N-/EPA
                              United States
                              Environmental Protection
                              Agency
                              Environmental Sciences Research
                              Laboratory
                              Research Triangle Park NC 27711
                              Research and Development
                              EPA-600/S7-82-047 Sept. 1982
Project Summary
                              Green River Air Quality Model
                              Development:   Meteorological
                              Data—August  1980 Field
                              Study  in   the   Piceance  Creek
                              Basin Oil Shale Resources Area

                              C. D. Whiteman, N. S. Laulainen, G. A. Sehmel, and J. M. Thorp
                                Special meteorological and air quality
                              studies were conducted during August
                              1980 in the Piceance Creek Basin oil
                              shale resource area of northwestern
                              Colorado as part of the U.S. Environ-
                              mental  Protection Agency (EPA)-
                              sponsored Green River Ambient
                              Model Assessment program. The
                              objective of the limited field study was
                              to collect initial data for developing,
                              calibrating, and validating a mesoscale
                              air quality model. The specific goals of
                              the  study were to investigate the
                              growth and characteristics ofconvec-
                              tive  boundary layers that form over
                              the  area during the daytime; to
                              characterize background pollutant
                              levels, visibility, and atmospheric
                              structure over the area; and to investi-
                              gate, by means of tracer experiments,
                              the dispersion and dry deposition of
                              pollutants released in nocturnal valley
                              drainage flows.
                                A  DC-3 aircraft was equipped with
                              air pollution and meteorological
                              instruments; air quality and visibility
                              data were collected during flights over
                              the test area.  A balloon-borne upper
                              air sounding  system was used to
                              monitor temporal changes in the
                              convective boundary layer structure.
                              Dual tracer experiments were con-
                              ducted  on four  occasions in the
                              shallow Corral Gulch near the federal
                              oil shale lease tract C-a using nonde-
                              positing  SF6 gas and depositing
                              lithium-traced particles collected on
                              two to five sampling arcs during well-
                              defined drainage flow events. The
                              processed data,  collected during the
                              two-week field study is summarized
                              and presented. Analysis and interpre-
                              tation of these data will be presented
                              in future reports as part of the Green
                              River Air Quality model development
                              program.
                                This Project Summary was developed
                              by EPA's Environmental Sciences
                              Research Laboratory. Research Triangle
                              Park. NC, to announce key findings of
                              the research project that is fully
                              documented in a separate report of
                              the same title (see Project Report
                              ordering information at back).

                              Introduction
                                A special meteorological and air
                              quality measurement study was con-
                              ducted in the complex terrain  of the
                              Piceance  Basin of northwestern Colo-
                              rado to aid in the design, calibration, and
                              validation of a mesoscale air  quality
                              model that is being developed under the
                              U.S. Environmental Protection Agency
                              (EPA)-sponsored  Green River Ambient
                              Model Assessment (GRAMA) program.
                              The GRAMA program's overall objective
                              is to develop dispersion  models with

