United States
                    Environmental Protection
                    Agency         	
 Industrial Environmental Research
 Laboratory
 Research Triangle Park NC 27711
                    Research and Development
EPA-600/S7-83-040  Sept. 1983
4>EPA         Project Summary
                    Control  of  Criteria  and  Non-
                    Criteria  Pollutants  from  Coal/Oil
                    Mixture  Combustion

                    M. E. Kelly, R. M. Parks, and J. H. E. Stalling
                      As the availability and cost of oil have
                    become uncertain in recent years, the
                    need for the U.S. to reduce its depend-
                    ence on oil has prompted significant
                    efforts  by government and industry in
                    finding alternate fuel sources. This
                    posture has been strengthened by the
                    Powerplant and Industrial Fuel Use Act
                    of 1978 that prohibits the use of gas
                    and oil  in new boilers without special
                    exemption. The Department of Energy
                    (DOE)  has taken an active role in
                    developing one such alternate fuel
                    technology: coal/oil mixture (COM)
                    combustion.
                      Recognizing that environmental
                    considerations must be made in any
                    evaluation of fuel conversion to COM,
                    DOE and EPA contracted with Radian
                    to identify and assess the effectiveness
                    of currently available methods of
                    controlling the release of criteria and
                    non-criteria (trace elements) pollutants
                    from the combustion of COMs. The
                    report  presents  this  assessment and
                    compares the costs and effectiveness
                    of various control technologies found to
                    be applicable to emissions from boilers
                    firing COM.
                      Emissions from COM combustion
                    were characterized  using data  from
                    various tests. The pollutants examined
                    most closely were particulate matter,
                    SO2, and NO*. Trace element emissions
                    and emissions of polynuclear organic
                    material were also examined. Conven-
                    tional emission control techniques were
                    determined to be the most effective in
                    reducing emissions from COM com-
                    bustion.
                      Emission rates and associated costs
                    for emissions control of particulate
matter and SOz were assessed for four
different COM compositions and various
boiler sizes. Fabric filters and electro-
static precipitators were considered for
particulate matter control; wet flue gas
desulfurization (dual alkali), dry scrub-
bing, and dry injection techniques were
considered  for three  levels of SO2
control (50%,  70%, 90%). Low-sulfur
fuels were also examined as an addi-
tional alternative.
  This Project Summary was developed
by EPA'3 Industrial Environmental
Research Laboratory. Research Tri-
angle Park. NC. to announce key find-
ings of the research project that is fully
documented in a separate report of the
same title (see Project Report ordering
information at back).

Introduction

  The need for the U.S. to reduce  its
dependence on oil and expand its use of
coal has prompted DOE to take an active
role in developing Coal/Oil Mixture
(COM) combustion technology. Sufficient
technical and economic information has
been  developed to allow private sector
implementation of COM combustion, and
a number of industrial and utility energy
producers are assessing the use of COM
at their facilities.
  As  COM combustion  technology be-
comes more widespread, DOE and EPA
recognize that certain  environmental
considerations will have to be addressed
in order to expand the use of COM in an
environmentally acceptable way. Specif-
ically,  it will be necessary to determine
the potential emissions from sources
burning COMs and evaluate, assess, and
compare the effectiveness of control

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technologies  in  controlling the criteria
and non-criteria pollutant emissions.
Radian has been under contract to EPA
and DOE to identify  and assess the
effectiveness of  currently  available
methods of controlling the release  of
criteria and non-criteria (trace elements)
pollutants from the combustion of COMs.
  The report of this  study contains
several chapters that focus on the various
considerations and assessments neces-
sary in making a conversion from oil  or
gas to COM. Chapter 2 presents some of
the technical and economic factors that
determine the suitability of COM as a fuel
and identifies  boilers that  might be
candidates for COM conversion.
  Chapter 3 discusses the emissions that
have been measured to date on combus-
tion units  burning COM. The criteria
pollutant emissions that are discussed
are  particulate matter, SO&  and  NO>.
Non-criteria pollutant emissions discus-
sed are the selected trace elements. As,
Be, Cd, Cr, Ni, Se,  V, and Hg, as well  as
polynuclear organic matter (POM) emis-
sions. Chapter 3 also  briefly discusses
control technologies applicable to boilers
that could be converted to burn COMs.
Several  of these  control devices are
selected  as most promising for further
technical and economic study in the
remainder of the report.
  Chapter 4 presents the environmental
impacts of  the selected control techno-
logies, including the primary pollutant
control capability and any secondary
environmental impacts. The potential for
multipollutant control is also discussed.
Chapter 5 addresses the cost  impacts of
the technologies discussed in Chapter 4
in terms of capital costs, annual operation
and maintenance costs, annualized
costs, and  cost  effectiveness. Compar-
isons of  multipollutant controls, add-on
controls, and low-sulfur COMs are also
presented in Chapter 5.

