United States
Environmental Protection
Agency
Environmental Monitoring Systems
Laboratory
Research Triangle Park NC 27711
 Research and Development
EPA/600/S4-85/012  Mar. 1985
Project Summary
Field  Experience with  Four
Portable  VOC  Monitors

Robert A. Ressl and Thomas C. Ponder, Jr.
  This report discusses the field opera-
tion  problems associated with use of
four portable volatile organic compound
(VOC) detection  instruments in con-
ducting  Reference Method  21 VOC
screenings. The  report presents the
results of the field trials and summarizes
the ease of use  of each instrument.
Information on operational problems
and  recommendations are  provided.
Also included are discussions of the
features that would make all portable
instruments more reliable, durable, or
convenient to use. Based on the data
collected for this study,  three of the
instruments report similar leak rates in
the facility where they were used.
  This Project Summary was developed
by EPA's  Environmental Monitoring
Systems Laboratory, Research Triangle
Park, NC, to announce key findings of
the research project that is fully docu-
mented in a separate report of the same
title  (see Project  Report ordering  in-
formation at back).

Introduction
  The U S. Environmental Protection
Agency (EPA)  has  issued performance
standards and guidelines to limit emis-
sions of volatile organic compounds (VOC)
from  several stationary source categories.
These industries such as petroleum  re-
fineries, synthetic organic chemical
plants, and natural gas processing plants
emit  significant quantities of VOCs from
sources other than classical point sources
into the workplace and surrounding  at-
mosphere. These fugitive VOC emissions
occur from valves, pumps, drains, pres-
sure  relief devices, etc.
  As described in 40 CFR 60, Appendix A,
Reference  Method 21  (RM 21), Deter-
mination of Volatile Organic Compound
Leaks, there are  technically feasible
devices suitable for monitoring fugitive
VOC leaks. These devices can be placed
near possible points of emissions and will
respond to releases of the organic com-
pounds. Specific instruments suitable for
this purpose include, but are not limited
to, catalytic  oxidation, flame ionization,
infrared absorption, and photoionization
detectors.
  Subsequent "field use of portable VOC
detectors has disclosed some instrument-
specific problems such as undetected
flame-outs,  plugged orifices from  dirt,
high background readings due to chem-
ical absorption on probe and  tubing
surfaces, high  humidity effects, varying
or lack of response, long response times,
and calibration drift. To identify and
document these types of problems, four
monitors were used to conduct screening
following RM 21 procedures.
  This report provides basic information
on each instrument, howthey were used,
what operational problems were encount-
ered during and between screenings, and
the  ease of  use of each  instrument in
relation to the other three. Special atten-
tion was given to documenting opera-
tional problems and ease of use.

Field Trial Methods
  The following VOC  analyzers were
used during the study

• Foxboro Century Systems  Portable
  Organic Vapor Analyzer Model OVA-
  108
• UnitedTechnology'sBacharach Instru-
  ments Model TLV Sniffer*
• Analytical Instruments Development,
  Inc., AID Model 712*
• HNu Systems, Inc., Model PI-101
"Registered Trademark

