
tion (EPA  Contract 68-02-3130). The pro-
gram is being conducted in nine tasks. Table
1 lists the  tasks and progress achieved.

  In Task 1, all of the basic elements of the
program were planned, including boiler se-
lection, burner design, and establishment of
a measurements plan. Two host site boilers
were selected and negotiations with the
operators completed so that a firm schedule
for the remaining aspects of the study could
 Readers mofe famliar with metric unto may use the con-
 version factors at the back of this Summary.

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Table 1.    Program Status Summary


              Task
         Program
       First
   Field Evaluation
        Second
    Field Evaluation
   Task 1 - Program Definition
       Host Boiler Selection

       Burner Engineering Design

       Analytical Measurements Plan


       Overall Program Plan

   Task 2 - Prototype Construction and
          Testing
       Burner and Support Equipment
       Construction

       Prototype Burner Tests

       Host Burner Tests

   Task 3 - Boiler Baseline Evaluation


   Task 4 - Burner Installation


   Task 5 - Performance Evaluation
   Task 6 - Industry Coordination


   Task 7 - Restoration
   Task 8 - Data Analysis

   Task 9 - Guideline Manual
  Boiler Inventory
  Evaluated
  Design Criteria
  Identified
  Measurements Protocol
  Completed
  Cold Flow Test Facility
  Designed and Under
  Construction
  Two Panel Meetings
  Were Held
Selected

Prototype DMB
Designed
Sampling System
Constructed and
Installed
                                      Initial Testing
                                      Completed
                                      Initial Testing
                                      Completed
                                      Initial Testing
                                      Completed
                                      Scheduled for
                                      Spring,  1981
                                       In Progress
Selected
Sampling System
Designed and Under
Construction
                    Scheduled for 1981

                    Scheduled for Spring,
                    1982
be established. The final burner designs were
established when the boilers were selected.
Prototype burners (including all controls)
were then constructed, installed in the large
watertube simulator (LWS)  furnace, and
evaluated using several coals as part of Task
2. In addition, the commercial burners used
in the host site boilers were also evaluated
in the LWS so that a one-to-one comparison
of operating characteristics could be deter-
mined and the potential problems identified.
  The Task 3 boiler baseline evaluations
of the host units establish normal operat-
ing characteristics and the potential for
reducing NO, emissions by  off-design
point operation. After baseline character-
ization, the lowNOx coal burners and all
support systems are installed on each
host boiler  in Task  4.  The burner and
burner systems then undergo checkout
testing to ensure their ability to perform
similarly to the original burners.
  At this point in the program, the low emis-
sion burner systems are ready for extensive
evaluation in Task 5. The retrofit boilers are
run over a sufficient range of operating con-
ditions consistent with the operational steam
requirements to define the multiburner op-
timization of emissions so that the operating
point can be established. Long-term evalua-
tions (18 months) are then conducted with
the boiler operating under a normal duty
cycle.  After  this task, the boiler/burner
system is inspected and the condition of all
systems documented.  Task 7 involves the
restoration of the boilers to their original
state.
  The  remaining Tasks 6 and 8 are accom-
plished concurrent with  all of the other tasks.
Lastly, the final report. Task 9, involves in-
tegrating the overall effort into  a concise
summary illustrating the application of the
technology to a wide variety of coal-fired in-
dustrial boilers.
  The  progress on each task listed in Table
1 was  achieved over the last 2 years. The
major accomplishments this year included
preparation of the measurements protocol,
baseline tests at the initial host boiler, and
initial prototype burner tests. These items are
discussed here.
  Note that  the  prototype burner design
discussed in this report is the initial flexible
design  based on the results of previous DMB
development efforts and Foster Wheeler
burner components. During tests of the in-
dustrial prototype burner in the LWS, some
design parameters  were changed consid-
      erably, including the incorporation of some
      proprietary Foster Wheeler components and
      parameter values. Results  of  this  LWS
      testing and the  changes  in  the burner
      designs are documented in subsequent an-
      nual reports.