Use of  COM  in Existing Boilers

  COMs  typically consist of 20-50% by
weight coal dispersed in oil or in an
oil/water mixture (known as COW—
coal/oil/water). The  coal is usually
ground to at least 70% minus 200 mesh.
A No. 6 heavy residual is typically chosen
over lighter distillate oils for COMs.  In
addition  to being  less expensive than
distillate  oil, heavy residuals reduce coal
settling problems with  COM,  relative to
lighter oils. Water is sometimes added to
the COM as a stabilizer; most commonly
the added water is 5-20% by weight.
  The suitability of converting a boiler
currently firing oil or gas to COM depends
on several technical and economic
factors. Whether a specific boiler is a
likely candidate for COM depends on the
age of the boiler (remaining useful life),
boiler  design,  size and capacity factor,
geographical location (proximity to COM
fuel supply), site-specific boiler modifica-
tions required, existing emission control
equipment, if any, and emission controls
required by the applicable environmental
regulations.

Technical Considerations

  Three factors must be evaluated in
determining the technical suitability of
converting  existing oil- or gas-fired
boilers to COM: COM fuel properties,
COM combustion  characteristics, and
boiler modifications required to accom-
modate COM-firing.
  Other than combustion characteristics,
the most important COM fuel properties
to be considered are viscosity, stability,
and abrasiveness. The  viscosity and
stability of  the COM are  interrelated:
generally, the more viscous the COM is
the  less  tendency there is for  fuel
instability (settling of coal particles).
Chemical  stabilizing additives (typically
emulsifying  agents, gelling agents, or
surfactants) have been  developed to
improve COM stability by keeping the coal
particles suspended in the oil. Although
maximum coal concentration is desirable
for economy and stability, there appears
to be an upper limit of about 60% coal in
the COM. Although 60% COM may be
possible, COM is typically available with
40-55% coal  in  oil.  The increased
abrasiveness of COM relative to oil can
potentially cause erosion  in pipe bends,
pumps, valves, and burners. These
potential problems can be minimized by
proper material selection, reduced fuel
velocities, and more finely ground coal.
  The  boiler modifications required in
converting from oil or gas to COM are
quite site-specific,  and depend on such
boiler  design factors  as  tube spacing,
burner design, furnace size, and bottom
ash removal capability. Boilers originally
designed for oil- or gas-firing commonly
have narrower tube spacings than boilers
originally designed for coal -f iri ng, maki ng
coal-fired boilers more ideally suited, in
that respect,  for  conversion to  COM
combustion. The  potential  exists, in
converting to COM, for ash deposition
and ash slagging (if the furnace tempera-
ture is not  maintained  below  the ash
fusion temperature). Bridging of molten
ash between the tubes leads to impaired
heat transfer and possible boiler derating.
Soot blowers will generally prevent these
problems; although some existing  oil-
fired boilers have soot blowers, additional
soot blowing capacity may be needed to
accommodate  COM combustion.  Since
most COM  combustion studies have
found air or steam atomization preferable
to mechanical atomization, the burners
may have to be  modified or  (in  some
cases) replaced. Consideration  in burner
design or modification is  also likely to
facilitate switching  from COM-to  oil-
firing with maximum flexibility. Combus-
tion of COM requires a larger combustion
space relative to oil to allowforthe longer
residence time  needed for complete
combustion of the coal particles. Refitting
for COM combustion will require  provi-
sions for a bottom ash handling facility in
most cases since units designed for oil-
and gas-firing do not often have bottom
ash removal capability.
  In addition to modifications made
directly to the boiler, other changes to the
facility may be required in converting to
COM.  These  changes are primarily
associated with the fuel handling system
(including pumps, piping, valves, and flow
measurement devices).  Storage tanks for
COM received from a centralized off-site
preparation plant may have to be modi-
fied to include agitators and temperature
control. And new storage equipment will
be required if dual fuel capability (COM
and oil) is desired.


