United States Environmental Protection Agency Environmental Monitoring Systems Laboratory Research Triangle Park NC 27711 Research and Development EPA/600/S4-85/012 Mar. 1985 Project Summary Field Experience with Four Portable VOC Monitors Robert A. Ressl and Thomas C. Ponder, Jr. This report discusses the field opera- tion problems associated with use of four portable volatile organic compound (VOC) detection instruments in con- ducting Reference Method 21 VOC screenings. The report presents the results of the field trials and summarizes the ease of use of each instrument. Information on operational problems and recommendations are provided. Also included are discussions of the features that would make all portable instruments more reliable, durable, or convenient to use. Based on the data collected for this study, three of the instruments report similar leak rates in the facility where they were used. This Project Summary was developed by EPA's Environmental Monitoring Systems Laboratory, Research Triangle Park, NC, to announce key findings of the research project that is fully docu- mented in a separate report of the same title (see Project Report ordering in- formation at back). Introduction The U S. Environmental Protection Agency (EPA) has issued performance standards and guidelines to limit emis- sions of volatile organic compounds (VOC) from several stationary source categories. These industries such as petroleum re- fineries, synthetic organic chemical plants, and natural gas processing plants emit significant quantities of VOCs from sources other than classical point sources into the workplace and surrounding at- mosphere. These fugitive VOC emissions occur from valves, pumps, drains, pres- sure relief devices, etc. As described in 40 CFR 60, Appendix A, Reference Method 21 (RM 21), Deter- mination of Volatile Organic Compound Leaks, there are technically feasible devices suitable for monitoring fugitive VOC leaks. These devices can be placed near possible points of emissions and will respond to releases of the organic com- pounds. Specific instruments suitable for this purpose include, but are not limited to, catalytic oxidation, flame ionization, infrared absorption, and photoionization detectors. Subsequent "field use of portable VOC detectors has disclosed some instrument- specific problems such as undetected flame-outs, plugged orifices from dirt, high background readings due to chem- ical absorption on probe and tubing surfaces, high humidity effects, varying or lack of response, long response times, and calibration drift. To identify and document these types of problems, four monitors were used to conduct screening following RM 21 procedures. This report provides basic information on each instrument, howthey were used, what operational problems were encount- ered during and between screenings, and the ease of use of each instrument in relation to the other three. Special atten- tion was given to documenting opera- tional problems and ease of use. Field Trial Methods The following VOC analyzers were used during the study • Foxboro Century Systems Portable Organic Vapor Analyzer Model OVA- 108 • UnitedTechnology'sBacharach Instru- ments Model TLV Sniffer* • Analytical Instruments Development, Inc., AID Model 712* • HNu Systems, Inc., Model PI-101 "Registered Trademark ------- The instruments used represent three types of detectors. The OVA and Analyt- ical Instruments Development, Inc., Mod- el 712 (AID) are flame mnization detec- tors(FID). UmtedTechnology's Bacharach Instruments, Inc., Model TLV Sniffer (TLV) uses catalytic oxidation. The HNu Systems, Inc., Model PI-101 (HNu) uses a photoionization detector (PID). A comparison of the manufacturers' published specifications was made with the RM 21 requirements. Although some of the instruments did not appear to meet the RM 21 requirements, all the instru- ments were used and their field exper- ience reported. No attempt was made to make a rigorous evaluation of each instrument or of RM 21. However, where possible, the requirements of RM 21 were met. Two types of operational tests were conducted with the equipment—a reli- ability check and field operations. In the reliability check the instruments were charged and allowed to operate for sever- al 8-hour periods. This test provided some assurance that the instruments could operate over an 8-hour period. In the field operations all four instruments were used to screen a series of 200 to 300 sources. Following the screening, the instrument operator completed an evalua- tion sheet, reported any problems with the instrument, and provided general subjective comments on the instrument as a leak detection tool. Screening was conducted at two petroleum refineries, a chemical manufacturing plant, and a natural gas processing facility. Summary of Evaluations The field trials were designed