      Measurements Protocol
        The measurements made during this field
      evaluation program will quantify the reduc-
      tions in NOX emissions achieved  by the EPA
      low emissions coal burner and will identify
      any potential problems in the application of
      this technology to field operating  boilers. The
      accuracy, completeness, and appropriate-
      ness of the measurements are, thus, key to
      the program's success.  A measurements
      protocol  (or measurements plan) has been
      prepared to ensure that the program goals
      are achieved; i.e., the evaluation of the EPA
      low emission coal burner technology on field
      operating boilers. Specifically, it identifies the
      parameters to be  measured, measurement
      methods, calibration procedures, measure-
      ment  frequency,  and data  quality  con-
      trol/assurance procedures. The  key aspects
      of the measurements protocol are summa-
      rized below.

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  The measurements in these programs will
be  associated  with  burner tests  in  the
research furnace at EER (LWS) and the field
boilers. The burner tests will be developmen-
tal. The measurements protocol for the LWS
tests includes measurement of key test con-
ditions and test outputs with accuracy and
repeatability sufficient to allow the relation-
ship between burner adjustments and burner
performance to be determined. The burner
tests in the field operating boilers will con-
stitute the actual field evaluations of the EPA
low emissions burner concept. The mea-
surements protocol for the field tests pro-
vides  more   detailed  and   complete
measurement methods; where possible, all
measurements are referenced to absolute or
NBS standards.
  The measurements have been organized
into categories of increasing complexity: 1)
standard measurement format, 2) detailed
measurement format, and 3) effluent stream
analysis. In addition, corrosion measure-
ments will be conducted as part of the field
tests.

Standard Measurement Format
  This minimum set of measurements will
be applied to all LWS and field tests. It in-
cludes measurement of the test inputs nec-
essary to specify operating  conditions,  as
well as routine measurement of output pa-
rameters. Table 2 lists the parameters and
measurement methods for the field tests.
The measurements for the LWS tests are
similar, except that the measurement meth-
ods are simplified. Where practical, con-
tinuous measurement methods have been
selected so that the duration of specific tests
will be limited by the  dynamics  of  the
burner/furnace systems  rather than  the
maximum data acquisition rate. For exam-
ple, gas-phase species in the combustion
products will be measured with continuous
gas analyzers. Where burner performance is
to be evaluated at specific test conditions,
the entire standard measurement format will
be applied. A portion of the  standard
measurement format  (02,  CO, and NOX
measurement) will be applied continuously
during  the long-term field tests.

Detailed Measurement Format
  This includes all measurements in the stan-
dard measurement format, plus intermittent
measurement of certain output parameters.
Table 3 lists the parameters and  measure-
ment methods for the field tests. Again, the
format for the LWS tests is somewhat sim-
pler. The detailed measurement format will
be applied to selected test conditions to more
fully characterize burner performance. Dur-
ing the LWS tests, the detailed measurement
format will be applied to the original equip-
ment burner tests and the tests of the op-
timized low  emission burner. The test
conditions will be selected to cover the range
of operation of the field boilers so that com-
plete maps of burner performance will be ob-
tained. During the  field tests, the detailed
measurement format will be applied similarly
to map burner/boiler performance. The de-
tailed measurement format includes manual
measurements of several parameters,  in-
cluding paniculate mass, particulate size
distribution, and SO3. These measurements
are time-consuming and may limit the rate
of testing.

Effluent Stream Analysis
  This, the most complex measurement for-
mat, will be applied to a few test conditions
of special significance. It is based on an EPA
Level 1 Environmental Assessment including
 Table 2.    Standard Measurement Format Summary (Field)

                        Test Conditions
bioassay, as well as certain other emission
measurements. As a minimum, the effluent
stream analysis will be applied to the full-load
operating conditions of the original equip-
ment burners and low-emission burners at
each field evaluation site.