Economic Considerations

  Several economic factors  will also
affect the desirability  of conversion to
COM firing.  Paramount among  these
considerations of the  use of COM in
general  is the cost of coal relative to the
cost of oil. Currently, widespread use of
COM is limited by the low price of oil. And
the increased use of COM may be limited
by the advent of coal/water mixtures as a
viable fuel option.
  Although the economics of conversion
for a particular boiler may be somewhat
complex, particularly for utility applica-
tions, the following factors are important
in every  case: capital availability; boiler
modifications required; difference be-
tween oil (or gas) and coal prices and the
predicted rates of escalation of the  fuel
costs;  security  of  oil  or gas supply;
availability,  composition, and price of
COM; boiler size and  capacity  factor;
remaining useful life of the boiler;  and
emission controls required.
  The economics of conversion are also
affected  by the composition of the COM
(percent  coal, sulfur content and  ash
content), the  COM fuel cost, and  the
source  of the COM  (on-  or off-site

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centralized preparation plant). COM fuel
cost is determined primarily by the cost of
coal and oil, which account for a bout 85%
of the fuel cost on a Btu basis.

COM Emissions

  Generally, when an oil-fired boiler is to
be  converted to COM combustion, the
uncontrolled  emissions  of  particulates
and NO, will be greater for COM-firing
than  for oil-firing.  The increased emis-
sions result from the contribution of coal
ash and  nitrogen to the combustion
emissions. Emissions of SO2 from  COM
combustion  may be less than or greater
than  oil-only SOz emissions, depending
on  the  relative  sulfur  contents of the
COM  and the oil. Trace element emissions
(except Ni and V) from COM combustion
may also be greater than those for oil-
only firing.

Paniculate Emissions

  Measured emissions of particulates (fly
ash)  from boilers firing  COM are  a
function of the ash content of the COM
and, to some degree, the amount of ash
deposition in the boiler. Since  the ash
content of residual oil is negligible when
compared to the ash content of coal, the
COM  ash content depends primarily on
the coal ash content and the percentage
of coal  used in preparing the COM.
Although  most  test data suggest that
most  of the  COM ash (80-90% plus) is
emitted as fly ash, some COM combustion
tests  have shown significantly lower fly
ash emissions.  Ash  deposition in the
boiler may cause the reduced measured
particulate emissions.

SOz  Emissions

  SO2 emissions from COM combustion
are a direct function of the fuel sulfur
content. The COM sulfur content  is in
turn determined by the sulfur contents of
the coal and oil used to make the COM
and the relative percentage of each in the
COM. At least 95% of the fuel sulfur is
typically emitted as SO2. But COMs made
with coal that has highly alkaline ash may
emit slightly less than 95% of  the fuel
sulfur, since the alkaline ash retains
some  of the fuel sulfur. Depending on the
relative sulfur contents of the oil and coal,
and the percentage of each fuel in the
COM, SOz emissions from the COM may
be greater or less  than SOz emissions
from the respective oil.

/VOx  Emissions

  Emissions of  NOx from boilers firing
COM are more difficult to quantify for all
potential applications than are SOz and
particulate emissions. For any particular
boiler,  NOx emissions can vary not only
with COM fuel composition, but also with
the amount of combustion air (excess air)
and, in some cases, with  boiler  load.
Properties of the COM fuel that influence
NOx emissions are:  nitrogen content of
the fuels used to make the COM, percent
coal in the COM,  and, possibly, the
presence of water in the COM. For a given
fuel composition, NOX emissions can vary
significantly from boiler to boiler due to
differences in burner and furnace design
and the use of combustion air preheat.
  NOx  emission data from several differ-
ent COM combustion  tests indicate
several general trends:
  • An increase  in NOx emissions at
     increased excess air levels.
  • An increase in  NOx emissions with
     increased COM nitrogen content.
  • Higher  NOx emissions from COM
     combustion than  from combustion
     of corresponding oil.
  • NOx emissions of 172-301 ng/J (0.4-
     0.7  lb/106 Btu) in  most tests,  al-
     though some tests showed emissions
     of  430 ng/J  (1.0  lb/108 Btu) or
     greater.

