United States Environmental Protection Agency Environmental Monitoring Systems Laboratory Las Vegas NV 89193 Research and Development EPA/600/S4-87/016 Aug. 1987 &EPA Project Summary Survey of Vendors of External Petroleum Leak Monitoring Devices for Use with Underground Storage Tanks B. Eklund and W. Crow Underground storage tanks (UST's) and their associated piping are major potential sources of environmental contamination. Since the 1984 Amend- ments to the Resource Recovery and Conservation Act (RCRA) require regu- lation of underground storage tank systems, the U.S. Environmental Pro- tection Agency (EPA) is currently in- vestigating topics related to UST's to aid in developing regulations. EPA has contracted with the Radian Corporation to compile information on the various types of external (out-of-tank) moni- toring systems or techniques which can be used to detect leaks or spills of petroleum hydrocarbon products. The compiled data were used to categorize external petroleum leak monitoring devices or techniques by functions and type, and the data will aid in the future development of uniform performance criteria for commercially available ex- ternal leak monitoring methods. The present study, which is limited to ex- ternal (outside-the-tank) petroleum leak monitoring devices, supports the EPA effort by providing information on the number, type, and performance capa- bilities of available leak monitors. The literature was searched to collect general information on external petro- leum leak monitors and, more specifi- cally, to develop a list of vendors. Additional information was collected from equipment vendors, trade groups, and other researchers. This Project Summary was devel- oped by EPA's Environmental Monitor- ing Systems Laboratory, Las Vegas, NV. to announce key findings of the research project that is fully docu- mented in a separate report of the same title (see Project Report ordering information at back). Introduction Underground storage tanks (UST's) and their associated piping are major potential sources of environmental contamination. Since the 1984 Amendments to the Resource Recovery and Conservation Act (RCRA) require regulation of underground storage tank systems, the U.S. Environ- mental Protection Agency (EPA) is cur- rently investigating topics related to UST's to aid in developing regulations. EPA has contracted with the Radian Corporation to compile information on the various types of external (out-of-tank) monitoring systems or techniques which can be used to detect leaks or spills of petroleum hydrocarbon products. The compiled data were used to categorize external petro- leum leak monitoring devices or tech- niques by function and type, and the data will aid in the future development of uniform performance criteria for com- mercially available external leak moni- toring methods. The present study, which is limited to external (outside-the-tank) petroleum leak monitoring devices, sup- ports the EPA effort by providing informa- tion on the number, type, and performance capabilities of available leak monitors. Procedures The literature was searched to collect general information on external petroleum ------- leak monitors and, more specifically, to develop a list of vendors. Additional in- formation was collected from equipment vendors, trade groups, and other re- searchers. A questionnaire soliciting in- formation on leak monitoring devices was developed and sent to the identified vendors. The questionnaire covered six topics: principle of operation, detection specificity, detection capability, experi- ence, cost, and recommended procedures. The vendor list included vendors of LIST monitoring systems and detectors that could potentially be used for the detection of petroleum hydrocarbon leaks or spills. It should be noted that this survey does not necessarily represent a complete list of vendors that manufacture external monitors for detecting petroleum leaks or spills from underground storage tanks and piping. Some vendors were likely to have been inadvertently omitted, and devices that are currently being marketed could have changed since this survey was performed. However, these data will be useful in identifying the different categories of commercial leak monitoring devices and aiding in the development of performance criteria for each monitoring category. This report summarizes and tabulates vendor responses to the ques- tionnaire. The report also includes a dis- cussion of related issues that remain to be resolved before final performance criteria can be established. The data collection approach used in this study has limitations. Reliance on vendor-supplied data was necessary be- cause of a lack of published, objective evaluative test results. However, since these vendor data have not been in- dependently verified, it is possible that some of these data are erroneous, biased, or self-serving. Conclusions The literature search yielded relatively little useful information on external leak detection monitoring devices. The vendor survey, however, was successful in gain- ing information from