United States
Environmental Protection
Agency
Municipal Environmental Research
Laboratory
Cincinnati OH 45268
Research and Development
EPA-600/S2-82-018 August 1982
Project Summary
Seattle  Distribution  System
Corrosion Control  Study:
Volume  III.  Potential for
Drinking Water Contamination
from Tin/Antimony  Solder

Carlos E. Herrera, Gregory J. Kirmeyer, and Brian P. Hoyt
  This study was conducted to evalu-
ate the potential leaching of metals
into drinking water from tin/antimony
solder. The study consisted of five
research steps: (1) An investigation of
the theory of corrosion products that
formed  from  the solder was con-
ducted using pe-pH diagrams and gal-
vanic coupling relationships, (2) static
laboratory metal leaching tests were
performed to determine the extent of
antimony leaching from the solder, (3)
field water samples were taken from
buildings that contained tin/antimony
soldered plumbing, (4)  continuous-
flow metal leaching tests were used to
compare metal leaching from tin/an-
timony solder with lead/tin  solder
under three water treatments (lime
plus sodium  carbonate, lime plus
sodium  bicarbonate, and lime plus
sodium bicarbonate plus silicate), and
(5) corrosion  films that formed on
both tin/antimony and lead/tin solder
were analyzed by scanning electron
microscopy and X-ray diffraction.

  The results indicate that increases in
metal concentrations  resulting from
the corrosion of tin/antimony solder
are minimal. Metal leaching from the
solder is inhibited by the sacrificial
corrosion of tin and the formation of a
stable, double-layer tin passivation
film (SnO and SnO2). Side-by-side
tests comparing metal leaching from
tin/antimony with that from lead/tin
solders show substantial reductions in
standing  water lead concentrations
when tin/antimony solder is used.

  The use of tin/antimony solder in
place of  lead-based solders should
result in reduced human exposure to
lead from drinking water with only
minimal  increases  in  antimony
exposure.

  This Project Summary was devel-
oped by  EPA's Municipal Environ-
mental  Research  Laboratory,
Cincinnati, OH, to announce key find-
ings of the research project that is fully
documented in a separate report of the
same title (see Project Report ordering
information at back).
Introduction
  The Seattle Water Department (SWD)
serves an average of 161 mgd of high
quality water to a population of more
than 1 million in the Greater Seattle
area. The water originates in the Cas-
cades from two mountain sources— the

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Cedar and Toll Rivers. The watersheds
are  well  protected  and  the  water
requires only disinfection with gaseous
chlorine to  meet state requirements
These mountain waters, which are pre-
dominantly  rainfall  and  snowmelt
runoff, are  very soft and tend to  be
highly corrosive to the unlined, metallic
pipes in home plumbing systems.
  The corrosiveness of Cedar and Tolt
water results from several related fac-
tors, including:
  • Acidity,  as indicated  by low  pH
    (after chlorination andfluoridation,
    pH is reduced to a range of 6.8 to
    7.2 for the Cedar supply and 5.8 to
    6.2 for the Tolt supply);
  • Dissolved oxygen concentration at
    saturated conditions;
  • Insufficient calcium and bicarbo-
    nate alkalinity in the water to form
    protective calcium carbonate films
    on pipe  surfaces; and
  • A relatively high [halogen + suit a -
    te]/'alkalinity  ratio that  indicates
    conditions  favorable to pitting
    corrosion.


  In 1970, three factors  combined to
intensify the corrosiveness of the water
supplies. First, the chlorine dosage at
the open distribution reservoir outlets
was increased to decrease the occur-
rence of positive bacteriological  sam-
ples within  the distribution system.
Second,  ammoniation  of the  water
supply was stopped at the request of the
U.S. Public Health Service to enable a
free chlorine residual to be maintained
throughout the distribution system. This
change from combined chlorination to
free chlorination was implemented to
provide quicker, more effective disinfec-
tion of the unfiltered water supply. The
third factor  that increased corrosive-
ness was the initiation of flouridation
with hydrofluorosilicic acid in 1970.