Trace Element Emissions

  Trace elements i n the COM fuel exit the
boiler either with the bottom ash or with
the flue gas, if there is not significant ash
deposition in the boiler. Most of the trace
elements emitted with the flue gas are
associated with the fly ash, though some
may remain in the vapor phase.
  The amount of trace elements emitted
from a particular boiler depends on:
combustion  temperature, fuel feed
mechanism, characteristics of the flue
gas, and COM properties (trace element
concentration).
  The combustion temperature deter-
mines the extent to which specific trace
elements are  volatilized and thus the
extent to which they may be emitted with
the fly ash or flue  gas. The fuel  feed
mechanism influences the partitioning of
non-combustible trace elements be-
tween the bottom ash and the fly ash. The
temperature of the flue gas affects the
relative amounts of volatile trace elements
which are emitted condensed on the fly
ash particles compared to being emitted
as a vapor.
  The concentration  of trace elements in
the coal and oil and the relative amounts
of coal and  oil used to prepare the COM
determine the concentration of trace
elements in the COM. Data on three coals
show that coal has higher concentrations
of As, Be. Cr, Hg, and Se. Residual oil has
higher concentrations of Cd. Ni, and V.

Pofynuclear Organic Material
(POM)

  The amount of POM emitted from any
combustion  source depends on  the
formation and the transformation mech-
anisms of the POM. POM is formed in the
combustion zone either by the breakdown
of larger  molecules or by the building up
of smaller ones. Evidence indicates  that
POM forms in the vapor phase and later
condenses on flue gas particulates. POM
formation  is related  to combustion
efficiency, and POM transformations are
related to boiler and downstream flue gas
temperatures. When properly fired, oil-
only combustion has been shown to
contribute almost no POM emissions to
the environment,  while coal-only com-
bustion  produces POM  emissions in
unpredictable patterns. Therefore, the
POM emissions from COMs cannot be
related  to the fuel  content of  any
particular component.

Applicable Control
Technologies

Particulate Control
Technologies

  Particulate  control technologies used
on coal-fired boilers are: electrostatic
precipitators (ESPs), fabric filters, venturi
(wet) scrubbers, side stream separators,
and  mechanical collectors. Side stream
separators and mechanical collectors are
used only on industrial coal-fired boilers.
Most industrial and utility oil-fired boilers
are  equipped with ESPs or have no
particulate matter control device. ESPs
are primarily used on utility boilers, while
most oil-fired  industrial boilers  are
uncontrolled.  Mechanical  collectors  and
venturi scrubbers are not often used to
control particulate emissions from  oil-
firing due to the relatively small size of the
oil fly ash (generally less than 2 /jm) and
the  inefficiency of  these collectors in
removing small  particles.
  High particulate control efficiencies
(98%  or greater) have  been widely
demonstrated with  ESPs, fabric filters,
and  wet scrubbers. In general,  these
technologies can reduce fly ash emissions
to 43  ng/J (0.1  lb/106  Btu)  or less,
comparable to controlled  and, in many
cases,  uncontrolled fly ash emissions
from oil-fired boilers. Fabric filters  are
generally the  most effective of the three
technologies. Bag blinding (caking of
moist  particulates  on  the  filter bag),
mentioned in  some  literature as a

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potential problem due to the hygroscopic
nature  of the fly ash,  has not been
observed in limited COM experience. In
fact, the fly ash from COM combustion
appears to have characteristics similar to
coal fly ash. Coal fly ash has been shown
to be highly suitable for fabric filter
collection. With  proper design (i.e.,
adequate specific  collection plate area),
ESPs can be as efficient as fabric filters.
There is a lack of resistivity data on COM
fly  ash, however; these  data  may be
particularly important for boilers firing a
COM made from low sulfur coal. It is likely
that the resistivity properties of the coal
fly ash will dominate the characteristics
of the COM ash.
  Wet scrubbers are somewhat less
effective than fabric filters or  ESPs,
especially for collecting submicron
particles. Venturi scrubbers are generally
the most efficient type of scrubber for
particulate  removal. Wet scrubbers,
however, have two main disadvantages:
they result in wet solids sludge and may
have liquid waste impacts; and the flue gas
becomes saturated, reducing plume
buoyancy and adversely affecting disper-
sion of gaseous pollutants(SO2andNO,).