approximately 70 percent of the vendors that were queried. Except for a notable lack of data regarding any common interference, operational, or maintenance problems, vendor re- sponses were generally thorough. A total of 49 vendors was identified that manufacture devices related to the out-of-tank measurement of petroleum hydrocarbon spills or leaks from UST installations. Vendor specifications were received for 63 of 69 (91 percent) dif- ferent products. Survey forms were completed by 30 of the 42 vendors that were queried. Survey forms were received for 44 of the 62 (71 percent) devices covered by the survey. Vendor responses provided a basis for dividing the external (out-of-tank) leak monitoring devices for UST systems into four categories: intermittent liquid-phase detection, intermittent gas-phase detec- tion, continuous liquid-phase detection, and continuous gas-phase detection. An examination of vendor survey data yielded the following information: • Commercial external (out-of-tank) leak monitors are designed primarily to detect leaks or spills of petroleum hydrocarbons; • Most leak monitoring systems can- not immediately distinguish between surface spills and leaks; • Most leak monitoring devices do not measure leak rates, although some devices (gaseous detectors) are capable of measuring hydrocarbon concentrations; • No uniform performance specifica- tions exist for external leak moni- toring devices; • Most leak monitoring systems re- quire the installation of observation wells or boreholes; • Vendor responses were limited with regard to: — Operational problems, — Interferences, — Maintenance problems, and — Performance testing procedures; • Most leak monitoring systems can be retrofitted at existing UST instal- lations; • Intermittent monitoring techniques are more labor-intensive than con- tinuous techniques, but may be more reliable; • Gas-phase detection can be more sensitive than liquid-phase detection, but the instrumentation may be more subject to false alarms and subject to interferences. • Equipment and installation costs (for permanent external leak detection systems) may vary considerably as these costs are dependent on the type of devices selected and the number of sensors used in each installation, local construction codes and permitting costs, and local labor costs; and • Operational and maintenance costs for permanent external leak moni- toring systems may vary also but are thought to be low based on informa- tion obtained from equipmen vendors. The performance characteristics fo each leak detection category are sum marized in Table 1. The data presented ir Table 1 are based on information obtainec from vendors and have not been verifiec by independent testing; therefore, these data may be biased. ------- Table 1. Characteristics of Leak Detection Sensors Leak Detection Category Type of Compounds Detected Detection Adjustable for Specific Compounds Potential Interferences Severity of Interferences False Positives or Negatives Temperature Range Can Systems Be Retrofitted? Are Wells Required? Can Devices Be Used in Wet Soils? Years on Market Detection Limits Lower Upper Response Characteristics Lag Time Rise Time Fall Time Drift Precision Intermittent Liquid-Phase Liquid hydrocarbons Generally not None Low Unlikely X)°C Yes Yes Yes >5 7/64 to 1/32 in. None N/A N/A N/A N/A N/A Continuous Liquid-Phase Vapor/liquid hydrocarbons Generally not Physical and chemical Variable Unlikely -45 to 120°C Yes Usually Yes 0-15 1/32 to 1/8 in. None 1 sec. to 10 hr. 1 sec. to 60 sec. 1 sec. to ? N/A Unknown Intermittent Gas-Phase Hydrocarbon vapors Varies between techniques Chemical Potentially high Both possible -20 to 60°C Yes Usually Yes 2-10 0. 1 to 15OO ppm 20OOppm to 100% LEL 1 sec. 3 sec. to 30 sec. 5 sec. to ? Negligible to <1%/ day full scale 5% to unknown Continuous Gas-Phase Hydrocarbon vapors Generally not Chemical Potentially high Both possible -70 to 70°C Yes Usually Yes 0-20 10 to 100 ppm 1% to 100% LEL 1 sec. to 10 min. 1 sec. to 20 sec. 20 sec. to several minutes Negligible to <1%/day full scale 5% to unknown NOTE: The information presented in this table is based on information provided by vendors of monitoring devices and not on actual performance data which has been independently verified. B. Eklund and W. Crow are with Radian Corporation, Austin, TX 78766. J. Jeffrey van Ee is the EPA Project Officer (see below). The complete report entitled "Survey of Vendors of External Petroleum Leak Monitoring Devices for Use with Underground Storage Tanks," fOrder No. PB 87-212 346/AS; Cost: $18.95, subject to change) will be available only from: National Technical Information Service 5285 Port Royal Road Springfield, VA22161 Telephone: 703-487-4650 The EPA Project Officer can be contacted at: Environmental Monitoring Systems Laboratory P. 0. Box 93478 U.S. Environmental Protection Agency Las Vegas. NV89193 ------- United States Environmental Protection Agency Center for Environmental Research Information Cincinnati OH 45268 . "- Official Business Penalty for Private Use $300 EPA/600/S4-87/016 ' ««"" ------- |