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  The instruments used represent three
types of detectors. The OVA and Analyt-
ical Instruments Development, Inc., Mod-
el 712  (AID) are flame mnization detec-
tors(FID). UmtedTechnology's Bacharach
Instruments, Inc., Model TLV Sniffer
(TLV) uses catalytic oxidation.  The HNu
Systems, Inc., Model PI-101 (HNu) uses a
photoionization detector (PID).
  A  comparison of the manufacturers'
published specifications was made with
the RM 21 requirements. Although some
of the instruments did not appear to meet
the RM 21 requirements,  all the instru-
ments  were used and their field exper-
ience reported. No attempt was made to
make  a  rigorous evaluation  of each
instrument or of RM 21. However, where
possible, the requirements of RM 21
were met.
  Two  types  of operational tests were
conducted with the equipment—a reli-
ability check and field operations. In the
reliability check the  instruments were
charged and allowed to operate for sever-
al 8-hour periods. This test provided some
assurance that the instruments  could
operate over an 8-hour period. In the field
operations  all four instruments were
used to screen a series  of 200 to 300
sources. Following the screening,  the
instrument operator completed an evalua-
tion sheet,  reported any problems with
the  instrument, and provided general
subjective comments on the instrument
as a leak detection tool. Screening was
conducted at two petroleum refineries, a
chemical manufacturing  plant, and  a
natural gas processing facility.
Summary of Evaluations
  The field trials were designed to provide
subjective comments on the instruments'
performances  Table 1  summarizes the
comments developed from the screen-
ings.
  All  the  instruments  except the HNu
were equipped with some kind of probe
filter,  and these filters were  always
installed. However,  a  2-inch  length of
plastic tubing loosely stuffed with glass
wool was added to protect the probe from
contamination by the  greases and oils
present at many sources. The instru-
ments' responses were the same with
and without the plastic tubing in place.
The tubing is easily replaced and reduces
time spent in the field cleaning the metal
sample probes. The tubing was normally
replaced on an  as-required basis which
was fairly frequently.  The replacement
criteria was based on appearance of the
tubing. If there was any visible contam-
ination on it, it was replaced.
  The TLV  comes without  a shoulder
strap making it very awkward to  use for
screening. Also, since the zero knob is
easily moved, a piece of tape was  used to
secure it. This prevented having  to con-
stantly check and reset the instrument
zero.
  The OVA comes with one strap. How-
ever,  after several screenings  it was
realized that if  worn  as  a backpack it
would be easier to use, make the operator
more mobile, and  speed  up the screen-
ings. Therefore,  a second  strap was
purchased from the manufacturer so that
the OVA could be worn  as a backpack,
using the two carrying  straps  as a shoul-
der harness. Since the OVA has a readout
on  the  hand-held probe, this did not
create any problem. However, when the
instrument flamed out,  relighting  it was a
little awkward since the operator had to
either get someone else to press the
igniter button on the case or let the case
slip forward on the shoulders and stretch
around to reach  it.
Desirable Instrument
Features and
Recommendations for
Future Studies
  The desirable features that should be
included in a field screening instrument
are as follows:

• The strap should allowfor carrying the
   instrument on the back, out of the way,
   leaving the  hands free for  climbing,
   handling log sheets, and manipulating
   the probe and readout (assuming the
   readout is attached to the probe).
• The calibration controls should be
   located in the backpack and protected
   by the instrument case cover. All
   controls should have locks to prevent
   unintentional movement.
• The readout should be analog and use
   a logarithmic scale that ranges from
   10 to 100,000 ppm. RM 21 must be
   modified to accept the resulting scale
   divisions.
• The readout should have a  lock-and-
   hold reading capability and/or  hold-
   highest-reading function switch.
• There should be provisions to use the
   instrument  as  a  go/no-go detector
   with indicator lights to show whether
   the  reading  is above  or below the
   calibration point.
• An igniter button should be located on
  the probe/readout if the instrument
  uses an FID.
• A series of status indication  lights
  should appear on the probe/readout
  assembly to show if the instrument
  has sufficient battery charge and if it is
  responding.
• The sample line connecting the back-
  pack and probe/readout should be at
  least 4 feet long and very flexible.
• A holster should be provided for the
  probe/readout so that both hands can
  be free for climbing and handling data
  sheets.
• The probe assembly should have pro-
  visions for frequent cleaning  because
  the probe becomes contaminated with
  grease and other materials during the
  screening process.
• The system should be protected from
  the elements and be able to operate in
  light  rain,  high  humidity, and  high
  ambient temperatures.
• The system should protect the recharge-
  able battery from  overcharging and
  deep discharge. Provisions should be
  made for easy battery removal and
  replacement.  Ideally, the charging
  system should be capable of being left
  on charge at all times. There should
  also be an indication of when the unit
  is within one hour of being too weak to
  operate effectively. This would provide
  time to check the instrument calibra-
  tion before the unit required  recharg-
  ing.
• The calibration system should allow
  for easy calibration to multiple calibra-
  tion gases

  Available and additional data on leak
rates, repeatability of screening values,
and responsefactorsforVOC instruments
should be assembled in a screening hand-
book to present the kinds of information
necessary for  a  proper  screening pro-
gram. Information should be included on
how to screen  various types  of  sources,
how to  prepare  log and repair sheets,
response factors  of various instruments,
lists of typical compounds encountered in
various types of facilities, etc. Screening
procedures should be developed for organ-
ic materials with response factors greater
than 10.

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 Table  1.    Summary of Operating Problems

           Item                       OVA
                                                                TLV
                                                                                          HNu
                                                                                                                    AID
Carrying strap
Battery


Battery charger


Instrument readout
 The best arrangement of
 the instruments evalu-
 ated.
Acceptable during
period of evaluation.