Combined SOz /Particulate
Control Technologies

  The combined SO2/particulate control
technologies  in use are:  wet flue  gas
desulfurization (FGD), spray drying FGD,
and fuel cleaning  and blending prior to
combustion.  Technologies  still being
developed  include:  dry injection  of
sodium-based compounds, and alkaline
fuel  additives. Except for alkaline fuel
additives, these technologies can be used
to simultaneously control SOz and
particulates.
  In general, the technology  exists to
control  SO2 from COM combustion to
levels equal to or lower than those from
existing oil-fired  boilers. FGD systems,
capable of achieving  at least 90% SOz
removal, are the most effective SOz
control  technologies. Significant SOz
control can also be obtained by: dry FGD
(spray drying, dry injection) to achieve
50% or  more SOz removal from a low-
sulfur  COM; or  COM  prepared with
physically cleaned coals, hydrodesulfur-
ized oil,  or naturally occurring low-sulfur
fuels. Blending cleaned fuels (or naturally
occurring low-sulfur fuels) to make the
COM avoids  boiler-site  solid  or liquid
waste  impacts associated with  FGD
control.
  Wet scrubbers are su itable for combined
SOa/particulate removal. Combined
SOz/particulate control with this system
favors venturi scrubbers, possibly pre-
ceded by a mechanical  collector. Sub-
stantial combined SOz/particulate control
is also  achievable  with spray drying
systems (including a fabric filter or an
ESP) and with dry injection of sodium-
based alkali  compounds into  a fabric
filter. The  disposal  of  highly soluble
sodium-based wastes from dry injection
may present more serious solid waste dis-
posal problems than the  disposal of cal-
cium-based wastes from  spray drying or
wet FGD systems.
  Physical coal  cleaning (PCC) can
reduce the ash content of the coal as well
as reducing  its sulfur  content.  But,
depending on the percentage of coal in
the COM and the final ash content of the
cleaned coal,  combustion of COM made
from PCC will still likely require additional
control to reduce particulate emissions to
levels typical of oil combustion.
/VOx Control Technologies

  Control technologies for NOX can be
divided  into:  combustion modification
controls, and  post-combustion controls.
Combustion modification includes:  low
excess air (LEA) operation, staged
combustion, flue gas recirculation (FGR),
and  low-NOx  burners. Post-combustion
controls include ammonia injection
("thermal De-NOx") and  flue gas treat-
ment.
  Despite the use of what are generally
accepted as the most efficient techno-
logies  applicable to COM units, NOX
emissions  from COM combustion may
still be greater than those from combustion
of typical No. 6  residual oils. Low-NO*
burners are the most effective of  the
candidate  NO,  control technologies
examined  in  this study. Limited data
indicate that low-NOx burners can reduce
NO,  emissions to oil-only levels or less.
However,  for high  nitrogen  content
COMs, NOX emissions may still be above
the levels  prescribed in  some emission
regulations, particularly in states  like
California   which have  stringent NO,
regulations. In addition, the development
status of low-NOx burners for commercial
utility and industrial boilers firing COM is
questionable. Staged combustion is  a
relatively effective NOx control technology.
This technique reduces fuel NOxformation
and  is thus particularly suitable for high
nitrogen content COMs,  which produce
substantial amounts  of fuel NOx when
combusted.  Staged combustion  has
reduced NO,  emissions  30-40% during
COM combustion tests. Operation at low
excess  air (LEA) levels  is primarily
effective  in  reducing  thermal NO,.
Available data from  LEA  tests during
COM combustion show NOx reductions of
10-20%. Thus, more  than just LEA
control should be required for high
nitrogen COMs to reduce NOx emissions
to the levels typical of oil combustion.
  Note that the effects of variables (e.g.,
COM properties, the  presence of water
in the COM,  combustion air  preheat
temperatures,  and boiler heat release
rate) on NOx emissions from  COM
combustion are not  fully quantifiable
based on existing data. Also, boiler-to-
boiler variations in burner and furnace
design may significantly vary NO, emis-
sions from combustion of a given  COM.