  Corrosion will be measured to ensure that
the low emission burners do not contribute
to furnace wall corrosion.  These measure-
ments will  be conducted only in the field
boilers, since the LWS tests are too brief to
accurately assess corrosion rates. Corrosion
panels will be installed before the low emis-
sion burners are installed so that data can
be  obtained with the original equipment
burners. While installing the low emission
burners, tube thickness will be measured at
several locations to establish baseline corro-
sion rates. After the long-term tests of the
low emission burners,  the corrosion panels
will be removed and the tube thicknesses will
be  remeasured, to provide a direct com-
parison of the corrosion rates for the two
burners.
  During the LWS tests,  data quality will be
maintained by following the test procedures
in the protocol. However, the increased im-
portance of the field tests requires a data
quality control plan. To ensure that the emis-
sion measurements are accurate, EPA meth-
ods will be used as the primary measurement
methods or as reference methods. In addi-
tion, the continuous monitoring system will
be  constructed,  calibrated,  verified, and
operated according to EPA Performance
Specifications 2 and 3. The field tests will
also be subjected to a quality assurance audit
by an independent EPA  contractor.
  The measurements protocol is a working
document. It is recognized that, in a 4-year
program, there are likely to be advances in
                                                                                        Test Outputs
Parameter
Furnace Design
Burner Design
Burner Adjustments

Registers
Dampers
Others
Fuel
Composition

Flow Rate
Combustion Air

Flow Rate
Temperature
Distribution

Measurement Method



Direct Measurement




Obtain Sample (analyze
under detailed format)
Boiler Instrumentation


Boiler Instrumentation
Boiler Instrumentation
Internal Flowmeters or
Boiler Instrumentation
Parameters Measurement Method
Flame Characteristics
Length
Width

Standoff
Stability
Gas Phase Species
02
NO/NO,

CO
CO2


Direct Observation
and/or Color Video

Flame Scanner


Continuous Analyzers



Other
Thermal Performance Boiler Instrumentation
Smoke Direct Observation
Windbox Pressure Boiler Instrumentation
Burner Temperatures Thermocouples

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Table 3.    Detailed Measurement Format Summary (Field)

                        Test Conditions
                                                    Test Outputs
    Parameter
                                     Measurement Method
                                 Parameters
                           Measurement Method
   Fuel
      Composition
ASTM Methods (ultimate
and proximate)
EER Laboratory Methods
(ultimate)
Particulate
   Total mass

   Composition
EPA Method 5

EER Laboratory Methods
(ultimate)
Size Distribution ASME Method Size Distribution
Carbon Balance
CO, C02
Hydrocarbons
Particulate
Bottom Ash

Coal
Sulfur Balance
SO2

S03

Particulate
Bottom Ash
Coal
Thermal Balance
Gas Concentrations in
the Furnace
Andersen Cascade Impactor

Standard Measurement Format
Hot F.I.D.
Same as Above
Grab Sample and EER Laboratory
Ultimate Analysis
Same as at left

Continuous Monitor and/or
EPA Method 6
EPA Method 8 and Controlled
Condensation
Same as Above
Same as Above
Same as at Left
ASME Method
Continuous Monitors

the state-of-the-art; therefore, the protocol
will be updated throughout the program.
These revisions will come about because of
data generated In the program and from data
obtained from such  other sources as en-
vironmental impact  studies and relevant
development programs.