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demonstrated applicability for evaluating
air quality impact development of the
Green River Oil Shale deposits in
Wyoming, Utah,  and  Colorado. The
specific goals of  the two-week field
study were:
  • to investigate the growth and char-
    acteristics of  convective boundary
    layers (CBLs) or  mixing layers that
    form over the  oil shale region
    during the daytime,
  • to characterize background pollu-
    tant levels, atmospheric visibility,
    and atmospheric  structure over
    the region, and
  • to investigate, by means of a dual
    tracer experiment using a particu-
    late and a gaseous tracer, the
    dispersion and deposition of pollu-
    tants released into well-developed,
    nocturnal valley drainage flows.
  It was clearly recognized that a single
two-week study would insufficiently
characterize the meteorological pheno-
mena  investigated.  It  was expected,
however,  that the initial experimental
design and results would lead to
improved designs and refined physical
hypotheses that could be tested further
in future experiments.
  The purpose of  this report  is to
present the processed data obtained in
the field study in a basic form that will
be useful to other investigators. Also,
the study will facilitate a scientific
interchange  of ideas that may lead to
progress in  understanding the meteo-
rology and air quality of this complicated
terrain  region.  Data analysis  will be
presented in future reports, as part of
the Green  River  Air  Quality  model
development program.
  Field experiments were  conducted
jointly with  other investigators who
performed related work in the oil shale
region during the same experimental
period. By combining forces with other
investigators, it was possible to reduce
costs and, at the same time, obtain a
larger data set for later analysis and use
by all  investigators. The field program
described in this report was conducted
cooperatively with  investigators from
the University of California Los Alamos
National Laboratory, who,  under U.S.
Department  of Energy and  EPA spon-
sorship, investigated the transport and
diffusion of  SFe tracer material in  the
nocturnal drainage flows of Corral
Gulch near  the federal  oil shale lease
Tract C-a. Their work included upper air
and tethered balloon profiles taken to
characterize atmospheric  conditions
during the tracer  experiments and  the
operation of an acoustic sounder and
surface meteorological stations. The
meteorological and tracer data collected
in their investigations have  been
published in a separate report prepared
by the researchers of the Los Alamos
National Laboratory.
  The Piceance Creek Basin of north-
western  Colorado is one  of several
basins in Colorado, Utah, and Wyoming
that are part of the Green River Oil Shale
Formation. The Piceance  Basin is a
shallow basin that is inclined toward
the north-northeast. The  two major
drainages in the basin, Piceance Creek
and Yellow Creek, drain northward into
the westward-flowing  White River, a
major tributary to the Green River and
ultimately the Colorado River. The
major  topographical  features of the
region include the Cathedral Bluffs, the
steep cliffs forming the western rim of
the basin; the Roan Plateau, the  name
given to the  flat-topped  highlands on
the south  edge of the basin; and the
Grand  Hogback,  a  sharp ridge  of
resistant rock running from  north  to
south forming the eastern boundary of
the basin.
  The CBL experiments were designed
to allow frequent soundings through
the entire depth of the CBL so that  its
height, temperature and wind structures
could be determined as a  function of
time during the day. These data were
collected  primarily  by balloon-borne
sondes  released from a point on the
ground within the  Piceance  Basin.
Soundings were  released  at approxi-
mately three-hour intervals from sunrise
until late afternoon. Release times were
coordinated,  as much as possible,  to
allow comparison of Piceance  Basin
profiles with rawinsonde profiles over
Grand  Junction  and  with aircraft
profiles over other parts of the Piceance
Basin. The upper air data were obtained
with a commercial balloon-borne sound-
ing system using expendable sondes
that were towed aloft by a 50-g helium-
filled balloon. The  time-multiplexed
radio frequency data were received by a
ground  receiving  station and decoded
into time, pressure,  temperature, and
wet-bulb temperature information.
  Upper air winds were obtained for the
sounding  ascents  by merging the
desired height data with data obtained
with  an optical  theodolite. Further
characteristics of the CBL were deter-
mined from  aircraft soundings  made
with  it, including  observations  of
temperature, wind, and pollutant profiles
with height, atmospheric aerosol char-
acteristics within the layer, and visibility
measurements. In connection with the
CBL observations,  components of the
surface energy budget were measured
at a site representative of the valley floor
in general,  having  a sparse cover of
sagebrush, bare  soil,  and natural
grasses.  At this site,  solar and net
radiation instruments were  mounted at
the 1 -m level on booms that extended
out 1  m from a guyed mast. Nearby,
temperature sensors were inserted into
undisturbed soil at depths of 2,5, and 20
cm in the  walls  of a  20-cm deep
excavated pit.
  In addition  to the supporting role
played by  the DC-3 aircraft m the CBL
experiments,  separate experiments
were designed to use the aircraft as a
platform from which to measure back-
ground pollutant concentrations in the
oil  shale  region and to  better  define
horizontal variations in  atmospheric
structure  over the region during  both
daytime and nighttime flights. Measure-
ments taken from the DC-3 aircraft
included  ozone and sulfur dioxide
concentrations, aerosol  concentrations,
and light-scattering coefficients,  as
well as aerosol  size distributions and
elemental  compositions. Vertical profiles
were made over the oil shale region at
altitudes generally between 2300- and
4300-m MSL
  The tracer experiments were designed
to answer basic scientific questions
about  the transport, diffusion, and
deposition of pollutants introduced into
a valley drainage flow. In  these experi-
ments two types of tracer materials were
utilized. The first type was a gaseous
SF6 tracer released by researchers from
Los  Alamos National  Laboratory. The
second type, a lithium-traced aerosol,
was released by  researchers from
Battelle, Pacific  Northwest  Laboratory
so  that comparisons  could be  made
between gas and aerosol tracer concen-
trations to determine how diffusion and
deposition will affect pollutant concen-
trations downwind  of  the pollutant
sources.  These  experiments  were
conducted during the nighttime when
the valley drainage flow had become
well established and had  attained a
near-steady state. Tracers were released
for 1  h  so that transport velocities
within the drainage flow would allow
tracer to be carried through the length
of the  sampling station grid. Sampling
stations were located  along multiple
lines perpendicular to the valley axis at
various downwind distances from the
source. The lines extended across the