Trace Element Control
Technologies

  Technologies with the greatest degree
of fine particulate control are the most
efficient for trace element collection,
since many of the trace elements tend to
be enriched on  the smaller  fly ash
particles. Thus, fabric filters achieve the
greatest degree of trace element control,
followed by ESPs and wet scrubbers. In
addition, physical coal cleaning and oil
hydrodesulfurization can reduce trace
element concentration in the fuel prior to
combustion.


Cost Impact of Control
Technologies

  The cost impacts of various particulate,
SO2, and NOx control technologies  for
boilers firing COM were evaluated in
terms of: capital costs, annual operating
and  maintenance costs, annualized
costs, and  cost effectiveness. (For this
study, cost effectiveness is defined as the
annualized cost of control divided  by the
tons of pollutant removed.) The impacts of
various particulate  and SOz control
technologies were evaluated for three
COM boiler sizes  and  four COM fuel
types. The  boiler sizes examined were:
8.8, 73, and 205 MW (30, 250, and 700 x
106  Btu/hr). The COM fuel types  for
which the  control technologies were
costed were selected from  typical coal
and  oil compositions. Uncontrolled SOz
and  particulate emission  rates were
calculated assuming that: all of the fuel
sulfur is emitted as SOz, and 90% of the
COM ash is em itted as fly ash. Each COM
fuel  was assumed to be a 50:50 mixture
of coal and  oil. The costs of particulate
and SC>2 control technologies given in the
report are based primarily on the techno-
logy costs used in EPA's development of
Industrial Boiler New Source Performance
Standards (NSPS).

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Comparison of FGD System
Costs

  The costs of various FGD systems are
compared for units firing low- and high-
sulfur COM. The costs are based on 70%
S02 removal  [a controlled SOz emission
level of 168 ng S02/J (0.4 lb/106 Btu)]
and 60% annual capacity factor. The
relative costs of the three  FGD systems
for specific applications may be altered
due to site-to-site variations  in SOa
removal, boiler capacity, reagent costs, or
availability of  existing equipment to
reduce retrofit costs.
  For boilers  firing low-sulfur COM, dry
injection FGD has the lowest capital costs
up to a boiler size  of about 200 x 106
Btu/hr. However, wet FGD has the lowest
capital cost of the three systems for larger
boilers. The result is due primarily to the
increased paniculate  matter  collection
associated with the use of a fabric filter in
the spray dryer and dry injection systems.
The lower paniculate emission control
levels achievable with fabric filters,
relative to a  wet FGD  system used  for
combined SOz/particulate removal,
result in higher waste disposal costs. An
ESP would likely be required upstream of
the wet  FGD to achieve  the same
particulate emission level. Similar findings
were made for high-sulfur COM.
  In comparing the annualized costs for
three FGD systems, all processes were
relatively close for low-sulfur COM. Wet
FGD had the lowest annualized  cost for
boilers above about 200 x 106  Btu/hr.
Wet FGD was  also the least expensive
system for high sulfur COM, while dry
injection  had the highest annualized
costs.