Boiler Baseline  Evaluation
  The initial host boiler is Pearl Station Unit
1, operated by Western Illinois Power Cor-
poration (WIPCO). This small utility boiler is
representative of the design used for many
larger industrial boilers. It has four Foster
Wheeler intervene burners (pre-NSPS), rated
at 70x10" Btu/hr each. These burners,  ar-
ranged two high by two wide on the front
wall, currently fire a high-volatile, high-sulfur
bituminous coal.
  This unit was tested to establish baseline
performance before installing the low NOX
burners. The tests were conducted in four
series:  burner modification test,  30-day
baseline test, thermal efficiency test, and ef-
fluent stream analysis.
  The  burner modification test  involved
evaluating boiler performance at conditions
spanning the full range of operation.  Rela-
tionships between the operating parameters
(load, excess air,  and burner settings) and
performance were evaluated. In addition,  the
potential for NO reduction by off-design
point operation, burners out of service, etc.,
was determined. The 30-day baseline test in-
volved  monitoring  burner/boiler  perfor-
mance continuously over a 30-day period.
       Boiler load and operating conditions were
       selected by boiler operators as determined
       by steam demand and previous experience.
       This test was conducted immediately after
       the burner modification test. Over the 30-day
       period, the boiler operated at full load most
       of the time. The emissions were comparable
       to those measured at full load during the
       burner modification test. The thermal effi-
       ciency  tests  included measurement of the
       distribution of heat absorption among the
       various components as well as assessment
       of overall thermal performance. Results of
       the burner modification test are summarized
       below. Data analysis for the other series is
       still in progress.
         The  maximum continuous rating (MCR)
       for the boiler is 20.0 MW. This corresponds
       to a firing rate of 70x10* Btu/hr for each
       burner. The design point excess air is 18 per-
       cent, resulting in 3.3 percent 02 in the dry
       combustion products. The boiler is normally
       base-loaded  and operates at this condition
       for extended periods.
         The flames from all four burners stabilized
       close to the throat exit (within about 2 in.).
       This is similar to the flame shape observed
       during  the tests of a similar burner in the
       LWS. The WIPCO furnace  was filled with
       luminous combustion products, and it was
       difficult to delineate flame boundaries. The
       flames were definitely shorter than the fur-
       nace depth  (no rear wall  flame impinge-
       ment); however, they were not symmetrical
       in the furnace. The flames on one side of the
       furnace brushed (or rolled)  along  the side
                     wall, while those on the other side remained
                     well clear of the wall. Measurements of fur-
                     nace gases along the side walls confirmed
                     that reducing conditions (zero 02 and high
                     CO) existed in the areas where the flame was
                     observed to contact the furnace wall. Mea-
                     surements of the same gases at 12 probe
                     locations upstream of the air heater resulted
                     in essentially uniform results. Thus, varia-
                     tions in gas concentrations exiting the burner
                     zone are effectively smoothed  out in the
                     upper furnace and/or convective pass. Reg-
                     ister adjustments were unsuccessful in pro-
                     ducing symmetrical flames. Foster Wheeler
                     has advised that this condition is unusual and
                     is investigating the problem.
                       Gas-phase concentrations measured up-
                     stream of the air heater at the MCR design
                     point were:
                                         Concentration
                          Species	Dry, 0% 02
                             02
                             NO
                             CO
                             C02
                             S02
                             HC
                  ~ • i i      *•
            3.42% (as  measured)
            829 ppm
            41 ppm
            18.0%
            2964 ppm
            1 ppm	
                       These results are the average of four tests.
                     The 02 concentration corresponds to 18.7
                     percent excess air, and the load averaged
                     20.5 MW. These are essentially the design
                     point conditions. Carbon and sulfur balances
                     based on the typical coal analysis result in
                     18.2 percent CO2 and 3200 ppm S02 for full
                                      4

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conversion. Thus, the C02 and S02 concen-
trations are reasonable. The low CO and HC
concentrations  are  comparable to those
observed on other Foster Wheeler boilers of
similar design (CO emissions are typically
reported as "less than 50 ppm"). The NOX
emissions are somewhat higher than ex-
pected for boilers  of this  type.  Foster
Wheeler had previously estimated 700 ppm
(600 ppm  <§> 3% 02).
  Burner/boiler  performance was measured
over a range of excess air at full load (MCR).
The NOX results are shown in Figure 1. NOX
is observed to decrease with excess 02 as
expected. The minimum excess 02 (2.5 per-
cent) was specified by the WIPCO manage-
ment. Based on  their experience, the flames
may become  unstable  at lower 02 levels.
However, this was not observed during the
current tests.  Over the range of excess air,
CO and  hydrocarbon (HC) emissions re-
mained the same as the design  point. With
all four burners  in service, the boiler could
be operated over a 13 to 21 MW range. The
upper end of the range was based on steam-
side limitations. Previous attempts to exceed
21 MW resulted in a loss of steam pressure
in  the  accumulator. The lower end of the
range was based on flame stability problems
which  have been  encountered at lower
loads. The reason for the instability has not
been determined. The instability may be due
to the  inability of the oversize coal feeders
to operate at low feed rates. Another pos-
sibility is that the flame scanning system was
improperly adjusted, resulting in a loss-of-
flame indication.
  The effect of load on NOX emissions with
all burners in service is shown in Figure 2.
   1000