  Corrosion  of the plumbing systems
and the associated water quality degra-
dation has been a major concern of the
SWD for many years. Studies performed
from 1972 to 1976 demonstrate that the
levels of lead, copper, and iron in over-
night standing tap water often exceed
the  maximum  contaminant  levels
defined by the National Interim Primary
and Secondary Drinking Water Regula-
tions. Cadmium  and zinc were also
found to increase after overnight stand-
ing in home plumbing, but they rarely
exceeded their maximum levels. These
metals originate from the copper and
galvanized pipes and the solders used in
home plumbing systems. Although the
health impact of metal levels from over-
night  standing water is not an accute
problem, it is certainly desirable to re-
duce exposure where possible.
  The use of lead-based solders to join
copper pipe can create a problem with
regard to lead leaching. To reduce the
potential for lead contributions from this
source, the maximum allowable lead in
solder was limited to 0.20% by amend-
ment of the Seattle plumbing code. The
effect of this amendment was to require
contractors to use  95/5 tin/antimony
solder

Purpose and Scope of Work
  This study was undertaken to evalu-
ate the potential leaching of metals into
drinking water from the tin/antimony
solder now being used in Seattle plumb-
ing. The study consisted of five research
steps: (1) An investigation of the theory
of corrosion products that formed from
the solder was conducted using pe-pH
diagrams and galvanic coupling rela-
tionships, (2) static  laboratory metal
leaching tests were performed to deter-
mine  the extent of antimony leaching
from the solder, (3) field water samples
were taken from the buildings that con-
tained tin/antimony soldered plumbing,
(4) continuous flow metal leaching tests
were  used to compare metal leaching
from tin/antimony solder with that from
lead/tin solder under three water treat-
ments (lime  plus  sodium carbonate,
lime plus sodium bicarbonate, and lime
plus sodium bicarbonate plus silicate),
and (5) corrosion films that formed on
both tin/antimony and lead/tin solder
were  analyzed  by scanning  electron
microscopy and X-ray diffraction.

Procedures,  Results and
Discussion
Theoretical Analysis
  An investigation of the theory of cor-
rosion products formed from the solder
was conducted using pe-pH  diagrams
and  galvanic  coupling  relationships.
Results indicated that the  leaching of
antimony from the solder may be inhi-
bited by two mechanisms:
  1. Sacrificial  Corrosion.   Though
    antimony alone is quite soluble, the
    galvanic  coupling  relationships
    among the three metals that make
    up a soldered joint (tin, antimony,
    and copper) indicate that the corro-
    sion of tin is theoretically more
    favorable  than  the corrosion of
    antimony. Tin, therefore, mayactas
    a sacrificial anode.
 2. Passivation. Since tin can be passi
    vated by tin oxide, a passivation filrr
    may cover the entire surface of tht
    solder  and therby inhibit meta
    leaching from the solder.

Laboratory Experiments
  Laboratory experiments  were con-
ducted to verify the theoretical phase of
the study Twenty test specimens con-
structed  from tin/antimony solder and
copper sheet were immersed in Cedar
water in a sealed 50-ml glass container.
The  samples were held under static
conditions at 20°C for periods of 0.5 to
98 hr. In addition, two samples of anti-
mony metal equalling the weight of
antimony in the solder specimens were
tested as described above for a 70-hr
period.
  The  laboratory  static coupon  tests
demonstrated that antimony dissolution
from tin/antimony  solder is substan-
tially  less  than   the  theoretical   or
observed dissolution from  pure  anti-
mony metal. The highest antimony con-
centration observed in the tin/antimony
solder  coupon test was  3.7 fjg/L,
whereas 18,000/ug/L and 22,000//g/L
of dissolved antimony were observed in
the  pure  antimony metal  corrosion
tests.
  These  results support the theoretical
conclusions already put forward. In the
short term, the inhibition of antimony
leaching from tin/antimony solder  is a
result of the galvanic coupling relation-
ship, namely the sacrificial corrosion of
tin.
Field Sampling
  The University of Washington has
been  using 95/5 tin/antimony solder
on  building plumbing  systems™Since
about 1968. The field study consisted of
taking 0.95-L samples of overnight tap
water that had stood overnight in eight
buildings on the University campus. The
plumbing  systems  of the  buildings
tested ranged from 1 to 10 years in age
and supposedly consisted of copper pip-
ing bonded with 95/5 tin/antimony
solder.
  Samples  of running water (0.95 L)
were  taken at the mechanical  room
(where the building  plumbing connects
with the distribution system) of each
building to obtain the characteristics of
the inflowwater The 0.95-L water sam-
ple that had stood overnight was then
taken from the potable water tap fur-
thest  from the mechanical room of the
building.