Cost Comparison of Low
Sulfur COM With Wet FGD

  The  annualized costs of using three
low-sulfur COMs were calculated relative
to the cost of using a 2.3% sulfur COM.
These costs are compared (in Figure 1) to
the costs of wet FGD at 70% SOz removal.
Emissions of SOz for each are less than
430 ng/J  (1.0 lb/106 Btu}.
  Wet  FGD is more expensive than low-
sulfur COMs with 50% coal. However, the
40% coal  COM (made with 0.7% S coal
and 0.5%  S oil) is more expensive than
FGD for boilers larger than about 300 x
106  Btu/hr. Of course, the  boiler size
where  FGD is less costly than low sulfur
COM depends on boiler capacity factor.
Although  both  FGD and annual  COM
costs depend directly on boiler capacity
factor,  COM costs are generally affected
more strongly  by changes in capacity
factor. FGD should be less costly than
low-sulfur  COM only for  large boilers
operated at relatively high annual capacity
factors (greater than about 0.6).
  Low-sulfur COM and an ESP or a fabric
filter  will  also  provide simultaneous
SOz/particulate  control. The combined
annual  cost of low-sulfur COM and a
fabric filter is  compared to the costs of
wet and dry FGD in Figure 2. Emission
control levels achievable with these
systems are: SOz—nominal 430 ng/J (1.0
Ib SOz/106 Btu); and particulate—21.5
ng/J  (0.05 lb/106 Btu) (dry FGD + fabric
filter), and 43 ng/J (0.1 lb/106 Btu) (wet
FGD). Figure 2 shows  the 50% coal low-
sulfur COM/fabric filter combination to
be the least expensive combined  S02/
particulate control technique  up to a
boiler size of about  325 x 106 Btu/hr. For
larger boilers, wet  FGD  is the  least
                                        expensive alternative. Both wet FGD and
                                        spray drying are less costly than the 40%
                                        coal low-sulfur COM/fabric filter com-
                                        bination.
   3,500
   3,000
   2,500
CD
^ 2,000
»•»
«i
 »
 o
O

.§ 7,500
   /,ooa
    500
                       Wet FGD; 70% SO2 removal: 2.3% S COM IB-1)
                       0.92 Ib SOi/10* Btu
              	   40% COM (0.7% S coal/0.5% S oil);
                       0.77 Ib SO2/10*Btu
              	50% COM 10.7% S coal/0.5% S oil);
                       0.83 Ib SOz/10*Btu
              	50% COM (0.7% S coal/0.87% S oil);
                      .0.99 Ib SO*/10* Btu
          Note: Low sulfur COM costs calculated
               relative to cost of 2.3% S COM
               (B-1)
                                                                     'COM
                                                                   Wet FGD
                                                                   COM
                                                                   COM
                                          60% Annual Boiler Capacity Factor •

                                          Double Alkali Wet FGD System
                                          (Combined 502 /Particulate Control)
        0
       (01
               29
              (100)
 59
(200)
 87
(300)
 116
(400)
 145
(500)
 174
(600)
203
(700)
 232
(800)
                                BoilerSize, MW(10*Btu/hr)
Figure 1.
           Comparison of wet FGD and low-sulfur COM annualized costs.

                                        5

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8
o
I
"
     5500 r
      5000
     4500
     4000
     3500
     3000
     2500
     2000
     1500
      1000
      500
                	Low-Sulfur COM/Fabric Filter
                           FGD
             Based on 60% Boiler Capacity Factor
40% Coal Low Sulfur COM  /
 fO. 7% S Coal/0.5% S Oil) '
                                                                    Wet FGD
                                                                70% SO2 Removal
        - 50% Coal Low Sulfur COM
          (0.7% S Coal/0.5% S Oil)
          0       29      59       87      116     145      174     203     232
         fO)      (100)    (200)     (300)    (400)     (500)    (600)     (700)    (800)

                               Boiler Size, MW (10* Btu/hr)
Figure 2.    Comparison of annual/zed costs of alternatives for combined SOz /paniculate control.

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     M. E. Kelly, R. M. Parks, andJ. H. E. Stellingare with Radian Corporation, Durham,
       NC 27705.
     Robert E. Hall is the EPA Project Officer (see below).
     The complete report, entitled "Control of Criteria and Non-Criteria Pollutants from
       Coal/Oil Mixture Combustion," (Order No. PB 83-247 247; Cost: $19.00.
       subject to change) will be available only from:
             National Technical Information Service
             5285 Port Royal Road
             Springfield, VA 22161
             Telephone: 703-487-4650
     The EPA Project Officer can be contacted at:
             Industrial Environmental Research Laboratory
             U.S. Environmental Protection Agency
             Research Triangle Park, NC27711
United States
Environmental Protection
Agency
Center for Environmental Research
Information
Cincinnati OH 45268
Postage and
Fees Paid
Environmental
Protection
Agency
EPA 335
Official Business
Penalty for Private Use $300
              PS    0000329

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