    900


    800

 I
 c)
 0  700
O  600
    500
O
                                       02 = 3.3 ± 0.3%
                                       Reg., Core - Baseline
               13      14      15     16      17

                                      Load.MW[e]
                                    18
19
                                                   20
                                                           21
Figure 2.    Effect of load.


The load curve  is quite flat  with  NOX
decreasing by about 50 ppm as the load is
reduced from 100 to 75 percent of MCR.
There was no significant change in CO or HC
emissions over this range. CO and HC emis-
sions were always less than 30 and 3 ppm,
respectively.
  The WIPCO boiler could not be operated
with one mill (two burners) in service without
supplementary oil firing for flame stability.
Attempts to shut off the supplementary oil
firing with two burners in service caused the
   ;ooo
    900
    800
O  700
o
    600
    500
                                                           Load = 20.3 ± 0.3 MW(e)
                                                           Reg., Core = Baseline
                    J_
        o            ;             2            3
                                     Excess Oz, %
Figure 1.    Effect of excess air variation at MCR.
                          flames to lift off the burners, resulting in a
                          loss-of-flame indication on the flame scan-
                          ning system. The flames might have stabi-
                          lized out of range of the scanning system,
                          but this was not confirmed due to the limited
                          duration of the tests. Foster Wheeler has ad-
                          vised that this is not typical of normal opera-
                          tion. The burners normally have a 2.5/1
                          turndown range and operate  stably with
                          some burners out of service.

                          Prototype Burner Tests
                            The DMB concept involves staging the
                          combustion process to minimize NOX emis-
                          sions while maintaining an overall oxidizing
                          atmosphere in the furnace to avoid furnace
                          slagging  and corrosion. NOX production
                          from fuel nitrogen compounds  is minimized
                          by driving a majority of the compounds into
                          the gas phase under fuel-rich conditions and
                          providing a stoichiometry/temperature his-
                          tory which maximizes  the decay of the
                          evolved nitrogen compounds to N2. Thermal
                          NOX production is also minimized by en-
                          thalpy loss from the fuel-rich  zone which
                          reduces  peak temperatures.
                            Figure 3 shows the DMB concept sche-
                          matically. Staging is achieved by arranging
                          the components for three zone combustion.
                          In the first zone, pulverized coal (transported
                          by the primary air) combines with the inner
                          secondary air to form a very fuel-rich (30 to
                          50 percent theoretical air) recirculation zone
                          which  provides flame stability.  The coal
                          devolatilizes and fuel nitrogen  compounds
                          are released to the gas phase. Outer secon-

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                 Tertiary Air
                   Outer
               Secondary Air
     Inner
  Secondary Air
            X
  Coal and _
Primary Air
                      Very Fuel Rich
                     Zone (A verage
                   Stoichiometry 40%)
                                   Progressive Air Addition Zone
                                    (Overall Stoichiometry 70%)
         Final Air Addition Zone for Burnout
            (Overall Stoichiometry 120%j
Figure 3.    DMB concept.