to provide subjective comments on the instruments' performances Table 1 summarizes the comments developed from the screen- ings. All the instruments except the HNu were equipped with some kind of probe filter, and these filters were always installed. However, a 2-inch length of plastic tubing loosely stuffed with glass wool was added to protect the probe from contamination by the greases and oils present at many sources. The instru- ments' responses were the same with and without the plastic tubing in place. The tubing is easily replaced and reduces time spent in the field cleaning the metal sample probes. The tubing was normally replaced on an as-required basis which was fairly frequently. The replacement criteria was based on appearance of the tubing. If there was any visible contam- ination on it, it was replaced. The TLV comes without a shoulder strap making it very awkward to use for screening. Also, since the zero knob is easily moved, a piece of tape was used to secure it. This prevented having to con- stantly check and reset the instrument zero. The OVA comes with one strap. How- ever, after several screenings it was realized that if worn as a backpack it would be easier to use, make the operator more mobile, and speed up the screen- ings. Therefore, a second strap was purchased from the manufacturer so that the OVA could be worn as a backpack, using the two carrying straps as a shoul- der harness. Since the OVA has a readout on the hand-held probe, this did not create any problem. However, when the instrument flamed out, relighting it was a little awkward since the operator had to either get someone else to press the igniter button on the case or let the case slip forward on the shoulders and stretch around to reach it. Desirable Instrument Features and Recommendations for Future Studies The desirable features that should be included in a field screening instrument are as follows: • The strap should allowfor carrying the instrument on the back, out of the way, leaving the hands free for climbing, handling log sheets, and manipulating the probe and readout (assuming the readout is attached to the probe). • The calibration controls should be located in the backpack and protected by the instrument case cover. All controls should have locks to prevent unintentional movement. • The readout should be analog and use a logarithmic scale that ranges from 10 to 100,000 ppm. RM 21 must be modified to accept the resulting scale divisions. • The readout should have a lock-and- hold reading capability and/or hold- highest-reading function switch. • There should be provisions to use the instrument as a go/no-go detector with indicator lights to show whether the reading is above or below the calibration point. • An igniter button should be located on the probe/readout if the instrument uses an FID. • A series of status indication lights should appear on the probe/readout assembly to show if the instrument has sufficient battery charge and if it is responding. • The sample line connecting the back- pack and probe/readout should be at least 4 feet long and very flexible. • A holster should be provided for the probe/readout so that both hands can be free for climbing and handling data sheets. • The probe assembly should have pro- visions for frequent cleaning because the probe becomes contaminated with grease and other materials during the screening process. • The system should be protected from the elements and be able to operate in light rain, high humidity, and high ambient temperatures. • The system should protect the recharge- able battery from overcharging and deep discharge. Provisions should be made for easy battery removal and replacement. Ideally, the charging system should be capable of being left on charge at all times. There should also be an indication of when the unit is within one hour of being too weak to operate effectively. This would provide time to check the instrument calibra- tion before the unit required recharg- ing. • The calibration system should allow for easy calibration to multiple calibra- tion gases Available and additional data on leak rates, repeatability of screening values, and responsefactorsforVOC instruments should be assembled in a screening hand- book to present the kinds of information necessary for a proper screening pro- gram. Information should be included on how to screen various types of sources, how to prepare log and repair sheets, response factors of various instruments, lists of typical compounds encountered in various types of facilities, etc. Screening procedures should be developed for organ- ic materials with response factors greater than 10. ------- Table 1. Summary of Operating Problems Item OVA TLV HNu AID Carrying strap Battery Battery charger Instrument readout The best arrangement of the instruments evalu- ated. Acceptable during period