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  The samples were then analyzed for
temperature, conductivity,  alkalinity,
total and dissolved antimony, and total
lead, copper, and zinc.
  The field sampling showed that, in the
long term, antimony corrosion is inhi-
bited  by the passivation of  tin in the
solder.  Of all the  samples tested, a
detectable antimony concentration was
found in only one building water sam-
ple.  In  addition,  scanning  electron
microscopy  showed that two  distinct
passivation films were present on the
tin/antimony-soldered  joints removed
from the buildings at the University of
Washington.

Metal Leaching Tests
  Short pipe sections of copper, copper
plus 50/50 lead/tin solder, and copper
plus 95/5 tin/antimony solder were
attached to continuous flow test units
for comparison of copper, lead, tin, and
antimony leaching  under three  alterna-
tive  treatments. Two velocities were
used in establishing corrosion  films in
the metal leaching sections. The pipe
sections  were  periodically removed
from the continuous flow test unit and
dissolved metals were determined after
periodic  22- to 24-hr contact with test
water in the laboratory.
  The side-by-side metal leaching tests
indicated that lead  leaching is substan-
tially  less from tin/antimony solder
than from lead/tin solder. Some lead
initially leaches from the tin/antimony
solder; but after approximately 6 weeks
of testing, lead leaching was reduced to
below  the detection limit.  Antimony
leaching from the  95/5 tin/antimony
solder was also consistently below the
detection limit of 1.4^g/L.

Conclusions
  Lead   leaching  is   substantially
reduced and the subsequent increase in
the  antimony concentration  of the
drinking water is  minimal if tin/antimo-
ny solder is used in plumbing systems in
place of  lead-based solder. The low
metal leaching levels from 95/5 tin/an-
timony solder are mainly because of the
sacrificial corrosion of tin and the for-
mation of a tin oxide passivation film
that protects the surface of the solder
from corrosion.
  The  theoretical   and experimental
results obtained  in  this study therefore
indicate that 95/5 tin/antimony solder
would be an excellent replacement for
lead-based solders  in private and com-
mercial  plumbing systems where lead
leaching is a problem.
  The full report was submitted in ful-
fillment of Grant No. R-806686-010 by
the Seattle  Water Department under
the sponsorship of the U.S.  Environ-
mental Protection Agency.
  Carlos E. Herrera, Gregory J. Kirmeyer, and Brian P. Hoyt are with the Seattle
    Water Department, Seattle, WA 98144.
  Marvin  C. Gardels is the EPA Project Officer (see below).
  The complete report, entitled "Seattle Distribution System Corrosion Control
    Study: Volume III. Potential  for Drinking Water Contamination from  Tin/
    Antimony Solder," (Order No. PB 82-231 242;  Cost: $10.50, subject to
    change) will be available only from:
          National Technical Information Service
          5285 Port Royal Road
          Springfield, VA22161
          Telephone: 703-487-4650
  The EPA Project Officer can be  contacted at:
          Municipal Environmental Research Laboratory
          U.S. Environmental Protection Agency
          Cincinnati, OH 45268
t US. GOVERNMENT PRINTING OFFICE 1982-559-017/0768

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