dary air is added in the second burner zone
where Stoichiometry increases to about 70
percent theoretical air. This is the optimum
range for reduction of bound nitrogen com-
pounds to N2. Air to complete the combus-
tion process is supplied through tertiary ports
outside the burner throat. This allows sub-
stantial residence time in the burner zone for
decay of bound nitrogen  compounds to N2
and radiative heat transfer to reduce peak
temperatures. The tertiary ports surrounding
the burner throat provide an overall oxidiz-
ing atmosphere  in the burner zone.
  A prototype DMB was designed  to meet
the requirements of the  initial host boiler.
The design involved integrating DMB design
parameters (based on previous tests),  the
characteristics of the host boiler, and Foster
Wheeler burner components. Figure  4 shows
the central portion of the burner without the
tertiary air ports.
  The prototype burner is being tested in the
LWS to optimize performance prior to install-
ing field operable burners in the host boiler.
The tests are  being  conducted  in  four
phases:
  • Flow Characteristics — This  includes
    cold flow measurements of velocity and
    swirl in the  burner exit and calibration
    of the air flow rates through the burner
    passages as functions of pressure drops.
  • Unstaged Tests — The burner is being
    tested unstaged to verify that field  per-
    formance will be satisfactory if a prob-
    lem should develop with the tertiary air
    port system during field operation.
   • Staged Tests — This is the  major test
    series: burner performance is evaluated
    at the design operating point.
  • Performance Optimization/Verification
    — This includes adjusting the burner for
    optimum balance of flame stability, ef-
    ficiency,  and emissions.
  The flow characterization tests have been
completed. The velocities and swirl in the
burner exit were measured as a function of
burner settings. This information will be used
to identify the aerodynamic conditions which
optimize overall burner performance so that
improved DMBs can be designed for future
applications.  Comparison with test results
                       Core Air
                      /Valve
          f
           from an intervene burner, which was also
           tested, shows that the pressure drop across
           the DMB  is consistently lower.  (Thus fan
           capacity in the host boiler should be ade-
           quate for  the DMB.)

             The initial combustion tests were con-
           ducted in a research furnace without refrac-
           tory insulation. Typical test results are shown
           in Figure 5.  Both unstaged and staged test
           results are shown at full load. For unstaged
           operation, the burner zone Stoichiometry is
           equal to the overall Stoichiometry. NO emis-
           sions were sensitive to excess air and were
           nominally 320 ppm at 120 percent theoretical
           air  (T.A.), a typical field burner operating
           condition.  The  CO emissions were unaf-
           fected by excess air down to about 110 per-
           cent T.A., where they rose  sharply. This
           unstaged  behavior is typical of the perfor-
           mance of many burners operating in field
           boilers.  However, the  CO emissions are
           about a factor of four higher than typical field
           levels. This is probably a consequence of the
           lack of insulation in the research furnace, as
           discussed below.

             A brief  series of staged tests were con-
           ducted with the overall excess air at 130 per-
           cent T.A. As the degree of staging was
           increased  (burner zone Stoichiometry de-
           creased), the NO emissions decreased as ex-
           pected. The dotted line in Figure 5 is  an
           extrapolation to the staged design point. CO
           emissions  increased substantially as  trie
           degree of staging increased. Again,  this is
           believed to be a consequence of the research
                                         Perforated Plate
                                            Air Hoods
                               Removable
                                 Nozzle
                                 Rings
                                         Firing
                                          Face
                                                                   Telescoping
                                                                 ' Inner Nozzle
Ignitor
                Coal Inlet
   Inner
Register

   Outer
Register
                                                                       Cast Refractory
                                                                            Exit
Figure 4.    Prototype DMB based on Foster Wheeler design (tertiary ports not shown).