of evaluation. Acceptable during period of evaluation The analog readout with logarithmic scale was conveniently lo- cated in the probe and very easy to use. No strap; instrument was earned by a handle that was sometimes inconvenient Acceptable during period of evaluation Acceptable during period of evaluation The readout in the con- trol unit was less con- venient to read than on the probe but was acceptable It required frequent scale changes that were some- what inconvenient. The strap was very nar- row and after an hour of carrying was quite uncomfortable Acceptable during period of evaluation Acceptable during period of evaluation. The readout in the con- trol unit was less con- venient to read than on the probe but was acceptable. It required frequent scale changes that were some- what inconvenient The strap was unpadded and, although reasonably wide, the edge of the strap became very uncom- fortable after an hour of carrying. Acceptable during period of evaluation Acceptable during period of evaluation The digital readout was difficult to read from an angle, and the fre- quency with which it had to be updated made selec- tion of a reading value difficult Calibration knob or zero/span adjustment On/off and other controls Sample line and instrument umbilical The knob could not be secured. However, since it was located on the control module, which had a cover, it did not require secur- ing. The controls are on the control module. The instrument and pump switches are easily moved (newer models have locking toggles). The handles on the hydrogen supply are too short (newer models have longer ones} The gas select knob was not used since span gases were used for calibration The sample line tends to kink after long use when the protective sleeve slips. The line could be longer. The electrical connector at the control module has been weakened and has shorted The zero adjust knob (only adjustment) was located on the control module and could not be secured. It was easily and frequently bumped, requiring re-zeroing of the instrument, until it was secured with tape. The on/ofl'/standby, battery, operate, and range switch caused no problems The sample hose could be longer During the evaluation period, the hose developed a kink and would frequently pinch off, causing the pump to stall and the instrument to operate improperly The zero knob was some- what protected and was quite stiff to turn. It is located on the control module and did not require securing. The controls were acceptable. The umbilical was too sh'prt. The calibration (zero and span) require a screwdriver to adjust The response and level knobs had locks to secure them. All were acceptable. The alarm, on/off switch, and the battery/AC/charge switch were frequently confused, which resulted in turning off the instrument instead of the audible alarm on several occasions. The umbilical was too short. ------- Table 1. (Continued) Item OVA TLV HNu AID Probe contamination Probe assembly Audible alarms Screening time Since all the plants had some sources where the probe could get dirty, all units were affixed with a 2-in. long piece of Tygon tubing with a glass wool plug as a primary filter. This flexible tip was also helpful when screening because it made it easier to get the probe tip close to the source interface. The assembly was con- veniently sized and not uncomfortably heavy. The alarm adjust knob on the back was broken off when the assembly was dropped. The alarm cannot be heard in most plant environments. The ear plug was very uncom- fortable and the oper- ators did not wear it. See OVA comments. See OVA comments. See OVA comments. Very good: per source. -30 seconds The probe is very lightweight and easy to manipulate The assembly was quite heavy and very diffi- cult to manipulate. See OVA comments Not Applicable. The assembly had a com- fortable feel. How- ever, the plastic bezel damaged during the second screening falls off frequently. See OVA comments Somewhat slow; —45 seconds per source Unknown; no response to sources. Very good; ~30 seconds per source. U. S. GOVERNMENT PRINTING OFFICE:1985/559 019/10796 ------- Robert A. Ressl and Thomas C. Ponder, Jr., are with PEI Associates, Inc., Arlington. TX 76012. Roosevelt Rollins is the EPA Project Officer (see below). The complete report, entitled "Field Experience with Four Portable VOC Monitors," (Order No. PB85-165 496/A S; Cost: $ JO. 00, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Environmental Monitoring Systems Laboratory U.S. Environmental Protection Agency Research Triangle Park, NC 27711 United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 Official Business Penalty for Private Use $300 APR H'85 HIVATE - - £$3D> n .» « 0 3 t, - X " N r w, w s ' '•ri; 625034! L—«- OCOC329 PS U S ENVIR PROfECTIOK AGENCY REGION 5 LIBRARY 230 S DEARBORN STREET CHICAGO IL 60604 ------- |