Acceptable during
period of evaluation

The analog readout
with logarithmic scale
was conveniently lo-
cated in the probe and
very easy to use.
 No strap; instrument
 was earned by a handle
 that was sometimes
 inconvenient
Acceptable during
period of evaluation

Acceptable during
period of evaluation

The readout in the con-
trol unit was less con-
venient to read than on
the probe but was
acceptable It
required frequent scale
changes that were some-
what inconvenient.
 The strap was very nar-
 row and after an hour
 of carrying was quite
 uncomfortable
Acceptable during
period of evaluation

Acceptable during
period of evaluation.

The readout in the con-
trol unit was less con-
venient to read than on
the probe but was
acceptable. It
required frequent scale
changes that were some-
what inconvenient
 The strap was unpadded
 and, although reasonably
 wide, the edge of the
 strap became very uncom-
 fortable after an hour
 of carrying.

 Acceptable during
 period of evaluation

 Acceptable during
 period of evaluation

 The digital readout was
 difficult to read from
 an angle, and the fre-
 quency  with which it had
 to be updated made selec-
 tion of a reading value
 difficult
Calibration knob
or zero/span
adjustment
On/off and other
controls
Sample line and
instrument
umbilical
 The knob could not be
 secured. However,
 since it was located on
 the control module,
 which had a cover, it
 did not require secur-
 ing.
The controls are on the
control module. The
instrument and pump
switches are easily
moved (newer models
have locking toggles).
The handles on the
hydrogen supply are
too short (newer
models have longer
ones} The gas select
knob was not used
since span gases were
used for calibration

The sample line tends
to kink after long use
when the protective
sleeve slips. The line
could be longer. The
electrical connector at
the control module has
been weakened and has
shorted
 The zero adjust knob
 (only adjustment) was
 located on the control
 module and could not be
 secured.  It was easily
 and frequently bumped,
 requiring re-zeroing of
 the instrument, until
 it was secured with
 tape.

 The on/ofl'/standby,
 battery, operate,  and
 range switch caused
 no problems
The sample hose could
be longer During the
evaluation period, the
hose developed a kink
and would frequently
pinch off, causing the
pump to stall and the
instrument to operate
improperly
The zero knob was some-
what protected and was
quite stiff to turn.
It is located on the
control module and did
not require securing.
The controls were
acceptable.
The umbilical was too
sh'prt.
The calibration (zero
and span) require a
screwdriver to adjust
The response and level
knobs had locks to
secure them. All were
acceptable.
The alarm, on/off switch,
and the battery/AC/charge
switch were frequently
confused, which resulted
in turning off the
instrument instead of the
audible alarm on several
occasions.
The umbilical was too
short.

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Table 1.    (Continued)

          Item
         OVA
                                    TLV
                                                             HNu
                                                                                       AID
 Probe contamination
 Probe assembly
 Audible alarms
 Screening time
Since all the plants had
some sources where the
probe could get dirty, all
units were affixed with a
2-in. long piece of Tygon
tubing with a glass  wool
plug as a primary filter.

This flexible tip was also
helpful when screening
because it made it easier
to get the probe tip close
to the source interface.

The assembly was con-
veniently sized and not
uncomfortably heavy.
The alarm adjust knob
on the back was broken
off when the assembly
was dropped.

The alarm cannot be
heard in most plant
environments. The  ear
plug was very uncom-
fortable and the oper-
ators did not wear it.
                                                    See OVA comments.
                                                                              See OVA comments.
                                                                             See OVA comments.
 Very good:
per source.
                                     -30 seconds
The probe is very
lightweight and easy
to manipulate
The assembly was quite
heavy and very diffi-
cult to manipulate.
                                                     See OVA comments
                          Not Applicable.
The assembly had a com-
fortable feel. How-
ever, the plastic bezel
damaged during the
second screening falls
off frequently.
                                                                                                        See OVA comments
Somewhat slow; —45
seconds per source
Unknown; no response
to sources.
Very good; ~30 seconds
per source.	
                                                                               U. S. GOVERNMENT PRINTING OFFICE:1985/559 019/10796

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     Robert A. Ressl and Thomas C. Ponder,  Jr., are with PEI Associates, Inc.,
       Arlington. TX 76012.
     Roosevelt Rollins is the EPA Project Officer (see below).
     The complete  report, entitled "Field Experience with Four Portable VOC
       Monitors," (Order No. PB85-165 496/A S; Cost: $ JO. 00, subject to change) will
       be available only from:
            National Technical Information Service
            5285 Port Royal Road
            Springfield, VA22161
            Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
            Environmental Monitoring Systems Laboratory
            U.S. Environmental Protection Agency
            Research Triangle Park, NC 27711
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Official Business
Penalty for Private Use $300
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