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                                  Load- 80 x 10*Bw/hr
   600
   500

   400
   300
   2OO
    700
 I  I  I  I  I  I
T.A. = Theoretical Air
     Staged
    130% T.A.
        ~ Staged
        Design Point
         118% T.A.
                             Unstaged
          I   I   I   I   I   I   1   I   I   1
600
                                             500
                                £400
                               Q

                               O
                               &300
                               g 200
                                  700
II  I   I  I  II
T.A. = Theoretical Air
                                                                   Staged
                                                                 '130% T.A.
                    (
                    ^-Unstaged

      I  I  I  I  I   I   I  I   I   I
        50
         100            150            50
                 Burner Zone Stoichiometry, 9
                                                              700
                                                                             150
                                                       T.A.
Figure 5.    Prototype burner performance in L WS (staged).
furnace design  which was  considerably
"colder" than field operating boilers.
  Following these tests, the  research fur-
nace was rebuilt. The new furnace was par-
tially insulated with refractory to provide a
thermal environment similar to  field oper-
 ting boilers. Figure 6 shows the results of
 taged tests repeated in the new test facil-
ity. These tests were conducted at lower ex-
cess air, and the NO emissions are essentially
the same as the extrapolation based on the
initial data. However,  CO emissions are
much lower, in the  same range as field
operating boilers. This confirms that the high
CO emissions measured in the initial furnace
were due to research furnace design and did
not  indicate burner performance which
would be measured in the field.
  The minimum burner zone Stoichiometry
tested,  85  percent T.A., was the burner
stability limit. Increasing the degree of stag-
ing beyond this point resulted in flame de-
tachment. The  minimum NO emissions at
the stability limit were 185 ppm, correspond-
ing to about 0.21 lb/106 Btu, close to the pro-
ject goal. Extrapolating the  NO emissions to
the design point (70 percent T.A.) indicates
approximately 100 ppm. During subsequent
test series, burner parameters will be ad-
justed to increase stability at low burner zone
Stoichiometry.
  The difference in thermal environment in
the old and new LWS provides additional in-
sight into the potential performance of the
DMB in a field  operating boiler. Foster
Wheeler has found that NOX emissions from
their commercial firing equipment can be
  •related with the heat release  per cooled
  face area in the lower portion of the fur-
                                nace. Figure 7 shows Foster Wheeler's cor-
                                relation for the pre-NSPS intervene burner.
                                Data for the prototype DMB (extrapolated
                                to the design point) are  also shown. Note
                                that the heat release per cooled surface area
                                (BZLR) for the new LWS  is slightly less than
                                for the initial field boiler (WIPCO).  The line
                                drawn through the prototype DMB  data has
                                the same shape as the correlations for the
                                intervene burner and  suggests that NOX
                                emissions from the field  evaluation will be
                                slightly higher than the prototype burner test
                                    700
                                I
                                    600
                                    500
  400
                                    300
                                ©   200
                                    700
                                              T.A. = Theoretical Air
                Old LWS
         Load = 80x10* Btu/hr
             0 - 130% T.A.
                                         Extrapolation
                                         of Old LWS Data
                                         to Design Point
results. Of course, this correlation does not
account for the differences in the furnace
geometry and flame-to-flame interactions in
the field evaluation  boiler.
  As discussed above, the prototype DMB
tests, involving no  optimization  of burner
geometry or adjustments, resulted in unac-
ceptable flame stability  at the design op-
erating point. Therefore, these low NO levels
can only be achieved in the field if the burner
can be modified to improve stability. How-
ever, NO emissions in the range of 0.2 lb/106
Btu appear feasible with the current design.

Future Efforts
  The schedule for the remainder of the pro-
gram depends on the schedule for installing
the DMBs in the field evaluation boilers. Both
boilers operate continuously except for brief
maintenance outages once or twice a year.
The outages are scheduled during  periods of
low power demand (spring and fall) when the
utilities are able to  purchase replacement
power from interconnected power plants. To
minimize  problems  for  the  field  boiler
owners/operators, the DMBs must  be in-
stalled  during the scheduled outages. Con-
sidering the overall aspects of the program
and the outage schedules, the earliest possi-
ble dates for installing the DMBs are:  initial
field evaluation (WIPCO), 3/15/81; and sec-
ond field evaluation, 3/15/82.
  Based on the prototype DMB test results,
additional testing in the LWS will be required
to identify the burner parameters and set-
tings which optimize performance and to
verify burner operation  over the required
                                          700
                                       -  600
                                                    ••°f
                       New LWS
                Load = 69-78 x 10* Btu/hr
                   0= 118-126% T.A.
                   I      I      I      I
                                         J300
                                          200
                                                                            700
                                          I      I       I
                                         T.A. = Theoretical Air
                                                                                                 e,
                                                                                                         I
                                                                                                                O
                                                                                                                I
                                       60    70
                                                   80
                        90
                     100   110
                                                                              60
          70
80
                                                                90
                                                             100    110
                                                            Burner Zone Stoichiometry, % T.A.
                                Figure 6.    Comparison of staged prototype burner performance in old and new L WS.