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valley floor and up the valley sidewalls.
Using  this  grid  and the two  tracer
materials, the experiments determined
transport, diffusion, and aerosol deposi-
tion as a function of downwind distance
from the tracer source.
  Airborne tracer concentrations down-
wind of the release point were measured
using one of three methods:
  • Samples of SFe and lithium-traced
    particles were  collected  and de-
    tected in real time at the Tract C-a
    Visitor's Center and at Meteoro-
    logical  Site  3  using commercial
    instrumentation.
  • Samples of  SF6 were  collected
    using  bag samplers distributed
    along four radio-controlled  sam-
    pling lines oriented perpendicular
    to the valley axis at distances of 1.6,
    2.5, 4.6, and 5.6 km down valley
    from the release point. SFe con-
    centrations were determined from
    these samples after collection.
  • Samples of SF6 were collected in
    syringes at various  points along a
    road that runs perpendicular to the
    valley axis approximately 6.8-km
    below the release point.  Concen-
    trations  were  determined  from
    these samples after collection.

Conclusions and
Recommendations
  The field experiments  are described,
the design and characteristics  of the
data collection systems are specified,
and the data  are  summarized  in the
form of figures and tables. The experi-
ments, rather than focusing on the
collection of large quantities of general
background meteorological and air
quality  data, were directed at investi-
gating specific meteorological pheno-
mena,  including  the evolution and
characteristics of  atmospheric mixing
layers and the dispersion capabilities of
nocturnal valley drainage  flows. The
reported data  will constitute important
input into development of a mathe-
matical model of pollutant transport and
diffusion  in the oil shale region now
being developed at Pacific Northwest
Laboratories.  It is  important to note,
however, that further investigations of
the meteorology and air quality of this
sparse and very complicated topograph-
ic region are essential. It is recommended
that a much more comprehensive set of
experiments  be initiated in the near
future to obtain a better understanding
of regional environmental effects of the
development of oil shale resources in
the Piceance Basin. Modeling work will
benefit from the phenomenological
approach advocated  here, but other
phenomena  (e.g.,  the buildup and
breakdown of  temperature  inversions,
the evolution of local wind systems, the
coupling and decoupling of synoptic and
valley flows, etc.) must be observed and
the scope of the observational work in
both time and space be expanded.
  C. D. Whiteman, N. S. Laulainen. G. A. Sehmel, andj. M. Thorp are with Battelle,
    Pacific Northwest Laboratory, Rich/and, WA 99532.
  Alan H. Huber is the EPA Project Officer (see below).
  The complete report, entitled "Green River Air Quality Model Development:
    Meteorological Data—August 1980 Field Study in the Piceance Creek Basin
    Oil Shale Resources Area." (Order No. PB 82-258 609; Cost: $ 15.00. subject
    to change) will be available only from:
          National Technical Information Service
          5285 Port Royal Road
          Springfield, VA 22161
          Telephone: 703-487-4650
  The EPA Project Officer can be  contacted at:
          Environmental Sciences Research Laboratory
          U.S. Environmental Protection Agency
          Research Triangle Park, NC 27711
                                                                                     « U.S. GOVERNMENT PRINTING OFFICE, 1M2-559-017/0833

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Environmental Protection
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Information
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Penalty for Private Use $300
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