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    1.2

    1.1

    1.0

    0.9


I  ^
?  0-7
S  0.6

5  o.s

    0.4

    0.3

    0.2

    0.1
               Foster Wheeler.
               Intervene Burner
               in Single-Wall-^
               Fired Field
               Boilers
                WIPCO
                   l
                   .DMB Prototype (LWS)
              100     200     300
               BZLR. 103Btu/hr-ft"
                                    400
Figure 7.    Prototype burner tests in the old
            and newL WS: comparison with
            Foster Wheeler NOiCorrelation.

range. Unfortunately, the time available prior
to the spring burner installation date will be
insufficient to incorporate the test results in
the field operable burner design and fabricate
four burners. Thus, this approach requires
the burner design to be established and
fabrication to be started based on  current
test data. Subsequent prototype burner test
results would then be used to verify that the
burner design is satisfactory. This is a high
risk approach because it is possible that the
prototype test results may determine that the
burner design must be modified.
                                             An alternate approach would be to incor-
                                           porate the Foster Wheeler proprietary burner
                                           criteria into the prototype OMB. Burners
                                           designed according to these criteria have
                                           already been demonstrated to be stable over
                                           the required operating range. They could be
                                           installed in the field  boiler and operated
                                           unstaged  without additional prototype
                                           burner testing. However, satisfactory staged
                                           operation would need to be verified. This ap-
                                           proach would ensure that the low NOX
                                           burners are installed as early as possible and
                                           would maximize the probability of success
                                           through the use of proven commercial hard-
                                           ware.  Approval to proceed with this  ap-
                                           proach has been received from the Project
                                           Officer.
  The second demonstration  has  been
scheduled so  that results from the initial
demonstration can  be evaluated  prior to
freezing the burner design. The burner de-
sign for the second  field evaluation will be
based on the  prototype burner design  re-
cently tested in the  LWS.

Conversion Factors
  Readers more familiar with metric units
may use the following factors to convert
nonmetric units  used in this Summary to
their metric equivalents:
Nonmetric	Times    Equals metric
                                                                                       Btu/hr
                                                                                       Btu/hr-ft2
                                                                                       lb/106 Btu
                 2.93
                11.35
                 430
   W,
kJ/hr-m2
  ng/J
                                               B. Folsom. L Nelson, A. Abele, J. Reese, and J.  Vatsky are with Energy and
                                                Environmental Research Corp., Irvine, CA 92714.
                                               G. Blair Martin is the EPA Project Officer (see below).
                                               The complete report, entitled "Evaluation of Low Emission Coal Burner Technology
                                                on Industrial Boilers: Second Annual Report (1980)," (Order No. PB 84-159
                                                227; Cost: $14.50, subject to change) will be available only from:
                                                       National Technical Information Service
                                                       5285 Port Royal Road
                                                       Springfield,  VA 22161
                                                       Telephone: 703-487-4650
                                               The EPA Project Officer can be contacted at:
                                                       Industrial Environmental Research Laboratory
                                                       U.S. Environmental Protection Agency
                                                       Research Triangle Park, NC 27711
United States
Environmental Protection
Agency
                                    Center for Environmental Research
                                    Information
                                    Cincinnati OH 45268
Official Business
Penalty for Private Use $300

                                                                                          US. GOVERNMENT PRINTING OFFICE: 1984-759-102/917

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